Page: 1
SAFETY DATA SHEET                                                                       Revision Date: 05/19/2017
                                                                                          Print Date: 6/9/2017
                                                                                   SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                                                                     Version: 1.2
852815
29 CFR 1910.1200 (OSHA HazCom 2012)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
   Product identifier
       Trade name                 :        Kubota®
                                           DIESEL EXHAUST FLUID
    Details of the supplier of the safety data        Emergency telephone number
    sheet                                             1-800-VALVOLINE (1-800-825-8654)
    Valvoline LLC
    100 Valvoline Way                                 Regulatory Information Number
    Lexington, KY 40509                               1-800-TEAMVAL
    United States of America (USA)
    1-800-TEAMVAL                                     Product Information
                                                      1-800-TEAMVAL
SECTION 2. HAZARDS IDENTIFICATION
    GHS Classification
    This material is not considered hazardous under the OSHA Hazard Communication Standard
    (HazCom 2012).
    GHS label elements
    This material is not considered hazardous under the OSHA Hazard Communication Standard
    (HazCom 2012).
    Other hazards
    None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
    Hazardous components
    Chemical name                        CAS-No.                       Classification        Concentration (%)
    UREA                                 57-13-6                                            32.50
SECTION 4. FIRST AID MEASURES
    General advice                    : No hazards which require special first aid measures.
    If inhaled                        : If breathed in, move person into fresh air.
                                        If unconscious, place in recovery position and seek medical
                                        advice.
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SAFETY DATA SHEET                                                                     Revision Date: 05/19/2017
                                                                                          Print Date: 6/9/2017
                                                                                   SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                                                                     Version: 1.2
852815
                                       If symptoms persist, call a physician.
    In case of skin contact        : First aid is not normally required. However, it is
                                     recommended that exposed areas be cleaned by washing
                                     with soap and water.
    In case of eye contact         : Remove contact lenses.
                                     Protect unharmed eye.
    If swallowed                   : Do not give milk or alcoholic beverages.
                                     Never give anything by mouth to an unconscious person.
                                     If symptoms persist, call a physician.
    Most important symptoms        : Signs and symptoms of exposure to this material through
    and effects, both acute and      breathing, swallowing, and/or passage of the material through
    delayed                          the skin may include:
                                     stomach or intestinal upset (nausea, vomiting, diarrhea)
                                     irritation (nose, throat, airways)
                                     Headache
                                     Dizziness
    Notes to physician             : No hazards which require special first aid measures.
SECTION 5. FIREFIGHTING MEASURES
    Suitable extinguishing media   : Use extinguishing measures that are appropriate to local
                                     circumstances and the surrounding environment.
                                     Water spray
                                     Foam
                                     Carbon dioxide (CO2)
                                     Dry chemical
    Specific hazards during        : Do not allow run-off from fire fighting to enter drains or water
    firefighting                     courses.
    Hazardous combustion           : acid vapors
    products                         Ammonia
                                     carbon dioxide and carbon monoxide
                                     Nitrogen oxides (NOx)
    Specific extinguishing         :
    methods
                                       Product is compatible with standard fire-fighting agents.
    Further information            : Standard procedure for chemical fires.
    Special protective equipment   : In the event of fire, wear self-contained breathing apparatus.
    for firefighters
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SAFETY DATA SHEET                                                                   Revision Date: 05/19/2017
                                                                                         Print Date: 6/9/2017
                                                                                  SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                                                                    Version: 1.2
852815
SECTION 6. ACCIDENTAL RELEASE MEASURES
    Personal precautions,         : Persons not wearing protective equipment should be excluded
    protective equipment and        from area of spill until clean-up has been completed.
    emergency procedures
    Environmental precautions     : Prevent further leakage or spillage if safe to do so.
    Methods and materials for     : Keep in suitable, closed containers for disposal.
    containment and cleaning up
    Other information             : Comply with all applicable federal, state, and local regulations.
SECTION 7. HANDLING AND STORAGE
    Advice on safe handling       : Smoking, eating and drinking should be prohibited in the
                                    application area.
                                    For personal protection see section 8.
    Materials to avoid            : No materials to be especially mentioned.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
   Components with workplace control parameters
   Components                  CAS-No.       Value type             Control                 Basis
                                             (Form of               parameters /
                                             exposure)              Permissible
                                                                    concentration
    UREA                              57-13-6            TWA         10 mg/m3               US WEEL
    Engineering measures          : General room ventilation should be adequate for normal
                                    conditions of use. However, if unusual operating conditions
                                    exist, provide sufficient mechanical (general and/or local
                                    exhaust) ventilation to maintain exposure below exposure
                                    guidelines (if applicable) or below levels that cause known,
                                    suspected or apparent adverse effects.
