Material Safety Data Sheet (MSDS) - Caustic Soda

Section 1: Chemical Product and Company Identification

Product Name : Caustic Soda

CAS# : 1310-73-2
TSCA : TSCA 8(b) inventory: Sodium hydroxide
CI# : Not available.
Synonym : Sodium Hydroxide
Chemical Formula : NaOH

COMPANY IDENTIFICATION
Supplier: Pon Pure Chemicals Group
CHENNAI, TAMILNADU, INDIA
24 Hour Health Emergency (91) 8939878447
(91) 9444038694
Transportation Emergency Phone (91) 8939768680
Company Name Place EMERGENCY TELEPHONE NUMBER
Pon Pure Chemicals Group India Day Emergency – 044-26161803-26161809

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Sodium hydroxide 1310-73-2 100

Toxicological Data on Ingredients: Sodium hydroxide LD50: Not available. LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant,
corrosive), of ingestion, of inhalation. The amount of tissue damage depends on length of contact. Eye
contact can result in corneal damage or blindness. Skin contact can produce inflammation and
blistering. Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract,
characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage,
choking, unconsciousness or death. Inflammation of the eye is characterized by redness, watering,
and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally,

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blistering.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC
EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs.
Repeated or prolonged exposure to the substance can produce target organs damage. Repeated
exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can
produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying
degree of respiratory irritation or lung damage.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of
water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water
may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek
medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt
or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform
mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give
mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek
immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product : Non-flammable.

Auto-Ignition Temperature : Not applicable.
Flash Points : Not applicable.

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Flammable Limits : Not applicable.
Products of Combustion : Not available.
Fire Hazards in Presence of Various Substances: of metals
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of
the product in presence of static discharge: Not available. Slightly explosive in presence of heat.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards:
sodium hydroxide + zinc metal dust causes ignition of the latter. Under proper conditions of
temperature, pressure and state of division, it can ignite or react violently with acetaldehyde, ally
alcohol, allyl chloride, benzene-1,4-diol, chlorine trifluoride, 1,2 dichlorethylene, nitroethane,
nitromethane, nitroparaffins, nitropropane, cinnamaldehyde, 2,2-dichloro-3,3-dimethylbutane.
Sodium hydroxide in contact with water may generate enough heat to ignite adjacent combustible
materials. Phosphorous boiled with NaOH yields mixed phosphines which may ignite spontanously in
air. sodium hydroxide and cinnamaldehyde + heat may cause ignition. Reaction with certain metals
releases flammable and explosive hydrogen gas.
Special Remarks on Explosion Hazards:
Sodium hydroxide reacts to form explosive products with ammonia + silver nitrate. Benzene extract of
allyl benzenesulfonate prepared from allyl alcohol, and benzene sulfonyl chloride in presence of
aquesous sodium hydroxide, under vacuum distillation, residue darkened and exploded. Sodium
Hydroxde + impure tetrahydrofuran, which can contain peroxides, can cause serious explosions. Dry
mixtures of sodium hydroxide and sodium tetrahydroborate liberate hydrogen explosively at 230-270
deg. C. Sodium Hydroxide reacts with sodium salt of trichlorophenol + methyl alcohol +
trichlorobenzene + heat to cause an explosion.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary:
Neutralize the residue with a dilute solution of acetic acid.
Large Spill:
Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled
material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas;
dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution of acetic
acid. Be careful that the product is not present at a concentration level above TLV. Check TLV on the
MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep container dry. Do not breathe dust. Never add water to this product. In case of insufficient
ventilation, wear suitable respiratory equipment. If you feel unwell, seek medical attention and
show the label when possible. Avoid contact with skin and eyes. Keep away from incompatibles
such as oxidizing agents, reducing agents, metals, acids, alkalis, moisture.
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Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store
above 23°C (73.4°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne
levels below recommended exposure limits. If user operations generate dust, fume or mist, use
ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection:
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified
respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested protective clothing might
not be sufficient; consult a specialist BEFORE handling this product.
Exposure Limits:
CEIL: 2 from ACGIH (TLV) [United States] [1995] Consult local authorities for acceptable exposure
limits.

Section 9: Physical and Chemical Properties

Physical state and appearance : Solid.

Odor : Odorless.
Taste : Not available.
Molecular Weight : 40 g/mole
Color : White.
pH (1% soln/water) : 13.5 [Basic.]

Boiling Point : 1388°C (2530.4°F)

Melting Point : 323°C (613.4°F)
Critical Temperature : Not available.
Specific Gravity : 2.13 (Water = 1)
Vapor Pressure : Not applicable.
Vapor Density : Not available.
Volatility : Not available.
Odor Threshold : Not available.
Water/Oil Dist. Coeff. : Not available.
Ionicity (in Water) : Not available.
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Dispersion Properties : See solubility in water.
Solubility : Easily soluble in cold water.

