Chem 2 - M2A
Chem 2 - M2A
General Chemistry 2
 Quarter 3: Week 2 - Module 2A
   Properties of Liquids and
    Intermolecular Forces
             Target
Jumpstart
                    Before going on, let’s check how accurate your observation and
             thinking skills are as you do the first activity.
Have fun and good luck! Are you ready? Let’s start!
      1.                                                 2.
       3.                                                  4.
5. 6.
7. 8.
9. 10.
       Matter is anything that occupies space and has mass. Matter is divided into
different phases such as solid, liquid, gas, plasma, and Bose-Einstein Condensates.
The first three phases of matter differ in various properties such as volume/shape,
density, compressibility, motion of their molecules, and their molecular behavior.
I. Surface Tension
       The cohesive forces between liquid molecules are responsible for the
phenomenon known as surface tension. The cohesive forces between molecules
down into a liquid are shared with all neighboring atoms. Those on the surface have
no neighboring atoms above, and exhibit stronger attractive forces upon their nearest
neighbors on the surface. This enhancement of the intermolecular attractive forces
at the surface is called surface tension.
        Surface tension is the measure of the elastic force in the surface of a liquid.
It is the amount of energy required to stretch or increase the surface of a liquid by a
unit area. It is the energy, or work, required to increase the surface area of a liquid
due to intermolecular forces. It is manifested as some sort of skin on the surface of
a liquid or in a drop of liquid.
        Molecules within a liquid are pulled in all directions by intermolecular forces.
Molecules at the surface are pulled downward and sideways by other molecules, not
upward away from the surface (See next page).
          Figure 2: Molecules within a liquid (Image Source: wps.prenhall.com)
   These intermolecular forces tend to pull the molecules into the liquid and cause
the surface to tighten like an elastic film or “skin”.
   Liquids that have strong intermolecular forces also have high
surface tension.
FYI:
      Surface tension is typically measured in dynes/cm, the force in dynes required
to break a film of length one cm. Equivalently, it can be stated as surface energy
in ergs per square centimeter. Water at 20°C has a surface tension of 72.8
dynes/cm compared to 22.3 for ethyl alcohol and 465 for mercury.
       Figure 5. Water strider walking on the surface of a quiet pond. (Image Source:
http://hyperphysics.phy-astr.gsu.edu/hbase/surten.html)
It’s Viewing Time!
       To view how water droplets form on the surface of the water pool because of
surface       tension,      you       may       refer      to       this     link:
https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Tex
tbook_Maps/Supplemental_Modules_(Physical_and_Theoretical_Chemistry)/Physic
al_Properties_of_Matter/States_of_Matter/Properties_of_Liquids/Surface_Tension.
Capillary Action
       Figure 6. Colored water seen rising up in glass tubes. Without capillary action,
the water level in all tubes would be the same. Smaller diameter tubes have more
relative surface area inside the tube, allowing capillary action to pull water up higher
than       in      the      larger       diameter       tubes       (Image       Source:
http://water.usgs.gov/edu/capillaryaction.html)
       Credit: Dr. Keith Hayward
      Figure 7. A doctor takes blood sample from a patient’s finger using a capillary
tube. (Image Source: https://www.colourbox.com/image/blood-testing-image-
6891015)
       Figure 8. Water mixed with food coloring rises up freshly-cut stalks of
celery (Image Source: http://water.usgs.gov/edu/capillaryaction.html)
 REMEMBER:
       Capillary action is a phenomenon wherein a liquid is able to rise up on a
 narrow tube. Adhesive forces between the tube and the liquid allow the liquid to
 exceed its weight. The narrower the tube, the higher the liquid will reach.
        Capillary action is the result of cohesive and adhesive forces. When liquid
 flows through a narrow space, the cohesive and adhesive forces act together to lift
 it against the natural force of gravity.
FYI:
      Viscosity is expressed in units of centipoise (cP), also known as stoke. It
is a metric system unit. The SI unit is Pascal-second (Pa-s) or Newton-
second/meter2 (N-s/m2).
       Table 1 below shows the viscosities of liquids of some pure substances. Water
has viscosity of 1 centipoise or 0.001 Pa/s at 20 oC.
       Substances with lower viscosities include carbon tetrachloride and benzene.
Glycerol has a resistance to flow of more than a thousand times greater than water.
REMEMBER:
       The more viscous a liquid is, the thicker is its consistency. The liquid with
the longest time to flow is, the most viscous while the one with the shortest time is
the least viscous.
        In general, stronger intermolecular forces leads to higher viscosity.
       Thus, the most viscous liquid has the strongest intermolecular force and
the least viscous liquid has the weakest intermolecular force.
Examples:
      1. Given the molecular structures of water and glycerol, can you tell why
         glycerol has a higher viscosity than water?
