2007 PLACE
Conference
                                                   September 16-20
                                                      St Louis, MO
      Biodegradable Flexible
           Packaging
          What it is and how it can be used
Presented by:
Stewart Richards
Technical Service & Development Manager Americas
Innovia Films Inc.
 “It took almost 5 billion
           years to
 create the earth as we
          know it –
with all its natural beauty.
But is has taken only 200
         years to
  bring the earth to the
         brink of
       destruction.
  It’s time to act now.”       Mikhail S. Gorbachev
                               President of the WORLD AWARDS
"The future depends on what we
      do in the present."
        -- Mahatma Gandhi
Biodegradable
     &/or
 Sustainable
  Packaging
 Key Drivers
     Drivers for Biodegradable &
       Sustainable Packaging
• Increasing governmental and industry awareness of the
  need to develop the use of sustainable resources. We
  need to preserve our resources & environment today, ... for
  future generations.
• One of the most pressing problems today is what to do with
  various waste products. Certain wastes can no longer be
  deposited in landfills, and landfill fees are on the rise.
• Very high proportion of flexible packaging is sourced from
  oil based derivatives.
• General public perception that ‘biodegradable is good’.
• Retailers and marketers are aware of and want to take
  advantage of these issues thereby creating a
  significant market opportunity.
Some Interesting Facts About
     Oil and Packaging
 8% of Oil is Converted into Plastics
 Over 50% of Packaging is Plastic
 Oil has increased in price 500% since 1990’s
 Only Discovering 1 Barrel of Oil for every 4 used
 2005…
  Middle East uncertainty, Oil supply, Gas prices,
  Katrina, Rita
Some Interesting Facts About
     Oil and Packaging
                                 Average $ per Barrel
 80
 70
 60
 50
 40
 30
 20
 10
  0
      1960's   1970's   1980's   1990's   2000   2001   2002   2003   2004   2005   2006
Biodegradability & Compostability
What is the difference?
   BIODEGRADABILITY - Capacity of a substance to be
    broken down by micro-organisms. [No set time scale]
   COMPOSTABILITY - A managed biodegradation
    process, through production of a useful compost in a
    maximum period of 180 days. This requires conformity
    to an agreed norm.
   COMPOSTABILITY NORMS – EN, ASTM, DIN,
    GreenPla
    Europe has adopted EN 13432 & U.S. has adopted
    ASTM D 6400.
               Composting Norm for
           ‘BIODEGRADABLE PLASTICS’
A BRIEF GUIDE TO ASTM 6400
   In simple terms, the biodegradability of the material is
    compared to a control (pure cellulose) and must biodegrade
    to a minimum of 90% of the control level.
   Constituents of the packaging material >1% by weight must
    be measured individually, and also biodegrade to a minimum
    of 90% of the control level.
   Constituents <1% by weight are exempted, but the sum of
    such constituents must not compromise biodegradation.
   Pilot composting & plant-growing tests are also carried out
    on the material.
   Heavy metal content tests are also required.
         Methods of Composting
                                           Home composting:
Industrial composting:                     Only suitable for unmodified
Suitable for all                           plant-based materials &
certified compostable                      materials tested specifically
materials
                                           Not suitable for materials
                                           that require higher temps
                                           to achieve
          Windrow Composting               biodegradation
     (not suitable for Oxo-degradables)
                              In-vessel Composting
               Product Certification
Packaging films having been fully tested & certified to the
European composting norm EN13432 as well as the American
standard ASTM 6400. They can therefore carry the following
logos:
                Compostable
                Kompostierbar
                7P0085
  Dincertco, Germany
  Also UK, Netherlands & Poland                 BPI logo, USA
       They are also certified as
       fully ‘home’ compostable…
                                    OK Compost, Belgium
         Sustainable Films
What does the Term Sustainable Mean ?
 A sustainable film is one that is sourced
  with high levels of renewable raw materials.
 All sustainable films currently available are
  sourced from Bio-Based materials.
 This results in   renewable cycles of less
  than 10 years
NE2
  The degree of sustainability is determined
  by the Carbon14 ratio
         Main Biopolymers
   Most biopolymers exhibit either ‘Cling Film’ or
    ‘LDPE type’ properties. (Tear resistant, stretchy,
    weld seals, low melting points). They also tend to
    lack transparency and gloss.
