Acgih Guidelines 1987
Acgih Guidelines 1987
e
Document Name: ACGIH: Guidelines for the Selection of Chemical
Protective Clothing, Third Edition
CFR Section(s): 46 CFR 153.933(a)
Official Incorporator:
THE EXECUTIVE DIRECTOR
OFFICE OF THE FEDERAL REGISTER
WASHINGTON, D.C.
Volume I: Field Guide
February 1987
Arthur D. Little, Inc. prepared this document with what it belieevs is the best currently
available information. The document is subject to revision as additional knowledge and
experience are gained. Arthur D. Little cannot guarantee the accuracy of information used
to deelop the chemical protective clothing recommendations contained herein, and the
mention of company names or products does not constitute endorsement by Arthur D.
Little. Arthur D. Little accepts no responsibility for damages or liabilities of any kind
which may be claimed to result from the use of this document.
Guidelines for the
Selection of Chemical
Protective Clothing
- Third Edition -
February 1987
iii
SPECIAL NOTE TO USERS
This document contains comprehensive tables of recommendations to aid and
facilitate the selection of chemical protective clothing (CPC). The
recommendations are based on an extensive compilation and analysis of CPC
vendors' literature and experimental test data published in technical
journals and reports. It is imperative that users of the recommendation
tables familiarize themselves with the background information that
precedes and accompanies the tables. The selection of CPC must take into
account the potential hazard and the conditions of use--neither is
considered in this document. The recommendations are not nor do they
imply a guarantee of safety.
Although every effort has been made to prepare this document as ac-
curately as possible, errors can and do occur. Users of this document
are asked to notify Lt. Jeffrey O. Stull, Commandant (G-DMT-3), U.S.
Coast Guard, 2100 Second Street, S.W., Washington, D.C. 20593
(202-267 -0853), or Mr. David Weitzman, U. S. Environmental Protection
Agency Office of Occupational Health and Safety t Room 3503 t Waterside
Mall, 401 M Street, S.W., Washington, D.C. 20460 (202-382-3647) of errors
so that they can be corrected.
iv
TABLE OF CONTENTS
VOLUME I
CHAPTER 1 - OVERVIEW 1
A. INTRODUCTION 1
A. CHEMICAL RESISTANCE 4
C. APPLICATION 5
D. REUSE 6
E. SUBSTITUTION OF CPC 6
F. COST 6
A. INTRODUCTION 7
C. INFLUENCING FACTORS 8
v
TABLE OF CONTENTS (CONTINUED)
C. ENSEMBLE EVALUATION 31
D. QUALITY CONTROL 39
E. SPLASH SUITS 39
A. PURCHASE 47
B. PRE-USE INSPECTION 47
C. DONNING 48
D. IN-USE 48
E. DOFFING 48
A. INTRODUCTION 51
vi
TABLE OF CONTENTS (CONTINUED)
vii
CHAPTER 1
OVERV-IEW
A. INTRODUCTION
Skin is an organ of the hwnan body and has a surface area of about
1.8 m. A principal function of skin is to protect our internal organs
from exposure to potentially harmful components of the external environ-
ment. Direct contact with chemicals can pose a significant challenge to
the skin; possible reactions are:
The latter type of reaction, which would include, for example, irrepara-
ble liver damage and cancer, receives a high level of attention from both
the lay and the technical communities. And, of course, such debilities
warrant serious consideration. However. it is also important to recog-
nize that primary skin irritations and sensitizations account for signif-
icantly greater nwnbers of lost time incidents. It is estimated that
skin diseases account for two-thirds of all identified job-related
diseases. Furthermore, seven out of ten industrial claims paid by
insurance companies are for temporary disability resulting from derma-
titis.
1
C. OBJECTIVE OF THE GUIDELINES
epe in one form or another is commercially available from hundieds of
vendors in the United States. Furthermore, the clothing is fabricated
from a wide variety of plastic and rubber materials. In addition. the
effectiveness of a particular item of clothing is highly dependent on the
chemical with which it may be challenged. For example, a neoprene glove
provides excellent protection from sulfurjc acid, but it is rapidly
permeated by toluene. Finally, the conditions under which the clothing
is used can affect performance. These factors combine to create a
perplexing situation for those who are involved in or responsible for the
protection of workers who handle chemicals--for example, at a hazardous
waste site.
2
instructions for selecting clothing types and doffing potentially contam-
inated clothing.
3
CHAPTER 2
CHEMICAL PROTECTIVE CLOTHING LIMITATIONS
The use of chemical protective clothing is but one component of the
overall program for maintaining the health and safety of workers. It
complements (and is not a substitute for) good planning, work practices,
engineering and administrative controls, or personal hygiene. Several
factors which should be considered in the specification and selection of
epe are discussed in the following paragraphs.
A. CHEMICAL RESISTANCE
The performance of epe as a barrier to chemicals is determined by the
materials and quality of its construction. Chemical protective clothing
is based on plastic and elastomeric materials. Typically each chemical
interacts with a given plastic or elastomer in a relatively unique
manner. That is, each chemical/material pair has peculiar interactions.
The situation becomes even more complex when multi-component solutions
are involved. Four important factors to bear in mind when considering
epe are:
• In general, there is no such thing as "impermeable" plastic or
rubber clothing.
4
• Lot-to-lot variations do occur and may have a significant
effect on the barrier effectiveness of the CPC. They may go
undetected due to quality control procedures insensitive to
chemical resistance issues.
C. APPLICATION
5
D. REUSE
E. SUBSTITUTION OF CPC
Particular caution is required when substituting clothing from one
manufacturer for that of another manufacturer. Clothing performance is
determined by the type of plastic or elastomer, the specific formulation
of that plastic or elastomer, and the clothing manufacturing process.
For example, materials classified generically as nitrile rubber can
differ significantly in composition and, therefore, chemical resistance.
Testing is the only means for identifying the superior products for a
particular application.
F. COST
Cost is an important consideration in the selection and utilization of
clothing, especially where clothing is likely to be damaged (e.g., tear,
puncture, etc.). In some cases it may be more cost-effective to adopt
the practice of using mUltiple changes of less expensive but relatively
poorer performing clothing than to attempt to extend the use of better
performing but more expensive clothing.
6
CHAPTER 3
PERMEATION THEORY
A. INTRODUCTION
This manual addresses the problem of selecting the most appropriate CPC
for situations where human exposure to potentially hazardous chemicals is
possible. An important concern in such situations is the effectiveness
of the CPC as a barrier to the chemicals. Barrier properties may be
estimated by simple immersion tests wherein the CPC or a portion thereof
is exposed to the chemical(s) of concern, and the material examined for
obvious signs of degradation, swelling, or weight changes. This has been
the traditional method for generating the chemical resistance tables
which are included in many CPC brochures. It is important to note,
however, that permeation may occur with little or no visible or physical
effect on clothing materials.
7
1. Permeation Rate
Classical permeation theory (Fick's Law) states that the chemical permea-
tion rate through a material is a function of the:
2. Breakthrough Time
Breakthrough time is defined as the elapsed time from initial contact of
the outside surface of the CPC with chemical to the first detection of
chemical on the inside surface. In some cases (e.g., when handling
suspect carcinogens), breakthrough time may be the single most important
criterion for CPC selection. Measured breakthrough times are readily
determined by permeation testing and are dependent on the sensitivity of
the analytical method used in the test and the test procedure. These
factors should be considered when comparing breakthrough time data.
C. INFLUENCING FACTORS
1. Temperature
Most CPC permeation data and other chemical resistance information are
generated at 20°-25°C. Permeation rates increase and breakthrough times
decrease with increasing temperatures. The extent of the reduction in
barrier performance with increasing temperature is dependent on the
chemical/material pair.
8
2. CPC Thickness
For a given chemical/clothing material pair:
3. Solubility Effect
Permeation rate is a direct function of the solubility of the chemical in
the CPC material. Solubility is the amount of chemical that can be
absorbed by a given amount of CPC material (i.e., grams liquid per gram
material); absorption may be accompanied by swelling. In general,
chemicals having high solubilities will rapidly permeate the CPC material
in question. Thus, simple immersion testing to determine solubility is
an expedient means for preliminary evaluation of candidate CPC items.
(See Volume II for further discussion of solubility and permeation.)
4. Multi-component Liquids
Multi-component liquids represent a difficult problem relative to the
selection of the most appropriate CPC. Rarely is there any prior CPC
experience with the particular solution of concern, and often the compo-
nents of the solution are not known. Furthermore, mixtures of chemicals
can be significantly more aggressive towards plastics and rubbers than
anyone of the components alone. Finally, the presence of a small
fraction of a rapidly permeating component may carry a chemical that
would permeate at a slower rate if in pure form.
9
5. Persistent Permeation
Once a chemical has begun to diffuse into a plastic/rubber material, it
will continue to diffuse even after the chemical on the outside surface
is removed. This is because a concentration gradient has been estab-
lished with the material, and there is a natural tendency for the chemi-
cal to move towards areas of lower concentration. This phenomenon has
significant implications relative to the reuse of CPC. F0r example, a
possible field scenario is:
• breakthrough does not occur during the workday since the glove
has low permeability to the chemical,
Of course, similar scenarios could occur over both shorter and longer
time frames, for example, morning to afternoon or over a weekend. The
user must take this possibility into account when reuse is considered.
Factors influencing persistent permeation were discussed in Chapter 2,
Part D.
10
CHAPTER 4
For the purposes of the Guidelines, the common items of CPC have been
divided into ten types that represent specific parts of the body for
which protection is designed. The objective is to facilitate the speci-
fication and purchase of CPC. The classification is presented in
Table 4.1 which is followed by sketches of several of the items.
Appendix C is a catalogue of presently available CPC and is organized
according to CPC material, with subcategories for each clothing class.
Appendix G addresses specifically full body protective clothing, and
Appendix H addresses splash suits.
11
TABLE 4.1
CLASSIFICATION OF CPC
Coat, Jacket
Coverall
Apron
Full-body Encapsulating
Hood
Shoe Cover
Boot
Face Shield
Glove
12
FACE SHIELD
HOOD
13
JACKET
COAT
14
\
15
APRON
COVERAllS
16
SPLASH SUIT
17
FULL BODY ENCAPSULATING SUIT
18
CHAPTER 5
FUll-BODY PROTECTION
A. INTRODUCTION
1. Purpose and Scope
The type of chemical protective clothing required for any given situa-
tion depends on the amount. composition and toxicity of the chemical(s)
involved. and the duration of exposure. In the most severe cases or in
cases where the above factors are poorly defined. the highest degree of
body and respiratory protection is required. The EPA has categorized
such protection as Level A protection. (See Appendix I.) As defined.
Level A protection includes a fully encapsulating. single-piece. chemi-
cally resistant ensemble with gas-tight closures and interfaces between
pants/boots and sleeves/gloves. It also includes a pressure -demand.
self-contained breathing apparatus or. a pressure-demand. airline
respirator (with escape bottle). Not all commercially available. fully
encapsulating ensembles meet the EPA's criteria for Level A protection.
The principal point of variance is the means for air supply and respira-
tory protection. (See Section S.B.8.)
19
please refer to other chapters of the Guidelines. Respiratory protec-
tion is not addressed in the Guidelines.
2. Sources of Information
The information presented in this chapter was obtained principally from
the vendors of ensembles and ensemble components and from review of the
literature pertinent to materials testing.
primary materials,
seams,
closures,
gloves,
boots,
exhaust valves,
visors,
air supply systems,
communication systems,
cooling systems, and
fittings.
1. Primary Materials
The primary material is the flexible plastic or rubber film, sheet,
coated fabric, or laminate that composes the major portion of the
external surface area of an encapsulating ensemble. In many cases the
primary material includes a supporting fabric for increased resistance
to tear and puncture. The primary materials of presently available
20
encapsulating ensembles are listed alphabetically in Table 5. l, along
with their respective ensemble vendors. In the table, each primary
material is described from left to right in the sequence of its composi-
tion from external to internal surface. For example, for a material
listed as butyl/polyester/chloroprene, butyl rubber is the outside
surface of the ensemble and the chloroprene is the surface facing the
wearer. Between these surface materials is a polyester fabric.
Nylon®, Dacron (polyester), and Nomex® fabrics are the principal sup-
porting fabrics of encapsulating ensembles. The fabrics may be of woven
or nonwoven type. The fabrics are either laminated to the plastic or
rubber film/sheet under heat and pressure or coated with a solution of
the plastic/rubber material. In addition to supplying strength, the
fabric layer serves as a wear indicator. Its appearance warns of
excessive abrasion and loss of thickness of the chemical barrier layer.
2. Seams
The seams discussed in this section are those formed when two pieces of
the primary material are joined. Other seams, such as those around
closures and fittings, are discussed later. A seam should, at a mini-
mum, equal the physical strength and chemical resistance of the primary
material. Basic seaming techniques and components are described here:
21
TABLE 5.1
Viton/Butyl/Nylon/Butyl Trelleborg
lThe primary materials are described with the external surface first and
2the surface facing the wearer last.
See Appendix D for the address and telephone number of each vendor.
22
Strapping - Strapping is a narrow strip of plastic/rubber material
that is cemented or welded over the seam. Strapping covers the
needle holes of the stitching and provides additional strength to
the seam.
3. Closures
Closures are used to seal the opening through which the ensemble is
donned and doffed. There are three types of closures currently being
used. The pressure sealing zipper is the most common. These zippers
are designed such that the teeth of the zipper protrude only slightly
through a plastic/rubber coated fabric. When the zipper is closed, the
teeth lock, tightly pressing the plastic/rubber on the two sides of the
zipper together forming a gas-tight seal.
23
conjunction with a restraint zipper. The zipper provides closure
strength and the sealing lips provide the gas-tight seal.
The third type of closure utilizes flaps of material (along both sides
of the opening) which are thermally welded together after the suit is
donned. Unsealing the suit is accomplished by cutting off the welded
portion of the flaps. The flaps are initially sufficiently large to
permit the closure to be sealed, cut, and resealed several times.
Closures may be located along one side or diagonally across the front of
the garment, or along the center of the back. Frontal closures allow
the user to seal or unseal his own suit. Rear closures provide easier
donning and doffing but require two people to seal the suit. Rear
closures are also less susceptible to liquid splashes. The lengths of
current closure designs vary. The greater the closure length. the
easier the donning and doffing; however, cost increases with length.
Some garments also have a protective flap which covers the closure. The
flap provides protection to the closure from physical abuse and chemical
splashes.
4. Glove/Sleeve Interface
Detachable gloves are secured to the sleeve by mechanical means and can
readily be replaced by the user. Alternative gloves can be used depend-
ing on the situation. There are three basic types of detachable glove/
sleeve interfaces:
24
slightly smaller in diameter than the other and fits snugly into
the larger one. The larger ring is positioned at the end of and
inside the garment sleeve. The smaller ring is placed inside the
glove at the glove cuff. The glove is then pushed down the garment
sleeve from the shoulder. As the glove passes through the sleeve
opening, the smaller insert is pressed inside the larger one, and a
compression seal is formed.
5. Boot/pant Interface
There are three types of boots used with encapsulating ensembles,:
booties, standard boots (i.e., a boot having sole, heel and closure),
and overboots. Booties are integral, sock-like terminations to the
garment legs. These are typically fabricated of the primary material
and are attached to the garment with a seam (usually of the same con-
struction as the primary material seam). Booties are designed to be
worn inside standard boots. Since the booties are attached to the
garment with a gas-tight seam, the standard boots worn over them do not
need a gas-tight interface. Typically, encapsulating suits with bootie
leg terminations have "splash guards." A splash guard is a flap of
primary material attached to the garment leg which can be pulled over
the top of the boot in order to minimize the entry of liquids into the
standard boot.
25
Standard boots may be integral or detachable. Gas - tight boot/pant
interfaces are achieved by means similar to those described above for
the glove/sleeve interfaces.
6. Exhaust Valves
Encapsulating suits are usually designed such that air from the respira-
tor flows into the suit creating a positive pressure in the suit. The
philosophy behind this design is that a positive pressure in the suit
counters inward leakage of gases and liquids through any openings or
pinholes in the suit. To prevent the build-up of excessive pressures
which can restrict movement and stress the suit seams, encapsulating
suits are equipped with exhaust valves. These valves are one-way
valves designed to open at "cracking pressures" low enough to prevent
excess pressures in and "ballooning" of the suits.
The second type of exhaust valve employs a spring to hold the diaphragm
pressed against the housing and the valve closed. When the pressure in
the suit is greater than the force of the spring, the valve opens. The
advantage of this type of exhaust valve is that the cracking pressure
can be closely controlled.
26
the wearer and to prevent overstressing the seams. The valve must have
sufficient air flow capacity to allow rapid pressure relief.
The design of the valve must provide a tight seal to prevent backflow or
back diffusion of outside air which may be contaminated. Both spring
controlled valves and flapper valves typically have diaphragms of
natural or silicone rubber. The housings are either metal or plastic.
These materials, as well as the metallic spring, are susceptible to
chemical attack. The valves should routinely be inspected for material
degradation and performance.
Both flapper and spring controlled valves are typically installed with
covers designed to prevent direct exposure of the valve to liquid
chemicals. Some valve covers are designed to seal themselves unless air
is flowing out.
7. Visors
Visors are either permanently attached to the suit or are removable.
Replacement of a permanently attached visor usually requires returning
the suit to the vendor. Removable visors employ a mechanical clamping
device and a rubber gasket to attach the visor in a gas - tight manner
seal. Visors must allow clear vision with a wide field of view. The
field of view should not be reduced significantly when the wearer turns
his head. The materials must resist scratches and be chemically resis-
tant. The thickness of the visor is another consideration; thin flexi-
ble visors may be subject to damage from creasing, whereas thick rigid
visors are generally heavier, but can provide better physical integrity.
27
Administration (MSHA) and National Institute for Occupational Safety and
Health (NIOSH). Supplied-air respirators are of two general types:
Egress bottles (or escape bottles) supply air to the wearer in the event
that the airline is severed. Most vendors supply egress bottles as an
option. In order to meet the criteria of Level A or B protection,
egress bottles are required for an ensemble that is supplied air by
umbilical hose.
A major consideration for selecting an air supply system is how well the
garment accommodates the space requirements of the air supply system.
The garment should provide sufficient space in its interior to allow a
comfortable fit to the user wearing a breathing apparatus. Components
of the air supply system should not chafe or cause internal wear of the
~ar.nent.
9. Communications sets
Voice communication when using full-body encapsulating ensemble can be
achieved by three principal means: voice amplification, hard-wire
systems, and wireless devices. Voice amplification systems, as the name
implies, consist of a microphone attached through an amplifier to a belt
mounted speaker. This system is useful when all persons are working
within talking distance of one another. Hard-wired systems consist of a
microphone and speaker headset which are connected by wire directly to
other workers or to a central, base unit and then to other workers.
This system is most conveniently used when the air supply to the
ensemble is by umbilical hose. Wireless systems are based on radio
transmitters/receivers and allow the greatest range of operations.
28
Microphones may be held in place against the neck (i.e., throat micro-
phones), mounted on or in the respirator face piece, suspended in front
of the mouth on a boom or, in the case of bone conduction microphones,
mounted somewhere on the head. Neck microphones are well accepted and
function well in high noise areas; however, some users report problems
due to slippage of the microphone. Readjustment is difficult when
wearing an encapsulating ensemble.
29
medium. Similar to the passive systems, ice, dry ice, and
frozen gels are the principal heat sinks. These systems are
battery powered and typically have operating periods of one to
four hours. Some systems can be controlled by the wearer.
In addition to the above systems, cooling can also be achieved from the
evaporation of water that is sprayed over the surface of the ensemble.
As with air supply systems, the selected cooling system (if any) should
not chafe the inside of the garment.
11. Fittings
Certain ensemble configurations include umbilical or other external air
supply, cooling and communication systems. Fittings are required where
the lines for these systems enter the ensemble, usually through the
primary material. The fittings should have standard threads or quick
disconnects for attaching the lines. These fittings and the means with
which they are attached to the ensemble must be selected with full
consideration to chemical resistance. Furthermore their attachment to
the ensemble must be sufficiently strong to prevent their being pulled
out.
30
provides the user with the full, gas-tight protection offered by the
standard suits and protects the (more expensive) standard suit from
gross contamination.
C. ENSEMBLE EVALUATION
1. Introduction
The performance of an encapsulating ensemble depends on its chemical
resistance, physical properties, fit, design features, and s~z~ng.
Chemical resistance is discussed elsewhere in the Guidelines. The
physical characteristics of encapsulating ensembles are for the most
part determined on the component level and are described below. Methods
for testing the overall ensemble are described in Section S.C.4.
Limited information is also provided for sizing and fit considerations.
2. Physical Properties
Standard tests exist for measuring many of the physical properties of
ensemble materials and in many cases these tests are specific to an
ensemble component. More than one test method exists for measuring some
physical properties. Selected standard tests are listed in Tables 5.2
and 5.3. ASTM standard test methods were selected because they are
readily available, regularly updated to reflect changes in the state of
the art, and actively supported by an identifiable group of persons that
are available for consultation.
31
TABLE 5.2
32
TABLE 5.3
Antifog MIL-A-1542B
• • 1
D~stort~on ASTM DBBl
1
Impact Strength ASTM D3029
1
Light Transmission and Haze ASTM Dl003
1
Key property. See Section S.C.3.
33
Brittleness - Evaluation of the lowest temperature at which flexi-
ble materials will not exhibit fractures or cracks when subjected
to specified impact conditions.
34
Puncture Propagation Tear - The force required for a sharp object
to snag and subsequently tear a material.
35
known as zipper crosswise strength and can be applied to other
types of garment closures.
4. Chemical Resistance
Other chapters of the Guidelines address the issue of chemical resis-
tance from the perspective of generic clothing materials categories.
For example, all butyl rubber materials regardless of thickness, source,
and formulation have been classified together in order to form the
chemical resistance recommendations in Matrix A. Generic classifica-
tions provide general guidance as to chemical resistance but, as noted
elsewhere, chemical resistance can vary significantly within a generic
class. In Table 5.4, ensemble-specific chemical resistance information,
for the fifteen chemicals composing the standard battery of test chemi-
cals in ASTM FlOOl-86, is presented. Breakthrough time and permeation
rate data are presented when available. In some other cases, qualita-
tive ratings of chemical resistance are listed as supplied by the
ensemble vendor. The qualitative ratings should be used with extreme
caution because, in several instances, it would appear that they are
generic rather than specific to the clothing material.
Pressure testing measures the integrity of the suit and visor material,
suit seams, and suit closures for gas tightness. The test involves the
inflation of the garment to a specified pressure and either measuring a
pressure drop over time or applying a soap solution to the outside of
the garment to detect leaks (by the appearance of bubbles). The suit
exhaust valves must be closed to perform the test and a provision must
36
TABLE 5.4
PRODUCT·SPECIFIC CHEMICAL RESISTANCE INFORMATION FOR FUll BODY ENCAPSULATING ENSEMBLES
..
'ii
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-1
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.J!Z 2:
:i I 1- « .!!
r=
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c: '10
fi o • Ii .~ 1.-
1= Ii ~i
I ! ~« 1£ iz_C~ ~1 ..."
AI:
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...i~-
Thickn ...
(mil.) «!! «~ c3~ o_ s!!: w- %2: .t: ~- ~
:: ... -
MBlerial Vendor I:- "'- <II-
Chlorinated Polyethylene ILC I4 1 20 0.25110201 l.ll I 0.1 I ) O.l ( ) 8 C 11 I >ll >ll I 1( ) >l( ) >ll ) C 0.5 I ) 1.21 I
Chlorobutyl/NomexlChlorobutyl Arrowhead 19
IlC 20
PVC/Nylon Andover 15
Tellon/Nomex/Tellon ChemFab 18 >8 I ) >81 I O.l{O.05 O.S{O.02, >B{ ) >8( ) >B{ I >S{ ) >SI ) >S ( I >B( ) >8 ( I >SI ) >8( ) >B( I
Viton/Nomex/Chlorobutyl Andover(21 20 U U A 8 U U U A C 8 8 A A U A
Viton/Butyl/Nylon/Butyl Trelleborg(31 NO 3 3 1 2 3 l 2 2 2 2 2 2 l 2
11) Number pleceding parentheses is breakthrough time in hours; number in par.nth.se. Is permeation rate illl'g/cm'/min.
If no parenthe,e. follows number. see footnote (31.
121 A • recomme"ded; B ; minor effect; C • moderate effect; U ~ not recommended
(31 I • not eftected; 2' slightly effected; 3.4.5' material can be destroyed
141 A' recommended; B • minol·to·moderat. effect; C'· moderato to seVOIO; X • not recommended
(51 No <lata
be made for attaching a pressure gauge. Some manufacturers specify the
pressure to which the suit should be inflated. The proposed ASTM method
specifies a maximum inflation pressure (3 inches water gauge pressure),
a test pressure (2 inches water), and an allowable pressure drop (20%)
over a three-minute period. It also requires using the soap solution to
locate leaks if the suit does not meet the pass/fail criteria.
38
D. QUALITY CONTROL
There is no industry standard test series by which the quality of fully
encapsulating ensembles is controlled. The level of manufacturer
quality assurance ranges from simple visual inspections to a large
battery of tests on the ensemble and its components. Some manufacturers
perform lot-by-Iot tests to verify chemical resistance and physical
properties of the primary materials. All the vendors listed in
Table 5.1 subject completed ensembles to pressure (inflation) testing,
as previously described. While closure, interface or seam imperfections
are thereby located and corrected prior to shipping, this does not test
exhaust values.
None of the vendors provided any insight into m~n~mum physical property
values or performance levels acceptable for any of the individual
components of an encapsulating ensemble. Indeed, while limits would be
most useful in evaluating suit components, it would be difficult to set
such limits since they are highly dependent on the application condi-
tions.
Both the ASTM F-23 Committee and the NFPA Subcommittee on Hazardous
Chemical Protective Clothing are developing standards which would
increase the information provided by manufacturers on the performance of
these garments. The proposed ASTM standard would specify documentation
requirements for chemical protective suits and suit components. The
NFPA is writing performance standards for each type of chemical protec-
tive suit in its proposed suit classification system.
E. SPLASH SUITS
Level B (and Level C) protective clothing, as defined by the EPA, is
used in situations where the atmospheric concentration of toxic sub-
stances requires a high level of respirator protection, but less skin
protection than Level A. (See Appendix I for further explanation.) The
garment should cover most of the body, but is not completely sealed.
This type of clothing is commonly referred to as a "splash suit."
Several of the major manufacturers of splash suits and their products
are listed in Appendix H. The styles and primary materials are given
along with the major construction features.
39
chloroprene, styrene/butadiene rubber, polyurethane, a blend of nitrile
rubber and polyvinyl chloride, and butyl rubber. The seams of the
primary material are usually stitched and cemented or welded.
The closures on splash suits need not be liquid proof. They typically
are either simple zippers or snaps. The snaps can be metal or plastic.
Closures often have a storm fly front, which is an extra flap of materi-
al in front of the closure to prevent direct liquid contact with the
closure.
There are no current ensembles which provide both flame and chemical
protection. Nearly all CPC materials will ignite and burn when con-
tacted by flame. These ensembles should not be used for situations
where the probability of contact with flame or flashover conditions is
high. Combined thermal and chemical protective suit systems should be
considered carefully. Thermal protection may be worn either inside or
outside the chemical protective suits. When externally worn, thermal
protective clothing is subject to contamination and must be disposed of
after use. When worn inside (e.g., aramid fiber jumpsuit), the integ-
rity of the chemical protective clothing will be lost in a flame situa-
tion, resulting in a potentially life-threatening situation. Alterna-
tively, thermal protection can be worn both inside and outside the suit.
40
In any of these cases, the additional burden (weight/heat stress) to the
wearer must be considered.
41
TABLE 5.5
PRIMARY MATERIAL
SEAMS
STITCHED APPLICABLE TO ALL MATERIALS REQUIRES STRAPPING OR SEALANTS LAPPED AND DOUBLE-STITCHED CONSTRUCTIONS
MUST BE TESTED FOR CHEMICAL RESISTANCE PREFERRED
PENETRATION THROUGH PINHOLES
TABLE 5.5 (CONTINUED)
CLOSURES
PRESSURE SEALING SIMPLE AVAILABLE MATERIALS HAVE LIMITED STAINLESS STEEL TEETH AND SLIDER AVAILABLE
ZIPPER CHEMICAL RESISTANCE FLAP MAY BE ADDED TO PROTECT ZIPPER
SEALING LIP PROTECTS ZIPPER FROM ENVIRONMENT TWO·STEP PROCESS: ZIPPER AND SEAL
ZIPPER REQUIRES DEXTERITY
SOME SEALING LIP MATERIALS MAY BECOME
STIFF/UNOPERABLE IN COlD WEATHER
FRONT MAY BE USER OPERATED, IF ZIPPER MORE DIFFICULT TO DON AND DOFF SUIT
EMERGENCY DOFFING, IF ZIPPER MORE SUSCEPTIBLE TO CHEMICAL EXPOSURE
AIRLINE LONG WORK PERIODS LIMITS RANGE OF OPERATIONS CHEMICAL RESISTANCE OF AIRLINE SHOULD
CODLING AIR CAN ALSO BE SUPPLIED BE CONSIDERED
TABLE 5.5 (CONTINUED)
'.
C(JfI>ONENT ADVANTAGES DISADVANTAGES COMMENTS
HARD-WIRED SYSTEM EXTENDS RANGE OF OPERATION REQUIRES ALL PERSONS BE CONNECTED BY WIRE
WIRELESS VOICE/HEARING QUALITY HIGH BATTERY LIFE LIMITS OPERATION PERIOD USER MUST DECIDE AMONG CONTINUOUSLY ON,
ALLOWS WIDE RANGE OF OPERATION SOME TRAINING REQUIRED PUSH TO ACTIVATE, OR VOICE ACTIVIATION.
ALSO, AMONG SIMPLEX, DUPLEX OR HALF-DUPLEX
B. PRE-USE INSPECTION
Each item of clothing should be inspected immediately upon removing it
from the package. First determine that the material of construction is
that which was ordered or specified for the task at hand. This will
involve comparing the item number with the catalogue number. Items of
different materials should be kept separated. (See Storage below.)
•
Visually inspect the items for defects such as imperfect seams, non-
uniform coatings, pinholes, malfunctioning closures, and tears. Some
flexible materials may stiffen during extended storage periods; flex the
product and observe for surface cracks or other signs of shelf life
deterioration. Pinholes may be detectable by holding the garment up to a
light in a dark room. Gloves with holes can be identified by pressuriz-
ing the glove. This can be accomplished by blowing into the glove and
47
then tightly rolling the gauntlet towards the fingers (thereby reducing
volume and increasing pressure) while observing that the glove holds
pressure. Alternatively, the glove could be inflated and then held under
water and examined for the presence of air bubbles. Full-body encapsu-
lating ensembles should be checked for the operation of pressure relief
valves and the fittings at the wrists, ankles, and neck. Standard
methods for leak testing full-body ensembles are discussed in Chap-
ter S.C.S.
c. DONNING
Once the clothing is on, all closures should be secured and checked. Use
the "buddy system." Finally, the fit of the clothing should be evalu-
ated. Improperly fitting protective clothing represents a severe poten-
tial hazard. Where clothing is too small, worker movement is restricted,
likelihood for tear is increased, and the potential for accelerated
worker fatigue is increased. Where the clothing is too large, the
possibility of snag is increased, and the dexterity and coordination of
the worker may be compromised.
D. IN-USE
During the course of the work task, each worker should periodically
inspect his protective clothing. Of principal concern are tears, punc-
tures, seam discontinuities, or closure failure that may have developed
while working. Evidence of chemical attack such as discoloration,
swelling, stiffening, or softening should also be noted. (Note: Permea-
tion can occur without any visible effects on the clothing material.)
Any item of clothing that has been physically damaged or chemically
degraded should be doffed and replaced as soon as safely possible.
E. DOFFING
48
..
Detailed doffing procedures have been developed by the EPA and are
contained in the Interim Standard Operating Safety Procedures of the
Office of Emergency and Remedial Response, Hazardous Response Support
Division. Part 7 and pertinent Annexes of the Interim Standard are
included herein as Appendix J.
They address:
• decontamination, and
It should be noted that, at the present time, there is very little docu-
mentation regarding clothing reuse. The use of disposable clothing, of
course, obviates the problem. Where reusable CPC is required, however,
the type of problem discussed above can best be. minimized by selecting
the most resistant clothing for the chemical at hand; such clothing will
absorb little or no chemical. Furthermore, used clothing should be
stored in well-ventilated areas. Ideally, there should be good air flow
around each item of clothing.
49
Finally, in storing protective clothing, different types of materials of
clothing should not be mixed. For example, gloves which are black in
color and virtually indistinguishable from one another may be made from
nitrile, neoprene, Viton, polyvinyl chloride, butyl, etc., materials.
Each material has unique chemical barrier properties. Mixing the gloves
significantly increases the chance that a worker will be wearing the
wrong clothing for the chemical of concern. It may be possible to
separate mixed gloves by using the manufacturer's product number that is
often found in the gauntlet area.
50
CHAPTER 7
CPC VENDORS' LITERATURE
A. INTRODUCTION
The most widely available sources of information on CPC are the product
catalogues of the CPC manufacturers and vendors. These booklets contain
descriptions of the types, sizes, and varieties of CPC produced by each
manufacturer. In most cases the basic materials of construction of the
CPC are also included in the product descriptions. Many manufacturers
also include information pertinent to the chemical resistance of their
products or of the materials from which the products are fabricated.
This information is often in the form of tables of qualitative chemical
resistance ratings or use recommendations for the products/materials and
particular chemicals. However, the leading manufacturers are increas-
ingly providing information from permeation testing. A few vendors also
provide information pertinent to abrasion, tear, etc., resistance but in
general most catalogues do not address such application-related issues.
Since the focus of these Guidelines is the selection of clothing for
protection from exposure to chemicals, the vendors' chemical ratings and
recommendations tables are the focus in this chapter; they are discussed
in more detail in Chapter 4 of Volume II.
Of the 150 CPC catalogues which were obtained and reviewed in the prepa-
ration of the Guidelines, 26 contained some form of chemical resistance
information for the products described therein. The information was both
qualitative and quantitative. The qualitative ratings/recommendations
typically were on a four-grade scale of "excellent," "good," "fair," and
either "poor" or "not recommended." In a small number of cases, five- or
six-grade scales were used. With the exception of those tables based on
permeation testing, these tables do not include information as to the
basis for the recommendations. From the results of interviews with
several of the vendors who do not supply permeation test results, it
would appear that, at present, most do not have (or at least are unwill-
ing to share) performance specifications or quantitative test data for
their products. The ratings/recommendations for a particular type of
product (for example, nitrile gloves) for a particular chemical may vary
from vendor to vendor. Both of these factors--little or no test data and
inconsistencies among recommendation tables--make the selection, from
qualitative information, of the best CPC for a given application a
difficult and uncertain task.
51
must be performed with caution since test results can be influenced by
the testing method. For example, analytical sensitivity can strongly
influence the detection of breakthrough. Also, some vendors report the
earliest breakthrough time found in replicate tests while others report
an average value.
Given the above facts, the most important consideration to keep in mind
when using vendor recommendation tables, including those based on permea-
tion tests, is that the tables are intended to provide guidance in the
selection of CPC. That is, the tables are meant as a place to start the
CPC selection process. The tables are meant for identifying candidate
CPC for further evaluation and are particularly useful for identifying
CPC from which poor performance would be expected and, therefore, which
can be dropped from consideration. In no way do the recommendations
address the wide variety of uses, challenges, and care to which the CPC
may be subjected. Most vendors strongly emphasize this point in the
descriptive text which accompanies the tables. Secondly, the vendors'
recommendations were not developed by, nor are they sanctioned by.
industrial hygienists or other safety professionals. CPC manufacturers
are in business to sell clothing and not to set the standards for safety
at any given work site. In conclusion, the principal purpose of the
catalogues is to provide information about products in terms of the
sizes, styles, and materials of construction. The ratings charts should
only be used as a starting point for further evaluation if chemical
resistance is an issue.
52
A result is that the recommendation may not take into account
formulation modifications that are required to put the material
into a form appropriate for CPC.
the performance of the same "nominal" product may also change. There is
no indication that recommendations are routinely updated to reflect these
changes. except in a few exceptional cases. These considerations may
also apply to permeation data and the recommendations based on them.
Again, the CPC recol11l1Jendation tables should only be used for guidance.
This includes those presented in the next chapter.
53
CHAPTER 8
CPC RECOMMENDATIONS
In this chapter, CPC recommendations for approximately 500 chemicals or
aqueous solutions are presented. In addition, the chemicals have been
grouped into generic families (e. g., acids, amines, etc.) and general
recommendations are made for each family which is represented by more
than one chemical having CPC performance information for a given mate-
rial. The recommendations are contained in Matrices A and B, and the
data on which the recommendations are based are tabulated in Appendices A
through E in Volume II. Appendix F in Volume II contains permeation data
for several non-aqueous, multi-component solutions. The matrices are
complemented by Appendices B through H which contain information perti-
nent to the acquisition of CPC such as a directory of vendors' addresses
and telephone numbers.
2. Chemical Classes
An alphabetical list of the chemicals is presented in Appendix B. Note
where a percentage follows the name of the chemical, it is indicative of
the concentration of the chemical in water. All other liquids are
single-component. Multi-component organic solutions are not addressed
although permeation data for some are presented in Appendix F in
Volume II. The right-hand column of Appendix B contains two pieces of
information for each chemical: the chemical abstract number (CAS number)
and a numeric "chemical class" code. The code is the "key" to Matrix A
since the matrix is organized numerically by chemical class, with the
code shown in parentheses following the generic class name. The chemical
classification scheme is summarized in Table 8.1 and is based on the
54
TABLE 8.1
ALDEHYDES
Aliphatic and Alicyclic 121
Aromatic and Heterocyclic 122
AMIDES
Amides 132
ANHYDRIDES, CARBOXYLIC
Aliphatic 161
CYANIDES
Cyanides 215
ESTERS, CARBOXYLIC
Formates 221
Acetates 222
Higher Monobasic 223
Polybasic 224
Aromatic Phthalates 226
55
TABLE 8.1 (Continued)
ETHERS
Aliphatic 241
Aromatic 242
Alkyl-Aryl 243
HALOGEN COMPOUNDS
Aliphatic, Unsubstituted 261
Aliphatic, Substituted 262
Aromatic, Unsubstituted 263
Aromatic, Substituted 264
Polynuclear 265
Vinyl Halides 267
HETEROCYCLIC COMPOUNDS
Nitrogen, Pyridines 271
Nitrogen, Quinolines 272
Nitrogen, Others 274
Oxygen, Epoxy Compounds 275
Oxygen, Furan Derivatives 277
Oxygen, Others 278
Sulfur 279
HYDRAZINES
Hydrazines 280
HYDROCARBONS
Aliphatic and Alicyclic 291
Aromatic 292
Polynuclear 293
HYDROXYL COMPOUNDS
Aliphatic & Alicyclic, Primary 311
Aliphatic & Alicyclic, Secondary 312
Aliphatic & Alicyclic, Tertiary 313
Aliphatic & Alicyclic, Polyols 314
Aromatic 316
56
TABLE 8.1 (Continued)
INORGANIC ACIDS
Inorganic Acids 370
INORGANIC BASES
Inorganic Bases 380
INORGANIC GASES
Inorganic Gases 350
INORGANIC SALTS
Inorganic Salts 340
ISOCYANATES
IS,ocyanates 210
KETONES
Aliphatic & Alicyclic 391
Alkyl-Aryl 393
LACTONES
Lactones 400
MISCELLANEOUS
Miscellaneous 560
NITRILES
Aliphatic & Alicyclic 431
Aromatic 432
NITRO COMPOUNDS
Unsubstituted 441
Substituted 442
Nitroso 443
ORGANIC SALTS
Organic Salts 550
ORGANO-METALLIC COMPOUNDS
Organo-Meta11ic Compounds 461
57
TABLE 8.1 (Continued)
ORGANO-PHOSPHOROUS COMPOUNDS
Organo-Phosphorous Compounds 460
ORGANO-SILICON COMPOUNDS
Organo-Silicon Compounds 480
PEROXIDES
Peroxides 300
QUINONES
Quinones 490
SULFUR COMPOUNDS
Thiols 501
Sulfides & Disulfides 502
Sulfoxides 503
Sulfonic Acids 504
Sulfonyl Chlorides 505
Others 507
58
system used by the Eastman Kodak Company. This system was selected
because it addresses a large fraction of the chemicals of concern herein.
Other classes have been added as needed.
In Matrix B (pp. 121-124), CPC recommendations are provided for the same
33 materials but in this case for generic famUies of chemicals. The
chemicals in each family and on which the Matrix B recommendations are
based are readily determined from Matrix A. Note that not all classes in
Matrix A are presented in Matrix B; furthermore, recommendations are not
given for all materials for all classe~. The criterion for being given a
recommendation in Matrix B is that the class must contain more than one
chemical with CPC recommendation for the material of concern. In many
cases there was considerable variability among the recommendations for
chemicals within a class; these 8.re indicated by double asterisks (**).
In these cases, please refer to Matrix A for specific information.
3. Materials
The 12 materials for which the most information is available are listed
across the top of the matrices. Where information on other materials was
available, recommendations for these materials are in the right-most
, column of the matrices. There were 21 such materials. A general charac-
terization of several of the physical properties of 13 of the materials
is presented in Table 8.2.
The 33 material categories were reduced from the approximately 145 types
and forms of clothing materials listed in Appendix E, and represent the
materials of construction for well over 90% of the CPC considered in the
Guidelines.
59
TABLE 8.2
Nitrile-Butadiene E E E G E G Medium
Rubber (NBR)
Neoprene E E G G E G G Medium
Polyethylene G F F P Low
Polyurethane E G E G G G G High
Styrene-Butadiene E G G G Low
Rubber (SBR)
* Ratings are subject to variation depen~ing on formulation, thickness, and whether the material is supported by fabric.
E-excellent; G-good; F-fair; P-poor
Selections based on the matrices' recommendations do not guarantee
protection since in no way do the matrices take into account such key
issues as the application of the CPC or quality differences between CPC
products.
4. Performance Information
The information on which the matrices are based is from three sources:
The vendors use a variety of rating scales; some have three grades, most
have four grades, and a few have five or six grades. In order to compare
ratings, a normalized four-grade system (i.e., A, B, C, D) was developed.
Briefly, products with the highest rating in a four- or three-grade
system or the highest two ratings in the case of a six-grade system were
given a normalized rating of "A." A normalized rating of "B" was given
to the next highest vendor's ranking, which was generally call "good,"
but in some three-grade systems was called "fair." A normalized rating
of "C" was given to the third highest vendor ranking except for the
three-grade systems. Typically, vendors called this ranking "fair."
Finally, all vendors' rankings of "poor" and "not recommended" were given
a normalized rating of "D."
B. RECOMMENDATIONS
61
consistency of the information for each pair. (The rationale is· de-
scribed in detail in Appendix H of Volume II.) For each data base, the
result was a classification of each chemical/material pair into one of
the four following groups:
or
or
Single and double, upper and lower case "r's" and "n's" are used to
convey the recommendations. Briefly, RR, R, rr, and r indicate various
degrees of good resistance and NN, N, nn, and n indicate various degrees
of poor chemical resistance. Double characters indicate that there are
test data to support the recommendations, and single characters indicate
that only qualitative information was available. Upper case characters
indicate consensus and a relatively large amount of information, whereas
62
TABLE 8.3
QUALITATIVE DESCRIPTION OF RECOMMENDATIONS IN MATRIX A*
Qualitative Ratings
Few/Excellent Many/Felr
Quantity/
MIIRY /E xcellent or or Mlny/Poor None
Resistance
Many/Good Few/Poor
Many/Excellent RR RR •• •• RR
!-.
Few/Excellent
or rr rr •• •• rr
Many/Good
Test
Data
Many/Fllr
or nn nn nn nn nn
Few/Poor
Many/Poor NN NN NN NN NN
No
None R r n N Recommend&-
tion
C. USER INSTRUCTIONS
To make the most effective use of the Guidelines, references must be made
to the matrices and the appendices. Assuming that the chemical(s) for
which protection is required is known, the procedure would be as follows:
64
on the basis of the recommendations for the similar chemicals.
Note that in Matrix B, asterisks are indicative that the
particular material exhibited considerable variability in its
resistance to the chemicals of the given class. In these cases
reference to Matrix A and caution in CPC selection is highly
advised.
65
MATRIX A
RECOMMENDATIONS BY CHEMICAL
66
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Source: Arthur D. Li tt Ie, Inc.
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Source: Arthur D. Little, Inc.
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Hexanal r r
Isobutyraldehyde rr nn NN NN
Propionaldehyde rr nn fiN fiN
Trichloroacetaldehyde on rr NN nn
Aromatic and Hetrocycfic (122)
I-Iote' Numvers in par'p.nthcses are chemical class codes -- see fable 8.1 arid API,',milx 3.
For explanation of recommendation codes (e.g. RR,R,NN, etc,) Ree Tablg 8.3.
Source: Arth!Jr O. Little, Irc,
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nn nn nn nn NEOP+NAT RUBe n)
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RR nn NN n NN nn NN N NN TEfLON( rr)
Dimethylformamide NEOP+-NAT RUB(nn)
SBR( rl
VIT/CLORBUTL(rr)
SILVERSHIELD(rr)
NEOP+-NAT RUB( r)
Formamide, 30%
rr nn nn nn nn POLYURETHANE(nn)
Hexamethylphosphoamlde
r r r r r
Urea
Amlnes, Aliphatic Be AI leyel Ie
Primary (141)
Allylamine nn NN nn NN
Butylamine nn NN n NN nn NN n TEFLON(rr)
'oJ
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Cyc lohexylamlne nn NN nn nn
Ethano I am I ne rr r n RR RR RR RR rr rr rr n n NEOPRENE+SBR( n)
POLYURETHANE( n)
SBR( n)
SBR/NEOPRENE( n)
Hote: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Dibutylamine n nn rr NN rr n
Diethylamine nn n NN NN n NN NN n NN nn n SARANEX(nn)
SBR( r)
VIT/CLORBUTL(nn)
SILVERSHIELO(rr)
Di isobutylamine nn rr rr rr
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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For exrolIHlnLion of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Anliur n. tit.tle, Inr..
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Tertiary (1113)
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g, RR,R,NN, etc.) see Table B.3.
Source: Arthur D. Little, Inc.
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SARANEX( rr)
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·3-Methylamlnopropylamlne rr HN nn NN
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N,N,N',N'-Tetramethylenedlamlne nn nn NN nn
-..J
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Triethylenetetramine rr rr nn rr
Amines, Aromatic
Primary (145)
Note: Numbers in parentheses are chemical class codes· -- see Table 8.1 and AppendIx 8.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc. .
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Note: Numbprs in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for axplanation or recommendation codes (e.g. RR,R,NN, etc.) see Table B.3.
Source: Arthur D. L i tt Ie, Inc.
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Potassium Cyanide r
Sodium Cyanide, <30% rr
Sodium Cyanide, 30-70% NN
Esters, Ca rboxyl Ie
Formates (221)
Ethylene Acetate n n n n
Ethyl formate r n r R n R N n POL YURETHANE I n)
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Methyl Ch loroformate nn
Methyl Formate n n
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B~
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Glycerin Trlacetate .. r
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR.R.NN. etc.) see Table 8.3.
Source: Arthur D. Little. Inc.
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Note: Numbers in parentheses are chern/cal class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Li tt Ie, Inc.
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For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Aromatic Phtha/,1tes (226)
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SBR( r)
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Dimethyl Phthalate r r
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Di-Sec-Octyl Phthalate r r
Methyl Sa I icylate n r
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Ethyl S I I iea te r r
ISflbutyl Ni tri te nn nn NN nn
letrabutyl Orthotitanate r r
lrlisooetyl Phosphate r r
Note: Numbers In parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
SOUl co: Arthur D. Li tt Ie, Inc.
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Dibenzyl Ether r n N R r r R r POLYURETHANE( n)
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Dibutylether n n
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2-Ethoxyethyl Acetate n n rr n n r NAT+NEOP+NBR( r)
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Ethyl Ether NN r n NN NN nn NN NN RR nn NN n TEFLON( rr)
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NEOPRENE+5BR( r)
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5BR( R)
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Methyl Cellosolve rr n R r nn R NEOP+NAT RUB(nn)
NA T+NEOP+NBR( r)
POLYURETHANEI nJ
5BRI n)
5BR/NEOPRENE( n)
Methyl Cellosolve Acetate
Methyl Cellulose n r r r POLYURETHANE( r)
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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l,3-Dioxolane n n
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Halogen Compounds
A I i pha tie, .IJnsubstituted (261)
Allyl Chloride r rr n TEfLON( rr)
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Chlorodibromomethane nn nn NN rr
Ch I0 r'ododeca ne r n
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur' D. I ittle, Inc.