Section 10: Stability and Reactivity Data

Stability : The product is stable.

Instability Temperature : Not available.
Conditions of Instability : Not available.
Incompatibility with various substances:
Highly reactive with metals. Reactive with oxidizing agents, reducing agents, acids, alkalis,
moisture.
Corrosivity : Not available.
Special Remarks on Reactivity:
Hygroscopic. Much heat is evolved when solid material is dissolved in water. Therefore cold
water and caution must be used for this process. Sodium hydroxide solution and octanol + diborane
during a work-up of a reaction mixture of oxime and diborane in tetrahyrofuran is very exothermic, a
mild explosion being noted on one occassion. Reactive with water, acids, acid chlorides, strong bases,
strong oxidizing agents, strong reducing agents, flammable liquids, organic halogens, metals (i.e
aluminum, tin, zinc), nitromethane, glacial acetic acid, acetic anhydride, acrolein, chlorohydrin,
chlorosulfonic acid, ethylene cyanohydrin, glyoxal, hydrochloric acid, sulfuric acid, hydrosulfuric acid,
nitric acid, oleum, propiolactone, acylonitrile, phorosous pentoxide, chloroethanol, chloroform-
methanol, tetrahydroborate, cyanogen azide, 1,2,4,5 tetrachlorobenzene, cinnamaldehyde. Reacts
with formaldehyde hydroxide to yield formic acid, and hydrogen.
Special Remarks on Corrosivity: Very caustic to aluminum and other metals in presence of
moisture.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans: Causes damage to the following organs: lungs.
Other Toxic Effects on Humans:
Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin
contact (corrosive, irritant, permeator), of eye contact (corrosive), of ingestion, .
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Dose: LDL [Rabbit] - Route: Oral; Dose: 500 mg/kg
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Special Remarks on Chronic Effects on Humans: May affect genetic material (mutagenic).
Investigation as a mutagen (cytogenetic analysis), but no data available.
Special Remarks on other Toxic Effects on Humans:

Acute Potential Health Effects: Skin: May be harmful if absorbed through skin. Causes severe
skin irritation and burns. May cause deep penetrating ulcers of the skin. Eyes: Causes severe eye
irritation and burns. May cause chemical conjunctivitis and corneal damage. Inhalation: Harmful if
inhaled. Causes severe irritation of the respiratory tract and mucous membranes with coughing,
burns, breathing difficulty, and possible coma. Irritation may lead the chemical pneumonitis and
pulmonary edema. Causes chemical burns to the respiratory tract and mucous membranes.
Ingestion: May be fatal if swallowed. May cause severe and permanent damage to the digestive tract.
Causes severe gastrointestinal tract irritation and burns. May cause perforation of the digestive tract.
Causes severe pain, nausea, vomiting, diarrhea, and shock. May cause corrosion and permanent
destruction of the esophagus and digestive tract.

Section 12: Ecological Information

Ecotoxicity : Not available.

BOD5 and COD : Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation
products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are
not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control
regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material

Identification: : Sodium hydroxide, solid UNNA: 1823 PG: II
Special Provisions for Transport: Not available.

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Section 15: Other Regulatory Information

Federal and State Regulations:

Illinois toxic substances disclosure to employee act: Sodium hydroxide Illinois chemical safety act:
Sodium hydroxide New York release reporting list: Sodium hydroxide Rhode Island RTK hazardous
substances: Sodium hydroxide Pennsylvania RTK: Sodium hydroxide Minnesota: Sodium hydroxide
Massachusetts RTK: Sodium hydroxide New Jersey: Sodium hydroxide Louisiana spill reporting:
Sodium hydroxide California Director's List of Hazardous Substances: Sodium hydroxide TSCA 8(b)
inventory: Sodium hydroxide CERCLA: Hazardous substances.: Sodium hydroxide: 1000 lbs. (453.6
kg)
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS:
This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): CLASS E: Corrosive solid.
DSCL (EEC):
HMIS (U.S.A.):
Health Hazard :3
Fire Hazard :0
Reactivity :2
Personal Protection :j
National Fire Protection Association (U.S.A.):
Health :3
Flammability :0
Reactivity :1
Specific hazard:Protective Equipment:
Gloves, Synthetic apron, Vapor and dust respirator. Be sure to use an approved/certified
respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash
goggles.

Section 16: Other Information

The information and recommendations contained herein are, to the best of Pon Pure Chemicals
Group knowledge and belief, accurate and reliable as of the date issued. You can contact Pon Pure
Chemicals Group to ensure that this document is the most current available from Pon Pure
Chemicals Group. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended
use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and
other necessary information is included with and/or on the container. Appropriate warnings and safe-

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handling procedures should be provided to handlers and users. Alteration of this document is strictly
prohibited. Except to the extent required by law, re-publication or retransmission of this document, in
whole or in part, is not permitted.

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