Thermodynamics 2 - 2
Thermodynamics 2 - 2
ME 325
CHAPTERS
1.   POWER FROM TWO PHASE SYSTEMS
2.   INTERNAL COMBUSTION ENGINES
3.   GAS COMPRESSORS
4.   STEAM ENGINES
5.   STEAM TURBINES
6.   HEAT TRANSFER
7.   FUELS AND COMBUSTION
8.   STEAM GENERATING UNITS
Chapter 1: POWER FROM TWO PHASE SYSTEM
TURBINE WT
             BOILER                                               2
 QA
                                                                        wO
                                                  CONDENSER                  QR
                                                                        wi
                                                                   3
                      B3                   PUMP
WP
                                                  1
  T
T1
                             evaporation
        B3                                                      S1=S2
WP
P2=P3
                           condensation           2   X2
               3
                           b) T – S diagram                             S
Rankine cycle is the ideal cycle for vapor power plants.
CYCLE ANALYSIS
1 – 2 : Isentropic expansion
2 – 3 : Constant pressure heat rejection
3 – B3 : Adiabatic pumping
B3 – 1 :Constant pressure addition of heat
A) BOILER
                  h1
                                QA + hB3 = h1
                                QA = h1 - hB3 , kJ/kg
                                QA = ms , kg/s (h1 - hB3) kJ/kg , kW
 QA          boiler             Where:
                                     h1 = h at P1, T1 (Table 3)
                                     QA = Heat added, kJ/kg
hB3
B) TURBINE
h1
                                                  W T + h 2 = h1
                turbine                           WT = h1 - h2 , kJ/kg
                                        WT
                                                  WT = ms, kg/s (h1 - h2) kJ/kg , kW
                           h2
C) CONDENSER                           Q R + h3 = h 2
                                       QR = h2 - h3 , kJ/kg
          h2                           QR = ms , kg/s (h2 - h3 ) kJ/kg , kW
                       wo              QW = mWCPWΔTW
                              QR       QW = [mCP (TWi n – TWout)]
                       wi              By heat balance : QR = QW
                                       mWCPWΔTW = ms (h2 - h3 )
          h3                                  ms (h2 − h3 )
                                       mw =
                                                  CP ∆T
               Where:
                    QR = heat rejected in the condenser
                    h2 = h at P2 and S1 = S2 , kJ/kg
                    h3 = hf at P2 = P3 , kJ/kg
                    mS = mass flow of steam , kg/s
                    mW = mass flow of cooling water , kg/s
                    TW = temperature of cooling water in
                    and out the condenser 0C
D) PUMP
                                        WP + h3 = hB3
                                        WP = hB3 - h3 , kJ/kg
hB3                                     WP = ms , kg/s (hB3 - h3) kJ/kg , kW
                            h3          WP = Vf3, m3/kg (PB3 - P3)kPa, kJ/kg
                                        Where:
                            WP               WP = pump work
                                             hB3 = enthalpy of feed water , kJ/kg
                                             h3 = hf at P2 = P3 , kJ/kg (table 2)
                                             Vf3 = specific volume of water entering
                                             the pump , m3/kg
                                             Vf3 = Vf at P3 (table 2)
EFFICIENCIES WITH STEAM RATES
  For cycle:
               Wnet   WT − WP
     eC =           =         x 100%
                QA      QA
   For engine:
               WT     WT
     eT =         =          x 100%
               EC   h1 − hf2
  Where:
       EC = energy chargeable to the engine
       EC = h1 – hf2 , (hf2 = last saturated enthalpy)
               3600 kJ/kW − Hr              kg
     WT =                      ,                         (For engine)
                  WT , kJ/kg              kW − Hr
             3600 kJ/kW − Hr ,             kg
     WC    =                             kW − Hr          (For cycle)
                WC , kJ/kg
                     3600 kJ/kW − Hr
     𝑒=                                        𝑥100%
          WS     , kg/kW – Hr h1 − hf2 , kJ/kg
        Ideal and Actual cycle
                                                                 W’ = actual work = WB
T                                1
                                          T1                     W’ = h1 – h2’ , kJ/kg
                                               S
              T – S diagram                                          WB
                                                                             nb          ng
TURBINE Gen WK
QA                                                       2
              BOILER                                                 wO
                                 CONDENSER                              QR
                                                                     wi
                       B3                 PUMP
                                                             3
                                                                    where:
                                                        WP                  nb = break efficiency
          Schematic diagram                                                 ng = generator efficiency
                                                                            WB = break work
                                                                            Wi = indicated work
     Efficiencies
                                                                            Wk = combined work
              WB                                                            ek = combined efficiency
     nb =        x 100%
              WI                                                            Wk = combined steam rate
              Wk
     ng =        x 100%                                                Mean Effective Pressure (Pm)
              WB
              Wk      Wk                                                            WI , kJ/kg
     ek =        =          x 100%                                         Pm =                 , kPa
              Ec   h1 − hf2                                                         VD , m3 /kg
                                                                          where:
                                     kJ
                        3600                                                  VD = V2 = volume displacement
                                 kW −Hr
     ek =                   kg                     kJ   x 100%                V2 = Vf2 + X2Vfg2
                  Wk   kW −Hr
                                 h1 − hf2 ,
                                                   kg
PROBLEMS:
 Given:
 QA = 4220 kJ/min
 WP = 2 kW                                                       1
 WT = 22.4 kW
                                                                             WT =22.4 kW
                                                                TURBINE
 Required:
   a) Wnet
                 QA =4220 kJ/min
   b) QR                           BOILER                                2
   c) ec                                                                     wO
                                                        CONDENSER                 QR
                                                                             wi
                                            B3                       3
                                                       PUMP
Solution:
For a) WP=2 kW
Wnet = WT - WP
Wnet = 22.4 kW – 2 kW
Wnet = 20.4 kW
                                            For c)
For b)                                           Wnet
                                            eC =      x 100%
By the first law of thermodynamics:               QA
Ein = Eout                                       1224 kJ/min
                                            eC =             x 100%
                                                 4220 kJ/min
For the cycle:
                                            eC = 29%
QA = Wnet + QR
QR = QA - Wnet
QR = 4220 kJ/min – 20.4 kW
QR = 4220 kJ/min – 1224 kJ/min
QR = 2996 kJ/min
   2. The condensing pressure for a Rankine engine is 1 bar ( h f = 417.4
      kJ/kg). Calculate the net work for 1 kg/s steam at the beginning of the
      expansion is at 50 bar and (a) saturated, (b) 350 0C, (c) 640 0C. note
      the variation of efficiency and of the quality at the end of the
      expansion.
                                             T                P1 = 50 bars
Given:                                                                       1
P2 = 1 bar = 0.1 MPa
                                                     B3
Required:
       Wnet                                                   P2 = 1 bar         2
       ec
                                                          3
for a: 50 bar and saturated
for b: 50 bar and 350 0C
for b: 50 bar and 640 0C                                          TS diagram for a)   S
                                                 For Wnet
                                                 WT = (h1 – h2)ms
For a)                                           WT = (2794.3 – 2158.97)ms
From steam tables                                WT = 635.33 kJ/kg (1 kg/s)
At P1 = 5 MPa and saturated (table 2)            WT = 635.33 kW
h1 = hg at 5.0 MPa
h1 = 2794.3 kJ/kg                                For ec
S1 = Sg at 5.0 MPa                                    WT h1 − h2
S1 = 5.974 kJ/kg – K                             eC =    =          x 100%
                                                      EC   h1 − hf2
                                                      2794.3 − 2158.3
                                                 eC =                  x 100%
                                                      2794.3 − 417.36
                                                 eC = 26.73%
                                                 For c)
    For b)
                                                 From steam tables
    From steam tables
                                                 At P1 = 5 MPa and 640 0C (table 3)
    At P1 = 5 MPa and 350 0C (table 3)
                                                 h1 = 3759.6 kJ/kg
    h1 = 3068.4 kJ/kg
                                                 S1 = 7.3632 kJ/kg – K
    S1 = 6.4493 kJ/kg – K
    For h2                                       For h2
    S1 = S2 = Sf2 + X2Sfg2                       S1 = S2 = Sf2 + X2Sfg2
    6.4493 = 1.3026 + X2(6.0568)                 7.3632 = 1.3026 + X2(6.0568)
    X2 = 0.8497 = 84.97%                         X2 = 1.00 = 100%
T P1 = 50 bars 1 T P1 = 50 bars
B3 B3
                 P2 = 1 bar                                   P2 = 1 bar
                                2                                                     2
             3                                           3
                                         S                                                S
                 TS diagram for b)
                                                  For Wnet
    For Wnet
                                                  Wnet = WT assuming that WP = 0
    Wnet = WT assuming that WP = 0                WT = (h1 – h2)ms
    WT = (h1 – h2)ms                              WT = (3759.6 – 2676.78)ms
    WT = (3068.4 – 2336.0709)ms                   WT = 1082.82 kJ/kg (1 kg/s)
    WT = 732.329 kJ/kg (1 kg/s)                   WT = 1082.82 kW
    WT = 732.329 kW
For ec For ec
         WT h1 − h2                                    WT h1 − h2
    eC =    =          x 100%                     eC =    =          x 100%
         EC   h1 − hf2                                 EC   h1 − hf2
             732.329 kJ/kg                                 1082.82 kJ/kg
    eC =                        x 100%            eC =                        x 100%
         (3068.4 − 417.36)kJ/kg                        (3759.6 − 417.36)kJ/kg
                                                  eC = 32.4%
    eC = 27.62%
       3. A steam is generated at 4.0 MPa at 440 0C, condensation occurs at
          0.105 MPa.
          a) For the rankine engine operating on the same limits, compute the
             efficiency and heat rate.
          b) For the rankine cycle occurs between the same limits, determine
             QA, QR, W net and ec.
          c) What mass flow rates is required for a net output of 30 MW.