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Note: Numbers In parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. little, Inc.
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For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
SOtHCe: Arthur D. Little, Inc.
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Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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For explanation of recommendation codes (e.g. RR,R,NN, etc. I see Table 8.3.
Source: Arthur D. Little, Inc.
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1-Chloro-2-propanol rr NN NN rr
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1,2-Dibromo-3-chloropropane n n
00
1.0
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2,2'-Dichloroethyl Ether nn RR TEFLON( rr)
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Ethylene Chlorohydrln rr r rr rr rr n
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2,2,2-Trichloroethanol SARANEX(nn)
Trifluoroethanol rr rr NN RR NN NEOP+NAT RUB(rr)
NEOP/NAT RUB(rr)
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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SARANEX(nn)
Aromatic, Substituted (26/i)
Pentachlorophenol NN rr NN rr
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little. Inc.
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For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Nitrogen, Pyridines (271)
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',2-Epoxybutane nn NN rr NN
Ethylene Oxide r r n NN n n
Note:' Numbers in parentheses are chemfcal class codes -- see Table 8.' and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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lIydrazines (280)
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TEfLON(nn)
NEOP/NAT RUB(NN)
l,2-Dimethylhydrazine n n
Hydraz I ne rr n r rr rr rr n CHLOROBUTYL(rrl
TEfLON( nn)
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Methy I hyd raz i ne NN nn nn rr CHLOROBUTYL(rr)
CR 39(rr)
TEfLON(NN)
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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SBR( nJ
SBR/NEOPRENE( n)
Butene n r r n
Butylene r r r SBR( rJ
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix 8.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Naphtha, V.H.& P N rr r N nn NN rr NN rr NN r n NEOP+NAT RUB(NN)
NEOPRENE+SBR( n)
POLYURETHANE( R)
SBR( n)
SBR/NEOPRENE( n)
Octadecane r n
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Tabie 8.3.
Sourc.: Arthur D. Little, Inc.
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Aromatic (292)
Benzene NN nn rr NN NN NN NN NN NN NN nn rr EVA(NN)
TEFLON( NN)
NEOP+NAT RUB(NN)
NEOPRENE+SBR( n)
POLYURETHANE(NN)
NONWOVEN PE(NN)
SARANEX(NN)
SBR( N)
NEOP/NAT RUB(NN)
PV ACETATE( rr)
SILVERSlfIELD( rr)
SBR/NEOPRENE( n)
p-tert-Butyl Toluene RR rr rr rr RR SILVERSHIElD(rr)
3-Chloro-2-methylpropene nn NN NN rr
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Cumene rr r n
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Dlethyl Benzene r n
Dllsopropyl Benzene (a I I I somers) r n
Divlnyl Benzene RR rr rr RR SILVERSHIELD(rr)
Ethyl Benzene r n nn n n TEFLON( rr)
Gaso line nn r rr N rr NN rr NN rr NN r nn NEOP+NAT RU8(NN)
NEOPRENE+SBR( n)
POLYURETHANE( R)
S8R( n)
S8R/NEOPRENE( n)
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Arom6tic (cont.) (292)
JP-4, Jet Fuel n r
Note:' Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Hydrocarbons (cont.)
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NEOP+NAT RUB(NN)
SBR( n)
NEOP/NAT RUB(NN)
m-Xylene NN nn nn rr RR
o-Xylene nn nn nn rr rr
p-Xylene nn nn rr NN rr
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Allyl Alcohol RR rr rr RR rr nn NN rr rr TEFLON( rr)
SARANEX(rr)
Amyl Alcohol rr r NN RR NN nn nn rr NN rr r NEOPRENE+SBR( R)
POL YURETHANE ( R)
SBR( R)
SBR/NEOPRENE( R)
Butyl Alcohol R r nn RR nn RR RR nn nn r TEFLON( rr)
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NEOPRENE +SBR ( n)
POL YURETHANE( r)
SBR( n)
SBR/NEOPRENE( n)
n-Butyl Carbitol r r
Butyl Cellosolve r NN rr rr n NAT+NEOP+NBR( r)
....
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Ca rb i to I r r
0 Diacetin r r
Diethylaminoethanoi rr nn rr rr
Ethano I, 30-70% rr
Ethano I, >70% rr
Ethanolamine rr r n RR RR RR rr rr n RR n n NEOPRENE+SBR( n)
POLYURETHANE( n)
SBR( n)
SBR/NEOPRENE( n)
Ethyl Cellosolve rr r NN NN NN NN NN n NAT+NEOP+NBR( R)
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur O. Little, Inc.
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PV ACETATEI rr)
SBR/NEOPRENE( r)
Methanol, <30S rr
Methano I, >10% rr
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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2.2.2-TrlchlorDcthanol SARANEX(nn)
2-Furylmethallol n r
Note: ' Numbers in parentheses are chemical class codes -- see Table 8. 1 and Appendix B.
For explanation of recommendation codes (e.g. RR.R.NN. etc. ) see Table 8.3.
Source: Arthur O. l.ittle, Inc.
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Source: Arthur D. Little, Inc.
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n-Butyl Benzoate r r
Creosote n r H rr r R r rr r SBR( r)
Creosote, Wood rr rr
Crasols n r r nn n n SARANEX(rr)
Ethyl Benzoate r r
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Pentach,orophenol NN rr NN rr
Phenol R nn NN nn n NN rr nn NN n TEFLON(rr)
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NAT+NEOP+NBR( r)
POLYURETHANE( r)
SBR( n)
NEOP/NAT RUB(rr)
SBR/NEOPRENE( r)
Pheno I, <30~ rr
Phenol, >70% RR NN nn NN rr NN RR
Pic ric Ac i d r R R r R n r r
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B;
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Inorganic Acids
Inorganic Acids (370)
Note: Numbers in parentheses are che.lcal class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur O. Little, Inc.
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For explanation of recommendation codes (e.g. RR,R,NN, I see Table 8.3.
",-"~",,,. Arthur D. Little, Inc.
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for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Li tt Ie, Inc.
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For explanation Of recommendation code. (e.g. RR,R.NN, etc. ) see Table 8.3.
Source: Arthur D. Li tt Ie, Inc.
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Inorganic Bases (380)
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Inorg6n;c Cases (350)
Ammonia n r r n r
Bromine NN
Ch lorlne n r rr n rr n NN NN rr rr SARAAEX(rr)
FI uorl ne n r r r n
Hydrocyanic Acid rr r rr nn r
Hydrogen Phosphide nn NN nn nn
Hydrogen Sui fide r r n R r R POLYURETHANE( n)
SBR( r)
5BR/NEOPRENE( n)
Nickel Carbonyl r r r
NI trlc Oxide r r r
HI trogen Dioxide n n
.....
.....
0
Nitrogen Tetroxide nn rr n rr nn nn n CHLOROBUTYL(rrl
TEFLON(NN)
eR 39(rr)
Note: Numbers in parentheses are chemical class codes -- see Table B.l and Appendix 8.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table B.3.
Source: Arthur D. little, Inc.
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Arsenic Trichloride n n
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
s.
Source: Arthur D. Little, Inc.
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Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Ketones
A I iphatic & Alicyclic (391)
Acetone RR HN NN NN nn NN NH HN NN NN TEFLON( rr)
NEOP+NAT RUB(NN)
NEOPRENE+SBR( n)
NA T+NEOP+NBR ( r)
POLYURETHANE ( r)
SARANEX(nn)
SBR( n)
VIT/CLORBUTL(nn)
NEOP/NAT RUB(NN)
PV ACETATE( rr)
SILVERSHIELO(rr)
SBR/NEOPRENE( n)
Cyclohexanone rr n n nn rr n nn n NEOP+NAT RUB(nn)
SILVERSHIELO(rr)
Olacetone Alcohol r n r R r R r POLYURETHANE( n)
SBR( r)
SBR/NEOPRENE( r)
Oi Isobutyl Ketone n n nn nn n rr NN rr H
I-'
I-' Oi Isobutyl Ketone, >70% RR RR rr RR SILVERSHIELO(rr)
w
Isophorone n r
Mesltyl Oxide nn n r VIT/ClORBUTl(rr)
4-Methoxy-4-methyl-2-pentanone rr rr rr nn
Methyl n-Butyl Ketone r n
Hote: Numbers In parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur O. Little, Inc.
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Ketones (cont.)
A I i phs tie & A I i eye lie (eont.)(391)
Methyl Ethyl Ketone RR nn NN NN NN NN NN NN nn NN NN NN CHLOROBUTYL(rr)
TEFLON(nn)
NEOP+NAT RUB(NN)
NEOPRENE+SBR( n)
POLYURETHANE( r)
SARANEX(NN)
SBR( r)
VIT/CLORBUTL(nn)
NEOP/NAT RUB(NN)
SBR/NEOPRENE( n)
Methyl Isobutyl Ketone NN n n NN NN nn NN NN rr nn nn n TEFLON(rr)
NEOP+NAT RUB( n)
SBR( r)
Methyl-vinyl-ketone nn VIT/CLORBUTL(rr)
N-Methyl-2-pyrrolldone NN NN NN NN
I-'
....
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Acetophenone n r TEFLON(rr)
Lactones
Lsetones (1100)
beta-Proplolactone rr nn nn nn NN nn nn POLYURETHANE(NN)
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
SOI'-"e: Arthur D. Little, Inc.
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Niscellaneous (560)
Asphalt r n
Mercury r r r r
Mi nera I Oi I r n
Hote: Numbers in parentheses are chemical class codes -- so~ T~~le 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, (;tc,) f,ce Table 8.3.
Source: Arthur D. Little, Inc.
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Aliphatic ~ Alicyclic (431)
Acetonitrile RR rr nn NN NN NN NN rr NN rr rr TEfLON( rr)
NEOP+NAT RUB( r)
SARANEX(rr)
VIT/CLORBUTL(rr)
SILVERSHIELD(rr)
Acryl on i trll e n nn N r n n NN N n TEfLON(nn)
NEOPRENE+SBR( n)
POL YURETHANE( r)
SARANEX(nn)
SBR( n)
SBR/NEOPRENE( n)
Bromoacetonitrile rr NN rr rr
Ch'oroacetonitrile rr NN rr rr
Ethyl Cyanide nn NN rr NN
........ I soamy I nit r I Ie nn rr rr rr
0'1 ~ethacrylonltrlle rr NN nn NN
Trlchloroacetonltrile rr rr rr rr
Va I e ron i t r i Ie rr NN nn rr
Aromatic (432)
Benzon I tri Ie rr NN rr nn
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Unsubstituted (11117)
Nitrobenzene rr rr NN NN n NN RR N RR TEFLON( rr)
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NEOPRENE+SBR( r)
POL YURETHANE( n)
SBR( n)
VIT/CLORBUTL(rr)
SllVERSHIElD(rr)
SBR/NEOPRENE( n)
Nltroethane rr n NN nn rr r NEOP+NAT RUB( r)
Nit rog I yce r i ne r r
Ni tromethane rr NN rr nn rr NN n n
Nit ropropane RR n nn NN NN NN NN nn nn POLYURETHANE(nn)
SILVERSHIELD(rr)
l-N It rop ropane rr nn rr nn TEFLON( rr)
2-N i t r~p ropane rr NN nn rr
I-'
I-'
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SBR( r)
SBR/NEOPRENE( r)
o-Nltrotoluene nn
p-N I t roto I uene . rr POLYCARBONAT(rr)
2,4,6-TrinltrotoIUene n N N r R POLYURETHANE ( n)
SBR( n)
SBR/NEOPRENE( n)
Substituted (*"2)
2-Chloro-2-nitropropane rr NN rr nn
n-Nltrosodimethylamlne nn
Picric Acid r R R r R n r r
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Organic salts (.5.50)
Benzethonlum Chloride rr rr rr rr
Organo-Metailic Compounds
Organo-Netsllic Compounds (461)
Ti tanlum Tetrachloride r n
Triethyl Aluminum n n
Tri octy I Phosphine r r
Organo-Phosphorous Compounds
Organo-Phosphorous Compounds (460)
Tributyl Phosphate r r
T,-I c rasy I Phosphate rr r r nn nn rr n rr RR rr rr r NEOPRENE+SBR( n)
POL YURETHANE( n)
SBR( n)
.....
..... SBR/NEOPRENE( r)
00 Trllsooctyl Phosphate r r
Note: Numbers In parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR.R.NN. etc.) see Table 8.3.
Source: Arthur D. Little. Inc.
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Peroxides (JOO)
alpha,alpha-Dimethylbenzyl Hydroperoxide TEfLON( rr)
Hydrogen Peroxide nn rr r r R r n nn r r TEFLON( nn)
NEOP+NAT RUB( r)
NEOPRENE+SBR( r)
POL YURETHANE ( r)
SBR( r)
SBR/NEOPRENE( r)
Hydrogen Peroxide, <30% CHLOROBUTYL(rr)
NAT+NEOP+NBR( r)
Hydrogen Peroxide, 30-70% RR NN rr rr n rr NEOP+NAT RUB(rr)
POLYURETHANE( r)
SBR( r)
NEOP/NAT RU8(rr)
Hydrogen Peroxide, >70% r n
Methyl Ethyl Ke tone Pe rox i de rr nn rr rr
Quinones
........
\0
Quinones (490)
Hydroquinone n R R rr r rr n rr r SBR( r)
Hyd roqu I none, <30% rr rr rr rr
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Thiols (~01)
tert-Butyl Mercaptan n n
Ethyl Mercaptan n n
Thionyl Chloride r n
Thiophenol nn rr
Su,rides Ii Oisulrides (~02)
Methanesulfonic Acid rr rr
p-Toluenesulfonic Acid rr rr rr
Others (507)
Disulfur Dichloride r n
Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. l i tt Ie, Inc.
MATRIX B
121
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Note: for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Class recommendations only for chemicals classes in which two or more chemicals· have
recommendations for a given material. Double asterisks (**) indicate a wide variation in ratings.
Source: Arthur D. Little, Inc.
~
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Halogen Compounds
AI iphatic, Unsubst.ituted nn nn r NN NN NN NN NN ** NN .. « n
Polynuclear NN nn rr
",., !"
VinYl Halides :~
Heterocyclic Compounds
furan De r I va t I ve s nn nn NN fir' n
Hydroxyl Compounds
Inorganic Acids
Note: for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Class recommendations only for chemicals classes In which two or more chemicals h~vp
recommendations for a given material. Double asterisks (**) Indicate a ",Ide varjf·ti~r ;'1 t"litings.
Source: Arthur D. Little, Inc.
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Inorganic Bases
I norgan I c Bases r r RR RR ** RR ** n ** rr r
Inorganic Gases
Inorganic Gases ** r n n r ** ** ** **
Inorganic Salts
Inorganic Salts r n ** r r r R
Isocyanates
Isocyanates NN n rr
Ketones, Aliphatic
Ketones, Aliphatic ** NN n NN NN N ** NN ** NN NN **
Nltri les, AI iphatlc
Nitrlles, AI i phat Ic rr NN ** NN rr NN rr
I-'
N
+:- Nitro Compounds
Unsubstituted rr r NN ** nn ** ** **
Organo-Phosphorous Compounds
orgno-Phosphorous compounds r r
Peroxides
Pe rox ides r
Sui fur Compounds
Thiols ** n
Note: For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Class recommendations only for chemicals classes in which two or more chemicals have
recommendations for a given material. Double asterisks (**) Indicate a wide variation In ratings.
Source: Arthur D. Little, Inc.
APPENDIX A
GLOSSARY
A-I
GLOSSARY
ABS Polymer of acrylonitrile, butadiene, and styrene; a strong,
rigid material used for structural components.
Cellulose Propionate - - Polymer; clear plastic used for face and eye
protection.
A-2
CPE -- See Chlorinated Polyethylene.
A-3
Natural Rubber -- Polyisoprene obtained from rubber plants. A highly
flexible and conforming material used principally for gloves. High
elasticity.
PE -- See Polyethylene.
Permeation Rate - - The rate at which the chemical moves through the
clothing material. This is expressed in terms of amount per unie area
per unit time.
A-4
PolYVinyl Alcohol - - A water-soluble polymer that, as long as it is
dry, exhibits exceptional resistance to many organic solvents that
rapidly permeate most rubbers. The material is somewhat stiff, thus
limiting dexterity.
PU -- See Polyurethane.
A-S
APPENDIX B
CHEMICAL INDEX
B-1
CHEMICAL NAKES AND SYNONYMS
B-2
CHEMICAL NAMES AND SYNONYMS
B-3
CHEMICAL NAMES AND SYNONYMS
B-4
CHEMICAL NAMES AND SYNONYMS
B-5
CHEMICAL NAMES AND SYNONYMS
B-6
CHEMICAL NAMES AND SYNONYMS
B-7
CHEMICAL NAMES AND SYNONYMS
B-8
CHEMI CAL NAMES AND SYNONYMS
B-9
CHEMICAL NAMES AND SYNONYMS
B-10
CHEMICAL NAMES AND SYNONYMS
B-ll
CHEMICAL NAMES AND SYNONYMS
B-12
CHEMICAL NAMES AND SYNONYMS
B-13
CHEKICAL NAMES AND SYNONYMS
B-14
CHEKICAL NAMES AND SYNONlHS
8-15
CHEMICAL NAMES AND SYNONYMS
B-16
CHEMICAL NAMES AND SYNONYMS
B-17
CHEMICAL NAMES AND SYNONYMS
B-18
CHEMICAL NAKES AND SYNONYMS
B-19
CHEMICAL NAMES AND SYNONYMS
B-20
CHEMICAL NAMES AND SYNONYMS
B-21
CHEMICAL NAMES AND SYNONYMS
B-22
CHEKlCAL NAMES AND SYNONYMS
B-23
CHEMICAL NAMES AND SYNONYMS
B-24
CHEMICAL NAMES AND SYNONYMS
B-25
CHEMICAL NAMES AND SYNONYMS
B-26
CHEKlCAL NAMES AND SYNONYMS
NAME:
'YN:
.. Ethyl Silicate
+-.
CASNO:
CLASS:
00078104
233 291
B-27
CHEMICAL NAMES AND SYNONYMS
B-28
CHEMICAL NAMES AND SYNONYMS
B-2'
CHEMICAL NAMES AND SYNONYMS
B-30
CHEMICAL NAMES AND SYNONYMS
B-31
CHEMICAL NAMES AND SYNONYMS
B-32
CHEMICAL NAKES AND SYNONYMS
B-33
CHEMICAL NAMES AND SYNONYMS
B-34
CHEKlCAL NAMES AND SYNONYMS
B-35
CHEMICAL NAMES AND SYNONYMS
B-36
CHEMICAL NAMES AND SYNONYMS
B-37
CHEMICAL NAMES AND SYNONYMS
B-38
CHEMICAL NAMES AND SYNONYMS
B-39
CHEMICAL NAMES AND SYNONYMS
B-40
CHEMICAL NAMES AND SYNONYMS
B-41
CHEMI CAL NAMES AND SYNONYMS
B-42
CHEMICAL NAMES AND SYNONYMS
B-43
CHEMICAL NAMES AND SYNONYMS
B-44
CHEKICAL HAKES AND SYNONYMS
B-45
CHEMICAL NAMES AND SYNONYMS
B-46
CHEMICAL NAMES AND SYNONYMS
B-47
CHEMICAL NAMES AND SYNONYMS
B-48
CHEMICAL NAMES AND SYNONYMS
B-49
CHEMICAL NAMES AND SYNONYMS
B-50
CHEMICAL NAMES AND SYNONYMS
B-51
CHEMICAL NAMES AND SYNONYMS
B-52
CHEMICAL NAMES AND SYNONYMS
S-53
CHEMICAL NAMES AND SYNONYMS
B-S4
CHEMI CAL NAMES AND SYNONYMS
~-55
APPENDIX C
PRODUCT INDEX
C-l
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
ACRYLIC (002)
BUTYL(003)
C-2
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
--------------------------------------------------------.-----------
Product: Butyl/Fabric/Butyl
Product: Butyl/Nylon/Butyl
BUTYL/NEOPRENE (038)
Product: Butyl/Polyester/Chloroprene Rubber
CELLULOSE ACETATE(OOl)
Product: Cellulose Acetate, Face Shield and Lens
CELLULOSE PROPIONATE(OOS)
Product: Cellulose Propionate, Face Shield and Lens
C-3
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
CHLOROBUTYL(006)
Product: ChlorobutylJNomex/Chlorobuty1
CPE(007)
CR 39(008)
GORE-TEX(018)
C-4
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
NAT+NEOP+NBR(019)
NATURAL RUBBER(013)
C-5
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
045 03 Masterman's(D)
045 06 General Scientific Safety Equipment Company(D)
045 07 Allied Glove & Safety Products Corp.(M)
045 07 Arbill Inc. (D)
045 07 Boss Manufacturing Company(M)
C-6
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
C-7
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
NEOP+NAT RUBBER(OlS)
NEOP/NAT RUBBER(039)
Product: Cloroprene/Natural Rubber Latex Glove, Unsupported
NEOPRENE (016)
C-8
\
\
Resistant
Material Code Type Vendor Name
C-9
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
c-10
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
C-ll
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
Product: Chloroprene/Fabric/Chloroprene
139 01 Eastco Industrial Safety Corp. (D)
139 01 Rainfair, Inc.(M)
139 01 Sawyer-Tower(M)
139 04 Eastco Industrial Safety Corp. (D)
139 04 Rainfair, Inc.(M)
139 04 Sawyer-Tower(M)
139 06 Eastco Industrial Safety Corp. (D)
139 06 Rainfair, Inc.(M)
C-l2
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
NEOPRENE+PVC(045)
Product: Chloroprene+PVC/Polyester
NEOPRENE+SBR RUBBER(017)
Product: Ch1oroprene(15%)+SBR(85%)/Cotton--Tuffprene
NITRlLE(02l)
C-13
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
C-14
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
Product: Nitrile/Fabric
C-15
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
NITRILE+PVC(020)
Product: Nitrile+PVC/Fabric
C-16
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Haterial Code Type Vendor Name
NONWOVEN FABRIC(024)
Product: Sontara
C-17
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
NONWOVEN PE(03l)
Product: Tyvek
071 01 Allied Glove & Safety Products Corp.(M)
071 01 American Scientific Products(D)
071 01 Arbi1l Inc. (D)
071 01 Charkate(M)
071 01 Clean Room Products, Inc.(M)
071 01 Coyne Safety Equipment, Inc.(D)
071 01 Daffin Disposables, Inc.(M)
071 01 Direct Safety Company(D)
071 01 Disposables Inc.(M)
071 01 Durafab Disposables, Inc.(M)
071 01 Eastco Industrial Safety Corp. (D)
071 01 Edmont Div. Becton, Dickinson & Co.(M)
071 01 Fisher Scientific Company(D)
071 01 Goodyear Rubber Products Corp.(S)
071 01 Holland Safety Supply Co. CD)
071 01 Hub Safety Equipment, Inc.CD)
071 01 IPESCo., Inc.CM)
071 01 Industrial Products Co., Inc.(D)
071 01 Industrial Safety and Security Co. (D)
071 01 Interex Corp. (D)
071 01 Kappler Disposables, Inc.(M)
071 01 Latex Glove Co., Inc(M)
071 01 Leonard Safety Epuipment, Inc.CD)
071 01 Magid Glove and Safety Mfg. Co.(M)
071 01 Mar-Mac Manufacturing Co., Inc.(M)
071 01 Masterman'sCD)
071 01 Melco, Inc. (M)
071 01 Mine Safety Appliances Co.CM)
071 01 Protech Safety Equipment Inc. (D)
071 01 Rockford Medical & Safety Co.(D)
071 01 Safeco Inc. CD)
071 01 Standard Glove & Safety Equip. Corp. CD)
071 01 Stauffer Manufacturing CompanyCM)
071 01 Superior Surgical Mfg. Co., Inc.(M)
071 01 H. Texie~ Glove Company Inc.(D)
071 01 United States Plastic Corp. (D)
071 02 Allied Glove & Safety Products Corp.(M)
071 02 American Scientific Products(D)
071 02 Arbill Inc. CD)
071 02 Boss Manufacturing Company(M)
071 02 Charkate(M)
071 02 Clean Room Products, Inc.(M)
071 02 Coyne Safety Equipment, Inc.(D)
071 02 Daffin Disposables, Inc.(M)
071 02 Direct Safety Company CD)
071 02 Disposables Inc.(M)
071 02 Durafab Disposables, Inc.(M)
071 02 Eastco Industrial Safety Corp. (D)
071 02 Edrnont Div. Becton, Dickinson & Co.(M)
071 02 Fisher Scientific Company(D)
071 02 General Scientific Safety Equipment Company(D)
C-18
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
C-19
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
C-20
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vundor Name
NONWOVEN PP(023)
C-21
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
PE(025)
048 03 Masterman's(D)
C-22
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
Product: Polyethylene/Tyvek
C-23
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
C-24
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
-----------------------------------~~-------------------------------
Product: Polyethylene/Tyvek (cant.)
076 05 Rockford Medical & Safety Co. CD)
076 06 Charkate{M)
076 06 Durafab Disposables, Inc.{M)
076 06 Industrial Products Co., Inc.(D)
076 06 Industrial Safety and Security Co. CD)
076 06 Kappler Disposables, Inc.(M)
076 06 Mar-Mac Manufacturing Co., Inc.eM)
076 06 Melco, Inc.(M)
076 06 Pro tech Safety Equipment Inc.{D)
076 07 Daffin Disposables, Inc.(M)
076 07 Durafab Disposables, Inc.(M)
076 07 Industrial Products Co., Inc.(D)
076 07 Industrial Safety and Security Co. (D)
076 07 Kappler Disposables, Inc.(M)
076 07 Mar-Mac Manufacturing Co., Inc.(M)
076 07 Protech Safety Equipment Inc. (D)
Product: Polyethylene/Fabric
Product: Polyethylene/Polyester
POLYCARBONATE(026)
POLYESTER(027)
C-2S
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
POLYURETHANE(028)
PV ALCOHOL(029)
C-26
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
PVC(030)
C-27
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
049 04 Aramsco(M)
049 04 Coyne Safety Equipment, Inc.(D)
049 04 Falcon Industries, Inc.(M)
049 04 Latex Glove Co., Inc(M)
049 04 Leonard Safety Epuipment, Inc.(D)
049 04 Miller Products Co., Inc.(D)
049 04 Protech Safety Equipment Inc. (D)
049 04 Safeco Inc. (D)
049 04 Safety Engineering & Supply Co. (D)
049 04 Sawyer-Tower(M)
049 04 Standard Safety Equipment Co.(M)
049 05 Andover Industries, Inc.(M)
049 05 Direct Safety Company(D)
049 05 Mine Safety Appliances Co.(M)
049 06 Aramsco(M)
049 06 Coyne Safety Equipment, Inc.(D)
049 06 Direct Safety Company(D)
049 06 Falcon Industries, Inc.(M)
049 06 General Scientific Safety Equipment Company(D)
049 06 Leonard Safety Epuipment, Inc.(D)
049 06 Magid Glove and Safety Mfg. Co.(M)
049 06 Miller Products Co., Inc.(D)
049 06 Mine Safety Appliances Co.(M)
049 06 Plastex Protective Products, Inc.(M)
049 06 Protexa11 Company(M)
049 06 Steele & Associates, Inc.(M)
049 07 Arbill Inc. (D)
049 07 Armin Corporation(M)
049 07 Direct Safety Company(D)
049 07 Interex Corp. (D)
049 07 La Crosse Footwear, Inc.(M)
049 07 Protexal1 Company(M)
049 07 Ranger (M).
049 07 Standard Safety Equipment Co. (M)
049 07 Steele & Associates, Inc.(M) .
C-28
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
C-29
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
C-30
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
C-31
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
C-32
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
C-33
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
C-34
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
SARANEX(032)
Product: PE/Polyviny1idenechloride/PE/Tyvek
C-3s
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
SBR(033)
SBR/NEOPRENE(047)
Product: Styrenebutadiene/Cotton/Chloroprene
SILVER 'SHIELD(042)
Product: Silver Shield (North Product), Glove
122 00 Arbil1 Inc.(D)
122 00 North Hand Protection(M)
C-36
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
TEFLON(014)
Product: TFE/Nomex/TFE
Product: TFE/Fiberg1ass/TFE
VITON(034)
Product: Fluoroelastomer/Fabric/Fluoroelastomer
Product: Fluoroelastomer/Polyester/F1uoroe1astomer
VITON/BUTYL(03S)
Product: Fluoroelastomer/Butyl/Nylon/Butyl
C-37
PRODUCT VENDORS BY RESISTANT MATERIAL
Resistant
Material Code Type Vendor Name
VITON/CHLOROBUTYL(036)
Product: FluoroelastomerjNomex/Chlorobutyl
VI TON/NEOPRENE (011)
Product: FluoroelastomerjNylon/Chloroprene
C-38
APPENDIX D
VENDOR DIRECTORY
D-1
VENDOR DIRECTORY
Ackwell
Address not available.
D-2
VENDOR DIRECTORY
Aramsco
Thorofare, NJ 08086
800/257-8146
Arbill Inc.
2207 W. Glenwood Avenue
Philadelphia, PA 19132
215/228-4011
Armin Corporation
One Penn Plaza
New York, NY 10119
212/736-2201
Arrowhead Products
4411 Katella Avenue
Los Alamitos, CA 90720
714/828-7770
Bard Parker
Address not available.
n-3
VENDOR DIRECTORY
Bel-Art Products
Industrial Road
Pequannock, NJ 07440
201/694-0500
Body-Guard
Division of Lion Uniform Inc.
P.O. Box 14343
Dayton, OH 45414
714/540-8010
California Safety
Address not available.
D-4
VENDOR DIRECTORY
Charkate
130 West 10th Street
Huntington Station, NY 11746
516/427-1802
Comasec
Drawer 10
Niblick Road
Enfield, CT 06082
203/741-2207
D-5
VENDOR DIRECTORY
Converse Inc.
55 Fordham Road
Wilmington, MA 01887
617/657-5500
Defense Apparel
247 Addison Road
Windsor, CT 06095
800/243-3847
Disposables Inc.
14 Locust Street
Manhasset, NY 11030
516/627-4554
VENDOR DIRECTORY
D-7
VENDOR DIRECTORY
Erista
Rex Gummiwarenfabrlc Gmbh
D-6102
Pfungstadt, FRG
Fairway Products
303 Arch Street
Hillsdale, HI 49242
517/439-9376
D-8
VENDOR. DIRECTORY
Granet
25 Loring Drive
P.O. Box 588
Framingham, HA 01701
617/875-3521
D-9
VENDOR DIRECTORY
Handgards Inc.
901 Hawkins
P.O. Box 27018
El Paso, T.X 79926
915/779-6606
b-10
VENDOR· DIRECTORY
ILC Dover
P.O. Box 266
Frederica, DE 19946
302/335-3911
IPESCo., Inc.
1903 Sharon Forest Drive
Charlotte, NC 28212
704/535-5550
Interex Corp.
3 Strathmore Rd.
Natick, MA 01760
800/225-5910
D-ll
VENDOR.' DIRECTORY
.l
~
KID AB
S-71100
Lindesberg, Sweden
D-12
VENDOR DIRECTORY
Kimberly-Clark Corp.
Industrial Garments Fabrics
1400 Holcomb Bridge Road
Roswell, GA 30076
404/587-8000
D-13
VENDOR DIRECTORY
Marathon Rubber
510 Sherman Street
Wausau, WI 54401
715/845 - 625.5
D-14
V~NDOR DIRECTORY
Masterman's
Auburn Industrial Park
P.O. Box 224
Auburn, MA 01501
617/755-7801.
Me1co, Inc.
6603 Governor Printz Blvd.
Wilmington, DE 19809
800/441-9749
0-15
VENDOR.; DIRECTORY
Nolato
Address not available.
»-16
VENDOR DIRECTORY
Panelgraphic Corporation
10 Henderson Drive
W. Caldwell, NJ 07006
800/222-0618
Plastimayd Corp.
2204 S.E. Seventh Avenue
P.O. Box 14217
Portland, OR 97214
503/232-5101
VENDOR DIRECTORY
Protexall Company
P.O. Box 307
Green Lake, WI 54941
414/294-6511
Rainfair, Inc.
P.O. Box 1647
Racine, WI 53401
800/558-5990
Ranger
Division of Endicott Johnson
1100 E. Main St.
Endicott, NY 13760
607/757-4260
Renco Corp
2060 Fairfax Avenue
Cherry Hill, NJ 08003
609/424-5755
D-18
VENDOR DIRECTORY
Rich Industries
Address not available.
Safeco Inc.
337 E. Center Street
P.o. Box 28
Kingsport, TN 37660
615/246-3552
0-19
VENDOR DIRECTORY
Sawyer-Tower
Division of Lion Uniform
2735 Kerns Avenue
Dayton, OH 45414
Seiberling
Address not available.
n-20
VENDOR DIRECTORY
Surety-Sure Seal
Address not available.
~21
VENDOR DIRECTORY
3M Company
3M Center
Bldg. 220-7W
St. Paul. MN 55144
612/733-6234
Trelleborg. Inc.
30700 Solon Industrial Parkway
Solon. OH 44139
216/248-8600
~22
VENDOR. DIRECTORY
Vidaro Corp.
333-T Martine1 Drive
P.O. Box 535-T
Kent, OH 44240
216/673-7413
Viny1produkter
.S-261
23 Landskrona, Sweden
D-23
APPENDIX E
E-l
PRODUCT DESCRIPTION CODES AND RESISTANT MATERIALS
E-2
Product Description Codes and Resistant Materials
(in numerical order -- alphabetical listing follows)
·'roduct Resistant
Code Material Product Description
E-3
Product Description Codes and Resistant Materials
(in numerical order -- alphabetical listing follows)
Product Resistant
Code Material Product Description
E-4
Product Description Codes and Resistant Materials
(in numerical order -- alphabetical listing follows)
Resistant
Material Product Description
E-5
Product Description Codes and Resistant Materials
(in alphabetical order of resistant material)
Product Resistant
Code Material Product Description
E-6
Product Description Codes and Resistant Materials
(in alphabetical order of resistant material)
roduct Resistant
":ode Material Product Description
------- ---------
081 NEOPRENE Chloroprene Rubber, Boots
093 NEOPRENE Ghloroprene Rubber/Nylon
125 NEOPRENE Chloroprene Milled/Chloroprene Latex Glove, Supported
138 NEOPRENE Chloroprene Rubber/Fabric
139 NEOPRENE Chloroprene/Fabric/Chloroprene
14.1 NEOPRENE Chloroprene Rubber/Kevlar
148 NEOPRENE Chloroprene/Cotton/Chloroprene
127 NEOPRENE+PVC Chloroprene+PVC/Polyester
065 NEOPRENE+SBR RUBBER Chloroprene (35%)+SBR(65%)/Nylon--Tufflon
066 NEOPRENE+SBR RUBBER Chloroprene(15%)+SBR(85%)/Cotton--Tuffprene
005 NITRILE Nitrile Rubber Latex Glove, Supported
019 NITRILE Nitrile Rubber Latex Glove, Unsupported
020 NITRILE Nitrile Rubber Glove, Solvent Dipped, Unsupported
033 NITRILE Nitrile Rubber, Sheet
059 NITRILE Nitrile Rubber/Polyester
078 NITRILE Nitrile Rubber/Nylon
084 NITRILE Nitrile Rubber, Boots
132 NITRILE Ni trile/Fabric
147 NITRILE Nitrile/Fabric/Nitrile
057 NITRILE+PVC Nitrile+PVC Glove, Supported
058 NITRILE+PVC Nitrile+PVC/Fabric
150 NITRILE+PVC Nitrile+PVC Boot
152 NITRILE+PVC Nitrile+PVC/Fabric/Nitrile+PVC
025 NONWOVEN FABRIC Sontara
071 NONWOVEN PE Tyvek
086 NONWOVEN PP Safeguard, Duraguard, Corovin
135 NONWOVEN PP Polypropylene, Nonwoven
006 PE Polyethylene Glove, Unsupported
041 PE Polyethylene, High Density, Film
042 PE Polyethylene, Medium Density, Film
048 PE Polyethylene, Low Density, Film
056 PE Polyethylene, Density Unknown, Film
075 PE Polyethylene/Sontara
076 PE PolyethylenejTyvek
091 PE Polyethylene/Fabric
105 PE Polyethylene/Polypropylene Nonwoven
134 PE Polyethylene/Nylon
137 PE Polyethylene/Polyester
109 PE/EVOH/PE PE/Ethylene Vinyl Alcohol/PE Glove, Unsupported
098 POLYCARBONATE Polycarbonate, Lens and Face Shield
096 POLYESTER Polyester, Face Shield and Lens
027 POLYURETHANE Polyurethane Rubber, Unsupported
040 POLYURETHANE Polyurethane Rubber/Polyester
050 POLYURETHANE Polyurethane Rubber/Nylon
082 POLYURETHANE Polyurethane Rubber, Boots
029 PTX Polymethylpentane, Face Shield
124 PV ACETATE Polyvinyl Acetate, Sheet
004 PV ALCOHOL Polyvinyl Alcohol Glove, Supported
035 PV ALCOHOL Polyvinyl Alcohol, Sheet
102 PV ALCOHOL Polyvinyl Alcohol Glove, Unsupported
003 PVC Polyvinyl Chloride Glove, Unsupported
E-7
Product Description Codes and Resistant Materials
(in alphabetical order of resistant material)
Product Resistant
Code Material Product Description
E-8
APPENDIX F
F-l
CLOTHING TYPE CODE
Coat, Jacket 01
Coveralls 02
Hood 06
Shoe Cover 07
Boot 08
Face Shield 09
Glove 00
F-2
APPENDIX G
G-l
MATERIAL PROTECTION LEVEL
Butyl / Nylon/ Butyl EPA: A (with emergency egress unit.)
STYLE VENDOR
LL-100 - Toxicological Butyl Andover Industries Inc.
THICKNESS: 14 mils 15 Union Street
MATERIAL WGT: 12 oz/sq yd Lawrence, MA 01840
ENSEMBLE WGT: No data (617) 794-1792
SIZES: No data
G-2
MATERIAL PROTECTION LEVEL
Butyl/Nylon / Butyl EPA: A (with emergency egress unit.)
STYLE VENDOR
LL-100 - Chemical Butyl Andover Industries Inc.
THICKNESS: 15 mils 15 Union Street
MATERIAL WGT: 11.5 oz/sq yd Lawrence, MA 01840
ENSEMBLE WGT: No data (617) 794-1792
SIZES: No data
G-3
MATERIAL PROTECTION LEVEL
Butyl/Nylon / Butyl EPA: A
STYLE VENDOR
305 B/BA Fyrepel Products Inc.
THICKNESS: 14 mils Box 518
MATERIAL WGT: 14 oz/sq yd Newark, OH 43055
ENSEMBLE WGT: 12 Ibs (614) 344-0391
SIZES: S, M, L. Xl
(for heights 5'4" - 6'5")
FITTINGS
. -...".,..,..
G-4
MATERIAL PROTECTION LEVEL
Butyl! Nylon! Butyl EPA: A
STYLE VENDOR
306 B/BA Fyrepel Products Inc.
THICKNESS: 14 mils Box 518
MATERIAL WGT: 14 oz/sq yd Newark, OH 43055
ENSEMBLE WGT: 12 Ibs (614) 344-0391
SIZES: S, M, L XL
(for heights 5'4" - S'5")
FITTINGS
AIRLINE: 1/4-inch brass.
COMMUNICATION: No data.
COOLING: No datl!..
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or boots.
MATERIAL: Butyl! nylon I butyl.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIM~MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
Tear Strength: No data.
INTERFACE: Splash guards.
Seam Strength: No data.
Zipper Strength: No data.·
Cut Resistance: No data.
VISOR
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Poly(methyl methacrylate). Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-S
MATERIAL PROTECTION LEVEL
Butyl/Nylon / Butyl EPA: A
STYLE VENDOR
Trellchem. Butyl Extra Trelleborg. Inc.
THICKNESS: 15-18 mils 30700 Solon Industrial Parkway
MATERIAL WGT: 15 oz/sq yd Solon. OH 44139
ENSEMBLE WGT: 15 Ibs (216) 248-8600
SIZES: S. M. L. XL
FITTINGS
AIRLINE: No data.
COMMUNICATION: None.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral boots or booties.
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: (ASTM 0-751). 110 Ibs/inch.
INTERFACE: Splash guard. Tear Strength; (ASTM 0-751). 10 Ibs.
Seam Strength: (ASTM 0-1682).110 Ibs.
Zipper Strength: No data,
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: 80 mil PVC visor. Flammability: No data.
INTERFACE: Adhesive bonded. interior strapped Stiffness: No data.
with butyl. Flex Fatigue: No data.
G-6
MATERIAL PROTECTION LEVEL
Butyl/Nylon / Butyl EPA: B
STYLE VENDOR
Trellchem, Butyl Trelleborg, Inc.
THICKNESS:· 15-18 mils 30700 Solon Industrial Parkway
MATERIAL WGT: 15 oz/sq yd Solon, OH 44139
ENSEMBLE WGT: 13 Ibs (216) 248-8600
SIZES: S, M, L, XL
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene or butyl. Air distribution system.
INTERFACE: Support ring in sleeve, elastic band.
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOUNG: No data.
BOOTS INFLATION VALVE: Yes.
TYPE: Integral boots or booties.
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
Tensile Strength: (ASTM 0-751), 110 Ibs/in.
MATERIAL: User specified and supplied.
Tear Strength: (ASTM 0-751), 10 Ibs.
INTERFACE: Splash guard.
Seam Strength: (ASTM 0-1682), 110 Ibs.
Zipper Strength: No data. .
Cut Resistance: No data.
VISOR Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-7
MATERIAL PROTECTION LEVEL
Butyl/Polyester / Chloroprene EPA: A
STYLE VENDOR
Chempruf 11, Betex/SCBA Mine Safety Appliances Co.
THICKNESS: 19 mils P.O. Box 426
MATERIAL WGT: 15.9 oz/sq yd Pittsburgh. PA 15230
ENSEMBLE WGT: No data (412) 273-5000
SIZES: One size
G-8
MATERIAL PROTECTION lEVEL
Butyl/Polyester / Chloroprene EPA: A
STYLE VENDOR
Chempruf II, Betex/DPBA Mine Safety Appliances Co.
THICKNESS: 19 mils P.O. Box 426
MATERIAL WGT: 15.9 oz/sq yd Pittsburgh, PA 15230
ENSEMBLE WGT: No data (412) 273-5000
SIZES: One size
G-9
MATERIAL PROTECTION LEVEL
Chlorinated Polyethylene EPA: No Rating (See Section 5.B.8.)
STYLE VENDOR
Chemturion, Model 12 ILC Dover, Inc.
THICKNESS: 20 mils P.O. Box 266
MATERIAL WGT: 19.7 oz/sq yd Frederica, DE 19946
ENSEMBLE WGT: 41bs (302) 335-3911
SIZES: L. XL
(tor heights 5'4" - 6'8")
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: User specified and supplied. Air distribution system or liquid pody cooling.
INTERFACE: Molded ABS connect ring in sleeve,
rubber connect ring in glove.
FITTINGS
AIRLINE: 1 /4-inch NPT brass.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties.
MATERIAL: Chlorinated polyethylene.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: Press-polished optical gra'de 40 mil Flammability: No data.
vinyl with polyester splash visors. Stiffness: No data.
INTERFACE: No data. Flex Fatigue: No data.
G-IO
MATERIAL PROTECTION LEVEL
Chlorinated Polyethylene EPA: A
STYLE VENDOR
Chemturion, Model' 3 IlC Dover, Inc.
THICKNESS: 20 mils P.O. Box 266
MATERIAL WGT: '9.7 oz/sq yd Frederica, DE , 9946
ENSEMBLE WGT: 4 Ibs (302) 335·39"
SIZES: One size
(for heights 5'4" - 6'4")
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data,
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties.
MATERIAL: Chlorinated polyethylene.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MA TERIAl: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: Press-polished optical grade 40 mil Flammability: No data.
vinyl with polyester splash visors. Stiffness: No data.
INTERFACE: No data. . Flex Fatigue: No data.
G-ll
MATERIAL PROTECTION LEVEL
Chlorinated Polyethylene EPA: A
STYLE VENDOR
Chemturion, Model 51 ILC Dover, Inc.
THICKNESS: 20 mils P.O. Box 266
MATERIAL WGT: 19.7 ozl sq yd Frederica, DE 19946
ENSEMBLE WGT: 4 Ibs (302) 335·3911
SIZES: S, M, L
(for heights 5'4" - 6'4")
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: Standard tire valve.
TYPE: Integral booties.
MATERIAL: Chlorinated polyethylene.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(pRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength; No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: Polycarbonate with antifog coating Flammability: No data.
and splash visors. Stiffness: No data.
INTERFACE: No data. Flex Fatigue: No data.
G-12
MATERIAL PROTECTION LEVEL
Chlorobutyl/Nomex/Chlorobutyl EPA: No Rating (See Section 5.B.8.)
STYLE VENDOR
SCAPE RFHCO Arrowhead Products
THICKNESS: 19 mils 4411 Katella Avenue
MATERIAL WGT: 17 oz/sq yd Los Alamitos. CA 90720
ENSEMBLE WGT: No data (714) 828-7770
SIZES: Nine sizes
FITTINGS
AIRLINE: Stainless steel quick disconnect for
vortex COOling system.
COMMUNICATION: Various types (optional).
BOOTS COOLING: See AIRLINE.
TYPE: Detachable boots. INFLATION VALVE: No data.
MATERIAL: PVC.
INTERFACE: Molded butyl connect rings in PHYSICAL PROPERTIES
(pRIMARY MATERIAL)
garment leg and boot with butyl rolldown covers.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR Puncture Resistance: No data.
TYPE: Detachable Abrasion Resistance: No data.
MATERIAL: 25 mil modified acrylic. Flammability: No data.
INTERFACE: Butyl rubber gasket. Stiffness: No data.
Flex Fatigue: No data.
G-13
MATERIAL PROTECTION LEVEL
Chlorobutyl/Nomex/Chlorobutyl EPA: No Rating (See Section 5.B.B.)
-i
STYLE VENDOR
Propellant Handlers Ensemble ILC Dover, Inc. I
I
THICKNESS: 20 mils P.O. Box 266 I
MATERIAL WGT: No data Frederica, DE 19946
ENSEMBLE WGT: No data (302) 335-3911
SIZES: No data
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: User specified and supplied.
INTERFACE: Metal connect rings in garment leg PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
and boot.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Polycarbonate. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
. Flex Fatigue: No data .
G-14
MATERIAL PROTECTION LEVEL
Chloroprene/Nylon EPA: 8
STYLE VENDOR
Type 500 CK National Draeger,lnc.
THICKNESS: No data 101 Technology Drive
MATERIAL WGT: No data Pittsburgh, PA 15230
ENSEMBLE WGT: No data (412) 787-8383
SIZES: Above 5'11"
Below 5'11"
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Viton. None.
INTERFACE: Support ring in sleeve, steel glove
clamp.
FITIINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERFACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-15
MATERIAL PROTECTION LEVEL
Chloroprene/Nylon EPA: No Rating (See Section 5.8.8.)
STYLE VENDOR
Type 600 CK National Draeger, Inc.
THICKNESS: No data '0' Technology Drive
MATERIAL WGT: No data Pittsburgh, PA 15230
ENSEMBLE WGT: No data (4'2) 787-8383
SIZES: One size
FITTINGS
AIRLINE: No data.·
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERFACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data,
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-16
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride/Nylon EPA: A (with emergency egress unit.)
STYLE VENDOR
LL-100 - Polyvinyl Chloride Andover Industries Inc.
THICKNESS: 15 mils , 5 Union Street
MATERIAL WGT: '0 oz/sq yd Lawrence, MA 01840
ENSEMBLE WGT: No data (617) 794-1792
SIZES: No data
G-17
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride/ Polyester EPA: No Rating (See Section 5.B.8.)
STYLE VENDOR
Stasafe, Accordion Standard Safety Equipment Co.
THICKNESS: 28-30 mils P.O. Box 188
MATERIAL WGT: 27 oz/sq yd Palatine, IL 60078-0188
ENSEMBLE WGT: No data (312) 359- 1400
SIZES: No data
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Polyvinyl chloride. Air distribution system or vortex cooling.
INTERFACE: Inserts in glove and sleeve create
compression seal.
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral overboots (optional).
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARV MATERIAL)
TYPE: Detachable boots (optional).
