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(Basf) Irgacor® Npa

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Ciba Specialty Chemicals

Additives

Lubricant Additives

® ®
Ciba IRGACOR NPA Oil soluble corrosion inhibitor

Typical chemical and IRGACOR NPA, iso nonyl phenoxy acetic acid, is a corrosion inhibitor for lubricating oils,
physical properties greases and fuels

CH O CH COOH
9 19 2

Appearance Clear amber liquid


Viscosity at 40 °C 1750 mm2/s
Density at 20 °C 1.03 g/cm3
Flash point 130 °C , Pensky-Martens
Solubility
Water < 0.01%
Mineral oil > 5%

Applications and Industrial lubricants 0.05-0.1 %


typical treat levels Greases 1-2 %
recommended Metal protectants 1-2 %
Fuels 25-50 ppm

Benefits Effective at low concentrations


Active in lubricants containing molybdenum disulphide
High activity in both hydrotreated and solvent refined base stocks
Contains no diluents
Easy to handle liquid

Date first Edition: April, 1996 Product Name: IRGACOR NPA page 1 of 8
Printing Date: July, 1997
Additive volatility The volatility of additives can have a major impact on lubricant performance characteristics.

Thermogravimetric analysis (TGA) provides information about the volatility of an additive,


as well as its thermal and oxidative stability.

Test procedure Additive < 50 mg , is heated in a controlled atmosphere (air)


at a rate of 10 °C per minute from 25 °C up to as high as 400 C.
The weight loss (in %) of the sample as a function of
temperature is represented graphically.

Weight loss (% w/w)


0 | | | |

20

40
Irgacor NPA
60

80

100 | | | |
100 200 300 400
Temperature (deg C)

Date first Edition: April, 1996 Product Name: IRGACOR NPA page 2 of 8
Printing Date: July, 1997
Performance benefits: Metal surface protection

Rust prevention The corrosion inhibitor response in solvent neutral base stocks differs from that of
hydrotreated base stocks. IRGACOR NPA is highly effective in both types of base oil
and outperforms a commercially available corrosion inhibitor.

(ASTM D 665)
Procedure B: Synthetic sea water Average concentration for ASTM D 665 B pass (%)
60 °C, 24 hrs
0.05

0.04

0.03

0.02

0.01

0
Irgacor NPA CI B

Solvent neutral base stock


Hydrotreated base stock
Corrosion inhibitor (CI) B is an alkylated succinic acid half amide

Rust preventive fluids Lubricants containing IRGACOR NPA provide good corrosion control under humid
conditions.

Test fluids IRGACOR NPA (%) - - 2.0


Calcium petroleum sulphonate (%) - 2.0 -
Light spindle oil neat balance balance

Humidity cabinet test Time to onset of rusting (days) 1 4 8


Mild steel coated with a light spindle oil (4 or more rust spots)
is stored at 100 % relative humidity
Temperature cycles between 42 °C
and 48 °C every 75 minutes.

Date first Edition: April, 1996 Product Name: IRGACOR NPA page 3 of 8
Printing Date: July, 1997
Oxidation stability When using IRGACOR NPA in a formulated lubricant the oxidative stability of different types
of base stocks can be equally achieved.

Test fluids IRGACOR NPA (%) 0.05


Antioxidant blend (%) 0.20
Irgamet 39 (%) 0.05
Base stock balance

TOST life test (ASTM D 943) Time to TAN = 2.0 mg KOH/g (hrs)
6000

4000

2000

0
solvent neutral hydrotreated
base stock base stock

Greases Good ferrous metal protection of a lithium grease is achieved with IRGACOR NPA in
Corrosion inhibition combination with oleylamine

Test greases IRGACOR NPA (%) - 1.0


Irganox L 57 (%) - 0.5
Oleylamine (%) - 1.0
Li-OH-stearate grease (NLGI Grade 2) neat balance

Dynamic EMCOR test Deionised water: bearing (rating) 1 0 (pass)


(IP 220/DIN 51802) Salt water: bearing (rating) 5 0/1

Date first Edition: April, 1996 Product Name: IRGACOR NPA page 4 of 8
Printing Date: July, 1997
Greases IRGACOR NPA provides good ferrous metal protection of calcium, EP lithium and MoS2
Corrosion inhibition greases.

