Fiitjee All India Test Series: Concept Recapitulation Test - Ii

FIITJEE
ALL INDIA TEST SERIES

CONCEPT RECAPITULATION TEST – II
JEE (Advanced)
PAPER – 1
Time Allotted: 3 Hours Maximum Marks: 180
General Instructions:
 The test consists of total 54 questions.
 Each subject (PCM) has 18 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Two Sections: Section-A & Section-D.
1. Section-A (01– 06, 19 – 24, 37 - 42) contains 18 multiple choice questions which have one or
more than one correct answer. Each question carries +4 marks for all correct answer.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both
of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.
Section-A (07 – 10, 25 – 28, 43 - 46) contains 12 questions. Based on this section contains TWO
(02) paragraphs. Based on each paragraph, there are TWO (02) questions.
Each question has only one correct answer and carries +3 marks for correct answer and –1 mark
for wrong answer.
2. Section-D (11 – 18, 29 – 36, 47 – 54) contains 24 Numerical answer type questions with answer
XXXXX.XX and each question carries +3 marks for correct answer. There is no negative marking.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/19 2
Physics PART – I
SECTION – A
(One or More than one correct type)
This section contains 6 questions. Each question has FOUR options (A), (B), (C) and (D). ONE
OR MORE THAN ONE of these four options is(are) correct.
1. Two particles A and B, each carrying a charge Q, are held fixed with a separation d
between them. A particle C having a mass m and charge –q, in kept at the middle point
of line AB.
It displaced through a distance x perpendicular to AB. Assume x << d. Then:
(A) Force experienced by C is proportional to x
(B) Force experienced by C is proportional to d
1/2
 m3 0 d3 
(C) Particle C may execute SHM with time period  
 qQ 
1/2
 m2 0 d2 
(D) Particle C may executes SHM with time period  
 qQ 
2. If the potential difference of Coolidge tube producing X-ray is increased, then choose the
correct option(s).
(A) the interval between k and k increases
(B) the interval between k and  0 increases
(C) the interval between k and  0 increases
(D)  0 does not change
Here  0 is cut off wavelength and k and kB are wavelength of k  and k B
characteristic X-rays.
3. For a single material

(A) its absorptive power and emissivity, have equal magnitude
(B) molar specific heat capacity is proportional to its specific heat capacity.
(C) mass is proportional to number of moles.
(D) density is proportional to volume of material.
Space for Rough work
3 AITS-CRT-II (Paper-1)-PCM-JEE(Advanced)/19
4. A container of large uniform cross sectional area A

A resting on a horizontal surface holds two
immiscible non viscous and incompressible liquids
of density d and 3d, each of height H/2. The lower H/2 d
density liquid is open to the atmosphere having
pressure P0. A tiny hole of area a(a<<A) is
punched to the vertical side of lower container at a H/2 3d
h
height h (0<h<H/2) for which range is maximum.
(A) h = H /3
2H
(B) Range R = Range R
3
3H
(C) Range R =
2
2
(D) Velocity of efflux v  gH
3
5. A uniform thin rod PQ of length ‘L’ is moving in a

uniform magnetic field B0 such that velocity of its ×B × × × ×
0
× × × × ×
4v × × × × ×
centre of mass is v and angular velocity is   .
L × × × ×V ×
Then × × × × ×
× × × Q × ×
(A) e.m.f. between end P and end Q of the rod is
B0 l v
(B) end P of the rod is at higher potential than end Q
of the rod
(C) end Q of the rod is at higher potential than end P
of the rod
(D) the electrostatic field induced in the rod has same
direction at all points along the length of rod.
6. There is an infinite long straight surface having width ‘a’. A point charge 
a
q is placed at a perpendicular distance from the surface symmetrically
2
a
as shown in the figure. If the flux linked with this infinitely long surface
q
due to charge q is . Then find the value of k is q
k0 a
(A) 6 (B) 4 2
(C) 2 (D) 12
(Paragraph Type)
This section contains TWO paragraphs. Based on the paragraph, there are TWO questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
correct.
Paragraph for Question Nos. 7 and 8
In the circuit shown in figure, R1 = R2 = R3 = 3 and e.m.f. of each cell E

A3
is E = 4V and negligible internal resistance. All ammeters are ideal.
Match the following:
b R1 c
E a E
A2 A1
R3
R2
7. Reading of ammeter A1 in ampere is