MATERIAL: Chloroprene. Tensile Strength: No data.
INTERFACE: Inserts in boot and garment leg Tear Strength: No data.
create compression seal. Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: 40 mil flexible vinyl. Flammability: No data.
INTERF ACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-1S
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride! Polyester EPA: A
STYLE VENDOR
Stasafe, Acidmaster Standard Safety Equipment Co.
THICKNESS: 28-30 mils P.O. Box 188
MATERIAL WGT: 27 oz/sq yd Palatine, IL 60078-0188
ENSEMBLE WGT: No data (312) 359-1400
SIZES: M, L, XL
(for heights 5'8" - 6'5")
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or overboots.
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: Polyvinyl chloride. Tensile Strength: No data.
Tear Strength: No data.
INTERFACE: PVC inserts in boot and garment leg
create compression seal. Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: 40 mil flexible PVC. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-19
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride/ Polyester EPA: A (with emergency egress unit.)
STYLE VENDOR
Stasafe, Compressed Air Standard Safety Equipment Co.
THICKNESS: 28-30 mils P.O. Box 188
MATERIAL WGT: 27 oz/sq yd Palatine, IL 60078-0188
ENSEMBLE WGT: No data (312) 359-1400
SIZES: One size
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Polyvinyl chloride. Air distribution system or vortex cooling.
INTERFACE: PVC inserts in glove and sleeve
create compression seal.
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral overboots (optional).
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots (optional).
MATERIAL: Chloroprene. Tensile Strength: No data.
INTERFACE: PVC inserts in boot and garment leg Tear Strength: No data.
create compression seal. Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: 40 mil flexible PVC. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
i
I
G-20
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: A
STYLE VENDOR
305 PVC/BA Fyrepel Products Inc.
THICKNESS: No data Box 518
MATERIAL WGT: 10 oz/sq yd Newark, OH 43055
ENSEMBLE WGT: No data (614) 344-0391
SIZES: S, M, L, XL
(for heights 5'4" - 6'5")
FITTINGS
AIRLINE: 1/4-inch brass.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or boots.
MATERIAL: PVC/nylon/PVC.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
Tensile Strength: No data.
MATERIAL: User specified and supplied.
Tear Strength: No data.
INTERFACE: Splash guards.
Seam Strength: No data..
Zipper Strength: No data.
Cut Resistance: No data.
VISOR Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Poly(methyl methacrylate). Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-21
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: A
STYLE VENDOR
306 PVC/SA Fyrepel Products Inc.
THICKNESS: No data Box 518
MATERIAL WGT: 10 oz/sq yd Newark, OH 43055
ENSEMBLE WGT: No data (614) 344-0391
SIZES: S, M, L, XL
(for heights 5'4" - 6'5")
FITTINGS
AIRLINE: 1/4-inch brass.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or boots.
MATERIAL: PVCI nylon/ PVC.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Poly(methyl methacrylate). Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-22
MATERIAL PROTECTION lEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: B
STYLE VENDOR
Type 500 PVC National Draeger. Inc.
THICKNESS: No data 101 Technology Drive
MATERIAL WGT: No data Pittsburgh, PA 15230
ENSEMBLE WGT: 13.2 Ibs (412) 787-8383
SIZES: Above 5' 11"
Below 5'11"
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Viton. None.
INTERFACE: Support ring in sleeve. steel glove
clamp.
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERFACE: Support ring in garment leg. steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-23
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: No Rating (See Section 5.B.8.)
STYLE VENDOR
Type 600 PVC National Draeger, Inc.
THICKNESS: No data. 101 Technology Drive
MA TERIAL WGT: No data. Pittsburgh, PA 15230
ENSEMBLE WGT: 14.3 Ibs (412) 787-8383
SIZES: One size
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERFACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-24
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: A
STYLE VENDOR
Type 700 PVC National Draeger, Inc.
THICKNESS: No data 101 Technology Drive
MATERIAL WGT: No data Pittsburgh, PA 15230
ENSEMBLE WGT: 12.1 Ibs (412) 787-8383
SIZES: One size
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERf-ACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
boot clamp. (PRIMARY MATERIAL)
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Polyvinyl chloride. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-25
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC -EPA: 8
STYLE VENDOR
Trellchem, Light Trelleborg, Inc.
THICKNESS: 15-18 mils 30700 Solon Industrial Parkway
MATERIAL WGT: 14.5 oz/sq yd Solon, OH 44139
ENSEMBLE WGT: 12.5 Ibs (216) 248-8600
SIZES: S, M, L. XL
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene. Air distribution system.
INTERFACE: Support ring in sleeve, elastic band.
FITTINGS
AIRLINE: No data.
COMMUNICATION: None.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral boots or booties.
MATERIAL: Polyvinyl chloride.
INTERFACE: Adhesive bonded. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: (ASTM 0-751),110 Ibs/in.
INTERFACE: Splash guard. Tear Strength: (ASTM 0-751), 10 Ibs.
Seam Strength: (ASTM 0-1682), 110 Ibs.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-26
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: A
STYLE VENDOR
Trellchem, Light Extra Trelleborg, Inc.
THICKNESS: 15-18 mils 30700 Solon Industrial Parkway
MATERIAL WGT: 14.5 oztsq yd Solon, OH 44139
ENSEMBLE WGT: 12.51bs (216) 248-8600
SIZES: S, M, L, XL
FITTINGS
AIRLINE: No data.
COMMUNICATION: None.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral boots or booties.
MATERIAL: Polyvinyl chloride.
INTERFACE: Adhesive bonded. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: (ASTM 0-751), 110 Ibstin.
INTERFACE: Splash guard. Tear Strength: (ASTM D-751), 10 Ibs.
Seam Strength: (ASTM 0-1682),110 Ibstin.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: 80 mil PVC visor. Flammability: No data.
INTERFACE: Adhesive bonded, interior strapped Stiffness: No data.
with PVC. Flex Fatigue: No data.
G-27
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: A
STYLE VENDOR
Acid King Wheeler Protective Apparel, Inc.
THICKNESS: 20 mils 4330 West Belmont Avenue
MATERIAL WGT: 14 oz/sq yd Chicago, IL 60641
ENSEMBLE WGT: No data (312) 685-5551
SIZES: Short. Regular, Long
(for heights 5'4'.' - 6'6")
FITTINGS
AIRLINE: 1/4-inch NPT..
COMMUNICATION: No data.
COOLING: 114-inch NPT or 3/4-inch GH thread.
BOOTS INfLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: PVC.
INTERFACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: (FTM 191 A, 5100), 94.1 Ibs (W),
100 Ibs (F).
Tear Strength: (ASTM 0-1117), 33.9 Ibs (W),
24.4 Ibs (F).
Seam Strength: (ASTM 16S3), 63 Ibs.
VISOR Zipper Strength: No data.
TYPE: Integral (optional). Cut Resistance: No data.
MATERIAL: 40 mil PVC. Puncture Resistance: (FTM 191A, 5120), 21.2Ibs.
INTERFACE: No data. Abrasion Resistance: (FTM 191 A, 5306), 3.000 cye,
no wear.
TYPE: Detachable (optional).
Flammability: (FTM 191 A, 5903.2), pass.
MATERIAL: 125 mil poly(methyl methacrylate).
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: (U.S.T. Method), 1,000 cyc,
no cracking.
G-28
MATERIAL PROTECTION LEVEL
Teflon/Fiberglass/Teflon EPA: A
STYLE VENDOR
Challenge 5200 Chemical Fabrics Corporation
THICKNESS: 10 mils P.O. Box 1137
MATERIAL WGT: 14.6 oz/sq yd Merrimack. NH 03054
ENSEMBLE WGT: 10 Ibs (603) 424-9000
SIZES: No data
G-29
MATERIAL PROTECTION LEVEL
Teflon/Nomex/Teflon EPA: A
STYLE VENDOR
Challenge 5100 Chemical Fabrics Corporation
THICKNESS: 18 mils P.O. Box 1137
MATERIAL WGT: 13.9 oz/ sq yd Merrimack, NH 03054
ENSEMBLE WGT: 14 Ibs (603) 424-9000
SIZES: One (large)
G-30
MATERIAL PROTECTION LEVEL
Viton/Nomex/Chlorobutyl EPA: A
STYLE VENDOR
Metro S.S. Andover Industries Inc.
THICKNESS: 20 mils 15 Union Street
MATERIAL WGT: 29 oz/sq yd Lawrence, MA 01840
ENSEMBLE WGT: No data (617) 794-1792
SIZES: S, M, L. XL, XXL
(for heights 5'6" - 6'7")
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties.
MA TERIAL: Viton / Nomex/ ch lorobutyl.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR
Puncture Resistance: No data.
TYPE: Detachable (optional). Abrasion Resistance: No data.
MA TERIAL: Polycarbonate with FEP splash Flammability: No data.
cover. Stiffness: No data.
INTERFACE: Chloroprene gasket Flex Fatigue: No data.
TYPE: Detachable (optional).
MATERIAL: User specified.
INTERFACE: Chloroprene gasket.
G-31
MATERIAL PROTECTION LEVEL
Viton / Nylon /Chloroprene EPA: A
STYLE VENDOR
Chempruf II, Vautex/SCBA Mine Safety Appliances Co.
THICKNESS: 23 mils P.O. Box 426
MATERIAL WGT: 19.1 oz/sq yd Pittsburgh, PA 15230
ENSEMBLE WGT: No data (412) 273-5000
SIZES: One size
G-32
MATERIAL PROTECTION LEVEL
Viton / Nylon / Chloroprene EPA: A
STYLE VENDOR
Chempruf II, Vautex/DPBA Mine Safety Appliances Co.
THICKNESS: 23 mils P.O. Box 426
MATERIAL WGr: 19.1 oz/sq yd Pittsburgh, PA 15230
ENSEMBLE WGT: No data (412) 273-5000
SIZES: One size
G-33
MATERIAL PROTECTION LEVEL
Viton / Nylon / Chloroprene EPA: B
STYLE VENDOR
Type SOD PF National Draeger, Inc.
THICKNESS: No data 101 Technology Drive
MATERIAL WGT: No data Pittsburgh, PA 15230
ENSEMBLE WGT: No data (412) 787-8383
SIZES: Above 5',,"
Below 5"1"
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Viton. None.
INTERFACE: Support ring in sleeve, steel glove
clamp.
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERFACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data. '
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-34
THIS PAGE LEFT INTENTIONALLY BLANK
G - 35
MATERIAL PROTECTION LEVEL
Viton / Nylon / Chloroprene EPA: A
STYLE VENDOR
Type 700 PF National Draeger. Inc.
THICKNESS: No data 101 Technology Drive
MATERIAL WGT: No data Pittsburgh, PA 15230
ENSEMBLE WGT: No data (412) 767-8363
SIZES: One size
FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERFACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture ReSistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Polyvinyl chloride. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-36
MATERIAL PROTECTION LEVEL
Viton / Polyester /Viton EPA: A
STYLE VENDOR
305 VISA Fyrepel Products Inc.
THICKNESS: 8 mils Box 518
MATERIAL WGT: 2.5 oz/sq yd Newark. OH 43055
ENSEMBLE WGT: No data (614) 344-0391
SIZES: S, M, L, XL
(for heights 5'4" - 6/5")
FITTINGS
AIRLINE: 1/ 4-inch brass.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or boots.
MA TERIAL: Viton / polyester !Viton.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Poly(methyl methacrylate). Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-37
MATERIAL PROTECTION LEVEL
Viton / Polyester /Viton EPA: A
STYLE VENDOR
306 VIBA Fyrepel Products Inc.
THICKNESS: 8 mils Box 518
MATERIAL WGT: 2.5 oz/sq yd Newark, OH 43055
ENSEMBLE WGT: No data (614) 344-0391
SIZES: S, M, L, XL
(for heights 5'4" - 6'5")
FITTINGS
AIRLINE: 1 /4-inch brass.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral boots or booties.
MATERIAL: Viton / polyester /viton. PHYSICAL PROPERTIES
INTERFACE: Same as garment seam. (PRIMARY MATERIAL)
TYPE: Detachable boots. Tensile Strength: No data.
MATERIAL: User specified and supplied. Tear Strength: No data.
INTERFACE: Splash guards. Seam Strength: No data.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Poly{methyl methacrylate). Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-38
MATERIAL PROTECTION LEVEL
Viton / Butyl/Nylon / Butyl EPA: B
STYLE VENDOR
Trelichem, Super Trelieborg, Inc.
THICKNESS: 15-18 mils 30700 Solon Industrial Parkway
MATERIAL WGT: 16 oz/sq yd Solon, OH 44139
ENSEMBLE WGT: 13 Ibs (216) 248-8600
SIZES: S, M, L, XL
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene or Viton/butyl. Air distribution system.
INTERFACE: Support ring in sleeve, elastic band.
FITTINGS
AIRLINE: No data.
COMMUNICATION: None.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral boots or booties.
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: (ASTM 0-751), 110 Ibs/in.
INTERFACE: Splash guard. Tear Strength: (ASTM 0-751), 10 Ibs.
Seam Strength: (ASTM 0-1682), 110 Ibs.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MA TERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
G-39
MATERIAL PROTECTION LEVEL
Vitonl Butyl INylon/8utyl EPA: A
STYLE VENDOR
Trellchem. Super Extra Trelleborg. Inc.
THICKNESS: 15-18 mils 30700 Solon Industrial Parkway
MATERIAL WGT: 16 oz/sq yd Solon. OH 44139
ENSEMBLE WGT: 15 Ibs (216) 248-8600
SIZES: S. M. L. XL
FITTINGS
AIRLINE: No data.
COMMUNICATION: None.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral boots or booties.
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: (ASTM 0-751). 110 Ibs/in.
INTERFACE: Splash guard. Tear Strength: (ASTM 0-751). 10 Ibs.
Seam Strength: (ASTM D-1682). 110 Ibs.
Zipper Strength: No data'.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: 80 mil PVC. Flammability: No data.
INTERFACE: Adhesive bonded. interior strapped Stiffness: No data.
with Viton / butyl. Flex Fatigue: No data.
G-40
APPENDIX H
H-1
SPLASH SUITS
VENDOR/
STYLE PRIMARY MATERIAL DESCRIPTION
DAFFIN DISPOSABLES
PCT POLYETHYLENE/TYVEK TYPES: JACKET, PANTS, COVERALLS,
SARANEX SARANEX/TYVEK ENCAPSULATING SUIT.
FEATURES: STORM FLY FRONT; ZIPPER CLOSURE;
ELASTIC CUFFS ON SLEEVES AND LEGS; INTEGRAL
OVERBOOTS ON SUITS; BOUND SEAHS;EXPANDED BACK
ACCOMMODATES SELF CONTAINED AIR SUPPLY OR
SUIT IS UMBILICALLY FED.
DEFENSE APPAREL
UNSUPPORTED PVC TYPES: JACKET, PANTS, BI8 OVERALL, COVERALL.
DISPOSABLES INC.
P.E. POLYETHYLENE/TYVEK TYPES: COVERALLS, ENCAPSULATING SUIT.
H-2
VENDOR/
STYLE PRIMARY MATERIAL DESCRIPTION
DURAFAB DISPOSABLES
POLYLAMINATED TYVEK POLYETHYLENE/TYVEK TYPES: JACKET, HOOO, PANTS, COVERALL,
SARANEX STYLE SARANEX/TYVEK ENCAPSULATING SUIT.
FEATURES: STITCHED, BOUND, OR BOUND AND SEALED SEAMS;
RAGLAN SLEEVES; SNAPS OR ZIPPER CLOSURE;
ZIPPER CLOSURE ON SUIT;
ELASTIC CUFFS ON SLEEVES AND LEGS;
EXPANDED BACK ON ENCAPSULATING SUITS YILL
ACCOMMODATE SELF CONTAINED AIR SUPPLY OR
SUIT IS UMBILLICALLY FED.
EDMONT
!JET !JEAR 500 PVC/NYLON/PVC TYPES: JACKET, HOOD, PANTS, BIB OVERALLS.
WET !JEAR 550 SUPPORTED PVC
!JET !JEAR 600 PVC/NYLON/PVC FEATURES: THERMALLY !JELDED SEAMS; BATWING
!JET !JEAR 700 NITRILE+PVC/NYLON SLEEVES; NON-CORROSIVE, NON-CONDUCTING
SNAPS.
ENCON
CHLDROPRENE/NYLON TYPES: JACKET, HOOD, PANTS, BIB OVERALLS.
FALCON
PREMIUM GRADE RAYON SUPPORTED PVC TYPES: JACKET, HOOD, PANTS, BIB OVERALLS.
CONTRACT GRADE PVC·RAYON-PVC
NYGRID PVC-NYLON-PVC FEATURES: LAPPED, DOUBLE-STITCHED, WELDED SEAMS;
UNSUPPORTED PVC RAGLAN SLEEVES: NON·CONDUCTIVE SNAPS;
SPLIT. SNAPS TO PREVENT "FREEZING"; WAIST,
WRIST, AND ANKLE TAKE UPS; DRAW-STRING
COAT HEM: !JELDED REINFORCEMENT IN CROTCH
AND ARMPIT.
KAPPLER
P.E. POLYETHYLENE/TYVEK TYPES: JACKET, PANTS, COVERALL, HOOO,
SARANEX SARANEX/TYVEK ENCAPSULATING SUIT.
FEATURES: BOUND OR WELDED SEAMS; ZIPPER CLOSURE;
STORM FLY FRONT; ELASITIC CUFFS ON SLEEVES
AND LEGS; INTEGRAL OVERBOOTS; EXPANDED BACK
ACCOMMODATES SELF CONTA1NED AIR SUPPLY
DR SUIT IS UMBILLICALlY FED.
MAGID
STANDARD DUTY SUPPORTED PVC TYPES: JACKET, HOOD, PANTS, BIB OVERALLS.
B-3
VENDOR/
STYLE PRIMARY MATERIA~ DESCRIPTION
RAINFAIR
POLYLON POLYURETHANE/NYLON TYPES: JACKET, HOOD, PANTS, BIB OVERALLS.
SUPER NYLO-GARD CHLOROPRENE/NYLON/CHLOROPRENE
NYLO-GARD CHLOROPRENE/NYLON FEATURES: STITCHED AND STRAPPED OR CEMENTED
DOLPHIN POLYURETHANE/NYLON SEAMS: STORM FLY FRONT: BATWING
ACID SUIT PVC/POLYESTER/PVC SLEEVES; REFLECTIVE TRIM.
SUPER NEOTEX CHLOROPRENE/COTTON/CHLOROPRENE
SUPER NYLO-SEAL CHLOROPRENE/NYLON
VULTEX SBR/COTTON/CHLOROPRENE
CHEM-KING PVC/NYLON
SBR YANKEE SBR/COTTON
SIEBE NORTON
F-100 CHLOROPRENE/NYLON/CHLOROPRENE TYPES: JACKET, HOOD, PANTS, BIB OVERALLS, COVERALL.
TUFF LON CHLOROPRENE+SBR/NYLON
SUPER TUFFPRENE CHLOROPRENE/COTTON/CHLOROPRENE FEATURES: LAP FRONT OR STORM FLY FRONT; DOUBLE
TUFFPRENE CH~OROPRENE+SBR/COTTON STITCHED SEAM II/SEALANT OR THERMALLY WELDED.
NSPN CHLOROPRENE+SBR/COTTON BATWING OR RAGLAN SLEEVES;
SHIELD BRAND PVC/NYLON/PVC INNER CUFF IN SLEEVE; TAKE-UP SNAPS ON CUFF;
TUFFGARD PVC/NYLON/PVC NON-CONDUCTIVE SNAPS.
006 1/2 H PVC/NYLON/PVC
NSPVH PVC/NY~ON/PVC
IIHEELER
34 LINE FABRIC SUPPORTED CHLOROPRENE TYPES; JACKET, HOOD, PANTS, BIB OVERALLS.
36 LINE FABRIC SUPPORTED PVC
3S LINE FILM UNSUPPORTED PVC FEATURES: STITCHED AND THERMALLY WELDED SEAMS: STORM
FLY FRONT; PLASTIC SNAPS.
H-4
APPENDIX I
1-1
PART 5
I. I NTRODUCTI ON
Personnel must wear protective equipment when response activities
involve known or suspected atmospheric contamination, when vapors,
gases, or particulates may be generated by site activities. or when
direct contact with skin-affecting substances may occur. Full face-
.piece respirators protect lungs, gastrointestinal tract, and eyes
against airborne toxicants. Chemical-resistant clothing protects the
skin from contact with skin-destructive and absorbable chemicals.
Good ~ersonal hygiene limits or prevents ingestion of material.
Equ i pment to protect the body aga i nst contact with known or ant i c i-
pated toxic chemicals has been divided into four categories according
to the degree of protection afforded:
Level A: Should be worn when the highest level of respiratory,
skin, and eye protection is needed.
Level B: Should be worn when the highest level of respiratory
protection ;s needed, but a lesser level of skin protection.
Level C: Should be worn when the criteria for using air-purifying
respirators are met.
Level 0: Should be worn only as a work uniform and not on any
site with respiratory or skin hazards. It provides no protection
against chemical hazards.
The Level of Protection selected should be based on:
Type and measured concentration of the chemical substance
in the ambient atmosphere and its toxicity.
Potential for exposure to substances in air. splashes of liquids,
or other direct contact with material due to work being done.
In situations where the type of chemical. concentration, and
possibilities of contact are not known, the appropriate Level of
Protection must be selected based on professional experience and
judgment until the hazards can be better identified.
While personnel protective equipment reduces the potential for contact
with toxic substances, ensuring the health and safety of responders
requires, in addition, safe work practices, decontamination. site
entry protocols, and other safety procedures. Together, these provide
an integrated approach for reducing harm to workers.
1-2
II. LEVELS OF PROTECTION
A. Level A Protection
1. Personnel protective equipment
Supplied-air respirator approved by the Mine Safety and
Health Administration (MSHA) and National Institute for'
Occupational Safety and Health (NIOSH).
Respirators may be: -
pressure-demand, self-contained breathing apparatus
(SCBA)
or
pressure-demand, airline respirator (with escape bottle
for Immediately Dangerous to Life and Health (IDLH) or
potential for IDLH atmosphere)
Fully encapsulating chemical-resistant suit
- Coveralls·
Long cotton underwear*
- Gloves (inner). chemical-resistant
Boots, chemical-resistant. steel toe and shank. (Depending
on suit construction, worn over or under suit boot)
Hard hat* (under suit)
- Disposable gloves and boot covers* (Worn over fully encap-
sulating suit)
- Cooling unit*
2-Way radio communications* (inherently safe)
2. Criteria for selection
- Meeting any of these criteria warrants use of Level A
Protection:
The chemical substance has been identified and -requires
the highest level of protection for skin, eyes, and the
respiratory system based on:
-- measured (or potent i a1 for) hi gh concent rat; on of
*Opt 1ona 1
I-3
atmospheric vapors. gases. or particulates
or
site operations and work functions involves high
potential for splash. immersion, or exposure to un-
expected vapors, gases. or particulates of materials
highly toxic to the skin.
- Substances with a hi gh degree of hazard to the sk i n .are
known or suspected to be present. and sk in contact is
possible.
- Operations must be conducted in confined, poorly' venti-
lated areas until the absence of substances requiring
Level A protection is determined.
- Direct readings on field Flame Ionization Dectors (FlO) or
Photoionization Detectors (PID) and similar instruments
indicate high levels of unidentified vapors and gases in
tpe air. (See Appendixes I and II.)
3. Guidance on selection
a. Fully encapsulating suits are primarily designed to
provide a gas or vapor tight barrier between the wearer
and atmospheric contaminants. Therefore Level A is gen~
eral1y worn when high concentrations of airborne sub-
stances are known or thought to be present and these
substances could severely effect the skin. Since Level A
requires the use of a self-contained breathing apparatus,
the eyes and respiratory system are also more protected.
Until air surveillance data are available to assist in the
selection of the appropriate Level of Protection. the use
of Level A may have to be based on indirect evidence of
the potential for atmospheric contamination or other means
of skin contact with severe skin affecting substances.
Conditions that may require Level A protection include:
- Confined spaces: Enclosed. confined, or poorly ventilated
areas are conducive to build up of toxic vapors, gases, or
particulates. (Explosive or oxygen-deficient atmospheres
also are more probable in confined spaces.} Confined space
entry does not automatically warrant wearing Level A pro-
tect; on, but shoul d' serve as a cue to carefully consi der
and to justify a lower Level of Protection.
- Suspected/known highly toxic substances: Various sub-
stances that are highly toxic especially through skin
1-4
absorption for example, fuming corrosives, cyanide com-
pounds, concentrated pesticides, Department of Tran-
sportation Poison "A" materials, suspected carcinogens,
and infectious substances may be known or suspected to be
involved. Field instruments may not be available to
detect or quantify air concentrations of these materials.
Unt i1 these substances are' i dent ifi ed and con cent rat ions
measured, maximum protection may be necessary.
Visible emissions: Visible air emissions from leaking
containers or railroad/vehicular tank cars, as well as
smoke from chemical fires and others, indicate high
potential for concentrations of substances that could be
extreme respiratory or skin hazards.
Job functions: Initial site entries are generally walk-
throughs in which instruments and visual observations
are used to make a pre 1 imi na ry eva 1 uat i on of the hazards.
In initial site entries, Level A should be worn when:
there ; s a pro,babil ity for exposure to hi gh con-
centrations of vapors, gases, or particulates.
substances are known or suspected of belng extremely
toxic directly to the skin or by being absorbed.
Subsequent entries are to conduct the many activities needed
to reduce the env;'ronmenta 1 impact of the i nci dent. Level s
of Protection for later operations are based not only on data
obtained from the initial and subsequent .environmental moni-
toring, but also on the probability of contamination and ease
of decontamination.
Examples of situations where Level A has been worn are:
Excavating of soil to sample buried drums suspected of
containing high concentrations of dioxin.
Entering a cloud of chlorine to repair a value broken in a
railroad accident.
Handling and moving drums known to contain oleum.
Responding to accidents involving cyanide, arsenic, and un-
diluted pesticides.
b. The fully encapsu1a}:ing suit provides the highest degree of
protection to skin, eyes, and respiratory system if the suit
material resists chemicals during the time the suit is worn.
While Level A provides maximum protection, all suit material
may be rap; dly permeated and degraded by certa in chem; ca 1s
1-5
from extremely high air concentrations, splashes, or immersion
of boots or gloves in concentrated liquids or sludges. These
limitations should be recognized when specifying the type of
fully encapsulating suit. Whenever possible, the suit
material should be matched with the substance it is used
to protect against.
,8. Level B Protection
1. Personnel protective equipment
Supplied-air respirator (MSHA/NIOSH approved).
Respirators may be:
-- pressure-demand, self-contained breathing apparatus
or
-- pressure-demand, airline respirator (with escape bottle
for IDLH or potential for IDLH atmosphere)
- Chemical-resistant clothing (overalls and long-sleeved
jacket; hooded, one or two-piece chemical-splash suit;
disposable chemical-resistant~ one-piece suits)
Long cotton underwear*
- Coveralls*
Gloves (outer), chemical-resistant
Gloves (inner), chemical-resistant
- Boots (outer), chemical-resistant, steel toe and shank
Boot covers (outer), chemical-resistant (disposable)*
- Hard hat (face shield)*
2-Way radio communications* (intrinsically safe)
2. Criteria for selection
Meeting anyone of these criteria warrants use of Level B
protection:
- The type and atmospheric concentration of toxic substances
has been identified and requires a high level of respira-
tory protection, but less skin protection than Level A.
These would-be atmospheres:
*Optional
I-6
with concentrat ions Immedi ately Dangerous to life and
Health, but subst~rice or concentration in the air
does not represent a severe skin hazard
or
that do not meet the selection criteria permitting the
use of air-purifying respirators.
I-7
factors and other selection criteria all affect the degree
of protection afforded. Therefore, a specialist should
select the most effective chemical-resistant clothing
based on the known or anticipated hazards and job function.
Level B equipment does provides a high level of protection
to the respiratory tract. Generally, if a self-contained
breathing apparatus is required for respiratory protection,
selecting chemical-resistant clothing (Level B) rather than
a fully encapsulating suit (Level A) is based on needing
less protection against known or anticipated substances
affecting the skin. Level B skin protection is selected
by:
- Comparing the concentrations of known or identified
substances in air with skin toxicity data.
- Determining the presence of substances that are destr~c
the to or readily absorbed through the skin by liquid
splashes, unexpected high levels of gases, vapor, or
particulates, or other means of direct contact.
- Assessi ng the effect of the substance (at its measured
air concentrations or potential for splashing)" on the
small areas left unprotected by chemical-resistant
clothing. A hooded garment taped .to the mask, and
boots and gloves taped to the suit further reduces area
of exposure.
c. For initial site entry and reconnaissance at an open site,
approaching whenever possible from upwind, level B protec-
tion (with good quality, hooded, chemical-resistant cloth-
ing) should protect response personnel, providing the
conditions described in selecting level A are k.nown or
judged to be absent.
C. level C Protection
1. Personnel protective equipment
- Air-purifying respirator, full-face, can·ister-equipped
(MSHA/NIOSH approved)
- Chemical-resistant clothing (coveralls; hooded, one-piece
or two-piece chemical splash suit; chemical-resistant hood
and apron; disposable chemical-resistant coveralls)
- Coveralls*
- Long cotton underwear*
- Gloves (outer), chemical-resistant
I-8
- Gloves (inner), chemical-resistant*
- Boots (outer), chemical-resistant, steel toe and shank
- Boot covers (outer), chemical-resistant (disposable)*
- Hard hat (face shield*)
- Escape mask*
- 2-Way radio communications* (inherently safe)
2. Criteria for selection
Meeting all of these criteria permits use of Level C protec-
tion:
- Oxygen concentrations are not less than 19.5% by volume.
- Measured air concentrations of identified substances will
be reduced by the respirator below the substance's thres-
hold limit value (TLV) and the concentration is within
the serVice limit of the canister.
- Atmospheri c contami nant concent rati ons do not exceed IDLH
levels.
- Atmospheric contamin~nts, liquid splashes, or other
direct contact will not adversely affect any body area
left unprotected by chemical-resistant clothing.
Job functions do not require self-contained breathing
apparatus.
Oi rect readi ngs are a few ppms above background on i n-
struments such as the FID or PIO. (See Appendices I and
II. )
*Opt i ona 1
I-9
remove the substances encountered. Quarter-or hal f-masks
~r cheekcartridge, full-face masks should be used only
with the approval of a qualified individual.
In addition, a full-face, air-purifying mask can be used
only if:
Substance has adequate warning properties.
Individual passes a qualitative fit-test for the mask.
- Appropriate cartridge/canister is used, and its service
limit concentration is not exceeded.
b. An air surveillance program is part of all response opera-
tions when atmospheric contamination is known or suspected.
It is particularly important that the air be thoroughly
monitored when personnel are wearing air-purifying respira-
tors. Per; odi c survei 11 ance usi ng di rect-read; ng ; nstru-
ments and ai r sampl i ng is needed to detect any changes in
air quality necessitating a higher level of respiratory
protection.
c. Level C protection with a full-face, air-purifying respi-
rator should be worn routinely in an atmosphere only after
the type of air contaminant is identified, concentrations
measured and the criteria for wearing air-purifying respi-
rator met. To permit flexibility in precrib;ng a Level of
Protection at certain environmental incidents, a specialist
could consider using air-purifying respirators in uni.den-
tified vapor/gas concentrations of a few parts per million
above background as indicated by a needle deflection on the
FlO or PIO. However a needle deflection of a few parts per
million above background should not be the sale criterion
for selecting Level· C. Since the individual components may
never be completely identified, a decision on continuous
wearing of Level C must be made after assessing all safety
considerations, including:
- The presence of (or potential for) organic or inorganic
vapors/gases against which a canister, is ineffective or
has a short service life.
The known (or suspected) presence in air of substances
with low TLVs or IOLH levels.
The presence of particulates in air.
- The errors associ ated with both the instruments and
monitorin~procedures used.
*Opti anal
1-10
The presence of (or potential for) substances in air
which do not el icit a response on the instrument
used.
The potential for higher concentrations in the ambient
atmosphere or in the air adjacent to specific site
operations.
d. The continuous use of air-purifying respirators (Level C)
must be based on the identification of the substances
contributing to the total vapor or gas concentration and
the application of published criteria for the routine use
of air-purifying devices. Unidentified ambient concen-
trations of organic vapors or gases in air approaching or
exceeding a few ppm above background require, as a mini-
mum, Level B protection.
D. Level 0 Protection
1. Personnel protective equipment
- Coverall s
- Gloves*
- Boots/shoes, leather or chemical-resistant, steel toe and
shank
- Safety glasses or chemical splash goggles*
- Hard hat (face shield)*
2. Criteria for selection
Meeting any of these criteria allows use of Level 0 protection:
- No contaminants are present.
Work functions preclude splashes, irTll1ersion, or potential
for unexpected inhalation of any chemicals.
Level 0 protection 1s primarily a work uniform. It can be
worn only in areas where there is no possibility of
contact with contamination.
1-11
commensurate with the hazards inst ituted, prel imi nary measures will
have to be based on experiences judgment, and professional knowledge.
One of the first concerns in evaluating an unknown situation is
atmospheric hazards. Toxic concentrations (or potential concentra-
tions) of vapors, gases, and particulates; low oxygen content explo-
sive potential and, to a lesser degree. the possibility of radiation
exposure all represent immediate atmospheric hazards. In addition to
maki ng ai r measurements to determi ne these hazards, vi sua 1 observa-
'tion and review of existing data can help determine the potential
risks from other materials.
Once immediate hazards, other than toxic substances have been elimi-
nated. the initial on-site survey and 'reconnaissance, which may
consist of more than one entry, continues. Its purpose is to further
char,cterize toxic hazards and, based on these findings, refine
preliminary safety requirements. ' As data are obtained from the
initial survey, the Level of Protection and other safety procedures
are adjusted. Initial data also provide information on which to base
further monitoring and sampling. No one method can determine a Level
of Protection in all unknown environments. Each situation must be
examined individually.
I-12
It. Arthur D. Uttle, Inc.
APPENDIX J
DOFFING PROCEDURES
(Excerpted from "Standard Operating
Safety Guidelines, It 1984, Office of
Emergency and Remedial Response,
U.S. Environmental Protection Agency)
J-l
PART 7
SITE CONTROL .. DECONTAMINATION
I. INTRODUCTION
Personnel responding to hazardous substance incidents may become
contaminated in a number of ways including:
.. Contacting vapors, gases, mists, or particulates in the air.
Being splashed by materials while sampling or openin! containers.
- Walking through puddles of liquids or on contaminated soil.
Using contaminated instruments or equipment.
Protective clothing and respirators help prevent the wearer from
becoming contaminated or inhaling contaminants; while good work
practices help reduce contamination on protective clothing, instru-
ments, and equipment.
Even with these safeguards, contami nat i on may occur. Hannfu 1 mate-
rials can be transferred into clean areas, exposi.ng unprotected
personnel. In removing contaminated clothing, personnel may contact
contaminants on the clothing or inhale them. To prevent such occur-
rences, methods to reduce contamination, and decontamination proced-
ures must be developed and established before anyone enters a site
and must cont i nue (modifi ed when necessa ry) throughout site opera ..
tions.
Decontamination consists of physically removing contaminants or
changing their chemical nature to innocuous substances. How extensive
decontami nat; on must be depends on a number of factors, the most
important being the type of contaminants involved. The more harmful
the contaminant, the more extensive and thorough decontamination must
be. Less harmful contaminants may require less decontamination.
Combining decontamination, the correct method of doffing personnel
protective equpment, and the use of site work zones minimizes cross-
contami nat i on from protect i've cloth; ng to wearer t equi pment to
personnel, and one area to another. Only general guidance can be
given on methods and techniques for decontamination. The exact
procedu re to use must be determi ned after eva 1uat i ng a number of
factors specific to the incident.
J-2
The initial decontamination plan assumes all personnel and equip-
ment leaving the Exclusion Zone (area of potential contamination)
are grossly contaminated. A system is then set up for personnel
decontami nat; on to wash and ri nse, at 1east once, all the pro-
tective equipment worn. This is done in combination with a
sequential doffing of protective equipment, starting at the first
stat i on with the most heavily contami nated item and progress i n9
to the last station with the least contaminated article. Each
piece precedure requires a separate station.
The spread of contaminants during the washing/doffing process is
further reduced by separating each decontamination station by a
minimum of 3 feet. Ideally, contamination should decrease as a
person moves from one station to another further along in the
1; ne •
1-3
------""""~.~~--=-.-.--...--..-------------------...
r----- - -- - ----,
t I EXCLUSION
~ HEAVY EQUIPMENT I
I DECONTAMINATION:
ZONE
I AREA I
I • I EXIT
I ___ - - - _______ ...1I
1. PATH
CONTAMINATION
REDUCTION
ZONE
LEGEND
_ _ • HOTI.INE
_ . CONTAMINATION
CONTROL LINE
to\ ACCESS CONTROl.
'0' POINT. EXTRANCE
CE:J ACCESS CONTROl.
POINT· EXIT
SUPPORT
ZONE
L._---r--_J I AREA I
'I - - _______ ..II
ENTRY
PATH
J-4
overall dimensions of work control zones, and amount of space
available at the site. A corridor of 75 feet by 15 feet should
be adequate for full decontamination. Whenever possible, it
should be a straight path.
The CRC boundaries should be conspicuously marked, with entry and
exit restricted. The far end is the hotline - the boundary
between the Exclusion Zone and the Contamination Reduction Zone.
Personnel exit 1ng the Excl usi on Zone must go through the CRe.
Anyone in the CRe should be wearing the Leliel of Protection
designated for the decontamination crew. Another corridor may be
required for heavy equipment needing decontamination. Within the
CRC, distinct areas. are set aside for decontamination of person-
nel, portable field equipment, removed clothing, etc. These
areas should be marked and personnel restricted to those wearing
the appropriate Level of Protection. All activities within the
corridor are confined to decontamination.
Personnel protective clothing, respirators, monitoring equipment,
and sampling supplies are all maintained outside of the CRee
Personnel don thei r protective equipment away from the CRC and
enter the Exclusion Zone through a separate access control point
at the hotline.
J-S
with higher air concentrations and greater amounts of liquid
contamination. Gross contamination also increases the proba-
bility of personnel contact. Swipe tests may help determine
the type and quantity of surface contaminants.
l. Level of Protection
The Level of Protection and specific pieces of clothing worn
determine on a preliminary basis the layout of the decontamin-
ation line. Each Level of Protection incorporates different
problems in decontamination and doffing of the equipment. For
exampl e: decontami nat ion of the harness straps and backpack
assembly of the sel f-contai ned breathi n9 apparatus is di f.
ficult. A butyl rubber apron worn over the harness makes
decontamination easier~ Clothing variations and different
Levels. of Protection may require adding or deleting stations
in the original decontamination procedure.
4. Work Function
The work each person does determines the potential for contact
with hazardous materials. In turn, this dictates the layout
of the decontamination· line. For example, observers, photo-
graphers. operators of air samplers, or others in the Ex-
clusion Zone performing tasKs that will not bring them in
contact with contaminants may not need to have their garments
washed and rinsed. Others in the Exclusion Zone with a
potential for direct contact with the hazardous material will
require more thorough decontamination. Different decontamin-
ation lines could be set up for different job functions. or
certain stations in a line could be omitted for personnel
performing certain tasks.
5. Location of Contamination
Contamination on the upper areas of protective clothing poses
a greater risk to the worker because volatile compounds may
generate a hazardous breathi ng concentrat i on both for the
. worker and for the decontamination personnel. There is also
an increased probabl1 ity of contact with skin when doff; ng
the upper part of clothing.
6. Reason for Leaving Site
The reason for leaving the Exclusion Zone also determines the
need and extent of decontamination. A worker leaving the
Exclusion Zone to pick up or drop off tools or instruments
and immediately returning may not require decontamination. A
worker reav; ng to get a new ai r cyl i nder or to change a
respirator or canister. however. may require some degree of-
decontamination. Individuals departing the CRC for a break,
lunch, or at the end of day. must be thoroughly decontaminated.
J-6
B. Effectiveness of Decontamination
There is no method to immediately determine how effective decon-
tamination is in removing contaminants. Discolorations, stains,
corros i ve effects. and substances adheri ng to obj ects may i n-
dicate contaminants have not been removed. However, observable
effects only indicate surface contamination and not permeation
(absorption) into clothing. Also many contaminants are not
easily observed.
Amethod for determining effectiveness of surface decontamination
is swi pe test; ng. Cloth or paper patches - swi pes - are wi ped
over predetermined surfaces of the suspect object and analyzed in
a laboratory. Both the inner and outer surfaces of protect 1ve
clothing should be swipe' tested. Positive indications of both
sets of swipes would indicate surface contamination has not been
removed and substances have penetrated or permeated through the
garment. Swipe tests can also be done on skin or inside clothing.
Permeation of protective garments requires laboratory analysis of
a pi ece of the materi a1• Both sw; pe and permeat i on test i n9
provide after-the-fact information. Along with visual obser-
vations, results of these tests can help evaluate the effec-
tiveness of decontamination.
C. Equipment
Decontamination equipment, materials, and supplies are generally
selected based on availability. Other considerations are ease of
equi pment decontami nat i on or di sposab111ty. Most equ i pment and
supplies can be easily procured. For example, soft-bristle scrub
brushes or 1ong-handl e brushes are used to remove contami nants.
Water 1n buckets or garden sprayers is used for rinSing. Large
ga hani zed wash tubs or stocle tanks can hold wash and ri nse
solutions. Children's wadi'ng pools can also be used. Large
plastic garbage cans or other similar containers lined with
plastic bags store contaminated clothing and equipment. Contam-
inated liquids can be stored .temporarily in metal or plastic cans
or drums. Other gear includes paper or cloth towels for drying
protective clothing and equipment.
O. Decontamination Solution
Personnel protective equipment. sampling tools, and other equip-
ment are usually decontaminated by scrubbing with detergent-water
using a soft-bristle brush followed by rinSing with copious
amounts of water. While this process may not be fully effective
in removing some contaminants (or in a few cases, contaminants
may react with water). it is a relatively safe option compared
with using a chemical decontaminating solution. This requires
that the contami nant be i denti fi ed. A decon chemi ca 1 1s then
needed that will change the contaminant into a less harmful
substance. EspeCially troublesome are unknown substances or
J-7
mi xtures from a var1 ety of known or unknown substances. The
appropriate decontamination solution must be selected in consul.
tation with an experienced chemist.
E. Establishment of Procedures
Once decontamination procedures have been established, all person-
nel requiring decontamination must be given precise instructions
(and practice, 1f necessary). Compliance must be frequently
checked. The time it takes for decontamination must be ascer-
tained. Personnel wearing SCBA's must leave their work area with
sufficient air to walk. to CRe and go through decontaminat'ion.
J-8
Life-saving care should be instituted immediately without consid-
ering decontamination. The outside garments can be removed
(depending on the weather) if they do not cause delays, interfere
with treatment, or aggravate the problem. Respirators and back-
pack assemblies must always be removed. Fully encapsulating
suits or chemi cal-resi stant cl oth1 ng can be cut away. If the
outer contaminated garments cannot be safely removed, the individ-
ual should be wrapped in plastic, rubber. or blankets to help
prevent contaminating the inside of ambulances and medical person-
nel. Outsi de garments are then removed at the medi ca 1 1'ac11 ity.
No attempt should be made to wash or rinse the victim at the
site. One exception would be if it is known that the individual
has been contaminated with an extremely toxic or corrosive
material which could also cause severe injury or loss of life.
For minor medical problems or injuries. the normal decontamination
procedure should be followed.
C. Heat St ress
Heat-related 111nesses range from heat fatigue to heat stroke,
the most serious. Heat stroke requires prompt treatment to
prevent irreversible damage or death. Protective clothing may
have to be cut off. Less serious forms of heat· stress requi re
prompt attention or they may lead to a heat stroke. Unless the
victim is obviously contaminated. decontamination should be
omitted or minimized and treatment begun immediately.
D. Chemical Exposure
Exposure to chemicals can be divided into two categories:
Injuries from direct contact. such as acid burns or inhalation
of toxic chemicals.
- Potential injury due to gross contamination on clothing or
equipment.
For inhaled contaminants treatment can only be by qualified
physicians. If the contaminant is on the skin orin the eyes,
1nmed1 ate measures must be taken to counteract the substance s I
J-9
V. PROTECTION FOR DECONTAMINATION WORKERS
The Level of Protection worn by decontamination workers is determined
by:
- Expected or visible contamination on workers.
- Type of contami nant and assoc i ated resp i ratory and sic i n hazards.
- Total vapor/gas concentrations in the CRC.
- Particulates and specific inorganic or organic vapors in the CRC.
- Results of swipe tests.
A. Level C Use
Level C includes a full-face, canister-type air-purifying
respirator. hard hat with face shield (if splash is a problem).
chemical-resistant boots and gloves. and protective clothing.
The body covering recommended is chemical.resistant overalls with
an apron, or chemical-resistant overalls and jacket.
A face shield is recommended to protect against splashes because
respirators alone may not provide this protection. The respirator
should have a canister approved for filtering any specific known
contami nants such as ammoni a • organi c vapors. aci d gases. and
part i cu 1ates.
B. Level B Use
In situations where site workers may be contaminated with un-
knowns. highly volatile" liquids, or highly toxic materials,
decontamination workers should wear Level B protection.
Level B protection includes SCBA, hard hat with face shield.
chemical-resistant gloves, and protective covering. The clothing
suggested is chemical-resistant overalls. jacket. and a rubber
apron. The rubber apron protects the SCBA harness assembly and
regulator from becoming contaminated.
J-10
should be placed in a clear plastic bag, and the bag taped and secured
around the instrument. Openings are made in the bag for sample
intake.
A. Decontamination Procedures
1. Sampling devices
Sampling devices require special cleaning. The EPA Regional
Laboratories can provide information on proper decontamination
lllethads.
2. Tools
Wooden tools are difficult to decontaminate because they
absorb chemicals. They should be kept on site and handled
only by protected workers. At the end of the response,
wooden tools should be discarded. For decontaminating
other tools, Regional Laboratories should be consulted.
3. Respi rators
Certain parts of contaminated respirators, such as the harness
assembly and leather or cloth components. are difficult to
decontaminate. If grossly contaminated. they may have to be
discarded. Rubber components can be soaked 1n soap and water
and scrubbed with a brush. Regulators must be mai ntai ned
according to manufacturer's recommendations. Persons respon-
sible for decontaminating respirators should be thoroughly
trained in respirator maintenance.
4. Heavy Equipment
Bulldozers, trucks, back-hoes, bulking chambers. and other
heavy equipment are di tfi cult to decontami nate. The method
generally used 1s to wash them with water under high pressure
and/or to scrub accessible parts with detergent/water solution
under pressure. if possible. In some cases, shovels, scoops,
and l1fts have been sand blasted or steam cleaned. Particular
care must be given to those components 1n direct contact ~ith
contaminants such as tires and scoops. Swipe tests should be
utilized to measure effectiveness.
B. Sanitizing of Pe.rsonnel Protective Equipment
Respirators, reusable protective clothing, and other personal
articles not only must be decontaminated before being reused, but
also sanitized. The inside of masks and clothing becomes soiled
due to exhalation, body oils. and perspiration. The manufac.
turer's instructions should be used to sanitize the respirator
mask. If practical protective clothing should be machine washed
I
J-H
C. Persistent Contamination
In some instances, clothing and equipment will become contamin-
anted with substances that cannot be removed by normal decontamin-
ation procedures. A solvent may be used to remove such contamin-
ation from equipment if it does not destroy or degrade the pro-
tective material. If persistent contamination is expected,
disposable garments should be used. Testing for persistent
contamination of protective clothing and appropriate decon-
tamination must be done by qualified laboratory personnel.
O. D·i sposa 1 of Contami nated Materi als
All materials and equipment used for decontamination must be
disposed of properly. Clothing. tools, buckets. brushes, and
all other equipment that is contaminated must be secured in drums
or other contai ners and label ed. Cl othi ng not compl etely decon-
taminated on-site should be secured in plastic bags before being
removed from the site.
Contaminated wash and rinse solutions should be contained by
using step-in-containers (for example, child's wading pool) to
hold spent solutions. Another containment method is to dig a
trench about 4 inches deep. and line tt with plastic. In both
cases the spent sol uti ons are transferred to drums, wh; ch are
labeled and disposed of with other substances on Site.
