750 Objective Chemistry for NEET/

Level 1:Basic Problems

Hydrogen Bonding
1. Which of the following H-bond strength order is not (d) CH,-C-CHC-CH,
correct?
O-H
(a) D,0 H,O b) H,O>H,02 9. Which is not stable?
(c)HF H,0> NH (d) HF > F . . H -F (a) KHF2 b) KI
2. Homointermolecular H-bonding is present between: (c) CH-CH(OH)2 (d)CiC-CHOH),
10. Pairs of strongest hydrogen bond is:
(a)R-NH, +R -NH
b) HS+ HS (a) SiH, and SiCl
(c) CHCl CH (b) CH,CoOH and CH,OCH
C-CH3
(c) CH,COOH and CH,COCH
d)H0 R-OH (d) H0 and H202
3. Which of the following species exist as dimer due to 11. Which of the hydrogen halides forms salts like KH
Hydrogen bonding ? (where X is a halogen atom) ?
(a) H,BO3 (a) HF (b) HCI (c) HI (d) HBr
b) HCO ions in NaHCO 12. Which of the following can form H-bond with water
(c)HCO ions in KHCO0 (a) HCN b) NH4F (c) NaHCO, (d) All
13. Which of the following intraction lies in the range oi
(d)0 nitrophenol
4. Symmetrical Hydrogen bondingis present in 8-42kJ/mole?
(a) F...HF (b) Xe...H0
(a) HF (d) H,0
()[Ni(dmg),] (d) All of these (c)Cs..OH (d) O,N(O)OH-H0
5. Species present in acidified water are/is 14. Incorrect statement for ice is:
(a) H,O (b) HO2 (a) Less density than liquid water
(b) Each O atom is surrounded by four equidistanc:
)H, O, d) All of these H-atoms
6. Which of the following statement is not correct ? (C) Distance between two adjacent O-atoms is equa
(a) Linear Hydrogen bonding is present in NH,3 (d) Open cage like crystal structure
(b) Solid boric acid has 2-D structure due to 15. Which of the following compounds has signiñcat
inter
molecular hydrogen bonding. intermolecular H-bonding
(c) Urea has high boiling point due to intramolecular [HE,N,O.CH,CH- OH]?
Hydrogen bonding. (a) HF,N,0 (b) CH,OH,CH,HF
(d) HC, ion exists only with large cation like Cs (c) HF,CH ,OH (d) CH-Oti, CH
Intramolecular hydrogen bonding is not present in : 16. Which of the following statement is not coret
(a) Urea (b) Choral hydrate (a) H-bond is berween

an electrostatie attraction
(C)Salicyladehyde (d) o-fluoro phenol covalenty bonded H-atom and
8. Which of the following compound does electro-nagetive atom
not have
hydrogen bonding ? (b)
(a) K,HP0
D,Os sinks in
H,O, but tloats on
D,Ou
(c) Crystal of hydrated CasO, are soft but
(b) K,HP anhydrous CaSO are very hard
(d) The crystal structure
(c)NaHCO,(5) of NatiCO, and KHCO
säme due to intermolecular H bonding
hemicalBonding 751)
Correct match is: in
hydrogen bonding
1 7 C o

intramolecular
(b) strong
Column-I
0-nitrophenol
Colmn-II bonding in
Chloral hydrate (p) Form (c) strong intramolecular hydrogen
Zig-zag chain p-nitrophenol
(g Form 2-D-sheet is larger than
HF (d) dipole m o m e n t of p-nitrophenol
structure
that of o-nitrophenol
(r) Intermolecular H-bond
H,BO 24. When ice melts to form liquid water at 0° C, there is a

(s) Intermolecular H-bond contraction in volume. This is due to

H2SO4
(a) the molecules contracting in size
(a) a-s, b-P, C-9, d-T (b) a-s, b-p, c-r, d-q hydrogen bonded
(6) a partial disruption of the
(ca-p, b-s, C-9, d-r (d) a-p, b-q, c-, d-p network of ice on melting
The correct order of decreasing extent of the (c) the absorption of heat during the melting process
hydrogen bonding is :
air into the water during the
(d) the dissolving of
(a) H0> HF> H202>H2S
melting process
(b) HO> HF> H2S> H,02

(c) HF>H,0>H20,>H2S Weak Intermolecular Attraction Forces

(d) H,0> H20> HF> H,S 25. The solubility ofinert gases in water in due to:
19, The boiling points at atmospheric pressure of (a) Kessom attraction (b) Debye attraction
HF,HS, NH3 can be arranged in the following
(c) London force (d) lon-dipole attraction
order
26. Dispersion force is present between
(a) HF> NH3 > HS (b) HF>H2S>NH (a) Polar +Polar molecules
(c) HF <H,S < NH3 (d) HF<NH <H2S (b) Nonpolar + Nonpolar molecules
20. The correct order of strength of H-bond in the (c) Polar + Nonpolar molecules
followingcompound (d) All of these
(a) H,0>H,02 > HF >H2S
27. Which force is least sensitive for distance?
(b) HF> H,02 > H,0>H,S
(a) lon-dipole, attraction (b) Dipole-induced dipole
()HF> H,0>H2S >H;02 (c)Ion-induced dipole (d) Dispersion force
(d) HF > H0 > H202>H,S 28. The strongest force among the following is:
21. Which statement is correct?
(a) London force (b) Ion-dipole interaction
(a) m.p. of H0, NH3 are maximum in their (c) Dipole-induced dipole interaction
respective due to intermolecular
group (d) Dipole-dipole interaction
H-bonding 29. Which of the following is not correctly matched with
(6) b.p. of CH, out of CH4, SiH,, GeH4 and SnH4 is respect to the intermolecular forces existing
least due to weak intermolecular force of
amongest the molecules (Hydrogen bonding is not
attraction taken as dipole-dipole attraction) ?
c) formic acid forms dimer by H-bonding (a) Benzene-London dispersion force, hydrogen
d) all are correct bonding
2n e correct order of the strength of H-bonds is
(b) Orthoph phoric acid- London dispersion force,
(a) H..F >H...0>H...N hydrogen bonding
6) H...N>H...0>H...F (c) Hydrochloric acid-London dispersion force,
C)H...0 >H...N>H...F dipole-dipole attraction
(d) H...F >H...N> (d) lodine monochloride-London dispersion force
23. H...0 whereas 30. Select incorrect statement:
distilled
trophenol can be easily steam
Pitrophenol cannot be. This is because of : (a) Among d-block elements, group 12 elements
in have the least
Srong intermolecular hydrogen bonding enthalpy of atomisation
(b) Cohesive forces in metals non-directional
0-nitrophenol bonds
are
752
(c) Group 1 elements have
Objective Chemistry for NEET/AIM
OH
NEETJAIIMS
metallic bonding than greater strength ot
corresponding group 2
NO2
elements due to
increasing electronegativity on
moving left to right in periodic
table. HO
O
(d) Hardness of copper (a) Intermolecular H-bonding
being more as compared to
potassium can be explained by metallic bond (b) Intramolecular H-bonding
strength. (c)vanderWaals' force
31. Select incorrect statement :
(d) All of these
(a) In s-block elements,
melting
increases on moving down the point generally 37. Which among the following attraction is strongest 2