    Given:
    P1 = 4.0 MPa T1 = 440 0C                                                  1
    P2 = 0.105 MPa
                                                                             TURBINE            WT
    Solution:
                               QA         BOILER                                      2
                                                                                           wO
                                                                   CONDENSER                    QR
                                                                                           wi
                                                   B3                             3
T               P1 = 4.0 MPa        1                            PUMP
                                    T1 = 440 0C
       B3                                                                    WP
             P2 = 0.105 MPa
                               2
            3
                                                    mS = 136,774.2181 kg/Hr
Q R = h2 – h3
QR = (2513.412185 - 423.24) kJ/kg
QR = 2090.1721 kJ/kg
    4. Steam at 100 bar, 600 0C is received by a Rankine engine and
       exhaust at 2 bar; ∆P and ∆K are negligible. (a) for the ideal engine,
       find W, W, e, and Pm. (b) for the actual engine nb = 84 %, ng = 93 %
       and the driven generator produces 30 MW. Find W k, ek, total throttle
       flow, and estimate the exhaust enthalpy h2’.
Given:
                                                                            WB   nb = 84 % ng = 93 %
                     0                          P1 = 10 MPa T1 = 600 0C
P1 = 10 MPa T1 = 600 C
P2 = 0.2 MPa                                                        1
nb = 84 %
ng = 93 %                                                                                     WK
                            QA                       P2 = 0.2 MPa       2
                                                                             wO
Required:                                                                       QR
                                                                             wi
For a: (for ideal engine)
       Wi, W, e, and Pm                    B3
                                                                        3
For b: (for actual engine)
       Wk, ek, total throttle                                       WP
       flow, h2’.
Solution:
                                                    h2 = hf2 + X2hfg2
For a)                                              h2 = 504.70 + (0.95994)( 2201.9)
From steam tables                                   h2 = 2618.39811 kJ/kg
At P1 = 10 MPa and T1 = 600 0C (table 3)
h1 = 3625.3 kJ/kg                                   For Wi
S1 = 6.9029 kJ/kg – K
                                                    Wi = (h1 – h2)kJ/kg
At P2 = 0.2 MPa (table 2)                           Wi = (3625.3 - 2618.39811) kJ/kg
                                                    Wi = 1006.90189 kJ/kg
hf2 = 504.70 kJ/kg S f2 = 1.5301 kJ/kg – K
hfg2 = 2201.9 kJ/kg S fg2 = 5.5970 kJ/kg – K        For W
Vf2 = 0.0010605 m3/kg                                     3600 kJ/kW – Hr
                                                     W=
For Vfg2                                                     Wi , kJ/kg
Vfg2 = Vg2 – Vf2                                          3600 kJ/kW – Hr
                                                      W=
Vfg2 = 0.8846395 m3/kg                                    1006.90189kJ/kg
                                                                      kg
                                                      W = 3.5753
For h2                                                            kW – Hr
S1 = S2 = Sf2 + X2Sfg2
6.9029 = 1.5301 + X2(5.5970)
X2 = 0.95994 = 95.994 %
For e
    WT h1 − h2
e =    =          x 100%
    EC   h1 − hf2                           For h2’
     1006.90189kJ/kg
e =                    x 100%               h2’ = h1 – WB
    (3625.3 − 504.70 )
                                            h2’ = 3625.3 kJ/kg – 845.7975876 kJ/kg
e = 32.266 %                                h2’ = 2779.502412 kJ/kg
For Pm
V2 = Vf2 + X2Vfg2
V2 = [0.0010605 + 0.95994 (0.8846395)] m 3/kg
V2 = 0.85026 m3/kg = V2
       1006.90189kJ/kg
  Pm =                 , kPa
        0.85026 m3/kg
  Pm = 1184.266 , kPa
                                       For ms
For b)                                                 kg              kJ
                                       H. R.k = Wk ,        (h1 − h2 )
                                                    kW – Hr            kg
For Wk                                            3600       kg                      kJ
WB = nbWi                              H. R.k =                    (3625.3 − 504.70)
                                                786.59176kW – Hr                     kg
WB = (0.84)(1006.90189 kJ/kg)                                   kJ
WB = 845.7975876 kJ/kg                 H. R.k = 14,282.07187
                                                             kW – Hr
Wk = ngWB
Wk = (0.93)( 845.7975876 kJ/kg)        ms = (Pout)(Wk )
Wk = 786.5917565 kJ/kg                 ms = (30000 kW)(4.57671kg/kW - Hr)
                                       ms = 137,301.5167 kg/Hr
For ek
     Wk       Wk
ek =     =          x 100%
     Ec    h1 − hf2
        786.5917565kJ/kg
ek =                         x 100%
     (3625.3 − 504.70) kJ/kg
ek = 25.20642%
     The Regenerative Cycle
                                                               mT
                                                                                       TURBINE
                                                                           1
                                                                                                                      WT
                                                                                                          5
              BOILER                                                               2 3
QA                                           m1                                              4
                                                                    m2                                                     QR
                                                                                                       CONDENSER
m3
                B9                               B8                   B7                    B6                6
                                9       O.H.               8   O.H.            7   O.H.
                                         3                      2                   1                     ( mT – m1 – m2 – m3)
                                                                                                                  S
                                                      T – S diagram
By heat balance E in = Eout
      A) BOILER
                       h1
                                          QA + hB9 = h1
                                          QA = h1 - hB9 , kJ/kg
                                          QA = mT, kg/s (h1 - hB9) kJ/kg , kW
QA              boiler                    Where:
                                               h1 = h at P1, T1 (Table 3)
                                               QA = Heat added, kJ/kg
                       hB9
     B) TURBINE
     h1 m                          WT = mTh1 – m1h2 – m2 h3 – m3 h4 – h5 (mT – m1 – m2 – m3)
          T
                                                 Where:
                                           WT     mT = total mass of steam ,kg/Hr
                                                  m1, m2, m3, = masses of extracted steam
                              h5
h2 h3 h4
 D) CONDENSER
         h5 (mT – m1 – m2 – m3)
                                            Q R + h6 = h5
                                            QR = h5 – h6 , kJ/kg
                                            QR = (mT – m1 – m2 – m3), kg/s (h5 – h6 ) kJ/kg , kW
                             QR
               (mT – m1 – m2 – m3)
          h6
      C) PUMP
                                                WP4 + h9 = hB9
hB9
                                                WP = hB9 – h9 , kJ/kg
                                     h9
                                                WP = mT, kg/s (hB9 – h9) kJ/kg , kW
                                                WP = Vf9, m3/kg (PB9 – P9)kPa, kJ/kg
                                   WP4
E) OPEN FEED WATER HEATER
PROBLEMS:
                                                                                                          S
Solution:
                                               For h4
Solving for h1, h2, h3, h4                     S1 = S2 = S3 = S4 = Sf4 + X4Sfg4
                                               6.7179 = 0.5210+ X2(7.8094)
From steam tables                              X4 = 0.793518068 = 79.3518068 %
At P1 = 6.0 MPa and T1 = 455 0C (table 3)      h4 = hf4 + X4hfg4
h1 = 3311.1 kJ/kg                              h4 = 151.53 + (0.793518068)( 2415.9)
S1 = 6.7179 kJ/kg – K                          h4 = 2068.5903 kJ/kg
                                                              h2 m1
For h3
S1 = S2 = S3 = S4 = Sf3 + X3Sfg3
6.7179 = 2.2166 + X2(4.3067)
                                                                                h6
X3 = 1.045185409 = 104.5185409 %
                                                 h7          O.H.
h3 = hf3 + X3hfg3                                                             (mT – m1)
                                                              2
h3 = 798.65 + (1.045185409)( 1968.2)
h3 = 2874.5973 kJ/kg                              mT
     m1 h2 + h6(mT – m1) = h7mT
h3 m2
                                      h5
         h6       O.H.            (mT – m1 – m2)
                   1
      (mT – m1)
h1 m T
WT
                                                                  (mT – m1 – m2)
                                                                  h4
                              m1                    m2
                                   h2          h3
WT = mTh1 – m1h2 – m2 h3 – h4 (mT – m1 – m2)
 For c)                                                  For eC
                                                                  Wnet WT − WP
 For eT                                                  eC =          =          x 100%
                                                                   EC     h1 − hf
                                                                              kJ
          WT      WT                                              983.1871723 − 6.0323616kJ/kg
                                                                                           kg
 eT =         =         x 100%                           eC =                               kJ               kJ   x 100%
          EC    h1 − hf                                                           3311.1          − 990.59
                           kJ                                                               kg               kg
             983.1871723                                 eC = 42.109485%
                             kg
 eT =              kJ              kJ   x 100%
          3311.1        − 990.59
                   kg              kg                    For QA
                                                         QA = h1 – hB7 = h1 – (h7 + WP3)
 eT = 42.36944345%                                       QA = 3311.1 – (990.59 + 3.8688)
                                                         QA = 2316.6412 kJ/kg
The Reheat Cycle
QRH
Reheater
                                                          2
                                                                      3
                                                   1
TURBINE WT
       QB                                                     4
                 BOILER                                                     wO
                                            CONDENSER                          QR
                                                                            wi
                                                          5
                          B5
                                            PUMP
WP
                                                          1
                                                               T1
   T                                                                  3
                                                                            S1=S2
                                    P1
                                 evaporation
            B5                                            2
                                  P2 – P3
WP
                                      P4                          4       S3=S4
                               condensation
                   5
                                                                                       S
                               b) T – S diagram
Cycle Analysis
  5) e = thermal efficiency
                                                       H. R. rankine − H. R. reheater
                                      % improvement=                                  X 100%
                                                                H. R. rankine
 PROBLEMS:
       1) Steam at 10 MPa, 500 0C enters an ideal engine that has one stage
          of reheat: exhaust is at 0.05 MPa and 85% quality. The work
          produced by the engine is 800 kJ/kg of steam. Determine the
          thermal efficiency of the engine.