VII. ANNEXES
Annex 1. 2. and 3 descri be bas i c decontami nat i on procedu res for a
worker wearing Level A. 8. or C protection. The basic decontamination
lines (Situation 1), consisting of approximately 19 stations, are
almost identical except for changes necessitated by different pro-
tective clothing or respirators. For each annex, three specific
situations are described in which the basic (or full decontamination)
procedure is changed to take into account di fferences in the extent
of contami nat ion, the accompany; ng changes in equi pment worn and
I
J-12
ANNEX 1
LEVEL A DECONTAMINATION
A. EQUIPMENT WORN
The full decontamination procedure outlined is for workers wearing
Level A protection (with taped joints between gloves, boots. and
suit) consisting of:
- Fully encapsulating suit.
- Self-contained breathing apparatus.
- Hard hat (optional).
- Chemical.resistant. steel toe and shank boots.
• Boot covers.
Inner and outer gloves,
J-13
Station 3: Boot Cover and Glove Rinse
Rinse off decon solution from Station 2 uSing copious amounts of
water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
or
high-pressure spray unit
water
2-3 long-handle. soft.bristle scrub brushes
Station 4: Tape Removal
Remove tape around boots and gloves and deposit in container with
plastic liner.
Equipment: container (20-30 gallons)
plastic liners
Station 5: Boot Cover Removal
Remove boot covers and deposit in container with plastic liner.
Equipment: container (30-50 gallons)
plastic liners
bench or stool
Station 6: Outer Glove Removal
Remove outer gloves and deposit in container with plastic liner.
Equipment: container (20-30 gallons)
plastic liners
Station 7: Suit/Safety Boot Wash
Thoroughly wash fully encapsulating suit and boots. Scrub suit
and boots with long-handle, soft-bristle scrub brush and copious
amounts of decon solution or detergent/water. Repeat as many
times as necessary.
Equipment: container (30-50 gallons)
decon solution
or
detergent/water
2-3 long-handle. soft.bristle scrub brushes
J-14
Station 8: Suit/Safety Boot Rinse
Rinse off decon solution or detergent/water using copious amounts
of water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
or
hi9h~pressure spray unit
water
2-3 long handle, soft-bristle scrub brushes
Station 9: Tank Change
If worker leaves Exclusion Zone to change air tank, this is the
last step 1n the decontamination procedure. Worker's air tank is
exchanged. new outer gloves and boots covers donned, and jOints
taped. Worker then returns to duty.
Equipment: air tanks
tape
boot covers
gloves
Station 10: Safety Boot Removal
Remove safety boots and deposit 1n container with plastic liner.
Equipment: container (30-50 gallons)
plastic liners
bench or stool
boot jack
Station 11: Fully Encapsulating Suit and Hard Hat Removal
With assistance of helper, remove fully encapsulating suit (and
hard hat). Hang suits on rack or layout on drop cloths.
Equipment: rack
drop cloths
bench or stool
Station 12: SC8A Backpack Removal
While still wearing facepiece, remove backpack and place on table.
Disconnect hose from regulator valve and proceed to next station •.
Equipment: table
J-15
Station 13: Inner Glove Wash
Wash with decon solution or detergent/water that will not harm
skin. Repeat as many times as necessary.
Equipment: basin or bucket
decon solution
or
detergent/water
sma 11 tabl e
Station 14: Inner Glove Rinse
Rinse with water. Repeat as many times as necessary.
Equipment: water basin
basin or bucket
small tabl e
Station 15: Facep;ece Removal
Remove facepiece. Deposit in container with plastic liner. Avoid
touching face with fingers.
Equipment: container (30-50 gallons)
plastic; liners
Station 16: Inner Glove Removal
Remove inner gloves and ~eposit in container with plastic liner.
Equipment: container (20-30 gallons)
plas t 1c li ne rs
Station 17: Inner Clothing Removal
Remove clothing soaked with perspiration. Place in container with
plastic liner. Inner clothing should be removed as soon as possible
since there is a possibility that small amounts of contaminants might
have been transferred in removing fully encapsulating suit.
Equipment: container (30-50 gallons)
plastic 1iners
Station 18: Field Wash
Shower if highly toxic. Skin-corrosive or skin.absorbable materials
are known or suspected to be present. Wash hands and face if shower
is not available.
J-16
Equipment: water
soap
sma 11 table
basin or buclcet
field showers
towel s
Station 19: Redress
Put on clean clothes. A dressing trailer is needed in inclement weather.
Equipment: tables
chai rs
lockers
clothes
S STATION NUMBER
I
T
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19
1 X X X X X X X X X X X X X X X X X X
2 X X X X X X X X X
3 X X X X X X X X X X
4 X X X X
J-17
Situation 3: Individual entering the eRe is expected to be minimally
contaminated. Extremely toxic or skin-corrosive materials are not
present. No outer gloves or boot covers are worn. Inner gloves are
not contaminated.
Situation 4: Same as Situation 3 except individual needs new air tank
and w,11 return to Exclusion Zone.
J-18
ANNEX 2
LEVEL B DECONTAMINATION
J-19
Station 3: Boot Cover and Glove Rinse
Rinse off decon solution from Station 2 using copious amounts of
water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
or
high-pressure spray unit
water
2.3 long-handle, soft.bristle scrub brushes
Station 4: Tape Removal
Remove tape around boots and gloves and deposit in container with
plastic liner.
Equipment: container (20-30 gallons)
plastic liners
Station 5: Boot Cover Removal
Remove boot covers and deposit in container with plastic liner.
Equipment: container (30-50 gallons)
plastic liners
bench or stool
Station 6: Outer Glove Removal
Remove outer gloves and deposit in container with plast1c liner.
Equipment: container (20-30 gallons
plastic liners
Station 7: Suit/Safety Boot Wash
Thoroughly wash chemical-resistant splash suit, SCBA, gloves. and
safety boots. Scrub with long-handle, soft-bristle scrub brush
and copious amounts of decon solution or detergent/water. Wrap
SCBA regulator (if belt-mounted type) ·with plastic to keep out
water. Wash backpack assembly with sponges or cloths.
Equipment: container (30-50 gallons)
decon solution
or
detergent/water
2-3 long-handle. soft-bristle scrub brushes
small buckets
sponges or cloths
1-20
Station 8: Suit/SCBA/Boot/Glove Rinse
Rinse off decon solution or detergent/water uSing copious amounts
of water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
or
high-pressure spray unit
water
small buckets
2-3 long-handle, soft-bristle scrub brushes
sponges or cloths
Station 9: Tank Change
If worker leaves Exclusion Zone to change air tank, this is the last
step in the decontamination procedure. Worker's air tank is
exchanged. new outer gloves and boots covers donned, and joints
taped. Worker returns to duty.
Equipment: air tanks
'tape
boot covers
gloves
Station 10: Safety Boot Removal
Remove safety boots and deposit 1n container with plastic liner.
Equipment: container (30-50 gallons)
plast; c 11 ners
bench or stoo 1
boot jack
Station 11: SCBA Backpack Removal
While still wearing facepiece, remove backpack and place on table.
Disconnect hose from regulator valve and proceed to next station.
Equipment: table
Station 12: Splash Suit Removal
With assistance of helper, remove splash suit. Deposit in container
with plastic liner.
Equipment: container (30-50 gallons)
p'ast i c 11 ne rs
bench or stool
J-21
Station 13: Inner Glove Wash
Wash inner gloves with decon solution or detergent/water that will
not harm skin. Repeat as many times as necessary.
Equipment: decen solution
or
detergent/water
basin or bucket
small table
Station 14: Inner Glove Rinse
Rinse inner gloves with water. Repeat as many times as necessary.
Equipment: water
basin or bucket
small table
Station 15: Facepiece Removal
Remove facep1ece. Avoid touching face with gloves. Deposit in
container with plastic liner.
Equipment: container (30-50 gallons)
plastic liners
Station 16: Inner Glove Removal
Remove inner gloves and deposit in container with plastic liner.
Equipment: container (20-30 gallons)
plastic liners
Station 17: Inner Clothing Removal
Remove clothing soaked with perspiration. Place in container with
plastic liner. Do not wear inner clothing off-site since there is
a possibility small amounts of contaminants might have been
transferred in removing fully encapsulating suit.
Equipment: container (30-50 gallons)
plastic liners
Station 18: Field Wash
Shower if highly toxic, skin-corrosive, or skin-absorbable materials
are known or suspected to be present. Wash hands and face if shower
is not available.
J-22
Equipment: water
soap
small tables
basins or buckets
field showers
Station 19: Redress
Put on clean clothes. A dressing trailer is needed in 1nclement
weather.
Equipment: tables
chairs
lockers
clothes
S STATION NUMBER
I
T
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19
1 X X X X X X X X X X . X X X X X X X X
2 X X X X X X X X X
3 X X X X X X X X X X X
4 X X X X
J-23
Situation 3: Individual entering the CRC is expected to be minimally
contamlnated. Extremely toxic or sKin-corrosive materials are not
present No outer gloves or boot covers are worn. Inner gloves are
not contaminated.
Situation 4: Same as Situation 3 except individual needs new air tank
and wlll return to Exclusion Zone.
J-24
ANNEX 3
LEVEL C DECONTAMINATION
A. EQUIPMENT WORN
The full decontamination procedure outlined is for workers wearing
Level C protection (with taped joints between gloves. boots. and
suit) consisting of:
One-piece. hooded, chemical-resistant splash suit.
Canister equipped. full-face mask.
Hard hat.
Chemical-resistant, steel toe and shank boots.
Boot covers.
Inner and outer gloves.
J-2S
Station 3: Boot Cover and Glove Rinse
Rinse off decon solution from Station 2 using copious amounts of
water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
or
high-pressure spray unit
water
2-3 long-handle, soft bristle scrub brushes
Station 4: Tape Removal
Remove tape around boots and gloves and deposit in container with
plastic liner.
Equipment: container (20-30 gallons)
plastic liners
Station 5: Boot Cover Removal
Remove boot covers and deposit in container with plastic liner.
Eqoipment: container (30-50 gallons)
plastic liners
bench or stool
Stltion 6: Outer Glove Removal
Remove outer gloves and deposit in contiiner with plastic liner.
·Equipment: container (20-30 gallons)
plastic liners
Station 7: Suit/Safety Boot Wash
Thoroughly wash splash suit and safety boots. Scrub with long-
handle. soft-bristle scrub brush and copious amounts of decon
solution or detergent/water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
decon solution
or
detergent/water
2-3 long-handle. soft-bristle scrub brushes
Station 8: Suit/Safety Boot Rinse
J-26
Rinse off dec on solution or detergent/water using copious amounts
of water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
or
high-pressure spray unit
water
2-3 long-handle, soft-bristle scrub brushes
Station 9: Canister or Mask Change
If worker leaves Exclusion Zone to change canister (or mask). this
is the last step in the decontamination procedure. Worker1s canister
is exchanged, new outer gloves and boots covers donned, and joints
taped. Worker returns to duty.
Equipment: canister (or mask)
tape
boot covers
gloves
Station 10: Safety Boot Removal
Remove safety boots and deposit in container with plastic liner.
Equipment: container (30-50 gallons)
plastic liners
bench or stool
boot jack
Station 11: Splash Suit Removal
With assistance of helper, remove splash suit. Deposit in container
with plastic liner.
Equipment: container (30-50 gallons)
bench or stool
liner
Station 12: Inner Glove Wash
Wash inner gloves with decon solution or detergent/wate~ that will
not harm skin. Repeat as many times as necessary.
Equipment: decon solution
or
detergent/water
basin or bucket
J-27
Station 13: Inner Glove Rinse
Rinse inner gloves with water. Repeat as many times as necessary.
Equipment: water
basin or bucket
small table
Station 14: Facepiece Removal
Remove hcepiece. Avoid touching face with gloves.Oeposit
facepiece in conta1ner with plastic liner.
Equipment: container (30-50 gallons)
plastic liners
Station 15: Inner Glove Removal
Remove inner gloves and deposit in container with plastic liner.
Equipment: container (20-30 gallons)
plast1 c 11 ners
Station 16·: Inner Clothing Removal
Remove clothing" soaked with perspiration. Place in container with
plastic liner. 00 not wear inner clothing off-site since there ;s
a possibility small amounts of contaminants might have been
transferred in removing splash suite.
Equipment: container (30.50 gallons)
plast i c 11 ners
Station 17: Ffe1d Wash
Shower if highly toxic, skin-corrosive or skin-absorbable materials
are known or suspected to be present. Wash hands and face if shower
is not available.
Equipment: water
soap
tables
wash basins/buckets
field showers
Station 18: Redress
Put on clean clothes. A dressing trailer is needed in inclement weather.
J-28
Equipment: tables
~hairs
lockers
~lothes
S STATION NUMBER
I
T
1 2 3 4 5 6 1 8 9 10 11 12 13 14 15 16 17 18
1 X X X X X X X X X X X X X X X X X X
2 X X X X X X X X X
3 X X X X X X X X X
4 X X X X
J-29
ANNEX 4
LEVEL A DECONTAMINATION, MINIMUM LAYOUT
A. EQUIPMENT WORN
The decontamination procedure outlined is for workers wearing Level A
protection (with taped joints between gloves, boots, and suit) consisting
of:
,
Fully encapsulating suit with integral boots and gloves.
Self-contained breathing apparatus.
Hard hat (optional).
Chemical.resistant, steel toe and shank boots.
Boot covers.
Inner and outer gloves.
J-30
rinse water
2-3 long-handle, soft-bristle scrub brushes
J-31
Equipment: water
soap
tab1 es
wash basin/bucket
J·-32
Volume II: Technical and Reference Manual
February 1987
Arthur D. Little, Inc. prepared this document with what it belieevs is the best currently
available information. The document is subject to revision as additional knowledge and
experience are gained. Arthur D. Little cannot guarantee the accuracy of information used
to deelop the chemical protective clothing recommendations contained herein, and the
mention of company names or products does not constitute endorsement by Arthur D.
Little. Arthur D. Little accepts no responsibility for damages or liabilities of any kind
which may be claimed to result from the use of this document.
ACKNOWLEDGEMENTS
This Guidelines for che Selection of Chemical Protective Clothing was
prepared by Arthur D. Little, Inc. (Cambridge, Massachusetts), under
subcontract to Los Alamos National Laboratory (New Mexico) for the
U. S. Environmental Protection Agency (EPA) and the u. S. Coast Guard.
Particularly helpful in the preparation of this, the third edition of
the Guidelines were J.F. Stampfer and H.J. Ettinger (Los Alamos National
Laboratory) and Krister Forsberg. Mr. Forsberg of the Royal Institut~
of Technology (Stockholm) reviewed each line of data presented in
Appendix A of Volwne II for consistency with the original literature
sources. We also thank Dr. Douglas Walters of the National Toxicology
Program for contributing an extensive compilation of glove permeation
data generated for the NTP by the Radian Corporation.
11i
SPECIAL,NOTt.fO USERS
This document contains comprehensive tables of recommendations to aic
and facilitate the selection of chemical protective clothing (epC). lne
recommendations are based on an extensive compilation and ar.alysis c)r
e"pc vendors' literature and €'xperimenta1 test data publi shed in techni-
cal journals and reports. It is imperative that users of th~ recommen-
dution tc:bles familiarize themselves with thE backgr0und informatior.
that precedes and accompanies the tables. The selection of CPC must
take into account the potential hazard and the conci tions 'Of use - -
neither is ~onsider~d in this document. The recommendations are noc no,
do they imply a guarantee of safety.
Al though every effort has been made to prepare this document as aCCLl-
ra~ely as possible, errors can and do occur. Users of this document a~e
asked to notify Lt. Jeffrey o. Stull, Commandant (G-DMT-3), U.S. Coast
Guard. 2100 Second Street, S.W., Washington, D.C. 20593 (202-267-0853),
or Mr. David Weitzman, U.S. Environmental Protection Agency, Office of
Occupational Health and Safety, Room 3503, Waterside Mall, 401 M Street.
S.W., Washington~ D.C. 20460 (202-382-3647) of errors so that they can
be corrected.
iv '
TABLE OF CONTENTS
VOLUME II
Page
CHAPTER 1 - OBJECTIVES, LIMITATIONS AND
ASSUMPTIONS FOR THE GUIDELINES 1
A. INTRODUCTION 1
B. OBJECTIVES 1
C. LIMITATIONS 2
D. ASSUMPTIONS 3
E. INSTRUCTIONS FOR GUIDELINES USE 3
CHAPTER 2 - PERMEATION THEORY 4
A. INTRODUCTION 4
B. IDEAL PERMEATION 4
C. ANOMALOUS PERMEATION 8
D. PERSISTENT PERMEATION 9
v
TABLE OF CONTENTS (CONTINUED)
Page
CHAPTER 4 - ANALYSIS OF THE VENDORS' LITERATURE 20
A. INTRODUCTION 20
B. REVIEW OF VENDORS' LITERATURE 20
C. PERSPECTIVES ON VENDORS' LITERATURE 23
D. CONCLUSION 24
B. GOVERNMENT 25
C. PROFESSIONAL ORGANIZATIONS 26
D. TECHNICAL LITERATURE 26
BIBLIOGRAPHY 28
vi
CHAPTER 1
OBJECTIVES, LIMITATIONS, AND
ASSUMPTIONS FOR THE GUIDELINES
A. INTRODUCTION
The selection of the best chemical protective clothing (CPC) for use
against a particular chemical can be a difficult and perplexing task. A
principal reason for this situation is that the necessary information,
if any is available. has not been organized. Vendors' recommendations
tables provide guidance but there is little or no basis on which to
compare products. Technical reports of CPC performance have increased
in number in recent years. but are scattered through the literature. and
again. there is no standard format for reporting data.
The EPA's Occupational Health and Safety staff has repeatedly faced this
situation in its attempts to provide guidance to field personnel in-
volved in the clean-up of hazardous waste sites. Furthermore. the
U.S. Coast Guard has particular needs for consolidating information on
full-body protective ensembles. We. therefore. have developed this
two-volume Guidelines for the Selection of Chemical Protective Clothing.
This third edition of the Guidelines has been completely updated from
those of 1983 and 1985. The key objectives. limitations, assumptions.
and instructions for use of this publication are described in the
following paragraphs.
B. OBJECTIVES
The main objective of the Guidelines is that it be a concise. up-to-date
source for information relative to selection of personal protective
clothing. Its principal focus is clothing for protection against
chemicals which are potentially harmful to humans. More specifically,
the Guidelines addresses the chemical resistance of protective clothing
materials and the design features of full-body protective ensembles and
splash suits. The Guidelines is designed to:
1
"
It. .<
.
• Provide listings of cre products and a directory of cpe
vendors.
c. LIMITATIONS
2
D. ASSUMPTIONS
The Guidelines is developed under three key assumptions:
3
CHAPTER 2
PERMEATION THEORY
A. INTRODUCTION
The purpose of the Guidelines is to facilitate the selection of CPC on
the basis of its effectiveness as a barrier to potentially hazardous
chemicals. Since chemical resistance is the focus, it is appropriate to
include a discussion of permeation theory. In Chapter 3. Volume I. a
brief overview of the key aspects of the theory is presented. The
present chapter contains a more in-depth discussion of the subject. In
addition several other theoretical factors which were considered in
developing the CPC recommendations are summarized.
B. IDEAL PERMEATION
Permeation of a chemical through a barrier is a three-step transport
process involving (1) the sorption of molecules of the chemical at the
contacted surface of the barrier, (2) the diffusion of the sorbed mole-
cules through the barrier, and (3) the desorption of the molecules from
the opposite surface of the barrier. 8 S , " In cases involving direct
liquid contact with a clothing material, the diffusion step is the rate
controlling step in the permeation process and, therefore, is the topic
of the remainder of the discussion.
J -D dc (1)
dx
where
4
estimated over a wide range of thicknesses and challenge concentration
conditions. Such a prediction is appropriate since permeatian criteria
for protective clothing might ultimately be specified as a maximum
allowable flux rather than a breakthrough time. as is more commonly the
case today.
(2)
where
1
(3)
J (5)
5
It should be noted here that many polymers swe11--thereby changing their
thickness--upon the invasion of a permeating chemical. Crank discusses
this on page 28 of The Mathematics of Diffusion.ls Conventional practice
is to disregard this change in the above integration and subsequent
calculation of D.
(6)
6
c:
....
0.,o
...
c:
g
U
~
t~
Steady State
~
a
Transition
Breakthrough
'/
'I
4---;-. Lag- Ti~e Extension
T L = Lag Time
O~----------~~~--~====~-=~=---------------------~
o Membrane Exposure Time, t
DL - (7)
C. ANOMALOUS PERMEATION
8
• where the chemical extracts components from the CPC materials.
For example, leaching of plasticizer from PVC clothing will
significantly affect its barrier as well as functional proper-
ties.
Nelson et a1. 222 , 'Weeks et a1. 326 ,327, and Crank and Park 84 present
additional discussions of this subject.
D. PERSI~TEltt PERMEATION
Once a chemical has begun to diffuse into a plastic/elastomer, it will
continue to diffuse even after the chemical on the surface is removed.
This is due to the concentration gradient that develops wi thin the CPC
and the natural tendency for a gradient to equilibrate with its surround-
ings. This phenomenon has significant implications relative to decontam-
ination and reuse of CPC.
First, in the case of CPC which has not suffered chemical breakthrough
but has absorbed some chemical before the chemical is removed from th.e
surface, the chemical may eventually appear on its inside surface. The
amount of chemical reaching the inside will be dependent upon the amount
of chemical absorbed and its permeation rate. For example, where the
absorbed amount is small and the rate slow, it is likely that a large
fraction of the absorbed chemical will return to the outside surface
where, if it is volatile, it will evaporate to the air, and little or no
chemical will reach the inside surface. On the other hand where the
permeation rate is fast, there is the potential that a large amount of
chemical will appear on the inside surface, perhaps after overnight
storage in a locker. liS
9
or functional groups tend to permeate a given material at relatively
similar rates. Extensions and refinements of this premise are
that: 282 ,316
10
Typical variations of the theory relate to the factors that are included
in the calculation of the solubility parameter and how these parameters
are weighted. One of the more widely accepted concepts is the three-
component parameter which combines factors for the hydrogen bonding,
polarity and dispersion forces of the chemical to yield its overall
solubility parameter. Other systems deal with two of these factors.
Still other systems favor the single-component solubility parameter and
then make adjustments for polarity or hydrogen bonding depending on the
application. Similar considerations are also required for the p1astic/
rubbe.r of CPC.
11
CHAPTER 3
TEST METHODS
A. INTRODUCTION
B. SOLUBILITY
12
performed simultaneously using as little as 0.5 g and as much as 100 g of
clothing material per test, depending on the sensitivity of the balance.
c. DEGRADATION
The physical and/or aesthetic qualities of CPC can be significantly and
and undesirably changed due to exposure to chemicals. Chemical degrada-
tion testing simply involves measuring the properties or qualities of
interest before and after exposure to the chemical. The results are
compared and the change, if there is any, judged as to its acceptability
for the intended application of the item of clothing. ASTM Method D543
describes one such method for plastic materials. ASTM Committee F-23 is
presently developing a method specifically focussed on clothing materi~
also
D. PERMEATION
Breakthrough time and permeation rate are determined by means of a
13
Challenge Chamber for
Test Chemical
Chamber
TFE-fluorocarbon Seal
14
principal factors considered in selecting an analytical method. For
relatively volatile chemicals, gas chromatography and infrared spectro-
photometry are the preferred methods. Liquid chromatography is used for
relatively nonvolatile organic compounds. Ion chromatography is particu-
larly useful for inorganic acids and salts. Finally, radiolabelled
compounds may be preferred where high sensitivity and specificity is
required; furthermore, if the compound of interest is readily available
in radiolabelled form, radiochemical methods may be significantly less
costly than the development and use of the other techniques.
A notable difference between the ASTM and ISO standards is the inclusion
of clothing labelling (marking) instructions in the ISO method. The
label must indicate the performance of the clothing material as a barrier
to the test chemicals. Such labeling is an aid to those considering the
use of the clothing much the same as fire extinguisher labels are.
15
acetate, n-hexane, methanol, nitrobenzene, 50% sodium hydroxide, sulfuric
acid, tetrachloroethylene, tetrahydrofuran, and toluene.
E. VISIBILITY
Face shields and lenses, in addition to being chemical barriers, must
provide clear, undistorted vision to the wearer. Hard, inflexible face
shields and lenses may be subject to crazing (Le., surface cracking)
upon contact with certain chemicals. Crazing renders the surface foggy
and can drastically reduce vision. Since chemical contact with the face
shield or lens is more likely to occur in uncontrolled or emergency
situations when reduced vision would be an additional severe hazard,
shields and lens materials should be tested for resistance to chemical
attack. Crazing can also reduce the impact strength of the material.
F. PENETRATION
ASTM Committee F-23 has promulgated method F903-84 for the evaluation of
the penetration resistance of CPC and its materials of construction.
Briefly, a swatch of material or seam or closure is clamped in a two-
16
chambered cell. The chemical of concern is charged to one chamber and
pressure applied. The unexposed surface in the second chamber is ob-
served for appearance of the chemical.
G. OTHER FACTORS
The focus of the Guidelines and the above discussion is chemical resis-
tance of clothing materials. It is important to consider, however, that
in the selection and use of protective clothing other factors may be of
equal" or greater importance. For example, gloves must provide the wearer
some minimum level of dexterity, and the fabrics must have some level of
tear resistance. The relative importance of the performance factors is
largely dependent on the work tasks to be carried out.
17
TABLE 3.1
Characteristics Test
A. Chemical Resistance
B. Strength
18
TABLE 3.1 (Continued)
Characteristics Test
C. Dexterity/Flexibility
D. Aging Resistance
*Physical property tests are listed in Tables 5.2 and 5.3 of Volume I.
19
CHAPTER 4
ANALYSIS OF THE VENDORS' LITERATURE
A. INTRODUCTION
The catalogues of 150 CPC vendors and materials suppliers were reviewed
during the preparation of the Guidelines. Twenty-six of these documents
included chemical resistance ratings charts for some or all of the
products listed. These tables encompassed both qualitative and quantita-
tive ratings. In only a few cases was the rationale for the qualitative
ratings described in the catalogues. The rationale is necessary for any
attempt to form conclusions regarding the expected performance of CPC and
to compare products. Consequently, telephone interviews were conducted
with the CPC vendors who provided qualitative ratings. The telephone
interviews yielded little information that would further aid the utiliza-
tion of the qualitative ratings. The overall impression was that most
vendors are either not testing clothing or are not willing to share their
results.
The situation is much different for the chemical resistance tables that
are based on permeation test results. Virtually all vendors who provide
such data followed ASTK Method F739, or a similar procedure.
1. Permeation Testinq
Permeation data are supplied or available on request from at least ten
CPC vendors or materials suppliers. This number is up from six in 1985.
Furthermore, the number of chemicals and range of products have increased
significantly, and this increase can be expected to continue. CPC users
have become more demanding of the vendors and the vendors have found that
test data are useful as points of product differentiation.
20
However, the increased availability of test results carries with it the
problems associated with comparing and interpreting data. The vendors do
not use a standard format for presenting the data and, as discussed
earlier, the test results can be highly dependent on the testing proce-
dure. In order to compare breakthrough times, it is necessary to know
the sensitivity of the detector. the surface area of the clothing
material, and the collection medium volume if the test is performed in a
closed-loop mode or the collection medium flowrate if the test is
performed in an open-loop mode. The following discussion provides some
insights into reviewing and utilizing published breakthrough time and
permeation rate data.
Test results are available from the following vendors: Ansell, Best,
ChemFab, Comasec, DuPont, Edmont, MSA, North, Pioneer. and Playtex. (see
the Appendix D of Volume I for the complete corporate name and address.)
All except Best provide breakthrough time data; Best ranks by break-
through time the materials tested. All except MSA report permeation rate
data The units used by all excep~ Edmont for permeation rate are
2
mg/m /s; Edmont reports values pg/cm /min, consistent with ~STM F739.
Multiply the Edmont values by 0.167 to convert them to mg/m Is. Only
Best and ChemFab report the sensitivity of the instrument used to detect.
breakthrough. Only MSA provides information on the mode of testing
(open-loop) and the collection medium flowrate. Some of the others
provide information on the mode of testing but not the collection medium
volume or flowrate. Consequently. it is not possible to rigorously
compare breakthrough time data from vendor to vendor. As suggested above
and by the vendors themselves the data should be used for guidance only
and imply no guarantee of protection.
2. Immersion Testing
Most qualitative recommendations tables appear to be based on simple
immersion tests in which the material was merely observed after some time
period. There is no standard time for immersion and. of course, the
rating associated with any given test is likely to vary from observer to
observer. Furthermore. in some cases materials that were swelled by
chemicals may have been given an acceptable recommendation if upon drying
they returned to their original size and appearance. Obviously a materi-
al which is visibly swelled by a chemical will not be a barrier to that
chemical and should be given a "not recommended" rating ..
21
3. Applicability of Ratings Tables
The degree of applicability of some of the ratings tables to presently
available CPC is somewhat limited by two factors: age and materials
composition. Many of the tables are more than ten years old. Between
the time that the tables were generated and now, it is probable that the
actual elastomer/plastic formulation used in the CPC has been changed.
This may have resulted from a CPC manufacturer switching raw materials
suppliers or modifying the formulation to meet changed processing, use or
cost requirements. Changes to, for example, the plasticizer, lubricant,
filler, and so forth, level in a elastomer/plastic formulation can in
some cases significantly influence the chemical resistance of the final
product.
Similarly, most of the ratings charts appear to have been developed for a
general class of material (for example, natural rubber or PVC) and not
the specific formulations used for protective clothing. Thus, the
ratings mayor may not be directly applicable to CPC.
The form of the elastomer/plastic can also influence the results on which
recommendations may be based. For example, a molded neoprene rubber can
have significantly different properties from those of a neoprene prepared
from a latex. Within the realm of CPC, it has recently been suggested
that gloves prepared by a latex process may perform differently from
gloves prepared by a solvent-dip process, but that additional evaluation
was required before definite conclusions could be reached. 326 It is not
clear whether the recommendations of manufacturers which have switched
from solvent to latex processing during the past 10 to 15 years have been
modified to reflect any performance differences that may have resulted.
The temperature range over which the ratings apply is not generally
stated. CPC users should note that there can be significant temperature
effects on permeation over the temperature range likely to be encountered
in the field. For example, the breakthrough times for benzene through a
0.08 cm neoprene were found to be 40 min at 7°C, 24 min at 2rC, and
16 min at 37°C.18
22
similarly. In these cases, the CPC user must carefully scrutinize the
catalogues in order to differentiate among the products and make the best
selection for the application at hand.
4. Multi-component Solutions
Multi-componet solutions represent a potentially large and difficult area
for CPC selection and use. In general most vendors address only aqueous
solutions in their ratings tables. Several vendors are careful to
designate a concentration range for each recommendation; many do not.
Small fractions of particularly permeable chemicals in a solution can
severely degrade clothing materials or can provide pathways for the
movement of other components of the solutions. Furthermore, there is an
unlimited number of solution compositions possible. Generally, the
vendors recommend that the CPC buyer conduct his own tests with the
specific solutions of concern. Multi-component solutions are of growing
interest to the research community and others. 104 ,124,278,302
5. Experience
Several manufacturers reported that some of the recommendations appearing"
in their tables were based on experience rather than testing. This may
or may not be appropriate depending on how the experience was judged.
For example, in many cases an item of CPC may be considered good for a
particular application because it does not fall apart or beCause it
returns to its original shape/size upon evaporation of absorbed chemical.
Obviously such criteria are not appropriate if skin contact with the
chemical is a primary concern.
Although the above findings and comments can be rather perplexing, for
those responsible for selecting CPC, the situation is changing rapidly
for the better:
23
analysis of epe performance, as evidenced by this publication
and an increase in government sponsored research and develop-
ment.
D. CONCWSION
During the next several years, other sources for epe recommendations can
be expected to increase. Such sources, of which this publication is an
example, will be based on the compilation of both manufacturers' recom-
mendations and the scientific literature. It is reasonable to predict
and it is hoped that the existence of one or more key secondary sources
will stimulate more testing and quantitative reporting of epe performance
by both the vendors and the technical community at large. The resul t
will be more firmly based epe selection decisions.
24
CHAPTER 5
SOURCES FOR CHEMICAL PROTECTIVE
CLOTHING INFORMATION
A. INDUSTRY
By far the best source for information on epc is the CPC vendors. The
large, full-line vendors and the specialty products manufacturers gener-
ally' have tested their products against a wide range of chemicals.
Furthermore, they have years of experience with their products. and
typically have a very good understanding of the products' capabilities
and limitations. A listing of vendors is given in Volume I. Appendix D.
B. GOVERNMENT
Principal sources of CPC information within federal government agencies
are:
25
c. PROFESSIONAL ORGANIZATIONS
In the United States, three professional organizations have committees
directly focused on protective clothing. ASTM formed Committee F-23 in
1977 for the purpose of developing standard test methods for protective
clothing. Subcommittees of F-23 are addressing the chemical resistance
of clothing, the physical properties of clothing, clothing classification
methods, and the performance 'of full-body protective ensembles. The
committee is composed of industry, government, and general interest
members. It meets twice a year and is a forum for discussing protective
clothing test methods. In addition in 1984 and in 1987 Committee F-23
sponsored international symposia on all aspects of protective clothing.
Proceedings of the symposia are published by ASTM as Standard Technical
Publications. For further information, telephone ASTM headquarters (215-
299-5579).
D. TECHNICAL LITERATURE
26
A new journal. Applied Industrial Hygiene. has been started by the
American Conference of Governmental Industrial Hygienist (ACGIH). 6500
Glenway Avenue. Bldg. D-7. Cincinnati, OH 45211. Telephone 513-661-7881.
Also articles on protective clothing are usually included in the proceed-
ings of Hazardous Materials Management Conference (Tower Conference
Management Cempany. Wheaton. IL 60187) and the Hazardous Material Spills
Conference (Government Industries, Inc., Rockville. MD 20850).
27
BIBLIOGRAPHY
28
1 Abernathy, R.N., R.B. Cohen, and J.J. Shirtz
Measurements of Hypergolic Fuels and Oxidants Permeation
Through Commercial Protective Materials--Part I: Inhibited
Red Fuming Nitric Acid and Unsymmetrical Dimethylhydrazine
Am. Ind. Hyg. Assoc. J. 44(7), pp. 505-513 (1983)
4 A1gera, R.
Development of a Hazardous Chemical Protective
Ensemble: Phase I Interim Report
This report available as:
Stull, J., Early Development of a Hazardous Chemical
Protective Ensemble, Final Report U.S. Coast Guard
Contract DTCG23-8l-C-20003, AD A174 885 (October 1986)
10 Anon.
Foot and Leg Protection
National Safety News, pp. 176-182 (March 1962)
29
II Anon.
A Summary of the Record of the NIOSH Open Meeting on
Chemical Protective Clothing
Rockville, Maryland, (June 3, 1981)
l2 Anon.
Balancing the Scales Between Protection and Economy
National Safety News, pp. 36-39 (April 1982)
13 Anon.
Protective Clothing Studies Reveal Wearer Preferences
Agrichemica1 Age, (June 1981)
14 Anon.
Protective Clothing for Chlorine, Edition 1
Chlorine Institute Pamphlet 65, The Chlorine Institute, Inc.
New York, New York, (June 1978)
15 Anon.
Best Safety Directory, Vol. I
A.M. Best Company, Oldwick, New Jersey 08858
16 Anon.
Health and Safety Market Guide '82
Ayde Marketing Limited, 2 Castle Street, Aylesbury, Bucks
HP20 20RF England
17 Anon.
Industry's Persistent Problem: Occupational Dermatitis
National Safety News, pp. 33-37 (November 1982)
18 Anon.
Dress Right for Safety: Foot Protection: Shoes
National Safety News, pp. 66-67 (March 1983)
19 Anon.
Dress Right for Safety: Hand Protection
National Safety News, pp. 62-65 (March 1983)
20 Anon.
Dress Right for Safety: General Body Protection
National Safety News, pp. 54-57 (March 1983)
30
21 Anon.
Dress Right for Safety: Disposable Apparel
National Safety News, pp. 57-59 (March 1983)
22 Anon.
Dress Right for Safety: Eye and Face Protection
National Safety News, pp. 41-44 (March 1983)
23 Anon.
A Shift Toward Protective Gear
Business Week, p. 56 (April 13, 1981)
24 Anon.
Safety Spinoffs From Space
National Safety News, pp. 30-32 (February 1984)
25 Anon.
Hazardous Waste Workers Are Seen Underprotected by Union,
Congressmen, Chemical Marketing Reporter, pp. 5,40
(April 1, 1985)
27 ARAMSCO
Catalogue
1986
28 Arbill Inc.
Catalogue
1986
29 Armin Corp.
Catalogue
1986
30 Arrowhead Products
Catalogue
1986
31 Aydelotte, C.L.
Consider Hazards Facing Worker in Making Proper Glove
Selections, Occupational Health & Safety, pp. 54,56
31
32 Barker, R.L., and Coletta, G.C.
Performance of Protective Clothing
ASTM STP 900, ASTM PCN 04-900000-55, Philidelphia, PA
(1986)
38 Barton, A. M.
Solubility Parameters
Chemical Reviews, 75(6), pp. 731-749 (1975)
39 Barton, A.F.M.
Handbook of Solubility Parameters and Other Cohesion
Parameters
CRC Press, Boca Raton, FL (1983)
40 Bel-Art Products
Catalogue
1981
41 Berardinelli, S.
Chemical Protective Clothing Standard Test Method
Development Final Report No.1: Penetration Test Method
NIOSH Contract No. 200-84-2702
32
42 Berardinelli, S.P., R.L. Mickelsen, and M.M. Roder
Chemical Protective Clothing: A Comparison of Chemical
Permeation Test Cells and Direct-Reading Instruments
Am. Ind. Hyg. Assoc. J. 44(12), pp. 886-889 (1983)
47 Body-Guard
Catalogue
1984
49 Bosserman, M.W.
How to Test Chemical-Resistance of Protective Clothing
National Safety News, pp. 51-53 (September 1979)
33
53 Butt, L.T., J. Pacitti, and J.R. Scott
Chemical Resistance Data Sheets, Vols. I and II
Rubber and Plastics Research Association (RAPRA) , Shawbury,
Shrewsbury, SY4 4NR England
57 Charkate
Catalogue
1986
58 Chemical Engineering
New Wardrobe for CPI Workers
pp. 14-15 (August 19, 1985)
60 Cheron, J.
Resistance des Gants de Protection aux Solvents
Industriels - Resultats Obtenus Avec L'Acetone Sur Dne
Centaine de Gants du Commerce
Travail et Securite, No. 527, Oct. 1975, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14
61 Cheron, J.
Resistance des Gants de Protection Aux So1vants
Industriels - Resultats Obtenus Avec Ie Trichlorethane Sur
Dne Centaine de Gants du Commerce
Travail et Securite, No. 502, Oct. 1973, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14
34
62 Cheron, J.
Resistance des Gants de Protection Aux Solvants
Industriels - Resultats Obtenus Avec L'Acetate D'Ethyle Sur
Une Centaine de Gants du Commerce
Travail et Securite, No. 547, Sept. 1976, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14
63 Cheron, J.
Resistance des Gants de Protection Aux Solvants
Industriels - Resultats Obtenus Avec L'Ethanol Sur Une
Centaine de Gants du Commerce
Travail et Securite, No. 550, Nov. 1976, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14
64 Cheron, J.
Resistance des Gants de Protection Aux Solvants
Industriels - Resultats Obtenus Avec Ie Toluene Sur Une
Centaine de Gants du Commerce
Travail et Securite, No. 503, Jan. 1975, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14
65 Cheron, J.
Resistance des Gants de Protection Aux So1vants
Industrie1s - Resu1tats Obtenus Avec Ie Trichlorethylene Sur
Une Centaine de Gants du Commerce
Travail et Securite, No. 491, Oct. 1972, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14
66 Cheron, J.
Resistance des Gants de Protection Aux So1vants
Industriels - Resultats Obtenus Avec Ie Perchlorethylene Sur
Une Centaine de Gants du Commerce
Travail et Securite, No. 498, June 1973, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14
67 Cheron, J.
Resistance des Gants de Protection Aux Solvants
Industrie1s - Resultats Obtenus Avec Ie Cyclohexane Sur Une
Centaine de Gants du Commerce
Travail et Securite, No. 521, Jan. 1975, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14
68 Cheron, J.
Resistance des Gants de Protection Aux Solvants
Industrieis - Resultats Obtenus Avec Ie White-Spirit Sur Une
Centaine de Gants du Commerce
Travail et Securite, No. 506, June 1974, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14
35
69 Cheron, J., J.-P. Guenier, B. Moncelon and Lima
Resistance des Gants de Protection Aux Solvants
Industriels - Tableaux Recapitulatifs
Travail et Securite, No.573, Dec. 1976, Institut
National de Recherche et de Securite, 75680, Paris, Cedex 14
70 Christensen, U.L.
Handsker - sikre/usiker (in Danish)
English summary available from Institute of York
Environment, Denmark Institute of Technology,
DK-2800 Lyngby (April 1983)
73 Coletta, G.C.
Chemical Protective Clothing: Technology Will Shape the
Future, Occupational Health & Safety, pp. 50-54
(September 1985)
74 Coletta, G.C.
Chemical Protective Clothing: Determining Good Performance
Occupational Health & Safety, pp. 20-22 (April 1985)
75 Coletta, G.C.
Chemical Protective Clothing: Testing Strategy and Test
Methods, Occupational Health & Safety, pp. 49-52 (May 1985)
76 Coletta, G.C.
Chemical Protective Clothing: Laboratory vs. Field
Performance, Occupational Health & Safety, pp. 85-87
(June 1985)
77 Coletta, G.C.
Chemical Protective Clothing: The Influence of Federal
Agencies, Occupational Health & Safety, pp. 27-29
(July 1985)
36
79 Colonial Glove & Garment Inc.
Catalogue
1986
80 Comasec, Inc.
Catalogue
1986
83 Crank, J.
Mathematics of Diffusion
Second Edition, Claredon Press (1975)
86 Cullinane, J.
Evaluation of the Permeation Resistance of Polymer Gloves
to an Organophosphorus Pesticide and Pesticide Carrier
Solvents
IT Corporation, Report to EPA under contract 68-03-3069,
(May 1985)
37
89 Dayton Flexible Products, Inc.
CacaL)gue
1984
91 Denney, D.
ASTM Eyps Plans, Seeks Input for Protective Clothing Data
FUe, Occupational Health & Safety, pp. 57-61
(July/August 1984)
92 Dickson. G.G.
Chemical Protective Clothing
~est's Safety Directory 1984
A.M. Best Co., Oldwick, NJ 08858, pp. 392-394
93 Dillon, I. G.
Permeation of Condensable Gases and Organic Liquids through
Polymeric Materials
National Aeronautics and Space Administration
Contract No. NAG-lO-OOOl
Final Report
95 Dionne, E.D.
Specialized Protective Apparel - An Item to Fit Every Need
National Safety News, p. 51 (May 1982)
96 Dionne, E.D.
A Glove Affair
National Safety News, (September 1982)
98 Disposables Inc.
Cata1ngue
1986
38
99 Dorsey Safety Products Co.
Catalog
1986
102 Dunham, T.D., W.J. Astleford, R.L. Bessey, and J.J. Kulesz
Recommended Standard for Occupational and Educational Eye
and Face Protection
Final Report NIOSH Contract HSM-99-73-l7, SwRI Project
02-3703
39
110 Encon Manufacturing Company
Catalogue
1986
40
120 Fisher Scientific Company
Catalogue
1981
122 Forsberg, K.
D~velopment of Safety Gloves. Gloves For Printers
ERGOLAB Report S 81:10
Stockholm/Goteborg, Sweden
(November 1981)
41
130 Gallagher, R.
Beat Corrosion With Rubber Hose
Chern. Engr., p. 105 (September 8, 1980)
42
140 Green, J., N.B. Levine, and R.C. Keller
Elastomers for·Liquld Rocket Fuel and Oxidizer AppHcat.
I&EC Product Research and Development, 2, p. 126 (1963)
147 Henriksen, H. R.
Selection of Materials for Protective Gloves. Polymer
Membranes to Protect Against Contact With Epoxy Products
Danish Directorate of Labor Inspection Services, Cophenbagen
(1982)
43
150 Henry, N.W., and J.F. Matheson
Dupont Monograph: Gloves-Their Selection and Testing
Haskell Laboratory for Toxicology and Industrial Medicine
Dupont Company, Wilmington, DE
(August 12, 1980)
44
161 Industrial Products Company, Inc.
Catalogue
1984
45
172 Kappler Disposables, Inc.
Catalogue
1984
177 Kodak
Functional Group Index of
KODAK Laboratory Chemicals
Kodak Publication No. JJ-1F (January 1981)
46
183 Leonard Safety Equipment, Inc.
Catalogue
1986
186 Llnnarson, A.
Penetration of Solvents Through Plastic Material
Lagersrapport, Forsvarets Forskningsansta1t, Stockholm
pp. 17 (1977)
192 Lynch, P.
Matching Protective Clothing to Job Hazards
Occupational Health and Safety, p. 30 (January 1980)
47
193 MacDonald, R.W., and R.Y.M. Huang
Permeation of Gases Through Modified Polymer Films V.
Permeation and Diffusion of Helium, Nitrogen, Methane
Ethane, and Propane through gamma-Ray Crosslinked
Polyethylene
J. Appl. Poly. Sci., 26, pp. 2239-2263 (1981)
199 Masterman's
Catalogue
1986
48
203 McNaughton, K.J.
The ABCs of Occupational Skin Disease - Part II
Chern. Engr., p. 149 (April 19, 1982)
205 Meares, P.
Transient Permeation of Organic Vapors through
Polymer Membranes
J. of Applied Polymer Science, 9, p. 917 (1-965)
208 Middleton, H. W.
Glove Corrosive Liquid Immersion and Permeability Study
Report on U. S. Energy Research and Development
Administration contract EY-76-C-04-0656 (August 1977)
49
213 Mine Safety Appliances Company
Data Sheets
13-00-07, 13-00-17, and 13-00-18
1986
50
223 Nelson, G.O., G.J. Carlson, and A.L. Buerer
Glove Permeation by Shale Oil and Coal Tar Extract
Lawrence Livermore Laboratory, UCRL 52893 (1980)
228 O'Brien, J.
Proper Sole Selection Key to Safety Footwear Comfort,
Protection, Occupational Health & Safety, pp. 52-53
(February 1986)
51
234 Pendergast Safety Equipment Company
Catalogue
1984
52
245 Rainfair, Inc.
Catalogue
1986
246 Ranger
Catalogue
1985
53
256 SGL Homalite Division of SGL Industries, Inc.
Catalogue
0776-5H
262 Salame, S.
The Prediction of Liquid Permeation in
Polyethylene and Related Polymers
SPE Transactions (October 1961)
54
267 Sansone, E.B., and Y.B. Tewari
The Permeability of Laboratory Gloves to
Selected Nitrosamines
Environmental Aspects of N-Nitroso Compounds (E. A. Walker
M. Castegnaro, L. Griciute and R.E. Lyle, eds.),
Lyon International Agency for Research on Cancer
pp. 517-529 (1978)
271 Sawyer-Tower
Catalogue
1986
274 Schoch, D.H., L.K. Tersegno, J.E. Winter, D.G. Bush, and
R.L. James
Testing of "Impervious" Gloves for Permeation by Organic
Solvents, American Industrial Hygiene Conference,
Cincinnati, OH (June 6-11, 1982)
55
276 Schwope, A.D .• M.A. Randel, and M.G. Broome
Dimethyl Sulfoxide Permeation through Glove Materials
Am. Ind. Hyg. Assoc. J., 42(10), pp. 722-725 (1981)
282 Snyder, F.J., C.F. Macy, L.A. Spane, and V.D. Iacono
Protection Capability of U.S. Army's POTMC Against Hazards
Posed by 900 Hazardous Chemicals
U.S. Army Natick R&D Command, 1976
283 Snyder, L.
Solutions to Solution Problems--1
Chemtech
(December 1979)
284 Snyder, L.
Solutions to Solution Problems--2
Chemtech
(March 1980)
S6
286 Spain, W.H., and J.L. Burson
Selective Protective Clothing with Six C's
Occupational Health and Safety, pp. 17-23 (September 198.