(6) Band
group. (a) HE...H,0 (b) Na. HCI
model proposed to
bonding is based on molecular explain
metallic
orbital theory (C)H,0..Cl2 (d) Cl-Cl..C-C
(c) d-block elements 38. Which of the following is observed in metallic
series in
get a dip at/near middle of
bonds
enthalpy of atomisation values (a) Mobile valence electrons
(d) Electricity conduction in a
can be considered similar
single layer of graphite (b) Localised electrons
conduction in metals
to electricity (c)Highly directed bond
model.
according to electron sea
(d) None of these
32. Which of the following statements 39. The molecular size of ICl and
is not true for the Br, is approximatel
metallic bond ? same, but b.p. if ICl is about 40°C
higher than that o
(a) It is electrical attraction between
an Br2. It is because:
electrons and the positive delocalised (a) ICl bond is stronger than Br-Br bond
part of the atom.
(b) Transition metals (b) IE of iodine < IE of bromine
may use inner
along with the outer s-electrons ford-electrons ()ICl is polar while Br, is
metallic nonpolar
bonding. (d) I has larger size than Br
(c) Strength of metallic bond does not depend on the 40. Which of the
type of hybrid orbitals following order of molecular force of
bonding participating in metallic attraction among given species is incorrect?
(d) Strength (a) HI> HBr > Cl2
of metallic bond is
inversely b) CHCl>
proportional to the radius of metallic atom. CCl > CH4
33. Which of these is not c) n-pentane >
true for metallic bond? iso-pentane
>
neo-pentane
(d) OH> O(CH
(a) Metallic bond is
non-directional in nature 41.
)2 >OBr
Which gas should not be
b) Metallic bonds are weaker than covalent bond collected over water because
of its high solubility in water ?
()Energy required to
vapourise a mole of Cu metal
is high than the (a) H2
energy required to vapourise a (b) N2
mole of a covalent substance (c) CH
like diamond d) HCI
(d) The valency electrons in a 42. Low
metalic bond are melting point is expected for a solid:
mobile (a) lonic solid
34. Which of the (c) Molecular solid
(b) Metallic solid
following physical properties can be d) Covalent solid
explained by electron sea model ? 43. Which substance has
(a) Electrical conduction the strongest London
(b) Thermal forces? dispersl
(c) Malleability
conduction
(d) All of these (a) SiH,
35. Which substance has the (c) Snt,
(b) CH
orces?
strongest l.ondon dispresion d) GeH
44. Which substance has the
(a) SiH (b) CH (c) SnH (a) CO highest melting point
(d) Get (b) co
36. The type of molecular forces of attaction (c) Sio
the following compound is present in (d) P,O5
nic Bond,ofLattice Energy and
erties onic RARP O (753
In hich of the t
Compounds
tollowing S,
d) Nactl0, ,NaNO
ln fused state,
oie n natune ? pain, both poorest conductor of electricity
(a) Belt,BeF,
compounds are (a) KCI (b) BeCl, (c) CaCl (d)
:

SrCl2
54. The
AlF BeC bLicatitt
) Mgcl,.Mg)
incorrect order
(a) AlF,MgF,
of lattic energy IS

ot the toll
(b) Li,N> Li,0
46. hichHaber sllowing energy term is not
(c) NaCl LiF (d) TiC> ScN
Bon- yele tor NaCl formation:? involved in S5. Choose the incorrect order of hydrated size of the
ions
a ydraion energy of Na
( tes of CI (a) Fg) aq)Br(aq)aq
(b) RbnK ()
Lattive energy of NaC Na (aq)
) Both a) and (b) (c) Na ag)Mg
(aq Al (aq) >

. vourable condition for ionic bond (d) Be Mg (a> Ca (ag)

ahigh Sublimation energy formation is
56. Which of the
of metal and following order of conductivity is not
cation larger correct ?
high electron attinity of nonmetal and smaller (a) NaCl > KCI > RbCI CsCl in molten state
>
anion. (b) NaCl < KCl < RbCl< CsCl in aq. solution
cLow sublimation energy and high (c) Fused LiCl< Fused NaCl
1.R of Metal
d Smaller cation, smaller anion and (d) NaCl < KCl < RbCl < CsCl in molten state
energy
high latitce 57. For a reaction A(g) +
B(g)> AB(s) the enthalpy
s. Which of the following order of Lattice Energy is not
change for the reaction will be (assuming AB (s) to be
correct? an ionic compound) :

(a) NaCl Na 2S (a) AH1E AHeg

(b) KF<LiF <MgO aE. AB()
c Na,S MgCl (6) AHegA +AH LE AHLE ABO) +
()MgO AIN
a9 In which of the following pair, both compounds show (c) 1.E. +E.Ag
+AHLE. AB()
onductivity ? (d) 1.E.+ E.Ap
58. In which of the
t
AHLE AB)
(a AlF
(moltren) AlCl 3(umoltend
.
following set do all the three
b) AiCl compounds have bonds that are mainly ionic?
g
(c) NaCl.HCl(a)
3ag,),Na (a) NaCl, NCl,CCl (b) CsBr,BaBr2 . SrO
(c) CsF3,BFs.NH d) Al,O.CaO,SP2
d) HCl
*
molten), AlFs(aq 59. Solid NaCl is a bad conductor of
electricity because:
Nhich of the has Lattice
following compound highest (a) in solid NaCl there are no ions
energy? (b) solid NaCl is covalent
(a) AIF (b) Na,S (c)AlO (d) CaF
(C)in solid NaCl there is no mobility of ions
What is the AH of the following reaction ?
(d) in solid NaCl there are no electrons
Mg(g) 2F(g)- Mg (g)+2F (g) or MgF;(8) 60. An ionic compound A"B is most likely to be formed
electron affinity of FR) = -328 kJ mol and when:

Firstionisation energy of Mg kJ moland (a) the ionization energy of A

=737.7 affinity of B is low
high and electron
Secon ionisation nergy of Mg =
1451kJ mol
(b) the ionization energy of A is low
and electron
a) (b) 1860.7 kJ mol
1532.7 kJ mol affinity of B is high
(c) 2516.7 kJ 1 (d) 1451kJmol (c)both, the ionization energy of and electron
mol A
. WhichO of the Isomosphous ?
affinity of B are high
following pairs is not

la) BasO KMnO4 (d) both, the ionization

energy of A and electron
b) KCIO ,KBF affinity of Bare low
(e) FeSo,7H,0,MgsO.711,0
754 Objective Chemistry for NEET/AIMS
61. A compound contains three elements A, B and C, if (d) Both energy increase down the group but incre
the oxidation of A =+2,B =+5 and C=-2, the in hydration energy is rapid erease
possible formula of the compound is: 70. The melting point of RbBr is 682°C while that
iNak
(a) Ag(B,C (b) A,(BCa)2 is 988°C. The principal reason for this fact is
(c) A(BC32 (d) ABC (a) the molar mass of NaF is smaller than that
RbBr
62. In an ionic compound A*X the degree of covalent
bonding is greatestwhen: (b) the bond in RbBr has more covalent
than the bond in NaF racter
(a) A and X ion are small
(b) A is small and X is large (c) the difference in electronegativity between h
and Br is smaller than the difference between
(c) A and X ions are approximately of the same Na
and F
S1ze
(d)X is small and A* is large (d) the internuclear distance, re +ra 1s greater for
RbBr than for NaF
63. In which of the following species the bonds are
non-directional ?
(a) NCl (b) RbCI (c) BeCl2 (d) BCl3
Polarisation and Fajan's Rule
64. Which of the following statements about LiCl and 71. Which of the following Polarising power order is no
NaCl is wrong? correct?
(a) LiCl has lower melting point than NaCl (a) Ca< Pb*2 (b) Na < Cu
(b) LiCl dissolves more in organic solvents whereas (c)Sn2<Sn4 (d) Zn*2>ca2
NaCl does not 72. Which of the following order is incorrect?
(c) LiCl would ionise in water less than NaCl (a) lonic character
(d) Fused LiCl would be less conducting than fused
=MCI MCl2 <MCl
<