     Given:                                                                           T1 =5000C
                                                                                  1
                                               T                                          3
     P1 = 10 MPa
     T1 = 500 0C                                                    P1 = 10 MPa
     P4 = 0.05 MPa                                      B5                            2
     WT = 800 kJ/kg
     X4 = 85 %
                                                        WP
                                                                 P4 = 0.05 MPa
     Required:                                               5                X4 = 85 % 4
                                      QRH
       a) eT
                           Reheater
                 P1 = 10 MPa                   3
                 T1 =500 C 0          2
                                  1
                                                        WT = 800 kJ/kg
                                  TURBINE
QB
     BOILER             P4 = 0.05 MPa 4
                                                   wO
                           CONDENSER                    QR
                                                   wi
         B5                PUMP            5            Q A = WT + Q R
                                      WP
                                                        For QR:
                                                        Q R = h 4 – h5
     Solution:
     From steam tables                                  But:
     At P4 = 0.05 MPa (table 2)                                  h4 – h5 = X4hfg4
                                                                 h4 – h5 = (o.85 %)(2305.4 kJ/kg)
     hf4 = 340.49 kJ/kg                                          h4 – h5 = 1959.59 kJ/kg = Q R
     hfg4 = 2305.4 kJ/kg
                                                        QA = 800 kJ/kg + 1959.59 kJ/kg
     for eT                                             QA = 2759.59 kJ/kg
              WT                                                800 kJ/kg
     eT =        X 100%                                 eT =                  X 100%
              QA                                              2759.59 kJ/kg
                                                        e T = 28.9898 %
Chapter 2: INTERNAL COMBUSTION ENGINES
Internal combustion engine is a heat engine deriving its energy by the heat
liberated by the mixture of some hydrocarbons with the atmospheric air.
           CYLINDER
       CYLINDER
         PISTON
       PISTON
PISTON ROD
   P                                            T
                                                                            3
             3
                           S=C                             V=C
                                       4              2
             2                                                              4
                        S=C
                                       1             1         V=C
1 – 2: isentropic compression, S = C
2 – 3: constant volume addition of heat, V = C
3 – 4: isentropic expansion, S = C
4 – 1: constant volume rejection of heat, V = C
Point 1 – 2: S = C
                          k−1
             T2     V1
                =
             T1     V2
             T2
                = rkk−1
             T1
Computing for the size
of the engine
Efficiencies and
Mean effective pressure
                                                 WB = Pmb LANc , kW
eb = brake thermal efficiency                    WB = 2πTN , kW
                         kJ                      Where: Pmb = brake mean effective
              3600
                      kW −Hr
eb =             kg                kJ
                                        X 100%         pressure, kPa
       mfb                   HHV                        A= πD2/4
             kW −Hr                kg
                                                 WI = PmI LANc , kW
ei = indicated thermal efficiency
                        kJ                       PS = shaft power
             3600
                      kW −Hr
ei =           kg              kJ
                                        X 100%            2π T, ft − lb N, rpm
       mfi              HHV                      Bhp =
             kW −Hr            kg                                              ft −lb
                                                                     33000
                                                                             hp −min
nm = mechanical efficiency
                                                                lb                  π
        WB       eb                                       P,           L, ft            D2 , in2   N, rpm c
nm =         =        X 100%                     Ihp =          in 2                4
        WI       ei                                                                       ft −lb
                                                                         33000
                                                                                         hp −min
ni = indicated engine efficiency
     ei                            1
ni =    X 100% where: e = e = 1 − k−1 X 100%
      e                          rk
nb = brake engine efficiency
nb = ni X nm
PROBLEMS:
  P1 = 1 atm                                       3
  T1 = 15.6 0C
  LHV= 37252 kJ/m3                                              S=C
  rk = 6                                                                    4 P1 = 1 atm
  k = 1.33
  nm = 81 %                                        2       S=C
  heat rate = 14142 kJ/kW – Hr
  WB = 29.85 kW                                                              1
                                                             T1 = 15.6 0C
  N = 200 rpm
                                                                                 V
  Dimensions : 23.5 X 23.5 cm
                                          For e
                                                       1
  Required:                               e = 1−        X 100%
    a) eb , ei                                    rkk−1
                                                      1
    b) nb, ni                             e = 1 − (1.33 −1) X 100%
    c) mep                                        6
                                          e = 44.6382 %
Solution:                                         31.42
                                           ni =           X 100%
                                                 44.6382
For a)                                     ni = 70.388 %
                   kJ                     nb = ni X nm
          3600                            nb = 0.70388 X 0.81
                 kW −Hr
eb =                kJ
                          X 100%
      14142                               nb = 57 %
            kW −Hr
eb = 25.456 %
                                          For c)
ei = eb /nm                                         WB      29.85 kW
ei = 25.456/81                            mep =        =             m3
                                                                        = 878.561 kPa
                                                    VD   0.033975997
ei = 31.42 %                                                           s
                                                   π                   200rpm
For b)                                    VD =       (.235m2 )(.235cm)
                                                   4                     60
 ni = ei X 100%
      e                                                   m3
                                          VD = 0.033975997
                                                           s
The Diesel Cycle
  P                3                                                           3
       2                                     T
                        S=C
                                                           P=C
                                    4               2
                 S=C
                                                                               4
                                    1              1             V=C
                                        V                                          S
      PV diagram of a four stroke                 TS diagram of a four stroke
      diesel engine                               diesel engine
Cycle Analysis
1 – 2: isentropic compression, S = C
2 – 3: constant pressure addition of heat, P = C
3 – 4: isentropic expansion, S = C
4 – 1: constant volume rejection of heat, V = C
PROBLEMS:
     0.214251m3
rk =
     0.015329m3
rk = 13.977
For b)
     1+c
rk =
       c
       1
c=
    rk − 1
         1
c=
    13.977− 1
c = 7.705941%
For c)
Q A = mCP T3 − T2
T2 = T1 rkk−1
T2 = 321.9 K 13.977.4
T2 = 924.4566753K
     kJ                       kJ
317        = .227 kg 1.0062            T3 − 924.4567 K
    cycle                   kg − k
T3 = 2312.327671K
T3 = 321.9 K 13.977.4 rc
       2312.327671K
rc =
      321.9 K 13.977.4
rc = 2.50128289
For d)
W = QA − QR
W = Q A − mCV T4 − T1
            kJ                     kJ
W = 317          − .227 kg 0.7186       (T4 − T1 )
           cycle                 kg − k
T4 = T1 rkc
T4 = 321.9 K 2.501282891.4
T4 = 1161.846928K
         kJ                     kJ
W = 317       − .227 kg 0.7186               1161.846928K − 321.9 K
        cycle                 kg − k
              kJ
W = 179.986
            cycle
For e)
                              kJ
         137.013991
                            cycle
e = 1−                kJ            X 100%
             317
                    cycle
e = 56.777921%
For f)
      W
Pm =
      VD
V2 = cVD
0.015329m3 = 0.0705941%VD
VD = 0.19892444m3
                    kJ
         179.986
                   cycle
Pm =
     0.19892444m3
Pm = 904.7958109kPa
Chapter 3: GAS COMPRESSORS
Operation of compressors
Discharge valve
Inlet valve
P 3 discharge 2
compression
                             suction
                  4                                          1
                                       V1 = VD
                                                                  V
                      Conventional diagram without clearance
P 3 2
                                                    compression
                                 expansion
                                   4                              1
                                                    V1
                                               VD
                                                                      V
                          Conventional diagram with clearance
V1, = V1 − V4
Volume of gas drawn into the cylinder
where:
     m1 = m1’ + m2
     m1 = total mass after admission
     m1’ = mass of gas drawn in and delivered
     mc = clearance of residual gas
     V1’ = volume of gas drawn in corresponding to mass m1’
     P1 = pressure at the start of compression
     T1 = temperature of start of compression
     V1 = total volume at end of admission corresponding to mass m1
             Work of Compression
             Q = ∆P + ∆K + ∆H + W
             Q = ∆H + W ∆P = 0 , ∆K = 0
             W = Q − ∆H
         1. Adiabatic Compression (Q = 0) (S = 0)
             W = −∆H = −m′ CP T2 − T1
                                               k −1
                    kR        T2   P2            k
              CP =          ,    =
                   k−1        T1   P1
                                   k −1
                 m′ kRT1     P2      k
              W=                          −1
                  1−k        P1
                                  k −1
                 kP1 V1 ′   P2      k          kJ
              W=                         −1        , kW
                 1−k        P1                 min
         2. Polytropic Work
             W = Q n − ∆H = m′ Cn T2 − T1 − m′ CP T2 − T1
                                                 Cv k − n
             W = m′ Cn − CP T2 − T1 but Cn =
                                                   1−n
                       Cv k − n
             W = m′             − CP T2 − T1
                         1−n
                       Cv k − n − CP (1 − n)
             W = m′                          T2 − T1
                               1−n
           Cv k − Cv n − CP − CP n
W = m′                                                          T2 − T1
                     1−n
where: CP = Cv k CP − Cv = R
      m′
W=         n CP − Cv     T2 − T1
    1−n                                                     n −1
    nm′RT1 T2          nm′ RT1 P2                            n
W=              −1 =                                                −1
      1 − n T1          1 − n P1
                            n −1
   nm′ RT1             P2    n
W=                                 − 1 , kW
    1−n                P1
 3. Isothermal work ∆H = 0
                                            2
    W = Q − ∆H = Q =                            pdv
                                            1
                   2
                dv                                  V2
    W= c           = c lnV 12 = c lnV2 − lnV1 = cln
            1 v                                     V1
                  V2            V2
    W = P1 V1 ′ ln = m′ RT1 ln , kW
                  V1            V1
Volumetric efficiency(n V)
               1                        1
          P3   n                   P2   n             V1
V4 = V3            = cVD                    = cVD
          P4                       P1                 V2
Since V1 = VD + cVD we have
                                                                1
                                                           P3 n
          V1 − V4 VD + cVD − cVD                           P4
   nV =      VD
                 =
                           VD
                                    1
               P2                   n                      V1
      = 1+c −c                          = 1+c−c
   nV          P1                                          V2
 PROBLEMS:
Given:
P2 = 630 kPaa                                 W=                            − 1 , kW
                                                 1−n            P1
R = 410 J/kg – k                                                                       .4
For b)
                      n −1
   nP1 V1 ′    P2      n
W=                           − 1 , kW
   1−n         P1
         2) There are compressed 0.142 kg/s of oxygen by a 35.56 cm X
            35.56 cm double acting motor driven compressor operating at 100
            rpm. P1 = 101.35 kPa, T1 = 27 0C and P2 = 310.131 kPaa.
