Measure

what is measurable
and make measurable
that which is not.
Galileo Galilei (1564-1642)

Instruction Manual and Safety Information

Xsample 330
Sample Changer
Module Firmware Version: from 1.007.021
M Series Instruments Software Version: from 2.98
DMA 4101/4501/5001 Software Version: from 2.0.0
(Original Instructions)
Disclaimer
This document may contain errors and omissions. If you discover any such errors, or if you would like to see
more information in this document, please contact us at our address below. Anton Paar assumes no liability
for any errors or omissions in this document.

Changes, copyright, trademarks, etc.

This document and its contents may be changed or amended by Anton Paar at any time without prior notice.
All rights reserved (including translation). This document, or any part of it, may not be reproduced, changed,
copied, or distributed by means of electronic systems in any form (print, photocopy, microfilm, or any other
process) without prior written permission by Anton Paar GmbH.
Trademarks, registered trademarks, trade names, etc. may be used in this document without being marked
as such. They are the property of their respective owner.

Further information
Published and printed by Anton Paar GmbH, Austria
Copyright © 2021 Anton Paar GmbH, Graz, Austria
Address of the instrument producer: Anton Paar GmbH
Anton-Paar-Str. 20
A-8054 Graz / Austria – Europe
Tel: +43 (0) 316 257-0
Fax: +43 (0) 316 257-257
E-Mail: info@anton-paar.com
Web: www.anton-paar.com

Date: April 2021

Document number: E67IB001EN-I
 Contents

Contents
1 Safety Instructions ................................................................................................................................ 5
2 Xsample 330 – An Overview ................................................................................................................ 7
2.1 View of Xsample 330 ...................................................................................................................... 8
3 Checking the Supplied Parts ............................................................................................................... 9
4 Installing the Device ........................................................................................................................... 12
4.1 Installation Requirements ............................................................................................................. 12
4.2 Installation ..................................................................................................................................... 12
4.3 Checking the Software Version of the Master Instrument ............................................................. 12
4.4 Mounting Xsample 330 ................................................................................................................. 12
4.5 Mounting the Adapters of the Master Instrument .......................................................................... 13
4.6 Checking for Leak Tightness ........................................................................................................ 14
4.7 Hose Connections ......................................................................................................................... 14
4.7.1 Connecting the Rinsing Hoses "Rinse" ................................................................................. 14
4.7.2 Connecting the Check Valve ................................................................................................ 15
4.7.3 Automatic Drying .................................................................................................................. 15
4.7.4 Xsample 330 ......................................................................................................................... 16
4.7.4.1 Hose connections for Xsample 330 (automatic drying) ................................................ 16
4.7.4.2 Alternative hose connections for Xsample 330 ............................................................. 17
5 Operating Xsample 330 with M Series Instruments ......................................................................... 18
5.1 Switching the Measuring System On/Off ...................................................................................... 18
5.2 Activating/Deactivating Xsample 330 ............................................................................................ 18
6 Performing a Measurement with Xsample 330 and M Series Instruments .................................... 19
6.1 Editing the Sample List ................................................................................................................. 19
6.2 Xsample 330 Method Settings ...................................................................................................... 19
6.2.1 Filling Mode .......................................................................................................................... 19
6.2.2 Filling Time ........................................................................................................................... 19
6.2.3 Filling Time - Repeated Mode ............................................................................................... 19
6.2.4 Pump Speed ......................................................................................................................... 19
6.2.5 Draining Mode ...................................................................................................................... 20
6.2.6 Cleaning ................................................................................................................................ 20
6.2.7 Special Cleaning ................................................................................................................... 21
6.3 Measurement Modes .................................................................................................................... 22
6.3.1 RM (Repeated Mode) ........................................................................................................... 22
6.3.2 MM (Multiple Measurement) ................................................................................................. 22
6.4 Starting a Measurement ................................................................................................................ 22
6.5 Rinsing Liquids .............................................................................................................................. 23
7 Xsample 330 Utilities with M Series Instruments ............................................................................. 24
7.1 Initialization ................................................................................................................................... 24
7.2 Customized Cleaning .................................................................................................................... 24
7.3 Service Utilities ............................................................................................................................. 24
8 Operating Xsample 330 with DMA 4101/4501/5001 .......................................................................... 25
8.1 Software Operation ....................................................................................................................... 25
8.2 Activating / Deactivating Xsample 330 .......................................................................................... 25
8.3 Automatic Drying ........................................................................................................................... 25
8.4 Cleaning ........................................................................................................................................ 25

E67IB001EN-I 3
 Contents

9 Measurement Settings with Xsample 330 and DMA 4101/4501/5001 ............................................. 26

9.1 Filling Programs ............................................................................................................................ 26
9.2 Cleaning Programs ....................................................................................................................... 26
9.2.1 Drain ..................................................................................................................................... 26
9.2.2 Clean ..................................................................................................................................... 27
9.2.3 Dry ........................................................................................................................................ 27
10 Performing a Measurement with Xsample 330 and DMA 4101/4501/5001 .................................. 28
10.1 Starting a Measurement .............................................................................................................. 28
11 Utilities of Xsample 330 with DMA 4101/4501/5001 ........................................................................ 29
11.1 Initialize ....................................................................................................................................... 29
12 Upkeep and Cleaning ........................................................................................................................ 29
12.1 Daily Maintenance ...................................................................................................................... 29
12.2 Weekly Maintenance ................................................................................................................... 29
12.3 Yearly Maintenance .................................................................................................................... 29
12.4 Wetted Parts ............................................................................................................................... 29
12.5 Storing and Transporting the Device .......................................................................................... 29
12.6 Packing the Device for Returns .................................................................................................. 29
13 Maintenance and Repair ................................................................................................................... 30
13.1 Maintenance Performed by an Authorized Anton Paar Service Engineer .................................. 30
13.2 Repair Performed by an Authorized Anton Paar Representative ............................................... 30
Appendix A: Technical Data .................................................................................................................. 31
Appendix B: Wetted Parts ..................................................................................................................... 32
Appendix C: Correcting Filling Problems ............................................................................................ 33
C.1: Checking the Hose Connections and Adapter Connections ....................................................... 33
C.2: Checking the Filling Process ....................................................................................................... 33
C.3: Correcting Problems with the Peristaltic Pump ........................................................................... 33
Appendix D: Cleaning Recommendations ........................................................................................... 34
Appendix E: Errors and Correction of Errors ...................................................................................... 36
Appendix F: Software Versions ............................................................................................................ 37
F.1: Xsample 330 with M Series Instruments ..................................................................................... 37
F.2: Xsample 330 with DMA 4101/4501/5001 .................................................................................... 37
Appendix G: Menu Tree ......................................................................................................................... 37
Appendix H: EU Declaration of Conformity ......................................................................................... 38

4 E67IB001EN-I
 1 Safety Instructions

Download Anton Paar documents for free from the Anton Paar website: http://www.anton-paar.com

1 Safety Instructions
• Read this document before using the device. • Use only accessories, consumables or spare
• Follow all hints and instructions in this document parts supplied or approved by Anton Paar
to ensure the correct use and safe functioning of GmbH.
the device. • Ensure that all operators have been trained
• The documentation is a part of the product. beforehand to use the device safely and
Keep it for the complete working life of the correctly.
product and make it easily accessible for all • Ensure that the device is sufficiently supervised
persons involved with the product. If you during operation. Especially when using erosive
receive any additions to or revisions of the or corrosive substances, The device must not
documentation from Anton Paar, these must be be operated unsupervised.
treated as part of the documentation. • Never use the device outside the specified
ambient conditions and specifications.
1.1 Liability • In case of damage or malfunction, do not
continue operating the device. Do not operate
• This document does not claim to address all the device under conditions which could result
safety issues associated with the use of the in damage to goods or injuries or loss of life.
device and samples. It is your responsibility to • In the case of liquids leaking from the
establish health and safety practices and to measuring system, make provisions to prevent
determine the applicability of regulatory contamination of the surroundings with harmful
limitations. or flammable substances or the generation of
• Anton Paar GmbH only warrants the proper an explosive atmosphere, e.g.:
functioning of the device if no modifications are - Provide sufficient ventilation of the setup
made to mechanics, electronics, module location.
firmware or instrument software. - Place the measuring system in an adequate
• Use the device only for the purpose described in fume cupboard.
the document. Anton Paar GmbH is not liable - Place the measuring system on a drip plate
for damages caused by incorrect use of the with adequate drainage.
device. • Place the waste container below the level of
Xsample 330.
• Protect the waste container against tipping.
1.2 Installation and Use
• Do not disconnect the waste container during
operation of the measuring system.
• Check the filling level of the waste container
CAUTION periodically, and empty the waste container
early enough.
Danger of hand injuries
• Do not touch the device during operation.
Parts of broken glass (petri dishes) could cause
hand injuries. Be careful when you unpack the
device.