NaCl (b) Polarizibility =F Cl<Br <1

<

65. Which of the

following substances has the (c) Polarising power =Na* <Ca*2 < Mg < Al
highest
melting point? (d) Covalent character =LiF < LiCl< LiBr <Lil
(a) NaCl (b) KCI
66. The stability
(c) Mgo (d)Bao 73. Which is the correct
decreasing order of covalent
of ionic crystal principally depends on: nature?
(a) high electron affinity of anion forming (a) Sicl, > AlCl > ZnCl>
(b) the lattice energy of crystal
species CaCl > MgCl2
(b) Sicl > AICl, > MgCl2 > CaCl2 > ZnCl2
(c) low I.E. of cation forming
species (c)ZnCl, > Sicl, > AICl, > MgCl, > CaCl,
d) low heat of sublimation of cation (d)
67. The
forming solid SiCl> AICl>ZnCl> MgCl, >Cad
compound with the highest degree of covalency 74. Which of the
following order is not correct?
iS
(a) CrO< Cr,0, <Cro, covalent character
(a) NaCl b)
MgCl2 (c)AgCl d) CsC1 (b) ZnO> ZnS ionic character
68. The salt having the least
solubility in water is: (c) BeCl2 > MgCl, > CaCl2 > SrCl,> BaCl ion
(a) BaCl2 (b) Ba(NO3)2 character
(c) MgsO (d) BasO (d) KCl< AgCl covalent character
69. Solubility of alkali metal fluorides increases down the 75. Select the most
ionic and most covalent
mpouns

group." Select correct explanation for given co

statement
respectively from the following :
(a) CrOs.Mn20, (b) PbO,Mn,0,
(a) Hydration energy increases and lattice (c) CrO.P,0 10
energy d) SnO,,Cr0s
decreases down the group 76.
b) Both energy decrease down the group but Magnesium cation has 1sation power close
polarisation powe
that of
decrease in hydration energy is rapid
(a) Li (b) Na (c) K (d)Cs
(c) Both energy decrease down the group but 77. Which of the following will be most covale
decrease in lattice energy is rapid
(a) NaCl (6) Nas (c) MgCl (d) Mg
 mical Bonding
(755
8. Among
the following the maximum covalent combination of ion will have
is shown by the B6. Which of the following
haracter
compound: highestpolarisation?
(a) AlCl
(b) MgCl () FeCl,
(d) SnCl (a) Fe ,Br
(b) Ni Br
. lonic potenti (¢)«ofelectropositive element will be (d) Fe, Br
which ofthe (c) Ni2 ,Br
highest in following compond
(a) CsC (b) MgCl, ()AlIF (d) SF
0. Which of thefollowi have maximum and minimum Solubility
when react with :

inniccharacter out ot Mno, MnF2, MnO.Mn,0,? 87. PbO forms a soluble product
(d) All
(a) MnO, Mn,0, respectively (a) dil. (b) H,S0, (c) HNO,
HCI
order not correct?
is
(b) MnF2 Mn,0, respectively 88. Which of the following solubility
NaBr Nal
MnO.MnO respectively (a) NaF< NaCl
<
<

(b) BeSO > MgsO, > CasO,

d) Mn 0- .MnO respectively
1Which of the following compound has maximum (c)Lico, > Na,CO, >K,CO,
covalent character ? (d) LiOH< NaOH <
KOH < RbOH
of Alkali metal salts
89. Incorrect s t a t e m e n t for solubility
a) CH-C-OLi (b) CF-CH,Li in a Group is
down the group
(a) Solubility of fluorides increases
increases down the
(b) CH CH-0Li' (c) CHg - CHLi (b) Solubility of bicarbonates
group
2. According to
Fajans rules, electrovalent-bond down group the
(c) Solubility of Chlorides increases
formation is favoured by: the group
(d) Solubility of Oxides increases down
(a) positive charge,
low and small size of cations and
90. Incorrect solubility order is:
large size of anions (a) SnCl2>SnCl, (in water)
b) low positive charge, and large size of cations and
(b) NaCl < LiCl (in acetone)
small size of anions
(c) Ag ,0 > Ag2S (in water)
(c) high negative charge, and large size of cations
and large size of anions (d) BaF,> BeF2 (in water)
91. Which of the following is least soluble
d) high positive charge, and small size of cations
and small size of anions (a) Ba(OH)2 (b) LiNO
3. Order of covalent character is not correct for (c) SrSO (d) LiCto
a) NaF <Na,0 < Na,N b) PbO < Pbs 92. Least mobile ion is

(c) CdCl< SnCl2 (d) AgCl> NaCl (a) [Be(H,0),]*2 (b)[Na(H,0),1

. Which of the following is a correct order of ionic
(c)[Mg(H,0),1* (d) [Li(H.0),l
character ? 93. Which ofthe following solubility order is not correct?
a) SnF, <SnCl < SnF <SnCl4 (a) MgF MgCl, < MgBr, < Mgl,
(b) SnCl< SnF, <SnCl2 < SnF2
)SnF, < SnCl, < SnCl < SnF
(b) Be(OH), Mg(OH)2 Ca(OH),
< < <
Sr(OH)D
() Li,O< Na,0 < K,0 < Rb,O< Cs,0o
d) SnF, < SnCl, <SnF2 < SnCl2 (d) CsF< CsCl< CsBr < Csl
correct?
Which of the followin statement is 94. Anhydrous AlCl, is covalent. From the data given
about by a

