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Acgih Guidelines 1987

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0% found this document useful (0 votes)
383 views592 pages

Acgih Guidelines 1987

guideline acgih
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 592

By Authority Of

THE UNITED STATES OF AMERICA


Legally Binding Document
By the Authority Vested By Part 5 of the United States Code § 552(a) and
Part 1 of the Code of Regulations § 51 the attached document has been duly
INCORPORATED BY REFERENCE and shall be considered legally
binding upon all citizens and residents of the United States of America.
HEED THIS NOTICE: Criminal penalties may apply for noncompliance.

e
Document Name: ACGIH: Guidelines for the Selection of Chemical
Protective Clothing, Third Edition
CFR Section(s): 46 CFR 153.933(a)

Standards Body: American Conference of Governmental Industrial


Hygienists

Official Incorporator:
THE EXECUTIVE DIRECTOR
OFFICE OF THE FEDERAL REGISTER
WASHINGTON, D.C.
Volume I: Field Guide

Volume II: Technical and


Reference Manual

Guidelines for the


Selection of Chemical
Protective Clothing
- Third Edition -
Volume I: Field Guide

Guidelines for the


Selection of Chemical
Protective Clothing
- Third Edition -

A.D. Schwope, Arthur D. Little, Inc.


P.P. Costas, Arthur D. Little, Inc.
J. O. Jackson, Los Alamos National Laboratory
J.O. Stull, U.S. Coast Guard
D.J. Weitzman, U.S. Environmental Protection Agency

February 1987

1330 Kemper Meadow Drive


Cincinnati, Ohio 45240-4148

Prepared by: Arthur D. Little, Inc.


Cambridge, MA 02140
Sponsor: U.S. Environmental Protection Agency
U.S. Coast Guard
Prime Contractor: Los Alamos National Laboratory
DISCLAIMER

Arthur D. Little, Inc. prepared this document with what it belieevs is the best currently
available information. The document is subject to revision as additional knowledge and
experience are gained. Arthur D. Little cannot guarantee the accuracy of information used
to deelop the chemical protective clothing recommendations contained herein, and the
mention of company names or products does not constitute endorsement by Arthur D.
Little. Arthur D. Little accepts no responsibility for damages or liabilities of any kind
which may be claimed to result from the use of this document.
Guidelines for the
Selection of Chemical
Protective Clothing
- Third Edition -

A.D. Schwope, Arthur D. Little, Inc.


P.P. Costas, Arthur D. Little, Inc.
J. O. Jackson, Los Alamos National Laboratory
J. O. Stull, U.S. Coast Guard
D.J. Weitzman, U.S. Environmental Protection Agency

February 1987

1330 Kemper Meadow Drive


Cincinnati, Ohio 45240-4148

Prepared by: Arthur D. Little, Inc.


Cambridge, MA 02140
Sponsor: U.S. Environmental Protection Agency
U.S. Coast Guard
Prime Contractor: Los Alamos National Laboratory
ACKNOWLEDGEMENTS
This Guidelines for the Selection of Chemical Protective Clothing was
prepared by Arthur D. Little, Inc., (Cambridge, Massachusetts), under
subcontract to Los Alamos National Laboratory (New Mexico) for the U.S.
Environmental Protection Agency (EPA) and the U.S. Coast Guard.
Particularly helpful in the preparation of this, the third edition of the
Guidelines were J .F. Stampfer and H.J. Ettinger (Los Alamos National
Laboratory), and Krister Forsberg. Mr. Forsberg of the Royal Institute
of Technology (Stockholm) reviewed each line of data presented in
Appendix A of Volume II for consistency with the original literature
sources. We also thank Dr. Douglas Walters of the National Toxicology
Program for contributing an extensive compilation of glove permeation
data generated for the NTP by the Radian Corporation.

The text, except for the addition of Chapter 5--Full-Body Protection to


Volume I, remains essentially the same (although updated) as the first
EPA and ACGIH editions for which we note the support and review comments
of W. Aaroe, B.E. Benson, S.P. Berandinelli, R. Ellis, E.R. Hoyle,
K. Hunninen, R.F. Kent, W.F. Keffer, R.C. Magor, A.P. Nielson,
M.D. Royer, A. Smith, R.S. Stricoff, F. Thompson, R.D. Turpin. L. Walz,
and R.W. Weeks. In addition, we appreciate the assistance of encapsulat-
ing ensemble manufacturers in the preparation of Appendix G of Volume I.

The authors also acknowledge the contributions of the Arthur D. Little


project team which included William Hawes, whose programming skills
greatly facilitated the information organization task, and T. Carroll,
C. Luciano, M. Rourke, and D. Ryan, who assisted us in gathering and
inputting the information. Finally, we thank the typists and report
production specialists who assembled the document.

iii
SPECIAL NOTE TO USERS
This document contains comprehensive tables of recommendations to aid and
facilitate the selection of chemical protective clothing (CPC). The
recommendations are based on an extensive compilation and analysis of CPC
vendors' literature and experimental test data published in technical
journals and reports. It is imperative that users of the recommendation
tables familiarize themselves with the background information that
precedes and accompanies the tables. The selection of CPC must take into
account the potential hazard and the conditions of use--neither is
considered in this document. The recommendations are not nor do they
imply a guarantee of safety.

Although every effort has been made to prepare this document as ac-
curately as possible, errors can and do occur. Users of this document
are asked to notify Lt. Jeffrey O. Stull, Commandant (G-DMT-3), U.S.
Coast Guard, 2100 Second Street, S.W., Washington, D.C. 20593
(202-267 -0853), or Mr. David Weitzman, U. S. Environmental Protection
Agency Office of Occupational Health and Safety t Room 3503 t Waterside
Mall, 401 M Street, S.W., Washington, D.C. 20460 (202-382-3647) of errors
so that they can be corrected.

iv
TABLE OF CONTENTS
VOLUME I

CHAPTER 1 - OVERVIEW 1

A. INTRODUCTION 1

B. CHEMICAL PROTECTIVE CLOTHING 1

C. OBJECTIVE OF THE GUIDELINES 2

D. AUDIENCE AND ORGANIZATION OF 2


GUIDELINES

CHAPTER 2 - CHEMICAL PROTECTIVE CLOTHING 4


LIMITATIONS

A. CHEMICAL RESISTANCE 4

B. DESIGN AND CONSTRUCTION 4

C. APPLICATION 5

D. REUSE 6

E. SUBSTITUTION OF CPC 6

F. COST 6

CHAPTER 3 - PERMEATION THEORY 7

A. INTRODUCTION 7

B. PERMEATION THEORY CONCEPTS 7

C. INFLUENCING FACTORS 8

CHAPTER 4 - CLASSIFICATION OF CHEMICAL 11


PROTECTIVE CLOTHING

v
TABLE OF CONTENTS (CONTINUED)

CHAPTER 5 - FULL-BODY PROTECTION 19


A. INTRODUCTION 19
B. ENSEMBLE DESIGN AND CONSTRUCTION 20

C. ENSEMBLE EVALUATION 31

D. QUALITY CONTROL 39

E. SPLASH SUITS 39

F. ENSEMBLE SELECTION CONSIDERATIONS 40

CHAPTER 6 - CPC USE PROCEDURES 47

A. PURCHASE 47

B. PRE-USE INSPECTION 47

C. DONNING 48

D. IN-USE 48

E. DOFFING 48

F. REUSE AND STORAGE 49

CHAPTER 7 - CPC VENDORS' LITERATURE 51

A. INTRODUCTION 51

B. COMMENTS ON VENDORS' CPC RATINGS AND 51


RECOMMENDATIONS
C. VENDORS' TEST METHODS 52

CHAPTER 8 - CPC RECOMMENDATIONS 54


A. SCOPE AND LIMITATIONS 54
B. RECOMMENDATIONS 61
C. USER INSTRUCTIONS 64

MATRIX A - RECOMMENDATIONS BY CHEMICAL 66


MATRIX B - RECOMMENDATIONS BY CHEMICAL 121
CLASS

vi
TABLE OF CONTENTS (CONTINUED)

APPENDIX A - GLOSSARY A-1


APPENDIX B - CHEMICAL INDEX B-1
APPENDIX C - PRODUCT INDEX C-1
APPENDIX D - VENDOR DIRECTORY D-1
APPENDIX E - PRODUCT DESCRIPTION CODE E-1
APPENDIX F - CLOTHING CLASSIFICATION CODE F-1
APPENDIX G - DATA SHEETS FOR ENCAPSULATING G-1
EMSEMBLES
APPENDIX H - PRODUCT DESCRIPTIONS FOR SPLASH H-1
SUITS
APPENDIX I - DEFINITION OF PROTECTION LEVELS 1-1
APPENDIX J - DOFFING PROCEDURES J-1

vii
CHAPTER 1
OVERV-IEW

A. INTRODUCTION
Skin is an organ of the hwnan body and has a surface area of about
1.8 m. A principal function of skin is to protect our internal organs
from exposure to potentially harmful components of the external environ-
ment. Direct contact with chemicals can pose a significant challenge to
the skin; possible reactions are:

• The skin will act as an effective barrier, and there will be no


detrimental effect due to the contact.

• The skin will suffer a primary irritation such as a burn


(corrosion), chafing due to extraction of essential oils, or
dermatitis.

• The skin will become sensitized to the chemical. Once sensi-


tized, the skin will react to quantities of chemicals much
smaller than otherwise would have any effect. Some chemicals
are both primary irritants and sensitizers.

• The skin will be penetrated by the chemical, and the chemical


and/or its metabolites will enter the blood stream. This may
or may not have a health effect, depending on the chemical and
the amount of exposure.

The latter type of reaction, which would include, for example, irrepara-
ble liver damage and cancer, receives a high level of attention from both
the lay and the technical communities. And, of course, such debilities
warrant serious consideration. However. it is also important to recog-
nize that primary skin irritations and sensitizations account for signif-
icantly greater nwnbers of lost time incidents. It is estimated that
skin diseases account for two-thirds of all identified job-related
diseases. Furthermore, seven out of ten industrial claims paid by
insurance companies are for temporary disability resulting from derma-
titis.

B. CHEMICAL PROTECTIVE CLOTHING

Along with engineering controls and carefully planned work procedures,


chemical protective clothing (CPC) is a key element in minimizing the
potential for worker exposure to chemicals. In the context of this
docwnent, CPC includes all items of clothing primarily intended to
prevent chemical contact with the skin. These include gloves, coveralls,
pants. jackets, and boots. Respirators are not included in this
classification.

1
C. OBJECTIVE OF THE GUIDELINES
epe in one form or another is commercially available from hundieds of
vendors in the United States. Furthermore, the clothing is fabricated
from a wide variety of plastic and rubber materials. In addition. the
effectiveness of a particular item of clothing is highly dependent on the
chemical with which it may be challenged. For example, a neoprene glove
provides excellent protection from sulfurjc acid, but it is rapidly
permeated by toluene. Finally, the conditions under which the clothing
is used can affect performance. These factors combine to create a
perplexing situation for those who are involved in or responsible for the
protection of workers who handle chemicals--for example, at a hazardous
waste site.

In recognition of this problem, the EPA's Occupational Health and Safety


Staff developed in 1983 the Guidelines for the Selection of Chemical
Protective Clothing. To this third edition of the Guidelines, the Coast
Guard's Office of Research and Development has added a chapter and three
appendices pertinent to full-body protection. The objective of the
Guidelines is that it be a concise, up-to-date source of information
pertinent to the selection of clothing for protection from chemicals.
All chapters and appendices have been updated as of December 1986.

D. AUDIENCE AND ORGANIZATION OF GUIDELINES


The Guidelines is principally directed towards:

• field safety personnel who are more typically faced with an


immediate need to provide the best clothing for workers on a
day-to-day basis, and

• planners and researchers who, for example, have the responsi-


bility for developing the safety plan for a particular project.
These personnel may have the time to investigate peculiarities
in clothing performance or to prescribe clothing testing in
anticipation of particular needs.

In order to satisfy such diverse requirements, the Guidelines is divided


into two volumes. Volume I is intenoed to be useful as a nfield manual."
It contains a discussion of the basic concepts of permeation and chemical
resistance, an overview of CPC vendors' literature, detailed discussion
of full-bOdy protection, an analysis of test methods for epe, and, proba-
bly most importantly, two matrices for the selection of protective
clothing. The matrices present clothing recommendations for 12 major
clothing materials and cover approximately 500 chemicals or aqueous
solutions. In addition, permeation data are provided for approximately
25 multi-component organic solutions. The appendices include an exten-
sive listing of epe sources organized by product type and principal
chemical barrier material. Detailed information is provided for full-
body ensembles. The appendices also ine-lude a glossary of epc terms and

2
instructions for selecting clothing types and doffing potentially contam-
inated clothing.

Volume I brings virtually all CPC performance information to one loca-


tion, and provides the basic information required to select, order and
intelligently use CPC. The sources are identified in the Bibliography of
Volume II.

Volume II is more technical in content. It contains a more detailed


discussion of permeation theory, CPC testing methods and CPC vendors'
literature. The appendix to Volume II contains all the data on which are
based the recommendations in the matrices of Volume I. In one sense,
Volume II could be considered a supporting document for Volume I. In
another, Volume II serves as the starting point for further investigation
of CPC.

Together the two volumes represent the most comprehensive compilation of


chemical protective clothing performance and use information available to
the public. We urge the use of the Guidelines as an important means for
maintaining the well-being of workers who may be exposed to potentially
harmful chemicals. We, furthermore, urge all users of the Guidelines to
participate in its continued improvement by sending comments and criti-
cisms to:

Lt. Jeffrey O. Stull


Commandant (G-DMT-3)
U.S. Coast Guard
2100 Second Street, S.W.
Washington, D.C. 20593

Mr. David Weitzman


U.S. Environmental Protection Agency
Office of Occupational Health and Safety (PM-273)
Room 3503 Waterside Mall
401 M Street, S.W.
Washington, D.C. 20460

3
CHAPTER 2
CHEMICAL PROTECTIVE CLOTHING LIMITATIONS
The use of chemical protective clothing is but one component of the
overall program for maintaining the health and safety of workers. It
complements (and is not a substitute for) good planning, work practices,
engineering and administrative controls, or personal hygiene. Several
factors which should be considered in the specification and selection of
epe are discussed in the following paragraphs.

A. CHEMICAL RESISTANCE
The performance of epe as a barrier to chemicals is determined by the
materials and quality of its construction. Chemical protective clothing
is based on plastic and elastomeric materials. Typically each chemical
interacts with a given plastic or elastomer in a relatively unique
manner. That is, each chemical/material pair has peculiar interactions.
The situation becomes even more complex when multi-component solutions
are involved. Four important factors to bear in mind when considering
epe are:
• In general, there is no such thing as "impermeable" plastic or
rubber clothing.

• No one clothing material will be a barrier to all chemicals.

• For a given clothing material type, chemical resistance can


vary significantly from product to product. For example, not
all brands of nitrile gloves provide equivalent protection.

• For certain chemicals or combinations of chemicals, there is no


commercially available glove or clothing that will provide more
than an hour's protection following contact. In these cases,
it is recommended that clothing be changed as soon as it is
safely possible after any contact with the chemical or chemical
mixture.

B. DESIGN AND CONSTRUCTION


Design and construction factors that can influence performance are as
follows:

• Stitched seams of clothing may be highly penetrable by chemi-


cals if not overlayed with tape or sealed with a coating.

4
• Lot-to-lot variations do occur and may have a significant
effect on the barrier effectiveness of the CPC. They may go
undetected due to quality control procedures insensitive to
chemical resistance issues.

• Pinholes may exist in elastomeric or plastic products due to


deficiencies or poor quality control in the formulation or in
the manufacturing processes.

• Thickness may vary from point to point on the clothing item.


Depending on the manufacturing process, the finger crotch area
of the glove is particularly susceptible to thin coverage.

• Garment closures differ significantly from manufacturer to


manufacturer and within one manufacturer's product line.
Attention should be paid to button and zipper areas and the
number of fabric overlaps in these areas.

Gloves are typically produced by one of two principal processes--latex-


dipping and solvent (cement) dipping. Latex gloves predominate the
market. - Researchers have speculated, however, that the chemical resis-
tance of a solvent-dipped glove may be greater than that of a latex-
dipped glove of the same generic material. The principal reason being
that the solvent-dipped glove is produced by a multiple-dip process while
the latex process is a single-dip operation. In a multiple-dip process,
imperfections in anyone layer are covered by subsequent layers. Since
the solvent-dip process is more involved, these products are generally
more expensive. Consequently, the manufacturers of such gloves typically
highlight the fact the gloves are solvent-dipped in justifying the cost.
Factors that may affect the performance of encapsulating ensembles and
splash suits are discussed in Chapter 5~

C. APPLICATION

The degree of protection provided by an item of clothing is also a


function of the application. For example, a less durable piece of
clothing may be more than adequate for a moderate duration, mild activity
(e. g., sampling) whereas it would not endure more than 5 minutes of a
vigorous, emergency response activity. Factors such as abrasion,
puncture and tear resistance, and reaction to perspiration and crumpling
should be considered. Temperature and, to some extent, humidity have
significant influences on the performance of elastomeric and plastic CPC.
Also with regard to application, it is important to recognize that
protective clothing can be cumbersome and restrictive and thereby hasten
the onset of worker fatigue. A result is that the period of safe and
effective worker activity may be reduced.

5
D. REUSE

Protective clothing decontamination and reuse are controversial and


unresolved issues at this time. Often surface contamination can be
removed by scrubbing with soap and water. In other cases, especially
with highly viscous liquids, surface decontamination may be practically
impossible, and the CPC should be discarded. A more subtle problem
arises with regard to the detection and removal of a chemical that has
been absorbed into the elastomer or plastic. Once absorbed, some of this
chemical will continue to diffuse through the material towards the inside
surface even after the surface has been decontaminated. For highly
resistant clothing the amount of chemical reaching the inside may be
insignificant. However, for moderately performing materials significant
amounts of chemical may reach the inside. This may not occur during the
work shift but can take place while, for example, a glove is stored
overnight. The next morning when the worker dons the glove, he may be
putting his skin into direct contact with a hazardous chemical. In
addition to chemical resistance, which is a function of temperature, both
duration and the surface area exposed affect the amount of chemical that
may reach the inside surface. Reuse decisions must consider these
factors as well as the toxicity of the involved chemical(s). In fact,
unless extreme care is taken to ensure decontamination, the reuse of CPC
which has been contacted with highly toxic chemicals is not advisable.
In summary, the decision to reuse CPC must take into account previous
uses; unfortunately, there is little or no documented experience for
guidance in this task.

E. SUBSTITUTION OF CPC
Particular caution is required when substituting clothing from one
manufacturer for that of another manufacturer. Clothing performance is
determined by the type of plastic or elastomer, the specific formulation
of that plastic or elastomer, and the clothing manufacturing process.
For example, materials classified generically as nitrile rubber can
differ significantly in composition and, therefore, chemical resistance.
Testing is the only means for identifying the superior products for a
particular application.

F. COST
Cost is an important consideration in the selection and utilization of
clothing, especially where clothing is likely to be damaged (e.g., tear,
puncture, etc.). In some cases it may be more cost-effective to adopt
the practice of using mUltiple changes of less expensive but relatively
poorer performing clothing than to attempt to extend the use of better
performing but more expensive clothing.

6
CHAPTER 3
PERMEATION THEORY
A. INTRODUCTION
This manual addresses the problem of selecting the most appropriate CPC
for situations where human exposure to potentially hazardous chemicals is
possible. An important concern in such situations is the effectiveness
of the CPC as a barrier to the chemicals. Barrier properties may be
estimated by simple immersion tests wherein the CPC or a portion thereof
is exposed to the chemical(s) of concern, and the material examined for
obvious signs of degradation, swelling, or weight changes. This has been
the traditional method for generating the chemical resistance tables
which are included in many CPC brochures. It is important to note,
however, that permeation may occur with little or no visible or physical
effect on clothing materials.

The barrier effectiveness of CPC can be measured by permeation testing.


The standard procedure for performing permeation tests is American
Society for Testing and Materials (ASTM) Method F739 - 85 promulgated by
ASTM Committee F-23. This same committee has developed a standard
battery of chemicals for permeation testing in ASTM FIOOl-86. The 15
chemicals in the battery represent a wide range of chemicals (e. g. ,
ketones, acids, bases, hydrocarbons, etc.) and are listed across the top
of Table 5.4. Permeation testing with these chemicals will facilitate
the comparison of clothing materials.

An overview of permeation theory and associated concepts is presented in


this chapter. For more detailed discussion, please refer to Chapter 2 of
Volume II.

B. PERMEATION THEORY CONCEPTS


Permeation of a liquid or vapor through a rubber or plastic material is a
three-step process involving:

• the sorption of the chemical at the outside surface of the CPC,

• the diffusion of the chemical through the CPC material, and

• the desorption of the chemical from the inside surface


(i.e., towards the wearer) of the CPC.

Of principal importance in selecting CPC for protection from chemicals is


the rate at which chemicals permeate the clothing materials and the time
elapsed between the contact with the chemical and the appearance of the
chemical on the inside of the CPC (i.e., breakthrough time).

7
1. Permeation Rate
Classical permeation theory (Fick's Law) states that the chemical permea-
tion rate through a material is a function of the:

• diffusion coefficient of the permeating chemical in the mate-


rial (this is a property of the chemical/material pair),

• the difference in chemical concentrations between the inside


and outside surfaces of the material, and

• the thickness of the material.

Permeation rate is often expressed in terms of the amount of a chemical


which passes through a given area of clothing per unit time. (Common
units are micrograms per square centimeter per minute.) Thus, obviously,
the total amount of chemical permeating an article of clothing increases
as the area exposed to the chemical is increased and also as the duration
of exposure is lengthened. For a given chemical/material pair, the
permeation rate decreases as the material thickness is increased. The
concentration gradient mentioned above pertains to concentrations in the
clothing material itself. Thus, there is generally a decrease in permea-
tion rate as the amount of chemical absorbed by the material decreases.
This is discussed further in Paragraph C.3. below.

2. Breakthrough Time
Breakthrough time is defined as the elapsed time from initial contact of
the outside surface of the CPC with chemical to the first detection of
chemical on the inside surface. In some cases (e.g., when handling
suspect carcinogens), breakthrough time may be the single most important
criterion for CPC selection. Measured breakthrough times are readily
determined by permeation testing and are dependent on the sensitivity of
the analytical method used in the test and the test procedure. These
factors should be considered when comparing breakthrough time data.

C. INFLUENCING FACTORS
1. Temperature
Most CPC permeation data and other chemical resistance information are
generated at 20°-25°C. Permeation rates increase and breakthrough times
decrease with increasing temperatures. The extent of the reduction in
barrier performance with increasing temperature is dependent on the
chemical/material pair.

8
2. CPC Thickness
For a given chemical/clothing material pair:

• Permeation is inversely proportional to thickness. Thus,


doubling the thickness will theoretically halve the permeation
rate.

• Breakthrough time increases with thickness. However, there is


no simple mathematical relationship for calculating the break-
through time at one thickness from that at another thickness.

3. Solubility Effect
Permeation rate is a direct function of the solubility of the chemical in
the CPC material. Solubility is the amount of chemical that can be
absorbed by a given amount of CPC material (i.e., grams liquid per gram
material); absorption may be accompanied by swelling. In general,
chemicals having high solubilities will rapidly permeate the CPC material
in question. Thus, simple immersion testing to determine solubility is
an expedient means for preliminary evaluation of candidate CPC items.
(See Volume II for further discussion of solubility and permeation.)

Caution in interpreting solubility data is required, however, since low


solubilities do not necessarily correspond to low permeation rates. It
is important to remember that permeation rate is a function of both
solubility and diffusion coefficient. Gases, for example, have low
solubilities but high diffusion coefficients and may permeate CPC
materials at rates several times greater than a liquid with moderate to
high solubility in the material.

4. Multi-component Liquids
Multi-component liquids represent a difficult problem relative to the
selection of the most appropriate CPC. Rarely is there any prior CPC
experience with the particular solution of concern, and often the compo-
nents of the solution are not known. Furthermore, mixtures of chemicals
can be significantly more aggressive towards plastics and rubbers than
anyone of the components alone. Finally, the presence of a small
fraction of a rapidly permeating component may carry a chemical that
would permeate at a slower rate if in pure form.

At the present time, researchers are attempting to develop correlations


for the prediction of multi-component permeation. Hovever, this work is
in its early stages. In the meantime, immersion and permeation testing
are recommended as the best means of selecting CPC for multi-component
solutions.

9
5. Persistent Permeation
Once a chemical has begun to diffuse into a plastic/rubber material, it
will continue to diffuse even after the chemical on the outside surface
is removed. This is because a concentration gradient has been estab-
lished with the material, and there is a natural tendency for the chemi-
cal to move towards areas of lower concentration. This phenomenon has
significant implications relative to the reuse of CPC. F0r example, a
possible field scenario is:

• chemical contacts and absorbs into a glove,

• breakthrough does not occur during the workday since the glove
has low permeability to the chemical,

• prior to removal, the glove is washed to remove surface chemi-


cal, but

• the next morning some fraction of the absorbed chemical has


reached the inside surface of the glove due to continued
diffusion.

Of course, similar scenarios could occur over both shorter and longer
time frames, for example, morning to afternoon or over a weekend. The
user must take this possibility into account when reuse is considered.
Factors influencing persistent permeation were discussed in Chapter 2,
Part D.

10
CHAPTER 4

CLASSIFICATION OF CHEMICAL PROTECTIVE CLOTHING


Personal protective clothing (PPC) is a broad category into which is
placed virtually any wearable item designed to protect the well-being of
a worker. Chemical protective clothing is a subcategory of PPC and is
intended to isolate the worker from contact with chemicals; it is the
subject of this manual. Items within the subcategory range from goggles
to gloves to full-body encapsulating ensembles. Respirators are not
considered chemical protective clothing within the context of the
Guidelines.

For the purposes of the Guidelines, the common items of CPC have been
divided into ten types that represent specific parts of the body for
which protection is designed. The objective is to facilitate the speci-
fication and purchase of CPC. The classification is presented in
Table 4.1 which is followed by sketches of several of the items.
Appendix C is a catalogue of presently available CPC and is organized
according to CPC material, with subcategories for each clothing class.
Appendix G addresses specifically full body protective clothing, and
Appendix H addresses splash suits.

The EPA also classifies protective clothing by the level of protection


that is required based on the severity of the hazard. The classification
scheme and guidance for using it is represented as Appendix I. Other
organizations may have different ways of classifying CPC based on either
function, application, or level of protection. Full-body protection is
discussed in more detail in Chapter S.

11
TABLE 4.1

CLASSIFICATION OF CPC

Coat, Jacket

Coverall

Apron

Pants, Bib Overall

Full-body Encapsulating

Hood

Shoe Cover

Boot

Face Shield

Glove

12
FACE SHIELD

HOOD

13
JACKET
COAT

14
\

PANTS BIB OVERALL

15
APRON
COVERAllS

16
SPLASH SUIT

17
FULL BODY ENCAPSULATING SUIT

18
CHAPTER 5
FUll-BODY PROTECTION
A. INTRODUCTION
1. Purpose and Scope
The type of chemical protective clothing required for any given situa-
tion depends on the amount. composition and toxicity of the chemical(s)
involved. and the duration of exposure. In the most severe cases or in
cases where the above factors are poorly defined. the highest degree of
body and respiratory protection is required. The EPA has categorized
such protection as Level A protection. (See Appendix I.) As defined.
Level A protection includes a fully encapsulating. single-piece. chemi-
cally resistant ensemble with gas-tight closures and interfaces between
pants/boots and sleeves/gloves. It also includes a pressure -demand.
self-contained breathing apparatus or. a pressure-demand. airline
respirator (with escape bottle). Not all commercially available. fully
encapsulating ensembles meet the EPA's criteria for Level A protection.
The principal point of variance is the means for air supply and respira-
tory protection. (See Section S.B.8.)

In less severe situations Level B or Level C protection is appropriate.


Level B protection includes the same respiratory protection as Level A
but two- as well as single-piece clothing is acceptable and gas-tight
closures and interfaces are not required. Level C protection includes
the same clothing as Level B. but an air-purifying respirator may be
worn.

The National Fire Protection Association (NFPA) Subcommittee on Hazard-


ous Chemical Protective Clothing is developing a classification for
chemical protective suits that distinguishes "vapor protective" garments
from "liquid (or splash) protective" garments. Each class is further
divided into "rugged" or "limited use" types of garments. The result is
four different classes of full-body protection. The performance re-
quirements for each class are being established and will be promulgated
as NFPA standards. Until the NFPA standard is finalized. there is no
way of comparing the EPA and NFPA systems.

The purpose of this chapter is to provide information that will help


guide the selection and specification of full-body encapsulating ensem-
bles as well as so-called "splash suits. II The chapter focuses on the
design features and physical properties of both types. Test methods are
also discussed. Tables and data sheets (Appendix G) are used to summa-
rize the information and enable quick comparison of commercially avail-
able full-body protective clothing. A summary of chemical resistance
information pertinent to specific ensemble materials is provided in
Table 5.4. For more comprehensive discussions of chemical resistance.

19
please refer to other chapters of the Guidelines. Respiratory protec-
tion is not addressed in the Guidelines.

2. Sources of Information
The information presented in this chapter was obtained principally from
the vendors of ensembles and ensemble components and from review of the
literature pertinent to materials testing.

In many cases the information is incomplete. Information gaps may be


generally accounted for by one of three reasons: the test has not been
performed, the information is proprietary, or the information was not
known to the vendor. The latter situation is typical of cases in which
the vendor was assembling an ensemble from components selected on the
bas is of overall performance rather than fundamental properties and
composition.

B. ENSEMBLE DESIGN AND CONSTRUCTION

Individual data sheets that characterize thirty-nine commercially


available fully encapsulating ensembles are presented as Appendix G.
The data sheets are in a standard format to facilitate comparison of the
various ensembles. In the following paragraphs, the fundamental ele-
ments of the ensembles and alternative 'approaches to their design are
discussed under the headings:

primary materials,
seams,
closures,
gloves,
boots,
exhaust valves,
visors,
air supply systems,
communication systems,
cooling systems, and
fittings.

Typically there are several designs available for each component. A


summary of the advantages and disadvantages of various types is pre-
sented in Section 5.F.

1. Primary Materials
The primary material is the flexible plastic or rubber film, sheet,
coated fabric, or laminate that composes the major portion of the
external surface area of an encapsulating ensemble. In many cases the
primary material includes a supporting fabric for increased resistance
to tear and puncture. The primary materials of presently available

20
encapsulating ensembles are listed alphabetically in Table 5. l, along
with their respective ensemble vendors. In the table, each primary
material is described from left to right in the sequence of its composi-
tion from external to internal surface. For example, for a material
listed as butyl/polyester/chloroprene, butyl rubber is the outside
surface of the ensemble and the chloroprene is the surface facing the
wearer. Between these surface materials is a polyester fabric.

Nylon®, Dacron (polyester), and Nomex® fabrics are the principal sup-
porting fabrics of encapsulating ensembles. The fabrics may be of woven
or nonwoven type. The fabrics are either laminated to the plastic or
rubber film/sheet under heat and pressure or coated with a solution of
the plastic/rubber material. In addition to supplying strength, the
fabric layer serves as a wear indicator. Its appearance warns of
excessive abrasion and loss of thickness of the chemical barrier layer.

In some cases I a wear indicator layer is incorporated into the outer


plastic/rubber material. Upon abrasion, the wear layer, which is a
different color, becomes visible alerting the user to take appropriate
action (i.e" repair or discard the suit).

As discussed in Chapter 3, the breakthrough time and permeation rate of


a chemical through a primary material is strongly influenced by the
material thickness. The primary materials listed in Table 5.1 range in
thickness from 8 mils to 28 mils. (One mil is equivalent to
0.001 inches or 0.025 mm.) The strength and durability of a primary
material is partially determined by its weight (1. e., weight per unit
area). The materials listed in Table 5.1 range in weight from
2.5 oz/sq yd to 29 oz/sq yd. The supporting materials (fabrics) range
in weight from about 1 oz/sq yd to 10 oz/sq yd.

2. Seams

The seams discussed in this section are those formed when two pieces of
the primary material are joined. Other seams, such as those around
closures and fittings, are discussed later. A seam should, at a mini-
mum, equal the physical strength and chemical resistance of the primary
material. Basic seaming techniques and components are described here:

Stitching - Stitching, typically with nylon thread, holds sections


of the primary material together. In some cases the stitching is
essential to the strength of the seam. Double stitching is usually
used in these cases. For additional strength, the primary material
is sometimes lapped (folded over) before stitching. In other
cases, the stitching is not intended to provide physical strength,
but rather to hold the sections in place while they are cemented or
welded together. Needle holes produced by stitching are potential
routes for chemical entry. The holes must be covered or sealed.

21
TABLE 5.1

ENCAPSULATING SUITS - PRIMARY MATERIALS

Primary Material l Ensemble Vendor 2

Butyl/Nylon/Butyl Andover Industries


Fyrepel Products
Trelleborg

Butyl/Polyester/Chloroprene Mine Safety Appliances

Chlorinated Polyethylene ILC Dover

Chlorobutyl/Nomexe/Chlorobutyl Arrowhead Products


ILC Dover

Chloroprene/Nylon National Draeger

Polyvinyl Chloride/Nylon Andover Industries

Polyvinyl Chloride/Polyester Standard Safety Equipment

Polyvinyl Chloride/Nylon/ Fyrepel Products


Polyvinyl Chloride National Draeger
Trelleborg
Wheeler Protective Apparel

Teflon8/Fiberglass/Teflon Chemical Fabrics Corporation

Teflon/Nomex/Teflon Chemical Fabrics Corporation

Viton/Nomex/Chlorobutyl Andover Industries

Viton/Nylon/Chloroprene Mine Safety Appliances


National Draeger

Viton/Butyl/Nylon/Butyl Trelleborg

Viton/Polyester/Viton Fyrepel Products

lThe primary materials are described with the external surface first and
2the surface facing the wearer last.
See Appendix D for the address and telephone number of each vendor.

22
Strapping - Strapping is a narrow strip of plastic/rubber material
that is cemented or welded over the seam. Strapping covers the
needle holes of the stitching and provides additional strength to
the seam.

Cement - Cements (adhesives) are solutions of plastics or rubbers


in a solvent. Cements are used to attach strapping or to form the
seam directly. When the solvent evaporates, the previously dis-
solved plastic/rubber remains. This residue must be equal in
chemical resistance to the primary material.

Welding - Welding is the joining of materials on a molecular level


and is contrasted with the mechanical approaches of stitching and
adhesives. There are two types of welding: thermal and solvent.
Thermal welding is achieved either by applying heat directly to the
plastic or by passing an electric current through the material to
generate heat (dielectric welding). Solvent welding is achieved by
partially dissolving the surfaces of the plastic material and
joining the surfaces under pressure. As the solvent dries, the
molecules of the two surfaces become entangled and bonding occurs.
A welded seam has the inherent chemical resistance of the primary
material since no other material composes the seam. Not all
primary materials are susceptible to welding; rubbers cannot be
welded.

Sealant - Sealants (top coatings) are plastics/rubbers that are


dissolved in a solvent. Sealants are used to fill the holes
created by stitching. The chemical resistance of the sealant must
equal that of the primary material.

3. Closures
Closures are used to seal the opening through which the ensemble is
donned and doffed. There are three types of closures currently being
used. The pressure sealing zipper is the most common. These zippers
are designed such that the teeth of the zipper protrude only slightly
through a plastic/rubber coated fabric. When the zipper is closed, the
teeth lock, tightly pressing the plastic/rubber on the two sides of the
zipper together forming a gas-tight seal.

Current pressure sealing zippers are manufactured using either chloro-


prene or polyvinyl chloride coated nylon or polyester fabric. Chloro-
prene is more commonly used because of the poor aging characteristics of
polyvinyl chloride. The zippers are typically equipped with nickel-
silver teeth and a brass slider. Zippers can be ordered with stainless
steel components for additional chemical resistance.

The second type of closure found on encapsulating ensembles is based on


extruded sealing lips. This closure is similar in principal to the
"Ziploc@" closure of plastic bags. Sealing lips are often used in

23
conjunction with a restraint zipper. The zipper provides closure
strength and the sealing lips provide the gas-tight seal.

The third type of closure utilizes flaps of material (along both sides
of the opening) which are thermally welded together after the suit is
donned. Unsealing the suit is accomplished by cutting off the welded
portion of the flaps. The flaps are initially sufficiently large to
permit the closure to be sealed, cut, and resealed several times.

Closures may be located along one side or diagonally across the front of
the garment, or along the center of the back. Frontal closures allow
the user to seal or unseal his own suit. Rear closures provide easier
donning and doffing but require two people to seal the suit. Rear
closures are also less susceptible to liquid splashes. The lengths of
current closure designs vary. The greater the closure length. the
easier the donning and doffing; however, cost increases with length.
Some garments also have a protective flap which covers the closure. The
flap provides protection to the closure from physical abuse and chemical
splashes.

Finally, the closure is typically attached to the primary material by


one of the methods described above for seaming. Again, this interface
must be of equal strength and chemical resistance as that of the primary
material.

4. Glove/Sleeve Interface

Gloves used with Level A encapsulating ensembles must be attached to the


garment in a gas-tight manner. Several physical configurations of the
glove/sleeve interface are discussed here. Chemical resistance of glove
materials is discussed elsewhere in the Guidelines.

Gas-tight glove/sleeve assemblies are of two types: integral and


detachable. An integral glove is directly and permanently attached to
the garment sleeve by seaming at the interface. Some manufacturers use
a rigid ring at the interface to aid this attachment. Most often the
seaming technique of the primary material seams (including stitching,
strapping, etc.) is used. The glove can only be removed by cutting or
debonding at the interface. The glove replacement procedure is not
simple, and it is sometimes required that the suit be returned to the
vendor. As with all seams, the glove/sleeve interface should be as
strong and as chemically resistant as the primary material.

Detachable gloves are secured to the sleeve by mechanical means and can
readily be replaced by the user. Alternative gloves can be used depend-
ing on the situation. There are three basic types of detachable glove/
sleeve interfaces:

Concentric Rings - This interface is based on two, tapered rings


about two inches wide and four inches in diameter. One ring is

24
slightly smaller in diameter than the other and fits snugly into
the larger one. The larger ring is positioned at the end of and
inside the garment sleeve. The smaller ring is placed inside the
glove at the glove cuff. The glove is then pushed down the garment
sleeve from the shoulder. As the glove passes through the sleeve
opening, the smaller insert is pressed inside the larger one, and a
compression seal is formed.

Ring/Clamp - This interface uses a support ring in the sleeve and a


clamp around the glove. The ring, about four inches in diameter
and one inch wide, is placed in the garment sleeve near the cuff.
The glove is then pulled over the ring on the outside of the
garment. A glove clamp, similar to a hose clamp, is placed around
the glove over the ring. The clamp is tightened to form the seal.
Some ensembles include an additional piece of primary material at
the end of the sleeve which folds over the clamp.

Connect Rings - In this type of interface. ,rings installed by the


manufacturer at the glove and the sleeve cuffs are mechanically
joined.

In general, the gloves should have equivalent or better chemical resis-


tance than the primary material. However, this is not essential since
the gloves can be replaced more readily than the ensemble.

Overgloves are sometimes used with encapsulating suits to provide an


additional layer of chemical permeation protection and to help minimize
physical abuse to attached gloves. Overgloves are typically large and
bulky and are not usually attached to the suit in a gas-tight manner.
Some encapsulating suits provide "splash guards" to prevent entrapment
of liquid chemicals between the inner and outer gloves. A splash guard
is a flap of primary material attached to the garment sleeve which can
be pulled over the end of an overglove.

5. Boot/pant Interface
There are three types of boots used with encapsulating ensembles,:
booties, standard boots (i.e., a boot having sole, heel and closure),
and overboots. Booties are integral, sock-like terminations to the
garment legs. These are typically fabricated of the primary material
and are attached to the garment with a seam (usually of the same con-
struction as the primary material seam). Booties are designed to be
worn inside standard boots. Since the booties are attached to the
garment with a gas-tight seam, the standard boots worn over them do not
need a gas-tight interface. Typically, encapsulating suits with bootie
leg terminations have "splash guards." A splash guard is a flap of
primary material attached to the garment leg which can be pulled over
the top of the boot in order to minimize the entry of liquids into the
standard boot.

25
Standard boots may be integral or detachable. Gas - tight boot/pant
interfaces are achieved by means similar to those described above for
the glove/sleeve interfaces.

Overboots are designed to be worn over standard boots. Overboots are


similar to booties (in that they have no firm sole or heel), but are
much larger. Overboots can be made integral to the garment by seaming,
in which case they are used in conjunction with standard boots which do
not have a gas-tight interface. Alternatively, overboots can be of the
pullover type with an elastic cuff, in which case they are used with
standard boots which have gas-tight interfaces.

6. Exhaust Valves
Encapsulating suits are usually designed such that air from the respira-
tor flows into the suit creating a positive pressure in the suit. The
philosophy behind this design is that a positive pressure in the suit
counters inward leakage of gases and liquids through any openings or
pinholes in the suit. To prevent the build-up of excessive pressures
which can restrict movement and stress the suit seams, encapsulating
suits are equipped with exhaust valves. These valves are one-way
valves designed to open at "cracking pressures" low enough to prevent
excess pressures in and "ballooning" of the suits.

Cracking pressures range from less than a tenth of an inch of water to


approximately 2.5 inches of water. Higher cracking pressures may
restrict movement, while lower cracking pressures may allow an internal
suit pressure to become negative relative to the outside atmosphere for
a short period of time. Studies are on-going to determine the relation-
ship between cracking pressure and suit performance. There are no
current guidelines for the selection of appropriate suit exhaust valves.

There are two types of exhaust valves used in encapsulating ensembles.


One type, the flapper valve, consists of a rubber diaphragm or disk
supported under tension in a housing such that when there is equal
pressure on both sides or less pressure on the inside of the ensemble,
the valve is closed. When over pressure exists inside the suit, the
diaphragm is pushed outward opening the valve. Flapper valves have a
cracking pressure that is quite low, only several tenths of an inch of
water, and cannot be adjusted.

The second type of exhaust valve employs a spring to hold the diaphragm
pressed against the housing and the valve closed. When the pressure in
the suit is greater than the force of the spring, the valve opens. The
advantage of this type of exhaust valve is that the cracking pressure
can be closely controlled.

In certain situations, such as when squatting, pressure can rapidly


build inside the ensemble because of the sudden loss of free volume.
This pressure must be relieved to prevent restricting the movement of

26
the wearer and to prevent overstressing the seams. The valve must have
sufficient air flow capacity to allow rapid pressure relief.

The design of the valve must provide a tight seal to prevent backflow or
back diffusion of outside air which may be contaminated. Both spring
controlled valves and flapper valves typically have diaphragms of
natural or silicone rubber. The housings are either metal or plastic.
These materials, as well as the metallic spring, are susceptible to
chemical attack. The valves should routinely be inspected for material
degradation and performance.

Both flapper and spring controlled valves are typically installed with
covers designed to prevent direct exposure of the valve to liquid
chemicals. Some valve covers are designed to seal themselves unless air
is flowing out.

7. Visors
Visors are either permanently attached to the suit or are removable.
Replacement of a permanently attached visor usually requires returning
the suit to the vendor. Removable visors employ a mechanical clamping
device and a rubber gasket to attach the visor in a gas - tight manner
seal. Visors must allow clear vision with a wide field of view. The
field of view should not be reduced significantly when the wearer turns
his head. The materials must resist scratches and be chemically resis-
tant. The thickness of the visor is another consideration; thin flexi-
ble visors may be subject to damage from creasing, whereas thick rigid
visors are generally heavier, but can provide better physical integrity.

Visors are made from polycarbonate, acrylics, fluorinated ethylene


propylene (FEP) , and flexible polyvinyl chloride. All these materials
have good clarity and strength. However, acrylic and polycarbonate
visors are susceptible to crazing (i.e., surface cracking) upon exposure
to certain chemicals. Crazing severely degrades vision clarity and can
cause catastrophic failure of the visor. For these reasons, splash
visors are sometimes worn over the primary visors. Splash visors are
clear, flexible, disposable films of highly chemically resistant materi-
als, such as FEP. They are intended to prevent liquid chemicals from
coming into direct contact with the visor and thereby increase the
useful life of the visor. However splash visors do not prevent visor
exposure to vapors which, in certain situations, can also cause crazing.

8. Air Supply systems


A detailed discussion of respirators is excluded from the Guidelines;
however, the general respiratory protection requirements of the EPA for
Levels A and B ensembles are reviewed here.

EPA guidelines on Levels A and B suits specify the use of a pressure-


demand, supplied-air respirator approved by the Mine Safety and Health

27
Administration (MSHA) and National Institute for Occupational Safety and
Health (NIOSH). Supplied-air respirators are of two general types:

pressure-demand, self-contained breathing apparatus (SCBA), or


pressure-demand, airline respirator (with escape bottle).

As discussed earlier in this chapter, not all encapsulating ensembles


are of the Level A or B type. Several encapsulating ensembles are
gas-tight but do not have a supplied-air respirator. The air supply for
these suits is umbilically fed to an air distribution system in the
ensemble, not to a respirator. In other ensembles the respirator or the
self-contained breathing apparatus is not fully isolated from the
external environment. The EPA designation for each of the thirty-nine
commercially available encapsulating ensembles is shown in the upper
right corner of the data sheets in Appendix G.

Egress bottles (or escape bottles) supply air to the wearer in the event
that the airline is severed. Most vendors supply egress bottles as an
option. In order to meet the criteria of Level A or B protection,
egress bottles are required for an ensemble that is supplied air by
umbilical hose.

A major consideration for selecting an air supply system is how well the
garment accommodates the space requirements of the air supply system.
The garment should provide sufficient space in its interior to allow a
comfortable fit to the user wearing a breathing apparatus. Components
of the air supply system should not chafe or cause internal wear of the
~ar.nent.

9. Communications sets
Voice communication when using full-body encapsulating ensemble can be
achieved by three principal means: voice amplification, hard-wire
systems, and wireless devices. Voice amplification systems, as the name
implies, consist of a microphone attached through an amplifier to a belt
mounted speaker. This system is useful when all persons are working
within talking distance of one another. Hard-wired systems consist of a
microphone and speaker headset which are connected by wire directly to
other workers or to a central, base unit and then to other workers.
This system is most conveniently used when the air supply to the
ensemble is by umbilical hose. Wireless systems are based on radio
transmitters/receivers and allow the greatest range of operations.

Whichever the system, it must be located and must operate in a manner


that minimizes its impact on worker performance and safety. The total
weight of the unit and the weight distribution of the unit, especially
if it is worn on the head, must be considered. Also the system must not
abrade the inside of the ensemble.

28
Microphones may be held in place against the neck (i.e., throat micro-
phones), mounted on or in the respirator face piece, suspended in front
of the mouth on a boom or, in the case of bone conduction microphones,
mounted somewhere on the head. Neck microphones are well accepted and
function well in high noise areas; however, some users report problems
due to slippage of the microphone. Readjustment is difficult when
wearing an encapsulating ensemble.

Three modes of operation are common: continuous, push-to-transmit, and


voice-activated. Continuous systems are convenient to use and require
virtually no training. However, they are continuously consuming power
requiring frequent replacement of batteries. Push-to-transmit systems
reduce battery consumption but require a free hand to operate. Voice-
activated systems combine the advantages of both, they are low energy
consumption and hand free operation. A slight drawback of voice-
activated systems is that some training is required in their use since
the first syllable of the first word is "lost" in activating the system.

Wireless systems operate on the basic principles of radio communication.


So-called simplex systems transmit and receive on the same frequency.
Thus, only one person can talk at a time and a fixed interval of time
must elapse before the next person can begin talking. In a duplex
system, two frequencies are utilized so that there can be rapid give-
and-take conversation, e.g., the telephone is a duplex system. Through
the use of a base station, duplex capability can be extended to large
groups of people. Half-duplex systems allow one person (e.g., the
foreman) to have full duplex capability but all others to have only
simplex capability. Thus, the foreman can talk to and hear all members
of his group but the group members can only talk to and hear the fore-
man. Obviously, each system has advantages and disadvantages in any
given situation.

10. Cooling Systems

In isolating the worker from the environment, fully encapsulating


ensembles can produce a significant thermal burden on the wearer.
Cooling due to natural convection and evaporation is prevented. Thermal
burden can be reduced by a variety of methods as follow:

Passive systems such as vests containing ice, dry ice, frozen


gels, or other heat sinks. These systems require equipment
for pre-freezing the heat sink contents prior to use. Typi-
cally such systems have a service life of one to four hours,
depending on the workload and the external temperatures.
There is no control over the cooling rate or cooling distribu-
tion.

Powered systems in which a chilled fluid is pumped in tubes in


contact with the head, neck, chest and other body regions.
The fluid may be air, water or some other heat transfer

29
medium. Similar to the passive systems, ice, dry ice, and
frozen gels are the principal heat sinks. These systems are
battery powered and typically have operating periods of one to
four hours. Some systems can be controlled by the wearer.

Umbilical air cooling systems which distribute air to the


head, neck, and other body regions through a tubular manifold
system. The air is exhausted through the pressure relief
valves. Air flow rate can be controlled by the wearer.

Umbilical air cooling systems in which pressurized air enters


the ensemble through an expansion valve (1. e., vortex tube).
The ensemble may contain one or more vortex tubes so that the
cooling air is evenly distributed. However, the noise of the
expansion restricts proximity to the head. With this system
the wearer can control the rate of cooling.

Powered cooling systems based on swing, Stirling cycle, and


conventional compressors. Fuel- and battery-powered systems
are available. To date these systems have not proven practi-
cal because of their weight. However. new developments in
high efficiency, high storage capacity batteries may change
this situation.

In addition to the above systems, cooling can also be achieved from the
evaporation of water that is sprayed over the surface of the ensemble.

As with air supply systems, the selected cooling system (if any) should
not chafe the inside of the garment.

11. Fittings
Certain ensemble configurations include umbilical or other external air
supply, cooling and communication systems. Fittings are required where
the lines for these systems enter the ensemble, usually through the
primary material. The fittings should have standard threads or quick
disconnects for attaching the lines. These fittings and the means with
which they are attached to the ensemble must be selected with full
consideration to chemical resistance. Furthermore their attachment to
the ensemble must be sufficiently strong to prevent their being pulled
out.

12. Disposable suits


Disposable encapsulating suits are designed for limited use. Their low
cost allows the user to discard the suit rather than decontaminate it
after use. These suits are typically large and loose fitting and do not
necessarily have gas-tight interfaces for glove and boot attachment and
pressure sealing zippers. Because of their low cost, disposable suits
are often used over standard encapsulating suits. This arrangement

30
provides the user with the full, gas-tight protection offered by the
standard suits and protects the (more expensive) standard suit from
gross contamination.

Disposable encapsulating suits are fabricated using polyethylene-coated


or Saranex@-laminated Tyvek@, or polyvinyl chloride film.

C. ENSEMBLE EVALUATION

1. Introduction
The performance of an encapsulating ensemble depends on its chemical
resistance, physical properties, fit, design features, and s~z~ng.
Chemical resistance is discussed elsewhere in the Guidelines. The
physical characteristics of encapsulating ensembles are for the most
part determined on the component level and are described below. Methods
for testing the overall ensemble are described in Section S.C.4.
Limited information is also provided for sizing and fit considerations.

2. Physical Properties
Standard tests exist for measuring many of the physical properties of
ensemble materials and in many cases these tests are specific to an
ensemble component. More than one test method exists for measuring some
physical properties. Selected standard tests are listed in Tables 5.2
and 5.3. ASTM standard test methods were selected because they are
readily available, regularly updated to reflect changes in the state of
the art, and actively supported by an identifiable group of persons that
are available for consultation.

The importance of material physical properties is often underestimated.


Physical properties provide a means for estimating and comparing the
strength and durability of various ensemble components. Information on
certain of these properties is considered essential to the evaluation of
ensembles. These key properties are identified in Tables 5.2 and 5.3
and discussed further in Section 5. C. 3. Although no vendor provides
data on all of the properties, it is useful for the user to be familiar
with the terms:

Abrasion Resistance - The amount of material removed from a surface


during relative motion against another surface.

Antifog - Measurement of the effect of water vapor condensation on


the read-through characteristics of clear materials.

Blocking - The adherence of materials to one another or themselves.

31
TABLE 5.2

PHYSICAL PROPERTY TEST METHODS


(Not Including Visors)

Property Test Method


l
Abrasion Resistance ASTM D3389
Blocking ASTM D1893
Brittleness ASTM D2l37
Bursting Strength ASTM 03786
Coating Adhesion ASTM D7sl
Cut Resistance l ASTM F23.20.0l 2
Durometer ASTM D2240
Flammabil i tyl ASTM Ds68
·
Fl ex Fatl.gue 1 ASTM D67l (Plastics)
ASTM D430 (Elastomers)
Hydrostatic Resistance ASTH D7sl
Low Temperature Bending ASTH D2l36
Ozone Resistance ASTM D304l
Penetration Resistance ASTH F903
Pressure (Inflation) Testing ASTM F23.s0.0l 2
Puncture Propagation Tear ASTM D2582
l 2
Puncture Resistance ASTM F23.20.02
Qualitative Leak Testing 2
ASTM F23.s0.02
Seam Strength1 ASTM D7sl
l
Stiffness ASTM Dl043 (Plastics)
ASTM DlOs3 (Elastomers)
1
Tear Strength ASTM D75l
1
Tensile Strength ASTM D75l (Supported Materials)
ASTM D4l2 (Unsupported Materials)
Thickness ASTM D75l
UV Light Resistance ASTM G26
Weight ASTM D7sl
1
Zipper Strength ASTM 2061

~Key physical property. See Section S.C.3.


Test method is currently being developed.

32
TABLE 5.3

VISOR PHYSICAL PROPERTY TEST METHODS

Property Test Method

Abrasion Resistance ASTM Dl044

Antifog MIL-A-1542B
• • 1
D~stort~on ASTM DBBl
1
Impact Strength ASTM D3029
1
Light Transmission and Haze ASTM Dl003

Scratch Resistance l ASTM F548


1
Stiffness ASTM Dl043 (Plastics)
ASTM Dl053 (Elastomers)

Tear Resistance ASTM Dl004

Tensile Strength ASTM D638


Thickness ASTM D638
UV Light Resistance ASTH G26

1
Key property. See Section S.C.3.

33
Brittleness - Evaluation of the lowest temperature at which flexi-
ble materials will not exhibit fractures or cracks when subjected
to specified impact conditions.

Bursting Strength - The multidirectional force required to break a


material.

Coating Adhesion The force required to peel a coating from a


substrate.

Compression Set The residual deformation of a material when


subjected to a compressive force then released.

Corrosion Resistance - The amount of mass or thickness loss from


materials upon exposure to chemical environments.

Cut Resistance - The force required to caUSe a sharp-edged blade to


cut the surface of a material.

Distortion - The deviation of the line of sight through flat or


curved sections of transparent materials.

Durometer - The degree to which materials resist indentation by a


specified probe under a specified load.

Flammability - The ignition, propagation, and self-extinguishing


characteristics of a material.

Flex Fatigue The number of repeated bends required to cause


cracking in a flexible material.

Hydrostatic Resistance - The force required to cause the penetra-


tion of water through a coated fabric.

Impact Resistance The force required to cause materials to


exhibit fractures or cracks when subjected to impact.

Light Transmission and Haze - The light-scattering properties of


transparent materials.

Low Temperature Bending - The degree of cracking that occurs at a


specified temperature in a flexible material when the material
is bent around a cylindrical rod.

Ozone Resistance - The degradation effects on a material as the


result of ozone exposure.

Penetration - The flow of a liquid on a non-molecular level through


closures, porous materials, seams, pinholes or imperfections in a
protective clothing material.

34
Puncture Propagation Tear - The force required for a sharp object
to snag and subsequently tear a material.

Puncture Resistance - The force required to penetrate a material


with a cylindrical probe in a direction normal to the surface of
the material.

Scratch Resistance The degree to which clear materials are


scratched or marred as a result of motion against another surface.

Seam Strength - The force required in tension to break a seam with


the force applied perpendicular to the direction of the seam. This
type of testing is similar to tensile testing of the primary
material.

Static - The resistance to an accumulation of electrical charge.

Stiffness The force required to twist or bend a material a


specified amount or the amount of bending occurring as a result of
a specific applied force.

Tear Strength - The force required to initiate or propagate a nick


or cut in a direction normal to the direction of the applied force.
Tear strength results are usually reported for both the warp and
fill (woof) directions of coated fabrics. Warp refers to threads
in a fabric running in the lengthwise direction (machine direc-
tion) , and fill to the fibers in the crosswise direction (cross
machine direction).

Tensile Strength - The force in tension required to break a materi-


al. Tensile strength results are usually reported for both the
warp and fill directions of coated fabrics.

UV Light Resistance - The degradation effects on a material as the


result of exposure to UV light.

Weight - There are two kinds of weight associated with encapsulat-


ing ensembles: the material weight and the ensemble weight.
Material weight is the weight per unit area (e.g., oz/sq yd) of the
primary material. The ensemble weight is the total weight of the
fabricated garment. In some cases, the ensemble weight reported by
vendors includes only the garment and detachable gloves and boots,
while in other cases ensemble weight includes breathing apparatus
and cooling. The ensemble weight reported on the data sheets in
Appendix G includes only garment, gloves, and boots and not cooling
and breathing apparatus.

Zipper Strength - The force required to pull a zipper apart in a


direction perpendicular to the zipper direction. This is also

35
known as zipper crosswise strength and can be applied to other
types of garment closures.

3. Key Physical Properties


ASTM Committee F-23 and the NFPA are developing standards which describe
a minimum battery of physical property tests to be preformed on an
encapsulating ensemble. These tests will complement chemical resistance
testing such as for permeation, degradation, and penetration resistance.
The battery of physical tests will also standardize the methods used for
measuring each physical property so that results can be compared from
one product to another. Until the ASTM and NFPA standards are final-
ized, the tests marked with an asterisk in Tables 5.2 and 5.3 should be
considered essential to the evaluation of the components of a fully
encapsulating ensemble.

4. Chemical Resistance
Other chapters of the Guidelines address the issue of chemical resis-
tance from the perspective of generic clothing materials categories.
For example, all butyl rubber materials regardless of thickness, source,
and formulation have been classified together in order to form the
chemical resistance recommendations in Matrix A. Generic classifica-
tions provide general guidance as to chemical resistance but, as noted
elsewhere, chemical resistance can vary significantly within a generic
class. In Table 5.4, ensemble-specific chemical resistance information,
for the fifteen chemicals composing the standard battery of test chemi-
cals in ASTM FlOOl-86, is presented. Breakthrough time and permeation
rate data are presented when available. In some other cases, qualita-
tive ratings of chemical resistance are listed as supplied by the
ensemble vendor. The qualitative ratings should be used with extreme
caution because, in several instances, it would appear that they are
generic rather than specific to the clothing material.

5. Complete Ensemble Testing


Only a few methods exist for evaluating the complete ensemble. These
methods can be classified in the categories of garment pressure (infla-
tion) testing, leak testing. and manned ensemble functionality testing.
A variety of methods exists for each category and the quantitativeness
of the results varies with the method. Draft ASTM standards have been
proposed for both garment pressure testing and qualitative leak testing.
These tests are described below.

Pressure testing measures the integrity of the suit and visor material,
suit seams, and suit closures for gas tightness. The test involves the
inflation of the garment to a specified pressure and either measuring a
pressure drop over time or applying a soap solution to the outside of
the garment to detect leaks (by the appearance of bubbles). The suit
exhaust valves must be closed to perform the test and a provision must

36
TABLE 5.4
PRODUCT·SPECIFIC CHEMICAL RESISTANCE INFORMATION FOR FUll BODY ENCAPSULATING ENSEMBLES
..
'ii
.
II
:1!
"e u j-
I
1
:i
:e
J
i-
- IIjl .1 ~
.S;
E i_ l!I C
iu
1.-
% I
fi-
-1

>
1~ ii
I
1.
.~ if
il ~'::
.J!Z 2:

:i I 1- « .!!
r=
Ii If i il
c: '10
fi o • Ii .~ 1.-
1= Ii ~i
I ! ~« 1£ iz_C~ ~1 ..."
AI:
Ii
i! j~
...i~-
Thickn ...
(mil.) «!! «~ c3~ o_ s!!: w- %2: .t: ~- ~
:: ... -
MBlerial Vendor I:- "'- <II-

But yl/N ylon/Butyl Andover (2 ) 14·15 A U U U B B U A U A B U 8 U


Fyrepel (4 ) 14 A X X B 8 B X A C A X X B X
Trelleborg(l) 15·18

Butyl/Polyester/Chloroprene MSA 19 81 ) 8( ) SI ) 0.21 )

Chlorinated Polyethylene ILC I4 1 20 0.25110201 l.ll I 0.1 I ) O.l ( ) 8 C 11 I >ll >ll I 1( ) >l( ) >ll ) C 0.5 I ) 1.21 I

Chlorobutyl/NomexlChlorobutyl Arrowhead 19
IlC 20

Chloroprene/Nylon Draeger NOI S)

PVC/Nylon Andover 15

PVC/Polyester Standard 28·30


Safety
PVC/Nylon/PVC Fyrepel (4 ) NO X X X 8 X X 8 A X 8 A X X X
Draeger NO
Trelleborg l31 18 3 l l l l l 2 3 3 1 4 3 4 3
Wheeler 20

Te lIon/F ilJorylass/Tellon ChemFab 10

Tellon/Nomex/Tellon ChemFab 18 >8 I ) >81 I O.l{O.05 O.S{O.02, >B{ ) >8( ) >B{ I >S{ ) >SI ) >S ( I >B( ) >8 ( I >SI ) >8( ) >B( I

Viton/Nomex/Chlorobutyl Andover(21 20 U U A 8 U U U A C 8 8 A A U A

Viton/Butyl/Nylon/Butyl Trelleborg(31 NO 3 3 1 2 3 l 2 2 2 2 2 2 l 2

Viton/Nylon/Chloroprene MSA 23 0.7 I ) BI I 8( I 0.11 )


Draeger NO

Viton/PolyesterlViton Fyrepel 141 8 X A 8 X X X A C 8 8 A A X A

11) Number pleceding parentheses is breakthrough time in hours; number in par.nth.se. Is permeation rate illl'g/cm'/min.
If no parenthe,e. follows number. see footnote (31.
121 A • recomme"ded; B ; minor effect; C • moderate effect; U ~ not recommended
(31 I • not eftected; 2' slightly effected; 3.4.5' material can be destroyed
141 A' recommended; B • minol·to·moderat. effect; C'· moderato to seVOIO; X • not recommended
(51 No <lata
be made for attaching a pressure gauge. Some manufacturers specify the
pressure to which the suit should be inflated. The proposed ASTM method
specifies a maximum inflation pressure (3 inches water gauge pressure),
a test pressure (2 inches water), and an allowable pressure drop (20%)
over a three-minute period. It also requires using the soap solution to
locate leaks if the suit does not meet the pass/fail criteria.

Leak testing measures the integrity of the entire ensemble to a gas


challenge agent in a manner simulating actual use. This testing
involves exposing a test subj ect wearing the ensemble in a closed
chamber to a challenge agent and measuring the agent concentration both
inside and outside the suit. The proposed ASTM method employs ammonia
gas at a concentration of 1000 to 2000 ppm and length of stain detection
tubes. Other methods may use different gases or aerosols (at non-toxic
concentrations) and appropriate detection methods. Dependent on the
means used to measure the presence of gas, the test can be qualitative,
semi-quantitative or quantitative. When concentration measurements are
precise, the results can be used in a semi-quantitative manner by
ratioing the external to internal gas challenge agent concentrations for
calculating a protection factor. Large protection factors are indica-
tive of high ensemble integrity.

Manned ensemble testing is often performed to determine the range of


activities that a user can do while wearing the ensemble .. These may
include different types of exercises or tasks which simulate the end
application of the suit. Results from these tests are generally subjec-
tive regarding the design, comfort, and fit of the garment. Measurement
of the wearers physiological condition (e.g., core temperature, skin
temperature, heart rate, and blood pressure) during this testing can
help quantify the results when compared to tests with the subject not
wearing the ensemble.

6. Ensemble Sizing and Fit


Manufacturers may offer one size or several sizes of their respective
garments. (See Appendix G.) There are no standards for s iz ing these
garments; consequently, one manufacturer's "large" may not fit the same
group of people as another manufacturer's "large." Generally, the more
sizes offered by a manufacturer, the greater the range of people who
will comfortably (and functionally) be fit by a given garment design.
The only way to gauge the fit of a garment is to actually tryon each of
the available sizes offered by the manufacturer.

38
D. QUALITY CONTROL
There is no industry standard test series by which the quality of fully
encapsulating ensembles is controlled. The level of manufacturer
quality assurance ranges from simple visual inspections to a large
battery of tests on the ensemble and its components. Some manufacturers
perform lot-by-Iot tests to verify chemical resistance and physical
properties of the primary materials. All the vendors listed in
Table 5.1 subject completed ensembles to pressure (inflation) testing,
as previously described. While closure, interface or seam imperfections
are thereby located and corrected prior to shipping, this does not test
exhaust values.

None of the vendors provided any insight into m~n~mum physical property
values or performance levels acceptable for any of the individual
components of an encapsulating ensemble. Indeed, while limits would be
most useful in evaluating suit components, it would be difficult to set
such limits since they are highly dependent on the application condi-
tions.

Both the ASTM F-23 Committee and the NFPA Subcommittee on Hazardous
Chemical Protective Clothing are developing standards which would
increase the information provided by manufacturers on the performance of
these garments. The proposed ASTM standard would specify documentation
requirements for chemical protective suits and suit components. The
NFPA is writing performance standards for each type of chemical protec-
tive suit in its proposed suit classification system.

E. SPLASH SUITS
Level B (and Level C) protective clothing, as defined by the EPA, is
used in situations where the atmospheric concentration of toxic sub-
stances requires a high level of respirator protection, but less skin
protection than Level A. (See Appendix I for further explanation.) The
garment should cover most of the body, but is not completely sealed.
This type of clothing is commonly referred to as a "splash suit."
Several of the major manufacturers of splash suits and their products
are listed in Appendix H. The styles and primary materials are given
along with the major construction features.

In many cases, chemical splash suits are almost identical to commercial


rain gear. Splash suit components include jacket, pants (usually
overalls), coveralls, and hood. Splash suits minimize exposure to
liquids. However, the closures and interfaces are not gas- or liquid-
tight.

The primary material in splash suits is typically a fabric-supported


plastic or rubber film/sheet. The most commonly used plastic is poly-
vinyl chloride. Other polymers used include: polyethylene,

39
chloroprene, styrene/butadiene rubber, polyurethane, a blend of nitrile
rubber and polyvinyl chloride, and butyl rubber. The seams of the
primary material are usually stitched and cemented or welded.

The closures on splash suits need not be liquid proof. They typically
are either simple zippers or snaps. The snaps can be metal or plastic.
Closures often have a storm fly front, which is an extra flap of materi-
al in front of the closure to prevent direct liquid contact with the
closure.

Other construction features of splash suits include batwing sleeves


(extra material under the arm for a greater degree of movement) and
take-up snaps on the sleeves and pant cuffs (to reduce but not seal arm
and leg openings). Splash suits do not include integral gloves, boots,
or air supply systems; these are separate components.

Disposable splash suits are fabricated using polyethylene-coated or


Saranexe-laminated Tyveke as the primary material. Jackets, pants,
coveralls, and hoods are available as disposables.

F. ENSEMBLE SELECTION CONSIDERATIONS


The selection of fully encapsulating ensembles and splash suits depends
on:

- the nature and severity of the hazard,


- the type and duration of the tasks to be performed,
- the performance features and limitations of the available
clothing, and
- cost.

The information provided in Appendix I provides considerable guidance to


assist in matching the level of protection to the hazard. The selection
of an ensemble for a specific application typically involves trade-offs
among physical and chemical properties, design features, and human
factors considerations.

There are no current ensembles which provide both flame and chemical
protection. Nearly all CPC materials will ignite and burn when con-
tacted by flame. These ensembles should not be used for situations
where the probability of contact with flame or flashover conditions is
high. Combined thermal and chemical protective suit systems should be
considered carefully. Thermal protection may be worn either inside or
outside the chemical protective suits. When externally worn, thermal
protective clothing is subject to contamination and must be disposed of
after use. When worn inside (e.g., aramid fiber jumpsuit), the integ-
rity of the chemical protective clothing will be lost in a flame situa-
tion, resulting in a potentially life-threatening situation. Alterna-
tively, thermal protection can be worn both inside and outside the suit.

40
In any of these cases, the additional burden (weight/heat stress) to the
wearer must be considered.

In Table 5.5 are listed the advantages and disadvantages of many of


alternatives discussed earlier. Chemical resistance issues are not
included in the table as they are discussed elsewhere in the Guidelines.
Neither is cost addressed. Ensemble design and component alternatives
are characterized in a qualitative manner since there are no generally
accepted quantitative criteria by which they can be assessed. The state
of the art is not sufficiently advanced for setting minimum physical
property or performance values for ensemble materials and components.
However, the NFPA Subcommittee on Hazardous Chemical Protective Clothing
is engaged in several studies to define performance levels for chemical
protective suits used in emergency response.

41
TABLE 5.5

ADVANTAGES AND DISADVANTAGES OF ALTERNATIVE ENSEMBLE COMPONENTS

COMPONENT ADVANTAGES DISADVANTAGES COMMENTS

PRIMARY MATERIAL

COMPOS I TI ON WIDE VARIETY AVAILABLE CHEMICAL RESISTANCE VARIES FROM MATERIAL


TO MATERIAL AND FROM VENDOR TO VENDOR.
FLAME RESISTANCE SHOULD BE CONSIDERED

SUPPORTING FABRIC ADDS STRENGTH INCREASES WEIGHT


REDUCES FLEXIBILITY
EDGES MUST BE SEALED

!lEAR I ND I CATOR INDICATES REDUCED PRDTECTION PREFERRED

THICKNESS! INCREASES STRENGTH INCREASES WEIGHT


!lEIGHT INCREASES PROTECTION REDUCES FLEXIBILITY

SEAMS

!lELDED CHEMICAL RESISTANCE EQUIVALENT TO RUBBER MATERIALS CANNOT BE WELDED


THAT OF PRIMARY MATERIAL
LESS BULKY
LESS SUSCEPTIBLE TO SNAGGING

STITCHED APPLICABLE TO ALL MATERIALS REQUIRES STRAPPING OR SEALANTS LAPPED AND DOUBLE-STITCHED CONSTRUCTIONS
MUST BE TESTED FOR CHEMICAL RESISTANCE PREFERRED
PENETRATION THROUGH PINHOLES
TABLE 5.5 (CONTINUED)

ADVANTAGES AND DISADVANTAGES OF ALTERNATIVE ENSEMBLE COMPONENTS

COMPONENT ADVANTAGES DISADVANTAGES COMMENTS

CLOSURES

PRESSURE SEALING SIMPLE AVAILABLE MATERIALS HAVE LIMITED STAINLESS STEEL TEETH AND SLIDER AVAILABLE
ZIPPER CHEMICAL RESISTANCE FLAP MAY BE ADDED TO PROTECT ZIPPER

SEALING LIP PROTECTS ZIPPER FROM ENVIRONMENT TWO·STEP PROCESS: ZIPPER AND SEAL
ZIPPER REQUIRES DEXTERITY
SOME SEALING LIP MATERIALS MAY BECOME
STIFF/UNOPERABLE IN COlD WEATHER

WELDED CHEMICAL RESISTANCE EQUIVALENT TO HEAT SEALING EQUIPMENT REQUIRED


THAT OF PRIMARY MATERIAL DON/DOFF REQUIRES HELPER
LIMITS NUMBER OF REUSES

FRONT MAY BE USER OPERATED, IF ZIPPER MORE DIFFICULT TO DON AND DOFF SUIT
EMERGENCY DOFFING, IF ZIPPER MORE SUSCEPTIBLE TO CHEMICAL EXPOSURE

BACK LESS SUSCEPTIBLE TO CHEMICAL EXPOSURE TWO·MAN OPERATION


EASIER TO DON/DOFF SUIT

GLOVE/SLEEVE &BOOT/PANT INTERFACE OVERGLOVES/BOOTS INCREASE PROTECTION AND


SERVICE LIFE BUT REDUCE MOBILITY, TACTILITY
AND DEXTERITY
INTEGRAL FACTORY SEALED AND TESTED DIFFICULT TO REPLACE, MAY REQUIRE
RETURN TO FACTORY
NOT INTERCHANGEABLE FOR FIT
OR CHEMICAL RESISTANCE
TABLE 5.5 (CONTINUED)

ADVANTAGES AND DISADVANTAGES OF ALTERNATIVE ENSEMBLE COMPONENTS

et:llPONENT ADVANTAGES DISADVANTAGES C!J4MENTS

DETACHABLE EASY TO REPLACE SEAL IS MADE IN FIELD AND IS


CAN BE OPTIMIZED FOR FIT AND NOT READILY TESTED
CHEMICAL RESISTANCE

--CONCENTRIC RINGS NO MECHANICAL PARTS RELIES ON et:IIPRESSION SEAL; NO


CLAMP OR LOCK
DIFFICULT TO INSPECT

- -RING/CLAMP SIMPLE MAY REQUIRE TWO PERSONS


EASILY INSPECTED CORROSION OF CLAMP
MECHANICAL SEAL

--CONNECT RINGS EASE OF USE COMPLEXITY


MECHANICAL SEAL REPAIR MAY REQUIRE RETURN TO FACTORY

EXHAUST VALVES VALVES SHOULD BE COVERED TO PREVENT DIRECT


EXPOSURE TO LIQUIDS. COVERS SHOULD BE OF A
DESIGN WHICH MINIMIZES BACK DIFFUSION

FLAPPER SIMPLE CANNOT ADJUST CRACKING PRESSURE


CHEMICAL RESISTANCE OF DIAPHRAGM

SPRING-OPERATED CAN ADJUST CRACKING PRESSURE CORROSION RESISTANCE OF SPRING


CHEMICAL RESISTANCE OF DIAPHRAGM
TABLE 5.5 (CONTINUED)

ADVANTAGES AND DISADVANTAGES OF ALTERNATIVE ENSEMBLE COMPONENTS

C(l4PONENT ADVANTAGES DISADVANTAGES COMMENTS

VISORS SPLASH VISORS INCREASE PROTECTION AND


VISOR SERVICE LIFE. SPLASH VISORS MAY
RESTRICT HEAD ROTATION AND INTERFERE
WITH VISION
INTEGRAL FACTORY SEALED AND TESTED REPLACEMENT REQUIRES RETURN TO FACTORY

DETACHABLE VISORS EASILY REPLACED SEALING IS USER DEPENDENT


CHEMICAL RESISTANCE OF GASKET

FLEXIBLE LI GHTWE IGHT MAY CREASE RESULTING IN DECREASE IN


CHEMICAL RESISTANCE

RIGID STURDY, DURABLE HEAVY, MAY SHATTER (IF GLASS)

AIR SUPPLY SYSTEMS

SCBA WIDE RANGE OF OPERATION DURATION OF ACTIVITY LIMITED BY AIR SUPPLY


ENSEMBLE MUST BE DESIGNED TO ACCOMOOATE
SCBA WEIGHT

AIRLINE LONG WORK PERIODS LIMITS RANGE OF OPERATIONS CHEMICAL RESISTANCE OF AIRLINE SHOULD
CODLING AIR CAN ALSO BE SUPPLIED BE CONSIDERED
TABLE 5.5 (CONTINUED)

ADVANTAGES AND DISADVANTAGES OF ALTERNATIVE ENSEMBLE COMPONENTS

'.
C(JfI>ONENT ADVANTAGES DISADVANTAGES COMMENTS

COMMUNICATION SETS VOICE COMMUNICATION IS ESSENTIAL FOR


SAFE, EFFICIENT WORK

VOICE-AMPLICATION INEXPENSIVE FUNCTIONAL OVER SHORT DISTANCES

HARD-WIRED SYSTEM EXTENDS RANGE OF OPERATION REQUIRES ALL PERSONS BE CONNECTED BY WIRE

WIRELESS VOICE/HEARING QUALITY HIGH BATTERY LIFE LIMITS OPERATION PERIOD USER MUST DECIDE AMONG CONTINUOUSLY ON,
ALLOWS WIDE RANGE OF OPERATION SOME TRAINING REQUIRED PUSH TO ACTIVATE, OR VOICE ACTIVIATION.
ALSO, AMONG SIMPLEX, DUPLEX OR HALF-DUPLEX

COOLING SYSTEMS ALLOWS EXTENDED WORK PERIODS ADDED WEIGHT/BULK


REDUCES LIKELIHOOD OF NEAT STRESS UMBILICAL SYSTEMS RESTRICT RANGE OF
OPERATION
PASSIVE SYSTEMS ALLOW NO CONTROL OF
COOLING RATE
CHAPTER 6
CPC USE PROCEDURES
A. PURCHASE
Protective clothing is purchased either directly from the manufacturer or
through a CPC distributor. Listings of these organizations may be found
in, for example, the Thomas Register or Best's Safety Directory. A
fairly extensive listing is provided as Appendices C and D. The larger
distributors carry several manufacturers' products and a wide variety of
products. Virtually every manufacturer has a catalogue of its products
which describes each product as to the sizes available, thickness of the
rubber or plastic barrier, and the materials of construction. For
convenience, detailed summaries of this information for full-body ensem-
bles is provided as Appendices G and H.

Many of the catalogues also contain chemical resistance ratings charts


for the products. The reliability of the ratings varies from vendor to
vendor. Some ratings are based on extensive testing, while others would
appear to have minimal supporting evidence. Further comments on CPC
vendors' literature are presented in Chapter 7.

In making CPC purchase decisions, important considerations are:

• the application to which the clothing will be put,

• the recommendations presented in Chapter 8,

• past experience with the particular item of clothing, and

• cost and availability.

B. PRE-USE INSPECTION
Each item of clothing should be inspected immediately upon removing it
from the package. First determine that the material of construction is
that which was ordered or specified for the task at hand. This will
involve comparing the item number with the catalogue number. Items of
different materials should be kept separated. (See Storage below.)

Visually inspect the items for defects such as imperfect seams, non-
uniform coatings, pinholes, malfunctioning closures, and tears. Some
flexible materials may stiffen during extended storage periods; flex the
product and observe for surface cracks or other signs of shelf life
deterioration. Pinholes may be detectable by holding the garment up to a
light in a dark room. Gloves with holes can be identified by pressuriz-
ing the glove. This can be accomplished by blowing into the glove and

47
then tightly rolling the gauntlet towards the fingers (thereby reducing
volume and increasing pressure) while observing that the glove holds
pressure. Alternatively, the glove could be inflated and then held under
water and examined for the presence of air bubbles. Full-body encapsu-
lating ensembles should be checked for the operation of pressure relief
valves and the fittings at the wrists, ankles, and neck. Standard
methods for leak testing full-body ensembles are discussed in Chap-
ter S.C.S.

c. DONNING

Each worker should thoroughly inspect the clothing he is to wear immedi-


ately before donning. Of principal concern are cuts, tears, punctures,
and discoloration or stiffness which may be indicative of chemical attack
resultant from previous use or non-uniformities in the rubber or plastic.
The wearer should understand all aspects of the clothing operation and
its limitations; this is especially important for full-body encapsulating
ensembles where misuse could potentially result in suffocation. Note
some materials may have temperature limitations; for example, some CPC
become stiff and may be unusable at low temperatures.

Once the clothing is on, all closures should be secured and checked. Use
the "buddy system." Finally, the fit of the clothing should be evalu-
ated. Improperly fitting protective clothing represents a severe poten-
tial hazard. Where clothing is too small, worker movement is restricted,
likelihood for tear is increased, and the potential for accelerated
worker fatigue is increased. Where the clothing is too large, the
possibility of snag is increased, and the dexterity and coordination of
the worker may be compromised.

D. IN-USE

During the course of the work task, each worker should periodically
inspect his protective clothing. Of principal concern are tears, punc-
tures, seam discontinuities, or closure failure that may have developed
while working. Evidence of chemical attack such as discoloration,
swelling, stiffening, or softening should also be noted. (Note: Permea-
tion can occur without any visible effects on the clothing material.)
Any item of clothing that has been physically damaged or chemically
degraded should be doffed and replaced as soon as safely possible.

E. DOFFING

A principal objective of the doffing process is to restrict the transfer


of chemical from the work area. A second objective is to avoid contact
of the person doffing the garment as well as others with chemical on the
outside of the garment.

48
..
Detailed doffing procedures have been developed by the EPA and are
contained in the Interim Standard Operating Safety Procedures of the
Office of Emergency and Remedial Response, Hazardous Response Support
Division. Part 7 and pertinent Annexes of the Interim Standard are
included herein as Appendix J.

They address:

• doffing site location,

• decontamination, and

• disposal of contaminated garments.

F. REUSE AND STORAGE

Several considerations relative to the storage and reuse of protective


clothing were discussed in Chapter 2. They primarily focus on hazards
that could potentially develop upon the storage of contaminated clothing.
Briefly, in cases where a chemical is absorbed by the clothing, the
chemical begins to permeate into the clothing. Short duration washing of
the clothing with soap and water removes surface contamination but not
absorbed chemical. After surface decontamination, some of the absorbed
chemical will continue to permeate the clothing material and may ulti-
mately appear on the inside surface. This can happen during periods of
overnight or weekend storage. Where such potential hazards may develop,
clothing can be checked inside and out for discoloration or, if possible,
by wipe testing for suspect chemicals prior to reuse. This is particu-
larly important for full-body encapsulating ensembles which are generally
subj ect to extensive reuse due to their cost. Note, however, that
negative (i.e., no chemical found) test results do not necessarily
preclude the possibility that some absorbed chemical will be released to
the inside of the CPC during reuse.

It should be noted that, at the present time, there is very little docu-
mentation regarding clothing reuse. The use of disposable clothing, of
course, obviates the problem. Where reusable CPC is required, however,
the type of problem discussed above can best be. minimized by selecting
the most resistant clothing for the chemical at hand; such clothing will
absorb little or no chemical. Furthermore, used clothing should be
stored in well-ventilated areas. Ideally, there should be good air flow
around each item of clothing.

Reuse of face shields and lens is a particularly important issue. Good


vision is required for both safety and efficiency on the work site. All
such items should be inspected for crazing, cracks, and fogginess prior
to use. See Chapter 3, Part D, in Volume II.

49
Finally, in storing protective clothing, different types of materials of
clothing should not be mixed. For example, gloves which are black in
color and virtually indistinguishable from one another may be made from
nitrile, neoprene, Viton, polyvinyl chloride, butyl, etc., materials.
Each material has unique chemical barrier properties. Mixing the gloves
significantly increases the chance that a worker will be wearing the
wrong clothing for the chemical of concern. It may be possible to
separate mixed gloves by using the manufacturer's product number that is
often found in the gauntlet area.

50
CHAPTER 7
CPC VENDORS' LITERATURE
A. INTRODUCTION
The most widely available sources of information on CPC are the product
catalogues of the CPC manufacturers and vendors. These booklets contain
descriptions of the types, sizes, and varieties of CPC produced by each
manufacturer. In most cases the basic materials of construction of the
CPC are also included in the product descriptions. Many manufacturers
also include information pertinent to the chemical resistance of their
products or of the materials from which the products are fabricated.
This information is often in the form of tables of qualitative chemical
resistance ratings or use recommendations for the products/materials and
particular chemicals. However, the leading manufacturers are increas-
ingly providing information from permeation testing. A few vendors also
provide information pertinent to abrasion, tear, etc., resistance but in
general most catalogues do not address such application-related issues.
Since the focus of these Guidelines is the selection of clothing for
protection from exposure to chemicals, the vendors' chemical ratings and
recommendations tables are the focus in this chapter; they are discussed
in more detail in Chapter 4 of Volume II.

B. COMMENTS ON VENDORS' CPC RATINGS AND RECOMMENDATIONS

Of the 150 CPC catalogues which were obtained and reviewed in the prepa-
ration of the Guidelines, 26 contained some form of chemical resistance
information for the products described therein. The information was both
qualitative and quantitative. The qualitative ratings/recommendations
typically were on a four-grade scale of "excellent," "good," "fair," and
either "poor" or "not recommended." In a small number of cases, five- or
six-grade scales were used. With the exception of those tables based on
permeation testing, these tables do not include information as to the
basis for the recommendations. From the results of interviews with
several of the vendors who do not supply permeation test results, it
would appear that, at present, most do not have (or at least are unwill-
ing to share) performance specifications or quantitative test data for
their products. The ratings/recommendations for a particular type of
product (for example, nitrile gloves) for a particular chemical may vary
from vendor to vendor. Both of these factors--little or no test data and
inconsistencies among recommendation tables--make the selection, from
qualitative information, of the best CPC for a given application a
difficult and uncertain task.

An increasing number of vendors have available or are providing permea-


tion test data, i.e., breakthrough times and permeation rates. These
data allow the comparison of CPC products. However, such comparisons

51
must be performed with caution since test results can be influenced by
the testing method. For example, analytical sensitivity can strongly
influence the detection of breakthrough. Also, some vendors report the
earliest breakthrough time found in replicate tests while others report
an average value.

Given the above facts, the most important consideration to keep in mind
when using vendor recommendation tables, including those based on permea-
tion tests, is that the tables are intended to provide guidance in the
selection of CPC. That is, the tables are meant as a place to start the
CPC selection process. The tables are meant for identifying candidate
CPC for further evaluation and are particularly useful for identifying
CPC from which poor performance would be expected and, therefore, which
can be dropped from consideration. In no way do the recommendations
address the wide variety of uses, challenges, and care to which the CPC
may be subjected. Most vendors strongly emphasize this point in the
descriptive text which accompanies the tables. Secondly, the vendors'
recommendations were not developed by, nor are they sanctioned by.
industrial hygienists or other safety professionals. CPC manufacturers
are in business to sell clothing and not to set the standards for safety
at any given work site. In conclusion, the principal purpose of the
catalogues is to provide information about products in terms of the
sizes, styles, and materials of construction. The ratings charts should
only be used as a starting point for further evaluation if chemical
resistance is an issue.

C. VENDORS' TEST METHODS

The quality of the test methods used by vendors to generate data to


support their recommendations range from state of the art to rudimentary.
Since the promulgation of ASTM Method F739, several CPC vendors have
generated tabulations of permeation data for their products. As addi-
tional standards are developed, an increase in testing can be expected.

It would appear, however, that many purveyors of recommendation tables


continue to rely on information provided by the supplier of the raw
materials from which the clothing is fabricated. In general, the suppli-
ers' ratings are based on some form of immersion testing, but little or
no permeation testing. Two drawbacks of this approach· are (1) the raw
material supplier may be unaware of the special needs of CPC, and (2) the
CPC vendor has no firsthand knowledge of the chemical resistance of his
products. Potential problems associated with the first drawback are:

• Chemical permeation of a rubber or plastic material can occur


with little or no physical effect on the rubber or plastic.
This mayor may not be detected by an immersion test.

• The information provided by the materials supplier is typically


developed for a general elastomer/plastic formulation or type.

52
A result is that the recommendation may not take into account
formulation modifications that are required to put the material
into a form appropriate for CPC.

A further comment on recommendation tables based on immersion testing is


that most are quite old, and based on subjective observation of immersion
test specimens rather than quantification of swelling, weight, or
strength changes. In many cases the details of the testing and the
qualitative descriptions for defining "excellent," "good," etc., were not
documented. Thus, it becomes impossible to compare results. Another
consideration associated with the age of the recommendations is that as
time passes and

1. raw materials suppliers change formulations,

2. CPC manufacturers change raw materials suppliers, and

3. CPC manufacturers change production methods,

the performance of the same "nominal" product may also change. There is
no indication that recommendations are routinely updated to reflect these
changes. except in a few exceptional cases. These considerations may
also apply to permeation data and the recommendations based on them.
Again, the CPC recol11l1Jendation tables should only be used for guidance.
This includes those presented in the next chapter.

53
CHAPTER 8
CPC RECOMMENDATIONS
In this chapter, CPC recommendations for approximately 500 chemicals or
aqueous solutions are presented. In addition, the chemicals have been
grouped into generic families (e. g., acids, amines, etc.) and general
recommendations are made for each family which is represented by more
than one chemical having CPC performance information for a given mate-
rial. The recommendations are contained in Matrices A and B, and the
data on which the recommendations are based are tabulated in Appendices A
through E in Volume II. Appendix F in Volume II contains permeation data
for several non-aqueous, multi-component solutions. The matrices are
complemented by Appendices B through H which contain information perti-
nent to the acquisition of CPC such as a directory of vendors' addresses
and telephone numbers.

A. SCOPE AND LIMITATIONS


1. Chemicals
Two matrices have been developed. Matrix A (pp. 66-120) contains CPC
recommendations for approximately 500 chemicals or aqueous solutions and
33 clothing materials. The chemicals are the liquids included in the
Clean Water Act (CWA) Sections 311 and 307a, the Clean Air Act (CAA)
Section 112, and the Resource Conservation and Recovery Act (RCRA)
Sections P, U, F, and K. Also included are any other chemicals (princi-
pally liquids but including some gases) for which there were CPC vendors'
recommendations or technical reports of permeation test results. No
recommendations are presented for non-aqueous, multi-component solutions.
Vendors' recommendations or permeation data were not available for all
the liquids addressed in the aforementioned acts. Approximately 40% of
the chemicals are included in OSHA Directive Subpart 2--Toxic and Hazard-
ous Substances, 29 CFR 1910.1000, Tables Z-l and Z-2.

2. Chemical Classes
An alphabetical list of the chemicals is presented in Appendix B. Note
where a percentage follows the name of the chemical, it is indicative of
the concentration of the chemical in water. All other liquids are
single-component. Multi-component organic solutions are not addressed
although permeation data for some are presented in Appendix F in
Volume II. The right-hand column of Appendix B contains two pieces of
information for each chemical: the chemical abstract number (CAS number)
and a numeric "chemical class" code. The code is the "key" to Matrix A
since the matrix is organized numerically by chemical class, with the
code shown in parentheses following the generic class name. The chemical
classification scheme is summarized in Table 8.1 and is based on the

54
TABLE 8.1

LISTING OF CHEMICAL CLASSES

Class Name Class Code

ACIDS, CARBOXYLIC, ALIPHATIC


Unsubstituted 102
Substituted 103
Polybasic 104
Others 106

ACID HALIDES, CARBOXYLIC


Aliphatic 111
Aromatic and Heterocyclic 112

ALDEHYDES
Aliphatic and Alicyclic 121
Aromatic and Heterocyclic 122
AMIDES
Amides 132

AMINES, ALIPHATIC & ALICYCLIC


Primary 141
Secondary 142
Tertiary 143
Polyamine 144
AMINES, AROMATIC
Primary 145
Secondary, Tertiary 146
Polyamine 147

ANHYDRIDES, CARBOXYLIC
Aliphatic 161

CYANIDES
Cyanides 215
ESTERS, CARBOXYLIC
Formates 221
Acetates 222
Higher Monobasic 223
Polybasic 224
Aromatic Phthalates 226

55
TABLE 8.1 (Continued)

LISTING OF CHEMICAL CLASSES

Class Name Class Code

ESTERS, OTHER THAN CARBOXYLIC


Sulfonates 232
Others 233

ETHERS
Aliphatic 241
Aromatic 242
Alkyl-Aryl 243

HALOGEN COMPOUNDS
Aliphatic, Unsubstituted 261
Aliphatic, Substituted 262
Aromatic, Unsubstituted 263
Aromatic, Substituted 264
Polynuclear 265
Vinyl Halides 267

HETEROCYCLIC COMPOUNDS
Nitrogen, Pyridines 271
Nitrogen, Quinolines 272
Nitrogen, Others 274
Oxygen, Epoxy Compounds 275
Oxygen, Furan Derivatives 277
Oxygen, Others 278
Sulfur 279

HYDRAZINES
Hydrazines 280

HYDROCARBONS
Aliphatic and Alicyclic 291
Aromatic 292
Polynuclear 293

HYDROXYL COMPOUNDS
Aliphatic & Alicyclic, Primary 311
Aliphatic & Alicyclic, Secondary 312
Aliphatic & Alicyclic, Tertiary 313
Aliphatic & Alicyclic, Polyols 314
Aromatic 316

56
TABLE 8.1 (Continued)

LISTING OF CHEMICAL CLASSES

Class Name Class Code

INORGANIC ACIDS
Inorganic Acids 370

INORGANIC BASES
Inorganic Bases 380

INORGANIC GASES
Inorganic Gases 350

INORGANIC SALTS
Inorganic Salts 340

ISOCYANATES
IS,ocyanates 210

KETONES
Aliphatic & Alicyclic 391
Alkyl-Aryl 393

LACTONES
Lactones 400

MISCELLANEOUS
Miscellaneous 560

NITRILES
Aliphatic & Alicyclic 431
Aromatic 432

NITRO COMPOUNDS
Unsubstituted 441
Substituted 442
Nitroso 443

ORGANIC SALTS
Organic Salts 550

ORGANO-METALLIC COMPOUNDS
Organo-Meta11ic Compounds 461

57
TABLE 8.1 (Continued)

LISTING OF CHEMICAL CLASSES

Class Name Class Code

ORGANO-PHOSPHOROUS COMPOUNDS
Organo-Phosphorous Compounds 460

ORGANO-SILICON COMPOUNDS
Organo-Silicon Compounds 480

PEROXIDES
Peroxides 300

QUINONES
Quinones 490

SULFUR COMPOUNDS
Thiols 501
Sulfides & Disulfides 502
Sulfoxides 503
Sulfonic Acids 504
Sulfonyl Chlorides 505
Others 507

58
system used by the Eastman Kodak Company. This system was selected
because it addresses a large fraction of the chemicals of concern herein.
Other classes have been added as needed.

In Matrix B (pp. 121-124), CPC recommendations are provided for the same
33 materials but in this case for generic famUies of chemicals. The
chemicals in each family and on which the Matrix B recommendations are
based are readily determined from Matrix A. Note that not all classes in
Matrix A are presented in Matrix B; furthermore, recommendations are not
given for all materials for all classe~. The criterion for being given a
recommendation in Matrix B is that the class must contain more than one
chemical with CPC recommendation for the material of concern. In many
cases there was considerable variability among the recommendations for
chemicals within a class; these 8.re indicated by double asterisks (**).
In these cases, please refer to Matrix A for specific information.

3. Materials
The 12 materials for which the most information is available are listed
across the top of the matrices. Where information on other materials was
available, recommendations for these materials are in the right-most
, column of the matrices. There were 21 such materials. A general charac-
terization of several of the physical properties of 13 of the materials
is presented in Table 8.2.

The 33 material categories were reduced from the approximately 145 types
and forms of clothing materials listed in Appendix E, and represent the
materials of construction for well over 90% of the CPC considered in the
Guidelines.

Multi-component materials are identified in two ways. Blends are indi-


cated by a "+." For example, a blend of nitrile rubber and PVC is
designated nitrile + PVC. Coated or laminated structures are indicated
by a "/." For example, nitrile rubber coated polyester fabric is desig-
nated nitrile/polyester. By grouping several types and forms of clothing
into one category, it is likely that in some cases particularly good or
particularly poor items have gone unnoted since there can be significant
differences in product quality between vendors. This is a compromise
that must be accepted and recognized in swnmary compilations such as
Matrices A and B. In genp.ra1. however, a given material will exhibit the
same performance relative to another mAterial independent of whether the
materia] s are free films or coatings and independent of source. For
example. if a butyl ruhbp.r glove is more resistant than a nitrile rubber
glove to A given chemiCAl. then it is highly likely that butyl rubber
gloves and clothing in both supported and unsupported form will be better
barrip.rs to that chemical than their nitrile counterparts. In other
words, differences in performances between products of a given material
will probably be small compared to performance differences between
categories of materials. In using the matrices. it must be remembered
that their purpose is to provide a starting point for CPC selections.