• The installation procedure shall be carried out

only by authorized persons who are familiar
with the installation instructions.

E67IB001EN-I 5
1 Safety Instructions

Operation in areas with risk of explosion Precautions for flammable samples and
• The device is not explosion-proof and therefore
cleaning agents
must not be operated in areas with risk of • Keep potential sources of ignition, like sparks or
explosion. open flames, at a safe distance from the
device.
Operation with explosive samples • You must place the device and all samples in a
suitable, closed and ventilated fume hood (with
• The device must not be used for the
monitoring) with shutdown of the measuring
measurement of carbon disulfide (samples of
system when the minimum flow rate is below
explosion group IIC).
the minimum LEL limit (lower explosion limit).

General precautions The fume cupboard must be approved for

flammable vapors.
• Observe and adhere to your national safety • Store only the minimum required amount of
regulations regarding the handling of all sample, cleaning agents, and other flammable
substances associated with your materials near the device.
measurements (e.g. use safety goggles,
gloves, respiratory protection, etc.). • Do not spill sample/cleaning agents or leave
their containers uncovered. Immediately
• Before a measurement check the wetted parts remove spilled sample/cleaning agents.
of the device for chemical resistance to the
samples and cleaning agents used. • Ensure that the setup location is sufficiently
ventilated. The environment of the device must
• Take care that the liquids (samples and be kept free of flammable gases and vapors.
cleaning agents) or gases that you use are
chemically compatible when they come into • Provide fire-extinguishing equipment.
contact with each other. They must not react • For the measurement of flammable samples,
exothermally or produce harmful substances. use only a waste container with enough volume
• Before you start a measurement or cleaning for the sample and solvent. However, make
procedure, take care that the hoses are sure the volume of the waste container does
properly connected and that the connections not exceed 5 L.
without screws are secured by hose clamps to • We recommend using a metal waste container
prevent the hoses from slipping off. that is grounded (connected to earth), e.g. the
• Check the tightness of the hose connections. optional safety waste container by Anton Paar.

• Take measures that spilled liquids cannot get • Fill only up to 900 mL solvent into the rinsing
into plug connections or venting slots of bottle to prevent solvent escaping in the
electrical appliances. unlikely event of a malfunction.

• Connect the measuring system to the AC • Use only samples and solvents with an flash
power supply via a safety switch located at a point over 185 °C (365 °F).
safe distance from the instruments. In an
emergency, turn off the power using this switch
instead of the power switch on the instruments.
1.3 Disposal
• Ensure that the measuring system is properly • Concerning the disposal of the device, observe
grounded (Xsample and master instrument). the legal requirements in your country.
• Only use such quantities of your substances for
your measurements as are required to obtain
proper results. Do not use the substances in a
quantity exceeding this amount.

6 E67IB001EN-I
 2 Xsample 330 – An Overview

1.4 Conventions for Safety Messages

The following conventions for safety messages are
used in this document: NOTICE
Description of risk
Notice indicates a situation which, if not avoided,
could result in damage to property.
DANGER
Description of risk
Danger indicates a hazardous situation which, if Wear safety goggles
not avoided, will result in death or serious injury. Wear safety goggles when handling
the device.

Wear protective gloves

WARNING Wear protective gloves when handling
the device.
Description of risk
Warning indicates a hazardous situation which, if
not avoided, could result in death or serious Use protective clothing
injury. Use protective clothing when handling
the device.

CAUTION
Description of risk
Caution indicates a hazardous situation which, if
not avoided, could result in minor or moderate
injury.

2 Xsample 330 – An Overview

Xsample 330 is an optional sample filling unit for • Xsample 330 can be used with the
Anton Paar measuring instruments. Xsample 330 is following M series instruments:
installed easily by Plug and Play. The sample is - DMA 4100 M
filled out of a sample vial into the measuring cell of - DMA 4500 M
the measuring instrument. - DMA 5000 M
Xsample 330 has an integrated peristaltic pump for - DSA 5000 M
single determination of samples with a viscosity up - Lovis M/ME
to 3,000 mPa·s. The sample changer is resistant • and:
against aggressive mediums.
- DMA 4101
Xsample 330 features sample recovery as well as - DMA 4501
cleaning and drying after measurement. - DMA 5001

E67IB001EN-I 7
2 Xsample 330 – An Overview

2.1 View of Xsample 330

7 4

6
Fig. 1: Front view of Xsample 330

1 Pump lever
2 Openings for the pump hose
3 "AIR" connector (max. 2 bar/29 psi)
4 "Cell" connector
5 "Rinse 1" and "Rinse 2" connectors
6 "Ambient" connector
7 Liquid sensor

Type plate
(P/N = mat. no.)

Connector

Fig. 2: Rear view of the device

Fig. 3: View of the underside of the device

8 E67IB001EN-I
 3 Checking the Supplied Parts

3 Checking the Supplied Parts

Xsample 330 has been tested and packed carefully 2. To check the delivery for completeness,
before shipment. However, damage may occur compare the supplied parts to those listed in
during transportation. table 1 and table 2.
1. Keep the packaging material (box, foam pieces, 3. If a part is missing, contact your local
transport protection) for possible returns or for Anton Paar representative.
questions from the transportation or the 4. If a part is damaged, contact the transportation
insurance company. company and your local Anton Paar represen-
tative.

Table 1: Supplied parts

Qty. Article description Mat. no.

1 Xsample 330 184372

1 Instruction manual and safety information 189703

2 Bottle for rinsing liquid 21312

E67IB001EN-I 9
3 Checking the Supplied Parts

Table 2: Accessories Xsample 330

Qty. Article description Mat. no.

1 Accessories Xsample 330 containing: 189904

2 Injection adapter UNF 1/4" black 159025

2 UNF-hose fixation DMA M/DSA M/SDA M 236464

1 Adapter UNF/hose (female/male) 26739

2 Tefzel Adapter UNF/hose (male/male) 234347

0.5 m Hose 3.2x6.4 Norprene Chemical 93980

2 Hose 750x3x2 PTFE 1x1/4"-28 UNF 110156

labeled with "Rinse"

1 Hose 190x3x2 PTFE "A" 78453

1 Hose 710x3x2 PTFE 2x1/4"-28 UNF 224314

with attached protective cap

1 Hose 163x3x2 PTFE 2x1/4"-28 UNF 175202

(rolled-up)

1 Cable clip self-adhesive L20B15H4 gray 62072

1 Check valve with 3x5 silicone hose and hose clamp 166080

10 E67IB001EN-I
 3 Checking the Supplied Parts

Table 2: Accessories Xsample 330

Qty. Article description Mat. no.