 REMEMBER:
        The larger number of –OH groups allow glycerol to form more H-bonds
 with other glycerol molecules, making its intermolecular forces stronger than
 those of water, and its resistance to flow greater.
 REMEMBER:
       The size of the molecules affects the viscosities of the hydrocarbons. The
 larger the molecule, even if it is nonpolar, the stronger the intermolecular
 forces and the greater the viscosity compared to nonpolar substances made up
 of small molecules.
It’s Thinking Time!
  The Idea:
         Viscosity and temperature are inversely proportional with each other.
   Figure 10. Evaporation of water in open and in closed containers (Image Source:
http:// boomeria.org/physicslectures/heat/equilibrium.jpg)
(a) The water molecules in the liquid evaporate and go into the vapor phase. In the
   open flask, some of the water molecules in the vapor phase find their way out of
   the flask are lost to the atmosphere.
(b) When a liquid evaporates to a gas in a closed container, the molecules cannot
    escape.
      Gas molecules move in random directions, collide with other gas particles and
the walls of the container.
       Some will strike the liquid surface and condense back into it. In the closed
flask, none of the gas particles are able to get out of the container, and eventually,
the number of molecules that go into the gaseous state would equal the number of
molecules that condense back.
       When the rate of condensation of the gas becomes equal to the rate of
evaporation of the liquid, the gas in the container is said to be in equilibrium with
the liquid.
                                liquid ⇋ vapor (gas)
  Figure 11. Equilibrium between liquid and gas (Image Source: http://
wpscms.pearsoncmg.com/wps/media/objects/3662/3750037/Aus_content_10/Fi
g10-20.jpg)
      Look at the given Figure below. Study the following plot of vapor pressure of
water as it varies with temperature.
       Ethyl alcohol and water have very low vapor pressures. Both liquids have the
strong dipole-dipole interaction called hydrogen bonding. Acetone is polar but does
not have H-bonding. Its vapor pressure is of intermediate value. Pentane is a
nonpolar substance, and its vapor pressure is high compared to those of water and
ethyl alcohol.
      When liquids evaporate, the molecules have to have sufficient energy to break
the attractive forces that hold them in the liquid state. The stronger these
intermolecular forces are, the greater the amount of energy needed to break them.
       For some substances with weak intermolecular forces, the energy requirement
is easy obtained from collisions with other molecules and absorption of energy from
the surroundings. Many molecules can vaporize, resulting in a high vapor pressure.
For molecules with strong intermolecular forces, gathering enough energy may not
be as easy, and register low vapor pressures.
  The Idea:
        The stronger the intermolecular forces of attraction, the lower the vapor
  pressure of a liquid.
  Remember:
         The relationship between vapor pressure and strength of intermolecular
  forces is consistent with the trends in two other properties of liquids, the enthalpy
  or molar heat of vaporization, and the boiling point of the liquid.
       It is easier to vaporize acetone (lower Hvap) than water (higher Hvap) at a given
temperature, and more acetone escapes into the vapor phase at a given temperature.
Acetone is a polar substance but has no H-bonding. It has weaker intermolecular
forces than water, and therefore acetone molecules are held less tightly to one
another in the liquid phase.
Boiling Point
        The boiling point of a liquid is the temperature at which the liquid converts
into a gas. A liquid boils when its vapor pressure equals the pressure acting on the
surface of the liquid. The boiling point is the temperature at which the vapor pressure
of a liquid is equal to the external pressure. Also, it is the temperature at which liquid
  boils. The boiling point of a liquid when the external pressure is 1 atm is called the
  normal boiling point.
         The normal boiling point is the temperature at which the liquid converts to
  a gas when the external pressure is 1 atm. The normal boiling point of water is 100 oC.
    Remember:
        The boiling point of a liquid depends on the external pressure. For
    example, at 1 atm, water boils at 100oC, but if the pressure is reduced to 0.5 atm,
    water boils at only 82oC.
    Remember:
           The boiling point is directly related to molar heat of vaporization: the higher
    ΔHvap, the higher the boiling point.
           The boiling points of substances often reflect the strength of the intermolecular
    forces operating among the molecules. At the boiling point, enough energy must
    be supplied to overcome the attractive forces among molecules before they can
    enter the vapor phase.
       Can you identify substances other than water that can exist naturally in all
three states? Can you identify some unusual properties of water? Can you explain
why water is said to be one of the most unusual substances on earth?
            Unlike all other liquids, the molecules in solid water are actually farther
     apart than they are in liquid water. When solid water forms, the hydrogen
     bonds result in a very open structure with unoccupied spaces, causing the
     solid to occupy a larger volume than the liquid. This makes ice less dense than
     liquid water, causing ice to float on water.
Explore
Objectives:
      A. To determine the properties of liquids;
      B. To explain how intermolecular forces affect the properties of liquids; and
      C. To explain the how the properties of water are related to its structure and
         intermolecular forces.
