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TUGAS 3 KESFAS A - 05191056 - Pradhitya Dwijati Wibowo

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Arlie

The document contains experimental data for a binary system including pressure (P), mole fractions (x1, x2), activity coefficients (lnγ1, lnγ2), and excess Gibbs energy (GE/RT) at different compositions and pressures. It also shows fitted models for the Margules and Van Laar equations to the experimental data with R2 values reported. Plots compare the experimental P-x data to predictions from the Margules and Van Laar models.

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© All Rights Reserved
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TUGAS 3 KESFAS A - 05191056 - Pradhitya Dwijati Wibowo

Uploaded by

Arlie
25 views10 pages
The document contains experimental data for a binary system including pressure (P), mole fractions (x1, x2), activity coefficients (lnγ1, lnγ2), and excess Gibbs energy (GE/RT) at different compositions and pressures. It also shows fitted models for the Margules and Van Laar equations to the experimental data with R2 values reported. Plots compare the experimental P-x data to predictions from the Margules and Van Laar models.

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TUGAS 3 KESFAS A_05191056_Pradhitya Dwijati Wibowo

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The document contains experimental data for a binary system including pressure (P), mole fractions (x1, x2), activity coefficients (lnγ1, lnγ2), and excess Gibbs energy (GE/RT) at different compositions and pressures. It also shows fitted models for the Margules and Van Laar equations to the experimental data with R2 values reported. Plots compare the experimental P-x data to predictions from the Margules and Van Laar models.

Copyright:

© All Rights Reserved
Download as XLSX, PDF, TXT or read online from Scribd
Download as xlsx, pdf, or txt
25 views10 pages

TUGAS 3 KESFAS A - 05191056 - Pradhitya Dwijati Wibowo

Uploaded by

Arlie
The document contains experimental data for a binary system including pressure (P), mole fractions (x1, x2), activity coefficients (lnγ1, lnγ2), and excess Gibbs energy (GE/RT) at different compositions and pressures. It also shows fitted models for the Margules and Van Laar equations to the experimental data with R2 values reported. Plots compare the experimental P-x data to predictions from the Margules and Van Laar models.

Copyright:

© All Rights Reserved
Download as XLSX, PDF, TXT or read online from Scribd
Download as xlsx, pdf, or txt
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P x1 x2 y1 y2 ln γ1 ln γ2 GE/RT

P2 sat 55.5269 0 1 0 1
50.2680 0.10 0.90 0.009479 0.990521 (0.4643) (0.0037) (0.0497)
44.7421 0.2 0.8 0.022815 0.977185 (0.3956) (0.0159) (0.0918)
39.0281 0.3 0.7 0.042014 0.957986 (0.3271) (0.0388) (0.1253)
33.2433 0.4 0.6 0.070328 0.929672 (0.2601) (0.0751) (0.1491)
27.5461 0.5 0.5 0.113136 0.886864 (0.1958) (0.1279) (0.1618)
22.1331 0.6 0.4 0.179355 0.820645 (0.1361) (0.2012) (0.1621)
17.2274 0.7 0.3 0.283398 0.716602 (0.0833) (0.2996) (0.1482)
13.0546 0.8 0.2 0.44616 0.55384 (0.0404) (0.4292) (0.1182)
9.80411 0.9 0.1 0.688254 0.311746 (0.0110) (0.5970) (0.0696)
P1 sat 7.58076 1 0 1 0

-0.0000
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
(0.1000)

(0.2000)

(0.3000)

(0.4000)

(0.5000)

(0.6000) f(x) = − 0.275243165566157 x − 0.516330894112269


R² = 0.993379126101186
(0.7000)

(0.8000)

(0.9000)

GALAT
ϒ1* ϒ2* P* y1* y2* x1* x2* ∑∆P2
0.5967 1.0000 55.5269 0.0000 1.0000 0.0000 1.0000 0.0000
0.6295 0.9970 50.3037 0.0095 0.9905 0.1000 0.9000 0.0013
0.6697 0.9861 44.8173 0.0227 0.9773 0.2000 0.8000 0.0057
0.7161 0.9641 39.1021 0.0417 0.9583 0.3000 0.7000 0.0055
0.7671 0.9289 33.2720 0.0699 0.9301 0.4000 0.6000 0.0008
0.8205 0.8789 27.5114 0.1130 0.8870 0.5000 0.5000 0.0012
0.8733 0.8141 22.0539 0.1801 0.8199 0.6000 0.4000 0.0063
0.9221 0.7357 17.1484 0.2853 0.7147 0.7000 0.3000 0.0062
0.9625 0.6465 13.0171 0.4484 0.5516 0.8000 0.2000 0.0014
0.9899 0.5507 9.8120 0.6883 0.3117 0.9000 0.1000 0.0001
1.0000 0.4532 7.5808 1.0000 0.0000 1.0000 0.0000 0.0000
0.0284