   Personal protective equipment
    Respiratory protection     : No personal respiratory protective equipment normally
                                 required.
    Eye protection                :   Not required under normal conditions of use. Wear splash-
                                      proof safety goggles if material could be misted or splashed
                                      into eyes.
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SAFETY DATA SHEET                                                                         Revision Date: 05/19/2017
                                                                                              Print Date: 6/9/2017
                                                                                       SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                                                                         Version: 1.2
852815
    Skin and body protection            :    Wear as appropriate:
                                             Safety shoes
                                             Wear resistant gloves (consult your safety equipment
                                             supplier).
    Hygiene measures                    :    General industrial hygiene practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
    Physical state                          : liquid
    Colour                                  : colourless
    Odour                                   : ammoniacal
    Odour Threshold                         : No data available
    pH                                      : 10
    Melting point/freezing point            : No data available
    Boiling point/boiling range             : No data available
    Flash point                             : Not applicable
    Evaporation rate                        : No data available
    Flammability (solid, gas)               : No data available
    Upper explosion limit                   : No data available
    Lower explosion limit                   : No data available
    Vapour pressure                         : 293.309 hPa
    Relative vapour density                 : No data available
    Relative density                        : 1.09 (20 °C)
    Density                                 : 1.09 g/cm3 (20 °C)
    Solubility(ies)
      Water solubility                      : soluble
         Solubility in other solvents       : No data available
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SAFETY DATA SHEET                                                                    Revision Date: 05/19/2017
                                                                                         Print Date: 6/9/2017
                                                                                  SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                                                                    Version: 1.2
852815
    Partition coefficient: n-         : No data available
    octanol/water
    Thermal decomposition             : No data available
    Viscosity
      Viscosity, dynamic              : No data available
         Viscosity, kinematic         : No data available
    Oxidizing properties              : No data available
SECTION 10. STABILITY AND REACTIVITY
    Reactivity                        : No decomposition if stored and applied as directed.
    Chemical stability                : Stable under recommended storage conditions.
    Possibility of hazardous          : Product will not undergo hazardous polymerization.
    reactions
    Conditions to avoid               : None known.
    Incompatible materials            : Acids
                                        Chlorine
                                        nitrates
                                        strong bases
                                        Strong oxidizing agents
    Hazardous decomposition
    products                             acid vapors
                                         carbon dioxide and carbon monoxide
                                         Nitrogen oxides (NOx)
                                         Ammonia
SECTION 11. TOXICOLOGICAL INFORMATION
    Information on likely routes of   : Inhalation
    exposure                            Skin contact
                                        Eye Contact
                                        Ingestion
    Acute toxicity
    Not classified based on available information.
    Components:
    UREA:
    Acute oral toxicity             : LD50 (Rat): 14,300 mg/kg
                                       Method: OECD Test Guideline 401
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SAFETY DATA SHEET                                                                     Revision Date: 05/19/2017
                                                                                          Print Date: 6/9/2017
                                                                                   SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                                                                     Version: 1.2
852815
    Skin corrosion/irritation
    Not classified based on available information.
    Components:
    UREA:
    Species: Rabbit
    Method: OECD Test Guideline 404
    Result: No skin irritation
    Serious eye damage/eye irritation
    Not classified based on available information.
    Product:
    Remarks: Unlikely to cause eye irritation or injury.
    Components:
    UREA:
    Species: Rabbit
    Result: No eye irritation
    Method: OECD Test Guideline 405
    Respiratory or skin sensitisation
    Skin sensitisation: Not classified based on available information.
    Respiratory sensitisation: Not classified based on available information.
    Components:
    UREA:
    Assessment: Does not cause skin sensitisation.
    Germ cell mutagenicity
    Not classified based on available information.
    Components:
    UREA:
    Genotoxicity in vitro           : Test Type: Ames test
                                       Test species: Salmonella typhimurium
                                       Metabolic activation: with and without metabolic activation
                                       Method: OECD Test Guideline 471
                                       Result: negative
                                     : Test Type: Ames test
                                       Test species: Escherichia coli
                                       Metabolic activation: with and without metabolic activation
                                       Method: OECD Test Guideline 471
                                       Result: negative
    Carcinogenicity
    Not classified based on available information.
    Reproductive toxicity
    Not classified based on available information.
    Components:
    UREA:
    Effects on foetal               : Species: Rat
    development                        Application Route: Oral
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SAFETY DATA SHEET                                                                      Revision Date: 05/19/2017
                                                                                         Print Date: 6/9/2017
                                                                                  SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                                                                    Version: 1.2
852815
                                      Developmental Toxicity: Lowest observed adverse effect level:
                                      500 mg/kg bw/day
    STOT - single exposure
    Not classified based on available information.
    STOT - repeated exposure
    Not classified based on available information.
