Revision date: 20/2/2018
SAFETY DATA SHEET Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830 Language: en-GB,IE
Date of print: 4/3/2020
Refrifluid B
Material number E701185x Page: 1 of 8
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1 Product identifier
Trade name: Refrifluid B
This safety data sheet pertains to the following products:
E7011852: 2 L
E7011854: 4 L
1.2 Relevant identified uses of the substance or mixture and uses advised against
General use: Corrosion inhibitor
Industrial use
Professional uses / Public domain
1.3 Details of the supplier of the safety data sheet
Company name: Lauda Dr. Wobser GmbH & Co. KG
Street/POB-No.: Pfarrstraße 41/43
Postal Code, city: 97922 Lauda-Königshofen
WWW: www.lauda.de
E-mail: info@lauda.de
Telephone: +49 (0)9343-503-0
Telefax: +49 (0)9343-503-222
Department responsible for information:
Department Quality Management,
Telephone: +49 9343 503-331, e-mail info@lauda.de
1.4 Emergency telephone number
GIZ-Nord, Göttingen, Germany,
Telephone: +49 551-19240
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to EC regulation 1272/2008 (CLP)
Repr. 2; H361 Suspected of damaging fertility or the unborn child.
2.2 Label elements
Labelling (CLP)
Signal word: Warning
Hazard statements: H361 Suspected of damaging fertility or the unborn child.
Document number Q5WA-E_17-018GB-05, printed by Lauda with Qualisys SUMDAT
Revision date: 20/2/2018
SAFETY DATA SHEET Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830 Language: en-GB,IE
Date of print: 4/3/2020
Refrifluid B
Material number E701185x Page: 2 of 8
Precautionary Statements: P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P501 Dispose of contents/container to hazardous or special waste collection point.
Special labelling
Text for labelling: Contains Sodium 2-ethylhexanoate.
2.3 Other hazards
No risks worthy of mention.
Results of PBT and vPvB assessment:
No data available
SECTION 3: Composition / information on ingredients
3.1 Substances: not applicable
3.2 Mixtures
Hazardous ingredients:
Ingredient Designation Content Classification
REACH 01-2119979083-31-xxxx Sodium 2-ethylhexanoate 5 - 10 % Repr. 2; H361.
EC No. 243-283-8
CAS 19766-89-3
Full text of H- and EUH-statements: see section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures
General information: First aider: Pay attention to self-protection!
In case of inhalation: Remove person to fresh air and keep comfortable for breathing. Seek medical attention if
problems persist.
Following skin contact: After contact with skin, wash immediately with soap and plenty of water. Take off
contaminated clothing and wash it before reuse. In the event of discomfort seek medical
treatment.
After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart.
Remove contact lenses, if present and easy to do. Continue rinsing. Subsequently consult an
ophthalmologist.
After swallowing: Rinse mouth and drink large quantities of water. Never give anything by mouth to an
unconscious person. Do not induce vomiting. Immediately get medical attention.
4.2 Most important symptoms and effects, both acute and delayed
No data available
Document number Q5WA-E_17-018GB-05, printed by Lauda with Qualisys SUMDAT
Revision date: 20/2/2018
SAFETY DATA SHEET Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830 Language: en-GB,IE
Date of print: 4/3/2020
Refrifluid B
Material number E701185x Page: 3 of 8
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media: Alcohol resistant foam, extinguishing powder, carbon dioxide
Extinguishing media which must not be used for safety reasons:
Full water jet
5.2 Special hazards arising from the substance or mixture
May form dangerous gases and vapours in case of fire.
Furthermore, there may develop: sodium compounds, carbon monoxide and carbon dioxide
5.3 Advice for firefighters
Special protective equipment for firefighters:
Wear self-contained positive pressure breathing apparatus and full firefighting protective
clothing.
Additional information: Hazchem-Code: -
Cool endangered containers with water jetspray. Do not allow fire water to penetrate into
surface or ground water.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Avoid exposure. Seal off endangered area. Keep unprotected people away. Provide good
ventilation. Avoid contact with the substance. Wear appropriate protective equipment. Take off
contaminated clothing and wash it before reuse.
6.2 Environmental precautions
Do not allow to penetrate into soil, waterbodies or drains.
6.3 Methods and material for containment and cleaning up
Collect with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding
agents, or sawdust) and place in closed containers for disposal. Thoroughly clean
surrounding area.
