This safety data sheet provides information on Doom weed killer. It is classified as an extremely flammable aerosol and contains propane, n-butane, and aromatic petroleum distillates. Exposure can cause skin and eye irritation. The product contains isopropyl alcohol and naphthalene and should be stored away from heat sources in a well ventilated area. Personal protective equipment including safety glasses and chemical resistant gloves should be worn when handling.
This safety data sheet provides information on Doom weed killer. It is classified as an extremely flammable aerosol and contains propane, n-butane, and aromatic petroleum distillates. Exposure can cause skin and eye irritation. The product contains isopropyl alcohol and naphthalene and should be stored away from heat sources in a well ventilated area. Personal protective equipment including safety glasses and chemical resistant gloves should be worn when handling.
This safety data sheet provides information on Doom weed killer. It is classified as an extremely flammable aerosol and contains propane, n-butane, and aromatic petroleum distillates. Exposure can cause skin and eye irritation. The product contains isopropyl alcohol and naphthalene and should be stored away from heat sources in a well ventilated area. Personal protective equipment including safety glasses and chemical resistant gloves should be worn when handling.
This safety data sheet provides information on Doom weed killer. It is classified as an extremely flammable aerosol and contains propane, n-butane, and aromatic petroleum distillates. Exposure can cause skin and eye irritation. The product contains isopropyl alcohol and naphthalene and should be stored away from heat sources in a well ventilated area. Personal protective equipment including safety glasses and chemical resistant gloves should be worn when handling.
PRODUCT CODE: 4520 PRODUCT USE: Weed Killer COMPANY NAME: QuestVapco Corporation COMPANY ADDRESS: PO Box 624 Brenham, TX 77834 COMPANY PHONE: 1-800-231-0454 EMERGENCY PHONE: 800-255-3924 SECTION II – HAZARDS IDENTIFICATION
CLASSIFICATION: Flammable Aerosol: Category 1
Liquefied Gas Skin Irritant: Category 2 Eye Irritant: Category 2b Aspiration Hazard: Category 1 HAZARD STATEMENT(S): DANGER: Extremely Flammable Aerosol Contains gas under pressure; May explode if heated. Causes skin and eye irritation. May be fatal if swallowed and enters airways. This product contains the following percentage of chemicals of unknown toxicity: 0% PRECAUTIONARY STATEMENTS: Keep away from heat, sparks, open flames, and hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Wash hands thoroughly after handling. Wear protective gloves. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. If swallowed: Immediately call a poison center or doctor. Do NOT induce vomiting. Store locked up. Dispose of contents and container in accordance with local, state, and national regulations.
SYMBOL: HAZARDS NOT OTHERWISE CLASSIFIED: N/A SECTION III – COMPOSITION/INFORMATION ON INGREDIENTS
EYES: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. INGESTION: Contact physician; do not induce vomiting unless directed by medical authority. INHALATION: Move to fresh air. If breathing is difficult, administer oxygen. If not breathing administer artificial respiration or at any sign of loss of consciousness seek immediate medical attention. SKIN: Immediately wash with soap and water for 15 minutes. Remove contaminated clothing and shoes immediately. Seek medical attention if irritation develops. ACUTE HEALTH HAZARDS: Eyes: redness, tearing, blurred vision Skin: defatting and dermatitis Oral: abdominal irritation, nausea, vomiting, diarrhea, aspiration risk CHRONIC HEALTH HAZARDS: None known NOTE TO PHYSICIAN: There is no specific treatment regimen. Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient. PAGE 1 of 4 Safety Data Sheet Doom
SECTION V – FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, and alcohol foam.