    Repeated dose toxicity
    Components:
    UREA:
    Species: Rat
    NOAEL: 2,250 mg/kg
    Application Route: Oral
    Aspiration toxicity
    Not classified based on available information.
    Further information
    Product:
    Remarks: No data available
    Carcinogenicity:
    IARC                            No component of this product present at levels greater than or
                                    equal to 0.1% is identified as probable, possible or confirmed
                                    human carcinogen by IARC.
    OSHA                            No component of this product present at levels greater than or
                                    equal to 0.1% is identified as a carcinogen or potential
                                    carcinogen by OSHA.
    NTP                             No component of this product present at levels greater than or
                                    equal to 0.1% is identified as a known or anticipated carcinogen
                                    by NTP.
SECTION 12. ECOLOGICAL INFORMATION
    Ecotoxicity
    Product:
    Toxicity to fish                : LC50 (Fish): > 9,100 mg/l
                                      Exposure time: 96 h
    Toxicity to daphnia and other   : EC50 (Daphnia magna (Water flea)): >= 10,000 mg/l
    aquatic invertebrates             Exposure time: 24 h
    Ecotoxicology Assessment
    Acute aquatic toxicity          : Not classified based on available information.
    Chronic aquatic toxicity        : Not classified based on available information.
    Components:
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SAFETY DATA SHEET                                                                   Revision Date: 05/19/2017
                                                                                         Print Date: 6/9/2017
                                                                                  SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                                                                    Version: 1.2
852815
    UREA:
    Toxicity to fish                : LC50 (Leuciscus idus (Golden orfe)): > 6,810 mg/l
                                      Exposure time: 96 h
                                      LC50 (Poecilia reticulata (guppy)): 17,500 mg/l
                                      Exposure time: 96 h
    Toxicity to daphnia and other   : EC50 (Water flea (Daphnia magna)): > 10,000 mg/l
    aquatic invertebrates             Exposure time: 24 h
                                      Test Type: static test
                                      Method: DIN 38412
                                      Remarks: Intoxication
    Toxicity to algae               : EC10 (Microcystis aeruginosa (blue-green algae)): 47 mg/l
                                      End point: Biomass
                                      Exposure time: 192 h
                                      Test Type: static test
                                      NOEC (Microcystis aeruginosa (blue-green algae)): 47 mg/l
                                      End point: Biomass
                                      Exposure time: 192 h
                                      Test Type: static test
    Persistence and degradability
    Product:
    Biodegradability              : Result: Inherently biodegradable.
    Components:
    UREA:
    Biodegradability                : Result: Readily biodegradable.
                                      Biodegradation: 96 %
                                      Exposure time: 16 d
                                      Method: OECD Test Guideline 302B
    No data available
    Bioaccumulative potential
    Components:
    UREA:
    Partition coefficient: n-       : log Pow: 1.73 (20 °C)
    octanol/water
    No data available
    Mobility in soil
    Components:
    No data available
    Other adverse effects
    No data available
    Product:
    Additional ecological           : No data available
    information
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SAFETY DATA SHEET                                                                   Revision Date: 05/19/2017
                                                                                         Print Date: 6/9/2017
                                                                                  SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                                                                    Version: 1.2
852815
     Components:
 SECTION 13. DISPOSAL CONSIDERATIONS
     Disposal methods
     General advice                : Dispose of in accordance with all applicable local, state and
                                     federal regulations.
     Contaminated packaging        : Empty remaining contents.
 SECTION 14. TRANSPORT INFORMATION
 International transport regulations
 REGULATION
 ID NUMBER       PROPER SHIPPING NAME           *HAZARD        SUBSIDIARY         PACKING       MARINE
                                                CLASS          HAZARDS            GROUP         POLLUTANT /
                                                                                                LTD. QTY.
 MX_DG
                 Not dangerous goods
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER
              Not dangerous goods
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO
              Not dangerous goods
INTERNATIONAL MARITIME DANGEROUS GOODS
              Not dangerous goods
TDG_INWT_C
                 Not dangerous goods
TDG_RAIL_C
                 Not dangerous goods
TDG_ROAD_C
                 Not dangerous goods
U.S. DOT - INLAND WATERWAYS
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SAFETY DATA SHEET                                                                     Revision Date: 05/19/2017
                                                                                           Print Date: 6/9/2017
                                                                                    SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                                                                      Version: 1.2
852815
                  Not dangerous goods
CFR_RAIL_C
                  Not dangerous goods
U.S. DOT - ROAD
                  Not dangerous goods
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID
     Marine pollutant                   no
 Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
 exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
 shipment.