            Compression and reexpansion are polytropic with n = 1.31.
            Determine a) n V, b) heat rejected c) work and d) power input by the
            driving motorfor an overall adiabatic efficiency of 70 %
Given:
                                          P   3              2 P2 = 310.131 kPaa
m1’ = 0.142 kg/s
                                                               kPa
P1 = 101.35 kPa
T1 = 27 0C = 300 K
P2 = 310.131 kPaa
nc= adiabatic efficiency of 70 %                                              P1 = 101.325 kPa
35.56 cm X 35.56 cm double acting                                             kPa
                                                        4                           1
n = 1.31                                                              V1
                                                              VD                    T1 = 300 K
N = 100 rpm
                                                                                    kPa
                                                                                      V
Required:                                         For b)
  a) nV                                           QR = heat rejected
  b) QR                                           QR = mCn (T2 – T1)
  c) W                                                  P1 V1
  d) Pi n                                         m=          but V1 = VD + cVD
                                                        RT 1            1
                                                                     P2 n
Solution:                                         nV = 1 + c − c
For a)                                                               P1
                                                                                             1
        V1 ′                                                                 310.131 kPaa   1.31
 nV =                                             0.92798 = 1 + c − c
        VD                                                                    101.35 kPa
  ′    m′ RT1                                     c = 5.3409813%
V1 =                                                            m3
         P1                                       V1 = 0.117721     1 + 0.05341
               kg
       0.142 0.2599
                           kJ
                                (300K)                            s
  ′             s         kg −k                                 m3
V1 =                                              V1 = 0.117721     1 + 0.05341
                  101.35 kPa                                      s
  ′                   m3                                        m3
V1 = 0.109242624                                  V1 = 0.124008
                       s                                         s
       πD2
VD =         LN                                                                     m3
        4                                               101.35 kPa 0.124008
       π . 3556m 2                      2         m=                                s
VD =                (.3556 m)(100rpm)                                 kJ
              4                         60                  0.2599           300K
                         3                                           kg −k
                       m                                       kg
VD = 0.117720984                                  m = 0.1611929
                        s                                       s
                      m3
        0.10924262
 nV =                 s
                      m3
                          X 100% = 92.798 %
        0.11772098
                       s
         Cv k − n
Cn =
           1−n
                 kJ
         0.6595               1.395− 1.31
                     kg −k
Cn =
              1 − 1.31
                      kJ
Cn = −0.180830645
                    kg − k
         n −1
T2   P2 n
   =
T1    P1
                                         1.31−1
            310.131 kPaa                  1.31
T2 = 300K
             101.35 kPa
T2 = 390.8975661K
Q R = mCn T2 − T1
               kg            kJ
Q R = 0.1611929   −0.180831                                90.8976 K
                s          kg − k
Q R = −2.649543458kW
For c)
   nP1 V1 ′ T2
W=             −1
   1 − n T1
   1.31(101.35 kPa)1 V1 ′                T2
W=                                          −1
            1−n                          T1
                                                  m3
        1.31 101.35 kPa 0.109242624                        390.8976 K
                                                  s
W=                                                                    −1
               −0.31                                         300 K
W = 14.17609582kW
For d)
         Wisen
Pin =
          nc
                             k −1
                 ′
         kP1 V1       P2       k
W=                                  −1
         1−k          P1
                                                      m3                   .395
         1.395 101.35 kPa 0.109242624                       310.131 kPaa   1.395
                                                       s
W=                                                                                 −1
                               −0.395                        101.35 kPa
W = 14.56797232kW
      14.56797232kW
Pin =
            . 70
Pin = 20.81138904kW
MULTISTAGE COMPRESSION
Multistaging is the compression of the gas in two or more cylinders in place
of a single cylinder compressor. It is used in reciprocating compressor. In
order to 1) save power, 2) limit the gas discharge temperature, and 3) limit
the pressure differential per cylinder.
P M 4 P M 4
PVn = C PVn = C
                                                               B                2
             B   3    2          PX
         N                                                 N                3
                                         1
                                                                       A                  1
                                   V                                                 V
    Two stage compression no pressure                Two stage compression with pressure
    drop without intercooling                        drop with intercooling
          PX P4
             =     ; PX 2 = P1 P4 ; PX = P1 P4
          P1 PX
                       PD               PD
            P2 = PX +      ; P3 = PX −
                        2                2
          Where:
                PX = intermediate pressure
                PD = pressure drop
                                                 Wout
                                      Wi n
         m’                   2                           3                 m’
                  1                                                   4
Intercooler
LP cylinder HP cylinder
PROBLEMS:
      1) There are compressed 11.83 m 3/min of air from 103.42 kPaa, 26.7 oC to
         827.36 kPaa. All clearances are 8 % a) find the isentropic power and
         piston displacement required for a single stage compression, b) using the
         same data, find the minimum ideal power for two stage compression when
         the intercooler cools the air to the initial temperature, c) find the
         displacement of each cylinder for conditions of part (b), d) how much heat
         is exchanged in the intercooler? e) for compressor efficiency of 78 % what
         driving motor output is required?