2 Inlet filter for solvent 20 µm 88159

2 Ferrule with screw joint 21826

2 Hose clamp Dmin 5.8 Dmax 6.5 21531

2 Clamping screw I-Torx M4x25 -

1 Angular screwdriver Torx T20 15462

2 Serrated washer -

1 Petri dish 15x80 mm glass 224349

E67IB001EN-I 11
4 Installing the Device

4 Installing the Device

4.1 Installation Requirements For details about updating the master
instrument’s software, contact your Anton Paar
representative.
NOTICE 3. Switch off the master instrument.
• Place the measuring system only on an
entirely flat surface.
• Do not place the measuring system near a 4.4 Mounting Xsample 330
heater, near an air conditioner or a ventilator,
or in direct sunlight.
Strictly observe the safety instructions in NOTICE
section 1. Switch off the master instrument before you
connect or disconnect the device.

4.2 Installation
WARNING
Before you can use Xsample 330 and the
corresponding master instrument as a measuring Liquids leaking from the device because of
system, you have to carry out the following tasks: improper installation may cause injuries and
risk of fire.
1. Check the master instrument’s software, see
Xsample 330 may only be connected by
section 4.3.
authorized personnel who are fully trained to use
2. Mount Xsample 330 into the master instrument, Xsample 330 correctly and safely.
see section 4.4.
3. Mount the adapters of the master instrument, TIP: Keep the packaging material, the cover of the
see section 4.5. slot and the bottom plate for possible returns or in
case you have to remove Xsample 330 again.
4. Check the adapter connection for leak
tightness, see section 4.6. 1. Place the master instrument on a flat surface.

5. Connect the hoses and the waste container, 2. Remove the cover of the slot for Xsample by
see section 4.7. unscrewing the two Allen screws.

4.3 Checking the Software Version of Slot cover

the Master Instrument Allen screws

Before mounting an Xsample module, ensure that

the latest software version is installed on the master
instrument (e.g. DMA M). For details about the Fig. 4: Removing the cover of the slot
required software version, see appendix F.
3. To remove the bottom plate, carefully pull it out.
1. Switch on the master instrument with the power
switch on its rear, see section 5.1.
2. With M series instruments:
Slot for Xsample
- Tap <Menu> and select Service > System
Information.
With DMA 4101/4501/5001:
- Tap Menu > System information
Bottom plate
In the line "Version" the currently installed
software version is displayed. Fig. 5: Removing the bottom plate

12 E67IB001EN-I
 4 Installing the Device

4. Insert Xsample 330 into the slot of the master 4.5 Mounting the Adapters of the
instrument, see fig. 6.
5. Make sure that the connector on the rear of
Master Instrument
Xsample 330 completely engages in the
corresponding connector in the slot of the 1. Take the two injection adapters UNF 1/4" from
master instrument. the Xsample 330 accessory box.
2. Pull out the plastic transport plugs from the tips
of the injection adapters.
WARNING TIP: Keep the plastic transport plugs for later use.
They can be used as an injection adapter tool to
Electrostatic charging of the device may widen the tips of the adapters in case of leaks.
cause sparking and fire.
To ensure proper grounding, fasten
Xsample 330 to the master instrument only by
the Torx screws M4x25 supplied with Xsample.
Do not use the two Allen screws holding the slot
cover of the master instrument for this purpose!

Adapters

Fig. 8: Mounting the adapters of the master instrument

3. Carefully insert the injection adapters into the

openings of the adapter holding plate on the
right side of the master instrument, see fig. 8.
4. Push both adapters towards the holding plate
Fig. 6: Inserting Xsample 330 into the slot of the master with moderate force.
instrument
5. Insert the screws through the bore holes of the
6. Put the serrated washer directly on the Torx adapters and screw them cautiously into the
screws M4x25 and insert them in the holes of adapter holding plate until some resistance
Xsample 330. against further turning can be felt and then stop
tightening the screw. The gap left between the
holding plate and the adapter, where the thread
Serrated of the screw can be seen, is approx. 3–8 mm
washers (approx. 0.12 - 0.31 in). If the screw for
fastening the adapter is over-tightened, the
density measuring cell may be damaged.

CAUTION
Torx screws
M4x25 Harmful liquids leaking from the instrument
Fig. 7: Fixing the screws supplied with Xsample 330 may cause injuries.
Do not over-tighten the screw, the density
7. Fix the screws hand-tight (160 cNm), see fig. 7.
measuring cell may be damaged.

E67IB001EN-I 13
4 Installing the Device

4.6 Checking for Leak Tightness 4.7.1 Connecting the Rinsing Hoses
"Rinse"
1. Insert the adapters Luer 1/4" UNF from the
accessory kit of the master instrument into the
openings of the injection adapters.
2. Close one adapter tightly with a male Luer plug. WARNING
3. Use a plastic syringe from the accessory kit of Danger of injuries and fire
the master instrument to inject, with moderate Leaked or spilled liquids may cause injuries and
pressure, air through the other adapter. fire.
4. Wait a few seconds. • Use only the rinsing bottles supplied with
5. Release the plunger of the syringe. Xsample 330.
• Do not overfill the rinsing bottles (over 900 mL).
- If the connections are tight, the plunger of • Secure the rinsing bottles against tipping.
the syringe will be slowly pushed back by the
pressure in the measuring cell.
- If the connections are leaky, the plunger of NOTICE
the syringe will not move. • Ensure that the system does not run out of
In this case, repeat the mounting of the rinsing liquid during operation.
adapters. • Ensure that the rinsing hoses (solvent filters)
always lead to the bottom of the rinsing bottles.
TIP: Keep the plastic transport plugs for later use.
They can be used as an injection adapter tool to
1. Open the screw caps of the supplied rinsing
widen the tips of the adapters in case of leaks.
bottles.
2. Take one hose labeled "Rinse" and lead the
4.7 Hose Connections end without connector through the hole of the
screw cap and liner.
To ensure correct functioning of Xsample 330, use 3. Attach a screw joint and ferrule onto the hose
only the supplied hoses as described in this manual end, see fig. 9.
and/or the respective section in the supplied system
manual. Depending on your measuring system Solvent inlet filter Liner (Teflon side) Hose "Rinse"
setup (e.g. different master instruments and
connected modules), hose lengths may differ.

Screw joint and ferrule Screw cap

WARNING (rinsing bottle)

Liquids leaking from the device or waste

Screw joint
vessel may cause injuries and risk of fire.
Switch off the master instrument before you Ferrule
connect or disconnect hoses.

Hose "Rinse"
CAUTION Fig. 9: Connecting a hose "Rinse"
Danger of hand injuries
4. Screw the hose end into the solvent inlet filter
Moving parts of the pump may squeeze your
(from the accessory box).
fingers and cause hand injuries.
Ensure that Xsample 330 is in idle mode before
you mount the hoses.
NOTICE
The solvent inlet filters must always be used to
prevent possible impurities from getting into the
valves. Impurities can cause residues in the
valve unit which may lead to malfunction.

14 E67IB001EN-I
 4 Installing the Device

5. Repeat the procedure with the second "Rinse" 2. Secure the hose ends by the supplied hose
hose and rinsing bottle. clamps, see fig. 10 B.
6. Screw the open ends of the "Rinse" hoses into 3. Cut the silicone hose to the required length, see
the "Rinse 1" and "Rinse 2" connectors on fig. 10 C.
Xsample 330. 4. With the open hose ends, connect the check
7. After you have filled in solvent, screw the screw valve in the correct flow direction to the "AIR"
caps onto the rinsing bottles. nozzle of the master instrument and the "AIR"
connector on Xsample 330.
4.7.2 Connecting the Check Valve
4.7.3 Automatic Drying
NOTICE Xsample 330 can be used with an automatic drying
To avoid malfunction, take care that function. This ensures operation with the instrument
• the check valve is mounted in the correct flow without any manual interaction if required. Filling -
direction: from the "AIR" nozzle on the master measuring - cleaning are performed in one flow. If
instrument to the air nozzle on the Xsample sample recovery is needed, a popup will inform the
(see the arrow on the check valve for the flow user to replace the sample vial by a waste vessel
direction); after the sample recovery. This type of application is
• the silicone hose is not buckled (otherwise the suitable for samples up to 500 mPa·s and not
air flow cannot reach the measuring system). higher.
1. Slip the ends of the supplied silicone hose onto Alternatively the Xsample 330 can be used to fill
the barbed check valve connectors up to at samples with a viscosity up to 3,000 mPa·s.
least the second ridge, see fig. 10 A. Therefore it is required to apply the alternative hose
connections for the system. A manual interaction of
the user is mandatory for this type of application.