59
TABLE 8.2

PHYSICAL CHARACTERISTICS OF CPC MATERIALS *

Material (Designation Abrasion Cut Heat Ozone Puncture Tear Relative


in Matrices) Resistance Resistance Flexibility Resistance Resistance Resistance Res htance Cost

Butyl Rubber (Butyl) F G G E E G G High

Chlorinated Polyethylene E G G G E G G Low


(CPE)

Natural Rubber E E E P E E Medium

Nitrile-Butadiene E E E G E G Medium
Rubber (NBR)

Neoprene E E G G E G G Medium

Nitrile Rubber (Nitrile) E E E G E G Medium

Nitrile Rubber + polyvinyl G G G F E G G Medium


0' ChLoride (Nitrile + PVC)
0

Polyethylene G F F P Low

Polyurethane E G E G G G G High

Polyvinyl AlcohoL (PVA) P G E G Very High

Polyvinyl Chloride (PVC) G P P E G G Low

Styrene-Butadiene E G G G Low
Rubber (SBR)

Vi ton G G G G E G G Very High

* Ratings are subject to variation depen~ing on formulation, thickness, and whether the material is supported by fabric.
E-excellent; G-good; F-fair; P-poor
Selections based on the matrices' recommendations do not guarantee
protection since in no way do the matrices take into account such key
issues as the application of the CPC or quality differences between CPC
products.

4. Performance Information
The information on which the matrices are based is from three sources:

• Vendors' qualitative chemical resistance charts that are often


included in CPC catalogues. The ratings in the charts of
approximately 26 vendors (including the five largest manufac-
turers of CPC) were tabulated and reviewed by chemical and
material classes. In total, over 7,500 individual ratings
composed the tabulation.

• Qualitative chemical resistance charts from the suppliers of


CPC raw materials.

• The technical and product literature which addresses chemical


resistance and permeation testing of CPC materials and prod-
ucts. In all, over 5,200 individual test results (such as
breakthrough time, permeation rate, tensile property, and
percent weight change) were tabulated.

The vendors use a variety of rating scales; some have three grades, most
have four grades, and a few have five or six grades. In order to compare
ratings, a normalized four-grade system (i.e., A, B, C, D) was developed.
Briefly, products with the highest rating in a four- or three-grade
system or the highest two ratings in the case of a six-grade system were
given a normalized rating of "A." A normalized rating of "B" was given
to the next highest vendor's ranking, which was generally call "good,"
but in some three-grade systems was called "fair." A normalized rating
of "C" was given to the third highest vendor ranking except for the
three-grade systems. Typically, vendors called this ranking "fair."
Finally, all vendors' rankings of "poor" and "not recommended" were given
a normalized rating of "D."

B. RECOMMENDATIONS

The recommendations in Matrices A and B resulted from a comprehensive


analysis of all the information described above. Briefly, two separate
computer data bases were developed: one for qualitative resistance
information, and one for quantitative data from CPC testing. (The test
data are presented in Appendices A through D of Volume II.) No attempt
was made to validate any of the data prior to their input. The method of
analysis served as an internal validation process. The information for
each chemical/material pair in each data base was analyzed separately
using computer algorithms which took into account the amount and

61
consistency of the information for each pair. (The rationale is· de-
scribed in detail in Appendix H of Volume II.) For each data base, the
result was a classification of each chemical/material pair into one of
the four following groups:

Group 1 -- significant amount of information indicating excellent


chemical resistance.

Group 2 -- lesser amount of information indicating excellent


chemical resistance.

or

significant amount of information indicating good


chemical resistance.

Group 3 -- significant amount of information indicating fair


chemical resistance.

or

lesser amount of information indicating poor chemical


r •• i.tance.
Group 4 -- significant amount of information indicating poor
chemical resi.tance.

In all cases the algorithms were designed to produce a conservative


classification; that is, inconsistencies were resolved in favor of the
lower group.

The results of the quantitative and qualitative analyses were then


combined to produce the recommendations shown in Matrix A. Again, this
was performed by means of a computer. The rationale was that shown in
Table 8.3. In all cases of inconsistencies between the data and qualita-
tive ratings, the test data were more influential in forming the recom-
mendation. In some cases (indicated by ** in the table), technical
judgment rather than a computer algorithm was used because the informa-
tion was not readily susceptible to simple computer analysis. Rather, it
required careful consideration as to source, methods, and past experi-
ence.

Single and double, upper and lower case "r's" and "n's" are used to
convey the recommendations. Briefly, RR, R, rr, and r indicate various
degrees of good resistance and NN, N, nn, and n indicate various degrees
of poor chemical resistance. Double characters indicate that there are
test data to support the recommendations, and single characters indicate
that only qualitative information was available. Upper case characters
indicate consensus and a relatively large amount of information, whereas

62
TABLE 8.3
QUALITATIVE DESCRIPTION OF RECOMMENDATIONS IN MATRIX A*

Qualitative Ratings

Few/Excellent Many/Felr
Quantity/
MIIRY /E xcellent or or Mlny/Poor None
Resistance
Many/Good Few/Poor

Many/Excellent RR RR •• •• RR

!-.
Few/Excellent
or rr rr •• •• rr
Many/Good
Test
Data
Many/Fllr
or nn nn nn nn nn
Few/Poor

Many/Poor NN NN NN NN NN

No
None R r n N Recommend&-
tion

*Recommendations obtained by computer algorithm. See Appendix H of Volume II


for rationale .
•• Rccolllllwn<ialiolis 101 these combinations were determined on basis of technical
illd'l':/I)""I lilll"" 111.111 C()IllIHllcr al!lorithrn.
lower case indicates a relatively small amount of information or incon-
sistencies.

The recommendations in Matrix B are based on the technical judgment of


the authors upon review of Matrix A. As stated in Point 6 of Section C
which follows, Matrix B is designed to provide general guidance to the
initial steps of clothing selection.

C. USER INSTRUCTIONS
To make the most effective use of the Guidelines, references must be made
to the matrices and the appendices. Assuming that the chemical(s) for
which protection is required is known, the procedure would be as follows:

1. Go to Appendix B, an alphabetical listing of chemicals listed


in Matrix A. Find the chemical and referring to the right-most
column, its class code. If the chemical is not listed, go to
Step 6.

2. Return to Matrix A, a numerical listing of the chemicals by


class. Locate the class which contains the subject chemical by
means of the numbers in the parentheses next to the class
names. Table 8.1 is a listing of the chemical classes and
their codes.

3. Locate the subject chemical and read across to determine which


is (are) the preferred clothing material(s) for the chemical.

4. Go to Appendix C. an alphabetical listing of CPC by material


type and by product type. The vendors for the CPC are listed
in the right column. Additional information on the products
can be found by referring to Appendix E and using the first two
digits of the product code from Appendix C. Also additional
information on encapsulating ensembles and splash suits can be
found in Appendices G and H. respectively.

5. Go to Appendix D. an alphabetical listing of the vendors and


their addresses and telephone numbers. Contact the vendor(s)
and initiate procurement procedures.

6. When the specific chemical of interest is not listed in Appen-


dix B. it may be possible to narrow the CPC alternatives
through the use of Matrix B. With the help of Table 8.1,
attempt to classify the chemical; then follow the general
recommendations provided in Matrix B. At this point, two
options are open: (a) follow Steps 4 and 5 above, or
(b) return to Matrix A. In Matrix A, review all the chemicals
in the class of interest and identify the one or two that are
most similar to the specific chemical in question. Select CPC

64
on the basis of the recommendations for the similar chemicals.
Note that in Matrix B, asterisks are indicative that the
particular material exhibited considerable variability in its
resistance to the chemicals of the given class. In these cases
reference to Matrix A and caution in CPC selection is highly
advised.

During the selection and eventual use of the CPC recommended in


Matrices A and B, it is important to remember that:

1. The recommendations are based on the best information avail-


able. In some cases, however, this information is very
limited.

2. The recommendations are a guide, not a guarantee.

3. The recommendations probably do not hold for extreme use


conditions (e.g., high and low temperatures, long-term contact,
high abrasion, etc.) nor do they consider the problems associ-
ated with reuse described in Chapter 6, Part F.

4. There may be certain products in each category that are better


or poorer than the norm. Also, the quality of construction of
even the "better" products can vary from batch to batch. In
their present form, the matrices do not address quality issues.
The assessment of quality and uniformity of quality can best be
gained through field experience and, therefore, left as a task
for the field personnel. It is possible that future Guidelines
will be modified to include recommendations for specific
products that are based on quality and field performance.

5. The "double" letter recommendations are based primarily on


breakthrough time data; permeation rate data were given only
secondary consideration.

A final comment pertains to the completeness of CPC product and vendor


listings presented in the appendices. The objective was to include at
least one source for any given item of CPC. The listings, therefore, are
extensive but are probably not all-inclusive; it is unlikely that all
distributors or all brands/lines of CPC are mentioned. The listings are
designed such that they can be readily expanded to cover additional
manufacturers or distributors as they become known to the EPA or
U.S. Coast Guard. Furthermore, the recommendations can also be modified
as additional performance information becomes available to the EPA or
U.S. Coast Guard.

65
MATRIX A

RECOMMENDATIONS BY CHEMICAL

66
~ ,: ~
,Ii :
~ ,~ ,., t.;
~
e ~ ~ ~
0' e ""
~ §"
~
~ ~ ,Ii ...."
~
...."
~
v
(.j

~
~
~
~::
~Io.;.
: ~
(.1
J.;;;.
~ ~
J.;;;.

~
e ~ ~ ~ ,
~
Of
,~ ~
J.;;;.

: :;~

Acids, Carboxylic, Aliphatic


Unsubstltuted (102)
Acetic Acid R rr nn RR nn RR nn n NN rr TEfLON( rr)
NEOP+NAT RUB(RR)
NEOPRENE+SBR( r)
NAT+NEOP+NBR( r)
POLYURETHANE( r)
SARANEX(rr)
SBR( r)
VIT/CLORBUTL(rr)
NEOP/NAT RUB(RR)
SBR/NEOPRENE( r)
Acetic Acid, <30% r rr n
Acetic Acid, 30-70% r rr rr rr rr POL YURETHANE( r)
Acetic Acid, >70% nn n rr rr SBR( r)
Acrylic Acid r n TEfLON( rr)
Butyric Acid r r
'"
-...J Diacetln r r
2-Ethylhexanoic Acid rr rr rr
Formic Acid R r R R R r NN R n NEOP+NAT RUB( r)
NEOPRENE+SBR( r)
POLYURETHANE( R)
SBR( R)
SBR/NEOPRENE( r)
Formic Acid, 30-70% r
Formic Acid, >10% rr rr nn rr nn n nn NEOP+NAT RUB(rr)

Note: Numbers In parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~ ~ ~
~ ~ I<i
~
~
~.
~
~
o,J ~ ~ 4v ~
0' e~ "
o,J
~
~
~
~
~
§ ~
~
...
~
o,J
...
~
o,J
~
... ~ J
It
4:~
~!.;.
,&
!.;.
t (J ~ J ~ ~ ~ ~ t
!.;.
~ t :;~

Acids, Carboxylic, Allph'tlc (cont.)


Vnsubstltuted (cont.) (102)
Glycerin Trlacetate r r
Lauric Acid n r r
Lauric Acid, 30-70% rr rr rr nn
Li no I e Ic Ac Id r n r r r
Methy I acry I Ic Acid n r
Oleic Acid n r r nn rr rr rr rr rr rr r r NEOP+NAT RUB( r)
NEOPRENE+SBR( n)
POLYURETHANE( r)
SBR( n)
SBR/NEOPRENE( r)
Pa I mit I c Ac I d NN rr nn rr r
Propionic Acid NN TEfLON( rr)
Stearic Ac Id r R R r R R POLYURETHANE( R)
SBR( R)
'"
00 SBR/NEOPRENE( r)

Note: Numbers in parentheses are chemical class codes -- see Tab~e 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Li tt Ie, Inc.
~ ~ ~
,~ ~ 41
.,.,
~ & ~
t2 ~
~ " ~ 41 41 ~ t2 ~ ""
~ ~
41
...
" ..." C.I ~ 4::~
i' ~ ~
, " ,&
~ i' ~I..;.
t2 ....~ ~ ~
J;;.
.;:) .t' ~ ~ ~
J;;.
~~
Q) (.J
~ ~ ~ .t' ~ ~

Ae Ids, Ca rboxyl ie, AI iphat Ie (cant.)


Substituted (103)

Ch Ioroacet ie Acid NN SARANEX(rr)


lact Ic Ac Id R r r R R R R R r r NEOP+NAT RUB( nl
NEOPRENE+SBR( rl
POLYURETHANE, R)
SBR( RI
SBR/NEOPRENE( rl
Lact Ic Acid, <30% r r
Lact ic Acid, >70% rr rr rr rr rr rr rr
Ma I ic Acid r r r
Polybasic (104)
Maleic Acid n n R R n n R r POL YURETHANE( n)
SBR, rl
SBR/NEOPRENE( r)
Maleic Acid, >70% rr rr rr rr rr rr
'"
-0 Ma I ic Acid r r r
OX8 Ilc Acid rr r RR RR RR RR rr n RR rr SBR( rl
Others (106/
Benzenesulfonlc Acid rr rr

Hote: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc. 1 see Table 8.3.
Source: Arthur D. Little, Inc.
~
CI..
~ :~ ~ ~
~
I<i
~
e ~ ~
CI..
R" e '"
o,J

~ ~" ~ ...." ...."'"' 8 ~


....or
~ ~ ~ CI..
" ~ ~~
.:)
I-.
t.' ~
I-;.
e ....~ ....~
or
}! I-;. ~ ~~
'1/ CJ ~ ~ ~ ~ t.' ~
CI.. 4- ~ ~ ti~

Acid Halides. Carboxylic


A I i phs tic (111)

Acetyl Chloride n r n TEFLON( rr)


SARANEX(nn)
Ethyl Chlorocarbonate r n
Aromatic and Heterocyclic (112)

Benzoyl Chloride rr n r nn rr NN nn n HYPALON(nn)


Aldehydes
A I iphat ic and A I i cye I i c (121)

Acetaldehyde RR NN NN NN NN NN NN nn NN NN TEFLON( rr)


NEOPRENE+SBR( r)
POLYURETHANE( r)
SBR( n)
VIT/CLORBUTL(nn)
SILVERSHIELD(rr)
SBR/NEOPRENE( n)
-...J
9 Acrolein rr NN NN nn NN VIT/CLORBUTL( rr)
Butyraldehyde nn n R nn r r nn R nn r TEFLON( rr)
POLYURETHANE( n)
SBR( r)
SBR/NEOPRENE( r)
Crotonaldehyde rr nn nn NN NN TEFLON( rr)
Decanal (a II isomers) rr rr rr rr NN rr rr SARANEX(rr)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR.R.NN. etc.) see Table 8.3.
Source: Arthur D. Little. Inc.
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Aldehydes (cont. )
Aliphatic llnd Alic~'clic (cont. ) (121)

Fo rma Idehyde, <37% RR rr r NN NN nn NN RR n NN RR r TErLON( rrl


NEOP+NAT RUB( n)
NEOPRENE. "SBf\! I')
POL YURETIIANE ( r)
SSRI R)
SILV[RSUIELG(rr)
SBR/NEO~'RtNE I r)

Glutaraldehyde rr rr rr rr
Hexanal r r
Isobutyraldehyde rr nn NN NN
Propionaldehyde rr nn fiN fiN
Trichloroacetaldehyde on rr NN nn
Aromatic and Hetrocycfic (122)

benzaldehyde rr 0 n nn nn n nn NN RR N n r NEOP+NAT RUS( n)


--J NE.OPRENE+SBR( n)
r-' POLYURETHANE( 11)
SeR( r)
SBR/NEOPJ\ENi.. ( n)
Furfl'ra I RR r n NN NN nn NN NN rr N rr r TEFLONI ,.;.)
NEOPRf.NE+~BR( ro'
'!
POLYURETIIANE( n~
SeR( 0)
SILVERSHI £lD( rr)
SBR/NEC·PREH!:( 0)

I-Iote' Numvers in par'p.nthcses are chemical class codes -- see fable 8.1 arid API,',milx 3.
For explanation of recommendation codes (e.g. RR,R,NN, etc,) Ree Tablg 8.3.
Source: Arth!Jr O. Little, Irc,
~
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Afn I des
Amides (132)
nn nn nn nn NEOP+NAT RUBe n)
N,N-Dimethylacetamide SARANEX(rr)

RR nn NN n NN nn NN N NN TEfLON( rr)
Dimethylformamide NEOP+-NAT RUB(nn)
SBR( rl
VIT/CLORBUTL(rr)
SILVERSHIELD(rr)
NEOP+-NAT RUB( r)
Formamide, 30%
rr nn nn nn nn POLYURETHANE(nn)
Hexamethylphosphoamlde
r r r r r
Urea
Amlnes, Aliphatic Be AI leyel Ie
Primary (141)

Allylamine nn NN nn NN
Butylamine nn NN n NN nn NN n TEFLON(rr)
'oJ
N VIT/CLORBUTL(nn)

Iso-Butylamine nn rr n NN nn NN n VIT/CLORBUTL( rr)

Cyc lohexylamlne nn NN nn nn
Ethano I am I ne rr r n RR RR RR RR rr rr rr n n NEOPRENE+SBR( n)
POLYURETHANE( n)
SBR( n)
SBR/NEOPRENE( n)

Hote: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~ ~ lu
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Amines, AI iphatie & AI leycl Ie (cont.)


Primary (1q1) (cont.)

Ethylamine, 30-70% rr rr TEfLON( rr)


SILVERSHIELO(nn)
I sopropylaminc nn nn NN NN TEfLON( rr)
PV ACETATE( rr)
Methylamine r nn rr rr n rr SBR( r)
Methy I am i ne, 30-70% rr nn rr NN NN rr SILVERSHIELO(rr)
Monoisopropanolamine rr rr rr rr
n- Propy I am i ne nn NN TEFLON(rr)
PV ACETATE ( rr)
Secondary (142)

sec-Butylamine nn nn nn NN
'-I o i a I Iyam i ne nn rr NN rr
w
Di-n-amylamine nn rr NN rr
Dibutylamine n nn rr NN rr n
Diethylamine nn n NN NN n NN NN n NN nn n SARANEX(nn)
SBR( r)
VIT/CLORBUTL(nn)
SILVERSHIELO(rr)
Di isobutylamine nn rr rr rr

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Aminas, AI iphat ic Pc AI i eyc I i c (cont. )


Secondary (,42) (cant.)
Oi isopropylamine nn rr NN rr TEFLON( rr)
Dimethylamine rr NN nn nn NN
Oimethylethanolamine rr NN nn nn
Dipropylamine nn TEFLON( rr)
POLYCARBONAT(rr)
Ethyl-n-butylamine nn rr NN nn
Ethylenlmine nn nn NN
n-Methylethanolamine rr NN rr CELLUL ACRYL(rr)
Morpho line RR nn N r NN RR n RR NEOPRENE+SBR( n)
POLYURETHANE( n)
SBR( n)
SILVERSHIELD(rr)
SBR/NEOPRENE( n)
'-l
J:-.
Pyrrole n n

;,ote: in p:lrentheses are chemical class codes -- see Table 8.1 and Appendix B.
NlIrnber~
For exrolIHlnLion of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Anliur n. tit.tle, Inr..
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Amlnes, Aliphatic Be Allcycl ic (cont.)
Tertiary (1113)

tert-Butyl ami ne nn nn nn NN 5BR( n)


Diethano I ami ne rr n rr n nn r rr TEFLON(rr)
NEOP+NAT RUB( r)
POLYURETHANE ( n)
5BR( n)
5BR/NEOPRENE( n)
Diethylaminoethanol rr rr rr rr
Dimethylbutylamine nn nn nn NN
n-Nitrosodimethylamine nn
Tria Ilylam I ne nn rr NN rr
Tr Iethano I am I ne r r r N R rr R rr rr n r POLYURETHANE( n)
5BR( nJ
5BR/NEOPRENE( nJ
Tri ethano I am i ne, >70% rr rr r rr rr rr
-...,J Triethylamine rr n nn RR NN rr .. n
V1
Tri-n-propylamine nn rr rr rr

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g, RR,R,NN, etc.) see Table B.3.
Source: Arthur D. Little, Inc.
~ ~ ~
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Amines, Allphat ic &: AI icycllc (cont.)


polyamine (144)

1.3-Diamlnopropane nn NN rr NN
Diethylenetrlamlne rr nn nn rr
Dimethylaminopropylamine nn NN nn NN
Ethy Iened I am I ne rr nn n NN rr nn NN n TEfLON( rr)
SARANEX( rr)
Imlnoblspropylamlne rr NN nn rr
·3-Methylamlnopropylamlne rr HN nn NN
Propylenedlamlne rr rr nn rr
Tetraethylenepentamlne rr nn nn rr
N,N,N',N'-Tetramethylenedlamlne nn nn NN nn
-..J
0\
Triethylenetetramine rr rr nn rr

Amines, Aromatic
Primary (145)

Ani line RR r ,.r HN NN NN nn NN RR NN NN rr TEfLON( rr)


NEOP+NAT RUB(rr)
NEOPRENE+SBR( n)
POLYURETHANE( rl
SARANEX( rr)
SBR( nl
NEOP/NAT RUB(NN)
SILVERSHIELD(rr)
SBR/NEOPRENE( nl
Dlmethylana line n n

Note: Numbers in parentheses are chemical class codes· -- see Table 8.1 and AppendIx 8.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc. .
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Amioes, Aromatic (coot. )


Secondary, Tertiary (146)

Dicyclohexylamine n n
l-Piperazineethaneamine rr
o-Toluidine TEFLON(rr)
Po Iyami ne (1"7)

Methyl Ani line n n


Phenylenediamine n r n
Anhyd r I des, Carboxyl ic
A I iphat ic (161 J
Acet Ie Anhyd ri de rr rr NN nn NN n TEFLON(rr)

'J
Propionic Anhydride NN
-..J

Note: Numbprs in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for axplanation or recommendation codes (e.g. RR,R,NN, etc.) see Table B.3.
Source: Arthur D. L i tt Ie, Inc.
~ ,: ~
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Cyanides
Cyanides (215)
Hyd rocya n I c Acid rr r rr nn r
Hylene r r POL YURETHANEI r)
SBRI n)
SBR/NEOPRENE ( n)
Potassium Cyanide r
Sodium Cyanide, <30% rr
Sodium Cyanide, 30-70% NN

Esters, Ca rboxyl Ie
Formates (221)
Ethylene Acetate n n n n
Ethyl formate r n r R n R N n POL YURETHANE I n)
.... SBRI R)
00 SBR/NEOPRENE( r)
Methyl Ch loroformate nn
Methyl Formate n n

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B~
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~ ~ lei
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Esters. Carboxylic (cont.1
Acetates (222)
Amyl Acetate R n n nn nn nn nn NN rr nn n n NEOP+NAT RUB( rl
NEOPRENE+SBR( nl
POLYURETHANE ( n)
SBR( NI
SBR/NEOPRENE( nl
Butyl Acetate rr .. NN NN nn NN NN rr NN nn TEFLON( rr)
NEOP+NAT RUB(NNI
NEOPRENE+SBR( nl
NAT+NEOP+NBR( r)
POLYURETHANE ( rl
SBR( rl
NEOP/NAT RUB(NNI
SILVERSHIELD(rr)
SBR/NEOPRENE( n)
Butyl Cel losolve Acetate NAT+NEOP+NBR( r)
2-Ethoxyethyl Acetate n nn nn nn n r NAT+NEOP+NBR( rl

'-J
Ethyl Acetate .... nn n NN NN nn NN NN n nn n n TEFLON( rrl
NEOP+NAT RUB( r)
\0
NEOPRENE+SBR( n)
POLYURETHANE( rl
SARANEX(nnl
SBR( NI
VIT/CLORBUTL(nnl
SILVERSHIELD(rrl
SBR/NEOPRENE( n)
Ethyl Acetoacetate n r
Glycerin Trlacetate .. r

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR.R.NN. etc.) see Table 8.3.
Source: Arthur D. Little. Inc.
~ ~ ,:4J
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Esters, Carboxyl ic (cont.)


AcetBtes (222) (cont.)
Isoamyl Acetate NN NN NN nn NN NN NEOP+NAT RUBINN)
HYPALON(nn)
NEOP/NAT RUBlnn)

Isopropyl Acetate n n

Methyl Acetate rr n NN r n n NN nn NN n POL YURETHANE( nJ


SBR( n)
SBR/NEOPRENE( n)

Methyl Cel losolve Acetate NAT +NEOP+NBR ( r)

Methyl Chloroacetate SARANEX( rr)

Propyl Aceta te rr n NN n n NN NN rr N n n NEOPRENE+SBR( n)


POL YURETHANE ( nJ
SBR( n)
SILVERSHIELD(rr)
SBR/NEOPRENEI n)
~
Vinyl Acetate n r n TEFLON( rr)

Higher Monobasic (223)


Butyl Acrylate n n TEFLONI rr)

Butyl Oleate r r

Butyl Stea ra te r r

Note: Numbers in parentheses are chern/cal class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Li tt Ie, Inc.
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Esters, Carboxylic (cant.)


Higher Monobasic (223) (cont.)
Ethy I Ac ry Ia te nn NN nn NN NN rr NN NN rr TEFLON( rrl
SARANEX(rr)
VIT/CLORBUTL(nn)
Ethyl Methacrylate nn nn nn rr NN
Isobutyl Acrylate nn nn rr NN
I~opropylmethacrylate nn nn rr NN·
Methyl Acryl ate rr n NN nn rr n TEfLON( rr)
Methyl Methacrylate nn n n NN n n n NN RR NN n TEfLON(rr)
Methyl Oleate r r
Propylmethacrylate nn nn rr NN
())
Polybasic (2211)
I-'
Oibenzyl Sebacate r r
Oibutyl Sebacate r n
Oi-(2-Ethylhexyl)-Sebacate r r
Oiethyl Oxalate r r
Diethyl Sebacate r r
Diisooctyl Sebacate r r
Tannic Acid R r R R rr R rr rr r NEOPRENE+SBR( r)
POLYURETHANE( r)
SBR( R)
SBR/NEOPRENE( r)
Tannic Acid, 30-70% rr rr rr rr
Tannic Acid, >70% rr rr nn

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Esters, CarboxyliC (cont.)
Aromatic Phtha/,1tes (226)

8is(2-Ethylhexyl) Phthalate rr r rr rr RR nn NN rr r
n··Butyl Phthalate RR n r nn NN rr NN rr RR N rr r NEOPRENE+SBR( n)
POL YURETHANE( n)
SBR( r)
SILVERSHIELO(rr)
SBR/NEOPRENE( r)
Di i socty I Phtha late r r
Dimethyl Phthalate r r
DI-n-octyl Phtha late n r nn NN nn NEOP+NAT RUB( r)
Di-Sec-Octyl Phthalate r r
Methyl Sa I icylate n r
00
N

Esters, other than Carboxylic


Others (233)

Ethyl S I I iea te r r
ISflbutyl Ni tri te nn nn NN nn
letrabutyl Orthotitanate r r
lrlisooetyl Phosphate r r

Note: Numbers In parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
SOUl co: Arthur D. Li tt Ie, Inc.
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Aliphatic (24')
Butyl Ce Iloso Ive r NN rr rr n NAT+NEOP+NBR( r)
Butyl Cellosolve Acetate NA T+N EO P+NBR ( r)
Dibenzyl Ether r n N R r r R r POLYURETHANE( n)
5BR( n)
SBR/NEOPRENE( n)
Dibutylether n n
t
2,2 -Dichloroethyl Ether nn rr TEFLON( rr)
2-Ethoxyethyl Acetate n n rr n n r NAT+NEOP+NBR( r)
Ethyl Cellosolve RR r NN NN NN NN NN n NA T+NEOP+NBR( r)
Ethyl Ether NN r n NN NN nn NN NN RR nn NN n TEFLON( rr)
NEOP+NAT RUB( n)
NEOPRENE+5BR( r)
POL YURETHANE( n)
5BR( R)
00
w
VIT/CLORBUTLINN)
5ILVER5HIELD(rr)
58R/NEOPRENE( r)
Isopropyl Ether rr n NN nn rr rr nn rr n NEOP/NAT RUBINN)
Methyl Cellosolve rr n R r nn R NEOP+NAT RUB(nn)
NA T+NEOP+NBR( r)
POLYURETHANEI nJ
5BRI n)
5BR/NEOPRENE( n)
Methyl Cellosolve Acetate
Methyl Cellulose n r r r POLYURETHANE( r)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~ ~ ~
~
4J 4j
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Ethers (cont.)
Aromatic (211?)
l,3-Dioxolane n n
Alkyl-Aryl (243)
Phenyl Ethyl Ether n n

Halogen Compounds
A I i pha tie, .IJnsubstituted (261)
Allyl Chloride r rr n TEfLON( rr)
PV ACETATE( rr)
n-Butyl Ch I ori de nn rr nn rr
Carbontetrabromide r n
Carbon Tetrachloride N nn r NN NN NN N NN RR NN rr n TEfLON( rr)
NEOP+NAT RUB(NN)
<Xl NEOPRENE+SBR( n)
.$:-
POL YURETHANE( n)
5BR( N)
NEOP/NAT RUB(NN)
PV ACETATE( rr)
5ILVERSHIELD(rr)
SBR/NEOPRENE( n)
2-Chloro-l,3-butadiene r NN NN rr NN n
Chlorodibromomethane nn nn NN rr
Ch I0 r'ododeca ne r n

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur' D. I ittle, Inc.
~ ~ ~
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Halogen Compounds (cont.)


Aliphstic, Unsubstituted (267) (cant.)
Chloroform N NN r NN NN n NN NN RR NN rr n TEFLON( rr)
NEOP+NAT RUB(NN)
NEOPRENE+SBR( n)
POLYURETHANE ( r)
SARANEX(NN)
SBR( N)
VIT/CLORBUTL(rr)
NEOP/NAT RUB(NN)
SILVERSHIELD(NN)
SBR/NEOPRENE( n)
Dlchlorobromomethane nn NN rr VITON/BUTYL(rr)
l,4-Dlchloro-2-butene nn NN NN NN NN rr NN RR SARANEX(rr)
Dlch loroethane r n n n n n TEFLON( rr)
cls-Dlchloroeth~Iene nn NN NN rr
(Xl l,2-Dlchloroeth~lene NN nn NN nn
\.n
trans-l,2-Dlchloroeth~Iene NN rr NN rr
Dlchloroeth~lene (all I somers) n n
Olchloropropane (all I somers) nn TEFLON(RR)
Dlchloropropane-Dlchloropropene TEFLON(rr)
2,3-Dlchloro-l-propene nn rr NN rr
l,3-Dlchloropropene nn rr NN rr
Ethyl Bromide NN rr NN nn

Note: Numbers In parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. little, Inc.
~ ~ ~
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"&~ ...tCDmpounds teont.)


.t.' lplt.t If:', IInsubs t i tuted (261) (cant.)
Ettl¥'ena D·lb.,romlde nn nn rr NN NN NN NN RR NN nn NN TEfLON( RR)
SARANEX(NN)
£t~ten& DLchlorlde nn nn r NN NN n NN NN nn NN rr n TEfLON(nn)
NEOP+NAT RUB(NN)
POLYURETHANE( nn)
NEOP/NAT RUB(NN)
SILVERSHIELO(rr)
E~l,.d:ene Dichloride nn rr NN nn
Freen 11 n r n R n n r n SBR( n)
Frecm. 12 r n R r n r SBR( n)
Freon 21' n n n n SBR( n)
freon ~ r r n n SBR( n)
I r run,· 1:"2 r n
Freon' nlWrc? r n
freon TF n r NN RR nn RR NN nn NN r NEOP+NAT RUB(NN)
NEOP/NAT RUB(nn)
'l'8On, "Me rr rr NN NN NN rr rr CHLOROBUTYL(rr)
TEfLON(nn)
Ha"O'lMne nn rr NN nn
Haxachlorocyclopentadlene
... nn nn rr rr
t~t'Opyl Chloride r r

IIote:. NtMIbers In parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
SOtHCe: Arthur D. Little, Inc.
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Halogen Compounds (cont.)


Aliphatic, Unsubstituted (261) (cant.)

Methyl Bromide n N r r nn N r SARANEX!rr)


SBR! r)
Methyl Chloride n N n n n n N NEOPRENE+SBR! n)
POLYURETHANE ( n)
SBR( n)
SBR/NEOPRENE! n)
Methyl Chloroform NN n r NN NN NN NN NN RR NN rr n TEFLON( rr)
NEOP+NAT RUB(NN)
POLYURETHANE!NN)
NEOP/NAT RUB(NN)
SILVERSHIELD(rr)
Methylene Bromide n n n n NN rr n
Methylene Chloride NN nn r NN NN nn NN NN nn NN nn n TEFLON(nn)
00
NEOP+NAT RUB!NN)
....., VIT/CLORBUTL(NN)
NEOP/NAT RUB(NN)
SILVERSHIELD(rr)
Methyl Iodide nn NN NN NN NN rr rr NEOP+NAT RUB(NN)
NEOP/NAT RUB(NN)
Propyl Ch loride PV ACETATE! rr)
Propylene Dichloride nn rr NN rr
Tetrachlorodifluoroethane r n
l,l,l,2-Tetrachloroethane nn rr NN rr
l,l,2,2-Tetrachloroethane nn n NN NN nn NN rr NN rr TEFLON( rr)
NEOP+NAT RUB!NN)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Halogen Compounds (cont.)


Aliphatic, Unsubstituted (261) (cont.)

Tetrachloroethylene NN rr I' NN NN NN nn NN nn NN RR n TEfLON(nn)


NEOP+NAT RUDINN)
NEOPRENE+SDR( n)
POLYURETHANE I n)
SARANEX(NN)
SBRI NI
SILVERSHIELD(rr)
SBR/NEOPRENE( n)
Tetrar'uoroethylene rr rr 1'1' rr
1,l,2-Trlchloroethane nn NN NN NN NN nn NN 1'1' TEFLON( 1'1')
POLYURETHANE(NN)
Trichloroethylene NN nn NN NN NN NN NN NN NN nn CHLOROBUTYL( r)
TEFLON(RR)
NEOP+NAT RUB(NN)
NEOPRENE+SBR( n)
(X) POLYURETHANE(nn)
(X) SARANEX(NN)
SBR( N)
NEOP/NAT RUB(NN)
SILVERSHIELD(rr)
SBR/NEOPRENE( n)
1,2, 3-T 1'1 ch I orop ropane nn nn rr rr

Note~ Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix ~.
For explanation of recommendation codes (e.g. RR,R,NN, etc. I see Table 8.3.
Source: Arthur D. Little, Inc.
~
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Halogen Compounds (cont.)


Aliphatic, Substituted (262)

2-Bromoethanol rr NN NN rr
1-Bromo-2-propanol rr NN rr rr
3-Bromo-l-propanol rr rr rr rr
Ch loroacetone r n n R n N r POL VURETHANE( 0)
SBR( 0)
SBR/NEOPRENE( 0)

Chloroacetonitri Ie rr NN rr rr.
3-Chloro-2-methylpropene nn NN NN rr
1-Chloro-2-propanol rr NN NN rr
3-Chloro-l-propanol rr nn NN rr
1,2-Dibromo-3-chloropropane n n
00
1.0
Dichloroacetyl Chloride nn rr NN rr
2,2'-Dichloroethyl Ether nn RR TEFLON( rr)
Epichlorohydrin nn n NN nn nn NN NN nn nn TEFLON(RR)
POLYURETHANE(nn)
SARANEX(nn)
Ethylene Chlorohydrln rr r rr rr rr n
Trichloroacetaldehyde rr rr NN rr
2,2,2-Trichloroethanol SARANEX(nn)
Trifluoroethanol rr rr NN RR NN NEOP+NAT RUB(rr)
NEOP/NAT RUB(rr)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~ ~ ~
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Halogen Compounds (cont.)


Aromat ic, lJnsubstituted (26J)
Benzyl Chloride n nn r N N n r H n TEfLON(rr)
POLYURETHANE( n)
SBR( n)
SBR/NEOPRENE( n)
Bromobenzene nn r nn rr rr n
Bromochloromethane r r
Chlorobenzene nn n r N NN n nn NN nn NN RR n TEfLON(rr)
NEOP+NAT RUB( n)
SBR( n)
o-Chlorotoluene nn rr
p-Chlorotoluene nn rr

\0
0
o Ich lorobenzene n nn n
1,2-Dichlorobenzene r nn rr n
1,3-Dlchlorobenzene nn rr
fluorobenzene r n
1,2,4-Trichlorobenzene NN NN rr NN rr NN TEfLON( rr)
SARANEX(nn)
Aromatic, Substituted (26/i)
Pentachlorophenol NN rr NN rr

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little. Inc.
~ ~ ~
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101
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: ~~

Halogen Compounds (cont.)


Polynuclear (265)
Chloronaphthalenes (a" Isomers) r N n n rr n rr r SILVERSHIELD(RR)
Polychlorinated Biphenyls ( PCB's) nn n NN rr NN rr n rr TEFLON( rr)
SARANEX(RR)
Vinyl Halides (267)
Dlmethylvlnylchlorlde NN rr NN rr
Vinyl Chloride n rr NN n rr SILVERSHIELD(rr)
Vinylldene fluoride rr NN NN NN rr

Note: 'Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~ ~
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Heterocyclic Compounds
Nitrogen, Pyridines (271)
r NN NN HN rr n NEOP+NAT RUBINN)
pyrid I ne NEOP/NAT RUB(nn)

Nitrogen, Others (274)


Ethylenimfne nn nn NN
n n
Pi perfd fne
Oxygen, Epoxy Compounds (275)
rr rr nn rr rr rr NEOP/NAT RUB(rr)
Allyl Glycfdyl Ether
Ep i ch I 0 rohyd r i n RR n NN nn nn NN NN nn nn TEfLON(RR)
POLYURETHANE(nn)
SARNEX(nn)

',2-Epoxybutane nn NN rr NN
Ethylene Oxide r r n NN n n

Phenyl Glycidyl Ether rr rr nn nn rr nn NEOP/NAT RUB(nn)


'"
N
NN n n n NN NN n NN n TEFLON( rr)
Propylene Oxide rr n
',3-Propylene Oxide nn NN NN NN

oxygen, Furan Oerivatives (277)


Furan nn n rr HN nn n
Tetrahydrofuran NN NN NN NN NN n NN NN n NN NN NN TEFLON(rr~
NEOP+NAT UB(NN)
SARANEX(NN)
VIT/CLORBUTL(NN)
NEOP/NAT RUB(NN)

oxygen, Others (278)


',4-Dioxane RR r NN NN n NN NN n NN NN TEfLON( rr)
NEOP+NAT RUB(nn)
SARANEX(nn)

Note:' Numbers in parentheses are chemfcal class codes -- see Table 8.' and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~
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Hydrazlnes
lIydrazines (280)
l,l-Dimethylhydrazine RR nn n NN NN NN NN NN nn n CHLOROBUTYL(rr)
TEfLON(nn)
NEOP/NAT RUB(NN)
l,2-Dimethylhydrazine n n
Hydraz I ne rr n r rr rr rr n CHLOROBUTYL(rrl
TEfLON( nn)
Hydraz i ne, 30-70~ rr rr rr rr RR rr n rr SILVERSHIELD(rr)
Methy I hyd raz i ne NN nn nn rr CHLOROBUTYL(rr)
CR 39(rr)
TEfLON(NN)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~ ~ ~
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H)I'd roca rbons


Aliphatic and Alicyclic (291)
Butad iene rr NN nn NN rr

Butane n N R r n N r NEOPRENE+SBR( rJ
POL YURETtIANE( RJ
SBR( nJ
SBR/NEOPRENE( n)

Butene n r r n

Butylene r r r SBR( rJ

cyclohexane N r r NN NN n RR NN nn NN RR n TEfLON( rrJ


NEOP+NAT RUB(NN)
NEOPRENE+SBR( nJ
POLYURETHANE( n)
SBR( n)
Decahydronaphthalene r n
oecane r n
\0
~
Di I sobutylene r n
Dipentene r n
Ethane n r rr r
Ethyl Si I ieate r r
Gasoline nn r rr N rr NN rr NN rr NN r nn NEOP+NAT RUB(NN)
NEOPRENE+SBR( n)
POL YURETHANE ( R)
SBR( n)
SBR/NEOPRENE( nJ

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
4.,
~ /S ~
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Hydrocarbons (cont.)
Aliphatic and A I icyel ic (cont.) (291)

Heptane NN nn rr RR rr NN rr NEOP/NAT RU8(NN)


Hexane NN rr NN NN NN NN NN RR NN RR TEFLON( rr)
NEOPRENE+S8R( n)
POL YURETHANE( R)
SBR( N)
VIT/CLOR8UTL(rr)
SILVERSHIELD(rr)
SBR/NEOPRENE( n)
l-Hexene r n
b-Ionone rr rr
Isobutylene rr
I sooctane n r r NN NN nn NN nn nn NN r n
Isoprene nn nn rr rr
\0 JP-4, Jet Fuel n r
\J1

Ke rosene n r nn N rr rr nn rr nn r n NEOP+NAT RUB(nn)


NEOPRENE+S8R( n)
POL YURETHANE( r)
SOR( n)
SBR/NEOPRENE( n)
Methane rr
Methyl Cyclopentane r n

Minera I Spirits N rr NN rr NN rr NN NEOP+NAT RUBlnn)


SARANEX(NN)
SBR( r)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix 8.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~
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Hydrocarbons (cont.)
Aliphatic and Alicyclic (cont.) (291)
Naphtha, V.H.& P N rr r N nn NN rr NN rr NN r n NEOP+NAT RUB(NN)
NEOPRENE+SBR( n)
POLYURETHANE( R)
SBR( n)
SBR/NEOPRENE( n)

Octadecane r n

n-Octane r nn rr rr rr nn n NEOP+NAT RUB( n)


Pentane n NN NN NN NN NN nn NN RR NEOP+NAT RUB(NN)
NEOP/NAT RUB(NN)
SILVERSHIElD(rr)
Pentene r r n SBR( r)
Pinene (a II I somers) r n
Propane N N R R n rr r r NEOPRENE+SBR( n)
POL YURETHANE( R)
\0 S8Re n)
a- SBR/NEOPRENE( n)
2,2,4-Trimethylpentane r n
2,4,4-Trimethyl-l-pentene r n
Turpentine N r r N N N nn nn rr N r n TEfLON(rr)
NEOP+NAT RUB(NN)
NEOPRENE+SBR( n)
POL YURETHANE( r)
SBR( n)
SBR/NEOPRENE( n)
4-Vlnyl-l-cyclohexane nn nn nn rr

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Tabie 8.3.
Sourc.: Arthur D. Little, Inc.
..,~ ~~ ~
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Hydrocarbons (cont.)
Aromatic (292)
Benzene NN nn rr NN NN NN NN NN NN NN nn rr EVA(NN)
TEFLON( NN)
NEOP+NAT RUB(NN)
NEOPRENE+SBR( n)
POLYURETHANE(NN)
NONWOVEN PE(NN)
SARANEX(NN)
SBR( N)
NEOP/NAT RUB(NN)
PV ACETATE( rr)
SILVERSlfIELD( rr)
SBR/NEOPRENE( n)
p-tert-Butyl Toluene RR rr rr rr RR SILVERSHIElD(rr)
3-Chloro-2-methylpropene nn NN NN rr
m-Creso I nn rr rr rr NN TEFLON( rr)
NEOP+NAT RUB(nn)
1.0
-...J
NEOP/NAT RUB(rr)
Cresol s n r r nn n n SARANEX(rr)
Cumene rr r n
Cymene r n
Dlethyl Benzene r n
Dllsopropyl Benzene (a I I I somers) r n
Divlnyl Benzene RR rr rr RR SILVERSHIELD(rr)
Ethyl Benzene r n nn n n TEFLON( rr)
Gaso line nn r rr N rr NN rr NN rr NN r nn NEOP+NAT RU8(NN)
NEOPRENE+SBR( n)
POLYURETHANE( R)
S8R( n)
S8R/NEOPRENE( n)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~
Ii;
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Hydrocarbons 1cont.)
Arom6tic (cont.) (292)
JP-4, Jet Fuel n r

Kerosene n r nn N rr rr nn rr nn r n NEOP+NAT RUBlnn)


NEOPRENE+SBR( n)
POLYURETHANE( r)
SBR( n)
SBR/NEOPRENEI n)
d-Limonene rr r rr rr rr n
Natura I Cas, LI qu If I ed r n
Nit robenzene N RR NN NN n NN RR N RR TEFLON( rr)
NEOP+NAT RUB( n)
NEOPRENE+SBR( r)
POLYURETHANE( n)
SBR( n)
\J:) VIT/CLOR9UTLlrr)
00 SILVERSHIELD(rr)
SBR/NEOPRENE( n)
Styrene n rr r NH NN HN NN NN rr NN r n TEFLON( rr)
SARANEX(nn)
VIT/CLORBUTL(rr)
1,2,3,4-Tetrahydronaphthalene r n
Toluene NN r rr NN NN nn NN NN NN HN nn TEFLONI rr)
NEOP+NAT RUBI n)
POLYURETHANE I r)
SARANEX(NN)
SBR( N)
VIT/CLORBUTL(rr)
NEOP/NAT RUB(NN)
SILVERSHIELD(rr)
SBR/NEOPRENE( n)

Note:' Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~
/.oj
~
~
lei

~ I ~ ~
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-../

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Hydrocarbons (cont.)
Aromatic (cont. ) (292)
Xylene n n r NN NN NN NN NN RR NN rr n TEfLON( rr)
NEOP+NAT RUB(NN)
SBR( n)
NEOP/NAT RUB(NN)
m-Xylene NN nn nn rr RR
o-Xylene nn nn nn rr rr
p-Xylene nn nn rr NN rr

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~
4,j
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,~
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""
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Hydroxyl Compounds
Aliphstlc ~ AlicYClic, Primary (Jl1)
Allyl Alcohol RR rr rr RR rr nn NN rr rr TEFLON( rr)
SARANEX(rr)
Amyl Alcohol rr r NN RR NN nn nn rr NN rr r NEOPRENE+SBR( R)
POL YURETHANE ( R)
SBR( R)
SBR/NEOPRENE( R)
Butyl Alcohol R r nn RR nn RR RR nn nn r TEFLON( rr)
NEOP+NAT RUB(nn)
NEOPRENE +SBR ( n)
POL YURETHANE( r)
SBR( n)
SBR/NEOPRENE( n)
n-Butyl Carbitol r r
Butyl Cellosolve r NN rr rr n NAT+NEOP+NBR( r)
....
0
Ca rb i to I r r
0 Diacetin r r
Diethylaminoethanoi rr nn rr rr
Ethano I, 30-70% rr
Ethano I, >70% rr
Ethanolamine rr r n RR RR RR rr rr n RR n n NEOPRENE+SBR( n)
POLYURETHANE( n)
SBR( n)
SBR/NEOPRENE( n)
Ethyl Cellosolve rr r NN NN NN NN NN n NAT+NEOP+NBR( R)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur O. Little, Inc.
~ ,.,
f.,j
,:~ ~
e~ ~
~
...~
c! ,., ~" e ~ eo,
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~ ~
... ~ '" "-
.;:.
~
~~

Hydroxyl Compounds (cont.)


Aliphatic & Alicyclic, Primary (cant.) (111 )

Ethyl Alcohol R NN NN nn RR NN rr NN r TEFLONI rr)


NEOP+NAT RUBlnn)
NEOPRENE+SBRI r)
POL YURETHANE I n)
SBRI n)
NEOP/NAT RUBlrr)
S6R/NEOPRENEI r)
Ethylene Chlorohydrin rr r rr rr rr n
2-Ethyl-l-Hexanol rr rr rr rr
Glycols r r
Hexyl Alcohol r r
Isobutyl Alcohol rr r nn NN NN RR NN n NN rr r NEOP+NAT RUB( r)
SBRI r)

......
Methanol rr rr rr NN NN nn NN nn NN NN nn rr TEFLON( rr)
0 NEOP+NAT RUB(NN)
...... NEOPRENE+SBRI r)
NAHNEOP+NBR( r)
POL YURETHANE( r)
SARANEX(rr)
SBRI R)
VIT/CLORBUTL(rr)
NEOP/NAT RUB(NN)
PV ACETATEI rr)
SBR/NEOPRENE( r)
Methanol, <30S rr
Methano I, >10% rr

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Hydroxyl Compounds (cont. )


Aliphatic & Alicyclic, Primary (cont.) (311)
rr n R r nn R NEOP+NAT RUH(on)
Methyl Ce 11050 I ve NflT+NEOP+NOR( rJ
POL YURETHANE( 1'1)
SBR( nJ
SBR/NEOPRENE( n)

1-0ctano I r r

n-Octano I r r nn RR rr RR rr RR r POLYURETHAN[( nJ
SBR( R)
SOR/NEOPRENE( r)

Propyl Alcohol r r nn RR NN RR NN n nn r r TEFLON! rr)


NEOPRENE+SBR( r)
POLYURETHANE( r)
SBR( r)
..... PV ACETATE ( rr)
0
N
SBR/NEOPRENE( r)

2.2.2-TrlchlorDcthanol SARANEX(nn)

Trlrluoro~thanol rr rr NN RR NN NEOP+NAT RUB(rr)


NEOP/NAT RUB(rr)

AI iphatic & A I i eyc I i c, Secondary (312)


Cumene rr r n

Cyc I ohexal'1o I n r r NN NN nn RR rr RR rr RR r SILVERSHIELD(rr)

2-Furylmethallol n r

Isopropyl Alr.ohol rr rr r NN RR nn RR NN nn r r CHLOROBUTYL(rr)


TEFL.ON( RR)
N[OP+NAT RUB(NN)
NAT+IlEOP+NBH( r)
SBR( r)
NFOP/NAT RUB(nn)

Isopropyl Chloride r '"


R r r R R R R R r
Lact I c Ac i d '"

Note: ' Numbers in parentheses are chemical class codes -- see Table 8. 1 and Appendix B.
For explanation of recommendation codes (e.g. RR.R.NN. etc. ) see Table 8.3.
Source: Arthur O. l.ittle, Inc.
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Hydroxyl Compounds (cont.)


Aliphstic ~ Alicyclic, Tertillry (3131
Lact ic Acid, <30% r r
Lact ic Acid, >70% rr rr rr rr rr rr rr
te rt-Butano I rr r NN rr NN r
Ci tric Ac id r R R R R R r NEOP+NAT RUB( r)
NEOPRENE+SBR( r)
POL YURETHANE( R)
SBR( R)
SBR/NEOPRENE( r)
Citric Acid, <30% rr rr rr rr rr nn rr
Diacetone Alcohol r n r R r R r POLYURETHANE( n)
SBR( r)
SBR/NEOPRENE( r)
Terpineol r n
I-'
0 Aliphstic & Alicyclic, PolyOls (3741
w
Diethylene Glycol r r r r
Diisopropyl Ketone n n
Ethylene Glycol R r r RR rr RR RR RR rr nn r r TEFLON( rr)
NEOP+NAT RUB(RR)
NEOPRENE+SBR( n)
POLYURETHANE( r)
SBR( R)
NEOP/NAT RUB(rr)
SBR/NEOPRENE( r)
Glycerol r r r R r R r r NEOP+NAT RUB( r)
POLYURETHANE( n)
SBR( R)
SBR/NEOPRENE( r)
Phenolphthalein rr rr rr rr
Propylene Glycol rr rr RR rr NEOP/NAT RUB(rr)

Note: Numbers in parentheses are chemIcal class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Hydroxyl Compounds (cont.)


Aromlltic (316)
Benzyl Alcohol rr r r R r r R rr r POLYURETHANE ( n)
SBR( R)
SBR/NEOPRENE( r)

Benzyl Benzoate r r

n-Butyl Benzoate r r

Creosote n r H rr r R r rr r SBR( r)

Creosote, Wood rr rr

m-Cresol nn rr rr rr NN TEFLON( rr)


NEOP+NAT RUB(nn)
NEOP/NAT RUB(rr)

Crasols n r r nn n n SARANEX(rr)

Ethyl Benzoate r r
.... rr rr
0
~
Nonylphenol
Pentach,orophenol NN rr NN rr
Phenol R nn NN nn n NN rr nn NN n TEFLON(rr)
NEOP+NAT RUB(rr)
NAT+NEOP+NBR( r)
POLYURETHANE( r)
SBR( n)
NEOP/NAT RUB(rr)
SBR/NEOPRENE( r)

Pheno I, <30~ rr
Phenol, >70% RR NN nn NN rr NN RR
Pic ric Ac i d r R R r R n r r

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B;
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Inorganic Acids
Inorganic Acids (370)

Boric Acid ,.,. rr rr r rr


Chlorosulfonic Acid n rr n n SARANEX(rr)
Chromic Acid n ,. NN N RR N r,. RR r
Chromic Acid, <30~ NEOP+NAT RUB(rr)
Chromic Acid, 30-70~ n n r n n nn
fluoroboric Acid r r
fluorosil icic Acid r ,.
Hydrobromic Acid ,. r R r R POLYURETHANE( nl
SBR( "1
SBR/NEOPRENE ( r)
Hydrobromic Acid, 30-70S r r
....
0 ,.,.
VI Hydrochloric Acid nn rr rr RR RR rr NN rr rr CHLOROBUTYL(rr)
TEFLON(nn)
NEOP+NAT RUB(rr)
NEOPRENE+SBR( n)
NAT+NEOP+NBR( r)
POLYCARBONAT(rr)
POLYURETHANE( n)
SARANEX(rr)
SBRI r)
NEOPRENE+PVC(rr)
SBR/NEOPRENE( n)
Hydrochloric Acid, <30~ ,. RR rr rr rr rr n rr r NEOP+NAT RUB(rr)
SBRI r)
NEOP/NAT RUB(rr)

Note: Numbers in parentheses are che.lcal class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur O. Little, Inc.
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Inorganic Acids (cont.)


Inorganic Acids (cont.)(J70)
Hydrochloric Acid, 30-70% r r RR RR n RR nn n nn rr r NEOP+NAT RUB(rr)
SARANEX(rr)
NEOP/NAT RUB(RRI
SILVERSHIELD(rr)
Hydrochloric Acid, >70% rr NEOP+NAT RU8(rr)
NEOP/NAT RUB(rr)
Hydrofluoric Acid nn r rr N N n n rr NN rr rr NEOPRENE+SBR( n)
POLYCARBONAT(rr)
POLYURETHANE( n)
SARANEX(rr)
SBR( n)
NEOPRENE+PVC(rrl
SBR/NEOPRENE( n)
Hyd ro f I uo ric Acid, <30% r R r r NAT+NEOP+NBR( r)
Hyd ro r I uo ric Acid, 30-70% r RR rr NN nn rr n nn r r NEOP+NAT RUB(RR)
SARANEX(nn)
....0 SBR( r)
NEOP/NAT RUB(rrl
0-

Hydrofluoric Acid, >70% rr NEOP+NAT RUB(rr)


NEOP/NAT RUB(rr)
Iodine Pentafluorlde n n
Ni trlc Acid n rr rr n rr nn n rr NN rr rr CHLOROBUTYL(rr)
TEFLON(nn)
NEOP+NAT RUB(rr)
NAT+NEOP+NBR( r)
POLYURETHANE( nl
SARANEX(rr)
SBR( n)
SILVERSHIELD(rr)
NEOPRENE+PVC(rrl
SBR/NEOPRENE( nl

Note~ Numbers In parentheses are chemical class codes -- see T-~Ie 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, I see Table 8.3.
",-"~",,,. Arthur D. Little, Inc.
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Inorganic Acids (cont.)


Inorgsnic Acids (cont.) (J70)
Nitric Acid, <30~ r r rr rr rr rr nn rr r NEOP+NAT RU8(rr)
NAT+NEOP+N8R( r)
SBR( r)
NEOP/NAT RU8(rr)
Nitric Acid, 30-70~ rr n nn n rr r NEOP+NAT RU8(rr)
SARANEX(rr)
NEOP/NAT RU8(rr)
Nitric Acid, >70~ n n nn n NN nn nn n NN rr SARANEX(rr)
S8R( r)
NEOP/NAT RU8(rr)
Nitric Acid, fuming Red nn nn rr rr rr NN NN rr CHLOR08UTYL(rr)
TEfLON(nn)
NEOP/NAT RU8(rr)
SILVERSHIELO(nn)
~
0
......
Perch lorl c Ac I d r r N rr rr rr rr rr r r NEOPRENE+S8R( n)
POLYURETHANE( n)
S8R( n)
S8R/NEOPRENE( n)
Perchloric Acid, 30-70~ n rr r rr n rr
Phosphoric Acid r rr rr rr rr rr n rr NEOP+NAT RUB( r)
NEOPRENE+SBR( n)
NAT+NEOP+NBR( r)
POLYURETHANE( n)
SARANEX(rr)
SBR( r)
S8R/NEOPRENE( n)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Li tt Ie, Inc.
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Inorganic Acids (cont.)


Inorganic Acids (cont.J(J70J
Phosphoric Acid, <30' r r r r r
Phosphoric Acid, 30-70% r r
Phosphoric Acid, >70~ r r RR rr rr rr rr rr r NEOP+NAT RUB( rr)
NEOP/NAT RUB( rr)
Phosphorus Oxych I0 rl de nn NN nn NN nn NONWOVEN PE(NN)
SARANEX(nn)
PV ACETATE(NN)
Phosphorus Trichloride r r
Su I fu ric Ac i d n RR rr N rr nn n rr NN rr rr CHLOROBUTYL(rr)
THLON(nn)
NEOP+NAT RUB(rr)
NEOPRENE+SBR( n)
NAT+NEOP+NBR( n)
POLYURETHANE( nJ
NONWOVEN PE(NN)
..... SARANEX(RR)
0 SBR( n)
00 VIT/CLORBUTL(rr)
SILVERSHIELD(rr)
NEOPRENE+PVC(rr)
SBR/NEOPRENE( n)
Sulfuric Acid, <30~ r r r R rr R RR rr r NEOP+NAT RUB( r)
NAT+NEOP+HBR( r)
NONWOVEN PE(nn)
SARANEX(rr)
SBR( r)
Su I fu rI c Ac i d, 30-70~ r rr rr rr rr rr rr r NEOP+NAT RUB(rr)
NONWOVEN PE(NN)
SARANEX(rr)
NEOP/NAT RUB(rr)
Sulfuric Acid, >70' r r n n nn N RR n NN rr TEFLON( rr)
NONWOVEN PE(NN)
SARANEX(rr)
SBR( r)
NEOP/NAT RUB(rr)
Sulfur Monochlorlde r n

Note: Numbers in parentheses are chemical c/a'i codes -- see Table 8.1 and Appendix B.
For explanation Of recommendation code. (e.g. RR,R.NN, etc. ) see Table 8.3.
Source: Arthur D. Li tt Ie, Inc.
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Inorganic Bases
Inorganic Bases (380)

Ammonium Hydroxide R r rr rr NN rr NN n NN r NEOP+NAT RUB(nn)


NEOPRENE+SBR( r)
POLYURETHANE( r)
SBR( R)
SBR/NEOPRENE( r)
Ammonium Hydroxide, <30~ RR RR RR NN rr
Ammonium Hydroxide, 30-70~ rr rr r rr NN R
Calcium Hydroxide r r
Potassium Hydroxide r R R r R R n NEOPRENE+SBR( r)
POLYURETHANE( n)
SBR( r)
SBR/NEOPRENE( r)
Potassium Hydroxide, <30~ r r
Potassium Hydroxide, 30-70~ r r r RR RR RR RR rr n RR r NEOP+NAT RUB(rr)
to"
SBR( r)
0
\0 Sodium Hydroxide n rr R R rr R rr rr POLYURETHANE( r)
SBR( r)
VIT/CLORBUTL(rr)
SILVERSHIELD(rr)
SBR/NEOPRENE( r)
Sodium Hydroxide, <301 rr NEOP+NAT RUB(rr)
Sodium Hyd rox I de, 30-70~ rr r rr RR RR RR RR RR n RR RR rr TEFLON( rr)
NAT+NEOP+NBR( r)
NONWOVEN PE(NN)
SARANEX(RR)
SBR( r)
NEOP/NAT RUB(rr)
NEOPRENE+PVC(rr)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
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Inorganic Glses
Inorg6n;c Cases (350)

Ammonia n r r n r
Bromine NN
Ch lorlne n r rr n rr n NN NN rr rr SARAAEX(rr)
FI uorl ne n r r r n
Hydrocyanic Acid rr r rr nn r
Hydrogen Phosphide nn NN nn nn
Hydrogen Sui fide r r n R r R POLYURETHANE( n)
SBR( r)
5BR/NEOPRENE( n)
Nickel Carbonyl r r r
NI trlc Oxide r r r
HI trogen Dioxide n n
.....
.....
0
Nitrogen Tetroxide nn rr n rr nn nn n CHLOROBUTYL(rrl
TEFLON(NN)
eR 39(rr)

Note: Numbers in parentheses are chemical class codes -- see Table B.l and Appendix 8.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table B.3.
Source: Arthur D. little, Inc.
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Inorganic Salts

Inorganic Salts (.140)


Ammon I urn Fluoride NEOP+NAT RUB( r)

Ammonium Fluoride, 30-70% rr rr rr rr

Ammonium 5ul fa te r R R r r R POL YURETHANE ( R)


SBR( r)
5BR/NEOPRENE( r)

Arsenic Trichloride n n

Bromine T r i f luo ride n n

Calcium Chloride r R R r r R POL YURETHANE ( r)


SBR( r)
5BR/NEOPRENE( r)

Calcium Hypochlorite r R R r r R POL YURETHANE( r)


SBR( n)
5BR/NEOPRENE( n)

Copper Chloride n r r r POL YURETHANE( r)


......
......
...... Copper 5u/fate n R r R POL YURETHANE ( r)
SBR( r)

Cupric Chloride r n R r R POLYURETHANE ( r)


SBR( n)
SBR/NEOPRENE( n)

Cupric 5u I fate r n R r r R POL YURETHANE( r)


SBR( n)
SBR/NEOPRENE( n)

Ferric Chloride r r R r R POL YURETHANE( r)


SBR( r)
SBR/NEOPRENE( r)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
s.
Source: Arthur D. Little, Inc.
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Inorganic Salts (cont.)


Inorganic Salts (cont.)(J40)
Potassium Dichromate r r R r R POLYURETHANE ( n)
SBR( r)
SBR/NEOPRENE( r)
Potass I um Bromide r r r
Potass I um Ch loride r
Potassium Cyanide r
Silver Nitrate r r n
Sodium Chloride r
Sodium Hypoch lor i te, 30-70% rr rr rr rr rr
Sodium Si I icate r r
Sodium Sulfide r r
..... Sodium Thiosulfate r r
.....
N
Stannous Chloride r r R r R POLYURETHANE( r)
SBR( r)
SBR/NEOPRENE( r)
Isocyanates
Isocyanates (210)
Methyl Isocyanate nn NN NN rr NN
Toluene 01 Isocyanate RR rr HH n rr rr RR nn RR TEFLOH(RR)
SILVERSHIELO(RR)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~ ~ ~
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Ketones
A I iphatic & Alicyclic (391)
Acetone RR HN NN NN nn NN NH HN NN NN TEFLON( rr)
NEOP+NAT RUB(NN)
NEOPRENE+SBR( n)
NA T+NEOP+NBR ( r)
POLYURETHANE ( r)
SARANEX(nn)
SBR( n)
VIT/CLORBUTL(nn)
NEOP/NAT RUB(NN)
PV ACETATE( rr)
SILVERSHIELO(rr)
SBR/NEOPRENE( n)
Cyclohexanone rr n n nn rr n nn n NEOP+NAT RUB(nn)
SILVERSHIELO(rr)
Olacetone Alcohol r n r R r R r POLYURETHANE( n)
SBR( r)
SBR/NEOPRENE( r)
Oi Isobutyl Ketone n n nn nn n rr NN rr H
I-'
I-' Oi Isobutyl Ketone, >70% RR RR rr RR SILVERSHIELO(rr)
w
Isophorone n r
Mesltyl Oxide nn n r VIT/ClORBUTl(rr)
4-Methoxy-4-methyl-2-pentanone rr rr rr nn
Methyl n-Butyl Ketone r n

Hote: Numbers In parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur O. Little, Inc.
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Ketones (cont.)
A I i phs tie & A I i eye lie (eont.)(391)
Methyl Ethyl Ketone RR nn NN NN NN NN NN NN nn NN NN NN CHLOROBUTYL(rr)
TEFLON(nn)
NEOP+NAT RUB(NN)
NEOPRENE+SBR( n)
POLYURETHANE( r)
SARANEX(NN)
SBR( r)
VIT/CLORBUTL(nn)
NEOP/NAT RUB(NN)
SBR/NEOPRENE( n)
Methyl Isobutyl Ketone NN n n NN NN nn NN NN rr nn nn n TEFLON(rr)
NEOP+NAT RUB( n)
SBR( r)
Methyl-vinyl-ketone nn VIT/CLORBUTL(rr)
N-Methyl-2-pyrrolldone NN NN NN NN
I-'
....
~ Alkyl-Aryl (J9J)
Acetophenone n r TEFLON(rr)
Lactones
Lsetones (1100)
beta-Proplolactone rr nn nn nn NN nn nn POLYURETHANE(NN)

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
SOI'-"e: Arthur D. Little, Inc.
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Miscellaneous

Niscellaneous (560)
Asphalt r n

Mercury r r r r

Mi nera I Oi I r n

Hote: Numbers in parentheses are chemical class codes -- so~ T~~le 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, (;tc,) f,ce Table 8.3.
Source: Arthur D. Little, Inc.
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...~
~ ~
...~ ~
'Of'
.30.
~
J;;;.
q,
J...
.::. t;~

Nltrlles
Aliphatic ~ Alicyclic (431)
Acetonitrile RR rr nn NN NN NN NN rr NN rr rr TEfLON( rr)
NEOP+NAT RUB( r)
SARANEX(rr)
VIT/CLORBUTL(rr)
SILVERSHIELD(rr)
Acryl on i trll e n nn N r n n NN N n TEfLON(nn)
NEOPRENE+SBR( n)
POL YURETHANE( r)
SARANEX(nn)
SBR( n)
SBR/NEOPRENE( n)
Bromoacetonitrile rr NN rr rr
Ch'oroacetonitrile rr NN rr rr
Ethyl Cyanide nn NN rr NN
........ I soamy I nit r I Ie nn rr rr rr
0'1 ~ethacrylonltrlle rr NN nn NN
Trlchloroacetonltrile rr rr rr rr
Va I e ron i t r i Ie rr NN nn rr
Aromatic (432)
Benzon I tri Ie rr NN rr nn

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~
I,;
~ ~
I,;
~
~
e ~ , ,.,
~
0' e ~
'"
-./

~ ~ ~ ~ :!
~
-./

E' ~ ! , ~
~
...
-./
...
-./ (J
-./
or ~ E'
o:tS
1,;1.;.

~
~
(.I '"
~ ~
I.;.

~
e ...
~
...~
~ ~ ,
~
,~ '"~ ~ t~

Nitro Compounds
Unsubstituted (11117)
Nitrobenzene rr rr NN NN n NN RR N RR TEFLON( rr)
NEOP+NAT RUB( n)
NEOPRENE+SBR( r)
POL YURETHANE( n)
SBR( n)
VIT/CLORBUTL(rr)
SllVERSHIElD(rr)
SBR/NEOPRENE( n)
Nltroethane rr n NN nn rr r NEOP+NAT RUB( r)
Nit rog I yce r i ne r r
Ni tromethane rr NN rr nn rr NN n n
Nit ropropane RR n nn NN NN NN NN nn nn POLYURETHANE(nn)
SILVERSHIELD(rr)
l-N It rop ropane rr nn rr nn TEFLON( rr)
2-N i t r~p ropane rr NN nn rr
I-'
I-'
'-I Nitrotoluene r r POLYURETHANE ( n)
SBR( r)
SBR/NEOPRENE( r)
o-Nltrotoluene nn
p-N I t roto I uene . rr POLYCARBONAT(rr)
2,4,6-TrinltrotoIUene n N N r R POLYURETHANE ( n)
SBR( n)
SBR/NEOPRENE( n)
Substituted (*"2)
2-Chloro-2-nitropropane rr NN rr nn
n-Nltrosodimethylamlne nn
Picric Acid r R R r R n r r

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~
I.;
~ ~
# ,
~
I.;

e~ : ~ it eo, ~
~
e~ ~

~
"
~ ~
~

~ I ~ ~
.... ~
.... CJ
: ttC~
~
~

~ ~ ~~

--
....~ ~ ~

: ~
CJ ~'" ~
#.;;.

~
....
~ ,
~
,
~
~ '" ~ ~~

Organ Ic Sa I ts
Organic salts (.5.50)
Benzethonlum Chloride rr rr rr rr
Organo-Metailic Compounds
Organo-Netsllic Compounds (461)
Ti tanlum Tetrachloride r n
Triethyl Aluminum n n
Tri octy I Phosphine r r
Organo-Phosphorous Compounds
Organo-Phosphorous Compounds (460)
Tributyl Phosphate r r
T,-I c rasy I Phosphate rr r r nn nn rr n rr RR rr rr r NEOPRENE+SBR( n)
POL YURETHANE( n)
SBR( n)
.....
..... SBR/NEOPRENE( r)
00 Trllsooctyl Phosphate r r

Note: Numbers In parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR.R.NN. etc.) see Table 8.3.
Source: Arthur D. Little. Inc.
~
l.; Ql
IS ~
l.;
~ ~ ~ ~
..."""
~
e ct-
c... 4.
t! c... g e ~

~ ~""
~ ..."" ..."" ~
"'ct-IS
(,j
~ ~ ~ ~ ~ "" ~ i' ,...
... ...~ ;:
~
J..
.:) ;: "
~
~ ~ ~ " .:) t~
Ql V ~ ~ ~ ~ 4. 4. ~ Ql

Peroxides
Peroxides (JOO)
alpha,alpha-Dimethylbenzyl Hydroperoxide TEfLON( rr)
Hydrogen Peroxide nn rr r r R r n nn r r TEFLON( nn)
NEOP+NAT RUB( r)
NEOPRENE+SBR( r)
POL YURETHANE ( r)
SBR( r)
SBR/NEOPRENE( r)
Hydrogen Peroxide, <30% CHLOROBUTYL(rr)
NAT+NEOP+NBR( r)
Hydrogen Peroxide, 30-70% RR NN rr rr n rr NEOP+NAT RUB(rr)
POLYURETHANE( r)
SBR( r)
NEOP/NAT RU8(rr)
Hydrogen Peroxide, >70% r n
Methyl Ethyl Ke tone Pe rox i de rr nn rr rr
Quinones

........
\0
Quinones (490)
Hydroquinone n R R rr r rr n rr r SBR( r)
Hyd roqu I none, <30% rr rr rr rr

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. Little, Inc.
~ ~ ~

e'" e'"
~ ~ ~ ~
~ ~
it
4-
g
0'
~""
~ ~
~
~
i" e t1c~
(,j
...." ...." ~ ~~
~ ~
J.;;;. J.;;;.
~ ~
....~
"
'q"
~
J.;;;. ~ ;;~
~
It.'
~ ~ ~ ~ ~
....
~ t' ~
4- 4- ~ ~

Sulfur Compounds
Thiols (~01)

tert-Butyl Mercaptan n n
Ethyl Mercaptan n n
Thionyl Chloride r n
Thiophenol nn rr
Su,rides Ii Oisulrides (~02)

Calcium Bisulfate, 30-70S r r


Carbon Disulfide NN NN N N n NN NN RR N RR TEfLON(nn)
NEOP+NAT RUB(NN)
POLYURETHANE( n)
SBR( H)
VIT/CLORBUTL(NN)
SBR/NEOPRENE( n)
Su,roxides (503)
~ Gimethyl Sulfoxide rr RR RR rr nn rr NN VIT/CLORBUTL(rr)
N
0 NEOP/NAT RUB(rr)
Sulfonic Acids (~04)

Methanesulfonic Acid rr rr
p-Toluenesulfonic Acid rr rr rr
Others (507)

Disulfur Dichloride r n

Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B.
for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Source: Arthur D. l i tt Ie, Inc.
MATRIX B

RECOMMENDATIONS BY CHEMICAL CLASS

121
~
t.j
~
CI)
~
t.j

e~
§
ct' ,
~ Q'
e~
"
-./
~ ~ ~ ~
~
4J
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t.j
ct'~
(.j
-./
....
-./

i' ~ ! ~
.... -./
~ i' ~I.:.
~
Q)
~
()
J;;.
~ ~
I.:.
~
e ...~ ~
....~
~ ~ , '" ,~
~
~
J;;.

~ ~~

Ac Ids, Ca rboxyllc, Allphat Ic


Unsubstituted R r r ** rr ** rr NN ** ** ** r
Polybasic rr rr rr rr n rr
Aldehydes
AI iphat ic and Alicyclic RR NN r ** NN nn NN ** NN NN ** r
Aromatic and Hetrocycl ic rr n nn nn n nn NN rr N r
Amides
Amides rr ** nn nn nn nn
Amlnes, Allphat Ic & Alicyclic
Prima ry ** ** n NN ** rr nn ** **
Seconda ry ** n NN nn ** ** NN ** n
I-'
N
Tertiary ** ** ** ** ** ** ** ** rr
N
Polyamine ** NN ** nn NN rr
Cyanides
Cyanides r
Esters, Ca rboxyl I c
formates n n n
Acetates ** ** n NN nn nn NN NN ** NN n **
Higher Monobasic nn nn ** NN nn nn NN rr NN **
Po Iybas ic r r r ** rr r
Aromatic Phthalates rr r ** ** ** nn rr r
Ethers
AI iphatic ** rr ** NN ** ** ** ** ** **

Note: for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Class recommendations only for chemicals classes in which two or more chemicals· have
recommendations for a given material. Double asterisks (**) indicate a wide variation in ratings.
Source: Arthur D. Little, Inc.
~
/oj
~ ~
~ /oj

e
~
~ ,~ ~
oJ
~
~ '?
oJ
~ t! w ~
~ §" /oj 'oJ
..." 8 .~
"
Q:~
,.;~
~ ~ ~

...~ ~...~ ~
oJ
J.. ,.; ~
J::' ~J..
~ ~
(./ ~ ~
~
~ ~ ,
~ ~
<t. ~
"C!
~'
Q:)
~~

Halogen Compounds

AI iphatic, Unsubst.ituted nn nn r NN NN NN NN NN ** NN .. « n

AI iphatlc, Substituted ** NN "r nn ** NN r'


Aromat Ic, Unsubstltuted nn nn r N n nn NN N rJ n

Polynuclear NN nn rr
",., !"
VinYl Halides :~

Heterocyclic Compounds

fpoxy Compounds ** ** n" nn NN ,,* nr, ~"l

furan De r I va t I ve s nn nn NN fir' n

Hyd raz I nes

Hyd raz i nes ** nn n ** ** ** nn 'I" .... n

Hyd roca rbons


~ Aliphatic Be A I i cyc I I c N r r NN ** ** ** ** 'I" NN "lR. n
N
w
Aromat ic ** rr r NN NN NN ** NN ** N~ Rf1 n

Hydroxyl Compounds

Aliphatic Be AI Icyc Ii c, Prima ry RR rr rr nn ** nn ** ** 'I" ** rr

Aliphatic Be Allcyc Ilc, Secondary rr rr r ** ** ** rr rr ** rr

Aliphatic Be AI Icye I Ie, Tertiary r ** rr rr rr *"


AI I phat ic Be AI icyc I ic, Polyols r ** rr rr rr rr ** **
Ar'oma tic ** r ** ** ** ** ** nn ** rr

Inorganic Acids

Inorganic Acids ** ** rr ** ** ** ** ** n ** rr ....

Note: for explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Class recommendations only for chemicals classes In which two or more chemicals h~vp
recommendations for a given material. Double asterisks (**) Indicate a ",Ide varjf·ti~r ;'1 t"litings.
Source: Arthur D. Little, Inc.
~ ~ ~
c.;
~
,~ ,~
e~ ~
~ ,: t., f
'oJ
e ~
'"
'oJ

~ 8 ~
'oJ

~ !
c.;
~
...
'oJ
...
'oJ
'oJ
~
4:~
i' t' e ~
...~ t' ~ i' ~'"
~ Col ~
I;;.
'"
~ ~ ~ ~
,~
,~ ~
I;;.
.::.
4b
:;~

Inorganic Bases
I norgan I c Bases r r RR RR ** RR ** n ** rr r
Inorganic Gases
Inorganic Gases ** r n n r ** ** ** **
Inorganic Salts
Inorganic Salts r n ** r r r R

Isocyanates
Isocyanates NN n rr
Ketones, Aliphatic
Ketones, Aliphatic ** NN n NN NN N ** NN ** NN NN **
Nltri les, AI iphatlc
Nitrlles, AI i phat Ic rr NN ** NN rr NN rr
I-'
N
+:- Nitro Compounds
Unsubstituted rr r NN ** nn ** ** **
Organo-Phosphorous Compounds
orgno-Phosphorous compounds r r
Peroxides
Pe rox ides r
Sui fur Compounds
Thiols ** n

Note: For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.
Class recommendations only for chemicals classes in which two or more chemicals have
recommendations for a given material. Double asterisks (**) Indicate a wide variation In ratings.
Source: Arthur D. Little, Inc.
APPENDIX A

GLOSSARY

A-I
GLOSSARY
ABS Polymer of acrylonitrile, butadiene, and styrene; a strong,
rigid material used for structural components.

Acetate -- Polymer of cellulose acetate; a clear, relatively inexpen-


sive material used for face and eye protection.

Acrylic -- Polymer of methyl methacrylate; clear plastic used for face


and eye protection.

Baypren -- See Neoprene.

Blend -- An intimate mixture of two or more materials.

Breakthrough Time The time elapsed between initial contact of a


chemical with the outside surface of a protective clothing material and
the time at which the chemical can be detected at the inside surface of
the material. Measured breakthrough times are dependent on the sensi-
tivity of the analytical methods used to detect the chemical and the
experimental procedures.

Butyl Rubber Copolymer of isobutylene and a small amount of


isoprene. Material has good resistance to weathering and a wide
variety of chemicals. Both supported and unsupported forms of butyl
rubber are used as protective clothing.

Cellulose Propionate - - Polymer; clear plastic used for face and eye
protection.

Chlorinated Polyethylene -- CPE, Chloropel-. A polyethylene elastomer


wi th a chlorine content of 36% to 45%. The material generally has
better chemical resistance and physical properties than polyethylene.

Chlorobutyl Rubber - - A chlorinated form of butyl rubber. Generally


has better heat than butyl rubber.

Chloroprene Rubber -- See Neoprene.

Chlorosulphonated Polyethylene See Hypalon-.

Contamination -- The presence of potentially harmful chemicals on the


surface of or within the polymer of CPC.

Copolymer -- A long chain molecule synthesized by reaction of more than


one monomer species with each other. Copolymers often have cost and/or
performance advantages over polymers produced from a single monomer
species.

A-2
CPE -- See Chlorinated Polyethylene.

CR-39 N Polymer of allyl diglyco1 carbonate. A clear, impact resis-


tant plastic used for face and eye protection.

Decontamination - - The removal of potentially harmful chemicals from


the surface of and from within the polymer of epe. Note surface
decontamination does not necessarily remove absorbed chemical.

Degradation -- The loss in physical properties of an item of protective


clothing due to exposure to chemicals, use, or ambient conditions
(e.g., sunlight).

Ethylene Vinyl Alcohol -- See EVOH.

EVALN -- See EVOH.

EVOR - - Polymer of ethylene vinyl alcohol. This polymer exhibits a


high resistance to non-polar organic compounds. However since it is
susceptible to attack by acids, bases and water, it is used as an
internal layer in laminates.

FEP Polymer of fluorinated ethylene propylene. Polymer with


exceptionally good chemical resistance with protective clothing appli-
cations in both film and coating form.

Flock-lined or Flocked -- A layer of fibers, typically cotton, adhered


to the inside of rubber gloves. The lining absorbs perspiration and
provides some insulating effect.

Gore-Tex N Fabric -- A proprietary fabric in which microporous PTFE is


laminated on one or both sides with a fabric. The fabric allows the
transmittance of moisture vapor which reduces heat stress. It prevents
penetration by many liquids and solids but does not provide vapor
protection.

HypalonN - - Polymer produced by the post chlorination and su1fonation


of polyethylene, thereby producing a rubbery material suitable for epe.

Laminated -- Joining two or more sheets or fabrics together by means of


heat or adhesive.

Latex -- A stable dispersion of polymer or rubber particles in water.


Latex gloves and coated fabrics are prepared by coagulating and cross-
linking the particles on a form or cloth substrate. Most natural
rubber, neoprene, and nitrile gloves are prepared from latices.

Latex-Dipped - - A glove prepared by dipping a glove form or a fabric


glove into a rubber latex bath. In one dip, the entire amount of
rubber that will form the glove is deposited.

A-3
Natural Rubber -- Polyisoprene obtained from rubber plants. A highly
flexible and conforming material used principally for gloves. High
elasticity.

Neoprene - - Polychloroprene. A synthetic rubber having chemical and


wear resistance properties that are generally superior to those of
natural rubber.

NBR (Nitrile-Butadiene Rubber) -- See Nitrile Rubber.

Nitrile Rubber -- Copolymer of acrylonitrile and butadiene. Also known


as acrylonitrile rubber, acrylonitrile-butadiene rubber, Buna-N, and
nitrile-butadiene rubber (NBR). Trademark names include HycarN,
Kyrnac N , and Paracril N • Used for supported and unsupported gloves and
coated fabric. Nitrile rubbers are available in a wide range of
acrylonitrile concentrations. In general, the higher the acrylonitrile
concentration the better the chemical resistance. However, stiffness
also increases at higher acrylonitrile concentrations.

PE -- See Polyethylene.

Penetration -- The movement of chemical through Zippers, stitched seams


or imperfections (e.g., pinholes) in a protective clothing material.

Permeation - - The process by which a chemical dissolves in and moves


through a protective clothing material on a molecular level.

Permeation Rate - - The rate at which the chemical moves through the
clothing material. This is expressed in terms of amount per unie area
per unit time.

Polycarbonate - - A hard, transparent plastic used for face and eye


protection. It has exceptional impact resistance and good chemical
resistance, and is commonly used as the lens of safety glasses.

Polyester -- A family of polymers that finds application in fiber form


as clothing and in film form as a clear material for face and eye
protection.

Polyethylene A fairly chemically resistant material that is used as


a freestanding film (e.g., apron) or a fabric coating .. Low density
polyethylene is the most common form used in protective clothing.

Polyurethane An extensive and multi-branched family of polymers


based on isocyanates. As used in protective clothing, polyurethanes
are rubbery polymers that are either coated onto fabrics or formed into
boots.

A-4
PolYVinyl Alcohol - - A water-soluble polymer that, as long as it is
dry, exhibits exceptional resistance to many organic solvents that
rapidly permeate most rubbers. The material is somewhat stiff, thus
limiting dexterity.

PU -- See Polyurethane.

PVA See Polyvinyl Alcohol.

PVC See Polyvinyl Chloride.

PVDC -- Polymer of polyvinylidene chloride.

Polyvinyl Chloride -- A stiff polymer that is made suitable for protec-


tive clothing applications by the addition of plasticizers. Used as a
freestanding material for gloves, aprons, etc., as well as coatings for
fabrics. Clear forms are also available as flexible face shields.

Safeguard CPF -- A proprietary non-woven fabric for limited use (i.e.,


disposable) clothing.

Saran N -- See PVDC.

Saranex® -- Multi-layer laminate of polyethylene and SaranN •

Solvent-Dipped -- A glove prepared by repeatedly dipping a glove form


or glove substrate into a solution of the rubber in a solvent. The
rubber is subsequently cured.

Sontara@ -- Proprietary spun-laced, limited use fabric.

SBR (Styrene-Butadiene Rubber) Also known as Buna-S. Trademark


names include Solprene lll , Plioflexlll , and StereonN • Used for fabric
coatings and boots.

Supported -- Materials containing a substrate such as cotton, polyester


or nylon fabric or scrim which is coated, laminated or impregnated with
a polymer or rubber.

TFE (PTFE) -- Polytetrafluoroethylene. An example is Teflon®.

Tyvek® - - A proprietary, porous non-woven fabric limited use (e. g. ,


disposable) clothing. Tyvek® may be coated with polyethylene or
SaranexN film.

Viton® -- A proprietary fluoroelastomer. Highly chemically resistant,


but expensive synthetic elastomer.