Given:
                                             P   3            2 P2 = 827.36 kPaa
V1’           3
    = 11.33 m /min                                              kPaa
P1 = 103.42 kPa                                                 kPa
T1 = 26.7 0C = 299.7 K
P2 = 827.36 kPaa
                                                                            P1 = 103.42 kPaa
c=8%
                                                                            kPa
n C = 78 %                                               4                         1
                                                                     V1           T1 = 299.7 K
Required:                                                       VD
    a) Wisen , VD (simgle stage)                                                  kPa
                                                                                     V
    b) Wi deal(two stage)
                                                        For single stage
    c) VDHP , VDLP
    d) QR
    e) Pout
Solution:
                                                                       PX = P1 P4
For a)
                                  k −1                                 PX = (103.42 kPaa) 827.36 kPaa
           kP1 V1 ′       P2        k
                                                                       PX = 292.5159 kPaa
Wisen    =                               −1
           1−k            P1                                                                      k −1
                                                                          2kP1 V1 ′        PX       k
                                          m3                0.4        W=                                 −1
          1.4 103.42 kPa 11.33 min                827.36    1.4            1−n             P1
Wisen =                                                           −1
                      −0.4                        103.42                                                   m3                 0.4
                        = 55.4640.49 kW W =
                                                                                                           min
Wisen = −3327.842949                                                                                                                −1
                    min                             −0.4                                                             103.42
                                        W = 47.285935 kW
       V1 ′
nV =
       VD                               For c)
                               1
 n V = 1 + c − c P2
                               n
                                                                             V1 ′
                 P1                                                    nV =
                                                            1               VDLP
                       827.36 kPaa                         1.4                                        1
 n V = 1 + 0.08 − 0.08                                                                          P2    n
                       103.42 kPaa                                      nV = 1 + c − c
 n V = 72.6691 %                                                                                P1
                                                                                                                                1
                    m3                                                                        292.52 kPaa                      1.4
           11.33                                                        n V = 1 + 0.08 − 0.08
                    min
  VD =                                                                                        103.42 kPaa
           . 726691
                 m3                                                     n V = 91.187895%
  VD = 15.591221
                min                                                                             m3
                                                                                    11.33
                                                                                                min
For b)                                                                   VDLP =
                                                                                  0.91187895
                                                                                         m3
  P           4 P4 = 827.36 kPaa                                         VDLP   = 12.425
                                                                                         min
                kPaa
                kPa                                                    P1 V1 ′ = m′ RT1
                                                                               P1 V1 ′
                              2                                        m =
                                                                         ′
                                                                                RT1
                          3               P1 = 103.42 kPaa                                                     m3
                                                                                103.42 kPaa 11.33
                                                                                                               min
                                          kPa                          m′ =                kJ
                                             1 T1 = 299.7 K                   0.28708             (299.7 K)
                                                                                          kg −K
                                              VkPa                                      kg
                                                                       m′ = 13.61898567
                      Wi n Wout                                                        min
                                              3      4
      m’ 1      2                                                      P3 V3 = m′ RT3
                                                    m’                       m′ RT3
                                                                       V3 =
                                                                               P3
                                                                                          kg
                              QR                                             13.61898567 (0.28708)299.7 K
                                                                                         min
                                                                       V3 =
                                                                                      292.5159 kPaa
             m3
V3 = 4.00576
             min
          V3
nV =
         VDHP
                     m3
           4.00576
                     min
VDHP =
           0.91187895
                    m3
VDHP     = 4.392864
                    min
For d)
Q R = m′ CP (T3 − T2 )
            k−1
T2   P2      k
   =
T1   P1
                             0.4
             292.5159 kPaa   1.4
T2 = 299.7 K
               103.42 kPaa
T2 = 403.362 K
                  kg
Q R = 13.61898567     (1.0062)(299.7 K − 403.362 K)
                 min
                   kJ
Q R = −1420.524275
                   kg
For e)
       WO
nC =
      Win
       47.285935kW
 Win =
           0.78
 Win = 60.622993kW
Chapter 4: STEAM ENGINE
1. Ideal PV diagram
P 2 3
                                    V
  2. VD = piston displacement
           πD2
     VD =      LN 2 , piston rod neglected
            4
           πD2       π(D2 − d2 )
     VD =      LN +              LN , piston rod considered
            4             4
                     Steam
    Steam engines are
    double acting         h1 ms = kg/s
    engines              1
            Head end       Crank end            crosshead
                                            d                 Brake power
                      h2   2
    Indicated power
                                condenser
h3
    3. Indicated power
       IP = Pmi VD
where:
     Pmi = indicated mean effective pressure
              area of card
    Pmi =                   X spring scale
             length of card
Pmi
length
  4. Brake Power
     BP = 2πTN
     Where:
        T = torque kN – m
        T=FXL
        N = speed rps
       WB = Pmb VD
       Where:
            Pmb = brake mean effective pressure
  6. Mechanical Efficiency
                Brake Power
       nm =
             Indicated Power
  7. Efficiencies
     a) ei = indicated thermal efficiency
               Indicated Power, kW
         ei =        kg           kJ
                ms ,    h1 − hf2
                   s             kg
    b) eb = brake thermal efficiency
              Brake Power, kW
       eb =        kg           kJ
              ms ,    h1 − hf2
                       s                   kg
    c) ni = indicated engine efficiency
              Indicated Power, kW
       ei =         kg           kJ
               ms ,    h1 − h2
                           s               kg
    d) nb = brake engine efficiency
              Brake Power, kW
       eb =       kg           kJ
             ms ,    h1 − h2
                       s                   kg
                    1
  Imep = P1 rc 1 + ln  − P2
                    rc
  actual mep = f(Imep)
PROBLEMS:
 Required:
   a) IP
 Solution:
                             πD2
                   IP = mep      LN 2
                               4
                kg π
     IP = 40000 2       0.360 m 2 0.45 m (200 rpm) 2
                m 4
                                     2.2 lb 3.28 ft
          IP = 732870.7342 kg − m
                                      1kg    1m
                 IP = 5288395.218 ft − lb
                     IP = 160.2544 Hp
                     π(D2 − d2 )
IHPCE   = actual mep             LN
                         4
                                          2
                             π[ 0.380 m    − 0.06 m 2 ]
IHPCE   = 180.9556164kPa                                0.405 m 250 rpm
                                          4
IHPCE = 33.76823681kW
                 π(D2 − d2 )
 IHPCE   = PmiCE             LN
                     4
                                              2
                               π[ 0.305 m      − 0.063 m 2 ]
 IHPCE   = 230.2723684kPa                                    0.380 m 240 rpm
                                               4
 IHPCE = 24.48152581kW
 BP = 2πTN
 T= FXL
 T = 356 N X 0.8 m
 T = 284.8 J
 BP = 2π . 2848 J 240 rpm
 BP = 7.157804702kW
 FP = 54.18386863 kW − 7.157804702kW
 FP = 47.02606393kW
      7.157804702kW
 nm =
      54.18386863kW
 nm = 13.21021345%
4) A steam engine with a 305 mm bore by 457 mm stroke controlled
   compression horizontal uniflow steam engine having an indicated engine
   efficiency of 70 % when operated between 0.862 MPa (gauge) and
   atmospheric pressure. Exhaust steam initially dry and saturated. Piston rod
   diameter is 44mm. Mechanical efficiency is 90 % when connected to an AC
   generator which has an efficiency of 83.5 % when running at 240 rpm.
  Given:                           Required:
                      d = 44 mm          a) kW rating of the generator
  N = 240 rpm
                      ni = 70 %          b) combined steam rate consider that at
  D = 305 mm
                      nm = 90 %             rated load compression ratio is 4 and f
  L = 457 mm
                                            ranges from 0.7 to 0.8
  P1 = 862 kPa(gauge) ng = 83.5 %
  P2 = 101.325 kPa
Solution:
For a)
                      1
Imep = P1 rc 1 + ln      − P2
                      rc
       P1
Imep =    1 + lnrk − P2
       rk
       963.325 kPa
Imep =              1 + ln4 − 101.325 kPa
            4
Imep = 473.3692539kPa
                      πD2
IHPHE    = actual mep     LN,
                       4
                                          2
                          π 0.305 m
IHPHE    = 355.0269404kPa                     0.457 m 240 rpm
                               4
IHPHE    = 47.41622954kW
                      π(D2 − d2 )
IHPCE    = actual mep             LN
                          4
                                               2
                                  π[ 0.305 m       − 0.044 m 2 ]
IHPCE    = 355.0269404kPa                                        0.457 m 240 rpm
                                                   4
IHPCE = 46.42942624kW
For b)
                                        3600 kJ/kW − Hr
                                   Ws =
     Wk                                     Wk , kW
ng =                                    3600 kJ/kW − Hr
     WB                            Ws =
     WB                                 70.52501032kW
nm =                               W = 51.049273
     WI                               s
WB = 93.84565578kW 0.9
WB = 84.4610902kW
Wk = 84.4610902kW 0.835
Wk = 70.52501032kW
Chapter 5: STEAM TURBINE
hf2
5. Thermal efficiency
                                                turbine output
      a. ntb = brake thermal efficiency =
                                                 ms (h1 − hf2 )
                                                               gen output
      b. ntc = combined or overall thermal efficiency =
                                                              ms (h1 − hf2 )
6. Engine efficiency of Turbine
                                            brake power
      a. neb = brake engine efficiency =
                                            ms (h1 − h2 )
                                                             gen output
      b. nec = combined or overall engine efficiency =
                                                             ms (h1 − h2 )
  7. Willan’s Line
       Willan’s line is a straight line which shows the relation between the steam
     consumption (ms , kg/Hr) and the load (L, kW) of steam turbine generator unit.
                                         ms kg/Hr
     y = bx + a                                                        Slope, b
          where:                           msf
                  msf − msn
              b=
                      FL                  Y = ms
              x = load                                                                 msf - msn
              a = no load steam
                   consumption           a = ms n
                                             no
                                                                      L           Full L kW
                                             load
                                                                                  load
PROBLEMS:
     h1 + KE1 = WT + KE2 + Q L + h2
     WT = (h1 − h2 ) + (KE1 − KE2 ) + Q L
                kJ       kJ          kJ         kJ
     WT = 600 − 486          + 16.8       + 2.5
                kg       kg          kg         kg
                 kJ
     WT = 133.3
                kg
     WT = 533.2 kJ
  2) A steam turbine with an internal efficiency of 90 % receives steam
     at 7 MPa and 550 0C and exhaust of 20 kPa. Determine the ideal
     turbine work, exhaust enthalpy and the exit quality of steam
Given:                          P1 = 7 MPa
                               T1 = 550 0C
nt= 90 %
P1 = 7 MPa
T1 = 550 0C
P2 = 0.020 MPa                                 nt= 90 %                  WT
Required:
     a) WTi
                                                            P2 = 0.020 MPa
     b) X2
Solution:
For h2
S1 = S2 = Sf2 + X2Sfg2
6.9486 = 0.8320 + X2(7.0766)
X2 = 0.864341633 = 86.4341633 %
h2 = hf2 + X2hfg2
h2 = 251.40 + (0.864341633) 2358.3
h2 = 2289.776873 kJ/kg
3) A steam turbine generator power plant 6.5 MW capacity has a full
   load steam consumption 6.0 kg per kW – Hr. no load steam
   consumption is 12 % of the full load consumption.
       a) Write the equation of the Willan’s line of this turbine.
       b) At 70 % of the rated load, calculate the hourly steam
          consumption.
Given:
P = 6500 kW
msf = 6.0 kg/kW – HR
msn = 0.12(ms f)
X = 0.70(6500 kW)
Required:
     a) Willan’s line
     b) X2
Solution:
y = bx + a
          kg                       kg
y = 5.28     0.70 (6500 kW) + 4680
          Hr                       Hr
y = 28704 kg/Hr
4) Steam with an enthalpy of 800 kcal/kg enters the nozzle at a
   velocity of 80 m/s. Find the velocity of the steam at the exit of the
   nozzle if its enthalpy is reduced to 750 kcal/lkg. Assuming the
   nozzle is horizontal and disregarding heat losses. Take g = 9.81
   m/s2 and J constant is 427 kg – m/kcal.