A
hose clamps

cut as required

hose

check valve C

Fig. 10: A: Connecting the hose ends to the check valve

B: Securing the hose ends by hose clamps
C: Cutting the silicone hose

E67IB001EN-I 15
4 Installing the Device

4.7.4 Xsample 330

4.7.4.1 Hose connections for Xsample 330 (automatic drying)

4
1 5

7 6

Fig. 11: Hose connections for Xsample 330

1 Hose "A" 5 Hose clamp

2 UNF hose fixation DMA M/DSA M/SDA M 6 Hoses "Rinse"
3 PTFE hose 710 mm with protective cap 7 Check valve with silicone hose
4 Norprene chemical hose 8 Petri dish

1. Screw the connector of hose "A" into the inlet 7. Cut a piece of approx. 320 mm length from the
adapter of the master instrument. Norprene chemical hose supplied with
2. The PTFE hose 710 mm has two connectors. A Xsample 330.
light brown end made of Peek and a white end 8. Open the pump lever.
made of Tefzel. Screw the Tefzel end into the 9. Guide the Norprene chemical hose through the
outlet adapter of the master instrument. pump and close the pump lever.
TIP: To avoid that the connectors of the hoses 10. Screw two Tefzel adapters (male/male) into the
become loose in the inlet and outlet adapter of the valve block connectors “Pump A ” and
master instrument, mount the UNF-hose fixation “Pump B”. Cross the Norprene chemical hose
DMA M/DSA M/SDA M. This prevents leakage of and slip both ends over these adapters.
the system. Fix the hose with hose clamps.
3. Guide the PTFE hose 710 mm through the 11. Connect the hoses “Rinse” to the valve block
cable clip (attached previously). and place a petri dish beneath the valve block.
4. Lead the PTFE hose 710 mm through the liquid 12. Connect the check valve in the correct flow
sensor. Press the hose carefully into the guide direction to the "AIR" nozzle of the master
of the liquid sensor. To do this, press cautiously instrument and the "AIR" connector on
on the protective cap. Xsample 330.
5. Ensure that the hose engages completely in the
guide of the liquid sensor.
6. Screw the PEEK end of this PTFE hose into the
connection “Cell” of the valve block.

16 E67IB001EN-I
 4 Installing the Device

4.7.4.2 Alternative hose connections for Xsample 330

5
3
1 10 6

4 10

Fig. 12: Alternative hose connections for Xsample 330

1 Hose "A" 6 PTFE hose 163 mm

2 UNF hose fixation DMA M/DSA M/SDA M 7 Hoses "Rinse"
3 PTFE hose 710 mm with protective cap 8 Self adhesive cable clip
4 Adapter UNF/hose 9 Check valve with silicone hose
5 Norprene chemical hose 10 Hose clamp

When using alternative hose connections 5. Roll up the PTFE hose, fix it with the cable clip
deactivate the checkbox “Automatic drying”. Tap and screw the other end of this PTFE hose into
<Menu> and select Setup > Measuring System an adapter UNF/hose.
Settings > Xsample 330 Module > Settings. 6. Cut a piece of approx. 320 mm length from the
1. Screw the connector of hose "A" into the inlet Norprene chemical hose supplied with
adapter of the master instrument. Xsample 330. Put an UNF/hose adapter on the
left end of this hose and fix it with a hose clamp.
2. The PTFE hose 710 mm has two connectors. A
light brown end made of Peek and a white end 7. Open the pump lever.
made of Tefzel. Screw the Tefzel end into the 8. Guide the Norprene chemical hose through the
outlet adapter of the master instrument. pump and close the pump lever.
TIP: To avoid that the connectors of the hoses 9. Connect the left adapter of the Norprene
become loose in the inlet and outlet adapter of the chemical hose to the PTFE hose 710 mm.
master instrument, mount the UNF-hose fixation Screw an UNF adapter male/male into the
DMA M/DSA M/SDA M. This prevents leakage of connector “Cell” on the valve block and slip the
the system. right end of the Norprene chemical hose over it.
Fix the hose with a hose clamp.
3. Lead the PTFE hose 710 mm through the liquid
sensor. Press the hose carefully into the guide 10. Mount the rolled-up PTFE hose 163 mm on the
of the liquid sensor. To do this, press cautiously valve block. Use the connections “A” and “B”.
on the protective cap. 11. Connect the hoses “Rinse” to the valve block
4. Ensure that the hose engages completely in the and place a petri dish beneath the valve block.
guide of the liquid sensor. 12. Connect the check valve in the correct flow
direction to the "AIR" connectors.

E67IB001EN-I 17
5 Operating Xsample 330 with M Series Instruments

5 Operating Xsample 330 with M Series Instruments

Only with DSA 5000 M, Lovis M/ME and
DMA 4100/4500/5000
5.2 Activating/Deactivating
Xsample 330
5.1 Switching the Measuring System In case you want to fill sample manually, you can
deactivate Xsample 330 without having to dismount
On/Off it:
After you have completed the installation of 1. Tap <Menu> and select Setup > Measuring
Xsample 330 and your other hardware components, System Settings > Xsample 330 Module.
switch on the measuring system. The master 2. Deactivate the check box "Sampling Unit is
instrument detects Xsample 330 automatically active".
during the startup.
To reactivate Xsample 330 after you are finished
• Connect the power inlet of the master with manual filling, activate the check box again.
instrument to the AC power supply using the
supplied power cord. TIP: After activating or deactivating Xsample 330,
an existing sample list will be reset.
• To switch on/off the measuring system, press
the power switch on the back of the master
instrument.

WARNING
High voltage at parts of the measuring
system can cause serious injuries or death.
• Connect the instruments to the mains supply
only with protective earthing.
• Never connect the instruments to the mains
supply with protective separation or protective
insulation.
• Make sure that the non-fused earth conductor
of the power cord is connected to earth.

NOTICE
Before switching the master instrument and
Xsample 330 on, make sure that the correct line
voltage is available (AC 100–240 V, 50/60 Hz). If
large voltage fluctuations are to be expected, we
recommend using a constant voltage source
(UPS).

18 E67IB001EN-I
 6 Performing a Measurement with Xsample 330 and M Series Instruments

6 Performing a Measurement with Xsample 330 and

M Series Instruments
Only with DSA 5000 M, Lovis M/ME and Available filling modes
DMA 4100/4500/5000
You can use the peristaltic pump of Xsample 330
Before you start measurements with Xsample 330, with one of the following filling modes:
define the filling parameters according to your
requirements. Then fill the sample into a vial, place - Forward Only
the free end of hose "A" in the vial, and start the Continuously fills for the set filling time. Use
measurement. this mode if you do not expect the incidence
of any bubbles in your samples.
- Forward/Back
6.1 Editing the Sample List The sample is filled and moved forward and
backward in the measuring system to
1. Tap <Sample List>. remove air bubbles which cling to the wall of
The sample list opens. the measuring cell.