287 Spence, M. W.
Chemical Permeation through Protective Clothing Material:
An Evaluation of Several Critical Variables
Paper Presented at the American Industrial Hygiene
Conference, Portland, OR (May 1981)
290 Stampfer, J.F., M.J. McLeod. A.M. Martinez. M.R. Betts, and
S.P. Berardinelli
Permeation of Polychlorinated Biphenyls and Solutions of
These Substances Through Selected Protective Clothing
Materials
Am. Ind. Hyg. Assoc. J .• 45(9), pp. 634-641 (1984)
291 Stampfer. J~F., M.J. McLeod, M.R. Betts. A.M. Martinez, and
S.P. Berardinelli
The Permeation of Eleven Protective Garment Materials by
Four Organic Solvents
Am. Ind. Hyg. Assoc. J .• 45, pp. 642-654 (1984)
292 Stampfer, J.F., M.J. McLeod, M.R. Betts. A.M. Martinez, and
S.P. Berardinelli
Chemical Permeation - A Summary Report of Recent NIOSH-
Directed Studies at the Los Alamos National Laboratory
Am. Ind. Hyg. Assoc. J., 45, pp. B-lO to B-12
(January 1984)
57
295 Standard Safety Equipment Company
Catalogue
1986
302 Stull, J.O., V.L. Man, V.A. Bastecki, and A.P. Bentz
A Comprehensive Materials Evaluation Program to Support the
Development and Selection of Chemical Protective Clothing
1986 Hazardous Material Spills Conference Proceedings,
St. Louis, Missouri (May 5-8, 1986)
58
305 Sweeting, O.J. (editor)
The Science and Technology of Polymer Films
Volume II, Wiley-Interscience, New York (1970)
307 3M Company
Catalogue
1'986
59
316 Varos, J.
Consider Abrasion Risk, Chemicals When Choosing Gloves
Occupational Health & Safety, pp. 60,62 (March 1986)
320 Waack, R., N.H. Alex, H.L. Frisch, V. Stannett, and M.Szwarc
Permeability of Polymer Films to Gases and Vapors
Ind. and Engr. Chern., 47(12), pp. 2524-2527 (1955)
323 Walters, D.
Personal Communication. National Toxicology Program
Glove Performance Study Performed by Radian
Corporation, Austin, Texas (June 1986)
60
326 Weeks, R.W., Jr., and M.J. McLeod
Permeation of Protective Garment Material by Liquid
Halogenated Ethanes and a Polychlorinated Biphenyl
u.s. Dept. of Health & Human Services, NIOSH Publication
No. 81-110 (January 1981)
61
336 Willson Safety Products
Catalogue
1985
339 Worklon
Catalogue
1981
62
APPENDICES
63
DESCRIPTION OF COLUMN HEADINGS
FOR APPENDICES A THROUGH E
64
APPENDIX A
PERMEATION DATA
A-l
SUMMARY OF PERFORMANCE DETAIL TESTS
PERllEATlON TEST
CHEMICAL IIAME/ RESIST AliT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATlOli RATE TEMP THICKNESS REF
CASIIO MATERIAL DESC CODE HOURS UG/CM**21M III OEG C CM NtII
Acetaldehyde
000750700 BUTYL 014 118 9.58 .40 23. .04 323
9.60 .40 23. 227
CPE 060 113 .17 . •50 25 • .07 302
UIOC • 66 23 • 142
•28 23 • 142
IlATlIW. RUBBER 001 103 48.10 23. 045
017 100 • 12 90.18 901.80 23 • .05 107
1lE000ENE 002 100 •28 901.80 · 9,018.00 23 • 107
018 100 .20 199.00 23. .05 323
125
.17 901.80 · 9,018.00 23. .04 107
103 n.14 23. 045
NITRILE 019 103 529.06 23. 045
118 < .01 967.93 23. .03 323
.07 967.93 23. .04 227
NITRILE+PVC 058 100 •05 901.80 9,018.00 23 • 107
PE 076 100 .05 901.80 9,018.00 23. 107
PV ALCOHOL 102 100 .27 282.56 23. .03 323
PVC 007 103 264.53 23. 045
077 100 .05 9.02 · 90.18 23. 107
SILVER SHIELD
.08 901.80 · 9,018.00 23. 107
122 118 > 6.00 23. .01 227
TEFLON 069 510 > 3.00 < •02 23 • .05 303
VITON 009 118 < •01 1,694.78 23 • .03 323
VITON/CHLOROBUTYL 112 113 .50 . • 66 25 • .04 302
UNK > 3.00 23. 142
Acetic Acid
000641970 CPE 060 113 > 3.00 25. .07 302
3.95 23. .05 204
2.40 42.08 23. .05 204
NATURAL RUBBER 001 UNK • 68 23 • 052
015 UNK • 85 23 • .04 052
017 100 2.25 23. .05 107
102 4.50 23. .05 026
2.50 23. .05 026
1.50 23. .05 026
2.00 23. .05 026
IIEOP+NAT RUBBER 026 102 1.50 23. .06 026
1.50 23. .04 026
3.50 23. .05 026
121 1.27 96.19 23. .05 237
NEOP/IIAT RUBBER 008 102 3.50 23. 026
UNK > 1.00 23. 052
NEOPRENE 002 100 > 6.00 23. 107
210 6.00 23. 080
018 100 7.00 23. .04 107
UNK > 1.00 23. .06 052
> 1.00 23. .09 052
NITRILE 005 210 6.00 < •02 23 • 080
019 100 4.50 23. .06 107
UIIK > 1.00 23. .05 052
A-2
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NANEI RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS UG/CH**21MIN DEG C CM NUH
.~
000641970 NITRILE+PVC 057 210 6.00 < •02 23 • 080
058 100 .27 23. 107
PE 076 100 .zs 23. 107
127 5.00 23. 104
PVC 003 UNIC .08 23. .02 052
007 100 3.00 23. 107
210 4.00 12.02 23. 080
UNIC > 1.00 23. 052
077 100 .75 23. 107
.10 23. 107
SARANEX 061 127 > 66.67 23. 104
TEFLON 069 510 > 4.00 < •02 zs . .05 303
VITON 009 UNIC > 1.00 23. .03 052
VITON/CHLOROBUTYL 112 113 > 3.00 zs. .04 302
Acetic Anhydride
001082470 BUTYL 014 118 > 8.00 < •02 23 • .09 323
CPE 060 113 1.ZS 23. .05 204
1.ZO 54.11 23. .05 204
NATURAL RUBBER 001 ZSO .05 10.02 20. .02 323
NEOPRENE 018 100 3.50 6.01 20. .05 323
PVC 007 100 .07 1ZO.24 20. .02 323
TEFLON 069 510 > 3.00 < •02 23 • .05 303
Acetone
000676410 BUTYL 014 118 > 20.33 23. .08 323
> 17.00 23. .04 227
216 > 4.00 21. .07 124
CPE 060 113 .33 · .42 25. .07 302
.53 · .58 22. .07 302
.45 · .52 ZS. .07 302
.28 23 • .05 204
•ZS 1,022.04 23. .05 204
NATURAL RUBBER 001 103 288.58 23. 045
210 .10 60.12 23 • 080
UNK •23 35.07 23. .12 274
017 100 .09 110.22 25. .03 222
.17 90.18 . 901.80 23. .05 107
102 .13 4.81 23 • .05 026
• 17 9.02 23. .05 026
.13 5.41 23 • .05 026
• 15 7.21 23 • .05 026
120 •04 210.42 25. .02 222
502 .10 82.16 25. .05 222
504 .ZS 66.13 25 • .05 222
•45 45.09 25 • .06 222
UNIC •10 > 140.28 23. .04 274
NEOP+NAT RUBBER 026 102 .08 100.20 25. .05 222
A-3
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST
CHEMICAl lIANE/ RESISTAIIT PRmtJCT VE8IDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKIIESS REf
CASIIO MATERIAL DESC CODE HOURS UG/CM**2/MIII OEG C CM IIUM
Acetonitrile
000750580 BUTYL 014 118 > 8.00 23. .07 323
> 8.00 23. .04 227
064 117 > 8.00 23. .02 213
A-4
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM
Acetophenone
000988620 TEFLON 069 510 > 92.00 < .02 25. .05 303
Acetyl Chloride
000753650 SARANEX 061 127 .62 1.10 23. 104
TEFLON 069 510 > 3.10 < .02 23. .05 303
Acrolein
001070280 BUTYL 014 118 > 15.00 23. .06 323
CPE 060 UNIC .13 23. 142
.92 23. 142
NITRILE 019 100 .07 966.13 23. .04 323
PV ALCOHOL 102 100 .25 3.01 23. .03 323
VITON 009 118 < •01 432.86 23 • .02 323
VITON/CHLOROBUTYL 112 UNIC > 3.00 23. 142
Acryl ic Acid
000791070 TEFLON 069 510 > 3.00 < .02 23. .05 303
Acryloni tri le
001071310 CPE 070 UNIC .28 23. .05 004
PE 076 127 .08 < .02 23. 104
SARANEX 061 127 .38 < .02 23. 104
TEFLON 069 510 .90 .08 23. 303
Allyl Alcohol
001071860 BUTYL 014 UNIC > 8.17 25. 287
064 117 > 8.00 23. .02 213
> 8.00 23. .01 213
> 8.00 23. .02 213
A-S
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICICNESS REF
CASNO MATEalAL OESC CODE HOURS UG/CM**2/MIN DEG C eM NUM
Allylamine
001071190 BUTYL 014 118 3.92 70.14 20. .06 323
NATURAL RUBBER 001 250 < .02 6,633.24 20. .01 323
PV ALCOHOL 102 100 .20 12,114.18 23. .07 323
PVC 007 100 < .02 9,829.62 20. .02 323
All yl Ch loride
001070510 CPE 070 UNK 1.25 23. .05 004
TEFLON 069 510 1.70 < .02 23. .05 303
2.76 < .02 23. .05 303
Anmonillll Hydroxide
013362160 NATURAL RUBBER 001 210 2.00 23. 080
NEOP+NAT RUBBER 026 121 .45 18.04 23. .05 237
NEOPRENE 002 210 6.00 < .02 23. 080
NITRILE 005 210 6.00 < .02 23. 080
NITRIlE+PVC 057 210 3.00 23. 080
058 100 .18 23. 107
PE 076 100 .07 23. 107
PVC 007 210 .75 23. 080
077 100 > 6.00 23. 107
.30 "23. 107
A-6
SUMMARY OF PERFORMAIICE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PROOUCT VEIIDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS Ref
CASIIO MATERIAL DESC CODE HOURS UG/CM**21MIN DEG C eM NUM
A-7
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PIQ)UCT VEIIDOI BREAlCTHRClJGH TINE PERMEATION RATE TEMP THICICNESS REF
CASIIO MATERIAL DESC CODE MOORS UG/CM**2/NIN DEG C eM ...
NITIILE
139
005
',7
210
2.75 23. .02 213
2.50 30.06 23. 080
019 100 1.60 120.24 25. .04 222
118 1.05 270.54 23. .04 323
1.10 270.54 23. .04 227
50] .30 180.36 25. .03 222
UIIIC > 1.00 23. .05 274
> 1.00 23. .05 274
1.50 3.01 25. .04 213
1.50 3.01 25. .04 213
2.50 3.01 25. .06 213
5.42 3.01 25. .06 273
NITIILE+PVC 057 210 6.00 < .02 23. 080
058 100 • 17 .90 • 9.02 23 • 107
PE 006 100 > 1.00 < 40.08 25. .01 222
505 .05 25. .01 222
076 100 •07 .90 • 9.02 23 • 107
111 6.58 23. .01 213
PV ALCOHOL 004 100 1.50 .90 • 9.02 23. 107
!JIlt > 1.00 23. .12 274
102 100 > 16.00 23. .03 323
PVC 003 120 .05 180.36 25. .01 222
•30 160.32 25 • .03 222
• 15 160.32 25 • .02 222
007 100 3.00 .90 • 9.02 23. 107
210 4.00 8.42 23. 080
UNIC > 1.00 23. .16 274
A-a
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAlCTHROUGH TIME PERMEATION RATE TEMP THICKNESS REf
CAStlO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM tlUM
Benzaldehyde
001005270 BUTYL 014 118 9.00 23. .07 323
NATURAL RUBBER 017 100 .23 9.02 • 90.18 23. .05 107
NEOPRENE 018 100 .65 24.05 23. .05 323
NITRILE 019 100 .40 25.85 21. .03 323
PE 076 100 .17 9.02 90.18 23. 107
PV ALCOHOl 004 100 > 6.00 < .90 23. 107
102 100 > 16.00 2:>. .03 323
VITOII 009 118 9.93 24.05 ~3. .03 323
Benzene
000714320 BUTYL 014 118 • 52 114. t9 :'} • )J!, 323
.S2 194.19 ~3. .()4 227
UIIK .33 2:!. .;}, 327
034 IIIIC 1.47 130.26 22. .08 078
064 117 .08 23. .02 213
> .08 23. .01 213
.67 21. .02 213
507 1.00 90.18 22. .06 078
UIIK .13 23. .04 327
BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213
CPE 070 UNIC .43 21. .05 004
EVA 074 UIIIC .01 21. .02 327
NATURAL RUBBER 001 210 .18 396.79 21. 080
017 100 .04 3,206.40 25. .03 222
120 .03 5,611.20 25. .02 222
502 .05 2,605.20 25. .05 222
504 •06 2,204.40 25 • .05 222
.12 1,603.20 25. .06 222
508 .03 501.00 22. .03 078
UIIK .01 23. .05 327
.02 21. .02 327
NEOP+NAT RUBBER 026 102 .05 2,805.60 25. .04 222
121 .05 2,254.50 21. .05 237
NEOP/NAT RUBBER OOB 114 .09 2,004.00 25. .05 222
.05 400.80 22. .05 078
NEOPRENE 002 100 .25 80.16 22. .07 078
.02 951.90 25. .'18 222
120 .40 300.60 25. .07 222
210 .25 559.12 23. 080
UtlK .29 517.03 22. .11 333
A-9
SUMMARY OF PERFORHAIICE DETAil TESTS
PERMEATION TEST
CHEMICAL tlAMEl RESISTAIIT PRODUCT VEtIIOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERiAl DESC COOE IKlJRS UG/CM**2/M IN DEG C CM MUM
A-IO
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN OEG C CM NUN
Benzenesulfonic Acid
000986790 NEOPRENE 018 100 > 20.00 23. .05 123
NITRILE 020 216 > 4.00 23. .04 123
Benzethonium Chloride
001215400 BUTYL 014 118 > 8.00 < .02 22. .06 323
NATURAL RUBBER 001 250 > 8.00 < .02 21. .02 323
NEOPRENE 018 100 > 8.00 < .02 19. .05 323
PVC 007 100 > 8.00 < .02 19. .02 323
Benzoni trite
001004700 BUTYL 014 118 > 8.00 23. .06 323
NATURAL RUBBER 001 506 < .01 24.05 23 •. .01 323
PV ALCOHOL 102 100 > 8.00 23. .03 323
V IT ON 009 118 .93 24.05 23. .03 323
Benzoyl Chloride
000988840 BUTYL 014 118 6.28 99.80 23. .06 323
HYPALON 108 210 .33 23 . .06 123
NEOPRENE 018 100 •25 23. .05 123
PV ALCOHOL 102 100 > 8.00 23. .05 323
PVC 003 100 < .01 596.39 23. .02 323
VITON 009 118 > 8.00 23. .02 323
.75 23. .03 123
A-ll
SlJIMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE IIOORS UG/CIf"*2/MIN DEG C eM NlJ4
Benzyl Alcohol
001005160 BUTYL 014 216 > 4.00 23. .01 123
VITON 009 118 > 20.00 23. .03 123
Bis(2-Ethylhexyl) Phthalate
001178170 BUTYl 014 118 > 8.00 23. .09 323
NATURAL IMlBER 011 100 > 6.00 < .90 23. .05 101
NEOPRENE OOZ 100 2.00 < .90 23. 101
018 100 > 6.00 < .90 23. .04 101·
NITRILE 019 100 > 6.00 < .90 23. .06 101
4.33 12.02 23. .05 323
PV ALCOHOl. 004 100 .SO 90.18- 901.80 23. 101
PVC 003 100 .03 12.02 23. .02 323
VI TON 009 118 > 8.00 23. .05 323
Boric Acid
100433530 BUTYl 014 118 > 8.00 < .02 20. .01 323
NEOPRENE 018 100 > 8.00 < .02 19. .05 323
NITRILE 019 100 > 8.00 < .02 21. .04 323
VITON 009 118 > 8.00 < .02 20. .03 323
BrOllline
Om6956O PE 016 121 < .02 23. 104
Bromoacetonitrile
005901100 BUTYl 014 118 > 8.00 23. .06 323
NATURAL RUBBER 001 506 < .01 51.11 23. .01 323
PV ALCOIIOl 102 100 > 8_00 23. .03 323
VITON 009 118 > 8.00 23. .02 323
Bromobenzene
001088610 BUTYL 014 118 .53 239.28 23. .06 323
NITRILE 019 118 .22 54.11 23. .04 323
PY ALCOHOl 102 100 > 8.00 23. .02 323
VITON 009 118 > 8.00 23. .03 323
2-BrOntOethanol
005405120 BUTYL 014 118 > 8.00 23. .09 323
NATURAL RUBBER 001 250 .02 66.13 23. .02 323
PVC 003 100 .03 456.91 23. .02 323
VITON 009 118 > 8.00 23. .05 323
l-Bromo-2-propanol
196861380 BUTYL 014 118 > 8.00 23. .06 323
NATURAL RUBBER 001 S06 .02 45.69 23. _01 323
PV ALCOHOL 102 100 > 8.00 23. .02 323
VITON 009 118 > 8.00 23. .02 323
A-12
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST
CHEMICAL NAME I RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL OESC COOE HOURS UG/CM**2!MIN OEG C CM NUM
3-Bromo-1-propanol
006271890 BUTYL 014 118 > 8.00 23. .06 323
NEOPRENE 018 100 > 8.00 23. .05 323
PV ALCOHOL 102 100 > 8.00 23. .03 323
VITON 009 118 > 8.00 23. .02 323
Butadiene
001069900 BUTYL 014 118 > 8.00 23. .07 323
NATURAL RUBBER 001 250 < .02 637.27 23. .02 323
NEOPRENE 018 100 .78 1.80 23. .05 323
PVC 003 100 < .02 126.25 23. .02 323
VITON 009 118 > 8.00 23. .05 323
Butyl Acetate
001238640 BUTYL 014 118 1.90 45.76 23. .04 227
1.53 36.07 23. .05 086
NATURAL RUBBER 001 210 .13 216.43 23. 080
017 100 .07 1,402.80 25. .03 222
102 .07 72.14 23. .05 026
.07 72.14 23. .05 026
.07 72.14 23. .05 026
.07 72.14 23. .05 026
120 .03 2,905.80 25. .02 222
502 .11 941.88 25. .05 222
504 .13 881.76 25. .05 222
.23 511.02 25. .06 222
NEOP+NAT RUBBER 026 102 .11 641.28 25. .05 222
.07 72.14 23. .06 026
.07 72.14 23. .04 026
.07 72.14 23. .05 026
NEOP/NAT RUBBER 008 102 .07 72.14 23. 026
114 .15 641.28 25. .05 222
IIEOPRENE 002 100 .09 220.44 25. .08 222
120 .06 320.64 25. .07 222
210 .25 72.14 23. 080
018 100 .32 210.42 23. .06 086
118 > 1.00 < 21.04 25. .08 222
120 .48 320.64 25. .05 222
.87 320.64 25. .07 222
> 1.00 < 21.04 25. .05 222
.18 831.66 25. .03 222
NITRILE 005 210 1.33 90.18 23. 080
019 100 .55 480.96 25. .04 222
1.25 90.18 - 901.80 23 • .06 107
. 97 250.50 25. .06 222
.67 450.90 25. .04 222
A-13
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM N\JM
Butyl Acrylate
001413220 TEFLON 069 510 > 3.00 < .02 23. .05 303
Butylamine
001097390 BUTYL 014 118 1.73 501.00 15. .10 323
CPE 060 UNK •50 23 . 142
1.00 23. 142
A-14
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP TH ICKNESS REF
CASNO MATERIAL OESC COOE HOURS UG/CM**2/MIN OEG C CM NUM
sec-Buty.lamine
139528460 BUTYL 014 118 2.68 180.36 21. .09 323
NEOPRENE 018 100 .27 1,402.80 25. .05 323
NITRILE 019 100 .33 1,482_96 14. .04 323
PVC 007 100 .01 4,529.04 24. .02 323
tert-Butylamine
000756490 BUTYL 014 118 > 8.00 < •02 15 . .09 323
NEOPRENE 018 100 1.17 360.72 23. .05 323
NITRILE 019 100 1.40 240.48 21. .04 323
PVC 007 100 .03 3,036.06 20. .02 323
n-Butyl Phthalate
000847420 BUTYL 014 118 > 16.00 23. .04 323
> 16.00 23. .04 227
NATURAL RUBBER 017 100 .28 23. .05 107
NEOPRENE 002 100 5.00 .90 9.02 23. 107
018 100 2.00 < .90 23. .04 107
125 103 < .02 23. 045
~'lTRllE 019 100 > 6.00 < .90 23. .06 107
103 < .02 23. 045
118 > 16.00 23. .03 323
> 16_00 23. .04 227
A-15
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HOURS UG/CM**2/MIN DEG C eM NUM
p-tert-Butyl Toluene
271302120 BUTYL 014 118 1.78 48.10 23. .06 323
1.70 48.10 23. .04 227
NEOPRENE 018 100 1.22 421.44 23. .05 323
NITRILE 019 100 > 6.00 23. .04 323
PV ALCOHOL 102 100 > 7.00 23. .03 323
SILVER SHIELD 122 118 > 8.00 23. .01 227
VITON 009 118 > 8.00 23. .02 323
> 8.00 23. .02 227
Butyraldehyde
00123n80 BUTYL 014 118 > 15.00 23. .07 323
NEOPRENE 018 100 • 73 15.75 23 • .05 323
PV ALCOHOl 102 100 •27 .78 23 • .03 323
TEFLON 069 510 > 7.50 < .02 23. .05 303
VITON 009 118 .90 54.11 23. .03 323
A-16
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME I RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO . MATERIAL DESC CODE HOURS UG/ot**2/MIN DEG C CM NUM
000562350 NATURAL RUBBER 017 100 .06 1,603.20 25. .03 222
120 .03 6,012.00 25. .02 222
502 .08 5,110.20 25. .05 222
504 . 50 S01.6O 25 . .05 222
.18 1,603.20 25. .06 222
NEOP+NAT RUBBER 026 102 .07 4,609.20 25. .05 222
NEOP/NAT RUBBER DOS 114 .17 3,106.20 25. .05 222
NEOPRENE 002 100 • 50 100.20 25 . .08 222
120 •08 501.00 25 . .07 222
UNIC •24 300.60 22 • .11 333
• 17 619.24 22 • .08 333
018 118 > 1.00 < 6.01 25. .08 222
120 .57 S01.6O 25. .05 222
• 68 901.SO 25 • .07 222
•38 901.SO 25 • .05 222
.22 801.60 25. .03 222
UNIC .14 2,244.48 22. .05 333
.32 1,756.51 22. .05 333
.24 1,997.99 22. .04 333
NITRILE 019 100 > 1.00 < 6.01 25. .04 222
2.50 9.02 90.18 23. .06 107
> 1.00 < '1,669.98 25. .06 222
> 1.00 < 6.01 25. .04 222
118 3.40 30.06 23. .04 227
181 > 1.00 < 6.01 25. .03 222
503 > 1.00 < 6.01 25. .03 222
UNIC > 3.33 22. .04 333
> 3.33 22. .04 333
NITRILE+PVC 058 100 .05 9.02 . 90.18 23. 107
PE 006 100 .03 501.00 25. .01 222
505 .13 SO.16 25. .01 222
076 100 .08 9.02 90.18 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
UNIC > 3.33 3.01 22. .09 333
102 100 > 8.00 23. .04 323
PVC 003 120 .01 1,002.00 25. .01 222
.03 2,004.00 25. .01 222
.14 601.20 25. .03 222
.04 S01.6O 25. .02 222
500 .02 2,104.20 25. .01 222
501 .02 2,505.00 25. .01 222
.02 2,004.00 25. .02 222
007 100 .42 90.18· 901.80 23. 107
UNIC .22 496.99 22. .11 333
.66 203.41 22. .11 333
.51 250.50 22. .10 333
on 100 .12 9.02 90.18 23. 107
.25 9.02 90.18 23. 107
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEFLON 069 510 > 3.00 < .02 23. .05 303
VITON 009 118 > 13.00 23. .02 227
Chlorine
A-17
SUMMARY OF PERfORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HClJRS UG/CM**2/MIJI DEG C CM lUI
Chloroacetic Acid
000791180 PE 076 127 > 8.00 23. 104
.08 65. 104
SARANEX 061 127 1.00 65. 104
Chloroacetonitrlle
001071420 BUTYL 014 118 > 8.00 23. .06 323
NATURAL RUBBER 001 506 « • 01 75.75 23 . .01 323
PV ALCOHOL 102 100 > 8.00 23. .03 323
VITON 009 118 > 8.00 23. .03 323
Chlorobenzene
001089070 BUTYL 014 118 .58 3,086.16 23. .07 323
NEOPRENE 002 utile • 18 23. .05 186
NITRILE 005 229 •21 940.21 23 • .11 210
019 120 • 25 960.25 23 • .04 210
PE 076 100 • 07 90.18 901.80 23 • 107
PV ALCOHOL 004 100 .25 9.02· 90.18 23. 107
102 100 > 8.00 c .02 23. .08 323
PVC 007 100 •03 3,757.50 23 • .02 323
utile .15 23. .05 186
.31 23. .07 186
TEfLON 069 510 > 3.00 c .02 23. .05 303
VITON 009 118 > 4.00 23. .03 210
8.00 c .02 23. .03 323
2·Chloro·1,3·butadiene (Chloroprene)
001269980 NEOPRENE 002 utile • 05 1,764.52 22 • .08 333
•05 783.56 22 • .11 333
018 lillie .07 22. .04 333
.11 22. .05 333
• 10 3,164.32 22 • .05 333
NITRILE 019 UNIC .06 2,329.65 22. .04 333
.12 2,on.15 22. .04 333
PV ALCOHOL 004 UNIe 16.67 22. .09 333
PVC 007 UNIe .08 669.34 22. .11 333
.09 851.70 22. .10 333
.07 954.91 22. .11 333
A-I8
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NlJII
Chlorodibromomethane
001244810 BUTYL 012 118 3.27 149.75 23. .10 323
PV ALCOHOL 004 100 .60 .02 23. .07 323
PVC 003 100 •03 1,106.21 23 • .02 323
VITON 009 118 > 8.00 23. .04 323
Chloroform (Trichloromethane)
000676630 CPE 060 113 . 50 - .58 25 • .07 302
070 UNK .20 23. .05 004
NATURAL RUBBER 017 100 •03 4,OOS.00 25 • .03 222
120 •01 15,030.00 25 • .02 222
502 .04 7,615.20 25. .05 222
504 .05 5,611.20 25. .05 222
•05 7,014.00 25 • .06 222
NEOP+NAT RUBBER 026 102 •05 7,014.00 25 • .05 222
NEOP/NAT RUBBER OOS 114 • 11 4,4OS.80 25 • .05 222
NEOPRENE 002 100 •02 2,705.40 25 • .OS 222
120 .01 6,813.60 25. .07 222
018 118 .36 2,004.00 25. .OS 222
120 .16 3,206.40 25. .05 222
.23 2,805.60 25_ .07 222
.17 2,505.00 25. .05 222
.06 4,4OS.80 25. .03 222
031 UNK .20 23. .04 187
NITRILE 019 100 •OS 9,418.80 25 • .04 222
.21 5,611.20 25. .06 222
.04 9,919.80 25. .04 222
118 .07 2,116.22 23. .04 227
503 •07 7,014.0025 • .03 222
033 UtlK .16 23. .05 187
PE 006 100 .01 1,603.20 25. .01 222
505 .05 25. .01 222
056 UtlK .07 23. .01 187
076 100 .10 9.02 90.18 23. 107
127 < .02 348.70 23. 104
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
102 100 > 8.00 23. .03 323
PVC 003 120 .01 15,030.00 25. .01 222
.01 > 16,699.98 25. .01 222
.01 5,410.80 25. .-03 222
.01 11,022.00 25. .02 222
500 .01 15,030.00 25. .01 222
501 .01 12,024.00 25. .01 222
•01 13,026.00 25 • .02 222
049 UtlK • 14 23 • .03 187
SARANEX 061 127 < •02 201.40 23 • 104
SILVER SHIELO 122 118 .17 .05 23. _01 227
TEFLON 069 510 > 3.60 < .02 23. .05 303
VITON 009 118 9.50 2.n 23. .02 227
VITON/CHLOROBUTYL 112 113 > 3.00 25. .04 302
3-Chloro-2-methylpropene
A-19
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2!MIN DEG C CM NlII
2-Chloro-2-nitropropane
005947180 BUTYL 012 118 > 8.00 < • 02 23 • .09 323
NATURAL RUBBER 017 506 .02 270.54 23. .02 323
PV ALCOHOL 004 100 > 8.00 < .02 23. .07 323
VITON 009 118 2.05 120.24 23. .04 323
1-Chloro-2-propanol
001270040 BUTYL 014 118 > 8.00 23. .06 323
NATURAL RUBBER 001 506 < .01 23. .01 323
PVC 003 100 .02 230.86 23. .02 323
VITON 009 118 > 8.00 23. .03 323
3-Chloro-1·propanol
006273050 BUTYL 014 118 > 8.00 23. .06 323
PV ALCOHOL 102 100 .80 92.58 23. .04 323
PVC 003 100 .18 409.42 23. .02 323
VITON 009 118 > 8.00 23. .03 323
Chlorosulfonic Acid
077909450 PE 076 127 1.OS 23. 104
SARAIIEX 061 127 5.83 23. 104
o-Chlorotoluene
000954980 NITRILE 005 229 .29 1,163.99 23. .11 210
019 120 .88 988.64 23. .04 210
VITON 009 118 > 4.00 23. .03 210
p-Chlorotoluene
001064340 NITRILE 005 229 .25 1,224.11 23. .11 210
019 120 .42 890.11 23. .04 210
VITON 009 118 > 4.00 23. .03 210
Chromic Acid
111157450 NATURAL RUBBER 001 210 1.17 23. OSO
NEOPRENE 002 210 1.25 23. 080
NITRILE 005 210 6.00 < .02 23. 080
NITRILE+PVC 057 210 6.00 < .02 23. 080
058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC 007 210 6.00 < .02 23. OSO
077 100 > 6.00 23. 107
> 6.00 23. 107
A-20
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**21MIN DEG C CH NUM
Creosote
080015890 BUTYL 034 UNIC > 90.00 22. .08 078
NEOPRENE 031 UNIC 4.50 Z2. .08 078
VITOII 032 UNIC > 96.00 22. .04 078
Creosote, Wood
080213940 NEOPRENE 018 100 > 4.00 23. .05 123
VITOII 009 118 > 19.00 23. .03 123
..·Cresol
001083940 NATURAL RUBBER 017 100 .60 25. .03 222
120 .23 15.03 25. .02 222
502 .50 2.00 25. .05 222
504 > 1.00 1.00 25. .05 222
> 1.00 1.00 25. .06 222
NEOP+IlAT RUBBER 026 102 .50 2.00 25. .05 222
NEOP/NAT RUBBER 008 114 > 1.00 1.00 25. .05 222
NEOPRENE 002 100 > 1.00 1.00 25. .08 222
018 118 > 1.00 1.00 25. .08 222
120 > 1.00 1.00 25. .05 222
> 1.00 1.00 25. .07 222
> 1.00 1.00 25. .05 222
> 1.00 1.00 25. .03 222
NITRilE 019 100 > 1.00 1.00 25. .04 222
> 1.00 1.00 25. .06 222
> 1.00 1.00 25. .04 222
503 > 1.00 1.00 25. .03 222
PE 006 100 > 1.00 1.00 25. .01 222
505 > 1.00 < .10 25. .01 222
PVC 003 120 .20 67.13 25. .01 222
.23 59.12 25. .01 222
> 1.00 1.00 25. .03 222
.23 63.13 25. .02 222
A-21
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG!CM**2/MIN DEG C CM
Cresols
013197730 PE 076 127 .67 1.00 .40 23. 104
SARANEX 061 127 > 2.00 < .13 23. 104
Cyclohexane
001108270 BUTYL 014 118 1.15 122.04 23. .07 323
1.10 122.04 23. .04 227
NATURAL RUBBER 001 210 .10 2,044.08 23. 080
017 100 10.02 25. .03 222
120 .03 1,503.00 25. .02 222
502 •13 1,302.60 25 • .05 222
504 .16 1,102.20 25. .05 222
.30 801.60 25. .06 222
NEOP+NAT RUBBER 026 102 .08 1,402.80 25. .05 222
NEOPRENE 002 120 • 16 70.14 25 • .07 222
210 .10 1,082.16 23. 080
018 100 .95 .18 23. .04 323
120 > 1.00 < 10.02 25. .05 222
.48 100.20 25. .05 222
1.20 100.20 25. .03 222
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 6.00 23. .04 323
> 1.00 < 10.02 25. .04 222
> 1.00 < 1.00 25. .06 222
> 1.00 < 1.00 25. .04 222
181 > 1.00 < 1.00· 25. .03 222
503 > 1.00 < 10.02 25. .03 222
NITRILE+PVC 057 210 3.00 12.02 23. 080
PE 006 100 .03 100.20 25. .01 222
505 .17 28.06 25. .01 222
PV ALCOHOL 102 100 .78 < .02 23. .03 323
PVC 003 120 .03 501.00 25. .01 222
•04 340.68 25 • .01 222
.27 100.20 25. .03 222
.09 200.40 25. .02 222
500 •03 310.62 25 • .01 222
501 •01 450.90 25 • .01 222
A-22
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/tM**2/MIN DEG C eM NUN
Cyclohexanol
001089300 BUTYL 014 118 > 11.00 23. .01 323
> 11.00 23. .04 221
NATURAL RUBBER 001 210 .42 72.14 23. 080
017 100 .25 9.02 • 90.18 23. .05 101
NEOPRENE 002 100 3.00 < .90 23. 107
210 3.00 60.12 23. 080
018 100 2.50 .90 • 9.02 23. .04 107
UIIIC > 8.00 23. .08 323
031 511 8.00 ******** '1,669.98 23. .01 323
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 6.00 < .90 23. .06 101
118 > 16.00 23. .03 323
> 16.00 23. .04 221
NITRILE+PVC 057 210 6.00 < .02 23. 080
058 100 .25 .90 - 9.02 23. 101
PE 076 100 > 6.00 < .90 23. 107
PV ALCOHOL 004 100 6.00 < .90 23. 101
102 100 > 16.00 23. .03 323
PVC 007 100 6.00 < .90 23. 107
210 6.00 < .02 23. 080
077 100 1.00 < .90 23. 101
> 6.00 < .90 23. 107
SILVER SHIELD 122 118 > 6.00 23. .01 227
VITON 009 118 > 8.00 23. .03 323
> 8.00 23. .02 227
CycI ohexanone
001089410 BUTYL 014 118 > 16.00 23. .05 323
> 16.00 23. .04 221
IIEOP+IIAT RUBBER 026 121 .28 132.26 23. .05 237
NITRILE 019 118 •48 518.84 23 • .03 221
PV ALCOHOL 102 100 > 7.00 23. .03 323
SILVER SHIELD 122 118 > 6.00 23. .01 221
VITON 009 118 •48 518.84 23 . .03 323
A-23
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAlCTHROJGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DEst COOE IKlJRS UG/CI4**2!M I N DEG C CM NUM
Diallyamine
001240270 BUTYL 014 118 3.33 90.18 21. .09 323
PV ALCOHOL 004 100 7.08 20.04 23. .08 323
PVC 007 100 .02 2,364.72 22. .02 323
VITON 009 118 4.62 19. .03 323
1,3-Dieminopropane
001097620 BUTYL 014 118 > 8.00 < .02 22. .06 323
NATURAL RUBBER 001 250 •05 440.88 25 • .02 323
NEOPRENE 018 100 4.53 33.40 23. .OS 323
PVC 007 100 • 11 103.54 21 • .02 323
Di-n-lIIIIYlamine
020509220 NEOPRENE 018 100 2.15 110.22 16. .OS 323
NITRILE 019 100 > 8.00 < .02 20. .04 323
PVC 007 100 .12 280.56 13. .02 323
VITON 009 118 > 8.00 < .02 16. .03 323
Dibutyl ..ine
001119220 NITRILE 019 100 > 8.00 < .02 24. .04 323
PV ALCOIIOL 102 100 > 8.00 < .02 23. .08 323
PVC 007 100 . .05 741.48 20. .02 323
YJTON 009 118 > 8.00 < .02 20. .03 323
Dichloroacetyl Chloride
000793670 BUTYL 014 118 3.92 72.14 23. .09 323
PV ALCOHOL 102 100 3.47 23. .07 323
PVC 003 100 .03 438.88 23. .02 323
VJTON 009 118 > 8.00 23. .03 323
Dichlorobenzene
253212260 CPE 070 UIIIC .65 23. .05 004
1,2-Dichlorobenzene
000955010 NITRILE 005 229 •33 1,015.36 23 • .11 210
019 120 •63 1,140.61 23 • .04 210
VJTON 009 118 > 4.00 23. .03 210
1,3-Dichlorobenzene
005417310 NITRILE 005 229 .28 1,130.59 23. .11 210
019 120 .50 1,157.31 23. .04 210
VITON 009 118 > 4.00 23. .03 210
A-24
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PROOUCT VENDOR BREAICTHROUGH TIME PERMEATION RATE TEMP THICICNESS REF
CASNO MATERIAL DESC COOE HOURS UG/CM**2/MIN OEG C CM NUM
DichlorObromomethane
000752740 BUTYL 014 118 .68 1,897.80 23. .07 323
PVC 007 100 .02 6,943.86 23. .02 323
VITON 009 118 7.83 •37 23 • .03 323
VITON/BUTYL 100 102 1.78 •02 23 • .08 323
1,4-0ichloro·2-butene
001105760 BUTYL 064 UIiIK > 24.00 23_ .07 334
CPE 060 UIiIIC .58 400. SO 23. .05 334
070 UIiIIC .75 23. .05 004
NEOPREIIE 002 UIiIIC 1.10 22 • .12 333
.n 22 • .10 333
•22 22 • .08 333
• 17 22 • .07 333
•57 118.24 22. .11 333
.36 51.10 22. .08 333
.45 31.06 23 • .10 335
•68 27.05 23. .12 335
.SO 27.05 23. .14 335
018 lIIlC .49 126.25 22 • .05 333
•37 22 • .05 333
•35 22. .05 333
.26 22 • .04 ·333
•23 41.08 22. .05 333
.30 38.08 23. .04 335
031 UIiIIC 1.38 SO.16 23. .14 334
.97 80.16 23. .13 334
1.23 121.24 23. .13 334
081 UtlIC 1.97 101.20 23. .15 335
3.35 40.08 23. .18 335
2.97 41.08 23. .20 335
1.60 121.24 23. .14 335
.92 113.23 23. .14 335
NITRILE 019 UIIIC .43 156.31 23. .04 335
.33 22 • .04 333
•27 22. .04 333
.33 22. .04 333
.44 ·,56.3, 22. .04 333
078 UtlIC .04 330.66 23. .03 334
PE 006 UlfIC > 24.00 23. .01 334
075 UIIIC .04 33.07 23. .03 334
076 127 1.25 23. 104
UlfIC > 24.00 23. .01 334
PV ALCOHOL 004 UIiIIC > 83.33 22. .09 333
PVC 007 UNIC .37 22. .11 333
.58 n.14 22. .11 333
.52 108.22 22 • .10 333
•58 87.17 22. .11 333
.60 22 . .12 333
•58 31.06 23 . .10 335
•50 30.06 23 • .11 335
049 UNIC •10 380.76 23. .os 334
A-25
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG!CM**2/MIN DEG C CM MUM
Dichloroethane
013002160 TEFLON 069 510 > 5.70 < •02 23 • .05 303
> 3.00 < .02 25. .05 303
cis'Dichloroethylene
001565920 BUTYl 014 118 .32 2,925.84 23. .07 323
PV ALCOHOL 004 100 .08 3,547.08 23. .05 323
PVC 007 100 .02 3,316.62 23. .02 323
VITON 009 118 1.68 30.06 23. .03 323
1,2'Oichloroethylene
005405900 NITRilE 019 100 .12 781.56 29. .04 323
PV ALCOHOL 004 100 .23 .50 23. .04 323
PVC 007 100 < .01 841.68 23. .02 323
VITON 009 118 .95 50.10 23. .03 323
trans'1,2'Dichloroethylene
001566050 BUTYl 014 118 .13 14,739.42 23. .06 323
PV ALCOHOl 004 100 2.63 1,142.28 23. .09 323
PVC 007 100 .02 6,262.50 23. .02 323
VITON 009 118 1.18 20.04 23. .03 323
Dichloropropane'Dichloropropene
080031980 TEFLON 069 510 > 3.00 < .02 23. .05 303
2,3·Dichloro·1·propene
000788860 BUTYL 014 118 1.90 140.28 23. .09 323
PV ALCOHOL 102 100 > 8.00 < .02 23. .09 323
PVC 007 100 .02 5,330.64 23. .02 323
VITON 009 118 > 8.00 < .02 23. .03 323
A-26
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C OM NUN
1,3·Dichloropropene
005427560 BUTYL 014 118 1.30 320.64 23. .07 323
PV ALCOHOL 102 100 8.00 < .02 23. .07 323
PVC 007 100 •02 6,513.00 23 • .02 323
VITON 009 118 8.00 < .02 23. .03 323
Di ethanol ami ne
001114220 BUTYL 014 118 8.00 24. .09 323
NEOPRENE 018 100 8.00 22. .05 323
NITRILE 019 100 8.00 26. .04 323
TEFLON 069 510 > 3.00 < .02 23. .05 303
VITON 009 118 8.00 27. .03 323
Diethylamine
001098970 BUTYL 014 118 • 78 460.92 23 • .09 323
NATURAL RUBBER 001 103 534.40 23. 045
NEOPRENE 125 103 396.79 23. 045
NITRILE 019 100 •75 90.18· 901.80 23 • .06 107
.20 1,332.66 24. .04 323
103 583.16 23. 045
PE 076 100 •08 90.18 • 901.80 23. 107
PVC 007 100 • 02 3,707.40 24 • .02 323
103 414.83 23. 045
SARANEX 061 127 .73 38.08 23. 104
SILVER SHIELD 122 118 > 8.00 23. .01 227
VITON 009 118 .58 8,537.04 20. .03 323
VITON/CHLOROBUTYL 112 113 .45 • .50 25. .04 302
Diethylaminoethanol
001003780 BUTYL 014 118 > 8.00 < .02 22. .07 323
NITRILE 019 118 > 8.00 < .02 22. .04 323
PV ALCOHOL 102 100 > 8.00 < .02 23. .09 323
VITON 009 118 > 8.00 < .02 22. .03 323
Diethylenetriamine
001114000 BUTYL 014 118 > 8.00 < .02 24. .08 323
NEOPRENE 018 100 8.00 < .02 22. .05 323
PVC 007 100 .63 3.01 22. .02 323
VITON 009 118 > 8.00 < .02 23. .03 323
Di isobutylamine
D01109630 NEOPRENE 018 100 .87 138.28 22. .05 323
NITRILE 019 100 > 8.00 20. .04 323
PV ALCOHOL 102 100 > 8.00 23. .08 323
VITON 009 118 > 8.00 22. .02 323
Diisobutyl Ketone
001088380 NATURAL RUBBER 001 210 .25 583.16 23. 080
NEOPRENE 002 210 .25 450.90 23. 080
NITRILE 005 210 4.75 30.06 23. 080
019 100 2.00 90.18 . 901.80 23. .06 107
NITRILE+PVC 057 210 1.25 3.01 23. 080
A-27
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VEIIDOR BREAKTHROUGH lINE PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOORS UG/CM**2/MI N DEG C CM NUM
Diisopropylamine
001081890 NEOPRENE 018 100 .67 450.90 12. .05 323
NITRILE 019 ·100 3.25 90.18 10. .04 323
PVC 007 100 .03 1,322.64 11. .02 323
TEFLON 069 510 > 4.50 < .02 24. .05 303
VITON 009 118 > 8.00 < .02 12. .03 323
N,N·DimethylacetaMide
001271950 CPE 070 UllIe .67 23. .05 004
SARANEX 061 127 1.07 2.00 23. 104
Dimethylamine
001244030 BUTYL 014 118 > 8.00 < •02 22 • .06 323
NATURAL RUBBER 001 250 .03 80.16 20. .02 323
NEOPRENE 018 100 > 8.00 < •02 22 • .05 323
PV ALCOHOL 102 100 .28 40.08 23. .07 323
PVC 007 100 .10 20.04 20. .02 323
Dimethylaminopropyleaine
001095570 BUTYL 014 118 > 8.00 < •02 16 • .09 323
NATURAL RUBBER 001 250 .01 2,114.22 16. .02 323
NEOPRENE 018 100 .48 470.94 20. .05 323
PVC 077 100 .03 2,189.37 20. .02 323
alpha,slphs·Dimethylbenzyl Hydroperox i de
000801590 TEFLON 069 510 > 3.50 < .02 23. .05 303
Dimethylbutylamine
001080980 BUTYL 014 118 1.68 320.64 24. .06 323
NITRILE 019 100 1.35 711.42 19. .04 323
PV ALCOHOL 102 100 .33 140.28 23. .08 323
PVC 007 100 .• 05 2,575.14 21. .02 323
Dimethylethanolamine
001080100 BUTYL 014 118 > 8.00 < •02 12 • .09 323
NATURAL RUBBER 001 250 .08 100.20 19. .02 323
NEOPRENE 018 100 3.92 30.06 21. .05 323
NITRILE 019 100 > 8.00 < •02 9• .04 323
A-28
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**21MIN DEG C eM NUM
Dimethylformamide
000681220 BUTYL 012 UN" 22.00 < .02 25. .04 273
23.00 < .02 25. .04 273
> 71.00 < .02 25. .06 273
> 71.00 < .02 25. .06 273
> 24.00 < .02 25. .04 273
> 24.00 < .02 25. .04 273
> 24.00 < .02 25. .06 273
> 24.00 < .02 25. .06 273
> 6.00 1.20 25. .04 273
> 6.00 1.20 25. .04 273
> 7.00 < ·1,669.98 25. .06 273
> 7.00 < '1,669.98 25. .06 273
014 118 > 8.00 23. .04 323
> 8.00 23. .04 227
107 UN" > 8.00 25. .04 149
> 8.00 25. .04 149
> 8.00 25. .04 149
NATURAL RUBBER 001 210 1.00 n1.44 23. 080
017 100 .50 90.18 901.80 23. .05 107
NEOP+NAT RUBBER 026 121 .62 66.13 23. .05 237
NEOPRENE 002 100 1.00 9.02 90.18 23. 107
210 .13 96.19 23. 080
018 100 .85 66.13 23. .05 323
• 17 9.02 . 90.18 23. .04 107
UN" 3.00 1.20 25. .04 273
3.50 1.20 25. .04 273
> 5.50 < .02 25. .06 273
> 6.00 < .02 25. .06 273
031 UN" .02 18.04 25. .04 149
.57 47.09 25. .04 149
1.10 74.15 25. .04 149
.10 20.04 25. .04 149
125 103 54.11 23. 045
NITRILE 005 120 .58 54.11 23. .06 236
210 1.00 120.24 23. 080
019 103 .114.23 23. 045
118 .15 90.18 23. .04 323
.22 > 90.18 23. .04 227
UN" 3.50 10.82 25. .04 273
3.50 12.02 25. .04 273
> 5.00 10.82 25. .06 273
> 5.00 10.22 25. .06 273
NITRILE+PVC 057 210 1.50 132.26 23. 080
PE 076 100 .50 < .90 23. 107
PV ALCOHOL 035 UNK .08 900.80 25. .07 149
.37 1,057.78 25. .07 149
.33 48.10 25. .07 149
.12 2,191.37 25. .07 149
102 100 .33 78.16 23. .04 323
.20 24.65 23. .03 323
PVC 007 210 1.00 138.26 23. 080
A-29
stJIIIWty OF PElFOIIIWICE DETAIL TESTS
PEIlllEATlOII TEST
CHEMICAL NAMEI RESISTANT PRODUCT VEIIDOR BREAKTIIROOGH TIlE PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL OESC COOE NOURS UG/CM**2/NIN OEG C CN IIUII
000681220 SILVER SHiElD 122 118 > 8.00 23. .01 227
TEFLON 069 510 > 11.20 < .02 23. .05 303
VITON 009 118 .13 39.08 23. .03 323
.13 39.08 23. .02 227
VITON/CNlOROBUTYl 112 113 > 3.00 25. .04 302
1,1-Dimethylhydrazine (Oimethylhydrazine,unsya·)
000571470 BUTYL 014 118 > 1.50 23. _03 001
> 1.50 23. .04 001
> 1.50 23. .08 001
034 UIIC 23.00 . 27.00 2.91 22. .08 078
CNLOROBUTYL 052 205 > 1.50 23. .05 001
CPE 060 113 .50 23. .05 001
NATURAL RUBBER 017 100 .17 23. .04 001
.23 23. .05 001
.06 23. .02 001
.18 23. .04 001
.06 23. .02 001
101 .10 23. .05 001
110 .22 23. .05 001
NEOP INA T RUBBER ooa 114 .03 23. .04 001
.15 23. .04 001
.15 23. .04 001
NEOPREIIE 002 100 1.12 23. .12 001
> 1.50 23. .13 001
018 100 .63 23. .05 001
031 UIIC .42 . .67 450.90 22. .08 078
NITRILE 019 100 .15 23. .04 001
.23 23. .04 001
.10 23. .03 001
118 .12 23. .03 001
PV ALCOHOl. 004 100 . .13 23. .09 001
PVC DOl 120 .22 23. .05 001
.68 23. .10 001
.03 23. .03 001
007 100 .47 23. .09 001
.58 23. .11 001
053 ,. .28
.05
.16
23.