6.4 Reference to other sections
Refer additionally to section 8 and 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Advices on safe handling: Obtain special instructions before use. Provide adequate ventilation, and local exhaust as
needed. Avoid contact with the substance. Take off contaminated clothing and wash it before
reuse. Safety shower and eye wash station should be easily accessible to the work area. Do not
eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Document number Q5WA-E_17-018GB-05, printed by Lauda with Qualisys SUMDAT
Revision date: 20/2/2018
SAFETY DATA SHEET Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830 Language: en-GB,IE
Date of print: 4/3/2020
Refrifluid B
Material number E701185x Page: 4 of 8
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storerooms and containers:
Keep containers in a dry, well-ventilated and cool place. Protect from heat and direct sunlight.
Store only in original container. Store carefully closed containers upright to prevent any leaks.
Storage temperature: 5 °C up to 35 °C
Shelf life: 24 months
Hints on joint storage: Keep away from food, drink and animal feedingstuffs.
7.3 Specific end use(s)
No information available.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Additional information: Contains no substances with occupational exposure limit values.
DNEL/DMEL: Information about Sodium 2-ethylhexanoate:
DNEL workers, long-term, systemic, dermal: 2 mg/kg bw/d
DNEL workers, long-term, systemic, inhalative: 14 mg/m³
DNEL consumers, long-term, systemic, oral: 1 mg/kg bw/d
DNEL consumers, long-term, systemic, dermal: 1 mg/kg bw/d
DNEL consumers, long-term, systemic, inhalative: 3.5 mg/m³
PNEC: Information about Sodium 2-ethylhexanoate:
PNEC water (freshwater): 0.36 mg/L
PNEC water (marine water): 0.036 mg/L
PNEC sewage treatment plant (STP): 71.7 mg/L
PNEC sediment (freshwater): 0.301 mg/kg dw
PNEC sediment (marine water): 0.03 mg/kg dw
PNEC soil: 0.058 mg/kg dw
8.2 Exposure controls
Provide adequate ventilation, and local exhaust as needed.
Personal protection equipment
Occupational exposure controls
Respiratory protection: If vapours form, use respiratory protection.
The filter class must be suitable for the maximum contaminant concentration
(gas/vapour/aerosol/particulates) that may arise when handling the product.
Hand protection: Protective gloves according to EN 374.
Glove material: Nitrile rubber
Breakthrough time: >480 min.
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Eye protection: Tightly sealed goggles according to EN 166.
Body protection: Wear suitable protective clothing.
Document number Q5WA-E_17-018GB-05, printed by Lauda with Qualisys SUMDAT
Revision date: 20/2/2018
SAFETY DATA SHEET Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830 Language: en-GB,IE
Date of print: 4/3/2020
Refrifluid B
Material number E701185x Page: 5 of 8
General protection and hygiene measures:
Obtain special instructions before use. Avoid contact with the substance. Wash hands before
breaks and immediately after handling the product. When using do not eat, drink or smoke.
Take off contaminated clothing and wash it before reuse. Safety shower and eye wash station
should be easily accessible to the work area.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance: Physical state at 20 °C and 101.3 kPa: liquid
Colour: rose-coloured, transparent
Odour: characteristic
Odour threshold: No data available
pH value: at 20 °C: 9.5
Melting point/freezing point: No data available
Initial boiling point and boiling range: 100 °C
Flash point/flash point range: No data available
Evaporation rate: No data available
Flammability: No data available
Explosion limits: No data available
Vapour pressure: at 20 °C: 2350 Pa
at 50 °C: 12381 Pa
Vapour density: No data available
Density: at 20 °C: 1.0 - 1.1 g/mL
Solubility: Miscible with most organic solvents and alcohols.
Water solubility: at 20 °C: miscible
Partition coefficient: n-octanol/water: No data available
Auto-ignition temperature: 480 °C
Decomposition temperature: No data available
Viscosity, dynamic: at 20 °C: 1.27 mPa*s
Viscosity, kinematic: at 20 °C: 1.23 mm²/s
Explosive properties: No data available
Oxidizing characteristics: No data available
9.2 Other information
Additional information: No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
refer to 10.3
10.2 Chemical stability
Stable under recommended storage conditions.
Document number Q5WA-E_17-018GB-05, printed by Lauda with Qualisys SUMDAT
Revision date: 20/2/2018
SAFETY DATA SHEET Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830 Language: en-GB,IE
Date of print: 4/3/2020
Refrifluid B
Material number E701185x Page: 6 of 8
10.3 Possibility of hazardous reactions
No dangerous reactions are known.