TIP: To get the <Sample List> function key instead

of the <Quick Settings> function key in the main 6.2.2 Filling Time
screen, change to the menu Setup > Measuring
System Settings > Sample List > Sample According to your application, choose the filling
List/Sample Settings and select "Sample List" in the time:
drop-down box. 1. Tap <Menu> and select Methods > Method
2. For each sample, enter the corresponding Settings > method name > Xsample 330
sample name. Module > Filling.
3. For each sample, select the method of your 2. Enter the filling time (1–999 s).
choice (see the reference guide of the master
TIP: Samples with higher viscosities require longer
instrument for details on measuring methods).
filling times.
TIP: As long as a sample list is processed, you can
Table 3: Recommended filling time for aqueous liquids
add further samples to it.
TIP: In the "Quick Settings" column, you can assign Sample vial Filling time Pump speed
certain parameters (e.g. a measuring mode) to a
50 mL 10 s 20 %
measurement.

6.2.3 Filling Time - Repeated Mode

6.2 Xsample 330 Method Settings
If you use the measurement mode "RM (Repeated
The filling parameters (filling mode, filling time, filling Mode)", see section 6.3.1, define an appropriate
time – repeated mode, pump speed) can be defined filling time.
separately for each method of the master
1. Tap <Menu> and select Methods > Method
instrument.
Settings > method name > Xsample 330
Module > Filling.
6.2.1 Filling Mode 2. Enter the filling time for the repeated mode (1–
999 s).
According to your application, choose how
Xsample 330 shall fill the sample:
1. Tap <Menu> and select Methods > Method
6.2.4 Pump Speed
Settings > method name > Xsample 330
The sample should not be sucked into the
Module > Filling.
measuring cell of the master instrument too fast,
2. Select one of the filling modes in the drop-down because air bubbles may form and lead to
box "Filling mode". erroneous measurements.

E67IB001EN-I 19
6 Performing a Measurement with Xsample 330 and M Series Instruments

TIP: You can also start an automatic cleaning

NOTICE without sample recovery. Then the sample is
• Fill enough sample to ensure that the previous automatically drained and the cleaning procedure is
sample is well replaced by the next sample. started immediately.
• Avoid bubbles in the measuring cell during
filling.
• Do not empty the sample vial completely. 6.2.6 Cleaning
1. Tap <Menu> and select Methods > Method Xsample 330 supports individual cleaning programs
Settings > method name > Xsample 330 for each method.
Module > Filling.
You can define different cleaning steps for each
2. Select a pump speed (from 1 % to 100 %). connected rinsing liquid.
• Rinsing liquid 1 should dissolve sample
NOTICE
residues in the measuring system.
After changing the pump speed, also adapt the
filling time, see section 6.2.2. • Rinsing liquid 2 should be highly volatile and
soluble in rinsing liquid 1.
Especially for high viscosity samples, you have to
You can specify different settings.
verify the optimal filling that does not cause air
bubbles during filling. "Expert Settings" allow you to specifically adapt the
cleaning, and drying procedures to your application.
TIP: In most cases a pump speed of approx. 30 %
is sufficient for high viscosity samples. 1. Tap <Menu> and select Methods > Method
Settings > method name > Xsample 330
Module > Cleaning.
6.2.5 Draining Mode
2. Activate/deactivate the check box "Automatic
According to your application, choose how Start of Cleaning".
Xsample 330 shall drain the sample: 3. Tap <Next>.
1. Tap <Menu> and select Methods > Method - Each row defines the parameters for a step
Settings > method name > Xsample 330 in the cleaning program.
Module > Cleaning. - Add rows by tapping the green "+" symbol.
2. Select one of the draining modes in the drop- - Delete rows by tapping "Delete Row".
down box "Draining mode". - Cleaning will proceed from top down.
4. Enter the cleaning parameters as required.
Available draining modes 5. Tap <Expert Settings> to specifically adapt
cleaning settings.
You can use the peristaltic pump of Xsample 330
with one of the following draining modes: TIP: To evaluate the cleaning settings, perform a
measurement and check the air density value
- No Drain afterwards (for a table with air density values, see
The filled sample will not be drained from the e.g. the DMA reference guide). If necessary,
measuring system before the cleaning increase the number of cycles and the drying time.
procedure starts. This is recommended for
samples which react with air and become NOTICE
solid. Use only with aqueous and low- If you activate “Automatic start of cleaning”
viscosity samples. please ensure, that you replace the sample vial
- Sample Recovery by a waste vessel after the filling process.
The internal air pump drains the sample out
of the system according to the set draining
time. Rinse
If you want to use Sample Recovery,
Enumerator for the rinsing liquid (1 or 2).
deactivate the option "Automatic Start of
Cleaning". A pop up message will ask you to
replace the sample vial by a waste vessel
after the draining procedure.

20 E67IB001EN-I
 6 Performing a Measurement with Xsample 330 and M Series Instruments

Rinse time Only when using alternative hose connections:

Do not forget to open the pump during the drying
To define for how long (in seconds) the connected procedure, as requested by the master instrument.
measuring system is rinsed with the corresponding Otherwise liquid may leak from the ambient or rinse
rinsing liquid. In case of bad cleaning performance, plug. The pump lever should be closed after the air
increase the rinse time with the appropriate rinsing pump stopped and the drying process is completed.
liquid.
TIP: To protect the pump hose, please leave the
pump lever open during longer pauses between
Pump speed (1–100 %) measurements. Please do not forget to close it
The pump speed or pump rate is given in percent before filling the subsequent measurement,
and determines how fast the liquid is rinsed through otherwise the sample cannot be filled.
the measuring system.
Recommended: 10–20 % Expert settings
For each rinsing liquid you can set the inject time
Soak time (0–999 s) and inject factor.

You can increase the cleaning efficiency for some

applications, especially with sticky samples, by
having Xsample 330 soak the measuring system
with rinsing liquid for a defined time before draining
it from the system.
Choose a rinsing liquid which dissolves the sample
sufficiently.
The efficiency of the soaking function depends on
diverse parameters:
- the number of cleaning cycles,
- whether the rinsing liquid is drained or not,
- the measuring system setup, With this settings you can create air gaps during the
- the viscosity of the rinsing liquid, rinsing process. The inject time is the filling time of
- the amount of sample residues after draining the rinsing liquid. The inject factor specifies the air
Set this parameter to "0" to deactivate the soaking gap in percent of the filling time of the rinsing liquid.
function. For example:
For a rinsing time of 120 s, an inject time of 10 s and
Dry time an inject factor of 10 %, the pump fills the measuring
system with rinsing liquid for 9 s and then 1 s (10 %
Adequate drying is essential for a good measuring
from 10 s) with air for the whole rinsing time of
performance as it prevents carry-over effects. "Dry
120 s.
Time" sets the time (in seconds) to dry the
measuring system after a cleaning step. TIP: If the Inject Factor is 100 %, the pump will fill
the measuring system just with air. 0 % Inject Factor
We recommend a minimum drying time of 2 minutes
means just rinsing the measuring system for the
after the last cleaning step (in the last row). Adapt
whole rinsing time.
the drying time to your rinsing liquid.
TIP: If you set the drying time too short, rinsing
liquid residues might trigger the liquid sensor when 6.2.7 Special Cleaning
the subsequent sample is filled. This may result in a
filling warning or bad filling behavior. Depending on the master instrument, Xsample 330
supports adjustments, special adjustments, and
TIP: Do not set the drying time too short. If the checks. The air density value of the measuring cell
measuring cell has not been dried completely, the is periodically checked by the master instrument. If
sample will be polluted by residues of the rinsing this value is outside of specification, Xsample 330
liquid leading to incorrect measurement results and will automatically perform a special cleaning of the
carry-over effects. measuring cell(s).