UNSUITABLE EXTINGUISHING MEDIA: Water spray/stream. SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing and NIOSH approved SCBA with full facepiece operated in positive pressure or pressure demand. Use water mist to keep material cool in fire situations. UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. HAZARDOUS COMBUSTION PRODUCTS: Oxides of carbon
SECTION VI – ACCIDENTAL RELEASE MEASURES
PERSONAL PROTECTIVE EQUIPMENT: Refer to section VIII for proper Personal Protective Equipment. SPILL: Use absorbent on spill sweep to clean. Dispose in accordance with local, state and federal laws. Small releases may be wiped up with wiping material. WASTE DISPOSAL: Dispose of in accordance with federal, state, and local regulations. Containers may be hazardous when empty. RCRA STATUS: Waste likely considered hazardous under RCRA, however product should be fully characterized prior to disposal (40 CFR 261). SECTION VII – HANDLING AND STORAGE
HANDLING AND STORAGE: Protect from sunlight. Store in a well ventilated place. Do not expose to temperatures exceeding 50°C/122°F. Pressurized container: Do not pierce or burn, even after use.
OTHER PRECAUTIONS: Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warning and precautions listed for the product. Keep out of the reach of children INCOMPATIBILITY: Some plastics
SECTION VIII – EXPOSURE CONTROLS/PERSONAL PROTECTION
HAZARDOUS INGREDIENT OSHA PEL ACGIH TLV
Aromatic Pet. Hydrocarbons Not Established Not Established Isopropyl Alcohol 400 ppm 200 ppm Naphthalene 10 ppm 10 ppm Propane/n-Butane 1000 ppm 1000 ppm
ENGINEERING CONTROLS / VENTILATION: Use only outdoors or in a well-ventilated area.
RESPIRATORY PROTECTION: Not required with adequate ventilation PERSONAL PROTECTIVE EQUIPMENT: Safety glasses and chemical resistant gloves ADDITIONAL MEASURES: Wash hands thoroughly after handling.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Clear to hazy light brown aerosol
ODOR: Petroleum odor ODOR THRESHOLD: N/D BOILING POINT: >350 FREEZING POINT: N/D FLAMMABILITY: Extremely Flammable Aerosol FLASH POINT: < 100°F AUTOIGNITION TEMPERATURE: N/D LOWER FLAMMABILITY LIMIT: N/A UPPER FLAMMABILITY LIMIT: N/A VAPOR PRESSURE (mm Hg): N/D VAPOR DENSITY (AIR=1): >4 EVAPORATION RATE: < 1 PAGE 2 of 4 Safety Data Sheet Doom SPECIFIC GRAVITY (H2O=1): 0.89 pH: N/A SOLIDS (%): N/D SOLUBILITY IN WATER: 0% PARTITION COEFFICIENT: n-OCTANOL/WATER (KOW): N/D VOLATILITY INCLUDING WATER (%): 99% VOLATILE ORGANIC COMPOUNDS (VOC): 27% DIELECTRIC STRENGTH (Volts): N/D DECOMPOSITION TEMPERATURE: N/D VISCOSITY: N/D SECTION X – STABILITY AND REACTIVITY DATA
REACTIVITY: If exposed to strong oxidizers, presents explosion hazard.
CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Temperatures greater than 122°F and sources of ignition. INCOMPATIBILITY: Some plastics HAZARDOUS DECOMPOSITION OR BY-PRODUCT: Oxides of carbon. Exposure to red hot surfaves may produce carbon monoxide. POSSIBLE HAZARDOUS REACTIONS: None Known
SECTION XI – TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION: Isopropyl Alcohol (67-63-0) LD50 (Oral,Rat) 5045 mg/kg; LD50 (Oral, Rabbit) 5045 mg/kg; LD50 (Dermal, Rabbit) 12,800 mg/kg; LC50 (Inhalation, Rat, 8hr) 16,000 ppm ROUTES OF ENTRY: Eyes, Ingestion, Inhalation, Skin EYES: May cause irritation, redness, itching or burning may indicate excessive exposure. INGESTION: May cause gastrointestinal irritation, headaches, nausea, diarrhea. INHALATION: May cause dizziness, headaches, excessive or prolonged exposure may cause unconsciousness. SKIN: May cause irritation, localized defatting. Redness and itching or burning sensation may indicate excessive exposure. MEDICAL CONDITION AGGRAVATED: None known ACUTE HEALTH HAZARDS: Eyes: redness, tearing, blurred vision Skin: defatting and dermatitis Oral: abdominal irritation, nausea, vomiting, diarrhea, aspiration risk CHRONIC HEALTH HAZARDS: None known CARCINOGENICITY: OSHA: No ACGIH: No NTP: No IARC: No OTHER: N/A
SECTION XII – ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: Isopropyl Alcohol (67-63-0) LC50 (Fathead Minnow, 96 hrs) 100,000 mg/L This pesticide is toxic to fish and aquatic invertebrates. Do not apply directly to water, to areas where surface water is present, or to intertidal areas below the mean high water mark. Drift and runoff may be hazardous aquatic organisms in water adjacent to treated areas. This chemical has properties and characteristics associated with chemicals detected in groundwater. The use of this chemical in areas where soils are permeable, particularly where the water table is shallow, may result in grounwater contamination. Application around a cistern or well may result in contamination of drinking water or groundwater. Drift or runoff may adversely affect aquatic invertebrates and nontarget plants. Do not contaminate water when disposing of equipment washwaters. Do not store near fertilizers, seeds, insecticides or fungicides. Do not apply when ground is frozen. Do not apply to areas underlain by roots of desirable trees and shrubs. BIODEGRADABILITY: Component or components of this product are not biodegradable. BIOACCUMULATION: Components in this mixture can bioaccumulate in aquatic organisms. SOIL MOBILITY: This product is mobile in soil. OTHER ECOLOGICAL HAZARDS: This material is toxic to aquatic life. SECTION XIII – DISPOSAL CONSIDERATIONS
WASTE DISPOSAL: Dispose of in accordance with federal, state, and local regulations. Containers may be hazardous when empty. RCRA STATUS: Waste likely considered hazardous under RCRA, however product should be fully characterized prior to disposal (40 CFR 261).
PAGE 3 of 4 Safety Data Sheet Doom SECTION XIV - TRANSPORTATION INFORMATION
PROPER SHIPPING NAME: Aerosols, Ltd. Qty.
HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 PACKAGING GROUP: N/A
AIR SHIPMENT PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950
CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): None SARA 311/312 HAZARD CATEGORIES: Fire Hazard SARA 313 REPORTABLE INGREDIENTS: Napthalene 91-20-3 STATE REGULATIONS: California Proposition 65: Warning: This product contains a chemical known to the State of California to cause cancer. Naphthalene Cas # 91-20-3, Illinois – RTK, Minnisota – RTK, New Jersey – RTK, Pennsilvania – RTK, Rhode Island - RTK INTERNATIONAL REGULATIONS: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification crieteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: Causes moderate eye irritation. Avoid contact with eyes, skin, or clothing. Harmful if swallowed. FLAMMABLE: Contents under pressure. Do not use near fire, sparks or flame. Do not puncture or incinerate container. Expoosure to temperatures above 130°F may cause bursting. EPA Reg. No. 44446-61 NFPA HEALTH: 2 HMIS HEALTH: 2 NFPA FLAMMABILITY: 3 HMIS FLAMMABILITY: 3 NFPA REACTIVITY: 1 HMIS REACTIVITY: 1 NFPA OTHER: None HMIS PROTECTION: B
SECTION XVI - ADDTIONAL INFORMATION
PREPARATION BY: Jonathon Jarvis
DATE PREPARED: 11/11/2013 REVISION DATE: 11/04/2014
N/A = Not Applicable; N/D = Not Determined
DISCLAIMER: To the best of our knowledge, information contained herein is accurate. However there is no assumption of liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazard which exists. The information contained in this SDS was obtained from current and reliable sources; however, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of the manufacturer, the manufacturer will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this SDS shall be created or inferred by any statement in this SDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this SDS. The user is responsible for full compliance. PAGE 4 of 4