d Minimum polarisation is brought below

cation of low radius Lattice energy 5137kJ/mol
bring about a large
A large cation is likely to
AH hydration for Al- -4665 kJ/ mol
degree of polarisation
AH hydration for
) VaXimum polarisation is brought abour by a
Cl--381kJ/ mol
cation of high charge Correct statement is:
is called
d) Distortion of cation Dy anion (a) The solution will consist of
Al &CI
polarisation (b) The solution will consist of
hydrated Al& Cl
 756 Objective Chemistry for NEET/AT
(c)Itwill remain covalent in aqueous solution 104. Por which of the following the tou
M
(d) None dissociation of H,0 will be least importar
a
95. Which of the following statement is incorrecet ? calculating solubility using Ksp ?
(a) AgCl< AgF solubility (a) Mg(OH) (b) Ca(OH),
(b) KCl< KI solubility in acetone (c) Sr(O) 2 (d) Ba(OH),
105. Which of the followingsolubility order is not c
(e)BeC,0 <BaC,O, solubility
(d) CaCrO, BaCro, Solubility (a) LiP<Licl< LiBr (b) BaF,
96. The correct decreasing order of ionic product of lead
BaCl,
(c) BeF> BeCl2 BeBr, (d) CsF <CsC]< Ralb
Csk
dihalide is 106. Which of the following is arranged in
orde
(a) PbF,> PbCl, PbBr, > Pbl
>
increasing hydration energy?
(b) PbE> PbBr, > PbCl, > Pbl2 (a) Fe < Zn2" <Al3 <Cu2
(c)PbF2>Pbl, > PbCl, > PbBr2 (b) Cu< Al <Fe3" < Zn2
d) PbCl > PbBr, > PbF2 > Pbl2
(c) Zn2< Cu2 <Fe A1
97. A white salt (X) reacts with an aqueous solution of (d) A13< Fe <Cu2 <Zn2*
BaCl to form a white precipitate. The salt X cannot 107. LiCl is soluble in benzene. This property develogs
be
LiCl because of:
(a) CuSO4 (b) washing soda (a) Smaller size of lithium ion
(c) Chile salt petre (d) Na,S,03.5H,0 (b) Li' is unable to cause distortion
98. Which is the correct order of
solubility in water ? (c) Formation of LiCl does not obey Fajans rule
(a) CsF > CsCl> CsBr > Csl
(d) Lithium is a s-block element
(b) LiF > LiCl> LiBr> Lil
108. Which of the
(c)RbC(O, >KC/O4 > NaC(O4 >LiCeO4 following is correct order of solubiliry
water?
(d) LiF> NaF > KF > RbF
(a) NaClo, < KCIO 4
(b) NaBF, <Naf
99. The Solubilities of carbonates decreases down the (c) MgsO <SrSO
magnesium group due to decrease in (d) None of these
109. If one assumes linear structure instead ot De
(a) Inter-ionic attracion
structure for water, then which one of the folow"
b) Entropy of solution formation
property can not be explained?
(c) Lattice energy of solids
(a) The formation of intermoleculer hydrogen
(d) Hydration energy of cations in water
100. Correct ionic
mobility order in water (b) The high boiling point of water
(a) Be2>Ba2 (b) Li* >Rb (c) Solubility of polar compound in water
(c) <C (d) Na" > Mg*2> A*3 (d) Solubility of water to form co-ordinate co
101. Select wrong statement bond
(a) A transition metal ion is more 110.
polarising than CsF Csaa) +Faa. i AH =
-40 kJ mol
s-block ions of comparable size &
charge energy of CsF is 750 kJ mol.Then the su
(b) Solubility order is AgF> AgCl>
AgBr> AglI of heat
of hydration of Cs and F ion 1s
(c) LiCl is soluble in organic solvents (a) -750 kJ mol (b) -790 kJ mol
(d) None of these is correct
102. Correct solubility order is: (c)-710 kJ mol (d)-830 kJ mol

(a) Fe(OH), Fe(OH) 2 (b) Cr(OH) ,

>

Ba(OH)
>
Melting Point, Boiling Point
(c) Mg(OH)2 Ba(OH), (d) AI(OH), KOH
<
>
111. The correct
103. Order of dielectric constant is correct for: order of volatility is :
(a) NH, <H,O
(a) HF> CH ,OH > H2SO,
(b) p - nitro phenol<
(b) H,0>H,02 >CH,0H (c)
o- nitro phenoi
CH,OH CH 0-CH
(c) H,02 >H,0>CH,COCH, (d) HF HCI
(d) HSO4 >H,0>H,0,
 mut
e m e s t a t e m e n t is
following
molecular H-bond: 123. Which of the N-family
hydride
Inter volatile a m o n g fluorides
is least
12. (a) Decreases Volatility (a) NH point a m o n g
IIA
least melting than its
Increases melting point (b) BeF2 has metal o x i d e
is greater
(b)
(c) Increases viscosity (C)melting point of a
corresponding metal fluoride

than He
(d) All
of these
point of H2 is higher o r d e r is not
(d) Boiling
of the following hydrides which one has the lowest
following
boiling point
124. Which of
the
13.boiling point?
correct?

AsH, (b) SbH (c)PH3 (d) NH3

(a) (a) BF3< BCl3
of H2, He,N2 and O2 in
m - d i c h l o r o b e n z e n e

temperature <
Critical (
O - d i c h l o r o b e n z e n e

) O-hydroxybenzaldehyde<p-hydrobenzaldehyde
4 decreasing order is (b)

> H2 > He (b) O2 >N2> He>H2

(a) N2>O2 (d) NH > PH3 matched ?
(d) O2>N2>H2>He
(c) N2>O2 > He>H2 ? 125. Which of the
following is not correctly
is not correctly match (M.P)
15. Which of the following (a) NH3 > SbH3>PH3>
AsH,
enthalpy ofvapourisation (Proton affinity)
(a) H,0<HF > PH3 > AsH3
> SbHs
(b) NH3 (Thermalstability)
NH, > PH3 Boiling point
SbH SiH4 > GeH4 SnH
>
(b) (c) CH4 >
(c) H2>He strength of
Dispersion force (B.P)
(d) H,0>H,Te > H,Se> HS point
between
(d) HF<NH, <H,0 boiling point 126. Select the
incorrect order of boiling
is not correct?
16. Which of the following
the following compounds:
alcohol is higher than than of (b) MeSO4 <H2SO4
Boiling point of
(a) (a) NgH < CH,N3
diethyl ether (c) Me,B03 <H3BOO3 (d) BF3< BI3
is higher than ice because of
(b) Density of of boiling points:
water
127. Incorrect order
inter molecular H-bonding
viscous than ethanol
(a) NH4>N2F4
(c) Glycerol is less (b) H0>0gF2
than HCl due to
(d) Ammonia is more easily liquified () p-chlorophenol> o-chlorophenol
H-bonding in NH3 (d) Cyclohexane >n-hexane
the compound:
17. Leastmelting point is shown by
(d) AICl
ThermalStability and Heating Effect
(b) SnCl (c) NaC
(a) PbCl melting point ?
18. Which substance has highest bicarbonate can exist in solid
(c) SiO2 (d) POs 128. Which of the following
(a) Co (b) CO2 order is state?
19. Strength of H-bond and Boiling point
(a) LiHCO (b) Mg(HcO,)2
opposite for
(c)Zn(HCO3)2 (d) KHCO 3
(a) HE, H,O, H,02 (b) HF,H20,NH3
(c) H20,H2S, H2Se Which of the following thermal stability order is not
129.
(c) HE HCI, HBr correct?
20. Incorrect order of M.R is:
(a) NaHC0, < KHCO3 < RbHCO
Zn> Cd> Hg
(a) Cr < MO < W(b) (b) CaO2> SrO2 > BaO2
(d) Fe>Co> Ni
(c) Cr> Mn> Fe (c) NaSO4> MgSO4 > Al2(SO4)3
not correct
Which of the following order is (d) CCl,>Sicl, >GeCl4>SnCl4
la) CaCl2 >FeCl, > FeCl, (M.P)
(B.P) 130. The decomposition temperature is maximum for:
(0)
CH 0-CH < C,Hs-OH (a) BeCO3 (b) CaCO
CH)2S0 > H2So, (volatility) (c) K2CO 3 d) Li,co
IA metal)
a) MF> M,0 (M.P.)(M
=

