ANNUAL EXAMINATION2022-23)

CLASS- XI |13S
CHEMISTRY

(SET- B

Time: 3 Hr. Max. Marks: 70

General Instructions:
Read the following instructions carcfully.
(a) There are 35 questions in this question paper with internal choice.
(b) SECTIONAconsists of 18 multiple-choice questions carrying I mark each
(c) SECTION B consists of 7 very short answer questions carrying 2 marks cach.
(d) SECTIONC consists of 5 short answer questions carrying 3 marks each.
(e)SECTION D consists of 2 case- based qucstions carrying 4 marks cach.
( SECTION E consists of 3 long answer questions carrying 5 marks each.
(g)All questions are compulsory.
h) Use of log tables and calculators is not allowed.

SECTIONA
The following questions are multiple-choice questions with one correct answer.
Each question carries 1 mark. There is no internal choice in this section.
QA. Principal. Azimuthal and magnetic quantum numbers are respectively related to:
a) Size, shape and orientation . (b) Shape, size and orientation
(c) Size. orientation and shape (d) None of the above
Q2. For a reaction A+2B C , the amount ofC formed by starting the reaction with 5 moles
of A and 8 moles of B is
(a) 5 moles ( b ) 8 moles
(c) 16 moles 4d) 4 moles
Q3. When propene is treated with HBr, the major preduct formed is
(a) 1-Bromopropane (b 2-Bromopropane
(c) 1,2-dibromopropane (d) Bromopropyne
4. Molality of a solution does not change with
(a) Volume b) Temperature
/ (c) Density (d) Concentration
.5. Mass percent of a solution containing 2 g of a substance A in 18 g of water is
(ay 10% (b) 15%
(c) 5% (d) 20%
Q6/ In wbich of the following pairs, the two molecules have identical bond orders:

N.0.2 (b) N,, 0,

(c) N,2,0, (d) O,N,
Q. Which of the following is not permissible'
(a) 4,I = 3. m0 (b) n-4, 1 2, m-
n= 4, 1 = 4, m= I
(d) n4, 1 0 , m= 0

XI-Chemistry-B () P.T.O.
 electron gain enthalpy?
98. Which of the following elements has the maximum negative
(a) Oxygen Cby Chlorine This section con
(c) Fluorine (d) Nitrogen following questio-
Show the resonanc
Q9. What type of reaction is shown by the reaction
para and meta dire
2H,0, (aq) 2H,O) + 0,(g)
(a) Combination reaction f b ) Displacement reaction /la) CH,CH,
Q.20. 50kg of N,(g) an
'(c) Decomposition reaction Disproportionation reaction of NH(g) formed
Qro. Hyperconjugation is most useful for stabinzing which of the following carbocation
(a) Neopentyl carbocation Tert-butyl carbocation
(a) The densi
(c) Iso-propyl carbocation (d) Ethyl carbocation the soluti
1. The structure of
4-Methylpent-2-en-1-ol is: (b) Calculate
9) CHCH,CH=CHCH.,OH (b) (CH,),C-CHCH,CH,OH is 0.040.

c ) (CH)CHÇH-CHCH,OH (d) CH,CH(OH)CH-CH-C(CH) Q1. a) What do y

S) Calculate
Q.2. Which conformer of alkane is most stable? in enough
(a) Skew ub) Staggered
(d) None of these Q22. Draw the bounda
(c) Eclipsed
S-orbital
Q13. For an ideal gas, CV and CP are related as a)

(a) Cy-C, =R (b)C+ C, Three p

C , - C y =R Five d-or
(c) C-Cy R I
The electronic configuration of chromium Q23. Exp>ain the foll
Q14. (Z24) i:
(a) [Ne] 3s2 3ps 3d 4s* 6) [Ne] 3s* 3p 3d5 4s' Homolyti
(c) [Ne] 3s* 3p* 3d' 4s (d) Ne] 3s* 3p* 4s 4p Functiona
Q.15 to Q. 18 Given below are two statements labelled as Assertion (A) and Reason (R) Q.24. Calculate the en
AH 6.03 K
from the options given below:
Select the most appropriate answer
?
(a) Both A and R are true and R is the correct explanation of A
CP [HO)] =