A-S
APPENDIX B

CHEMICAL INDEX

B-1
CHEMICAL NAKES AND SYNONYMS

NAME: Acetaldehyde CASNO: 00075070


SYN: CLASS: 121
NAME: Acetamide CASNO: 00060355
SYN: CLASS: 132
NAME: Acetic Acid CASNO: 00064197
SYN: CLASS: 102
NAME: Acetic Acid, <30\ CASNO: 00064197
SYN: CLASS: 102
NAME: Acetic Acid, 30-70\ CASNO: 00064197
SYN: CLASS: 102
NAME: Acetic Acid, >70\ CASNO: 00064197
S1N: CLASS: 102
NAME: Acetic Anhydride CASNO: 00108247
SYN: CLASS: 161
NAME: Acetone CASNO: 00067641
SYN: CLASS: 391
NAME: Acetone Cyanohydrin CASNO:
SYN: (See 2-Kethylactonitrile) CLASS:
NAME: Acetonitrile CASNO: 00075058
SYN: ClASS: 431
NAME: Acetophenone CASNO: 00098862
SYN: CLASS: 393
NAME: Acetyl Bromide CASNO: 00506967
SYN: CLASS: 111
NAME: Acetyl Chloride CASNO: 00075365
SYN: ClASS: 111
NAME: Acetylene CASNO: 00074862
SYN: ClASS: 291

B-2
CHEMICAL NAMES AND SYNONYMS

NAME: Acrolein CASNO: 00107028


SYN: CLASS: 121

NAME: Acrylamide CASNO: 00079061


SYN: Propeneamide, 2 CLASS: 132

NAME: Acrylic Acid CASNO: 00079107


SYN: CLASS: 102

NAME: Acrylonitrile CASNO: 00107131


SYN: CLASS: 431

NAME: Adipic Acid CASNO: 00124049


SYN: Hexanedioic Acid CLASS: 104

NAME: Alkazene CASNO: 00093527


SYN: Dibromoethylbenzene CLASS: 262

NAME: Allyl Alcohol CASNO: 00107186


SYN: CLASS: 311

NAME: Allylamine CASNO: 00107119


SYN: CLASS: 141

l;JAME: Allyl Chloride CASNO: 00107051


jYN: CLASS: 261

NAME: Allyl Glycidyl Ether CASNO: 00106923


SYN: CLASS: 275

NAME: Aluminum Acetate CASNO: 08006131


SYN: Burow's Solution CLASS: 222

NAME: Aluminum Chloride CASNO: 07446700


SYN: CLASS: 340

NAME: Aluminum Fluoride CASNO: 07784181


SYN: CLASS: 340

NAME: Aluminum Hydroxide CASNO: 21645512


SYN: CLASS: 340

B-3
CHEMICAL NAMES AND SYNONYMS

NII.NE: Aluminum Nitrate CASNO: 13473900


Syt1: CLASS: 340

NAME: Aluminum Phosphate CASNO: 07784307


SYN: CLASS; 340

NAME: Aluminum Sulfate CASNO: 10043013


SYN: CLASS: 340

NAME: Aminoethanol,2 CASNO:


SYN: (See Ethanolamine) CLASS:

NAME: Ammonia CASNO: 07664417


SYN: CLASS: 350

NAME: Ammonium Carbonate CASNO: 10361292


SYH: CLASS: 340

NAME: Ammonium Chloride CASNO: 12125029


SYN: CLASS: 340

NAME: Ammonium Fluoride CASNO: 12125018


SYN: CLASS: 340

NAME: Ammonium Fluoride, 30-70% CASNO: 12125018


SYN: CLASS: 340

NAME: Ammonium Hydroxide CASNO: 01336216


SYN: CLASS: 380

NAME: Ammonium Hydroxide, <30% CASNO: 01336216


SYN: CLASS: 380

NAME: Ammonium HydroXide. 30-70% CASNO: 01336216


SYN: CLASS: 380

NAME: Ammonium Hydroxide. >70% CASNO: 01336216


SYN: CLASS: 380

NAME: Ammonium Nitrate CASNO: 06484522


SYN: CLASS: 340

B-4
CHEMICAL NAMES AND SYNONYMS

NAHE: Ammonium Nitrate, <30t CASNO: 06484522


SYN: GlASS: 340

NAME: Ammonium Persu1fate CASNO: 07727540


SYN: ClASS: 340

NAME: Ammonium Phosphate CASNO: 07722701


S'lN: ClASS: 340

NAHE: Ammonium Phosphate, <30% CASNO: 07722701


SYN: ClASS: 340

NAME: Ammonium Sulfate CASNO: 07783202


sm: ClASS: 340

NAME: Ammonium Sulfide CASNO: 12135761


SYN: ClASS: 340

NA..~E: Amyl Acetate CASNO: 00628637


S'.tN: Pentyl Acetate ClASS: 222

Ni.ME: Amyl Alcohol CASNO: 00071410


SYN: Pentanol ClASS: 311

TAME: Aniline CASNO: 00062533


.:iYN: Benzamine ClASS: 145

NAME: Aniline, >70% CASNO: 00062533


SYN: CLASS: 145

NAME: Antimony Penta chloride CASNO: 07647189


SYN: ClASS: 370

NAME: Aroclor CASNO:


SYN: (See Polychlorinated Biphenyls (PCBs)) ClASS:

NAME: Arsenic Trichloride CASNO: 07784341


SYN: CLASS: 340

NAME: Asphalt CASNO: 08052424


SYN: ClASS: 560

B-5
CHEMICAL NAMES AND SYNONYMS

NAME: Aziridine CASNO:


SYN: (See Ethylenimine) ClASS:

NAME: Benzal Chloride CASNO:


SYN: (See Benzyl Dichloride) CLASS:

NAME: Benzaldehyde CASNO: 00100527


SYN: CLASS: 122

NAME: Benzamine CASNO:


SYN: (See Aniline) CLASS:

NAME: Benzendiol,l,3 CASNO:


SYN: (See Resorcinol) CLASS:

NAME: Benzene CASNO: 00071432


SYN: CLASS: 292

NAME: Benzenesulfonic Acid CASNO: 00098679


SYN: CLASS: 106

NAME: Benzenesu1fony1 Chloride CASNO: 00098099


SYN: CLASS: 505

NAME: Benzenethio1 CASNO:


SYN: (See Thiopheno1) CLAS~:

NAME: Benzethonium Chloride CASNO: 00121540


SYN: CLASS: 550

NAME: Benzidine CASNO: 00092875


SYN: ClASS: 147

NAME: Benzonitri1e CASNO: 00100470


SYN: CLASS: 432

NAME: p-Benzoquinone CASNO: 00106514


SYN: CLASS: 490

NAME: Benzotrich1oride GASNO: 00098077


SYN: Trich1oromethy1-benzene ClASS: 263

B-6
CHEMICAL NAMES AND SYNONYMS

NAME: Benzoyl Chloride CASNO: 00098884


SYN: ClASS: 112

NAME: Benzyl Alcohol CASNO: 00100516


SYN: ClASS: 316

NAME: Benzyl Benzoate CASNO: 00120514


SYN: ClASS: 316

NAME: Benzyl Chloride CASNO: 00100447


SYN: Chloromethyl Benzene ClASS: 263

NAME: Benzyl Dichloride CASNO: 00098873


SYN: Benzal Chloride ClASS: 263

NAME: 2,2'-Bioxirane CASNO: 01464535


SYN: Erythritol Anhydride ClASS: 275

NAME: Bis(2-chloroethoxy) Methane CASNO: 00111911


SYN: ClASS: 241 262

NAME: Bis(ch1oromethy1) Ether CASNO: 00542881


SYN: Dichloromethy1 Ether,sym- ClASS: 262 241

\ME: Bis(2-Ethy1hexyl) Phthalate CASNO: 00117817


.,YN: ClASS: 226

NAME: Boric Acid CASNO: 10043353


SYN: ClASS: 370

NAME: Bromine CASNO: 07726956


SYN: ClASS: 350

NAME: Bromine Cyanide CASNO:


SYN: (See Cyanogen Bromide) ClASS:

NAME: Bromine Trifluoride CASNO: 07787715


SYN: ClASS: 340

NAME: Bromoacetonitri1e CASNO: 00590170


SYN: ClASS: 431

B-7
CHEMICAL NAMES AND SYNONYMS

NAME: Bromobenzene CASNO: 00108861


SYN: ClASS: 263

NAME: Bromochloromethane CASNO: 00074975


SYN: ClASS: 263

NAME: 2-Bromoethanol CASNO: 00540512


SYN: ClASS: 262

NAME: Bromomethane CASNO:


SYN: (See Methyl Bromide) ClASS:

NAME: 4-Bromophenyl Phenyl Ether CASNO: 00101553


SYN: ClASS: 242 265

NAME: I-Bromo-2-propanol CASNO: 19686738


SYN: ClASS: 262

NAME: 3-Bromo-l-propanol CASNO: 00627189


SYN: ClASS: 262

NAME: Burow's Solution CASNO:


SYN: (See Aluminum Acetate) ClASS:

NAME: Butadiene CASNO: 00106990


SYN: ClASS; 291
NAME: Butane CASNO: 00106978
SYN: ClASS: 291

NAME: Butanediol,1,3 CASNO;


SYN: (See 1,3-Buty1ene Glycol) ClASS;

NAME: Butanethiol, 1 CASNO;


SYN: (See n-Buty1 Mercaptan) ClASS:

NAME: Butanol, 1 CASNO:


SYN: (See Butyl Alcohol) ClASS:

NAME: tert-Butano1 CASNO: 00075650


SYN: Methy1propanol, 2-,2- CLASS; 313

B-8
CHEMI CAL NAMES AND SYNONYMS

NAME: Butanone,2 CASNO:


SYN: (See Methyl Ethyl Ketone) CLASS:

NAME: Butenal,trans-2 CASNO:


SYN: (See Crotonaldehyde) CLASS:

NAME: Butene CASNO: 00106989


SYN: CLASS: 291

NAME: Butoxyethano1, 2 CASNO:


SYN: (See Butyl Cellosolve) CLASS:

NAME: Butoxyethylacetate, 2 CASNO:


SYN: (See Butyl Cellosolve Acetate) CLASS:

NAME: Butyl Acetate CASNO: 00123864


SYN: CLASS: 222

NAME: Butyl Acrylate CASNO: 00141322


Sl.'N: CLASS: 223

NAME: Butyl Alcohol CASNO: 00071363


SYN: Butanol, 1 CLASS: 311

NAME: Butylamine CASNO: 00109739


'iYN: CLASS: 141

NAME: iso-Butylamine CASNO: 00078819


SYN: Methylpropylamine, 2- CLASS: 141

NAME: see-Butylamine CASNO: 13952846


SYN: CLASS: 142

NAME: tert-Butylamine CASNO: 00075649


SYN: CLASS: 143

NP.ME: n-Butyl Benzoate CASNO: 00136607


SYN: CLASS: 316

NAME: Butyl Benzyl Phthalate CASNO: 00085687


SYN: CLASS: 226

B-9
CHEMICAL NAMES AND SYNONYMS

NAME: n-Buty1 Carbito1 CASNO: 00112345


SYN: CLASS: 311
NAME: Butyl Ce11oso1ve CASNO: 00111762
SYN: Butoxyethanol, 2 CLASS: 241 311
NAME: Butyl Celloso1ve Acetate CASNO: 00112072
SYN: Butoxyethylacetate, 2 CLASS: 222 241
NAME: n-Butyl Chloride CASNO: 00109693
SYN: Chlorobutane, 1- CLASS: 261
NAME: Butylene CASNO: 25167673
SYN: CLASS: 291
NAME: l,3-Butylene Glycol CASNO: 00107880
SYN: Butanedio1,l,3 CLASS: 314
NAME: n-Buty1 Mercaptan CASNO: 00109795
SYN: Butanethio1, 1 CLASS: 501
NAME: tert-Buty1 Mercaptan CASNO: 00075661
SYN: CLASS: 501
NAME: Butyl Oleate CASNO: 0014277'
SYN: CLASS: 223
NAME: n-Buty1 Phthalate CASNO: 00084742
SYN: CLASS: 226
NAME: Butyl Stearate CASNO: 00123955
SYN: CLASS: 223
NAME: p-tert-Buty1 Toluene CASNO: 27130212
SYN: CLASS: 292
NAME: Butyra1dehyde CASNO: 00123728
SYN: CLASS: 121
NAME: Butyric Acid CASNO: 00107926
SYN: CLASS: 102
NAME: Calcium Bisulfate, 30-70% CASNO: 13780035
SYN: CLASS: 502

B-10
CHEMICAL NAMES AND SYNONYMS

NAME: Calcium Chloride CASNO: 10043524


SYN: CLASS: 340

NAME: Calcium Hydroxide CASNO: 01305620


SYN: CLASS: 380

NAME: Calcium Hydroxide, <30% CASNO: 01305620


SYN: CLASS: 380

NAME: Calcium Hypochlorite CASNO: 07778543


SYN: CLASS: 340

NAME: Calcium Hypochlorite, <30% CASNO: 07778543


SYN: CLASS: 340

NAME: Carbitol CASNO: 00111900


SYN: CLASS: 311

NAME: Carbolic Acid CASNO:


SYN: (See Phenol) CLASS:

NAME: Carbon Bisulfide CASNO:


SYN: (See Carbon Disulfide) CLASS:

'AME: Carbon Disulfide CASNO: 00075150


dYN: Carbon Bisulfide CLASS: 502

NAME: Carbon Oxyfluoride CASNO: 00353504


SYN: CLASS: 350

NAME: Carbontetrabromide CASNO: 00558134


SYN: Te trabromome thane CLASS: 261

NAME: Carbon Tetrachloride CASNO: 00056235


SYN: Tetrachlorometbane CLASS: 261

NAME: Carbonyl Chloride CASNO:


SYN: (See Phosgene) CLASS:

NAME: Cellosolve Acetate CASNO:


SYN: (See 2-Ethoxyetbyl Acetate) CLASS:

B-ll
CHEMICAL NAMES AND SYNONYMS

NAME: Chloral CASNO:


SYN: (See Trichloroacetaldehyde) CLASS:

NAME: Chlorine CASNO: 07782505


SYN: CLASS: 350

NAME: Chlorine Cyanide CASNO:


SYN: (See Cyanogen Chloride) CLASS:

NAME: Chloroacetaldehyde CASNO: 00107200


SYN: CLASS: 121 262

NAME: Chloroacetic Acid CASNO: 00079118


SYN: CLASS: 103

NAME: Chloroacetone CASNO: 00078955


SYN: CLASS: 262

NAME: Chloroacetonitrile CASNO: 00107142


SYN: ClASS: 262 431

NAME: p-ChloroanUine CASNO: 00106478


SYN: Ch1orobenzamine,4 ClASS: 145 264
NAME: Ch1orobenzamine,4 CASNO:
SYN: (See p-Chloroanl1lne) CLASS:
NAME: Chlorobenzene CASNO: 00108907
SYN: CLASS: 263
NAME: 2-Chloro-l,3-butadlene CASNO: 00126998
SYN: Ch1oroprene CLASS: 261

NAKE: Chlorobutane,l- CASNO:


SYN: (See n-Buty1 Chloride) CLASS:

NAME: p-Ch1oro-m-creso1 CASNO: 00059507


SYN: CLASS: 292 316 264

NAKE: Ch1orodibromomethane CASNO: 00i24481


SYN: CLASS: 261

B-12
CHEMICAL NAMES AND SYNONYMS

NAME: Chlorododecane CASNO: 00112527


SYN: ClASS: 261

NAME: Ch1oroethane CASNO: 00075003


SYN: ClASS: 261

NAME: Chloroethanol CASNO:


SYN: (See Ethylene Ch1orohydrin) ClASS:

NAME: Chloroethene CASNO:


SYN: (See Vinyl Chloride) ClASS:

NAME: 2-Chloroethyl Vinyl Ether CASNO: 00110758


SYN: ClASS: 241 262

NAME: Chloroform CASNO: 00067663


SYN: Trichloromethane ClASS: 261

NAME: Chloromethane CASNO:


SYN: (See Methyl Chloride) ClASS:

NAME: Chloromethyl Benzene CASNO:


SYN: (See Benzyl Chloride) ClASS:

NAME: Chloromethyl Methyl Ether CASNO: 00107302


~YN: ClASS: 241 262

NAME: 3-Chloro-2-methy1propene CASNO: 00563473


SYN: ClASS: 262 292

NAME: 2-Chloronaphthalene CASNO: 00091587


SYN: ClASS: 265

NAME: Chloronaphthalenes (all isomers) CASNO: 25586430


SYN: ClASS: 265

NAME: 2-Chloro-2-nitropropane CASNO: 00594718


SYN: ClASS: 442

NAME: 2-Chlorophenol CASNO: 00095578


SYN: ClASS: 316 264

B-13
CHEKICAL NAMES AND SYNONYMS

NAME: 4-Chlorophenyl Phenyl Ether CASNO: 07005723


SYN: ClASS: 265 242

NAME: Chloroprene CASNO:


SYN: (See 2-Chloro-l,3-butadiene) ClASS:

NAME: Chloropropane CASNO:


SYN: (See Isopropyl Chloride) ClASS:

NAME: Chloropropane, 1 CASNO:


SYN: (See Propyl Chloride) ClASS:

NAME: l-Ch1oro-2-propano1 CASNO: 00127004


SYN: ClASS: 262

NAME: 3-Ch1oro-1-propano1 CASNO: 00627305


SYN: ClASS: 262

NAME: 3-Ch1oropropionitri1e CASNO: 00542767


SYN: ClASS: 262 431

NAME: Ch1orosulfonic Acid CASNO: 07790945


SYN: ClASS: 370

NAME: o-Chlorotoluene CASNO: 00095498


SYN: ClASS: 263

NAME: p-Ch1oroto1uene CASNO: 00106434


SYN: ClASS: 263
NAME: Chromic Acid CASNO: 11115745
SYN: ClASS: 370

NAME: Chromic Acid, <30% CASNO: 11115745


SYN: ClASS: 370

NAME: Chromic Acid, 30-70% CASNO: 11115745


SYN: ClASS: 370

NAME: Chromic Acid, >70% CASNO: 11115745


SYN: ClASS: 370

B-14
CHEKICAL NAMES AND SYNONlHS

NAME: Citric Acid CASNO: 00077929


SYN: CLASS: 313

NAME: Citric Acid, <30, CASNO: 00077929


SYN: CLASS: 313

NAME: Copper Chloride CASNO: 01344678


SYN: CLASS: 340

NAME: Copper Sulfate CASNO: 01344736


SYN: CLASS: 340

NAME: Creosote CASNO: 08001589


SYN: CLASS: 316
NAME: Creosote. Wood CASNO: 08021394
SYN: CLASS: 316
NAME: m-Cresol CASNO: 00108394
SYN: CLASS: 292 316
NAME: Cresols CASNO: 01319773
SYN: CLASS: 292 316
NAME: Crotona1dehyde CASNO: 04170303
;YN: 8utena1.trans-2 CLASS: 121
NAME: Cuaene CASNO: 00098828
SYN: Methylethyl Benzene CLASS: 292 312
NAME: Cupric Chloride CASNO: 07447394
SYN: CLASS: 340
NAME: Cupric Chloride. <30t CASNO: 07447394
SYN: CLASS: 340
NAME: Cupric Nitrate CASNO: 03251238
SYN: ClASS: 340
NAME: Cupric Sulfate CASNO: 07758987
SYN: ClASS: 340

8-15
CHEMICAL NAMES AND SYNONYMS

NAME: Cupric Sulfate, <30% CASNO: 01758987


SYN: CLASS: 340
NAME: Cyanogen CASNO: 00460195
SYN: CLASS: 350
NAME: Cyanogen Bromide CASNO: 00506683
SYN: Bromine Cyanide CLASS: 215 350
NAME: Cyanogen Chloride CASNO: 00506774
SYN: Chlorine Cyanide CLASS: 215 350
NAME: Cyc10hexane CASNO: 00110827
SYN: ClASS: 291
NAME: Cyc1ohexanol CASNO: 00108930
SYN: CLASS: 312
NAME: Cyclohexanone CASNO: 00108941
SYN: ClASS: 391
NAME: Cyclohex.y1amine CASNO: 00108918
SYN: ClASS: 141
NAME: Cymene CASNO: 251551 c1
SYN: ClASS: 292
NAME: Decahydronaphthalene CASNO: 00091178
SYN: ClASS: 291
NAME: Decana1 (all isomsers) CASNO: 00112312
SYN: ClASS: 121
NAME: Decane CASNO: 00124185
SYN: ClASS: 291
NAME: Diacetin CASNO: 25395317
SYN: Glycerol Diacetate ClASS: 311 102
NAME: Dlacetone Alcohol CASNO: 00123422
SYN: CLASS: 391 313

B-16
CHEMICAL NAMES AND SYNONYMS

NAME: Diallyamine CASNO: 00124027


SYN: CLASS: 142

NAME: Diamine CASNO:


SYN: (See Hydrazine) CLASS:

NAME: Diaminoethane,l,2 CASNO:


SYN: (See Ethylenediamine) CLASS:

NAME: l,3-Diaminopropane CASNO: 00109762


SYN: CLASS: 144

NAME: Di-n-amy1amine CASNO: 02050922


SYN: CLASS: 142

NAME: Dibenzy1 Ether CASNO: 00103504


SYN: ClASS: 241

NAME: Dibenzy1 Sebacate CASNO: 00140249


SYN: ClASS: 224

NAME: l,2-Dibromo-3-chloropropane CASNO: 00096128


SYN: ClASS: 262

lJ~: Dibromoethane, 1 ,2 CASNO:


J: (See Ethylene Dibromide) ClASS:

NAME: Dibromoethy1benzene CASNO:


SYN: (See A1kazene) CLASS:

NAME: Dibromomethane CASNO:


SYN: (See Methylene Bromide) ClASS:

NAME: Dibuty1amine CASNO: 00111922


SYN: ClASS: 142

NAME: Dibuty1ether CASNO: 00142961


SYN: CLASS: 241

NAME: Dibuty1 Sebacate CASNO: 00109433


SYN: CLASS: 224

B-17
CHEMICAL NAMES AND SYNONYMS

NAME: Dichloroacetyl Chloride CASNO: 00079367


SYN: CLASS: 262

NAME: Dichlorobenzene CASNO: 25321226


SYN: CLASS: 263

NAME: 1,2-Dichlorobenzene CASNO: 00095501


SYN: CLASS: 263

NAME: 1,3-Dichlorobenzene CASNO: 00541731


SYN: CLASS: 263

NAME: 1,4-Dich1orobenzene CASNO: 00106467


SYN: CLASS: 263

NAME: Dich1orobromomethane CASNO: 00075274


SYN: CLASS: 261

NAME: 1,4-Dich1oro-2-butene CASNO: 00110576


SYN: CLASS: 261

NAME: Dichloroethane CASNO: 01300216


SYN: CLASS: 261

NAME: Dich1oroethane,1,1 CASNO:


SYN: (See Ethylidene Dichloride) ClASS:

NAME: Dich1oroethane.l,2 CASNO:


SYN: (See Ethylene Dichloride) CLASS:

NAME: cis-Dich1oroethylene CASNO: 00156592


SYN: CLASS: 261

NAME: Dichloroethy1ene,1,1 CASNO:


SYN: (See Viny1idene Chloride) CLASS:
NAME: 1,2-Dich1oroethy1ene CASNO: 00540590
SYN: CLASS: 261

NAME: trans-1,2-Dich1oroethylene CASNO: 00156605


SYN: CLASS: 261

B-18
CHEMICAL NAKES AND SYNONYMS

~.AME: Dichloroethylene (all isomers) CASNO: 25323302


SYN: CLASS: 261

NAME: 2,2 ' -Dich1oroethyl Ether CASNO: 00111444


SYN: CLASS: 241 262

NAME: Dich1oroisopropy1 Ether CASNO: 00108601


SYN: CLASS: 241 262

NAME: Dich1oromethane CASNO:


SYN: (See Methylene Chloride) CLASS:

NAME: Dichloromethyl Ether,sym- CASNO:


SYN: (See Bis(ch1oromethy1) Ether) CLASS:

NAME: 2,4-Dich1oropheno1 CASNO: 00120832


SYN: CLASS: 264 316

NAME: 2,6-Dich1oropheno1 CASNO: 00087650


SYN: CLASS: 264 316

NAME: Dich1oropheny1arsine CASNO: 00696286


SYN: Phenyl Dichloroarsine CLASS: 461

NAME: Dichloropropane 1,2 CASNO:


«:!YN: (See Propylene Dichloride) CLASS:

rlAME: Dichloropropane (all isomers) CASNO: 26638197


SYN: CLASS: 261

NAME: Dichloropropane-Dich1oropropene CASNO: 08003198


SYN: ClASS: 261

NAME: 2,3-Dichloro-l-propene CASNO: 00078886


SYN: CLASS: 261

NAME: Dichloropropene(s) CASNO: 26952238


SYN: CLASS: 261

NAME: 1,3-Dichloropropene CASNO: 00542756


SYN: ClASS: 261

B-19
CHEMICAL NAMES AND SYNONYMS

NAME: Dicyc1ohexy1amine CASNO: 00101837


SYN: CLASS: 146

NAME: Diethano1amine CASNO: 00111422


SYN: CLASS: 143

NAME: Dietby1amine CASNO: 00109897


SYN: CLASS: 142

NAME: Diethy1aminoethano1 CASNO: 00100378


SYN: CLASS: 311 143

NAME: D1ethy1arsine CASNO: 00692422


SYN: CLASS: 461

NAME: Diethy1 Benzene CASNO: 25340174


S"iN: CLASS: 292

NAME: Diethylene Dioxide,l,4 CASNO:


SYN: (See l,4-Dioxane) CLASS:

NAME: Diethylene Glycol CASNO: 00111466


SYN: CLASS: 314

NAME: Dlethy1enetriamine CASNO: 00 1114Cv


SYN: CLASS: 144
NAME: Dl-(2-Etby1hexy1)-Sebacate CASNO: 00122623
SYN: Dloctyl Sebacate CLASS: 224
NAME: l,2-Dietbylbydrazine CASNO: 01615801
SYN: CLASS: 280
NAME: O,O-Dietbyl S-Kethyl Dlthiophosphate CASNO: 03288582
SYN: CLASS: 460
NAME: Diethyl-p-nitropheny1 Phosphate CASNO: 00311455
SYN: CLASS: 460 442
NAME: Diethyl Oxalate CASNO: 00095921
SYN: CLASS: 224

B-20
CHEMICAL NAMES AND SYNONYMS

NAME: Diethy1 Phthalate CASNO: 00084662


SYN: CIASS: 226

NAME: Diethy1 Sebacate CASNO: 00110407


SYN: CIASS: 224

NAME: Dihepty1 Phthalate CASNO: 03648213


SYN: CIASS: 226

NAME: Dihydrosafro1e CASNO: 00094586


SYN: CIASS: 278

NAME: Diisobutylamine CASNO: 00110963


SYN: ClASS: 142

NAME: Diisobutylene CASNO: 25167708


SYN: CIASS: 291

NAME: Diisobutyl Ketone CASNO: 00108838


SYN: CIASS: 391

NAME: Diisobutyl Ketone, >70% CASNO: 00108838


SYN: ClASS: 391

NAME: Diisobutyl Phthalate CASNO: 00084695


"N: CIASS: 226

NAME: Diisoctyl Phthalate CASNO: 27554263


SYN: CIASS: 226

NAME: Diisodecyl Phthalate CASNO: 26761400


SYN: CIASS: 226

NAME: Diisononyl Phthalate CASNO: 28553120


SYN: CIASS: 226

NAME: Diisooctyl Sebacate CASNO: 27214900


SYN: ClASS: 224

NAME: Diisopropylamine CASNO: 00108189


SYN: ClASS: 142

B-21
CHEMICAL NAMES AND SYNONYMS

NAME: Diisopropy1 Benzene (all isomers) CASNO: 25321099


SYN: CLASS: 292

NAME: Diisopropy1 F1uorophosphate CASNO: 00055914


SYN: CLASS: 460 262

NAME: Diisopropy1 Ketone CASNO: 00565800


SYN: CLASS: 314

NAME: N,N-Dimethy1acetamide CASNO: 00127195


SYN: CLASS: 132

NAME: Dimethy1amine CASNO: 00124403


SYN: CLASS: 142

NAME: Dimethy1aminopropy1amine CASNO: 00109557


SYN: CLASS: 144
NAME: Dimethy1ana1ine CASNO: 00121697
SYN: CLASS: 145
NAME: a1pha,a1pha-Dimethy1benzy1 Hydroperoxide CASNO: 00080159
SYN: CLASS: 300

NAME: Dimethy1buty1amine CASNO: 00108098


SYN: CLASS: 143
NAME: Dimethy1ethano1amine CASNO: 00108010
SYN: CLASS: 142
NAME: Dimethy1formamide CASNO: 00068122
SYN: CLASS: 132
NAME: Dimethylhydrazine,sym- CASNO:
SYN: (See 1,2-Dimethy1hydrazine) CLASS:
NAME: Dimethy1hydrazine,unsym- CASNO:
SYN: (See 1,1-Dimethy1hydrazine) CLASS:
NAME: 1,1-Dimethy1hydrazine CASNO: 00057147
SYN: Dimethy1hydrazine,unsym- CLASS: 280

B-22
CHEKlCAL NAMES AND SYNONYMS

HAKE: l,2-Dimethylhydrazine CASNO: 00540738


SYN: Dimethylhydrazine,sym- ClASS: 280

NAME: a1pha,a1pha-Dimethylphenethylamine CASNO: 00122098


SYN: ClASS: 141 145

NAME: 2.4-Dimethy1pheno1 CASNO: 00105679


SYN: ClASS: 316

NAME: Dimethyl Phthalate CASNO: 00131113


SYN: ClASS: 226

NAME: Dimethyl Sulfate CASNO: 00077781


SYN: CLASS: 507

NAME: Dimethyl Sulfoxide CASNO: 00067685


SYN: ClASS: 503

NAME: Dimethylvinylchloride CASNO: 00513371


SYN: ClASS: 267

NAME: Dinonyl Phthalate CASNO: 00084764


SYN: CLASS: 226

NAME: Dioctyl Sebacate CASNO:


"'YN: (See Di-(2-Ethylhexyl)-Sebacate) ClASS:

NAME: Di-n-octyl Phthalate CASNO: 00117840


SYN: ClASS: 226
NAME: l.4-Dloxane CASNO: 00123911
SYN: Diethylene Dioxide,l,4 ClASS: 278
NAME: l.3-Dioxolane CASNO: 00646060
SYN: ClASS: 242
NAME: Dipentene CASNO: 00138863
SYN: ClASS: 291
NAME: Dipropylamine CASNO: 00142847
SYN: ClASS: 142

B-23
CHEMICAL NAMES AND SYNONYMS

NAME: Di-See-Oety1 Phthalate CASNO: 00131157


SYN: CLASS: 226

NAME: Disodium Phosphate CASNO: 07558794


SYN: CLASS: 330

NAME: Disu1fur Dichloride CASNO: 10025679


SYN: CLASS: 507

NAME: Dithiophosphorie Acid CASNO:


SYN: (See Tetraethyldithiopyrophosphate) CLASS:

NAME: Diundeey1 Phthalate CASNO: 03648202


SYN: ClASS: 226

NAME: Divinyl Benzene CASNO: 01321740


SYN: CLASS: 292

NAME: Epiehlorohydrin CASNO: 00106898


SYN: ClASS: 275 262

NAME: l,2-Epoxybutane CASNO: 00106887


SYN: CLASS: 275

NAME: Erythritol Anhydride CASNO:


SYN: (See 2,2'-Bioxirane) CLASS:
NAME: Ethane CASNO: 00074840
SYN: ClASS: 291
NAME: Ethanol CASNO:
SYN: (See Ethyl Alcohol) ClASS:

NAME: Ethanol, <30' CASNO: 00064175


SYN: CLASS: 311
NAME: Ethanol, 30-70' CASNO: 00064175
SYN: CLASS: 311
NAME: Ethanol, >70% CASNO: 00064175
SYN: CLASS: 311

B-24
CHEMICAL NAMES AND SYNONYMS

NAME: Ethanolamine CASNO: 00141435


SYN: Aminoethanol.2 ClASS: 141 311

NAME: Ethoxyethanol. 2 CASNO:


SYN: (See Ethyl Cellosolve) ClASS:

NAME: 2-Ethoxyethyl Acetate CASNO: 00111159


SYN: Cel1oso1ve Acetate ClASS: 222 241

NAME: Ethyl Acetate CASNO: 00141786


SYN: ClASS: 222

NAME: Ethyl Ce11oso1ve CASNO: 00110805


SYN: Ethoxyethano1. 2 ClASS: 311 241

NAME: Ethyl Acetoacetate CASNO: 00141979


SYN: ClASS: 222

NAME: Ethyl Acrylate CASNO: 00140885


SYN: ClASS: 223

NAME: Ethyl Alcohol CASNO: 00064175


SYN: Ethanol ClASS: 311
1AME: Ethy1amine CASNO: 00075047
.)YN: Monoethylamine ClASS: 141

NAME: Ethy1amine. <30% CASNO: 00075047


SYN: ClASS: 141

NAME: Ethy1amine. 30-70% CASNO: 00075047


SYN: ClASS: 141

NAME: Ethylamine. >70% CASNO: 00075047


SYN: ClASS: 141

NAME: Ethyl Benzene CASNO: 00100414


SYN: ClASS: 292

NAME: Ethyl Benzoate CASNO: 00093890


SYN: ClASS: 316

B-25
CHEMICAL NAMES AND SYNONYMS

NAME: Ethyl Bromide CASNO: 00074964


SYN: CLASS: 261

NAME: Ethy1-n-buty1amine CASNO: 13360639


SYN: CLASS: 142

NAME: Ethyl Ch1orocarbonate CASNO: 00541413


SYN: CLASS: 111

NAME: Ethyl Cyanide CASNO: 00107120


SYN: PropionitrUe CLASS: 431

NAME: Ethy1dime thy1me thane CASNO:


SYN: (See Isopentane) CLASS:

NAME: Ethylene Acetate CASNO: 00111557


SYN: CLASS: 221

NAME: Ethylene Ch1orohydrin CASNO: 00107073


SYN: Chloroethano1 CLASS: 311 262

NAME: Ethylenediamine CASNO: 00107153


SYN: Diaminoethane,1,2 CLASS: 144

NAME: Ethylene Dibromide CASNO: 00106934


SYN: Dlbromoethane,1,2 CLASS: 261

NAME: Ethylene Dichloride CASNO: 00107062


SYN: Dich1oroethane,1,2 CLASS: 261

NAME: Ethylene Glycol CASNO: 00107211


SYN: CLASS: 314

NAME: Ethylene Glycol Monoacetate CASNO: 00524596


SYN: CLASS: 103 314 313

NAME: Ethylene Oxide CASNO: 00075218


SYN: Oxirane CLASS: 275

NAME: Ethy1enimine CASNO: 00151564


SYN: Aziridine CLASS: 274 142

B-26
CHEKlCAL NAMES AND SYNONYMS

.LiAME: Ethyl Ether CASNO: 00060297


SYN: CLASS: 241

NAME: Ethyl Formate CASNO: 00109944


SYN: CLASS: 221

NAME: 2-Ethy1hexanoic Acid CASNO: 00149575


SYN: CLASS: 102

NAME: 2-Ethy1-1-Hexano1 CASNO: 00104767


SYN: CLASS: 311

NAME: Ethylidene Dichloride CASNO: 00075343


SYN: Dich1oroethane,l,l CLASS: 261

NAME: Ethyl Mercaptan CASNO: 00075081


SYN: CLASS: 501

NAME: Ethyl Methacrylate CASNO: 00097632


SYN: CLASS: 223

NAME: Ethyl Kethanesulfonate CASNO: 00062500


SYN: CLASS: 232

NAME:
'YN:
.. Ethyl Silicate
+-.
CASNO:
CLASS:
00078104
233 291

NAME: Ferric Chloride CASNO: 07705080


SYN: CLASS: 340

NAME: Ferrous Chloride CASNO: 07758943


SYN: ClASS: 340

NAME: Fluorine CASNO: 07782414


SYN: CLASS: 350

NAME: Fluorobenzene CASNO: 00462066


SYN: CLASS: 263

NAME: Fluoroboric Acid CASNO: 16872110


SYN: Tetrafluoroboric Acid ClASS: 370

B-27
CHEMICAL NAMES AND SYNONYMS

NAME: Fluorosilicic Acid CASNO: 16961834


SYN: ClASS: 370
NAME: Fluorosulfonic Acid CASNO: 07789211
SYN: ClASS: 504
NAME: Formaldehyde, <37% CASNO: 00050000
SYN: Formalin ClASS: 121
NAME: Formalin CASNO:
SYN: (See Formaldehyde, <37%) ClASS:
NAME: Formamide, 30% CASNO: 00075127
SYN: ClASS: 132
NAME: Formic Acid CASNO: 00064186
SYN: Methanoic Acid ClASS: 102
NAME: Formic Acid, <30% CASNO: 00064186
SYN: ClASS: 102
NAME: Formic Acid, 30-70% CASNO: 00064186
SYN: ClASS: 102
NAME: Formic Acid, >70% CASNO: 00064181=
SYN: ClASS: 102
NAME: Freon 11 CASNO: 00075694
SYN: ClASS: 261
NAME: Freon 12 CASNO: 00075718
SYN: ClASS: 261
NAME: Freon 21 CASNO: 00075434
SYN: ClASS: 261
NAME: Freon 22 CASNO: 00075456
SYN: ClASS: 261
NAME: Freon 112 CASNO: 00076120
SYN: ClASS: 261

B-28
CHEMICAL NAMES AND SYNONYMS

NAME: Freon 114B2 CASNO: 00124732


SYN: ClASS: 261

NAME: Freon TF CASNO: 00076131


SYN: ClASS: 261

NAME: Freon THC CASNO: 57762319


SYN: ClASS: 261

NAME: Furan CASNO: 00110009


SYN: Furfuran ClASS: 277

NAME: Furfural CASNO: 00098011


SYN: ClASS: 122

NAME: Furfuran CASNO:


SYN: (See Furan) ClASS:

NAME: 2 -Fury1metbanol CASNO: 00098000


SYN: ClASS: 312

NAME: Gasoline CASNO: 08006619


SYN: ClASS: 291 292

NAME: Glutaraldehyde GASNO: 00111308


"YN: ClASS: 121

NAME: Glycerin Triacetate CASNO: 00102761


SYN: Triacetine ClASS: 102 222

NAME: Glycerol CASNO: 00056815


SYN: Propanetriol.1.2.3 ClASS: 314

NAME: Glycerol Diacetate CASNO:


" SYN: (See Diacetin) ClASS:

NAME: Glycidaldehyde CASNO: 00765344


SYN: ClASS: 275 122

NAME: Glycols CASNO: 68606213


SYN: ClASS: 311

B-2'
CHEMICAL NAMES AND SYNONYMS

NAME: Halothane CASNO: 00151677


SYN: CLASS: 261

NAME: Heptane CASNO: 00142825


SYN: ClASS: 291

NAME: Hexach1orobenzene CASNO: 00118741


SYN: ClASS: 263

NAME: Hexach1orobutadiene CASNO: 00087683


SYN: ClASS: 261

NAME: Hexach1orocyc1opentadiene CASNO: 00077474


SYN: ClASS: 261

NAME: Hexach1oropropene CASNO: 01888717


SYN: ClASS: 261

NAME: Hexaethy1tetraphosphate CASNO: 00757584


SYN: ClASS: 460

NAME: Hexamethy1phosphoamide CASNO: 00680319


SYN: ClASS: 132

NAME: Hexanal CASNO: 0006625 1

SYN: ClASS: 121

NAME: Hexane CASNO: 00110543


SYN: ClASS: 291

NAME: Hexanedioic Acid CASNO:


SYN: (See Adipic Acid) ClASS:

NAME: Hexano1 CASNO:


SYN: (See Hexy1 Alcohol) ClASS:

NAME: Hexanone, 2 CASNO:


SYN: (See Methyl n-Butyl Ketone) ClASS:

NAME: 1-Hexene CASNO: 00592416


SYN: ClASS: 291

B-30
CHEMICAL NAMES AND SYNONYMS

NAME: Hexy1 Alcohol CASNO: 00111273


SYN: Hexano1 CLASS: 311

NAME: Hydrazine CASNO: 00302012


SYN: Diamine ClASS: 280

NAME: Hydrazine, <30t CASNO: 00302012


SYN: ClASS: 280

NAME: Hydrazine, 30-70t CASNO: 00302012


SYN: CLASS: 280

NAME: Hydrazine, >70, CASNO: 00302012


SYN: ClASS: 280

NAME: Hydrobromic Acid CASNO: 10035106


SYN: ClASS: 370

NAME: Hydrobromic Acid, 30-70t CASNO: 10035106


SYN: CLASS: 370

NAME: Hydrochloric Acid CASNO: 07647010


SYN: ClASS: 370

~: Hydrochloric Acid, <30t CASNO: 07647010


m: CLASS: 370

NAME: Hydrochloric Acid, 30-70t CASNO: 07647010


SYN: CLASS: 370

NAME: Hydrochloric Acid, >70t CASNO: 07647010


SYN~ CLASS: 370

NAME: Hydrocyanic Acid CASNO: 00074908


SYN: CLASS: 215 350

NAME: Hydrocyanic Acid, <30t CASNO: 00074908


SYN: ClASS: 370

NAME: Hydrofluoric Acid CASNO: 07664393


SYN: Hydrogen-Fluoride ClASS: 370

B-31
CHEMICAL NAMES AND SYNONYMS

NAME: Hydrofluoric Acid, <30% CASNO: 07664393


SYN: CLASS: 370
NAME: Hydrofluoric Acid, 30-70% CASNO: 07664393
SYN: CLASS: 370
NAME: Hydrofluoric Acid, >70% CASNO: 07664393
SYN: CLASS: 370
NAME: Hydrogen Fluoride CASNO:
SYN: (See Hydrofluoric Acid) CLASS:
NAME: Hydrogen Peroxide CASNO: 07722841
SYN: CLASS: 300
NAME: Hydrogen Peroxide, <30% CASNO: 077~2841
SYN: CLASS: 300
NAME: Hydrogen Peroxide, 30-70%
\ .
CASNO: 07722841
SYN: ClASS: 300
NAME: Hydrogen Peroxide, >70% CASNO: 07722841
SYN: CLASS: 300
NAME: Hydrogen Phosphide CASNO: 07803512
SYN: Phosphine CLASS: 350
NAME: Hydrogen Sulfide CASNO: 07783064
SYN: CLASS: 350
NAME: Hydroquinone CASNO: 00123319
SYN: CLASS: 490
NAME: Hydroquinone. <30, CASNO: 00123319
SYN: CLASS: 490
NAME: Hy1ene CASNO: 00101655
SYN: ClASS: 215
NAME: Iminobispropy1amine CASNO: 00056188
SYN: CLASS: 144

B-32
CHEMICAL NAKES AND SYNONYMS

NAME: Iodine Pentafluoride CASNO: 07783666


SYN: CLASS: 370

NAME: b-Ionone CASNO: 14901076


SYN: CLASS: 291

NAKE: Isoamyl Acetate CASNO: 00123922


SYN: CLASS: 222

NAME: Isoamy1nitrile CASNO: 00110463


SYN: CLASS: 431

NAME: Isobutene CASNO:


SYN: (See Isobuty1ene) CLASS:

NAKE: Isobutyl Acrylate CASNO: 00106638


SYN: CLASS: 223

NAME: Isobutyl Alcohol CASNO: 00078831


SYN: CLASS: 311

NAME: Isobuty1ene CASNO: 00115117


SYN: Isobutene.,· CLASS: 291

NAME: Isobutyl Nitrite CASNO: 00542563


SYN: CLASS: 233

NAKE: Isobutyra1dehyde CASNO: 00078842


SYN: CLASS: 121

NAKE: Isooctane CASNO: 26635643


SYN: CLASS: 291

NAME: Isopentane CASNO: 00078784


SYN: Ethyldimethylmethane CLASS: 291

NAKE: Isophorone CASNO: 00078591


SYN: CLASS: 391

NAKE: Isoprene CASNO: 00078795


SYN: CLASS: 291

B-33
CHEMICAL NAMES AND SYNONYMS

NAME: Isopropyl Acetate CASNO: 00108214


SYN: CLASS: 222

NAME: Isopropyl Alcohol CASNO: 00067630


SYN: Propanol, 2- CLASS: 312

NAME: Isopropylamine CASNO: 00075310


SYN: CLASS: 141

NAME: Isopropyl Chloride CASNO: 00075296


SYN: Chloropropane CLASS: 261 312

NAME: Isopropyl Ether CASNO: 00108203


SYN: CLASS: 241

NAME: Isopropylmethacrylate CASNO: 04655349


SYN: CLASS: 223

NAME: Isosafrole CASNO: ·00120581


SYN: CLASS: 278

NAME: JP-4, Jet Fuel CASNO: 99901291


SYN: CLASS: 291 292

NAME: Kerosene CASNO: 08008206


SYN: CLASS: 291 292
NAME: Lactic Acid CASNO: 00079334
SYN: CLASS: 103 312
NAME: Lactic Acid, <30% CASNO: 00079334
SYN: CLASS: 103 312
NAME: Lactic Acid, >70% CASNO: 00079334
SYN: CLASS: 103 312
NAME: Lauric Acid CASNO: 00143077
SYN: CLASS: 102
NAME: Lauric Acid, 30-70\ CASNO: 00143077
SYN: CLASS: 102

B-34
CHEKlCAL NAMES AND SYNONYMS

NAME: Ligroine CASNO:


SYN: (See Naphtha, V.K.& P) CLASS:

NAME: d-Limonene CASNO: 05989275


SYN: Menthadiene CLASS: 292

NAME: Linoleic Acid CASNO: 00060333


SYN: CLASS: 102

NAME: Maleic Acid CASNO: 00110167


SYN: CLASS: 104

NAME: Maleic Acid, >70\ CASNO: 00110167


SYN: CLASS: 104

NAME: Malic Acid CASNO: 06915157


SYN: ClASS: 104 103

NAME: Ma10nitrile CASNO: 00109773


SYN: Propane Dinitri1e CLASS: 431

NAME: Menthadiene CASNO:


SYN: (See d-Limonene) CLASS:

NAME: Mercury CASNO: 07439976


SYN: CLASS: 560

NAKE: Mesity1 Oxlde CASNO: 00141797


SYN: Kethy1pentenone, 4-.3-.2- CLASS: 391

NAME: Methacry1onitri1e CASNO: 00126987


SYN: CLASS: 431

NAME: Methane CASNO: 00074828


SYN: CLASS: 291

NAME: Methanesu1fonic Acid CASNO: 00075752


SYN: CLASS: 504

NAME: Kethanethio1 CASNO:


SYN: (See Kethylmercaptan) ClASS:

B-35
CHEMICAL NAMES AND SYNONYMS

NAKE: Methanoic Acid CASNO:


SYN: (See Formic Acid) ClASS:

NAME: Methanol CASNO: 00067561


SYN: Methyl Alcohol ClASS: 311

NAME: Methanol, <30% CASNO: 00067561


SYN: ClASS: 311

NAME: Methanol, 30-70% CASNO: 00067561


SYN: ClASS: 311

NAME: Methanol, >70% CASNO: 00067561


SYN: ClASS: 311

NAME: Methoxyethano1, 2 CASNO:


SYN: (See Methyl Ce1losolve) ClASS:

NAME: 4-Methoxy-4-methyl-2-pentanone CASNO: 00107700


SYN: ClASS: 391

NAME: Methyl Acetate CASNO: 00079209


SYN: ClASS: 222

NAME: Methyl Alcohol CASNO:


SYN: (See Methanol) ClASS:

NAME: Methyl Acrylate CASNO: 00096333


SYN: ClASS: 223
NAME: Methy1acrylic Acid CASNO: 00079414
SYN: ClASS: 102

NAME: 2-Methylactonitrile CASNO: 00075865


SYN: Acetone Cyanohydrin ClASS-: 431 400
NAME: Methylamine CASNO: 00074895
SYN: Monome thy1amine ClASS: 141

NAME: Methylamine, 30-70% CASNO: 00074895


SYN: ClASS: 141

B-36
CHEMICAL NAMES AND SYNONYMS

NAME: 3-Metby1aminopropy1amine CASNO: 06291845


SYN: ClASS: 144

NAME: Methyl Aniline CASNO: 00100618


SYN: ClASS: 147

NAME: 2-Methy1aziridine CASNO: 00075558


SYN: Propylenimine, 1 ,2 ClASS: 274 142

NAME: Methyl Bromide CASNO: 00074839


SYN: Bromomethane ClASS: 261

NAME: Methylbutadiene,l CASNO:


SYN: (See l,3-Pentadiene) ClASS:

NAME: Methyl n-Buty1 Ketone CASNO: 00591786


SYN: Hexanone, 2 ClASS: 391

NAME: Methyl Cellosolve CASNO: 00109864


SYN: Me thoxyethano 1 , 2 ClASS: 311 241

NAME: Methyl Cellosolve Acetate CASNO: 00110496


SYN: ClASS: 241 222

NAME: Methyl Cellulose CASNO: 09004615


SYN: ClASS: 241

NAME: Kethyl Chloride CASNO: 00074813


SYN: Chloromethane ClASS: 261

NAME: Kethyl Chloroacetate CASNO: 00096344


SYN: ClASS: 222

NAME: Kethyl Chloroform CASNO: 00011556


SYN: Trichloroethane,l,l,l ClASS: 261

NAKE: Methyl Chloroformate CASNO: 00019221


SYN: ClASS: 221

NAME: Kethylcyc10hexane CASNO: 00108812


SYN: ClASS: 291

B-37
CHEMICAL NAMES AND SYNONYMS

NAME: Methyl Cyclopentane CASNO: 00096377


SYN: ClASS: 291

NAME: Methylene Bromide CASNO: 00074953


SYN: Dibromomethane ClASS: 261

NAME: Methylene Chloride CASNO: 00075092


SYN: Dichloromethane ClASS: 261

NAME: 4,4'-Methylenedianiline CASNO: 00101779


SYN: ClASS: 147

NAME: n-Methylethanolamine CASNO: 00109831


SYN: ClASS: 142

NAME: Methylethyl Benzene GASNO:


SYN: (See Cumene) ClASS:

NAME: Methyl Ethyl Ketone CASNO: 60078933


SYN: Butanone, 2 ClASS: 391

NAME: Methyl Ethyl Ketone Peroxide GASNO: 01338234


SYN: ClASS: 300

NAME: Kethyl Formate CASNO: 00107313


SYN: ClASS: 221

NAME: Methy1hydrazine CASNO: 00060344


SYN: ClASS: 280

NAME: Kethyl Iodide CASNO: 00074884


SYN: ClASS: 261

NAME: Methyl Isobutyl Ketone GASNO: 00108101


SYN: Methy1pentanone, 4-,2- ClASS: 391

NAME: Methyl Isocyanate CASNO: 00624839


SYN: ClASS: 210

NAME: 1-Methyl-4-Isopropeny1benzene CASNO: 01195320


SYN: ClASS: 292

B-38
CHEMICAL NAMES AND SYNONYMS

NAME: Me thy lmercap tan CASNO: 00074931


SYN: Methanethiol CLASS: 501

NAME: Methyl Methacrylate CASNO: 00080626


SYN: CLASS: 223

NAME: Methyl Oleate CASNO: 00112629


SYN: CLASS: 223

NAME: Methyl Parathion CASNO: 00298000


SYN: CLASS: 460 442

NAME: Methylpentanone, 4-,2- CASNO:


SYN: (See Methyl Isobutyl Ketone) CLASS:

NAME: Methylpentenone, 4-,3-,2- CASNO:


SYN: (See Mesityl Oxide) CLASS:

NAME: Methylpropanol, 2-,2- CASNO:


SYN: (See tert-Butanol) CLASS:

NAME: Methylpropylamine, 2- CASNO:


SYN: (See iso-Butylamine) CLASS:

NAME: Kethylpyridine,2 CASNO:


SYN: (See alpha-Picoline) CLASS:

NAME: Methyl Salicylate CASNO: 00119368


SYN: CLASS: 226
NAME: Methyl-vinyl-ketone CASNO: 00078944
SYN: CLASS: 391
NAME: Mineral Oil CASNO: 08012951
SYN: CLASS: 560

NAME: Mineral Spirits CASNO: 08052413


SYN: CLASS: 291
NAME: Monoethylamine CASNO:
SYN: (See Ethylamine) CLASS:

B-39
CHEMICAL NAMES AND SYNONYMS

NAME: Monoisopropano1amine CASNO: 00078966


SYN: CLASS: 141

NAME: Monomethy1amine CASNO:


SYN: (See Methylamine) CLASS:

NAME: Morpho line CASNO: 00110918


SYN: CLASS: 142

NAME: N-Methyl-2-pyrro1idone CASNO: 00872504


SYN: CLASS: 391

NAME: Naphtha, V.M.& P CASNO: 08032324


SYN: Ligroine CLASS: 291

NAME: Naptha1ene CASNO: 00091203


SYN: CLASS: 293

NAME: Natural Gas, Liquified CASNO: 64741486


SYN: CLASS: 292

NAME: Nickel Carbonyl CASNO: 13463393


SYN: CLASS: 350

NAME: Nickel Chloride CASNO: 07718549


SYN: CLASS: 340

NAME: Nitric Acid CASNO: 07697372


SYN: CLASS: 370
NAME: Nitric Acid, <30% CASNO: 07697372
SYN: CLASS: 370

NAME: Nitric Acid, 30-70% CASNO: 07697372


SYN: CLASS: 370
NAME: Nitric Acid, >70% CASNO: 07697372
SYN: CLASS: 370
NAME: Nitric Acid, Fuming Red CASNO: 08007587
SYN: CLASS: 370

B-40
CHEMICAL NAMES AND SYNONYMS

NAME: Nitric Oxide CASNO: 10102439


SYN: ClASS: 350

NAME: Nitrobenzene CASNO: 00098953


SYN: ClASS: 441 292

NAME: Nitroethane CASNO: 00079243


SYN: ClASS: 441

NAME: Nitrogen Dioxide CASNO: 10102440


SYN: ClASS: 350

NAME: Nitrogen Tetroxide CASNO: 10544726


SYN: ClASS: 350

NAME: Nitroglycerine CASNO: 00055630


SYN: ClASS: 441

NAME: Nitromethane CASNO: 00075525


SYN: ClASS: 441

NAME: Nitropropane CASNO: 25322014


SYN: ClASS: 441

NAME: l-Nitropropane CASNO: 00108032


SYN: ClASS: 441

NAME: 2-Nitropropane CASNO: 00079469


SYN: ClASS: 441

NAME: Nitropropane. >70% CASNO: 25322014


SYN: ClASS: 441

NAME: n-Nitrosodimethy1amine CASNO: 00055185


SYN: ClASS: 143 442

NAME: Nitroto1uene CASNO: 01321126


SYN: ClASS: 441

NAME: o-Nitroto1uene CASNO: 00088722


SYN: ClASS: 441

B-41
CHEMI CAL NAMES AND SYNONYMS

NAME: p-Nitrotoluene CASNO: 00099990


SYN: ClASS: 441
NAME: Nonylphenol CASNO: 25154523
SYN: ClASS: 316
NAME: Octadecane CASNO: 00593453
SYN: ClASS: 291
NAME: n-Octane CASNO: 00111659
SYN: ClASS: 291
NAME: l-Octanol CASNO: 00111875
SYN: CLASS: 311
NAME: n-Octanol CASNO: 29063283
SYN: ClASS: 311
NAME: Oleic Acid CASNO: 00112801
SYN: CLASS: 102
NAME: Oxalic Acid CASNO: 00144627
SYN: CLASS: 104
NAME: Oxirane CASNO:
SYN: (See Ethylene Oxide) ClASS:
NAME: Palmitic Acid CASNO: 00057103
SYN: ClASS: 102
NAME: Paraldehyde CASNO: 00123637
SYN: ClASS: 121
NAME: Pentach1oroethane CASNO: 00076017
SYN: ClASS: 261
NAME: Pentachlorophenol CASNO: 00087865
SYN: ClASS: 264 316
NAME: 1,3-Pentadiene CASNO: 00504609
SYN: Methylbutadiene,l ClASS: 291

B-42
CHEMICAL NAMES AND SYNONYMS

NAME: Pentane CASNO: 00109660


SYN: CLASS: 291

NAME: Pentanol CASNO:


SYN: (See Amyl Alcohol) CLASS:
NAME: Pentene CASNO: 25377724
SYN: CLASS: 291
NAME: Pentyl Acetate CASNO:
SYN: (See Amyl Acetate) CLASS:
NAME: Perch10ric Acid CASNO: 07601903
SYN: CLASS: 370

NAME: Perchloric Acid, <30% CASNO: 07601903


SYN: CLASS: 370

NAME: Perchloric Acid, 30-70% CASNO: 07601903


SYN: CLASS: 370

NAME: Perchloroethylene CASNO:


SYN: (See Tetrachloroethylene) CLASS:
NAME: Phenetole CASNO:
SYN: (See Phenyl Ethyl Ether) CLASS:

NAME: Phenol CASNO: 00108952


SYN: Carbolic Acid CLASS: 316

NAME: Phenol. <30% CASNO: 00108952


SYN: CLASS: 316

NAME: Phenol, 30-70% CASNO: 00108952


SYN: CLASS: 316

NAME: Phenol, >70% CASNO: 00108952


SYN: CLASS: 316

NAME: Phenolphthalein CASNO: 00077098


SYN: CLASS: 314

B-43
CHEMICAL NAMES AND SYNONYMS

NAME: Phenyl Dichloroarsine CASNO:


SYN: (See Dichlorophenylarsine) CLASS:

NAME: Phenylenediamine CASNO: 00108452


SYN: ClASS: 147

NAME: Phenyl Ethyl Ether CASNO: 00103731


SYN: Pheneto1e CLASS: 243

NAME: Phenyl G1ycidy1 Ether CASNO: 00122601


SYN: CLASS: 275

NAME: Phenylhydrazine CASNO: 00110063


SYN: CLASS: 280

NAME: Phosgene CASNO: 00075445


SYN: Carbonyl Chloride ClASS: 350

NAME: Phosphine CASNO:


SYN: (See Hydrogen Phosphide) ClASS:
NAME: Phosphoric Acid CASNO: 07664382
SYN: CLASS: 370

NAME: Phosphoric Acid, <30% CASNO: 07664382


SYN: CLASS: 370

NAME: Phosphoric Acid, 30-70% CASNO: 07664382


SYN: ClASS: 370

NAME: Phosphoric Acid, >70% CASNO: 07664382


SYN: CLASS: 370

NAME: Phosphorus Oxychloride CASNO: 10025873


SYN: CLASS: 370
NAME: Phosphorus Trichloride CASNO: 07719122
SYN: ClASS: 370

NAME: 4-Picoline CASNO: 00108894


SYN: ClASS: 271

B-44
CHEKICAL HAKES AND SYNONYMS

NAME: alpha-Picoline CASNO: 00109068


SYN: Kethylpyridine,2 CLASS: 271

NAME: Picric Acid CASNO: 00088891


SYN: Trinitrophenol,2,4.6 ClASS: 316 442

NAME: Picric Acid, <30% CASNO: 00088891


SYN: CLASS: 316 442

NAME: Pinene (all isomers) CASNO: 25766181


SYN: CLASS: 291
NAKE: 1-Piperazineethanamine CASNO: 00140318
SYN: ClASS: 146

NAME: PiperIdine CASNO: 00110894


SYN: ClASS: 274

NAME: Polychlorinated Biphenyls (PCBs) CASNO: 01336363


SYN: Aroclor ClASS: 265

NAME: Potassium Dichromate CASNO: 07778509


SYN: ClASS: 340

NAME: Potassium Hydroxide CASNO: 01310583


SYN: CLASS': 380

NAME: Potassium Hydroxide. <30t CASNO: 01310583


SYN: CLASS: 380

NAME: Potassium Hydroxide, 30-70% CASNO: 01310583


SYN: CLASS: 380

NAME: Potassium Bromide CASNO: 07758023


SYN: ClASS: 340

NAME: Potassium Chloride CASNO: 03811049


SYN: ClASS: 340

NAKE: Potassium Cyanide CASNO: 00151508


SYN: ClASS: 215 340

B-45
CHEMICAL NAMES AND SYNONYMS

NAME: Promethazinehydrochloride CASNO: 00058333


SYN: CLASS:

NAME: Propane CASNO: 00074986


SYN: CLASS: 291

NAME: Propane Dinitrile CASNO:


SYN: (See Malonitrile) CLASS:

NAME: Propanetriol,1,2,3 CASNO:


SYN: (See Glycerol) CLASS:

NAME: Propanol CASNO:


SYN: (See Propyl Alcohol) CLASS:

NAME: Propanol, 2- CASNO:


SYN: (See Isopropyl Alcohol) CLASS:

NAME: Prop argyl Alcohol CASNO: 00107197


SYN: CLASS: 311

NAME: Propene amide , 2 CASNO:


SYN: (See Acrylamide) CLASS:
NAME:" beta-Propiolactone CASNO: 00057578
SYN: CLASS: 400
NAME: Propionaldehyde CASNO: 00123386
SYN: CLASS: 121
NAME: Propionic Acid CASNO: 00079094
SYN: CLASS: 102
NAME: Propionic Anhydride CASNO: 00123626
SYN: CLASS: 161
NAME: Propionitrile CASNO:
SYN: (See Ethyl Cyanide) CLASS:
NAME: Propyl Acetate CASNO: 00109604
SYN: CLASS: 222

B-46
CHEMICAL NAMES AND SYNONYMS

NAME: Propyl Acetate, >70' GASNO: 00109604


SYN: CLASS: 222

NAME: Propyl Alcohol CASNO: 00071238


SYN: Propanol CLASS: 311

NAME: n-Propylamine CASNO: 00107108


SYN: CLASS: 141

NAME: Propyl Chloride CASNO: 00540545


SYN: Chloropropane, 1 CLASS: 261

NAME: Propylenediamine CASNO: 00078900


SYN: CLASS: 144

NAME: Propylene Dichloride CASNO: 00078875


SYN: Dichloropropane 1,2 CLASS: 261

NAME: Propylene Glycol CASNO: 00057556


SYN: CLASS: 314
NAME: Propylene Oxide CASNO: 00075569
SYN: CLASS: 275

NAME: l,3-Propy1ene Oxide CASNO: 00503300


SYN: CLASS: 275

NAME: Propy1enimine,l,2 CASNO:


SYN: (See 2-Methylaziridine) CLASS:

NAME: Propy1methacry1ate CASNO: 02210288


SYN: CLASS: 223
NAME: Pyre thr ins CASNO: 00121299
SYN: CLASS: 223
NAME: Pyridine CASNO: 00110861
SYN: CLASS: 271

NAME: Pyrrole CASNO: 00109977


SYN: CLASS: 142

B-47
CHEMICAL NAMES AND SYNONYMS

NAME: Quinoline CASNO: 00091225


SYN: CLASS: 272
NAME: Resorcinol CASNO: 00108463
SYN: Benzendiol,l,3 CLASS: 316
NAME: Safrole CASNO: 00094597
SYN: CLASS: 278
NAME: Silver Nitrate CASNO: 07761888
SYN: CLASS: 340
NAME: Sodium Chloride CASNO: 07647145
SYN: CLASS: 340
NAME: Sodium Cyanide CASNO: 00143339
SYN: CLASS: 215
NAME: Sodium Cyanide, <30% CASNO: 00143339
SYN: CLASS: 215
NAME: Sodium Cyanide, 30-70\ CASNO: 00143339
SYN: CLASS: 215
NAME: Sodium Hydroxide CASNO: 01310732
SYN: CLASS: 380
NAME: Sodium Hydroxide, <30\ CASNO: 01310732
SYN: ClASS: 380
NAKE: Sodium Hydroxide, 30-70\ CASNO: 01310732
SYN: CLASS: 380
NAME: Sodium Hydroxide, >70\ CASNO: 01310732
SYN: ClASS: 380
NAME: Sodium Hypochlorite CASNO: 07681529
SYN: CLASS: 340
NAME: Sodium Hypochlorite, 30-70% CASNO: 07681529
SYN: CLASS: 340

B-48
CHEMICAL NAMES AND SYNONYMS

NAME: Sodium Pentachlorophenate CASNO: 00131522


SYN: ClASS: 292

NAME: Sodiumpentach1orophenate, <30% CASNO: 00131522


SYN: ClASS: 292

NAME: Sodium Silicate CASNO: 01344098


SYN: ClASS: 340

NAME: Sodium Sulfate CASNO: 07681381


SYN: ClASS: 340

NAME: Sodium Sulfide CASNO: 01313822


SYN: ClASS: 340

NAME: Sodium Thiosulfate CASNO: 07772987


SYN: ClASS: 340

NAME: Stannous Chloride CASNO: 07772998


SYN: ClASS: 340

NAME: Stearic Acid CASNO: 00057114


SYN: ClASS: 102

NAME: Styrene CASNO: 00100425


SYN: ClASS: 292

NAME: Sulfuric Acid CASNO: 07664939


SYN: ClASS: 370

NAME: Sulfuric Acid, <30% CASNO: 07664939


SYN: ClASS: 370

NAME: Sulfuric Acid, 30-70% CASNO: 07664939


SYN: ClASS: 370

NAME: Sulfuric Acid, >70% CASNO: 07664939


SYN: ClASS: 370

NAME: Sulfur Monochloride CASNO: 12771083


SYN: ClASS: 370

B-49
CHEMICAL NAMES AND SYNONYMS

NAME: Sulfurus Acid CASNO: 07782992


SYN: CLASS: 370
NAME: TNT CASNO:
SYN: (See 2,4,6-Trinitrotoluene) CLASS:

NAME: Tannic Acid CASNO: 01401554


SYN: CLASS: 224
NAME: Tannic Acid, <30% CASNO: 01401554
SYN: CLASS: 224
NAME: Tannic Acid, 30-70% CASNO: 01401554
SYN: CLASS: 224
NAME: Tannic Acid, >70% CASNO: 01401554
SYN: CLASS: 224
NAME: Terpineol CASNO: 08000417
SYN: CLASS: 313
NAME: Tetrabromomethane CASNO:
SYN: (See Carbontetrabromide) CLASS:
NAME: Tetrabutyl Orthotitanate CASNO: 05593704
SYN: CLASS: 233
NAME: l,2,4,5-Tetrach1orobenzene CASNO: 00095943
SYN: CLASS: 263
NAME: Tetrach1orodif1uoroethane CASNO: 28605745
SYN: CLASS: 261
NAME: l,l,l,2-Tetrach1oroethane CASNO: 00630206
SYN: CLASS: 261
NAME: l,l,2,2-Tetrach1oroethane CASNO: 00079345
SYN: CLASS: 261
NAME: Tetrachloroethylene CASNO: 00127184
SYN: Perch1oroethy1ene CLASS: 261

B-50
CHEMICAL NAMES AND SYNONYMS

_.nKE: Tetrachloromethane CASNO:


SYN: (See Carbon Tetrachloride) ClASS:

NAME: Tetraethyldithiopyrophosphate CASNO: 03689245


8YN: Dithiophosphoric Acid ClASS: 460

NAME: Tetraethylenepentamine CASNO: 00112572


SYN: ClASS: 144

NAME: Tetraethyllead CASNO: 00078002


SYN: ClASS: 461

NAME: Tetraf1uoroboric Acid CASNO:


SYN: (See F1uoroboric Acid) ClASS:

NAME: Tetraf1uoroethy1ene CASNO: 00116143


SYN: ClASS: 261

NAME: Tetrahydrofuran CASNO: 00109999


SYN: ClASS: 277

NAKE: 1, 2, 3,4-Tetrahydronaphtha1ene CASNO: 00119642


SYN: Tetra1in CLASS: 292
NAME: Tetra1in CASNO:
<:VN: (See 1,2,3,4-Tetrahydronaphtha1ene) ClASS:
••I\ME: N,N,N',N'-Tetramethylenediamine CASNO: 00110189
SYN: CLASS: 144
NAME: Tetranitromethane CASNO: 00509148
SYN: ClASS: 441

NAME: Thionyl Chloride CASNO: 07719097


SYN: ClASS: 501

NAME: Thiophene CASNO: 00110021


SYN: ClASS: 502 279

NAME: Thiophenol CASNO: 00108985


SYN: Benzenethiol ClASS: 501

B-51
CHEMICAL NAMES AND SYNONYMS

NAME: Titanium Tetrachloride CASNO: 07550450


SYN: ClASS: 461

NAME: Toluene CASNO: 00108883


SYN: ClASS: 292

NAME: Toluene Diisocyanate CASNO: 26471625


SYN: CLASS: 210

NAME: p-Toluenesulfonic Acid CASNO: 00104154


SYN: ClASS: 504

NAME: o-Toluidine CASNO: 00095534


SYN: CLASS: 146

NAME: Triacetine CASNO;


Sl'N: (See Glycerin Triacetate) CLASS:

NAME; Trially1amine CASNO: 00102705


SYN: ClASS: 143

NAME: Tributyl Phosphate CASNO: 00126738


SYN: CLASS: 460

NAME: Trichloroacetaldehyde CASNO: 00075876


SYN: Chloral CLASS: 121 262

NAME: Trichloroacetic Acid CASNO: 00760390


SYN: CLASS: 103
NAME: Trichloroacetic Acid CASNO: 00076039
SYN: ClASS: 103

NAME: Trichloroacetonitrile CASNO: 00545062


SYN: CLASS: 431
NAME: 1,2,4-Trichlorobenzene CASNO: 00120821
SYN: CLASS: 263
NAME: 1,1,2-Trichloroethane CASNO: 00079005
SYN: ClASS: 261

B-52
CHEMICAL NAMES AND SYNONYMS

NAME: Trichloroethane,l,l,l CASNO:


SYN: (See Methyl Chloroform) ClASS:

NAME: 2,2,2-Trichloroethanol CASNO: 00115208


SYN: ClASS: 311 262

NAME: Trichloroethene CASNO:


SYN: (See Trichloroethylene) ClASS:

NAME: Trichloroethylene CASNO: 00079016


SYN: Trich1oroethene ClASS: 261

NAME: Trichloromethane CASNO:


SYN: (See Chloroform) ClASS:

NAME: Trichloromethanethio1 CASNO: 00075707


SYN: ClASS: 262 501

NAME: Trich1oromethyl-benzene CASNO:


SYN: (See Benzotrichloride) ClASS:

NAME: l,2,3-Trichloropropane CASNO: 00096184


SYN: ClASS: 261

NAME: Tricresyl Phosphate CASNO: 01330785


SYN: Trito1yl Phosphate ClASS: 460

NAME: Triethanolamine CASNO: 00102716


SYN: ClASS: 143

NAME: Triethanolamine, >70% CASNO: 00102716


SYN: CLt\SS: 143

NAME: Triethyl Aluminum CASNO: 00097938


SYN: ClASS: 461

NAME: Triethylamine CASNO: 00121448-


SYN: ClASS: 143

NAME: Triethylenetetraamine CASNO: 00112243


SYN: ClASS: 144

S-53
CHEMICAL NAMES AND SYNONYMS

NAME: Trif1uoroethano1 CASNO: 00075898


SYN: ClASS: 311 262

NAME: Triisooctyl Phosphate CASNO: 25103122


SYN: ClASS: 233 460
NAME: Trimethylamine CASNO: 00075503
SYN: ClASS: 143
NAME: 2,2,4-Trimethy1pentane CASNO: 00540841
SYN: ClASS: 291

NAME: 2,4,4-Trimethy1-1-pentene CASNO: 00107391


SYN: ClASS: 291

NAME: Trinitrophenol ,2 ,4,6 CASNO:


SYN: (See Picric Acid) ClASS:
NAME: 2,4,6-Trinitroto1uene CASNO: 00118967
SYN: TNT ClASS: 441
NAME: Triocty1 Phosphine CASNO: 04731537
SYN: ClASS: 461
NAME: Tri-n-propy1amine CASNO: 00102692
SYN: ClASS: 143
NAME: Tris(2,3-dibromopropy1) Phosphate CASNO: 00126727
SYN: ClASS; 460
NAME: Tritoly1 Phosphate CASNO:
SYN: (See Tricresy1 Phosphate) CLASS:
NAME: Turpentine CASNO: 08006642
SYN: CLASS: 291
NAME: Urea CASNO: 00057136
SYN: ClASS: 132
NAME: Va1eronitri1e CASNO: 00110598
SYN: ClASS: 431

B-S4
CHEMI CAL NAMES AND SYNONYMS

NAME: Vinyl Acetate CASNO: 00108054


SYN: ClASS: 222

NAME: Vinyl Chloride CASNO: 00075014


SYN: Chloroethene ClASS: 267

NAME: 4-Viny1-1-cyclohexane CASNO: 00100403


SYN: ClASS: 291

NAME: Vinylidene Chloride CASNO: 00075354


SYN: Dich1oroethylene, 1,1 ClASS: 267

NAME: Vinylidene Fluoride CASNO: 00075387


SYN: ClASS: 267

NAME: Water GASNO: 07732185


SYN: ClASS: 560

NAME: Xylene CASNO: 00133207


SYN: ClASS: 292

NAME: m-Xy1ene CASNO: 00108383


SYN: ClASS: 292

NAME: o-Xy1ene GASNO: 00095476


SYN: ClASS: 292

NAME: p-Xy1ene CASNO: 00106423


SYN: ClASS: 292

~-55
APPENDIX C

PRODUCT INDEX

C-l
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

ACRYLIC (002)

Product: Acrylic, Face Shield and Lens

097 09 Leonard Safety Epuipment, Inc.(D)


097 09 Protech Safety Equipment Inc. (D)

BUTYL(003)

Product: Butyl Rubber Latex Glove, Unsupported

012 00 Direct Safety Company(D)


012 00 Hub Safety Equipment, Inc.(D)
012 00 Latex Glove Co., Inc(M)
012 00 Mine Safety Appliances Co.(M)
012 00 North Hand Protection(M)
012 00 Protech Safety Equipment Inc. (D)
012 00 Safeco Inc. (D)

Product: Butyl Rubber Latex Glove, Supported

013 00 Latex Glove Co., Inc(M)


013 00 Mine Safety Appliances Co.(M)

Product: Butyl Rubber Glove, Solvent Dipped, Unsupported

014 00 LRC Safety Products Co. (D)


014 00 North Hand Protection(M)

Product: Butyl Rubber, Sheet

034 03 Record Industrial Co.(M)


034 05 Andover Industries, Inc.(M)
034 07 General Scientific Safety Equipment Company(D)
034 07 Safety Engineering & Supply Co. (D)
034 07 Tingley Rubber Corp.(M)

Product: Butyl Rubber/Nylon

064 03 General Scientific Safety Equipment Company(D)


064 03 Steel Grip Safety Apparel Co., Inc.(M)
064 05 Major Safety Service, Inc.(D)
064 06 United States Safety Service Co. (D)

Product: Butyl Rubber, Boots

085 08 Tingley Rubber Corp.(M)

C-2
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name
--------------------------------------------------------.-----------
Product: Butyl/Fabric/Butyl

130 05 Fyrepel Products Inc.(M)

Product: Butyl/Nylon/Butyl

140 01 Record Industrial Co.(M)


140 04 Record Industrial Co.(M)
140 05 Goodall Rubber Company(M)
140 05 Trelleborg, Inc.(M)

BUTYL/NEOPRENE (038)
Product: Butyl/Polyester/Chloroprene Rubber

110 05 Mine Safety Appliances Co.(M)

CELLULOSE ACETATE(OOl)
Product: Cellulose Acetate, Face Shield and Lens

099 09 Allied Glove & Safety Products Corp.(M)


099 09 Arbill Inc. (D)
099 09 Cesco Safety Products(M)
099 09 Direct Safety Company(D)
099 09 Eastco Industrial Safety Corp. (D)
099 09 Fisher Scientific Company(D)
099 09 General Scientific Safety Equipment Company(D)
099 09 Hub Safety Equipment, Inc.(D)
099 09 Inco Safety Products Co.(M)
099 09 Industrial Safety and Security Co. (D)
099 09 Latex Glove Co., Inc(M)
099 09 Leonard Safety Epuipment, Inc.(D)
099 09 Magid Glove and Safety Mfg. Co.(M)
099 09 Masterman's(D)
099 09 Protech Safety Equipment Inc. (D)
099 09 Pulmosan Safety Equipment Corp. (D)
099 09 Rockford Medical & Safety Co. (D)
099 09 The Sager Corporation(M)
099 09 Willson Safety Products(M)

CELLULOSE PROPIONATE(OOS)
Product: Cellulose Propionate, Face Shield and Lens

094 09 Eastco Industrial Safety Corp. (D)


094 09 Industrial Safety and Security Co. (D)
094 09 Interex Corp. (D)
094 09 Leonard Safety Epuipment, Inc. (D)
094 09 Rockford Medical & Safety Co. (D)
094 09 The Sager Corporation(M)
094 09 Willson Safety Products(M)

C-3
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

CHLOROBUTYL(006)

Product: Chlorobutyl RubberJNomex

052 05 ILC Dover(K)

Product: ChlorobutylJNomex/Chlorobuty1

142 05 Arrowhead Products(M)

CPE(007)

Product: Chlorinated Polyethylene

060 01 ILC Dover(K)


060 01 Jones Safety Supply, Inc.(D)
060 01 Safety Engineering & Supply Co. (D)
060 01 Safety First Industries(M)
060 03 Safety First Industries(M)
060 04 ILC Dover(K)
060 04 Jones Safety Supply, Inc.{D)
060 04 Safety Engineering & Supply Co. (D)
060 04 Safety First Industries{M)
060 05 ILC Dover(H)
060 05 Jones Safety Supply, Inc.{D)
060 05 Safety First Industries (M)
060 06 ILC Dover(H)
060 06 Jones Safety Supply, Inc.(D)
060 06 Safety First Industries{M)

CR 39(008)

Product: Cr 39, Lens and Face Shield

095 09 PPG Ind~stries, Inc.{S)


095 09 SGL Homa1ite Industries{S)

GORE-TEX(018)

Product: Microporous Teflon/Polyester

092 01 Goodall Rubber Company{M)


092 02 Body-Guard(M)
092 02 Goodall Rubber Company(M)
092 02 Vidaro Corp. (M)
092 04 Goodall Rubber Company(M)
092 06 Goodall Rubber Company(M)

C-4
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

NAT+NEOP+NBR(019)

Product: Natural Rubber+Chloroprene+Nitrile Glove, Unsupported

023 00 Allied Glove & Safety Products Corp.(M)


023 00 Industrial Safety and Security Co. (D)
023 00 Keystone Protection Corp. (D)
023 00 Leonard Safety Epuipment, Inc.(D)
023 00 Pioneer Industrial Products Co.(M)

NATURAL RUBBER(013)

Product: Natural Rubber Latex Glove, Supported

001 00 Allied Glove & Safety Products Corp.(M)


001 00 Best Manufacturing Company(M)
001 00 Boss Manufacturing Company(M)
001 00 Comasec(M)
001 00 Eastco Industrial Safety Corp. (D)
001 00 Edmont Div. Becton, Dickinson & Co.(M)
001 00 General Scientific Safety Equipment Company(D)
001 00 Goodyear Rubber Products Corp.(S)
001 00 Granet(M)
001 00 Holland Safety Supply Co. (D)
001 00 IPESCo., Inc.(M)
001 00 Industrial Products Co., Inc.(D)
001 00 Industrial Safety and Security Co. (D)
001 00 Interex Corp. (D)
001 00 Intermarket Latex, Inc.(M)
001 00 Keystone Protection Corp. (D)
001 00 Latex Glove Co., Inc(M)
001 00 Magid Glove and Safety Mfg. Co.(M)
001 00 Masterman's(D)
001 00 Miller Products Co., Inc.(D)
001 00 Mine Safety Appliances Co.(M)
001 00 Mont~ Glove Company(M)
001 00 Protech Safety Equipment Inc .. (D)
001 00 Safeco Inc. (D)
001 00 W.H. Salisbury & Co.(M)
001 00 Standard Glove & Safety Equip. Corp.(D)
001 00 Stauffer Manufacturing Company(M)
001 00 H. Texter.Glove Company Inc. (D)

Product: Natural Rubber Glove, Solvent Dipped, Unsupported

015 00 Arbill Inc. (D)


015 00 North Hand Protection(M)

C-5
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Natural Rubber Latex Glove, Unsupported

017 00 Allied Glove & Safety Products Corp.(M)


017 00 Ansell Industrial Products(M)
017 00 Best Manufacturing Company(M)
017 00 Boss Manufacturing Company(M)
017 00 Comasec(M)
017 00 Dayton Flexible Products(M)
017 00 Defense Appare1(M)
017 00 Eastco Industrial Safety Corp. (D)
017 00 Edmont Div. Becton, Dickinson & Co.(M)
017 00 General Scientific Safety Equipment Company(D)
017 00 Glover Latex, Inc.(M)
017 00 Goodyear Rubber Products Corp.(S)
017 00 Granet(M)
017 00 Holland Safety Supply Co. (D)
017 00 IPESCo., Inc.(M)
017 00 Industrial Products Co., Inc.(D)
017 00 Industrial Safety and Security Co. (D)
017 00 Interex Corp. (D)
017 00 Intermarket- Latex, Inc.(M)
017 00 Keystone Protection Corp. (D)
017 00 LRC Safety Products Co. (D)
017 00 Latex Glove Co., Inc(M)
017 00 Leonard Safety Epuipment, Inc.(D)
017 00 Magid Glove and Safety Mfg. Co.(M)
017 00 Masterman's(D)
017 00 Memphis Glove Company(M)
017 00 Killer Products Co., Inc.(D)
017 00 Kine Safety Appliances Co.(M)
017 00 North Hand Protection(M)
017 00 Pioneer Industrial Products Co.(M)
017 00 Protech Safety Equipment Inc. (D)
017 00 Renco Corp(M)
017 00 Robar Protective Products(D)
017 00 Rockford Medical & Safety CO. CD)
017 00 Safeco Inc. (D)
017 00 Y.H. Salisbury & Co.(M)
017 00 Standard Glove & Safety Equip. Corp.(D)
017 00 Stauffer Manufacturing Company(M)
017 00 H. Texier Glove Company Inc. (D)

Product: Natural Rubber, Sheet

045 03 Masterman's(D)
045 06 General Scientific Safety Equipment Company(D)
045 07 Allied Glove & Safety Products Corp.(M)
045 07 Arbill Inc. (D)
045 07 Boss Manufacturing Company(M)

C-6
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Natural Rubber, Sheet (cont.)


045 07 Defense Apparel(M)
045 07 La Crosse Footwear, Inc.(M)
045 07 Latex Glove Co., Inc(M)
045 07 Lehigh Safety Shoe Co.(M)
045 07 Leonard Safety Epuipment, Inc.(D)
045 07 Magid Glove and Safety Mfg. Co.(M)
045 07 Ranger(M)
045 07 Record Industrial Co.(M)
045 07 Safety Engineering & Supply Co. (D)
045 07 Tingley Rubber Corp.(M)

Product: Natural Rubber, Boots

080 08 Allied Glove & Safety Products Corp.(M)


080 08 Arbill Inc. (D)
080 08 Boss Manufacturing Company(M)
080 08 Direct Safety Company(D)
080 08 Eastco Industrial Safety Corp. (D)
080 08 Interex Corp. (D)
080 08 Iron Age Protective Company(M)
080 08 Jordan David Safety Products(M)
080 08 La Crosse Footwear, Inc.(M)
080 08 Latex Glove Co., Inc(M)
080 08 Lehigh Safety Shoe Co.(M)
080 08 Leonard Safety Epuipment, Inc.(D)
080 08 Masterman'sCD)
080 08 Miller Products Co., Inc.(D)
080 08 Rainfair, Inc.(M)
080 08 Record Industrial Co.(M)
080 08 Robar Protective Products(D)
080 08 Safety Engineering & Supply Co. (D)
080 08 Tingley Rubber Corp.(M)

Product: Natural Rubber/Nylon

087 03 Frommelt Industries,Inc.(M)

Product: Natural Rubber/Cotton

089 01 Boss Manufacturing Company(M)


089 01 Record Industrial Co.(M)
089 02 Boss Manufacturing Company(M)
089 03 Boss Manufacturing Company(M)
089 03 Direct Safety Company(D)
089 03 Fisher Scientific Company(D)
089 03 Protech Safety Equipment Inc. (D)
089 03 Rockford Medical & Safety Co. (D)

C-7
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Natural Rubber/Polyester


136 01 Plastex Protective Products, Inc.(M)
136 03 Standard Glove & Safety Equip. Corp.(D)
136 04 Plastex Protective Products, Inc.(M)
136 06 Plastex Protective Products, Inc.(M)

NEOP+NAT RUBBER(OlS)

Product: Chloroprene+Natural Rubber Latex Glove, Unsupported

026 00 Ansell Industrial Products(M)


026 00 Arbill Inc. (D)
026 00 Clean Room Products, Inc.(M)
026 00 Eastco Industrial Safety Corp. (D)
026 00 Hub Safety Equipment, Inc.(D)
026 00 Industrial Products Co., Inc.(D)
026 00 Intermarket Latex, Inc.(M)
026 00 International Playtex, Inc.(M)
026 00 Keystone Protection Corp. (D)

NEOP/NAT RUBBER(039)
Product: Cloroprene/Natural Rubber Latex Glove, Unsupported

008 00 Ansell Industrial Products(M)


008 00 Industrial Products Co., Inc.(D)

NEOPRENE (016)

Product: Chloroprene Latex Glove, Supported

002 00 Allied Glove & Safety Products Corp.(M)


002 00 Arbill Inc. (D)
002 00 Best Manufacturing Company(M)
002 00 Boss Manufacturing Company(M)
002 00 Comasec(M)
002 00 Eastco Industrial Safety Corp. (D)
002 00 Edmont Div. Becton, Dickinson & Co.(M)
002 00 General Scientific Safety Equipment Company(D)
002 00 Goodyear Rubber Products Corp.(S)
002 00 Granet(M)
002 00 Holland Safety Supply Co. (D)
002 00 Hub Safety Equipment, Inc.(D)
002 00 IPESCo., Inc. (M)
002 00 Industrial Products Co., Inc.(D)
002 00 Industrial Safety and Security Co. (D)
002 00 Interex Corp. (D)
002 00 Intermarket Latex, Inc.(M)
002 00 Keystone Protection Corp. (D)
002 00 Latex Glove Co., Inc(M)
002 00 Leonard Safety Epuipment, Inc.(D)

C-8
\
\

PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Chloroprene Latex Glove, Supported (cont.)


002 00 Magid Glove and Safety Mfg. Co.(M)
002 00 Major Safety Service, Inc.(D)
002 00 Masterman's(D)
002 00 Miller Products Co., Inc.(D)
002 00 Mine Safety Appliances Co.(M)
002 00 Monte Glove Company(M)
002 00 OKI Supply Co.(M)
002 00 Pioneer Industrial Products Co.(M)
002 00 Pro tech Safety Equipment Inc. (D)
002 00 Rockford Medical & Safety Co. (D)
002 00 Safeco Inc. (D)
002 00 Standard Glove & Safety Equip. Corp.(D)
002 00 Stauffer Manufacturing Company(M)
002 00 H. Texier Glove Company Inc.(D)
002 00 Trelleborg, Inc.(M)
002 00 Wheeler Protective Apparel, Inc.(M)

Product: Chloroprene Milled/Chloroprene Latex Glove, Unsupported

010 00 Allied Glove & Safety Products Corp.(M)


010 00 Arbill Inc. (D)
010 00 Boss Manufacturing Company(M)
010 00 Direct Safety Company(D)
010 00 Industrial Safety and Security Co. (D)
010 00 Keystone Protection Corp. (D)
010 00 Leonard Safety Epuipment, Inc.(D)
010 00 Pioneer Industrial Products Co.(M)

Product: Ch1oroprene Rubber Latex (Baypren) Glove, Unsupported

011 00 Allied Glove & Safety Products Corp.(M)


011 00 Best Manufacturing Company(M)
011 00 Direct Safety Company(D)
011 00 Eastco Industrial Safety Corp. (D)
011 00 Granet(M)
011 00 IPESCo·., Inc. (M)
011 00 Interex Corp. (D)
011 00 Safeco Inc. (D)

Product: Chloroprene Rubber Latex Glove, Unsupported

018 00 Allied Glove & Safety Products Corp.(M)


018 00 Ansell Industrial Products(M)
018 00 Best Manufacturing Company(M)
018 00 Eastco Industrial Safety Corp. (D)
018 00 Edmont Div. Becton, Dickinson & Co.(M)
018 00 General Scientific Safety Equipment Company(D)
018 00 Goodyear Rubber Products Corp.(S)
018 00 Holland Safety Supply Co. (D)
018 00 Hub Safety Equipment, Inc.(D)

C-9
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Chloroprene Rubber Latex Glove, Unsupported (cont.)


018 00 IPESCo., Inc. (M)
018 00 Industrial Products Co., Inc.(D)
018 00 Industrial Safety and Security Co. (D)
018 00 Interex Corp. (D)
018 00 Intermarket Latex, Inc.(M)
018 00 Keystone Protection Corp. (D)
018 00 LRC Safety Products Co. (D)
018 00 Latex Glove Co., Inc(M)
018 00 Leonard Safety Epuipment, Inc.(D)
018 00 Magid Glove and Safety Mfg. Co.(M)
018 00 Masterman's(D)
018 00 Memphis Glove Company(M)
018 00 Mine Safety Appliances Co.(M)
018 00 Pioneer Industrial Products Co.(M)
018 00 Protech Safety Equipment Inc. (D)
018 00 Renco Corp(M)
018 00 Rockford Medical & Safety Co. (D)
018 00 Safeco Inc.(D)
018 00 Standard Glove & Safety Equip. Corp.(D)
018 00 Stauffer Manufacturing Company(M)
018 00 H. Texier Glove Company Inc. (D)

Product: Chloroprene Rubber, Sheet

031 01 Miller Products Co., Inc.(D)


031 02 Miller Products Co., Inc.(D)
031 03 Acme Mills Company(M)
031 03 Arbill Inc. (D)
031 03 Boss Manufacturing Company(M)
031 03 Magid Glove and Safety Mfg. Co.(M)
031 03 Masterman's(D)
031 04 Killer Products Co., Inc.(D)
031 05 Andover Industries, Inc.(M)
031 06 Miller Products Co., Inc.(D)
031 07 General Scientific Safety Equipment Company(D)
031 07 Ranger(M)
031 07 Record Industrial Co.(M)
031 07 Safety Engineering & Supply Co. (D)
031 07 Tingley Rubber Corp.(M)

Product: Chloroprene Rubber/Polyester

051 02 Boss Manufacturing Company(M)


051 03 Fairway Products(M)
051 03 LRC Safety Products Co. (D)
051 03 Pulmosan Safety Equipment Corp. (D)
051 04 Boss Manufacturing Company(M)
051 06 Boss Manufacturing Company(M)

c-10
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Chloroprene Rubber, Boots

081 08 Allied Glove & Safety Products Corp.(M)


081 08 Boss Manufacturing Company(M)
081 08 Eastco Industrial Safety Corp. (D)
081 08 General Scientific Safety Equipment Company(D)
081 08 Keystone Protection Corp. (D)
081 08 La Crosse Footwear, Inc.(M)
081 08 Latex Glove Co., Inc(M)
081 08 Lehigh Safety Shoe Co.(M)
081 08 Magid Glove and Safety Mfg. Co.(M)
081 08 Masterman's(D)
081 08 Pro tech Safety Equipment Inc. (D)
081 08 Rainfair. Inc.(M)
081 08 Record Industrial Co.(M)
081 08 Robar Protective Products(D)
081 08 Safety Engineering & Supply Co. (D)
081 08 Standard Safety Equipment Co.(M)
081 08 Tingley Rubber Corp.(M)
...
Product: Chloroprene Rubber/Nylon

093 01 Eastco Industrial Safety Corp. (D)'


093 01 Encon Manufacturing Co.(M)
093 01 Keystone Protection Corp. (D)
093 01 Marathon Rubber(M)
093 01 Miller Products Co., Inc.(D)
093 01 Mine Safety Appliances Co.(M)
093 01 National Safety Wear, Inc.(M)
093 01 Protech Safety Equipment Inc. (D)
093 01 Protexall Company(M)
093 01 Rainfair, Inc.(M)
093 01 Record Industrial Co.(M)
093 01 Safeco Inc. (D)
093 01 Safety Engineering & Supply Co. (D)
093 01 Safety First Industries(M}
093 01 Sawyer-Tower(M)
093 01 Tingley Rubber Corp.(M)
093 02 Encon Manufacturing Co.(M)
093 02 Keystone Protection Corp. (D)
093 02 Marathon Rubber(M)
093 02 Miller Products Co., Inc.(D)
093 03 Encon Manufacturing Co.(M)
093 03 Protexall Company(M)
093 03 Safety First Industries(M)
093 04 Eastco Industrial Safety Corp. (D)
093 04 Encon Manufacturing Co.(M)
093 04 Keystone Protection Corp. (D)
093 04 Marathon Rubber(M)

C-ll
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Chloroprene Rubber/Nylon (cont.)


093 04 Miller Products Co., Inc.(D)
093 04 Mine Safety Appliances Co.(M)
093 04 National Safety Wear, Inc.(M)
093 04 Protech Safety Equipment Inc. (D)
093 04 Rainfair, Inc.(M)
093 04 Record Industrial Co.(M)
093 04 Safeco Inc. (D)
093 04 Safety Engineering & Supply Co. (D)
093 04 Sawyer-Tower(M)
093 04 Tingley Rubber Corp.(M)
093 05 National Draeger, Inc.(M)
093 06 Eastco Industrial Safety Corp. (D)
093 06 Encon Manufacturing Co.(M)
093 06 Keystone Protection Corp. (D)
093 06 National Safety Wear, Inc.(M)
093 06 Rainfair, Inc.(M)
093 06 United States Safety Service Co. (D)

Product: Chloroprene Milled/Chloroprene Latex Glove, Supported


125 00 Direct Safety Company(D)
125 00 Miller Products Co., Inc.(D)

Product: Chloroprene Rubber/Fabric


138 01 Safety Engineering & Supply Co. (D)
138 01 Safety First Industries(M)
138 01 Tingley Rubber Corp.(M)
138 01 Wheeler Protective Apparel, Inc.(M)
138 03 Pro tech Safety Equipment Inc. (D)
138 03 Safety First Industries(M)
138 04 Safety Engineering & Supply Co. (D)
138 04 Tingley Rubber Corp.(M)
138 04 Wheeler Protective Apparel, Inc.(M)
138 06 Wheeler Protective Apparel, Inc.(M)

Product: Chloroprene/Fabric/Chloroprene
139 01 Eastco Industrial Safety Corp. (D)
139 01 Rainfair, Inc.(M)
139 01 Sawyer-Tower(M)
139 04 Eastco Industrial Safety Corp. (D)
139 04 Rainfair, Inc.(M)
139 04 Sawyer-Tower(M)
139 06 Eastco Industrial Safety Corp. (D)
139 06 Rainfair, Inc.(M)

Product: Chloroprene Rubber/Kevlar


141 01 Safety First Industries(M)
141 03 Safety First Industries(M)
141 04 Safety First Industries(M)

C-l2
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

NEOPRENE+PVC(045)

Product: Chloroprene+PVC/Polyester

127 01 Direct Safety Company(D)


127 02 Direct Safety Company(D)
127 04 Direct Safety Company(D)
127 06 Direct Safety Company(D)

NEOPRENE+SBR RUBBER(017)

Product: Chloroprene (35%)+SBR(65%)/Nylon--Tufflon

065 01 General Scientific Safety Equipment Company (D)


065 01 Sawyer-Tower(M)
065 04 General Scientific Safety Equipment Company (D)
065 04 Sawyer-Tower(M)

Product: Ch1oroprene(15%)+SBR(85%)/Cotton--Tuffprene

066 01 General Scientific Safety Equipment Company (D)


066 01 Protech Safety Equipment Inc. (D)
066 01 Safeco Inc. (D)
066 01 Sawyer-Tower(M)
066 04 General Scientific Safety Equipment Company (D)
066 04 Pro tech Safety Equipment Inc. (D)
066 04 Safeco Inc. (D)
066 04 Sawyer-Tower(M)
066 06 General Scientific Safety Equipment Company (D)
066 06 Pro tech Safety Equipment Inc. (D)
066 06 Safeco Inc.(D)
066 06 Sawyer-Tower(K)

NITRlLE(02l)

Product: Nitrile Rubber Latex Glove, Supported

005 00 Allied Glove & Safety Products Corp.(M)


005 00 Arbill Inc. (D)
005 00 Best Manufacturing Company(M)
005 00 Boss Manufacturing Company(M)
005 00 Comasec(M)
005 00 Eastco Industrial Safety Corp. (D)
005 00 Edmont Div. Becton, Dickinson & Co.(M)
005 00 General Scientific Safety Equipment Company(D)
005 00 Goodyear Rubber Products Corp.(S)
005 00 Granet(M)

C-13
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Nitrile Rubber Latex Glove, Supported (cont.)


005 00 Holland Safety Supply Co. (D)
005 00 IPESCo., Inc.(M)
005 00 Industrial Products Co., Inc.(D)
005 00 Industrial Safety and Security Co. (D)
005 00 Interex Corp. (D)
005 00 Intermarket Latex, Inc.(M)
005 00 Keystone Protection Corp. (D)
005 00 LRC Safety Products Co. (D)
005 00 Latex Glove Co., Inc(M)
005 00 Leonard Safety Epuipment, Inc.(D)
005 00 Magid Glove and Safety Mfg. Co.(M)
005 00 Masterman's(D)
005 00 Miller Products Co., Inc.(D)
005 00 Monte Glove Company(M)
005 00 North Hand Protection(M)
005 00 Pioneer Industrial Products Co.(M)
005 00 Pro tech Safety Equipment Inc. (D)
005 00 Robar Protective Products(D)
005 00 Safeco Inc. (D)
005 00 Standard Glove & Safety Equip. Corp.(D)
005 00 Stauffer Manufacturing Company(M)
005 00 H. Texier Glove Company Inc. (D)

Product: Nitrile Rubber Latex Glove, Unsupported

019 00 Allied Glove & Safety Products Corp.(M)


019 00 Ansell Industrial Products(M)
019 00 Arbill Inc. (D)
019 00 Best Manufacturing Company(M)
019 00 Boss Manufacturing Company(M)
019 00 Clean Room Products, Inc.(M)
019 00 Direct Safety Company(D)
019 00 Eastco Industrial Safety Corp. (D)
019 00 Edmont Div. Becton, Dickinson & Co.(M)
019 00 General Scientific Safety Equipment Company(D)
019 00 Glover Latex, Inc.(M)
019 00 Goodyear Rubber Products Corp.(S)
019 00 Granet(M)
019 00 Holland Safety Supply Co. (D)
019 00 Hub Safety Equipment, Inc.(D)
019 00 IPESCo., Inc. (M)
019 00 Industrial Products Co., Inc.(D)
019 00 Industrial Safety and Security Co. (D)
019 00 Interex Corp. (D)
019 00 Intermarket Latex, Inc.(M)
019 00 Keystone Protection Corp. (D)
019 00 LRC Safety Products Co. (D)
019 00 Latex Glove Co., Inc(M)
019 00 Leonard Safety Epuipment, Inc.(D)
019 00 Magid Glove and Safety Mfg. Co.(M)

C-14
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Nitrile Rubber Latex Glove, Unsupported (cont.)


019 00 Masterman's(D)
019 00 Memphis Glove Company(M)
019 00 North Hand Protection(M)
019 00 Pioneer Industrial Products Co.(M)
019 00 Protech Safety Equipment Inc. (D)
019 00 Renco Corp(M)
019 00 Rockford Medical & Safety Co. (D)
019 00 Safeco Inc. (D)
019 00 Standard Glove & Safety Equip. Corp.(D)
019 00 Stauffer Manufacturing Company(M)
019 00 H. Texier Glove Company Inc. (D)

Product: Nitrile Rubber Glove, Solvent Dipped, Unsupported

020 00 Ansell Industrial Products(M)


020 00 Industrial Products Co., Inc.(D)
020 00 Intermarket Latex, Inc.(M)
020 00 Keystone Protection Corp. (D)

Product: Nitrile Rubber, Sheet

033 03 Boss Manufacturing Company(M)


033 03 Record Industrial Co.(M)
033 03 Rockford Medical & Safety Co. (D)

Product: Nitrile Rubber/Polyester

059 03 Protexa1l Company(M)

Product: Nitrile Rubber/Nylon

078 03 Protech Safety Equipment Inc. (D)


078 03 Safeco Inc. (D)
078 03 Sawyer-Tower(M)

Product: Nitrile Rubber, Boots

084 08 Eastco Industrial Safety Corp. (D)


084 08 Magid Glove and Safety Mfg. Co.(M)
084 08 Rainfair, Inc.(M)

Product: Nitrile/Fabric

132 01 General Scientific Safety Equipment Company(D)


132 03 Allied Glove & Safety Products Corp.(M)
132 03 Eastco Industrial Safety Corp. (D)
132 03 Edmont Div. Becton, Dickinson & Co.(M)
132 03 Goodyear Rubber Products Corp.(S)
132 03 Holland Safety Supply Co. (D)
132 03 Industrial Products Co., Inc.(D)

C-15
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Nitrile/Fabric (cont.)


132 03 Industrial Safety and Security Co. (D)
132 03 Interex Corp. (D)
132 03 Masterman's(D)
132 03 Protech Safety Equipment Inc. (D)
132 03 Safeco Inc. (D)
132 03 Standard Glove & Safety Equip. Corp.(D)
132 03 Stauffer Manufacturing Company(M)
132 03 H. Texier Glove Company Inc. (D)
132 04 General Scientific Safety Equipment Company(D)
132 05 Eastco Industrial Safety Corp. (D)

NITRILE+PVC(020)

Product: Nitrile+PVC Glove, Supported

057 00 Barry Manufacturing Co. Ltd.(M)


057 00 Comasec(M)
057 00 North Hand Protection(M)

Product: Nitrile+PVC/Fabric

058 01 Allied Glove & Safety Products Corp. (M)·


058 01 Eastco Industrial Safety Corp. (D)
058 01 Edmont Div. Becton, Dickinson & Co.(M)
058 01 Goodyear Rubber Products Corp.(S)
058 01 Holland Safety Supply Co. (D)
058 01 Industrial Products Co., Inc.(D)
058 01 Industrial Safety and Security Co. (D)
058 01 Interex Corp. (D)
058 01 Masterman's(D)
058 01 Protech Safety Equipment Inc. (D)
058 01 Rainfair, Inc.(M)
058 01 Safeco Inc. (D)
058 01 Standard Glove & Safety Equip. Corp.(D)
058 01 Stauffer ~anufacturing Company(M)
058 01 H. Texier Glove Company Inc. (D)
058 02 Edmont Div. Becton, Dickinson & Co.(M)
058 02 Goodyear Rubber Products Corp.(S)
058 02 Holland Safety Supply Co. (D)
058 02 Industrial Products Co., Inc.CD)
058 02 Industrial Safety and Security Co. (D)
058 02 Interex Corp. (D)
058 02 Masterman's(D)
058 02 Protech Safety Equipment Inc. (D)
058 02 Standard Glove & Safety Equip. Corp. CD)
058 02 Stauffer Manufacturing Company(M)
058 02 H. Texier Glove Company Inc. (D)
058 03 Protexall Company(M)
058 04 Allied Glove & Safety Products Corp.(M)
058 04 Eastco Industrial Safety Corp. (D)

C-16
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Haterial Code Type Vendor Name

Product: Nitrile+PVC/Fabric (cont.)