60 Data Eksperimen VS Margules Model (P-xy diagram)


50

P-xi
40
p-yi
P-xi
)
60 Data Eksperimen VS Margules Model (P-xy diagram)
50

P-xi
40
p-yi
P-xi
P (kPa)
30 Margules+Barker
P-yi
Margules+Barker
20

10

0
0 0.2 0.4 0.6 0.8 1 1.2
x1* ; y1*
GE/x1x2RT

(0.5526)
(0.5739)
(0.5967)
(0.6212)
(0.6474)
(0.6755)
(0.7058)
(0.7385)
(0.7739)

y= -0,2752x - 0,5163
GE/x1x2RT = -0,2752x - 0,5163

A12 = -0.5163
A21 = -0.7915
P x1 x2 y1 y2 ln γ1 ln γ2 GE/RT
P2 sat 55.5269 0 1 0 1
50.2680 0.10 0.90 0.009479 0.990521 (0.4643) (0.0037) (0.0497)
44.7421 0.2 0.8 0.022815 0.977185 (0.3956) (0.0159) (0.0918)
39.0281 0.3 0.7 0.042014 0.957986 (0.3271) (0.0388) (0.1253)
33.2433 0.4 0.6 0.070328 0.929672 (0.2601) (0.0751) (0.1491)
27.5461 0.5 0.5 0.113136 0.886864 (0.1958) (0.1279) (0.1618)
22.1331 0.6 0.4 0.179355 0.820645 (0.1361) (0.2012) (0.1621)
17.2274 0.7 0.3 0.283398 0.716602 (0.0833) (0.2996) (0.1482)
13.0546 0.8 0.2 0.44616 0.55384 (0.0404) (0.4292) (0.1182)
9.80411 0.9 0.1 0.688254 0.311746 (0.0110) (0.5970) (0.0696)
P1 sat 7.58076 1 0 1 0

-0.

(0.2...

(0.4...

(0.6...

(0.8...

(1.0...

(1.2...

(1.4... f(x) = 0.647081573374124 x − 1.870840136257


R² = 0.999808072174016
(1.6...

(1.8...

(2.0...

GALAT
ϒ1* ϒ2* P* y1* y2* x1* x2* ∑∆P2
0.5859 1.0000 55.5269 0.0000 1.0000 0.0000 1.0000 0.0000
0.6196 0.9969 50.2900 0.0093 0.9907 0.1000 0.9000 0.0005
0.6607 0.9855 44.7795 0.0224 0.9776 0.2000 0.8000 0.0014
0.7082 0.9628 39.0327 0.0413 0.9587 0.3000 0.7000 0.0000
0.7605 0.9264 33.1691 0.0695 0.9305 0.4000 0.6000 0.0055
0.8152 0.8749 27.3805 0.1129 0.8871 0.5000 0.5000 0.0274
0.8695 0.8083 21.9087 0.1805 0.8195 0.6000 0.4000 0.0504
0.9197 0.7281 17.0090 0.2869 0.7131 0.7000 0.3000 0.0477
0.9613 0.6372 12.9064 0.4517 0.5483 0.8000 0.2000 0.0219
0.9896 0.5400 9.7505 0.6925 0.3075 0.9000 0.1000 0.0029
1.0000 0.4417 7.5808 1.0000 0.0000 1.0000 0.0000 0.0000
0.1577

60 Data Eksperimen VS Van Laar Model (P-xy diagram)


50

40 P-xi
p-yi
60 Data Eksperimen VS Van Laar Model (P-xy diagram)
50

40 P-xi
P (kPa) p-yi
30 P-xi Van
Laar+Barker
P-yi Van
20 Laar+Barker

10

0
0 0.2 0.4 0.6 0.8 1 1.2
x1* ; y1*
GE/x1x2RT x1x2RT/GE

(0.5526) (1.8098)
(0.5739) (1.7423)
(0.5967) (1.6758)
(0.6212) (1.6098)
(0.6474) (1.5447)
(0.6755) (1.4803)
(0.7058) (1.4167)
(0.7385) (1.3541)
(0.7739) (1.2922)

y= 0,6471x - 1,8708
x1x2RT/GE= 0,6471x - 1,8709

A12 = -1.8708
A21 = -1.2237

A12' = -0.5345
A21' = -0.8172
P x1 x2 y1 y2 ln γ1 ln γ2 GE/RT
P2 sat 55.5269 0 1 0 1
50.2680 0.10 0.90 0.009479 0.990521 (0.4643) (0.0037) (0.0497)
44.7421 0.2 0.8 0.022815 0.977185 (0.3956) (0.0159) (0.0918)
39.0281 0.3 0.7 0.042014 0.957986 (0.3271) (0.0388) (0.1253)
33.2433 0.4 0.6 0.070328 0.929672 (0.2601) (0.0751) (0.1491)
27.5461 0.5 0.5 0.113136 0.886864 (0.1958) (0.1279) (0.1618)
22.1331 0.6 0.4 0.179355 0.820645 (0.1361) (0.2012) (0.1621)
17.2274 0.7 0.3 0.283398 0.716602 (0.0833) (0.2996) (0.1482)
13.0546 0.8 0.2 0.44616 0.55384 (0.0404) (0.4292) (0.1182)
9.80411 0.9 0.1 0.688254 0.311746 (0.0110) (0.5970) (0.0696)
P1 sat 7.58076 1 0 1 0