2. is not
correct? 131. Least stable hydride is:
Which of the following order
H C o , <H,0 (critical emperature)
temperature) (a) silane (b) germane
(b) H,0< D,0 (B.P) ()plumbane (d) stannane
-nitrophenol< p-nitrophenol (volatility) 132. Which of the following
(c) pairs of nitrates gives
paramagnetic gas on thermal decomposition ?
d) Li>Na >K> Rb> Cs (M.P)
 758 Objective Chemintry for NEWTIAI
(a) KNO, and Pb(NO ) (c) Increases and inereRses
respectively
(b) KNO and NaNO, (d) Decreases and decreases
respectively
(c)Pb(NO,), and Cu(NO,), 144. 0, yan can not be obtained by thermal decsma
(b) All of these of mit
133. Which of the nitrate does (n) KMnO,
on heating not give any (b) KClO
residue? (c) K,Cr0, (d) (NI)t0
(a) Sodium nitrate (b) Lithium nitrate 145. Which of the following order of thermal
(c) Ammoniumnitrate (d) Lead nitrate not correct?
stability
134. Whose thermal
decomposition will surely be a redox (a) Na ,50,> Mg5O, Al,(50,),
change (b)CaO,>SrO, Bao,
(a) Li,CO (b) NaHCO (c) Na Mg AlF,
(c) NH Cl (d) NaNO (d) NH, PH, As
135. Which of the following reactions is incorrect? 146. Which of the following is not correct for 11A
(a) HNO H,0+NO, +02 (a) Thermal stability of carbonates,
metal
(b) Pb(NO,)2 increase on moving down the zroup sulphatrs
Pb0, +
NO2 + 02
(c) MgCl,.6H,0 (b) Thermal stability of all type
Mg(OH), HC +
moving down the group
of oxides decrease
in
(d) Fe(SO)3 Fe,0, SO
+
(c) Solubility of lydroxides increases
136. Which of the
following compound has max K ,at high down the group
on
movy
temperature?
(d) Bicarbonates do not exist in solid state
(a) BeCO (b) Li,cO, (C) MgCO, (d)
137. Which of the BaCO
hydride?
following is the strongest reducing Covalency, Sidgwick Concept and
Octet Rule
(a) H,O b) HS
138. Salt which
()HSe HTe (d) 147. Which
produce acidic gas on decomposition and of the following species does not obey
leaving behind yellow or white residue ? rule?
(a) (NH)Cr,0, (b) NHNO0 (a) SiF (b) PCI,
(c) Zn(NO3)2 (d) NaNO (c) ICI (d) BE,
139. Which of the
following compounds in thermal 148. Which of the
molecule is not hypovalet
decomposition yields a basic
as well as acidic oxide? completes its octet ?
(a) KCIO (b) NaNO, (c) (a) AICl,
140. Which of the following
K,CO, (d) MgCO, (b) AlBr
compound give metal and
oxygen gas at high temperature ?
(c) AlF (c) BE
149. Which of the following
(a) NaNO (b) Ag,CO, (c) interaction is assocated
141. Which does not K,CO, (d)Li,co expansion of octet ?

gives reddish brown vapour on

(a) NH, BF +
heating? IH,N BE,
(a) LiNO (b) BeF, +2F
(b) KNO [BeF,
(c) Be(NO,)2
142. Which one of the (d)Pb(NO,2 (c) Sbe, + HF
»|SbE,1
following gives mixture of SO, and (d) B F
SO,on heating? 150.
BF
In which
(a) ZnSO (b) Cuso
of the
tollowing molecule elect of
carbon is not
(c) Fe,(SO,) (d) FeSO, promoted to 2p sub shell
(a) HCN
143. Alkaline earth metal carbonate are (b) CO
decomposed on (c) CS
heating and produce residue. Thermal stability of 151. An
(d) Co
reactant and residue (On moving down the element (X) forns the o
group) XCI, X 0, and
compounds of
X
(a) Increase and decreases respectively Ca X, but does not torm
Which of the following is the elements
(b) Decreases and increases respectively (a) B (b) Al (c) N (d)P
 nical Bonding
( 759
Which trihalide
ion is unknown due neither hypervalent
52. vacant d-orbital ?
to absence of 166. Which of the following species is
nor hypovalent 1
(a) F (b) Br3 (c)13 (d) co
(d) Cl3 (a) Clo (b) BF3 (c) SO2
s3.
Oxidation number of iodine varies from 167. Which set contains only covalently bonded4
(a)-1 to +1 b) -1 to +7 molecules?
HBr
b) +3 to +5 (d) -1 to +5 (a) BCl3, SiCl, PCl3 (b) NH4Br, NgH4,
Boi cannot form which of the following anions (c) I2, H25, Nal (d) Al, O3, Ass
154.
(a)BF (b) BH (B(OH) (d) BO 168. In a compound
of the following is/are electron NCC=cMCO)
NC
Which
55. compounds deficient
?
CH are:
(a) NaBH4 (b) AIF (c) AlCl (c) LiAlH4 the number of sigma and pi bonds respectively
56. Which of the following set of species does not follow (a) 19, 11 (b) 19, 5 (c)13, 11 (d) 7, 3
does not contain any
octet rule? 169. Which of the following
(a) Co,PCl,.PCl3, AlCl3 6) AlCl3,BF3, PCI,, SF, co-ordinate bond ?
(a) H,0 (b) BF (c) HF (d) NH
(c)Co,NH3 H,0 (d)H,0,Ni3, 2, AlCl
57. Which of the following species are hypervalent? does not have
170. Which of the following molecules
( Clo4 (I) BF (1) so (co co-ordinate bonds ?

(b) 1,II (a) PH (b) NO (c) O cd) co

(a) 1,1,II (c)I,V (d) I,I,IV
58. Pseudo inert gas configuration is:

(a) ns np (b) (n - 1Dd"nsnp Valence Bond Theory (VBTT

then
(c) nsnp nd0 171. If the z-axis is taken as the internuclear axis,
(c) nsnpSnd-9 combinations of atomic
which of the following
59. Pair of polyhalides, which do not exist?
orbitals is a nonbonding combination?
(a) I5,ICl (b) Br3,ICl (a) s and Px (b) P and dy

()F,Cl (d) ICl, BrF ( Px and py (d) all of these

of octet rule 172. Which of the following statements is not correct for
60. Pair of compounds which are exception
sigma and pi bond formed between two carbon
but not electron efficient ?
atoms?
(a) AlF3,AIcl3 (b) BeH4,B,H6
(a) Free rotation of atoms around a sigma-bond is
(C) LiH,LiAIH 4 (d) NaBH4 , SiF4 allowed but not in case of a pi-bond
O1. Which of the following is a covalent compound?
b) Sigma-bond determines the direction between
(a) AlO3 b) AIF3 carbon atoms but a pi-bond has no primary effect
()AIClg (d) Al,(S04)3 in this regard
of super octet
62. Which of the following is an example (c) Sigma-bond is stronger than a pi-bond
molecule? (d) Bond energies ofsigma and pi- bonds are of the
(a) CIF (b) PCls order 264kJ/mol and 347 kJ/mol respectively
three
(d) All the 173. Select correct statements regardingo and r bonds
theoretically not
Which of the ollowing molecule is (a) a-bond lies on the line joining the nuclei of
possible? bonded atoms
(a) SF (c) OF (d) O2F2 (b) n-electron cloud lies on either side to the line
(b) OF2
4. formula MHPO4.
phosphate of a metal has thebe : joining the nuclei of bonded atoms
e formula of its chloride would (c) (2p3d,) Pi-bond is weaker than
(d) M2Cl (2p. -