058 04 Edmont Div. Becton, Dickinson & Co.(M)
058 04 Goodyear Rubber Products Corp.(S)
058 04 Industrial Products Co., Inc.(D)
058 04 Industrial Safety and Security Co. (D)
058 04 Interex Corp. (D)
058 04 Masterman's(D)
058 04 Protech Safety Equipment Inc. (D)
058 04 Rainfair, Inc.(M)
058 04 Safeco Inc. (D)
058 04 Standard Glove & Safety Equip. Corp.(D)
058 04 Stauffer Manufacturing Company(M)
058 04 H. Texier Glove Company Inc. (D)
058 06 Allied Glove & Safety Products Corp.(M)
058 06 Eastco Industrial Safety Corp. (D)
058 06 Edmont Div. Becton, Dickinson & Co.(M)
058 06 Goodyear Rubber Products Corp.(S)
058 06 Holland Safety Supply Co. (D)
058 06 Industrial Products Co., Inc.(D)
058 06 Industrial Safety and Security Co. (D)
058 06 Interex Corp. (D)
058 06 Masterman's(D)
058 06 Protech Safety Equipment Inc. (D)
058 06 Rainfair, Inc.(M)
058 06 Safeco Inc.(D)
058 06 Standard Glove & Safety Equip. Corp.(D)
058 06 Stauffer Manufacturing Company(M)
058 06 H. Texier Glove Company Inc. (D)

NONWOVEN FABRIC(024)

Product: Sontara

025 01 Mar-Mac Manufacturing Co., Inc.(M)


025 01 Protech Safety Equipment Inc. (D)
025 02 Mar-Mac Manufacturing Co., Inc.(M)
025 02 Pro~ech Safety Equipment Inc. (D)
025 03 Mar-Mac Manufacturing Co., Inc. (M)
025 03 Protech Safety Equipment Inc. (D)
025 04 Mar-Mac Manufacturing Co., Inc.(M)
025 04 Protech Safety Equipment Inc. (D)
025 OS Mar-Mac Manufacturing Co., Inc.(M)
025 06 Mar-Mac Manufacturing Co., Inc.(M)
025 06 Protech Safety Equipment Inc. (D)
025 07 Pro tech Safety Equipment Inc. (D)

C-17
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

NONWOVEN PE(03l)
Product: Tyvek
071 01 Allied Glove & Safety Products Corp.(M)
071 01 American Scientific Products(D)
071 01 Arbi1l Inc. (D)
071 01 Charkate(M)
071 01 Clean Room Products, Inc.(M)
071 01 Coyne Safety Equipment, Inc.(D)
071 01 Daffin Disposables, Inc.(M)
071 01 Direct Safety Company(D)
071 01 Disposables Inc.(M)
071 01 Durafab Disposables, Inc.(M)
071 01 Eastco Industrial Safety Corp. (D)
071 01 Edmont Div. Becton, Dickinson & Co.(M)
071 01 Fisher Scientific Company(D)
071 01 Goodyear Rubber Products Corp.(S)
071 01 Holland Safety Supply Co. CD)
071 01 Hub Safety Equipment, Inc.CD)
071 01 IPESCo., Inc.CM)
071 01 Industrial Products Co., Inc.(D)
071 01 Industrial Safety and Security Co. (D)
071 01 Interex Corp. (D)
071 01 Kappler Disposables, Inc.(M)
071 01 Latex Glove Co., Inc(M)
071 01 Leonard Safety Epuipment, Inc.CD)
071 01 Magid Glove and Safety Mfg. Co.(M)
071 01 Mar-Mac Manufacturing Co., Inc.(M)
071 01 Masterman'sCD)
071 01 Melco, Inc. (M)
071 01 Mine Safety Appliances Co.CM)
071 01 Protech Safety Equipment Inc. (D)
071 01 Rockford Medical & Safety Co.(D)
071 01 Safeco Inc. CD)
071 01 Standard Glove & Safety Equip. Corp. CD)
071 01 Stauffer Manufacturing CompanyCM)
071 01 Superior Surgical Mfg. Co., Inc.(M)
071 01 H. Texie~ Glove Company Inc.(D)
071 01 United States Plastic Corp. (D)
071 02 Allied Glove & Safety Products Corp.(M)
071 02 American Scientific Products(D)
071 02 Arbill Inc. CD)
071 02 Boss Manufacturing Company(M)
071 02 Charkate(M)
071 02 Clean Room Products, Inc.(M)
071 02 Coyne Safety Equipment, Inc.(D)
071 02 Daffin Disposables, Inc.(M)
071 02 Direct Safety Company CD)
071 02 Disposables Inc.(M)
071 02 Durafab Disposables, Inc.(M)
071 02 Eastco Industrial Safety Corp. (D)
071 02 Edrnont Div. Becton, Dickinson & Co.(M)
071 02 Fisher Scientific Company(D)
071 02 General Scientific Safety Equipment Company(D)

C-18
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Tyvek (cont. )


071 02 Goodyear Rubber Products Corp.(S)
071 02 Holland Safety Supply Co. (D)
071 02 Hub Safety Equipment, Inc.(D)
071 02 IPESCo., Inc.(M)
071 02 Industrial Products Co., Inc.(D)
071 02 Industrial Safety and Security Co. (D)
071 02 Interex Corp. (D)
071 02 Kappler Disposables, Inc.(M)
071 02 Latex Glove Co., Inc(M)
071 02 Leonard Safety Epuipment, Inc.(D)
071 02 Magid Glove and Safety Mfg. Co.(M)
071 02 Mar-Mac Manufacturing Co., Inc.(M)
071 02 Masterman's(D)
071 02 Melco, Inc. (M)
071 02 Mine Safety Appliances Co.(M)
071 02 Protech Safety Equipment Inc. (D)
071 02 Rockford Medical & Safety Co. (D)
071 02 Safeco Inc. (D)
071 02 Standard Glove & Safety Equip. Corp.(D)
071 02 Stauffer Manufacturing Company(M)
071 02 Superior Surgical Mfg. Co., Inc.(M)
071 02 H. Texier Glove Company Inc. (D)
071 02 United States Plastic Corp. (D)
071 03 Acme Mills Company(M)
071 03 Allied Glove & Safety Products Corp.(M)
071 03 Arbill Inc. (D)
071 03 Boss Manufacturing Company(M)
071 03 Clean Room Products, Inc.(M)
071 03 Coyne Safety Equipment, Inc.(D)
071 03 Daffin Disposables, Inc.(M)
071 03 Direct Safety Company(D)
071 03 Disposables Inc.(M)
071 03 Durafab Disposables, Inc.(M)
071 03 Latex Glove Co., Inc(M)
071 03 Leonard Safety Epuipment, Inc.(D)
071 03 Magid Glove and Safety Mfg. Co.(M)
071 03 Mar-Mac Manufacturing Co.,"Inc.(M)
071 03 Masterman's(D)
071 03 Melco, Inc. (M)
071 03 Mine Safety Appliances Co.(M)
071 03 Protech Safety Equipment Inc. (D)
071 03 Rockford Medical & Safety Co. (D)
071 03 Superior Surgical Mfg. Co., Inc.(M)
071 03 United States Plastic Corp. (D)
071 04 Allied Glove & Safety Products Corp.(M)
071 04 Arbill Inc. (D)
071 04 Charkate(M)
071 04 Coyne Safety Equipment, Inc.(D)
071 04 Daffin Disposables, Inc.(M)
071 04 Direct Safety Company(D)

C-19
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Tyvek (cont. )


071 04 Disposables Inc.{M)
071 04 Durafab Disposables, Inc.(M)
071 04 Eastco Industrial Safety Corp. (D)
071 04 Edmont Div. Becton, Dickinson & Co.(M)
071 04 Goodyear Rubber Products Corp.{S)
071 04 Holland Safety Supply Co. (D)
071 04 Hub Safety Equipment, Inc.{D)
071 04 IPESCo., Inc. (M)
071 04 Industrial Products Co., Inc.(D)
071 04 Industrial Safety and Security Co. (D)
071 04 Interex Corp. (D)
071 04 Kappler Disposables, Inc.(M)
071 04 Latex Glove Co., Inc(M)
071 04 Leonard Safety Epuipment, Inc.(D)
071 04 Magid Glove and Safety Mfg. Co.(M)
071 04 Mar-Hac Manufacturing Co., Inc. (M)
071 04 Masterman's(D)
071 04 Melco, Inc. (M)
071 04 Mine Safety Appliances Co.(M)
071 04 Protech Safety Equipment Inc. (D)
071 04 Rockford Medical & Safety Co. (D)
071 04 Safeco Inc. (D)
071 04 Standard Glove & Safety Equip. Corp.(D)
071 04 Stauffer Manufacturing Company{M)
071 04 Superior Surgical Mfg. Co., Inc.(M)
071 04 H. Texier Glove Company Inc. (D)
071 04 United States Plastic Corp. (D)
071 05 Charkate(H)
071 05 Coyne Safety Equipment, Inc.(D)
071 05 Daffin Disposables, Inc.(M)
071 05 Direct Safety Company(D)
071 05 Disposables Inc.(M)
071 05 Durafab Disposables, Inc.(M)
071 05 Hub Safety Equipment, Inc.(D)
071 05 IPESCo., Inc.(M)
071 05 Industrial Products Co., Inc. (D)
071 05 Industrial Safety and Security Co. (D)
071 05 Kappler Disposables, Inc.(M)
071 05 Mar-Mac Manufacturing Co., Inc.(M)
071 05 Mine Safety Appliances Co.(M)
071 06 American Scientific Products(D)
071 06 E.D. Bullard Company(M)
071 06 Charkate(H)
071 06 Clean Room Products, Inc.(M)
071 06 Coyne Safety Equipment, Inc.(D)
071 06 Direct Safety Company(D)
071 06 Disposables Inc.(M)
071 06 Durafab Disposables, Inc.(M)
071 06 Eastco Industrial Safety Corp. (D)
071 06 Edmont Div. Becton, Dickinson & Co.(M)

C-20
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vundor Name

Product: Tyvek (cont. )


071 06 General Scientific Safety Equipment Company(D)
071 06 Goodyear Rubber Products Corp.(S)
071 06 Holland Safety Supply Co. (D)
071 06 Industrial Products Co., Inc.(D)
071 06 Industrial Safety and Security Co. (D)
071 06 Interex Corp. (D)
071 06 Kappler Disposables, Inc.(M)
071 06 Mar-Mac Manufacturing Co., Inc.(M)
071 06 Hasterman's(D)
071 06 Melco, Inc. (M)
071 06 Mine Safety Appliances Co.(M)
071 06 Protech Safety Equipment Inc. (D)
071 06 Rockford Medical & Safety Co. CD)
071 06 Safeco Inc. CD)
071 06 Standard Glove & Safety Equip. Corp.(D)
071 06 Stauffer Manufacturing Company(M)
071 06 Superior Surgical Mfg. Co., Inc.(M)
071 06 H. Texier Glove Company Inc. (D)
071 06 United States Safety Service Co. (D)
071 07 Allied Glove & Safety Products Corp.(M)
071 07 American Scientific Products(D)
071 07 Arbill Inc. (D)
071 07 Charkate(M)
071 07 Clean Room Products, Inc.(M)
071 07 Coyne Safety Equipment, Inc.CD)
071 07 Daffin Disposables, Inc.CM)
071 07 Direct Safety Company(D)
071 07 Disposables Inc.(M)
071 07 Durafab Disposables, Inc.(M)
071 07 General Scientific Safety Equipment Company(D)
071 07 Hub Safety Equipment, Inc.CD)
071 07 Industrial Products Co., Inc.CD)
071 07 Industrial Safety and Security Co. (D)
071 07 Kappler Disposables, Inc.(M)
071 07 Leonard Safety Epuipment, Inc.(D)
071 07 Mar~Mac Manufacturing Co.,. Inc. (M)
071 07 Masterman's(D)
071 07 Mine Safety Appliances Co.(M)
071 07 Rockford Medical & Safety Co. (D)
071 07 Superior Surgical Mfg. Co., Inc. (M)

NONWOVEN PP(023)

Product: Polypropylene, Nonwoven

135 02 Kimberly-Clark Corp.(M)

C-21
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

PE(025)

Product: Polyethylene Glove, Unsupported

006 00 Allied Glove & Safety Products Corp.(M)


006 00 Arbill Inc. (D)
006 00 Armin Corporation(M)
006 00 Eastco Industrial Safety Corp. (D)
006 00 Edmont Div. Becton, Dickinson & Co.(M)
006 00 General Scientific Safety Equipment Company CD)
006 00 Goodyear Rubber Products Corp.(S)
006 00 Granet(M)
006 00 Holland Safety Supply Co. (D)
006 00 Industrial Products Co., Inc.(D)
006 00 Industrial Safety and Security Co. (D)
006 00 Interex Corp. (D)
006 00 Latex Glove Co., Inc(M)
006 00 Magid Glove and Safety Mfg. Co.(M)
006 00 Masterman's(D)
006 00 Protech Safety Equipment Inc. (D)
006 00 Protexall Company(M)
006 00 Rockford Medical & Safety Co. (D)
006 00 Safeco Inc. (D)
006 00 Standard Glove & Safety Equip. Corp. CD)
006 00 Stauffer Manufacturing Company(M)
006 00 H. Texier Glove Company Inc. CD)
006 00 United States Plastic Corp. (D)

Product: Polyethylene, High Density, Film

041 01 Miller Products Co., Inc.(D)

Product: Polyethylene, Medium Density, Film

042 03 Allied Glove & Safety Products Corp.(M)


042 03 Eastco Industrial Safety Corp. (D)
042 03 General Scientific Safety Equipment Company(D)
042 03 Keystone Protection Corp. (D)
042 03 Latex Glove Co., Inc(M)
042 03 Rockford Medical & Safety Co. (D)
042 06 Magid Glove and Safety Mfg. Co.(M)
042 07 General Scientific Safety Equipment Company(D)
042 07 Interex Corp. (D)
042 07 Latex Glove Co., Inc(M)
042 07 Magid Glove and Safety Mfg. Co.(M)

Product: Polyethylene, Low Density, Film

048 03 Masterman's(D)

C-22
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Polyethylene, Density Unknown, Film

056 03 American Scientific Products(D)


056 03 Armin Corporation(M)
056 03 Charkate(M)
056 03 Edmont Div. Becton, Dickinson & Co.(M)
056 03 Goodyear Rubber Products Corp.(S)
056 03 Granet(M)
056 03 Holland Safety Supply Co. (D)
056 03 Industrial Products Co., Inc.(D)
056 03 Industrial Safety and Security Co. (D)
056 03 Interex Corp. (D)
056 03 Masterman's(D)
056 03 Protech Safety Equipment Inc. (D)
056 03 Protexall Company(M)
056 03 Safeco Inc. (D)
056 03 Standard Glove & Safety Equip. Corp.(D)
056 03 Stauffer Manufacturing Company(M)
056 03 H. Texier Glove Company Inc. (D)

Product: Polyethylene/Tyvek

076 01 Allied Glove & Safety Products Corp.(M)


076 01 Arbill Inc. (D)
076 01 Daffin Disposables, Inc.(M)
076 01 Durafab Disposables, Inc.(M)
076 01 Eastco Industrial Safety Corp. (D)
076 01 Edmont Div. Becton, Dickinson & Co.(M)
076 01 Goodyear Rubber Products Corp.(S)
076 01 Holland Safety Supply Co. (D)
076 01 Industrial Products Co., Inc.(D)
076 01 Industrial Safety and Security Co. (D)
076 01 Interex Corp. (D)
076 01 Kappler Disposables, Inc.(M)
076 01 Latex Glove Co., Inc(M)
076 01 Magid Glove and Safety Mfg. Co.(M)
076 01 Mar-Mac Manufacturing Co., Inc. (M)
076 01 Masterman's(D)
076 01 Mine Safety Appliances Co.(M)
076 01 Pro tech Safety Equipment Inc. (D)
076 01 Rockford Medical & Safety Co. (D)
076 01 Safeco Inc. (D)
076 01 Standard Glove & Safety Equip. Corp.(D)
076 01 Stauffer Manufacturing Company(M)
076 01 H. Texier Glove Company Inc. (D)
076 02 Arbill Inc. (D)
076 02 Daffin Disposables, Inc.(M)
076 02 Disposables Inc.(M)
076 02 Durafab Disposables, Inc.(M)

C-23
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Polyethylene/Tyvek (cont.)


076 02 IPESCo., Inc.(M)
076 02 Industrial Products Co., Inc.(D)
076 02 Industrial Safety and Security Co. (D)
076 02 Kappler Disposables, Inc.(M)
076 02 Latex Glove Co., Inc(M)
076 02 Magid Glove and Safety Mfg. Co.(M)
076 02 Mar-Mac Manufacturing Co., Inc.(M)
076 02 Melco, Inc.(M)
076 02 Mine Safety Appliances Co.(M)
076 02 Protech Safety Equipment Inc.(D)
076 02 Rockford Medical & Safety Co. (D)
076 03 Charkate(M)
076 03 Daffin Disposables, Inc.(M)
076 03 Durafab Disposables, Inc.(M)
076 03 Mar-Mac Manufacturing Co., Inc.(M)
076 03 Melco, Inc.(M)
076 03 Mine Safety Appliances Co.(M)
076 03 Protech Safety Equipment Inc.(D)
076 03 Rockford Medical & Safety Co. (D)
076 04 Allied Glove & Safety Products Corp.(M)
076 04 Arbill Inc.(D)
076 04 Durafab Disposables, Inc.(M)
076 04 Eastco Industrial Safety Corp. (D)
076 04 Edmont Div. Becton, Dickinson & Co.(M)
076 04 Goodyear Rubber Products Corp.(S)
076 04 Holland Safety Supply Co. (D)
076 04 Industrial Products Co., Inc.(D)
076 04 Industrial Safety and Security Co. (D)
076 04 Interex Corp. (D)
076 04 Kappler Disposables, Inc.(M)
076 04 Latex Glove Co., Inc(M)
076 04 Magid Glove and Safety Mfg. Co.(M)
076 04 Mar-Hac Manufacturing Co., Inc.(M)
076 04 Masterman's(D)
076 04 Mine Safety Appliances Co.(M)
076 04 Protech Safety Equipment Inc.(D)
076 04 Rockford Medical & Safety Co. (D)
076 04 Safeco Inc. (D)
076 04 Standard Glove & Safety Equip. Corp.(D)
076 04 Stauffer Manufacturing Company(M)
076 04 H. Texier Glove Company Inc. (D)
076 OS Charkate(M)
076 05 Daffin Disposables, Inc.(M)
076 OS Disposables Inc.(M)
076 05 Durafab Disposables, Inc.(M)
076 05 Hub Safety Equipment, Inc.(D)
076 05 Industrial Products Co., Inc.(D)
076 05 Industrial Safety and Security Co. (D)
076 05 Kappler Disposables, Inc.(M)
076 OS Mar-Mac Manufacturing Co., Inc.(M)

C-24
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name
-----------------------------------~~-------------------------------
Product: Polyethylene/Tyvek (cant.)
076 05 Rockford Medical & Safety Co. CD)
076 06 Charkate{M)
076 06 Durafab Disposables, Inc.{M)
076 06 Industrial Products Co., Inc.(D)
076 06 Industrial Safety and Security Co. CD)
076 06 Kappler Disposables, Inc.(M)
076 06 Mar-Mac Manufacturing Co., Inc.eM)
076 06 Melco, Inc.(M)
076 06 Pro tech Safety Equipment Inc.{D)
076 07 Daffin Disposables, Inc.(M)
076 07 Durafab Disposables, Inc.(M)
076 07 Industrial Products Co., Inc.(D)
076 07 Industrial Safety and Security Co. (D)
076 07 Kappler Disposables, Inc.(M)
076 07 Mar-Mac Manufacturing Co., Inc.(M)
076 07 Protech Safety Equipment Inc. (D)

Product: Polyethylene/Fabric

091 01 General Scientific Safety Equipment Company(D)


091 02 General Scientific Safety Equipment Company(D)
091 03 Fisher Scientific Company(D)
091 04 General Scientific Safety Equipment Company(D)
091 06 General Scientific Safety Equipment Company(D)

Product: Polyethylene/Polyester

137 03 Protexa1l Company(M)

POLYCARBONATE(026)

Product: Polycarbonate, Lens and Face Shield

098 09 Arbill Inc. (D)


098 09 Eastco Industrial Safety Corp. (D)
098 09 Fis~er Scientific Company(D)
098 09 Inco Safety Products Co.(M)
098 09 Industrial Safety and Security Co. (D)
098 09 Interex Corp. (D)
098 09 Magid Glove and Safety Mfg. Co.(M)
098 09 Rockford Medical & Safety Co. (D)
098 09 The Sager Corporation(M)

POLYESTER(027)

Product: Polyester, Face Shield and Lens

096 09 SGL Homalite Industries(S)

C-2S
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

POLYURETHANE(028)

Product: Polyurethane Rubber. Unsupported

027 00 Colonial Glove & Garment Inc.(M)

Product: Polyurethane Rubber/Nylon

050 01 Boss Manufacturing Company(M)


050 01 Eastco Industrial Safety Corp. (D)
050 01 Jordan David Safety Products(M)
050 01 Miller Products Co .• Inc.(D)
050 01 Mine Safety Appliances Co.(M)
050 01 National Safety Wear. Inc.(M)
050 01 Rainfair. Inc.(M)
050 01 Rockford Medical & Safety Co. (D)
050 02 Boss Manufacturing Company(M)
050 02 Miller Products Co .• Inc.(D)
050 04 Eastco Industrial Safety Corp. (D)
050 04 Jordan David Safety Products(M)
050 04 Miller Products Co .• Inc.(D)
050 04 Mine Safety Appliances Co.(M)
050 04 National Safety Wear. Inc.(M)
050 04 Rainfair. Inc.(M)
050 04 Rockford Medical & Safety Co. (D)
050 06 Eastco Industrial Safety Corp. (D)
050 06 Rainfair. Inc.(M)

Product: Polyurethane Rubber. Boots

082 08 Eastco Industrial Safety Corp. (D)


082 08 Jordan David Safety Products(M)
082 08 Rainfair. Inc.(M)

PV ALCOHOL(029)

Product: Polyvinyl Alcohol Glove. Supported

004 00 Arbill Inc. (D)


004 00 Eastco Industrial Safety Corp. (D)
004 00 Edmont Div. Becton, Dickinson & Co.(M)
004 00 Goodyear Rubber Products Corp.(S)
004 00 Holland Safety Supply Co. (D)
004 00 Industrial Products Co., Inc.(D)
004 00 Industrial Safety and Security Co. (D)
004 00 Interex Corp. (D)
004 00 LRC Safety Products Co. (D)
004 00 Magid Glove and Safety Mfg. Co.(M)
004 00 Major Safety Service, Inc.(D)
004 00 Masterman's(D)
004 00 Protech Safety Equipment Inc. (D)

C-26
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Polyvinyl Alcohol Glove, Supported (cont.)


004 00 Safeco Inc. (D)
004 00 Standard Glove & Safety Equip. Corp.(D)
004 00 Stauffer Manufacturing Company(M)
004 00 H. Texier Glove Company Inc. (D)

Product: Polyvinyl Alcohol Glove, Unsupported


102 00 General Scientific Safety Equipment Company(D)

PVC(030)

Product: Polyvinyl Chloride Glove, Unsupported


003 00 Alliance Supply, Inc.(M)
003 00 Allied Glove & Safety Products Corp.(M)
003 00 Arbill Inc.(D)
003 00 Armin Corporation(M)
003 00 Best Manufacturing Company(M)
003 00 Boss Manufacturing Company(M)
003 00 Clean Room Products, Inc.(M)
003 00 Dayton Flexible Products(M)
003 00 Defense Apparel(M)
003 00 Eastco Industrial Safety Corp. (D)
003 00 Edmont Div. Becton, Dickinson & Co.(M)
003 00 Goodyear Rubber Products Corp.(S)
003 00 Holland Safety Supply Co. (D)
003 00 Hub Safety Equipment, Inc.(D)
003 00 IPESCo., Inc.(M)
003 00 Industrial Products Co., Inc.(D)
003 00 Industrial Safety and Security Co. (D)
003 00 Interex Corp. (D)
003 00 Intermarket Latex, Inc.(M)
003 00 Keystone Protection Corp. (D)
003 00 Latex Glove Co., Inc(M)
003 00 Leonard Safety Epuipment, Inc.(D)
003 00 Magid Glove and Safety Mfg. Co.(M)
003 00 Masterman's(D)
003 00 Miller Products Co., Inc. (D)
003 00 Mine Safety Appliances Co.(M)
003 00 Monte Glove Company(M)
003 00 North Hand Protection(M)
003 00 OKI Supply Co.(M)
003 00 Oak Technical, Inc.(M)
003 00 Pioneer Industrial Products Co.(M)
003 00 Pro tech Safety Equipment Inc. (D)
003 00 Protexall Company(M)
003 00 Rockford Medical & Safety Co. (D)
003 00 Safeco Inc. (D)
003 00 Standard Glove & Safety Equip. Corp.(D)
003 00 Stauffer Manufacturing Company(M)
003 00 H. Texier Glove Company Inc. (D)

C-27
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Polyvinyl Chloride, Sheet

049 04 Aramsco(M)
049 04 Coyne Safety Equipment, Inc.(D)
049 04 Falcon Industries, Inc.(M)
049 04 Latex Glove Co., Inc(M)
049 04 Leonard Safety Epuipment, Inc.(D)
049 04 Miller Products Co., Inc.(D)
049 04 Protech Safety Equipment Inc. (D)
049 04 Safeco Inc. (D)
049 04 Safety Engineering & Supply Co. (D)
049 04 Sawyer-Tower(M)
049 04 Standard Safety Equipment Co.(M)
049 05 Andover Industries, Inc.(M)
049 05 Direct Safety Company(D)
049 05 Mine Safety Appliances Co.(M)
049 06 Aramsco(M)
049 06 Coyne Safety Equipment, Inc.(D)
049 06 Direct Safety Company(D)
049 06 Falcon Industries, Inc.(M)
049 06 General Scientific Safety Equipment Company(D)
049 06 Leonard Safety Epuipment, Inc.(D)
049 06 Magid Glove and Safety Mfg. Co.(M)
049 06 Miller Products Co., Inc.(D)
049 06 Mine Safety Appliances Co.(M)
049 06 Plastex Protective Products, Inc.(M)
049 06 Protexa11 Company(M)
049 06 Steele & Associates, Inc.(M)
049 07 Arbill Inc. (D)
049 07 Armin Corporation(M)
049 07 Direct Safety Company(D)
049 07 Interex Corp. (D)
049 07 La Crosse Footwear, Inc.(M)
049 07 Protexal1 Company(M)
049 07 Ranger (M).
049 07 Standard Safety Equipment Co. (M)
049 07 Steele & Associates, Inc.(M) .

Product: Polyvinyl Chloride/Fabric

053 01 Allied Glove & Safety Products Corp.(M)


053 01 Aramsco(M)
053 01 Boss Manufacturing Company(M)
053 01 Durafab Disposables, Inc.(M)

C-28
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Polyvinyl Chloride/Fabric (cont.)


053 01 Jomac Products Inc.(M)
053 01 Jones Safety Supply, Inc.(D)
053 01 Jordan David Safety Products(M)
053 01 Keystone Protection Corp. (D)
053 01 Major Safety Service, Inc.(D)
053 01 Masterman's(D)
053 01 Mine Safety Appliances Co.(M)
053 01 OKI Supply Co.(M)
053 01 Plastex Protective Products, Inc.eM)
053 01 Protech Safety Equipment Inc. (D)
053 01 Record Industrial Co.(M)
053 01 Robar Protective Products(D)
053 01 Safeco Inc.(D)
053 01 Safety Engineering & Supply Co. (D)
053 01 Sawyer-Tower(M)
053 01 Standard Safety Equipment Co.(M)
053 01 Tingley Rubber Corp.(M)
053 01 Wheeler Protective Apparel, Inc.(M)
053 02 Boss Manufacturing Company(M)
053 02 Durafab Disposables, Inc.(M)
053 02 Jomac Products Inc.(M)
053 02 Jones Safety Supply, Inc.(D)
053 02 Keystone Protection Corp. (D)
053 02 Major Safety Service, Inc.CD)
053 02 Standard Safety Equipment Co.CM)
053 03 Allied Glove & Safety Products Corp.CM)
053 03 Charkate(M)
053 03 Durafab Disposables, Inc.(M)
053 03 Eastco Industrial Safety Corp. (D)
05~ 03 Edmont Div. Becton, Dickinson & Co.(M)
053 03 Fisher Scientific Company(D)
053 03 Goodyear Rubber Products Corp.(S)
053 03 Holland Safety Supply Co. CD)
053 03 Industrial Products Co., Inc.CD)
053 03 Industrial Safety and Security Co. (D)
053 03 Interex Corp. CD)
053 03 Jomac Products Inc.(M)
053 03 Jones Safety Supply, Inc.(b)
053 03 Keystone Protection Corp. (D)
053 03 Major Safety Service, Inc.CD)
053 03 Masterman's(D)
053 03 Protech Safety Equipment Inc. CD)
053 03 Safeco Inc.(D)
053 03 Standard Glove & Safety Equip. Corp. CD)
053 03 Standard Safety Equipment Co.(M)
053 03 Stauffer Manufacturing Company(M)
053 03 H. Texier Glove Company Inc. (D)
053 03 Wheeler Protective Apparel, Inc.(M)
053 04 Jomac Products Inc.CM)
053 04 Jones Safety Supply, Inc.(D)

C-29
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Polyvinyl Chloride/Fabric (cont.)


053 04 Jordan David Safety Products(M)
053 04 Keystone Protection Corp. (D)
053 04 Major Safety Service, Inc.(D)
053 04 Masterman's(D)
053 04 Mine Safety Appliances Co.(M)
053 04 OKI Supply Co.(M)
053 04 Plastex Protective Products, Inc.(M)
053 04 Protech Safety Equipment Inc.(D)
053 04 Record Industrial Co.(M)
053 04 Robar Protective Products(D)
053 04 Safeco Inc. (D)
053 04 Safety Engineering & Supply Co. (D)
053 04 Sawyer-Tower(M)
053 04 Tingley Rubber Corp.(M)
053 04 Wheeler Protective Apparel, Inc.(M)
053 05 Major Safety Service, Inc.(D)
053 05 Safety Engineering & Supply Co. (D)
053 05 Standard Safety Equipment Co.(M)
053 05 Wheeler Protective Apparel, Inc.(M)
053 06 Boss Manufacturing Company(M)
053 06 Jomac Products Inc.(M)
053 06 Jones Safety Supply, Inc.(D)
053 06 Major Safety Service, Inc.(D)
053 06 P1astex Protective Products, Inc.(M)
053 06 Pu1mosan Safety Equipment Corp. (D)
053 06 Standard Safety Equipment Co.(M)
053 06 United States Safety Service Co. (D)
053 06 Wheeler Protective Apparel, Inc.(M)

Product: Polyvinyl Chloride, Film

054 01 Defense Apparel(M)


054 01 Durafab Disposables, Inc.(M)
054 01 OKI Supply Co.(M)
054 01 P1astimayd Corp.(M)
054 01 Robar Pr~tective Products(D)
054 02 Defense Appare1(M)
054 02 Durafab Disposables, Inc.(M)
054 03 Durafab Disposables, Inc.(M)
054 03 Fairway Products(M)
054 03 LRC Safety Products Co. (D)
054 03 Melco, Inc.(M)
054 03 OKI Supply Co.(M)
054 03 P1astimayd Corp.(M)
054 03 Pu1mosan Safety Equipment Corp. (D)
054 03 Ronco Textile Products, Inc.(M)
054 04 Defense Appare1(M)
054 04 OKI Supply Co.(M)
054 04 Plastimayd Corp.(M)
054 04 Robar Protective Products(D)

C-30
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Polyvinyl Chloride, Film (cont.)


054 06 General Scientific Safety Equipment Company(D)
054 06 Melco, Inc.(M)
054 06 Pulmosan Safety Equipment Corp. (D)
054 07 Allied Glove & Safety Products Corp.(M)
054 07 Defense Apparel(M)
054 07 Eastco Industrial Safety Corp. (D)
054 07 General Scientific Safety Equipment Company(D)
054 07 Interex Corp. (D)
054 07 Iron Age Protective Company(M)
054 07 Leonard Safety Epuipment, Inc.(D)
054 07 Me1co, Inc.(M)
054 07 Plastex Protective Products, Inc.(M)
054 07 Pulmosan Safety Equipment Corp. (D)
054 07 United States Plastic Corp. (D)

Product: Polyvinyl Ch1oride/Ny1on

077 01 Allied Glove & Safety Products Corp.(M)


077 01 Aramsco(M)
077 01 Boss Manufacturing Company(M)
077 01 Direct Safety Company(D)
077 01 Eastco Industrial Safety Corp. (D)
077 01 Edmont Div. Becton, Dickinson & Co.(M)
077 01 Goodyear Rubber Products Corp.(S)
077 01 Holland Safety Supply Co. (D)
077 01 Industrial Products Co., Inc.(D)
077 01 Industrial Safety and Security Co. (D)
077 01 Interex Corp. (D)
077 01 Jomac Products Inc.(M)
077 01 Jones Safety Supply, Inc.(D)
077 01 Jordan David Safety Products(M)
077 01 Masterman's(D)
077 01 Miller Products Co., Inc.(D)
077 01 Mine Safety Appliances Co.(M)
077 01 National Safety Wear, Inc.(M)
077 01 OKI Supply Co.(M)
077 01 Plastex Protective Products, Inc. (M)
077 01 Protech Safety Equipment Inc. (D)
077 01 Rainfair, Inc.(M)
077 01 Robar Protective Products(D)
077 01 Rockford Medical & Safety Co. (D)
077 01 Safeco Inc. (D)
077 01 Safety Engineering & Supply Co. (D)
077 01 Sawyer-Tower(M)
077 01 Standard Glove & Safety Equip. Corp.(D)
077 01 Stauffer Manufacturing Company(M)
077 01 H. Texier Glove Company Inc. (D)
077 01 Tingley Rubber Corp.(M)
077 02 Boss Manufacturing Company(M)
077 02 Jomac Products Inc.(M)

C-31
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Polyvinyl Chloride/Nylon (cont.)


077 02 Jones Safety Supply, Inc.(D)
077 02 Miller Products Co., Inc.(D)
077 02 Plastex Protective Products, Inc.(M)
077 03 Boss Manufacturing Company(M)
077 03 Frommelt Industries, Inc.(M)
077 03 Jomac Products Inc.(M)
077 03 Jones Safety Supply, Inc.(D)
077 03 OKI Supply Co.(M)
077 03 Plastex Protective Products, Inc.(M)
077 03 Protech Safety Equipment Inc. (D)
077 04 Allied Glove & Safety Products Corp.(M)
077 04 Direct Safety Company(D)
077 04 Eastco Industrial Safety Corp. (D)
077 04 Edmont Div. Becton, Dickinson & Co.(M)
077 04 Goodyear Rubber Products Corp.(S)
077 04 Holland Safety Supply Co. (D)
077 04 Industrial Products Co., Inc. (D) .
077 04 Industrial Safety and Security Co. (D)
077 04 Interex Corp. (D)
077 04 Jomac Products Inc.(M)
077 04 Jones Safety Supply, Inc.(D)
077 04 Jordan David Safety Products(M)
077 04 Kasterman's(D)
077 04 Miller Products Co., Inc.(D)
077 04 Mine Safety Appliances Co.(M)
077 04 National Safety Wear, Inc.(M)
077 04 OKI Supply Co.(M)
077 04 Plastex Protective Products, Inc.(M)
077 04 Protech Safety Equipment Inc. (D)
077 04 Rainfair, Inc.(M)
077 04 Robar Protective Products(D)
077 04 Rockford Medical & Safety Co. (D)
077 04 Safeco Inc.(D)
077 04 Safety Engineering & Supply Co. (D)
077 04 Sawyer-Tower(M)
077 04 Standard Glove & Safety Equip. Corp. (D)
077 04 Stauffer Manufacturing Company(M)
077 04 H. Texier Glove Company Inc.(D)
077 04 Tingley Rubber Corp.(M)
077 05 Mine Safety Appliances Co.(M)
077 06 Allied Glove & Safety Products Corp.(M)·
077 06 Boss Manufacturing Company(M)
077 06 Colonial Glove & Garment Inc.(M)
077 06 Direct Safety Company(D)
077 06 Eastco Industrial Safety Corp. (D)
077 06 Edmont Div. Becton, Dickinson & Co.(M)
077 06 Falcon Industries, Inc.(M)
077 06 General Scientific Safety Equipment Company(D)
077 06 Goodyear Rubber Products Corp.(S)
077 06 Holland Safety Supply Co. (D)

C-32
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Polyvinyl Chloride/Nylon (cont.)


077 06 Industrial Products Co., Inc.(D)
077 06 Industrial Safety and Security Co. (D)
077 06 Interex Corp. (D)
077 06 Jomac Products Inc.(M)
077 06 Jones Safety Supply, Inc.(D)
077 06 Masterman's(D)
077 06 Plastex Protective Products, Inc.(M)
077 06 Pro tech Safety Equipment Inc.(D)
077 06 Pulmosan Safety Equipment Corp. (D)
077 06 Rainfair, Inc.(M)
077 06 Robar Protective Products(D)
077 06 Safeco Inc. (D)
077 06 Standard Glove & Safety Equip. Corp.(D)
077 06 Stauffer Manufacturing Company(M)
077 06 H. Texier Glove Company Inc. (D)

Product: Polyvinyl Chloride, Boots

083 08 Allied Glove & Safety Products Corp.(M)


083 08 Boss Manufacturing Company(M)
083 08 Defense Apparel(M)
083 08 Direct Safety Company(D)
083 08 Eastco Industrial Safety Corp. (D)
083 08 Interex Corp. (D)
083 08 Iron Age Protective Company(M)
083 08 Jordan David Safety Products(M)
083 08 La Crosse Footwear, Inc.(M)
083 08 Latex Glove Co., Inc(M)
083 08 Lehigh Safety Shoe Co.(M)
083 08 Masterman's(D)
083 08 Miller Products Co., Inc.(p)
083 08 Protexa11 Company(M)
083 08 Rainfair, Inc.(M)
083 08 Standard Safety Equipment Co.(M)
083 08 Steele & Associates, Inc.(M)
083 08 Tingley Rubber Corp. (M)
083 08 The Tracies Co.(M)
083 08 Tre11eborg, Inc.(M)
083 08 Wheeler Protective Apparel, Inc.(M)

Product: Polyvinyl Ch1oride/Rayon

088 01. Direct Safety Company(D)


088 01 Jomac Products Inc.(M)
088 01 Jones Safety Supply, Inc.(D)
088 01 Protech Safety Equipment Inc. (D)
088 03 Jomac Products Inc.(M)
088 03 Jones Safety Supply, Inc.(D)
088 04 Direct Safety Company(D)
088 . 04 Jomac Products Inc.(M)

C-33
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Polyvinyl ChloridefRayon (cont.)


088 04 Jones Safety Supply, Inc.(D)
088 06 Direct Safety Company(D)
088 06 Falcon Industries, Inc.(M)
088 06 Jomac Products Inc.(M)
088 06 Jones Safety Supply, Inc.(D)

Product: Polyvinyl Chloride/Fabric/Polyvinyl Chloride

131 01 Eastco Industrial Safety Corp. CD)


131 01 Rainfair, Inc.(M)
131 01 Sawyer-Tower(M)
131 04 Eastco Industrial Safety Corp. CD)
131 04 Rainfair, Inc.(M)
131 04 Sawyer-Tower(M)
131 05 Fyrepel Products Inc.(M)
131 06 Eastco Industrial Safety Corp. CD)
131 06 Rainfair, Inc.(M)

Product: Polyvinyl Chloride/Nylon/Polyvinyl Chloride

133 01 Edmont Div. Becton, Dickinson & Co.(M)


133 01 Goodyear Rubber Products Corp.(S)
133 01 Holland Safety Supply Co. (D)
133 01 Industrial Products Co., Inc.(D)
133 01 Industrial Safety and Security Co. (D)
133 01 Interex Corp. (D)
133 01 Masterman's(D)
133 01 Plastex Protective Products, Inc.(M)
133 01 Protech Safety Equipment Inc. CD)
133 01 Safeco Inc. (D)
133 01 Standard Glove & Safety Equip. Corp.(D)
133 01 Stauffer Manufacturing Company(M)
133 01 Superior Surgical Mfg. Co., Inc.(M)
133 01 H. Texier Glove Company Inc. (D)
133 02 Superior Surgical Mfg. Co., Inc.(M)
133 03 Edmont Div. Becton, Dickinson & Co.(M)
133 03 Goodyear Rubber Products Corp.(S)
133 03 Holland Safety Supply Co. (D)
133 03 Industrial Products Co., Inc.(D)
133 03 Industrial Safety and Security Co. (D)
133 03 Interex Corp. (D)
133 03 Masterman's(D)
133 03 Protech Safety Equipment Inc. (D)
133 03 Standard Glove & Safety Equip. Corp.(D)
133 03 Stauffer Manufacturing Company(M)
133 03 H. Texier Glove Company Inc. (D)
133 04 Edmont Div. Becton, Dickinson & Co.(M)
133 04 Goodyear Rubber Products Corp.(S)
133 04 Holland Safety Supply Co. (D)
133 04 Industrial Products Co., Inc.(D)

C-34
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: Polyvinyl Chloride/Nylon/Polyvinyl Chloride (cont.)


133 04 Industrial Safety and Security Co. (D)
133 04 Interex Corp. (D)
133 04 Masterman's(D)
133 04 Plastex Protective Products, Inc.(M)
133 04 Protech Safety Equipment Inc. (D)
133 04 Safeco Inc. (D)
133 04 Standard Glove & Safety Equip. Corp.(D)
133 04 Stauffer Manufacturing Company(M)
133 04 H. Texier Glove Company Inc. (D)
133 05 Goodall Rubber Company(M)
133 05 National Draeger, Inc.(M)
133 05 Trelleborg, Inc.(M)
133 06 Edmont Div. Becton, Dickinson & Co.(M)
133 06 Goodyear Rubber Products Corp.(S)
133 06 Holland Safety Supply Co. (D)
133 06 Industrial Products Co., Inc.(D)
133 06 Industrial Safety and Security Co. (D)
133 06 Interex Corp. (D)
133 06 Masterman's(D)
133 06 Plastex Protective Products, Inc.(M)
133 06 Pro tech Safety Equipment Inc. (D)
133 06 Safeco Inc.(D)
133 06 Standard Glove & Safety Equip. Corp.(D)
133 06 Stauffer Manufacturing Company(M)
133 06 H. Texier Glove Company Inc. (D)

Product: Polyvinyl Chloride/Polyester

144 03 Steel Grip Safety Apparel Co., Inc.(M)

SARANEX(032)

Product: PE/Polyviny1idenechloride/PE/Tyvek

061 01 Magid Glove and Safety Mfg. Co.(M)


061 01 Mar-Mac Manufacturing Co., Inc.(M)
061 01 Pro tech Safety Equipment Inc. (D)
061 ·01 Rockford Medical & Safety Co. (D)
061 02 Charkate(M)
061 02 Daffin Disposables, Inc.(M)
061 02 Durafab Disposables, Inc.(M)
061 02 Industrial Products Co., Inc.(D)
061 02 Industrial Safety and Security Co.(D)
061 02 Kappler Disposables, Inc.(M)
061 02 Magid Glove and Safety Mfg. Co.(M)
061 02 Mar-Mac Manufacturing Co., Inc.(M)
061 02 Melco, Inc. (M)
061 02 Protech Safety Equipment Inc. (D)
061 03 Charkate(M)
061 03 Mar-Mac Manufacturing Co., Inc.(M)

C-3s
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

Product: PE/Polyvinylidenech1oride/PE/Tyvek (cont.)


061 03 Protech Safety Equipment Inc. (D)
061 04 Magid Glove and Safety Mfg. Co.(M)
061 04 Mar-Mac Manufacturing Co., Inc.(M)
061 04 Protech Safety Equipment Inc. (D)
061 04 Rockford Medical & Safety Co. (D)
061 05 Charkate(M)
061 05 Daffin Disposables, Inc.(M)
061 05 Durafab Disposables, Inc.(M)
061 05 Hub Safety Equipment, Inc.(D)
061 05 Leonard Safety Epuipment, Inc.(D)
061 05 Mar-Mac Manufacturing Co., Inc.(M)
061 05 Mar-Mac Manufacturing Co., Inc.(M)
061 05 Mine Safety Appliances Co.(M)
061 05 Rockford Medical & Safety Co. (D)
061 06 Industrial Products Co., Inc.(D)
061 06 Industrial Safety and Security Co. (D)
061 06 Kappler Disposables, Inc.(M)
061 06 Pro tech Safety Equipment Inc. (D)
061 07 Daffin Disposables, Inc.(M)
061 07 Industrial Products Co., Inc.(D)
061 07 Industrial Safety and Security Co. (D)
061 07 Kappler Disposables, Inc.(M)
061 07 Mar-Mac Manufacturing Co., Inc.(M)

SBR(033)

Product: Styrenebutadiene Rubber/Fabric

063 01 Eastco Industrial Safety Corp. (D)


06301 Rainfair, Inc.(M)
063 01 Safety Engineering & Supply Co. (D)
063 01 Tingley Rubber Corp.(M)
063 03 Protexal1 Company(M)
063 04 Eastco Industrial Safety Corp. (D)
063 04 Rainfair, Inc.(M)
063 04 Safety Engineering & Supply Co. (D)
063 04 Tingley Rubber Corp.(M)
063 06 Eastco Industrial Safety Corp. (D)
063 06 Rainfair, Inc.(M)

SBR/NEOPRENE(047)

Product: Styrenebutadiene/Cotton/Chloroprene

149 03 Steel Grip Safety Apparel Co., Inc.(M)

SILVER 'SHIELD(042)
Product: Silver Shield (North Product), Glove
122 00 Arbil1 Inc.(D)
122 00 North Hand Protection(M)

C-36
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

TEFLON(014)

Product: FEP Glove

036 00 Clean Room Products, Inc.(M)

Product: TFE/Nomex/TFE

069 05 Chemical Fabrics Corporation(M)

Product: TFE/Fiberg1ass/TFE

146 05 Chemical Fabrics Corporation(M)

VITON(034)

Product: F1uoroe1astomer Glove, Solvent Dipped, Unsupported

009 00 Direct Safety Company(D)


009 00 Hub Safety Equipment, Inc.(D)
009 00 Latex Glove Co., Inc(M)
009 00 Mine Safety Appliances Co.(M)
009 00 North Hand Protection(M)
009 00 Protech Safety Equipment Inc.(D)
009 00 Safeco Inc.(D)

Product: Fluoroelastomer, Sheet

032 01 Mine Safety Appliances Co.(M)


032 04 Mine Safety Appliances Co.(M)
032 05 Andover Industries; Inc.(M)

Product: Fluoroelastomer/Fabric/Fluoroelastomer

129 05 Fyrepel Products Inc.(M)

Product: Fluoroelastomer/Polyester/F1uoroe1astomer

143 03 Steel Grip Safety Apparel Co., Inc.(M)


143 04 Superior Surgical Mfg. Co., Inc.(M)

VITON/BUTYL(03S)

Product: Fluoroelastomer/Butyl/Nylon/Butyl

100 02 Trelleborg, Inc.(M)


100 05 Goodall Rubber Company(M)
100 05 Trelleborg, Inc.(M)

C-37
PRODUCT VENDORS BY RESISTANT MATERIAL

Resistant
Material Code Type Vendor Name

VITON/CHLOROBUTYL(036)

Product: FluoroelastomerjNomex/Chlorobutyl

152 OS Andover Industries, Inc.(M)

VI TON/NEOPRENE (011)

Product: FluoroelastomerjNylon/Chloroprene

III 05 Mine Safety Appliances Co.(M)


III 05 National Draeger, Inc.(M)

C-38
APPENDIX D

VENDOR DIRECTORY

D-1
VENDOR DIRECTORY

Ackwell
Address not available.

Acme Mills Company


5151 Loraine
Detroit, MI 48208
313/894-7110

Alliance Supply, Inc.


3 Bridge Street
Newton, MA 02158
617/244-2900

Allied Glove & Safety Products Corp.


325 E. Chicago Street
Milwaukee, WI 53202
414/272-0302

American Scientific Products


Division of American Hospital Supply
1430 Waukegan Road
McGaw Park, IL 60085
800/842-1208

Andover Industries, Inc.


15 Union Street
Lawrence, MA 01840
617/794-1793

Angelica Uniform Group


700 Rosedale Avenue
St. Louis, MO 63112
800/325-8032

D-2
VENDOR DIRECTORY

Ansell Industrial Products


Industrial Road
P.O. Box 1252
Dothan, AL 36302
800/633-0909

Aramsco

Thorofare, NJ 08086
800/257-8146

Arbill Inc.
2207 W. Glenwood Avenue
Philadelphia, PA 19132
215/228-4011

Armin Corporation
One Penn Plaza
New York, NY 10119
212/736-2201

Arrowhead Products
4411 Katella Avenue
Los Alamitos, CA 90720
714/828-7770

Bard Parker
Address not available.

Barry Manufacturing Co. Ltd.


920 Lakeshore Road East
Mississauga, ON CAN
416/274-3691

n-3
VENDOR DIRECTORY

Bel-Art Products
Industrial Road
Pequannock, NJ 07440
201/694-0500

Best Manufacturing Company


Edison Street
Menlo, GA 30731
800/241-0323

Body-Guard
Division of Lion Uniform Inc.
P.O. Box 14343
Dayton, OH 45414
714/540-8010

Boss Manufacturing Company


221 W. First Street
Kewanee, IL 61443
309/852-2131

Broner Glove Co.


359 Robbins Drive
Troy, MI 48084
800/521-1318

E.D. Bullard Company


2680 Bridgeway
Sausalito, CA 94965
415/332-0410

California Safety
Address not available.

D-4
VENDOR DIRECTORY

Cesco Safety Products


1535 Walnut Steet
Kansas City, MO 64108
816-842-8500

Charkate
130 West 10th Street
Huntington Station, NY 11746
516/427-1802

Chemical Fabrics Corporation


Daniel Webster Highway
P.O. Box 1137
Merrimack, NH 03054
603/424-9000

Clean Room Products, Inc.


1800 Ocean Avenue
Ronkonkoma, NY 11779
516/588-7000

Cofish International, Inc.


P.O. Box 13
East Haddam, CT 06423
203/873-9500

Colonial Glove & Garment Inc.


1800 Ocean Avenue
Ronkonkoma, NY 11779
516/588-6900

Comasec
Drawer 10
Niblick Road
Enfield, CT 06082
203/741-2207

D-5
VENDOR DIRECTORY

Converse Inc.
55 Fordham Road
Wilmington, MA 01887
617/657-5500

Coyne Safety Equipment, Inc.


725 Route 113
P.O. Box 390
Sellersville, PA 18960
215/723-0926

Daffin Disposables, Inc.


One Daffin Square
Secretary, HD 21664
301/943-8777

Dayton Flexible Products


Division of Baxter Travenol
2210 Arbor Boulevard
Dayton, OH 45439
513/298-7511

Defense Apparel
247 Addison Road
Windsor, CT 06095
800/243-3847

Direct Safety Company


7815 South 46th Street
Phoenix, AZ 85044
800/528-7405

Disposables Inc.
14 Locust Street
Manhasset, NY 11030
516/627-4554
VENDOR DIRECTORY

Dorsey Safety Products Co.


P.O. Box 23465
Chattanooga, TN 37422
615/894-7233

Dow Chemical Company


2020-T Dow Center
Midland, MI 48640
517/636-1000

E.1. du Pont de Nemours & Co., Inc.


Spunbonded Products Division
Centre Road Building
Wilmington, DE 19898
302/999-3095

E.I. du Pont de Nemours & Company


Business and Marketing Service
Elastomers
Wilmington, DE 19898
800/441-7111

Durafab Disposables, Inc.


Box 658
Cleburne, TX 76031
817/645-8851

Eastco Industrial Safety Corp.


130 West 10th Street
Huntington Station, NY 11746
516/427-1802

Edmont Div. Becton, Dickinson & Co.


1300 Walnut Street
Coshocton, OH 43812
614/622-4201

D-7
VENDOR DIRECTORY

Elliott Glove Company / Inc.


5C4 Pecor Street
Oconto. WI 54153
414/834-5622

Encon Manufacturing Co.


13333 Northwest Freeway
P.O. Box 3826
Houston, TX 77253
713/462-4723

Erista
Rex Gummiwarenfabrlc Gmbh
D-6102
Pfungstadt, FRG

Exxon Chemical Company


Polymers Group
A Division of Exxon Corporation
P.O. Box 3272
Houston, TX 77253
713/870-6546

Fairway Products
303 Arch Street
Hillsdale, HI 49242
517/439-9376

Falcon Industries, Inc.


401 Isom Road
San Antonio, TX 78216
512-344-3469

Fisher Scientific Company


711 Forbes Avenue
Pittsburg, PA 15219
412/562-8300

D-8
VENDOR. DIRECTORY

Frommelt Industries, Inc.


Safety Products Division
4343 Chavene11e Drive
P.O. Box 658
Dubuque, IA 52004
800/553-5560

Fyrepel Products Inc.


Box 518
Newark, OH 43055
614/344-0391

General Scientific Safety Equipment Company


1821 John F. Kennedy Boulevard
Philadelphia, PA 19103
215/564-6366

Glover Latex. Inc.


514 S. Rose Street
P.O. Box 167
AnAheim, CA 92805
714/535-8920

Goodall Rubber Company


P.O. Box 8237
Trenton, NJ 08650
609/587-4000

Goodyear Rubber Products Corp.


329 McCarter Highway
-Newark, NJ 07114
201/242-5550

Granet
25 Loring Drive
P.O. Box 588
Framingham, HA 01701
617/875-3521

D-9
VENDOR DIRECTORY

Greene Rubber Co., Inc.


160 Second Street
Cambridge, MA 02142
617/547-7655

Halprin Supply Co.


3804 S. Broadway Pl.
Los Angeles, CA 90037
213/232-3131

Handgards Inc.
901 Hawkins
P.O. Box 27018
El Paso, T.X 79926
915/779-6606

Holcomb Safety Garment Co.


4925 W. Grand Avenue
Chicago, IL 60639
312/648-1778

Holland Safety Supply Co.


P.O. Box 645
208 Market Street
Lexington, NC 27292
800/222-8133

Hub Safety Equipment, Inc.


121 Liberty Street
P.O. Box 454
South Quincy, MA 02269
617-773-2487

Hy-Test Safety Shoes


Div. International Shoe Company
P.O. Box. 14485
St. Louis, MO 63178
314/426-1675

b-10
VENDOR· DIRECTORY

ILC Dover
P.O. Box 266
Frederica, DE 19946
302/335-3911

IPESCo., Inc.
1903 Sharon Forest Drive
Charlotte, NC 28212
704/535-5550

Inco Safety Products Co.


Box 1733
Reading, PA 19603
215/376-6161

Industrial Products Co., Inc.


21 Cabot Blvd.
Langhorne, PA 19047
800/523-3944

Industrial Safety and Security Co.


1390 Newbrecht Road
Lima, OH 45801
800/537-9721

Interex Corp.
3 Strathmore Rd.
Natick, MA 01760
800/225-5910

Intermarket Latex, Inc.


213 Hanna Building
Cleveland, OH 44115
800/824-7419

D-ll
VENDOR.' DIRECTORY

International Playtex, Inc.


Glove Division
.700 Fairfield Ave ."
Stamford, CT 06lO2
203/356-8000

.l
~

Iron Age Pnotective Company


2406 Woodmere Drive
Pittsburgh, PA 15205
412/922-7000

Jomac Products Inc.


863 Easton Road
Warrington, PA 18976
215/343-0800

Jones Safety Supply. Inc.


719 Gainsboro Road, Nti
P.O. Box 111
R.oanoke. VA 24002
703/982-8444

Jordan David Safety Products


P.O. Box 400
Warrington. PA 18976
215/343-6470

KID AB
S-71100
Lindesberg, Sweden

Kappler Disposables, Inc.


P.O. Box 218
Guntersville, AL 35976
800/633-2410

D-12
VENDOR DIRECTORY

Keller Glove Mfg. Co.


Route 611
Plumsteadville, PA 18949
215/343-1135

Keystone Protection Corp.


?20 E. Luzerne Street
Philadelphia, PA 19124
215/426-3600

Kimberly-Clark Corp.
Industrial Garments Fabrics
1400 Holcomb Bridge Road
Roswell, GA 30076
404/587-8000

LRC Safety Products Co.


Rt. 46 West
Little Falls, NJ 07424
201/256-4100

La Crosse Footwear, Inc.


P.O. Box 1328
La Crosse, WI 54602
608/782-3020

Lab Safety Supply Company


Div. Science Related Materials, Inc.
3430 North Palmer Drive
Janesville. WA 53547
608/754-2345

Latex Glove Co., Inc


318 Huehl Road
Northbrook, IL 60062
800/323-8393

D-13
VENDOR DIRECTORY

Lehigh Safety Shoe Co.


Division of Endicott Johnson
1100 E. Main Street
Endicott, NY 13760
607/754-7980

Leonard Safety Epuipment, Inc.


253 Waterman Ave.
P.O. Box 4344
E. Providence, RI 02914
800/556-7170

Lion Uniform, Inc .


2735 Kearns Avenue
Dayton, OH 45414
513/278-6531

Magid Glove and Safety Mfg. Co.


2060 N. Kolmar Ave.
Chicago, IL 60639
312/384-2070

Major Safety Service. Inc.


4500 Patent Rd.
Norfolk, VA 23502
800/446-8274

Mar-Mac Manufacturing Co., Inc.


P.o. Box 278
McBee, SC 29101
803/335-8211

Marathon Rubber
510 Sherman Street
Wausau, WI 54401
715/845 - 625.5

D-14
V~NDOR DIRECTORY

Masterman's
Auburn Industrial Park
P.O. Box 224
Auburn, MA 01501
617/755-7801.

Me1co, Inc.
6603 Governor Printz Blvd.
Wilmington, DE 19809
800/441-9749

Memphis Glove Company


Division of Shelby Group, Inc.
P.O. Box 171814
Memphis, TN 38187
901/795-0672

Miller Products Co., Inc.


29 Warren Street
New York, NY 10007
212-267-5334

Mine Safety Appliances Co.


608 Penn Center Blvd.
Pittsburgh, PA 15235
800/672-2222

Monte Glove Company


Monte Lane
Maben, MI 39750
601/263-5353

National Draeger, Inc.


101 Technology Drive
P.O. Box 120
Pittsburgh, PA 15230
412/787-8383

0-15
VENDOR.; DIRECTORY

National Safety Wear, Inc.


18 East Main St.
Malone, NY 12953
518/483-7246

Neese Industries Inc.


P.O. Box 628
Gonzales, LA 70737
800/535-8042

Nolato
Address not available.

North Rand Protection


A Division of Siebe North, Inc.
4090 Azalea Drive
P.O. Box 70729
Charleston, SC 29405
803/554-0660

OKI Supply Co.


7584 Reinhold Drive
Cincinnati, OR 45237
513/761-9811

Oak Medical Supply Co.


Subsidiary of The Oak Rubber Company
219 S. Sycamore Street
Ravenna, OR 44266
216-296-3416

Oak Technical, Inc.


218 Sycamore Street
Ravenna, OR 44266
216/296-3416

»-16
VENDOR DIRECTORY

PPG Industries, Inc.


Optical Products, Chemical
One PPG Place
Pittsburgh, PA 15272
412/434-3751

Panelgraphic Corporation
10 Henderson Drive
W. Caldwell, NJ 07006
800/222-0618

Pendergast Safety Equipment Co.


6900 Tulip St.
Philadelphia, PA 19135
215/332-1663

Pharmasea1 Laboratories Inc.


1015 Grandview Avenue
Glendale, CA 91201
213/240-8900

Pioneer Industrial Products Co.


512 East Tiffin Street
Willard, OH 44890
419/933-2211

Plastex Protective Products, Inc.


9 Grand Street
P.O. Box 57
Garfield, NJ 07026
201/779-4946

Plastimayd Corp.
2204 S.E. Seventh Avenue
P.O. Box 14217
Portland, OR 97214
503/232-5101
VENDOR DIRECTORY

Protech Safety Equipment Inc.


P.O. Box 455
Linden, NJ 07036
201/862-1550

Protexall Company
P.O. Box 307
Green Lake, WI 54941
414/294-6511

Pu1mosan Safety Equipment Corp.


30-48 Linden Place
Flushing, NY 11354
212/939-3200

Rainfair, Inc.
P.O. Box 1647
Racine, WI 53401
800/558-5990

Ranger
Division of Endicott Johnson
1100 E. Main St.
Endicott, NY 13760
607/757-4260

Record Industrial Co.


1020 Eighth Avenue
P.O. Box 407
King of Prussia, PA 19406
215/337-2500

Renco Corp
2060 Fairfax Avenue
Cherry Hill, NJ 08003
609/424-5755

D-18
VENDOR DIRECTORY

Rich Industries
Address not available.

Robar Protective Products


2213 W. Gl "wood Avenue
Philadelphia, PA 19132
800/523-5367

Rockford Medical & Safety Co.


4620 Hydraulic Rd.
P.O. Box 5166
Rockford, IL 61125
815/874-7891

Ronco Textile Products, Inc.


1405 East Lake Avenue
Peoria Heights, IL 61614
309/685-7266

SGL Homalite Industries


P.O. 3049
Wilmington, DL 19804
302/652-3686

Safeco Inc.
337 E. Center Street
P.o. Box 28
Kingsport, TN 37660
615/246-3552

Safety Engineering & Supply Co.


P.O. Box 147
Deer Park, TX 77536
713/476-9118

0-19
VENDOR DIRECTORY

Safety First Industries


4900 Campbell Road
Willoughby, OH 44094
216/946-1880

The Sager Corporation


65 E. Palatine Road
Prospect Heights, IL 60070
312/541-1361

W.H. Salisbury & Co.


Box 1060
7520 N. Long Avenue
Skokie, IL 60077
312/679-6700

Sawyer-Tower
Division of Lion Uniform
2735 Kerns Avenue
Dayton, OH 45414

Seiberling
Address not available.

Shelby-Wolverine Glove Company


P.O. Box 8735
Grand Rapids, MI 49518
616/698-7220

Singer Safety Co.


3800 N. Milwaukee Ave.
Chicago, IL 60641
312/286-1000

n-20
VENDOR DIRECTORY

Standard Glove & Safety Equip. Corp.


34300 Lakeland Boulevard
Eastlake, OH 44094
216-951-7440

Standard Safety Equipment Co.


P.O. Box 188
Palatine, IL 60078
312/359-1400

Stauffer Manufacturing Company


P.O. Box 45
6th Street
Red Hill, PA 18076
215/679-4446

Steel Grip Safety Apparel Co., Inc.


700 Garfield Street
Danville, IL 61832
217/442-6240

Steele & Associates, Inc.


P.O. Box 20368
Seattle, WA 98102
206/324-9445

Superior Surgical Mfg. Co., Inc.


Superior Surgical Park
Seminole Boulevard at lOOth Terrace
Seminole, FL 33542
813/397-9611

Surety-Sure Seal
Address not available.

~21
VENDOR DIRECTORY

H. Texier Glove Company Inc.


Highway 22 at Mountain Avenue
North Plainfield. NJ 07061
201/757-0616

3M Company
3M Center
Bldg. 220-7W
St. Paul. MN 55144
612/733-6234

Tingley Rubber Corp.


P.O. Box 100
South Plainfield. NJ 07080
201/757-7474

The Tracies Co.


102 Cabot St.
Holyoke. MA 01040
413/533-7141

Trelleborg. Inc.
30700 Solon Industrial Parkway
Solon. OH 44139
216/248-8600

United States Plastic Corp.


1390 Neubrecht Road
Lima. OH 45801
419/228-2242

United States Safety Service Co.


1535 Walnut St.
P.O. Box 1237
Kansas City. MO 64141
816/842-8500

~22
VENDOR. DIRECTORY

Vidaro Corp.
333-T Martine1 Drive
P.O. Box 535-T
Kent, OH 44240
216/673-7413

Viny1produkter
.S-261
23 Landskrona, Sweden

Yhee1er Protective Apparel, Inc.


4330 W. Belmont Ave.
Chicago, IL 60641
312/685-5551

Willson Safety Products


P.O. Box 622
Reading, PA 19603
215/376--6161

D-23
APPENDIX E

PRODUCT DESCRIPTION CODE

E-l
PRODUCT DESCRIPTION CODES AND RESISTANT MATERIALS

"/" INDICATES A lAYERED (EITHER COATED OR LAMINATED) MATERIAL STRUCTURE.


LAYERS ARE DESCRIBED BEGINING WITH THE EXTERIOR SURFACE.

"+" INDICATES A POLYMER BLEND.

SUPPORTED: BARRIER ~TERIAL IS COATED ONTO A CLOTH GLOVE.

UNSUPPORTED: BARRIER MAT~RIAL IS PRESENT AS A FREE-STANDING OR FLOCKED MEMBRANE.

NOTE: FABRICS SUCH AS DISPOSAGUriRD, DURAGUARD, GOR-TEX, SAFE-GUARD, SONTARA,


AND TYVEK ARE NOT COATED AND, THEREFORE, ARE PERMEABLE TO AIR AND MORE
COMFORTABLE TO WEAR. THEY ARE PRIMARILY RECOMMENDED AS BARRIERS TO
PARTICUlATES. CAUTION IS RECOMMENDED WHEN USING THESE FABRICS AS
SPlASH PROTECTION SINCE THEY ARE RAPIDLY PENETRATED BY GASES AND
MANY ORGANIC LIQU1DS.

E-2
Product Description Codes and Resistant Materials
(in numerical order -- alphabetical listing follows)

·'roduct Resistant
Code Material Product Description

001 NATURAL RUBBER Natural Rubber Latex Glove, Supported


002 NEOPRENE Chloroprene Latex Glove, Supported
003 PVC Polyvinyl Chloride Glove, Unsupported
004 PV ALCOHOL Polyvinyl Alcohol Glove, Supported
005 NITRILE Nitrile Rubber Latex Glove, Supported
006 PE Polyethylene Glove, Unsupported
007 PVC Polyvinyl Chloride Glove, Supported
008 NEOP/NAT RUBBER Cloroprene/Natural Rubber Latex Glove, Unsupported
009 VI TON Fluoroelastomer Glove, Solvent Dipped, Unsupported
010 NEOPRENE Chloroprene Milled/Chloroprene Latex Glove, Unsupported
011 NEOPRENE Chloroprene Rubber Latex (Baypren) Glove, Unsupported
012 BUTYL Butyl Rubber Latex Glove, Unsupported
013 BUTYL Butyl Rubber Latex Glove, Supported
014 BUTYL Butyl Rubber Glove, Solvent Dipped, Unsupported
015 NATURAL RUBBER Natural Rubber Glove, Solvent Dipped, Unsupported
016 BUTYL/NAT RUBBER Butyl/Natural Rubber Latex Glove, Supported
017 NATURAL RUBBER Natural Rubber Latex Glove, Unsupported
018 NEOPRENE Chloroprene Rubber Latex Glove, Unsupported
019 NITRILE Nitrile Rubber Latex Glove, Unsupported
020 NITRILE Nitrile Rubber Glove, Solvent Dipped, Unsupported
022 VITON/NEOPRENE Fluoroelastomer/Chloroprene Glove, Solv Dipped, Unsupp
023 NAT+NEOP+NBR Natural Rubber+Chloroprene+Nitrile Glove, Unsupported
025 NONtJOVEN FABRIC Sontara
026 NEOP+NAT RUBBER Chloroprene+Natural Rubber Latex Glove, Unsupported
027 POLYURETHANE Polyurethane Rubber, Unsupported
028 PVC Polyvinyl Chloride/Tyvek
029 PTX Po lymethylpentane, Face Shield
030 PVC Polyvinyl Chloride, Face Shield
031 NEOPRENE Chloroprene Rubber, Sheet
032 VITON Fluoroelastomer, Sheet
033 NITRILE Nitrile Rubber, Sheet
034 BUTYL Buty~ Rubber, Sheet
035 PV ALCOHOL Polyvinyl Alcohol, Sheet
036 TEFLON FEP Glove
040 POLYURETHANE Polyurethane Rubber/Polyester
041 PE Polyethylene, High Density, Film
042 PE Polyethylene, Medium Density, Film
044 TEFLON FEP Glove (Crumpled)
045 NATURAL RUBBER Natural Rubber, Sheet
046 BUTYL/NEOPRENE Butyl/Chloroprene Rubber, Boots
047 SBR Styrenebutadiene Rubber Latex Glove
048 PE . Polyethylene, Low Density, Film
049 PVC Polyvinyl Chloride, Sheet
050 POLYURETHANE Polyurethane Rubber/Nylon
051 NEOPRENE Chloroprene Rubber/Polyester
052 CHLOROBUTYL Chlorobutyl Rubber/Nomex
053 PVC Polyvinyl Chloride/Fabric
054 PVC Polyvinyl Chloride, Film
055 TEFLON FEP/Fiberglass
056 PE Polyethylene, Density Unkr,own, Film
057 NITRILE+PVC Nitrile+PVC Glove, Supported

E-3
Product Description Codes and Resistant Materials
(in numerical order -- alphabetical listing follows)

Product Resistant
Code Material Product Description

058 NITRILE+PVC Nitrile+PVC/Fabric


059 NITRILE Nitrile Rubber/Polyester
060 CPE Chlorinated Polyethylene
061 SARANEX PE/Polyvinylidenechloride/PE/Tyvek
062 TEFLON FEP/Nylon
063 SBR Styrenebutadiene Rubber/Fabric
064 BUTYL Butyl Rubber/Nylon
065 NEOPRENE+SBR RUBBER Chloroprene (35%)+SBR(65%)/Nylon--Tufflon
066 NEOPRENE+SBR RUBBER Chloroprene(l5%)+SBR(85%)/Cotton--Tuffprene
067 TEFLON TFE/Nomex
068 TEFLON FEP/Nomex
069 TEFLON TFE/Nomex/TFE
070 CPE Chlorinated Polyethylene/Nylon
071 NONWOVEN PE Tyvek
072 TEFLON TFE/Nomex/TFE Glove
073 TEFLON FEP, Face Shield and Lens
074 EVA Ethylene(86%) Vinyl Acetate(14%)/Polyester
075 PE Polyethylene/Sontara
076 PE Polyethylene/Tyvek
077 PVC Polyvinyl Chloride/Nylon
078 NITRILE Nitrile Rubber/Nylon
079 GORE-TEX Microporous Teflon/Nomex
080 NATURAL RUBBER Natural Rubber, Boots
081 NEOPRENE Chloroprene Rubber, Boots
082 POLYURETHANE Polyurethane Rubber, Boots
083 PVC Polyvinyl Chloride, Boots
084 NITRILE Nitrile Rubber, Boots
085 BUTYL Butyl Rubber, Boots
086 NONWOVEN PP Safeguard, Duraguard, Corovin
087 NATURAL RUBBER Natural Rubber/Nylon
088 PVC Polyvinyl Chloride/Rayon
089 NATURAL RUBBER Natural Rubber/Cotton
090 VITON Fluoroelastomer/Fiberglass
091 PE Polyethylene/Fabric
092 GORE-TEX Microporous Teflon/Polyester
093 NEOPRENE Chloroprene Rubber/Nylon
094 CELLULOSE PROPIONATE Cellulose Propionate, Face Shield and Lens
095 CR 39 Cr 39, Lens and Face Shield
096 POLYESTER Polyester, Face Shield and Lens
097 ACRYLIC Acrylic, Face Shield and Lens
098 POLYCARBONATE Polycarbonate, Lens and Face Shield
099 CELLULOSE ACETATE Cellulose Acetate, Face Shield and Lens
100 VITON/BUTYL Fluoroelastomer/Butyl/Nylon/Butyl
101 VITON/NITRILE Fluoroelastomer/Nitrile Rubber Glove, Unsupported
102 PV ALCOHOL Polyvinyl Alcohol Glove, Unsupported
103 EPDt-1jBUTYL Ethylenepropylene/Butyl Rubber G"tove, Unsupported
104 HYPALON/NEOPRENE Chlorosulfonated Polyethylene/Chloroprene Glov.Unsupp
105 PE Polyethylene/Polypropylene Nonwoven
106 PVC Polyvinyl Chloride Glove, Kid 490, Supported
107 BUTYL Butyl Rubber/Nomex
108 HYPALON Chlorosulfonated Polyethylene Rubber Glove. Unsupp

E-4
Product Description Codes and Resistant Materials
(in numerical order -- alphabetical listing follows)

Resistant
Material Product Description

109 PE/EVOR/PE PE/Ethylene Vinyl Alcohol/PE Glove, Unsupported


110 BUTYLjNEOPRENE Buty1/Po1yester/Chloroprene Rubber
111 VITONjNEOPRENE Fluoroelastomer/Ny1on/Ch1oroprene
112 VITON/CHLOROBUTYL F1uoroe1astomer/Polyester/Chlorobuty1
113 ECO/BUTYL Epichlorohydrin/Buty1 Rub Glove, Solv Dipped, Unsupp
114 VITON/BUTYL F1uoroe1astomer/Buty1 Glove, Solvent Dipped, Unsupported
llS BUTYL/NEOPRENE Buty1/Ch1oroprene Rubber Glove, Supported
116 BUTYL/NEOPRENE Buty1/Ch1oroprene Rubber Glove, Unsupported
117 HYPALON Hypa1on/Po1yester/Hypa1on
118 BUTYL Butyl/Polyester/Butyl Rubber
119 HYPALON/NEOPRENE Hypalon/Polyester/Chloroprene
122 SILVER SHIELD Silver Shield (North Product), Glove
124 PV ACETATE Polyvinyl Acetate, Sheet
125 NEOPRENE Chloroprene Mil1ed/Chloroprene Latex Glove, Supported
126 NEOP+NAT RUBBER Ch1oroprene+Nat Rub/Chloroprene+Nat Rub, Unsupported
127 NEOPRENE+PVC Chloroprene+PVC/Po1yester
128 ETHYLENE -METHYL ACRL Ethylene-methyl Acrylate Glove
129 VITON Fluoroelastomer/Fabric/F1uoroelastomer
130 BUTYL Butyl/Fabric!Butyl
131 PVC Polyvinyl Ch1oride/Fabric/Polyvinyl Chloride
132 NITRILE Nitrile/Fabric
133 PVC Polyvinyl Chloride/Nylon/Polyvinyl Chloride
134 PE Po1yethylene/Ny1on
135 NONWOVEN PP Polypropylene, Nonwoven
136 NATURAL RUBBER Natural Rubber/Polyester
137 PE Polyethylene/Polyester
138 NEOPRENE Ch1oroprene Rubber/Fabric
139 NEOPRENE Chloroprene/Fabric/Chloroprene
140 BUTYL Butyl/Ny1on/Butyl
141 NEOPRENE Chloroprene Rubber/Kev1ar
142 CHLOROBUTYL Chlorobutyl/Nomex/Ch1orobutyl
143 VITON Fluoroe1astomer/Polyester/Fluoroelastomer
144 PVC Polyvinyl Chloride/polyester
145 VITON Fluoroelastomer/Dacron
146 TEFLON TFE/Fiberg1ass/TFE
147 NITRILE Nitri1e/Fabric/Nitri1e
148 NEOPRENE Chloroprene/Cotton/Chloroprene
149 SBR/NEOPRENE Styrenebutadiene/Cotton/Ch1oroprene
150 NITRlLE+PVC Nitri1e+PVC Boot
152 NITRlLE+PVC Nitrile+PVC/Fabric/Nitrile+PVC
153 VITON/CHLOROBUTYL Fluoroelastomer/Nomex/Ch1orobutyl

E-5
Product Description Codes and Resistant Materials
(in alphabetical order of resistant material)

Product Resistant
Code Material Product Description

097 ACRYLIC Acrylic, Face Shield and Lens


012 BUTYL Butyl Rubber Latex Glove, Unsupported
013 BUTYL Butyl Rubber Latex Glove, Supported
014 BUTYL Butyl Rubber Glove, Solvent Dipped, Unsupported
034 BUTYL Butyl Rubber, Sheet
064 BUTYL Butyl Rubber/Nylon
085 BUTYL Butyl Rubber, Boots
107 BUTYL Butyl Rubber/Nomex
118 BUTYL Butyl/Polyester/Butyl Rubber
130 BUTYL Butyl/Fabric/Butyl
140 BUTYL Butyl/Nylon/Butyl,
016 BUTYL/NAT RUBBER Buty1/Natural Rubber Latex Glove, Supported
046 BUTYL/NEOPRENE Butyl/Chloroprene Rubber, Boots
110 BUTYL/NEOPRENE Butyl/Polyester/Chloroprene Rubber
115 BUTYL/NEOPRENE Butyl/Chloroprene Rubber Glove, Supported
116 BUTYL/NEOPRENE Butyl/Chloroprene Rubber Glove, Unsupported
099 CELLULOSE ACETATE Cellulose Acetate, Face Shield and Lens
094 CELLULOSE PROPIONATE Cellulose Propionate, Face Shield and Lens
052 CHLOROBUTYL Chlorobuty1 Rubber/Nomex
142 CHLOROBUTYL Chlorobutyl/Nomex/Chlorobutyl
060 CPE Chlorinated Polyethylene
070 CPE Chlorinated Polyethylene/Nylon
095 CR 39 Cr 39, Lens and Face Shield
113 ECO/BUTYL Epichlorohydrin/Butyl Rub Glove, Solv Dipped, Unsupp
103 EPDM/BUTYL Ethylenepropylene/Butyl Rubber Glove, Unsupported
128 ETHYLENE-METHYL ACRL Ethylene-methyl Acrylate Glove
074 EVA Ethylene(86%) Vinyl Acetate(l4%)/Polyester
079 GORE-TEX Microporous Teflon/Nomex
092 GORE-TEX Microporous Teflon/Polyester
108 HYPALON Chlorosulfonated Polyethylene Rubber Glove, Unsupp
117 HYPALON Hypalon/Polyester/Hypalon
104 HYPALON/NEOPRENE Chlorosulfonated Polyethylene/Chloroprene Glov,Unsupp
119 HYPALON/NEOPRENE Hypalon/Polyester/Chloroprene
023 NAT+NEOP+NBR Natural Rubber+Chloroprene+Nltrlle Glove, Unsupported
001 NATURAL RUBBER Natural Rubber Latex Glove, Supported
015 NATURAL RUBBER Natural Rubber Glove, Solvent Dipped, Unsupported
017 NATURAL RUBBER Natural Rubber Latex Glove, Unsupported
045 NATURAL RUBBER Natural Rubber, Sheet
080 NATURAL RUBBER Natural Rubber, Boots
087 NATURAL RUBBER Natural Rubber/Nylon
089 NATURAL RUBBER Natural Rubber/Cotton
136 NATURAL RUBBER Natural Rubber/Polyester
026 NEOP+NAT RUBBER Chloroprene+Natural Rubber Latex Glove, Unsupported
126 NEOP+NAT RUBBER Chloroprene+Nat Rub/Chloroprene+Nat Rub, Unsupported
008 NEOP/NAT RUBBER Cloroprene/Natural Rubber Latex Glove, Unsupported
002 NEOPRENE Chloroprene Latex Glove. Supported
010 NEOPRENE Chloroprene Milled/Chloroprene Latex Glove, Unsupported
all NEOPRENE Chloroprene Rubber Latex (Baypren) Glove, Unsupported
018 NEOPRENE Chloroprene Rubber Latex Glove, Unsupported
031 NEOPRENE Chloroprene Rubber, Sheet
051 NEOPRENE Chloroprene Rubber/Polyester

E-6
Product Description Codes and Resistant Materials
(in alphabetical order of resistant material)

roduct Resistant
":ode Material Product Description
------- ---------
081 NEOPRENE Chloroprene Rubber, Boots
093 NEOPRENE Ghloroprene Rubber/Nylon
125 NEOPRENE Chloroprene Milled/Chloroprene Latex Glove, Supported
138 NEOPRENE Chloroprene Rubber/Fabric
139 NEOPRENE Chloroprene/Fabric/Chloroprene
14.1 NEOPRENE Chloroprene Rubber/Kevlar
148 NEOPRENE Chloroprene/Cotton/Chloroprene
127 NEOPRENE+PVC Chloroprene+PVC/Polyester
065 NEOPRENE+SBR RUBBER Chloroprene (35%)+SBR(65%)/Nylon--Tufflon
066 NEOPRENE+SBR RUBBER Chloroprene(15%)+SBR(85%)/Cotton--Tuffprene
005 NITRILE Nitrile Rubber Latex Glove, Supported
019 NITRILE Nitrile Rubber Latex Glove, Unsupported
020 NITRILE Nitrile Rubber Glove, Solvent Dipped, Unsupported
033 NITRILE Nitrile Rubber, Sheet
059 NITRILE Nitrile Rubber/Polyester
078 NITRILE Nitrile Rubber/Nylon
084 NITRILE Nitrile Rubber, Boots
132 NITRILE Ni trile/Fabric
147 NITRILE Nitrile/Fabric/Nitrile
057 NITRILE+PVC Nitrile+PVC Glove, Supported
058 NITRILE+PVC Nitrile+PVC/Fabric
150 NITRILE+PVC Nitrile+PVC Boot
152 NITRILE+PVC Nitrile+PVC/Fabric/Nitrile+PVC
025 NONWOVEN FABRIC Sontara
071 NONWOVEN PE Tyvek
086 NONWOVEN PP Safeguard, Duraguard, Corovin
135 NONWOVEN PP Polypropylene, Nonwoven
006 PE Polyethylene Glove, Unsupported
041 PE Polyethylene, High Density, Film
042 PE Polyethylene, Medium Density, Film
048 PE Polyethylene, Low Density, Film
056 PE Polyethylene, Density Unknown, Film
075 PE Polyethylene/Sontara
076 PE PolyethylenejTyvek
091 PE Polyethylene/Fabric
105 PE Polyethylene/Polypropylene Nonwoven
134 PE Polyethylene/Nylon
137 PE Polyethylene/Polyester
109 PE/EVOH/PE PE/Ethylene Vinyl Alcohol/PE Glove, Unsupported
098 POLYCARBONATE Polycarbonate, Lens and Face Shield
096 POLYESTER Polyester, Face Shield and Lens
027 POLYURETHANE Polyurethane Rubber, Unsupported
040 POLYURETHANE Polyurethane Rubber/Polyester
050 POLYURETHANE Polyurethane Rubber/Nylon
082 POLYURETHANE Polyurethane Rubber, Boots
029 PTX Polymethylpentane, Face Shield
124 PV ACETATE Polyvinyl Acetate, Sheet
004 PV ALCOHOL Polyvinyl Alcohol Glove, Supported
035 PV ALCOHOL Polyvinyl Alcohol, Sheet
102 PV ALCOHOL Polyvinyl Alcohol Glove, Unsupported
003 PVC Polyvinyl Chloride Glove, Unsupported

E-7
Product Description Codes and Resistant Materials
(in alphabetical order of resistant material)

Product Resistant
Code Material Product Description

007 PVC Polyvinyl Chloride Glove, Supported


028 PVC Polyvinyl Chloride/Tyvek
030 PVC PolyVinyl Chloride, Face Shield
049 PVC Polyvinyl Chloride, Sheet
053 PVC Polyvinyl Chloride/Fabric
054 PVC Polyvinyl" Chloride, "Film ;
077 PVC Polyvinyl Chloride/Nylon
083 PVC Polyvinyl Chloride, Boots
088 PVC Polyvinyl Chloride/Rayon
106 PVC Polyvinyl Chloride Glove, Kid 490, Supported
131 PVC Polyvinyl Chloride/Fabric/Polyvinyl Chloride
133 PVC Polyvinyl Chloride/Nylon/Polyvinyl Chloride
144 PVC Polyvinyl Chloride/Polyester
061 SARAN EX PE/Polyvinylidenechloride/PE/Tyvek
047 SBR Styrenebutadiene Rubber Latex Glove
063 SBR Styrenebutadiene Rubber/Fabric
149 SBR/NEOPRENE Styrenebutadiene/Cotton/Chloroprene
122 SILVER SHIELD Silver Shield (North Product), Glove
036 TEFLON FEP Glove
044 TEFLON FEP Glove (Crumpled)
055 TEFLON FEP/Fiberglass
062 TEFLON FEP/Nylon
067 TEFLON TFE/Nomex
068 TEFLON FEP/Nomex
069 TEFLON TFE/Nomex/TFE
072 TEFLON TFE/Nomex/TFE Glove
073 TEFLON FEP, Face Shield and Lens
146 TEFLON TFE/Fiberglass/TFE
009 VITON Fluoroelastomer Glove, Solvent Dipped, Unsupported
032 VITON Fluoroelastomer, Sheet
090 VI TON Fluoroelastomer/Fiberglass
129 VI TON Fluoroelastomer/Fabric/Fluoroelastomer
143 VITON Fluoroelastomer/Polyester/Fluoroelastomer
145 VITON Fluoroelastomer/Dacron
100 VI TON/BUTYL Fluoroelastomer/Butyl/Nylon/Butyl
114 VITON/BUTYL Fluoroelastomer/Butyl Glove, Solvent Dipped, Unsupported
112 VITON/CHLOROBUTYL Fluoroelastomer/Polyester/Chlorobutyl
153 VITON/CHLOROBUTYL Fluoroelastomer/Nomex/Chlorobutyl
022 VI TON/NEOPRENE Fluoroelastomer/Chloroprene Glove", Solv Dipped, Unsupp
III VITON/NEOPRENE Fluoroelastomer/Nylon/Chloroprene
101 VITON/NITRILE Fluoroelastomer/Nitrile Rubber Glove, Unsupported

E-8
APPENDIX F

CLOTHING CLASSIFICATION CODE

F-l
CLOTHING TYPE CODE

(Number corresponds to type shown in Appendix C.)

Coat, Jacket 01
Coveralls 02

Apron ... '03

Pants, Bib Overall 04

Full-body Encapsulating Suit 05

Hood 06

Shoe Cover 07

Boot 08

Face Shield 09

Glove 00

F-2
APPENDIX G

DATA SHEETS FOR ENCAPSULATING ENSEMBLES


(For definitions of terms used in
this appendix, see Chapter 5 and
Appendix A)

G-l
MATERIAL PROTECTION LEVEL
Butyl / Nylon/ Butyl EPA: A (with emergency egress unit.)

STYLE VENDOR
LL-100 - Toxicological Butyl Andover Industries Inc.
THICKNESS: 14 mils 15 Union Street
MATERIAL WGT: 12 oz/sq yd Lawrence, MA 01840
ENSEMBLE WGT: No data (617) 794-1792
SIZES: No data

GARM ENT SEAM EXHAUST VALVES


Stitched, strapped with butyl. NUMBER: 4. TYPE: Flapper valve.
MATERIALS: No data.
LOCATION: Shoulder and leg areas.
CRACKING PRESSURE: 112-inch water.
CLOSURE MAX FLOW RATE: No data.
Pressure sealing zipper (Talon, Inc.). Teeth and SPLASH COVER: Yes.
slider. 67% copper, 12% nickel, 11 % zinc.
LOCATION: Front. LENGTH: 48 inches.
CLOSURE/SUIT SEAM: Same as garment.
SPLASH COVER: Yes. AIR SUPPLY
Umbilical feed. Hood accommodates face mask,
suit accommodates internal, emergency egress
unit
GLOVES
TYPE: Integral gloves (optional). COOLING
MATERIAL: Butyl. Air distribut!or. system (optional).
INTER~ACE: Same as garment seam.
TYPE: Detachable gloves (optional).
MATERIAL: Butyl.
INTERFACE: Inserts in glove and sleeve create FITTINGS
compr9ssion seal or support ring in sleeve with AIRLINE: Nt, data.
glove clamp. COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or overboots.
MATERIAL: Butyl/nylon/butyl.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: integral (optional). Abrasion Resistance: No data.
MATERIAL: Polycarbonate with 2.5 mit FEP or Flammability: No data.
30 mil PVC splash visor. Stiffness: No data.
INTERFACE: No data. Flex Fatigue: No data.
TYPE: Detachable (optional).
MATERIAL: Polycarbonate/triacetate.
INTERFACE: Chloroprene gasket.

G-2
MATERIAL PROTECTION LEVEL
Butyl/Nylon / Butyl EPA: A (with emergency egress unit.)

STYLE VENDOR
LL-100 - Chemical Butyl Andover Industries Inc.
THICKNESS: 15 mils 15 Union Street
MATERIAL WGT: 11.5 oz/sq yd Lawrence, MA 01840
ENSEMBLE WGT: No data (617) 794-1792
SIZES: No data

GARMENT SEAM EXHAUST VALVES


Stitched, strapped with butyl. NUMBER: 4. TYPE: Flapper valve.
MATERIALS: No data.
LOCATION: Shoulder and leg areas.
CRACKING PRESSURE: No data.
CLOSURE MAX FLOW RATE: No data.
Pressure sealing zipper (Talon, Inc.). Teeth and SPLASH COVER: Yes.
slider: 67% copper, 12% nickel, 11 % zinc.
LOCATION: Front. LENGTH: 48 inches.
CLOSURE/SUIT SEAM: Same as garment.
SPLASH COVER: Yes. AIR SUPPLY
Umbilical feed. Hood accommodates face mask,
suit accommodates internal, emergency egress
unit
GLOVES
TYPE: Integral gloves (optional). COOLING
MATERIAL: Butyl. Air distribution system (optional).
INTERFACE:. Same as garment seam.
TYPE: Detachable gloves (optional).
MATERIAL: Butyl.
INTERFACE: Inserts in glove and sleeve create FITTINGS
compression seal or support ring in sleeve with AIRLINE: No data.
glove clamp. COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or overboots.
MATERIAL: Butyl/nylon I butyl.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral (optional). Abrasion Resistance: No data.
MATERIAL: Polycarbonate with 2.5 mil FEP or Flammability: No data.
30 mil PVC splash visor. Stiffness: No data.
INTERFACE: No data. Flex Fatigue: No data.
TYPE: Detachable (optional). •
MATERIAL: Polycarbonate/triacetate.
INTERFACE: Chloroprene gasket.

G-3
MATERIAL PROTECTION LEVEL
Butyl/Nylon / Butyl EPA: A

STYLE VENDOR
305 B/BA Fyrepel Products Inc.
THICKNESS: 14 mils Box 518
MATERIAL WGT: 14 oz/sq yd Newark, OH 43055
ENSEMBLE WGT: 12 Ibs (614) 344-0391
SIZES: S, M, L. Xl
(for heights 5'4" - 6'5")

GARMENT SEAM EXHAUST VALVES


Stitched, strapped with butyl. NUMBER: 4. TYPE: Flapper valve (Glendale, Inc.)
MATERIALS: No data.
LOCATION: Back of legs.
CRACKING PRESSURE: 0.4 psi.
CLOSURE MAX FLOW RATE: No data.
Pressure sealing zipper. SPLASH COVER: Yes.
LOCATION: Back. LENGTH: 48 inches.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: Yes.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus or umbilical feed. Hood
accommodates face mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: User specified and supplied. Air distribution system or ice vest/jacket.
INTERFACE: Inserts in glove and sleeve create
compression seal.

FITTINGS
. -...".,..,..

AIRLINE: 1/4-inch brass.


COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or boots.
MATERIAL: Butyl I nylon I butyl.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Poly(methyl methacrylate). Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-4
MATERIAL PROTECTION LEVEL
Butyl! Nylon! Butyl EPA: A

STYLE VENDOR
306 B/BA Fyrepel Products Inc.
THICKNESS: 14 mils Box 518
MATERIAL WGT: 14 oz/sq yd Newark, OH 43055
ENSEMBLE WGT: 12 Ibs (614) 344-0391
SIZES: S, M, L XL
(for heights 5'4" - S'5")

GARMENT SEAM EXHAUST VALVES


Stitched, strapped with butyl. NUMBER: 4. TYPE: Flapper valve (Glendale, Inc.)
MATERIALS: No data.
LOCATION: Back of legs.
CRACKING PRESSURE: 0.4 psi.
CLOSURE MAX FLOW RATE: No data.
Pressure sealing zipper. SPLASH COVER: Yes.
LOCATION: Front LENGTH: No data.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: Yes.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus or umbilical feed. Hood
accommodates face mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: User specified and supplied. Air distribution system or ice vest/jacket
INTERFACE: Inserts in glove and sleeve create
compression seal. ~

FITTINGS
AIRLINE: 1/4-inch brass.
COMMUNICATION: No data.
COOLING: No datl!..
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or boots.
MATERIAL: Butyl! nylon I butyl.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIM~MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
Tear Strength: No data.
INTERFACE: Splash guards.
Seam Strength: No data.
Zipper Strength: No data.·
Cut Resistance: No data.
VISOR
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Poly(methyl methacrylate). Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-S
MATERIAL PROTECTION LEVEL
Butyl/Nylon / Butyl EPA: A

STYLE VENDOR
Trellchem. Butyl Extra Trelleborg. Inc.
THICKNESS: 15-18 mils 30700 Solon Industrial Parkway
MATERIAL WGT: 15 oz/sq yd Solon. OH 44139
ENSEMBLE WGT: 15 Ibs (216) 248-8600
SIZES: S. M. L. XL

GARMENT SEAM EXHAUST VALVES


Oouble lapped. stitched. cemented. interior NUMBER: 1. TYPE: No data.
strapped with chloroprene. exterior strapped with MATERIALS: Polyethylene/polystryrene. rubber
butyl. diaphragm.
LOCATION: Hood area.
CLOSURE CRACKING PRESSURE: 0.3-inch water.
Pressure sealing zipper. MAX FLOW RATE: No data.
LOCATION: Front LENGTH: 53 inches. SPLASH COVER: Yes.
CLOSURE/SUIT SEAM: Same as garment seam.
SPLASH COVER: Yes.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus. Hood accommodates face
mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene or butyl. Air distribution system.
INTERFACE: Support ring in sleeve. elastic band.

FITTINGS
AIRLINE: No data.
COMMUNICATION: None.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral boots or booties.
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: (ASTM 0-751). 110 Ibs/inch.
INTERFACE: Splash guard. Tear Strength; (ASTM 0-751). 10 Ibs.
Seam Strength: (ASTM 0-1682).110 Ibs.
Zipper Strength: No data,
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: 80 mil PVC visor. Flammability: No data.
INTERFACE: Adhesive bonded. interior strapped Stiffness: No data.
with butyl. Flex Fatigue: No data.

G-6
MATERIAL PROTECTION LEVEL
Butyl/Nylon / Butyl EPA: B

STYLE VENDOR
Trellchem, Butyl Trelleborg, Inc.
THICKNESS:· 15-18 mils 30700 Solon Industrial Parkway
MATERIAL WGT: 15 oz/sq yd Solon, OH 44139
ENSEMBLE WGT: 13 Ibs (216) 248-8600
SIZES: S, M, L, XL

GARMENT SEAM EXHAUST VALVES


Double lapped, stitched, cemented, interior NUMBER: 1. TYPE: No data.
strapped with chloroprene, exterior strapped with MATERIALS: Polyethylene/polystyrene, rubber
butyl. diaphragm.
LOCATION: Chest area.
CLOSURE CRACKING PRESSURE: 0.3-inch water.
Pressure sealing zipper. MAX FLOW RATE: No data
LOCATION: Front. LENGTH: 41 inches. SPLASH COVER: Yes.
CLOSURE/SUIT SEAM: Same as garment seam.
SPLASH COVER: Yes.
AIR SUPPLY
External back pack or umbilical feed.

GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene or butyl. Air distribution system.
INTERFACE: Support ring in sleeve, elastic band.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOUNG: No data.
BOOTS INFLATION VALVE: Yes.
TYPE: Integral boots or booties.
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
Tensile Strength: (ASTM 0-751), 110 Ibs/in.
MATERIAL: User specified and supplied.
Tear Strength: (ASTM 0-751), 10 Ibs.
INTERFACE: Splash guard.
Seam Strength: (ASTM 0-1682), 110 Ibs.
Zipper Strength: No data. .
Cut Resistance: No data.
VISOR Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-7
MATERIAL PROTECTION LEVEL
Butyl/Polyester / Chloroprene EPA: A

STYLE VENDOR
Chempruf 11, Betex/SCBA Mine Safety Appliances Co.
THICKNESS: 19 mils P.O. Box 426
MATERIAL WGT: 15.9 oz/sq yd Pittsburgh. PA 15230
ENSEMBLE WGT: No data (412) 273-5000
SIZES: One size

GARMENT SEAM EXHAUST VALVES


Double stitched, interior strapped with NUMBER: 3. TYPE: Flapper valve.
chloroprene, exterior sealed with liquid butyl. MATERIALS: Chloroprene valve cover.
chloroprene and natural rubber valve disk. nylon
valve seat, stainless steel slide ring, nylon
CLOSURE threaded ring.
LOCATION: Hood area.
Pressure sealing zipper (Dynat, Inc.). stainless
CRACKING PRESSURE: No data.
steel teeth, brass slider. chloroprene backing.
MAX FLOW RATE: No data.
LOCATION: Front. LENGTH: 72 inches. SPLASH COVER: None.
CLOSURE/SUIT SEAM: Same as garment.
SPLASH COVER: None. . AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus. Hood accommodates face
mask.
GLOVES
rYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene or butyl. Air distribution system (optional).
INTERFACE: Brass support ring in sleeve.
stainless steel glove clamp. natural rubber glove
ring sleeve.
TYPE: Detachable overgloves. FITTINGS
MA TERIAL: Viton or butyl. AIRLINE: No data.
INTERFACE: None. COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable booties.
MATERIAL: Butyl I polyester I chloroprene.
INTERFACE: None. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: NBR + SBR + natural rubber. Tensile Strength: No data.
INTERFACE: Aluminum support ring in garment Tear Strength: No data.
leg. stainless steel boot clamp. Seam Strength: No data.
Zipper Strength: No. data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: 5/32-inch poly(methyl methacrylate) Flammability: No data.
or 1 18-inch glass.
Stiffness: No data.
INTERFACE: Natural rubber gasket. Flex Fatigue: No data.

G-8
MATERIAL PROTECTION lEVEL
Butyl/Polyester / Chloroprene EPA: A

STYLE VENDOR
Chempruf II, Betex/DPBA Mine Safety Appliances Co.
THICKNESS: 19 mils P.O. Box 426
MATERIAL WGT: 15.9 oz/sq yd Pittsburgh, PA 15230
ENSEMBLE WGT: No data (412) 273-5000
SIZES: One size

GARMENT SEAM EXHAUST VALVES


Double stitched, interior strapped with NUMBER: 3. TYPE: Flapper valve.
chloroprene. exterior sealed with liquid butyl. MATERIALS: Chloroprene valve cover,
chloroprene and natural rubber valve disk, nylon
valve seat, stainless steel slide ring, nylon
CLOSURE threaded ring.
LOCATION: Hood area.
Pressure sealing zipper (Dynat, Inc.), stainless CRACKING PRESSURE: No data.
stesl teeth, brass slider, chloroprene backing.
MAX FLOW RATE: No data.
LOCATION: Front LENGTH: 72 inches. SPLASH COVER: None.
CLOSURE/SUIT SEAM: Same as garment.
SPLASH COVER: None. AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus or umbilical feed. Hood
accommodates face mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene or butyl. Air distribution system (optional).
INTERFACE: Brass support ring in sleeve,
stainless steel glove clamp, natural rubber glove
ring sleeve.
TYPE: Detachable overgloves. FITTINGS
MATERIAL: Butyl or Viton. AIRLINE: Aluminum and vinyl washers, brass
INTERFACE: None. fittings, quick disconnect.
COMMUNICATION: No data.
BOOTS COOLING: No data.
TYPE: Detachable booties. INFLATION VALVE: No data.
MA TERIAL: Butyl/polyester I chloroprene.
INTERFACE: None. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: NBR + SBR + natural rubber. Tensile Strength: No data.
INTERFACE: Aluminum support ring in garment Tear Strength: No data.
leg, stainless steel boot clamp. Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data..
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: 5/32-inch poly(methyl methacrylate) Flammability: No data.
or 1 IS-inch glass. Stiffness: No data.
INTERFACE: Natural rubber gasket. Flex Fatigue: No data.

G-9
MATERIAL PROTECTION LEVEL
Chlorinated Polyethylene EPA: No Rating (See Section 5.B.8.)

STYLE VENDOR
Chemturion, Model 12 ILC Dover, Inc.
THICKNESS: 20 mils P.O. Box 266
MATERIAL WGT: 19.7 oz/sq yd Frederica, DE 19946
ENSEMBLE WGT: 41bs (302) 335-3911
SIZES: L. XL
(tor heights 5'4" - 6'8")

GARMENT SEAM EXHAUST VALVES


Thermally welded. NUMBER: 2. TYPE: Flapper valve.
MATERIALS: No data.
LOCATION: Shoulder area.
CRACKING PRESSURE: No data.
CLOSURE MAX FLOW RATE: No data.
Inner restraint zipper with extruded chlorinated SPLASH COVER: Yes.
polyethylene sealing lips.
LOCATION: Front. LENGTH: No data.
CLOSURE/SUIT SEAM: Same as garment.
SPLASH COVER: None. AIR SUPPLY
Umbilical feed.

GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: User specified and supplied. Air distribution system or liquid pody cooling.
INTERFACE: Molded ABS connect ring in sleeve,
rubber connect ring in glove.

FITTINGS
AIRLINE: 1 /4-inch NPT brass.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties.
MATERIAL: Chlorinated polyethylene.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: Press-polished optical gra'de 40 mil Flammability: No data.
vinyl with polyester splash visors. Stiffness: No data.
INTERFACE: No data. Flex Fatigue: No data.

G-IO
MATERIAL PROTECTION LEVEL
Chlorinated Polyethylene EPA: A

STYLE VENDOR
Chemturion, Model' 3 IlC Dover, Inc.
THICKNESS: 20 mils P.O. Box 266
MATERIAL WGT: '9.7 oz/sq yd Frederica, DE , 9946
ENSEMBLE WGT: 4 Ibs (302) 335·39"
SIZES: One size
(for heights 5'4" - 6'4")

GARMENT SEAM EXHAUST VALVES


Thermally welded. NUMBER: 2. TYPE: Flapper valve.
MATERIALS: No data. .
LOCATION: Shoulder area.
CRACKING PRESSURE: No data.
CLOSURE MAX FLOW RATE: No data.
Inner restraint zipper with extruded chlorinated SPLASH COVER: Yes.
polyethylene sealing lips.
LOCATION: Front. LENGTH: No data.
CLOSURE/SUIT SEAM: Same as garment.
SPLASH COVER: None. AIR SUPPLY
Expanded back accommodates self·contained
breathing apparatus. Hood accommodates face
mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: User $ecified and supplied. liquid body cooling (optional).
INTERFACE: Molded ASS connect ring in sleeve.
rubber connect ring in glove.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data,
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties.
MATERIAL: Chlorinated polyethylene.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MA TERIAl: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: Press-polished optical grade 40 mil Flammability: No data.
vinyl with polyester splash visors. Stiffness: No data.
INTERFACE: No data. . Flex Fatigue: No data.

G-ll
MATERIAL PROTECTION LEVEL
Chlorinated Polyethylene EPA: A

STYLE VENDOR
Chemturion, Model 51 ILC Dover, Inc.
THICKNESS: 20 mils P.O. Box 266
MATERIAL WGT: 19.7 ozl sq yd Frederica, DE 19946
ENSEMBLE WGT: 4 Ibs (302) 335·3911
SIZES: S, M, L
(for heights 5'4" - 6'4")

GARMENT SEAM EXHAUST VALVES


Thermally welded. NUMBER: 4. TYPE: Spring operated.
MATERIALS: No data.
LOCATION: Legs and shoulder areas.
CRACKING PRESSURE: No data.
CLOSURE MAX FLOW RATE: No data.
Inner restraint zipper with extruded chlorinated SPLASH COVER: Yes.
polyethylene sealing lips.
LOCATION: Rear. LENGTH: No data.
CLOSURE/SUIT SEAM: Same as garment
SPLASH COVER: None. AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus (Bio-Marine Bio-Pak 60P
rebreather). Hood accommodates face mask.
GLOVES
TYPE: Integral gloves. COOLING
MATERIAL: Polyvinyl chloride. Liquid body cooling.
INTERFACE: Same as garment seam.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: Standard tire valve.
TYPE: Integral booties.
MATERIAL: Chlorinated polyethylene.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(pRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength; No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: Polycarbonate with antifog coating Flammability: No data.
and splash visors. Stiffness: No data.
INTERFACE: No data. Flex Fatigue: No data.

G-12
MATERIAL PROTECTION LEVEL
Chlorobutyl/Nomex/Chlorobutyl EPA: No Rating (See Section 5.B.8.)

STYLE VENDOR
SCAPE RFHCO Arrowhead Products
THICKNESS: 19 mils 4411 Katella Avenue
MATERIAL WGT: 17 oz/sq yd Los Alamitos. CA 90720
ENSEMBLE WGT: No data (714) 828-7770
SIZES: Nine sizes

GARMENT SEAM EXHAUST VALVES


Cemented. strapped with butyl. NUMBER: 3. TYPE: Flapper valve - Sierra Eng 50.

MATERIALS: Aluminum housing and plate. butyl


rubber antibackstreaming valve.
CLOSURE LOCATION: Hip and hood areas.
Pressure sealing zipper (B.F. Goodrich). brass CRACKING PRESSURE: C.S-inch water.
teeth and slider. chloroprene coated nylon filled MAX FLOW RATE: No data.
cotton fabric. SPLASH COVER: Yes.
LOCATION: Front. LENGTH: 4S or 50 in.
CLOSURE/SUIT SEAM: Sewn in and overlaid AIR SUPPLY
with cement bonded suit material strapping. Expanded back accommodates self-contained.
SPLASH COVER: Yes. 2-hour back pack. liquid air charged. 7.0 liters. or
umbilical feed.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Butyl. Uquid air evaporation. air distribution system.
INTERFACE: Molded butyl connect ring in sleeve Vortex cooling (optional).
and glove with butyl rolldown covers.

FITTINGS
AIRLINE: Stainless steel quick disconnect for
vortex COOling system.
COMMUNICATION: Various types (optional).
BOOTS COOLING: See AIRLINE.
TYPE: Detachable boots. INFLATION VALVE: No data.
MATERIAL: PVC.
INTERFACE: Molded butyl connect rings in PHYSICAL PROPERTIES
(pRIMARY MATERIAL)
garment leg and boot with butyl rolldown covers.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR Puncture Resistance: No data.
TYPE: Detachable Abrasion Resistance: No data.
MATERIAL: 25 mil modified acrylic. Flammability: No data.
INTERFACE: Butyl rubber gasket. Stiffness: No data.
Flex Fatigue: No data.

G-13
MATERIAL PROTECTION LEVEL
Chlorobutyl/Nomex/Chlorobutyl EPA: No Rating (See Section 5.B.B.)

-i
STYLE VENDOR
Propellant Handlers Ensemble ILC Dover, Inc. I
I
THICKNESS: 20 mils P.O. Box 266 I
MATERIAL WGT: No data Frederica, DE 19946
ENSEMBLE WGT: No data (302) 335-3911
SIZES: No data

GARMENT SEAM EXHAUST VALVES I


. I
Nylon stitch.ed, strapped with chlorobutyl NUMBER: 4. TYPE: Flapper valve. I

(chloroprene adhesive). - MATERIALS: No data.


LOCATION: Legs and shoulder areas.
CRACKING PRESSURE: No data.
CLOSURE MAX FLOW RATE: No data.
SPLASH COVER: Yes. I
Inner restraint zipper with extruded chlorinated I
polyethylene sealing lips.
LOCATION: No' data. LENGTH: No data. I
CLOSURE/SUIT SEAM: Same as garment.
SPLASH COVER: None. AIR SUPPLY I
External back pack or umbilical feed.
I
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: User specified and supplied. No data.
INTERFACE: Metal connect rings in sleeve and
glove.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: User specified and supplied.
INTERFACE: Metal connect rings in garment leg PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
and boot.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Polycarbonate. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
. Flex Fatigue: No data .

G-14
MATERIAL PROTECTION LEVEL
Chloroprene/Nylon EPA: 8

STYLE VENDOR
Type 500 CK National Draeger,lnc.
THICKNESS: No data 101 Technology Drive
MATERIAL WGT: No data Pittsburgh, PA 15230
ENSEMBLE WGT: No data (412) 787-8383
SIZES: Above 5'11"
Below 5'11"

GARMENT SEAM EXHAUST VALVES


Double stitched, exterior strapped with NUMBER: None. TYPE: Not available.
chloroprene. MATERIALS: Not available.
LOCATION: Not available.
CRACKING PRESSURE: Not available.
CLOSURE MAX FLOW RATE: Not available.
Pressure sealing zipper. SPLASH COVER: Not available.
LOCATION: Front. LENGTH: No data.
CLOSURE/SUIT SEAM: No data.
: SPLASH COVER: Yes.
AIR SUPPLY
i External back pack. Face mask incorporated in
suit

GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Viton. None.
INTERFACE: Support ring in sleeve, steel glove
clamp.

FITIINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERFACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-15
MATERIAL PROTECTION LEVEL
Chloroprene/Nylon EPA: No Rating (See Section 5.8.8.)

STYLE VENDOR
Type 600 CK National Draeger, Inc.
THICKNESS: No data '0' Technology Drive
MATERIAL WGT: No data Pittsburgh, PA 15230
ENSEMBLE WGT: No data (4'2) 787-8383
SIZES: One size

GARMENT SEAM EXHAUST VALVES


Double stitched, exterior strapped with NUMBER: 1. TYPE: No data.
chloroprene. MATERIALS: No data.
LOCATION: Chest area.
CRACKING PRESSURE: No data.
CLOSURE MAX FLOW RATE: No data.
Pressure sealing zipper. SPLASH COVER: Yes.
LOCATION: Front. LENGTH: No data.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: None.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus. Face mask incorporated in
suit. .-.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Viton. None.
INTERFACE: Support ring in sleeve, steel glove
clamp.

FITTINGS
AIRLINE: No data.·
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERFACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data,
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-16
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride/Nylon EPA: A (with emergency egress unit.)

STYLE VENDOR
LL-100 - Polyvinyl Chloride Andover Industries Inc.
THICKNESS: 15 mils , 5 Union Street
MATERIAL WGT: '0 oz/sq yd Lawrence, MA 01840
ENSEMBLE WGT: No data (617) 794-1792
SIZES: No data

GARMENT SEAM EXHAUST VALVES


Stitched, strapped with PVC. NUMBER: 4. TYPE: Flapper valve.
MATERIALS: No data.
LOCATION: Shoulder and leg areas.
CRACKING PRESSURE: No data.
CLOSURE MAX FLOW RATE: No data.
Pressure sealing zipper (Talon, Inc.). Teeth and SPLASH COVER: Yes.
slider: 67% copper, 12% nickel, 11% zinc.
LOCATION: Front. LENGTH: 48 inches.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: Yes. AIR SUPPLY
Umbilical feed. Hood accommodates face mask.
suit accommodates internal. emergency egress
unit
GLOVES
TYPE: Integral gloves (optional). COOLING
MATERIAL: Polyvinyl chloride. Air distribution system (optional).
INTERFACE: Same as garment seam.
TYPE: Detachable gloves (optional).
MATERIAL: Polyvinyl chloride.
INTERFACE: Support ring in sleeve. stainless FITTINGS
steel glove clamp. AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties.
MATERIAL: PVC/nylon.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
Tear Strength: No data.
INTERFACE: Splash guards.
Seam Strength: No data.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR Puncture Resistance: No data.
TYPE: Integral (optional). Abrasion Resistance: No data.
MATERIAL: Polycarbonate with 2.5 mil FEP or Flammability: No data.
30 mil PVC splash visor. Stiffness: No data.
INTERFACE: No data. Flex Fatigue: No data.
TYPE: Detachable (optional).
MATERIAL: Polycarbonate/triacetate.
INTf:RFACE: Chloroprene gasket

G-17
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride/ Polyester EPA: No Rating (See Section 5.B.8.)

STYLE VENDOR
Stasafe, Accordion Standard Safety Equipment Co.
THICKNESS: 28-30 mils P.O. Box 188
MATERIAL WGT: 27 oz/sq yd Palatine, IL 60078-0188
ENSEMBLE WGT: No data (312) 359- 1400
SIZES: No data

GARMENT SEAM EXHAUST VALVES


Stitched, str~pped with PVC (welded). NUMBER: 4. TYPE: Flapper valve.
MATERIALS: ASS housing, natural rubber
flapper.
LOCATION: Back and leg areas.
CLOSURE CRACKING PRESSURE: No data.
Pressure sealing zipper. MAX FLOW RATE: No data.
LOCATION: Rear. LENGTH: No data. SPLASH COVER: Yes.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: None.
AIR SUPPLY
External back pack or umbilical feed. Face mask
incorporated in suit.

GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Polyvinyl chloride. Air distribution system or vortex cooling.
INTERFACE: Inserts in glove and sleeve create
compression seal.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral overboots (optional).
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARV MATERIAL)
TYPE: Detachable boots (optional).
MATERIAL: Chloroprene. Tensile Strength: No data.
INTERFACE: Inserts in boot and garment leg Tear Strength: No data.
create compression seal. Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: 40 mil flexible vinyl. Flammability: No data.
INTERF ACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-1S
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride! Polyester EPA: A

STYLE VENDOR
Stasafe, Acidmaster Standard Safety Equipment Co.
THICKNESS: 28-30 mils P.O. Box 188
MATERIAL WGT: 27 oz/sq yd Palatine, IL 60078-0188
ENSEMBLE WGT: No data (312) 359-1400
SIZES: M, L, XL
(for heights 5'8" - 6'5")

GARMENT SEAM EXHAUST VALVES


Stitched, strapped with PVC (welded). NUMBER: 4. TYPE: Flapper valve.
MATERIALS: ASS housing, natural rubber
flapper.
LOCATION: Back and leg areas.
CLOSURE CRACKING PRESSURE: No data.
Pressure sealing zipper. MAX FLOW RATE: No data.
LOCATION: Rear. LENGTH: No data. SPLASH COVER: Yes.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: None.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus. Hood accommodates face
mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Polyvinyl chloride. Air distribution system or vortex cooling.
INTERFACE: PVC inserts in glove and sleeve
create compression seal.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or overboots.
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: Polyvinyl chloride. Tensile Strength: No data.
Tear Strength: No data.
INTERFACE: PVC inserts in boot and garment leg
create compression seal. Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: 40 mil flexible PVC. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-19
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride/ Polyester EPA: A (with emergency egress unit.)

STYLE VENDOR
Stasafe, Compressed Air Standard Safety Equipment Co.
THICKNESS: 28-30 mils P.O. Box 188
MATERIAL WGT: 27 oz/sq yd Palatine, IL 60078-0188
ENSEMBLE WGT: No data (312) 359-1400
SIZES: One size

GARMENT SEAM EXHAUST VALVES


Stitched, st~apped with PVC (welded). NUMBER: 4. TYPE: Flapper valve.
MATERIALS: ASS housing, natural rubber
flapper.
LOCATION: Back and leg areas.
CLOSURE CRACKING PRESSURE: No data.
Standard zipper. Pressure sealing zipper optional. MAX FLOW RATE: No data.
LOCATION: Rear. LENGTH: No data. SPLASH COVER: Yes.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: Yes.
AIR SUPPLY
Umbilical feed. Hood accommodates face mask.
Egress bottle (optional).

GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Polyvinyl chloride. Air distribution system or vortex cooling.
INTERFACE: PVC inserts in glove and sleeve
create compression seal.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral overboots (optional).
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots (optional).
MATERIAL: Chloroprene. Tensile Strength: No data.
INTERFACE: PVC inserts in boot and garment leg Tear Strength: No data.
create compression seal. Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: 40 mil flexible PVC. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.
i
I

G-20
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: A

STYLE VENDOR
305 PVC/BA Fyrepel Products Inc.
THICKNESS: No data Box 518
MATERIAL WGT: 10 oz/sq yd Newark, OH 43055
ENSEMBLE WGT: No data (614) 344-0391
SIZES: S, M, L, XL
(for heights 5'4" - 6'5")

GARMENT SEAM EXHAUST VALVES


Stitched, strapped with PVC. NUMBER: 4. TYPE: Flapper valve (Glendale. Inc.)
MATERIALS: No data.
LOCATION: Back of legs.
CRACKING PRESSURE: 0.4 psi.
CLOSURE MAX FLOW RATE: No data.
Pressure sealing zipper. SPLASH COVER: Yes.
LOCATION: Back. LENGTH: 48 inches.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: Yes.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus or umbilical feed. Hood
accommodates face mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: User specified and supplied. Air distribution system or ice vest/jacket
INTERFACE: Inserts in glove and sleeve create
compression seal.

FITTINGS
AIRLINE: 1/4-inch brass.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or boots.
MATERIAL: PVC/nylon/PVC.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
Tensile Strength: No data.
MATERIAL: User specified and supplied.
Tear Strength: No data.
INTERFACE: Splash guards.
Seam Strength: No data..
Zipper Strength: No data.
Cut Resistance: No data.
VISOR Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Poly(methyl methacrylate). Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-21
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: A

STYLE VENDOR
306 PVC/SA Fyrepel Products Inc.
THICKNESS: No data Box 518
MATERIAL WGT: 10 oz/sq yd Newark, OH 43055
ENSEMBLE WGT: No data (614) 344-0391
SIZES: S, M, L, XL
(for heights 5'4" - 6'5")

GARMENT SEAM EXHAUST VALVES


Stitched. strapped with PVC. NUMBER: 4. TYPE: Flapper valve (Glendale, Inc.)
MATERIALS: No data.
LOCATION: Back of legs.
CRACKING PRESSURE: 0.4 psi.
CLOSURE MAX FLOW RATE: No data.
Pressure sealing zipper. SPLASH COVER: Yes.
LOCATION: Front LENGTH: No data.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: Yes.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus or umbilical feed. Hood
accommodates face mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: User specified and supplied. Air distribution system or ice vest/jacket
INTERFACE: Inserts in sleeve and glove create
compression seal.

FITTINGS
AIRLINE: 1/4-inch brass.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or boots.
MATERIAL: PVCI nylon/ PVC.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Poly(methyl methacrylate). Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-22
MATERIAL PROTECTION lEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: B

STYLE VENDOR
Type 500 PVC National Draeger. Inc.
THICKNESS: No data 101 Technology Drive
MATERIAL WGT: No data Pittsburgh, PA 15230
ENSEMBLE WGT: 13.2 Ibs (412) 787-8383
SIZES: Above 5' 11"
Below 5'11"

GARMENT SEAM EXHAUST VALVES


Double stitched. exterior strapped with PVC. NUMBER: None. TYPE: Not available.
MATERIALS: Not available.
LOCATION: Not available.
CRACKING PRESSURE: Not available.
CLOSURE MAX FLOW RATE: Not available.
Pressure sealing zipper. SPLASH COVER: Not available.
LOCATION: Front. LENGTH: No data.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: Yes.
AIR SUPPLY
External back pack. Face mask incorporated in
suit.

GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Viton. None.
INTERFACE: Support ring in sleeve. steel glove
clamp.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERFACE: Support ring in garment leg. steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-23
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: No Rating (See Section 5.B.8.)

STYLE VENDOR
Type 600 PVC National Draeger, Inc.
THICKNESS: No data. 101 Technology Drive
MA TERIAL WGT: No data. Pittsburgh, PA 15230
ENSEMBLE WGT: 14.3 Ibs (412) 787-8383
SIZES: One size

GARMENT SEAM EXHAUST VALVES


Double stitched, exterior strapped with PVC. NUMBER: 1. TYPE: No data.
MATERIALS: No data.
LOCATION: Chest area.
CRACKING PRESSURE: No data.
CLOSURE MAX FLOW RATE: No data.
Pressure sealing zipper. SPLASH COVER: Yes.
LOCATION: Front. LENGTH: No data.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: None.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus. Face mask incorporated in
suit.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Viton. None.
INTERFACE: Support ring in sleeve, steel glove
clamp.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERFACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-24
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: A

STYLE VENDOR
Type 700 PVC National Draeger, Inc.
THICKNESS: No data 101 Technology Drive
MATERIAL WGT: No data Pittsburgh, PA 15230
ENSEMBLE WGT: 12.1 Ibs (412) 787-8383
SIZES: One size

GARMENT SEAM EXHAUST VALVES


Double stitched, exterior strapped with PVC. NUMBER: 2. TYPE: No data.
MATERIALS: No data.
LOCATION: Hood area.
CRACKING PRESSURE: No data.
CLOSURE MAX FL.OW RATE: No data.
Pressure sealing zipper. SPLASH COVER: Yes.
LOCATION: Front. LENGTH: No data.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: None.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus. Hood accommodates face
mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Viton. None.
INTERFACE: Support ring in sleeve, steel glove
clamp.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERf-ACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
boot clamp. (PRIMARY MATERIAL)
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Polyvinyl chloride. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-25
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC -EPA: 8

STYLE VENDOR
Trellchem, Light Trelleborg, Inc.
THICKNESS: 15-18 mils 30700 Solon Industrial Parkway
MATERIAL WGT: 14.5 oz/sq yd Solon, OH 44139
ENSEMBLE WGT: 12.5 Ibs (216) 248-8600
SIZES: S, M, L. XL

GARM ENT SEAM EXHAUST VALVES


Double lappe.d, stitched, exterior welded. NUMBER: 1. TYPE: No data.
MATERIALS: Polyethylene/polystyrene, rubber
diaphragm.
LOCATION: Chest area.
CLOSURE CRACKING PRESSURE: 0.3-inch water.
Pressure sealing zipper. MAX FLOW RATE: No data.
LOCATION: Front. LENGTH: 41 inches. SPLASH COVER: Yes.
CLOSURE/SUIT SEAM: Stitched, cemented,
interior and exterior strapped with PVC.
SPLASH COVER: Yes. AIR SUPPLY
External back pack or umbilical feed.

GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene. Air distribution system.
INTERFACE: Support ring in sleeve, elastic band.

FITTINGS
AIRLINE: No data.
COMMUNICATION: None.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral boots or booties.
MATERIAL: Polyvinyl chloride.
INTERFACE: Adhesive bonded. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: (ASTM 0-751),110 Ibs/in.
INTERFACE: Splash guard. Tear Strength: (ASTM 0-751), 10 Ibs.
Seam Strength: (ASTM 0-1682), 110 Ibs.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-26
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: A

STYLE VENDOR
Trellchem, Light Extra Trelleborg, Inc.
THICKNESS: 15-18 mils 30700 Solon Industrial Parkway
MATERIAL WGT: 14.5 oztsq yd Solon, OH 44139
ENSEMBLE WGT: 12.51bs (216) 248-8600
SIZES: S, M, L, XL

GARMENT SEAM EXHAUST VALVES


Double lapped, stitched, exterior welded NUMBER: 1. TYPE: No data.
MATERIALS: Polyethylene/ polystyrene, rubber
diaphragm.
LOCATION: Hood area.
CLOSURE CRACKING PRESSURE: 0.3-inch water.
Pressure sealing zipper. MAX FLOW RATE: No data.
LOCATION: Front LENGTH: 53 inches. SPLASH COVER: Yes.
CLOSURE/SUIT SEAM: Stitched, cemented,
interior and exterior strapped with PVC.
SPLASH COVER: Yes. AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus. Hood accommodates face
mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene. Air distribution system.
INTERFACE: Support ring in sleeve, elastic band.

FITTINGS
AIRLINE: No data.
COMMUNICATION: None.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral boots or booties.
MATERIAL: Polyvinyl chloride.
INTERFACE: Adhesive bonded. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: (ASTM 0-751), 110 Ibstin.
INTERFACE: Splash guard. Tear Strength: (ASTM D-751), 10 Ibs.
Seam Strength: (ASTM 0-1682),110 Ibstin.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: 80 mil PVC visor. Flammability: No data.
INTERFACE: Adhesive bonded, interior strapped Stiffness: No data.
with PVC. Flex Fatigue: No data.

G-27
MATERIAL PROTECTION LEVEL
Polyvinyl Chloride (PVC)/Nylon/PVC EPA: A

STYLE VENDOR
Acid King Wheeler Protective Apparel, Inc.
THICKNESS: 20 mils 4330 West Belmont Avenue
MATERIAL WGT: 14 oz/sq yd Chicago, IL 60641
ENSEMBLE WGT: No data (312) 685-5551
SIZES: Short. Regular, Long
(for heights 5'4'.' - 6'6")

GARMENT SEAM EXHAUST VALVES


Stitched. thermally welded. NUMBER: 2. TYPE: Flapper valve.
MATERIALS: No data.
LOCATION: Shoulder and leg areas.
CRACKING PRESSURE: No data.
CLOSURE MAX FLOW RATE: No data.
Pressure sealing zipper. SPLASH COVER: Yes.
LOCATION: Rear. LENGTH: 44 inches.
CLOSURE/SUIT SEAM: Stitched, thermally
welded.
SPLASH COVER: None. AIR SUPPLY
Expanded back accommodates self-contained
back pack or umbilical feed. Hood
accommodates face mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: PVC. Air distribution system (optional).
INTERFACE: Support ring in sleeve, steel glove
clamp.

FITTINGS
AIRLINE: 1/4-inch NPT..
COMMUNICATION: No data.
COOLING: 114-inch NPT or 3/4-inch GH thread.
BOOTS INfLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: PVC.
INTERFACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: (FTM 191 A, 5100), 94.1 Ibs (W),
100 Ibs (F).
Tear Strength: (ASTM 0-1117), 33.9 Ibs (W),
24.4 Ibs (F).
Seam Strength: (ASTM 16S3), 63 Ibs.
VISOR Zipper Strength: No data.
TYPE: Integral (optional). Cut Resistance: No data.
MATERIAL: 40 mil PVC. Puncture Resistance: (FTM 191A, 5120), 21.2Ibs.
INTERFACE: No data. Abrasion Resistance: (FTM 191 A, 5306), 3.000 cye,
no wear.
TYPE: Detachable (optional).
Flammability: (FTM 191 A, 5903.2), pass.
MATERIAL: 125 mil poly(methyl methacrylate).
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: (U.S.T. Method), 1,000 cyc,
no cracking.

G-28
MATERIAL PROTECTION LEVEL
Teflon/Fiberglass/Teflon EPA: A

STYLE VENDOR
Challenge 5200 Chemical Fabrics Corporation
THICKNESS: 10 mils P.O. Box 1137
MATERIAL WGT: 14.6 oz/sq yd Merrimack. NH 03054
ENSEMBLE WGT: 10 Ibs (603) 424-9000
SIZES: No data

GARMENT SEAM EXHAUST VALVES


Welded half-inch lap seam, exterior strapped with NUMBER: 4. TYPE: Halkey Roberts 780-RPA.1.
Teflon tape. MATERtALS: Nylon housing, silicon rubber
diaphragm. 304 stainless steel spring.
LOCATION: Upper back.
CLOSURE CRACKING PRESSURE: 2-inch water.
Pressure sealing zipper (YKK. Inc.). MAX FLOW RATE: No data.
Chloroprene tape. brass teeth and slider. SPLASH COVER: Yes.
LOCATION: Back. LENGTH: 36 inches.
CLOSURE/SUIT SEAM: Fiberglass heat sealed to
garment. zipper chloroprene tape bonded to AIR SUPPLY
fiberglass with toluene base adhesive. Expanded back accommodates self-contained
SPLASH COVER: Yes. breathing apparatus. Hood accommodates face
mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: 10 mil Teflon. None.
INTERFACE: Support ring in sleeve. stainless
steel glove clamp. splash guard.
TYPE: Detachable gloves.
MATERIAL: 10 mil. solvent-dipped butyl. FITTINGS
INTERFACE: Elastic butyl rubber band. AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties.
MATERIAL: Teflon/fiberglass/Teflon.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: (FTM 191.5102.2).221 Ibs/in
INTERFACE: Splash guards.
CN), 192 Ibs/in (F).
Tear Strength: (FTM 191, 5134), 13.7 Ibs CN),
9.0 Ibs (F).
Seam Strength: (ASTM 3786), 50 psi.
VISOR
Zipper Strength: (FTM 191. 5100.1). 70 pli.
TYPE: Integral. Cut Resistance: No data.
MATERIAL: 10 mil FEP. Puncture Resistance: No data.
INTERFACE: 5-6 mil Teflon tape heat sealed on Abrasion Resistance: (FTM 191, 5302). 0.064
both sides. grams lost
Flammability: (ASTM D-568), non-burning.
Stiffness: (FTM 191, 5200.1); 4.0 cm.
Flex Fatigue: No data.

G-29
MATERIAL PROTECTION LEVEL
Teflon/Nomex/Teflon EPA: A

STYLE VENDOR
Challenge 5100 Chemical Fabrics Corporation
THICKNESS: 18 mils P.O. Box 1137
MATERIAL WGT: 13.9 oz/ sq yd Merrimack, NH 03054
ENSEMBLE WGT: 14 Ibs (603) 424-9000
SIZES: One (large)

GARMENT SEAM EXHAUST VALVES


Stitched, interior and exterior strapped with Teflon NUMBER: 2. TYPE: Stratotech,
tape (welded). Part No. 739- 1.5.
MATERIALS: Aluminum housing, silicon rubber
diaphragm, 304 stainless steel spring.
CLOSURE LOCATION: Upper back.
Pressure sealing zipper (YKK, Inc.). CRACKING PRESSURE: 1- to 1.5-inch water.
Chloroprene tape, brass teeth and slider. MAX FLOW RATE: No data.
LOCATION: Back. LENGTH: 36 inches. SPLASH COVER: Yes.
CLOSURE/SUIT SEAM: Fiberglass heat sealed to
garment, zipper chloroprene tape bonded to AIR SUPPLY
fiberglass with toluene base adhesive. Expanded back accommodates self-contained
SPLASH COVER: Yes. breathing apparatus. Hood accommodates face
mask.
GLOVES
TYPE: Integral gloves. COOLING
MATERIAL: 4 mil Teflon. External cooling ice pouch/heat exchanger
INTERFACE: Bonded at glove ring with toluene- interfaces with full body cooling garment and
based adhesive. pouch which circulates water through garment.
TYPE: Detachable gloves.
MATERIAL: 10 mil, solvent-dipped butyl. FITTINGS
INTERFACE: Elastic butyl rubber band. AIRLINE: None.
COMMUNICATION: None.
COOLING: No data.
BOOTS INFLATION VALVE: None.
TYPE: Integral booties.
MATERIAL: Teflon/Nomex/Teflon.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: (ASTM 0-751), 113.7Ibs/in 0N),
INTERFACE: Splash guards. 95.8 Ibstin (F).
Tear Strength: (ASTM 0-751), 21.0 Ibs 0N),
19.6 Ibs (F).
VISOR Seam Strength: (ASTM 3786), 50 psi.
Zipper Strength: (FTM 191,5100.1),70 pli.
TYPE: Integral. Cut Resistance: No data.
MATERIAL: 10 mil FEP. Puncture Resistance: No data.
INTERFACE: 5-6 mil Teflon tape heat sealed on Abrasion Resistance: (FTM 191, 5302), 0.656
both sides. . grams lost.
Flammability: (ASTM 0-568), non-burning.
Stiffness: (FTM 191,5200.1),4.5 cm.
Flex Fatigue: No data.

G-30
MATERIAL PROTECTION LEVEL
Viton/Nomex/Chlorobutyl EPA: A

STYLE VENDOR
Metro S.S. Andover Industries Inc.
THICKNESS: 20 mils 15 Union Street
MATERIAL WGT: 29 oz/sq yd Lawrence, MA 01840
ENSEMBLE WGT: No data (617) 794-1792
SIZES: S, M, L. XL, XXL
(for heights 5'6" - 6'7")

GARMENT SEAM EXHAUST VALVES


Double stitched, interior strapped with butyl, NUMBER: 2. TYPE: Flapper valve.
exterior strapped with Viton. MATERIALS: No data.
LOCATION: Chest and sleeve areas.
CRACKING PRESSURE: 1 /2-inch water.
CLOSURE MAX FLOW RATE: No data.
Pressure sealing zipper. SPLASH COVER: Yes.
LOCATION: Front. LENGTH: 60 inches.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: Yes.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus. Hood accommodates face
mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Viton. Air distribution system (optional).
INTERFACE: Inserts in glove and sleeve create
compression sea/.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties.
MA TERIAL: Viton / Nomex/ ch lorobutyl.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR
Puncture Resistance: No data.
TYPE: Detachable (optional). Abrasion Resistance: No data.
MA TERIAL: Polycarbonate with FEP splash Flammability: No data.
cover. Stiffness: No data.
INTERFACE: Chloroprene gasket Flex Fatigue: No data.
TYPE: Detachable (optional).
MATERIAL: User specified.
INTERFACE: Chloroprene gasket.

G-31
MATERIAL PROTECTION LEVEL
Viton / Nylon /Chloroprene EPA: A

STYLE VENDOR
Chempruf II, Vautex/SCBA Mine Safety Appliances Co.
THICKNESS: 23 mils P.O. Box 426
MATERIAL WGT: 19.1 oz/sq yd Pittsburgh, PA 15230
ENSEMBLE WGT: No data (412) 273-5000
SIZES: One size

GARMENT SEAM EXHAUST VALVES


Double stitched, interior strapped with NUMBER: 3. TYPE: Flapper valve.
chloroprene, exterior sealed with liquid Viton. MATERIALS: Chloroprene valve cover,
chloroprene and natural rubber valve diSk,· nylon
valve seat, stainless steel slide ring, nylon
CLOSURE threaded ring.
LOCATION: Hood area.
Pressure sealing zipper (Dynat, Inc.), stainless
CRACKING PRESSURE: No data.
steel teeth, brass slider, chloroprene backing.
MAX FLOW RATE: No data.
LOCATION: Front LENGTH: 72 inches.
SPLASH COVER: None.
CLOSURE/SUIT SEAM: Same as garment
SPLASH COVER: None. AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus. Hood accommodates face
mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene or Viton. Air distribution system (optional).
INTERFACE: Brass support ring in glove,
stainless steel glove clamp, natural rubber glove
ring sleeve.
TYPE: Detachable overgloves. FITTINGS
MATERIAL: Butyl or Viton. AIRLINE: No data.
INTERFACE: None. COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable booties.
MATERIAL: Viton/ nylon I chloroprene.
INTERFACE: None. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: NBR + SBR + natural rubber. Tensile Strength: No data.
INTERFACE: Aluminum support ring in garment Tear Strength: No data.
leg, stainless steel boot clamp. Seam Strength: No data.
Zipper Strength: No da~.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable.
Abrasion Resistance: No data.
MATERIAL: 5/32-inch poly(methyl methacrylate) Flammability: No data.
or 1/8-inch glass. Stiffness: No data.
INTERFACE: Natural rubber gasket.
Flex Fatigue: No data.

G-32
MATERIAL PROTECTION LEVEL
Viton / Nylon / Chloroprene EPA: A

STYLE VENDOR
Chempruf II, Vautex/DPBA Mine Safety Appliances Co.
THICKNESS: 23 mils P.O. Box 426
MATERIAL WGr: 19.1 oz/sq yd Pittsburgh, PA 15230
ENSEMBLE WGT: No data (412) 273-5000
SIZES: One size

GARMENT SEAM EXHAUST VALVES


Doubie stitched, interior strapped with NUMBER: 3. TYPE: Flapper valve.
chioroprene, exterior sealed with liquid Viton. MATERIALS: Chloroprene valve cover,
chloroprene and natural rubber valve disk, nylon
valve seat, stainless steel slide ring, nylon
CLOSURE threaded ring.
LOCATION: Hood area.
Pressure sealing zipper (Dynat, Inc.), stainless CRACKING PRESSURE: No data.
steel teeth, brass slider, chloroprene backing.
MAX FLOW RATE: No data.
LOCATION: Front. LENGTH: 72 inches. SPLASH COVER: None.
CLOSURE/SUIT SEAM: Same as garment.
SPLASH COVER: None. AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus or umbilical feed. Hood
accommodates face mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene or Viton. Air distribution system (optional).
INTERFACE: Brass support ring in sleeve,
stainless steel glove ring, natural rubber glove
ring sleeve.
TYPE: Detachable overgloves. FITTINGS
MATERIAL: Butyl or Viton. AIRLINE: Aluminum and vinyl washers, brass_
INTERFACE: None. fittings, quick disconnect.
COMMUNICATION: No data.
BOOTS COOLING: No data.
TYPE: Detachable booties. INFLATION VALVE: No data.
MATERIAL: Viton I nylon I chloroprene.
INTERFACE: None. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: NBR + SBR + natural rubber. Tensile Strength: No data.
INTERFACE: Aluminum support ring in garment Tear Strength: No data.
leg, stainless steel boot clamp. Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: 5/32-inch poly(methyl methacrylate) Flammability: No data.
or 1 IS-inch glass. Stiffness: No data.
INTERFACE: Natural rubber gasket. Flex Fatigue: No data.

G-33
MATERIAL PROTECTION LEVEL
Viton / Nylon / Chloroprene EPA: B

STYLE VENDOR
Type SOD PF National Draeger, Inc.
THICKNESS: No data 101 Technology Drive
MATERIAL WGT: No data Pittsburgh, PA 15230
ENSEMBLE WGT: No data (412) 787-8383
SIZES: Above 5',,"
Below 5"1"

GARMENT SEAM EXHAUST VALVES


Double stitched, interior strapped with NUMBER: None. TYPE: Not available.
chloroprene, exterior sealed with Viton sealing MATERIALS: Not available.
compound. LOCATION: Not available.
CRACKING PRESSURE: Not available.
CLOSURE MAX FLOW RATE: Not available.
Pressure sealing zipper. SPLASH COVER: Not available.
LOCATION: Front LENGTH: No data.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: Yes.
AIR SUPPLY
External back pack. Face mask incorporated in
suit

GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Viton. None.
INTERFACE: Support ring in sleeve, steel glove
clamp.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERFACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data. '
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-34
THIS PAGE LEFT INTENTIONALLY BLANK

G - 35
MATERIAL PROTECTION LEVEL
Viton / Nylon / Chloroprene EPA: A

STYLE VENDOR
Type 700 PF National Draeger. Inc.
THICKNESS: No data 101 Technology Drive
MATERIAL WGT: No data Pittsburgh, PA 15230
ENSEMBLE WGT: No data (412) 767-8363
SIZES: One size

GARMENT SEAM EXHAUST VALVES


Double stitched, interior strapped with NUMBER: 2. TYPE: No data.
chloroprene, exterior sealed with Viton sealing MATERIALS: No data.
compound. LOCATION: Hood area.
CRACKING PRESSURE: No data.
CLOSURE MAX FLOW RATE: No data.
Pressure sealing zipper. SPLASH COVER: Yes.
LOCATION: Front. LENGTH: No data.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: None.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus. Hood accommodates face
mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Viton. None.
INTERFACE: Support ring in sleeve, steel glove
clamp.

FITTINGS
AIRLINE: No data.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Detachable boots.
MATERIAL: Chloroprene.
INTERFACE: Support ring in garment leg, steel PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
boot clamp.
Tensile Strength: No data.
Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture ReSistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Polyvinyl chloride. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-36
MATERIAL PROTECTION LEVEL
Viton / Polyester /Viton EPA: A

STYLE VENDOR
305 VISA Fyrepel Products Inc.
THICKNESS: 8 mils Box 518
MATERIAL WGT: 2.5 oz/sq yd Newark. OH 43055
ENSEMBLE WGT: No data (614) 344-0391
SIZES: S, M, L, XL
(for heights 5'4" - 6/5")

GARMENT SEAM EXHAUST VALVES


Stitched. strapped with Viton. NUMBER: 4. TYPE: Flapper valve (Glendale, Inc.)
MATERIALS: No data.
L.OCATION: Back of legs.
CRACKING PRESSURE: 0.4 psi.
CLOSURE MAX FL.OW RATE: No data.
Pressure sealing zipper. SPL.ASH COVER: Yes.
LOCATION: Back. LENGTH: 48 inches.
CLOSURE/SUIT SEAM: No data.
SPLASH COVER: Yes.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus or umbilical feed. Hood
accommodates face mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: User specified and supplied. Air distribution system or ice vest/jacket.
INTERFACE: Inserts in glove and sleeve create
compression seal.

FITTINGS
AIRLINE: 1/ 4-inch brass.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral booties or boots.
MA TERIAL: Viton / polyester !Viton.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: No data.
INTERFACE: Splash guards. Tear Strength: No data.
Seam Strength: No data.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Poly(methyl methacrylate). Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-37
MATERIAL PROTECTION LEVEL
Viton / Polyester /Viton EPA: A

STYLE VENDOR
306 VIBA Fyrepel Products Inc.
THICKNESS: 8 mils Box 518
MATERIAL WGT: 2.5 oz/sq yd Newark, OH 43055
ENSEMBLE WGT: No data (614) 344-0391
SIZES: S, M, L, XL
(for heights 5'4" - 6'5")

GARMENT SEAM EXHAUST VALVES


Stitched, strapped with Viton. NUMBER: 4. TYPE: Flapper valve (Glendale, Inc.)
MATERIALS: No data.
LOCATION: Back of legs.
CRACKING PRESSURE: 0.4 psi.
CLOSURE MAX FLOW RATE: No data.
SPLASH COVER: Yes.
Pressure sealing zipper.
LOCATION: Front LENGTH: No data.
CLOSURE/SuiT SEAM: No data.
SPLASH COVER: Yes. AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus or umbilical feed. Hood
accommodates face mask.
GLOVES
COOLING
TYPE: Detachable gloves.
MATERIAL: User specified and supplied. Air distribution system or ice vest/jacket
INTERFACE: Inserts in glove and sleeve create
compression seal.

FITTINGS
AIRLINE: 1 /4-inch brass.
COMMUNICATION: No data.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral boots or booties.
MATERIAL: Viton / polyester /viton. PHYSICAL PROPERTIES
INTERFACE: Same as garment seam. (PRIMARY MATERIAL)
TYPE: Detachable boots. Tensile Strength: No data.
MATERIAL: User specified and supplied. Tear Strength: No data.
INTERFACE: Splash guards. Seam Strength: No data.
Zipper Strength: No data.
Cut Resistance: No data.
VISOR Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MATERIAL: Poly{methyl methacrylate). Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-38
MATERIAL PROTECTION LEVEL
Viton / Butyl/Nylon / Butyl EPA: B

STYLE VENDOR
Trelichem, Super Trelieborg, Inc.
THICKNESS: 15-18 mils 30700 Solon Industrial Parkway
MATERIAL WGT: 16 oz/sq yd Solon, OH 44139
ENSEMBLE WGT: 13 Ibs (216) 248-8600
SIZES: S, M, L, XL

GARMENT SEAM EXHAUST VALVES


Double lapped, stitched, cemented, interior NUMBER: 1. TYPE: No data.
strapped with chloroprene, exterior strapped with MATERIALS: Polyethylene/polystyrene, rubber
Viton. diaphragm.
LOCATION: Chest area.
CLOSURE CRACKING PRESSURE: 0.3-inch water.
Pressure sealing zipper. MAX FLOW RATE: No data.
LOCATION: Front. LENGTH: 41 inches. SPLASH COVER: Yes.
CLOSURE/SUIT SEAM: Same as garment seam.
SPLASH COVER: Yes.
AIR SUPPLY
External back pack or umbilical feed.

GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene or Viton/butyl. Air distribution system.
INTERFACE: Support ring in sleeve, elastic band.

FITTINGS
AIRLINE: No data.
COMMUNICATION: None.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral boots or booties.
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: (ASTM 0-751), 110 Ibs/in.
INTERFACE: Splash guard. Tear Strength: (ASTM 0-751), 10 Ibs.
Seam Strength: (ASTM 0-1682), 110 Ibs.
Zipper Strength: No data.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Detachable. Abrasion Resistance: No data.
MA TERIAL: No data. Flammability: No data.
INTERFACE: No data. Stiffness: No data.
Flex Fatigue: No data.

G-39
MATERIAL PROTECTION LEVEL
Vitonl Butyl INylon/8utyl EPA: A

STYLE VENDOR
Trellchem. Super Extra Trelleborg. Inc.
THICKNESS: 15-18 mils 30700 Solon Industrial Parkway
MATERIAL WGT: 16 oz/sq yd Solon. OH 44139
ENSEMBLE WGT: 15 Ibs (216) 248-8600
SIZES: S. M. L. XL

GARMENT SEAM EXHAUST VALVES


Double lapped. stitched. cemented. interior NUMBER: 1. TYPE: No data.
strapped with chloroprene. exterior strapped with MATERIALS: Polyethylene/polystyrene. rubber
Viton. diaphragm.
LOCATION: Hood area.
CLOSURE CRACKING PRESSURE: 0.3-inch water.
Pressure sealing zipper. MAX FLOW RATE: No data.
LOCATION: Front. LENGTH: 53 inches. SPLASH COVER: Yes.
CLOSURE/SUIT SEAM: Same as garment seam.
SPLASH COVER: Yes.
AIR SUPPLY
Expanded back accommodates self-contained
breathing apparatus. Hood accommodates face
mask.
GLOVES
TYPE: Detachable gloves. COOLING
MATERIAL: Chloroprene or Viton/butyl. Air distribution system.
INTERFACE: Support ring in sleeve. elastic band.

FITTINGS
AIRLINE: No data.
COMMUNICATION: None.
COOLING: No data.
BOOTS INFLATION VALVE: No data.
TYPE: Integral boots or booties.
MATERIAL: Polyvinyl chloride.
INTERFACE: Same as garment seam. PHYSICAL PROPERTIES
(PRIMARY MATERIAL)
TYPE: Detachable boots.
MATERIAL: User specified and supplied. Tensile Strength: (ASTM 0-751). 110 Ibs/in.
INTERFACE: Splash guard. Tear Strength: (ASTM 0-751). 10 Ibs.
Seam Strength: (ASTM D-1682). 110 Ibs.
Zipper Strength: No data'.
VISOR Cut Resistance: No data.
Puncture Resistance: No data.
TYPE: Integral. Abrasion Resistance: No data.
MATERIAL: 80 mil PVC. Flammability: No data.
INTERFACE: Adhesive bonded. interior strapped Stiffness: No data.
with Viton / butyl. Flex Fatigue: No data.

G-40
APPENDIX H

PRODUCT DESCRIPTIONS FOR SPLASH SUITS

H-1
SPLASH SUITS

VENDOR/
STYLE PRIMARY MATERIAL DESCRIPTION

BOSS MFG. CO.


3PC PVC/COTTON TYPES: JACKET, HOOD, PANTS, BIB OVERALL.
3PN PVC/NYLON
3PN PVC/NYLON/PVC FEATURES: PVC SEAMS SEWN AND THERMALY WELDED;
3NN CHLOROPRENE/NYLON CHLOROPRENE AND SBR SEAMS CEMENTED;
3RC SBR/COTTON BATWING OR RAGLAN SLEEVES;
3RC SBR/COTTON/SBR STORM FLY FRONT; NICKLE PLATED
3NP POLYURETHANE/NYLON SNAPS OR NON'CORROSIVE, NON'CONDUCTIVE
3PR PVC/POLYESTER PLASTI C SNAPS.
3PF UNSUPPORTED PVC

DAFFIN DISPOSABLES
PCT POLYETHYLENE/TYVEK TYPES: JACKET, PANTS, COVERALLS,
SARANEX SARANEX/TYVEK ENCAPSULATING SUIT.
FEATURES: STORM FLY FRONT; ZIPPER CLOSURE;
ELASTIC CUFFS ON SLEEVES AND LEGS; INTEGRAL
OVERBOOTS ON SUITS; BOUND SEAHS;EXPANDED BACK
ACCOMMODATES SELF CONTAINED AIR SUPPLY OR
SUIT IS UMBILICALLY FED.

DEFENSE APPAREL
UNSUPPORTED PVC TYPES: JACKET, PANTS, BI8 OVERALL, COVERALL.

FEATURES: ZIPPER CLOSURES.

DIRECT SAFETY COMPANY


RAINMASTER SUPPORTED PVC TYPES: JACKET, PANTS, BIB OVERALLS.
RAINMASTER UNSUPPORTED PVC
PVC/NYLON/PVC FEATURES: NON'CONDUCTIVE SNAPS.

DISPOSABLES INC.
P.E. POLYETHYLENE/TYVEK TYPES: COVERALLS, ENCAPSULATING SUIT.

FEATURES: STORM FLY FRONT; ELASTIC CUFFS ON SLEEVES;


INTEGRAL OVERBOOTS ON SUITS; ZIPPER CLOSURE;
MYLAR FACE SHIELD IN ENCAPSULATING SUIT;
UMBILICALLY FED SUIT.

H-2
VENDOR/
STYLE PRIMARY MATERIAL DESCRIPTION

DURAFAB DISPOSABLES
POLYLAMINATED TYVEK POLYETHYLENE/TYVEK TYPES: JACKET, HOOO, PANTS, COVERALL,
SARANEX STYLE SARANEX/TYVEK ENCAPSULATING SUIT.
FEATURES: STITCHED, BOUND, OR BOUND AND SEALED SEAMS;
RAGLAN SLEEVES; SNAPS OR ZIPPER CLOSURE;
ZIPPER CLOSURE ON SUIT;
ELASTIC CUFFS ON SLEEVES AND LEGS;
EXPANDED BACK ON ENCAPSULATING SUITS YILL
ACCOMMODATE SELF CONTAINED AIR SUPPLY OR
SUIT IS UMBILLICALLY FED.

EDMONT
!JET !JEAR 500 PVC/NYLON/PVC TYPES: JACKET, HOOD, PANTS, BIB OVERALLS.
WET !JEAR 550 SUPPORTED PVC
!JET !JEAR 600 PVC/NYLON/PVC FEATURES: THERMALLY !JELDED SEAMS; BATWING
!JET !JEAR 700 NITRILE+PVC/NYLON SLEEVES; NON-CORROSIVE, NON-CONDUCTING
SNAPS.

ENCON
CHLDROPRENE/NYLON TYPES: JACKET, HOOD, PANTS, BIB OVERALLS.

FALCON
PREMIUM GRADE RAYON SUPPORTED PVC TYPES: JACKET, HOOD, PANTS, BIB OVERALLS.
CONTRACT GRADE PVC·RAYON-PVC
NYGRID PVC-NYLON-PVC FEATURES: LAPPED, DOUBLE-STITCHED, WELDED SEAMS;
UNSUPPORTED PVC RAGLAN SLEEVES: NON·CONDUCTIVE SNAPS;
SPLIT. SNAPS TO PREVENT "FREEZING"; WAIST,
WRIST, AND ANKLE TAKE UPS; DRAW-STRING
COAT HEM: !JELDED REINFORCEMENT IN CROTCH
AND ARMPIT.

KAPPLER
P.E. POLYETHYLENE/TYVEK TYPES: JACKET, PANTS, COVERALL, HOOO,
SARANEX SARANEX/TYVEK ENCAPSULATING SUIT.
FEATURES: BOUND OR WELDED SEAMS; ZIPPER CLOSURE;
STORM FLY FRONT; ELASITIC CUFFS ON SLEEVES
AND LEGS; INTEGRAL OVERBOOTS; EXPANDED BACK
ACCOMMODATES SELF CONTA1NED AIR SUPPLY
DR SUIT IS UMBILLICALlY FED.

MAGID
STANDARD DUTY SUPPORTED PVC TYPES: JACKET, HOOD, PANTS, BIB OVERALLS.

FEATURES: WELDED SEAMS; NON-METALIC SNAPS; STORM


FLY FRONT.

B-3
VENDOR/
STYLE PRIMARY MATERIA~ DESCRIPTION

RAINFAIR
POLYLON POLYURETHANE/NYLON TYPES: JACKET, HOOD, PANTS, BIB OVERALLS.
SUPER NYLO-GARD CHLOROPRENE/NYLON/CHLOROPRENE
NYLO-GARD CHLOROPRENE/NYLON FEATURES: STITCHED AND STRAPPED OR CEMENTED
DOLPHIN POLYURETHANE/NYLON SEAMS: STORM FLY FRONT: BATWING
ACID SUIT PVC/POLYESTER/PVC SLEEVES; REFLECTIVE TRIM.
SUPER NEOTEX CHLOROPRENE/COTTON/CHLOROPRENE
SUPER NYLO-SEAL CHLOROPRENE/NYLON
VULTEX SBR/COTTON/CHLOROPRENE
CHEM-KING PVC/NYLON
SBR YANKEE SBR/COTTON

RECORD INDUSTRIAL CO.


COATED CLOTHING BUTYL/NYLON/BUTY~ TYPES: JACKET, HOOD, PANTS, BIB OVERALLS_
CHLOROPRENE/COTTON
SUPPORTED PVC FEATURES: STORM FLY FRONT: RAGLAN SLEEVES: METAL OR
PLASTIC SNAPS; ~AIST ADJUSTERS.

SIEBE NORTON
F-100 CHLOROPRENE/NYLON/CHLOROPRENE TYPES: JACKET, HOOD, PANTS, BIB OVERALLS, COVERALL.
TUFF LON CHLOROPRENE+SBR/NYLON
SUPER TUFFPRENE CHLOROPRENE/COTTON/CHLOROPRENE FEATURES: LAP FRONT OR STORM FLY FRONT; DOUBLE
TUFFPRENE CH~OROPRENE+SBR/COTTON STITCHED SEAM II/SEALANT OR THERMALLY WELDED.
NSPN CHLOROPRENE+SBR/COTTON BATWING OR RAGLAN SLEEVES;
SHIELD BRAND PVC/NYLON/PVC INNER CUFF IN SLEEVE; TAKE-UP SNAPS ON CUFF;
TUFFGARD PVC/NYLON/PVC NON-CONDUCTIVE SNAPS.
006 1/2 H PVC/NYLON/PVC
NSPVH PVC/NY~ON/PVC

RAINMASTER SUPPORTED PVC


RAINMASTER UNSUPPORTED PVC

IIHEELER
34 LINE FABRIC SUPPORTED CHLOROPRENE TYPES; JACKET, HOOD, PANTS, BIB OVERALLS.
36 LINE FABRIC SUPPORTED PVC
3S LINE FILM UNSUPPORTED PVC FEATURES: STITCHED AND THERMALLY WELDED SEAMS: STORM
FLY FRONT; PLASTIC SNAPS.

H-4
APPENDIX I

DEFINITION OF PROTECTION LEVELS


(Excerpted from "Hazardous Materials
Incident Response Operations," 1984,
Office of Emergency and Remedial
Response, Hazardous Response Support
Division, U.S. Environmental Protection
Agency)

1-1
PART 5

SITE ENTRY - LEVELS OF PROTECTION

I. I NTRODUCTI ON
Personnel must wear protective equipment when response activities
involve known or suspected atmospheric contamination, when vapors,
gases, or particulates may be generated by site activities. or when
direct contact with skin-affecting substances may occur. Full face-
.piece respirators protect lungs, gastrointestinal tract, and eyes
against airborne toxicants. Chemical-resistant clothing protects the
skin from contact with skin-destructive and absorbable chemicals.
Good ~ersonal hygiene limits or prevents ingestion of material.
Equ i pment to protect the body aga i nst contact with known or ant i c i-
pated toxic chemicals has been divided into four categories according
to the degree of protection afforded:
Level A: Should be worn when the highest level of respiratory,
skin, and eye protection is needed.
Level B: Should be worn when the highest level of respiratory
protection ;s needed, but a lesser level of skin protection.
Level C: Should be worn when the criteria for using air-purifying
respirators are met.
Level 0: Should be worn only as a work uniform and not on any
site with respiratory or skin hazards. It provides no protection
against chemical hazards.
The Level of Protection selected should be based on:
Type and measured concentration of the chemical substance
in the ambient atmosphere and its toxicity.
Potential for exposure to substances in air. splashes of liquids,
or other direct contact with material due to work being done.
In situations where the type of chemical. concentration, and
possibilities of contact are not known, the appropriate Level of
Protection must be selected based on professional experience and
judgment until the hazards can be better identified.
While personnel protective equipment reduces the potential for contact
with toxic substances, ensuring the health and safety of responders
requires, in addition, safe work practices, decontamination. site
entry protocols, and other safety procedures. Together, these provide
an integrated approach for reducing harm to workers.

1-2
II. LEVELS OF PROTECTION
A. Level A Protection
1. Personnel protective equipment
Supplied-air respirator approved by the Mine Safety and
Health Administration (MSHA) and National Institute for'
Occupational Safety and Health (NIOSH).
Respirators may be: -
pressure-demand, self-contained breathing apparatus
(SCBA)
or
pressure-demand, airline respirator (with escape bottle
for Immediately Dangerous to Life and Health (IDLH) or
potential for IDLH atmosphere)
Fully encapsulating chemical-resistant suit
- Coveralls·
Long cotton underwear*
- Gloves (inner). chemical-resistant
Boots, chemical-resistant. steel toe and shank. (Depending
on suit construction, worn over or under suit boot)
Hard hat* (under suit)
- Disposable gloves and boot covers* (Worn over fully encap-
sulating suit)
- Cooling unit*
2-Way radio communications* (inherently safe)
2. Criteria for selection
- Meeting any of these criteria warrants use of Level A
Protection:
The chemical substance has been identified and -requires
the highest level of protection for skin, eyes, and the
respiratory system based on:
-- measured (or potent i a1 for) hi gh concent rat; on of

*Opt 1ona 1

I-3
atmospheric vapors. gases. or particulates
or
site operations and work functions involves high
potential for splash. immersion, or exposure to un-
expected vapors, gases. or particulates of materials
highly toxic to the skin.
- Substances with a hi gh degree of hazard to the sk i n .are
known or suspected to be present. and sk in contact is
possible.
- Operations must be conducted in confined, poorly' venti-
lated areas until the absence of substances requiring
Level A protection is determined.
- Direct readings on field Flame Ionization Dectors (FlO) or
Photoionization Detectors (PID) and similar instruments
indicate high levels of unidentified vapors and gases in
tpe air. (See Appendixes I and II.)
3. Guidance on selection
a. Fully encapsulating suits are primarily designed to
provide a gas or vapor tight barrier between the wearer
and atmospheric contaminants. Therefore Level A is gen~
eral1y worn when high concentrations of airborne sub-
stances are known or thought to be present and these
substances could severely effect the skin. Since Level A
requires the use of a self-contained breathing apparatus,
the eyes and respiratory system are also more protected.
Until air surveillance data are available to assist in the
selection of the appropriate Level of Protection. the use
of Level A may have to be based on indirect evidence of
the potential for atmospheric contamination or other means
of skin contact with severe skin affecting substances.
Conditions that may require Level A protection include:
- Confined spaces: Enclosed. confined, or poorly ventilated
areas are conducive to build up of toxic vapors, gases, or
particulates. (Explosive or oxygen-deficient atmospheres
also are more probable in confined spaces.} Confined space
entry does not automatically warrant wearing Level A pro-
tect; on, but shoul d' serve as a cue to carefully consi der
and to justify a lower Level of Protection.
- Suspected/known highly toxic substances: Various sub-
stances that are highly toxic especially through skin

1-4
absorption for example, fuming corrosives, cyanide com-
pounds, concentrated pesticides, Department of Tran-
sportation Poison "A" materials, suspected carcinogens,
and infectious substances may be known or suspected to be
involved. Field instruments may not be available to
detect or quantify air concentrations of these materials.
Unt i1 these substances are' i dent ifi ed and con cent rat ions
measured, maximum protection may be necessary.
Visible emissions: Visible air emissions from leaking
containers or railroad/vehicular tank cars, as well as
smoke from chemical fires and others, indicate high
potential for concentrations of substances that could be
extreme respiratory or skin hazards.
Job functions: Initial site entries are generally walk-
throughs in which instruments and visual observations
are used to make a pre 1 imi na ry eva 1 uat i on of the hazards.
In initial site entries, Level A should be worn when:
there ; s a pro,babil ity for exposure to hi gh con-
centrations of vapors, gases, or particulates.
substances are known or suspected of belng extremely
toxic directly to the skin or by being absorbed.
Subsequent entries are to conduct the many activities needed
to reduce the env;'ronmenta 1 impact of the i nci dent. Level s
of Protection for later operations are based not only on data
obtained from the initial and subsequent .environmental moni-
toring, but also on the probability of contamination and ease
of decontamination.
Examples of situations where Level A has been worn are:
Excavating of soil to sample buried drums suspected of
containing high concentrations of dioxin.
Entering a cloud of chlorine to repair a value broken in a
railroad accident.
Handling and moving drums known to contain oleum.
Responding to accidents involving cyanide, arsenic, and un-
diluted pesticides.
b. The fully encapsu1a}:ing suit provides the highest degree of
protection to skin, eyes, and respiratory system if the suit
material resists chemicals during the time the suit is worn.
While Level A provides maximum protection, all suit material
may be rap; dly permeated and degraded by certa in chem; ca 1s

1-5
from extremely high air concentrations, splashes, or immersion
of boots or gloves in concentrated liquids or sludges. These
limitations should be recognized when specifying the type of
fully encapsulating suit. Whenever possible, the suit
material should be matched with the substance it is used
to protect against.
,8. Level B Protection
1. Personnel protective equipment
Supplied-air respirator (MSHA/NIOSH approved).
Respirators may be:
-- pressure-demand, self-contained breathing apparatus
or
-- pressure-demand, airline respirator (with escape bottle
for IDLH or potential for IDLH atmosphere)
- Chemical-resistant clothing (overalls and long-sleeved
jacket; hooded, one or two-piece chemical-splash suit;
disposable chemical-resistant~ one-piece suits)
Long cotton underwear*
- Coveralls*
Gloves (outer), chemical-resistant
Gloves (inner), chemical-resistant
- Boots (outer), chemical-resistant, steel toe and shank
Boot covers (outer), chemical-resistant (disposable)*
- Hard hat (face shield)*
2-Way radio communications* (intrinsically safe)
2. Criteria for selection
Meeting anyone of these criteria warrants use of Level B
protection:
- The type and atmospheric concentration of toxic substances
has been identified and requires a high level of respira-
tory protection, but less skin protection than Level A.
These would-be atmospheres:

*Optional

I-6
with concentrat ions Immedi ately Dangerous to life and
Health, but subst~rice or concentration in the air
does not represent a severe skin hazard
or
that do not meet the selection criteria permitting the
use of air-purifying respirators.

- The atmosphere contains less than 19.5% oxygen.


It is highly unlikely that the work being done will generate
high concentrations of vapors, gases or particulates, or
splashes of material that will affect the skin of personnel
wearing Level B protection.
- Atmospheric concentrations of unidentified vapors or gases
are indicated by direct readings on instruments such
as the FlO or P10 or simil ar instruments, but vapors and
gases are not suspected of containing high levels of
chemicals toxic to skin. (See Appendixes I and II.)
3. Guidance on selection
a. Level B does not afford the maximum skin (and eye) pro-
tection as does a fully encapsulating suit since the,
chemical-resistant clothing is not considered gas, vapor,
or particulate tight. However, a good quality, hooded,
chemical-resistant, one-piece garment, with taped wrist,
ankles, and hood does provides a reasonable degree of
protection against 'splashes and to lower concentrations in
air. At most abandoned hazardous waste sites, ambient
atmospheric gas or vapor levels have not approached concen-
trations sufficiently high to warrant Level A protection.
In all but' a few ci rcumstances (where hi ghly toxic mater-
ials are suspected) Level B should provide the protection
needed for initial entry. Subsequent operations at a site
require a reevaluation of Level B protection based on the
probability of being' splashed by chemicals, their effect
on the skin, the presence of hard-to-detect air contaim-
inants, or the generation of highly toxic gases, vapors,
or particulates, due to the work being done. '
b. The chemical-resistant clothing required in Level B is
available in a wide variety of styles, materials, construc-
tion detail, and permeability. One or two-piece garments
are available with or without hoods. Disposal suits with
a variety of fabrics and design characteristics are also
available. Taping joints between the gloves, boots and
suit, and between hood and respirator reduces the pos-
sibl ity for splash and vapor or gas penetration. These

I-7
factors and other selection criteria all affect the degree
of protection afforded. Therefore, a specialist should
select the most effective chemical-resistant clothing
based on the known or anticipated hazards and job function.
Level B equipment does provides a high level of protection
to the respiratory tract. Generally, if a self-contained
breathing apparatus is required for respiratory protection,
selecting chemical-resistant clothing (Level B) rather than
a fully encapsulating suit (Level A) is based on needing
less protection against known or anticipated substances
affecting the skin. Level B skin protection is selected
by:
- Comparing the concentrations of known or identified
substances in air with skin toxicity data.
- Determining the presence of substances that are destr~c­
the to or readily absorbed through the skin by liquid
splashes, unexpected high levels of gases, vapor, or
particulates, or other means of direct contact.
- Assessi ng the effect of the substance (at its measured
air concentrations or potential for splashing)" on the
small areas left unprotected by chemical-resistant
clothing. A hooded garment taped .to the mask, and
boots and gloves taped to the suit further reduces area
of exposure.
c. For initial site entry and reconnaissance at an open site,
approaching whenever possible from upwind, level B protec-
tion (with good quality, hooded, chemical-resistant cloth-
ing) should protect response personnel, providing the
conditions described in selecting level A are k.nown or
judged to be absent.
C. level C Protection
1. Personnel protective equipment
- Air-purifying respirator, full-face, can·ister-equipped
(MSHA/NIOSH approved)
- Chemical-resistant clothing (coveralls; hooded, one-piece
or two-piece chemical splash suit; chemical-resistant hood
and apron; disposable chemical-resistant coveralls)
- Coveralls*
- Long cotton underwear*
- Gloves (outer), chemical-resistant

I-8
- Gloves (inner), chemical-resistant*
- Boots (outer), chemical-resistant, steel toe and shank
- Boot covers (outer), chemical-resistant (disposable)*
- Hard hat (face shield*)
- Escape mask*
- 2-Way radio communications* (inherently safe)
2. Criteria for selection
Meeting all of these criteria permits use of Level C protec-
tion:
- Oxygen concentrations are not less than 19.5% by volume.
- Measured air concentrations of identified substances will
be reduced by the respirator below the substance's thres-
hold limit value (TLV) and the concentration is within
the serVice limit of the canister.
- Atmospheri c contami nant concent rati ons do not exceed IDLH
levels.
- Atmospheric contamin~nts, liquid splashes, or other
direct contact will not adversely affect any body area
left unprotected by chemical-resistant clothing.
Job functions do not require self-contained breathing
apparatus.
Oi rect readi ngs are a few ppms above background on i n-
struments such as the FID or PIO. (See Appendices I and
II. )

.3. Guidance on selection


a. Level C protection is distinguished from Level B by the
equipment used to protect the respiratory system, assuming
the same type of chemical-resistant clothing is used. The
main selection criterion for Level C is that conditions
permit wearing air-purifying respirators. .
The a; r- pur; fyi ng devi ce must be a full-face respi rator
(MSHA/NIOSH approved) equipped with a canister suspended
from the chin or on a harness. Canisters must be able to

*Opt i ona 1

I-9
remove the substances encountered. Quarter-or hal f-masks
~r cheekcartridge, full-face masks should be used only
with the approval of a qualified individual.
In addition, a full-face, air-purifying mask can be used
only if:
Substance has adequate warning properties.
Individual passes a qualitative fit-test for the mask.
- Appropriate cartridge/canister is used, and its service
limit concentration is not exceeded.
b. An air surveillance program is part of all response opera-
tions when atmospheric contamination is known or suspected.
It is particularly important that the air be thoroughly
monitored when personnel are wearing air-purifying respira-
tors. Per; odi c survei 11 ance usi ng di rect-read; ng ; nstru-
ments and ai r sampl i ng is needed to detect any changes in
air quality necessitating a higher level of respiratory
protection.
c. Level C protection with a full-face, air-purifying respi-
rator should be worn routinely in an atmosphere only after
the type of air contaminant is identified, concentrations
measured and the criteria for wearing air-purifying respi-
rator met. To permit flexibility in precrib;ng a Level of
Protection at certain environmental incidents, a specialist
could consider using air-purifying respirators in uni.den-
tified vapor/gas concentrations of a few parts per million
above background as indicated by a needle deflection on the
FlO or PIO. However a needle deflection of a few parts per
million above background should not be the sale criterion
for selecting Level· C. Since the individual components may
never be completely identified, a decision on continuous
wearing of Level C must be made after assessing all safety
considerations, including:
- The presence of (or potential for) organic or inorganic
vapors/gases against which a canister, is ineffective or
has a short service life.
The known (or suspected) presence in air of substances
with low TLVs or IOLH levels.
The presence of particulates in air.
- The errors associ ated with both the instruments and
monitorin~procedures used.
*Opti anal

1-10
The presence of (or potential for) substances in air
which do not el icit a response on the instrument
used.
The potential for higher concentrations in the ambient
atmosphere or in the air adjacent to specific site
operations.
d. The continuous use of air-purifying respirators (Level C)
must be based on the identification of the substances
contributing to the total vapor or gas concentration and
the application of published criteria for the routine use
of air-purifying devices. Unidentified ambient concen-
trations of organic vapors or gases in air approaching or
exceeding a few ppm above background require, as a mini-
mum, Level B protection.
D. Level 0 Protection
1. Personnel protective equipment
- Coverall s
- Gloves*
- Boots/shoes, leather or chemical-resistant, steel toe and
shank
- Safety glasses or chemical splash goggles*
- Hard hat (face shield)*
2. Criteria for selection
Meeting any of these criteria allows use of Level 0 protection:
- No contaminants are present.
Work functions preclude splashes, irTll1ersion, or potential
for unexpected inhalation of any chemicals.
Level 0 protection 1s primarily a work uniform. It can be
worn only in areas where there is no possibility of
contact with contamination.

III. PROTECTION IN UNKNOWN ENVIRONMENTS


In all incident response, selecting'the appropriate personnel pro-
tection equipment ;s one of the first steps in reducing health
effects from toxic substances. Until the taxies hazards at an
environmental incident can be ident1fied and personnel safety measures

1-11
commensurate with the hazards inst ituted, prel imi nary measures will
have to be based on experiences judgment, and professional knowledge.
One of the first concerns in evaluating an unknown situation is
atmospheric hazards. Toxic concentrations (or potential concentra-
tions) of vapors, gases, and particulates; low oxygen content explo-
sive potential and, to a lesser degree. the possibility of radiation
exposure all represent immediate atmospheric hazards. In addition to
maki ng ai r measurements to determi ne these hazards, vi sua 1 observa-
'tion and review of existing data can help determine the potential
risks from other materials.
Once immediate hazards, other than toxic substances have been elimi-
nated. the initial on-site survey and 'reconnaissance, which may
consist of more than one entry, continues. Its purpose is to further
char,cterize toxic hazards and, based on these findings, refine
preliminary safety requirements. ' As data are obtained from the
initial survey, the Level of Protection and other safety procedures
are adjusted. Initial data also provide information on which to base
further monitoring and sampling. No one method can determine a Level
of Protection in all unknown environments. Each situation must be
examined individually.

I-12
It. Arthur D. Uttle, Inc.
APPENDIX J

DOFFING PROCEDURES
(Excerpted from "Standard Operating
Safety Guidelines, It 1984, Office of
Emergency and Remedial Response,
U.S. Environmental Protection Agency)

J-l
PART 7
SITE CONTROL .. DECONTAMINATION

I. INTRODUCTION
Personnel responding to hazardous substance incidents may become
contaminated in a number of ways including:
.. Contacting vapors, gases, mists, or particulates in the air.
Being splashed by materials while sampling or openin! containers.
- Walking through puddles of liquids or on contaminated soil.
Using contaminated instruments or equipment.
Protective clothing and respirators help prevent the wearer from
becoming contaminated or inhaling contaminants; while good work
practices help reduce contamination on protective clothing, instru-
ments, and equipment.
Even with these safeguards, contami nat i on may occur. Hannfu 1 mate-
rials can be transferred into clean areas, exposi.ng unprotected
personnel. In removing contaminated clothing, personnel may contact
contaminants on the clothing or inhale them. To prevent such occur-
rences, methods to reduce contamination, and decontamination proced-
ures must be developed and established before anyone enters a site
and must cont i nue (modifi ed when necessa ry) throughout site opera ..
tions.
Decontamination consists of physically removing contaminants or
changing their chemical nature to innocuous substances. How extensive
decontami nat; on must be depends on a number of factors, the most
important being the type of contaminants involved. The more harmful
the contaminant, the more extensive and thorough decontamination must
be. Less harmful contaminants may require less decontamination.
Combining decontamination, the correct method of doffing personnel
protective equpment, and the use of site work zones minimizes cross-
contami nat i on from protect i've cloth; ng to wearer t equi pment to
personnel, and one area to another. Only general guidance can be
given on methods and techniques for decontamination. The exact
procedu re to use must be determi ned after eva 1uat i ng a number of
factors specific to the incident.

II. PRELIMINARY CONSIDERATIONS


A. Initial Planning

J-2
The initial decontamination plan assumes all personnel and equip-
ment leaving the Exclusion Zone (area of potential contamination)
are grossly contaminated. A system is then set up for personnel
decontami nat; on to wash and ri nse, at 1east once, all the pro-
tective equipment worn. This is done in combination with a
sequential doffing of protective equipment, starting at the first
stat i on with the most heavily contami nated item and progress i n9
to the last station with the least contaminated article. Each
piece precedure requires a separate station.
The spread of contaminants during the washing/doffing process is
further reduced by separating each decontamination station by a
minimum of 3 feet. Ideally, contamination should decrease as a
person moves from one station to another further along in the
1; ne •

. While planning site operations. methods should be developed to


prevent the contamination of people and equipment. For example,
USing remote sampling techniques, not opening containers by hand,
bagging monitoring instruments. using drum grapplers, watering
down dusty areas. and not wa 1k.ing through areas of obvi ous con-
tamination would reduce the probability of becoming contaminated
and require a less elaborate decontamination procedure.
The initial decontamination plan is based on a worst-case situ-
ation or assumes no information 1s available about the incident.
Specific conditions at the site are then evaluated. including:
- Type of contaminant.
- The amount of contamination.
- Levels of protection required.
- Type of protective clothing worn.
The initial decontamination plan is modified, eliminating unneces-
sary stations or othe~ise adapting it to site conditions. For
instance. the initial plan might require a complet:e wash and
rinse of chemical protective garments. If disposable garments
are worn, the wash/rinse step could be omitted. Wearing dis-
posable boot covers and gloves could eliminate washing jnd
rinsing these items and reduce the number of stations needed.
B. Contamination Reduction Corridor
An area within the Contamination Reduction Zone is designated the
Contamination Reduction Corridor (eRe). The eRe controls access
into and out of the Exclusion Zone and confines decontamination
activities to a limited area.' The size of the corridor depends
on the number of stations in the decontamination procedure,

1-3
------""""~.~~--=-.-.--...--..-------------------...

r----- - -- - ----,
t I EXCLUSION
~ HEAVY EQUIPMENT I
I DECONTAMINATION:
ZONE
I AREA I
I • I EXIT
I ___ - - - _______ ...1I
1. PATH

-.-- II - - I I - I I - - Q c o - - II--IC---a ___ • ___ ._

CONTAMINATION
REDUCTION
ZONE

LEGEND
_ _ • HOTI.INE
_ . CONTAMINATION
CONTROL LINE
to\ ACCESS CONTROl.
'0' POINT. EXTRANCE
CE:J ACCESS CONTROl.
POINT· EXIT

-0_ oG-o-S-o o---.~o __ ~~_. ___ • .---0---0-0_0_


~-.-.------.,
t I
r---------.. I
: DRESSOUT I I REDRESS :
I AAEA I

SUPPORT
ZONE
L._---r--_J I AREA I
'I - - _______ ..II

ENTRY
PATH

CONTAMINATION REDUCTION ZONE UYOUT


FIGURE T·1

J-4
overall dimensions of work control zones, and amount of space
available at the site. A corridor of 75 feet by 15 feet should
be adequate for full decontamination. Whenever possible, it
should be a straight path.
The CRC boundaries should be conspicuously marked, with entry and
exit restricted. The far end is the hotline - the boundary
between the Exclusion Zone and the Contamination Reduction Zone.
Personnel exit 1ng the Excl usi on Zone must go through the CRe.
Anyone in the CRe should be wearing the Leliel of Protection
designated for the decontamination crew. Another corridor may be
required for heavy equipment needing decontamination. Within the
CRC, distinct areas. are set aside for decontamination of person-
nel, portable field equipment, removed clothing, etc. These
areas should be marked and personnel restricted to those wearing
the appropriate Level of Protection. All activities within the
corridor are confined to decontamination.
Personnel protective clothing, respirators, monitoring equipment,
and sampling supplies are all maintained outside of the CRee
Personnel don thei r protective equipment away from the CRC and
enter the Exclusion Zone through a separate access control point
at the hotline.

III. EXTENT OF DECONTAMINATION REQUIRED


A. Modifications of Initial Plan
The ori 9i nal decontami nati on plan lIIust be adapted to spec1 f1 c
conditions found at incidents. These conditions may require more
or 1ess personnel decontami nat 1on than planned, depend; ng on a
n·umber of factors.
1. Type of Contaminant
The extent of personnel decontamination depends on the effects
the contami nants have on the body. Contami nants do not ex-
hibit the same degree ~f toxicity (or other hazard). When-
ever it is known or suspected that personnel can become
contaminated with highly toxic or skin-destructive substances,
a full decontamination procedure should be followed. If less
hazardous materials are involved. the procedure can be down-
graded.
2. Amount of Cont~inat1on
'.
The amount of contamination on protective clothing is usually
determined visually. If it is badly contaminated, a thorough
decontamination is generally required. Gross material remain-
ing on the protective clothing for any extended period of
time may degrade or permeate it. This likelihood increases

J-S
with higher air concentrations and greater amounts of liquid
contamination. Gross contamination also increases the proba-
bility of personnel contact. Swipe tests may help determine
the type and quantity of surface contaminants.
l. Level of Protection
The Level of Protection and specific pieces of clothing worn
determine on a preliminary basis the layout of the decontamin-
ation line. Each Level of Protection incorporates different
problems in decontamination and doffing of the equipment. For
exampl e: decontami nat ion of the harness straps and backpack
assembly of the sel f-contai ned breathi n9 apparatus is di f.
ficult. A butyl rubber apron worn over the harness makes
decontamination easier~ Clothing variations and different
Levels. of Protection may require adding or deleting stations
in the original decontamination procedure.
4. Work Function
The work each person does determines the potential for contact
with hazardous materials. In turn, this dictates the layout
of the decontamination· line. For example, observers, photo-
graphers. operators of air samplers, or others in the Ex-
clusion Zone performing tasKs that will not bring them in
contact with contaminants may not need to have their garments
washed and rinsed. Others in the Exclusion Zone with a
potential for direct contact with the hazardous material will
require more thorough decontamination. Different decontamin-
ation lines could be set up for different job functions. or
certain stations in a line could be omitted for personnel
performing certain tasks.
5. Location of Contamination
Contamination on the upper areas of protective clothing poses
a greater risk to the worker because volatile compounds may
generate a hazardous breathi ng concentrat i on both for the
. worker and for the decontamination personnel. There is also
an increased probabl1 ity of contact with skin when doff; ng
the upper part of clothing.
6. Reason for Leaving Site
The reason for leaving the Exclusion Zone also determines the
need and extent of decontamination. A worker leaving the
Exclusion Zone to pick up or drop off tools or instruments
and immediately returning may not require decontamination. A
worker reav; ng to get a new ai r cyl i nder or to change a
respirator or canister. however. may require some degree of-
decontamination. Individuals departing the CRC for a break,
lunch, or at the end of day. must be thoroughly decontaminated.

J-6
B. Effectiveness of Decontamination
There is no method to immediately determine how effective decon-
tamination is in removing contaminants. Discolorations, stains,
corros i ve effects. and substances adheri ng to obj ects may i n-
dicate contaminants have not been removed. However, observable
effects only indicate surface contamination and not permeation
(absorption) into clothing. Also many contaminants are not
easily observed.
Amethod for determining effectiveness of surface decontamination
is swi pe test; ng. Cloth or paper patches - swi pes - are wi ped
over predetermined surfaces of the suspect object and analyzed in
a laboratory. Both the inner and outer surfaces of protect 1ve
clothing should be swipe' tested. Positive indications of both
sets of swipes would indicate surface contamination has not been
removed and substances have penetrated or permeated through the
garment. Swipe tests can also be done on skin or inside clothing.
Permeation of protective garments requires laboratory analysis of
a pi ece of the materi a1• Both sw; pe and permeat i on test i n9
provide after-the-fact information. Along with visual obser-
vations, results of these tests can help evaluate the effec-
tiveness of decontamination.
C. Equipment
Decontamination equipment, materials, and supplies are generally
selected based on availability. Other considerations are ease of
equi pment decontami nat i on or di sposab111ty. Most equ i pment and
supplies can be easily procured. For example, soft-bristle scrub
brushes or 1ong-handl e brushes are used to remove contami nants.
Water 1n buckets or garden sprayers is used for rinSing. Large
ga hani zed wash tubs or stocle tanks can hold wash and ri nse
solutions. Children's wadi'ng pools can also be used. Large
plastic garbage cans or other similar containers lined with
plastic bags store contaminated clothing and equipment. Contam-
inated liquids can be stored .temporarily in metal or plastic cans
or drums. Other gear includes paper or cloth towels for drying
protective clothing and equipment.
O. Decontamination Solution
Personnel protective equipment. sampling tools, and other equip-
ment are usually decontaminated by scrubbing with detergent-water
using a soft-bristle brush followed by rinSing with copious
amounts of water. While this process may not be fully effective
in removing some contaminants (or in a few cases, contaminants
may react with water). it is a relatively safe option compared
with using a chemical decontaminating solution. This requires
that the contami nant be i denti fi ed. A decon chemi ca 1 1s then
needed that will change the contaminant into a less harmful
substance. EspeCially troublesome are unknown substances or

J-7
mi xtures from a var1 ety of known or unknown substances. The
appropriate decontamination solution must be selected in consul.
tation with an experienced chemist.
E. Establishment of Procedures
Once decontamination procedures have been established, all person-
nel requiring decontamination must be given precise instructions
(and practice, 1f necessary). Compliance must be frequently
checked. The time it takes for decontamination must be ascer-
tained. Personnel wearing SCBA's must leave their work area with
sufficient air to walk. to CRe and go through decontaminat'ion.

IV. DECONTAMINATION DURING MEDICAL EMERGENCIES


A. Basic Considerations
Part of overall planning for incident response is managing medical
emergencies. The plan should provide for:
- Some response team members fully trained in first aid and CPR.
- Arrangements with the nearest medical -facility for transporta.
tion and treatment of injured, and for treatment of personnel
suffering from exposure to chemicals.
• Consultation services with a toxicologist.
- Emergency ey'e washes, showers, and/or wash stat ions.
- First aid k.its, blankets, stretcher, and resuscitator.
In addition, the plan should establish methods for decontaminating
personnel with medical problems and injuries. There is the
possibility that the decontamination may aggravate or cause more
serious health effects. If prompt life-saving first aid and
medical treatment is required, decontamination procedures should
be omitted. Whenever pOSSible, response personnel should accom-
pany contami nated vi ct ims to the medi ca 1 facil ity to advi se on
matters involving decontamination.
B. PhYSical Injury
Physical injuries can range from a sprained ankle to a compound
fracture, from a minor cut to massive bleeding. Depending on the
seri ousness of the injury, treatment may be gi ven at the site by
trained response personnel. For more serious injuries, additional
ass istance may be requi red at the site or the vi ct im may have to :
be treated at a medical facility.

J-8
Life-saving care should be instituted immediately without consid-
ering decontamination. The outside garments can be removed
(depending on the weather) if they do not cause delays, interfere
with treatment, or aggravate the problem. Respirators and back-
pack assemblies must always be removed. Fully encapsulating
suits or chemi cal-resi stant cl oth1 ng can be cut away. If the
outer contaminated garments cannot be safely removed, the individ-
ual should be wrapped in plastic, rubber. or blankets to help
prevent contaminating the inside of ambulances and medical person-
nel. Outsi de garments are then removed at the medi ca 1 1'ac11 ity.
No attempt should be made to wash or rinse the victim at the
site. One exception would be if it is known that the individual
has been contaminated with an extremely toxic or corrosive
material which could also cause severe injury or loss of life.
For minor medical problems or injuries. the normal decontamination
procedure should be followed.
C. Heat St ress
Heat-related 111nesses range from heat fatigue to heat stroke,
the most serious. Heat stroke requires prompt treatment to
prevent irreversible damage or death. Protective clothing may
have to be cut off. Less serious forms of heat· stress requi re
prompt attention or they may lead to a heat stroke. Unless the
victim is obviously contaminated. decontamination should be
omitted or minimized and treatment begun immediately.
D. Chemical Exposure
Exposure to chemicals can be divided into two categories:
Injuries from direct contact. such as acid burns or inhalation
of toxic chemicals.
- Potential injury due to gross contamination on clothing or
equipment.
For inhaled contaminants treatment can only be by qualified
physicians. If the contaminant is on the skin orin the eyes,
1nmed1 ate measures must be taken to counteract the substance s I

effect. First aid treatment usually is flooding the affected


area with water; however. for a few chemi eals. water may cause
more severe problems.
When protective clothing is grossly contaminated. contaminants
may be transferred to treatment personnel or the wearer and
cause injuries. Unless severe med1cal problems have oceurreU
simul taneously with splashes the protective clothing shoul d be
I

washed off as rapidly as possible and carefully removed.

J-9
V. PROTECTION FOR DECONTAMINATION WORKERS
The Level of Protection worn by decontamination workers is determined
by:
- Expected or visible contamination on workers.
- Type of contami nant and assoc i ated resp i ratory and sic i n hazards.
- Total vapor/gas concentrations in the CRC.
- Particulates and specific inorganic or organic vapors in the CRC.
- Results of swipe tests.
A. Level C Use
Level C includes a full-face, canister-type air-purifying
respirator. hard hat with face shield (if splash is a problem).
chemical-resistant boots and gloves. and protective clothing.
The body covering recommended is chemical.resistant overalls with
an apron, or chemical-resistant overalls and jacket.
A face shield is recommended to protect against splashes because
respirators alone may not provide this protection. The respirator
should have a canister approved for filtering any specific known
contami nants such as ammoni a • organi c vapors. aci d gases. and
part i cu 1ates.
B. Level B Use
In situations where site workers may be contaminated with un-
knowns. highly volatile" liquids, or highly toxic materials,
decontamination workers should wear Level B protection.
Level B protection includes SCBA, hard hat with face shield.
chemical-resistant gloves, and protective covering. The clothing
suggested is chemical-resistant overalls. jacket. and a rubber
apron. The rubber apron protects the SCBA harness assembly and
regulator from becoming contaminated.

VI. DECONTAMINATION OF EQUIPMENT


Insofar as possible, measures should be taken to prevent contamination
of sampling and monitoring equipment. Sampling devices become con-
taminated. but monitoring instruments, unless they are splashed.
usually do not. Once contaminated. instruments are difficult to
clean without damaging them. Any delicate instrument which cannot be'
easily decontaminated should be protected while it is being used. It

J-10
should be placed in a clear plastic bag, and the bag taped and secured
around the instrument. Openings are made in the bag for sample
intake.
A. Decontamination Procedures
1. Sampling devices
Sampling devices require special cleaning. The EPA Regional
Laboratories can provide information on proper decontamination
lllethads.
2. Tools
Wooden tools are difficult to decontaminate because they
absorb chemicals. They should be kept on site and handled
only by protected workers. At the end of the response,
wooden tools should be discarded. For decontaminating
other tools, Regional Laboratories should be consulted.
3. Respi rators
Certain parts of contaminated respirators, such as the harness
assembly and leather or cloth components. are difficult to
decontaminate. If grossly contaminated. they may have to be
discarded. Rubber components can be soaked 1n soap and water
and scrubbed with a brush. Regulators must be mai ntai ned
according to manufacturer's recommendations. Persons respon-
sible for decontaminating respirators should be thoroughly
trained in respirator maintenance.
4. Heavy Equipment
Bulldozers, trucks, back-hoes, bulking chambers. and other
heavy equipment are di tfi cult to decontami nate. The method
generally used 1s to wash them with water under high pressure
and/or to scrub accessible parts with detergent/water solution
under pressure. if possible. In some cases, shovels, scoops,
and l1fts have been sand blasted or steam cleaned. Particular
care must be given to those components 1n direct contact ~ith
contaminants such as tires and scoops. Swipe tests should be
utilized to measure effectiveness.
B. Sanitizing of Pe.rsonnel Protective Equipment
Respirators, reusable protective clothing, and other personal
articles not only must be decontaminated before being reused, but
also sanitized. The inside of masks and clothing becomes soiled
due to exhalation, body oils. and perspiration. The manufac.
turer's instructions should be used to sanitize the respirator
mask. If practical protective clothing should be machine washed
I

after a thorough decontamination; otherwise it must be cleaned by


hand.

J-H
C. Persistent Contamination
In some instances, clothing and equipment will become contamin-
anted with substances that cannot be removed by normal decontamin-
ation procedures. A solvent may be used to remove such contamin-
ation from equipment if it does not destroy or degrade the pro-
tective material. If persistent contamination is expected,
disposable garments should be used. Testing for persistent
contamination of protective clothing and appropriate decon-
tamination must be done by qualified laboratory personnel.
O. D·i sposa 1 of Contami nated Materi als
All materials and equipment used for decontamination must be
disposed of properly. Clothing. tools, buckets. brushes, and
all other equipment that is contaminated must be secured in drums
or other contai ners and label ed. Cl othi ng not compl etely decon-
taminated on-site should be secured in plastic bags before being
removed from the site.
Contaminated wash and rinse solutions should be contained by
using step-in-containers (for example, child's wading pool) to
hold spent solutions. Another containment method is to dig a
trench about 4 inches deep. and line tt with plastic. In both
cases the spent sol uti ons are transferred to drums, wh; ch are
labeled and disposed of with other substances on Site.

VII. ANNEXES
Annex 1. 2. and 3 descri be bas i c decontami nat i on procedu res for a
worker wearing Level A. 8. or C protection. The basic decontamination
lines (Situation 1), consisting of approximately 19 stations, are
almost identical except for changes necessitated by different pro-
tective clothing or respirators. For each annex, three specific
situations are described in which the basic (or full decontamination)
procedure is changed to take into account di fferences in the extent
of contami nat ion, the accompany; ng changes in equi pment worn and
I

other factors. The situations illustrate decontamination setups


based on known or assumed conditions at an 1ncident~ Many other
variations are possible.
Annex 4 describes a minimum layout for Level A personnel decontamin-
ation. The number of individual stations have been reduced. Although
the decontamination equipment and amount of space required is less
than needed in the procedures previously described. there is also a
much higher probability of cross.contamination.

J-12
ANNEX 1
LEVEL A DECONTAMINATION

A. EQUIPMENT WORN
The full decontamination procedure outlined is for workers wearing
Level A protection (with taped joints between gloves, boots. and
suit) consisting of:
- Fully encapsulating suit.
- Self-contained breathing apparatus.
- Hard hat (optional).
- Chemical.resistant. steel toe and shank boots.
• Boot covers.
Inner and outer gloves,

B. PROCEDURE FOR FULL DECONTAMINATION


Station 1: Segregated Equipment Drop
Deposit equipment used on-site (tools, sampling devices and containers.
monitoring instruments. radios, clipboards, etc.) on plastic drop
cloths or in different containers with plastic liners, Each will be
contaminated to a different degree. Segregation at the drop reduces
the probability of cross-contamination.
Equipment: various size containers
plast i c 1i ners
plastic drop cloths
Station 2: Boot Cover and Glove Wash
Scrub outer boot covers and gloves with decon solution or detergent/
water.
Equipment: container (20-30 gallons)
decon solution
or
detergent water
2-3 long-handle. soft-bristle scrub brushes

J-13
Station 3: Boot Cover and Glove Rinse
Rinse off decon solution from Station 2 uSing copious amounts of
water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
or
high-pressure spray unit
water
2-3 long-handle. soft.bristle scrub brushes
Station 4: Tape Removal
Remove tape around boots and gloves and deposit in container with
plastic liner.
Equipment: container (20-30 gallons)
plastic liners
Station 5: Boot Cover Removal
Remove boot covers and deposit in container with plastic liner.
Equipment: container (30-50 gallons)
plastic liners
bench or stool
Station 6: Outer Glove Removal
Remove outer gloves and deposit in container with plastic liner.
Equipment: container (20-30 gallons)
plastic liners
Station 7: Suit/Safety Boot Wash
Thoroughly wash fully encapsulating suit and boots. Scrub suit
and boots with long-handle, soft-bristle scrub brush and copious
amounts of decon solution or detergent/water. Repeat as many
times as necessary.
Equipment: container (30-50 gallons)
decon solution
or
detergent/water
2-3 long-handle. soft.bristle scrub brushes

J-14
Station 8: Suit/Safety Boot Rinse
Rinse off decon solution or detergent/water using copious amounts
of water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
or
hi9h~pressure spray unit
water
2-3 long handle, soft-bristle scrub brushes
Station 9: Tank Change
If worker leaves Exclusion Zone to change air tank, this is the
last step 1n the decontamination procedure. Worker's air tank is
exchanged. new outer gloves and boots covers donned, and jOints
taped. Worker then returns to duty.
Equipment: air tanks
tape
boot covers
gloves
Station 10: Safety Boot Removal
Remove safety boots and deposit 1n container with plastic liner.
Equipment: container (30-50 gallons)
plastic liners
bench or stool
boot jack
Station 11: Fully Encapsulating Suit and Hard Hat Removal
With assistance of helper, remove fully encapsulating suit (and
hard hat). Hang suits on rack or layout on drop cloths.
Equipment: rack
drop cloths
bench or stool
Station 12: SC8A Backpack Removal
While still wearing facepiece, remove backpack and place on table.
Disconnect hose from regulator valve and proceed to next station •.
Equipment: table

J-15
Station 13: Inner Glove Wash
Wash with decon solution or detergent/water that will not harm
skin. Repeat as many times as necessary.
Equipment: basin or bucket
decon solution
or
detergent/water
sma 11 tabl e
Station 14: Inner Glove Rinse
Rinse with water. Repeat as many times as necessary.
Equipment: water basin
basin or bucket
small tabl e
Station 15: Facep;ece Removal
Remove facepiece. Deposit in container with plastic liner. Avoid
touching face with fingers.
Equipment: container (30-50 gallons)
plastic; liners
Station 16: Inner Glove Removal
Remove inner gloves and ~eposit in container with plastic liner.
Equipment: container (20-30 gallons)
plas t 1c li ne rs
Station 17: Inner Clothing Removal
Remove clothing soaked with perspiration. Place in container with
plastic liner. Inner clothing should be removed as soon as possible
since there is a possibility that small amounts of contaminants might
have been transferred in removing fully encapsulating suit.
Equipment: container (30-50 gallons)
plastic 1iners
Station 18: Field Wash
Shower if highly toxic. Skin-corrosive or skin.absorbable materials
are known or suspected to be present. Wash hands and face if shower
is not available.

J-16
Equipment: water
soap
sma 11 table
basin or buclcet
field showers
towel s
Station 19: Redress
Put on clean clothes. A dressing trailer is needed in inclement weather.
Equipment: tables
chai rs
lockers
clothes

c. FULL DECONTAMINATION (SIT. 1) AND THREE MODIFICATIONS

S STATION NUMBER
I
T
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19

1 X X X X X X X X X X X X X X X X X X

2 X X X X X X X X X
3 X X X X X X X X X X

4 X X X X

Situation 1: The individual entering the Contamination Reduction


Corrldor 1S observed to be grossly contaminated or extremely toxic
substances are known or suspected to be present.
Situation 2: Same as Situation 1 except individual needs new air tank
and w111 return to Exclusion Zone.

J-17
Situation 3: Individual entering the eRe is expected to be minimally
contaminated. Extremely toxic or skin-corrosive materials are not
present. No outer gloves or boot covers are worn. Inner gloves are
not contaminated.
Situation 4: Same as Situation 3 except individual needs new air tank
and w,11 return to Exclusion Zone.

J-18
ANNEX 2
LEVEL B DECONTAMINATION

A. ' EQJIPMENT WORN


The full decontamination procedure outlined is for workers wearing
Level B protection (with taped joints between gloves. boot, and suit)
consisting of:
- One-piece, hooded, chemical-resistant splash suit.
Self-contained breathing apparatus.
- Hard hat.
Chemical-resistant, steel toe and shank boots.
- Boot covers
Inner and outer gloves.