6) The entrance and exit enthalpies of a steam turbine are 4000 and
   3000 kJ/kg respectively, what is the mass of steam entering the
   turbine if the generator power is 3 MW and the generator efficiency
   is 90 %.
Given:
P1 = 2.85 MPa
T1 = 400 0C
P2 = 0.0085 MPa
Required:
Solution:
                   ms t
                                                        ms 2
                          ms 1
                                      5000 kW                  7500 kW
                          Turbine 1                Turbine 2
                                            10000 kW
From steam tables                       for b)
At P1 = 2.85 MPa and 400 0C (table 3)
h1 = 3233.4 kJ/kg                                         yT = mst = y1 + y2
                                        for unit 1
From steam tables                       y1 = b1 x + a1
At P2 = 0.0085 MPa (table 2)                          kg                    kg
                                        y1 = 4.16          (5000 kW) + 3200
h3 = hf at 0.0085 MPa                              kW − Hr                  Hr
                                                     kg
h3 = 178.7 kJ/kg                        y1 = 24000
                                                     Hr
for a)
                                        for unit 2
                                        y2 = b2 x + a2
for unit 1                                         kg                    kg
y = bx + a                              y2 = 4          (5000 kW) + 5000
24000 kg/Hr = b1 (5000 kW) + a1                 kW − Hr                  Hr
                                                     kg
50 % load                               y2 = 25000
                                                     Hr
        kg                                           kg         kg
13600 = b1 2500 kW + a1                 yT = 24000      + 25000
        Hr                                           Hr         Hr
By elimination:                                      kg
              kg                        yT = 49000
b1 = 4.16                                            Hr
           kW − Hr
            kg                          for c)
a1 = 3200
            Hr                          combined Heat rate , kJ/kW – HR
y1 = b1 x + a1                                            kg              kJ
y1 = 4.16x + 3200                                 mst ,         h1 − h3
                                                          Hr              kg
                                        H. R. =
                                                     10000 kW
                                                       kg                      kJ
for unit 2                                        49000 3233.4 − 178.7
                                                               Hr              kg
y = bx + a                              H. R. =
35000 kg/Hr = b2 (7500 kW) + a2                         10000 kW
                                                           kJ
50 % load                               H. R. = 14968.03
        kg                                               kW − Hr
20000 = b2 3750 kW + a2
        Hr                              for d)
By elimination:
           kg                                              kJ
b2 = 4                                         3600
        kW − Hr                         ek =          kW −Hr
            kg                                     H. R.
a2 = 5000                                                       kJ
            Hr                                    3600
y2 = b2 x + a2                          ek =               kW −Hr
                                                               kJ
y2 = 4x + 5000                               14968.03
                                                      kW −Hr
                                        ek = 24.05126%
Chapter 6: HEAT TRANSFER
                          T2           Q            Where:
   T1                                                   Q = heat transfer, kJ
        1                 2                                                                kJ
                                                          k = thermal conductivity
                                                                                     Hr − m − K
                                                          A = cross sectional area, m2
                                                          T = time, Hr
                                                          X = thickness of the material, m
                 X
Conduction through composite walls:
                                                                  k 1 A T1 − T2      RT = R1 + R2 + R3
                                                             Q1 =                          1
                 k1           k2           k3                            X1          RT =
                                                                  k 2 A T2 − T3            U
                                                             Q2 =                    Where:
                                                                         X2                X1 X2 X3
        T1           T2        T3           T4      Q             k 3 A T3 − T4      RT = + +
                                                             Q3 =                          k1 k2 k3
             1       2             3            4                        X3          U = overall heat
                                                                  A T1 − T4                            W
                                                             Q= X       X   X
                                                                                     transfer coeff. , 2
                                                                   1                                m −K
                                                                      + 2+ 3
                                                                   k1   k2   k3
                 X1           X2           X3
Conduction through fluid film:
                                                                   A Ti − To
   hi          k1           k2       k3             Q=    1        X1       X2       X3       1
                                               ho              +        +        +        +
                                                          hi       k1       k2       k3       ho
                                          To        where:
        Ti     T1     T2 T3           T4  Q                                               kJ
                                                    h0 = outside film coefficient ,
        i      1      2          3     4 o                                          Hr − m2 − K
                                                                                        kJ
                                                    hi = inside film coefficient ,
                                                                                   Hr − m2 − K
               X1         X2         X3
Mean temperature difference
  1. Arithmetic mean temperature                         difference
     (AMTD)
  2. Logarithmic mean temperature                        difference
     (LMTD)
                                          m2                                              m2
                       Heat lost by hot fluid = heat lost by cold fluid
            Temperature gradient                             Temperature gradient
            (parallel flow)                                  (parallel flow)
            θmax = T1 − t1                                   θmax = T1 − t 2
            θmin = T2 − t2                                   θmin = T2 − t 1
PROBLEMS:
                                   Solution:
Given:
                                                       kA T1 − T2
                                                   Q=
X = 15 cm                                                  X
T1 = 200 0C = 473 0K                               Q k T1 − T2
                                                     =
T2 = 30 0C = 303 0K                                A       X
                                                     W
K = 5 W/m - K                                Q     5     473 − 303 K
                                               = m−K
                                             A        0.15 m
Required:                                      Q             W
                                                 = 5666.66667 2
     a) Q                                      A             m
2) Two walls of cold storage plant are composed of an insulating material
   (k = 0.25 kJ/Hr – m – 0C) 100 mm thick at the outer layer and material
   (k = 3.5 kJ/Hr – m – 0C) 15 cm thick at inner layer. If the surface
   temperature at cold side is 30 0C and hot side is 250 0C, find the heat
   transmitted per square meter.
 Given:
                                                    k1    k2
 X1 = 10 cm
 X2 = 15 cm                                                    Q
 T1 = 250 0C = 523 0K                      T1        T2   T3
 T2 = 30 0C = 303 0K                            1    2     3
 K1 = 0.25 kJ/Hr – m – 0C
 k2 = 3.5 kJ/Hr – m – 0C
 Required:                                          X1    X2
      a) Q/A
  Solution:
                Q   T1 − T3
                  = X    X
                A     1
                        + 2
                     k1     k2
             Q     523 − 303 K
               = 0.10 m 0.15 m
             A          +
                   0.25    3.5
          Q                    kJ
            = 496.7741935
          A                Hr − m2
                                                                  Q   T1 − T2
Required:                                                           =    X1
                                                                  A
     a) Q/A                                                               k1
     b) T1, T2, T3, T4                                                       W    1471.712494− T2 K
                                                                  534.4379923 2 =        0.8
     c) X2 is doubled                                                        m
                                                                                                  2.96
Solution:                                                         T2 = 1327.269793K
for a)                                                            Q   T2 − T3
                                                                    =    X2
                                                                  A
                   A Ti − To                                              k2
Q=       1         X1       X2       X3       1                              W    1327.269793− T3 K
              +         +        +        +                       534.4379923 2 =        0 .13
         hi        k1       k2       k3       ho                             m
Q                         1478− 300 K                                                            0.0692
  =      1         0.8           0.13         0.00254       1
                                                                  T3 = 323.2677844K
A             +           +               +             +
         85        2.96       0.0692           43 .3        23
Q              W                                                  Q   T3 − T4
  = 534.4379923 2                                                   =
A              m                                                  A      X3
                                                                          k3
for b)                                                                       W    323.2677844− T2 K
                                                                  534.4379923 2 =       0.00254
                                                                             m
                                                                                                  43 .3
                                                                  T4 = 323.2364336K
Q   Ti − T1
  =    1
A
              hi
           W    1478− T1 K
534.4379923 2 =     1
           m
                                               85
T1 = 1471.712494K
for c)
                     A Ti − To
Q=        1         X1       2X 2       X3        1
               +         +          +        +
          hi        k1       k2         k3       ho