3p,)
(a) MCI (b) MCI2 (MCI Pi-bond
65. The com ionic character (d) a-bond has primary effect to decide direction of
mpound that has the highest
covalent bond, while n-bond has no
45$ociated with the X-Cl bond is: primary
(a) PCls (c) CCl (d) SiCl effect in direction of a bond
(b) BCl3
 760 Objective Chemistry for NEET/AT
174. The combination of orbital that cannot produce non 183. Which of the following p-d
AIIMS
overlapping form
form abont
bonding molecular orbital is (inter nuclear axis is (a) px + dyz
Z-axis) (b) py + dyz
x-internuclear axis
y-inter nuclear axis
(a) Py +d2y2 b) P. +dy (c) d2,2 +"2y? z-inter nuclear axis
(c)s+d (d)dy+d (d) pz + dyz
y-inter nuclear axis
175. Which of the following orbital can not formnas well
as a bond ?
Hybridisation, Geometry and VSEPR
(a) dy (b) d, (c) d (d) dye Theory
176. Which of the following combination does not allow
formation of o bond ? 184. Sp -p overlapping is present in
(a) s+ P (b) Py +Py (a) CH-0-H (b) CCl
() dy +d (d) P +d2 (c) NH (d) so,
177. Which of the following combination of orbitals does 185. Geometry of SF is
not form covalent bond (x-axis is internuclear axis) ? (a) Sea-saw (b) r-shape
(a) s+Py (b) Py + Py (c) distorted tetrahedral (d) all of these
(c) dy + dy (d) dyy +dy 186. In which of the following pairs, the
178. Which of the
hybridisation c
following would result in the central atoms is same, but molecular
geometry is n
formulation of strongest n-bond if the molecular axis the same?
is X-axis ?
Ca) SOg,Co3 (b) SO ,NH
(a) 2p, 2px (b) 2py +2Py
(c) 2p, +3dy (d) 2P +4p (c)PCl5,POCI (d) XeF2,ICl
187. Which of the following molecular geometry is
179. Which of the
following orbital combination does not
form -bond ? produced by sp°d hybridisation ??
(a) Px+ Px sideways overlapping (a) Triangular planar (b) Sea-saw
(6) d22 +Py sideways overlapping (c) T shape (d) Linear
(c) d +dy sideways 188. Select
overlapping hybridisation which have non planar geon
(d) dy +P, when all are bond pair, but planar when there a
180. Which of the
sideways overlapping lone pairs on central atom :
following overlaps is incorrect
(assuming Z-axis in inter nuclear axis) ? (a) sp3 (b) sp'd
) 2P, +2p, > TBond formation (c)sp'd2 (d) all of these
(i) 2P, + 2p, > t Bond
formation 189.
Cii) 3d, +3d,
Ifp, and p, orbital participate in sp hybridiston
> T Bond formation
S atom,
iv) 2s +2pP, > 7 Bond
formation
d-orbital involved in mbonding in SO,a
(v) (a) da dye (b) ddad
3d, 3d, a Bond formation
+

(vi) 2P, +2p, >a Bond formation (c) da,dy (d)dydd,

190. In Which of the following molecules no.ot lone
(a) (i), Gi), (ii) (b) (ii), (vi) and bond pairs on central atom are not equa
(c) (i), (v) (d) i), (ii), (iv) (a) H,0 (b) l (c) 0,F, (d)SCl
181. From the following options most effective n-bond is : 191. Molecule in which d-orbitals is no
used

(a) 2pm-3p (b) 3dn 3dr

(c) 2pm-3dn hybridisation?
182. Correct order of extent of
(d) 3dn-3pr (a) I (b) ICl (c) ICl
(d) POCT;

overlapping is 192. Lone

pair bond pair
(a) Is 1s <2s-2s< 2s-2p repullsion is maximu
(a) BrF (b) SE
(d) SF
(b) 2p-2p (axial) 2p 2p (c) PF
(colateral)
<

193. Which of the set

hybridisath

(c) 1s-1s> 2s -2p (axial) >

2s-2p >2s-2s state but
of species have sane
different shapes ?
(d) 1s 1s> 2s 2p> 25-2s> 2p -2p (axial)
(a) NO,NO,, NO (b) ClO,,SF,,XeP
(c) (d) so,",PO,',CIO
NH,H ,O' ,OF,
ohemical Bonding
which of the
following set
N.O,03.NH,
(b) H,0,NO, all have
is
not
correct?
(c) I3,ICl,N
all are V coordinate bonds 204. In
all are shape molecules which of the
following compounds
761)
SF,SiF,X are linear molecules
(d) angles (F-E-F; where
according to VSEPR E = all
central element) theare bond
195. Which of the
following tetrahedral
have same in shape
(a) XeF theory? 90
() ICl i) (c) SF b) XeFs
(a) ) and (i)
SO ii) SnCl shape ? 205. Which
of the (d) None
these of
(iv) XeF2 (a) d following statement is wrong?
c)) and (iv) (b) (ii) and
(iv)
orbital taking part in dsp is
196. Which of the () andd) (b) dorbital da
not involve in following (ii)
orbital of central (c) dorbitals
taking part in sp'd is
d,
(a) da
bonding in XeO F atom does taking part in sp d is
6) d molecule ? (d) d
d, and d
97. In which of the following set,(c)thedy ) da d
orbitals taking part in sp d is
d,.d, and
member involves sp° central atom of 206. ,2
hybridization? each In whichspecies number of lone
(a) 10,1Cl, and IF number of d-orbitals used pair on iodine and
b) XeO,XeO4,XeF is same? in
hybridisation by iodine
)SO,S0,so (d) PCI,BF ,Clo (a) ICl (b) ICl (c) IF
198. Which is not correcdy matched ? 207. Select in which
both have sea-saw
(d) ICI
(a) Xe0Trigonal bipyramidal (a) Xe0,F2, SiF shape ?
b) XeO F,SF
(b) CIF-bent T-shape () TeCl,,IC
(d) TeCl, XeOF2
c)XeOF -Square pyramidal 208. Out of
Ng,l.l
and 0, the linear species is/are :
(d) XeF-Linear (a) Ng and 1
199. Which of the (b) I, and O
following possess two lone pairs at (c)Ng and 1 (d) N.I and I5
central atom and has
square planar shape ? 209. In which of the
following compound (s) F atom(s)
a) SF (b) XeO (c)CIF3 d) 1Cl occupy any position around central atom?
can

400. In the structure of IF, (lodine heptafluoride). (a) SF b) CH F (c) BrF

210. Specifiy the hybridisations of central atom the
(d)PCI,F
Incorrect statement is: in

(a) dyd22,d2 orbitals are involved in following species respectively {Ng NOCI, N,0}:
hybridisátion (a) sp,sp.sp b) sP.Sp.sp
of
equatorial
than bonds (c) sp,sp,sp
D) axial bonds
are longer (d) sp.spsp
)there are 10 different orthogonal angles 211. VSEPR theory does not state
:
a) the resultant geometry is a decahedral (a) the order of repulsion between different pair of
same hybridization,
shape electrons is lp-p>lp - bp> bp - bp (lp lone
airs ne molecules having the of electrons . pair electrons, bp = bond pair electrons)
and number of lone pairs
(b) as the number of lone pair of electrons on central
a) SeF, Xe0F2 (b) SeF,,XeF2 atom increase, the deviation in BA from normal
(d) SeCl,,XeF,
(c) XeOF, TeFa BA (Bond Angle) also increase
all show trigonal
202. Seler of species in which (c) the number of lone pair on O in H,O is l while on
Ct the group N is NH, is 2.
bipyramidal geometry (b) CIO,,IF,Co (d) the structure Xenon-tluorides and
(a) PF,JF5, XeF Xenon oxyfluorides could be explained on the
(d) XeF,
PE, ,IC
(c) , XeF2, SF4 the X Y Plane, basis of VSEPR theory.
is
203. equatorial molecule

212. Which of the tollowing statement is not correct

plane in PCI, produce
bonds
axial
EIon
is maxiinum.
he orbital hybridizing to (a) Lone pair-lone pair repulsion
(b) d, ,dy (b) Lone pair and double bond occupy
equatorial
(a) P,,d
(d) d,,du position in trigonal bipyramidal
structure.

