JIYA Lal MITTAL DAV PUBLIC SCHOOL
PA1 EXAM
Class: 12th Subject: Chemistry
Time: 02 Hours M.M==50
General Instruction:
Note: All the questions are compulsory carrying 01 mark.
1.Increasing the temperature of an aqueous solution will cause
a) Decrease in Molality b) Decrease in Molarity
b) Decrease in Mole Fraction d) Decrease in % w/w
2.Thevan’t Hoff factor ‘i’ for a compound which undergoes dissociation in One solvent and association in
other solvent is respectively:
a) Greater than 1 and greater than One
b) Less than 1 and greater than 1
c) Less than 1 and less than 1
d) Greater than 1 and less than 1
3.At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is
a) Less than rate of crystallization
b) Greater than the rate of crystallization
c) Equal to the rate of crystallization
d) Zero
4.If two liquids A and B form minimum boiling azeotrope at some specific composition then
a) A-B interaction are stronger than those betwe3en A-A or B-B
b) VapourPressure of solution increases because more number of molecules of liquids A and B can escape
from the solution.
c) Vapour Pressure of the solution decreases because less no molecules of only one of the liquid escape
from the solution.
d) A-B interaction is weaker than those between A-A or B-B interactions.
5.Which of the following does not show positive deviation from Roult’s Law:
a) Benzene and Chloroform
b) Benzene and Acetone
c) Benzene and Ethanol
d) Benzene and Carbon tetra chloride
6.The solubility gas in liquid increases with
a) Increase in temperature
b) Reduction of gas pressure
c) Decrease in temperature
d) Amount of liquid taken
7.If 0.1M solution of glucose and 0.1M Urea are placed on two sides of semi permeable membrane to equal
height, then it will be correct to say that:
a)There will be no net movement across the membrane
b)Glucose will flow towards the Urea solution
c)Urea will flow towards the glucose solution
d)Water will flow from Urea solution towards glucose solution
8.For which of the following Van’t Hoff factor cannot be greater than Unity:
a) K4[Fe(CN)6] b) AlCl3
c) NH2CONH2 d) KNO3
9.Red Blood Cells placed in a solution having less t6han 0.9% NaCl will _________and may sometime
_________because NaCl solution will have _________ Osmotic Pressure than that of fluid inside Red Blood
Cells
a)Burst, Swell, Higher b) Swell, Burst, Higher
c)Burst, Swell, Lower d) Swell, Burst, Lower
10.Benzoic Acid dissolve in benzene shows
a)It’s normal molecular mass b) Double of it’s molecular mass
c)Half of its normal molecular mass d) Not definite.
11.The boiling point of solution of 0.11g of substance in 15g of ether was found to be 0.1°C higher than that
of pure ether. The molecular weight of substance will be (Kb= 2.16°C kg/mole)
a)148 b) 158
c) 168 d) 178
12. The solution of sucrose (molar mass= 342 g/mole) has been prepared by dissolving 68.5 g of sucrose in
1000 g of water. The freezing point of solution obtained will be (Kf for water = 1.86 K kg/mole)
a) -0.372°C b) -0.520°C c) + 0.372°C d) -0.570°C
13. 0.6g of solute is dissolved in 0.1L of a solvent which develop an osmotic pressure of 1.23 atm at 27°C.
The molecular mass of the substance is
a) 149.5 g/mole b) 120 g/mole c) 430 g/mole d) None of these
14. The unit of freezing point depression constant is
a) K/mole b) K/kg/mole c) K kg/mole d) K/kg
15. Which of the following will have the highest freezing point at 1 atm
a) 0.1 M NaCl solution b) 0.1 M Sugar solution
c) 0.1 M BaCl2 d) 0.1 M FeCl3 solution
16. A solution prepared by dissolving 15 g of Non volatile solute in 270 g of H2O gave relative lowering of
vapour pressure of 0.005, the molecular weight of the solute is
a) 324 b) 200 c) 225 d) 20
17. Pressure Cooker reduces cooking time because
a) The heat is more evenly distributed
b) The Higher pressure tenderizes the food
c) The boiling point of water inside is elevated
d) Large flame is used.
18. The osmotic pressure of a solution is given by the relation
a) π = RT/C b) π = CT/R c) ) π = RC/T d) ) π/C = RT
19. What would be the value of Van’t Hoff factor for dilute aqueous solution of K2SO4
a) 1 b) 2 c) 3 d) 4
20. Two liquids A and B boil at 145 °C and 190 ° C, Which of them have higher vapour pressure at 80 ° C
a) Liquid A b) Liquid B c) Both A and B d) None of these
21. Solution containing 6.8 g of non ioning solute in 100 g of Water was found to freeze at -0.93 °C, the
molar mass of the solute is (Kf = 1.86° C/ mole)
a) 13.6 b) 34 c) 68 d) 136
22. The correct sequence of decrease in the bond angle of the following hydrides is
a) NH3> PH3>AsH3>SbH3 b) NH3> AsH3>PH3>SbH3
c) SbH3> AsH3>PH3>NH3 d) PH3> NH3>AsH3>SbH3
23.H2S is more acidic than H2O because
(a)oxygen is more electronegative than sulphur.
(b) atomic number of sulphur is higher than oxygen.
(c) H — S bond dissociation energy is less as compared to H — O bond.
(d) H — O bond dissociation energy is less also compared to H — S bond.