B. PROCEDURE FOR FULL DECONTAMINATION


Station 1~ Segregated Equipment Drop
Deposit equipment used on-site (tools, sampling devices and containers.
monitoring instruments, radios, clipboards, etc.) on plastic drop
cloths or in different containers with plastic liners. Each will be
cont.aminated to a different degree. Segregation at the drop reduces
the probability of cross-contamination.
Equipment: various size containers
plastic liners
plastic drop cloths
Station 2: Boot Cover and Glove Wash
Scrub outer boot covers and gloves with decon solution or detergent/,
water.
Equipment: container (20-30 gallons)
decon 'sol ut i on
or
detergent water
2-3 long-handle. soft-bristle scrub brushes

J-19
Station 3: Boot Cover and Glove Rinse
Rinse off decon solution from Station 2 using copious amounts of
water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
or
high-pressure spray unit
water
2.3 long-handle, soft.bristle scrub brushes
Station 4: Tape Removal
Remove tape around boots and gloves and deposit in container with
plastic liner.
Equipment: container (20-30 gallons)
plastic liners
Station 5: Boot Cover Removal
Remove boot covers and deposit in container with plastic liner.
Equipment: container (30-50 gallons)
plastic liners
bench or stool
Station 6: Outer Glove Removal
Remove outer gloves and deposit in container with plast1c liner.
Equipment: container (20-30 gallons
plastic liners
Station 7: Suit/Safety Boot Wash
Thoroughly wash chemical-resistant splash suit, SCBA, gloves. and
safety boots. Scrub with long-handle, soft-bristle scrub brush
and copious amounts of decon solution or detergent/water. Wrap
SCBA regulator (if belt-mounted type) ·with plastic to keep out
water. Wash backpack assembly with sponges or cloths.
Equipment: container (30-50 gallons)
decon solution
or
detergent/water
2-3 long-handle. soft-bristle scrub brushes
small buckets
sponges or cloths

1-20
Station 8: Suit/SCBA/Boot/Glove Rinse
Rinse off decon solution or detergent/water uSing copious amounts
of water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
or
high-pressure spray unit
water
small buckets
2-3 long-handle, soft-bristle scrub brushes
sponges or cloths
Station 9: Tank Change
If worker leaves Exclusion Zone to change air tank, this is the last
step in the decontamination procedure. Worker's air tank is
exchanged. new outer gloves and boots covers donned, and joints
taped. Worker returns to duty.
Equipment: air tanks
'tape
boot covers
gloves
Station 10: Safety Boot Removal
Remove safety boots and deposit 1n container with plastic liner.
Equipment: container (30-50 gallons)
plast; c 11 ners
bench or stoo 1
boot jack
Station 11: SCBA Backpack Removal
While still wearing facepiece, remove backpack and place on table.
Disconnect hose from regulator valve and proceed to next station.
Equipment: table
Station 12: Splash Suit Removal
With assistance of helper, remove splash suit. Deposit in container
with plastic liner.
Equipment: container (30-50 gallons)
p'ast i c 11 ne rs
bench or stool

J-21
Station 13: Inner Glove Wash
Wash inner gloves with decon solution or detergent/water that will
not harm skin. Repeat as many times as necessary.
Equipment: decen solution
or
detergent/water
basin or bucket
small table
Station 14: Inner Glove Rinse
Rinse inner gloves with water. Repeat as many times as necessary.
Equipment: water
basin or bucket
small table
Station 15: Facepiece Removal
Remove facep1ece. Avoid touching face with gloves. Deposit in
container with plastic liner.
Equipment: container (30-50 gallons)
plastic liners
Station 16: Inner Glove Removal
Remove inner gloves and deposit in container with plastic liner.
Equipment: container (20-30 gallons)
plastic liners
Station 17: Inner Clothing Removal
Remove clothing soaked with perspiration. Place in container with
plastic liner. Do not wear inner clothing off-site since there is
a possibility small amounts of contaminants might have been
transferred in removing fully encapsulating suit.
Equipment: container (30-50 gallons)
plastic liners
Station 18: Field Wash
Shower if highly toxic, skin-corrosive, or skin-absorbable materials
are known or suspected to be present. Wash hands and face if shower
is not available.

J-22
Equipment: water
soap
small tables
basins or buckets
field showers
Station 19: Redress
Put on clean clothes. A dressing trailer is needed in 1nclement
weather.
Equipment: tables
chairs
lockers
clothes

C. FULL DECONTAMINATION (SIT. 1) AND THREE MODIFICATIONS

S STATION NUMBER
I
T
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19

1 X X X X X X X X X X . X X X X X X X X

2 X X X X X X X X X
3 X X X X X X X X X X X
4 X X X X

Situation 1: The individual entering the Contamination Reduction


Corr,dor 1S observed to be grossly contaminated or extremely toxic
substances are known or suspected to be present.
Situation 2: Same as Situation 1 except individual needs new air tank
and w,lt return to Exclusion Zone.

J-23
Situation 3: Individual entering the CRC is expected to be minimally
contamlnated. Extremely toxic or sKin-corrosive materials are not
present No outer gloves or boot covers are worn. Inner gloves are
not contaminated.
Situation 4: Same as Situation 3 except individual needs new air tank
and wlll return to Exclusion Zone.

J-24
ANNEX 3
LEVEL C DECONTAMINATION

A. EQUIPMENT WORN
The full decontamination procedure outlined is for workers wearing
Level C protection (with taped joints between gloves. boots. and
suit) consisting of:
One-piece. hooded, chemical-resistant splash suit.
Canister equipped. full-face mask.
Hard hat.
Chemical-resistant, steel toe and shank boots.
Boot covers.
Inner and outer gloves.

B. PROCEDURE FOR FULL DECONTAMINATION


Station 1: Segregated Equipment Drop
Deposit equipment used on-site (tools, sampling devices and c~ntainers.
monitoring instruments. radios, clipboards, etc.) on plastic drop
cloths or in different containers with plastic liners. Each will be
contaminated to a different degree. Segregation at the drop reduces
the probability of cross-contamination.
Equipment: various size containers
plastic liners
plastic drop cloths
Station 2: Boot Cover and Glove Wash
Scrub outer boot covers and gloves with decon solution or detergent/
water.
Equipment: container (20-30 gallons)
decon solution
or
detergent water
2-3 long-handle. soft-bristle scrub brushes

J-2S
Station 3: Boot Cover and Glove Rinse
Rinse off decon solution from Station 2 using copious amounts of
water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
or
high-pressure spray unit
water
2-3 long-handle, soft bristle scrub brushes
Station 4: Tape Removal
Remove tape around boots and gloves and deposit in container with
plastic liner.
Equipment: container (20-30 gallons)
plastic liners
Station 5: Boot Cover Removal
Remove boot covers and deposit in container with plastic liner.
Eqoipment: container (30-50 gallons)
plastic liners
bench or stool
Stltion 6: Outer Glove Removal
Remove outer gloves and deposit in contiiner with plastic liner.
·Equipment: container (20-30 gallons)
plastic liners
Station 7: Suit/Safety Boot Wash
Thoroughly wash splash suit and safety boots. Scrub with long-
handle. soft-bristle scrub brush and copious amounts of decon
solution or detergent/water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
decon solution
or
detergent/water
2-3 long-handle. soft-bristle scrub brushes
Station 8: Suit/Safety Boot Rinse

J-26
Rinse off dec on solution or detergent/water using copious amounts
of water. Repeat as many times as necessary.
Equipment: container (30-50 gallons)
or
high-pressure spray unit
water
2-3 long-handle, soft-bristle scrub brushes
Station 9: Canister or Mask Change
If worker leaves Exclusion Zone to change canister (or mask). this
is the last step in the decontamination procedure. Worker1s canister
is exchanged, new outer gloves and boots covers donned, and joints
taped. Worker returns to duty.
Equipment: canister (or mask)
tape
boot covers
gloves
Station 10: Safety Boot Removal
Remove safety boots and deposit in container with plastic liner.
Equipment: container (30-50 gallons)
plastic liners
bench or stool
boot jack
Station 11: Splash Suit Removal
With assistance of helper, remove splash suit. Deposit in container
with plastic liner.
Equipment: container (30-50 gallons)
bench or stool
liner
Station 12: Inner Glove Wash
Wash inner gloves with decon solution or detergent/wate~ that will
not harm skin. Repeat as many times as necessary.
Equipment: decon solution
or
detergent/water
basin or bucket

J-27
Station 13: Inner Glove Rinse
Rinse inner gloves with water. Repeat as many times as necessary.
Equipment: water
basin or bucket
small table
Station 14: Facepiece Removal
Remove hcepiece. Avoid touching face with gloves.Oeposit
facepiece in conta1ner with plastic liner.
Equipment: container (30-50 gallons)
plastic liners
Station 15: Inner Glove Removal
Remove inner gloves and deposit in container with plastic liner.
Equipment: container (20-30 gallons)
plast1 c 11 ners
Station 16·: Inner Clothing Removal
Remove clothing" soaked with perspiration. Place in container with
plastic liner. 00 not wear inner clothing off-site since there ;s
a possibility small amounts of contaminants might have been
transferred in removing splash suite.
Equipment: container (30.50 gallons)
plast i c 11 ners
Station 17: Ffe1d Wash
Shower if highly toxic, skin-corrosive or skin-absorbable materials
are known or suspected to be present. Wash hands and face if shower
is not available.
Equipment: water
soap
tables
wash basins/buckets
field showers
Station 18: Redress
Put on clean clothes. A dressing trailer is needed in inclement weather.

J-28
Equipment: tables
~hairs
lockers
~lothes

C. FULL DECONTAMINATION (SIT. 1) AND THREE MODIFICATIONS

S STATION NUMBER
I
T
1 2 3 4 5 6 1 8 9 10 11 12 13 14 15 16 17 18

1 X X X X X X X X X X X X X X X X X X
2 X X X X X X X X X
3 X X X X X X X X X
4 X X X X

Situation 1: The individual entering the Contamination Reduction Corridor


1S observed to be grossly contaminated. or extremely skin corrosive substances
are known or suspected to be present.
Situation 2: Same as Situation 1 except 1ndividual needs new canister or
mask and wl1l return to Exclusion Zone.
Situation 3: Individual entering the CRC fs expected to be minimally
contam1nated. Extremely skin-corrosive materials are not present. No
outer gloves or boot covers are worn. Inner gloves are not ·contaminated.
Situation 4: Same as Situation 3 except individual needs new canister or
mask and w111 return to Exclusion Zone.

J-29
ANNEX 4
LEVEL A DECONTAMINATION, MINIMUM LAYOUT

A. EQUIPMENT WORN
The decontamination procedure outlined is for workers wearing Level A
protection (with taped joints between gloves, boots, and suit) consisting
of:
,
Fully encapsulating suit with integral boots and gloves.
Self-contained breathing apparatus.
Hard hat (optional).
Chemical.resistant, steel toe and shank boots.
Boot covers.
Inner and outer gloves.

B. PROCEDURE FOR FULL DECONTAMINATION


Station 1: Segregated Equipment Crop
Deposit equipment used on-site (tools, sampling devices and containers,
monitoring instruments, radios, clipboards, etc.) on plastic drop
cloths or in different containers with plastic liners. Each will be
contaminated to a different degree. Segregation at the .drop reduces
the probability of cross-contamination.
Equipment: various size containers
plastic liners
plastic drop clothes
Station 2: Outer Garment, Boots, and Gloves Wash and ,Rinse
Scritb outer boots, outer gloves, and fully-encapsulating suit with
.decon solution or detergent water. Rinse off using copious amounts
of \ldiwr.
'Equipment: containers (30-50 gallons)
de,con so 1ut i on
or
'detergent water

J-30
rinse water
2-3 long-handle, soft-bristle scrub brushes

Station 3: Outer Boot and Glove Removal


Remove outer boots and gloves. Deposit in container with plastic
li nero
Equipment: container (30.50 gallons)
plasti c 11 ners
bench or stool
Station 4: Tank Change
If worker leaves Exclusion Zone to change air tank, this is the last
step in the decontamination procedure. Worker's air tank is exchanged,
new outer gloves and boot covers donned. joints taped, and worker
returns to duty.
Equipment: air tanks
tape
boot covers
gloves .
Station 5: Boot. Gloves, and Outer Garment Removal
Boots, fully-encapsulating suit, and inner gloves removed and depOSited
in separate containers lined with plastic.
Equipment: containers (30-50 gallons)
pl ast i c 11 ners
bench or stool
Station 6: SCBA Removal
SCBA backpack and facepiece is removed. Hands and face are thoroughly
washed. SCBA deposited on plastic sheets.
Equipment: plastic sheets
basin or bucket
soap and towels
bench
Station 7: Field Wash
Thoroughly wash hands and face. Shower as soon as possible.

J-31
Equipment: water
soap
tab1 es
wash basin/bucket

J·-32
Volume II: Technical and Reference Manual

Guidelines for the


Selection of Chemical
Protective Clothing
- Third Edition -

A.D. Schwope, Arthur D. Little, Inc.


P.P. Costas, Arthur D. Little, Inc.
J. O~ Jackson, Los Alamos National Laboratory
J.O. Stull, U.S. Coast Guard
D.J. Weitzman, U.S. Environmental Protection Agency

February 1987

1330 Kemper Meadow Drive


Cincinnati, Ohio 45240-4148

Prepared by: Arthur D. Little, Inc.


Cambridge, MA 02140
Sponsor: U.S. Environmental Protection Agency
U.S. Coast Guard
Prime Contractor: Los Alamos National Laboratory
DISCLAIMER

Arthur D. Little, Inc. prepared this document with what it belieevs is the best currently
available information. The document is subject to revision as additional knowledge and
experience are gained. Arthur D. Little cannot guarantee the accuracy of information used
to deelop the chemical protective clothing recommendations contained herein, and the
mention of company names or products does not constitute endorsement by Arthur D.
Little. Arthur D. Little accepts no responsibility for damages or liabilities of any kind
which may be claimed to result from the use of this document.
ACKNOWLEDGEMENTS
This Guidelines for che Selection of Chemical Protective Clothing was
prepared by Arthur D. Little, Inc. (Cambridge, Massachusetts), under
subcontract to Los Alamos National Laboratory (New Mexico) for the
U. S. Environmental Protection Agency (EPA) and the u. S. Coast Guard.
Particularly helpful in the preparation of this, the third edition of
the Guidelines were J.F. Stampfer and H.J. Ettinger (Los Alamos National
Laboratory) and Krister Forsberg. Mr. Forsberg of the Royal Institut~
of Technology (Stockholm) reviewed each line of data presented in
Appendix A of Volwne II for consistency with the original literature
sources. We also thank Dr. Douglas Walters of the National Toxicology
Program for contributing an extensive compilation of glove permeation
data generated for the NTP by the Radian Corporation.

The text, except for the addition of Chapter 5--Full-Body Protection to


Volwne I, remains essentially the same (although updated) as the first
EPA and ACGIH editions for which we note the support and review comments
of W. Aaroe, B.E. Benson, S.P. Berandinelli, R. Ellis, E.R. Hoyle, K.
Hunninen, R.F. Kent, W.F. Keffer, A.P. Nielson, R.C. Magor, M.D. Royer,
A. Smith, R.S. Stricoff, F. Thompson, R.D. Turpin, L. Walz, and R.W.
Weeks. In addition, we appreciate the assistance of encapsulating
ensemble manufacturers in the preparation of Appendix G of Volume I.

The authors also acknowledge the contributions of the Arthur D. Little


proj ect team which included William Hawes, whose programming skills
greatly facilitated the information organization task and T. Carroll.
C. Luciano, M. Rourke, and D. Ryan, who assisted us in gathering and
inputing the information. Finally, we thank the typists and report
production specialists who assembled the document.

11i
SPECIAL,NOTt.fO USERS
This document contains comprehensive tables of recommendations to aic
and facilitate the selection of chemical protective clothing (epC). lne
recommendations are based on an extensive compilation and ar.alysis c)r
e"pc vendors' literature and €'xperimenta1 test data publi shed in techni-
cal journals and reports. It is imperative that users of th~ recommen-
dution tc:bles familiarize themselves with thE backgr0und informatior.
that precedes and accompanies the tables. The selection of CPC must
take into account the potential hazard and the conci tions 'Of use - -
neither is ~onsider~d in this document. The recommendations are noc no,
do they imply a guarantee of safety.

Al though every effort has been made to prepare this document as aCCLl-
ra~ely as possible, errors can and do occur. Users of this document a~e
asked to notify Lt. Jeffrey o. Stull, Commandant (G-DMT-3), U.S. Coast
Guard. 2100 Second Street, S.W., Washington, D.C. 20593 (202-267-0853),
or Mr. David Weitzman, U.S. Environmental Protection Agency, Office of
Occupational Health and Safety, Room 3503, Waterside Mall, 401 M Street.
S.W., Washington~ D.C. 20460 (202-382-3647) of errors so that they can
be corrected.

iv '
TABLE OF CONTENTS
VOLUME II
Page
CHAPTER 1 - OBJECTIVES, LIMITATIONS AND
ASSUMPTIONS FOR THE GUIDELINES 1
A. INTRODUCTION 1
B. OBJECTIVES 1
C. LIMITATIONS 2

D. ASSUMPTIONS 3
E. INSTRUCTIONS FOR GUIDELINES USE 3
CHAPTER 2 - PERMEATION THEORY 4

A. INTRODUCTION 4

B. IDEAL PERMEATION 4

C. ANOMALOUS PERMEATION 8

D. PERSISTENT PERMEATION 9

E. CHEMICAL CLASSIFICATION AND 9


SOLUBILITY PARAMETER
CHAPTER 3 - TEST METHODS 12
A. INTRODUCTION 12
B. SOWBILITY 12
C. DEGRADATION 13
D. PERMEATION 13
E. VISIBILITY 16
F. PENETRATION 16
G. OTHER FACTORS 17

v
TABLE OF CONTENTS (CONTINUED)

Page
CHAPTER 4 - ANALYSIS OF THE VENDORS' LITERATURE 20
A. INTRODUCTION 20
B. REVIEW OF VENDORS' LITERATURE 20
C. PERSPECTIVES ON VENDORS' LITERATURE 23

D. CONCLUSION 24

CHAPTER 5 - SOURCES OF CHEMICAL PROTECTIVE 25


CLOTHING INFORMATION
A. INDUSTRY 25

B. GOVERNMENT 25

C. PROFESSIONAL ORGANIZATIONS 26

D. TECHNICAL LITERATURE 26

BIBLIOGRAPHY 28

APPENDICES - DESCRIPTION OF COLUMN HEADINGS FOR 63


APPENDICES A THROUGH E
APPENDIX A - PERMEATION DATA A-1
APPENDIX B - WEIGHT CHANGE DATA B-1
APPENDIX C - SWELLING DATA C-1
APPENDIX D - DIFFUSION COEFFICIENTS D-1
APPENDIX E - TENSILE DATA E-1
APPENDIX F - PERMEATION DATA FOR MULTI-COMPONENT F-1
LIQUIDS
APPENDIX G - VENDOR CODES FOR USE WITH DATA G-1
SUMMARIES IN APPENDICES A THROUGH E
APPENDIX H - RATIONALE FOR RECOMMENDATIONS IN H-1
MATRIX A

vi
CHAPTER 1
OBJECTIVES, LIMITATIONS, AND
ASSUMPTIONS FOR THE GUIDELINES
A. INTRODUCTION
The selection of the best chemical protective clothing (CPC) for use
against a particular chemical can be a difficult and perplexing task. A
principal reason for this situation is that the necessary information,
if any is available. has not been organized. Vendors' recommendations
tables provide guidance but there is little or no basis on which to
compare products. Technical reports of CPC performance have increased
in number in recent years. but are scattered through the literature. and
again. there is no standard format for reporting data.

The EPA's Occupational Health and Safety staff has repeatedly faced this
situation in its attempts to provide guidance to field personnel in-
volved in the clean-up of hazardous waste sites. Furthermore. the
U.S. Coast Guard has particular needs for consolidating information on
full-body protective ensembles. We. therefore. have developed this
two-volume Guidelines for the Selection of Chemical Protective Clothing.
This third edition of the Guidelines has been completely updated from
those of 1983 and 1985. The key objectives. limitations, assumptions.
and instructions for use of this publication are described in the
following paragraphs.

B. OBJECTIVES
The main objective of the Guidelines is that it be a concise. up-to-date
source for information relative to selection of personal protective
clothing. Its principal focus is clothing for protection against
chemicals which are potentially harmful to humans. More specifically,
the Guidelines addresses the chemical resistance of protective clothing
materials and the design features of full-body protective ensembles and
splash suits. The Guidelines is designed to:

• Educate (or review for) the user the technical concepts


associated with the chemical resistant clothing. The goal is
to provide the Guidelines user the background necessary to
make the best possible decisions relative to selecting ar..d
using CPC.

• Bring together and compare the considerable amount of vendors'


chemical resistance information with data published in the
technical literature pertinent to CPC performance. The goal
is to provide consensus recommendations as to the most appro-
priate clothing for the chemicals of interest.

1
"
It. .<
.
• Provide listings of cre products and a directory of cpe
vendors.

• Provide specific, detailed information on full-body protective


clothing.

• Aid further study of CPC by inclusion of a comprehensive


reference listing.

• Be readily updateable as more information becomes available.

c. LIMITATIONS

The scope of the Guidelines is limited to gloves, garments, boots, and


lenses and face shields. Respirators are not covered. The chemicals
are principally liquids, but a small number of gases and some solids
with high vapor pressures are included. The chemicals were selected
from the listings of Clean Water Act (CWA) Sections 311 and 307a, Clean
Air Act (CAA) Section 112, and Resource Conservation and Recovery Act
(RCRA) Sections P, U, F, and K. Also addressed were any other chemicals
for which there were CPC manufacturers' or vendors' recommendations or
technical reports of permeation or compatibility test results.

Regarding the CPC manufacturers and vendors referred to in the directo-


ry, the listing is not all inclusive. The objective, however, is to
include at least one source for any given item of CPC. In other words,
it is unlikely that all distributors of certain brands/lines of CPC are
mentioned. The listing is designed such that it can be readily expanded
to cover additional manufacturers or distributors as they become known.

The recommendations, which compose Matrices A and B, Volume I, Chapter


8, are the result of comparative analysis of both the vendors' and
technical literature in combination with technical judgment. For many
chemicals the information available was sufficient for there to be a
high level of confidence in the recommendations; these recommendations
are listed as double upper case letters in the Matrices. For other
chemicals there was less information and the recommendations are listed
in lower case. For many chemicals there was no information and no
recommendation is given.

A further limitation is that the Guidelines does not address multi-


component solutions in-depth. Such mixtures, especially where several
organic solvents are involved can have greater permeation than ~ny one
of the components alone. Special care must be taken when solutions are
involved. Furthermore, the Guidelines does not consider all the possi-
ble applications to which CPC will be put.

2
D. ASSUMPTIONS
The Guidelines is developed under three key assumptions:

• Its users would have a background in the physical sciences


and, specifically, chemistry.

• Its users would have some information about the identity of


the chemicals to which the CPC may be exposed.

.. Its users would have some information about the degree of


hazard with which the worker may be faced. The Guidelines
provides ratings of the expected performance of the materials
of construction of CPC. The Guidelines does not prescribe the
level of clothing necessary for a given task, although Appen-
dix I of Volume I provides some assistance in this regard.

E. INSTRUCTIONS FOR GUIDELINES USE


The Guidelines is divided into two volumes. Volume I is directed more
towards day-to-day field use, while Volume II is designed more as a
reference manual. The individual responsible for selecting CPC at the
hazardous waste site should be familiar with all aspects of Volume I.
It provides:

• Basic discussions of chemical resistance and permeation of CPC


materials.

• Recommendations for CPC for 509 chemicals or aqueous solu-


tions.

• Detailed descriptions of full-body encapsulating ensembles.

• Sources for acquisition of recommended clothing.

The responsible on-site individual should also be aware of Volume II and


its contents. Volume II, however, was designed principally to be used
by the occupational health and safety professional providing further
guidance to field personnel.

The volumes are in loose-leaf format to allow for rapid update in


response to additional information on CPC performance and user comments.
In this regard, all Guidelines users are asked to inform Lt. Jeffrey O.
Stull, Commandant (G-DMT-3), U.S. Coast Guard, 2100 Second Street, S.W.,
Washington, D.C. 20593 (202-267-0853), or Mr. David Weitzman, U.S.
Environmental Protection Agency, Office of Occupational Health and
Safety, Room 3503, Waterside Mall, 401 M Street, S.W., Washington, D.C.
20460 (202-382-3647) of problems in understanding or using the Guide-
lines.

3
CHAPTER 2
PERMEATION THEORY
A. INTRODUCTION
The purpose of the Guidelines is to facilitate the selection of CPC on
the basis of its effectiveness as a barrier to potentially hazardous
chemicals. Since chemical resistance is the focus, it is appropriate to
include a discussion of permeation theory. In Chapter 3. Volume I. a
brief overview of the key aspects of the theory is presented. The
present chapter contains a more in-depth discussion of the subject. In
addition several other theoretical factors which were considered in
developing the CPC recommendations are summarized.

B. IDEAL PERMEATION
Permeation of a chemical through a barrier is a three-step transport
process involving (1) the sorption of molecules of the chemical at the
contacted surface of the barrier, (2) the diffusion of the sorbed mole-
cules through the barrier, and (3) the desorption of the molecules from
the opposite surface of the barrier. 8 S , " In cases involving direct
liquid contact with a clothing material, the diffusion step is the rate
controlling step in the permeation process and, therefore, is the topic
of the remainder of the discussion.

The rate of mass diffusion through a unit surface area of a clothing


barrier (or membrane) is proportional to the concentration gradient of
the chemical (permeant) across the barrier. This relationship is mos t
often expressed by Fick's Law:

J -D dc (1)
dx
where

J is the mass flux, pg/min/cm2;


D is the diffusion coefficient, cm2/min;
c is the concentration in the membrane, pg/cm 3 ; and
x is the distance, in cm, from the contacted membrane surface.

The minus sign in the equation accounts for a decreasing c as x in-


creases.

Integration of equation (1) results in a relationship which is useful for


determining the diffusion coefficient from test data. Once D is known
for a given chemical/material pair, then the chemical flux can be

4
estimated over a wide range of thicknesses and challenge concentration
conditions. Such a prediction is appropriate since permeatian criteria
for protective clothing might ultimately be specified as a maximum
allowable flux rather than a breakthrough time. as is more commonly the
case today.

Where D is not a function of chemical concentration, membrane thickness,


or contact time (such as during the steady-state permeation of a non-
reactive gas). this integration is straightforward and yields equation
(2):

(2)

where

C is the permeant concentration in the upstream (higher concentra-


1
tion) surface of the membrane (at x - 0);

C is the permeant concentration in the downstream surface of the


2 membrane (at x - 1); and

1 is the membrane thickness.

In cases where D is a function of concentration, an integral diffusion


coefficient ~ can be defined as:

1
(3)

Examples of rr as a function of concentration would include:


D (1 + f (c»
o
(4)
f(c)
D e
o
where D is the zero-concentration diffusion coefficient. Such a concen-
o
tration dependence may occur when organics, such as solvent liquids,
diffuse through polymeric materials. The result of integrating equation
(1) with an integral diffusion coefficient is Equation (5):

J (5)

5
It should be noted here that many polymers swe11--thereby changing their
thickness--upon the invasion of a permeating chemical. Crank discusses
this on page 28 of The Mathematics of Diffusion.ls Conventional practice
is to disregard this change in the above integration and subsequent
calculation of D.

D or D can be determined by measuring both C and the permeation flux.


C2 is considered to be 0 when permeation testsl are carried out such that
downstream membrane surface <at x - .2) is continuously exposed to and
flushed by a fluid in which the concentration of the permeant is far
below saturation. In the case of the diffusion of a neat chemical, C is
the solubility of the compound in the polymer (i.e., C - C ) and can1 be
I
determined by a separate, 10ng- term immersion experiment. s The rate of
permeation is typically determined by analytical methods such as GC, lR,
UV, or scintillation counting (in the case that the permeant is radio-
labeled) of a col1ectin& fluid that contacts the downstream surface of
the membrane. ASTM Method F739-85 is an appropriate procedure for such
testing. A graphical, idealized representation of chemical permeation
through a membrane is presented in Figure 1 in terms of measured concen-
tration versus contact time.

In practice, the determination of the diffusion coefficient is not always


straightforward. Consequently, techniques have been developed for~
estimating this parameter at particular stages of the permeation process.
Of particular importance because of the relative ease of their determina-
tion and their utility in predictive models are the steady-state diffu-
sion coefficient, Ds' and the lag time diffusion coefficient, DL. In the
following paragrapHs, the significance of these diffusion coefficients
and methods for their determination are described. Other, more complex,
methods for estimating D are presented by Crank lS and Crank'and Park. l •

1. Steady-State Diffusion Coefficient (Os>


In ideal diffusion, a constant concentration gradient develops across the
membrane and the flux becomes constant (1.e., steady-state permeation)
following the transition period after breakthrough. (In many cases
involving CPC, non-ideal diffusion occurs and a steady state does not
develop. 222) A steady-state diffusion coefficient, D , can be calculated
directly from equation (6)::., s

(6)

assuming C is small compared to C .


2 1
The steady-state coefficient may be useful in the selection of clothiu&
materials in cases where some limited exposure toa permeating chemical
·.-,be acceptabl••

6
c:

....
0.,o
...
c:
g
U
~
t~
Steady State
~
a

Transition

Breakthrough
'/
'I
4---;-. Lag- Ti~e Extension
T L = Lag Time
O~----------~~~--~====~-=~=---------------------~
o Membrane Exposure Time, t

FIGURE 1 IDEAL PERMEATION THROUGH A POLYMERIC MEMBRANE - FIXED COLLECTION VOLUME


2. Lag Time Diffusion Coefficient COL>
Another technique for calculating a diffusion coefficient is the lag time
method. The lag time coefficient, D , is determined by extending the
L
steady-state portion of the permeation curve (see Figure 1) to the time
axis. The time, T , at the intercept is substituted into equation (7):
L

DL - (7)

and D calculated. DL may then be used in equation (2), but this is


stricfty valid only for those barriers in which the diffusion coefficient
is constant. In many cases, DL is a good approximation for Ds and ill
some cases a fair appro;..:imation to 15 for those barriers in which the
diffusion coefficient is '.'ariable.

In conclusion, it must be noted that at present there is no overall


theory that allows the pre die tion of the permeabil i ty of CPC. Some 0 f
the problems faced in developing predictive methods are discussed in the
next paragraph.

C. ANOMALOUS PERMEATION

In the previous paragraph ideal permeation was described as a diffusion


process in which the breakthrough time is followed by a period of smooth
transition to a steady-state situation in which the permeation rate does
not change with time. Ideal diffusion is likely to occur with many of
the chemical/material pairs experienced on a hazardous waste site. It
should be recognized, however, that deviations (i.e., anomalies) from the
ideal may occur in a large fraction of the cases. As the name implies,
anomalous permeation is not predictable. However, there are several
general conditions under which the probability of non-ideal permeation is
increased:

• where there may be a reaction of the chemical with the plastic/


elastomer of the CPC or some other component of the material.
In some cases the reaction will lengthen the breakthrough time
and reduce permeation rate by consuming chemical. In other
cases the reaction will reduce the barrier effectiveness of the
CPC by degrading its properties.

• where the chemical, merely by its being absorbed, changes the


properties of the CPC. Many organic liquids are known to craze
(produce surface cracks) in the hard, clear plastics used for
lenses and face shields.

8
• where the chemical extracts components from the CPC materials.
For example, leaching of plasticizer from PVC clothing will
significantly affect its barrier as well as functional proper-
ties.

Nelson et a1. 222 , 'Weeks et a1. 326 ,327, and Crank and Park 84 present
additional discussions of this subject.

D. PERSI~TEltt PERMEATION
Once a chemical has begun to diffuse into a plastic/elastomer, it will
continue to diffuse even after the chemical on the surface is removed.
This is due to the concentration gradient that develops wi thin the CPC
and the natural tendency for a gradient to equilibrate with its surround-
ings. This phenomenon has significant implications relative to decontam-
ination and reuse of CPC.

First, in the case of CPC which has not suffered chemical breakthrough
but has absorbed some chemical before the chemical is removed from th.e
surface, the chemical may eventually appear on its inside surface. The
amount of chemical reaching the inside will be dependent upon the amount
of chemical absorbed and its permeation rate. For example, where the
absorbed amount is small and the rate slow, it is likely that a large
fraction of the absorbed chemical will return to the outside surface
where, if it is volatile, it will evaporate to the air, and little or no
chemical will reach the inside surface. On the other hand where the
permeation rate is fast, there is the potential that a large amount of
chemical will appear on the inside surface, perhaps after overnight
storage in a locker. liS

Second, in order to achieve complete decontamination of the CPC, both


surface and absorbed chemical must be removed. Since the absorbed
chemical will leave the CPC only by a diffusional process, either very
long times or conditions which accelerate diffusion are required. These
would include high temperatures, vacuum, or p~rhaps a dry-cleaning
process in which a chemical non-degrading to the CPC is used to extract
the hazardous chemical. Because of this problem of persistent permea-
tion, extreme caution is advised when using CPC that has been exposed to
highly toxic chemicals. In fact, where such chemicals are involved, it
may be prudent practice to use disposable clothing.

E. CHEMICAL CLASSIFICATION AND SOLUBILITY PARAMETER


The Guidelines provides CPC recommendations for 509 chemicals or aqueous
solutions. For those chemical/material pairs for which no recommenda-
tions are given, it is suggested that CPC can be selected on the basis of
the family to which the chemicals belong. The premise, which is substan-
tiated in permeation literature, is that chemicals of similar composition

9
or functional groups tend to permeate a given material at relatively
similar rates. Extensions and refinements of this premise are
that: 282 ,316

• higher molecular weight members of a homologous series of


chemicals permeate at slower rates than lower molecular weight
members.

• pendant groups (which increase the size of a molecule) tend to


slow the permeation rate relative to that of the simple mole-
cule.

• permeation rate tends to decrease with increasing boiling


point.

• polar chemicals tend to permeate polar materials more rapidly


than non-polar chemicals, and the converse is true.

The 509 chemicals or aqueous solutions were categorized into 29 main


classes and 67 subclasses according to structure and functional
groups. 117 For example. hydrocarbons is a main class which is divided
into aliphatic, aromatic, and polynuclear aromatic subclasses. The
classes are listed in Table 8.1, Chapter 8 of Volume I. The class into
which each chemical was placed can be determined from Appendix B of
Volume I.

Upon review of those classes which contain a sufficient number of chemi-


cals on which to base a conclusion, the above generalizations relative to
the chemical resistance of materials would appear to apply for most of
the chemical/material pairs addressed in this study.

A second means for predicting the chemical resistance of CPC materials is


through the use of solubility parameter theory. This theory attempts to
quantify the qualitative nature of the above generalizations. According
to the theory, the physical and chemical properties of a chemical can be
combined mathematically to yield a parameter that is then compared to an
empirically determined parameter for the plastic/elastomer. In cases
where the parameter of the chemical approximates that of the material,
the chemical is predicted to have a high solubility in, or dissolve the
material. In other words -likes dissolve likes.- Extrapolation of this
theory to CPC implies that a material is not likely'to be resistant to a
chemical having a similar solubility parameter. An especially attractive
feature of the theory is that solubility parameters can be calculated for
multi-component solutions by weighting the individual parameters accord-
ing to the relative concentrations of each component in the solution.
Consequently, there is the potential for making decisions relative to
selecting CPC for the virtually limitless number of solutions that may be
encountered.

10
Typical variations of the theory relate to the factors that are included
in the calculation of the solubility parameter and how these parameters
are weighted. One of the more widely accepted concepts is the three-
component parameter which combines factors for the hydrogen bonding,
polarity and dispersion forces of the chemical to yield its overall
solubility parameter. Other systems deal with two of these factors.
Still other systems favor the single-component solubility parameter and
then make adjustments for polarity or hydrogen bonding depending on the
application. Similar considerations are also required for the p1astic/
rubbe.r of CPC.

The results of a limited number of tests of the theory relative to CPC


materials show some promise for its application to CPC se1ection. 287
Henriksen has reviewed the theory in considerable detail, and applied it
to the data of Nelson et al. and his own data for epoxy solutions. 147
Christensen 10 has also subjected the data of Nelson et al. to an analysis
based on solubility parameter. The data of Nelson are particularly
useful in this regard since they result from a large number of experi-
ments with a broad variety of chemicals with well-specified CPC. How-'
ever, it is important to note that the theory is just that, "a theory,"
and that there are many variations of the theory, several of which are
reviewed by Barton 38 and more recently by L. Snyder. 283 ,284

Although solubility parameter theory offers promise for predicting CPC


performance, the application of the theory to CPC is in its early stages.
Significant problems must be solved before the theory can be applied to
the confident selection of CPC. For example, methods must be developed
for estimating the two- and/or three-component factors for chemicals
other than relatively simple solvents. Similarly I methods are required
for estimating the solubility parameters of CPC materials. Perkins et
al. have estimated the solubility parameters of selected CPC materi-
a1s.236 However, solubility parameters of CPC materials may be strongly
influenced by formulation. Finally, it must be remembered that solubil-
ity parameter theory is an equilibrium concept. It does not take into
account the dynamics of the permeation process. Also needed are
approaches to predicting the time-containing element of the permeation
equation, i.e., the diffusion coefficient.

11
CHAPTER 3
TEST METHODS
A. INTRODUCTION

The barrier effectiveness of a particular item of clothing to a particu-


lar chemical/mixture is dependent on the specific interactions between
the clothing material and the chemical/mixture. This in turn is deter-
mined by the formulation of the clothing material, its method of manufac-
ture, and its thickness. Temperature and other conditions of use also
influence clothing barrier properties. Finally, the composition of the
chemical/mixture is of major importance since relatively small percentag-
es of a second, third, etc., component can drastically alter the way in
which a chemical interacts with a material.

With the above in mind it is highly desirable that protective clothing


selection decisions be based on the results of testing of the chemi-
cal/clothing material pair of interest. The objective of such testing is
to quantify the key parameters discussed in Chapter 2. Of particular
concern are:

• The solubility of the chemical/mixture in the clothing material.

• The breakthrough time of the chemical for the material.

• The permeation rate of the chemical through the material.

B. SOLUBILITY

Solubility is the weight of chemical absorbed by a known weight of


material. In general, chemicals having solubilities > 10% rapidly
permeate the rubber or plastic. ASTM Method 0471-79 and ISO Method 2025
(International Standards Organization) describe methods for determining
solubility. The procedure simply involves immersing the material in the
chemical. In case of multi-layered clothing materials, only the normally
outside surface should be exposed to chemical. If the solubility values
are to be later used in calculating permeation rates, then each material
of the multi-layer system should be tested separately. Periodically the
material is removed, patted dry and weighed until a constant weight is
obtained. In addition to noting weight changes, the chemical and the
material should be inspected for discoloration, indicative of decomposi-
tion of the clothing material. Also the clothing material should be
examined for physical degradation using a knife, spatula, or other probe.

Solubility testing is simple and can readily be performed wherever at


least a two decimal place balance is available. Multiple tests can be

12
performed simultaneously using as little as 0.5 g and as much as 100 g of
clothing material per test, depending on the sensitivity of the balance.

Solubility testing represents the minimum level of evaluation that can be


performed for any unknown or multi-component hazardous waste.

c. DEGRADATION
The physical and/or aesthetic qualities of CPC can be significantly and
and undesirably changed due to exposure to chemicals. Chemical degrada-
tion testing simply involves measuring the properties or qualities of
interest before and after exposure to the chemical. The results are
compared and the change, if there is any, judged as to its acceptability
for the intended application of the item of clothing. ASTM Method D543
describes one such method for plastic materials. ASTM Committee F-23 is
presently developing a method specifically focussed on clothing materi~
also

Similar to solubility testing, degradation can be performed in the field.


and can be used as a means for screening candidate clothing materials
prior to more involved and expensive testing such as the permeation test
described below.

D. PERMEATION
Breakthrough time and permeation rate are determined by means of a

evaluation of protective clothing materials.1..


permeation test. ASTK Method F739-85 was specifically developed for the
(A printed copy of this
method is available from ASTK, 1916 Race Street, Philadelphia, PA 19103.)
The method uses a test cell which is divided into two chambers at the
midline by the clothing material to be tested. (See Figure 2.) The
potentially hazardous chemical is placed in one chamber and the other
chamber (i.e., the collection chamber) is monitored for the chemical of
interest. As shown, the cell is assembled for a liquid challenge chemi-
cal. Gaseous chemicals can also be tested by forming the cell from two
collection chambers. The test gas is then flowed continuously through
the challenge chamber. Of interest are the time the chemical is first
detected (i.e., breakthrough time) and the subsequent rate of permeation.
Of critical importance in conducting the test is that the collecting
medium not interact with the clothing material; air, nitrogen, helium, or
water are preferred collection media.

The detection of breakthrough is dependent on the sensitivity of the


analytical method used for measuring the chemical in the collection
medium. Typical preferred analytical methods include gas, liquid and ion
chromatography, analysis for total combustible organics, ultraviolet and
infrared spectrophotometry, and radioanalysis. The properties of the
chemical, the sensitivity requirements for the test, and cost are the

13
Challenge Chamber for
Test Chemical

Chamber

TFE-fluorocarbon Seal

FIGURE 2. SKETCH OF ASTM F739-85


PERMEATION TEST CHAMBER

14
principal factors considered in selecting an analytical method. For
relatively volatile chemicals, gas chromatography and infrared spectro-
photometry are the preferred methods. Liquid chromatography is used for
relatively nonvolatile organic compounds. Ion chromatography is particu-
larly useful for inorganic acids and salts. Finally, radiolabelled
compounds may be preferred where high sensitivity and specificity is
required; furthermore, if the compound of interest is readily available
in radiolabelled form, radiochemical methods may be significantly less
costly than the development and use of the other techniques.

Permeation testing of protective clothing materials has increased signif-


icantly during the past five years. The Journal of the American Indus-
trial Hygiene Association has become the principal vehicle for dissemina-
tion of test findings. (See Bibliography.) Also of note is Standard
Technical Publication 900 of the ASTM which contains several pertinent
articles. 32 In addition permeation data are available from several
clothing and clothing material vendors.'6,80,107 ,213,227 ,238

The International Standards Organization (ISO) has promulgated two other


methods for evaluating chemical protective clothing:

• Method 6529 - Protective Clothing Resistant to Penetration by


Dangerous Liquid Chemicals.

• Method 6530 - Clothing for Limited (ed.) Protection Against


Dangerous Liquid Chemicals.

Neither method is recommended since the results are difficult to inter-


pret relative to the selection of CPC. Presently ISO is in the final
stages of developing a standard permeation test. This standard is
analogous to ASTM Method F739.

A notable difference between the ASTM and ISO standards is the inclusion
of clothing labelling (marking) instructions in the ISO method. The
label must indicate the performance of the clothing material as a barrier
to the test chemicals. Such labeling is an aid to those considering the
use of the clothing much the same as fire extinguisher labels are.

With the significant increase in permeation data in recent years, the


need and opportunity for data interpretation and comparison have also
increased. Permeation test results are highly dependent on the experi-
mental procedure, generic material, cell configuration, and analytical
sensitivity. ASTM Committee F-23 is presently developing a specification
for data reporting that will facilitate interpretation and comparison of
test results. This same committee has promulgated a list of fifteen
chemicals (ASTM FlOOl-86) that can serve as a standard battery for
ranking clothing barrier properties. The fifteen chemicals represent a
wide range of chemical families and are: acetone, acetonitrile, carbon
disulphide, dichloromethane. diethylamine. dimethylformamide, ethyl

15
acetate, n-hexane, methanol, nitrobenzene, 50% sodium hydroxide, sulfuric
acid, tetrachloroethylene, tetrahydrofuran, and toluene.

E. VISIBILITY
Face shields and lenses, in addition to being chemical barriers, must
provide clear, undistorted vision to the wearer. Hard, inflexible face
shields and lenses may be subject to crazing (Le., surface cracking)
upon contact with certain chemicals. Crazing renders the surface foggy
and can drastically reduce vision. Since chemical contact with the face
shield or lens is more likely to occur in uncontrolled or emergency
situations when reduced vision would be an additional severe hazard,
shields and lens materials should be tested for resistance to chemical
attack. Crazing can also reduce the impact strength of the material.

ANSI/ASTM Method F484-77 describes a procedure for measuring stress


crazing by chemicals. A method for assessing the effect of chemicals on
clear plastics is by measuring the transparency of the plastic before and
after exposure to the chemical; ASTM D1746 describes one such method.
While both these methods will adequately show up potential incompatibili-
ties, they require equipment that is not likely to be available in field
or chemistry laboratories. A simpler test, which could be performed on
site, requires only a placard on which are printed letters ranging from
large to small in size. Analogous to a common vision test, the placard
is read through an unexposed face shield or lens material, with a dis-
tance of 10 to 15 feet between the plastic and the placard. Note is made
of the ease with which the letters can be read and the minimum size
letter which can be read. The face shield or lens material is then
swabbed or immersed in the chemical of interest for at least one hour.
(Note, if the face shield or lens has different coatings or plastic
layers on the inside and outside surfaces, only the outside surface
should be exposed to the chemical.) Remove the material from the chemi-
cal and allow to air dry. Inspect the material and repeat the placard
reading test.

F. PENETRATION

In addition to permeation, which occurs by molecular diffusion, liquid


chemicals can cross a CPC barrier by penetration. Penetration is the
movement of chemical through holes such as at seams, zippers, and other
closures as well as through flaws in the CPC. Penetration can also occur
through porous woven and non-woven fabrics and through fabrics based on
microporous films. Gore-Tex· is one brand of such microporous film-based
fabric.

ASTM Committee F-23 has promulgated method F903-84 for the evaluation of
the penetration resistance of CPC and its materials of construction.
Briefly, a swatch of material or seam or closure is clamped in a two-

16
chambered cell. The chemical of concern is charged to one chamber and
pressure applied. The unexposed surface in the second chamber is ob-
served for appearance of the chemical.

G. OTHER FACTORS

The focus of the Guidelines and the above discussion is chemical resis-
tance of clothing materials. It is important to consider, however, that
in the selection and use of protective clothing other factors may be of
equal" or greater importance. For example, gloves must provide the wearer
some minimum level of dexterity, and the fabrics must have some level of
tear resistance. The relative importance of the performance factors is
largely dependent on the work tasks to be carried out.

At present there is no standard, overall protocol for evaluating protec-


tive clothing or clothing materials for all the performance parameters of
importance to workers on hazardous waste sites. Instead, individual
tests appropriate for the evaluation of specific parameters must be
selected from the volumes of procedures promulgated by federal, military,
and standards organizations. A 1978 NIOSH study addressed this problem
and resulted in a listing of test methods especially pertinent to protec-
tive clothing. 78 That compilation has been expanded where appropriate
and is presented herein as Table 3.1. For completeness, the chemical
resistance methods mentioned above are included in the Table. In addi-
tion to this listing, several tests specific to full-body protective
clothing are discussed in Chapter 5 of Volume I.

17
TABLE 3.1

TEST METHODS FOR CHEMICAL PROTECTIVE CLOTHING *

Characteristics Test

A. Chemical Resistance

1. Permeation Resistance ASTM F739-8l: Resistance of


Protective Clothing Materials to
Permeation by Hazardous Liquid
Chemicals

2. Swelling and Solubility ASTM 0471-79: Rubber Property--


Effects of Liquids

3. Strength Degradation ASTM D543: Resistance of


Plastics to Chemical Reagents

4. Crazing ASTM F484-77: Stress Crazing of


Acrylic Plastics in Contact With
Liquid or Semi-Liquid Compounds

5. Tr ansparency ASTM 1746-70: Transparency of


Plastic Sheeting

6. Penetration Resistance ASTM F903-84: Resistance of


Protective Clothing Materials to
Penetration by Liquids

B. Strength

1. Tear Resistance ASTM D751-73: Testing of Coated


and Strength Fabrics

ASTM D412-75: Rubber Properties


in Tension

Fed. 19lA-S102 (ASTM 01682):


Strength and Elongation,
Breaking of Woven Cloth:
Cut Strip Method

Fed. 191A-S134 (ASTM D2261):


Tearing Strength of Woven
Fabrics by the Tongue Method

2. Puncture Resistance See Reference 78

3. Abrasion Resistance ASTM Dl175: Abrasion Resistance


of Textile Fabrics

18
TABLE 3.1 (Continued)

TEST METHODS FOR CHEMICAL PROTECTIVE CLOTHING *

Characteristics Test

C. Dexterity/Flexibility

1. Dexterity (gloves only) See References 78, 122, 289

2. Flexibility ASTM D1388: Stiffness of


Fabrics, Cantilever Test Method

D. Aging Resistance

1. Ozone Resistance ASTM D304l-72: Coated Fabrics--


Ozone Cracking in a Chamber

ASTM D1149-64: Rubber


Deterioration--Dynamic Ozone
Cracking in a Chamber

2. UV Resistance ASTM G27: Operating Xenon-Arc


Type Apparatus for Light
Exposure of Non-Metallic
Materials--Method A--Continuous
Exposure to Light

*Physical property tests are listed in Tables 5.2 and 5.3 of Volume I.

19
CHAPTER 4
ANALYSIS OF THE VENDORS' LITERATURE
A. INTRODUCTION

Chapter 7 of Volume I contains an overview of the maj or strengths and


weaknesses of the literature supplied by CPC vendors. The purpose and
strength of this literature is to describe the composition, styles, and
sizes of protective clothing. In recent years the literature of several
clothing manufacturers has also become an important source of chemical
resistance information, particularly permeation data. However, much of
the literature remains weak in its level of documentation as to the basis
for the qualitative chemical resistance tables. As noted in Volume I,
ratings tables are intended for and should be used only for guidance in
the selection of CPC. This chapter extends the depth of the Volume I
discussion of the present vendors' chemical resistance tables and
discusses their future.

B. REVIEW OF VENDORS' LITERATURE

The catalogues of 150 CPC vendors and materials suppliers were reviewed
during the preparation of the Guidelines. Twenty-six of these documents
included chemical resistance ratings charts for some or all of the
products listed. These tables encompassed both qualitative and quantita-
tive ratings. In only a few cases was the rationale for the qualitative
ratings described in the catalogues. The rationale is necessary for any
attempt to form conclusions regarding the expected performance of CPC and
to compare products. Consequently, telephone interviews were conducted
with the CPC vendors who provided qualitative ratings. The telephone
interviews yielded little information that would further aid the utiliza-
tion of the qualitative ratings. The overall impression was that most
vendors are either not testing clothing or are not willing to share their
results.

The situation is much different for the chemical resistance tables that
are based on permeation test results. Virtually all vendors who provide
such data followed ASTK Method F739, or a similar procedure.

1. Permeation Testinq
Permeation data are supplied or available on request from at least ten
CPC vendors or materials suppliers. This number is up from six in 1985.
Furthermore, the number of chemicals and range of products have increased
significantly, and this increase can be expected to continue. CPC users
have become more demanding of the vendors and the vendors have found that
test data are useful as points of product differentiation.

20
However, the increased availability of test results carries with it the
problems associated with comparing and interpreting data. The vendors do
not use a standard format for presenting the data and, as discussed
earlier, the test results can be highly dependent on the testing proce-
dure. In order to compare breakthrough times, it is necessary to know
the sensitivity of the detector. the surface area of the clothing
material, and the collection medium volume if the test is performed in a
closed-loop mode or the collection medium flowrate if the test is
performed in an open-loop mode. The following discussion provides some
insights into reviewing and utilizing published breakthrough time and
permeation rate data.

Test results are available from the following vendors: Ansell, Best,
ChemFab, Comasec, DuPont, Edmont, MSA, North, Pioneer. and Playtex. (see
the Appendix D of Volume I for the complete corporate name and address.)
All except Best provide breakthrough time data; Best ranks by break-
through time the materials tested. All except MSA report permeation rate
data The units used by all excep~ Edmont for permeation rate are
2
mg/m /s; Edmont reports values pg/cm /min, consistent with ~STM F739.
Multiply the Edmont values by 0.167 to convert them to mg/m Is. Only
Best and ChemFab report the sensitivity of the instrument used to detect.
breakthrough. Only MSA provides information on the mode of testing
(open-loop) and the collection medium flowrate. Some of the others
provide information on the mode of testing but not the collection medium
volume or flowrate. Consequently. it is not possible to rigorously
compare breakthrough time data from vendor to vendor. As suggested above
and by the vendors themselves the data should be used for guidance only
and imply no guarantee of protection.

2. Immersion Testing
Most qualitative recommendations tables appear to be based on simple
immersion tests in which the material was merely observed after some time
period. There is no standard time for immersion and. of course, the
rating associated with any given test is likely to vary from observer to
observer. Furthermore. in some cases materials that were swelled by
chemicals may have been given an acceptable recommendation if upon drying
they returned to their original size and appearance. Obviously a materi-
al which is visibly swelled by a chemical will not be a barrier to that
chemical and should be given a "not recommended" rating ..

At present there is no standard immersion test for CPC. ASTM Committee


F-23 is considering several, but final acceptance is not expected before
1988. It is likely that the procedure will specify the immersion time
and two or three properties to be measured before and after immers ion.
Initially a standard immersion test will be useful for identifying
chemical/material pairs that are grossly incompatible. In time, once
larger amounts of data become available from standard immersion and
permeation tests, correlations may be developed that will allow more
sensitive prediction of CPC performance from immersion test data alone.

21
3. Applicability of Ratings Tables
The degree of applicability of some of the ratings tables to presently
available CPC is somewhat limited by two factors: age and materials
composition. Many of the tables are more than ten years old. Between
the time that the tables were generated and now, it is probable that the
actual elastomer/plastic formulation used in the CPC has been changed.
This may have resulted from a CPC manufacturer switching raw materials
suppliers or modifying the formulation to meet changed processing, use or
cost requirements. Changes to, for example, the plasticizer, lubricant,
filler, and so forth, level in a elastomer/plastic formulation can in
some cases significantly influence the chemical resistance of the final
product.

Significant differences exist between various vendors' ratings for


nominally the same CPC chemical/material pair. While this may be due to
the subjectivity of the test methods, there also may be real differences
between products. The difference may in part be due to the fact that the
different formulations of the same base elastomer/plastic material may
perform differently, and in part due to the manufacturing methods. In
other words, it is possible for one supplier to have a more chemically
resistant material (e.g. I PVC or butyl rubber, etc.) than another suppli-
er. This point has been documented in the literature. 268

Similarly, most of the ratings charts appear to have been developed for a
general class of material (for example, natural rubber or PVC) and not
the specific formulations used for protective clothing. Thus, the
ratings mayor may not be directly applicable to CPC.

The form of the elastomer/plastic can also influence the results on which
recommendations may be based. For example, a molded neoprene rubber can
have significantly different properties from those of a neoprene prepared
from a latex. Within the realm of CPC, it has recently been suggested
that gloves prepared by a latex process may perform differently from
gloves prepared by a solvent-dip process, but that additional evaluation
was required before definite conclusions could be reached. 326 It is not
clear whether the recommendations of manufacturers which have switched
from solvent to latex processing during the past 10 to 15 years have been
modified to reflect any performance differences that may have resulted.

The temperature range over which the ratings apply is not generally
stated. CPC users should note that there can be significant temperature
effects on permeation over the temperature range likely to be encountered
in the field. For example, the breakthrough times for benzene through a
0.08 cm neoprene were found to be 40 min at 7°C, 24 min at 2rC, and
16 min at 37°C.18

Finally, the sensitivity, if any, of the ratings to lot-to-lot variations


in the products are not provided. Also some manufacturers rate several
grades or thicknesses of a given CPC material as if they all performed

22
similarly. In these cases, the CPC user must carefully scrutinize the
catalogues in order to differentiate among the products and make the best
selection for the application at hand.

4. Multi-component Solutions
Multi-componet solutions represent a potentially large and difficult area
for CPC selection and use. In general most vendors address only aqueous
solutions in their ratings tables. Several vendors are careful to
designate a concentration range for each recommendation; many do not.
Small fractions of particularly permeable chemicals in a solution can
severely degrade clothing materials or can provide pathways for the
movement of other components of the solutions. Furthermore, there is an
unlimited number of solution compositions possible. Generally, the
vendors recommend that the CPC buyer conduct his own tests with the
specific solutions of concern. Multi-component solutions are of growing
interest to the research community and others. 104 ,124,278,302

5. Experience
Several manufacturers reported that some of the recommendations appearing"
in their tables were based on experience rather than testing. This may
or may not be appropriate depending on how the experience was judged.
For example, in many cases an item of CPC may be considered good for a
particular application because it does not fall apart or beCause it
returns to its original shape/size upon evaporation of absorbed chemical.
Obviously such criteria are not appropriate if skin contact with the
chemical is a primary concern.

On the other hand, experience can be a suitable basis for a recommenda-


tion when it originates from careful observation of worker well-being.
For example, a particular type of glove may prevent contact dermatitis
where all other gloves fail.

C. PERSPECTIVES ON VENDORS' LITERATURE

Although the above findings and comments can be rather perplexing, for
those responsible for selecting CPC, the situation is changing rapidly
for the better:

• There is a growing general understanding among CPC buyers that


chemicals can permeate CPC without there being any outward sign
of degradation or swelling of the material.

• There is growing technical/scientific interest in CPC perfor-


mance. Many of the larger chemical companies, several indepen-
dent testing laboratories, and some universities now have
groups evaluating CPC materials. Furthermore, the federal
government has become keenly aware of the need for rigorous

23
analysis of epe performance, as evidenced by this publication
and an increase in government sponsored research and develop-
ment.

• The general acceptance of a standard permeation test method.

• Vendors are becoming more comfortable with the liability


aspects of publishing test data. In fact publishing data
obtained under well-specified conditions may be less risky than
the promulgation of qualitative recommendations tables.
Vendors routinely print disclaimers along with their test data
which caution that they may not apply to the particular condi-
tion to which the buyer intends to subject epe. The buyer is
also advised to perform his own testing with the actual chemi-
cal/chemical mixtures at the use temperatures.

D. CONCWSION

The primary sources of information pertinent to the chemical resistance


of epe are the epe vendors and manufacturers. This is not likely to
change in the near future. Users of the vendors' recommendations and
data tables must always bear in mind the limitations of the charts, as
described above. The tables are for guidance only. That is the charts
are a good place to start the epe selection process, but they are not
guarantees of safety. Whenever possible, the potential epe user should
evaluate candidate products against the particular chemicals and solu-
tions of concern. Final selection must take into account the epe appli-
cation.

During the next several years, other sources for epe recommendations can
be expected to increase. Such sources, of which this publication is an
example, will be based on the compilation of both manufacturers' recom-
mendations and the scientific literature. It is reasonable to predict
and it is hoped that the existence of one or more key secondary sources
will stimulate more testing and quantitative reporting of epe performance
by both the vendors and the technical community at large. The resul t
will be more firmly based epe selection decisions.

24
CHAPTER 5
SOURCES FOR CHEMICAL PROTECTIVE
CLOTHING INFORMATION
A. INDUSTRY
By far the best source for information on epc is the CPC vendors. The
large, full-line vendors and the specialty products manufacturers gener-
ally' have tested their products against a wide range of chemicals.
Furthermore, they have years of experience with their products. and
typically have a very good understanding of the products' capabilities
and limitations. A listing of vendors is given in Volume I. Appendix D.

A second source of information is the chemical manufacturers. These


organizations provide clothing for their workers and often conduct their
own analysis of protective clothing performance for their chemical
products.

B. GOVERNMENT
Principal sources of CPC information within federal government agencies
are:

EPA - Office of Occupational Health and Safety, Room 3503, Waterside


Mall, 401 M Street, S.W., Washington, D.C. 20460. Telephone
202-382-3647 (David Weitzman).

Federal Emergency Management Agency (FEMA) - United States Fire


Administration, Office of Firefighter Health and Safety, 16825 South
Seton Avenue, Emmitsburg, MD 21727. Telephone 301-447-1182 (Robert
McCarthy) .

OHSA - Technical Assistance, Room N3657, 200 Constitution Avenue, NW


Washington, D.C. 20210. Telephone 202-523-7505 (Ching Bien).

NIOSH - Division of Safety Research, Testing and Criteria Branch,


ASI Section, 944 Chestnut Ridge Road, Morgantown,. WV 26505. Tele-
phone 304-291-4339 (Stephen Berardinelli).

U.S. Coast Guard - Headquarters, Office of Research and Development.


Commandant, G-DMT-3, 2100 Second Street, S.W., Washington, D.C.
20593. Telephone 202-267-0853 (Lt. Jeffrey Stull).

These agencies are involved in the study, development, and utilization of


protective clothing.

25
c. PROFESSIONAL ORGANIZATIONS
In the United States, three professional organizations have committees
directly focused on protective clothing. ASTM formed Committee F-23 in
1977 for the purpose of developing standard test methods for protective
clothing. Subcommittees of F-23 are addressing the chemical resistance
of clothing, the physical properties of clothing, clothing classification
methods, and the performance 'of full-body protective ensembles. The
committee is composed of industry, government, and general interest
members. It meets twice a year and is a forum for discussing protective
clothing test methods. In addition in 1984 and in 1987 Committee F-23
sponsored international symposia on all aspects of protective clothing.
Proceedings of the symposia are published by ASTM as Standard Technical
Publications. For further information, telephone ASTM headquarters (215-
299-5579).

The American Industrial Hygiene Association addresses CPC through its


technical committee Personal Protective Devices (other than respirators).
The committee meets once a year in coincidence with the American Indus-
trial Hygiene Conference. This week-long conference typically includes
one or two sessions devoted to protective clothing. At these sessions,
technical papers are presented describing research, evaluation or use of
protective clothing. Information on this and other AlHA activities may
be obtained from AlHA headquarters (216-762-7924).

The National Fire Protection Association (NFPA) formed a subcommittee on


Hazardous Chemical Protective Clothing in 1986. This subcommittee was
established under the NFPA Technical Committee on Protective Equipment
for Firefighters. The subcommittee is engaged in writing performance
oriented (manufacturing) standards on chemical protective suits for
emergency response personnel. Its membership is composed of
representatives from users, manufacturers, testing laboratories, and
government. It meets three times a year and plans to complete proposed
standards for chemical protective suits by December 1987. For further
information, contact Bruce Teele of the NFPA (617-770-3000).

D. TECHNICAL LITERATURE

In recent years, the principal sources of published technical papers and


reports on personal protective clothing have been the:

• American Industrial Hygiene Association Journal, a monthly


publication. AlHA, 475 Wolf Ledges Park, Akron, OH 44311.-1087.
Telephone 216-762-7924.

• National Technical Information Service (NTIS). Essentially all


federal government sponsored studies may be obtained through
NTIS. NTIS, U.S. Department of Commerce, 5285 Port Royal Road,
Springfield, VA 22161. Telephone 703-487-4650.

26
A new journal. Applied Industrial Hygiene. has been started by the
American Conference of Governmental Industrial Hygienist (ACGIH). 6500
Glenway Avenue. Bldg. D-7. Cincinnati, OH 45211. Telephone 513-661-7881.
Also articles on protective clothing are usually included in the proceed-
ings of Hazardous Materials Management Conference (Tower Conference
Management Cempany. Wheaton. IL 60187) and the Hazardous Material Spills
Conference (Government Industries, Inc., Rockville. MD 20850).

A bibliography of publications related to chemical protective clothing


follows.

27
BIBLIOGRAPHY

28
1 Abernathy, R.N., R.B. Cohen, and J.J. Shirtz
Measurements of Hypergolic Fuels and Oxidants Permeation
Through Commercial Protective Materials--Part I: Inhibited
Red Fuming Nitric Acid and Unsymmetrical Dimethylhydrazine
Am. Ind. Hyg. Assoc. J. 44(7), pp. 505-513 (1983)

2 Acme Mills Company


Catalogue
1986

3 Aitken, A., and R.M. Barrer


Transport and Solubility of Isomeric Paraffins in Rubber
Trans. Faraday Soc. 51(385), pp. 116-130 (January 1955)

4 A1gera, R.
Development of a Hazardous Chemical Protective
Ensemble: Phase I Interim Report
This report available as:
Stull, J., Early Development of a Hazardous Chemical
Protective Ensemble, Final Report U.S. Coast Guard
Contract DTCG23-8l-C-20003, AD A174 885 (October 1986)

5 Alliance ,Supply, Inc.


Catalogue
1986

6 Allied Glove & Safety Products Corp.


Catalogue
1986

7 American Scientific Products


Catalogue
1984

8 Ando~er Industries, Inc.


Catalog
1986

9 Angelica Uniform Group


Catalogue
1986

10 Anon.
Foot and Leg Protection
National Safety News, pp. 176-182 (March 1962)

29
II Anon.
A Summary of the Record of the NIOSH Open Meeting on
Chemical Protective Clothing
Rockville, Maryland, (June 3, 1981)

l2 Anon.
Balancing the Scales Between Protection and Economy
National Safety News, pp. 36-39 (April 1982)

13 Anon.
Protective Clothing Studies Reveal Wearer Preferences
Agrichemica1 Age, (June 1981)

14 Anon.
Protective Clothing for Chlorine, Edition 1
Chlorine Institute Pamphlet 65, The Chlorine Institute, Inc.
New York, New York, (June 1978)

15 Anon.
Best Safety Directory, Vol. I
A.M. Best Company, Oldwick, New Jersey 08858

16 Anon.
Health and Safety Market Guide '82
Ayde Marketing Limited, 2 Castle Street, Aylesbury, Bucks
HP20 20RF England

17 Anon.
Industry's Persistent Problem: Occupational Dermatitis
National Safety News, pp. 33-37 (November 1982)

18 Anon.
Dress Right for Safety: Foot Protection: Shoes
National Safety News, pp. 66-67 (March 1983)

19 Anon.
Dress Right for Safety: Hand Protection
National Safety News, pp. 62-65 (March 1983)

20 Anon.
Dress Right for Safety: General Body Protection
National Safety News, pp. 54-57 (March 1983)

30
21 Anon.
Dress Right for Safety: Disposable Apparel
National Safety News, pp. 57-59 (March 1983)

22 Anon.
Dress Right for Safety: Eye and Face Protection
National Safety News, pp. 41-44 (March 1983)

23 Anon.
A Shift Toward Protective Gear
Business Week, p. 56 (April 13, 1981)

24 Anon.
Safety Spinoffs From Space
National Safety News, pp. 30-32 (February 1984)

25 Anon.
Hazardous Waste Workers Are Seen Underprotected by Union,
Congressmen, Chemical Marketing Reporter, pp. 5,40
(April 1, 1985)

26 Ansell Industrial Products


Catalogue
1986

27 ARAMSCO
Catalogue
1986

28 Arbill Inc.
Catalogue
1986

29 Armin Corp.
Catalogue
1986

30 Arrowhead Products
Catalogue
1986

31 Aydelotte, C.L.
Consider Hazards Facing Worker in Making Proper Glove
Selections, Occupational Health & Safety, pp. 54,56

31
32 Barker, R.L., and Coletta, G.C.
Performance of Protective Clothing
ASTM STP 900, ASTM PCN 04-900000-55, Philidelphia, PA
(1986)

33 Barnes, J.D., G.M. Martin, and F.L. McCrackin


Performance of Plastic Packaging for Hazardous Materials
Transportation. IV
NTIS Report No. DOT/MTB/OHKO-77/5, PB298047 (1979)

34 Barnhart, Y.L., C.R. Tony, and L.A. Nicodemus


Catalog of Available Protective Clothing Supplement to
Final Report: 'Protective Clothing - Assessment of Ne~d'
NIOSH Publication PB-276344 (August 1974)

35 Barnhart, Y.L., C.R. Toney, and L.A. Nicodemus


Protective Clothing--Assessment of Need, Vol. I
Final Report prepared by Bendix Corporation, Launch
Support Division under the United States Department of
Health, Education, and Yelfare - Public Health Service,
Center for Disease Control, NIOSH-TR-75.0l, PB24ll07
(August 1974)

36 Barrer, R.M., and R.R. Fergusson


Diffusion of Benzene in Rubber and Polyethylene
Trans. Faraday Soc., 54(427) pp. 989-1000 (1958)

37 Barry Manufacturing Co. Ltd.


Catalogue
1986

38 Barton, A. M.
Solubility Parameters
Chemical Reviews, 75(6), pp. 731-749 (1975)

39 Barton, A.F.M.
Handbook of Solubility Parameters and Other Cohesion
Parameters
CRC Press, Boca Raton, FL (1983)

40 Bel-Art Products
Catalogue
1981

41 Berardinelli, S.
Chemical Protective Clothing Standard Test Method
Development Final Report No.1: Penetration Test Method
NIOSH Contract No. 200-84-2702

32
42 Berardinelli, S.P., R.L. Mickelsen, and M.M. Roder
Chemical Protective Clothing: A Comparison of Chemical
Permeation Test Cells and Direct-Reading Instruments
Am. Ind. Hyg. Assoc. J. 44(12), pp. 886-889 (1983)

43 Berardinelli, S.P., and R. Hall


Site-Specific Whole Glove Chemical Permeation
Am. Ind. Hyg. Assoc. J., 46, pp. 60-64, (February 1985)

44 Beret, S., and S.L. Hager


Ethylene Solubility and Diffusion in Low Density
P'olyethylene and Ethylene Polymers
J. Appl. Poly. Sci., 24, pp. 1787-1796 (1979)

45 Best Manufacturing Company


Catalogue
1986

46 Best, A.M., Company


Best's Safety Directory, 2 Volumes
24th Edition, 1984

47 Body-Guard
Catalogue
1984

48 Boss Manufacturing Company


Catalogue
No. 20-4-81
1985

49 Bosserman, M.W.
How to Test Chemical-Resistance of Protective Clothing
National Safety News, pp. 51-53 (September 1979)

50 Brandrup, J. and E.H. Immergut


Polymer Handbook
John Wiley & Sons, New York (1966)

51 Broner Glove Company


Catalogue
1983

52 Bush, D.G., L.E. Tersegno, J.E. Winter, and D.H. Schoch


A Method for Testing Permeability of Protective Clothing
to Acids and Bases
Industrial Hygiene Section
Eastman Kodak Company
Rochester, NY (June 1982)

33
53 Butt, L.T., J. Pacitti, and J.R. Scott
Chemical Resistance Data Sheets, Vols. I and II
Rubber and Plastics Research Association (RAPRA) , Shawbury,
Shrewsbury, SY4 4NR England

54 Calingaert, G., and H. Shapiro


Permeability of Protective Glove Materials to
Tetraethyllead and Ethylene Bromide
Industrial and Engineering Chemistry, 40(2), p. 332 (1948)

55 Calingaert, G., and H. Shapiro


Permeability of Protective Glove Materials to Tetraethyllead
and Ethylene Bromide
Industrial and Engineering Chemistry, 40(2), pp. 332-335
(February 1948)

56 Cesco Safety Products


Catalogue
1986

57 Charkate
Catalogue
1986

58 Chemical Engineering
New Wardrobe for CPI Workers
pp. 14-15 (August 19, 1985)

59 Chemical Fabrics Corporation


Catalogue
1986

60 Cheron, J.
Resistance des Gants de Protection aux Solvents
Industriels - Resultats Obtenus Avec L'Acetone Sur Dne
Centaine de Gants du Commerce
Travail et Securite, No. 527, Oct. 1975, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14

61 Cheron, J.
Resistance des Gants de Protection Aux So1vants
Industriels - Resultats Obtenus Avec Ie Trichlorethane Sur
Dne Centaine de Gants du Commerce
Travail et Securite, No. 502, Oct. 1973, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14

34
62 Cheron, J.
Resistance des Gants de Protection Aux Solvants
Industriels - Resultats Obtenus Avec L'Acetate D'Ethyle Sur
Une Centaine de Gants du Commerce
Travail et Securite, No. 547, Sept. 1976, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14

63 Cheron, J.
Resistance des Gants de Protection Aux Solvants
Industriels - Resultats Obtenus Avec L'Ethanol Sur Une
Centaine de Gants du Commerce
Travail et Securite, No. 550, Nov. 1976, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14

64 Cheron, J.
Resistance des Gants de Protection Aux Solvants
Industriels - Resultats Obtenus Avec Ie Toluene Sur Une
Centaine de Gants du Commerce
Travail et Securite, No. 503, Jan. 1975, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14

65 Cheron, J.
Resistance des Gants de Protection Aux So1vants
Industrie1s - Resu1tats Obtenus Avec Ie Trichlorethylene Sur
Une Centaine de Gants du Commerce
Travail et Securite, No. 491, Oct. 1972, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14

66 Cheron, J.
Resistance des Gants de Protection Aux So1vants
Industriels - Resultats Obtenus Avec Ie Perchlorethylene Sur
Une Centaine de Gants du Commerce
Travail et Securite, No. 498, June 1973, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14

67 Cheron, J.
Resistance des Gants de Protection Aux Solvants
Industrie1s - Resultats Obtenus Avec Ie Cyclohexane Sur Une
Centaine de Gants du Commerce
Travail et Securite, No. 521, Jan. 1975, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14

68 Cheron, J.
Resistance des Gants de Protection Aux Solvants
Industrieis - Resultats Obtenus Avec Ie White-Spirit Sur Une
Centaine de Gants du Commerce
Travail et Securite, No. 506, June 1974, Institut National
de Recherche et de Securite, 75680, Paris, Cedex 14

35
69 Cheron, J., J.-P. Guenier, B. Moncelon and Lima
Resistance des Gants de Protection Aux Solvants
Industriels - Tableaux Recapitulatifs
Travail et Securite, No.573, Dec. 1976, Institut
National de Recherche et de Securite, 75680, Paris, Cedex 14

70 Christensen, U.L.
Handsker - sikre/usiker (in Danish)
English summary available from Institute of York
Environment, Denmark Institute of Technology,
DK-2800 Lyngby (April 1983)

71 Clean Room Products, Inc.


Catalogue
1986

72 Cofish International, Inc.


Catalogue
1986

73 Coletta, G.C.
Chemical Protective Clothing: Technology Will Shape the
Future, Occupational Health & Safety, pp. 50-54
(September 1985)

74 Coletta, G.C.
Chemical Protective Clothing: Determining Good Performance
Occupational Health & Safety, pp. 20-22 (April 1985)

75 Coletta, G.C.
Chemical Protective Clothing: Testing Strategy and Test
Methods, Occupational Health & Safety, pp. 49-52 (May 1985)

76 Coletta, G.C.
Chemical Protective Clothing: Laboratory vs. Field
Performance, Occupational Health & Safety, pp. 85-87
(June 1985)

77 Coletta, G.C.
Chemical Protective Clothing: The Influence of Federal
Agencies, Occupational Health & Safety, pp. 27-29
(July 1985)

78 Coletta, G.C., A.D. Schwope, I. Arons, J. King, and A. Sivak


Development of Performance Criteria for Protective
Clothing Used Against Carcinogenic Liquids
Arthur D. Little, Inc., Report to NIOSH under contract
210-76-0130 (October 1978)

36
79 Colonial Glove & Garment Inc.
Catalogue
1986

80 Comasec, Inc.
Catalogue
1986

81 Costello, R.J., and M.V. King


Protecting Workers Who Clean Up Hazardous Waste Sites
Am. Ind. Hyg. Assoc. J., 43, p. 12 (January 1982)

82 Coyne Safety Equipment, Inc.


Catalogue
1986

83 Crank, J.
Mathematics of Diffusion
Second Edition, Claredon Press (1975)

84 Crank, J., and G. Park


Diffusion In Polymers
Academic Press, N.Y. (1968)

85 Crowe, W.H., and A.M. Marysiuk


How to Work Safely With HF Alkylation
Hydrocarbon Proc., 44(5), p. 192 (1965)

86 Cullinane, J.
Evaluation of the Permeation Resistance of Polymer Gloves
to an Organophosphorus Pesticide and Pesticide Carrier
Solvents
IT Corporation, Report to EPA under contract 68-03-3069,
(May 1985)

87 Daffin Disposables, Inc.


Catalogue
1986

88 Davis, S.L., C.E. Feigley, and G.A. Dwiggins


Comparison of Two Methods Used to Measure Permeation-of
Glove Materials by a Complex Organic Mixture
Performance of Protective Clothing, ASTM STP 900, R.L.
Barker and G.C. Coletta, Eds., American Society for Testing
and Materials, Philadelphia, pp. 7-21 (1986)

37
89 Dayton Flexible Products, Inc.
CacaL)gue
1984

90 Defense Apparel, Inc.


Catalogue
1986

91 Denney, D.
ASTM Eyps Plans, Seeks Input for Protective Clothing Data
FUe, Occupational Health & Safety, pp. 57-61
(July/August 1984)

92 Dickson. G.G.
Chemical Protective Clothing
~est's Safety Directory 1984
A.M. Best Co., Oldwick, NJ 08858, pp. 392-394

93 Dillon, I. G.
Permeation of Condensable Gases and Organic Liquids through
Polymeric Materials
National Aeronautics and Space Administration
Contract No. NAG-lO-OOOl
Final Report

94 Dillon, I.G., and E. Obasuyi


Permeation of Hexane Through !utyl Nomex
Am. Ind. Hyg. Assoc. J., 4'1(5), pp. 233-235
(May 1985)

95 Dionne, E.D.
Specialized Protective Apparel - An Item to Fit Every Need
National Safety News, p. 51 (May 1982)

96 Dionne, E.D.
A Glove Affair
National Safety News, (September 1982)

97 Direct Safety Company, Inc.


Catalogue
1986

98 Disposables Inc.
Cata1ngue
1986

38
99 Dorsey Safety Products Co.
Catalog
1986

100 Dow Chemical Company


Selection of Gloves for Use With Chlorinated Solvents
Chlorinated Solvents Information
Midland, Michigan 48640

101 Duffy, R.M., A.R.Beer, and J.C. Sawicki


U.S.Research in Depth on Protective Clothing
Fire International, pp. 41-43 (August/September 1985)

102 Dunham, T.D., W.J. Astleford, R.L. Bessey, and J.J. Kulesz
Recommended Standard for Occupational and Educational Eye
and Face Protection
Final Report NIOSH Contract HSM-99-73-l7, SwRI Project
02-3703

103 E.D. Bullard Company


Catalogue
1986

104 E.I. du Pont de Nemours & Company


Spunbonded Product Division
Guide E-64312
1986
105 E.I. du Pont de Nemours & Company
Industrial and Speciality Polymers
Catalogue E-26276

106 Eastco Industrial Safety Corp.


Catalogue
1985

107 Edmont Division of Becton, Dickinson Company


Catalogue
1986

108 Elliott Glove Company, Inc.


Catalogue
1986

109 Ellis, A.C.


Hazardous Waste Site Clean-Up A 'Hot' Problem
National Safety News, pp. 38-41 (July 1984)

39
110 Encon Manufacturing Company
Catalogue
1986

111 Engle, R.L., and V.A. Nusbaum


Selecting Protective Gloves. The Importance of Chemical
Permeation Testing
Professional Safety, pp. 32-35 (September 1984)

112 Erista, Inc.


Catalogue

113 Exxon Chemical Company


Polymers Group
Elastomers - Design Materials
Catalogue SYN-75-l75l, 1975

114 Fairway Products


Catalogue
1984

115 Falcon Industries, Inc.


Catalogue
1981

116 Feigley, C.E.


Personal Communication
Dept. of Envir. Health Sciences
University of South Carolina
Columbia, S.C. 29208
(October 1982)

117 Fels, M., and R.Y.M. Huang


Diffusion Coefficients of Liquids in Polymer Membranes by
a Desorption Method
J. Appl. Poly. Sci., 14, pp. 523-536 (1970)

118 Ferguson, J.S., and Y.F Martin


An Overview of Occupational Safety and Health Guidelines
for Superfund Sites, Am. Ind. Hyg. Assoc. J., 46(4),
pp. 175-180 (1985)

119 Figard, Yilliam H.


Permeation: An Important Factor in
Hand Protection Selection
Occupational Health and Safety
(December 1982)

40
120 Fisher Scientific Company
Catalogue
1981

121 Flynn, .J .H.


A Collection of Kinetic Data for the Diffusion of Olganic
Compounds in Polyolefins
Polymer, 23, pp. 1325-1344 (August 1982)

122 Forsberg, K.
D~velopment of Safety Gloves. Gloves For Printers
ERGOLAB Report S 81:10
Stockholm/Goteborg, Sweden
(November 1981)

123 Forsberg, K., and K.G. Olsson


Faststallande av riktlinjer for val av
kemikalieskyddshandskar
ASF-kontrakt 83-0750

124 Forsberg, K., and S. Faniadis


The Permeation of Multi-Component Liquids Through New and
Pre-Exposed Glove Materials
Am. Ind. Hyg. Assoc. J., 47(3), pp. 189-193 (March 1986)

125 Frederick, E.B., and M.C. Henry


A Study of Seam Leakage in Coated Fabrics
J. Coated Fibrous Materials, 1, p. 18 (1971)

126 Friel, J.V., M.J. McGoff, and S.J. Rodgers


Material Development Study for a Hazardous Chemical
Protective Clothing Outfit
MSA Research Corp. for United States Coast Guard
Report No. CG-D-58-80 (August 1980)

127 Frommelt Industries, Inc.


Catalogue
1986

128 Fyrepel Products, Inc.


Catalogue
1986

129 Ga1ic, George J.


Polycarbonate Lenses--New Technology in Eye Protection
National Safety News
July, 1981

41
130 Gallagher, R.
Beat Corrosion With Rubber Hose
Chern. Engr., p. 105 (September 8, 1980)

131 Garland, C.E.


New Developments in Materials and Chemical Compatibilities
Proceedings of The Fourth Annual Hazardous Materials
Management Conference, Atlantic City, NJ (June 2-4, 1986)

132 Garland, C.E., L.E. Goldstein, and C. Cary


Testing Fully Encapsulated Chemical Suits in a Simulated
Work Environment
Performance of Protective Clothing, ASTM STP 900, R.L.
Barker and G.C. Coletta, Eds., American Society for Testing
and Materials, Philadelphia, pp. 276··285 (1986)

133 General Scientific Safety Equipment Company


Catalogue
1986

134 Glover Latex, Inc.


Catalogue
1986

135 Gc1dbGrg, H. M., and S. Herszenson


Cutting Oil Dermatitis: Sharpeni:.g worker Defenses
Occupational Health and Safety, p. 30 (May 1982)

136 Goodall Rubber Company


Catalogue
1986

137 Goodyear Rubber Products Corp.


Catalogue
1985

138 Gough, T.A., K.S. Webb, and M.F. L'1c?l-,aU


Diffusion of Nitrosamines through r: -..:'act ive Gloves
Enviromental Aspects of N-Nitroso CQrnpGu.C1ds, (E.A. Walker
M. Castegnaro, L. Griciute, and R.E. Lyle, eds.)
pp. 531-534, Lyon International Agency [or Research
en Cancer (1978)

139 Granet, Inc.


Catalogue
1982

42
140 Green, J., N.B. Levine, and R.C. Keller
Elastomers for·Liquld Rocket Fuel and Oxidizer AppHcat.
I&EC Product Research and Development, 2, p. 126 (1963)

141 Greene Rubber Company, Inc.


Catalogue
1984

142 Haas, T.J., R.B. Gaines, and K.J. Patterson


Permeation Testing of Certain Personal Protective Clothing
Materials by Hazardous Liquid Chemicals
l~84 Hazardous Material Spills Conference Proceedings,
Nashville, TN, April 9-12 (1984)

143 Halprin Supply Co.


Catalogue
1981

144 Hammer, W.M., and K.R. Nicholson


Survey of Personnel Protective Clothing and Respiratory
Apparata for use by Coast Guard Personnel in Response to
Discharges of Hazardous Chemicals
Pollution Prevention Projects, Branch Office of Research
and Development, U.S. Coast Guard, Washington, D.C.

145 Hayes, M.J., and G.S. Park


The Diffusion of Benzene in Rubber - Part I
Trans. Faraday Soc., 51(392), p. 1134 (1955)

146 Heck, W.B., and R.L. Johnson


Aluminum A1ky1s Safe Handling
Ind. and Engr. Chem., 54(12), p. 35 (1962)

147 Henriksen, H. R.
Selection of Materials for Protective Gloves. Polymer
Membranes to Protect Against Contact With Epoxy Products
Danish Directorate of Labor Inspection Services, Cophenbagen
(1982)

148 Henry. N.W. III


How Protective is Protective Clothing?
Performance of Protective Clothing. ASTK STP 900, R.L.
Barker and G.C. Coletta, Eds., American Society for Testing
and Materials, Philadelphia, pp. 51-58 (1986)

149 Henry, N.W., and C.N. Schlatter


The Development of a Standard Method for Evaluating Chemical
Protective Clothing to Permeation by Liquids
Am. Ind. Hyg. Assoc. J., 42, p. 202 (1981)

43
150 Henry, N.W., and J.F. Matheson
Dupont Monograph: Gloves-Their Selection and Testing
Haskell Laboratory for Toxicology and Industrial Medicine
Dupont Company, Wilmington, DE
(August 12, 1980)

151 Hodgman, Inc.


Catalogue
1986

152 Hogstedt, C., and R. Stahl


Skin Absorption and Protective Gloves in Dynamite Work
Am. Ind. Hyg. Assoc. J., 41, p. 367 (1980)

153 Holcomb Safety Garment Company


Catalogue
1984

154 Holland Safety Supply Company


Catalogue
1986 .

155 Hopfenburg, H.B.


Permeability of Plastic Film and Coatings
Plenum Press, N.Y. (1974)

156 Hub Safety Equipment, Inc.


Catalogue
1985

157 Hy-Test Safety Shoes, Inc.


Catalogue
1986

158 ILC Dover Division of ILC Industries. Inc.


Da~a Sheet
1986

159 IPES Company, Inc.


Catalogue
1986

160 Inco Safety Products Company


Catalogue
1981

44
161 Industrial Products Company, Inc.
Catalogue
1984

162 Industrial Safety and Security Company


Catalogue
1986

163 Interex Corp.


Catalogue
1986

164 Intermarket Latex, Inc.


Catalogue
1985

165 International Playtex, Inc., Industrial Glove Division


Catalogue
1986

166 Iron Age Protective Company


Catalogue
1986

167 Jaxco, Inc.


Catalogue
1986

168 Johnson, R.E., and M.D. Lowish


Protection Should Fit Yorker, Job
Occupational Health and Safety (August 1983)

169 Jomac Products, Inc.


Catalogue
1985

170 Jones Safety Supply,Inc.


Catalogue
1986

171 Jordan David Safety Products


Catalogue
1981

45
172 Kappler Disposables, Inc.
Catalogue
1984

173 Kashi, K.P., M. Muthu, and S.K. Majumder


Rapid Evaluation of Phosphine Permeability through Various
Flexible Films and Coated Fabrics
Pestic. Sci., 8, pp. 492-496 (1977)

174 Keller Glove Manufacturing Company


Catalogue
1982

175 Keystone Protection Corp.


Catalogue
1986

176 Kimberly-Clark Corp.


Catalogue
1985

177 Kodak
Functional Group Index of
KODAK Laboratory Chemicals
Kodak Publication No. JJ-1F (January 1981)

178 Kokes, R.J., and F.A. Long


Diffusion of Organic Vapors into Polyvinyl Acetate
J. Amer. Chem. Soc., 75, p. 6142 (1953)

179 LRC Safety Products Company


Catalogue
1984

180 La Crosse Footwear, Inc.


Catalogue
1986

181 Latex Glove Company, Inc.


Catalogue
1986
182 Lehigh Safety Shoe Company
Catalogue
1986

46
183 Leonard Safety Equipment, Inc.
Catalogue
1986

184 Levine, S.P., and Martin, W.F.


Protecting Personnel at Hazardous Waste Sites
Butterworth Publishers, Stoneham, MA, 1985

185 Lilani, H.N.


Non-Asbestos Fabrics Perform Against Heat and Metal
Splashes, Occupational Health & Safety, pp. 58-61
(January 1986)

186 Llnnarson, A.
Penetration of Solvents Through Plastic Material
Lagersrapport, Forsvarets Forskningsansta1t, Stockholm
pp. 17 (1977)

187 Linnarson, A., and K. Halvarson


Study of Polymer Material Permeability for Organic Compounds
FOA Report C-204l4-H2, Progress Report, Stockholm, 1981

188 Lion Uniform, Inc.


Catalogue
1985

189 Lloyd, G.A.


Summarized Results of Permeation Tests on Protective
Clothing Materials
Ministry of Agriculture Fisheries and Food, Operator
Protection Research Group, Information Sheet No. 19,
(June 1986)

190 Lloyd, G.A.


Efficiency of Protective Clothing for Pesticide Spraying
Performance of Protective Clothing, ASTM STP 900, R.L.
Barker and G.C. Coletta, Eds., American Society for Testing
and Materials, Philadelphia, pp. 121-135 (1986)

191 Lynch, A.L.


Protective Clothing in Handbook of Laboratory Safety
2nd Edition, N.V. Steeve editor
CRC Press, Boca Raton, FL (1971)

192 Lynch, P.
Matching Protective Clothing to Job Hazards
Occupational Health and Safety, p. 30 (January 1980)

47
193 MacDonald, R.W., and R.Y.M. Huang
Permeation of Gases Through Modified Polymer Films V.
Permeation and Diffusion of Helium, Nitrogen, Methane
Ethane, and Propane through gamma-Ray Crosslinked
Polyethylene
J. Appl. Poly. Sci., 26, pp. 2239-2263 (1981)

194 Magid Glove and Safety Manufacturing Company


Catalogue
1985

195 Major Safety Service, Inc.


Catalogue
1984

196 Mar-Mac Manufacturing Company, Inc.


Catalogue
1986

197 Marathon Rubber


Catalogue
1986

198 Martone, J.A., and Bergen, G.A.


A Rocket Propellant Handler's Suit for Protection from
Chlorine Trifluoride and Elemental Fluorine
Technical Report AFRPL-TR-7l-44 (August 1971)
NTIS AD731556

199 Masterman's
Catalogue
1986

200 Mathias, C.G.T.


Managing Hand Dermatitis in the Workplace
Occupational Health and Safety, p. 46 (May 1982)

201 McFee, D.R.


How Well Do Gloves Protect Hands Against Solvents
A.S.S.E. Journal, 9, p. 11 (May 1964)

202 McGuffey, J.R., R. Paluzelle, and W.E. Muldrew


Handling Gaseous Fluorine in Industry
Ind. and Engr. Chem., 54(5), p. 46 (1962)

48
203 McNaughton, K.J.
The ABCs of Occupational Skin Disease - Part II
Chern. Engr., p. 149 (April 19, 1982)

204 Meade, J., W. Ellis, and J. Ludington


Evaluation of the Resistance of a Chlorinated Polyethylene
Protective Garment Material to Permeation and Degradation by
Liquid Chemicals
U.S. Environmental Protection Agency Contract No. 68-03-3113
(1985)

205 Meares, P.
Transient Permeation of Organic Vapors through
Polymer Membranes
J. of Applied Polymer Science, 9, p. 917 (1-965)

206 Melco, Inc.


Catalogue
1986

207 Memphis Glove Company


Catalogue
1986

208 Middleton, H. W.
Glove Corrosive Liquid Immersion and Permeability Study
Report on U. S. Energy Research and Development
Administration contract EY-76-C-04-0656 (August 1977)

209 Mihal, C.P., Jr.


Effect of Heat Stress of Physiological Factors for
Industrial Workers Performing Routine Work and Wearing
Impermeable Vapor-Barrier Clothing
Am. Ind. Hyg. Assoc. J., (February 1981)

210 Mikatavage, M., S.S. Que Hee, and H.E. Ayer


Permeation of Chlorinated Aromatic Compounds Through Viton
and Nitrile Glove Materials
Am. Ind. Hyg. Assoc. J., 45(9), pp. 617-621 (1984)

211 Mikkelson, T.J., S. Watanabe, J.H. Rytting, andT. Hi.guchi


Effect of Self-Association of Phenol on Its Transport
Across Polyethylene Film
J. Pharm. Sci., 69, p. 133 (1980)

212 Miller Products Company, Inc.


Catalogue
1986

49
213 Mine Safety Appliances Company
Data Sheets
13-00-07, 13-00-17, and 13-00-18
1986

214 Monte Glove Company


Catalogue
1981

215 Morrow, R.W., and J.H. Hamilton


Moca Permeation of Protective Clothing
Prepared for Department of Energy Under U.S. Government
Contract W-7405 eng. 26

216 Moursiden, J.T., and O. Faber


Penetration of Protective Clothing By Allergens and
Irritants
Trans. St. John's Hosp. Dermatol. Soc., 59, p. 230 (1973)

217 Mueller, W.J.


Permeability of Rubber to Organic Liquids
Rubber Age, p. 982 (September 1957)

218 National Draeger, Inc.


Catalogue
1986

219 National Research Council


Prudent Practices for Handling Hazardous Chemicals in
Laboratories
National Academy Press, Washington, DC (1981)

220 National Safety Wear, Inc.


Catalogue
1984

221 National Tech. Info. Service


Protective Clothing: Industrial Environments.
Protective Clothing for Industrial Atmospheres Including
Protection from Explosive Materials and Fuels
U. S. Department of Commerce, NTIS, PB83-'804922

222 Nelson, G.O., B. Lum, G. Carlson, C. Wong, and J. Johnson


Glove Permeation by Organic Solvents
Am. Ind. Hyg. Assoc. J., 42(3), p. 217 (1981)

50
223 Nelson, G.O., G.J. Carlson, and A.L. Buerer
Glove Permeation by Shale Oil and Coal Tar Extract
Lawrence Livermore Laboratory, UCRL 52893 (1980)

224 Nesse Industries, Inc.


Catalogue
1984

225 Newns, A.C., and G.S. Park


The Diffusion Coefficient of Benzene in a Variety of
Elastomeric Polymers
J .. Polymer Sci. Part C, 22(2), pp. 927-937 (1969)

226 Niles, H.M.


Selecting Gloves for Handling Toxic Liquids Involves
Several Factors, Occupational Health & Safety, pp. 34-36
(December 1985)

227 North Hand Protection, Div. of Siebe North, Inc.


Catalogue
1986

228 O'Brien, J.
Proper Sole Selection Key to Safety Footwear Comfort,
Protection, Occupational Health & Safety, pp. 52-53
(February 1986)

229 O.K.!. Supply Company


Catalogue
1981

230 Oak Medical Supply Company


Catalogue
1981

231 Oak Technical, Inc.


Catalogue
1986

232 PPG Industries, Inc.


Catalogue
A-69l-45C, 10M, 179, 1986

233 Panelgraphic Corporation


Catalogue
1986

51
234 Pendergast Safety Equipment Company
Catalogue
1984

235 Perkins, J.L., and A.D. Tippit


Use of Three-Dimensional Solubility Parameter to Predict
Glove Permeation
Am. Ind. Hyg. Assoc. J., 46, pp. 455-459 (August 1985)

236 Pioneer Industrial Products, Division of Brunswick Corp.


Catalogue M-104-l
1986

237 Plastex Protective Products, Inc.


Catalogue
1986

238 P1astimayd Corp.


Catalogue
1986

239 Podkowka, J., and Puchalik, A.


Comparative Evaluation of Diffusion Coefficients
for Gases and Vapors of Organic Substances through
Polyethylene Membranes Determined by Absorption and
Desorption Upstream Time Lag Method
J. Appl. Poly. Sci., 27, pp. 1471-1478 (1982)

240 Polakoff, P.L.


Chemical Mixture Hazard Evaluation Differs from that of
Single Substances, Occupational Health & Safety, pp. 55-56
(September 1985)

241 Prager, S., and F.A. Long


Diffusion of Hydrocarbons in Po1yisobuty1ene
J. Amer. Chem. Soc., 73, p. 4072 (1951)

242 Protech Safety Equipment, Inc.


Catalogue
1986

243 Protexall Company


Catalogue
1986

244 Pulmosan Safety Equipment Corp.


Catalogue
1984

52
245 Rainfair, Inc.
Catalogue
1986

246 Ranger
Catalogue
1985

247 Record Industries Company


Catalogue
1986

248 Renco Corp.


Catalogue
1984

249 Richards, R.W.


The Permeability of Polymers to Gases, Vapors and Liquids
Tech. Report No. 135, Ministry of Defense Explosives
Research and Development Establishment (March 1973)

250 Riley, M.W., D.J. Cochran, and C.A. Schanbacher


Force Capability Differences Due to Gloves
Ergonomics, 28(2) pp. 441-447 (1985)

251 Robar Protective Products


Catalogue
1981

252 Rockford Medical & Safety Company


Catalogue
1986

253 Rogers, C.E., V. Stannett, and M. Szwarc


The Sorption, Diffusion,and Permeation of Organic Vapors
in Polyethylene
J. Poly. Sci., 45, pp. 61-82 (1960)

254 Ronco Textile Products, Inc.


Catalogue
1986

255 Ronk, R., M.K. White, and H. Linn


Personal Protective Equipment for Hazardous Materials
Incidents: A Selection Guide, NIOSH, DHHS (NIOSH)
Publication No. 84-114, (October 1984)

53
256 SGL Homalite Division of SGL Industries, Inc.
Catalogue
0776-5H

257 Safeco, Inc.


Catalogue
1986

258 Safety Engineering & Supply Company


Catalogue
1986

259 Safety First, Industries


Catalogue
1986

260 Sager Corporation, Racine Glove Division


Catalogue
1986

261 Salame, H., and S. Steingiser


Barrier Polymers
Presented at the Am. Chem. Soc. Symposium in New York City
(Hay 1976)

262 Salame, S.
The Prediction of Liquid Permeation in
Polyethylene and Related Polymers
SPE Transactions (October 1961)

263 Salisbury, W.H. & Company


Catalogue
1986

264 Sansone, E.B., and L.A. Jonas


Resistance of Protective Clothing Haterials to
Permeation by Solvent "Splash"
Environmental Res., 26, pp. 340~346 (1981)

265 Sansone, E.B., and L.A. Jonas


The Effect of Exposure to Daylight and Dark Storage
on Protective Clothing Haterial Permeability
Am. Ind. Hyg. Assoc. J., 42(11), pp. 841-843 (1981)

266 Sansone, E.B., and Y.B. Tewari


The Permeability of Laboratory Gloves to Selected Solvents
Am. Ind. Hyg. Assoc. J., 39(2), p. 169 (1978)

54
267 Sansone, E.B., and Y.B. Tewari
The Permeability of Laboratory Gloves to
Selected Nitrosamines
Environmental Aspects of N-Nitroso Compounds (E. A. Walker
M. Castegnaro, L. Griciute and R.E. Lyle, eds.),
Lyon International Agency for Research on Cancer
pp. 517-529 (1978)

268 Sansone, E.B., and Y.B. Tewari


Differences in the Extent of Solvent Penetration Through
Natural Rubber and Nitrile Gloves From Various Manufacturers
Am. Ind. Hyg. Assoc. J., 41, pp. 527-528 (July 1980)

269 Sansone, E.B., and Y.B. Tewari


The Permeability of Protective Clothing Materials to
Benzene Vapor
Am. Ind. Hyg. Assoc. J., 41(3), pp. 170-174 (1980)

270 Sansone, E.B.', and Y.B. Tewari


Penetration of Protective Clothing Materials by l,2-Dibromo-
3-Chloropropane, Ethylene Dibromide, and Acrylonitrile
Am. Ind. Hyg. Assoc. J., 39, pp. 921-922 (November 1978)

271 Sawyer-Tower
Catalogue
1986

272 Schlatter, C.N.


Permeation Resistance of Gloves After Repeated Cleaning
and Exposure to Liquid Chemicals
Edmont Division, Becton, Dickinson and Company

273 Schlatter, C.N., and D.J. Miller


Influence of Film Thickness on the Permeation Resistance
Properties of Unsupported Glove Films
Performance of Protective Clothing, ASTK STP 900, R.L.
Barker and G.C. Coletta, Eds., American Society for Testing
and Materials, Philadelphia, pp. 75-81 (1986)

274 Schoch, D.H., L.K. Tersegno, J.E. Winter, D.G. Bush, and
R.L. James
Testing of "Impervious" Gloves for Permeation by Organic
Solvents, American Industrial Hygiene Conference,
Cincinnati, OH (June 6-11, 1982)

275 Schwope, A.D.


The Effectiveness of TYVEK Composites as Barriers To
AROCLOR 1254 (PCB), Trich1orobenzene, and Mineral Spirts
Report to Textile Fibers Dept., The Dupont Company
from Arthur D. Little (1979)

55
276 Schwope, A.D .• M.A. Randel, and M.G. Broome
Dimethyl Sulfoxide Permeation through Glove Materials
Am. Ind. Hyg. Assoc. J., 42(10), pp. 722-725 (1981)

277 Shelby-Wolverine Glove Company


Catalogue
1986

278 Silkowski, J.B., S.W. Horstman, and M.S. Morgan


Permeation Through Five Commercially Available Glove
Materials by Two Penachlorophenol Formulations
Am. Ind. Hyg. Assoc. J., 45, pp. 501-504 (August 1984)

279 Singer Safety Company


Catalogue
1985

280 Smith, I.D., and J. Roepke


Personnel Protection Equipment for Use With Laser Chemicals
NASA and LEMSCO, White Sands Test Facility, AD-P004-490
(May 1984)

281 Smolander, J., V. Louhevaara, and Korhonen, O.


Physiological Strain in Work with Gas Protective Clothing
at Low Ambient Temperature, Am. Ind. Hyg. Assoc. J., 46,
pp. 720-723 (December 1985)

282 Snyder, F.J., C.F. Macy, L.A. Spane, and V.D. Iacono
Protection Capability of U.S. Army's POTMC Against Hazards
Posed by 900 Hazardous Chemicals
U.S. Army Natick R&D Command, 1976

283 Snyder, L.
Solutions to Solution Problems--1
Chemtech
(December 1979)

284 Snyder, L.
Solutions to Solution Problems--2
Chemtech
(March 1980)

285 Soles, E., J.M. Smith, and W.R. Parrish


Gas Transport through Polethylene Membranes
AIChE Journal, 28(3), pp. 474-479 (1982)

S6
286 Spain, W.H., and J.L. Burson
Selective Protective Clothing with Six C's
Occupational Health and Safety, pp. 17-23 (September 198.