Q                          1478− 300 K
  =       1         0.8        2(0.13 )          0.00254       1
A              +           +                 +             +
          85        2.96       0.0692             43 .3        23
Q              W
  = 288.5276698 2 (decreased by 46.01288%)
A              m
Q   Ti − T1
  =    1
A
               hi
           W    1478− T1 K
288.5276698 2 =     1
           m
                                                  85
T1 = 1474.605557K (increased)
Solution:                                                           seawater
                                                                                702 mmHg
                                                       0
      T                       TC = 40.8512 C                                    condenser
                              702 mmHg
                                                       T2 = 37.5 0C                         Tm = 37.5 0C
                                                                                            mT = mw + ms
                     T1 = 29.5 0C
                                                           m2
 For a)                                For b)
                                           ms = 32700 kg/Hr
   Solution:
                                           hs = 2757 kJ/kg
                                                    md = 38750 kg/Hr
                                                    hd = 403 kJ/kg
                     27 0C
                                                       82 0C mc =
          hci = 113.25 kJ/kg                                 hco = 343.3 kJ/kg
                                        m = 71450 kg/Hr
                                        hm = 355 kJ/kg
For a:
TC = condensing temperature
TC = Ts a t at 355 kJ/kg
TC = 85 0C
For b:
For c:
By heat balance:
mshs + md hd + hci mc = mhm + mchco
32700 kg/Hr (2757 kJ/kg) + 38750 kg/Hr (403 kJ/kg) + 113.25 kJ/kg mc = 71450 kg/Hr (355
kJ/kg) + mc355 kJ/kg
32700 kg/Hr (2757 kJ/kg) + 38750 kg/Hr (403 kJ/kg) + 113.25 kJ/kg mc = 71450 kg/Hr (355
kJ/kg) + mc355 kJ/kg
105770150 kJ/Hr + 113.25 kJ/kg mc = 25364750 kJ/Hr + mc355 kJ/kg
80405400 kJ/Hr = mc355 kJ/kg – 113.25 kJ/kg mc
80405400 kJ/Hr = 241.75mc
mc = 332597.3113 kg/Hr
For d:
Q = mc hco − hci
Q = UALMTD
                         kJ          kJ
Q = 332597.3113 kg/Hr 355   − 113.25
                         kg          kg
                         kJ          kJ
Q = 332597.3113 kg/Hr 355 − 113.25
                         kg          kg
                kJ
Q = 80405400.01 = 22334.83334 kW
               Hr
                              kW
22334.83334kW = 3.632               A 18 C
                             m2 − K
A = 341.6365844m2
 For e:
 Tave = 54.5 C
 𝛒ave = 986 kg/m3
       ms     332597.3113 kg/Hr              m3
 Vf =      =                    = 337.3197883
      𝛒ave       986 kg/m3                   Hr
 Vf = A X V X N
      π
 Vf = (ID)2 X V X N
      4
               m3 π              1.8m
 337.3197883 = (0.012m)2 X            XN
               Hr 4                s
 N = 460 tubes
 A = πODLN
 341.6365844m2 = π 0.016m L 460tubes
 L = 14.77 m = 15 m
           R1
                      R2
                                                         Di        Do
          2πkL T1 − T2          Where:
     Q=              R2
                ln                   Q = heat transferred, W
                     R1
                                     K = thermal conductivity, W/m – K
                                     L = length of pipe
                                     R1 = inside radius
                                     R2 = outside radius
                                  R2
                           R3          R1
       2πk 1 L T1 − T2                             2πL T2 − T3
Q1 =             R2
                                             Q=        R          R
            ln                                       ln 2       ln 3
                                                      R1           R2
                 R1                                         +
                                                      k1        k2
       2πk 2 L T2 − T3
Q2 =             R3
            ln
                 R2
                                                              hi
                                                                        ho
                 Q i = Ai hi Ti − T1
                 Q i = hi 2πR1 L Ti − T1
Q o = Ao ho T3 − To
Q o = ho 2πR 3 L T3 − To
                                        Ti − T0
                 Q=                     R            R
                          1           ln 2         ln 3         1
                                        R1          R2
                                 +             +          +
                         hi A1       2πk 1 L       2π2L       h0 A3
PROBLEMS:
Given:
15 cm X 6 m uninsulated B.I. pipe
Ti = 385 0F
To = 85 0F
Required:
     a) Annual cost of heat lost
Solution:
From pipe
For 15 cm (5.9055 in) Sch. 80 for steam use
      Do = 6.625 in = 16.8275 cm
      Di = 5.761 in = 14.639294 cm
      Ki ron = 30 BTU/Hr – ft – F
      hi = 1000 BTU/Hr – ft2 – F
      ho = 2 BTU/Hr – ft2 - F
      Ao = 3.171909 m2
      Ai = 2.7582442 m2
              BTU
hi = 1000
          Hr − ft − F
                 W
hi = 5675.056 2
               m −K
          BTU
ho = 2
       Hr − ft − F
                  W
ho = 11.35011 2
               m −K
              Ti − T0
Q=                   R
       1           ln 2          1
                     R1
              +             +
      hi A1       2πk 1 L       h0 A3
                                        385 − 85 /1.8
 Q=                                              0.168275
                     1                      ln                              1
                 W                      +        0.14639294
                                                              +            W
       5675 .056 2 (2.7582442 )             2π 51.906 6           11.35011 2 (3.171909 )
                m −K                                                      m −K
                                        385 − 85 /1.8
 Q=                                              0.168275
                     1                      ln                              1
                 W                      +        0.14639294
                                                              +            W
       5675 .056 2 (2.7582442 )             2π 51.906 6           11.35011 2 (3.171909 )
                m −K                                                      m −K
 Q = 5986.588499 W
                                         kJ 31536000s                     1000             1BTU
total cost = 5986.588499
                                         s     yr                    106 BTU 0.75          1055 J
total cost = 238601.0173 pesos
Chapter 7: FUELS AND COMBUSTION
Classifications of fuels
Combustion
Actual air – fuel ratio theoretical air – fuel ratio plus excess air
1. Specific gravity
                                  density
                      S. G =                    , for liquids
                             density of water
                                  density
                       S. G =                 , for gases
                               density of air
2. API and Baume gravity units
                       141.5
             API =                − 131.5 , (petroleum products)
                    SG at 15.6 C
                                    140
                    Baume =                  − 130 , brine
                                SG at 15.6 C
   SG at temperature T, applying correction factor:
                     SGT = SG15 .6 1 − 0.0007 T − 15.6
3. For higher and lower heating value
   a. Dulong’s formula, used for solid fuels of known ultimate analysis:
                                                    O               kJ
               Q h = 33,820 C + 144,212 H −             + 9,304 S ,
                                                    8               kg
   b. ASME formula for petroleum products
                           Q h = 41,130+ 139.6 X API
   c. Bureau of standards formula
                          Q h = 51,716+ 8,793.8 (SG)2
   d. Difference between HHV and LHV
                             Q h − Q L = 9 H2 2442
       Where:
                                 H2 = 26 − 15(SG)
4. Combustion of solid fuel with known ultimate analysis:
                    A                          O              kg air
              Theo. = 11.5 C + 34.5 H −             + 4.3 S ,
                    F                           8             kg fuel
   Molecular weights:
   C : 12      N2 : 28
   H2 : 2      S : 32
   O2 : 32
         5. Theoretical and actual air fuel ratio
Cn Hm + aO2 + 3.76 a N2 = bCO2 + cH2 O + 3.76 a N2 , (Theo)
Cn Hm + 1 + e aO2 + 1 + e 3.76 a N2 = bCO2 + cH2 O + deO2 + (1 + e)3.76 a N2 , (actual)
                m               m            m              m
Cn Hm + n +       O2 + 3.76 n +   N2 = nCO2 + H2 + 3.76 n +   N , (Theo)
                4               4            2              4 2
PROBLEMS:
    Required:
         a) Heating value
         b) A/F
    Solution:
    For a)
                                         O               kJ
                 Q h = 33,820 C + 144,212 H −+ 9,304 S ,
                                         8               kg
                                         0.035                     kJ
    Q h = 33,820 0.685 + 144,212 0.025 −         + 9,304 (0.015) ,
                                           8                       kg
                                          kJ
                         Q h = 26280.6325
                                          kg
    For b)
                         A                     O           kg air
                 Theo.     = 11.5 C + 34.5 H −   + 4.3 S ,
                         F                     8           kg fuel
             A                               0.035                   kg air
    Theo.      = 11.5 (0.685) + 34.5 0.025 −         + 4.3 (0.015) ,
             F                                 8                     kg fuel
                                 A             kg air
                           Theo. = 8.6535625
                                 F             kg fuel
    2. Liquid octane fuel is burned with idel proportions of air calculate.
       a) Ideal fuel air ratio
       b) Actual fuel air ratio if e = 20 %
Solution:
               m                m               m                  m
 C8 H18 + n +     O2 + 3.76 n +     N2 = nCO2 + H2 O + +3.76 n +        N , Theo
                4                4              2                   4 2
              18                18              18                  18
C8 H18 + 8 +      O2 + 3.76 8 +     N2 = 8CO2 + H2 O + +3.76 8 +         N2 , Theo
               4                4               2                    4
       C8 H18 + 12.5 O2 + 3.76 12.5 N2 = 8CO2 + 9H2 O + 3.76 12.5 N2 , (Theo)
                                  A/FA = (1 + e)A/FT
                                                       kg air
                           A/FA = (1 + 0.20)15.05263
                                                      kg fuel
                                                kg air
                                A/FA = 18.0632
                                                kg fuel
    3. A steam generator burns fuel oil with 20 % excess air the fuel oil may be
       represented as C14H30. The flue gas leaves the preheater at 0.31 MPa.
       Find the minimum stack gas temperature to avoid condensation.
    Given:                       Solution:
                                             mol of water vapor
    e = 20 %                     PV = Patm
                                                 total mol
    C14H30
    P = 0.31 MPa
    Required:
      a) Stack gas temp.
Solution:
 Cn Hm + 1 + e aO2 + 1 + e 3.76 a N2 = bCO2 + cH2 O + deO2 + (1 + e)3.76 a N2 , actual
 C14 H30 + 1.2 21.5 O2 + 4.512 21.5 N2 = 14CO2 + 15H2 O + 4.3O2 + 4.512 21.5 N2 , actual
                                                        15
                                       PV = 310 kPa
                                                     130.308
                                            PV = 35.68 kPa
From steam table
Tsa t at 0.03568 MPa = 72.685 0C
     4. There are 20 kg of fine gas formed per kg of fuel oil burned in the
        combustion of a fuel oil C12H26. What is the excess air in percent?