24. The boiling points of hydrides of group 16 are in the order
(a) H2O > H2Te > H2S > H2Se (c) H2O > H2Te > H2Se > H2S
(b) H2O > H2S > H2Se > H2Te (d) None of these
25. In the manufacture of sulphuric acid by contact process Tyndall box is used to
(a) convert SO2 and SO3 (c) filter dust particles
(b) test the presence of dust particles (d) remove impurities
26. Fluorine differs from rest of the halogens in some of its properties. This is due to
(a) its smaller size and high electronegativity.
(b) lack of d-orbitals.
(c) low bond dissociation energy.
(d) All of the these.
27. The set with correct order of acidity is
(a) HClO< HClO2 < HClO3 < HClO4(b) HClO4 < HClO3 < HClO2 <HClO
(c) HClO< HClO4 < HClO3 < HClO2(d) HClO4 < HClO2 < HClO3 <HClO
28. When chlorine reacts with cold and dilute solution of sodium hydroxide, it forms
(a) Cl– and ClO– (b) Cl– and ClO2– (c) Cl– and ClO3– (d) Cl– and ClO4–
29. The formation of O2+ [PtF6]– is the basis for the formation of first xenon compound. This is because
(a) O2 and Xe have different sizes.
(b) both O2 and Xe are gases.
(c) O2 and Xe have comparable electro-negativities.
(d) O2 and Xe have comparable ionisation enthalpies.
30. Partial hydrolysis of XeF4 gives
(a) XeO3 (b) XeOF2 (c) XeOF4 (d) XeF2
31. Helium is preferred to be used in balloons instead of hydrogen because it is
(a) incombustible
(b) lighter than hydrogen
(c) more abundant than hydrogen
(d) non polarizable
32. The increasing order of reducing power of the halogen acids is
(a) HF <HCl<HBr< HI (b) HI <HBr<HCl< HF
(c) HBr<HCl< HF < HI (d) HCl<HBr< HF < HI
33. The isoelectronic pair is
(a) Cl2O, ICl2– (b) ICl2– ClO2 (c) IF2+, I3– (d) ClO2–, ClF2+
34. The correct order of acid strength is:
(a) HClO4 < HClO3 < HClO2 <HClO (b) HClO2 < HClO3 < HClO4 <HClO
(c) HClO4 <HClO< HClO3 < HClO2 (d) HClO< HClO2 < HClO3 < HClO4
35. In BrF3, molecule, the lone pairs occupy equatorial positions to minimise.
(a) lone pair-bond pair repulsions only
(b) bond pair-bond pair repulsions only
(c) lone pair-lone pair and lone pair-bond pair repulsions
(d) lone pair-lone pair repulsions only.
36. The ONO angle is maximum in
(a) NO3– (b) NO2– (c) NO2 (d) NO2+
37. The correct order of bond angles (smallest first) in H2S, NH3, BF3, SiH4 is
(a) H2S < SiH4 < NH3 < BF3. (b) NH3 < H2S < SiH4 < BF3
(c) H2S < NH3 < SiH4 < BF3 (d) H2S < NH3 < BF3 < SiH4.
38. Which of the following oxides of nitrogen is solid?
(a) NO2 (b) N2O (c) N2O3 (d) N2O5
39.Which one of the following arrangements represents the correct order of electron gain enthalpy (with
negative sign) of the given atomic species?
(a) F < Cl < O < S (b) S < O < Cl < F (c) O < S < F <Cl (d) Cl < F < S < 0
40. Which one of the following contains the maximum number of lone pair of electrons on the central atom?
(a) ClO3– (b) XeF4 (c) SF4 (d) I3–
41. Among the following molecules:
XeO3, XeOF4, XeF6, those containing same number of lone pairs on Xe are:
(a) (i) and (ii) only (b) (i) and (iii) only
(c) (ii) and (iii) only (d) (i), (ii) and (iii)
42. Oxidizing power of perhalates decreases in the order
(a) BrO4– > IO4– >ClO4– (b) Cl04– > BrO4 > IO4–
(c) IO4– > BrO4– > ClO4– (d) ClO4– > IO4– > BrO4–
43. There are no S-S bond in
(a) S2O42- (b) S2O52 (c) S2O32- (d) S2O72-
44. Among the tri halides of Nitrogen, which one is the least basic?
(a) NF3 (b) NCl3 (c) NBr3 (d) Nl3
45. Which of the following oxides is the most acidic?
(a) N2O5 (b) P2O5 (c) As2O5 (d) Sb2O5
46. Molecular shapes of SF4, CF4 and XeF4 are:
(a) the same with 2,0, and 1 lone pairs of electrons respectively.
(b) the same with 1,1 and 1 lone pairs of electrons respectively.
(c) different with 0,1 and 2 lone pairs of electrons respectively.
(d) different with 1,0 and 2 lone pairs of electrons respectively.
47. Which of the following hydrogen halides is most volatile?
(a) HF (b) HCl (c) HBr (d) HI
48. The shape of ClO3– is
(a) triangular pyramid (b) tetrahedral
(c) triangular planer (d) triangular bipyramid.
49. The shape and hybridization of some xenon oxy fluorides are given below. Choose the wrong answer.
(a) XeOF2-T shaped-sp³d (b) XeOF4-square pyramidal-sp³d²
(c) XeO2F2-Trigonal bipyramid-sp³d (d) XeO3F2-Tetrahedral-sp³.
50. Which among the following factors is most important in making fluorine the strongest oxidising agent?
(a) electron affinity (b) ionisation energy
(c) hydration energy (d) bond dissociation energy.