10.4 Conditions to avoid
Protect from heat and direct sunlight.
10.5 Incompatible materials
No data available
10.6 Hazardous decomposition products
Sodium compounds, hydrocarbons, carbon monoxide and carbon dioxide
Thermal decomposition: No data available
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Toxicological effects: The statements are derived from the properties of the single components. No toxicological data
is available for the product as such.
Acute toxicity (oral): Based on available data, the classification criteria are not met.
Acute toxicity (dermal): Based on available data, the classification criteria are not met.
Acute toxicity (inhalative): Based on available data, the classification criteria are not met.
Skin corrosion/irritation: Based on available data, the classification criteria are not met.
Serious eye damage/irritation: Based on available data, the classification criteria are not met.
Sensitisation to the respiratory tract: Based on available data, the classification criteria are
not met.
Skin sensitisation: Based on available data, the classification criteria are not met.
Germ cell mutagenicity/Genotoxicity: Based on available data, the classification criteria are
not met.
Carcinogenicity: Based on available data, the classification criteria are not met.
Reproductive toxicity: Repr. 2; H361 = Suspected of damaging fertility or the unborn child.
Effects on or via lactation: Lack of data.
Specific target organ toxicity (single exposure): Based on available data, the classification
criteria are not met.
Specific target organ toxicity (repeated exposure): Based on available data, the classification
criteria are not met.
Aspiration hazard: Based on available data, the classification criteria are not met.
Other information: Avoid contact during pregnancy/while nursing.
Information about Sodium 2-ethylhexanoate:
LD50 oral: > 2,000 mg/kg
LD50 dermal: > 2,000 mg/kg
Document number Q5WA-E_17-018GB-05, printed by Lauda with Qualisys SUMDAT
Revision date: 20/2/2018
SAFETY DATA SHEET Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830 Language: en-GB,IE
Date of print: 4/3/2020
Refrifluid B
Material number E701185x Page: 7 of 8
SECTION 12: Ecological information
12.1 Toxicity
Further details: No data available
12.2 Persistence and degradability
Further details: No data available
12.3 Bioaccumulative potential
Partition coefficient: n-octanol/water:
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
No data available
12.6 Other adverse effects
General information: Do not allow to penetrate into soil, waterbodies or drains.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Waste key number: 07 06 04* = other organic solvents, washing liquids and mother liquors
* = Evidence for disposal must be provided.
Recommendation: Dispose of waste according to applicable legislation.
Contaminated packaging
Recommendation: Dispose of waste according to applicable legislation. Non-contaminated packages may be
recycled.
SECTION 14: Transport information
14.1 UN number
ADR/RID, IMDG, IATA-DGR: not applicable
14.2 UN proper shipping name
ADR/RID, IMDG, IATA-DGR: Not restricted
14.3 Transport hazard class(es)
ADR/RID, IMDG, IATA-DGR: not applicable
Document number Q5WA-E_17-018GB-05, printed by Lauda with Qualisys SUMDAT
Revision date: 20/2/2018
SAFETY DATA SHEET Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No. 2015/830 Language: en-GB,IE
Date of print: 4/3/2020
Refrifluid B
Material number E701185x Page: 8 of 8
14.4 Packing group
ADR/RID, IMDG, IATA-DGR: not applicable
14.5 Environmental hazards
Marine pollutant: no
14.6 Special precautions for user
No dangerous good in sense of these transport regulations.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
No data available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations - Great Britain
Hazchem-Code: -
No data available
National regulations - EC member states
Volatile organic compounds (VOC):
0 % by weight = 0 g/L
15.2 Chemical Safety Assessment
For this mixture a chemical safety assessment is not required.
SECTION 16: Other information
Further information
Wording of the H-phrases under paragraph 2 and 3:
H361 = Suspected of damaging fertility or the unborn child.
Reason of change: Changes in section 2: Labelling
Changes in section 3: Composition / information on ingredients
Date of first version: 28/11/2012
Department issuing data sheet
Contact person: see section 1: Department responsible for information
For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safety
assessment, chapter R.20 (Table of terms and abbreviations).
The information in this data sheet has been established to our best knowledge and was up-to-date at time of
revision. It does not represent a guarantee for the properties of the product described in terms of the legal warranty
regulations.
Document number Q5WA-E_17-018GB-05, printed by Lauda with Qualisys SUMDAT