GALAT
ϒ1* ϒ2* P* y1* y2* x1* x2* ∑∆P2
1.0000 1.0000 55.5269 0.0000 1.0000 0.0000 1.0000 0.0000
1.0000 1.0000 50.7323 0.0149 0.9851 0.1000 0.9000 0.2156
1.0000 1.0000 45.9377 0.0330 0.9670 0.2000 0.8000 1.4294
1.0000 1.0000 41.1431 0.0553 0.9447 0.3000 0.7000 4.4730
1.0000 1.0000 36.3484 0.0834 0.9166 0.4000 0.6000 9.6419
1.0000 1.0000 31.5538 0.1201 0.8799 0.5000 0.5000 16.0619
1.0000 1.0000 26.7592 0.1700 0.8300 0.6000 0.4000 21.4009
1.0000 1.0000 21.9646 0.2416 0.7584 0.7000 0.3000 22.4411
1.0000 1.0000 17.1700 0.3532 0.6468 0.8000 0.2000 16.9364
1.0000 1.0000 12.3754 0.5513 0.4487 0.9000 0.1000 6.6114
1.0000 1.0000 7.5808 1.0000 0.0000 1.0000 0.0000 0.0000
99.2117

60 Data Eksperimen VS Margules Model (P-xy diagram)


50

P-xi
40
p-yi
P-xi
P (kPa)

30 Margules+Barker
P-yi
Margules+Barker
20

10

0
0 0.2 0.4 0.6 0.8 1 1.2
x1* ; y1*
GE/x1x2RT

(0.5526)
(0.5739)
(0.5967)
(0.6212)
(0.6474)
(0.6755)
(0.7058)
(0.7385)
(0.7739)

y = -0,2752x - 0,5163
GE/x1x2RT = -0,2752x - 0,5163

A12 = 0
A21 = 0

ram)

es+Barker

es+Barker

1.2
P x1 x2 y1 y2 ln γ1 ln γ2 GE/RT
P2 sat 55.5269 0 1 0 1
50.2680 0.10 0.90 0.009479 0.990521 (0.4643) (0.0037) (0.0497)
44.7421 0.2 0.8 0.022815 0.977185 (0.3956) (0.0159) (0.0918)
39.0281 0.3 0.7 0.042014 0.957986 (0.3271) (0.0388) (0.1253)
33.2433 0.4 0.6 0.070328 0.929672 (0.2601) (0.0751) (0.1491)
27.5461 0.5 0.5 0.113136 0.886864 (0.1958) (0.1279) (0.1618)
22.1331 0.6 0.4 0.179355 0.820645 (0.1361) (0.2012) (0.1621)
17.2274 0.7 0.3 0.283398 0.716602 (0.0833) (0.2996) (0.1482)
13.0546 0.8 0.2 0.44616 0.55384 (0.0404) (0.4292) (0.1182)
9.80411 0.9 0.1 0.688254 0.311746 (0.0110) (0.5970) (0.0696)
P1 sat 7.58076 1 0 1 0

GALAT
ϒ1* ϒ2* P* y1* y2* x1* x2* ∑∆P2
1.0000 1.0000 55.5269 0.0000 1.0000 0.0000 1.0000 0.0000
1.0000 1.0000 50.7323 0.0149 0.9851 0.1000 0.9000 0.2156
1.0000 1.0000 45.9377 0.0330 0.9670 0.2000 0.8000 1.4294
1.0000 1.0000 41.1431 0.0553 0.9447 0.3000 0.7000 4.4730
1.0000 1.0000 36.3484 0.0834 0.9166 0.4000 0.6000 9.6419
1.0000 1.0000 31.5538 0.1201 0.8799 0.5000 0.5000 16.0619
1.0000 1.0000 26.7592 0.1700 0.8300 0.6000 0.4000 21.4009
1.0000 1.0000 21.9646 0.2416 0.7584 0.7000 0.3000 22.4411
1.0000 1.0000 17.1700 0.3532 0.6468 0.8000 0.2000 16.9364
1.0000 1.0000 12.3754 0.5513 0.4487 0.9000 0.1000 6.6114
1.0000 1.0000 7.5808 1.0000 0.0000 1.0000 0.0000 0.0000
99.2117

60 Data Eksperimen VS Van Laar Model (P-xy diagram)


50

40 P-xi
p-yi
P (kPa)

30 P-xi Van
Laar+Barker
P-yi Van
20 Laar+Barker

10

0
0 0.2 0.4 0.6 0.8 1 1.2
x1* ; y1*
GE/x1x2RT x1x2RT/GE

(0.5526) (1.8098)
(0.5739) (1.7423)
(0.5967) (1.6758)
(0.6212) (1.6098)
(0.6474) (1.5447)
(0.6755) (1.4803)
(0.7058) (1.4167)
(0.7385) (1.3541)
(0.7739) (1.2922)

y= 0,6471x - 1,8708
x1x2RT/GE= 0,6471x - 1,8709

A12 = -1.8708
A21 = -1.2237

A12' = 0
A21' = 0

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