E67IB001EN-I 21
6 Performing a Measurement with Xsample 330 and M Series Instruments

The settings for special cleanings are separate from

Table 4: Examples for filling aqueous liquids with
the normal cleaning settings:
"Repeated Mode"
1. Tap <Menu> and select Setup > Measuring
System Settings > Xsample 330 Module > Max.
Filling
Special Cleaning Settings. Master Filling Pump no. of
time –
instr. time speed deter-
2. Enter the cleaning parameters as required. RM
min.
See table 6.2.6 for an explanation of the DMA M 9s 4s 10 % 5
parameters.
DSA M 19 s 9s 10 % 5
TIP: Do not set the special cleaning parameters too
40 s 15 s 10 % 5
low because insufficient special cleaning may result SDA M
in a bad adjustment or check. 20 s 10 s 20 % 5

6.3 Measurement Modes 6.3.2 MM (Multiple Measurement)

With "Multiple Measurement" mode, you can
These settings can be defined separately for each
perform up to 10 measurements of one filled
method of the master instrument.
sample. For details on multiple measurement, refer
TIP: The measurement mode can be set either to the reference guide of the master instrument.
generally for all samples measured with a particular
1. Tap <Menu> and select Methods > Method
method (menu Methods > Method Settings >
Settings > method name > Measurement
method name > Measurement Mode (X)) or for
Mode (X)
particular samples using the sample list (column
"Quick Settings"). 2. Highlight "MM (Multiple Measurement)", and
tap <Next>.
3. Use the "Multiple Measurement Cycles" drop-
6.3.1 RM (Repeated Mode) down box to select the number of
measurements.
With "Repeated" mode, you can refill a certain
amount of sample in relation to the set filling time. 4. Tap <OK>.
The repeated mode fills the sample out of the same 5. Tap <Home> to return to the main screen.
vial. For details about the repeated mode, see the
reference guide of the master instrument.
Depending on the number of modules in a 6.4 Starting a Measurement
measuring system, sample viscosity, and pump
speed, the parameter "Filling time – Repeated 1. Before starting a measurement, check whether:
mode", see section 6.2.3, has to be adapted and - the measuring system is clean and ready for
evaluated to avoid that the sample vial is emptied measurement,
completely. - all hoses are connected correctly, see
section 4.7
NOTICE - the hose connections are tight,
Use the repeated mode function only with a hose - the free end of hose "A" is immersed in the
extension for hose PTFE hose 710 mm and with sample vessel
vials that contain at least 50 mL sample. The - Xsample 330 is activated, see section 5.1
liquid sensor should not be reached. - the correct filling parameters are set, see
section 6.2
1. Tap <Menu> and select Methods > Method - the correct sample list mode is set,
Settings > method name > Measurement 2. Tap <Start> on the master instrument to start
Mode (X). the measurement.
2. Highlight "RM (Repeated Mode)". The sample is filled automatically into the
3. Tap <OK>. measuring cell and the measurement starts.
4. Tap <Home> to return to the main screen.

22 E67IB001EN-I
 6 Performing a Measurement with Xsample 330 and M Series Instruments

WARNING
Liquid leaking from the waste vessel may
lead to injuries and risk of fire.
Do not leave dangerous quantities of substances
in the waste vessel.

TIP: To abort the current measurement, tap <Stop>.

6.5 Rinsing Liquids

To ensure reliable measuring results, effective
cleaning of the measuring cell(s) after a
measurement cycle is essential.
•Rinsing liquid 1 should dissolve and remove
sample residues in the measuring system. It
needs to be a good solvent for all sample
components.
•Rinsing liquid 2 should remove rinsing liquid 1 and
be easily evaporated by a stream of dry air in
order to accelerate the drying procedure for the
measuring system. It needs to be highly volatile
and a good solvent for rinsing liquid 1.
For cleaning recommendations see appendix D.

WARNING
Rinsing liquids with low flash point
temperatures are a potential fire and
explosion hazard.
If you use such rinsing liquids, make sure to fulfill
the corresponding safety precautions, see
section 1.

E67IB001EN-I 23
7 Xsample 330 Utilities with M Series Instruments

7 Xsample 330 Utilities with M Series Instruments

7.1 Initialization
This utility initializes Xsample 330.
1. Tap <Menu> and select Xsample 330 Utilities >
Initialization.
Xsample 330 will be initialized.
2. Tap <OK> to return to the "Xsample 330
Utilities", tap <Redo> to repeat the initialization,
or tap <Home> to return to the main screen.

7.2 Customized Cleaning

This utility executes a rinsing and drying program of
the measuring cell similar to method-specific
cleaning (for routine operation) but with its own
settings independent of those of method-specific
cleaning or special cleaning.
1. Tap <Menu> and select Xsample 330 Utilities >
Customized Cleaning.
2. Define a cleaning program as described in
section 6.2.6.
3. Tap <Clean>.
Xsample 330 will be cleaned.
4. Tap <OK>.
5. Tap <Home> to return to the main screen.

7.3 Service Utilities

Utilities from this set perform service functions.

24 E67IB001EN-I
 8 Operating Xsample 330 with DMA 4101/4501/5001

8 Operating Xsample 330 with DMA 4101/4501/5001

8.1 Software Operation 8.4 Cleaning
See the Reference Guide Instrument Software for a 1. Tap Menu , then select Cleaning.
comprehensive description of the instrument soft- 2. Select one of the Cleaning programs from the
ware and instructions for its use. drop-down box. The device comes with one
TIP: The home button beside the display will always pre-defined program.
bring you back to the home screen, which is the See section 9.2 on how to define or edit cleaning
place where you basically start all operations. programs.
• Tap Menu to open the menu.
• Tap to access the dashboard.

8.2 Activating / Deactivating

Xsample 330
To fill samples manually, deactivate Xsample 330:
1. Tap Menu , then select System >
Settings > Xsample 330.
2. Under Settings deactivate Xsample 330.

To activate Xsample:
1. Tap Menu , then select System >
Settings > Module reactivation

8.3 Automatic Drying

You can activate/deactivate the automatic drying
function. When you use automatic drying see
section 4.7.4.1 for correct hose connections and
section 4.7.4.1 for further information.
1. Tap Menu , then select System >
Settings > Xsample 330.
2. Under Settings activate or deactivate
automatic drying.

E67IB001EN-I 25
9 Measurement Settings with Xsample 330 and DMA 4101/4501/5001

9 Measurement Settings with Xsample 330 and

DMA 4101/4501/5001
Before you start measurements with Xsample 330
and DMA 4101/4501/5001, define the filling,
9.2 Cleaning Programs
draining and cleaning parameters of your Xsample
1. To define cleaning programs tap Menu , then
according to your requirements.
select System > Settings > Xsample 330
> Cleaning Programs.
9.1 Filling Programs 2. Create a new cleaning program by tapping .
3. If you want to edit an existing one, tap on the
1. To define filling programs tap Menu , then according program .
select System > Settings > Xsample 330
TIP: The device comes with predefined settings,
> Filling programs.
which you can use as a template. Click and hold the
2. Create a new filling program by tapping . icon to copy and adapt the program to your
TIP: The device comes with several predefined requirements.
settings, which you can use as a template. Click and 4. Tap edit .
hold the icon to copy and adapt the program to your
requirements. 5. Enter a new name and a description of your
cleaning program in the tab General.
6. In the tab Cleaning steps you can define up to
30 steps. The whole cleaning procedure
consists of three parts:
- Draining
- Cleaning
- Drying

Fig. 13: Creating or editing a filling program

3. If you want to edit an existing one, tap on the

according program .
4. Enter a new name and a description of your
filling program. Select one of the predefined
filling modes from the drop down box.
- Forward only Fig. 14: Creating or editing a cleaning program
- Forward/Back
5. For further information see 7. Define the parameters for each single step. The
first step is always a draining step. You cannot
- section 6.2.1 (“Available filling modes”) for move or remove this step.
filling modes,
- section 6.2.2 and table 3 for filling time, For information about rinsing liquids and cleaning
- section 6.2.3 for filling time for repetition settings see section 6.2.6.
- section 6.2.4 for pump speed.
9.2.1 Drain
Select the Draining mode:
- No drain
- Sample recovery
Available draining modes are explained in
section 6.2.5.

