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CH 22 Mechanisms

Keto-enol tautomerism favors the enol form under acidic conditions and the keto form under basic conditions. Halo-genation of alkenes proceeds through an anti-Markovnikov addition in acidic media, with the halogen adding to the carbon with more hydrogen substituents. In basic media, halo-genation of alkenes is irreversible and proceeds through a Markovnikov addition, with the halogen adding to the carbon with fewer hydrogen substituents. Saponification involves hydrolysis of an ester using a strong base such as sodium hydroxide or potassium hydroxide.
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0% found this document useful (0 votes)
57 views3 pages

CH 22 Mechanisms

Keto-enol tautomerism favors the enol form under acidic conditions and the keto form under basic conditions. Halo-genation of alkenes proceeds through an anti-Markovnikov addition in acidic media, with the halogen adding to the carbon with more hydrogen substituents. In basic media, halo-genation of alkenes is irreversible and proceeds through a Markovnikov addition, with the halogen adding to the carbon with fewer hydrogen substituents. Saponification involves hydrolysis of an ester using a strong base such as sodium hydroxide or potassium hydroxide.
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