         Given:
         C12H36
         m = 20 kg gas per kg
         fuel
         Required:
              a) e in percent
 Solution:
                  m                 m              m                  m
   C12 H26 + n +      O2 + 3.76 n +    N2 = nCO2 + H2 O + +3.76 n +      N , Theo
                   4                4               2                 4 2
                               26                 26
                C12 H26 + 12 +     O2 + 3.76 12 +     N2
                                4                 4
                                      26                  26
                           = 12CO2 + H2 O + +3.76 12 +       N2 , Theo
                                      2                    4
       C12 H26 + 18.5 O2 + 3.76 18.5 N2 = 12CO2 + 13H2 O + +3.76 18.5 N2 , Theo
                                      A/FA = (1 + e)A/FT
                                 kg air                   kg air
                              19         = 1 + e 15.05263
                                 kg fuel                 kg fuel
                                          e = 27.18 %
5. A fuel oil is burned with 50% excess air. What is the volume rate of flow
   in m3/min of the wet products at a pressure of 102 kPa and a temperature
   of 305 0C when fuel is burned at a rate of 45 kg/min. assume that
   combustion requirement of the fuel oil is similar to those C12H26
  Given:
  C12H36
  P = 102 kPa
  mf = 45 kg/ min
  T = 305 0C
  e = 50 %
  Required:
       a) Vf
 Solution:
       C12 H26 + 1 + e aO2 + 1 + e 3.76 a N2
                  = bCO2 + cH2 O + deO2 + (1 + e)3.76 a N2 , (actual)
       C12 H26 + 18.5 O2 + 3.76 18.5 N2
                  = 12CO2 + 13H2 O + 18.5 O2 + 3.76 18.5 N2 , actual
                             mfa = A/FA X mf
                                   kg air
                 mfa = 23.40894118         X 45 kgfuel/min
                                   kg fuel
                         mfa = 1053.45 kgair/min
Solving for gas constant R
                          from PV = mRT
                            kgair              kJ
        102 kPa V = 1053.45       0.289552216       (578 K)
                             min             kg − K
                                     m3
                          Vf = 17.28
                                     min
 6. A 485 kW diesel engine uses fuel oil of 25 0API gravity. Fuel consumption
    is 0.395 kg/kW – Hr. cost of fuel is 35.5 pesos per liter. For continuous
    operation, determine the minimum volume of cubical day tank in liter. The
    ambient temperature is 42 0C
   Given:                            Solution:
                                                       m
                                                      ρ=
   P = 485 kW                                           V
   25 0API                           Where: m = mass flow
   mf = 0.395 kg/ kW – Hr                   V = volume flow
   35.5 pesos per liter                     𝛒 = density
   T = 42 0C
                                     Solving for m:
   Required:                                      m = P X mf
        a) volume                                               kg
                                        m = 485 kW X 0.395
                                                              kW – Hr
                                                             kg
                                                 m = 191.575
                                                             Hr
                       141.5                                       m
     SG at 15.6 C =                                             ρ=
                    131.5 + API                                    V
                       141.5
    SG at 15.6 C =                                                 m
                   131.5 + 25 API                               V=
       SG at 15.6 C = 0.90415                                      ρ
                                                                          kg
                   ρf                                           191.575
              SG =                                        V=              Hr
                   ρw                                          887.441308
                                                                               kg
                            kg                                                 m3
         ρf15 .6 = 904.15
                            m3                                   m3
                                                  V = 0.215873431 X 24 Hrs
  SGT = SG15 .6 1 − 0.0007 T − 15.6                              Hr
SG42 = 0.90415 1 − 0.0007 42− 15.6                    V = 5.810962345m3
         SG42 = 0.887441308
                            kg
        ρf42 = 887.441308 3
                            m
Solution:
                             72
                      N2 =       = 2.571
                             28
                              20
                      CO2 =      = 0.4545
                              44
                             3.5
                      O2 =       = 0.109375
                             32
                               4.5
                      H2 O =       = 0.25
                               18
                      Total : 3.38492 kg/mol
                                  0.25
                      PV = Patm
                                3.38492
                      PV = 0.101325 0.073856
                      PV = 0.0075 MPa
                      From steam tables T at 0.0075 MPa
                      T = 40.29 C
8. A diesel electric plant consumed 210 gal. of fuel at 30 0C and produced
   4000 kW – Hr fuel used is 30 0API and was purchased at 30 pesos per
   liter at 15.6. For continuous operation estimate the cost per kW – Hr of
   the fuel used.
 Given:
 V = 210 gal
 30 0API
 30 pesos per liter at 15.6
 T = 30 0C
 Required:
      a) Cost per kW – Hr
Solution:
                                  price     kg
              cost per kW − Hr =        X
                                    kg    kW − Hr
                                141.5
              SG at 15.6 C =
                             131.5 + API
                                 141.5
              SG at 15.6 C =
                             131.5 + 30 API
              SG at 15.6 C = 0.87616099
                      ρf
              SG =
                      ρw
              ρf30   = SG X ρw
                                           kg          kg
              ρf30 = 0.867329287X1000         = 3.2832
                                           m3          gal
                     m
              ρ=          m = Vρ
                     V
              m = Vρ
                                     kg
              m = 210 gal X 3.2832
                                     gal
              m = 689.472 kg
                                        price     kg
                   cost per kW − Hr =         X
                                         kg     kW − Hr
                                    30 peso/lit   689.472 kg
            cost per kW − Hr =                  X
                                  0.87616 kg/lit 4000kW − Hr
                  cost per kW − Hr = 5.90 peso/kW − Hr
9. Calculate the higher heating value of a certain fuel in a day tank having a
   specific gravity 0.918 at a temperature of 38 0C.
  Given:
  SG30 = 0.918
  T = 38 0C
  Required:
       a) HHV
Solution:
                            141.5
                 API =                − 131.5
                         SG at 15.6 C
                           141.5
                 API =           − 131.5
                         0.932623
                 API = 20.2226146
                 Q h = 41,130+ 139.6 X API
         Required:
              a) days
Solution:
                    mf , kg           day
no. of days =               kg   X          where: mff = mass flow of fuel
                    mff ,            24 Hrs
                            Hr
BOILERS
Classifications of boilers:
  1. Fire tube boiler
  2. Water tube boiler
Boiler rating
                            H. S. A. m2
  Rated boiler horsepower =
                                 k
  where:
       k = 1.1 m2/Bo – Hp , fire tube
       k = 0.91 m2/Bo – Hp , water tube
       k = 12 ft2/Bo – Hp
       k = 10 ft2/Bo – Hp
boiler efficiency:
           kg            kJ
       mfs     hs − hf
           Hr            kg
nBo =       kg         kJ
                            X 100 %
        mf X HHV
            Hr        kg
PROBLEMS:
    Required:
            a) Volume of air
            b) Weight
  Solution:
  For a:
  PV = mRT
         A kg air       kg fuel
  ma =             X mf
         F kg fuel        Hr
                                                         kJ
                                          hs − hf
                                                         kg
factor of evaporation =                             kJ
                         2257 kg
           kJ           kJ
(1.1)2257 = hs − hf
           kg           kg
         kJ          kJ
 hs − hf    = 2482.7
         kg          kg
                           O              kJ
Q h = 33,820 C + 144,212 H −  + 9,304 S ,
                            8             kg
                                    0.06                      kJ
Q h = 33,820 0.705 + 144,212 0.045−          + 9,304 (0.03) ,
                                      8                       kg
               kJ
Q h = 29530.17
               kg
              kg               kJ
        mfs         hs − hf
              Hr                kg
nBo =          kg             kJ     X 100 %
         mf         X HHV
              Hr              kg
                     kg              kJ
         175000 2482.7
                     Hr              kg
0.70 =        kg                     kJ
                                           X 100 %
         mf         X 29530.17
              Hr                     kg
                     kg
mf = 21018.33
                     Hr
     A kg air       kg fuel
ma =           X mf
     F kg fuel         Hr
               kg air             kg
ma = 9.53025           X 21018.33
               kg fuel            Hr
                    kg
ma = 200309.9395
                    Hr
PVa = ma RT
                kg          kJ
     200309.9395 0.28708                                      15.6 + 273 K
                Hr         kg −k
Va =
                   101.325 kPa
                      m3
      Va = 163789.1585
                       kg
                   kg 24Hrs    1MT
      mf = 21018.33   X     X
                   Hr   day   1000 kg
      mf = 504.44 MT
   mf = 91000 kg
   ms 1 = 1591 kg
   ms 2 = 1364 kg
   nBo1 = 65 %
   nBo2 = 60 %
   F.E.1 = 1.2
   F.E.2 = 1.15
   HHV = 7590 kcal/kg
   Required:
          a) No of hours
 Solution:
                                    mF
       mf = 91000 kg
                                                                F.E.2 = 1.15
      HHV = 7590 kcal/kg                                        ms 2 = 1364 kg
                                                                nBo2 = 60 %
                             F.E.1 = 1.2                        kg
                             nBo1 = 65 % Boiler 1         Boiler 2
                             ms 1 = 1591
                             kg
                                                               mS2
                                              mS1
           mF kg
no Hrs =             kg
         mf
            Hr
         91000 kg
no Hrs =
         mf1 + mf2
                                                   For boiler no :
For boiler no 1:                                                   kg               kJ
                kg               kJ                          mfs         hs − hf
          mfs         hs − hf                      nBo 2 =
                                                                   Hr                kg
                Hr                kg                               kg              kJ
nBo 1 =         kg              kJ                            mf         X HHV
           mf         X HHV                                        Hr              kg
                Hr              kg                                 kg                          kJ
                kg                     kJ                   1364         1.15 (2257)
        1591              1.2 (2257)               mf2 =
                                                                    Hr                         kg
                 Hr           kg                                                          kJ
mf1 =                        kJ                            0.6 X 31770.222
          0.65   X 31770.222                                               kg
                             kg                                   kg
                     kg                            mf2 = 185.7258
mf1 = 208.66                                                      Hr
                     Hr
                                                       91000 kg
                                            no Hrs =
                                                       mf1 + mf2
                                                       91000 kg
                                 no Hrs =              kg                 kg
                                             208.66 + 185.7258
                                                   Hr          Hr
                                       no Hrs = 230.7385306Hrs