(c) Py Px
 762 Objective Chemistry for NEET/AT
(c) More electronegative atoms occupies axial Column-I AIIMS
position in trigonal bipyramidal structure. Column-II
(d) Bigger atoms occupy axial positions in trigonal (A) SF4 (1) Tetrahedral
bipyramidal structure. (B) BrF'3 (2)
213. In which of the following molecule central atom use Pyramidal
equivalent orbitals for each bond formation? (C) BrOs (3) Sea-saw shaped
(a) H,0 (b) AsCls (D) NH4 (4) Bent T-shaped
(c) IF d) SF4
214. Which of the following species contains minimum Code:
number of atoms in 'XY plane? (a) A (3) B (2) C (1) D (4)
(a) XeF (b) SF6 (c)IF (d) PCls (b) A (3) B (4) C (2) D (1)
215. Which of the following molecular shape d.,-orbital (c) A (1) B (2) C (3) D (4)
must not be involved in bonding ?
(d) A (1) B (4) C (3) D (2)
(a) Pentagonal planar (6) Trigonal planar
223. In which of the following pairs, the number of
(c)Linear (d) Square planar and molecular
216. Assuming pure 2s and 2p orbitals of carbon are used
pairs geometry same?
in forming CH4 molecule, which of the (a) TeCl4,P"Cl4 (b) NO3,PCl
following
statement is false ? (c)SiCl4 , BF4 (d) BrFs,XeFs
(a) Three C- H bonds will be at right angle 224. Which of the following molecule has
(b) One C- H bond will be weaker than other three triangular geometry ? equilater
C- H bonds (1) CIF (11) COF2 (II) BF3 (TV) Xe0
(c) The shape of molecule will be tetrahedral (a) I, II, IlI (b) I1, III
(d) The angle of C-H bond formed
by s-s (c) III only (d) 1, II, IV
overlapping will be uncertain with respect to 225. In which of the
other three bonds. following, all fluorine atoms are notir
217. Which molecule has both same plane?
shape and geometry (a) XeF
identical? (b) SF
(a) SnCl2 (b) PCls (c) CF (d) XeOF
(c)XeF4 (d) ICl3 226. After the hybridisation of central atom in
218. If in XeF2 molecule the t
angle between two lone pair formation of SF4 , which set of d-orbitals remainpur
obitals in a, the angle between lone
pair orbital and
bond pair orbital is ß and the
angle between bond pair (a) d2,d,2y2 (6) d,22,dydd
orbitals isy: (c) d2,dy,d,a,d, (d) d, ,dy d Only
(a) a =B=y (b) a>B>Y 227. The shape of[IF,] and[CIF,] ions isrespectve
(c) Y>B>a d) y>a>B (a) See-saw and linear
219. Which of the
following species used both axial set of (b) See-saw and bent
d-orbitals in
hybridisation of central atom ? (c) Tetrahedral, linear
(a) PBr (b) PCI (c) ICi (d) CIF3 (d) Square planar and linear
220. Which of the
following
pT dr bonding?
elements can be involved in 228. Which of the following molecules/species na
minimum number of total lone pairs ?
(a) Carbon (d) Xef,
(b) Nitrogen (a) ICl (b) BE (c)SnCl
(c) Phosphorus (d) Boron
shape i
229. Which of the following pair has the same
221. Which of the following pairs of ions are isoelectronic different hybridisation ?
and isostructural ?
(a) SO.CO (b) BeCl. HCN
(a) CO,NO2 (b) ClO3,C0
(c) NO.cIo, (d) XeF2, SnCl
(c)so3 ,No (d) CIo,SOo 230. The incorrect statement
regarding

222. Match of the species given in Columns I with

the hybridisation (O oneanothe"

shape given in column lI and mark the correct (a) All sp'd* hybrid orbitals are at 90° to one
option:
themical Bonding 763
total twelve 90° state is:
There are
angles in perfect 239. Incorrect match hybridisation
of
octahydral geometry (a) H4Xe0, - sp*d (b) N sp
c)All orbitals lengths are identical
(c) I spd
(d)PO-sp3
d) All orbitals are having equal energy central atom is sp
in which
240. Pair of species
Which ofthe following molecule is not planar?
81.
(b) XeF hybridised?
(a) CIF (b) CIO,CIO
(a) CH3,CF3
(c) XeF (d) NO,Cl (d) CIO2,NO2
(c) NO set with
Which of the following has different hybridisation the correct
232.
241. Which one of the following is
thanother? and shape ?
respect to molecule, hybridization
(a) Br3 (b) XeOs
(a) BeCl2, sp", linear
(c) SeCl4 (d) AsF planar
(b) BeCl2, sp, triangular
In which of the following species are planar
?
283. (c) BCl3, p , triangular planar
(a) 15.XeF2.CIF, (b) tetrahedral
(d) BCl3, sp*,
is:
H0,0Cl,ICI2 242. The hybridization of the central
atom in ICl,
()XeF3,XeF,,BF3 (d) All are correct d) sp*
(a) dsp (b) sp (c) sp
Which of the following pair, geometry is same ??
of the central atom is not
234. 243. The state of hybridization
(a) SeF,XeF5,IFs (b) SF4,F, XeOF4 ,PCl the same as in the others:
(b) O in H,0
(c)SF6,PF,,SiF (d) COCl2, SOCl2,XeOF2 (a) B in BF3
s-character (in (d) P in PCl
235. The correct order of increasing (c) Nin NH3
of following the central atom will changee
244. The hybridization of
hybrid orbitals
percentage) in the
when
molecule/ion is:
(0) CO (11) XeF4 (II) I (IV) BeCl2 (a) NH combines with H*

(a) II < IlI< IV<I<V

(b) II< V< IlI < V <I (b) H3BO, combines with OH
(d) II< V < III < I <V
(c) IlI<I <I<V< IV
not correctly
(c)NH forms NH2
of the following species
are
Z36. Which
(d) H0 combines with H*
according to the VSEPR
matched with the geometries
245. CH3-CH2-CH=CH,
has hybridisation:
theory? b) sp*,sp°,spsp
(a) sp, sp, sp , sp*
(a) BrF>Octahedral
(6) SnCl» Trigonal bipyramidal (c)sp,sp,sp,sp (d) sp,sp,sp*, sp
hybridisation of Xe in cationic
246. What is the state of
(c) CIF Linear part of solid XeF6?
(d) IF> Tetrahedral (a) spd3 (b) sp'd2 (c)sp'd (d) sp3
molecule, all P-Cl bond
nwhich of the following 247. The hybridisation of central iodine atom in
length are identical ? IFs, I and 13 are respectively
(a) PF,Cl2 (b) PCl3
these (a) sp'd2, sp'd, sp3 (b) sp'd, sp$d, sp3
(c) PCI F2 (d) All of
238. about hybridisation
is :
(c) sp'd*, sp°d*, sp* (d) spd, sp^d2, sp3
Incorrect statement

a) It is an endothermic process 248. Which of the following species uses both axial set of
with
orbitals
increases
d-orbitals in hybridisation of central atom ?
Energy of hybrid
decreasing S-character
can not
(a) PBr (b) PCI
electrons
Orbitals having paired (c) ICl4 (d) None of these
participate in hybridisation
orbitals mainly 249. The H-0-H bond angles
Electronic of hybrid
geometry
which participate
in
H,O are

epends upon type

of orbitals approximately 107°. The orbitals used
thesebonds are best described as:
by oxygen in
in hybridisation
 764 Objective Chemistry for NEET/A
(a) p-orbitals (b) sp-hybrid orbitals 260. The geometrical arrangement of orbitals AlUMS
(c) sp-hybrid orbital (d)sp -hybrid orbital I3arerespectively and shae
an