23.
.10
.06
001
001
23. .07 001
054 ,. .33
.53
.02
23.
23.
.05
.05
001
001
23. .05 001
077 168 .08 . .17 190.38 22. .04 078
212 .08 23. .03 001
VITON 009 118 .20 23. .03 001
Dimethyl Sulfoxide
000676850 CPE 060 113 > 3.00 25. .07 302
NATURAL RUBBER 001 210 1.33 n1.44 23. 080
UIIC 1.50 . 2.00 25. .02 276
017 100 > 1.00 < 10.02 25. .03 222
1.00 .90 . 9.02 23. .05 107
A-30
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HOURS UG/CM**21MIN DEG C CM NOM
000676850 NATURAL RUBBER 017 120 > 1.00 < 10.02 25. .02 222
203 > 1.00 < 10.02 25. .05 222
> 1.00 < 10.02 25. .06 222
NEOP/NAT RUBBER 008 114 4.00 25. .05 276
NEOPRENE 002 100 > 8.00 25. .05 276
> 3.00 9.02 90.18 23. 107
120 > 1.00 < 10.02 25. .07 222
210 6.00 < .02 23. 080
UNK 1.77 23. .05 186
018 100 > 6.00 < .90 23. .04 107
120 > 1.00 < 10.02 25. .05 222
1.00 < 10.02 25. .05 222
> 1.00 < 10.02 25. .03 222
NITRILE 005 210 4.33 5.41 23. 080
019 100 > 1.00 < 10.02 25. .04 222
2.00 • 3.00 25. .04 276
> 4.00 .90 . 9.02 23. .06 107
191 .47 350.70 25. .03 222
NITRILE+PVC 057 210 1.33 4.81 23. 080
P£ 006 100 > 1.00 < 10.02 25. .01 222
PVC 003 120 .05 380.76 25. .01 222
•70 300.60 25 • .03 222
•57 320.64 25 . .02 222
007 100 1.17 •90 • 9.02 23 • 107
210 .83 6.01 23. 080
VITON/CHLOROBUTfL 112 113 > 3.00 25. .04 302
OJ ·n·octyl Phthalate
001178400 NITRILE+PVC 058 100 .42 23. 107
PE 076 100 .08 23. 107
PVC on 100 .42 23. 107
> 6.00 < .90 23. 107
A-31
SUPlMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTAIIT PRmUCT VEIIDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASIIO MATERIAL DESC CODE IKlJRS UG/CM"'*2/MIN OEG C CM NUM
Dipropyl_ine
001428470 TEFLa! 510 3.00 < .02 23. .05 303
Divinyl B_ _
013217400 IUTTL 014 118 2.22 1,430.86 23. .05 323
2.20 1,430.86 23. .04 227
MITRILE 019 100 1.00 2,703.60 23. .04 323
PV ALCOMOl 102 100 > 18.00 23. .03 323
SILVER SHIELD 122 ',8 > 8.00 23. .01 227
Vital 009 118 > 17.00 23. .02 323
> 17.00 23. .02 227
Epichlorohydrin
001068980 BUTYL 014 118 24.00 23. .04 291
24.00 23. .04 291
24.00 23. .04 291
24.00 23. .04 291
> 8.00 < ·1,669.98 23. .07 323
> 8.00 < '1,669.98 23. .07 323
034 UIQC 79.00 •20 22 • .08 078
NATUltAL RUBBER 001 250 < .02 504.34 23. .02 323
< .02 504.34 23. .02 323
A-32
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM
001068980 NATURAL RUBBER 011 UNIC -os 130.26 23. .02 291
.06 138.28 23 . .02 291
NEOPRENE 018 100 •33 362.72 23. .04 291
•25 314.63 23 • .04 291
031 UNIC 1.00 - 1.33 110.22 22. .08 018
NITRILE 020 503 .42 1,252.50 23. .04 291
.33 1,152.30 23. .04 291
PE .' 006 100 .OS 9.45 23. .01 291
.05 9.74 23. .01 291
PV ALCOHOL 035 UNK < •08 130.26 22 • .01 078
102 100 •05 127.25 23 • .OS 291
.02 105.21 23. .OS 291
5.82 .30 23. .07 323
5.82 .30 23. .01 323
SARANEX 061 127 1.00 3.32 23. .02 291
1.00 3.44 23 • .02 291
•95 52.30 23. 104
TEFLON 036 214 7.00 .02 23. .01 291
7.00 .02 23. .01 291
069 510 > 3.40 < .02 23. .05 303
VITON 009 118 1.00 51.20 23. .02 291
1.00 51.90 23. .02 291
1.00 50.70 23. .02 291
2.OS 6.13 23. .03 323
2.OS 6.13 23. .03 323
l,2-Epoxybutane
001068870 BUTYL 014 118 .75 20.04 23. .06 323
NEOPRENE 018 100 .07 20.04 23. .05 323
PV ALCOHOL 004 100 > 8.00 < .02 23. .04 323
VITON 009 118 .03 20.04 23. .03 323
A-33
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAlCTHRClJGH TIME PERMEATION RATE TEMP THICKNESS REf
CASNO MATERIAL DESC CalE HOURS UG/CM**2/MIII DEG C DI
Ethyl Acetate
001417860 BUTYL 014 118 7.60 ZO.44 23. .04 227
CPE 060 113 .97 . 1.17 25. .07 302
NATURAL RUBBER 001 210 .18 54.11 23. 080
017 100 .08 9.02 90.18 23. .05 107
NEOPRENE 002 100 • 33 9.02 90.11 23 • 107
210 •20 41.10 23 • 080
018 100 .25 9.02 90.18 23. .04 107
NITRILE 005 210 • 50 66.13 23 • 080
019 118 .13 871.74 23. .04 227
NITRILE+PVC 057 210 .50 41.10 23. 080
PE 076 100 .07 9.02 90.18 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
PVC 007 210 • 33 78.16 23 • 080
SARAIIEX 061 127 .60 6.61 23. 104
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEfLCIII 069 510 > 3.10 < .02 23. .05 303
> 4.30 < .02 24. .05 303
VITCIII/CHLOROBUTYL 112 113 .33 • .66 25. .04 302
Ethyl Acrylate
001'08850 250 250 .02 1,040.08 23. .02 323
BUTYL 014 118 > 1.00 23. .09 3Z3
064 117 .67 23. .02 213
.81 23. .01 213
.67 23. .02 213
BUTYL/NEOPRENE 110 117 1.00 23. .02 213
CPE 060 113 1.08 • 1.17 25. .07 302
lIIIC .50 23. 142
1.42 23. 142
070 lIIIC • 40 23 • .05 004
IEOPRENE 093 117 < .08 23. .02 213
138 117 .08 23. .03 213
139 117 < .25 23. .02 213
PE 076 117 < .08 23. .01 213
PV ALCOHOL 102 100 > 1.00 23. .08 3Z3
PVC 003 100 .03 1,040.08 23. .02 323
049 117 •05 23 • .01 213
A-34
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME I RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2!MIN DEG C CM NUM
A-35
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAlCTHRClIGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOORS UG/CM**2/MIN DEG C CM NUN
Ethylamine, 30-70%
0007504n BUTYL 014 118 > 12.00 < -1,669.98 23. .04 227
NITRILE 019 118 1.10 180.96 23. .04 227
SILVER SHIELD 122 118 .47 36.07 23. .01 227
TEFLON 069 510 > 3.00 < .02 23. .05 303
Ethyl Benzene
001004140 PV ALCOHOL 102 100 .55 23. .08 323
TEFLON 069 510 > 3.00 < •02 23 • .05 303
Ethyl Bromide
000749640 NEOPRENE 018 100 .07 1,322.64 23. .04 323
PV ALCOHOL 102 100 1.07 .42 23. .08 323
PVC 003 100 < .02 2,104.20 23. .02 323
VITON 009 118 1.43 30.06 23. .04 323
Ethyl·n·butylamine
133606390 NITRILE 019 100 1.22 210.42 24. .04 323
PV ALCOHOL 102 100 6.72 20.04 23. .09 323
PVC 007 100 .06 2,648.62 24. .02 323
VITON 009 118 3.80 1,482.96 23. .03 323
A-36
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATI 011 TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**Z/MIN DEG C CM NUM
A-37
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICICNESS REF
CASNO MATERIAL DESC CClOE HClURS UG/CIf**2!MJN DEG C
Ethyl_ Glycol
001072110 NATlIIAL IUlBER 001 210 6.00 .02 23. 080
017 100 > 1.00 < 10.02 25. .03 222
> 6.00 < ."90 23. .05 107
120 > 1.00 < 10.02 25. .02 222
502 > 1.00 e 10.02 25. .05 Z22
504 > 1.00 < 10.02 25. .05 222
> 1.00 10.02' 25. .06 Z22
IlECP+IIAT RUBBER 026 102 > 1.00 < 10.02 25. .05 222
121 > 1.00 < .02 23. .05 237
II£OP/IIAT RUBBER 008 11' > 1.00 < 10.02 25. .05 222
IIEOPRENE 002 100 > 6.00 < .90 23. 107
> 1.00 < 10.02 25. .08 222
210 6.00 < .02 23. 080
018 100 > 6.00 < .90 23. .04 107
118 > 1.00 < 10.02 25. .08 222
120 > 1.00 < 10.02 25. .05 222
> 1.00 e 10.02 25. .07 222
> 1.00 < 10.02 25. .05 Z22
A-38
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VEIIOOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM
0010nl10 NEOPRENE 018 120 > 1.00 < 10.02 25. .03 222
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 1.00 < 10.02 25. .04 222
> 6.00 < .90 23. .06 107
> 1.00 < 10.02 25. .04 222
503 > 1.00 < 10.02 25. .03 222
NITRllE+PVC 057 210 6.00 < .02 23. 080
058 100 > 6.00 < .90 23. 107
PE 006 100 > 1.00 < 10.02 25. .01 222
505 > 1.00 < .10 25. .01 222
076 100 > 6.00 < .90 23. 107
PV ALCOHOL 004 100 2.00 .90 9.02 23. 107
PVC 003 120 > 1.00 < 10.02 25. .01 222
> 1.00 25. .01 222
> 1.00 < 10.02 25. .03 222
> 1.00 < 10.02 25. .02 222
500 > 1.00 < 10.02 25. .01 222
501 > 1.00 < 10.02 25. .01 222
> 1.00 < 10.02 25. .02 222
007 100 > 6.00 < .90 23. 107
210 6.00 < .02 23. 080
on 100 .75 .90 9.02 23. 107
> 6.00 < .90 23. 107
TEFLON 069 510 > 16.80 < .02 23. .05 303
Ethylenimine (Aziridine)
001515640 BUTYL 034 UIIIC 10.00 • 16.00 4.51 22. .08 078·
NEOPREIIE 010 120 < .08 22. .02 078
Ethyl Ether
000602970 BUTYL 014 118 .13 554.31 23. .04 227
NATURAL RUBBER 001 210 • 17 1.563.12 23 • 080
NEOPRENE 002 100 .17 9.02· 90.18 23. 107
210 .20 1.232.46 23. 080
018 100 .17 9.02 90.18 23. .04 107
125 103 330.66 23. 045
NITRILE 005 210 2.30 84.17 23. 080
019 100 2.00 9.02' 90.18 23. .06 107
103 264.53 23. 045
118 .23 131.06 23. .04 227
NITRILE+PVC 057 210 .42 1,863.n 23. 080
PE 076 100 .03 90.18 901.80 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
102 100 > 8.00 23. .04 323
PVC 007 210 .33 2,104.20 23. 080
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEFLON 069 510 > 3.00 < .02 23. .05 303
> 3.00 < .02 23. .05 303
VITON 009 118 .20 129.26 23. .03 323
.20 129.26 23. .02 227
A-39
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST
CHE"'ICAl NAMEI RESISTANT PRODUCT V[NDOR 8REAKTHROUGH TINE PERMEATION RATE TEMP THICKNESS Ref
CASNO MATERIAL DESC COOE HOURS UG/CM**2!MIN DEG C CM NUM
'·Ethvlhexanoi,· Acid
NEOPRENE 018 lOa 4 CO 2~. .G~ i23
NITRILE 019 100 > ':'.00 23. .i:.. 1 ~3
PVC 003 215 > ... 00 23 • .v.. 123
- . t:thvl- 1 - Hexanol
:1'1047670 6~ITYl ~18 > B.OO 23. • <iT 323
NEOPRENE 100 ~.OO 23. .G~ 3::3
p" ALCOHOL 10C > 8.00 23. .09 ';23
V! TOIl oo'? "8 8.'.,0 23. . 03 ~.'3
A-40
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM MUM
Freon TF
000761310 NATURAL RUBBER 017 100 .15 1,002.00 25. .03 222
120 .04 3,006.00 2S. .02 222
502 .28 821.64 2S. .OS 222
504 .27 101.40 2S. .05 222
.48 591.18 2S. .06 222
IIEOP+NA T RUBBER 026 102 .27 101.40 25. .05 222
121 .21 474.95 23. .05 237
NEOP/NAT RUBBER 008 114 .21 791.S8 2S. .05 222
NEOPRENE 002 100 2.00 .90 9.02 23. 107
> 1.00 < 10.02 25. .08 222
120 3.00 20.04 25. .07 222
018 100 4.00 < .90 23. .04 107
118 > 1.00 < 10.02 2S. .08 222
120 > 1.00 < 10.02 2S. .05 222
> 1.00 < 10.02 2S. .07 222
> 1.00 < 10.02 2S. .05 222
> 1.00 < 10.02 25. .03 222
NITRILE 019 100 > 1.00 < 10.02 25. .04 222
> 6.00 < .90 23. .06 107
> 1.00 < 10.02 2S. .06 222
> 1.00 < 10.02 25. .04 222
503 > 1.00 < 10.02 25. .03 222
NITRlLE+PVC 058 100 .2S 90.18 901.80 23. 107
PE 006 100 .08 10.02 2S. .01 222
S05 > 1.00 < 1.00 25. .01 222
076 100 .13 9.02 90.18 23. 107
PV ALCOHOL 004 100 .SO .90 9.02 23. 107
PVC 003 120 .04 3,406.80 25. .01 222
.09 2,204.73 25. .01 222
.18 190.38 25. .03 222
.13 240.48 25. .02 222
SOD .04 2,605.20 25. .01 222
5(11 .04 3,006.00 25. .01 222
.05 1,903.80 25. .02 222
on 100 .30 9.02 . 90.18 23. 107
A-41
SUMMARY OF PERFORNAICE DETAIL TESTS
PEIIMEA TlOII TEST
CHEMICAL NAMEI RESISTANT PROOUCT VENDOR BREAKTIIItOOGH TUIE PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM
Freon TNC
577623190 NATURAL RUBBER 017 100 •05 901.80 9,018.00 23 • .05 107
NEOPRENE 002 100 • 17 90.18 901.80 23 • 107
018 100 •OS 901.80 9,018.00 23 • .04 107
NITRILE 019 100 • 17 901.80 9,018.00 23 • .06 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
Furln (Furfuran)
001100090 BUTYL 014 118 1.35 60.12 23. .09 323
PV ALCOHOl. 102 100 1.89 .GII 23. .09 323
PVC 003 100 .02 2,951.89 23. .02 323
VITOII 009 118 .33 138.28 23. .05 323
Furfurel
000980110 IUTYL 014 118 > 16.00 23. .04 323
> 16.00 23. .04 227
NATURAL RUIIER 001 210 .25 30.06 23. oao
017 100 .25 9.02 • 90.18 23. .05 107
002 100 2.00 9.02· 90.18 23. 107
210 .50 18.04 23. oao
011 '00 .33 9.02· 90.18 23. .04 107
IITIULE 005 210 .92 156.31 23. oao
019 118 • 40 1,591.38 23 • .03 323
.47 1,591.11 23. .04 227
-
IITRILE+PW: 057 210 .67 144.29 23. oao
fIE 076 100 .GII ~ .90 23. 107
PV ALCGNOL 100 > 6.00 ~ .90 23. 107
102 '00 > 16.00 23. .03 323
PVC 007 210 1.17 108.22 23. oao
SILva SlIELD 122 "1 > 8.00 23. .01 227
TE'LCII 069 "0 > 1.00 ~ .02 23. .05 303
VITa. 009 "1 3.50 88.98 23. .03 323
3.60 88.98 23. .02 227
GeNt I,.
-
010II66190 IUTYL 064 117 •• 23. .02 213
IUTYLJI8ECIIIDE 110 117 .33 23. .02 213
IlEClMlAT IIUIIEI 121 .07 1,076.15 23. .05 237
IITRILE 0 79 100 6.00 ~ .90 23. .06 107
-
IITRILE+PW: 051 100 .08 90.18· 901.1D· 23. 107
fIE 076 100 .05 90.11· 901.1D 23. 107
PV ALCGNOL '00 6.00 < .90 23. 107
PVC 077 100 .07 9.02· 90.11 23. 107
.GII 90.18· 901.80 23. 107
VI Ta./llEOPIIENE 111 117 8.00 23. .02 213
Glutereldehyde
00",3080 BUTYL 014 118 > 8.00 < .02 23. .09 323
NEOPIEIE 018 100 > 1.00 < .02 23. .05 323
PVC 003 100 1.17 6.01 23. .02 323
VITOII 009 118 > 1.00 < .02 23. .04 323
Jr-42
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATI TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM
Halothane
001516nO BUTYl 014 118 3.07 138.28 23. .09 323
PV ALCOHOL 102 100 > 8.00 23. .07 323
PVC 007 100 .03 4,064.11 23. .02 323
VITON 009 118 .62 432.86 23. .05 323
Heptane
001428250 NATURAL RUBBER 001 210 .10 703.07 23. 080
UNIC •02 > 521.04 23 . .12 274
017 UNIC •03 > 531.06 23 . .04 274
NEOP/NAT RUBBER OOS UNIC • 08 > 526.05 23 . .05 274
NEOPRENE 002 210 .75 499.00 23. 080
018 UNK > 1.00 23. .06 274
> 1.00 23. .09 274
NITRILE 005 210 6.00 < .02 23. 080
019 UNK > 1.00 23. .05 274
> 1.00 23. .05 274
NITRILE+PVC 057 210 3.00 18.04 23. 080
PVC 007 210 .50 180.36 23. 080
UNIC .25 > 450.90 23. .16 274
VITON 009 UNIC > 1.00 23. .03 274
Hexachlorocyclopentadiene
000n4740 BUTYL 014 118 > 8.00 < .02 23. .06 323
NITRILE 019 100 > 8.00 < .02 23. .04 323
PV ALCOHOL 102 100 > 8.00 < .02 23. .08 323
VITON 009 118 > 8.00 < .02 23. .03 323
Hexamethylphosphoamide
006803190 BUTYl 034 UNIC 1.00 1.50 .OZ ZZ. .08 078
NITRILE 033 UNIC 1.00 . 1.50 13.03 22 . .09 078
PE 006 209 •25 . .42 4.01 22. .01 078
Hexane
001105430 BUTYL 012 UNIC .13 > 2,344.68 25. .04 273
.17 1,923.84 25. .04 273
.33 1,833.66 25. .06 273
.42 1,238.47 25. .06 273
.03 > 2,344.68 25. .04 273
.17 2,314.6Z Z5. .04 273
.50 1,370.74 25. .06 273
.50 1,226.45 25. .06 273
.12 > 2,344.68 25. .04 273
.17 > 2,344.68 25. .04 273
.33 1,1n.34 25. .06 273
.33 1,490.98 25. .06 273
014 UNK .04 256.11 25. 287
107 UNK .35 23. .04 094
.17 45. .04 094
CPE 060 113 > 3.00 25. .07 302
NATURAL RUBBER 001 210 .08 751.50 23. 080
NEOPRENE 002 100 1.50 9.02 . 90.18 23. 107
A-43
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM*·2/MIN DEG C eM NUM
Hydrazine (Diamine)
003020120 BUTYL 014 118 > 8.00 23. .04 323
NEOPRENE 018 100 > 16.00 23. .05 323
NITRILE 019 118 > 8.00 23. .04 323
PVC 003 100 > 8.00 23. .03 323
Hydrazine, 30·7QX
003020122 BUTYL 014 118 > 8.00 < .02 23. .04 227
NATURAL RUBBER 017 100 > 6.00 < .90 23. .05 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
018 100 > 6.00 < .90 23. .04 107
NITRILE 019 100 > 6.00 < .90 23. .06 107
118 > 8.00 < .02 23. .04 227
A-44
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PROOUCT VENDOR BREAICTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS UG/CM**2/MIN DEG C CM NUM
Hydrochloric Acid
076470100 BUTYL 064 117 > 8.00 23. .02 213
> 8.00 23. .01 213
> 8.00 23. .02 213
BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213
CPE 070 lINlC > 3.00 23. .05 004
NATURAL RUBBER 001 210 6.00 < .02 23. 080
NEOP+NAT RUBBER 026 121 4.42 12.02 23. .05 237
NEOPRENE 002 210 6.00 < .02 23. 080
093 117 > 8.00 23. .02 213
138 117 > 8.00 23. .03 213
NEOPRENE+PVC 127 117 > 8.00 23. .02 213
NITRILE 005 210 6.00 < .02 23. 080
NITRILE+PVC 057 210 6.00 < .02 23. OS()
058 117 1.75 23. .01 213
PVC 007 210 6.00 < .02 23. 080
049 117 > 8.00 23. .01 213
> 8.00 23. .01 213
053 117 5.11 23. .02 213
077 117 < 5.00 23. .01 213
2.92 23. .01 213
144 117 4.33 23. .02 213
SARANEX 061 117 5.00 23. .01 213
VITON 145 117 > 8.00 23. .02 213
VITON/NEOPRENE 111 117 > 8.00 23. .02 213
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAlCTHRooGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HooRS UG/tM**2/MIN DEG C CM lUI
Hydroeyanie Aeid
000749080 BUTYL 034 lIIIC 1.00 < .02- .04 148
PE 076 lIIIC 1.00 .12- .02 148
PVC 049 UIII( .50 .28- .08 148
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS UG/CH**2/MIN DEG C CM NUM
A-47
S~~.AAY OF PERF~ii"J."C:E DET A: L -:S~S
PERMEATlOtI TEST
C~E'" I CAL tlA.~E/ RESISTAMT PRODUCT VENDOR BREAKTHROUGH TIME PER~EATIO~ RATE TENP TiiICI"ESS REF
CAStlO MATERIAL OESC COOE HOURS UG/CM**Z/MIN DEG C CM NUll
Hydroquinone
001233190 NITRILE+PVC 058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC on 100 > 6.00 23. 107
6.00 23. 107
Hydroqu;none. <3OX
001233191 NATURAL RUBBER 017 100 > 6.00 < .90 23. .05 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
018 100 > 6.00 < .90 23. .04 107
NITRILE 019 100 > 6.00 < .90 23. .06 107
PVC 007 100 > 6.00 < .90 23. 107
Iminobispropylemine
000561880 BUTYL 014 118 > 8.00 28. .09 323
NATURAL RUBBER 001 250 .10 84.17 26. .02 323
NEOPRENE 01a 100 > 8.00 27. .05 323
VITOII 009 118 > 8.00 27. .04 323
b·lonone
149010760 BUTYL 014 118 . > 9.00 23. .06 323
PV ALCOHOL 10l 100 > 14.00 23. .04 323
> 8.00 23. .03 323
118 > 8.00 23. .03 323
ISOlllllYl Acetate
001239220 BUTYL 107 120 .03 1,903.80 25. .02 222
NYPAlON 10S 120 .50 ·350.70 2S. .05 222
NATURAL RUBBER 017 100 .09 1,102.20 25. .03 222
502 • 16 791.58· 25 • .05 222
504 .17 661.32 25 •. .05 222
.32 470.94 25 • .06 222
NEOP+NAT RUBBER 026 102 •16 761.52 2S. .OS 222
NEOP/NAT RUBBER 008 114 .20 731.46 25. .05 222
NEOPRENE 002 100 .20 140.28 2S. .os 222
120 .09 120.24 2S. .07 222
018 118 > 1.00 25. .08 222
120 .SO 310.62 2S. .OS 222
.27 541.08 25. .03 222
NITRILE 019 100 > 1.00 25. .04 222
> 1.00 2S. .06 222
A-48
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG!CM**2!MIN OEG C CM NUM
Isoamylnitrile
001104630 NEOPRENE 018 100 .78 224.25 23. .05 000
NITRILE 019 100 2.93 9.62 23. .04 323
PV ALCOHOL 102 100 > 8.00 23. .03 323
VITON 009 118 1. 13 55.31 23. .02 323
Isobutyl Acrylate
001066380 BUTYL 014 118 > 8.00 23. .09 323
NITRILE 019 100 1.13 126.25 23. .05 323
PV ALCOHOL 102 100 > 8.00 23. .08 323
PVC 003 100 •02 204.41 23 • .02 323
Isobutyl Alcohol
000788310 BUTYL 014 118 > 8.00 23. .07 323
NATURAL RUBBER 001 210 2.00 4.51 23. 080
017 100 .42 9.02 90.18 23. .05 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
210 6.00 < .02 23. 080
018 100 .17 < .90 23. .04 107
> 8.00 23. .05 323
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 6.00 < .90 23. .06 107
118 > 8.00 23. .05 323
NITRILE+PVC 057 210 4.00 4.81 23. 080
058 100 .12 •90 • 9.02 23 • 107
PE 076 100 .05 . 90 . 9.02 23 . 107
PVC 007 100 .17 < .90 23. 107
210 2.00 4.51 23. 080
077 100 .50 < .90 23. 107
2.00 . 90 . 9.02 23 . 107
VITON 009 118 > 8.00 23. .05 323
Isobutyl Nitrite
005425630 BUTYL 014 118 1.30 132.26 23. .04 323
NITRILE 019 100 1.63 6.01 23. .06 323
PVC 003 100 .03 1,454.90 23. .02 323
VITON 009 118 .33 619.24 23. .04 323
Isobutyraldehyde
000788420 BUTYL 014 118 > 8.00 23. .06 323
NEOPRENE 018 100 .42 48.70 23. .05 323
A-49
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PROOUCT VENDOR BREAlCTHROOGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE IKlJRS UG/CM**2/MIN DEG C CM NUM
Isooctane
266356430 NATURAL RUBBER 001 103 294.59 23. 045
NEOPRENE 002 100 6.00 < .90 23. 107
018 100 1.00 9.02 90.18 23. .04 107
125 103 < .02 23. 045
NITRILE 019 100 6.00 < .90 23. .06 107
103 < .02 23. 045
NITRILE+PVC 058 100 .28 .90 9.02 23. 107
PE 076 100 .23 9.02 90.18 23. 107
PV ALCOHOL 004 100 •67 .90 • 9.02 23. 107
PVC 007 103 3.01 23. 045
077 100 .25 .90 • 9.02 23. 107
1.25 .90 9.02 23. 107
Isoprene
000787950 NEOPRENE 018 100 •27 192.38 23 • .05 323
NITRILE 019 100 •87 27.66 23 . .04 323
PV ALCOHOL 102 100 > 12.00 23. .03 323
VITON 009 118 6.20 1.14 23. .03 323
I sopropyl ami ne
000753100 BUTYL 014 118 4.08 36.07 24. .09 323
IIEOPRENE 018 100 .23 913.82 21. .05 323
A-50
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HOORS UG/CM**21MIN OEG C CM lUI
Isopropyl Ether
001082030 CPE 070 UNK > 3.00 23. .05 004
NATURAL RUBBER 017 UNIC • 06 > 480.96 23 • .04 274
NEOP/NAT RUBBER 008 UNIC •12 > 501.00 23 • .05 274
NEOPRENE 018 UNK > 1.00 23. .09 274
•71 > 10.02 23 • .06 274
NITRilE 019 UNK > 1.00 23. .05 274
PV ALCOHOL 004 UNK > 1.00 23. .12 274
PVC 007 UNK .25 > 501.00 23. .16 274
VITON 0D9 UNK > 1.00 23. .03 274
Isopropylmethacryl ate
046553490 BUTYL 014 118 > 8.00 23. .09 323
NITRI.lE 019 100 1.88 36.07 23. .05 323
PV AlCOllOl 102 100 > 8.00 23. .09 323
PVC 003 100 •02 354.71 23 • .02 323
Kerosene
080082060 NATURAL RUBBER 017 100 •50 .90 • 9.02 23 • .OS 107
NEOP+NAT RUBBER 026 121 •60 12.02 23 • .OS 237
NEOPRENE 002 100 > 6.00 < .90 23. 107
018 100 > 6.00 < .90 23. .04 107
NITRilE 019 100 > 6.00 < .90 23. .06 107
NITRllE+PVC 058 100 1.25 9.02 • 90.18 23. 107
PE 076 100 .20 9.02 • 90.18 23. 107
PV AlCOHOl 004 100 > 6.00 < .90 23. 107
PVC 007 100 > 6.00 < .90 23. 107
077 100 .50 9.02 90.18 23. 107
3.00 9.02 • 90.18 23. 107
A-51
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICICNESS REF
CASNO MATERIAL DESC cmE HOURS UG/CM**2!MIN DEG C eM lUI
d-li.onene (Menthadiene)
059892750 BUTYL 014 118 > 8.00 23_ .02 323
IIEOPREIIE 018 100 1.08 23. .05 323
IIITRILE 019 100 > 20.00 23. .04 323
PV ALCOHOL 102 100 > 8.00 23. .03 323
Methacrylonitrile
001269870 BUTYL 014 118 > 8.00 23. .09 323
NATUltAl RUllBER 001 250 < .02 1,803.60 23. .02 323
PV AlCOHOl 102 100 .40 .48 23. .06 323
PVC 003 100 .03 1,142.28 23. .02 323
Meth~ulfonic Acid
000757520 NEOPRENE 018 100 > 4.00 23. .05 123
PVC 003 215 > 4.00 23. .05 123
A-S2
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HooRS UG/CM**2/MIN DEG C CM NUM
000675610 NEOP+NAT RUBBER 026 102 .25 1.20 23. .05 026
121 .30 6.01 23. .05 237
NEOP/NAT RUBBER 008 102 .25 1.20 23. 026
114 .40 4.01 25. .05 222
UNK > 1.00 23. .05 274
NEOPRENE 002 100 .25 .90 23. 107
.29 6.01 25. .08 222
120 .38 5.01 25. .07 222
210 6.00 .02 23. 080
018 100 1.00 < .90 23. .04 107
118 > 1.00 < 4.01 25. .08 222
120 > 1.00 < 4.01 25. .05 222
> 1.00 < 4.01 25. .07 222
> 1.00 < 4.01 25. .05· 222
> 1.00 < 4.01 25. .03 222
UNK > 1.00 23. .09 274
> 1.00 23. .06 274
031 UNK 1.03 23. .04 187
093 111 5.92 23. .02 213
138 111 5.00 23. .03 213
139 111 > 8.00 23. .02 213
NITRILE 005 210 6.00 < .02 23. 080
019 100 1.15 23.05 25. .04 222
.18 90.18 901.80 23. .06 107
> 1.00 4.01 25. .06 222
.90 36.07 25. .04 222
503 .65 29.06 25. .03 222
UNK > 1.00 23. .05 274
033 UNK .91 23. .05 187
NITRILE+PVC 051 210 6.00 < .02 23. 080
058 100 .33 .90 9.02 23. 107
PE 006 100 > 1.00 < 4.01 25. .01 222
505 > 1.00 < 4.01 25. .01 222
016 100 .22 < .90 23. 107
111 > 8.00 23. .01 213
PV ALCOHOL 004 100 .02 124.15 23. 123
.02 124.15 21. 124
UNK .04 > 30.06 23. .12 274
PVC 003 120 .03 36.01 25. .01 222
.03 34.07 25. .01 222
.05 18.04 25. .03 222
.05 23.05 25. .02 222
500 .03 34.07 25. .01 222
501 .02 38.08 25. .01 222
.04 30.06 25. .02 222
001 100 .15 9.02 90.18 23. 107
210 6.00 < .02 23. 080
UNK > 1.00 23. .16 274
1.50 23. .07 186
.77 23. .05 186
049 117 .83 23. .01 213
UNK .68 23. .03 187
077 100 .17 .90 23. 107
A-53
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS UG/CM**21MIN OEG C CM MUM
4-Methoxy-4-.ethyl-2-pentanone
001077000 BUTYL 014 118 > 13.00 23. .07 323
NEOPRENE 018 100 1.65 33.07 23. .05 323
PV ALCOIIOl. 102 100 > 14.00 23. .03 323
vnON 009 118 .40 116.03 23. .03 323
Methyl Acetate
000792090 BUTYL 014 118 > 8.00 23. .09 323
IATURAL USER 001 250 < •02 6,012.00 23 • .02 323
P£ 076 100 •07 .90· 9.02 23 • 107
PV ALCOIIOl. 102 100 .68 12.02 23. .07 323
PVC 003 100 < .02 6,012.00 23. .02 323
Methyl Acrylate
00096D30 BUTYL 014 118 > 8.00 23. .09 323
IATURAL RlIIIER 001 250 .02 625.25 23. .02 323
1lE0PIIEIIE 018 100 .25 3,168.32 23. .05 323·
PV ALCOIIOl. 102 100 1.50 1.80 23. .07 323
TEFlCII 069 510 3.00 < .02 23. .05 303
Methyleaine C_ _ thyleaine)
000748950 IATURAL RUlBER 017 100 .42 9.02 • 90.18 23. .05 107
1E0PR£1I£ OOZ 100 6.00 < .90 23. 107
018 100 4.50 9.02 • 90.18 23. .04 107
InRIl£ 019 100 6.00 < .90 23. .06 107
PVC 007 100 2.25 •90 • 9.02 23 • 107
Methyleaine, 3O-7OX
000748952 BUTYL 014 118 > 15.00 < .02 23. .04 227
InRILE 019 118 > 8.00 23. .04 227
InRIl£+pvc GSa 100 .50 9.02 90.18 23. 107
P£ 076 100 .17 9.02 90.18 23. 107
PVC on 100 .17 < .90 23. 107
1.00 •90 9.02 23 • 107
SILVER SHIELD 122 118 1.90 12.02 23. .01 227
VnON 009 118 > 16.00 < .02 23. .02 227
3-Methyl_inopropylealne
062918450 BUTYL 014 118 > 8.00 < .02 20. .07 323
IATURAL RUBBER 001 250 .05 731.46 16. .02 323
NEOPRENE 018 100 1.05 160.32 16. .05 323
PVC 007 100 •03 671.34 14 • .02 323
A-54
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATIOIi TEsT
CHEMICAL NAMEI REsiSTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE ':MP THICKNEsS REF
CASNO MATERIAL DESC COOE HOURS UG/CM**2/MIN DEG C CM HUM
Methyl Chloroacetate
000963440 SARANEX 061 127 8.00 18.04 23. '04
A-55
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME I RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C eM NUM
A-56
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME I RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUN
A-57
SUMMARY OF PERFORMANCE DETAIL TeSTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2!MIN DEG C CM NUM
n-Methylethanolamine
001098310 BUTYL 014 118 > 8.00 < .02 19. .07 323
CELLULOSE ACETATE 099 118 > 8.00 < .02 20. .03 323
NATURAL RUBBER 001 250 .08 150.30 20. .02 323
NEOPRENE 018 100 > 8.00 < .02 20. .06 323
h-58
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RA~ ,EMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM
Methyl hydraz i ne
000603440 BUTYL 014 118 > 2.00 22. .23 321
> 2.00 22. .04 321
064 113 .01 22. .03 321
085 211 > 2.00 22. .11 321
CHLOROBUTYL 052 205 > 2.00 23. .04 321
CPE 060 113 .87 22. .05 321
070 113 1.10 22. .05 321
CR 39 095 122 > 2.00 22. .17 321
PVC 003 103 .52 22. .13 321
1.90 22. .13 321
053 126 > 2.00 22. .05 321
083 211 > 2.00 22. .20 321
TEFLON 055 210 < .01 22. .02 321
062 UNIC < .01 22. .02 321
067 UNK < .01 22. .02 321
068 lINK < .01 22. .02 321
069 UIIK < .01 22. .02 321
VITON 009 118 1.50 22. .05 321
Methyl Iodide
000748840 BUTYL 014 118 •92 492.98 23 • .09 323
NATURAL RUBBER 017 100 .03 13,026.00 25. .03 222
120 •03 > 16,699.98 25 . .02 222
502 .05 8,116.20 25. .05 222
504 • 04 9,218.40 25 • .05 222
•06 6,913.80 25 • .06 222
NEOP+NAT RUBBER 026 102 .03 8,917.80 25. .04 222
A-59
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HooRS UG/CM**2/MIN DEG C CM NUM
000748840 NEOP/NAT RUBBER OOS 114 .09 5,310.60 25. .05 222
NEOPRENE 002 100 •25 1,402.80 25 • .08 222
120 •01 4,609.20 25 • .07 222
018 100 .10 7,893.76 23. .05 323
118 • 28 2,905.80 25 • .OS 222
120 •07 6,312.60 2S • .05 222
.20 3,707.40 25. .07 222
•07 5,611.20 2S • .05 222
•04 7,915.80 2S • .03 222
NITRILE 019 100 .01 6,613.20 25. .03 222
• 13 8,016.00 25 • .05 222
•09 6,012.00 2S • .04 222
181 8,216.40 25. .03 222
503 • 03 11,022.00 25 . .03 222
PE 006 100 •01 1,102.20 25 • .01 222
50S •04 300.60 25 • .01 222
PV ALCOHOL 102 100 > 8.00 23. .07 323
VITOII 009 118 6.35 4.21 23. .04 323
A-60
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL OESC COOE HOURS UG/CM**2/MIN OEG C CM NUM
MethyL Isocyanate
006248390 BUTYL 014 118 • 72 13 • .06 323
1,012.00 90.18 23. .07 323
NATURAL RUBBER 001 250 .01 20. .02 323
•02 10,641.24 23 • .01 323
NEOPRENE 018 100 • 01 20 • .05 323
• 02 2,254.50 23 • .04 323
PV ALCOHOL 004 100 > 8.00 < .02 23. .03 323
> 8.00 < .02 23. .05 323
V IT ON 009 118 .02 21. .03 323
.07 1,212.42 23. .03 323
MethyL MethacryLate
000806260 BUTYL 014 118 4.98 24.05 23. .09 323
NATURAL RUBBER 001 250 < • 02 9,619.20 23 . .02 323
PE 076 100 .03 9.02 90.18 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
102 100 > 8.00 23. .06 323
PVC 003 100 < • 02 9,619.20 23 • .02 323
TEFLON 069 510 > 3.10 < .02 23. .OS 303
MethyL'vinyL'ketone
000789440 CPE 060 UNK .50 23. 142
1.67 23. 142
VITON/CHLOROBUTYL 112 UNK > 3.00 23. 142
MineraL Spirits
080524130 NEOP+NAT RUBBER 026 121 .22 138.28 23. .05 237
NEOPRENE 002 100 > 6.00 < • 90 23 • 107
018 100 1.50 •90 9.02 23 • .04 107
NITRILE 019 100 > 6.00 < • 90 23 . .06 107
NITR I LE+PVC 058 100 .10 9.02 90.18 23. 107
PE 076 100 .10 9.02 90.18 23. 107
127 < .08 7.01 23. 104
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
PVC 007 100 2.50 •90 9.02 23 . 107
077 100 .10 .90 9.02 23. 107
.10 9.02 90.18 23. 107
SARAN EX 061 127 > .17 < .20 23. 104
Monoisopropanolamine
000789660 BUTYL 014 118 > 8.00 25. .07 323
NEOPRENE 018 100 > 8.00 24. .05 323
PVC 007 100 > 8.00 25. .02 323
VITON 009 118 > 8.00 25. .04 323
MorphoL ine
A-61
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEA TI 011 TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C OM NUM
N-Methyl-2-pyrrolidOne
008n5040 NATURAL RUBBER 001 103 3.61 23. 045
IIEOPRENE 125 103 6.01 23. 045
IIITRILE 019 103 24.05 23. 045
PVC 007 103 24.05 23. 045
Nitric Acid
076973no BUTYL 064 117 > 8.00 23. .02 213
> 8.00 23. .01 213
> 8.00 23. .02 213
BUTYl/IIEOPRENE 110 117 > 8.00 23. .02 213
CPE 070 UIIIC > 3.00 23. .05 004
IIATURAL RUBBER 001 210 2.00 23. 080
IIEOP+IlAT RUBBER 026 121 > 8.00 < .02 23. .05 237
IIEOPREIIE 002 210 2.00 23. 080
093 117 2.67 23. .01 213
138 117 1.n 23. .03 213
139 117 3.08 23. .02 213
IIEOPRENE+PVC 127 117 1.08 23. .02 213
IIITRIlE 005 210 4.00 23. 080
IIITRI'LE+PVC 057 210 4.50 23. 080
058 117 .42 23. .01 213
PE 076 117 8.00 23. .01 213
PVC 007 210 3.75 23. 080
049 117 3.00 23. .01 213
.42 23. .01 213
053 117 < .33 23. .02 213
077 117 < .08 23. .01 213
.75 23. .01 213
A-62
IUMMARY OF PiRf0RM4NCE D~TAI~ lJITI
PUMEAlICIN TnT
CHEMICAL NAMEI RESISTANT PRQOUCT VENDOR IREAKTHROUGH TIME PUMIATION ItAT~ liMP THICKNUS Rif
CASNO MATERIAL PEiCCOI)E HOURS UG/CM**i!/MIN DIG C eM NLIM
A· I'd
SUMMARY Of PERFORMANCE DETAIL TESTS
PERMEATlOII TEST
CHEMICAL lIANE/ RESISTAltT PRaJUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASIIO MATERIAL DESC CODE HOURS UC/CM**2/M I N DEG C CM NUM
lIitrobenzene
000989530 BUTYL 014 118 > 23.00 23. .06 323
> 23.00 23. 4.00 227
064 117 > 8.00 23. .01 213
CPE 060 113 1.03 25. .07 302
070 lINK 1.03 23. .05 004
NATURAL RUBBER 017 100 .08 9.02 90.18 23. .05 107
IIEOPRENE 018 100 .75 1.14 23. .05 323
031 511 •67 132.26 23 • 323
IIITRllE 019 118 .48 10.22 23. .04 323
.55 10.22 23. .04 227
Py AlCOHOL 004 100 > 6.00 < .90 23. 107
102 100 > 16.00 23. .03 323
SILVER SHIELD 122 118 > 8.00 23. .01 227
TEFLOII 069 510 > 3.00 < .02 23. .05 303
A:-64
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM
000989530 TEFLON 069 510 > 3.00 < .02 24. .05 303
VITON 009 118 > a.oo 23. .03 323
> 8.00 23. .02 227
VITON/CHLOROBUTYL 112 113 2.83 3.00 25. .04 302
Nitroethane
000792430 BUTYL 014 118 > 8.00 23. .09 323
NATUttAL RUBBER 001 250 •03 186.37 23 . .02 323
NEOPRENE 018 100 • 82 102.20 23 . .04 323
PV ALCOHOL 102 100 3.52 2.40 23. .07 323
Nitrogen Tetroxide
10544n60 BUTYL 014 118 > 2.00 22. .23 321
.68 22. .05 321
064 113 .60 22. .03 321
085 211 > 2.00 22. .11 321
CHLOROBUTYL 052 205 > 2.00 23. .04 321
CPE 060 113 1.15 22. .05 321
070 113 1.25 22. .06 321
CR 39 095 122 > 2.00 22. .17 321
PE 091 UNIe: 1.17 22. .04 321
PVC 003 103 .33 22 • .13 321
•20 22. .13 321
053 126 .65 22. .05 321
083 211 > 2.00 22. .19 321
TEFLON 062 UtIle: < .01 23. .02 321
067 UNIe: < .01 23. .02 321
069 UNIe: < .01 23. .02 321
< .01 23. .02 321
VITON 009 118 .77 22. .03 321
Nltromethene
000755250 BUTYL 014 118 > 8.00 23. .09 323
NATURAL RUBBER 001 250 < .02 96.19 23. .02 323
017 100 .07 < .90 23. .05 107
NEOPRENE 002 100 1.50 < .90 23. 107
018 100 1.00 .90 9.02 23. .04 107
1.07 3.01 23. .05 323
NITRILE 019 100 .50 90.18 901.80 23. .06 107
PE 076 100 > 6.00 < .90 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
102 100 .17 30.06 23. .07 323
Nitropropane
253220140 BUTYL 014 118 > 8.00 < .02 23. .04 227
034 UtIle: > 101.00 22. .08 078
NITRILE 019 118 .27 177.35 23. .04 227
033 UNIe .42 . .83 200.40 22. .09 078
NITRILE+PVC 058 100 < .08 9.02 90.18 23. 107
PE 076 100 .OS 9.02 - 90.18 23. 107
PV ALCOHOL 035 UNIe < .08 44.09 22. .02 078
SILVER SHIELO 122 "a > 8.00 23. .01 227
VITON 009 l1a .35 73.41 23. 2.00 227
A-65
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME I RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/eM**2/MIN DEG C eM NUN
1-Nitropropane
001080320 BUTYL 014 118 > 8_00 23. .04 323
NITRILE 019 118 • 20 177.35 23 • .04 323
PV ALCOHOL 102 100 > 15.00 23. .03 323
TEFLON 069 510 > 3.00 < .02 23. .05 303
VITON 009 118 .28 156.91 23. .03 323
2-N i tropropane
000794690 BUTYL 014 118 > 8.00 23. .08 323
NATURAL RUBBER 001 250 .03 192.38 23. .02 323
NEOPRENE 018 100 .n 144.29 23. .04 323
PV ALCOHOL 102 100 > 8.00 23. .06 323
n-Nitrosodimethylamine
000551850 CPE 060 113 •50 23 • .OS 204
.70 438.88 23. .OS 204
Nonyl pheno I
251545230 NEOPRENE 018 100 > 20.00 23. .05 123
NITRILE 019 100 > 4.00 23. .04 123
n-Octane
001116590 NATURAL RUBBER 001 210 •33 120.24 23 • 080
NEOPRENE 002 210 7.00 216.43 23. 080
NITRILE DOS 210 6.00 < .02 23. 080
NITRILE+PVC OS7 210 4.75 n.14 23. 080
PVC 007 210 .92 108.22 23. 080
n-Octanol
290632830 NATURAL RUBBER 001 210 .75 10.22 23. 080
017 100 1.00 < .90 23. .05 107
NEOPRENE 002 100 > 7.00 < .90 23. 107
210 6.00 .02 23. 080
018 100 7.00 < .90 23. .04 107
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 6.00 .90 23. .06 107
NITRILE+PVC 057 210 6.00 < ,02 23. 080
PV ALCOHOL 004 100 4.00 < .90 23. 107
PVC 007 100 > 6.00 .90 23. 107
210 6.00 .02 23. 080
Oleic Acid
001128010 NATURAL RUBBER 017 100 .50 •90 9.02 23 • .05 107
NEOPRENE 002 100 2.50 .90 23. 107
018 100 1.00 .90 9.02 23. .04 107
NITRILE 019 100 > 6.00 < .90 23. .06 107
NITRILE+PVC OS8 100 > 6.00 .90 23. 107
PE 076 100 > 6.00 < .90 23. 107
PV ALCOHOL 004 100 1.00 < .90 23. 107
PVC 007 100 1.50 .90 9.02 23. 107
077 100 > 6.00 < .90 23. 107
> 6.00 .90 23. 107
A-66
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREA(THROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM
Oxal ic Acid
001446270 BUTYL 014 118 > 8.00 < .02 19. .07 323
NATURAL RUBBER 001 210 6.00 < .02 23. 080
017 100 > 6.00 23. .05 107
NEOPRENE 002 100 > 6.00 23. 107
210 6.00 < .02 23. 080
018 100 > 6.00 23. .04 107
> 8.00 < .02 19. .05 323
NITRILE DOS 210 6.00 < .02 23. 080
019 100 > 6.00 23. .06 107
> 8.00 < .02 19. .04 323
NITR I LE+PVC 057 210 6.00 < .02 23. 080
058 100 > 6.00 23. 107
PE 076 100 6.00 23. 107
PVC 007 100 > 6.00 23. 107
210 6.00 < .02 23. 080
077 100 > 6.00 23. 107
> 6.00 23. 107
VITON 009 118 > 8.00 < .02 20. .03 323
Pentachlorophenol
000878650 NEOPRENE 002 100 .10 < .90 23. 107
018 100 .10 < .90 23. .04 107
NITRILE 019 100 > 6.00 < .90 23. .06 107
PV ALCOHOL 004 100 .12 90.18 901.80 23. 107
PVC 007 100 3.00 < .90 23. 107
Pentane
001096600 NATURAL RUBBER 001 210 .05 913.82 23. 080
017 100 .03 2,705.40 25. .03 222
120 .01 5,711.40 25. .02 222
502 .06 1,803.60 25. .05 222
504 .06 1,803.60 25. .05 222
.09 1,603.20 25. .06 222
NEOP+NAT RUBBER 026 102 .07 1,803.60 25. .05 222
NEOP/NAT RUBBER 008 114 .03 2,304.60 25. .05 222
NEOPRENE 002 100 • 75 .90 - 9.02 23 • 107
.11 25.05 25. .08 222
120 .11 24.05 25 • .07 222
210 •50 667.33 23. 080
018 100 .08 .28 . 23. .05 000
.50 90.18 901.80 23. .04 107
118 > 1.00 < 2.00 25. .08 222
120 1.08 10.02 25. .05 222
> 1.00 2.00 25. .07 222
A-67
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEI> C eM NUM
Perchloric Acid
076019030 NATURAL RUBBER 001 210 6.00 < .02 23. 080
IIEOPRENE 002 210 6.00 < .02 23. 080
NITRILE 005 210 6.00 < .02 23. 080
IIITRI LE+PVC 057 210 6.00 < .02 23. 080
058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC 007 210 6.00 < .02 23. 080
077 100 > 6.00 23. 107
> 6.00 23. 107
A-68
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRtouCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS RH
CASNO MATERIAL DESC COOE HOURS UG/CM**2/MIN DEG C eM IIUM
001089520 NATURAL RUBBER 017 502 > 1.67 < 3.01 25. .05 222
504 > 1.00 < 3.01 25. .05 222
> 1.00 < 3.01 25. .06 222
NEOP+NAT RUBBER 026 102 > 1.00 < 3.01 25. .05 222
NEOP/NAT RUBBER 008 114 > 1.00 < 3.01 25. .05 222
NEOPRENE 002 100 > 6.50 < .90 23. 107
> 1.65 < 3.01 25. .08 222
210 .67 23. 080
018 100 3.00 9.02 90.18 23. .04 107
118 > 1.00 < 3.01 25. .oe 222
120 > 1.00 < 3.01 25. .05 222
> 1.00 < 3.01 25. .07 222
> 1.00 < 3.01 25. .05 222
> 1.00 < 3.01 25. .03 222
NITRILE 005 210 .67 23. 080
019 100 .93 300.60 25. .04 222
> 1.00 < 3.01 25. .06 222
.53 300.60 25. .04 222
503 • 60 > 250.50 25 . .03 2U
NITRILE+PVC 057 210 2.00 23. 080
PE 006 100 > 1.00 3.01 25. .01 222
505 1.00 3.01 25. .01 222
PV ALCOHOL 004 100 .50 9.02 90.18 107
PVC 003 . 120 •05 190.38 25 . .01 222
• 13 120.24 2~ . .01 222
.53 n.15 25. .03 222
.25 100.20 25. .02 222
500 • 10 130.26 25 . .01 222
501 • 10 120.24 25 • .01 222
.06 120.24 25. .02 222
007 100 1.25 •90 9.02 23 • 10?
