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Chapter - 2 (Solution)

This document contains a chemistry test with multiple choice and short answer questions covering the topic of solutions. The multiple choice questions cover concepts like molality, Raoult's law, azeotropes, colligative properties, and Henry's law. The short answer questions require defining key terms, explaining phenomena like changes in boiling point and freezing point, and solving problems involving concentration, molar mass, and colligative properties. Long answer questions involve experimental observations with salt solutions and eggs as well as calculating molar mass from osmotic pressure data.

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94 views4 pages

Chapter - 2 (Solution)

This document contains a chemistry test with multiple choice and short answer questions covering the topic of solutions. The multiple choice questions cover concepts like molality, Raoult's law, azeotropes, colligative properties, and Henry's law. The short answer questions require defining key terms, explaining phenomena like changes in boiling point and freezing point, and solving problems involving concentration, molar mass, and colligative properties. Long answer questions involve experimental observations with salt solutions and eggs as well as calculating molar mass from osmotic pressure data.

Uploaded by

Acoustify -Music
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Class-12

Subject-Chemistry
Topic-Solution

1.The molality of 98% H2 SO4 (density = 1.8 g/mL) by weight is:


(a) 6 m (b) 18 m (c) 10 m (d) 4 m

2.Which of the following does not show positive deviation from Raoult's law?

3.Which condition is not satisfied by an ideal solution?

4.. Azeotrope mixture are:


(a) mixture of two solids
(b) those will boil at different temperature
(c) those which can be fractionally distilled
(d) constant boiling mixtures

5.

6.. Solute when dissolve in water


(a) increases the vapour pressure of water
(b) decreases the boiling point of water
(c) decrease the freezing point of water
(d) All of the above
7.Which of the following is true for Henry's constant
(a) It decreases with temperature
(b) It increases with temperature
(c) Independent on temperature
(d) It do not depend on nature of gases.

8.Which one is the best colligative property for determination of molecular mass of polymer?
(a) osmotic pressure
(b) elevation in boiling point
(c) depression in freezing point
(d) osmosis
VERY SHORT ANSWER TYPE QUESTIONS (1 Mark)
1.What role does the molecular interaction play in the solution of alcohol and water ?
2.. Why NaCl is used to clear snow from roads ?

3.. Why the boiling point of solution is higher than pure liquid ?

4.Henry law constant for two gases are 21.5 and 49.5 atm, which gas is more soluble ?

5.Define azeotrope. Give an example of maximum boiling azeotrope.

6.. Calculate the volume of 75% of H2 SO4 by weight (d = 1.8 gm/ml) required to prepare 1 L of 0.2 M solution.

7.Why water cannot be completely separated from aqueous solution of ethyl alcohol ?

8.Why osmotic pressure is considered as colligative property ?

9.Liquid A and B on mixing produce a warm solution. Which type of deviation does this solution show ?

10.What role does the molecular interaction play in solution containing chloroform and acetone ?
SHORT ANSWER TYPE QUESTIONS (2 Marks)

1.On mixing liquid X and Y, volume of the resulting solution decreases. What type of deviation from
Raoult’s law is shown by the resulting solution ? What change in temperature would you observe after
mixing liquids X and Y ?

2.Explain the significance of Henry’s constant (KH). At the same temperature, hydrogen is more soluble
in water than helium. Which of them will have higher value of KH and why ?

3.. What do you mean by colligative properties ? Which colligative property is used to determine molar
mass of polymer and why ?

4.Why is it advised to add ethylene glycol to water in a car radiator in hill station ?

5.Define Henry’s law. Give their two application

6.. The dissolution of ammonium chloride in water is endothermic process. What is the effect of
temperature on its solubility ?

7.Why is liquid ammonia bottle first cooled in ice before opening it ?

8.

9.
10.

11.

12.

13.

14.

LONG ANSWER TYPE QUESTIONS (5 Marks)


1.

2.
(a) Outer shells of two eggs are removed. One of the egg is placed in pure water and the other is placed
in saturated solution of NaCl. What will be observed and why ?

(b) A solution prepared by dissolving 8.95 mg of a gene fragment in 35.0 ml of water has an osmotic pressure of
0.335 ton at 25ºC. Assuming the gene fragment is a non-electrolyse, determine the molar mass.
Questions based on Vant hoff’s factor

1.What is Van’t Hoff factor ?

Q. 2. What is the Van’t Hoff factor in K4 [Fe(CN)6 ] and BaCl2 ?

Q. 3. Why the molecular mass becomes abnormal ?

Q.4.. What is van’t Hoff factor ? How is it related with :


(a) degree of dissociation (b) degree of association
Q.5.

Q6.Which of the following solutions have highest boiling point and why ?
(a) 1M glucose (b) 1M KCl (c) 1M aluminium nitrate

Q.7.

Q.8.

Q.9.

Q10.

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