250. Among given species identify the isostructural pairs: (a) trigonal bipyramidal geometry, linear eh
(a) [NFand BF (b) (b) hexagonal geometry, T-shape shape
[BF and NH1 (c) triangular planar geometry, triangular
(c) [BCl and BrCl,] (d) [NH and NO3] (d) tetrahedral geometry, pyramidal shane hape
261. Which of the following statements is
251. Phosphorus pentachloride in the solid exists as:
PCI,? incorren
(a) PCl (b) PCICI (a) Its three P-Cl bond lengths are
equal
(c) PCIPCl (d) PCls Cl2 (b) It involves sp'd hybridization
252. Bonds present in N,05 (nitrogen pentaoxide) are: (c) It has an regular geometry
(a) only ionic (d) Its shape is trigonal bipyramidal
(b) only covalent 262. Molecular shapes of SF4, CE and
(c) covalent and co-ordinate
XeF, are:
(a) the same with 2,0 and 1 lone
pair of electr
(d) covalent and ionic respectively
253. Number of S-S bond is H,S,O, (b) the same, with 1,1 and 1 lone pair of
(a) n (b) (n -1) (c) (n -2) (d) (n + 1)
electrons
respectively
254. Number of identical Cr-O bonds in dichromate ion (c) different, with 0,1 and 2 lone pair of electror
Cr,0 is: respectively
(a) 4 (b) 6 (c) 7 (d) 8 (d) different with 1,0 and 2 lone pair of electron
255. Which of the following are isoelectronic and respectively
isostructural ? 263. The molecule exhibiting maximum number o
NO3, CO, ClO, S0 non-bonding electron pairs (1.p.) around the cenri
(a) NOg,CO (b) SO3,NO3
atom is:
(a) XeOF (b) XeOF2
(c) ClOg,CO (d) co,clO
256. Which of the following xenon compound has the
(c)XeF3 (d) XeO
264. Which is the following pairs of species have dentcz
same number of lone pairs as in
Ia?
shapes?
(a) XeO4 (b) XeF4 (c) XeF2 (d) XeO (a) NO and NO2 (b) PCl5 and BrFs
257. The shape of XeF3 is:
(c)XeF and ICl (d) TeCl, and Xe0
(a) Trigonal planar (b) Pyramidal
265. The shapes of XeF, XeF; and SnCl, are
(c) Bent T-shape (d) See-saw
(a) octahedral, trigonal bipyramidal and bent
258. SbF reacts with
XeF and XeF6 to form ionic
(6) square pyramidal, pentagonal planar and i
compounds [XeF3 ][SbF,] and [XeF3 1[SbF, ] then
molecular shape of [XeF; ] ion and
[XeF5] ion (C)square planar, pentagonal planar and angu
respectively (d) see-saw, T-shaped and linear
(a) Square pyramidal, T-shaped 266. Amongst NO, AsO,co2,Clog,s0; and
(b) Bent-T-shape, square pyramidal the non-planar species are
(c) See-saw, square pyramidal (a) co ,so ,BO (b) AsO clO,SO;
(d) Square pyramidal, see-saw (d) so,NO;, BO;
(c) NO,Co,BO
259. Correct statement regarding molecules SF4, CF order of initials T or F for tolo
and 267. Give the correct Fift
XeF4 are: Statements. Use T if statement is true and
(a) 2, 0 and 1 lone pairs of central atom
respectively false
(b) 1,0 and 1 lone pairs of central atom respectively () The order of repulsion between difteren
(c) 0,0 and 2 lone pairs of central atom respectively electrons isl, -1, >1, -b, > b, -D,
(d) 1,0 and 2 lone pairs of central atom respectively
 ( 765)
hemical Bonding (d) H02
(c) HS
the number of lone pair of electrons
(a) SOCl2 (b) CO
MS (11) In
general,,
increases, value of bond angle
on central atom
Bond Strength,
Bond Length,
pe of from normal bond angle also increases Formal Charge
of lone pair on O in H20 is 2 while Resonance and in NO,
1on

) The number and oxygen

is 1 nitrogen
on N
in NH3 278. Formal charge
on

structures of xenon fluorides and xenon

( The arerespectively
could not be explained the basis
OXyfluorides on

(a) O,
(b) +1,3
of VSEPR theory -2
(d) TFFF
orrect (a) TTTF
(b) TFTF (c) TFTTT
(c)+1,
(d) O,3 is :
of the IBr2 ion? bond length
is the geometry
68, What
b8.

compound having
shortestS O
279. The
(a) Linear (b) SO
shape with bond angle of about 90 (a) SOF
(b) Bent (d) SOCl2
with bond angle of about 109 (c) SOF 1S
(c)Bent shape bond energy

with bond angle of about 120 280. The

bond having the highest
(d) Bent shape
(b) C = S
molecule? (a) C C
What is the shape ofthe ClF, (d) P = N
269. b) Trigonal pyramidal (c) C= O C --Cl bond
trons (a) Trigonal planar molecule, the
(d) Tetrahedral 281. In which
of the following
(c)Tshaped ?
will be greatest
length
rons,
Which species has
the same as NH,?
shape (b) CH,Cl
270. (c) NO, (d) SO (a) CH,C (d) CF,Cl2
(a) SO (b) Co
rons, do all (c) CHC has unequal
bond
theory, in which species
VSEPR the following
molecules

271. According to
282. Which of
in the s a m e plane?
rons, theatoms lie length?
(c) PF5 (d) SF,
2. CH3 (b) PF3
1. CH (a) BF S- F bond length are

(b) 2 only molecule all

er of (a) 1 onlyy 2 283. In which
neither 1 nor
entral (d) identical?
(c)both 1 and 2 (b) H,C = SF4

is assumed by (a) SF
272. Linear structure (11) CS2 (d) OSF2
() NCO (c) OSF
bond length:
(IV) Solid BeH2 284. Correct
order of given
ntical (I11) NO2
(b) (1), II)
and (IV O-N
(a) all four
(d) (11)
and (111) wo
(c) (), (ITD) and (II1) and NO2, X Y W>z

of nitrogen, N20, NO (a) w> x =z> y(b)

0.
Among the oxides are : x> W =Z> y
molecules with
electrons
unpaired (C) x>z>y =w(d)
NO2 but has bond
(b) NO and no pt pt bond -

(a) NO and NO dimer 285. The species having

and its order equal to that of O2
(d) NO2
(c)NO and NO2 network
(c) So (d) XeO
near
pair
consists of only (a) ClO PO
(b)
lar *Which of the following dissociation energy will
order of bond
solid ? 286. The inocrrect
(b) P4O 10 ,SO3
(a) SiO2.P,O 10 be
30 (d) Diamond, Sio B r - Br
have S - S (a) H-H>Cl-Cl >
(C)PO10.P,O6 ions
does not
P - P> C l - Cl
275. Which following (b) S i - Si>
ich of
the
N>0-0
linkage? (d) S,03 (c) C-C>N-
S06 (c) S,0 (d) H-Cl>H- Br H - I >
(a) S,0 (b)
and NO2,
unpaired
bond lengths are
276Among 287. In which of the following option, all
Wins
CaO2
fit
js KO,,KAIO2,
not equal ?
electron is present in KAlO,
(b) KO2
and
(a) BF (b) NF (c) XeF4 (d) ClF
airof (a) NO and CaO2 (d) CaO2 only
(c) KO only
277. Structure of S,Cl, is
analogous
to: