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Solution to Advanced Level Problem Solving-2209

JEE 2022 | Chemistry
Solid State, Liquid Solution, Electrochemistry, Chemical Kinetics, Surface
Chemistry, Coordination Compounds, Metallurgy, Stereochemistry,
d-Block Elements, Aromatic Compounds, Environmental Chemistry &
Practical Organic Chemistry

1.(C) 2.(B) 3.(B)

Cl 
.log    E0
0.0591 0.0591 1
4.(A) Ecell  E0   |Ag  log
Ag|Ag  1  KSP  Ag 1  Ag  
 c
 Ag    Cl   Ag  
0.0591  c    c
E cell  0  log  0.0591log
1  Ag   Cl   Ag  
 a    a
If Ag     Ag   then Ecell  0
c a
x
3
40  39.6
5.(B)  174
39.6 50
x  29.29g
29.29
%  100  72%
40.65
6.(C) 4.05  105  2  C  0.082  330
C  7.483 107
 Ksp  5.6 1013
29.29
7.(C) SO42   174  0.224
900  29.29 1

1.24 1000
13
  Ba 2   5.6 10  2.5 1012 M.
  0.224
29.29
8.(A) Tb  i  K b  m  3  0.54  174  0.3
0.9
9.(D) 10.(BC) 11.(AB)

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12.[A-p, s]  [B-r]  [C-q]  [D-p, s]

(A) Fe(OH)3  Lyophobic colloid & hence irreversible
(B) Micelles  They are associated colloids
(C) Gelatin  It is a lyophilic colloid
(D) Arsenious sulphide (AS2S3 )  lyophobic colloid and hence irreversible
13.(D) Sulphide ore is concentrated by froth flotation by using wetting oil.
14.(B) 15.(B)

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Cd2  4CH3 NH2 

1 [Cd(CH NH ) ]2 K
16.(ABD) 3 2 4

Cd2  2en 
K
[Cd(en)2 ]2

2
-B is more stable than A due to chelation.
17.(B) 18.(D)
1
19.(C) Cell reaction is H2  g   O2  g   H2O  
2
0.06 1 0.06 1
Ecell  1.246  log  1.246  log
2 PH2  PO2 2 20 10

0.06  1
 1.246  1.3    1.246  0.054  1.3V
2  2
V 1.3
20.(A) i    0.04825A
R 26.94
5
Time of electrolysis   500 minutes
10 103
1
Cu 2  aq   H2O  Cu   aq   O2  2H   aq 
2
i  t 0.04825  500  60
 moles of H formed    0.015 M
F 96500
21.(B) In resulting solution, Cu 2   0.05  0.0075  0.0425 M,  H    0.015 M and SO 42   0.05 M
 2
  Cu 2      H   SO2  SO4 
kk k k  Cu 2    H   4
Cu 2  H SO24 1000 1000 1000
0.01104  0.0425 0.035  104  0.015 0.016  104  0.05
   0.00425  0.00525  0.008  0.0175Scm1
1000 1000 1000
 1.75Sm 1
d c c
22.(A) 4d c c sin  5444 '   2 a  r  0.78
2
8  12
23.(C) d   3.37 gm / cc
NA  a3
1.2  N A
24.(C) Total number of unit cells   7.5  1021
12  8
25.(B) 26.(BCD) 27.(B) 28.(C)
29.(D)
30. [A-s]  [B-r]  [C-q]  [D-p]
(A) Coagulation  It is done by addition of electrolyte
(B) Dialysis  If is a method of preparation of colloid
(C) Peptization  It is defined as the process of converting a precipitate into colloidal solution by
shaking it with dispersion medium in the presence of small amount of electrolyte
(D) Tyndall effect: The scattering of light as the light beam passes through a colloid.

VMC | Chemistry | Solutions 3 ALPS-2209| JEE-2022

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31.(AD)

M L, In metal carbonyl complexes, C–O bond length increases compared to that in CO molecule

as filled ‘d’ orbital of metal atom overlaps with   antibonding M.O. of CO [CrCl3 (H 2 O)3 ].3H 2 O is
not hydrate isomer of [Cr(H 2O)6 ]Cl 3 .
Facial and Meridional isomers of [Ma3b3 ]n  complex are optically inactive as each one contains plane
of symmetry.
32.(B) 33.(B)
34.(C)  Cm  
m b C

When C1  4 104  m  107

And when C2  9 104  m  97
So 107  m  b  2  102 ....…. (i)
97   
m  b  3  10
2
....…. (ii)
b  1000
 m  
m b C


m   m  b C  107  10  2  10
3 2

 1
m  127 ohm cm mole
2 1

35.(D) For 25 104  M NaCl Solution

 m  
m b C

 
1/2
 m  127  103 25 104

 m  127  103  5 102

 m  77
1000.G.

M
M M M 25 104  77 1000
So       0.1925cm1
1000G 1000G 1000G 1000
M MR 1000
36.(D)    
1000G 1000 MR
1000  0.1925
  192.5
5  103
 400
2

37.(B)

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2 4
Total mole  n A  n B  n C  1    3mole
3 3
2
38.(C) moleB 
3
39.(B) 40.(AB) 41. A - P; B - R; C - Q; D - P, Q, S
42.(C) Highly reactive metals are extracted by electrolytic process.
43.(D) 44.(C)
45.(ABD)
0.0591
Ecell  Ecell
0
 log Q if Q = 1
n
E cell  E 0cell

0.01 0.12 0.12 0.12

(A) Q 1 (B) Q 1 (C) Q  0.01 (D) Q 1
0.12 0.01 1 0.01

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46.(ABD) [CoF6 ]3 : 0  P and High spin complex

Total isomers = 4
47.(C) 48.(D)
49.(D) Deposition order Cu  M  Zn
I t w
Cu required  
96500 E
20  t  1 2  2  96500
t  19300sec

In 28950  19300  9650sec M 2 , will deposit as M.

20  9650
mole of M  2 
9650
mole of M deposit  1
1
Initial mole of M2  1 2; remain M 2 moles = 2  1  1;  M2    0.5
2
50.(AC)
20  28950
Total charge   6F
96500
Mole of Br2 formed = 2
Mole of Cl2 formed = 1
2
51.(A) Zn 2  4NH3 Zn  NH3 4 K f  1109
1 x 18  4x  4y x
2
Zn  NH3 4 1
Zn 2    1013
 K  NH  
f 3
4
10  10
9 4

For Zn 2  2e  Zn  s 
0.06 1 13
E R.P.  0.76  log 13  0.76  0.06   1.15V
2 10 2

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2
Cu 2  4NH3 Cu  NH3 4 K f  1 1012
1 18
1 y 18  4x  4y y
2
Cu  NH3 4
Cu 2    1016
 
K f  NH3 
4

For Cu 2  2e  Cu  s 
0.06 1
E R.P.  0.34  log 16  0.34  0.06  8  0.14V
2 10
2 6
52.(ABD) P0  X A PA  X B PB   300   500  450mm of Hg
8 8
P0  Ps 450  420 1
Now, RLVP   
P0 450 15

Also, RLVP 
in 

 in  N 
32i
70
i  1.25  1   2  1  
1 32i
 8 
15 70
So   0.25 (or 25%)
25 32 4
 n produced   
Cl 100 70 35
1 4 2
 n pbCl2 precipitated   
2 35 35
53.(C) 54.(AC) 55. A - Q, R, S; B - Q; C - P; D - R, S
56.(B) Pb is mainly extracted by self reduction method.
57.(C) 58.(D) 59.(AB)
At Cathode: Cu 2  2e  Cu  s 

At Anode: Cu  s   Cu 2  2e
2.68  3600 63.5
Increase in mass of cathode = decrease in mass of Anode    3.174 g
96500 2
60.(ABC)
P  20 6 18 6 1
    ….(i)
20 M 180 M 10
P  20.02 6 18 6 1
    ….(ii)
20.02 M 198 M 11
From (i) and (ii) calculation gives
M 54gm / mole
P  20.22 torr

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61.(ACD) d-orbitals losses their degeneracy because of the formation of complexes.