(a) CP [HO(s)] =

(b) Both A and R are true but R is not the correct explanation of A.
Sc) A is true but R is false. ealculate the st
(d) A is false but R is true.
(i) CHOH
Crafts reaction.
Assertion (A) : Nitrobenzene does not undergo Friedel (ii) C(graphi
Reason (R) : Nitrobenzene is a m-directing
and exact
/ (ii) H,(g) +
Q46. Assertion (A) : It is impossible to determine the exact position momentum
Q25. Assign oxidatic
of an simultaneously.
electron
KAI(SO
Reason (R) : The path of an electron in an atom is clearly defined.
Assertion (A) : Second ionization enthalpy will be higher the first ionization enthalpy. KCr0,
Reason (R): lonization enthalpy is a quantitative measure ofthe tendency of an element
This section cor
to lose clectron. questions are st
2- ene are position isomers.
QJ8. Assertion (A) : Pent- 1- ene and penl-
Reason (R) : Position isomers differ in the poSilion of functional group or a substituent. Q.26. a Explain
Use Use the
to have 1

XI-Chemistry-B (2)
 SECTION-B
This section contains 7 questions win internal
following questions are very short answer type andchoice in two
questions. The
Show the resonance in the carry 2 marks each.
para and meta
following withproper curved arrow notation and discuss ortho/
directing groups:
/(a) CHCH (
Q.20. 50kg of N, (g) and 10 kg of H,(g) are mixed to CHCHO
of NH,(g) formed.
Identify the limiting reagent inproduce NH,(g). Calculate the amount
the production of
OR NH, in this solution.
(a) The density of 3 M solution
the solution.
of NaCl is 1.25 g ml-1. Calculate the
molality of
(b) Calculate the molarity of ethanol in water in
which the mole fraction
is 0.040. of ethanol
Q1. a) What do you mean by mole fraction?
Calculate the molarity of NaOH in the solution
in enough water to
prepared
form 100 ml of the solution.
by dissolving it's 40 g
,22. Draw the boundary surface diagrams assigning
proper coordinate axis of
S-orbital
Three p orbitals
Five Five d-orbitals
Q23. Explain the following with examples:
Homolytic/Heterolytic cleavage
Functional isomer of alcohol
Q.24. Calculate the enthalpy change on freezing of 1.0 mol
AH6.03 KJ mo at 0°C.
of water at 10.0°C to ice at -10.0°C.
CP [H,O()] 75.3 J mol' K.
=

CP [H,O(s)] 36.8 J mol' K".

=

OR
álculate the standard enthalpy of formation of CH,OH. from the following data:
() CH,OH() +3/2 0,(g) Co, (g) +2H,0 (); AH°= 726KJ mo -

i) C(graphite)+O,(g >CO,(g); AH° = -393KJ mol-1

Cii) H(g)+1/20,(g)- H,O (); AH° =
-286 KJ
Q.25. Assign oxidation number to the underlined,elements in each of themo
following species:
KAIKSO), 12 H,O XeO
KCr,O,
SECTION-
This section contains 5 questions with internal choice in two
questions. The following
questions are short answer type and carry 3 marks each.
Q.26. Explain the hybridization and shape of BrF, with proper diagram.
U s e the molecular orbital energy leve! dingram to show that N, would be expected
to have triple bond.

(3) XI-Chemistry-B P.T.O.

 27. the
Wnte net ionic equation for the reaction of potassium dichromate (VI), K,Cr,0, with
sodium sulphite, Na,SO,, in an acid solution to give chromium(ll) ion and the sulphate
ion. (Balance by Oxidation number method) Based on t

OR
Predict in
A lic
Permanganate (VII) ion, MnO, in hasic solution oxidises iodide ion, I to produce
molecular iodine (I,) and manganese (IV) oxide (MnO,). Write a balanced ionic b lemp
equation
to represent this redox reaction
(1Balance by Half-rection method). For C
Q28. (i) Which of the following molecules are aromatic in nature, Explain with all the 4Fe(s
necessary conditions of aromaticity. cntro
of thi
(AH

(a) Define
i)
(ii)
(b) Explai
(c) Differ=
Q32. The Table belc
OR Elements:
i) How many structure isomers are possible in diphenylmethane (C13H12) when one
of the hydrogen is replaced by chlorine atom?
a The Table beic
How will you differentiate between different
types of free radical. Group Elemen
Q29. Ja) What is the basic difference between orbit and orbital. Group 1
How many sub-shells are associated with the n= 4?
How many electrons would be present in the subshells having an ms value of -
Li
1/2 for n-4?
Na
930. Describe step-by-step complete mechanism for the addition of HBr for the
formation of 2-Bromopropane from propene.
How will you convert ethanoic acid into m-nitrochlorobenzene. Rd
SECTION-D Cs
The following questions are case-based questions. Each question has an internal choice
and carries 4 (1+1+2) marks each. Read the passage carefully and answer the The graphs bel
questions
that foilow. second period a
g31. We know that the heat absorbed at constant volume is equal to change in the internal a funetion of Z
energy i.e.. AU = q, . But most of chemical reactions are carried out not at constant
500
volume, but in flasks or test tubes under constant atmospheric pressure. We need to detine
another state function which may be suitable under these conditions.
Entropy as a measure of the degree of ralndomness or disorder in the system. The greater
1500
the disorder in an isolated system, the higher is the
entropy. The change in entropy
accompanying a chemical reaction may be estimatled qualitatively by a consideration of
the structures of the species taking part in the reaclion. Decrease of regularity in structure
would mean increase in entropy. For a given Substance, the crystalline solid state is the 5)
State of lowest entropy (most ordered), he gaseous state is state of highest entropy.

Fig(a)
(4)
XI-Chemistry-B XI-Chemistry-B
 Based on the above data, answer the 10llowing questions:

Predict in which of the following. entropy increases/decreases

a) A liquid crystallizes into a solid.

Temperature of a crystalline solid
is raiscd from 0 K to 115 K.
For oxidation of Iron:
4Fe(s) + 30, (s) ----2Fe,O,(s)
entropy change is -549,4 JK-lnol "at 298 K. Inspite of negativeentropy change
of this reaction, vlhy is the reaction spontaneous?
(AH° for this reaction is -1648 * 10'mol -)

OR
(a) Define the following:
(i) Third law of thermodynamics
ii) Gibbs free energy.
(b) Explain the relation between equilibrium constant and gibbs free energy
(c) Differentiate betveen extensive and intensive property.
Q32. The Table below shovws the Electron Gain Enthalpies / (kJ mol) of Some Main Group
Elements:

The Table beiow shows the Electron Gain Enthalpies / (k% mol-) of Some Main
Group Elements:

Group 1 AH Group 16 AH Group 177 AH Group 0 AH

H 73 He 48
Li - 60
141 F 328 Ne +16
Na 53 S -200 Cl 349 Ar 96
- 48
Se - 195
Br - 325 Kr 96
Rb 47 Te 190 295 Xe 77
Cs 46 Po 174 At 270 Rn
The graphs below shows
Fig. (a) First ionization enthalpies (A, H) of elements of the
second period as a function of atomic
number (Z) and Fig. (b) AH of alkali metals as
a function of Z.

2500
550
LI(5201
2000 N
500
(20401 Nat 496)
1500 N11)
450
1
1102)-
1000
100 b03)
LI
500 201 7
10 350L
Alomie numl» 1{79
t o n e umbeit

Fig.(a) Fig. (b)

XI-Chemistry-B (5)
 Answer the following
questions based on the abOve data
Which of the
following pairs af elemerts would have a most negative
gain enthalpy and electron
6) Why is ionization
whyi) o or F (GHYF or CI.

.(c)
enthalpy of nitrogen greater than that of oxygen?
Differentiate between lonization
cnthalpy and Elcctron gain enthalpy.
OR
Would you expect the second
Yess negative than the first? electron gain enthalpy of O as positive, more
negative or
Justily your answer.
The SECTIONE
following questions are long answer type and carry 5
questions have an internal choice. marks each. Two
Q.33. The value
of for the
KP reaction at 500k :

2NOCI(g)2NO(g) Cl,(g) is 1.8 10 bar'

+ x

Calculate Kc for reaction this temperature.

at
Explain
b

Lewis acid and bases with

examples each.
For the
following reaction
2H.(g)+CO (g)CH,OH (g)
Describe the effect of the
following on the equilibrium of the reaction:
(i) addition of H,
(ii) removal of CO
OR
(a) Distinguish between Homogcneois. and Hetrogeneous equiibrium?
(b) What is the law of chemical equilibrium? Explain
mathematically
(c) Derive the relation between Kp and Kc, where
Kp and Kc are the equiibrium
constant in terms of pressure and concentration
respectively.
34. (a) Discuss the mechanism of Electrophilic substitution reaction for the chlorination
of benzene.
(2)
(b) Give examples of o, p and m- directing substituents and discuss their effect on
the reactivity of benzene ring showing all the resonating structures. (3)
OR
Ca) Conyert the following: (2)
Ethanoic acid to Methane
h) 2-chlorobutane to but-2-ene
( Explain the mechanism of Kolbe's electrolysis of sodium ethanoate (CH,COONa)

Q.35. 4)) Which out of NH, and NF, has higher dipole moment and why?
Compare the relative stability'of the following species and indicate their magnetic

properties: O,, 0, (Superoxide),0,* (peroxide).

the axial bonds longer
Describe the hybridisation in case of PCI,. Why
are as

compared to equatorial bonds?

st, P, c '

XI-Chemistry-B