210 1.33 23. 080
TEFLON 069 510 > 3.00 < .02 23. .05 303
Phenol, >70%
001089523 BUTYL 014 118 > 20.00 23. .06 323
20.00 23. .04 227
NEOPRENE 018 100 > 10.67 23. .05 000
125 103 < .02 23. 045
NITRILE 019 103 18.04 23. 045
118 .58 1,274.54 23. .03 323
.65 > 9,018.00 23. .04 221
NITRILE+PVC 058 100 .83 .90 9.02 23. 107
PE 076 100 6.00 < .90 23. 107
PVC 007 103 18.04 23. 045
on 100 .50 .90 9.02 23. 107
1.50 .90 9.02 23. 107
VITON 009 118 > 15.00 23. .03 323
> 15.00 < .02 23. .02 227
Phenolphthalein
000770980 NATURAL RUBBER 017 506 > 8.00 23. .02 323
NEOPRENE 018 100 > 8.00 23. .04 323
A-69
SUMMARY OF PERFORMAICE DETAIL TESTS
PERMEATION TEST
Phosphoric Acid
076643820 IlATURAL IlU8BER 001 210 6.00 < .02 23. 080
1lE000EIIE 002 210 6.00 < .02 23. 080
II ITR ILE 005 210 6.00 < .02 23. 080
IIITRILE+PVC 057 210 6.00 < .02 23. 080
PE 076 127 > 14.00 23. 104
PVC 007 210 6.00 < .02 23. 080
SARAIIEX 061 127 > 14.00 23. 104
1·Piperazineethanallne
001403180 BUTYL 014 118 > 4.00 23. .05 123
1.70
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOORS UG/CM**2/MIN DEG C CM MUM
Proaethazinehydrochloride
000583330 BUTYL 014 118 > 8.00 < .02 19. .06 323
NEOPRENE 018 100 > 8.00 < .02 19. .02 323
NITRILE 019 100 > 8.00 < .02 22. .02 323
PVC 007 100 > 8.00 < .02 20. .05 323
beta'Propiolactone
000575780 NATURAL RUBBER 017 508 .25 .33 4.31 22. .03 078
PE 006 209 .17 .50 1.20 22. .01 078
POLYURETHANE 050 178 < .08 831.66 22. .01 078
Propionaldehyde
001233860 BUTYL 014 118 > 13.00 23. .06 323
A-71
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAICTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**21MIN DEG C
Propionic Acid
000790940 PE 076 127 .OS 1.62 23. 104
TEFLON 069 510 > 3.00 < .02 23. .05 303
propionic Anhydride
001236260 PE 076 127 •08 76.35 23 • 104
Propyl Acetate
001096040 BUTYL 014 118 2.70 17.20 23. .04 227
NATURAL RUBBER 017 100 .08 90.18 901.80 23. .OS 107
NITRILE 019 100 .33 9.02' 90.18 23. .06 107
118 .28 435.87 23. .04 227
PE 076 100 .05 .90 9.02 23. 107
PV ALCOHOL 004 100 2.00 .90 9.02 23. 107
SILVER SHIELD 122 118 > 6.00 23. .01 227
n'Propylamine
001071080 CPE 070 UNIC .15 23. .05 004
TEFLON 069 510 > 10.20 < .02 23. .05 303
Propylenediamine
000789000 BUTYL 014 118 > 8.00 < .02 17. .07 323
NEOPRENE 018 100 > 8.00 < .02 24. .05 323
PVC 007 100 .30 9.02 17. .02 323
VITON 009 118 > 8.00 < .02 25. .02 323
A-72
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS UG/CM**2/MIN DEG C eM NUM
Propylene Glycol
000575560 NATURAL RUBBER 001 503 > 3.00 23. .06 086
017 120 > 3.00 23. .05 086
NEOP/NAT RUBBER 008 114 > 3.00 23. .06 086
NITRILE+PVC 058 100 > 6.00 23. 107
PE 006 512 > 3.00 23. .01 086
076 100 > 6.00 23. 107
PVC 077 100 > 6.00 23. 107
> 6.00 23. 107
Propylene Oxide
000755690 BUTYL 014 118 2.20 42.08 23. .06 323
NATURAL RUBBER 001 506 < .01 1,973.14 23. .02 323
PE 076 100 .05 9.02 . 90.18 23. 107
PV ALCOHOL 004 100 •58 9.02 90.18 23. 107
102 100 .07 •90 23 • .03 323
TEFLON. 069 510 2.28 •02 23 • .03 303
2.83 •02 23 • .05 303
VITON 009 118 .02 10,769.30 23. .03 323
',3'Propylene Oxide
005033000 BUTYL 014 118 1.13 561.12 23. .07 323
NATURAL RUBBER 001 250 < .01 30.06 23. .02 323
PV ALCOHOL 004 100 .17 3.01 23. .03 323
VITON 009 118 .03 30.06 23. .03 323
Propylmethacrylate
022102880 BUTYL 014 118 6.83 48.10 23. .08 323
IIITRILE 019 100 1.00 150.30 23. .04 323
PV ALCOHOL 004 100 > 8.00 < • 02 23 • .07 323
PVC 003 100 .03 462.92 23. .02 323
Pyridine
001108610 NATURAL RUBBER 017 100 .04 701.40 25. .03 222
120 .03 1,202.40 25. .02 222
502 .13 400.80 25. .05 222
504 .20 501.00 25. .05 222
.43 300.60 25. .06 222
IIEOP+NAT RUBBER 026 102 .14 400.80 25. .05 222
IIEOP/IIAT RUBBER 008 114 .23 300.60 25. .05 222
IIEOPREIIE 002 100 .65 200.40 25. .08 222
120 .03 701.40 25. .07 222
018 118 .85 400.80 25. .08 222
120 .33 901.80 25. .05 222
.63 601.20 25. .07 222
.43 701.40 25. .05 222
.07 1,703.40 25. .03 222
NITRILE 019 100 .18 3,206.40 25. .04 222
.25 3,006.00 25. .06 222
•16 3,507.00 25 • .04 222
181 .09 4,0011,00 25. .03 222
503 .17 2,404.80 25. .03 222
A-73
SUMMARY OF PERFORMANCE DETAIL TESTS
PEIlNEATlON TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE IIClJRS UG/CM**21MIII OEG C CM NUM
001108610 PE 006 100 > 1-(10 < 100.20 25. .01 222
505 > 1_00 < 10.02 25. .01 222
Sodiln Hydroxide
013107320 CPE 060 113 > 3_00 25. .07 302
NITRllE+PVC 058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC 077 100 > 6.00 23. 107
> 6.00 23. 107
SILVER SHIElD 122 118 > 6_00 23. .01 227
VITON/CHlOROBUTYl 112 113 > 3_00 25. .04 302
015
017
....
117
210
100
>
>
>
>
8.00
6_00
1.00
1.00
6.00
< .02
23.
23.
23.
23.
23.
.02
.04
.05
213
080
052
052
107
NEOP/NAT RUBBER OOIS UNIC > 1.00 23. 052
IIEOPREIIE 002 100 > 6.00 23. 107
210 6.00 < .02 23. 080
018 100 > 6.00 23. .04 107
UNIe > 1.00 23. .09 052
> 1.00 23. .06 052
093 117 > 8.00 23. .02 213
138 117 > 8.00 23. .03 213
139 117 > 8.00 23. .01 213
IIEOPRENE+PVC 127 117 > 8.00 23. .02 213
IIITRllE 005 210 6.00 < .02 23. 080
019 100 > 6.00 23. .06 107
UNK > 1.00 23.- .05 052
IIITRllE+PVC 057 210 6.00 < .02 23. 080
058 117 > 8.00 23. .01 213
tIONWOVElI PE 071 127 < .17 .63 23. 104
PE 076 117 > 8.00 23. .01 213
127 > 8.00 < .02 23. 104
PVC 003 UNK > 1.00 23. .02 052
007 100 > 6.00 23. 107
210 6.00 < .02 23. 080
UNK > 1.00 23. 052
049 117 > 8.00 23. .01 213
> 8.00 23. .01 213
A-74
SUMMARY OF PERFORMANCE ~E1AIL TESTS
PERMEATION TEST
CHEMI::AL NAME; RE~ISTANT PROOUC"r VENOOR BREAKTHROUGH liME PERMEATION R~, TEMP THIC"HE~:' "to
CASNO MATERIAL DESC COOE HWRS UG/CM**Z/MIN OEG C CM NUk
Styrene
001004250 CPE 060 113 1.00 • 1.17 25. .07 302
NATURAL RUBBER 001 210 .17 348.70 23. 080
NEOPRENE 002 210 .20 517.03 23. 080
125 103 30.06 23. 045
JUTRILE OOS 210 .50 733.46 23. 080
019 103 456.91 23. 045
NITRILE+PVC 057 210 .67 186.37 23. 080
058 100 . 07 9.02 90.111 23 . 107
PE 076 100 .17 9.02 90.111 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
PVC 007 103 156.31 23. 045
210 •33 216.43 23 • 080
SARAIIEX 061 127 .n 69.74 23 • 104
TEFLON 069 510 > 4.00 < .02 23. .05 303
VITON/CHLOROBUTYL 112 113 > 3.00 25. .04 302
Sulfuric Acid
076649390 BUTYL 064 117 > 8.00 23. .02 213
> 8.00 23. .01 213
> 8.00 23. .02 213
BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213
CPE 060 113 > 3.00 25. .07 302
070 UNIC > 3.00 23. .05 004
NATURAL RUBBER 001 210 1.D 23. 080
NEOP+NAT RUBBER 026 121 1.5] 462.92 23. .05 237
NEOPRENE 002 210 2.50 23. 080
093 117 1.17 23. .02 213
138 117 2.25 23. .03 213
139 117 3.67 23. .02 213
NEOPRENE+PVC 127 117 1.33 23. .02 213
NITRILE OOS 210 6.00 < .02 23. 080
NITRILE+PVC 057 210 4.00 23. 080
058 117 .42 23. .01 213
NONWOVEN PE 071 127 < .08 3,006.00 23. 104
PE 076 117 > 8.00 23. .01 213
PVC 007 210 1.75 23. 080
A-75
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATlOli TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UGfCM*·21MIIi DEG C CM NUM
A-76
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM
Tamic Acid
014015540 NITRILE+PVC 058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC 077 100 > 6.00 23. 107
> 6.00 23. 107
1,1,2,2-Tetrachloroethane
000793450 BUTYL 014 118 4.60 70.14 23. .07 323
NATURAL RUBBER 017 100 .11 2,605.20 25. .03 222
120 .03 5,611.20 25. .02 222
502 .09 2,905.80 25. .05 222
504 .17 1,402.80 25. .04 222
.35 1,302.60 25. .06 222
NEOP+NAT RUBBER 026 102 .15 3,206.40 25. .05 222
NEOPRENE 002 100 .10 501.00 25. .08 222
120 .09 601.20 25. .07 222
018 118 > 1.07 < 20.04 25. .08 222
120 .53 1,102.20 25. .05 222
.83 1,002.00 25. .07 222
.30 1,402.80 25. .05 222
.16 2,204.40 25. .03 222
NITRILE 019 100 .37 3,206.40 25. .04 222
1.23 > 300.60 25. .06 222
.22 3,106.20 25. .04 222
503 .32 2,204.40 25. _03 222
PE 006 100 .07 10.02 25. .01 222
114 .31 1,402.80 25. .05 222
505 > 1.00 < 2.00 25. _01 222
PV ALCOHOL 004 100 > 8.00 < .02 23. _04 323
PVC 003 120 .02 5,410.80 25. _01 222
.02 6,012.00 25. _01 222
.10 2,505.00 25. .03 222
)..-77
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATlOII TEST
CHEMICAL NAMEI RESISTANT PRODUCT VEIIDOR BREAIClHROOGH TINE PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE IIOORS UG/CM**2/MIN DEG C CM lUI
Tetrachloroethylene (Perchloroethylene)
001271840 BUTYL 014 118 • 17 > 751.50 23 • .04 291
• 17 > 751.50 23 • .04 291
.13 895.12 25. .04 Z88
UIIIC • 13 895.79 23 • .04 100
CPE 070 UIIIC 1.07 23. .05 004
NATURAL RUBBER 001 210 • 10 601.20 23 • 080
017 UIIIC < .02 > 751.50 23. .02 291
< .02 > 751.50 23. .02 291
NEOP+tIAT RUBBER 026 121 .05 1,478.95 23. .05 237
NEOPRENE 002 210 .12 571.14 23. 080
010 100 .20 980.29 25. .05 288
018 100 .10 > 641.28 23. .04 291
.13 > 641.28 23. .04 291
UIIIC .20 979.96 23. .05 100
NITRILE 005 210 4.00 6.01 23. 080
019 100 5.00 •90 • 9.02 23 • .06 107
118 1.28 33.07 23. .04 323
1.30 33.07 23. .04 227
UIIIC 3.52 28.26 23. .03 100
020 100 3.52 28.22 25. .03 Z88
191 7.25 47.09 23. .04 291
5.33 41.08 23. .04 291
MITRILE+PVC 057 210 6.20 90.18 23. 080
058 100 • 08 90.18' 901.80 23 • 107
PE 006 100 < .02 > 686.37 23. .01 291
< .02 > 686.37 23. .01 291
< • 02 769.87 25 • .01 288
UIIIC < •02 769.54 23 • .01 100
076 100 • 08 90.18' 901.80 23 • 107
PV ALCOHOL 004 100 5.00 < .90 23. 107
102 100 > 16.00 23. .04 323
.60 2.00 23. .05 291
• 35 11.62' 23 • .05 291
.80 1.20 23. .05 291
> 6.00 25. .05 288
UIIIC > 8.00 23. .05 100
PVC 003 100 < .01 180.96 23. .02 323
118 < .02 744.82 25. .01 288
UIIIC < .02 745.49 23. .01 100
007 210 .75 114.23 23. 080
SARAIIEX 061 127 .27 1.14 23. 104
.08 10.02 23. .02 291
• 03 20.04 23 . .02 291
SILVER SHIELD 122 118 > 6.00 23. .01 227
A-78
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM
Tetraethylenepentemine
001125720 BUTYL 012 118 > 8.00 25. .09 323
NATURAL RUBBER 017 506 1.77 12.02 28. .02 323
NEOPRENE 018 100 > 8.00 27. .05 323
VITON 009 118 > 8.00 23. .04 323
Tetrafluoroethylene
001161430 BUTYL 014 118 > 8.00 23. .06 323
NEOPRENE 018 100 > 8.00 23. .06 323
PV ALCOHOL 102 100 > 8.00 23. .03 323
VITON 009 118 > 8.00 23. .03 323
Tetrahydrofuran
001099990 BUTYL 014 118 .45 671.54 23. .07 323
.52 673.34 23. .04 227
064 117 .12 23. .02 213
.10 23 • .01 213
•08 23. .02 213
BUTYL/NEOPRENE 110 117 < .08 23. .02 213
CPE 060 113 .45 • .05 25. .07 302
070 UNK .20 23. .05 004
NATURAL RUBBER 017 100 .04 >16,699.98 25. .03 222
120 .02 >16,699.98 25. .02 222
502 .06 > 16,699.98 25. .05 222
504 .04 3,507.00 25. .05 222
.11 2,404.80 25. .06 222
NEOP+NAT RUBBER 026 102 .06 > 16,699.98 25. .05 222
NEOPINAT RUBBER DDS 114 .02 > 16,699.98 25.· .05 222
NEOPRENE 002 100 .03 8,016.00 25. .08 222
120 .02 9,619.20 25. .07 222
018 118 .33 9,018.00 25. .08 222
120 .09 16,032.00 25. .05 222
.23 11,022.00 25. .07 222
.08 14,028.00 25. .05 222
.05 > 16,699.98 25. .03 222
D93 117 .03 23. .02 213
125 103 829.66 23. 045
138 117 < .08 23. .03 213
A-79
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST
CHEMICAL NAME/
CASNO
RESISTANT
MATERIAL
PRODUCT VENDOR
DESC CODE
BREAKTHROUGH TIME
HOURS
PERMEATION RATE
UG/CM**2/MIN DEG C eM ...
TEMP THICKNESS REf
N,N,N',N'·TetramethylenedfaMine
001101890 BUTYL 012 118 1.08 48.10 20. .07 323
014 118 1.08 48.10 23. .07 323
IIITRILE 019 100 1.80 90.18 23. .05 323
1.80 90.18 24. .05 323
PVC 003 100 .03 1,923.84 23. .02 323
VITON 009 118 .43 1,725.44 23. .04 323
.43 1,725.44 24. .04 323
Thiophenol (Benzenethiol)
001089850 BUTYL 014 118 .28 2,024.04 21. .05 124
PV ALCOHOL 004 100 > 4.00 21. 124
Toluene
001088830 BUTYL 012 UNIC .17 273.55 25. .04 273
.n 254.31 25. .04 273
.50 2n.75 25. .06 273
.50 276.55 25. .06 273
.17 267.53 25. .04 273
.25 304.81 25. .04 273
.50 281.36 25. .06 273
.67 251.30 25. .06 273
.17 245.29 25. .04 273
.17 253.71 25. .04 273
.33 300.60 25. .06 273
A-80
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE .EMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM
A-81
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME I RESISTANT PRODUCT VENDOR B~EAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOORS UG/CM**2/MIN DEG C eM NUM
A-82
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM
Toluene Diisocyanate
264716250 BUTYL 014 118 > 8.00 23. .04 323
> 8.00 23. .04 227
CPE 070 UNIC > 3.00 23. .05 004
NATURAL RUBBER 017 100 • 12 9.02 . 90.18 23. .05 107
NITRILE 005 120 > 8.00 23. .06 236
019 118 3.86 10.82 23. .03 323
3.70 10.82 23. .04 227
PE 076 100 1.00 .90 • 9.02 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
102 100 > 16.00 23. .03 323
SILVER SHIELD 122 118 > 8.00 23. .01 227
TEFLON 069 510 > 3.30 < .02 23. .05 303
VITON 009 118 > 16.00 23. .03 323
> 16.00 23. .02 227
p'Toluenesulfonic Acid
001041540 CPE 070 UNK > 3.00 23. .05 004
NEOPRENE 018 100 > 4.00 23. .05 123
PVC OOJ 215 > 4.00 23. .05 123
o'Toluidine
000955340 TEFLON 069 510 > 3.30 < .02 23. .05 303
Triallylamine
001027050 NEOPRENE 018 100 1.05 561.12 19. .05 323
NITRILE 019 100 > 8.00 < .02 22. .04 323
PVC 007 100 .08 621.24 20. .02 323
VITON 009 118 > 8.00 < .02 17. .03 323
Trichloroacetaldehyde (Chloral)
000758760 BUTYL 014 118 3.32 50.10 23. .07 323
PV ALCOHOL 102 100 > 8.00 < .02 23. .08 323
PVC 007 100 .07 2,845.68 23. .02 323
A-B3
SUMMARY OF PERFORMANCE DETAIL TeSTS
PERMEATION TEST
CHEMICAL NAME! RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS UG!CM**2/MIN DEG C eM NUM
000758760 VITON 009 118 7.28 < .02 23. .03 323
Trichloroacetonitrile
005450620 BUTYL 014 118 1.98 316.23 23. .06 323
IIEOPRENE 018 100 1.12 927.65 23. .06 323
PV ALCOHOL 102 100 > 8.00 23. .06 323
VITOII 009 118 1.00 184.57 23. .03 323
1,Z,4'Trichlorobenzene
001208210 BUTYL 014 UNK .08 23. .04 290
.08" 23. .04 290
IIATURAL RUBBER 017 UNK .08 23. .02 290
.08 23. .02 290
1lE000ENE 010 UNK 4.00 23. .03 290
5.00 23. .03 290
018 UNK 1.00 23. .04 290
PE 006 UNK .17 23. .01 290
.17 23. .01 290
076 127 < .25 5.01 23. 104
PV ALCOHOL 102 UNK 1.00 23. .05 290
1.00 23. .05 290
SARANEX 061 127 .25 . 1.00 •10 23 • 104
UNK 1.00 23. .02 290
1.00 23. .02 290
TEFLON 036 UNK 1.00 23. .01 290
8.00 23. .01 290
VITON 009 UNK .17 23. .02 290
.17 23. .02 290
1,l,2'Trichloroeth_
000790050 BUTYL 014 118 5.78 42.08 23. .09 323
UNK .83 23. .06 326
064 UNK .75 23. .04 326
IIATlIIAL RUBBER 017 lINK .02 23. .02 326
IIEOPRENE 018 UNK .12 23. .06 326
IIITRILE 019 utlK .03 23. .02 326
PE 042 UNK .06 23. .01 326
POL \'URETHANE 050 UNK < .02 23. .01 326
PV ALCOHOL 102 100 > 8.00 23. .07 323
UNK .25 23. .04 326
PVC 003 118 .03 1,238.47 23. .02 323
TEFLON 036 UNK > 24.00 23. .01 326
044 UNIe 2.92 23. .01 326
VITON 009 118 > 8.00 23. .05 323
UNK > 24.00 23. .03 326
2,2,2' Trichloroethanol
001152080 SARANEX 061 127 .32 13.23 23. 104
Trichloroethylene (Trichloroethene)
000790160 BUTYL 014 118 .23 3,308.40 23. .06 323
.08 > 826.65 23. .04 291
.08 > 826.65 23. .04 291
A-84
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C eM HUM
A-85
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME I RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEJIP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/eM**2/MIN DEG C eM NUM
1,2,3·Trichloropropene
000961840 BUTYL 014 118 > 8.00 < .02 23. .06 323
NITRILE 019 100 •35 20.04 23 • .04 323
PVALCOHOl 004 100 > 8.00 < .02 23. .03 323
VITON 009 118 > 8.00 < .02 23. .03 323
A-86
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATIOH RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN OEG C CM NUM
013307850 NITRILE 019 100 > 6.00 < .90 23. .06 107
NITRILE+PVC 058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
> 8.00 23. .08 323
PVC 003 100 > 8.00 23. .02 323
007 100 > 6.00 < .90 23. 107
on 100 > 6.00 23. 107
> 6.00 23. 107
VITON 009 118 > 8.00 23. .04 323
Triethanolamine
001027160 NITRILE+PVC 058 100 > 6.00 21. 107
PE 076 100 > 6.00 23. 107
PVC on 100 > 6.00 23. 107
> 6.00 23. 107
Triethanolamine, >7OX
001027163 NATURAL RUBBER 017 100 1.00 < .90 21. .OS 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
018 100 > 6.00 < .90 21. .04 107
NITRILE 019 100 > 6.00 < .90 23. .06 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
PVC 007 100 > 6.00 < .90 21. 107
Triethylllline
001214480 CPE 070 lINlC > 3.00 21. .os 004
NEOPRENE 018 100 .62 811.62 20. .05 323
NITRILE 019 118 > 8.00 < .02 19. .04 323
020 216 > 4.00 21. .04 123
PVC 007 100 .07 290.58 20. .02 323
VITON 009 118 > 8.00 < .02 24. .03 323
TriethyLenetetraaaine
001122430 BUTYL 014 118 > 8.00 < .02 20. .06 323
NEOPRENE 018 100 > 8.00 < .02 19. .05 323
NITRILE 019 100 > 8.00 < .02 16. .04 323
VITON 009 118 > 8.00 < .02 20. .03 323
Trifluoroethanol
000758980 NATURAL RUBBER 017 100 > 1.00 < 4.01 25. .03 222
120 > 1. 10 < 4.01 25. .02 222
502 > 1.33 < 4.01 25. .05 222
504 > 1.07 < 4.01 25. .05 222
> 1.65 < 4.01 25. .06 222
NEOP+NAT RUBBER 026 102 > 1.65 < 4.01 25. .05 222
NEOP/NAT RUBBER 008 114 > 1.02 < 4.01 25. .05 222
NEOPRENE 002 100 > 1.00 < 4.01 25. .08 222
120 > 1.00 < 4.01 25. .07 222
018 118 > 1.00 < 4.01 25. .08 222
120 1.00 < 4.01 25. .05 222
> 1.00 < 4.01 25. .07 222
> 1.00 < 4.01 25. .05 222
A-87
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEtI' THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**Z/MIN DEG C CM NUt
000758980 NEOPRENE 018 120 > 1.00 < 4.01 25. .03 222
NITRILE 019 100 .33 1,903.80 25. .04 222
.97 1,102.20 25. .06 222
.28 2,304.60 25. .04 222
503 .12 3,106.20 25. .03 222
PE 006 100 > 1.00 < 4.01 25. .01 222
505 > 1.00 < 4.01 25. .01 222
076 127 > 8.00 < .02 23. 104
PVC 003 120 .os 1,202.40 25. .01 222
.12 1,903.80 25. .01 222
.25 1,302.60 25. .03 222
.11 1,102.20 25. .02 222
500 .04 1,002.00 25. .01 222
501 .07 300.60 25. .01 222
.05 901.80 25. .02 222
Tri·n·propylamine
001026920 NEOPRENE 018 100 > 8.00 23. .05 323
NITRILE 019 100 > 8.00 23. .04 323
PV ALCOHOL 102 100 > 8.00 23. .06 323
VITON 009 118 > 8.00 23. .04 323
Turpentine
OS0066420 NEOP+NAT RUBBER 026 121 .07 264.53 23. .05 237
NITRILE 019 100 .50 < .90 23. .06 107
PV ALCOHOl 004 100 6.00 < •90 23 • 107
TEFLON 069 510 > 3.60 < .02 23. .05 303
valeronltri le
001105980 BUTYL 014 118 > 8.00 < •02 23 • .07 323
NATURAL RUBBER 017 506 .03 126.25 23. .02 323
NEOPRENE 018 100 .68 126.25 23. .05 323
PV ALCOIIOL 004 100 > 8.00 < •02 23 • .07 323
Vinyl Acetate
001080540 TEFLON 069 510 1.23 •05 23 • .05 303
2.28 •05 23 • .05 303
4·Vinyl·1·cyclohexane
001004030 BUTYL 012 118 .52 354.71 23. .07 323
NITRILE 019 100 6.53 1.20 23. .04 323
PV ALCOHOL 004 100 .90 23. .09 323
VITON 009 118 > 8.00 23. .04 323
A-8S
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REf
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM
000753870 NATURAL RUBBER 001 250 < .02 6.01 23. .02 323
NEOPRENE 018 100 > 5.00 23. .05 323
< .02 .37 23. .05 323
PVC 003 100 < .02 1.80 23. .02 323
VITON 009 118 > 8.00 23. .04 323
Xylene
001332070 NATURAL RUBBER 001 210 .12 444.89 23. 080
017 100 .04 3,406.80 25 • .03 222
120 • 02 5,811.60 25. .02 222
502 .08 3,707.40 25. .05 222
504 .08 2,805.60 25. .05 222
.13 2,404.80 25. .06 222
NEOP+NAT RUBBER 026 102 .07 30.06 23. .06 026
.07 30.06 23. .05 026
NEOP/NAT RUBBER 008 102 .07 30.06 23. 026
114 .12 2,505.00 25. .05 222
NEOPRENE 002 100 .06 501.00 25. .08 222
120 .05 601.20 25. .07 222
210 .13 408.82 23. 080
018 118 .73 701.40 25. .08 222
120 .23 1,302.60 25. .05 222
.30 1,402.80 25. .07 222
.38 801.60 25. .05 222
.09 3,406.80 25. .03 222
031 511 .27 492.98 23. 323
125 103 30.06 23. 045
NITRILE 005 210 1.67 300.60 23. 080
019 100 .80 100.20 25. .04 222
1.25 90.18 • 901.80 23. .06 107
> 1.00 < 50.10 25. .06 222
.95 100.20 25. .04 222
.45 168.34 23. .05 323
103 84.17 23. 045
503 .47 300.60 25. .03 222
NITRILE+PVC 057 210 .75 330.66 23. 080
058 100 > .05 9.02 90.18 23. 107
PE 006 505 .07 100.20 25. .01 222
076 100 .08 9.02 90.18 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
102 100 > 8.00 23. .09 323
PVc 003 100 .02 192.38 23. .02 323
120 .03 3,006.00 25. .01 222
.02 3,507.00 25. .01 222
.08 1,703.40 25. .02 222
500 .01 4,509.00 25. .01 222
501 .01 3,507.00 25. .01 222
.03 2,104.20 25. .02 222
007 103 n.14 23. 045
210 .66 389.11 23. 080
TEFLON 069 510 > 3.00 < .02 23. .05 303
VITON 009 118 > 8.00 23. .04 323
A-89
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST
CHEMICAL IIAME/ RESISTANT PRODUCT VEIIDQR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASIIO MATERIAL DESC COOE HOURS UG/CM**2!MIN DEC C CM NUM
..-Xylene
001083830 BUTYl 014 118 _65 87.78 23. .06 323
.17 228.79 23. .05 086
NEOPRENE 018 100 .23 198.55 23. .06 086
NITRILE 019 100 1.03 188.78 23. .04 323
1.62 n.14 23. .06 086
118 .27 396.79 23. .04 086
120 .65 198.73 23. .05 086
020 503 •55 180.36 23 • .04 086
PY ALCOIIOl 102 100 > 12.67 23. .03 323
VITON 009 118 > 16.00 23. .03 323
8.00 23. .04 086
o-Xylene
000954760 BUTYL 014 118 .87 116.63 23. .07 323
CPE 060 113 1.20 23. .05 204
1.05 186.37 23. .05 204
IIITItILE 019 100 .20 179.76 23. .04 323
PV ALCOHOL 102 100 > 12.67 23. .03 323
VITON 009 118 > 8.00 23. .03 323
p-Xylene
001064230 BUTYl 014 118 .45 90.78 23. .07 323
II ITR IlE 019 100 .87 85.97 23. .04 323
PV ALCOtIOL 102 100 > 14.00 23. .03 323
PVC 003 100 < .01 185.17 23. .02 323
YITON 009 118 > 16.00 23. .03 323
A-90
APPENDIX B
B-1
SUMMARY OF PERFORMANCE DETAil TESTS
IMMERSION UEIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM
Acetic Acid
000641970 CPE 060 113 27.00 24.00 23. .05 204
28.00 24.00 23. .05 204
31.00 24.00 23. .05 204
NATURAL RUBBER 001 UNK '1.00 1.00 25. 208
NEOPRENE 002 UNK 4.00 1.00 25. 208
NITRILE 005 UNK '2.00 1.00 25. 208
Acetic Anhydride
001082470 BUTYL 014 118 1.00 8.00 23. .09 323
CPE 060 113 6.10 24.00 23. .05 204
2.70 24.00 23. .05 204
8.20 24.00 23. .05 204
NATURAL RUBBER 001 250 4.00 8.00 20. .02 323
NEOPRENE 018 100 16.00 8.00 20. .05 323
PVC 007 100 -12.00 8.00 20. .02 323
Acetone
000676410 BUTYL 014 UNK .90 24.00 22. 201
CPE 060 113 50.00 .58 23. .05 204
58.00 .25 23. .05 204
64.00 .25 23. .05 204
NATURAL RUBBER 001 120 3.00 .08 23. .05 236
4.00 .50 23. .05 236
B-2
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM
000676410 NATURAL RUBBER 001 120 4.00 1.00 23. .05 236
3.00 4.00 23. .05 236
UNK ·2.00 1.00 25. 208
017 UNK ·2.00 24.00 22. 201
NEOPRENE 002 UNK -3.00 1.00 25. 208
010 120 1.00 •08 23 • .06 236
7.00 .50 23. .06 236
8.00 1.00 23. .06 236
4.00 4.00 23. .06 236
018 UNK -1.40 24.00 22. 201
- .30 24.00 22. 201
-8.00 24.00 22. 201
-.70 24.00 22. 201
NITRILE 005 120 9.00 4.00 23. .06 236
55.00 1.00 23. .06 236
32.00 • 50 23 • .06 236
17.00 .08 23. .06 236
UNK -3.00 1.00 25. 208
020 UNK 2.70 24.00 22. 201
PE 041 UNK 1.00 8,760.00 23. 305
042 UNIC 1.20 8,760.00 23. 305
048 UNK 1.20 8,760.00 23. 305
PV ALCOHOL 102 UNK -15.70 24_00 22. 201
PVC 003 120 2.00 4.00 23. .08 236
29.00 1.00 23. .08 236
30.00 •50 23 • .08 236
14.00 .08 23. .08 236
UNK -16.10 24.00 22. 201
Acetonitrile
000750580 NEOPRENE 010 120 < .01 .08 23. .06 236
1.00 .50 23. .06 236
< .01 1.00 23. .06 236
1.00 4.00 23. .06 236
Allylamine
001071190 BUTYL 014 118 15.00 8.00 20. .06 323
NATURAL RUBBER 001 250 34.00 8.00 20. .01 323
PV ALCOHOL 102 100 14.00 8.00 23. .07 323
PVC 007 100 ·6.00 8.00 20. .02 323
B-3
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS DEG C CM NUM
013362161 NATURAL RUBBER 001 120 1.00 4.00 23. .05 236
1.00 1.00 23. .05 236
< .01 .50 23. .05 236
< .01 . 08 23 • .05 236
NEOPRENE 010 120 1.00 •08 23 • .06 236
< .01 .50 23. .06 236
1.00 1.00 23. .06 236
1.00 4.00 23. .06 236
NITRILE 005 120 2.00 4.00 23. .06 236
2.00 1.00 23. .06 236
1.00 .50 23. .06 236
1.00 .08 23. .06 236
PVC 003 120 < .01 .08 23. .08 236
1.00 •50 23 • .08 236
1.00 1.00 23. .08 236
1.00 4.00 23. .08 236
Benzene
000714320 BUTYL 014 118 117.00 168.00 23. 327
B-4
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CAS NO MATERIAL DESC CODE HOURS DEG C CM NUM
Boric Acid
100433530 BUTYL 014 118 2.00 8.00 20. .07 323
NEOPRENE 018 100 2.00 8.00 19. .05 323
NITRILE 019 100 2.00 8.00 21. .04 323
VITON 009 118 .20 8.00 20. .03 323
2· Bromoethanol
005405120 BUTYL 014 118 .20 8.00 23. .09 323
NATURAL RUBBER 001 250 2.00 8.00 23. .02 323
PVC 003 100 •• 20 8.00 23. .02 323
VITON 009 118 .60 8.00 23. .05 323
Butyl Acetate
B-5
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION ~EIGHT CHANGE TEST
CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT ~IGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM
Butylamine
001097390 BUTYL 014 118 62.00 8.00 15. .10 323
NATURAL RUBBER 001 250 148.00 8.00 20. .02 323
NEOPRENE 018 100 166.00 8.00 18. .05 323
PVC 007 100 62.00 8.00 18. .02 323
sec'Butylamine
139528460 BUTYL 014 118 83.00 8.00 21. .09 323
NEOPRENE 018 100 122.00 8.00 25. .05 323
NITRILE 019 100 108.00 8.00 14. .04 323
PVC 007 100 ·4.00 8.00 24. .02 323
tert'Butylamine
000756490 BUTYL 014 118 23.00 8.00 15. .09 323
NEOPRENE 018 100 55.00 8.00 23. .05 323
NITRILE 019 100 69.00 8.00 21. .04 323
PVC 007 100 ·20.00 8.00 20. .02 323
Butyraldehyde
001237280 BUTYL 034 UNK 7.70 3.00 25. 126
12.50 20.00 25. 126
B-6
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM
Chlorobenzene
001089070 BUTYL 014 118 169.00 8.00 23. .07 323
PV ALCOHOL 102 100 ·4.00 8.00 23. .08 323
PVC 007 100 101.00 8.00 23. .02 323
VITON 009 118 2.00 8.00 23. .03 323
Chlorodibromomethane
001244810 BUTYL 012 118 382.00 8.00 23. .10 323
PV ALCOHOL 004 100 ·.30 8.00 23. .07 323
PVC 003 100 385.00 8.00 23. .02 323
VITON 009 118 1.00 8.00 23. .04 323
Chloroform (Trichloromethane)
000676630 BUTYL 034 UNK 9.00 3.00 25. 126
NEOPRENE 010 120 23.00 .08 23. .06 236
39.00 .50 23. .06 236
110.00 1.00 23. .06 236
35.00 4.00 23. .06 236
PE 041 UNK 12.00 8,760.00 23. 305
042 UNK 16.20 8,760.00 23. 305
048 UNK 25.10 8,760.00 23. 305
3·Chloro·2·methylpropene
005634730 BUTYL 014 118 142.00 8.00 23. .06 323
PV ALCOHOL 004 100 28.00 8.00 23. .04 323
PVC 007 100 2.00 8.00 23. .02 323
VIT ON 009 118 7.00 8.00 23. .03 323
2· Chloro·2·ni tropropane
005947180 BUTYL 012 118 2.00 8.00 23. .09 323
NATURAL RUBBER 017 506 94.00 8.00 23. .02 323
PV ALCOHOL 004 100 '.80 8.00 23. .07 323
VITON 009 118 70.00 8.00 23. .04 323
B-7
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAME! RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS DEG C eM MUM
111157452 PVC 003 120 < .01 .08 23. .08 236
Cyclohexylamine
001089180 BUTYL 014 118 95.00 8.00 20. .06 323
NATURAL RUBBER 001 250 299.00 8.00 20. .02 323
NEOPRENE 018 100 294.00 8.00 22. .05 323
NITRILE 019 100 247.00 8.00 24. .04 323
Diall yamine
001240270 BUTYL 014 118 44.00 8.00 21. .09 323
PV ALCOHOL 004 100 '20.00 8.00 23. .08 323
PVC 007 100 '26.00 8.00 22. .02 323
VITON 009 118 4.00 8.00 19. .03 323
1,3'Oiaminopropane
001097620 BUTYL 014 118 30.00 8.00 22. .06 323
NATURAL RUBBER 001 250 18.00 8.00 25. .02 323
NEOPRENE 018 100 22.00 8.00 23. .05 323
PVC 007 100 24.00 8.00 21. .02 323
Oi ·n·amylami ne
020509220 NEOPRENE 018 100 74.00 8.00 16. .OS 323
NITRILE 019 100 2.00 8.00 20. .04 323
PVC 007 100 '23.00 8.00 13. .02 323
VITON 009 118 .20 8.00 16. .03 323
Oichloroacetyl Chloride
000793670 BUTYL 014 118 164.00 8.00 23. .09 323
PV ALCOHOL 102 100 '8.00 8.00 23. .07 323
PVC 003 100 230.00 8.00 23. .02 323
VITON 009 118 '9.00 8.00 23. .03 323
Oichlorobromomethane
000752740 BUTYL 014 118 347.00 8.00 23. .07 323
PVC 007 100 328.00 8.00 23. .02 323
VITON 009 118 2.00 8.00 23. .03 323
VITON!BUTYL 100 102 '2.00 8.00 23. .08 323
1,4·Oichloro·2·butene
001105760 BUTYL 034 UNIC 19.00 20.00 25. 126
17.00 3.00 25. 126
cis'Oichloroethylene
001565920 BUTYL 014 118 198.00 8.00 23. .07 323
PV ALCOHOL 004 100 358.00 8.00 23. .05 323
VITON 009 118 9.00 8.00 23. .03 323
l,2'Oichloroethylene
B-8
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENOOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HooRS DEG C eM NUM
trans' 1,2'Oichloroethylene
001566050 BUTYL 014 118 3.00 8.00 23. .06 323
PV ALCOHOL 004 100 '30.00 8.00 23. .09 323
PVC 007 100 '7.00 8.00 23. .02 323
VITON 009 118 8.00 8.00 23. .03 323
2,2"Oichloroethyl Ether
001114440 BUTYL 034 UNK 11.00 20.00 25. 126
3.80 3.00 25. 126
CPE 060 113 129.00 .83 23. .05 204
125.00 .83 23. .05 204
123.00 •83 23 • .05 204
2,3·Oichloro·1·propene
000788860 BUTYL 014 118 66.00 8.00 23. .09 323
PV ALCOHOL 102 100 2.00 8.00 23. .09 323
PVC 007 100 76.00 8.00 23. .02 323
VITON 009 118 4.00 8.00 23. .03 323
1,3-0ichloropropene
005427560 BUTYL 014 118 65.00 8.00 23. .07 323
PV ALCOHOL 102 100 '2.00 8.00 23. .07 323
PVC 007 100 199.00 8.00 23. .02 323
VITON 009 118 3.00 8.00 23. .03 323
Oiethanolamine
001114220 BUTYL 014 118 2.00 8.00 24. .09 323
NEOPRENE 018 100 5.00 8.00 22. .05 323
NITRILE 019 100 14.00 8.00 26. .04 323
VITON 009 118 3.00 8.00 27. .03 323
Diethylamine
001098970 BUTYL 014 118 88.00 8.00 23. .09 323
NITRILE 019 100 55.00 8.00 24. .04 323
PVC 001 100 '26.00 8.00 24. .02 323
VITON 009 118 83.00 8.00 20. .03 323
Diethylaminoethanol
001003780 BUTYL 014 118 2.00 8.00 22. .07 323
NITRILE 019 118 12.00 8.00 22. .04 323
PV ALCOHOL 102 100 '19.00 8.00 23. .09 323
VITON 009 118 5.00 8.00 22. .03 323
Diethylenetriamine
001114000 BUTYL 014 118 8.00 8.00 24. .08 323
NEOPRENE 018 100 12.00 8.00 22. .05 323
PVC 007 100 19.00 8.00 22. .02 323
VIT ON 009 118 8.00 8.00 23. .03 323
B-9
SUMMARY OF PERFORMANCE DETAil TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HooRS DEG C CM NlI4
Oiisobutylamine
001109630 NEOPRENE 018 100 57.00 8.00 22. .05 323
NITRilE 019 100 -1.00 8.00 20. .04 323
PV ALCOHOL 102 100 4.00 8_00 23. .08 323
VITON 009 118 -2.00 8.00 22. .02 323
Oiisopropylamine
001081890 NEOPRENE 018 100 51.00 8.00 12. .05 323
NITRilE 019 100 6.00 8.00 10. .04 323
PVC 007 100 -23.00 8.00 11. .02 323
VITON 009 118 1.00 8.00 12. .03 323
N,N-Oimethylacetamide
001271950 NATURAL RUBBER 001 120 18.00 4.00 23. .05 236
15.00 1.00 23. .05 236
21.00 .50 23. .05 236
32.00 •OS 23 • .05 236
NEOPRENE 010 120 36.00 4.00 23. .06 236
12.00 1.00 23. .06 236
12.00 .50 23. .06 236
5.00 •08 23 • .06 236
005 _OS 23 _
NITRILE 120 18.00 .06 236
53.00 • 50 23 • .06 236
21.00 1.00 23. .06 236
186.00 4.00 23. .06 236
oimethyl ami ne
001244030 BUTYL 014 118 .80 8.00 22. .06 323
NATURAL RUBBER 001 250 10.00 8.00 20. .02 323
NEOPRENE 018 100 12.00 8.00 22. .05 323
PV ALCOHOL 102 100 '6.00 8.00 23. .07 323
PVC 007 100 3.00 8_00 20. .02 323
oimethyl butylamine
001080980 BUTYL 014 118 67.00 8.00 24. .06 323
NITRilE 019 100 76.00 8.00 19. .04 323
PV ALCOHOL 102 100 ·22.00 8.00 23. .08 323
PVC 007 100 -3.00 8.00 21. .02 323
Dimethylethanolamine
001080100 BUTYl 014 118 .80 8.00 12. .09 323
NATURAL RUBBER 001 250 17.00 8.00 19. .02 323
NEOPRENE 018 100 57.00 8.00 21. .05 323
;iTRILE 019 100 34.00 8.00 9. .04 323
Oimethylformamide
B-IO
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS OEG C CM NUM
000681220 NATURAL RUBBER 001 120 1.00 .08 23. .05 236
2.00 . 50 23 . .05 236
4.00 1.00 23. .05 236
4.00 4.00 23. .05 236
NEOPRENE 010 120 2.00 .08 23. .06 236
7.00 •50 23 . .06 236
9.00 1.00 23. .06 236
9.00 4.00 23. .06 236
1.1·Oimethylhydrazine (Dimethylhydrazine.unsym·)
000571470 BUTn 034 UNK 10.00 168.00 22. 078
NEOPRENE 031 UNK 30.00 168.00 22. 078
NITRILE 033 UNK 38.00 168.00 22. 078
PVC 077 168 35.00 168.00 22. 078
Dimethyl Sulfoxide
000676850 NA ruRAL RUBBER 001 120 2.00 4.00 23. .05 236
2.00 .08 23. .05 236
2.00 .50 23. .05 236
3.00 1.00 . 23. .05 236
NEOPRENE 010 120 1.00 .08 23. .06 236
1.00 .50 23. .06 236
1.00 1.00 23. .06 236
3.00 4.00 23. .06 236
NITRilE 005 120 39.00 4.00 23. .06 236
19.00 1.00 23. .06 236
9.00 .50 23. .06 236
4.00 .08 23. .06 236
PVC 003 120 14.00 4.00 23. .08 236
12.00 1.00 23. .08 236
9.00 .50 23. .08 236
8.00 .08 23. .08 236
Oimethylvinylchloride
005133710 NITRILE 019 100 100.00 8.00 23. .05 323
PV ALCOHOL 004 100 '10.00 8.00 23. .08 323
PVC 003 100 '23.00 8.00 23. .02 323
VIT ON 009 118 8.00 8.00 23. .04 323
Dipropylamine
001428470 BUTYL 034 UNK 61.00 3.00 25. 126
POLYCARBONATE 098 UNK .. 10 3.00 25. 126
Epi ch l orohydr i n
001068980 BUTYL 014 118 3.00 24.00 23. .04 291
1.00 8.00 23. .07 323
1.00 8.00 23. .07 323
034 UNIC 5.00 168.00 22. 078
NATURAL RUBBER 001 250 13.00 8.00 23. .02 323
13.00 8.00 23. .02 323
017 UNK 30.00 24.00 23. .02 291
NEOPRENE 018 100 100.00 24.00 23. .04 291
031 UNK 44.00 168.00 22. 078
B-ll
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAME I RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEC C CM NUH
1,2'Epoxybutane
001068870 BUTYL 014 118 50.00 8.00 23. .06 323
NEOPRENE 018 100 150.00 8.00 23. .05 323
PV ALCOHOL 004 100 ·3.00 8.00 23. .04 323
VITON 009 118 94.00 8.00 23. .03 323
Ethanol, >70%
000641753 PE 041 UNK .20 8,760.00 23. 305
042 UNK .20 8,760.00 23. 305
048 UNK < .01 8,760.00 23. 3C5
Ethanolamine (Aminoethanol,2)
001414350 BUTYL 014 118 2.00 8.00 26. .07 323
NEOPRENE 018 100 7.00 8.00 20. .05 323
PVC 007 100 12.00 8.00 25. .02 323
VITON 009 118 6.00 8.00 22. .05 323
Ethyl Acetate
B-12
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION UEIGHT CHANGE TEST
CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS OEG C CM NUM
Ethyl Acrylate
001408850 250 250 67.00 8.00 23. .02 323
BUTYl 014 118 13.00 8.00 23. .09 323
PV ALCOHOL 102 100 '9.00 8.00 23. .08 323