(a) Blue vitriol– CuSO 4  5H 2 O
(c) Potassium ferrocyanide – K 4 [Fe(CN)6 ]
(d) Potassium ferricyanide – K 3[Fe(CN)6 ]
62.(C) 63.(A)

64.(BCD) H2  g  H H H2  g 
P1 C 2C P
2
Anodic reaction
1
H2  H  e
2
Cathodic reaction
1
H  e  H2
2
1 1
H H
H2 H2
2   2 
(anode) (cathode) (cathode) (anode)

E 0cell  0

0.06  PH2 cathode

E cell  E cell
0
 log
1
 PH2 anode  H cathode
 1 C  1
E cell  0.06 log 
9

2C   0.06 log 2  3  0.06  log 2  log 3  0.06  0.3  0.48   0.0468 volt
 
g.w.t. 1000
65.(ABC) Tf  m  K f    Kf
MM (g.w.t.)solvent
2.25 1000
0.256    5.12
MM 250
M.M.  180g / mol
g.w.t. 1000 2.25 1000
Tb  m  K b    Kb    2.53  0.1265
MM (g.w.t)solvent 180 250
B.P. of solution = 353.3  0.1265  353.425K
2.25
V.P. nB 180
 XB    0.00388
Psolvent n A  n B 2.25  250
180 72
66.(B) 67.(ABC) 68. A-P; B-P,Q,S; C-P,Q,R,S; D-P, S
69.(C) Refer NCERT 70.(B) 71.(D)
72.(AC) Cu   Cu 2   Cu
E0cell  E0 E
cu  |Cu 2 Cu  |Cu

e   Cu   Cu
Cu  Cu 2  2e 
Cu   Cu 2  e 

E  1 0.521  2  0.337  0.153

Cu  |Cu 2

E0cell  0.153  0.521  0.368 reaction is spontaneous

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73.(ACD) x A PA  X B PB  700 ….(i)

x A ''PA  x B ''PB  0.30 PA  0.70 PB0  600 ….(ii)
If moles of A & B initially are x and y then
2 1
x  0.75  x  y   0.30   x  y  ….(iii)
3 3
x y
And xA  or x B  ….(iv)
xy xy
Solving gives
2500
x A  0.6 , x B  0.4 , PA  torr and PB  500 torr
3
74.(C) 75.(ABC)

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76.(B) Dolomite : CaCO3 .MgCO3

77.(ABCD) 78.(C)
79.(CD)
Create a cell with required cell reaction
O2  SO42  S2 O82  H 2 O E 0cell  1.23  2.01  0
 Nonspontaneous cell reaction
80.(BD)
Number of particles from K 4  Fe  CN 6   5
Number of particles from FeSO4  NH 4 2 SO4 .6H 2 O  5
Number of particles from KCl.MgCl2 .8H2O  5
81.(C) 82.(ABC) 83.(D) 84.(A)
85.(D)
86.(ABC)
On basis of given SRP values
87.(AB)
1 2
Ptotal  PB0 X B  PT0 X T = 42   36  = 38 mm.
3 3
PM YB  PB0  X B where YB is the mole fraction of Benzene is vapour phase
38  YB  14
14 7
YB  
38 19
88.(B)
89. [A-R] [B-P] [C-S] [D-PQRD]
90.(B) Heating of ore in presence of oxygen is called Roasting. Roasting is done to convert ore into its oxide.

VMC | Chemistry | Solutions 10 ALPS-2209| JEE-2022