Materials:
      liquid samples: water, ethyl alcohol, kerosene        three droppers
      beakers or glass jars with wide mouth                 three pieces blade
      small piece of wax paper or plastic sheet             glass jar
      old newspapers to catch drips and spills              one-peso coins
      plastic straw                                         plastic sheet
      salt                                                  pepper
      sugar                                                 talcum powder
Procedure:
Part A: “Liquid and Drops on A Wax Paper”
     a. Lay a piece of wax paper flat on the surface of the table.
     b. Using a dropper, place a drop of a liquid sample on the wax paper.
         Do the same for the two other liquids. Make sure a different dropper
         is used for each of the liquid samples to avoid contamination.
     c. Observe and record the appearance of the drops of the liquid samples
        on wax paper.
REMINDER:
         1. Use the different materials for their intended purposes only for this
            activity.
         2. Do not play with the materials especially the sharp ones.
         3. Dispose the used materials and liquids properly.
         4. Do NOT mix the liquids.
         5. Never taste the liquids.
Part A:
      1. How would you describe the appearance of the drops of the liquid samples
         on wax paper?
         ________________________________________________________________________
         ________________________________________________________________________
         ________________________________________________________________________
         ________________________________________________________________________
         ________________________________________________________________________
Part B:
      1. Did the blade float on the surface of the liquids? Why or why not?
         ________________________________________________________________________
         ________________________________________________________________________
         ________________________________________________________________________
         ________________________________________________________________________
         ________________________________________________________________________
Part C:
      1. What happened to the level of the water in the glass jar?
         ________________________________________________________________________
         ________________________________________________________________________
      2. What happened to the water in the jar when you added more one-peso
         coins?
         ________________________________________________________________________
         ________________________________________________________________________
      3. How many coins were added without causing the water to overflow?
         ________________________________________________________________________
Part D:
     3. What are the properties of water and how do they relate to its structure
        and intermolecular forces?
        ________________________________________________________________________
        ________________________________________________________________________
        ________________________________________________________________________
        ________________________________________________________________________
        ________________________________________________________________________
        ________________________________________________________________________
Performance Task:
  Goal: To draw and explain the relationship of the properties of water to an
       environmental phenomenon
           Note: On a short bond paper, draw and explain how the property of water
                 is related to one of the following situations:
  Standard: Criteria for your task is shown in the given rubric on the next page:
                             Rubric for Essay: High School
                      Highly
                                         Proficient          Developing             Beginning
  CRITERIA          Proficient                                                                        SCORE
                                            (3)                 (2)                    (1)
                         (4)
                 The essay is         The essay is         The essay is          The         essay
                 focused,             focused on the       focused on topic      poorly
 Focus/ Main
                 purposeful, and      topic        and     and     includes      addresses topic
 Point
                 reflects     clear   includes             few       loosely     and     includes
                 insight       and    relevant ideas.      related ideas.        irrelevant ideas.
                 ideas.
                 Persuasively         Supports main        Supports main         Provides little or
                 supports main        point     with       point with some       no support for
                 point with well-     developed            underdeveloped        the main point
 Support         developed            reasons and/or       reasons and/or
                 reasons and/or       examples             examples
                 examples
                 Effectively          Organizes ideas      Some                  Little  or   no
 Organization
                 organizes ideas      to  build    an      organization of       organization of
 & Format
                 to     build     a   argument             ideas to build        ideas to build
 (Paragraphs,
                 logical, coherent                         an argument           an argument
 Transitions)
                 argument
                 Effective     and    Appropriate use      Some use of           Little or no use
 Language        creative use of      of elements of       elements      of      of elements of
 Use, Style &    elements        of   style       Uses     style Contains        style      Many
 Conventions     style to enhance     correct              frequent errors       errors        in
 (Sentence       meaning Uses         grammar,             in     grammar,       grammar,
 structure,      correct              spelling,    and     spelling,   and       spelling,    and
 word choice,    grammar,             punctuation          punctuation           punctuation,
 grammar,        spelling,            with few errors                            makes reader’s
 spelling,       punctuation                                                     comprehension
 punctuation)    throughout with                                                 difficult
                 very few errors
                 Distinctive          Sufficient           Very         little   No
                 experimentation      experimentation      experimentation       experimentation
                 with language        with language        to       enhance      nor
 Originality     and usage to         and usage to         concepts Does         enhancement of
 (Expression     enhance              enhance              not        exhibit    concepts     No
 of the theme    concepts             concepts             creativity            adherence    to
 in a creative   Applies higher       Applies     basic                          the theme
 way)            order thinking       creative skills to
                 and       creative   relay ideas
                 skills to relay
                 complex ideas
Gauge
Direction: Write the CAPITAL letter of the correct answer on a separate paper.
           (15 points)
Answer Key