(A) 2/3 (B) 4/3
(C) 1 (D) 4
8. Reading of ammeter A2 in ampere is

(A) 8/3 (B) 1/3
(C) 1 (D) 2
m, 
Smooth, horizontal surface
9. The thin rod is released from the vertical position as shown, and falls by itself, then
angular speed of the rod just before it falls flat, will be
g 3g
(A) (B)
 
4g 6g
(C) (D)
 
10. KE of the rod, just before it falls flat, will be


(A) mg (B) mg
2
 
(C) mg (D) mg
4 6
SECTION – D
(Numerical Answer Type)
This section contains EIGHT questions. The answer to each question is a NUMERICAL
VALUE. For each question, enter the correct numerical value (in decimal notation,
truncated/rounded‐off to the second decimal place; e.g. xxxxx.xx).
11. A 10 kg mass rests on a horizontal frictionless table. How much energy (in Joule) is
needed to accelerate the mass from rest to a speed of 5 m/s?
12. A block of mass 2kg is gently placed over a massive plank moving horizontally over a
smooth surface with velocity 6 m/s. The coefficient of friction between the block and
plank is 0.2. The distance travelled by the block till it slides on the plank is (g=10 m/s2)
13. The two ends A and B of a uniform rod of length  = VA = 20 m/s

1m are moving with velocities VA and VB as shown. The
A= 53o B
velocity VB (m/s) is
A B= 37o
VB
14. A hollow sphere and a solid sphere have equal mass and equal moment of inertia about
the respective diameter. Find the ratio of their square of radii is given by
15. A steel wire of cross-sectional area 2mm2 and Young’s modulus 2  1011N / m2 is
stretched longitudinally by a force of 200 N. The elastic potential energy stored per unit
volume in the string is n × 104. Find the value of ‘n’.
16. A uniform electric field E is present horizontally along the paper A

throughout region but uniform magnetic field B0 is present
horizontally (perpendicular to plane of paper in inward direction) E  B0
right to the line AB as shown. A charge particle having charge q
and mass m is projected vertically upward and crosses the line
AB after time t0. The speed of projection if particle moves after t0
with constant velocity. (given qE = mg) is nto. Find the value of ‘n’. q, m
(g = 9.8 m/s2)
B
17. A cylindrical uniform rod of mass 0.72 kg and radius 6 cm B

rests on two parallel rails, that are d = 50 cm apart. The rod L
caries a current I = 48A (In the direction shown) and rolls
d
along the rails without slipping. If it starts from rest, uniform i
magnetic field of magnitudes 0.25 T is directed L
perpendicular to the rod and the rail, then find the friction
force(In N) between rod and rails
18. A system of coordinates is drawn in a medium whose refractive y

2 P
index varies as   , where 0  y  1 . A ray of light is H
1  y2
incident at origin at an angle 600 with y –axis as shown in the
figure. At point P ray becomes parallel to x-axis. Find the value of x
O
0
‘H’. 60
Chemistry PART – II
SECTION – A
19. Choose correct statement(s) regarding PCl5 molecule.

(A) Phosphorus uses 3d orbital in hybridization
(B) Three different bond angles are observed in the molecule
(C) In solid state it contains ion-pairs
(D) All P – Cl bonds are of equal length
20. Which of the following solution(s) form buffer if they are taken in 2 : 1 molar ratio?
(A) CH3COOH and CH3COONa (B) NH4OH and NaCl
(C) NH4OH and NH4Cl (D) NaHCO3 and Na2CO3
21. Which of the following compound(s) on catalytic hydrolysis forms carbonyl

compound(s)?
(A) CH3CH = CH2 (B) CH3C  CH
(C) CH3C  CCH3 (D) HC  CH
22. Which of the following compound(s) contain(s) hydrogen atoms?

(A) Silicate anions (B) Silicones
(C) Silanes (D) Selenes
23. Which of the following complex(es) is/are insoluble in water?

(A) Na2[Zn(CN)4] (B) [Co(NH3)3Cl3]
(C) [Cr(H2O)6]Br3 (D) H2[SiF6]
24. FeCl3  K 4 Fe  CN6   Precipitate 

The correct statement(s) regarding the precipitate in above reaction is/are
(A) it is blue in colour
(B) one mole of the precipitate can consume 12 moles of NaOH
(C) the maximum van’t Hoff factor of the ppt. can be seven
(D) the ppt. becomes soluble in hot water
(Paragraph Type)
correct.