287 Spence, M. W.
Chemical Permeation through Protective Clothing Material:
An Evaluation of Several Critical Variables
Paper Presented at the American Industrial Hygiene
Conference, Portland, OR (May 1981)

288 Spence, M.W.


Glove Materials for Chlorinated Solvents: Permeation
Resistance Comparison for Four Solvents
American Industrial Hygiene Conference, Detroit, MI
(May 21-25, 1984)

289 Sperling, L., B. Jonsson, I. Holmer, and T. Lewin


Test Program for Work Gloves
Department of Occupational Safety, Division for Occupational
Medicine, Labor Physiology Unit in Umea, Sweden, Research
Report 1980:18 (1980) (translated from Swedish)

290 Stampfer, J.F., M.J. McLeod. A.M. Martinez. M.R. Betts, and
S.P. Berardinelli
Permeation of Polychlorinated Biphenyls and Solutions of
These Substances Through Selected Protective Clothing
Materials
Am. Ind. Hyg. Assoc. J .• 45(9), pp. 634-641 (1984)

291 Stampfer. J~F., M.J. McLeod, M.R. Betts. A.M. Martinez, and
S.P. Berardinelli
The Permeation of Eleven Protective Garment Materials by
Four Organic Solvents
Am. Ind. Hyg. Assoc. J .• 45, pp. 642-654 (1984)

292 Stampfer, J.F., M.J. McLeod, M.R. Betts. A.M. Martinez, and
S.P. Berardinelli
Chemical Permeation - A Summary Report of Recent NIOSH-
Directed Studies at the Los Alamos National Laboratory
Am. Ind. Hyg. Assoc. J., 45, pp. B-lO to B-12
(January 1984)

293 Stampfer, J.F., and R.J. Beckman


A Screening Test for Selecting Chemical Protective Clothing
Los Alamos National Laboratory, Los Alamos, NM

294 Standard Glove & Safety Equipment Corp.


Catalogue
1986

57
295 Standard Safety Equipment Company
Catalogue
1986

296 Stannett, V., and H. Yasuda


Liquid Versus Vapor Permeation Through Polymer Films
J. Poly. Sci. Part B, Poly. Letters, 1(6), pp. 289-293
(1963)

297 Stauffer Manufacturing Company


Catalogue
1986

298 Steel Grip Safety Apparel Company, Inc.


Catalogue
1986

299 Steele & Associates, Inc.


Catalogue
1986

300 Stokoe, A.L., and K.J. Ledbury


Permeability of Polymers to Organic Fluids
Tech. Report No. 18, Ministry of Technology Explosives
Research and Development Establishment
Waltham Abby, Essex, England (February 1970)

301 Streng, D.R., W.F. Martin, L.P. Wallace, and G. Kleiner


Hazardous Waste Sites and Hazardous Substance Emergencies
Worker Bulletin
DHHS (NIOSH) Publication No. 83-100

302 Stull, J.O., V.L. Man, V.A. Bastecki, and A.P. Bentz
A Comprehensive Materials Evaluation Program to Support the
Development and Selection of Chemical Protective Clothing
1986 Hazardous Material Spills Conference Proceedings,
St. Louis, Missouri (May 5-8, 1986)

303 Stull, Jeffrey


Personal Communication.
U.S. Department of Transportation, Coast Guard
(August 1986)

304 Superior Surgical Manufacturing Company, Inc.


Catalogue
1986

58
305 Sweeting, O.J. (editor)
The Science and Technology of Polymer Films
Volume II, Wiley-Interscience, New York (1970)

306 Texier, H. Glove Company, Inc.


Catalogue
1985

307 3M Company
Catalogue
1'986

308 Tingley Rubber Corp.


Catalogue
1985

309 Tracies Co., The


Catalogue
1986

310 Trel1eborg, A.B.


Resistance Table
Trelleborg A.B. (Sweden)

311 Tre1leborg, Inc.


Catalogue
1986

312 United States Plastic Corp.


Catalogue
1986

313 United States Safety Service Company


Catalogue
1986

314 Vaccari, J.A.


Guide to Selecting Elastomers
Product Engineering, p.36 (July 1978)

315 Van Amerongen, G.J.


Diffusion in Elastomers
Rubber and Chem. Tech. Rubber Reviews for 1964, 37(5),
pp. 1065-1152 (1964)

59
316 Varos, J.
Consider Abrasion Risk, Chemicals When Choosing Gloves
Occupational Health & Safety, pp. 60,62 (March 1986)

317 Vidaro Corp.


Catalogue
1981

318 Vrentas, J.S., H.T. Liu, and J.L. Duda


Effect of Solvent Size on Diffusion in Polymer-Solvent
Systems
J. Appl. Poly. Sci., 25, pp. 1793-1797 (1980)

319 Vrentas, J.S., and J.L. Duda


Diffusion of Large Penetrant Molecules in Amorphous Polymers
J. Poly. Sci., Phys. Ed., 17, pp. 1085-1096 (1979)

320 Waack, R., N.H. Alex, H.L. Frisch, V. Stannett, and M.Szwarc
Permeability of Polymer Films to Gases and Vapors
Ind. and Engr. Chern., 47(12), pp. 2524-2527 (1955)

321 Wakefield, M.E., and M.S. Hall


Development of a Specification for an Improved Ensemble
for Propellant Handlers
Final Report on NASA Contract NASlO-97l4, MCR-80-647
(December 1980)

322 Walker, E.A., M. Castegnaro, L. Garren, and B. Pignatelli


Limitations to the Protective Effect of Rubber Gloves
for Handling Nitrosamines
Environmental Aspects of N-Nitrosamines Compounds
(E.A. Walker, M. Castegnaro, L. Griciute, and R.E. Lyle,
eds.), Lyon International Agency for Research on Cancer,
pp. 535-542 (1978)

323 Walters, D.
Personal Communication. National Toxicology Program
Glove Performance Study Performed by Radian
Corporation, Austin, Texas (June 1986)

324 Weaver, L.A.


Hazardous Site Water Restrictions Pose Problem for Exposed
Workers, Occupational Health & Safety, pp. 54-58 (May 1985)

325 Weeks, R.W., Jr., and B.J. Dean


Permeation of Methano1ic Aromatic Amine Solutions Through
Commercially Available Glove Materials
Am. Ind. Hyg. Assoc. J., 38, pp. 721-725 (1977)

60
326 Weeks, R.W., Jr., and M.J. McLeod
Permeation of Protective Garment Material by Liquid
Halogenated Ethanes and a Polychlorinated Biphenyl
u.s. Dept. of Health & Human Services, NIOSH Publication
No. 81-110 (January 1981)

327 Weeks, R.W., Jr., and M.J. McLeod


Permeation of Protective Garment Material By Liquid
Benzene and by Tritiated Water
Am. Ind. Hyg. Assoc. J., 43, pp. 201-211 (1982)

328 Weitzman, D., and L.C. Jonas


Industrial Hygiene Program for Hazardous Waste Site
Investigations
Am. Ind. Hyg. Assoc. J., 42, pp. 653-655 (1981)

329 Wells, Dr. J.W.,


Equipment Innovations Cut Risks for Divers in Polluted
Waters, Sea Technology, p.22-23 (December 1984)

330 Wheeler Protective Apparel, Inc.


Catalogue
G12, 1986

331 Wheeler, C.P., and Goldberg, H.M.


Hazard Education Must Overcome Generalities
Occupational Health and Safety, pp. 31-34 (September 1983)

332 Wilcher, F.E.


ISEA Forms Unit to Certify Personal Protective
Equipment
National Safety News, p. 36 (September 1981)

333 Williams, J.R.


Permeation of Glove Materials by Physiologically
Harmful Chemicals
Am. Ind. Hyg. Assoc. J., 40(10), pp. 877-882 (1979)
334 Williams, J.R.
Chemical Permeation of Protective Clothing
Am. Ind. Hyg. Assoc. J., 41, pp. 884-887 (1980)

335 Williams, J.R.


Evaluation of Intact Gloves and Boots for
Chemical Permeation
Am. Ind. Hyg. Assoc. J., 42, pp. 468-471 (1981)

61
336 Willson Safety Products
Catalogue
1985

337 Wittenberg, L.J.


Experimental Verification of Tritium Control by Glove-Box
Containment
Nuclear Technology, 38, pp. 434-440 (Kay 1978)

338 Wolfe, P.R., and L.A. Rich


FEMA's Strategy for Emergency Response
Chemical Week, p. 15 (July 3, 1985)

339 Worklon
Catalogue
1981

340 ZippIer, D.B.


Personal Protective Clothing
1984 Occupational Health and Safety Symposium, Wilmington,
DE (October 3-5, 1984)

62
APPENDICES

63
DESCRIPTION OF COLUMN HEADINGS
FOR APPENDICES A THROUGH E

Chemical Name: Alphabetical listing of chemicals as


shown in Appendix B of Volume I.
Synonym, if given, in parentheses.

CAS No: Chemical Abstract Service (CAS)


Registry Number.

Resistant Material: The normally outside material of the


CPC (i.e., the chemical contact sur-
face). See Appendix E of Volume I.

Product Description: See column 1 of Appendix E in


Volume I.

Vendor: See Appendix E of Volume II.


UNK - Unknown.

Breakthrough Time: See Appendix A of Volume I.

Penneation Rate: See Appendix A of Volume I.

Percent Weight Change/ Change in weight of CPC specimen


Immersion Time: due to immersion in chemical for
time indicated.

Percent Swell/ Volume change due to immersion in


Immersion Time: chemical for time indicated.
b 2
Diffusion Coefficient: a x 10 cm /sec.

Temperature: Test temperature, if reported; other-


wise assumed to be 25°C.

Thickness: Initial thickness of test specimen,


if reported; otherwise no value is
given.

Ref Number: Source of data. See Bibliography.

64
APPENDIX A

PERMEATION DATA

A-l
SUMMARY OF PERFORMANCE DETAIL TESTS
PERllEATlON TEST

CHEMICAL IIAME/ RESIST AliT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATlOli RATE TEMP THICKNESS REF
CASIIO MATERIAL DESC CODE HOURS UG/CM**21M III OEG C CM NtII

Acetaldehyde
000750700 BUTYL 014 118 9.58 .40 23. .04 323
9.60 .40 23. 227
CPE 060 113 .17 . •50 25 • .07 302
UIOC • 66 23 • 142
•28 23 • 142
IlATlIW. RUBBER 001 103 48.10 23. 045
017 100 • 12 90.18 901.80 23 • .05 107
1lE000ENE 002 100 •28 901.80 · 9,018.00 23 • 107
018 100 .20 199.00 23. .05 323

125
.17 901.80 · 9,018.00 23. .04 107
103 n.14 23. 045
NITRILE 019 103 529.06 23. 045
118 < .01 967.93 23. .03 323
.07 967.93 23. .04 227
NITRILE+PVC 058 100 •05 901.80 9,018.00 23 • 107
PE 076 100 .05 901.80 9,018.00 23. 107
PV ALCOHOL 102 100 .27 282.56 23. .03 323
PVC 007 103 264.53 23. 045
077 100 .05 9.02 · 90.18 23. 107

SILVER SHIELD
.08 901.80 · 9,018.00 23. 107
122 118 > 6.00 23. .01 227
TEFLON 069 510 > 3.00 < •02 23 • .05 303
VITON 009 118 < •01 1,694.78 23 • .03 323
VITON/CHLOROBUTYL 112 113 .50 . • 66 25 • .04 302
UNK > 3.00 23. 142

Acetic Acid
000641970 CPE 060 113 > 3.00 25. .07 302
3.95 23. .05 204
2.40 42.08 23. .05 204
NATURAL RUBBER 001 UNK • 68 23 • 052
015 UNK • 85 23 • .04 052
017 100 2.25 23. .05 107
102 4.50 23. .05 026
2.50 23. .05 026
1.50 23. .05 026
2.00 23. .05 026
IIEOP+NAT RUBBER 026 102 1.50 23. .06 026
1.50 23. .04 026
3.50 23. .05 026
121 1.27 96.19 23. .05 237
NEOP/IIAT RUBBER 008 102 3.50 23. 026
UNK > 1.00 23. 052
NEOPRENE 002 100 > 6.00 23. 107
210 6.00 23. 080
018 100 7.00 23. .04 107
UNK > 1.00 23. .06 052
> 1.00 23. .09 052
NITRILE 005 210 6.00 < •02 23 • 080
019 100 4.50 23. .06 107
UIIK > 1.00 23. .05 052

A-2
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NANEI RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS UG/CH**21MIN DEG C CM NUH

.~
000641970 NITRILE+PVC 057 210 6.00 < •02 23 • 080
058 100 .27 23. 107
PE 076 100 .zs 23. 107
127 5.00 23. 104
PVC 003 UNIC .08 23. .02 052
007 100 3.00 23. 107
210 4.00 12.02 23. 080
UNIC > 1.00 23. 052
077 100 .75 23. 107
.10 23. 107
SARANEX 061 127 > 66.67 23. 104
TEFLON 069 510 > 4.00 < •02 zs . .05 303
VITON 009 UNIC > 1.00 23. .03 052
VITON/CHLOROBUTYL 112 113 > 3.00 zs. .04 302

Acetic Acid, >70%


000641973 NATURAL RUBBER 001 1ZO .35 18.04 23. .05 Z36
NITRILE 005 120 1.97 1,328.65 23. .06 Z36
PVC 003 1ZO 1.42 1.80 23. .08 Z36

Acetic Anhydride
001082470 BUTYL 014 118 > 8.00 < •02 23 • .09 323
CPE 060 113 1.ZS 23. .05 204
1.ZO 54.11 23. .05 204
NATURAL RUBBER 001 ZSO .05 10.02 20. .02 323
NEOPRENE 018 100 3.50 6.01 20. .05 323
PVC 007 100 .07 1ZO.24 20. .02 323
TEFLON 069 510 > 3.00 < •02 23 • .05 303

Acetone
000676410 BUTYL 014 118 > 20.33 23. .08 323
> 17.00 23. .04 227
216 > 4.00 21. .07 124
CPE 060 113 .33 · .42 25. .07 302
.53 · .58 22. .07 302
.45 · .52 ZS. .07 302
.28 23 • .05 204
•ZS 1,022.04 23. .05 204
NATURAL RUBBER 001 103 288.58 23. 045
210 .10 60.12 23 • 080
UNK •23 35.07 23. .12 274
017 100 .09 110.22 25. .03 222
.17 90.18 . 901.80 23. .05 107
102 .13 4.81 23 • .05 026
• 17 9.02 23. .05 026
.13 5.41 23 • .05 026
• 15 7.21 23 • .05 026
120 •04 210.42 25. .02 222
502 .10 82.16 25. .05 222
504 .ZS 66.13 25 • .05 222
•45 45.09 25 • .06 222
UNIC •10 > 140.28 23. .04 274
NEOP+NAT RUBBER 026 102 .08 100.20 25. .05 222

A-3
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST

CHEMICAl lIANE/ RESISTAIIT PRmtJCT VE8IDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKIIESS REf
CASIIO MATERIAL DESC CODE HOURS UG/CM**2/MIII OEG C CM IIUM

000676410 NEOP+IIAT JUlIER 026 102 • 12 8.42 23 • .06 026


• 08 12.63 23 • .04 026
• 13 4.81 23 • .05 026
121 • 05 126.25 23 • .05 237
NEOP/MAT RUBlER 008 102 .13 4.81 23. 026
114 .13 46.09 25. .05 222
UNIC • 13 > 150.30 23 • .05 274
IIEOPREIIE 002 100 .17 90.18 901.80 23. 107
• 04 180.36 25 • .08 222
120 • 04 310.62 25 • .07 222
210 • 10 n.14 23 • 080
018 100 • 23 334.27 23 • .05 323
.08 90.18' 901.80 23. .04 107
118 •95 86.17 25 • .08 222
120 .32 140.28 25. .05 222
.53 110.34 25. .07 222
• 55 90.18 25 • .05 222
• 27 140.28 25 • .03 222
> 1.00 23. .09 274
•43 120.24 23 • .06 274
125 103 1,557.11 23. 045
II ITR IlE 005 210 .33 480.96 23. 080
019 100 .09 2,004.00 25. .04 222
.22 < 801.60 25. .06 222
• 08 < 801.60 25 • .04 222
181 .07 801.60 25. .03 222
503 .05 1,503.00 25. .03 222
UIIC .08 > 150.30 23. .05 274
• 10 > 110.22 23 • .05 274
I ITR ILE+PVt 057 210 .25 312.62 23. 080
PE 006 100 > 1.00 < 30.06 25. .01 222
505. •07 2.00 25 • .01 222
076 100 .05 9.02' 90.18 23. 107
PV ALCOHOl 004 100 > 4.00 21. 124
UNIC .50 > 60.12 23. .12 274
102 100 •07 13.83 23 • .04 323
007 210 .30 541.08 23. 080
UNIC .15 > 140.28 23. .16 274
SARAIIEX 061 127 .55 19.84 23. 104
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEFLON D69 510 > 3.00 < .02 23. .05 303
> 3.50 < .02 25. .05 303
VITON 009 118 < •01 4,843.87 23 • .02 323
UNIC •03 > 150.30 23 • .03 274
VITON/CHlOROBUTYL 112 113 .87 • 1.28 25. .04 302
1.58 • 1.63 20. .04 302
.n . .88 27. .04 302
.88 1.02 25. .04 302

Acetonitrile
000750580 BUTYL 014 118 > 8.00 23. .07 323
> 8.00 23. .04 227
064 117 > 8.00 23. .02 213

A-4
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM

000750580 BUTYL 064 117 > 8.00 23. .01 213


> 8.00 23. .02 213
BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213
CPE 060 113 1.33 1.42 25. .07 302
NATURAL RUBBER 001 103 150.30 23. 045
506 < •01 117.23 23 • .01 323
NEOPRENE 018 100 1.27 10.82 23. .06 323
093 117 < .18 23. .02 213
125 103 72.14 23. 045
138 117 • 58 23 • .03 213
139 117 • 83 23 • .01 213
NITRILE 019 103 66.13 23. 045
PE 076 117 < • 01 23 • .02 213
PV ALCOHOL 102 100 > 8.00 23. .04 323
PVC 007 103 66.13 23. 045
049 117 .05 23. .01 213
SARANEX 061 117 > 8.00 23. .01 213
SILVER SHIELD 122 118 > 8.00 23. .01 227
TEFLON 069 510 > 4.50 < .02 25. .05 303
VITON 145 117 > 8.00 23. .01 213
VITON/CHLOROBUTYL 112 113 1.50 . 1.75 25. .04 302
VI TON/NEOPRENE 111 117 .75 23. .02 213

Acetophenone
000988620 TEFLON 069 510 > 92.00 < .02 25. .05 303

Acetyl Chloride
000753650 SARANEX 061 127 .62 1.10 23. 104
TEFLON 069 510 > 3.10 < .02 23. .05 303

Acrolein
001070280 BUTYL 014 118 > 15.00 23. .06 323
CPE 060 UNIC .13 23. 142
.92 23. 142
NITRILE 019 100 .07 966.13 23. .04 323
PV ALCOHOL 102 100 .25 3.01 23. .03 323
VITON 009 118 < •01 432.86 23 • .02 323
VITON/CHLOROBUTYL 112 UNIC > 3.00 23. 142

Acryl ic Acid
000791070 TEFLON 069 510 > 3.00 < .02 23. .05 303

Acryloni tri le
001071310 CPE 070 UNIC .28 23. .05 004
PE 076 127 .08 < .02 23. 104
SARANEX 061 127 .38 < .02 23. 104
TEFLON 069 510 .90 .08 23. 303

Allyl Alcohol
001071860 BUTYL 014 UNIC > 8.17 25. 287
064 117 > 8.00 23. .02 213
> 8.00 23. .01 213
> 8.00 23. .02 213

A-S
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICICNESS REF
CASNO MATEalAL OESC CODE HOURS UG/CM**2/MIN DEG C eM NUM

001071860 BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213


CPE 070 UNK 2.00 23. .05 004
NEOPRENE 002 UNIC 2.35 1.44 25. 287
093 117 1.58 23. .02 213
138 117 6.08 23. .03 213
139 117 3.42 23. .02 213
PE 076 117 1.67 23. .01 213
PV ALCOHOL 004 lINK .24 33.07 25. 287
PVC 049 117 1.75 23. .01 213
077 117 < .08 23. .01 213
SARANEX 061 117 > 8.00 23. .01 213
TEFLON 069 510 > 3.10 < .02 23. .05 303
VITON 145 117 > 8.00 23. .01 213
VI TON/NEOPRENE 111 117 > 8.00 23. .02 213

Allylamine
001071190 BUTYL 014 118 3.92 70.14 20. .06 323
NATURAL RUBBER 001 250 < .02 6,633.24 20. .01 323
PV ALCOHOL 102 100 .20 12,114.18 23. .07 323
PVC 007 100 < .02 9,829.62 20. .02 323

All yl Ch loride
001070510 CPE 070 UNK 1.25 23. .05 004
TEFLON 069 510 1.70 < .02 23. .05 303
2.76 < .02 23. .05 303

Anmonillll Fluoride, 30·rox


121250182 NATURAL RUBBER 017 100 > 6.00 23. .05 107
NEOPRENE 002 100 > 6.00 23. 107
018 100 > 6.00 23. .04 107
IITRILE 019 100 > 6.00 23. .06 107
PVC 007 100 > 6.00 23. 107

Anmonillll Hydroxide
013362160 NATURAL RUBBER 001 210 2.00 23. 080
NEOP+NAT RUBBER 026 121 .45 18.04 23. .05 237
NEOPRENE 002 210 6.00 < .02 23. 080
NITRILE 005 210 6.00 < .02 23. 080
NITRIlE+PVC 057 210 3.00 23. 080
058 100 .18 23. 107
PE 076 100 .07 23. 107
PVC 007 210 .75 23. 080
077 100 > 6.00 23. 107
.30 "23. 107

Anmonillll Hydroxide, <3OX


013362161 NATURAL RUBBER 001 UNK > 1.00 23. 052
017 100 1.75 23. .05 107
NEOPRENE 002 100 > 6.00 23. 107
018 100 > 6.00 23. .04 107
UNIC > 1.00 23. .06 052
> 1.00 23. .09 052
NITRILE 019 100 > 6.00 23. .06 107

A-6
SUMMARY OF PERFORMAIICE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PROOUCT VEIIDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS Ref
CASIIO MATERIAL DESC CODE HOURS UG/CM**21MIN DEG C eM NUM

013362161 IIITRILE 019 UIIIC > 1.00 23. .05 052


PVC 003 UNIe •02 23 • .02 052
007 100 4.00 23. 107
VITOII 009 UNIe > 1.00 23. .03 052

ABnonhn Hydroxide, 3O.7QX


013362162 PE 076 127 < .02 10.32 23. 104

~l Acetate (Pentyl Acetate)


006286310 IlATURAL RUBBER 001 210 .20 60.12 23. 080
IIEOPREIIE 002 210 .25 66.13 23. 080
IIITRILE DOS 210 .67 30.06 23. 080
019 100 1.00 9.02 90.18 23. .06 107
IIITRILE+PVC 057 210 .83 42.08 23. 080
P£ 076 100 < .05 9.02 • 90.18 23. 107
PV ALCOIIOl 004 100 > 6.00 < .90 23. 107
PVC 007 210 .50 48.10 23. 080

Myl Alcohol (Pent_l>


000714100 BUTYL 014 118 > 8.00 < .02 23. .07 323
IlATURAl RUBBER 017 100 .12 .90 • 9.02 23. .05 107
IIEClPlEIiE 002 100 > 6.00 < .90 23. 107
018 100 > 6.00 < .90 23. .04 107
5.35 .20 23. .05 323
II ITRI LE 019 100 .50 < .90 23. .06 107
> 8.00 < .02 23. .04 323
IIITRILE+PVC 058 100 .08 .90 • 9.02 23. 107
P£ 076 100 .20 < .90 23. 107
PV ALCOIIOl 004 100 3.50 < .90 23. 107
PVC 007 100 .20 < .90 23. 107
077 100 .17 • .54 9.02 23. 107
.17 < .90 23. 107
VITCII 009 118 > 8.00 < .02 23. .05 323

Anll lne (Benz. .lne)


000625330 BUTYL 012 > 6.50 1.99 25. .04 273
> 6.50 1.99 25. .04 273
> 22.00 < .02 25. .06 273
> 22.00 < .02 25. .06 273
7.00 < .02 25. .04 273
7.00 < .02 25. .04 273
> 23.00 < .02 25. .06 273
> 23.00 < .02 25. .06 273
7.00 1.20 25. .04 273
7.00 < .02 25. .04 273
> 8.00 < .02 25. .06 273
> 8.00 < .02 25. .06 273
014 118 > 8.00 23. .03 323
> 8.00 23. ;04 227
064 117 > 8.00 23. .02 213
> 8.00 23. .01 213
> 8.00 23. .02 213
BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213

A-7
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PIQ)UCT VEIIDOI BREAlCTHRClJGH TINE PERMEATION RATE TEMP THICICNESS REF
CASIIO MATERIAL DESC CODE MOORS UG/CM**2/NIN DEG C eM ...

000625330 IlATURAl RUBBER 001 210 1.00 6.01 23. 080


UIIIC .53 23. .12 274
017 100 > 1.00 < 40.08 25. .03 222
.50 •90 • 9.02 23 • .05 107
120 > 1.00 < 40.08 25. .02 222
504 > 1.00 < 40.08 25. .05 222
> 1.00 < 40.08 25. .06 222
UIIIC •50 > 10.02 23 • .04 274
IIEOP+IlAT RUBBER 026 121 1.00 252.50 23. .05 237
IIEOP/IIAT RUBBER 008 114 • 09 15.03 25 • .05 222
UIIIC > 1.00 23. .05 274
NEOPRENE 002 100 3.00 .90 • 9.02 23. 107
120 > 1.00 < 40.08 25. .07 222
210 .50 12.02 23. 080
018 100 .58 .90 • 9.02 23. .04 107
120 > 1.00 < 40.08 25. .05 222
> 1.00 < 40.08 25. .05 222
> 1.00 < 40.08 25. .03 222
UIIIt > 1.00 23. .06 274
> 1.00 23. .09 274
.50 6.01 25. .04 273
1.00 6.01 25. .04 273
2.00 3.01 25. .06 m
2.50 9.02 25. .06 273
093 117 1.73 23. .02 213
138 111 4.33 23. .03 213

NITIILE
139
005
',7
210
2.75 23. .02 213
2.50 30.06 23. 080
019 100 1.60 120.24 25. .04 222
118 1.05 270.54 23. .04 323
1.10 270.54 23. .04 227
50] .30 180.36 25. .03 222
UIIIC > 1.00 23. .05 274
> 1.00 23. .05 274
1.50 3.01 25. .04 213
1.50 3.01 25. .04 213
2.50 3.01 25. .06 213
5.42 3.01 25. .06 273
NITIILE+PVC 057 210 6.00 < .02 23. 080
058 100 • 17 .90 • 9.02 23 • 107
PE 006 100 > 1.00 < 40.08 25. .01 222
505 .05 25. .01 222
076 100 •07 .90 • 9.02 23 • 107
111 6.58 23. .01 213
PV ALCOHOL 004 100 1.50 .90 • 9.02 23. 107
!JIlt > 1.00 23. .12 274
102 100 > 16.00 23. .03 323
PVC 003 120 .05 180.36 25. .01 222
•30 160.32 25 • .03 222
• 15 160.32 25 • .02 222
007 100 3.00 .90 • 9.02 23. 107
210 4.00 8.42 23. 080
UNIC > 1.00 23. .16 274

A-a
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAlCTHROUGH TIME PERMEATION RATE TEMP THICKNESS REf
CAStlO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM tlUM

000625330 PVC 049 117 1.25 23. .01 213


on 100 .33 .90 • 9.02 23. 107
• 50 •90 9.02 23 . 107
SARANEX 061 117 > 8.00 23. .01 213
SILVER SHIELD 122 118 > 8.00 23. .01 227
TEFLON 069 510 > 3.30 < .02 23. .05 303
VITON 009 118 .10 112.42 23. .03 323
.17 112.42 23. .02 227
UIIK > 1.00 23. .03 274
145 117 •83 23 • .01 213
VITOII/NEOPRENE 111 117 > 8.00 23. .02 213

Benzaldehyde
001005270 BUTYL 014 118 9.00 23. .07 323
NATURAL RUBBER 017 100 .23 9.02 • 90.18 23. .05 107
NEOPRENE 018 100 .65 24.05 23. .05 323
NITRILE 019 100 .40 25.85 21. .03 323
PE 076 100 .17 9.02 90.18 23. 107
PV ALCOHOl 004 100 > 6.00 < .90 23. 107
102 100 > 16.00 2:>. .03 323
VITOII 009 118 9.93 24.05 ~3. .03 323

Benzene
000714320 BUTYL 014 118 • 52 114. t9 :'} • )J!, 323
.S2 194.19 ~3. .()4 227
UIIK .33 2:!. .;}, 327
034 IIIIC 1.47 130.26 22. .08 078
064 117 .08 23. .02 213
> .08 23. .01 213
.67 21. .02 213
507 1.00 90.18 22. .06 078
UIIK .13 23. .04 327
BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213
CPE 070 UNIC .43 21. .05 004
EVA 074 UIIIC .01 21. .02 327
NATURAL RUBBER 001 210 .18 396.79 21. 080
017 100 .04 3,206.40 25. .03 222
120 .03 5,611.20 25. .02 222
502 .05 2,605.20 25. .05 222
504 •06 2,204.40 25 • .05 222
.12 1,603.20 25. .06 222
508 .03 501.00 22. .03 078
UIIK .01 23. .05 327
.02 21. .02 327
NEOP+NAT RUBBER 026 102 .05 2,805.60 25. .04 222
121 .05 2,254.50 21. .05 237
NEOP/NAT RUBBER OOB 114 .09 2,004.00 25. .05 222
.05 400.80 22. .05 078
NEOPRENE 002 100 .25 80.16 22. .07 078
.02 951.90 25. .'18 222
120 .40 300.60 25. .07 222
210 .25 559.12 23. 080
UtlK .29 517.03 22. .11 333

A-9
SUMMARY OF PERFORHAIICE DETAil TESTS
PERMEATION TEST

CHEMICAL tlAMEl RESISTAIIT PRODUCT VEtIIOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERiAl DESC COOE IKlJRS UG/CM**2/M IN DEG C CM MUM

000714320 002 !11K •14 1,167.33 22 • .OS 333


010 120 .11 521.04 22. .04 078
018 100 .28 165.93 23. .05 323
• 10 300.60 22 • .04 078
120 • 19 1,002.00 25 . .05 222
•27 1,102.20 25 • .07 222
•27 801.60 25 • .05 222
•OS 1,803.60 25 • .03 222
UNIC • 12 22 • .04 333
.10 22. .05 333
• 19 1,893.78 22 • .05 333
.33 23. .06 327
031 3.10 50.10 22. .24 078
1.00 SO.16 22. .16 078
•41 230.46 22 • .OS 078
•27 330.66 37 • .OS 078
•67 190.38 7• .OS 078
• 40 230.46 22 • .OS 078
•11 501.00 22 • .04 078
093 117 < .OS 23. .02 213
138 117 < •OS 23 . .03 213
139 117 > 8.00 23. .02 213
IIITRllE 005 210 .33 901.80 23. OSO
503 .10 501.00 22. .02 078
019 100 •32 .03 23 • .04 323
1.05 400.SO 25. .04 222
.77 511.02 25. .06 222
•32 851.70 25 • .05 222
181 • 15 1,102.20 25 • .03 222
503 .07 1,302.60 25. .03 222
UNIC .17 23. .04 327
.23 870.74 22. .04 333
•32 939.88 22 • .04 333
033 UIIIC •OS 501.00 22 • .04 078
IIITRIlE+PVC 057 210 •75 1SO.36 23 • OSO
058 100 .03 901.80· 9,018.00 23. 107
IIOIIWOI/EII PE 071 UIIIC .01 23. .01 327
PE 006 100 < •01 250.50 25 . .01 222
209 < .02 350.70 22. .01 078
505 .07 50.10 25. .01 222
042 UIIIC < .03 23. .01 327
076 100 •03 90.18· 901.SO· 23 . 107
117 .OS 23. .01 213
IIIIIC •01 23 • .01 327
•02 220.44 22 • .01 078
POl YURETHAIIE 050 178 •03 110.22 22 • .02 078
PY AlCOHOl 004 100 .12 < .90 23. 107
•17 8.02 22 • .02 078
UNIC > 33.33 22. .09 333
•33 23 • .02 327
035 IIIIIC .05 39.OS 22. .01 078
102 100 .82 < .02 23. .03 323
PVC 003 100 < •01 1,182.56 23 • .02 323

A-IO
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN OEG C CM NUN

000714320 PVC 003 120 •01 3,507.00 25 . .01 222


•01 4,108.20 25 . .01 222
. 04 1,503.00 25 • .03 222
•04 1,603.20 25 . .02 222
500 < .01 4,709.40 25. .01 222
501 .01 3,607.20 25. .01 222
< •01 4,909.80 25 . .02 222
UNK •02 23 • .01 327
007 210 .50 240.48 23. 080
UNIC .30 481.96 22. .10 333
• 17 599.20 22 • .11 333
•31 421.84 22 . .11 333
049 117 •10 23 • .01 213
on 117 < .16 23. .01 213
168 • 10 150.30 22 • .04 078
SARANEX 061 117 •25 23 . .01 213
UNK • 17 23 • .01 327
SILVER SHIELD 122 118 > 8.00 23. .01 227
TEFLON 036 UNK • 17 23 • .01 327
069 510 > 3.20 < .02 23. .05 303
> 3.00 < .02 25. .05 303
VITON 009 118 5.93 .07 23. .02 323
6.00 .07 23. .02 227
UNK •50 23 • .02 327
032 UNK 15.00 .50 22. .16 078
145 117 > 8.00 23. .01 213
VITON/NEOPRENE 111 117 3.50 23. .02 213

Benzenesulfonic Acid
000986790 NEOPRENE 018 100 > 20.00 23. .05 123
NITRILE 020 216 > 4.00 23. .04 123

Benzethonium Chloride
001215400 BUTYL 014 118 > 8.00 < .02 22. .06 323
NATURAL RUBBER 001 250 > 8.00 < .02 21. .02 323
NEOPRENE 018 100 > 8.00 < .02 19. .05 323
PVC 007 100 > 8.00 < .02 19. .02 323

Benzoni trite
001004700 BUTYL 014 118 > 8.00 23. .06 323
NATURAL RUBBER 001 506 < .01 24.05 23 •. .01 323
PV ALCOHOL 102 100 > 8.00 23. .03 323
V IT ON 009 118 .93 24.05 23. .03 323

Benzoyl Chloride
000988840 BUTYL 014 118 6.28 99.80 23. .06 323
HYPALON 108 210 .33 23 . .06 123
NEOPRENE 018 100 •25 23. .05 123
PV ALCOHOL 102 100 > 8.00 23. .05 323
PVC 003 100 < .01 596.39 23. .02 323
VITON 009 118 > 8.00 23. .02 323
.75 23. .03 123

A-ll
SlJIMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE IIOORS UG/CIf"*2/MIN DEG C eM NlJ4

Benzyl Alcohol
001005160 BUTYL 014 216 > 4.00 23. .01 123
VITON 009 118 > 20.00 23. .03 123

Benzyl Chloride (Chloromethyl Benzene)


001004470 CPE 070 utile .78 23. .05 004
TEFLON 069 510 > 3.20 < .02 23. .05 303

Bis(2-Ethylhexyl) Phthalate
001178170 BUTYl 014 118 > 8.00 23. .09 323
NATURAL IMlBER 011 100 > 6.00 < .90 23. .05 101
NEOPRENE OOZ 100 2.00 < .90 23. 101
018 100 > 6.00 < .90 23. .04 101·
NITRILE 019 100 > 6.00 < .90 23. .06 101
4.33 12.02 23. .05 323
PV ALCOHOl. 004 100 .SO 90.18- 901.80 23. 101
PVC 003 100 .03 12.02 23. .02 323
VI TON 009 118 > 8.00 23. .05 323

Boric Acid
100433530 BUTYl 014 118 > 8.00 < .02 20. .01 323
NEOPRENE 018 100 > 8.00 < .02 19. .05 323
NITRILE 019 100 > 8.00 < .02 21. .04 323
VITON 009 118 > 8.00 < .02 20. .03 323

BrOllline
Om6956O PE 016 121 < .02 23. 104

Bromoacetonitrile
005901100 BUTYl 014 118 > 8.00 23. .06 323
NATURAL RUBBER 001 506 < .01 51.11 23. .01 323
PV ALCOIIOl 102 100 > 8_00 23. .03 323
VITON 009 118 > 8.00 23. .02 323

Bromobenzene
001088610 BUTYL 014 118 .53 239.28 23. .06 323
NITRILE 019 118 .22 54.11 23. .04 323
PY ALCOHOl 102 100 > 8.00 23. .02 323
VITON 009 118 > 8.00 23. .03 323

2-BrOntOethanol
005405120 BUTYL 014 118 > 8.00 23. .09 323
NATURAL RUBBER 001 250 .02 66.13 23. .02 323
PVC 003 100 .03 456.91 23. .02 323
VITON 009 118 > 8.00 23. .05 323

l-Bromo-2-propanol
196861380 BUTYL 014 118 > 8.00 23. .06 323
NATURAL RUBBER 001 S06 .02 45.69 23. _01 323
PV ALCOHOL 102 100 > 8.00 23. .02 323
VITON 009 118 > 8.00 23. .02 323

A-12
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST

CHEMICAL NAME I RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL OESC COOE HOURS UG/CM**2!MIN OEG C CM NUM

3-Bromo-1-propanol
006271890 BUTYL 014 118 > 8.00 23. .06 323
NEOPRENE 018 100 > 8.00 23. .05 323
PV ALCOHOL 102 100 > 8.00 23. .03 323
VITON 009 118 > 8.00 23. .02 323

Butadiene
001069900 BUTYL 014 118 > 8.00 23. .07 323
NATURAL RUBBER 001 250 < .02 637.27 23. .02 323
NEOPRENE 018 100 .78 1.80 23. .05 323
PVC 003 100 < .02 126.25 23. .02 323
VITON 009 118 > 8.00 23. .05 323

tert-Butanol (Methylpropanol, 2- ,2-)


000756500 BUTYL 014 118 > 8.00 23. .07 323
NATURAL RUBBER 001 250 .02 18.04 23. .02 323
NEOPRENE 018 100 2.75 .05 23. .05 323
PVC 007 100 .08 18.04 23. .02 323

Butyl Acetate
001238640 BUTYL 014 118 1.90 45.76 23. .04 227
1.53 36.07 23. .05 086
NATURAL RUBBER 001 210 .13 216.43 23. 080
017 100 .07 1,402.80 25. .03 222
102 .07 72.14 23. .05 026
.07 72.14 23. .05 026
.07 72.14 23. .05 026
.07 72.14 23. .05 026
120 .03 2,905.80 25. .02 222
502 .11 941.88 25. .05 222
504 .13 881.76 25. .05 222
.23 511.02 25. .06 222
NEOP+NAT RUBBER 026 102 .11 641.28 25. .05 222
.07 72.14 23. .06 026
.07 72.14 23. .04 026
.07 72.14 23. .05 026
NEOP/NAT RUBBER 008 102 .07 72.14 23. 026
114 .15 641.28 25. .05 222
IIEOPRENE 002 100 .09 220.44 25. .08 222
120 .06 320.64 25. .07 222
210 .25 72.14 23. 080
018 100 .32 210.42 23. .06 086
118 > 1.00 < 21.04 25. .08 222
120 .48 320.64 25. .05 222
.87 320.64 25. .07 222
> 1.00 < 21.04 25. .05 222
.18 831.66 25. .03 222
NITRILE 005 210 1.33 90.18 23. 080
019 100 .55 480.96 25. .04 222
1.25 90.18 - 901.80 23 • .06 107
. 97 250.50 25. .06 222
.67 450.90 25. .04 222

A-13
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM N\JM

001238640 NITRILE 019 100 1.08 102.20 23. .06 086


118 •48 327.05 23 . .04 227
.25 300.60 23. .04 086
120 •53 217.10 23 • .05 086
503 •33 350.70 25 . .03 222
020 503 .32 150.30 23. .04 086
NITRILE+PVC 057 210 .67 60.12 23. OBO
PE 006 100 .03 20.04 25. .01 222
50s .20 6.01 25. .01 222
512 .03 66.13 23. .01 086
076 100 .17 9.02 90.18 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
PVC 003 120 . 02 6,012.00 25 • .01 222
.02 6,913.80 25. .01 222
•04 3,306.60 25 • .03 222
•03 4,308.60 25 • .02 222
500 •01 25 • .01 222
501 .03 6,412.80 25. .01 222
.03 4,108.20 25. .02 222
007 210 •33 n.14 23 . OBO
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEFLON 069 510 > 3.00 < .02 23. .05 303
VITON 009 118 .23 318.97 23. .04 086

Butyl Acrylate
001413220 TEFLON 069 510 > 3.00 < .02 23. .05 303

Butyl Alcohol (Butanol, 1)


000713630 NATURAL RUBBER 001 210 2.00 12.02 23. OBO
017 100 .25 9.02 90.18 23. .05 107
NEOP+NAT RUBBER 026 121 .58 > 6.01 23. .05 237
NEOPRENE 002 100 > 8.00 < .90 23. 107
210 6.00 < .02 23. 080
018 100 4.00 .90 9.02 23. .04 107
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 6.00 < .90 23. .06 107
NITRILE+PVC 057 210 6.00 < .02 23. 080
OS8 100 .58 . 90 9.02 23 • 107
PE 076 100 > 6.00 < .90 23. 107
127 > 8.00 < 30.06 23. 104
PV ALCOHOL 004 100 .50 9.02 90.18 23. 107
> 8.00 23. 123
> 4.00 21. 124
PVC 007 100 3.00 .90 9.02 23. 107
210 2.00 15.03 23. 080
on 100 . 42 < .90 23 . 107
.67 9.02 90.18 23. 107
TEFLON 069 510 > 15.60 < .02 23. .05 303

Butylamine
001097390 BUTYL 014 118 1.73 501.00 15. .10 323
CPE 060 UNK •50 23 . 142
1.00 23. 142

A-14
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP TH ICKNESS REF
CASNO MATERIAL OESC COOE HOURS UG/CM**2/MIN OEG C CM NUM

001097390 CPE 070 UNK _33 23. .05 004


NATURAL RUBBER 001 250 .02 7,745.46 20. .02 323
NEOPRENE 018 100 .20 2,474.94 18. .05 323
PVC 007 100 .02 5,531.04 18. .02 323
TEFLON ' 069 510 > 3.00 < .02 23. .05 303
VITON/CHLOROBUTYL 112 UNK .50 23. 142

iso-Butylamine (Methylpropylamine, 2-)


000788190 BUTYL 014 118 3_70 60.12 28. .09 323
CPE 060 UNK 2.28 23. 142
2.42 23. 142
NEOPRENE 018 100 .32 889.78 26. .05 323
138 117 < .08 23. .03 213
PV ALCOIIOL 102 100 .32 835.67 23. .07 323
PVC 007 100 .02 3,432.85 28. .02 323
VITON/CHLOROBUTYL 112 UNK 1.25 23. 142

sec-Buty.lamine
139528460 BUTYL 014 118 2.68 180.36 21. .09 323
NEOPRENE 018 100 .27 1,402.80 25. .05 323
NITRILE 019 100 .33 1,482_96 14. .04 323
PVC 007 100 .01 4,529.04 24. .02 323

tert-Butylamine
000756490 BUTYL 014 118 > 8.00 < •02 15 . .09 323
NEOPRENE 018 100 1.17 360.72 23. .05 323
NITRILE 019 100 1.40 240.48 21. .04 323
PVC 007 100 .03 3,036.06 20. .02 323

Butyl Cellosolve (Butoxyethanol, 2)


001117620 NITRILE 019 100 .45 37. .06 107
.35 37. .06 107
118 > 4.00 22. .03 122
.15 200.40 34. .04 122
PV ALCOHOL 004 100 > 18.00 22. .04 122

n-Butyl Chloride (Chlorobutane,1-)


001096930 NITRILE 019 100 .20 661.32 23. .05 323
PV ALCOHOL 004 100 > 8.00 < .02 23. .08 323
PVC 003 100 .20 2,278.55 23. .02 323
VITo.. 009 118 7.42 3.01 23. .05 323

n-Butyl Phthalate
000847420 BUTYL 014 118 > 16.00 23. .04 323
> 16.00 23. .04 227
NATURAL RUBBER 017 100 .28 23. .05 107
NEOPRENE 002 100 5.00 .90 9.02 23. 107
018 100 2.00 < .90 23. .04 107
125 103 < .02 23. 045
~'lTRllE 019 100 > 6.00 < .90 23. .06 107
103 < .02 23. 045
118 > 16.00 23. .03 323
> 16_00 23. .04 227

A-15
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HOURS UG/CM**2/MIN DEG C eM NUM

000847420 NITRILE+PVC 058 100 > 6.00 23. 107


PE 076 100 > 6.00 23. 107
PV ALCOHOL 004 100 > 6.00 .90 23. 107
102 100 > 16.00 23. .03 323
PVC on 100 > 6.00 23. 107
> 6.00 23. 107
SILVER SHIELD 122 118 > 6.00 23. .01 227
VITON 009 118 > 8.00 23. .03 323
> 8.00 23. .02 227

p-tert-Butyl Toluene
271302120 BUTYL 014 118 1.78 48.10 23. .06 323
1.70 48.10 23. .04 227
NEOPRENE 018 100 1.22 421.44 23. .05 323
NITRILE 019 100 > 6.00 23. .04 323
PV ALCOHOL 102 100 > 7.00 23. .03 323
SILVER SHIELD 122 118 > 8.00 23. .01 227
VITON 009 118 > 8.00 23. .02 323
> 8.00 23. .02 227

Butyraldehyde
00123n80 BUTYL 014 118 > 15.00 23. .07 323
NEOPRENE 018 100 • 73 15.75 23 • .05 323
PV ALCOHOl 102 100 •27 .78 23 • .03 323
TEFLON 069 510 > 7.50 < .02 23. .05 303
VITON 009 118 .90 54.11 23. .03 323

Carbon Disulfide (Carbon Bisulfide)


000151500 BUTYL 014 118 •05 591.58 23 • .06 323
• 12 588.24 23 • .04 227
CPE 060 113 .13 . .17 25. .07 302
070 UIIIC .13 23. .05 004
IIEOP+NAT RUBBER 026 121 .02 889.78 23. .05 237
NITRILE 019 100 •50 90.18 . 901.80 23 . .06 107
118 .15 306.61 23. .04 323
• 22 306.61 23 . .04 227
PE 076 100 .12 9.02 ,90.18 23. 107
PV ALCOHOl 004 100 > 6.00 < .90 23. 107
102 100 > 16.00 23. .03 323
TEFLON 069 510 •36 .05 23 • .05 303
.34 .07 23. .05 303
•30 .05' 23 . .05 303
.22 24 • .05 303
• 22 24. .05 303
.60 24. .05 303
.60 24. .05 303
VITON 009 118 > 16.00 23. .03 323
> 16.00 23. .02 227
VITON/CHLOROBUTYL 112 113 .18 .25 25. .04 302

Carbon Tetrachloride (Tetrachloromethane)


000562350 CPE 060 113 3.48 23. .05 204
3.45 78.16 23. .05 204

A-16
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME I RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO . MATERIAL DESC CODE HOURS UG/ot**2/MIN DEG C CM NUM

000562350 NATURAL RUBBER 017 100 .06 1,603.20 25. .03 222
120 .03 6,012.00 25. .02 222
502 .08 5,110.20 25. .05 222
504 . 50 S01.6O 25 . .05 222
.18 1,603.20 25. .06 222
NEOP+NAT RUBBER 026 102 .07 4,609.20 25. .05 222
NEOP/NAT RUBBER DOS 114 .17 3,106.20 25. .05 222
NEOPRENE 002 100 • 50 100.20 25 . .08 222
120 •08 501.00 25 . .07 222
UNIC •24 300.60 22 • .11 333
• 17 619.24 22 • .08 333
018 118 > 1.00 < 6.01 25. .08 222
120 .57 S01.6O 25. .05 222
• 68 901.SO 25 • .07 222
•38 901.SO 25 • .05 222
.22 801.60 25. .03 222
UNIC .14 2,244.48 22. .05 333
.32 1,756.51 22. .05 333
.24 1,997.99 22. .04 333
NITRILE 019 100 > 1.00 < 6.01 25. .04 222
2.50 9.02 90.18 23. .06 107
> 1.00 < '1,669.98 25. .06 222
> 1.00 < 6.01 25. .04 222
118 3.40 30.06 23. .04 227
181 > 1.00 < 6.01 25. .03 222
503 > 1.00 < 6.01 25. .03 222
UNIC > 3.33 22. .04 333
> 3.33 22. .04 333
NITRILE+PVC 058 100 .05 9.02 . 90.18 23. 107
PE 006 100 .03 501.00 25. .01 222
505 .13 SO.16 25. .01 222
076 100 .08 9.02 90.18 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
UNIC > 3.33 3.01 22. .09 333
102 100 > 8.00 23. .04 323
PVC 003 120 .01 1,002.00 25. .01 222
.03 2,004.00 25. .01 222
.14 601.20 25. .03 222
.04 S01.6O 25. .02 222
500 .02 2,104.20 25. .01 222
501 .02 2,505.00 25. .01 222
.02 2,004.00 25. .02 222
007 100 .42 90.18· 901.80 23. 107
UNIC .22 496.99 22. .11 333
.66 203.41 22. .11 333
.51 250.50 22. .10 333
on 100 .12 9.02 90.18 23. 107
.25 9.02 90.18 23. 107
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEFLON 069 510 > 3.00 < .02 23. .05 303
VITON 009 118 > 13.00 23. .02 227

Chlorine

A-17
SUMMARY OF PERfORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HClJRS UG/CM**2/MIJI DEG C CM lUI

0778Z5050 BUTYL 064 117 > 8.00 23. .02 213


> 8.00 23. .01 213
> 8.00 23. .02 213
BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213
NEOPRENE 093
138
',7
117
>
>
8.00
8.00
23. .02 213
23. .03 213
139 117 > 8.00 23. .02 213
PE 076 117 .08 23. .01 213
PVC 049 117 • 92 23 • .01 213
•08 23 • .01 213
053 117 « .08 23. .02 213
SARANEX 061 117 > 8.00 23. .01 213
VITON 145 117 > 8.00 23. .01 213
VITON/NEOPRENE 111 117 > 8.00 23. .02 213

Chloroacetic Acid
000791180 PE 076 127 > 8.00 23. 104
.08 65. 104
SARANEX 061 127 1.00 65. 104

Chloroacetonitrlle
001071420 BUTYL 014 118 > 8.00 23. .06 323
NATURAL RUBBER 001 506 « • 01 75.75 23 . .01 323
PV ALCOHOL 102 100 > 8.00 23. .03 323
VITON 009 118 > 8.00 23. .03 323

Chlorobenzene
001089070 BUTYL 014 118 .58 3,086.16 23. .07 323
NEOPRENE 002 utile • 18 23. .05 186
NITRILE 005 229 •21 940.21 23 • .11 210
019 120 • 25 960.25 23 • .04 210
PE 076 100 • 07 90.18 901.80 23 • 107
PV ALCOHOL 004 100 .25 9.02· 90.18 23. 107
102 100 > 8.00 c .02 23. .08 323
PVC 007 100 •03 3,757.50 23 • .02 323
utile .15 23. .05 186
.31 23. .07 186
TEfLON 069 510 > 3.00 c .02 23. .05 303
VITON 009 118 > 4.00 23. .03 210
8.00 c .02 23. .03 323

2·Chloro·1,3·butadiene (Chloroprene)
001269980 NEOPRENE 002 utile • 05 1,764.52 22 • .08 333
•05 783.56 22 • .11 333
018 lillie .07 22. .04 333
.11 22. .05 333
• 10 3,164.32 22 • .05 333
NITRILE 019 UNIC .06 2,329.65 22. .04 333
.12 2,on.15 22. .04 333
PV ALCOHOL 004 UNIe 16.67 22. .09 333
PVC 007 UNIe .08 669.34 22. .11 333
.09 851.70 22. .10 333
.07 954.91 22. .11 333

A-I8
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NlJII

Chlorodibromomethane
001244810 BUTYL 012 118 3.27 149.75 23. .10 323
PV ALCOHOL 004 100 .60 .02 23. .07 323
PVC 003 100 •03 1,106.21 23 • .02 323
VITON 009 118 > 8.00 23. .04 323

Chloroform (Trichloromethane)
000676630 CPE 060 113 . 50 - .58 25 • .07 302
070 UNK .20 23. .05 004
NATURAL RUBBER 017 100 •03 4,OOS.00 25 • .03 222
120 •01 15,030.00 25 • .02 222
502 .04 7,615.20 25. .05 222
504 .05 5,611.20 25. .05 222
•05 7,014.00 25 • .06 222
NEOP+NAT RUBBER 026 102 •05 7,014.00 25 • .05 222
NEOP/NAT RUBBER OOS 114 • 11 4,4OS.80 25 • .05 222
NEOPRENE 002 100 •02 2,705.40 25 • .OS 222
120 .01 6,813.60 25. .07 222
018 118 .36 2,004.00 25. .OS 222
120 .16 3,206.40 25. .05 222
.23 2,805.60 25_ .07 222
.17 2,505.00 25. .05 222
.06 4,4OS.80 25. .03 222
031 UNK .20 23. .04 187
NITRILE 019 100 •OS 9,418.80 25 • .04 222
.21 5,611.20 25. .06 222
.04 9,919.80 25. .04 222
118 .07 2,116.22 23. .04 227
503 •07 7,014.0025 • .03 222
033 UtlK .16 23. .05 187
PE 006 100 .01 1,603.20 25. .01 222
505 .05 25. .01 222
056 UtlK .07 23. .01 187
076 100 .10 9.02 90.18 23. 107
127 < .02 348.70 23. 104
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
102 100 > 8.00 23. .03 323
PVC 003 120 .01 15,030.00 25. .01 222
.01 > 16,699.98 25. .01 222
.01 5,410.80 25. .-03 222
.01 11,022.00 25. .02 222
500 .01 15,030.00 25. .01 222
501 .01 12,024.00 25. .01 222
•01 13,026.00 25 • .02 222
049 UtlK • 14 23 • .03 187
SARANEX 061 127 < •02 201.40 23 • 104
SILVER SHIELO 122 118 .17 .05 23. _01 227
TEFLON 069 510 > 3.60 < .02 23. .05 303
VITON 009 118 9.50 2.n 23. .02 227
VITON/CHLOROBUTYL 112 113 > 3.00 25. .04 302

3-Chloro-2-methylpropene

A-19
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2!MIN DEG C CM NlII

005634730 BUTYL 014 118 .50 120.24 23. .06 323


PV ALCOHOL 004 100 .03 80.16 23. .04 323
PVC 007 100 .01 120.24 23. .02 323
VIT ON 009 118 3.83 30.06 23. .03 323

Chloronaphthalenes (all isomers)


255864300 NITRILE 019 118 2.90 > 7.93 23. .04 227
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
SILVER SHIELD 122 118 > 8.00 23. .01 227
VITON 009 118 > 16.00 < -1,669.98 23. .02 227

2-Chloro-2-nitropropane
005947180 BUTYL 012 118 > 8.00 < • 02 23 • .09 323
NATURAL RUBBER 017 506 .02 270.54 23. .02 323
PV ALCOHOL 004 100 > 8.00 < .02 23. .07 323
VITON 009 118 2.05 120.24 23. .04 323

1-Chloro-2-propanol
001270040 BUTYL 014 118 > 8.00 23. .06 323
NATURAL RUBBER 001 506 < .01 23. .01 323
PVC 003 100 .02 230.86 23. .02 323
VITON 009 118 > 8.00 23. .03 323

3-Chloro-1·propanol
006273050 BUTYL 014 118 > 8.00 23. .06 323
PV ALCOHOL 102 100 .80 92.58 23. .04 323
PVC 003 100 .18 409.42 23. .02 323
VITON 009 118 > 8.00 23. .03 323

Chlorosulfonic Acid
077909450 PE 076 127 1.OS 23. 104
SARAIIEX 061 127 5.83 23. 104

o-Chlorotoluene
000954980 NITRILE 005 229 .29 1,163.99 23. .11 210
019 120 .88 988.64 23. .04 210
VITON 009 118 > 4.00 23. .03 210

p-Chlorotoluene
001064340 NITRILE 005 229 .25 1,224.11 23. .11 210
019 120 .42 890.11 23. .04 210
VITON 009 118 > 4.00 23. .03 210

Chromic Acid
111157450 NATURAL RUBBER 001 210 1.17 23. OSO
NEOPRENE 002 210 1.25 23. 080
NITRILE 005 210 6.00 < .02 23. 080
NITRILE+PVC 057 210 6.00 < .02 23. 080
058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC 007 210 6.00 < .02 23. OSO
077 100 > 6.00 23. 107
> 6.00 23. 107

A-20
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**21MIN DEG C CH NUM

Chromic Acid, <3OX


111157451 NEOP+NAT RUBBER 026 121 > 8.00 < .02 23. .05 237

Chromic Acid, 30·7QX


111157452 NITRILE 019 100 4.00 23. .06 107
PVC 007 100 > 6.00 23. 107

Citric Acid, <lOX


000779291 NATURAL RUBBER 017 100 > 6.00 23. .05 107
NEOPRENE 002 100 > 6.00 23. 107
018 100 > 6.00 23. .04 107
NITRILE 019 100 > 6.00 23. .06 107
NITRILE+PVC 058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PV ALCOHOL D04 100 .83 23. 107
PVC 007 100 > 6.00 23. 107
on 100 > 6.00 23. 107
> 6.00 23. 107

Creosote
080015890 BUTYL 034 UNIC > 90.00 22. .08 078
NEOPRENE 031 UNIC 4.50 Z2. .08 078
VITOII 032 UNIC > 96.00 22. .04 078

Creosote, Wood
080213940 NEOPRENE 018 100 > 4.00 23. .05 123
VITOII 009 118 > 19.00 23. .03 123

..·Cresol
001083940 NATURAL RUBBER 017 100 .60 25. .03 222
120 .23 15.03 25. .02 222
502 .50 2.00 25. .05 222
504 > 1.00 1.00 25. .05 222
> 1.00 1.00 25. .06 222
NEOP+IlAT RUBBER 026 102 .50 2.00 25. .05 222
NEOP/NAT RUBBER 008 114 > 1.00 1.00 25. .05 222
NEOPRENE 002 100 > 1.00 1.00 25. .08 222
018 118 > 1.00 1.00 25. .08 222
120 > 1.00 1.00 25. .05 222
> 1.00 1.00 25. .07 222
> 1.00 1.00 25. .05 222
> 1.00 1.00 25. .03 222
NITRilE 019 100 > 1.00 1.00 25. .04 222
> 1.00 1.00 25. .06 222
> 1.00 1.00 25. .04 222
503 > 1.00 1.00 25. .03 222
PE 006 100 > 1.00 1.00 25. .01 222
505 > 1.00 < .10 25. .01 222
PVC 003 120 .20 67.13 25. .01 222
.23 59.12 25. .01 222
> 1.00 1.00 25. .03 222
.23 63.13 25. .02 222

A-21
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG!CM**2/MIN DEG C CM

001083940 PVC 003 500 .13 44.09 25. .01 222


501 • 13 55.11 25 • .01 222
. 12 56.11 25 • .02 222
TEFLON 069 510 > 4.00 < .02 23. .05 303

Cresols
013197730 PE 076 127 .67 1.00 .40 23. 104
SARANEX 061 127 > 2.00 < .13 23. 104

Crotonaldehyde (Butenal, trans-2)


041703030 BUTYL 014 118 > 8.00 23. .07 323
CPE 070 UNK .63 23. .05 004
NEOPRENE 018 100 .35 209.22 23. .05 323
PV ALCOHOL 102 100 < •01 57.n 23 . .03 323
TEFLON 069 510 > 3.10 < .02 23. .05 303
VITON 009 118 • 12 313.83 23 • .03 323

Cumene (Methyl ethyl Benzene)


000988280 CPE 070 UNK 1.30 23. .05 004

Cyclohexane
001108270 BUTYL 014 118 1.15 122.04 23. .07 323
1.10 122.04 23. .04 227
NATURAL RUBBER 001 210 .10 2,044.08 23. 080
017 100 10.02 25. .03 222
120 .03 1,503.00 25. .02 222
502 •13 1,302.60 25 • .05 222
504 .16 1,102.20 25. .05 222
.30 801.60 25. .06 222
NEOP+NAT RUBBER 026 102 .08 1,402.80 25. .05 222
NEOPRENE 002 120 • 16 70.14 25 • .07 222
210 .10 1,082.16 23. 080
018 100 .95 .18 23. .04 323
120 > 1.00 < 10.02 25. .05 222
.48 100.20 25. .05 222
1.20 100.20 25. .03 222
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 6.00 23. .04 323
> 1.00 < 10.02 25. .04 222
> 1.00 < 1.00 25. .06 222
> 1.00 < 1.00 25. .04 222
181 > 1.00 < 1.00· 25. .03 222
503 > 1.00 < 10.02 25. .03 222
NITRILE+PVC 057 210 3.00 12.02 23. 080
PE 006 100 .03 100.20 25. .01 222
505 .17 28.06 25. .01 222
PV ALCOHOL 102 100 .78 < .02 23. .03 323
PVC 003 120 .03 501.00 25. .01 222
•04 340.68 25 • .01 222
.27 100.20 25. .03 222
.09 200.40 25. .02 222
500 •03 310.62 25 • .01 222
501 •01 450.90 25 • .01 222

A-22
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/tM**2/MIN DEG C eM NUN

001108270 PVC 003 501 .04 300.60 25. .02 222


007 210 • 55 216.43 23 • 080
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEFLON 069 510 > 3.40 < .02 23. .05 303
VITON 009 118 > 7.00 23. .02 323
> 7.00 23. .02 227

Cyclohexanol
001089300 BUTYL 014 118 > 11.00 23. .01 323
> 11.00 23. .04 221
NATURAL RUBBER 001 210 .42 72.14 23. 080
017 100 .25 9.02 • 90.18 23. .05 101
NEOPRENE 002 100 3.00 < .90 23. 107
210 3.00 60.12 23. 080
018 100 2.50 .90 • 9.02 23. .04 107
UIIIC > 8.00 23. .08 323
031 511 8.00 ******** '1,669.98 23. .01 323
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 6.00 < .90 23. .06 101
118 > 16.00 23. .03 323
> 16.00 23. .04 221
NITRILE+PVC 057 210 6.00 < .02 23. 080
058 100 .25 .90 - 9.02 23. 101
PE 076 100 > 6.00 < .90 23. 107
PV ALCOHOL 004 100 6.00 < .90 23. 101
102 100 > 16.00 23. .03 323
PVC 007 100 6.00 < .90 23. 107
210 6.00 < .02 23. 080
077 100 1.00 < .90 23. 101
> 6.00 < .90 23. 107
SILVER SHIELD 122 118 > 6.00 23. .01 227
VITON 009 118 > 8.00 23. .03 323
> 8.00 23. .02 227

CycI ohexanone
001089410 BUTYL 014 118 > 16.00 23. .05 323
> 16.00 23. .04 221
IIEOP+IIAT RUBBER 026 121 .28 132.26 23. .05 237
NITRILE 019 118 •48 518.84 23 • .03 221
PV ALCOHOL 102 100 > 7.00 23. .03 323
SILVER SHIELD 122 118 > 6.00 23. .01 221
VITON 009 118 •48 518.84 23 . .03 323

Cyc Iohexyl lIIIIi ne


001089180 BUTYL 014 118 2.93 290.58 20. .06 323
NATURAL RUBBER 001 250 •02 8,9n.92 20 • .02 323
NEOPRENE 018 100 •60 1,322.64 22 • .05 323
NITRILE 019 100 1.02 1,843.68 24. .04 323

Decanal (all isomsers)


001123120 BUTYL 064 117 > 8.00 2'3. .02 213
> 8.00 23. .01 213
> 8.00 23. .02 213

A-23
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAlCTHROJGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DEst COOE IKlJRS UG/CI4**2!M I N DEG C CM NUM

001123120 BUTYL/NEOPRENE 110 117 2.50 23. .02 213


NEOPRENE 093 117 4.00 23. .02 213
138 117 > 8.00 23_ .03 213
139 117 > 8.00 23. .02 213
PE 076 117 > 8.00 23. .01 213
PVC 049 117 < .08 23. .01 213
SARANEX 061 117 > 8.00 23. .01 213
VITON 145 117 > 8.00 23. .01 213
VITON/NEOPRENE 111 117 > 8.00 23. .02 213

Diallyamine
001240270 BUTYL 014 118 3.33 90.18 21. .09 323
PV ALCOHOL 004 100 7.08 20.04 23. .08 323
PVC 007 100 .02 2,364.72 22. .02 323
VITON 009 118 4.62 19. .03 323

1,3-Dieminopropane
001097620 BUTYL 014 118 > 8.00 < .02 22. .06 323
NATURAL RUBBER 001 250 •05 440.88 25 • .02 323
NEOPRENE 018 100 4.53 33.40 23. .OS 323
PVC 007 100 • 11 103.54 21 • .02 323

Di-n-lIIIIYlamine
020509220 NEOPRENE 018 100 2.15 110.22 16. .OS 323
NITRILE 019 100 > 8.00 < .02 20. .04 323
PVC 007 100 .12 280.56 13. .02 323
VITON 009 118 > 8.00 < .02 16. .03 323

Dibutyl ..ine
001119220 NITRILE 019 100 > 8.00 < .02 24. .04 323
PV ALCOIIOL 102 100 > 8.00 < .02 23. .08 323
PVC 007 100 . .05 741.48 20. .02 323
YJTON 009 118 > 8.00 < .02 20. .03 323

Dichloroacetyl Chloride
000793670 BUTYL 014 118 3.92 72.14 23. .09 323
PV ALCOHOL 102 100 3.47 23. .07 323
PVC 003 100 .03 438.88 23. .02 323
VJTON 009 118 > 8.00 23. .03 323

Dichlorobenzene
253212260 CPE 070 UIIIC .65 23. .05 004

1,2-Dichlorobenzene
000955010 NITRILE 005 229 •33 1,015.36 23 • .11 210
019 120 •63 1,140.61 23 • .04 210
VJTON 009 118 > 4.00 23. .03 210

1,3-Dichlorobenzene
005417310 NITRILE 005 229 .28 1,130.59 23. .11 210
019 120 .50 1,157.31 23. .04 210
VITON 009 118 > 4.00 23. .03 210

A-24
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PROOUCT VENDOR BREAICTHROUGH TIME PERMEATION RATE TEMP THICICNESS REF
CASNO MATERIAL DESC COOE HOURS UG/CM**2/MIN OEG C CM NUM

DichlorObromomethane
000752740 BUTYL 014 118 .68 1,897.80 23. .07 323
PVC 007 100 .02 6,943.86 23. .02 323
VITON 009 118 7.83 •37 23 • .03 323
VITON/BUTYL 100 102 1.78 •02 23 • .08 323

1,4-0ichloro·2-butene
001105760 BUTYL 064 UIiIK > 24.00 23_ .07 334
CPE 060 UIiIIC .58 400. SO 23. .05 334
070 UIiIIC .75 23. .05 004
NEOPREIIE 002 UIiIIC 1.10 22 • .12 333
.n 22 • .10 333
•22 22 • .08 333
• 17 22 • .07 333
•57 118.24 22. .11 333
.36 51.10 22. .08 333
.45 31.06 23 • .10 335
•68 27.05 23. .12 335
.SO 27.05 23. .14 335
018 lIIlC .49 126.25 22 • .05 333
•37 22 • .05 333
•35 22. .05 333
.26 22 • .04 ·333
•23 41.08 22. .05 333
.30 38.08 23. .04 335
031 UIiIIC 1.38 SO.16 23. .14 334
.97 80.16 23. .13 334
1.23 121.24 23. .13 334
081 UtlIC 1.97 101.20 23. .15 335
3.35 40.08 23. .18 335
2.97 41.08 23. .20 335
1.60 121.24 23. .14 335
.92 113.23 23. .14 335
NITRILE 019 UIIIC .43 156.31 23. .04 335
.33 22 • .04 333
•27 22. .04 333
.33 22. .04 333
.44 ·,56.3, 22. .04 333
078 UtlIC .04 330.66 23. .03 334
PE 006 UlfIC > 24.00 23. .01 334
075 UIIIC .04 33.07 23. .03 334
076 127 1.25 23. 104
UlfIC > 24.00 23. .01 334
PV ALCOHOL 004 UIiIIC > 83.33 22. .09 333
PVC 007 UNIC .37 22. .11 333
.58 n.14 22. .11 333
.52 108.22 22 • .10 333
•58 87.17 22. .11 333
.60 22 . .12 333
•58 31.06 23 . .10 335
•50 30.06 23 • .11 335
049 UNIC •10 380.76 23. .os 334

A-25
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG!CM**2/MIN DEG C CM MUM

001105760 PVC 049 UNK .05 370.74 23. .04 334


2.87 144.29 23. .20 334
053 UNK .06 400.80 23. .03 334
.09 250.50 23. .05 334
.13 330.66 23. .05 334
077 lINK .02 430.86 23. .02 334
083 UNK 6.43 81.16 23. .26 335
2.73 122.24 23. .20 335
SARANEX 061 UNK > 24.00 23. .02 334
VITON 009 UNK > 8.30 23. .03 335
090 UNK > 24.00 23. .02 334

Dichloroethane
013002160 TEFLON 069 510 > 5.70 < •02 23 • .05 303
> 3.00 < .02 25. .05 303

cis'Dichloroethylene
001565920 BUTYl 014 118 .32 2,925.84 23. .07 323
PV ALCOHOL 004 100 .08 3,547.08 23. .05 323
PVC 007 100 .02 3,316.62 23. .02 323
VITON 009 118 1.68 30.06 23. .03 323

1,2'Oichloroethylene
005405900 NITRilE 019 100 .12 781.56 29. .04 323
PV ALCOHOL 004 100 .23 .50 23. .04 323
PVC 007 100 < .01 841.68 23. .02 323
VITON 009 118 .95 50.10 23. .03 323

trans'1,2'Dichloroethylene
001566050 BUTYl 014 118 .13 14,739.42 23. .06 323
PV ALCOHOl 004 100 2.63 1,142.28 23. .09 323
PVC 007 100 .02 6,262.50 23. .02 323
VITON 009 118 1.18 20.04 23. .03 323

2,2 " Dichloroethyl Ether


001114440 CPE 060 113 1.20 23. .05 204
1.45 480.96 23. .05 204
070 UNK 1.33 23. .05 004
TEFLON 069 510 > 3.00 < .02 23. .05 303

Dichloropropane (all isomers)


266381970 CPE 070 UNK .60 23. .05 004
TEFLON 069 510 > 3.10 < •02 23 • .05 303

Dichloropropane'Dichloropropene
080031980 TEFLON 069 510 > 3.00 < .02 23. .05 303

2,3·Dichloro·1·propene
000788860 BUTYL 014 118 1.90 140.28 23. .09 323
PV ALCOHOL 102 100 > 8.00 < .02 23. .09 323
PVC 007 100 .02 5,330.64 23. .02 323
VITON 009 118 > 8.00 < .02 23. .03 323

A-26
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C OM NUN

1,3·Dichloropropene
005427560 BUTYL 014 118 1.30 320.64 23. .07 323
PV ALCOHOL 102 100 8.00 < .02 23. .07 323
PVC 007 100 •02 6,513.00 23 • .02 323
VITON 009 118 8.00 < .02 23. .03 323

Di ethanol ami ne
001114220 BUTYL 014 118 8.00 24. .09 323
NEOPRENE 018 100 8.00 22. .05 323
NITRILE 019 100 8.00 26. .04 323
TEFLON 069 510 > 3.00 < .02 23. .05 303
VITON 009 118 8.00 27. .03 323

Diethylamine
001098970 BUTYL 014 118 • 78 460.92 23 • .09 323
NATURAL RUBBER 001 103 534.40 23. 045
NEOPRENE 125 103 396.79 23. 045
NITRILE 019 100 •75 90.18· 901.80 23 • .06 107
.20 1,332.66 24. .04 323
103 583.16 23. 045
PE 076 100 •08 90.18 • 901.80 23. 107
PVC 007 100 • 02 3,707.40 24 • .02 323
103 414.83 23. 045
SARANEX 061 127 .73 38.08 23. 104
SILVER SHIELD 122 118 > 8.00 23. .01 227
VITON 009 118 .58 8,537.04 20. .03 323
VITON/CHLOROBUTYL 112 113 .45 • .50 25. .04 302

Diethylaminoethanol
001003780 BUTYL 014 118 > 8.00 < .02 22. .07 323
NITRILE 019 118 > 8.00 < .02 22. .04 323
PV ALCOHOL 102 100 > 8.00 < .02 23. .09 323
VITON 009 118 > 8.00 < .02 22. .03 323

Diethylenetriamine
001114000 BUTYL 014 118 > 8.00 < .02 24. .08 323
NEOPRENE 018 100 8.00 < .02 22. .05 323
PVC 007 100 .63 3.01 22. .02 323
VITON 009 118 > 8.00 < .02 23. .03 323

Di isobutylamine
D01109630 NEOPRENE 018 100 .87 138.28 22. .05 323
NITRILE 019 100 > 8.00 20. .04 323
PV ALCOHOL 102 100 > 8.00 23. .08 323
VITON 009 118 > 8.00 22. .02 323

Diisobutyl Ketone
001088380 NATURAL RUBBER 001 210 .25 583.16 23. 080
NEOPRENE 002 210 .25 450.90 23. 080
NITRILE 005 210 4.75 30.06 23. 080
019 100 2.00 90.18 . 901.80 23. .06 107
NITRILE+PVC 057 210 1.25 3.01 23. 080

A-27
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VEIIDOR BREAKTHROUGH lINE PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOORS UG/CM**2/MI N DEG C CM NUM

001088380 PE 076 100 .08 9.02 90.18 23. 107


PV ALCOHOL 004 100 > 6.00 < • 90 23 • 107
PVC 007 210 1.00 8.42 23. 080

Diisobutyl Ketone, >70%


001088383 BUTYL 014 118 3.27 247.69 23. .04 323
3.30 247.69 23. .04 227
NITRILE 019 118 2.93 294.59 23. .03 323
3.00 293.99 23. .03 227
PV ALCOHOL 102 100 > 16.00 23. .03 323
SILVER SHIELD 122 118 > 6.00 23. .01 227
VITON 009 118 1.13 544.69 23. .03 323
1.20 544.69 23. .02 227

Diisopropylamine
001081890 NEOPRENE 018 100 .67 450.90 12. .05 323
NITRILE 019 ·100 3.25 90.18 10. .04 323
PVC 007 100 .03 1,322.64 11. .02 323
TEFLON 069 510 > 4.50 < .02 24. .05 303
VITON 009 118 > 8.00 < .02 12. .03 323

N,N·DimethylacetaMide
001271950 CPE 070 UllIe .67 23. .05 004
SARANEX 061 127 1.07 2.00 23. 104

Dimethylamine
001244030 BUTYL 014 118 > 8.00 < •02 22 • .06 323
NATURAL RUBBER 001 250 .03 80.16 20. .02 323
NEOPRENE 018 100 > 8.00 < •02 22 • .05 323
PV ALCOHOL 102 100 .28 40.08 23. .07 323
PVC 007 100 .10 20.04 20. .02 323

Dimethylaminopropyleaine
001095570 BUTYL 014 118 > 8.00 < •02 16 • .09 323
NATURAL RUBBER 001 250 .01 2,114.22 16. .02 323
NEOPRENE 018 100 .48 470.94 20. .05 323
PVC 077 100 .03 2,189.37 20. .02 323

alpha,slphs·Dimethylbenzyl Hydroperox i de
000801590 TEFLON 069 510 > 3.50 < .02 23. .05 303

Dimethylbutylamine
001080980 BUTYL 014 118 1.68 320.64 24. .06 323
NITRILE 019 100 1.35 711.42 19. .04 323
PV ALCOHOL 102 100 .33 140.28 23. .08 323
PVC 007 100 .• 05 2,575.14 21. .02 323

Dimethylethanolamine
001080100 BUTYL 014 118 > 8.00 < •02 12 • .09 323
NATURAL RUBBER 001 250 .08 100.20 19. .02 323
NEOPRENE 018 100 3.92 30.06 21. .05 323
NITRILE 019 100 > 8.00 < •02 9• .04 323

A-28
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**21MIN DEG C eM NUM

Dimethylformamide
000681220 BUTYL 012 UN" 22.00 < .02 25. .04 273
23.00 < .02 25. .04 273
> 71.00 < .02 25. .06 273
> 71.00 < .02 25. .06 273
> 24.00 < .02 25. .04 273
> 24.00 < .02 25. .04 273
> 24.00 < .02 25. .06 273
> 24.00 < .02 25. .06 273
> 6.00 1.20 25. .04 273
> 6.00 1.20 25. .04 273
> 7.00 < ·1,669.98 25. .06 273
> 7.00 < '1,669.98 25. .06 273
014 118 > 8.00 23. .04 323
> 8.00 23. .04 227
107 UN" > 8.00 25. .04 149
> 8.00 25. .04 149
> 8.00 25. .04 149
NATURAL RUBBER 001 210 1.00 n1.44 23. 080
017 100 .50 90.18 901.80 23. .05 107
NEOP+NAT RUBBER 026 121 .62 66.13 23. .05 237
NEOPRENE 002 100 1.00 9.02 90.18 23. 107
210 .13 96.19 23. 080
018 100 .85 66.13 23. .05 323
• 17 9.02 . 90.18 23. .04 107
UN" 3.00 1.20 25. .04 273
3.50 1.20 25. .04 273
> 5.50 < .02 25. .06 273
> 6.00 < .02 25. .06 273
031 UN" .02 18.04 25. .04 149
.57 47.09 25. .04 149
1.10 74.15 25. .04 149
.10 20.04 25. .04 149
125 103 54.11 23. 045
NITRILE 005 120 .58 54.11 23. .06 236
210 1.00 120.24 23. 080
019 103 .114.23 23. 045
118 .15 90.18 23. .04 323
.22 > 90.18 23. .04 227
UN" 3.50 10.82 25. .04 273
3.50 12.02 25. .04 273
> 5.00 10.82 25. .06 273
> 5.00 10.22 25. .06 273
NITRILE+PVC 057 210 1.50 132.26 23. 080
PE 076 100 .50 < .90 23. 107
PV ALCOHOL 035 UNK .08 900.80 25. .07 149
.37 1,057.78 25. .07 149
.33 48.10 25. .07 149
.12 2,191.37 25. .07 149
102 100 .33 78.16 23. .04 323
.20 24.65 23. .03 323
PVC 007 210 1.00 138.26 23. 080

A-29
stJIIIWty OF PElFOIIIWICE DETAIL TESTS
PEIlllEATlOII TEST

CHEMICAL NAMEI RESISTANT PRODUCT VEIIDOR BREAKTIIROOGH TIlE PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL OESC COOE NOURS UG/CM**2/NIN OEG C CN IIUII

000681220 SILVER SHiElD 122 118 > 8.00 23. .01 227
TEFLON 069 510 > 11.20 < .02 23. .05 303
VITON 009 118 .13 39.08 23. .03 323
.13 39.08 23. .02 227
VITON/CNlOROBUTYl 112 113 > 3.00 25. .04 302

1,1-Dimethylhydrazine (Oimethylhydrazine,unsya·)
000571470 BUTYL 014 118 > 1.50 23. _03 001
> 1.50 23. .04 001
> 1.50 23. .08 001
034 UIIC 23.00 . 27.00 2.91 22. .08 078
CNLOROBUTYL 052 205 > 1.50 23. .05 001
CPE 060 113 .50 23. .05 001
NATURAL RUBBER 017 100 .17 23. .04 001
.23 23. .05 001
.06 23. .02 001
.18 23. .04 001
.06 23. .02 001
101 .10 23. .05 001
110 .22 23. .05 001
NEOP INA T RUBBER ooa 114 .03 23. .04 001
.15 23. .04 001
.15 23. .04 001
NEOPREIIE 002 100 1.12 23. .12 001
> 1.50 23. .13 001
018 100 .63 23. .05 001
031 UIIC .42 . .67 450.90 22. .08 078
NITRILE 019 100 .15 23. .04 001
.23 23. .04 001
.10 23. .03 001
118 .12 23. .03 001
PV ALCOHOl. 004 100 . .13 23. .09 001
PVC DOl 120 .22 23. .05 001
.68 23. .10 001
.03 23. .03 001
007 100 .47 23. .09 001
.58 23. .11 001

053 ,. .28
.05
.16
23.
23.
.10
.06
001
001
23. .07 001

054 ,. .33
.53
.02
23.
23.
.05
.05
001
001
23. .05 001
077 168 .08 . .17 190.38 22. .04 078
212 .08 23. .03 001
VITON 009 118 .20 23. .03 001

Dimethyl Sulfoxide
000676850 CPE 060 113 > 3.00 25. .07 302
NATURAL RUBBER 001 210 1.33 n1.44 23. 080
UIIC 1.50 . 2.00 25. .02 276
017 100 > 1.00 < 10.02 25. .03 222
1.00 .90 . 9.02 23. .05 107

A-30
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HOURS UG/CM**21MIN DEG C CM NOM

000676850 NATURAL RUBBER 017 120 > 1.00 < 10.02 25. .02 222
203 > 1.00 < 10.02 25. .05 222
> 1.00 < 10.02 25. .06 222
NEOP/NAT RUBBER 008 114 4.00 25. .05 276
NEOPRENE 002 100 > 8.00 25. .05 276
> 3.00 9.02 90.18 23. 107
120 > 1.00 < 10.02 25. .07 222
210 6.00 < .02 23. 080
UNK 1.77 23. .05 186
018 100 > 6.00 < .90 23. .04 107
120 > 1.00 < 10.02 25. .05 222
1.00 < 10.02 25. .05 222
> 1.00 < 10.02 25. .03 222
NITRILE 005 210 4.33 5.41 23. 080
019 100 > 1.00 < 10.02 25. .04 222
2.00 • 3.00 25. .04 276
> 4.00 .90 . 9.02 23. .06 107
191 .47 350.70 25. .03 222
NITRILE+PVC 057 210 1.33 4.81 23. 080
P£ 006 100 > 1.00 < 10.02 25. .01 222
PVC 003 120 .05 380.76 25. .01 222
•70 300.60 25 • .03 222
•57 320.64 25 . .02 222
007 100 1.17 •90 • 9.02 23 • 107
210 .83 6.01 23. 080
VITON/CHLOROBUTfL 112 113 > 3.00 25. .04 302

ojmethyl vjnylch loride


005133710 NITRILE 019 100 .15 354.71 23. .05 323
PV ALCOHOL 004 100 1.18 6.01 23. .08 323
PVC 003 100 .02 420.84 23. .02 323
VITON 009 118 2.22 24.05 23. .04 323

OJ ·n·octyl Phthalate
001178400 NITRILE+PVC 058 100 .42 23. 107
PE 076 100 .08 23. 107
PVC on 100 .42 23. 107
> 6.00 < .90 23. 107

1,4·Dioxane (Diethylene Dioxide,1 ,4)


001239110 BUTYL 014 118 > 20.00 23. .07 323
> 20.00 23. .04 227
NATURAL RUBBER 017 100 .15 420.84 25. .03 222
• 08 90.1B . 901.80 23. .05 107
120 .04 801.60 25. .02 222
502 .20 340.68 25. .05 222
504 .17 280.56 25. .05 222
.45 150.30 25. .06 222
NEOP+NAT RUBBER 026 102 .28 340.68 25. .05 222
NEOP/NAT RUBBER 008 114 .30 220.44 25. .05 222
NEOPRENE 002 100 .14 220.44 25. .08 222
120 .09 330.66 25. .07 222
018 100 .27 560.92 23. .05 323

A-31
SUPlMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTAIIT PRmUCT VEIIDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASIIO MATERIAL DESC CODE IKlJRS UG/CM"'*2/MIN OEG C CM NUM

001239110 NEOPRENE 018 118 1.78 150.30 25. .08 222


120 .73 300.60 25. .05 222
.73 240.48 25. .07 222
.47 370.74 25. .05 222
.25 551.10 25. .03 222
125 103 360.n 23. 045
NITRILE 019 100 •42 861.n 25 • .04 222
1.05 3.01 25. .06 222
.45 821.64 25. .04 222
103 2,068.13 23. 045
118 .40 463.53 23. .04 323
.47 463.53 23. .04 227
503 .28 711.42 25. .03 222
PE 006 '00 .02 300.60 25. .01 222
505 •17 60.12 25 • .01 222
076 100 .05 .90 . 9.02 23. 107
PV ALtoIIDL 102 100 > 16.00 23. .03 323
PVC 003 120 •03 3,707.40 25 • .01 222
.01 4,008.00 25. .01 222
.1' 1,503.00 25. .03 222
•06 1,102.20 25 • .02 222
500 .02 5,010.00 25. .01 222
501 •02 3,807.60 25 • .01 222
.02 4,008.00 25. .02 222
007 103 402.80 23. 045
SARAICEX 061 127 • 83 17.43 23 • 104
SILVER SHIELD 122 118 > 8.00 23. .01 2Z7
TEFLa! 069 510 > 3.20 < •02 23 • .05 303
VItal 009 "8 •38 161.12 23 • .03 323
.38 161.'2 23. .02 227

Dipropyl_ine
001428470 TEFLa! 510 3.00 < .02 23. .05 303

Divinyl B_ _
013217400 IUTTL 014 118 2.22 1,430.86 23. .05 323
2.20 1,430.86 23. .04 227
MITRILE 019 100 1.00 2,703.60 23. .04 323
PV ALCOMOl 102 100 > 18.00 23. .03 323
SILVER SHIELD 122 ',8 > 8.00 23. .01 227
Vital 009 118 > 17.00 23. .02 323
> 17.00 23. .02 227

Epichlorohydrin
001068980 BUTYL 014 118 24.00 23. .04 291
24.00 23. .04 291
24.00 23. .04 291
24.00 23. .04 291
> 8.00 < ·1,669.98 23. .07 323
> 8.00 < '1,669.98 23. .07 323
034 UIQC 79.00 •20 22 • .08 078
NATUltAL RUBBER 001 250 < .02 504.34 23. .02 323
< .02 504.34 23. .02 323

A-32
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM

001068980 NATURAL RUBBER 011 UNIC -os 130.26 23. .02 291
.06 138.28 23 . .02 291
NEOPRENE 018 100 •33 362.72 23. .04 291
•25 314.63 23 • .04 291
031 UNIC 1.00 - 1.33 110.22 22. .08 018
NITRILE 020 503 .42 1,252.50 23. .04 291
.33 1,152.30 23. .04 291
PE .' 006 100 .OS 9.45 23. .01 291
.05 9.74 23. .01 291
PV ALCOHOL 035 UNK < •08 130.26 22 • .01 078
102 100 •05 127.25 23 • .OS 291
.02 105.21 23. .OS 291
5.82 .30 23. .07 323
5.82 .30 23. .01 323
SARANEX 061 127 1.00 3.32 23. .02 291
1.00 3.44 23 • .02 291
•95 52.30 23. 104
TEFLON 036 214 7.00 .02 23. .01 291
7.00 .02 23. .01 291
069 510 > 3.40 < .02 23. .05 303
VITON 009 118 1.00 51.20 23. .02 291
1.00 51.90 23. .02 291
1.00 50.70 23. .02 291
2.OS 6.13 23. .03 323
2.OS 6.13 23. .03 323

l,2-Epoxybutane
001068870 BUTYL 014 118 .75 20.04 23. .06 323
NEOPRENE 018 100 .07 20.04 23. .05 323
PV ALCOHOL 004 100 > 8.00 < .02 23. .04 323
VITON 009 118 .03 20.04 23. .03 323

Ethanol8lline (Ami noethanol.2)


001414350 BUTYL 014 118 > 8.00 26. .01 323
NATURAL RUBBER 001 210 4.50 6.61 23. 080
011 100 3.50 .90 9.02 23. .05 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
210 6.00 < .02 23. 080
018 100 > 6.00 < .90 23. .04 107
> 8.00 20. .05 323
NITRILE OOS 210 6.00 < .02 23. 080
019 100 > 6.00 < .90 23. .06 107
NITRILE+PVC OS7 210 5.00 4.21 23. 080
OS8 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PV ALCOHOL 004 100 2.50 .90 - 9.02 23. 107
PVC 007 100 > 6.00 < .90 23. 107
> 8.00 25. .02 323
210 2.00 1.82 23. 080
077 100 > 6.00 23. 107
> 6.00 23. 107
VITON 009 118 > 8.00 22. .05 323

A-33
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAlCTHRClJGH TIME PERMEATION RATE TEMP THICKNESS REf
CASNO MATERIAL DESC CalE HOURS UG/CM**2/MIII DEG C DI

Ethyl Acetate
001417860 BUTYL 014 118 7.60 ZO.44 23. .04 227
CPE 060 113 .97 . 1.17 25. .07 302
NATURAL RUBBER 001 210 .18 54.11 23. 080
017 100 .08 9.02 90.18 23. .05 107
NEOPRENE 002 100 • 33 9.02 90.11 23 • 107
210 •20 41.10 23 • 080
018 100 .25 9.02 90.18 23. .04 107
NITRILE 005 210 • 50 66.13 23 • 080
019 118 .13 871.74 23. .04 227
NITRILE+PVC 057 210 .50 41.10 23. 080
PE 076 100 .07 9.02 90.18 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
PVC 007 210 • 33 78.16 23 • 080
SARAIIEX 061 127 .60 6.61 23. 104
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEfLCIII 069 510 > 3.10 < .02 23. .05 303
> 4.30 < .02 24. .05 303
VITCIII/CHLOROBUTYL 112 113 .33 • .66 25. .04 302

Ethyl Cellosolve (Ethoxyethanol, 2)


001108050 BUTYL 014 118 > 8.00 23. .06 323
> 8.00 23. .08 323
NATURAL RUBBER 001 103 1.20 23. 045
250 •02 72.14 23 • .02 323
506 < •01 49.30 23 • .01 323
NEOPRENE 018 100 4.08 18.64 23. .06 323
125 103 6.01 23. 045
IITRILE 019 100 1.53 56.51 23. .04 323
103 54.11 23. 045
PV ALCOtIOL 102 100 .05 132.26 23. .08 3Z3
PVC 007 100 .07 162.32 23. .02 323
103 6.01 23. 045

Ethyl Acrylate
001'08850 250 250 .02 1,040.08 23. .02 323
BUTYL 014 118 > 1.00 23. .09 3Z3
064 117 .67 23. .02 213
.81 23. .01 213
.67 23. .02 213
BUTYL/NEOPRENE 110 117 1.00 23. .02 213
CPE 060 113 1.08 • 1.17 25. .07 302
lIIIC .50 23. 142
1.42 23. 142
070 lIIIC • 40 23 • .05 004
IEOPRENE 093 117 < .08 23. .02 213
138 117 .08 23. .03 213
139 117 < .25 23. .02 213
PE 076 117 < .08 23. .01 213
PV ALCOHOL 102 100 > 1.00 23. .08 3Z3
PVC 003 100 .03 1,040.08 23. .02 323
049 117 •05 23 • .01 213

A-34
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME I RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2!MIN DEG C CM NUM

001408850 SARANEX 061 117 1.33 23. .01 213


TEFLON 069 510 > 17.00 < .02 23. .05 303
VITON 145 117 < •08 23 . .01 213
VITON/CHLOROBUTYL 112 113 • 23 .53 25 . .04 302
UtIle > 3.00 23. 142
VITON/NEOPRENE 111 117 • 20 23 . .02 213

Ethyl Alcohol (Ethanol) .