PVC 003 100 74.00 8.00 23. .02 323
Ethyl Benzene
001004140 PV ALCOHOL 102 100 .40 8.00 23. .08 323
Ethyl Bromide
000749640 NEOPRENE 018 100 231.00 8.00 23. .04 323
PV ALCOHOL 102 100 ·14.00 8.00 23. .08 323
PVC 003 100 132.00 8.00 23. .02 323
VITON 009 118 13.00 8.00 23. .04 323
Ethyl·n·butylamine
133606390 NITRILE 019 100 36.00 8.00 24. .04 323
PV ALCOHOL 102 100 '24.00 8.00 23. .09 323
PVC 007 100 -31.00 8.00 24. .02 323
VITON 009 118 17.00 8.00 23. .03 323
B-13
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION ~EIGHT CHANGE TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM MUM
Ethylenediamine (Diaminoethane,1,2)
001071530 BUTYL 014 118 2.00 8.00 18. .07 323
CPE 060 113 ·5.00 24.00 23. .05 204
13.00 24.00 23. .05 204
·6.40 24.00 23. .05 204
NATURAL RUBBER 001 250 9.00 8.00 20. .01 323
NEOPRENE 018 100 9.00 8.00 18. .05 323
PVC 007 100 .80 8.00 16. .02 323
B-14
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION UEIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT UEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS OEG C CM NUM
Ethylene Glycol
0010nl10 NATURAL RUBBER 001 120 1.00 .50 23. .05 236
1.00 .08 23. .05 236
2.00 1.00 23. .05 236
< .01 4.00 23. .05 236
NEOPRENE 010 120 18.00 4.00 23. .06 236
< .01 1.00 23. .06 236
6.00 .50 23. .06 236
< .01 .08 23. .06 236
NITRILE 005 120 2.00 4.00 23. .06 236
1.00 1.00 23. .06 236
1.00 .50 23. .06 236
1.00 .08 23. .06 236
PE 041 UNIC < .01 8,760.00 23. 305
042 UNIC < .01 8,760.00 23. 305
048 UNIC < .01 8,760.00 23. 305
PVC 003 120 3.00 4.00 23. .08 236
2.00 1.00 23. .08 236
", 8.00 .50 23. .08 236
< .01 .08 23. .08 236
2·Ethyl·I·Hexanol
001047670 BUTYL 014 118 4.00 8.cio 23. .07 323
NEOPRENE 018 100 3.00 8.00 23. .05 323
PV ALCOHOL 102 100 '.30 8.00 23. .09 323
VITON 009 118 3.00 8.00 23. .03 323
Ethyl Methacrylate
000976320 BUTYL 014 118 33.00 8.00 23. .09 323
NITRILE 019 100 109.00 8.00 23. .05 323
B-15
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL OESC COOE HOURS OEG C CM NUM
Freon TF
000761310 NEOPRENE 010 120 4.00 4.00 23. .06 236
1.00 1.00 23. .06 236
< .01 .08 23. .06 236
1.00 •50 23 • .06 236
NITRILE 005 120 1.00 4.00 23. .06 236
1.00 1.00 23. .06 236
< .01 .50 23. .06 236
1.00 .08 23. .06 236
Furan (Furfuran)
001100090 BUTYL 014 118 46.00 8.00 23. .09 323
PV ALCOHOL 102 100 '22.00 8.00 23. .09 323
PVC 003 100 '49.00 8.00 23. .02 323
VITON 009 118 17.00 8.00 23. .05 323
Gasoline
080066190 NEOPRENE 010 120 2.00 •08 23 • .06 236
8.00 .50 23. .06 236
7.00 1.00 23. .06 236
9.00 4.00 23. .06 236
NITRILE 005 120 1.00 .08 23. .06 236
2.00 .50 23. .06 236
2.00 1.00 23. .06 236
4.00 4.00 23. .06 236
PE 041 UNIC 6.70 8,760.00 23. 305
042 UNIC 8.80 8,760.00 23. 305
048 UNIC 13.50 8,760.00 23. 305
Glutaraldehyde
001113080 BUTYL 014 118 1.00 6.00 23. .09 323
B-16
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION ~IGHT CHANGE TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM
Halothane
001516nO BUTYL 014 118 210.00 8.00 23. .09 323
PV ALCOHOL 102 100 ·22.00 8.00 23. .07 323
PVC 007 100 ·35.00 8.00 23. .02 323
VIT ON 009 118 81.00 8.00 23. .05 323
Heptane
001428250 PE 041 UNK .70 8,760.00 23. 305
042 UNK 6.90 8,760.00 23. 305
048 UNK 10.00 8,760.00 23. 305
Hexachlorocyclopentadiene
000n4740 BUTYL 014 118 26.00 8.00 23. .06 323
NITRILE 019 100 19.00 8.00 23. .04 323
PV ALCOHOL 102 100 2.00 8.00 23. .08 323
VITON 009 118 2.00 8.00 23. .03 323
Hexamethylphosphoamide
006803190 BUTYl 034 UNK 8.00 168.00 22. 078
NEOPRENE 031 UNK 272.00 168.00 22. 078
NITRILE 033 UNK 78.00 168.00 22. 078
PE 006 209 22.00 168.00 22. 078
POLYURETHANE 050 178 242.00 168.00 22. 078
VITON 032 UNK 250.00 168.00 22. 078
Hexane
001105430 NEOPRENE 010 120 4.00 4.00 23. .06 236
28.00 1.00 23. .06 236
1.00 .50 23. .06 236
1.00 .08 23. .06 236
NITRILE 005 120 1.00 .08 23. .06 236
< .01 .50 23. .06 236
< .01 1.00 23. .06 236
1.00 4.00 23. .06 236
Hydrochloric Acid
076470100 BUTYL 034 UNK 11.00 20.00 25. 126
.90 3.00 25. 126
POLYCARBONATE 098 UNK < .01 3.00 25. 126
< .01 20.00 25. 126
B-17
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NIJ4
076470102 NATURAL RUBBER 001 120 3.00 1.00 23. .05 236
5.00 4.00 23. .OS 236
NEOPRENE 010 120 1.00 .08 23. .06 236
1.00 .50 23. .06 236
1.00 1.00 23. .06 236
2.00 4.00 23. .06 236
NITRILE 005 120 1.00 .08 23. .06 236
2.00 .50 23. .06 236
2.00 1.00 23. .06 236
3.00 4.00 23. .06 236
PVC 003 120 < .01 .08 23. .08 236
1.00 .50 23. .08 236
1.00 1.00 23. .08 236
2.00 4.00 23. .08 236
Iminobispropylamine
000561880 BUTYL 014 118 4.00 8.00 28. .09 323
NATURAL RUBBER 001 250 21.00 8.00 26. .02 323
NEOPRENE 018 100 24.00 8.00 27. .os 323
VITON 009 118 3.00 8.00 27. .04 323
Isobutyl Acrylate
001066380 BUTYL 014 118 16.00 8.00 23. .09 323
NITRILE 019 100 103.00 8.00 23. .05 323
PV ALCOHOL 102 100 ·2.00 8.00 23. .08 323
B-18
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION ~IGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME fEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS OEG C CM NUM
Isobutyl Alcohol
000788310 BUTYL 014 118 •06 8.00 23 . .07 323
NEOPRENE 018 100 ·3.00 8.00 23. .05 323
NITRILE 019 118 7.00 8.00 23. .05 323
VIT ON 009 118 .02 8.00 23. .05 323
Isobutyl Nitrite
005425630 BUTYL 014 118 81.00 8.00 23. .04 323
NITRILE 019 100 38.00 8.00 23. .06 323
PVC 003 100 ·31.00 8.00 23. .02 323
VITON 009 118 50.00 8.00 23. .04 323
Isopropyl8llline
000753100 BUTYL 014 118 28.00 8.00 24. .09 323
NEOPRENE 018 100 60.00 8.00 21. .05 323
PVC 007 100 ·18.00 8.00 18. .02 323
VITON 009 118 67.00 8.00 26. .04 323
Isopropylmethacrylate
046553490 BUTYL 014 118 36.00 8.00 23. .09 323
NITRILE 019 100 69.00 8.00 23. .05 323
PV ALCOHOL 102 100 ·3.00 8.00 23. .09 323
PVC 003 100 63.00 8.00 23. .02 323
Kerosene
OS0082060 NEOPRENE OlD 120 1.00 •OS 23 . .06 236
1.00 .50 23. • (V, 236
1.00 1.00 23. .06 236
3.00 4.00 23. .06 236
NITRILE DOS 120 1.00 .OS 23. .06 236
B-19
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAME/ RESISTANT PRooUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CooE HClJRS DEG C CM NUM
Methacryloni tri le
001269870 BUTYL 014 118 ·1.00 8.00 23. .09 323
NATURAL RUBBER 001 250 7.00 8.00 23. .02 323
PV ALCOHOL 102 100 -6.00 8.00 23. .06 323
PVC 003 100 10.00 8.00 23. .02 323
Methanol, <3OX
000675611 PE 041 UNK .10 8,760.00 23. 305
042 UNK < .01 8,760.00 23. 305
048 UII1C < •01 8,760.00 23 • 305
Nethanol, >701
000675613 PE 041 UNK .10 8,760.00 23. 305
042 UNK .10 8,760.00 23. 305
048 UNK < .01 8,760.00 23. 305
Methyl Acetate
000792090 BUTYL 014 118 1.00 8.00 23. .09 323
NATURAL RUBBER 001 250 ·20.00 8.00 23. .02 323
PV ALCOHOl t02 tOO ·25.00 8.00 23. .07 323
PVC 003 100 t2.00 8.00 23. .02 323
Methyl Acrylate
000963330 BUTYL 014 118 5.00 8.00 23. .09 323
NATURAL RUBBER 001 250 54.00 8.00 23. .02 323
NEOPRENE 018 100 50.00 8.00 23. .05 323
PV ALCOHOL 102 100 -4.00 8.00 23. .07 323
B-20
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION ~IGHT CHANGE TEST
CHEMICAL NAME! RESISTANT PROOUCT VENDOR PERCENT ~IGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM
Methyl Chloroformate
0.0.0.7'92210. BUTYL 0.34 UN!:: 13.0.0. 20.0.0. 25. 126
11.0.0. 3.0.0. 25. 126
13-21
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C eM NUM
n-Methylethanolamine
001098310 BUTYL 014 118 2.00 8.00 19. .07 323
CELLULOSE ACETATE 099 118 9.00 8.00 20. .03 323
NATURAL RUBBER 001 250 8.00 8.00 20. .02 323
NEOPRENE 018 100 4.00 8.00 20. .06 323
Methylhydrazine
000603440 BUTYL 034 UNK 6.70 20.00 25. 126
3.40 3.00 25. 126
Methyl Iodide
000748840 BUTYL 014 118 2OB.00 8.00 23. .09 323
NEOPRENE 018 100 511.00 8.00 23. .05 323
PV ALCOHOL 102 100 ·18.00 8.00 23. .07 323
VITON 009 118 4.00 8.00 23. .04 323
Methyl Isocyanate
006248390 BUTYL 014 118 32.00 8.00 13. .06 323
32.00 8.00 23. .07 323
NATURAL RUBBER 001 250 49.00 8.00 20. .02 323
49.00 8.00 23. .01 323
NEOPRENE 018 100 90.00 8.00 20. .05 323
PV ALCOHOL 004 100 6.00 8.00 23. .03 323
VITON 009 118 74.00 8.00 21. .03 323
74.00 8.00 23. .03 323
Methyl Methacrylate
00OB06260 BUTYL 014 118 23.00 8.00 23. .09 323
NATURAL RUBBER 001 250 112.00 8.00 23. .02 323
PV ALCOHOL 102 100 ·7.00 8.00 23. .06 323
PVC 003 100 102.00 8.00 23. .02 323
Monoisopropanolamine
000789660 BUTYL 014 118 2.00 8.00 25. .07 323
NEOPRENE 018 100 6.00 8.00 24. .05 323
B-22
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAME I RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS OEG C CM NUM
Nit robenzene
000989530 BUTYL 034 UNK 15.00 20.00 25. 126
4.20 3.00 25. 126
Nitroethane
000792430 BUTYL 014 118 •30 8.00 23 • .09 323
NATURAL RUBBER 001 250 2.00 8.00 23. .02 323
NEOPRENE 018 100 23.00 8.00 23. .04 323
PV ALCOHOL 102 100 ·1.00 8.00 23. .07 323
Nitromethane
000755250 BUTYL 014 118 ·.50 8.00 23. .09 323
NATURAL RUBBER 001 250 ·4.00 8.00 23. .02 323
NEOPRENE 018 100 4.00 ·8.00 23. .05 323
PV ALCOHOL 102 100 ·2.00 8.00 23. .07 323
Nitropropane
253220140 BUTYL 034 UNK 2.00 168.00 22. 078
NEOPRENE 031 UNK 23.00 168.00 22. 078
NITRILE 033 UNK n.oo 168.00 22. 078
PE 006 209 7.00 168.00 22. 078
POLYURETHANE 050 178 99.00 168.00 22. 078
PV ALCOHOL 035 UNIC < 1.00 168.00 22. 078
PVC 077 168 42.00 168.00 22. 078
VITON 032 UNK 107.00 168.00 22. 078
2-Nitropropane
000794690 BUTYL 014 118 -.50 8.00 23. .08 323
B-23
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HOURS DEG C CM NUN
000794690 NATURAL RUBBER 001 250 18.00 8.00 23. .02 323
NEOPRENE 018 100 53.00 8.00 23. .04 323
PV ALCOHOL 102 100 '2.00 8.00 23. .06 323
n-Nitrosodimethylamine
000551850 CPE 060 113 115.00 .83 23. .05 204
112.00 .83 23. .05 204
109.00 .33 23. .05 204
o-Nitrotoluene
000SSn20 BUTYL 034 UNK 15.20 20.00 25. 126
9.90 3.00 25. 126
p-Nitrotoluene
000999900 BUTYL 034 lINK .10 3.00 25. 126
.20 20.00 25. 126
POLYCARBOIIATE 098 UNK .20 3.00 25. 126
2.00 20.00 25. 126
Oleic Acid
001128010 PE 041 UNIC 1.40 8,760.00 23. 305
042 UNIC 1.70 8,760.00 23. 305
048 lINK 2.40 8,760.00 23. 305
Oxalic Acid
001446270 BUTYl 014 118 1.00 8.00 19. .07 323
NEOPRENE 018 100 3.00 8.00 19. .05 323
NITRILE 019 100 2.00 8.00 19. .04 323
VITOII 009 118 .90 8.00 20. .03 323
Phenol, <3OX
001089521 PE 041 UNK .20 8,760.00 23. 305
042 lINK .10 8,760.00 23. 305
048 UNIC .20 8,760.00 23. 305
B-24
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HOURS OEG C CM NUM
beta'Propiolactone
000575780 BUTYL 034 UNIC 1.00 168.00 22. 078
NATURAL RUBBER 017 508 9.00 168.00 22. 078
NEOPRENE 031 UNIC 31.00 168.00 22. 078
NITRILE 033 UNIC 29.00 168.00 22. 078
PE 006 209 18.00 168.00 22. 078
POLYURETHANE 050 178 185.00 168.00 22. 078
PVC 077 168 15.00 168.00 22. 078
VITON 032 UNIC 69.00 168.00 22. 078
n'Propylamine
B-25
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HOURS OEG C eM NUM
Propylenedi ami ne
000789000 BUTYL 014 118 ·3.00 8.00 17. .07 323
NEOPRENE 018 100 1.00 8.00 24. .05 323
PVC 007 100 5.00 8.00 17. .02 323
VITON 009 118 8.00 8.00 25. .02 323
l,3'Propylene Oxide
005033000 BUTYL 014 118 21.00 8.00 23. .07 323
NATURAL RUBBER 001 250 58.00 8.00 23. .02 323
PV ALCOHOL 004 100 ·9.00 8.00 23. .03 323
VITON 009 118 94.00 8.00 23. .03 323
Propyl.ethacrylate
022102880 BUTYL 014 118 38.00 8.00 23. .08 323
NITRILE 019 100 152.00 8.00 23. .04 323
PV ALCOHOL 004 100 .• 60 8.00 23. .07 323
PVC 003 100 106.00 8.00 23. .02 323
B-26
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HooRS DEG C CM NUM
1,1,1,2·Tetrachloroethane
006302060 BUTYL 014 118 128.00 8.00 23. .07 323
PV ALCOHOL 102 100 ·3.00 8.00 23. .08 323
PVC 007 100 83.00 8.00 23. .02 323
VIT ON 009 118 2.00 8.00 23. .03 323
1,1,2,2·Tetrachloroethane
000793450 BUTYL 014 118 167.00 8.00 23. .07 323
PV ALCOHOL 004 100 .10 8.00 23. .04 323
PVC 007 100 247.00 8.00 23. .02 323
VITON 009 118 .80 8.00 23. .03 323
Tetrachloroethylene (Perchloroethylene)
001271840 BUTYL 014 118 510.00 24.00 23. .04 291
NATURAL RUBBER 017 UNK no.oo 24.00 23. .02 291
NEOPRENE 018 100 360.00 24.00 23. .04 291
NITRILE 005 120 8.00 .08 23. .06 236
11.00 .50 23. .06 236
11.00 1.00 23. .06 236
B-27
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAME/ RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HooRS DEG C CM NUM
Tetraethyl enepentami ne
001125720 BUTYL 012 118 3.00 8.00 25. .09 323
NATURAL RUBBER 017 506 17.00 8.00 28. .02 323
NEOPRENE 018 100 11.00 8.00 27. .05 323
VITON 009 118 3.00 8.00 23. .04 323
N,N,N',N"Tetramethylenediamine
001101890 BUTYL 012 118 156.00 8.00 20. .07 323
014 118 156.00 8.00 23. .07 323
NITRILE 019 100 37.00 8.00 23. .05 323
37.00 8.00 24. .05 323
PVC 003 100 3.00 8.00 23. .02 323
VITON 009 118 31.00 8.00 23. .04 323
31.00 8.00 24. .04 323
Toluene
001088830 BUTYL 014 UNIC 2~00 24.00 22. 201
IIAJURAL RUBBER 001 UNIC '2.00 1.00 25. 208
017 UNK •04 24.00 22 • 201
IIEOP/NAT RUBBER 008 UNK •• 04 24.00 22. 201
NEOPRENE 002 UNIC '3.00 1.00 25. 208
018 UNIC .50 24.00 22. 201
'.50 . •50 24.00 22 • 201
.80 24.00 22. 201
NITRILE 005 120 25.00 1.00 23. .06 236
33.00 .50 23. .06 236
17.00 .08 23. .06 236
27.00 4.00 23. .06 236
UNIC '1.00 1.00 25. 208
020 UNIC 2.50 24.00 22. 201
PE 041 UNIC 7.50 8,760.00 23. 305
042 UNIC 9.80 8,760.00 23. 305
048 UNIC 15.10 8,760.00 23. 305
PV ALCOHOL 102 UNIC 10.50 24.00 22. 201
PVC 003 UNIC '29.00 24.00 22. 201
Toluene Diisocyanate
264716250 NATURAL RUBBER 001 120 25.00 4.00 23. .05 236
15.00 1.00 23. .05 236
9.00 •50 23 • .05 236
4.00 • 08 23 • .05 236
PVC 003 120 32.00 4.00 23. .08 236
26.00 1.00 23. .08 236
14.00 .50 23. .08 236
6.00 .08 23. .08 236
B-28
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS DEG C CM NUM
Triallylamine
001027050 NEOPRENE 018 100 31.00 8.00 19. .05 323
NITRILE 019 100 4.00 8.00 22. .04 323
PVC 007 100 ·20.00 8.00 20. .02 323
VIT ON 009 118 1.00 8.00 17. .03 323
Trichloroacetaldehyde ·(Chloral)
000758760 BUTYL 014 118 105.00 8.00 23. .07 323
PV ALCOHOL 102 100 '.30 8.00 23. .08 323
PVC 007 100 125.00 8.00 23. .02 323
VITON 009 118 19.00 8.00 23. .03 323
1, 1, 2'Trichloroethane
000790050 BUTYL 014 118 so.oo 8.00 23. .09 323
UNIC SO.OO 24.00 23. 326
SO.OO 168.00 23. 326
064 UNIC 49.00 168.00 23. 326
47.00 24.00 23. 326
NATURAL RUBBER 001 UNIC '2.00 1.00 25. 208
017 UNIC 473.00 168.00 23. 326
464.00 24.00 23. 326
NEOPRENE 002 UNIC '3.00 1.00 25. 208
018 UNIC 290.00 24.00 23. 326
291.00 168.00 23. 326
NITRILE 005 UNIC ·3.00 1.00 25. 208
019 UNIC > 1, 000.00 168.00 23. 326
> 1,000.00 24.00 23. 326
PE 042 UNIC 5.00 24.00 23. 326
16.00 168.00 23. 326
076 UNIC 131.00 24.00 23. 326
147.00 168.00 23. 326
POLYURETHANE 050 UNIC 7'9.00 168.00 23. 326
58.00 24.00 23. 326
PV ALCOHOL 102 100 '2.00 8.00 23. .07 323
UNIC .SO 24.00 23. 326
.90 168.00 23. 326
PVC 003 118 238.00 8.00 23. .02 323
on UNIC 227.00 24.00 23. 326
273.00 168.00 23. 326
TEFLON 036 UNIC .40 168.00 23. 326
.30 24.00 23. 326
VITON 009 118 3.00 8.00 23. .05 323
UNIC 5.00 168.00 23. 326
4.00 24.00 23. 326
Trichloroethylene (Trichloroethene)
000790160 BUTn 014 118 440.00 24.00 23. .04 291
034 UNIC 148.00 168.00 22. 078
NATURAL RUBBER 001 UNIC '3.00 1.00 25. 208
017 UNIC 700.00 24.00 23. .02 291
NEOPRENE 002 UNIC '3.00 1.00 25. 208
018 100 .400.00 24.00 23. .04 291
B-29
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST
CHEMICAL NAME I RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HooRS DEG C CM NUM
1,2,3'Trichloropropane
000961840 BUTYL 014 118 19.00 8.00 23. .06 323
NITRILE 019 100 182.00 8.00 23. .04 323
PV ALCOHOL 004 100 4_00 8.00 23. .03 323
VITON 009 118 .50 8.00 23. .03 323
Triethylamine
001214480 NEOPRENE 018 100 70.00 8.00 20. .05 323
NITRILE 019 118 6.20 8.00 19. .04 323
PVC 007 100 '28.00 8.00 20. .02 323
VITON 009 118 2.00 8.00 24. .03 323
Triethylenetetraamine
001122430 BUTYL 014 118 3.00 8.00 20. .06 323
NEOPRENE 018 100 6.00 8.00 19. .05 323
NITRILE 019 100 23.00 8.00 16. .04 323
VITON 009 118 6.00 8.00 20. .03 323
Tri-n'propylamine
001026920 NEOPRENE 018 100 15.00 8.00 23. .05 323
NITRILE 019 100 .70 8.00 23. .04 323
PV ALCOHOL 102 100 -14.00 8.00 23. .06 323
VITON 009 118 '1.00 8.00 23. .04 323
Turpentine
080066420 NEOPRENE 010 120 1.00 .08 23. .06 236
3.00 .50 23. .06 236
4.00 1.00 23. .06 236
10.00 4.00 23. .06 236
NITRILE 005 120 < .01 .08 23. .06 236
B-30
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION ~EIGHT CHANGE TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT ~IGHT CHANGE IMMERSION TIM, -EMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM HUM
Valeroni tri le
001105980 BUTYL 014 118 .70 8.00 23. .07 323
NATURAL RUBBER 017 506 32.00 8.00 23. .02 323
NEOPRENE 018 100 58.00 8.00 23. .05 323
PV ALCOHOL 004 100 ·4.00 8.00 23. .07 323
4·Vinyl·l·cyclohexane
001004030 BUTYL 012 118 102.00 8.00 23. .07 323
NITRILE 019 100 21.00 B.OO 23. .04 323
PV ALCOHOL 004 100 ·1.00 8.00 23. .09 323
VITON 009 118 .60 8.00 23. .04 323
Xylene
001332070 NITRILE 005 1Z0 10.00 .08 23. .06 236
19.00 .50 23. .06 236
27.00 1.00 23. .06 236
35.00 4.00 23. .06 236
019 100 82.00 8.00 23. .05 323
PE 041 UNIC 7.90 8,760.00 23. 305
042 UIIIC 10.30 8,760.00 23. 305
048 UIIIC 15.40 8,760.00 23. 305
PV ALCOHOL 102 100 ·4.00 8.00 23. .09 323
PVC 003 100 ·7.00 8.00 23. .02 323
VITON 009 118 1.00 8.00 23. .04 323
o·Xylene
000954760 CPE 060 113 116.00 .60 23. .05 204
112.00 .60 23. .05 204
109.00 .73 23. .05 204
B-31
AP·PENDIX C
SWELLING DATA
C-I
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION SWELLING TEST
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR SWELL (PERCENT VOLUME) IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM
Benzene
000714320 BUTYL 014 UNK 124.00 24.00 23. 327
064 UNK 82.00 24.00 23. 327
NATURAL RUBBER 017 UNK 377.00 24.00 23. 327
383.00 24.00 23. 327
NEOPRENE 018 UNK 284.00 24.00 23. 327
NITR.IlE 019 UNK 182.00 24.00 23. 327
NONIoIOVEN PE 071 UNK 166.00 24.00 23. 327
PE 042 UNK 37.00 24.00 23. 327
076 UNa: 14.00 24.00 23. 327
PVC 003 UNK '18.00 24.00 23. 327
SARANEX 061 UNK 71.00 24.00 23. 327
TEFLON 036 UNa: 6.40 24.00 23. 327
VITOH 009 UNK 18.00 24.00 23. 327
Dibutylamine
001119220 NITRILE 019 100 28.00 8.00 24. .04 323
PV ALCOHOL 102 100 ·26.00 8.00 23. .08 323
PVC 007 100 '26.00 8.00 20. .02 323
VITOH 009 118 .40 8.00 20. .03 323
Eptchlorohydrin
001068980 BUTYL 014 118 < .01 24.00 23. .04 291
. NATURAL RUBBER 017 UNK 30.00 24.00 23. .02 291
NEOPRENE 018 100 120.00 24.00 23. .04 291
NITRILE 020 503 240.00 24.00 23. .04 291
PE 006 100 15.00 24.00 23. .01 291
PV ALCOHOL 102 100 ·7.00 24.00 23. .05 291
TEFLON 036 214 < .01 24.00 23. .01 291
VITON 009 118 35.00 24.00 23. .02 291
Ethylene Dibromide ...(O"tbromoethane,1 ,2)
001069340 BUTYL 014 118 30.00 24.00 23. .04 291
NA ruRAL RUBBER 017 UNK 240.00 24.00 23. .02 291
NEOPRENE 018 100 > 1,000.00 24.00 23. .04 291
NITRILE· 020 503 230.00 24.00 23. .04 291
PE 006 100 35.00 24:00 23. .01 291
PV ALCOHOL 102 100 .< .01 24.00 23. .05 291
TEFLON 036 214 < .01 24.00 23. .01 291
VIT ON 009 118 < .01 24.00 23. .02 291
Ethylene Dichloride (Dichloroethane,1,2)
001070620 BUTYL 014 UNK 19.00 24.00 23. 326
19.00 4.00 23. 326
19.00 1.00 23. 326
064 UNa: 25.00 24.00 23. 326
25.00 4.00 23. 326
25.00 1.00 23. 326
NATURAL RUBBER 017 UNK 118.00 1.00 23. 326
124.00 24.00 23. 326
118.00 4.00 23. 326
NEOPRENE 018 UNK 141.00 4.00 23. 326
C-2
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION SYELLING TEST
CHEMICAL NAMEI RESISTANT PRCl)tJCT VENDOR SYELL (PERCENT VOLUME) IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC talE HooRS DEG C 04 NUM
001070620 NEOPRENE 018 UNIC . 142.00 24.00 23. 326
123.00 1.00 23. 326
NITRILE 019 UNIC 275.00 4.00 23. 326
286.00 24.00 23. 326
259.00 1.00 23. 326
020 UNIC 252.00 1.00 23. 326
254.00 24.00 23. 326
252.00 4.00 23. 326
PE 042 UNIC 8.00 1.00 23. 326
20.00 24.00 23. 326
20.00 4.00 23. 326
076 UNIC 4.30 1.00 23. 326
9.00 4.00 23. 326
9.00 24.00 23. 326
POlYURETHANE 050 UNIC < • 01 24.00 23 • 326
1.50 4.00 23. 326
•30 1.00 23 • 326
PV ALCOHOL 102 UNIC .30 1.00 23. 326
1.50 4.00 23. 326
1.00 24.00 23. 326
PVC 077 UNIC > 1,000.00 1.00 23. 326
TEFLON 036 UNIC < • 01 24.00 23 • 326
< .01 1.00 23. 326
< •01 4.00 23 • 326
VITON 009 UNIC 9.00 4.00 23. 326
< •01 1.00 23 • 326
11.00 24.00 23. 326
Methyl Chloroform (Trlchloroethane,1,1,'>
000715560 BUTYL 014 UNIC 249.00 1.00 25. 326
260.00 4.00 25. 326
263.00 24.00 25. 326
064 UNIC 11.00 1.00 25. 326
153.00 4.00 25. 326
1S1.00 24.00 25. 326
NATURAL RUBBER 017 UNIC 334.00 1.00 25. 326
429.00 4.00 25. 326
425.00 24.00 25. 326
NEOPRENE 018 UNIC . 213.00 1.00 25 • 326
239.00 4.00 25. 326
246.00 24.00 25. 326
NITRILE 019 UNIC 182.00 1.00 25. 326
208.00 4.00 25. 326
214.00 24.00 25. 326
PE 042 UNIC 9.60 1.00 25. 326
9.60 4.00 25. 326
9.60 24.00 25. 326
076 UNIC ·5.00 1.00 25. 326
13.30 4.00 25. 326
12.30 24.00 25. 326
POLYURETHANE 050 UNIC 14.30 1.00 25. 326
15.70 4.00 25. 326
13.70 24.00 25. 326
C-3
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION SWELLING TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR SWELL (PERCENT VOLUME) IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOORS DEG C CM NUM
Tetrachloroethylene (Perchloroethylene)
001271840 BUTYL 014 118 280.00 24.00 23. .04 291
NATURAL RUBBER 017 UNK 530.00 24.00 23. .02 291
NEOPRENE 018 100 320.00 24.00 23. .04 .2~
NITRILE 020 191 60.00 24.00 23. .04 29.
PE 006 100 85.00 24.00 23. .01 291
PV ALCOHOL 102 100 '12.00 24.00 23. .05 291
TEFLON 036 214 < .01 24.00 23. .01 291
VITON 009 118 < .01 24.00 23. .02 291
1,1,2'Trlchloroethane
000790050 BUTYL 014 UNIC '1.00 24.00 23. 326
10.00 1.00 23. 326
7.00 4.00 23. 326
064 UNK 44.00 24.00 23. 326
44.00 4.00 23. 326
42.00 1.00 23. 326
NATURAL RUBBER 017 UNK 146.00 1.00 23. 326
154.00 24.00 23. 326
154.00 4.00 23. 326\· ..
NEOPRENE 018 UNIC 158.00 1.00 23. 326
140.00 4.00 23. 316
158.00 24.00 23. 326
NITRILE 019 UNK 355.00 24.00 23. 326
339.00 4.00 23. 326
277.00 1.00 23. 326
PE 042 UNK '16.00 4.00 23. 326
'23.00 1.00 23. 326
'20.00 24.00 23. 326
076 UNI( '1.00 24.00 23. 326
4.00 4.00 23. 32"
'4.00 1.00 23. 3;
POLYURETHANE 050 UNK '5.00 4.00 23. 326
C-4'
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION SWELLING TEST
" -
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR SWELL (PERCENT VOLUME) IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM
Trichloroethylene (Trlchloroethene)
000790160 BUTYL 014 118 320.00 24.00 23. .04 291
NATURAL RUBBER 017 UNK 580.00 24.00 23. .02 291
NEOPltENE 018 100 410.00 24.00 23. .04 291
NITRILE 020 503 220.00 24.00 23. .04 291
PE 006 100 70.00 24.00 23. .01 291
PV ALCOHOL 102 100 -10.00 24.00 23. .05 291
TEFLON 036 214 < .01 24.00 23. .01 291
VITON 009 118 20.00 24.00 23. .02 291
C-5
APPENDIX D
DIFFUSION COEFFICIENTS
D-l
SUMMARY OF PERFORMANCE DETAIL TESTS
DIFFUSION COEFFICIENTS
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR DIFFUSION COEFFICIENT CH**2/SEC TEMP THICKNESS REF
CASNO MATERIAL DESC CODE b DEG C CH NUM
Acetone
000676410 PV ACETATE 124 UNK 1.30 -11.00 40_ 178
Allyl Chloride
001070510 PV ACETATE 124 UNK 1.30 -11.00 40. 178
Benzene
000714320 BUTYL 014 UNK 4.33 '8_00 23. 327
064 UNK 5.30 -7.00 23. 327
EVA 074 UNK 1.90 -6.00 23. 327
NATURAL RUBBER 017 UNK 1.45 -6.00 23. 327
1.60 -5.00 23. 327
045 UNK 1.50 -7.00 25. 225
NEOPRENE 018 UNK 5.70 -7.00 23. 327
NITRILE 019 UNK 3.50 -7.00 23. 327
NONWOVEN PE 071 UNK 1.13 -6.00 23. 327
PE 042 UNK 8.33 -9.00 23. 327
048 UNK 1.90 '9.00 O. 253
076 UNK 8.80 -7.00 23. 327
PV ACETATE 124 UNK 4.80 '13.00 40. 178
PV ALCOHOL 004 UNK 7.30 -7.00 23. 327
PVC 003 UNK 4.50 -7.00 23. 327
SARAN EX 061 UNK 1.67 -8.00 23. 327
TEFLON 036 UNK 6.n -9.00 23. 327
VITON 009 UNK 6.00 -8.00 23. 327
Chlorobenzene
001089070 NEOPRENE 002 UNK 6.61 ·5.00 23. 186
PVC 007 UNK 7.36 '5.00 23. 186
Dimethyl Sulfoxide
000676850 NEOPRENE 002 UNK 6.60 -4.00 23. 186
Ethane
000748400 PE 048 UNK 8.15 -8.00 25. 193
D-2
SUMMARY OF PERFORMANCE DETAIL TESTS
DIFFUSION COEFFICIENTS
CHEMICAL NAMEI RESISTANT PROOUCT VENDOR DIFFUSION COEFFICIENT CM**2/SEC TEMP THICKNESS REF
CASNO MATERIAL DESC COOE a b DEG C CM NUM
Hexane
001105430 NEOPRENE 002 UNI( 1.35 -5.00 23. 186
PE 041 UN" 7.50 '11.00 O. 253
042 UN" 1.50 -10.00 O. 253
048 UNIC 1.20 '9.00 O. 253
2.50 -8.00 30. 253
PVC 007 UN" 3.68 -5.00 23. 186
Isobutylene (Isobutene)
001151170 PE 048 UNIC 4.70 -8.00 30. 253
3.10 -9.00 O. 253
1.25 -9.00 -8. 253
Isopropylamine
000753100 PV ACETATE 124 UNIC 1.70 -12.00 40. 178
Methane
000748280 PE 048 UN" 1.96 -7.00 25. 193
Propane
000749860 PE 048 UNIC 2.00 -8.00 25. 193
n-Propylami ne
Ir3'
SUMMARY OF PERFORMANCE DETAIL TESTS
01 FFUSION COEFFICIENTS
CHEMICAL NAME/ RESISTANT PRODUCT VENDOR DIFFUSION COEFFICIENT CM**2/SEC TEMP THICKNESS REF
CASNO MATERIAL DESC CODE a b DEG C CM NUN
Toluene
001088830 BUTYl 014 118 3.67 -7.00 22. 122
216 1.02 ·6.00 37. 122
NEOPRENE 002 UNK 5.56 ·5.00 23. 186
018 509 6.17 -7.00 22. 122
NITRILE 019 100 3.45 -7.00 37. _06 122
2.57 ·7.00 37. .06 122
1.50 -7.00 22_ 122
2.95 ·7.00 37. .04 122
118 1.17 -7.00 22. 122
4.15 -7.00 37. 122
1.67 ·7.00 22. 122
509 2.67 ·7.00 22. 122
020 216 3.50 -7.00 22. 122
6.95 ·7.00 37. 122
5.17 ·7.00 22. 122
PVC 003 215 5.50 -7.00 22. 122
007 129 3.33 ·7.00 22. 122
3.27 ·7.00 37. 122
UNK 8.10 -5.00 23. 186
VITON 009 118 2.33 -8.00 37. 122
VITON/NEOPRENE 022 216 3.33 ·8.00 22. 122
5.17 -8.00 37. 122
1,1,2-Trichloroethane
000790050 BUTYL 014 UNK 1.67 -7.00 23. 326
064 UNK 8.33 ·8.00 23. 326
NATURAL RUBBER 017 UNK 1.47 ·6.00 23. 326
NEOPRENE 018 UNK 1.35 -6.00 23. 326
NITRILE 019 UNK 5.50 ·7.00 23. 326
PE 042 UNK 2.00 ·8.00 23. 326
POLYURETHANE 050 UNK > 2.83 ·7.00 23. 326
PV ALCOHOL 102 lJNIC 2.67 ·7.00 23. 326
TEFLON 036 UNIC < 4.83 -11.00 23. 326
044 UNK 4.00 -10.00 23. 326
VITON 009 UNK < 1.20 -9.00 23. 326
Trichloroethylene (Trichloroethene)
000790160 NEOPRENE 002 UNK 5.03 -5_00 23. 186
PVC 007 UNK 1.45 -6.00 23. 186
APPENDIX E
TENSILE DATA
E-l
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION TENSILE STRENGTH CHANGE TEST
CHEMICAL NAME I RESISTANT PROOUCT VENDOR PERCENT TENSILE CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUH
Freon TMC
577623190 BUTYL 064 113 6.82 .08 23. 321
085 211 2.27 .08 23. 321
CHLOROBUTYL 052 205 B.38 •08 23 . 321
CPE 060 113 -12.70 • 08 23 • 321
070 113 -20.00 •08 23 . 321
PVC 053 126 16.13 . 08 23 • 321
TEFLON 055 210 48.15 . 08 23 • 321
Hydrazine (Diamine)
003020120 BUTYL 064 113 -25.00 . 08 23 . 321
085 211 -15.91 .08 23. 321
CHLOROBUTYL 052 205 '2.78 • 08 23 • 321
CPE 060 113 < .01 . 08 23 • 321
070 113 -15.00 .08 23. 321
PVC 053 126 9.68 . 08 23 • 321
TEFLON 055 210 166.67 .08 23. 321
Hydrochloric Acid
076470100 BUTYL 064 113 15.91 .08 23. 321
085 211 '4.55 .08 23. 321
CHLOROBUTYL 052 205 '13.89 .08 23. 321
CPE 060 113 . I 1.11 .08 23. 321
070 113 '62.50 .08 23. 321
PVC 053 126 35.48 . 08 23 . 321
TEFLON 055 210 174.07 • 08 23 • 321
Hydrogen Peroxide
077228410 BUTYL 064 ,,3 36.36 • 08 23 . 321
085 211 '4.55 • 08 23 . 321
CPE 060 113 '9.52 . 08 23 . 321
070 113 ·45.00 .08 23. 321
PVC 053 126 35.48 .08 23. 321
TEFLON 055 210 29.63 .08 23. 321
E-2
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION TENSILE STRENGTH CHANGE TEST
C~,~lI CAi_ ~A~1(/ REST:;;;"'" PRODUCi VENDOR PERCENT T~h~ILE CHANGE IMMERSION TIME iHIP TiliCK""S'; -<t.r
CASNO MATERIAL DESC COOE HooRS OEG C eM NUM
Methylhydrazine
000603440 BUTYL 064 113 ·4.55 • 08 23 • 321
085 211 ·4.55 .08 23. 321
CHLOR08UTYL 052 205 ·11.11 .08 23. 321
CPE 060 113 ·7.94 •08 23 • 321
070 113 -12.50 .08 23. 321
PVC 053 126 ·22.58 •08 23 . 321
TEFLON 055 210 85.19 •08 23 . 321
Nitric Acid
076973720 BUTYL 064 113 2.27 •08 23 • 321
085 211 4.55 •08 23 • 321
CHLOROBUTYL 052 20S ·27.78 •08 23 . 321
CPE 060 113 1.59 • 08 23 • 321
070 113 ·40.00 •08 23 • 321
PVC 053 126 ·16.13 • 08 23 • 321
TEFLON 055 210 133.33 •08 23 • 321
Nitrogen Tetroxide
105447260 BUTYL 064 113 36.36 •08 23 . 321
085 211 ·20.45 . 08 23 • 321
CHLOROBUTYL 052 205 ·47.22 •08 23 • 321
CPE 060 113 ·26.98 •08 23 • 321
070 113 ·52.50 •08 23 • 321
PVC 053 126 ·19.35 •08 23 • 321
TEFLON 055 210 207.41 .08 23. 321
Sulfuric Acid
076649390 BUTYL 064 113 2.27 .08 23. 321
085 211 -9.09 •08 23 • 321
CHLOROBUTYL OS2 20S '5.56 •08 23 • 321
E-3
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION TENSILE STRENGTH CHANGE TEST
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT TENSILE CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM
"
APPENDIX F
F-l
CROSS-REFERENCE OF CHEMICALS IN MIXTURES
COMPONENT MIXTURE
Acetone
000676410 000400029
000400079
000400169
000400179
000400189
000400199
000400209
000400219
000400229
Acetonitrile
000750580 000400059
Atlox 3403F
000300060 000400389
000400399
Atlox 3404F
000300070 000400389
000400399
Butadiene
001069900 000400059
Butyl Acetate
001238640 000400089
000400109
Butyl Alcohol
000713630 000400089
000400109
Cyc1ohexano1
001089300 000400359
000400369
000400379
Diesel Oil
000300020 000400149
Epoxy Resin
000300010 000400079
000400099
Ethyl Acetate
001417860 000400019
000400029
000400109
F-2
CROSS-REFERENCE OF CHEMICALS IN MIXTURES
COMPONENT MIXTURE
Ethyl Alcohol
000641750 000400019
000400029
000400039
000400089
000400299
000400309
000400319
000400329
000400339
000400349
000400359
000400369
000400379
Hexane
001105430 000400169
000400179
000400189
000400199
000400209
000400219
000400229
000400239
Isobutyl Alcohol
000788310 000400049
Isopropyl Alcohol
000676300 000400049
000400059
000400069
Methanol
000675610 000400029
000400109
Methyl Acetate
000792090 000400039
Methyl Ce11oso1ve
001098640 000400079
Methylene Chloride
000750920 000400139
000400239
000400249
F-3
CROSS-REFERENCE OF CHEMICALS IN MIXTURES
COMPONENT MIXTURE
Methyl Parathion
002980000 000400389
000400399
Nitrobenzene
000989530 000400329
000400339
000400349
Organophosphate
000300030 000400159
Pentachlorophenol
000878650 000400149
Phenol
001089520 000400139
Polyamide
000300000 000400049
Propylene Glycol
000575560 000400159
Sodium Hydroxide
013107320 000400289
Sodium Pentachlorophenate
001315220 000400289
Tenneco 500-100
000300050 000400389
000400399
F-4
CROSS-REFERENCE OF CHEMICALS IN MIXTURES
COMPONENT MIXTURE
--------- -------
Toluene
001088830 000400049
000400089
000400099
000400109
000400119
000400249
Water
077321850 000400389
Xylene
001332070 000400089
000400099
000400129
000400299
000400309
000400319
F-5
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS
F-6
SUMMARY OF PERFORMANCE DETAil FOR MIXTURE COMPONENTS
F-7
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS
F-8
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS
F-9
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS
F-IO
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS
F-ll
SUMMARY OF PERFORMANCE DETAil FOR MIXTURE COMPONENTS
F-12
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS
F-13
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS
F-14
APPENDIX G
G-l
VENDOR CODES FOUND IN APPENDICES A THROUGH E
VENDOR
CODE VENDOR NAME
VENDOR
CODE VENDOR NAME
G-3
VENDOR CODES FOUND IN APPENDICES A THROUGH E
VENDOR
CODE VENDOR NAME
G-4
APPENDIX H
R-l
1. overview
CPC chemical resistance information was formed into two data bases:
There was a separate field for each test and each qualitative rating for
each chemical/material pair. The total number of fields was about
10,000.
2. Test Data
Five types of data were considered: breakthrough time, % swell (volume),
% change in elongation, % change in weight due to immersion, and diffu-
sion coefficient. The data were scanned and classified as follows:
H-2
The totals in each classification were compared and the resistant material
put i.nto one of the following four groups:
The criteria for Group I were at least two tests with breakthrough times
grea ~er than 1 hour; no breakthrough times less than 1 hour and no data
indiating "poor" resistance in either swelling, weight change, elonga-
tion, or diffusion coefficient.
The. riterion for Group II was one or more "good" and no "fair" or "poor"
in alY of the five tests. Alternatively, the material would be put in
Group II if there were two breakthrough times greater than 1 hour (with
none less than 1 hour) and two or less "poor" in the other four tests.
The criterion for Group III was one or more "fair" or "poor" test results,
The criteria for Group IV were one or more breakthrough times less than
0.2 Lour or two breakthrough times less than 1 hour.
3. Qualitative Information
"'he ,-riteria for ,:;rolJp 1::: were less ~han c:hree A or B ra::i;'~~'s a~,ci ,:c·
.::; 01: D i'atings. .:;''..ts'rnativel:l, Group II conditior:s would be ;ne;~ 'C:' d.
t:<Jc.dl. of three or more A. or B 0:::- C ratings, the nwnber of. A. pi.us 3
rati~gs greater than the number of C ratir.gs, ar:d no D ratings,
The criteria for Group III were less than a total of three C or D ratings
or, alternatively, a total of three or more B, C or D ratings with the
number of C plus D ratings greater than the number of B ratings.
H-3
'l'~e c-ciceri0n for Grcup Iii "la'; ;:] total of three or more c:: and D L.1,-"icg,"'.
4. Matrix A Recommendations
H-4