   Only Cellulose or PLA based films exhibit
    ‘orientated’ type properties (stiffness, dimensional
    stability, transparency and gloss)
   Most biopolymers (with the exception of Cellulose
    and PLA films) are based on synthetic rather than
    renewable resources, but all are truly biodegradable
    these days...
     Current Issues with
     Biodegradable Films
 Achievement of Moisture Barrier
 Cost
 Infra-structure to cope with
 composting of biodegradable used or
 waste films
     Current Issues with
     Biodegradable Films
Currently best moisture barrier achieved
with Cellulose based films
Transparent Films 2g/100in2/day
Metallised Films 0.32g/100in2/day
Transparent BOPP < 0.4g/100in2/day
Metallised BOPP < 0.04g/100in2/day
Ceramis coated PLA which is transparent
is achieving < 0.70g/100in2/day
  Cellulose Films and Making
   them truly Biodegradable
 Heat-sealable Cellophane Films have always
 been in excess of 90% biodegradable
 Coatings to make them heat-sealable such
 as PVdC did not allow them meet the
 composting norms
 Biodegradable heat-sealable coatings now
 being used that allow the films to meet the
 norms.
 The “Holy Grails” of moisture and oxygen
 barrier are still being pursued
The Cellulose Film Cycle
        Elements Required for
   Biodegradation of Cellulose Films
 High Enough Water Activity
 Aerobic Environment
 Nutrient
 Elevated Temperature will increase rate
 of degradation but not essential
Biodegradation of Cellulose Films
                      120
                      100
% degradation (C02)
                      80
                                                                         Control (pure cellulose)
                      60                                                 Uncoated
                                                                         Natureflex NP
                                                                         Coated NE
                                                                         NatureFlex
                      40
                      20
                       0                                                             Evolution of the Disintegration of Cellulose Film
                            0     5   10 15 20 25 30 35 40 45
                                                 Days
                                          Full film sheet present
                                Total visible disintegration confirmed
    Cellulose Films Used
Extensively for Fresh Produce
                Extends shelf life by controlling
                moisture environment (prevents
                mold growth)
                Perforation controls gas
                environment (controls ripening)
                Maintains produce aroma
                Reduces Waste Produce and all
                packaging is compostable
          Pristine Tomatoes
   Preserving the quality of the fruit from
    vine to consumer is essential to
    successful marketing.
   Consumers buy tomatoes based on:
      ¾   Color
      ¾   Appearance
      ¾   Flavor
      ¾   Aroma
              The Results-Extension of
                 Produce Shelf Life
                               Vine Tomatoes
Film          Weight loss   Mold      Ripening /     Aroma         Skin         Color
                                      Softening                    Appearance
Cellulose     Low           OK @ 36   Moderate       Good          No Change    No Change
mid barrier                 days
Cellulose     High          OK @ 36   Moderate       Good          No Change    No change
low barrier                 days
BOPP          Medium        25 days   Moderate       Lost tomato   Mold         No change
Perforated                                           aroma
BOPP          Lowest        25 days   Moderate       Lost tomato   Mold         No change
Breathable                                           aroma
PLA           Highest       OK @ 36   Moderate       Lost tomato   Wrinkled @   No change
                            days                     aroma         26 days
Control       Medium        OK @ 36   Overripe and   Lost tomato   Wrinkled @   No change
unwrapped                   days      soft @ 26      aroma         26 days
                                      days
Future structures from Bio-based
              Films
    Typical structure using Oil-based Films
                            Reverse Printed Polypropylene
             Adhesive
                            Polyethylene
     Polypropylene Film provides durability
      and good surface for print graphics
      Polyethylene Film provides enhanced
      sealability
Future structures from Bio-based
              Films
  Proposed structure using Bio-based Films
                           Reverse Printed Cellulose Film
             Adhesive
                           Bio-based Sealant Film
     Cellulose film provides durability and
      good surface for print graphics
      Bio-based Sealant Film provides
      enhanced sealability
Persistence Pays
                     Thank You
PRESENTED BY
Stewart Richards
Technical Service & Development Manager Americas
Innovia Films Inc.
Stewart.Richards@innoviafilms.com
                                    Please remember to turn
                                    in your evaluation sheet...