26 E67IB001EN-I
 9 Measurement Settings with Xsample 330 and DMA 4101/4501/5001

9.2.2 Clean
For information about important requirements for
suitable rinsing liquids and the following cleaning
settings see section 6.2.6.
Define:
- Rinse with rinsing liquids
- Rinsing time
- Pump speed
- Soak time
- Inject time
- Inject factor

9.2.3 Dry
Define the Drying time, see section 6.2.6.
(“Dry time”)

E67IB001EN-I 27
10 Performing a Measurement with Xsample 330 and DMA 4101/4501/5001

10 Performing a Measurement with Xsample 330 and

DMA 4101/4501/5001
For a comprehensive description of the master To perform a measurement without
instruments measurement settings refer to the predefined product
manual of the master instrument.
1. Select Measurement in the menu.
Preparatory steps 1. Specify a sample name.

Before starting a measurement, check that: 2. Select a measurement mode from the drop
down box. See the manual of the master
- the measuring system is clean and ready for instrument for a detailed description of the
measurement, available measurement modes.
- all hoses are connected correctly, see
- Multiple filling
section 4.7
- Temperature scan
- the hose connections are tight,
- ASTM D4052
- the free end of hose "A" is immersed in the
- Repeated mode
sample vessel
- Multiple measurement
- the pump lever is closed,
- Standard
- Xsample 330 is activated, see section 8.2
- the correct filling parameters are set, see 3. Define the required Xsample settings.
section 9.1 a. Activate or deactivate Automatic start of
Then fill the sample into a vial, place the free end of cleaning.
hose "A" in the vial, and start the measurement. b. Select a filling and a cleaning program from
the drop down box according to your
requirements, see section 9.
10.1 Starting a Measurement 4. Tap MEASURE to start the measurement.

To start a product measurement

1. Select Products in the menu, the select the
specific product.
2. Tap edit
3. Define the required Xsample settings.
a. Activate or deactivate Automatic start of
cleaning.
b. Select a filling and a cleaning program from Fig. 16: Measurement without predefined product
the drop down box according to your
requirements, see section 9. NOTICE
4. Tap Create measurement . If you activate “Automatic start of cleaning”
5. Specify a sample name. please ensure, that you replace the sample vial
by a waste vessel after the filling process.
6. Tap MEASURE to start the measurement.

Fig. 15: Product measurement

28 E67IB001EN-I
 11 Utilities of Xsample 330 with DMA 4101/4501/5001

11 Utilities of Xsample 330 with DMA 4101/4501/5001

Tap Menu , then select System > Settings >
Xsample 330 > Tools & utilities

11.1 Initialize
This utility initializes Xsample 330.

12 Upkeep and Cleaning

Upkeep and cleaning procedures have to be 12.4 Wetted Parts
performed by the customer.
Materials, which are in contact with samples and the
cleaning liquids are listed in appendix B.
12.1 Daily Maintenance
Check the hoses and hose connections visually for 12.5 Storing and Transporting the
leak tightness and cleanliness during operation.
Make sure that the filling tube area of the device is
Device
periodically wiped.
Empty all hoses before you move or lift the device.
Carry the device in front of you and keep it close to
12.2 Weekly Maintenance your body.

Check for wear and tear of the pump hose and

change the pump hose if necessary. 12.6 Packing the Device for Returns
In case of sending back the device, please use the
12.3 Yearly Maintenance original packaging.

Replacement of all wetted hoses and solvent filters.

E67IB001EN-I 29
13 Maintenance and Repair

13 Maintenance and Repair

13.1 Maintenance Performed by an 13.2 Repair Performed by an Autho-
Authorized Anton Paar Service rized Anton Paar Representative
Engineer In case your instrument needs repair, contact your
local Anton Paar representative, who will take care
The Xsample 330 does not require a periodical
of the necessary steps. If your instrument needs to
maintenance which shall be performed by an autho-
be returned, request an RMA (Return Material
rized Anton Paar Service Engineer.
Authorization Number). It must not be sent without
the RMA and the filled “Safety Declaration for
Following parts are excluded from the Instrument Repairs”.
warranty (wear and tear parts) Please make sure it is cleaned before return. All
• hoses liquids must be drained from the device. The safety
waste container must be completely empty.
• filters
TIP: Find the contact data of your local Anton Paar
representative on the Anton Paar website
(http://www.anton-paar.com) under “Contact”.
IMPORTANT: You must not return instruments that
are contaminated by radioactive materials, infec-
tious agents or other harmful substances that cause
health hazards.

30 E67IB001EN-I
 Appendix A: Technical Data

Appendix A: Technical Data

Xsample 330

Viscosity range up to 3,000 mPa·s at ambient and measuring

temperaturea

Filling mode with peristaltic pump:

• Suction mode in one direction
• Suction mode with pumping back and forward

Typical time for filling and measuring cycle 2 to 5 minutes

Minimum sample volume approx. 10 mL to 20 mL

Quality of air necessary class 3 according to ISO 8573-1:

max. particle size: 5 μm
max. pressure dew point: –20 °C (–4 °F)
max. oil content: 1 mg/m3

Environmental conditions (EN 61010) indoor use only

Operating temperature +15 °C to +35 °C (+59 °F to +95 °F)

Pollution degree 2

Over voltage category II

Altitude max. 3,000 m (9,840 ft)

Power supply supplied by the master instrument

AC power supply voltage according to technical
data plate at the rear of the master instrument
(protective grounding required)

Dimensions excl. master instrument (L x W x H)

205 mm x 148 mm x 205 mm
Xsample 330 (8.1 in x 5.8 in x 8.1 in)

Weight incl. packaging, excl. master instrument

Xsample 330 approx. 3.8 kg (8.4 lbs)

Weight excl. master instrument

Xsample 330 approx. 1.9 kg (4.2 lbs)
a Recommended for samples with a viscosity up to 500 mPa·s at ambient and measuring temperature. For samples with a
viscosity higher than 500 mPa·s at ambient and measuring temperature, bubbles may occur during filling.
When using the automatic drying function only samples with 500 mPa·s viscosity are recommended. For higher viscosities
apply the alternative hose connections and deactivate the automatic drying function.

E67IB001EN-I 31
Appendix B: Wetted Parts

Appendix B: Wetted Parts

The following materials are in contact with the samples and the cleaning agents:

Xsample 330

Material Part

Norprene chemical pump Hose Norprene Chemical

chemical resistance according to manufacturer
(Norprene Chemical Tubing from Saint Gobain)

HDPE (High density polyethylene) waste vessel

PCTFE (Polychlorotrifluoroethylene) adapter UNF/hose female/male

PTFE (Polytetrafluoroethylene) hoses, Injection adapter UNF 1/4" black

FEP (Fluorethylenpropylen) hoses connecting pump hose and valve block

PEEK (Polyether ether ketone ) fluidblock distribution plate

Kalrez FFKM membranes of valves V1, V2 and V3 (inside the

fluidblock)

ETFE (Ethylen-Tetrafluorethylen) adapter UNF/hose male/male

For the wetted parts of the master instrument, see the manual of the master instrument.

32 E67IB001EN-I
 Appendix C: Correcting Filling Problems

Appendix C: Correcting Filling Problems

If the sample is not pumped properly and/or bubbles
occur in the hoses, the measuring cell is badly filled
C.3: Correcting Problems with the
and, consequently, the measuring results may show Peristaltic Pump
bad repeatability.
If the peristaltic pump does not work properly, check
To find the cause for the bad filling, check for leak
the following:
tightness and the proper functioning of the
peristaltic pump. 1. Open the pump lever and check whether the
hose is placed correctly in the pump, see
C.1: Checking the Hose Connections section 4.7.

and Adapter Connections 2. Check whether the hose has collapsed or is

sticking together. If yes, replace the hose with a
new one.
Make sure that all hoses and adapters are tightly
connected. 3. Close the pump lever.
4. Check the filling process again, see
C.2: Checking the Filling Process appendix C.2.