For dissociation reactions, like 2 SO3  g 
 2 SO2  g  O2  g , the degree of dissociation of
SO3 can be determined by vapour density measurement of the reacting species through the
following relation.
Dd

 n  1 d
The molecular mass of the reaction mixture at equilibrium is 60. Initially only SO3 was taken for
the reaction.
Answer the following questions on the basis of above write up.
25. What is the value of ‘D’ in the reaction?

(A) 60 (B) 30
(C) 40 (D) 80
26. What is the value of ‘’ for the reaction?

(A) 0.2 (B) 0.4
(C) 0.6 (D) 0.8
OH
CH Cl
 3
Anhy. AlCl
 P    Q 
3
Zn dust Cl

 R  
2
h
  S    T    U
(S)  Monosubstituted product
(T)  Disubstituted product
(U)  Trisubstituted product
Answer the following questions on the basis of above write up.
27. The unknown compounds S, T, U are

(A) position isomers (B) functional isomers
(C) metamers (D) different compounds
28. The most deactivating unknown compound towards EAS reaction is:
(A) R (B) U
(C) T (D) S
SECTION – D
29. The energy of the first orbit of hydrogen atom is -13.6 eV. If the fourth ionization enthalpy
of beryllium atom is expressed as Y  10–19 J, what is the value of ‘Y’?
30. How much heat is absorbed in calorie unit by heating 5 moles of a gas at constant
pressure from 900 K to 1727.21 K?
[CP = 4R, R = 2 Cal]
31. What is the kinetic energy of one mole of helium gas at 10000 K in kJ mol–1 unit?
KOH
32. Optically active chloride P    Q 
Conc.H SO
 Q  
Heat
 R    S 
2 4
Major Minor
Ozonolysis
R    T   U
‘Q’ forms a hydrocarbon when treated with C2H5MgBr. ‘U’ is the simple aliphatic
aldehdye that give aldol condensation. (T) is acetophenone. What is the molar mass of
(P) in gram unit?
33. O
Heating
 X  
Decarboxylation
 CH3  C  CH3  3 CO 2
One mole of (X) on heating produces one mole of acetone and three moles of CO2. The
tri-sodium salt of the keto acid (X) reacts with CH3COCl in presence of pyridine to form
acid anhydride. How much CH3COCl in gram can be completely consumed by one mole
of the tri-sodium salt of (X)?
34. P  NaOH
 Excess NaOH
  Q     R 
metal chloride green ppt. green solution
H O CH3COOH
R    S 
2 2

BaCl2 T  
Soln yellow soln yellow ppt.
What is the molar mass of (P) in gram unit?
35. Electrolysis of molten CuSO4 is carried out in an electrolytic cell, using inert electrodes.
How many gram of copper will be deposited at cathode by passing 14 F of electricity
through the cell?
36. How many gram of magnesium carbonate (MgCO 3) can be completely dissolved in 3.26
litre of 5 M HCl solution according to the following reaction?
MgCO 3  2HCl  MgCl2  CO2  H2O
Mathematics PART – III
SECTION – A
37. If f  x   2x  sin x and g  x   3 x, then

(A) range of gof is R (B) gof is one – one
(C) both f and g are one – one (D) both f and g are onto
38. lim x
x 
 x  1  x equals 
ln 1  x   x 1  cos x
(A) lim (B) lim
x 0x 2 x 0 x2
1 x  1 x
(C) lim (D) lim
x 0 x x 0
x  x 2  2x
 x 1  1  t dt, x  2
39. If f  x    0
  , then
 5x  1, x  2
(A) f(x) is not continuous at x = 2
(B) f (x) is continuous but not differentiable at x = 2
(C) f (x) is differentiable everywhere
(D) the right derivative of f  x  at x = 2 does not exist
n n1 n2
n n 1 n2
40. If f  x   Pn Pn1 Pn 2 , where the symbols have their usual meanings, then
n n 1 n2
Cn Cn1 Cn2
f  x  is divisible by
(A) n2  n  1 (B)  n  1 !
(C) n! (D) n2  3n  1
41. The solution/s of the equation 9 cos12 x  cos2 2x  1  6 cos6 x cos 2x  6 cos6 x  2cos 2x
is/are
 2
(A) x  n  , n  I (B) x  n  cos1 4 ,n  I
2 3
2
(C) x  n  cos1 ,n  I (D) x  n, n  I
3
x2 y2
42. If a straight line through a point P  ,2  ,   0 , meets the ellipse
  1 at A and D
9 4
and x – and y–axes at B and C respectively such that PA  PD  PB  PC , then '  ' can
lie in the interval
(A) 7,   (B)  12,  8 
(C)  5, 0  (D) 10,  
(Paragraph Type)
correct.
Let a1,a2 ,a3 , ... be a harmonic progression such that a1  5 and a20  25 .
43. The value of n for which an is maximum is