Test greases IRGACOR NPA (%) - 1.0 - 1.5 - 1.0


Ca soap grease neat balance - - - -
EP Li soap grease - - neat balance - -
MoS2 grease - - - - neat balance

Static rust test (ASTM D 1743) Bearing (rating) (1) 3 1 3 1 3 1


Roller bearings, prepacked with free of free of free of
grease ,stored at 100 % relative rust rust rust
humidity and 25 °C for 2 weeks

(1) Average of three results

IRGACOR NPA has little effect on the consistency, shear stability and water washout

Date first Edition: April, 1996 Product Name: IRGACOR NPA page 5 of 8
Printing Date: July, 1997
Engine oils A combination of IRGACOR NPA and Sarkosyl O improves corrosion control of first fill
Corrosion inhibition engine oils.

Test fluids IRGACOR NPA (%) - 0.3


Sarkosyl O (%) - 0.2
Engine oil (1) neat balance

Kesternich test (DIN 50 017) Rust rating (%) 5.0 0.5


KFW (2) 40 °C, 5 cycles (% rust covering panel surface)
1 cycle: 8 hrs 40 °C 80 % humidity
16 hrs cool to RT < 75 % humidity

(1) Engine oil API SF/CC SAE 15W/40, contains OCP non-dispersant VI improver
(2) KFW Alternation of climate (temperature) under conditions of water condensation
(Kondenswasser - Wechselklima)

Fuels In fuels metal protectants limit the formation of ions which catalyse oxidation processes
Corrosion inhibition leading to gum formation. IRGACOR NPA is highly effective at low concentrations.

Test fluids IRGACOR NPA (ppm) - 25 50


Gasoline neat balance balance

Static immersion test Sea water: panel appearance heavy rust trace rust no rust
Steel panels are partly immersed in a Gasoline: panel appearance heavy rust slight rust no rust
jar containing a mixture of synthetic Vapour: panel appearance heavy rust slight rust no rust
sea water and straight run gasoline
(1 : 7.5 ). The mixture is shaken
vigorously for one minute. The jar is
stored for 3 weeks at room temp.

Date first Edition: April, 1996 Product Name: IRGACOR NPA page 6 of 8
Printing Date: July, 1997
Fuels IRGACOR NPA is a highly effective corrosion inhibitor at low concentrations in fuels.
Corrosion inhibition

Test fluids IRGACOR NPA (ppm) - 25 50


Gasoline neat balance balance

Dynamic immersion test. Degree of rust on the spindle (rating) heavy rust trace rust no rust
(ASTM D 665 B test modified).
Steel spindles are completely
immersed for 3 hours at 26 °C in a
vigorously stirred mixture of straight
run gasoline (300ml) and synthetic
sea water (30 ml).

Date first Edition: April, 1996 Product Name: IRGACOR NPA page 7 of 8
Printing Date: July, 1997
Safety and Handling Please read Material Safety Data Sheet ( MSDS ) before handling.

Product Specification This information is available on request through our local representative.

Packaging This information is available on request through our local representative.

Quality Policy The objective of our quality policy is the continuous fulfilment of the internal and external
requirements agreed upon with our partners with regards to everybody’s performance.
As an integral part of the way we conduct our business, we want to focus all the activities of
Additives Division in the realm of Research, Development, Production, Marketing and
Administration on
- fulfilling continuously agreed upon requirements the first time around
- identifying and eliminating possible defects as early as possible
The Quality System of Additives Division is based on the principles of the
SN-ISO-Standard 9001 / EN 29001.
By means of training and information, all employees are to be familiarised with the divisional
quality principles and, consequently, to commit them to acting correspondingly in their area
of responsibility.

Important The following supercedes Buyer’s documents. SELLER MAKES NO REPRESENTATION


OR WARRANTY, EXPRESS OR IMPLIED, INCLUDING OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE. No statements herein are to be construed
as inducements to infringe any relevant patent. Under no circumstances shall Seller be
liable for incidental, consequential or indirect damages for alleged negligence, breach of
warranty, strict liability, tort or contract arising in connection with the product(s). Buyer’s
sole remedy and Seller’s sole liability for any claims shall be Buyer’s purchase price. Data
and results are based on controlled or lab work and must be confirmed by Buyer by testing
for its intended conditions of use. The product(s) has not been tested for, and is therefore
not recommended for, uses for which prolonged contact with mucous membranes,
abraded skin, or blood is intended; or for uses for which implantation within the human
body is intended.

Ciba Specialty Chemicals Inc. Business Unit Lubricant Additives


Additives Ciba Specialty Chemicals Inc., 1997
Reference AD7 Publ. No. 28993/96/e
CH-4002 Basle Edited in Switzerland

Date first Edition: April, 1996 Product Name: IRGACOR NPA page 8 of 8
Printing Date: July, 1997

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