1. Place the free end of hose "A" into a sample

vessel filled with distilled water.
2. Tap <Start>.
3. Check the filling process carefully by U-View™.
4. While the peristaltic pump is in operation, check
the following:
• Do air bubbles occur? If yes, check
- the connection where the air bubbles
occurred for leak tightness.
- the pump Speed (possibly too high).
• Is water constantly dripping out of a
connection? If yes, check the connection where
the water dripped out for leak tightness.
• Is water pumped out of the sample vial and is
water constantly dripping out of the waste
hose? If not, check whether the peristaltic pump
is functioning properly, see appendix C.3.
5. Tap <Stop> on the master instrument.

E67IB001EN-I 33
Appendix D: Cleaning Recommendations

Appendix D: Cleaning Recommendations

To ensure reliable measuring results, effective General recommendations
cleaning of the measuring cell(s) after measurement
is essential. These recommendations are a rough • Clean and dry the measuring cell at least once
guideline. Consider adapting them to the after each working day or work shift.
requirements of your application and configuration • Adapt the parameters "Rinsing mode" and
(e.g. the number of connected modules). "Pump Speed" to ensure that enough cleaning
• Cleaning liquid 1 should dissolve and remove liquid is pumped through the measuring
sample residues in the measuring system. It system, see section 6.5.
needs to be a good solvent for all sample • For rinsing the measuring system, use the
components. <Rinsing> function in the menu "Xsample 330
If you use water as cleaning liquid 1, we Utilities".
recommend using ultra-pure (bi-distilled or • When drying the measuring system, do not
deionized) water. forget to open the pump lever.
• Cleaning liquid 2 should remove cleaning • Use a drying cartridge to dry the measuring
liquid 1 and be easily evaporated by a stream cell(s) in case of high air humidity.
of dry air in order to accelerate drying • Check whether the cleaning and drying was
procedure for the measuring System. It needs successful by measuring the density of air.
to be highly volatile and a good solvent for Compare the determined density with the
cleaning liquid 1. reference value, see the air density table in the
DMA M reference guide:
NOTICE air = 0.001199 g/cm3 for T = 20 °C, p = 1013 mbar
Ensure that cleaning liquid 1 and cleaning
• Replace worn out hoses immediately,
liquid 2 do not react chemically with each other
especially those for the peristaltic pump.
or with the sample.

Recommendations for cleaning and drying

NOTICE Alcolyzer measuring systems
Before you fill any cleaning liquid into the
measuring system, make sure that all wetted • If a pH measuring module is installed,
parts are resistant to it, see appendix B. disconnect the pH measuring module before
starting a cleaning procedure.
TIP: To avoid carry-over effects and residues in the
• Drying is only necessary when the density
hoses, do not set the drying time after the last
meter of the Alcolyzer measuring system needs
cleaning liquid too short.
to be adjusted with air and water.
• Only use high-proof ethanol without denaturant
Finding suitable cleaning liquids
for drying.
Put a drop of sample onto a borosilicate plate and • Instead of drying, you can leave ultra-pure
dilute it with an appropriate solvent. If the applied water in the measuring system.
solvent is easily miscible with the sample, it qualifies
• In case of cleaning with laboratory cleaner,
as cleaning liquid 1 for the sample. If you intend to
rinse the system with approx. 200 mL of ultra-
use two cleaning liquids, do the same test with
pure water afterwards.
cleaning liquid 2.

34 E67IB001EN-I
 Appendix D: Cleaning Recommendations

Examples of cleaning liquids

Table 5: Suggested cleaning liquids and drying times

Suggested cleaning liquids Drying

and volumes time [s]

Product Internal
Sample Cleaning liquid 1 Cleaning liquid 2
group air pump

Alcoholic • alcopops ultra-pure waterb concentrated alcoholc 300

beveragese • beer 150 mL 50 mL
• cider
• gin
• sparkling winea
• spirits
• vodka
• wine

Wort warm water, approx. laboratory cleanerd -

60 °C 50 mL
200 mL

Nonalcoholic mineral watera concentrated alcohol - 240

beveragese 150 mL

syrup ultra-pure water concentrated alcohol 300

200 mL 50 mL

soft drinks ultra-pure water concentrated alcohol 240

150 mL 50 mL

Petroleum base oil BO1112 petroleum naphthaf Acetone 300

productse 40 mL 40 mL

engine oil LU1205 petroleum naphtha Acetone 300

50 mL 40 mL

jet fuel JF1107 petroleum naphtha Acetone 300

50 mL 40 mL
a degas before measurement
b bi-distilled or deionized water
c high-proof alcohol 96 %
d 1 % solution of the cleaner (e.g. Mucasol ®, Alconox®, Tergazyme®, Extran®, or RBS50®)
e clean hose "A" with a tissue before putting it into the next vial.
f PZN 7284259

E67IB001EN-I 35
Appendix E: Errors and Correction of Errors

Appendix E: Errors and Correction of Errors

Error Code Error message Cause Correction

-1701 Error (-1701) in Xsample 330. unexpected error contact your local Anton Paar
Module An unexpected error representative.
occurred. Please contact your
Anton Paar representative.

-1702 Error (-1702) in Xsample 330. unexpected error contact your local Anton Paar
Module An unexpected error representative.
occurred. Please contact your
Anton Paar representative.

-1703 Error (-1703) in Xsample 330. invalid configuration contact your local Anton Paar
Invalid configuration in representative.
EEPROM. Please contact your
Anton Paar representative.

-1704 Error (-1704) in Xsample 330. invalid configuration contact your local Anton Paar
Invalid configuration of pump representative.
type. Please contact your
Anton Paar representative.

-1705 Error (-1705) in Xsample 330. pump error contact your local Anton Paar
Pump error occurred. Please representative.
contact your Anton Paar
representative.

36 E67IB001EN-I
 Appendix F: Software Versions

Appendix F: Software Versions

F.1: Xsample 330 with M Series Instruments
Version of module
Release Document
firmware / master Comments
date number
instrument softwarea

First firmware version released for

1.000.013 / 2.93 24.11.2018 E67IB001EN-A
Xsample 330

1.007.021 / 2.95 12.06.2019 E67IB001EN-C Automatic drying

1.007.021 / 2.96 29.10.2019 E67IB001EN-D

E67IB001EN-E

1.007.021 / 2.97 24.07.2020

E67IB001EN-F
1.007.021 / 2.98 18.12.2020
a Required combinations

F.2: Xsample 330 with DMA 4101/4501/5001

Version of module
Date of Document
firmware / master Comments
release number
instrument software

1.007.021 / 2.0.0 31.03.2021 E67IB001EN-G First version released for Xsample 330

E67IB001EN-H

E67IB001EN-I

Appendix G: Menu Tree

The coloring of the menu tree indicates which parts Administrator
of the menu are accessible for users with
Administrator, Manager
administrator, manager, or operator rights:
Administrator, Manager, Operator

Xsample 330 Utilities Initialization

Customized Cleaning
Service Utitlities Valve Schematic
Methods > Method Settings > Measurement Mode (X) RM (Repeated Mode)
method name
Repeated Mode Settings
Xsample 330 Module Filling
Cleaning
Setup > Measuring System Settings Xsample 330 Module Settings
Special Cleaning

E67IB001EN-I 37
Appendix H: EU Declaration of Conformity

Appendix H: EU Declaration of Conformity

38 E67IB001EN-I