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Worksheet Class Xii - Chemistry Chapter - Haloalkanes and Haloarenes

This document is a worksheet for Class XII Chemistry covering the topics of haloalkanes and haloarenes. It contains 23 questions testing understanding of concepts such as: why sulfuric acid is not used in reactions of alcohols with KI; factors affecting boiling points and reactivity of alkyl halides; properties of ambident nucleophiles; factors influencing dipole moments and miscibility with water; and mechanisms of nucleophilic substitution reactions. It also addresses topics like optical activity, asymmetric carbons, enantiomers, and electrophilic aromatic substitution.

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Apratim Nag
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732 views3 pages

Worksheet Class Xii - Chemistry Chapter - Haloalkanes and Haloarenes

This document is a worksheet for Class XII Chemistry covering the topics of haloalkanes and haloarenes. It contains 23 questions testing understanding of concepts such as: why sulfuric acid is not used in reactions of alcohols with KI; factors affecting boiling points and reactivity of alkyl halides; properties of ambident nucleophiles; factors influencing dipole moments and miscibility with water; and mechanisms of nucleophilic substitution reactions. It also addresses topics like optical activity, asymmetric carbons, enantiomers, and electrophilic aromatic substitution.

Uploaded by

Apratim Nag
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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WORKSHEET

Class XII - CHEMISTRY


CHAPTER - HALOALKANES AND HALOARENES

1. Why is sulphuric acid not used during the reaction of alcohols with KI?
2. Arrange each set of compounds in the order of increasing boiling points.
a) Bromomethane, Bromoform, Chloromethane, Dibromomethane.
b) 1-Chloropropane, Isopropyl chloride, 1-chlorobutane.
3. Which alkyl halide from the following pairs would you expect to react more rapidly
by an SN 2 mechanism? Explain your answer.
a) CH3CH2CH2CH2Br or CH3CH2CHCH3

Br

CH3

b) CH3CH2CHCH3 or H3C-C-Br
 
Br CH3

c) CH3CH2CHCH2Br or CH3CH2CHCH2Br
 
CH3 CH3

4. Which of the following has the highest dipole moment?


(i) CH2Cl2 (ii) CHCL2 (iii) CCl4
5. What are ambident nucleophiles? Explain with an example.
6. Which compound in each of the following pairs will react faster in SN 2 reaction with
OH?
(i) CH3Br or CH3I (ii) (CH3)3 CCl or CH3Cl
7. Explain why (i) the dipole moment of chlorobenzene is lower than that of cyclohexyl
chloride? (ii) alkyl halides, though polar, are immiscible with water? (iii) Grignard
reagents should be prepared under anhydrous conditions?

8. Arrange the compounds of each set in order of reactivity towards SN2 displacement:
a) 2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane.
b) 1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 2-Bromo-3-methylbutane.

XII / Chemistry Page 1 of 3


c) 1-Bromobutane, 1-Bromo-2, 2-dimethylpropane, 1-Bromo-2-methylbutane, 1-Bromo-
3-methylbutane.
9. p-Dichlorobenzene has higher melting point and lower solubility than 0- and m-
isomers. Discuss
10. The treatment of alkyl chlorides with aqueous KOH leads to the formation of alcohols
but in presence of alcoholic KOH, alkenes are the major products.
11. Which is a better nucleophile, a bromide ion or an iodide ion?
12. What are chiral and achiral objects?
13. What is plane polarized light?
14. What do you understand by the term optical activity of compounds?
15. Explain why thionyl chloride method is preferred for preparing alkyl chlorides from
alcohols?
16. What is an asymmetric carbon?
17. Explain as to why haloarenes are much less reactive than haloalkanes towards
nucleophilic substitution reactions.
Or
Which compound in each of the following pairs will react faster in SN2 reaction with
–OH? Why?
a) CH3 Br or CH3I
b) (CH3)3CCl or CH3Cl
18. Which ones in the following pairs of substances undergoes SN2 substitution reaction
faster and why?
19. Which one in the following pairs undergoes SN1 substitution reaction faster and why?

a)

b)

20. What are enantiomers? Draw the structures of the possible enantiomers of 3-
methylpent 1-ene.
21. Although chlorine is an electron withdrawing group, yet it is ortho, para-directing in
electrophile aromatic substitution reactions. Why?

XII / Chemistry Page 2 of 3


22. Answer the following:
a) Haloalkanes easily dissolve in organic solvents, why?
b) What is known as a racemic ixture? Give an example.
c) Or the two bromoderivatives, C6H5CH(CH3)Br and C6H5CH(C6H5)Br, which one is
more reactive in SN1 substitution reaction and why?
23. Give reasons:
a) tert-Butyl chloride reacts with aqueous sodium hydroxide by SN1 mechanism while n-
butyl chloride reacts by SN2 mechanism.
b) Alkyl halides, though polar, are immiscible with water.
c) Vinyl chloride is unreactive in nucleophilic substitution reactions.
d) Neo-pentyl bromide undergoes nucleophilic substitution reaction very slowly.
e) 3-Bromocyclohexene is more reactive than 4-bromocyclohexene in hydrolysis with
aqueous NaOH.
f) Iodoform is obtained by reaction of acetone with hypoiodite ion but not iodide ion.

XII / Chemistry Page 3 of 3

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