(A) 22 (B) 23
(C) 24 (D) 25
44. The least value of n for which an  0 is

(A) 22 (B) 23
(C) 24 (D) 25
Let A  4, 2  and B  0,1 be two points on a parabola, the normals at which intersect at the
point P  2,2  .
45. The equation of the directrix of the parabola is

(A) x  y  1  0 (B) x  2
(C) y  3 (D) 2x  y  1  0
46. The focus of the parabola is

6 6  16 7 
(A)  ,   (B)  , 
5 5  5 5
 12 6   6 6
(C)  ,  (D)   , 
 5 5  5 5
SECTION – D
1
47.
x 
 
If 2  x 2  3 , then the positive root of x 2    , (where {x} denotes the fractional part
of x) is equal to
  100x   99 sin x  
48. Let L  lim      , where [.] denotes the greatest integer function. The
x 0
  sin x   x  
number of divisors of L is equal to
 xy  f x
49. If f  x   f  y   f   for all x, y  R , xy  1 and lim  2 , then the value of
 1  xy  x  0 x
f  3 is
f '  2 
x
50. The number of solutions of the equation sin    2x  x 2  2  1 is
2
2 2
51. The minimum value of  tan A  cosB    cot A  sinB  , where A and B are independent
variables, is of the form a  b c , where a, b, c are natural numbers. The value of
a  b  c is equal to
2
52. The smallest value of ‘a’ for which the inequality  a  1 x   a  1 x   a  1  0 holds
for all x  2 , is equal to
53. Three distinct dice are thrown and the sum of the numbers appearing on the top faces is
12. If n is the number of ways in which this is possible, the sum of the digits of n is equal
to
54. The papers of 4 students can be checked by any one of the 7 teachers. If the probability
that all the 4 papers are checked by exactly 2 teachers is A, then the value of 50A is
equal to

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FIITJEE

ALL INDIA TEST SERIES

 The test consists of total 54 questions.

 Each subject (PCM) has 18 questions.

 This question paper contains Three Parts.

 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.

3. For a single material

Space for Rough work

4. A container of large uniform cross sectional area A

5. A uniform thin rod PQ of length ‘L’ is moving in a

Paragraph for Question Nos. 7 and 8

In the circuit shown in figure, R1 = R2 = R3 = 3 and e.m.f. of each cell E

7. Reading of ammeter A1 in ampere is

8. Reading of ammeter A2 in ampere is

Paragraph for Question Nos. 9 and 10

Smooth, horizontal surface

10. KE of the rod, just before it falls flat, will be

13. The two ends A and B of a uniform rod of length  = VA = 20 m/s

Space for Rough work

16. A uniform electric field E is present horizontally along the paper A

17. A cylindrical uniform rod of mass 0.72 kg and radius 6 cm B

18. A system of coordinates is drawn in a medium whose refractive y

Space for Rough work

19. Choose correct statement(s) regarding PCl5 molecule.

21. Which of the following compound(s) on catalytic hydrolysis forms carbonyl

22. Which of the following compound(s) contain(s) hydrogen atoms?

23. Which of the following complex(es) is/are insoluble in water?

24. FeCl3  K 4 Fe  CN6   Precipitate 

Paragraph for Question Nos. 25 and 26

25. What is the value of ‘D’ in the reaction?

26. What is the value of ‘’ for the reaction?

Space for Rough work

Paragraph for Question Nos. 27 and 28

27. The unknown compounds S, T, U are

Space for Rough work

What is the molar mass of (P) in gram unit?

Space for Rough work

Mathematics PART – III

37. If f  x   2x  sin x and g  x   3 x, then

Space for Rough work

Paragraph for Question Nos. 43 and 44

43. The value of n for which an is maximum is

44. The least value of n for which an  0 is

Paragraph for Question Nos. 45 and 46

45. The equation of the directrix of the parabola is

46. The focus of the parabola is

Space for Rough work

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