 SECTION 15. REGULATORY INFORMATION
     EPCRA - Emergency Planning and Community Right-to-Know Act
     CERCLA Reportable Quantity
     Components                          CAS-No.           Component RQ Calculated product RQ
                                                                  (lbs)          (lbs)
     AMMONIUM HYDROXIDE                  1336-21-6                1000             *
     ((NH4)(OH))
      *: Calculated RQ exceeds reasonably attainable upper limit.
     SARA 304 Extremely Hazardous Substances Reportable Quantity
     This material does not contain any components with a section 304 EHS RQ.
     SARA 311/312 Hazards             : No SARA Hazards
     SARA 313                           This material does not contain any chemical components with
                                        known CAS numbers that exceed the threshold (De Minimis)
                                        reporting levels established by SARA Title III, Section 313.
     California Prop 65            This product does not contain any chemicals known to State
                                   of California to cause cancer, birth defects, or any other
                                   reproductive harm.
     The components of this product are reported in the following inventories:
     TSCA                        : On TSCA Inventory
     DSL                              : All components of this product are on the Canadian DSL
     AICS                             : On the inventory, or in compliance with the inventory
     ENCS                             : On the inventory, or in compliance with the inventory
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SAFETY DATA SHEET                                                                                 Revision Date: 05/19/2017
                                                                                                       Print Date: 6/9/2017
                                                                                                SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                                                                                  Version: 1.2
852815
    KECI                               : On the inventory, or in compliance with the inventory
    PICCS                              : On the inventory, or in compliance with the inventory
    IECSC                              : On the inventory, or in compliance with the inventory
    Inventories
    AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
    (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
SECTION 16. OTHER INFORMATION
    Further information
    Revision Date: 05/19/2017
    NFPA:                                                 HMIS III:
                     Flammability
                                                              HEALTH                                0
                           0
                                      Instability
           Health
                     0          0                             FLAMMABILITY                          0
                                                              PHYSICAL HAZARD                       0
                                                              0 = not significant, 1 =Slight,
                    Special hazard.                           2 = Moderate, 3 = High
                                                              4 = Extreme, * = Chronic
    NFPA Flammable and Combustible Liquids Classification
    Not applicable
    Full text of H-Statements
    Sources of key data used to compile the Safety Data Sheet
    Valvoline internal data including own and sponsored test reports
    The UNECE administers regional agreements implementing harmonised classification for
    labelling (GHS) and transport.
    The information accumulated herein is believed to be accurate but is not warranted to be whether
    originating with the company or not. Recipients are advised to confirm in advance of need that the
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SAFETY DATA SHEET                                                                    Revision Date: 05/19/2017
                                                                                          Print Date: 6/9/2017
                                                                                   SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                                                                     Version: 1.2
852815
    information is current, applicable, and suitable to their circumstances. This SDS has been
    prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE).
    List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data
    sheet :
    ACGIH : American Conference of Industrial Hygienists
    BEI : Biological Exposure Index
    CAS : Chemical Abstracts Service (Division of the American Chemical Society).
    CMR : Carcinogenic, Mutagenic or Toxic for Reproduction
    FG : Food grade
    GHS : Globally Harmonized System of Classification and Labeling of Chemicals.
    H-statement : Hazard Statement
    IATA : International Air Transport Association.
    IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA).
    ICAO : International Civil Aviation Organization
    ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization”
    IMDG : International Maritime Code for Dangerous Goods
    ISO : International Organization for Standardization
    logPow : octanol-water partition coefficient
    LCxx : Lethal Concentration, for xx percent of test population
    LDxx : Lethal Dose, for xx percent of test population.
    ICxx : Inhibitory Concentration for xx of a substance
    Ecxx : Effective Concentration of xx
    N.O.S.: Not Otherwise Specified
    OECD : Organization for Economic Co-operation and Development
    OEL : Occupational Exposure Limit
    P-Statement : Precautionary Statement
    PBT : Persistent , Bioaccumulative and Toxic
    PPE : Personal Protective Equipment
    STEL : Short-term exposure limit
    STOT : Specific Target Organ Toxicity
    TLV : Threshold Limit Value
    TWA : Time-weighted average
    vPvB : Very Persistent and Very Bioaccumulative
    WEL : Workplace Exposure Level
    CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act
    DOT : Department of Transportation
    FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act
    HMIRC : Hazardous Materials Information Review Commission
    HMIS : Hazardous Materials Identification System
    NFPA : National Fire Protection Association
    NIOSH : National Institute for Occupational Safety and Health
    OSHA : Occupational Safety and Health Administration
    PMRA : Health Canada Pest Management Regulatory Agency
    RTK : Right to Know
    WHMIS : Workplace Hazardous Materials Information System
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SAFETY DATA SHEET                          Revision Date: 05/19/2017
                                                Print Date: 6/9/2017
                                         SDS Number: 000000158928
Kubota® DIESEL EXHAUST FLUID                           Version: 1.2
852815
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