000641750 NATURAL RUBBER 001 210 1.50 6.01 23. 080
017 100 .47 4.01 25. .03 222
•50 .90 . 9.02 23 . .05 107
120 • 20 14.03 25 • .02 222
502 > 1.00 < 4.01 25. .05 222
504 > 1.00 < 4.01 25. .05 222
> 1.00 < 4.01 25. .06 222
NEOP+NAT RUBBER 026 121 .37 > .33 23. .05 237
NEOP/NAT RUBBER 008 114 > 1.00 < 4.01 25. .05 222
NEOPRENE 002 100 3.00 • 90 • 9.02 23 • 107
> 1.00 < 4.01 25. .08 222
120 > 1.00 < 4.01 25. .07 222
210 2.00 3.01 23. 080
018 100 1.50 .90 . 9.02 23. .04 107
"8 > 1.00 < 4.01 25. .08 222
120 > 1.00 < 4.01 25. .05 222
> 1.00 < 4.01 25. .07 222
> 1.00 < 4.01 25. .05 222
> 1.00 < 4.01 25. .03 222
031 511 .82 1.80 23. 323
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 1.00 < 4.01 25. .04 222
4.00 •90 . 9.02 23 • .06 107
> 1.00 < 4.01 25. .06 222
> 1.00 < 4.01 25. .04 222
503 > 1.00 < 4.01 25. .03 222
NITRILE+PVC 057 210 6.00 < .02 23. 080
058 100 .25 .90 9.02 23. 107
PE 006 505 > 1.00 4.01 25.
< .01 222
076 100 .05 > 9,018.00 23. 107
PV ALCOHOL 004 100 1.67 55." 23. 123
1.67 5.51 21. 124
PVC 003 120 .05 43.09 25. .01 222
.08 37.07 25. .01 222
.33 28.06 25. .03 222
.18 43.09 25. .02 222
500 .06 28.06 25. .01 222
501 .05 34.07 25. .01 222
.03 57.11 25. .02 222
007 100 1.00 .90 9.02 23. 107
210 2.50 6.01 23. 080
077 100 .25 < .90 23. 107
.50 .90 9.02 23. 107
TEFLON 069 510 > 3.00 < .02 23. .05 303

A-35
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAlCTHRClIGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOORS UG/CM**2/MIN DEG C CM NUN

Ethylamine, 30-70%
0007504n BUTYL 014 118 > 12.00 < -1,669.98 23. .04 227
NITRILE 019 118 1.10 180.96 23. .04 227
SILVER SHIELD 122 118 .47 36.07 23. .01 227
TEFLON 069 510 > 3.00 < .02 23. .05 303

Ethyl Benzene
001004140 PV ALCOHOL 102 100 .55 23. .08 323
TEFLON 069 510 > 3.00 < •02 23 • .05 303

Ethyl Bromide
000749640 NEOPRENE 018 100 .07 1,322.64 23. .04 323
PV ALCOHOL 102 100 1.07 .42 23. .08 323
PVC 003 100 < .02 2,104.20 23. .02 323
VITON 009 118 1.43 30.06 23. .04 323

Ethyl·n·butylamine
133606390 NITRILE 019 100 1.22 210.42 24. .04 323
PV ALCOHOL 102 100 6.72 20.04 23. .09 323
PVC 007 100 .06 2,648.62 24. .02 323
VITON 009 118 3.80 1,482.96 23. .03 323

Ethyl Cyanide (Propionitri le)


001071200 BUTYL 014 118 .40 167.73 23. .06 323
NATURAL RUBBER 001 506 < .01 79.36 23. .01 323
PV ALCOHOL 102 100 > 8.00 23. .03 323
PVC 003 100 < .01 18.04 23. .02 323

Ethylene ChlorOhydrin (Chloroethanol)


001070730 BUTYL 014 118 8.00 < •02 23 • .06 323
NEOPRENE 018 100 4.98 •70 23 • .05 323
PV ALCOHOl 102 100 1.85 20.04 23. .09 323
VITOU 009 118 > 8.00 < •02 23 • .05 323

Ethylenediamine (Di ..inoethane,1,2)


001071530 BUTYL 014 118 > 8.00 < •02 18 • .07 323
CPE D60 113 2.00 23. .05 204
2.67 36.07 23. .05 204
NATURAL RUBBER 001 250 .08 501.00 20. .01 323
NEOPRENE 018 100 6.65 20.04 18. .05 323
PE 076 127 .25 10.22 23. 104
PVC 007 100 • 17 BO.16 16 • .02 323
SARANEX 061 127 > 8.00 < .02 23. 104
TEFLON 069 510 > 3.20 < .02 23. _05 303

Ethylene Dibromide (Dibromoethane,1,2)


001069340 BUTYL 014 118 1.70 75.15 23. .04 291
1.83 79.16 23. .04 291
3.33 36.07 23. .07 323
D64 117 •55 23 • .02 213
•38 23 • .01 213
•38 23 • .02 213

A-36
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATI 011 TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**Z/MIN DEG C CM NUM

001069340 BUTYL/NEOPRENE 110 117 < • 08 23 • .02 213


CPE 070 UNIC .73 23. .05 004
NATURAL RUBBER D17 UNIC < .02 ,. 731.46 23. .02 291
< • 02 ,. 731.46 23 • .02 291
NEOPRENE 018 100 • 13 731.46 23 • .04 291
• 20 > 731.46 23 . .04 291
093 117 < .33 23. .02 213
125 103 354.71 23. 045
139 117 .08 23. .02 213
NITRILE 019 103 583.16 23. 045
020 503 • 58 > 731.46 23 • .04 291
• 45 731.46 23 • .04 291
PE 006 100 < • 03 158.32 23 • .01 291
< • 03 141.28 23 • .01 291
076 117 • 75 23 • .01 213
PV ALCOIIOl 102 100 > 24.00 23. .05 291
> 24.00 23. .05 291
> 8.00 23. .08 323
PVC 007 100 .03 1,406.81 23. .02 323
103 294.59 23. 045
049 117 .12 23. .01 213
SARANEX 061 117 .55 23. .01 213
127 .17 49.10 23. .02 291
• 13 49.10 23 • .02 291
TEFLON 036 214 1.00 23. .01 291
> 24.00 23. .01 291
> 24.00 23. .01 291
069 510 > 3.40 < .02 23. .05 303
VITON 009 118 > 24.00 23. .02 291
> 24.00 23. .02 291
> 8.00 23. .03 323
145 117 .58 23. .01 213
VITON/IIEOPRENE 111 117 1.08 23. .02 213

Ethylene Dichloride (Dichloroethane,1,2)


001070620 BUTYL 014 118 2.98 531.06 23. .06 323
2.90 318.64 23. .04 227
UIIIC 2.33 23. .06 326
064 UIIIC 1.17 23. .04 326
CPE 070 UNIC .25 23. .05 004
NATURAL RUBBER 001 250 .01 350.70 23. .02 323
017 100 .01 1,603.20 ·25. .03 222
120 .02 3,106.20 25. .02 222
502 .08 1,302.60 25. .05 222
504 .06 2,505.00 25. .05 222
.16 801.60 25. .06 222
UNIC .03 23. .02 326
NEOP+NAT RUBBER 026 102 .08 1,302.60 25. .05 222
NEOP/NAT RUBBER 008 114 .01 1,302.60 25. .05 222
NEOPRENE 002 100 .03 701.40 25. .08 222
120 .04 801.60 25. .07 222
018 118 .70 501.00 25. .08 222
120 .27 701.40 25. .05 222

A-37
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICICNESS REF
CASNO MATERIAL DESC CClOE HClURS UG/CIf**2!MJN DEG C

001070620 NEOPRENE 018 120 .47 801.60 25. .07 222


• 14 1.002.00 25 • .05 222
•06 1.803.60 25 • .03 222
UNIC .33 23. .06 326
NITRILE 019 100 • 11 3.807.60 25 • .04 222
.28 2.605.20 25. .06 222
• 12 3.907.80 25 • .04 222
118 .13 1.869.73 23. .04 227
503 •08 3.907.80 25 • .03 222
UNIC .04 23. .02 326
020 UNIC .04 23. .03 326
PE 006 100 .02 10.02 25. .01 222
505 .09 10.02 25. .01 222
042 UlIC .04 23. .01 326
076 100 •05 .90 • 9.02 23 • 107
PV ALCOHOL 004 100 > 3.00 .90 9.02 23. 107
> 1.00 < .02 23. .03 323
102 100 > 1.00 23. .04 323
5.50 23. .05 32l
utIIC .37 23. .04 326
003 120 •01 11.022.00 25 • .01 222
•01 9.719.40 25 • .01 222
.03 4.509.00 25. .03 222
.02 6.913.80 25. .02 222
500 .01 25. .01 222
501 •01 13.026.00 25 • .01 222
•01 7.115.60 25 • .02 222
SILVER SHIELD 122 111 > 6.00 23. .01 227
TEFLe. 036 UIIIC > 24.00 23. .01 326
044 lII( 1.50 23. .01 326
Vile. 009 111 6.90 4.88 23. .02 227
> 1.00 e .02 23. .03 32l
1].67 23. .03 326

Ethyl_ Glycol
001072110 NATlIIAL IUlBER 001 210 6.00 .02 23. 080
017 100 > 1.00 < 10.02 25. .03 222
> 6.00 < ."90 23. .05 107
120 > 1.00 < 10.02 25. .02 222
502 > 1.00 e 10.02 25. .05 Z22
504 > 1.00 < 10.02 25. .05 222
> 1.00 10.02' 25. .06 Z22
IlECP+IIAT RUBBER 026 102 > 1.00 < 10.02 25. .05 222
121 > 1.00 < .02 23. .05 237
II£OP/IIAT RUBBER 008 11' > 1.00 < 10.02 25. .05 222
IIEOPRENE 002 100 > 6.00 < .90 23. 107
> 1.00 < 10.02 25. .08 222
210 6.00 < .02 23. 080
018 100 > 6.00 < .90 23. .04 107
118 > 1.00 < 10.02 25. .08 222
120 > 1.00 < 10.02 25. .05 222
> 1.00 e 10.02 25. .07 222
> 1.00 < 10.02 25. .05 Z22

A-38
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VEIIOOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM

0010nl10 NEOPRENE 018 120 > 1.00 < 10.02 25. .03 222
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 1.00 < 10.02 25. .04 222
> 6.00 < .90 23. .06 107
> 1.00 < 10.02 25. .04 222
503 > 1.00 < 10.02 25. .03 222
NITRllE+PVC 057 210 6.00 < .02 23. 080
058 100 > 6.00 < .90 23. 107
PE 006 100 > 1.00 < 10.02 25. .01 222
505 > 1.00 < .10 25. .01 222
076 100 > 6.00 < .90 23. 107
PV ALCOHOL 004 100 2.00 .90 9.02 23. 107
PVC 003 120 > 1.00 < 10.02 25. .01 222
> 1.00 25. .01 222
> 1.00 < 10.02 25. .03 222
> 1.00 < 10.02 25. .02 222
500 > 1.00 < 10.02 25. .01 222
501 > 1.00 < 10.02 25. .01 222
> 1.00 < 10.02 25. .02 222
007 100 > 6.00 < .90 23. 107
210 6.00 < .02 23. 080
on 100 .75 .90 9.02 23. 107
> 6.00 < .90 23. 107
TEFLON 069 510 > 16.80 < .02 23. .05 303

Ethylene Oxide (Oxirane)


000752180 NITRILE 019 103 .37 23. 045

Ethylenimine (Aziridine)
001515640 BUTYL 034 UIIIC 10.00 • 16.00 4.51 22. .08 078·
NEOPREIIE 010 120 < .08 22. .02 078

Ethyl Ether
000602970 BUTYL 014 118 .13 554.31 23. .04 227
NATURAL RUBBER 001 210 • 17 1.563.12 23 • 080
NEOPRENE 002 100 .17 9.02· 90.18 23. 107
210 .20 1.232.46 23. 080
018 100 .17 9.02 90.18 23. .04 107
125 103 330.66 23. 045
NITRILE 005 210 2.30 84.17 23. 080
019 100 2.00 9.02' 90.18 23. .06 107
103 264.53 23. 045
118 .23 131.06 23. .04 227
NITRILE+PVC 057 210 .42 1,863.n 23. 080
PE 076 100 .03 90.18 901.80 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
102 100 > 8.00 23. .04 323
PVC 007 210 .33 2,104.20 23. 080
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEFLON 069 510 > 3.00 < .02 23. .05 303
> 3.00 < .02 23. .05 303
VITON 009 118 .20 129.26 23. .03 323
.20 129.26 23. .02 227

A-39
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST

CHE"'ICAl NAMEI RESISTANT PRODUCT V[NDOR 8REAKTHROUGH TINE PERMEATION RATE TEMP THICKNESS Ref
CASNO MATERIAL DESC COOE HOURS UG/CM**2!MIN DEG C CM NUM

V I TON/CHlOR08IIl Yl l1Z lH _U~· . .17 25.

'·Ethvlhexanoi,· Acid
NEOPRENE 018 lOa 4 CO 2~. .G~ i23
NITRILE 019 100 > ':'.00 23. .i:.. 1 ~3
PVC 003 215 > ... 00 23 • .v.. 123

- . t:thvl- 1 - Hexanol
:1'1047670 6~ITYl ~18 > B.OO 23. • <iT 323
NEOPRENE 100 ~.OO 23. .G~ 3::3
p" ALCOHOL 10C > 8.00 23. .09 ';23
V! TOIl oo'? "8 8.'.,0 23. . 03 ~.'3

E: ",~ >:';0" Dichloride {Dichloroethane, 1 ,1>


: ..~ :5.:;·, J:j BUTYl 012 118 1.~2 186.37 23. .(j9 323
I>V ALCOHOL (J04 lOa 2.73 23. .08 323
PVC 003 100 .02 1,902.46 23. _02 323
. 03 ~,929.85 23 . .02 323
VITON 009 H8 2.43 36.07 23. .04 323

~ [~)lt "'et~ ~c ryl ate


~OC9!OlO BUTYl 014 118 6.57 12.02 23. .09 !:23
CPE 070 UNK •53 23 • .05 004
N!TRILl: 019 100 . 38 186.37 23 . .05 323
PV ALCOHOL 102 100 > 8.00 23. .06 323
PVC 003 100 . 03 84.17 23 . .02 323

Ft'rmaldellyde, <37% (Fol'IIIal in)


000500000 BUTYL 014 118 16.00 23. .04 323
> 16.00 23. .04 227
CPE 070 UNK > 3.00 23. .05 004
NATURAL RUBBER 001 506 .20 .02 23. .02 323
017 100 1.00 .90 9.02 23. .05 107
lINK .10 3.34 26. .02 148
NEOPRENE 002 100 2.00 .90 9.02 23. 107
018 100 2.00 < .90 23. .04 107
125 103 < .02 23. 045
NITRILE 019 100 > 6.00 < .90 23. .06 107
103 < .02 23. 045
118 > 21.00 23. .04 323
> 21.00 23. .04 227
UNK > 6.00 < .02 26. .03 148
NITRILE+PYC 058 100 .50 .90 9.02 23. 107
PE 076 100 > 6.00 < .90 23. 107
127 > 8.00 < .02 23. 104
PVC 003 100 .07 .05 23. .02 323
007 100 1.33 .90 9.02 23. 107
103 < .02 23. 045
on 100 .33 .90 9.02 23. 107
6.00 9.02 90.18 23. 107
SILVER SHielD 122 118 > 6.00 23. .01 227
TEFLOII 069 510 3.00 < .02 23. .05 303
YITON 009 118 16.00 23. .02 323

A-40
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM MUM

OOOSOOOOO VITON 009 118 > 16.00 23. .02 227

Formic Acid (MethBnoic Acid)


000641860 PE 076 127 .07 .03 23. 104

Formic Acid, >70%


000641863 NATURAL RUBBER 017 100 2.00 23. .05 107
NEOP+~AT RUBBER 026 121 3.20 12.02 23. .05 237
NEOPRENE 002 100 > 6.00 23. 107
018 100 > 6.00 23. .04 107
NITRILE 019 100 4.00 23. .06 107
NITRILE+PVC 058 100 .50 23. 107
PE 076 100 .20 23. 107
PVC 007 100 6.00 23. 107
on 100 .67 23. 107
1.25 23. 107

Freon TF
000761310 NATURAL RUBBER 017 100 .15 1,002.00 25. .03 222
120 .04 3,006.00 2S. .02 222
502 .28 821.64 2S. .OS 222
504 .27 101.40 2S. .05 222
.48 591.18 2S. .06 222
IIEOP+NA T RUBBER 026 102 .27 101.40 25. .05 222
121 .21 474.95 23. .05 237
NEOP/NAT RUBBER 008 114 .21 791.S8 2S. .05 222
NEOPRENE 002 100 2.00 .90 9.02 23. 107
> 1.00 < 10.02 25. .08 222
120 3.00 20.04 25. .07 222
018 100 4.00 < .90 23. .04 107
118 > 1.00 < 10.02 2S. .08 222
120 > 1.00 < 10.02 2S. .05 222
> 1.00 < 10.02 2S. .07 222
> 1.00 < 10.02 2S. .05 222
> 1.00 < 10.02 25. .03 222
NITRILE 019 100 > 1.00 < 10.02 25. .04 222
> 6.00 < .90 23. .06 107
> 1.00 < 10.02 2S. .06 222
> 1.00 < 10.02 25. .04 222
503 > 1.00 < 10.02 25. .03 222
NITRlLE+PVC 058 100 .2S 90.18 901.80 23. 107
PE 006 100 .08 10.02 2S. .01 222
S05 > 1.00 < 1.00 25. .01 222
076 100 .13 9.02 90.18 23. 107
PV ALCOHOL 004 100 .SO .90 9.02 23. 107
PVC 003 120 .04 3,406.80 25. .01 222
.09 2,204.73 25. .01 222
.18 190.38 25. .03 222
.13 240.48 25. .02 222
SOD .04 2,605.20 25. .01 222
5(11 .04 3,006.00 25. .01 222
.05 1,903.80 25. .02 222
on 100 .30 9.02 . 90.18 23. 107

A-41
SUMMARY OF PERFORNAICE DETAIL TESTS
PEIIMEA TlOII TEST

CHEMICAL NAMEI RESISTANT PROOUCT VENDOR BREAKTIIItOOGH TUIE PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM

000761310 PVC on 100 1.00 9.02 . 90.18 23. 107

Freon TNC
577623190 NATURAL RUBBER 017 100 •05 901.80 9,018.00 23 • .05 107
NEOPRENE 002 100 • 17 90.18 901.80 23 • 107
018 100 •OS 901.80 9,018.00 23 • .04 107
NITRILE 019 100 • 17 901.80 9,018.00 23 • .06 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107

Furln (Furfuran)
001100090 BUTYL 014 118 1.35 60.12 23. .09 323
PV ALCOHOl. 102 100 1.89 .GII 23. .09 323
PVC 003 100 .02 2,951.89 23. .02 323
VITOII 009 118 .33 138.28 23. .05 323

Furfurel
000980110 IUTYL 014 118 > 16.00 23. .04 323
> 16.00 23. .04 227
NATURAL RUIIER 001 210 .25 30.06 23. oao
017 100 .25 9.02 • 90.18 23. .05 107
002 100 2.00 9.02· 90.18 23. 107
210 .50 18.04 23. oao
011 '00 .33 9.02· 90.18 23. .04 107
IITIULE 005 210 .92 156.31 23. oao
019 118 • 40 1,591.38 23 • .03 323
.47 1,591.11 23. .04 227

-
IITRILE+PW: 057 210 .67 144.29 23. oao
fIE 076 100 .GII ~ .90 23. 107
PV ALCGNOL 100 > 6.00 ~ .90 23. 107
102 '00 > 16.00 23. .03 323
PVC 007 210 1.17 108.22 23. oao
SILva SlIELD 122 "1 > 8.00 23. .01 227
TE'LCII 069 "0 > 1.00 ~ .02 23. .05 303
VITa. 009 "1 3.50 88.98 23. .03 323
3.60 88.98 23. .02 227

GeNt I,.

-
010II66190 IUTYL 064 117 •• 23. .02 213
IUTYLJI8ECIIIDE 110 117 .33 23. .02 213
IlEClMlAT IIUIIEI 121 .07 1,076.15 23. .05 237
IITRILE 0 79 100 6.00 ~ .90 23. .06 107

-
IITRILE+PW: 051 100 .08 90.18· 901.1D· 23. 107
fIE 076 100 .05 90.11· 901.1D 23. 107
PV ALCGNOL '00 6.00 < .90 23. 107
PVC 077 100 .07 9.02· 90.11 23. 107
.GII 90.18· 901.80 23. 107
VI Ta./llEOPIIENE 111 117 8.00 23. .02 213

Glutereldehyde
00",3080 BUTYL 014 118 > 8.00 < .02 23. .09 323
NEOPIEIE 018 100 > 1.00 < .02 23. .05 323
PVC 003 100 1.17 6.01 23. .02 323
VITOII 009 118 > 1.00 < .02 23. .04 323

Jr-42
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATI TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM

Halothane
001516nO BUTYl 014 118 3.07 138.28 23. .09 323
PV ALCOHOL 102 100 > 8.00 23. .07 323
PVC 007 100 .03 4,064.11 23. .02 323
VITON 009 118 .62 432.86 23. .05 323

Heptane
001428250 NATURAL RUBBER 001 210 .10 703.07 23. 080
UNIC •02 > 521.04 23 . .12 274
017 UNIC •03 > 531.06 23 . .04 274
NEOP/NAT RUBBER OOS UNIC • 08 > 526.05 23 . .05 274
NEOPRENE 002 210 .75 499.00 23. 080
018 UNK > 1.00 23. .06 274
> 1.00 23. .09 274
NITRILE 005 210 6.00 < .02 23. 080
019 UNK > 1.00 23. .05 274
> 1.00 23. .05 274
NITRILE+PVC 057 210 3.00 18.04 23. 080
PVC 007 210 .50 180.36 23. 080
UNIC .25 > 450.90 23. .16 274
VITON 009 UNIC > 1.00 23. .03 274

Hexachlorocyclopentadiene
000n4740 BUTYL 014 118 > 8.00 < .02 23. .06 323
NITRILE 019 100 > 8.00 < .02 23. .04 323
PV ALCOHOL 102 100 > 8.00 < .02 23. .08 323
VITON 009 118 > 8.00 < .02 23. .03 323

Hexamethylphosphoamide
006803190 BUTYl 034 UNIC 1.00 1.50 .OZ ZZ. .08 078
NITRILE 033 UNIC 1.00 . 1.50 13.03 22 . .09 078
PE 006 209 •25 . .42 4.01 22. .01 078

Hexane
001105430 BUTYL 012 UNIC .13 > 2,344.68 25. .04 273
.17 1,923.84 25. .04 273
.33 1,833.66 25. .06 273
.42 1,238.47 25. .06 273
.03 > 2,344.68 25. .04 273
.17 2,314.6Z Z5. .04 273
.50 1,370.74 25. .06 273
.50 1,226.45 25. .06 273
.12 > 2,344.68 25. .04 273
.17 > 2,344.68 25. .04 273
.33 1,1n.34 25. .06 273
.33 1,490.98 25. .06 273
014 UNK .04 256.11 25. 287
107 UNK .35 23. .04 094
.17 45. .04 094
CPE 060 113 > 3.00 25. .07 302
NATURAL RUBBER 001 210 .08 751.50 23. 080
NEOPRENE 002 100 1.50 9.02 . 90.18 23. 107

A-43
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM*·2/MIN DEG C eM NUM

001105430 NEOPRENE 002 210 .67 576.15 23. 080


UNK .86 23. .05 186
•06 27.66 25 • 287
018 100 .75 .03 23. .05 323
.75 90.18 . 901.80 23. .04 107
UNK 1.00 121.44 25. .04 273
1.00 75.15 25. .04 273
1.00 91.38 25. .06 273
1.00 52.91 25. .06 273
031 UNK .33 37. .04 187
125 103 12.02 23. 045
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 4.00 23. .04 323
> 6.00 < .90 23. .06 107
103 6.01 23. 045
UNK > 7.00 < .02 25. .04 273
> 18.00 < .02 25. .04 273
> 17.00 < .02 25. .06 273
> 17.00 < .02 25. .06 273
033 UNK 1.31 37. .OS 187
NITRILE+PVC 057 210 1.50 42.08 23. 080
058 100 .07 90.18 901.80 23. 107
PE 056 UNK .07 37. .01 187
076 100 .0190.18 901.80 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
UNK > 8.17 25. 287
102 100 > 14.00 23. .03 323
PVC 007 103 90.18 23. 045
210 .42 270.54 23. 080
UNK .31 23. .05 186
.62 23. .07 186
049 UNK .48 37. .03 187
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEFLON 069 510 > 5.00 < .02 23. .05 303
> 5.00 < .02 23. .05 303
VITON 009 118 > 11.00 23. .02 323
> 11.00 23. .02 227
VITON/CHLOROBUTYL 112 113 > 3.00 25. .04 302
> 3.00 25. .04 302

Hydrazine (Diamine)
003020120 BUTYL 014 118 > 8.00 23. .04 323
NEOPRENE 018 100 > 16.00 23. .05 323
NITRILE 019 118 > 8.00 23. .04 323
PVC 003 100 > 8.00 23. .03 323

Hydrazine, 30·7QX
003020122 BUTYL 014 118 > 8.00 < .02 23. .04 227
NATURAL RUBBER 017 100 > 6.00 < .90 23. .05 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
018 100 > 6.00 < .90 23. .04 107
NITRILE 019 100 > 6.00 < .90 23. .06 107
118 > 8.00 < .02 23. .04 227

A-44
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PROOUCT VENDOR BREAICTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS UG/CM**2/MIN DEG C CM NUM

003020122 NITRILE+PVC 058 100 > 6.00 23. 107


PE 076 100 > 6.00 23. 107
PVC 007 100 > 6.00 < .90 23. 107
077 100 > 6.00 23. 107
> 6.00 23. 107
SILVER SHIELD 122 118 2.10 6.01 23. .01 227

Hydrochloric Acid
076470100 BUTYL 064 117 > 8.00 23. .02 213
> 8.00 23. .01 213
> 8.00 23. .02 213
BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213
CPE 070 lINlC > 3.00 23. .05 004
NATURAL RUBBER 001 210 6.00 < .02 23. 080
NEOP+NAT RUBBER 026 121 4.42 12.02 23. .05 237
NEOPRENE 002 210 6.00 < .02 23. 080
093 117 > 8.00 23. .02 213
138 117 > 8.00 23. .03 213
NEOPRENE+PVC 127 117 > 8.00 23. .02 213
NITRILE 005 210 6.00 < .02 23. 080
NITRILE+PVC 057 210 6.00 < .02 23. OS()
058 117 1.75 23. .01 213
PVC 007 210 6.00 < .02 23. 080
049 117 > 8.00 23. .01 213
> 8.00 23. .01 213
053 117 5.11 23. .02 213
077 117 < 5.00 23. .01 213
2.92 23. .01 213
144 117 4.33 23. .02 213
SARANEX 061 117 5.00 23. .01 213
VITON 145 117 > 8.00 23. .02 213
VITON/NEOPRENE 111 117 > 8.00 23. .02 213

Hydrochloric Acid, <lOX


076470101 NATURAL RUBBER 017 100 > 6.00 23. .05 107
102 > 8.00 23. .05 026
> 8.00 23. .05 026
> 8.00 23. .05 026
> 8.00 23. .05 026
NEOP+NAT RUBBER 026 102 > 8.00 23. .06 026
> 8.00 23. .04 026
> 8.00 23. .05 026
NEOP/NAT RUBBER oos 102 > 8.00 23. 026
NEOPRENE 002 100 > 6.00 23. 107
018 100 > 6.00 23. .04 107
NITRILE 019 100 > 6.00 23. .06 107
NITRILE+PVC 058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC 007 100 > 6.00 23. 107
on 100 > 6.00 23. 107
> 6.00 23. 107

Hydrochloric Acid, 30-70%


lr45
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAlCTHRooGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HooRS UG/tM**2/MIN DEG C CM lUI

076470102 NATURAL RUBBER 001 UNIC > 1.00 23. 052


015 UIIIC > 1.00 23. .04 052
017 100 > 5.00 23. .05 107
102 > 8.00 23. .05 026
5.50 23. .05 026
> 8.00 23. .05 026
> 8.00 23. .05 026
NEOP+NAT RUBBER 026 102 > 2.50 23. .06 026
> 8.00 23. .04 026
> 8.00 23. .05 026
NEOP/NAT RUBBER 008 102 > 8.00 23. 026
UNIC > 1.00 23. 052
NEOPRENE 002 100 > 6.00 23. 107
018 100 > 6.00 23. .04 107
UNIC > 1.00 23. .06 052
NITRILE 019 100 > 6.00 23. .06 107
UtaC > 1.00 23. .05 052
PE 076 127 .58 23. 104
PVC 003 UtaC .40 23. .02 052
007 100 ) 5.00 23. 107
UNIC ) 1.00 23. D52
SARAIIEX 061 127 > 46.67 < .02 23. 104
SILVER SHIELD 122 118 > 6.00 23. .01 227
YITON 009 UNIC > 1.00 23. .03 052
Hydrochlorie Aeld, >7OX
076470103 IIATURAL IlUB8£R 017 102 > 6.00 23. .05 026
5.50 23. .05 026
> 6.00 23. .05 026
5.50 23. .05 026
NEOP+IlAT RUBBER 026 102 > 2.50 23. .06 026
5.50 23. .04 026
> 6.00 23. .05 026
NEOP/NAT RUBBER 008 102 > 6.00 23. 026

Hydroeyanie Aeid
000749080 BUTYL 034 lIIIC 1.00 < .02- .04 148
PE 076 lIIIC 1.00 .12- .02 148
PVC 049 UIII( .50 .28- .08 148

H)/drofluorie Add (Hydrogen fluoride)


076643930 BUTYL 064 117 > 8.00 23. .02 213
> 8.00 23. .01 213
7.08 23. .02 213
BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213
NEOPRENE 093 117 > 8.00 23. .02 213
138 117 4.25 23. .03 213
139 117 > 8.00 23. .02 213
NEOPRENE+PVC 127 117 3.50 23. .02 213
IIITRILE+PVC 058 117 1.08 23. .01 213
PE 076 117 1.50 23. .01 213
PVC 049 117 > 8.00 23. .01 213
2.17 23. .01 213
A-46
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS UG/CH**2/MIN DEG C CM NUM

076643930 PVC 053 117 2.08 23. .02 213


1.67 23. .02 213
077 117 < .08 23. .01 213
.92 23. .01 213
144 117 •42 23 . .02 213
SARANEX 061 117 3.17 23. .01 213
VITON 145 117 > 8.00 23. .01 213
VITON/NEOPRENE 111 117 > 8.00 23. .02 213

Hydrofluoric Acid, 30·70X


076643932 NATURAL RUBBER 017 100 3.50 23. .05 107
102 > 8.00 23. .05 026
1.50 23. .05 026
> 8.00 23. .05 026
4.50 23. .05 026
NEOP+NAT RUBBER 026 102 3.00 23. .06 026
3.50 23. .04 026
8.00 23. .05 026
121 > 8.00 < •02 23 • .05 237
NEOP/NAT RUBBER 008 102 > 8.00 23. 026
NEOPRENE 002 100 1.25 23. 107
018 100 1.00 23. .04 107
NITRILE 019 100 2.00 23. .06 107
NITR I LE+PVC 058 100 .08 23. 107
PE 076 100 > 6.00 23. 107
127 > .50 < .10 23: 104
PVC 007 100 .67 23. 107
077 100 2.00 23. 107
1.50 23. 107
SARANEX 061 127 > .50 < • 10 23 • 104

Hydrofluoric Acid, >70%


076643933 NATURAL RUBBER 017 102 4.00 23. .05 026
1.50 23. .05 026
4.00 23. .05 026
1.50 23. .05 026
NEOP+NAT RUBBER 026 102 1.50 23. .06 026
1.50 23. .04 026
4.00 23. .05 026
NEOP/NAT RUBBER DOS 102 4.00 23. 026

Hydrogen Peroxide, 30·70X


Om28412 NATURAL RUBBER 017 100 > 6.00 23. .05 107
102 > 8.00 23. .05 026
> 8.00 23. .05 026
> 8.00 23. .05 026
> 8.00 23. .05 026
NEOP+NAT RUBBER 026 102 > 8.00 23. .06 026
> 8.00 23. .04 026
> 8.00 23. .05 026
NEOP/NAT RUBBER 008 102 > 8.00 23. 026
NEOPRENE 002 100 • 12 23 • 107
018 100 .08 23. .04 107

A-47
S~~.AAY OF PERF~ii"J."C:E DET A: L -:S~S
PERMEATlOtI TEST

C~E'" I CAL tlA.~E/ RESISTAMT PRODUCT VENDOR BREAKTHROUGH TIME PER~EATIO~ RATE TENP TiiICI"ESS REF
CAStlO MATERIAL OESC COOE HOURS UG/CM**Z/MIN DEG C CM NUll

~n228412 NITRILE 019 100 > 6.00 23. .06 107


PVC 007 100 > 6.00 23. 107

Hydrogen Phosphide (Phosphine)


078035120 NATURAL RUBBER OS7 UNK .50 < .02 23. .05 173
NEOPRENE 031 UNK .42 .02 23. .05 173
093 UNK .17 < .02 23. .03 173
PE 091 UNK .33 < .02 23. .04 173
.42 < .02 23. .04 173
PVC 054 UNK 1.67 < .02 23. .02 173
.67 < .02 23. .02 173

Hydroquinone
001233190 NITRILE+PVC 058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC on 100 > 6.00 23. 107
6.00 23. 107

Hydroqu;none. <3OX
001233191 NATURAL RUBBER 017 100 > 6.00 < .90 23. .05 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
018 100 > 6.00 < .90 23. .04 107
NITRILE 019 100 > 6.00 < .90 23. .06 107
PVC 007 100 > 6.00 < .90 23. 107

Iminobispropylemine
000561880 BUTYL 014 118 > 8.00 28. .09 323
NATURAL RUBBER 001 250 .10 84.17 26. .02 323
NEOPRENE 01a 100 > 8.00 27. .05 323
VITOII 009 118 > 8.00 27. .04 323

b·lonone
149010760 BUTYL 014 118 . > 9.00 23. .06 323
PV ALCOHOL 10l 100 > 14.00 23. .04 323
> 8.00 23. .03 323
118 > 8.00 23. .03 323

ISOlllllYl Acetate
001239220 BUTYL 107 120 .03 1,903.80 25. .02 222
NYPAlON 10S 120 .50 ·350.70 2S. .05 222
NATURAL RUBBER 017 100 .09 1,102.20 25. .03 222
502 • 16 791.58· 25 • .05 222
504 .17 661.32 25 •. .05 222
.32 470.94 25 • .06 222
NEOP+NAT RUBBER 026 102 •16 761.52 2S. .OS 222
NEOP/NAT RUBBER 008 114 .20 731.46 25. .05 222
NEOPRENE 002 100 .20 140.28 2S. .os 222
120 .09 120.24 2S. .07 222
018 118 > 1.00 25. .08 222
120 .SO 310.62 2S. .OS 222
.27 541.08 25. .03 222
NITRILE 019 100 > 1.00 25. .04 222
> 1.00 2S. .06 222

A-48
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG!CM**2!MIN OEG C CM NUM

001239220 NITRilE 019 100 1.08 63.13 25. .04 222


191 .70 130.26 25. .03 222
PE 006 100 • 03 20.04 25 • .01 222
505 > 1.00 < 10.02 25. .01 222
PVC 003 120 • 02 3,306.60 25 . .01 222
•02 3,306.60 25 . .01 222
•08 1,603.20 25 . .03 222
.06 2,505.00 25. .02 222
500 •02 25 . .01 222
501 .02 4,509.00 25. .01 222
.03 2,104.20 25. .02 222

Isoamylnitrile
001104630 NEOPRENE 018 100 .78 224.25 23. .05 000
NITRILE 019 100 2.93 9.62 23. .04 323
PV ALCOHOL 102 100 > 8.00 23. .03 323
VITON 009 118 1. 13 55.31 23. .02 323

Isobutyl Acrylate
001066380 BUTYL 014 118 > 8.00 23. .09 323
NITRILE 019 100 1.13 126.25 23. .05 323
PV ALCOHOL 102 100 > 8.00 23. .08 323
PVC 003 100 •02 204.41 23 • .02 323
Isobutyl Alcohol
000788310 BUTYL 014 118 > 8.00 23. .07 323
NATURAL RUBBER 001 210 2.00 4.51 23. 080
017 100 .42 9.02 90.18 23. .05 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
210 6.00 < .02 23. 080
018 100 .17 < .90 23. .04 107
> 8.00 23. .05 323
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 6.00 < .90 23. .06 107
118 > 8.00 23. .05 323
NITRILE+PVC 057 210 4.00 4.81 23. 080
058 100 .12 •90 • 9.02 23 • 107
PE 076 100 .05 . 90 . 9.02 23 . 107
PVC 007 100 .17 < .90 23. 107
210 2.00 4.51 23. 080
077 100 .50 < .90 23. 107
2.00 . 90 . 9.02 23 . 107
VITON 009 118 > 8.00 23. .05 323
Isobutyl Nitrite
005425630 BUTYL 014 118 1.30 132.26 23. .04 323
NITRILE 019 100 1.63 6.01 23. .06 323
PVC 003 100 .03 1,454.90 23. .02 323
VITON 009 118 .33 619.24 23. .04 323

Isobutyraldehyde
000788420 BUTYL 014 118 > 8.00 23. .06 323
NEOPRENE 018 100 .42 48.70 23. .05 323

A-49
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PROOUCT VENDOR BREAlCTHROOGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE IKlJRS UG/CM**2/MIN DEG C CM NUM

000788420 PV ALCOHOL 102 100 .02 1.57 23. .04 323


VITON 009 118 •07 69.14 23 • .03 323

Isooctane
266356430 NATURAL RUBBER 001 103 294.59 23. 045
NEOPRENE 002 100 6.00 < .90 23. 107
018 100 1.00 9.02 90.18 23. .04 107
125 103 < .02 23. 045
NITRILE 019 100 6.00 < .90 23. .06 107
103 < .02 23. 045
NITRILE+PVC 058 100 .28 .90 9.02 23. 107
PE 076 100 .23 9.02 90.18 23. 107
PV ALCOHOL 004 100 •67 .90 • 9.02 23. 107
PVC 007 103 3.01 23. 045
077 100 .25 .90 • 9.02 23. 107
1.25 .90 9.02 23. 107

Isoprene
000787950 NEOPRENE 018 100 •27 192.38 23 • .05 323
NITRILE 019 100 •87 27.66 23 . .04 323
PV ALCOHOL 102 100 > 12.00 23. .03 323
VITON 009 118 6.20 1.14 23. .03 323

Isopropyl Alcohol (Propanol, 2·)


000676300 CPE 060 113 > 8.00 23. .05 204
NATURAL RUBBER 001 210 1.50 12.63 23. 080
017 100 .12 < .90 23. .05 107
102 .25 .12 23. .05 026
.17 1.80 23. .05 026
.25 .12 23. .05 026
.37 01.20 23. .05 026
NEOP+NAT RUBBER 026 102 .15 1.20 23. .06 026
.23 1.20 23. .04 026
.25 .12 23. .05 026
121 .52 6.01 23. .05 237
NEOPINAT RUBBER 008 102 .25 .12 23. 026
NEOPRENE 002 100 > 6.00 < .90 23. 107
210 2.00 4.81 23. 080
018 100 > 6.00 < .90 23. .04 107
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 6.00 < .90 23. .06 107
NITRILE+PVC 057 210 6.00 < .02 23. 080
058 100 .58 .90 9.02 23. 107
PE 076 100 .17 .90 9.02 23. 107
PVC 007 100 2.50 < .90 23. 107
210 2.17 12.02 23. oao
077 100 .50 .90 9.02 23. 107
.50 .90 • 9.02 23. 107
TEFLON 069 510 > 3.00 < .02 23. .05 303

I sopropyl ami ne
000753100 BUTYL 014 118 4.08 36.07 24. .09 323
IIEOPRENE 018 100 .23 913.82 21. .05 323

A-50
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HOORS UG/CM**21MIN OEG C CM lUI

000753100 PVC 007 100 •03 4,671.32 18 • .02 323


TEFLON 069 510 > 3.00 < .02 23. .05 303
VITON 009 118 • 18 3,342.67 26 • .04 323

Isopropyl Ether
001082030 CPE 070 UNK > 3.00 23. .05 004
NATURAL RUBBER 017 UNIC • 06 > 480.96 23 • .04 274
NEOP/NAT RUBBER 008 UNIC •12 > 501.00 23 • .05 274
NEOPRENE 018 UNK > 1.00 23. .09 274
•71 > 10.02 23 • .06 274
NITRilE 019 UNK > 1.00 23. .05 274
PV ALCOHOL 004 UNK > 1.00 23. .12 274
PVC 007 UNK .25 > 501.00 23. .16 274
VITON 0D9 UNK > 1.00 23. .03 274

Isopropylmethacryl ate
046553490 BUTYL 014 118 > 8.00 23. .09 323
NITRI.lE 019 100 1.88 36.07 23. .05 323
PV AlCOllOl 102 100 > 8.00 23. .09 323
PVC 003 100 •02 354.71 23 • .02 323

Kerosene
080082060 NATURAL RUBBER 017 100 •50 .90 • 9.02 23 • .OS 107
NEOP+NAT RUBBER 026 121 •60 12.02 23 • .OS 237
NEOPRENE 002 100 > 6.00 < .90 23. 107
018 100 > 6.00 < .90 23. .04 107
NITRilE 019 100 > 6.00 < .90 23. .06 107
NITRllE+PVC 058 100 1.25 9.02 • 90.18 23. 107
PE 076 100 .20 9.02 • 90.18 23. 107
PV AlCOHOl 004 100 > 6.00 < .90 23. 107
PVC 007 100 > 6.00 < .90 23. 107
077 100 .50 9.02 90.18 23. 107
3.00 9.02 • 90.18 23. 107

lactic Acid, >701


000793343 NATURAL RUBBER 017 100 > 6.00 < .90 23. .05 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
018 100 > 6.00 < .90 23. .04 107
NITRILE 019 100 > 6.00 < .90 23. .06 107
NITRILE+PVC 058 100 > 6.00 < .90 23. 107
PE 076 100 > 6.00 < .90 23. 107
PV ALCOIIOL 004 100 > 6.00 < .90 23. 107
PVC 007 100 > 6.00 < .90 23. 107
077 100 > 6.00 < .90 23. 107
> 6.00 < .90 23. 107

lauric Acid, 30·701


001430772 NATURAL RUBBER 017 100 > 6.00 23. .05 107
NEOPRENE 002 100 > 6.00 23. 107
018 100 > 6.00 23. .04 107
NITRILE 01~ 100 > 6.00 23. .06 107
PVC 007 100 .25 23. 107

A-51
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICICNESS REF
CASNO MATERIAL DESC cmE HOURS UG/CM**2!MIN DEG C eM lUI

d-li.onene (Menthadiene)
059892750 BUTYL 014 118 > 8.00 23_ .02 323
IIEOPREIIE 018 100 1.08 23. .05 323
IIITRILE 019 100 > 20.00 23. .04 323
PV ALCOHOL 102 100 > 8.00 23. .03 323

Maleic Acid, >701


001101673 NATURAl RUBBER 017 100 > 6.00 23. .05 107
NEOPREIIE 002 100 > 6.00 23. 107
018 100 > 6.00 23. .04 107
NITRILE 019 100 > 6.00 23. .06 107
NITRllE+PVC 058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC 007 100 > 6.00 23. 107
077 100 > 6.00 23. 107
> 6.00 23. 107

Mesftyl Oxide (Methylpentenone, 4- ,3- ,2-)


001417970 CP£ 060 UIQC 1.83 23. 142
.33 23. 142
VITON/CHLOROBUTYL 112 UNIC > 3.00 23. 142

Methacrylonitrile
001269870 BUTYL 014 118 > 8.00 23. .09 323
NATUltAl RUllBER 001 250 < .02 1,803.60 23. .02 323
PV AlCOHOl 102 100 .40 .48 23. .06 323
PVC 003 100 .03 1,142.28 23. .02 323

Meth~ulfonic Acid
000757520 NEOPRENE 018 100 > 4.00 23. .05 123
PVC 003 215 > 4.00 23. .05 123

Methanol (Methyl Alcohol)


000675610 BUTYl 064 117 > 8.00 23. .02 213
> 8.00 23. .01 213
> 8.00 23. .02 213
BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213
CPE 060 113 > 3.00 25. .07 302
NATURAL RUBBER 001 210 6.00 < .02 23. 080
017 100 .33 8.02 25 • .03 222
.22 < •90· 23. .05 107
102 .25 1.20 23. .05 026
.25 1.20 23. .05 026
.25 1.20 23. .05 026
.25 1.20 23. .05 026
120 .03 18.04 25. .02 222
502 > 1.00 < 4.01 25. .05 222
504 .30 4.01 25. .05 222
> 1.00 < 4.01 25. .06 222
UNK > 1.00 23. .04 274
NEOP+NAT RUBBER 026 102 .25 1.20 23. .06 026

A-S2
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HooRS UG/CM**2/MIN DEG C CM NUM

000675610 NEOP+NAT RUBBER 026 102 .25 1.20 23. .05 026
121 .30 6.01 23. .05 237
NEOP/NAT RUBBER 008 102 .25 1.20 23. 026
114 .40 4.01 25. .05 222
UNK > 1.00 23. .05 274
NEOPRENE 002 100 .25 .90 23. 107
.29 6.01 25. .08 222
120 .38 5.01 25. .07 222
210 6.00 .02 23. 080
018 100 1.00 < .90 23. .04 107
118 > 1.00 < 4.01 25. .08 222
120 > 1.00 < 4.01 25. .05 222
> 1.00 < 4.01 25. .07 222
> 1.00 < 4.01 25. .05· 222
> 1.00 < 4.01 25. .03 222
UNK > 1.00 23. .09 274
> 1.00 23. .06 274
031 UNK 1.03 23. .04 187
093 111 5.92 23. .02 213
138 111 5.00 23. .03 213
139 111 > 8.00 23. .02 213
NITRILE 005 210 6.00 < .02 23. 080
019 100 1.15 23.05 25. .04 222
.18 90.18 901.80 23. .06 107
> 1.00 4.01 25. .06 222
.90 36.07 25. .04 222
503 .65 29.06 25. .03 222
UNK > 1.00 23. .05 274
033 UNK .91 23. .05 187
NITRILE+PVC 051 210 6.00 < .02 23. 080
058 100 .33 .90 9.02 23. 107
PE 006 100 > 1.00 < 4.01 25. .01 222
505 > 1.00 < 4.01 25. .01 222
016 100 .22 < .90 23. 107
111 > 8.00 23. .01 213
PV ALCOHOL 004 100 .02 124.15 23. 123
.02 124.15 21. 124
UNK .04 > 30.06 23. .12 274
PVC 003 120 .03 36.01 25. .01 222
.03 34.07 25. .01 222
.05 18.04 25. .03 222
.05 23.05 25. .02 222
500 .03 34.07 25. .01 222
501 .02 38.08 25. .01 222
.04 30.06 25. .02 222
001 100 .15 9.02 90.18 23. 107
210 6.00 < .02 23. 080
UNK > 1.00 23. .16 274
1.50 23. .07 186
.77 23. .05 186
049 117 .83 23. .01 213
UNK .68 23. .03 187
077 100 .17 .90 23. 107

A-53
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS UG/CM**21MIN OEG C CM MUM

000675610 PVC on 100 •50 9.02 . 90.18 23. 107


117 < • 08 23 • .01 213
SARANEX 061 117 > 8.00 23. .01 213
TEFLON 069 510 > 14.20 < .02 23. .05 303
> 5.00 < .02 24. .05 303
VITON 009 UtlK > 1.00 23. .03 274
145 117 .83 23. .01 213
VITON/CHLOROBUTYL 112 113 > 3.00 25. .04 302
VITON/NEOPRENE 111 117 > 8.00 23. .02 213

4-Methoxy-4-.ethyl-2-pentanone
001077000 BUTYL 014 118 > 13.00 23. .07 323
NEOPRENE 018 100 1.65 33.07 23. .05 323
PV ALCOIIOl. 102 100 > 14.00 23. .03 323
vnON 009 118 .40 116.03 23. .03 323

Methyl Acetate
000792090 BUTYL 014 118 > 8.00 23. .09 323
IATURAL USER 001 250 < •02 6,012.00 23 • .02 323
P£ 076 100 •07 .90· 9.02 23 • 107
PV ALCOIIOl. 102 100 .68 12.02 23. .07 323
PVC 003 100 < .02 6,012.00 23. .02 323

Methyl Acrylate
00096D30 BUTYL 014 118 > 8.00 23. .09 323
IATURAL RlIIIER 001 250 .02 625.25 23. .02 323
1lE0PIIEIIE 018 100 .25 3,168.32 23. .05 323·
PV ALCOIIOl. 102 100 1.50 1.80 23. .07 323
TEFlCII 069 510 3.00 < .02 23. .05 303
Methyleaine C_ _ thyleaine)
000748950 IATURAL RUlBER 017 100 .42 9.02 • 90.18 23. .05 107
1E0PR£1I£ OOZ 100 6.00 < .90 23. 107
018 100 4.50 9.02 • 90.18 23. .04 107
InRIl£ 019 100 6.00 < .90 23. .06 107
PVC 007 100 2.25 •90 • 9.02 23 • 107

Methyleaine, 3O-7OX
000748952 BUTYL 014 118 > 15.00 < .02 23. .04 227
InRILE 019 118 > 8.00 23. .04 227
InRIl£+pvc GSa 100 .50 9.02 90.18 23. 107
P£ 076 100 .17 9.02 90.18 23. 107
PVC on 100 .17 < .90 23. 107
1.00 •90 9.02 23 • 107
SILVER SHIELD 122 118 1.90 12.02 23. .01 227
VnON 009 118 > 16.00 < .02 23. .02 227

3-Methyl_inopropylealne
062918450 BUTYL 014 118 > 8.00 < .02 20. .07 323
IATURAL RUBBER 001 250 .05 731.46 16. .02 323
NEOPRENE 018 100 1.05 160.32 16. .05 323
PVC 007 100 •03 671.34 14 • .02 323

A-54
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATIOIi TEsT

CHEMICAL NAMEI REsiSTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE ':MP THICKNEsS REF
CASNO MATERIAL DESC COOE HOURS UG/CM**2/MIN DEG C CM HUM

Methyl Bromide (Bromomethane)


000748390 SARANEX 061 127 > 8.00 23. 104

Methyl Cellosolve (Methoxyethanol, 2>


001098640 BUTYL 014 118 > 20.00 23. .05 '23
NEOP+NAT RUBBER 026 121 .58 6.01 23. .05 237
NITRilE 019 100 .67 60.12 23. 123

Methyl Chloroacetate
000963440 SARANEX 061 127 8.00 18.04 23. '04

Methyl Chloroform (Trichloroethane,',1,1>


000715560 BUTYL 014 118 .48 918.50 25. .04 288
UIIIC .48 919.84 23. .04 100
1.00 25. .05 326
064 UIIIC .42 25. .04 326
NATURAL RUBBER 001 210 .13 901.80 23. 080
017 100 .06 2,605.20 25. .03 222
120 .03 5,711.40 25. .02 222
502 .12 3,106.20 25. .05 222
504 .12 1,803.60 25. .05 222
.22 1,202.40 25. .06 222
UNK .07 25. .02 326
NEOP+NAT RUBBER 026 102 .13 3,006.00 25. .05 222
NEOP/NAT RUBBER OOS 114 .17 2,404.80 25. .05 222
NEOPRENE 002 100 .07 1,002.00 25. .os 222
120 .04 701.40 25. .07 222
210 .20 781.56 23. OSO
010 100 .40 895.12 25. .05 288
018 100 .32 745.49 23. .05 323
120 .32 1,002.00 25. .05 222
.80 801.60 25. .07 222
.42 901.80 25. .05 222
.27 1,002.00 25. .03 222
UIIK .40 895.79 23. .05 100
.75 25. .06 326
NITRilE 005 210 2.00 601.20 23. 080
019 100 .18 4,108.20 25. .04 222
2.00 901.80 9,018.00 23. .06 107
> 1.00 < 10.02 25. .06 222
.93 50.10 25. .04 222
118 .62 459.32 23. .04 323
.68 459.32 23. .04 227
181 .60 25. .03 222
503 .06 2,605.20 25. .03 222
UIIIC .50 25. .02 326
.28 282.56 23. .03 100
020 100 .28 282.23 25. .03 288
NITRllE+PVC 057 210 .83 96.19 23. 080
058 100 .15 90.18 901.80 23. 107
.10 901.80 9,018.00 23. 107
PE 006 100 .03 130.26 25. .01 222

A-55
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME I RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C eM NUM

000715560 PE 006 100 < .02 154.48 25. .01 288


505 .20 30.06 25. .01 222
UNK < .02 154.48 23. .01 100
042 UNK • 05 25 • .01 326
076 100 • 13 .90 9.02 23 • 107
.02 90.18 901.80 23. 107
UNK • 20 25 • .01 326
POLYURETHANE 050 UNK • 03 25 • .01 326
PV ALCOHOL 004 100 1.00 < .90 23. 107
102 100 > 8.00 23. .03 323
> 6.00 25. .05 288
UNK > 8.00 23. .05 100
PVC 003 118 .02 1,593.18 25. .01 288
500 • 01 3,206.40 25 • .01 222
501 • 01 4,008.00 25 • .02 222
UNK .02 1,593.18 23. .01 100
007 210 .50 120.24 23. 080
077 100 .10 9.02 90.18 23. 107
.25 9.02 90.18 23. 107
.03 90.18 901.80 23. 107
UNK .05 25. .03 326
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEFLON 069 510 > 3.00 < .02 23. .05 303
VITOII 009 118 > 15.17 23. .03 323
> 15.00 23. .02 227
> 6.00 25. .02 288
UNK > 8.00 23. .02 100
> 24.00 25. .03 326

Methylene Bromide (Dfbromomethane)


000749530 PE 076 100 .03 9.02 90.18 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107

Methylene Chloride (Dichloromethane)


000750920 BUTYL 014 118 • 17 698.06 25 • .04 288
UNK • 17 696.39 23 • .04 100
CPE 060 113 .25 • • 42 25 • .07 302
NATURAL RUBBER 001 210 .10 1,803.60 23. 080
UIIK .03 > 140.28 23. .12 274
017 100 .02 8,216.40 25. .03 222
120 •01 13,026.00 25 • .02 222
502 .05 4,308.60 25. .05 222
504 •03 4,809.60 25 •. .05 222
• 05 3,807.60 25 • .06 222
UNK .03 > 120.24 23. .04 274
NEOP+NAT RUBBER 026 102 .05 4,609.20 25. .05 222
121 • 03 1,274.54 23 • .05 237
NEOP/NAT RUBBER 008 114 • 07 3,406.80 25 • .05 222
UNK .03 > 160.32 23. .05 274
NEOPRENE 002 100 .13 1,102.20 25. .08 222
120 .01 2,805.60 25. .07 222
210 .08 1,803.60 23. 080
010 100 < .02 2,688.70 25. .05 288

A-56
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME I RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUN

000750920 NEOPRENE 018 118 .22 2,004.00 25. .08 222


120 .07 3,507.00 25. .05 222
.15 2,605.20 25. .07 222
.11 2,805.60 25. .05 222
• 03 4,809.60 25 . .03 222
tAlK < .02 2,687.36 23. .05 100
.21 > 150.30 23. .09 274
.08 > 140.28 23. .06 274
125 103 1,881.76 .02 23. 045
NITRILE DOS 210 3.00 5,410.80 23. 080
019 100 .04 12,024.00 25. .04 222
.11 8,216.40 25. .06 222
.04 13,026.00 25. .04 222
103 4,016.02 23. 045
118 .07 4,605.19 23. .04 227
503 .03 1,903.80 25. .03 222
tAlK < .02 5,639.26 23. .03 100
.04 > 125.25 23. .05 274
.03 > 150.30 23. .05 274
020 100 < .02 5,644.60 25. .03 288
NITR I LE+PVC OS7 210 .20 2,645.28 23. 080
PE 006 100 .01 300.60 25. .01 222
< .02 420.84 25. .01 288
50s .03 100.20 25. .01 222
tAlK < .02 420.84 23. .01 100
076 100 .02 90.18 901.80 23. 107
PV ALCOHOL 004 100 .28 < .90 23. 107
tAlK > 1.00 23. .12 274
102 100 > 8.00 23. .04 323
> 6.00 25. .05 288
tAlK > 8.00 23. .05 100
PVC 003 118 < .02 25. .01 288
120 .01 25. .01 222
.01 > 16,699.98 25. .01 222
.02 12,024.00 25. .03 222
.01 > 16,699.98 25. .02 222
500 .01 > 16,699.98 25. .01 222
501 .01 > 16,699.98 25. .01 222
.01 > 16,699.98 25. .02 222
tAlK < .02 23. .01 100
007 103 2,555.10 23. 045
210 .10 3,486.96 23. 080
tAlK .17 > 150.30 23. .16 274
SILVER SHIELD 122 118 1.90 .02 23. .01 227
TEFLON 069 510 .78 .02 23. .05 303
.84 .02 23. .05 303
.92 .02 23. .05 303
.62 24. .05 303
.62 24. .05 303
.58 24 . .05 303
•75 24. . 05 303 .
VITON 009 118 1.00 44.00 23. .02 227
1.38 23.38 25. .02 288

A-57
SUMMARY OF PERFORMANCE DETAIL TeSTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2!MIN DEG C CM NUM

000750920 VITON 009 UNK 1.38 22.85 23. .02 100


.95 > 10.02 23. .03 214
VITON/CHLOROBUTYL 112 113 .42 .60 25. .04 302
1.03 - 1.12 15. .04 302
.30 .41 25. .04 302
.15 - • 23 35 • .04 302

n-Methylethanolamine
001098310 BUTYL 014 118 > 8.00 < .02 19. .07 323
CELLULOSE ACETATE 099 118 > 8.00 < .02 20. .03 323
NATURAL RUBBER 001 250 .08 150.30 20. .02 323
NEOPRENE 018 100 > 8.00 < .02 20. .06 323

Methyl Ethyl Ketone (Butanone,2)


000789330 BUTYL 014 118 > 8.00 < .02 23. .06 323
216 > 4.00 23. .07 123
> 4.00 21. 124
111 1.61 23. .02 213
2.33 23. .01 213
2.00 23. .02 213
BUTYL/IIEOPRENE 110 111 .08 23. .02 213
CPE 060 113 .41 • .58 25. .07 302
IIATUIIAl. RUBBER 001 103 925.85 23. 045
511.03 23. 045
210 • 10 1,022.04 23 • 080
250 •02 100.20 23 • .01 323
011 100 • 04 601.20 25 • .03 222
.11 901.80· 9,018.00 23. .05 107
120 .02 801.60 25. .02 222
502 .12 320.64 25. .05 222
504 .13 400.80 25. .05 222
• 21 200.40 25 • .06 222
1lE000000T RUBBER 026 102 •09 310.62 25 • .05 222
121 .08 1,004.00 23. .05 231
1lE00/llAT RUBBER ooa 114 • 15 230.46 25 • .05 222
1lE000EliE 002 100 .28 200.40 25. .08 222
120 •04 501.00 25 • .01 222
210 • 12 121.44 23 • 080
018 100 .22 3,066.12 23. .05 323
118 .65 Z30.46 25. .08 222
120 • 13 601.20 25 • .05 222
•45 330.66 25 • .01 222
• 11 601.20 25 • .05 222
.01 901.80 25. .03 222
093 111 c .08 23. .02 213
125 103 .60 23. 045
138 117 c •08 23 • .03 213
139 111 c .08 23. .02 213
IITRILE 005 210 .33 492.98 23. 080
019 100 • 11 3,106.20 25 • .04 222
• 20 1,903.80 25 • .06 222
.10 2,204.40 25. .04 222
103 1.20 23. 045

h-58
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RA~ ,EMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM

000789330 NITRILE 019 181 • 06 2,805.60 25 . .03 222


503 .16 1,503.00 25. .03 222
NITRILE+PVC 057 210 . 15 607.21 23 . 080
PE 006 100 > .02 10.02 25. .01 222
505 . 16 < 3.01 25 . .01 222
076 100 .05 9.02 90.18 23. 107
117 .03 23. .01 213
PV ALCOHOL 004 100 •50 9.02 90.18 23 . 107
102 100 5.37 .15 23. .07 323
PVC 007 103 4.81 23. 045
210 .27 n1.44 23. 080
049 117 .08 23. .01 213
SARANEX 061 117 .15 23. .01 213
127 •48 7.82 23 • 104
TEFLON 069 510 > 3.00 < .02 23. .05 303
VITOII 145 117 < .16 23. .01 213
VITOII/CHLOROBUTYL 112 113 .42 • .66 25. .04 302
VI TON/NEOPRENE 111 117 .07 23. .02 213

Methyl Ethyl Ketone Peroxide


013382340 BUTYL 014 118 > 4.00 23. .07 323
NATURAL RUBBER 001 250 .75 6.01 23. .02 323
NEOPRENE 018 100 > 4.00 23. .05 323
VITON 009 118 > 4.00 23. .04 323

Methyl hydraz i ne
000603440 BUTYL 014 118 > 2.00 22. .23 321
> 2.00 22. .04 321
064 113 .01 22. .03 321
085 211 > 2.00 22. .11 321
CHLOROBUTYL 052 205 > 2.00 23. .04 321
CPE 060 113 .87 22. .05 321
070 113 1.10 22. .05 321
CR 39 095 122 > 2.00 22. .17 321
PVC 003 103 .52 22. .13 321
1.90 22. .13 321
053 126 > 2.00 22. .05 321
083 211 > 2.00 22. .20 321
TEFLON 055 210 < .01 22. .02 321
062 UNIC < .01 22. .02 321
067 UNK < .01 22. .02 321
068 lINK < .01 22. .02 321
069 UIIK < .01 22. .02 321
VITON 009 118 1.50 22. .05 321

Methyl Iodide
000748840 BUTYL 014 118 •92 492.98 23 • .09 323
NATURAL RUBBER 017 100 .03 13,026.00 25. .03 222
120 •03 > 16,699.98 25 . .02 222
502 .05 8,116.20 25. .05 222
504 • 04 9,218.40 25 • .05 222
•06 6,913.80 25 • .06 222
NEOP+NAT RUBBER 026 102 .03 8,917.80 25. .04 222

A-59
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HooRS UG/CM**2/MIN DEG C CM NUM

000748840 NEOP/NAT RUBBER OOS 114 .09 5,310.60 25. .05 222
NEOPRENE 002 100 •25 1,402.80 25 • .08 222
120 •01 4,609.20 25 • .07 222
018 100 .10 7,893.76 23. .05 323
118 • 28 2,905.80 25 • .OS 222
120 •07 6,312.60 2S • .05 222
.20 3,707.40 25. .07 222
•07 5,611.20 2S • .05 222
•04 7,915.80 2S • .03 222
NITRILE 019 100 .01 6,613.20 25. .03 222
• 13 8,016.00 25 • .05 222
•09 6,012.00 2S • .04 222
181 8,216.40 25. .03 222
503 • 03 11,022.00 25 . .03 222
PE 006 100 •01 1,102.20 25 • .01 222
50S •04 300.60 25 • .01 222
PV ALCOHOL 102 100 > 8.00 23. .07 323
VITOII 009 118 6.35 4.21 23. .04 323

M.thyl Isobutyl K.tOM(Methylpentanone, 4·,2·)


001081010 BUTYL 012 UNIC 1.50 19.24 25. .04 273
2.67 22.24 2S. .04 273
5.00 52.30 25. .06 273
4.50 39.08 25. .06 273
1.50 36.07 25. .04 273
2.17 40.88 25. .04 273
5.00 4.81 25. .06 273
5.67 1.20 25. .06 273
.17 30.06 25. .04 273
.83 70.34 25. .04 273
3.00 16.83 25. .06 273
3.75 7.82 25. .06 273
014 118 4.07 6.01 23. .05 086
IIATURAL RUBBER 001 210 .25 420.84 23. 080
017 100 .10 90.18 901.80 23. .OS 107
NEOPRENE 002 210 .25 541.08 23. 080
010 120 •62 2n.22 23 • .06 086
018 100 .47 S29.39 23. .06 086
UNIC .33 303.61 25 •. .04 273
.33 284.37 25. .04 273
.50 298.80 25. .06 273
.53 2n.75 25. .06 273
NITRILE 005 210 1.67 841.68 23. 080
019 100 .80 402.47 23. .06 086
118 .20 492.65 23. .04 086
120 .35 848.36 23. .05 086
UNIC .50 304.81 25. .04 273
.50 290.38 2S. .04 273
1.17 290.38 25. .06 273
1.17 256.71 25. .06 273
020 503 .32 1,033.73 23. .04 086
NITRILE+PVC 057 210 .30 781.S6 23. OSO
PE 006 512 .01 60.12 23. .01 086

A-60
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL OESC COOE HOURS UG/CM**2/MIN OEG C CM NUM

001081010 PE 076 100 .03 9.02 90.18 23. 107


PV ALCOHOL 004 100 > 6.00 < .90 23. 107
PVC 007 210 .50 991.98 23. 080
TEFLON 069 510 > 3.00 < .02 23. .05 303
VITON 009 118 .20 1,743.48 23. .04 086

MethyL Isocyanate
006248390 BUTYL 014 118 • 72 13 • .06 323
1,012.00 90.18 23. .07 323
NATURAL RUBBER 001 250 .01 20. .02 323
•02 10,641.24 23 • .01 323
NEOPRENE 018 100 • 01 20 • .05 323
• 02 2,254.50 23 • .04 323
PV ALCOHOL 004 100 > 8.00 < .02 23. .03 323
> 8.00 < .02 23. .05 323
V IT ON 009 118 .02 21. .03 323
.07 1,212.42 23. .03 323

MethyL MethacryLate
000806260 BUTYL 014 118 4.98 24.05 23. .09 323
NATURAL RUBBER 001 250 < • 02 9,619.20 23 . .02 323
PE 076 100 .03 9.02 90.18 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
102 100 > 8.00 23. .06 323
PVC 003 100 < • 02 9,619.20 23 • .02 323
TEFLON 069 510 > 3.10 < .02 23. .OS 303

MethyL'vinyL'ketone
000789440 CPE 060 UNK .50 23. 142
1.67 23. 142
VITON/CHLOROBUTYL 112 UNK > 3.00 23. 142

MineraL Spirits
080524130 NEOP+NAT RUBBER 026 121 .22 138.28 23. .05 237
NEOPRENE 002 100 > 6.00 < • 90 23 • 107
018 100 1.50 •90 9.02 23 • .04 107
NITRILE 019 100 > 6.00 < • 90 23 . .06 107
NITR I LE+PVC 058 100 .10 9.02 90.18 23. 107
PE 076 100 .10 9.02 90.18 23. 107
127 < .08 7.01 23. 104
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
PVC 007 100 2.50 •90 9.02 23 . 107
077 100 .10 .90 9.02 23. 107
.10 9.02 90.18 23. 107
SARAN EX 061 127 > .17 < .20 23. 104

Monoisopropanolamine
000789660 BUTYL 014 118 > 8.00 25. .07 323
NEOPRENE 018 100 > 8.00 24. .05 323
PVC 007 100 > 8.00 25. .02 323
VITON 009 118 > 8.00 25. .04 323

MorphoL ine

A-61
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEA TI 011 TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C OM NUM

001109180 BUTYl 014 118 > 16.00 23. .04 323


> 16.00 23. .04 227
NATURAL RUBBER 017 100 .50 .90 - 9.02 23. .05 107
II ITR IlE 019 118 .73 1,240.28 23. .03 323
•80 1,238.47 23 • .04 227
PV ALCOHOL 004 100 3.00 < .90 23. 107
102 100 6.17 25.25 23. .03 323
SILVER SHielD 122 118 > 8.00 23. .01 227
VITON 009 118 1.80 581.36 23. .02 323
1.90 583.16 23. .02 227

N-Methyl-2-pyrrolidOne
008n5040 NATURAL RUBBER 001 103 3.61 23. 045
IIEOPRENE 125 103 6.01 23. 045
IIITRILE 019 103 24.05 23. 045
PVC 007 103 24.05 23. 045

Naphtha, V_M.I P (Ligroine)


080323240 CPE 070 UIIIC > 3.00 23. .05 004
1lE0P+1IAT RUBBER 026 121 .07 96.19 23. .05 237
NEOPREIIE 002 100 > 6.00 < .90 23. 107
018 100 • 25 90.18' 901.80 23 • .04 107
IIITRIlE 019 100 > 6.00 < .90 23. .06 107
NITRIlE+PVC 058 100 •15 9.02 90.18 23 • 107
PE 076 100 .05 90.18· 901.80 23. 107
PV ALCOHOL 004 100 > 7.00 < .90 23. 107
PVC 007 100 2.00 < .90 23. 107
077 100 .08 .90 • 9.02 23. 107
.n 9.02 . 90.18 23. 107

Nitric Acid
076973no BUTYL 064 117 > 8.00 23. .02 213
> 8.00 23. .01 213
> 8.00 23. .02 213
BUTYl/IIEOPRENE 110 117 > 8.00 23. .02 213
CPE 070 UIIIC > 3.00 23. .05 004
IIATURAL RUBBER 001 210 2.00 23. 080
IIEOP+IlAT RUBBER 026 121 > 8.00 < .02 23. .05 237
IIEOPREIIE 002 210 2.00 23. 080
093 117 2.67 23. .01 213
138 117 1.n 23. .03 213
139 117 3.08 23. .02 213
IIEOPRENE+PVC 127 117 1.08 23. .02 213
IIITRIlE 005 210 4.00 23. 080
IIITRI'LE+PVC 057 210 4.50 23. 080
058 117 .42 23. .01 213
PE 076 117 8.00 23. .01 213
PVC 007 210 3.75 23. 080
049 117 3.00 23. .01 213
.42 23. .01 213
053 117 < .33 23. .02 213
077 117 < .08 23. .01 213
.75 23. .01 213

A-62
IUMMARY OF PiRf0RM4NCE D~TAI~ lJITI
PUMEAlICIN TnT

CHEMICAL NAMEI RESISTANT PRQOUCT VENDOR IREAKTHROUGH TIME PUMIATION ItAT~ liMP THICKNUS Rif
CASNO MATERIAL PEiCCOI)E HOURS UG/CM**i!/MIN DIG C eM NLIM

076973no PVC 144 117 •58 n. .oa 2U


.ARANEX 061 117 5.00 U. .01 113
fill-ViR SHIELD 122 "0 ,. 6.00 U. .0' U1
VITOII '45 117 ,. •• 00 u. .0' In
VlTON/NEOPRENE 111 117 • 1.00 23. .02 ;113

Nitric Acid. <30X


07691Jn, NATURAL RUBBER 0'7 100 >
,.
6.00 n. .05 107
'Ol 1,00 IS. ,05 Oll6
,. .,00 IS. .05 016
•,. •• 00 U• .05 016
•• 00 n. .0S OZ6
NEOP+NAT RUBBER 026 10Z l' a.oo n. .06 026
l'
,.
',00 n. .04 026
,.
8,00 n. .05 016
NEOP/NAT RUBBER 008 102 •• 00 U. 016
NEOPRENf 002
ota
'00 • 6.00 II. 101
100 •,. 6,00 n. .04 Hl1
NITItIl-E 019 100
,. 6.00 n. ,06 101
NlTRII..I:+PVC 05' 100 6.00 U. 101
Pi
PVC
076
007
100
100 ,. ."
6,00
U.
U.
10'1'
101
0'17 100 I> 6.00 n. 101
4.n u. Ul1
Nitrle A~ld. 30·7OX
076973nZ NATURAl. RUSSER 017 10~ 6.00 n. .05 O~fI
1.00 U. •05 02•
5,50 II. .05 026
,. '.00 ~~. .Il~ 02A
NEOP+IlAT RUBBER Oil6 102 .. 1.00 23. .06 0"
,. 2.00 n. .04 026
,.
6.00 n. .O~ O~6
NEOP IlIA T RURBEIl 008 102 6.00 n. (I'~
NEOPREIIE 002 100 6.00 n. 101
018 100 2.n 13, .04 107
PE 076 '27 .83 23. Ul4
PVC 007 '00 5.75 U.
'ARANIX 04' 127 46.67 •02 U•
'0'
1114
Nitric Acid. "70"
076Q731l!] IIA nIRA~ RUuaER 001 UIIK ,. '.00 n. O~~
015 UN" 10 1.00 n. .1l4 O!iji
N~OP/NAT .U8BtR ooa UNK J> , .00 n. 1l§2
N~OPllfn 0'8 UIII(
" 1.110 n, .1111 fl!li'
, • lib ~j. .116 O~,.
NITIIIL~ 019 UNI( l> Lila ~:t. •iI~ u~ ..
"IfRI~~TPVC OS8 ,UO .1u U. lUI
I'~ 01'6 1i,10 .It l~ HII
PVC 003 UIIK .lu n. .111 (I~a
uut UNit ,. , .00 n. 1l§2
ISAIlANElI 061 '~1 n.
" 1~ lil~
YIION OW UN" 1.tJ(l ~$. 1i1 U';;I

A· I'd
SUMMARY Of PERFORMANCE DETAIL TESTS
PERMEATlOII TEST

CHEMICAL lIANE/ RESISTAltT PRaJUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASIIO MATERIAL DESC CODE HOURS UC/CM**2/M I N DEG C CM NUM

Nitric Acid. Fuaing Red


080075870 BUTYL 014 118 > 1.50 23. .03 001
> 1.50 23. .04 001
> 1.50 23. .08 001
CHlOROBUTYl 052 205 > 1.50 23. .05 001
CPE 060 113 .45 23. .05 001
NATURAL RUBBER 017 100 > 1.50 23. .04 001
> 1.50 23. .05 001
> 1.50 23. .04 001
101 > 1.50 23. .05 001
110 > 1.50 23. .05 001
IIEOP/IIAT RUBBER 008 114 > 1.50 23. .04 001
> 1.50 23. .04 001.
> 1.50 23. .04 001
IIEOPREIIE 002 100 > 1.50 23. .13 001
> 1.50 23. .13 001
018 100 > 1.50 23. .05 001
NITRILE 019 100 > 1.50 23. .04 001
> 1.50 23. .04 001
> 1.50 23. .03 001
118 > 1.50 23. .03 001
PV AUXlflOl 004 100 < .01 23. .09 001
PVC 003 120 .20 23. .05 001
.57 23. .10 001
.07 23. .03 001
007 100 .92 23. .09 001
.67 23. .11 001
.43 23. .10 001
053 189 .37 23. .07 001
•07 23 • .06 001
.25 23. .07 001
054 189 .04 23. .05 001
.01 23. .05 001
077 212 .12 23. .03 001
SILVER SHIELD 122 118 .58 23. .01 227
YITOII 009 118 > 1.50 23. .03 001

lIitrobenzene
000989530 BUTYL 014 118 > 23.00 23. .06 323
> 23.00 23. 4.00 227
064 117 > 8.00 23. .01 213
CPE 060 113 1.03 25. .07 302
070 lINK 1.03 23. .05 004
NATURAL RUBBER 017 100 .08 9.02 90.18 23. .05 107
IIEOPRENE 018 100 .75 1.14 23. .05 323
031 511 •67 132.26 23 • 323
IIITRllE 019 118 .48 10.22 23. .04 323
.55 10.22 23. .04 227
Py AlCOHOL 004 100 > 6.00 < .90 23. 107
102 100 > 16.00 23. .03 323
SILVER SHIELD 122 118 > 8.00 23. .01 227
TEFLOII 069 510 > 3.00 < .02 23. .05 303

A:-64
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM

000989530 TEFLON 069 510 > 3.00 < .02 24. .05 303
VITON 009 118 > a.oo 23. .03 323
> 8.00 23. .02 227
VITON/CHLOROBUTYL 112 113 2.83 3.00 25. .04 302

Nitroethane
000792430 BUTYL 014 118 > 8.00 23. .09 323
NATUttAL RUBBER 001 250 •03 186.37 23 . .02 323
NEOPRENE 018 100 • 82 102.20 23 . .04 323
PV ALCOHOL 102 100 3.52 2.40 23. .07 323

Nitrogen Tetroxide
10544n60 BUTYL 014 118 > 2.00 22. .23 321
.68 22. .05 321
064 113 .60 22. .03 321
085 211 > 2.00 22. .11 321
CHLOROBUTYL 052 205 > 2.00 23. .04 321
CPE 060 113 1.15 22. .05 321
070 113 1.25 22. .06 321
CR 39 095 122 > 2.00 22. .17 321
PE 091 UNIe: 1.17 22. .04 321
PVC 003 103 .33 22 • .13 321
•20 22. .13 321
053 126 .65 22. .05 321
083 211 > 2.00 22. .19 321
TEFLON 062 UtIle: < .01 23. .02 321
067 UNIe: < .01 23. .02 321
069 UNIe: < .01 23. .02 321
< .01 23. .02 321
VITON 009 118 .77 22. .03 321

Nltromethene
000755250 BUTYL 014 118 > 8.00 23. .09 323
NATURAL RUBBER 001 250 < .02 96.19 23. .02 323
017 100 .07 < .90 23. .05 107
NEOPRENE 002 100 1.50 < .90 23. 107
018 100 1.00 .90 9.02 23. .04 107
1.07 3.01 23. .05 323
NITRILE 019 100 .50 90.18 901.80 23. .06 107
PE 076 100 > 6.00 < .90 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
102 100 .17 30.06 23. .07 323

Nitropropane
253220140 BUTYL 014 118 > 8.00 < .02 23. .04 227
034 UtIle: > 101.00 22. .08 078
NITRILE 019 118 .27 177.35 23. .04 227
033 UNIe .42 . .83 200.40 22. .09 078
NITRILE+PVC 058 100 < .08 9.02 90.18 23. 107
PE 076 100 .OS 9.02 - 90.18 23. 107
PV ALCOHOL 035 UNIe < .08 44.09 22. .02 078
SILVER SHIELO 122 "a > 8.00 23. .01 227
VITON 009 l1a .35 73.41 23. 2.00 227

A-65
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME I RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/eM**2/MIN DEG C eM NUN

1-Nitropropane
001080320 BUTYL 014 118 > 8_00 23. .04 323
NITRILE 019 118 • 20 177.35 23 • .04 323
PV ALCOHOL 102 100 > 15.00 23. .03 323
TEFLON 069 510 > 3.00 < .02 23. .05 303
VITON 009 118 .28 156.91 23. .03 323

2-N i tropropane
000794690 BUTYL 014 118 > 8.00 23. .08 323
NATURAL RUBBER 001 250 .03 192.38 23. .02 323
NEOPRENE 018 100 .n 144.29 23. .04 323
PV ALCOHOL 102 100 > 8.00 23. .06 323

n-Nitrosodimethylamine
000551850 CPE 060 113 •50 23 • .OS 204
.70 438.88 23. .OS 204

Nonyl pheno I
251545230 NEOPRENE 018 100 > 20.00 23. .05 123
NITRILE 019 100 > 4.00 23. .04 123

n-Octane
001116590 NATURAL RUBBER 001 210 •33 120.24 23 • 080
NEOPRENE 002 210 7.00 216.43 23. 080
NITRILE DOS 210 6.00 < .02 23. 080
NITRILE+PVC OS7 210 4.75 n.14 23. 080
PVC 007 210 .92 108.22 23. 080

n-Octanol
290632830 NATURAL RUBBER 001 210 .75 10.22 23. 080
017 100 1.00 < .90 23. .05 107
NEOPRENE 002 100 > 7.00 < .90 23. 107
210 6.00 .02 23. 080
018 100 7.00 < .90 23. .04 107
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 6.00 .90 23. .06 107
NITRILE+PVC 057 210 6.00 < ,02 23. 080
PV ALCOHOL 004 100 4.00 < .90 23. 107
PVC 007 100 > 6.00 .90 23. 107
210 6.00 .02 23. 080

Oleic Acid
001128010 NATURAL RUBBER 017 100 .50 •90 9.02 23 • .05 107
NEOPRENE 002 100 2.50 .90 23. 107
018 100 1.00 .90 9.02 23. .04 107
NITRILE 019 100 > 6.00 < .90 23. .06 107
NITRILE+PVC OS8 100 > 6.00 .90 23. 107
PE 076 100 > 6.00 < .90 23. 107
PV ALCOHOL 004 100 1.00 < .90 23. 107
PVC 007 100 1.50 .90 9.02 23. 107
077 100 > 6.00 < .90 23. 107
> 6.00 .90 23. 107

A-66
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREA(THROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM

Oxal ic Acid
001446270 BUTYL 014 118 > 8.00 < .02 19. .07 323
NATURAL RUBBER 001 210 6.00 < .02 23. 080
017 100 > 6.00 23. .05 107
NEOPRENE 002 100 > 6.00 23. 107
210 6.00 < .02 23. 080
018 100 > 6.00 23. .04 107
> 8.00 < .02 19. .05 323
NITRILE DOS 210 6.00 < .02 23. 080
019 100 > 6.00 23. .06 107
> 8.00 < .02 19. .04 323
NITR I LE+PVC 057 210 6.00 < .02 23. 080
058 100 > 6.00 23. 107
PE 076 100 6.00 23. 107
PVC 007 100 > 6.00 23. 107
210 6.00 < .02 23. 080
077 100 > 6.00 23. 107
> 6.00 23. 107
VITON 009 118 > 8.00 < .02 20. .03 323

Palmi tic Acid


000571030 NATURAL RUBBER 017 100 .08 23. .05 107
NEOPRENE 002 100 > 6.00 23. 107
018 100 > 6.00 23. .04 107
NITRILE 019 100 .50 23. .06 107
PVC 007 100 1.25 23. 107

Pentachlorophenol
000878650 NEOPRENE 002 100 .10 < .90 23. 107
018 100 .10 < .90 23. .04 107
NITRILE 019 100 > 6.00 < .90 23. .06 107
PV ALCOHOL 004 100 .12 90.18 901.80 23. 107
PVC 007 100 3.00 < .90 23. 107

Pentane
001096600 NATURAL RUBBER 001 210 .05 913.82 23. 080
017 100 .03 2,705.40 25. .03 222
120 .01 5,711.40 25. .02 222
502 .06 1,803.60 25. .05 222
504 .06 1,803.60 25. .05 222
.09 1,603.20 25. .06 222
NEOP+NAT RUBBER 026 102 .07 1,803.60 25. .05 222
NEOP/NAT RUBBER 008 114 .03 2,304.60 25. .05 222
NEOPRENE 002 100 • 75 .90 - 9.02 23 • 107
.11 25.05 25. .08 222
120 .11 24.05 25 • .07 222
210 •50 667.33 23. 080
018 100 .08 .28 . 23. .05 000
.50 90.18 901.80 23. .04 107
118 > 1.00 < 2.00 25. .08 222
120 1.08 10.02 25. .05 222
> 1.00 2.00 25. .07 222

A-67
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEI> C eM NUM

001096600 NEOPRENE 018 120 .63 16.03 2S. .05 222


.33 21.04 2S. .03 222
NITRILE 005 210 6.00 < .02 23. 080
019 100 .03 < .02 23. .04 323
> 1.00 < 2.00 2S. .04 222
> 6.00 < .90 23. .06 107
> 1.00 < 2.00 2S. .06 222
> 1.00 < 2.00 2S. .04 222
S03 .09 10.02 2S. .03 222
NITRILE+PVC 057 210 1.2S 90.18 23. 080
058 100 • 18 9.02 . 90.18 23 . 107
PE 006 100 • 01 400.80 2S • .01 222
S05 • OS 70.14 2S . .01 222
076 100 • 08 90.18 • 901.80 23 • 107
PV ALCOIIOI. 004 100 > 6.00 < .90 23. 107
102 100 .25 < .02 23. .03 323
PVC 003 120 .01 1,102.20 25. .01 222
.01 811.62 2S. .01 222
• 1S 100.20 25 • .03 222
•04 250.50 25 • .02 222
SOD •01 721.44 25 • .01 222
S01 •01 1,603.20 25 • .01 222
•02 1,603.20 25 • .02 222
007 210 •33 210.42 23 • 080
SILVER SHIELD 122 118 > 6.00 23. .01 227
VITON 009 118 > 8.00 23. .02 323
> 8.00 23. .02 227

Perchloric Acid
076019030 NATURAL RUBBER 001 210 6.00 < .02 23. 080
IIEOPRENE 002 210 6.00 < .02 23. 080
NITRILE 005 210 6.00 < .02 23. 080
IIITRI LE+PVC 057 210 6.00 < .02 23. 080
058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC 007 210 6.00 < .02 23. 080
077 100 > 6.00 23. 107
> 6.00 23. 107

Perchloric Acid, 30'7Ol


076019032 NATURAL RUBBER 017 100 > 6.00 23. .05 107
NEOPRENE 002 100 > 6.00 23. 107
018 100 > 6.00 23. .04 107
NITRILE 019 100 > 6.00 23. .06 107
PVC 007 100 > 6.00 23. 107

Phenol (Carbol ic Acid)


001089520 CPE 060 113 3.40 23. .OS 204
~ 2.92 60.12 23. .05 204
NATURAL RUBBER 001 210 .S8 23. 080
017 100 > 1.00 < 3.01 25. .03 222
1.00 9.02 90.18 23. .05 107
120 •27 15.03 25 • .02 222

A-68
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRtouCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS RH
CASNO MATERIAL DESC COOE HOURS UG/CM**2/MIN DEG C eM IIUM

001089520 NATURAL RUBBER 017 502 > 1.67 < 3.01 25. .05 222
504 > 1.00 < 3.01 25. .05 222
> 1.00 < 3.01 25. .06 222
NEOP+NAT RUBBER 026 102 > 1.00 < 3.01 25. .05 222
NEOP/NAT RUBBER 008 114 > 1.00 < 3.01 25. .05 222
NEOPRENE 002 100 > 6.50 < .90 23. 107
> 1.65 < 3.01 25. .08 222
210 .67 23. 080
018 100 3.00 9.02 90.18 23. .04 107
118 > 1.00 < 3.01 25. .oe 222
120 > 1.00 < 3.01 25. .05 222
> 1.00 < 3.01 25. .07 222
> 1.00 < 3.01 25. .05 222
> 1.00 < 3.01 25. .03 222
NITRILE 005 210 .67 23. 080
019 100 .93 300.60 25. .04 222
> 1.00 < 3.01 25. .06 222
.53 300.60 25. .04 222
503 • 60 > 250.50 25 . .03 2U
NITRILE+PVC 057 210 2.00 23. 080
PE 006 100 > 1.00 3.01 25. .01 222
505 1.00 3.01 25. .01 222
PV ALCOHOL 004 100 .50 9.02 90.18 107
PVC 003 . 120 •05 190.38 25 . .01 222
• 13 120.24 2~ . .01 222
.53 n.15 25. .03 222
.25 100.20 25. .02 222
500 • 10 130.26 25 . .01 222
501 • 10 120.24 25 • .01 222
.06 120.24 25. .02 222
007 100 1.25 •90 9.02 23 • 10?
210 1.33 23. 080
TEFLON 069 510 > 3.00 < .02 23. .05 303

Phenol, >70%
001089523 BUTYL 014 118 > 20.00 23. .06 323
20.00 23. .04 227
NEOPRENE 018 100 > 10.67 23. .05 000
125 103 < .02 23. 045
NITRILE 019 103 18.04 23. 045
118 .58 1,274.54 23. .03 323
.65 > 9,018.00 23. .04 221
NITRILE+PVC 058 100 .83 .90 9.02 23. 107
PE 076 100 6.00 < .90 23. 107
PVC 007 103 18.04 23. 045
on 100 .50 .90 9.02 23. 107
1.50 .90 9.02 23. 107
VITON 009 118 > 15.00 23. .03 323
> 15.00 < .02 23. .02 227

Phenolphthalein
000770980 NATURAL RUBBER 017 506 > 8.00 23. .02 323
NEOPRENE 018 100 > 8.00 23. .04 323

A-69
SUMMARY OF PERFORMAICE DETAIL TESTS
PERMEATION TEST

CIIEtII CAL lIME/


CASIO
IfSI STAIIT
MATERIAL
PltCllUCT YEIIDOR
DESC emE
BREAlCTIlltCUiH TIME
IDlRS
PERMEATION RATE
UG/CH**21MIN DEG C CM ....
TEMP THICKNESS REF

000770980 NITRILE 019 100 > 8.00 23. .04 323


PVC 003 100 > 8.00 23. .02 323

Phosphoric Acid
076643820 IlATURAL IlU8BER 001 210 6.00 < .02 23. 080
1lE000EIIE 002 210 6.00 < .02 23. 080
II ITR ILE 005 210 6.00 < .02 23. 080
IIITRILE+PVC 057 210 6.00 < .02 23. 080
PE 076 127 > 14.00 23. 104
PVC 007 210 6.00 < .02 23. 080
SARAIIEX 061 127 > 14.00 23. 104

Phosphoric Acid, >701


076643823 IlATURAL RUBBER 017 100 > 6.00 23. .05 107
102 > 6.00 23. .05 026
> 6.00 23. .05 026
> 6.00 23. .05 026
> 6.00 23. .05 026
1lE000llAT RUBBER 026 102 > 6.00 23. .06 026
> 6.00 23. .04 026
> 6.00 23. .05 026
1lE00/IlAT RUBBER ooa 102 > 6.00 23. 026
1lE000EliE 002 100 > 6.00 23. 107
018 100 > 6.00 23. .04 107
II ITR IlE 019 100 > 6.00 23. .06 107
IIITRILE+PVC 058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC 007 100 > 6.00 23. 107
on 100 > 6.00 23. 107
> 6.00 23. 107

Phosphorus OXydIlor Ide


100258730 CPE 060 UIIIC .83 23. 052
1lE000EliE 002 UIIIC < .01 23. 052
018 UIIIC > 1.00 23. .09 052
.57 23. .06 052
IInRllE+pvc 058 UIIIC .48 23. 052
IIOIIUDVEIiPE 071 UIIIC .08 23. 052
PV ACETATE 124 UIIIC .03 23. 052
PVC 007 UIIIC < .01 23. 052
WAIIEX 061 UIIIC .84 23. 052
VITON 009 UIIIC .26 23. .03 052

1·Piperazineethanallne
001403180 BUTYL 014 118 > 4.00 23. .05 123

polychlorinated Biphenyls (PCBs) (Aroclor)


01D63630 BUTYL 014 118 24.00 23. .04 290
> 24.00 23. .04 290
CPE 070 UIIIC > 3.00 23. .05 004
IIATURAL RUBIER 017 UIIIC 1.00 23. .02 290
.08 23. .02 290
IIEOPREIIE 010 UIIIC > 24.00 23. .03 290

1.70
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOORS UG/CM**2/MIN DEG C CM MUM

013363630 NEOPRENE 010 UNK > 24.00 23. .03 290


> 24.00 23. .03 290
> 24.00 23. .03 290
018 100 > 24.00 23. .04 290
> 24.00 23. .04 290
24.00 23. .04 290
24.00 23. .04 290
PE 006 100 1.00 23. .01 290
1.00 23. .01 290
076 127 < 1.00 < .02 23. 104
PV ALCOHOL 102 100 > 24.00 23. .05 290
> 24.00 23. .05 290
SARANEX 061 127 1.00 • 2.00 < .02 23. 104
6.00 23. .02 290
7.00 23. .02 290
7.00 23. .02 290
TEFLON 036 UNK > 24.00 23. .01 290
> 24.00 23. .01 290
> 24.00 23. .01 290
VITON 009 118 > 24.00 23. .02 290
> 24.00 23. .02 290
> 24.00 23. .02 290

Potassium Hydroxide, 30'70%


013105832 NATURAL RUBBER 001 210 1.33 23. 080
017 100 > 6.00 23. .05 107
NEOP+NAT RUBBER 026 121 > 8.00 < .02 23. .05 237
NEOPRENE 002 100 > 6.00 23. 107
210 3.00 23. 080
018 100 > 6.00 23. .04 107
NITRILE 005 210 6.00 < .02 23. 080
019 100 > 6.00 23. .06 107
NITRILE+PVC 057 210 6.00 < .02 23. 080
058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC 007 100 > 6.00 23. 107
210 6.00 < .02 23. 080
077 100 > 6.00 23. 107
> 6.00 23. 107

Proaethazinehydrochloride
000583330 BUTYL 014 118 > 8.00 < .02 19. .06 323
NEOPRENE 018 100 > 8.00 < .02 19. .02 323
NITRILE 019 100 > 8.00 < .02 22. .02 323
PVC 007 100 > 8.00 < .02 20. .05 323

beta'Propiolactone
000575780 NATURAL RUBBER 017 508 .25 .33 4.31 22. .03 078
PE 006 209 .17 .50 1.20 22. .01 078
POLYURETHANE 050 178 < .08 831.66 22. .01 078

Propionaldehyde
001233860 BUTYL 014 118 > 13.00 23. .06 323

A-71
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAICTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**21MIN DEG C

001233860 NEOPRENE 018 100 .20 67.94 23. .OS 323


PV ALCOHOL 102 100 < .01 27.05 23. .04 .323
VITON 009 118 < .01 85.37 23. .03 323

Propionic Acid
000790940 PE 076 127 .OS 1.62 23. 104
TEFLON 069 510 > 3.00 < .02 23. .05 303

propionic Anhydride
001236260 PE 076 127 •08 76.35 23 • 104

Propyl Acetate
001096040 BUTYL 014 118 2.70 17.20 23. .04 227
NATURAL RUBBER 017 100 .08 90.18 901.80 23. .OS 107
NITRILE 019 100 .33 9.02' 90.18 23. .06 107
118 .28 435.87 23. .04 227
PE 076 100 .05 .90 9.02 23. 107
PV ALCOHOL 004 100 2.00 .90 9.02 23. 107
SILVER SHIELD 122 118 > 6.00 23. .01 227

Propyl Alcohol (Propanol)


000712380 NATURAL RUBBER 001 210 1.17 9.02 23. 080
017 100 .33 .90 9.02 23. .05 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
210 1.50 6.01 23. 080
018 100 2.50 < .90 23. .04 107
NITRILE DOS 210 6.00 < .02 . 23. 080
019 100 > 6.00 < .90 23. .06 107
NITRILE+PVC 057 210 6.00 < .02 23. 080
OS8 100 .OS .90 9.02 23. 107
PE 076 100 .05 .90 9.02 23. 107
PVC 007 100 1.50 .90 9.02 23. 107
210 2.00 9.02 23. 080
on 100 .33 .90 . 9.02 23. 107
.25 .90 9.02 23. 107
TEFLON 069 510 > 3.00 < .02 23. .05 303

n'Propylamine
001071080 CPE 070 UNIC .15 23. .05 004
TEFLON 069 510 > 10.20 < .02 23. .05 303

Propylenediamine
000789000 BUTYL 014 118 > 8.00 < .02 17. .07 323
NEOPRENE 018 100 > 8.00 < .02 24. .05 323
PVC 007 100 .30 9.02 17. .02 323
VITON 009 118 > 8.00 < .02 25. .02 323

Propylene Dichloride (Dichloropropane 1,2)


000788750 BUTYL 014 118 2.15 190.38 23. .08 323
PV ALCOHOL 102 100 > 8.00 < .02 23. .07 323
PVC 007 100 .03 11,452.86 23. .02 323
VITON 009 118 > 8.00 < .02 23. .03 323

A-72
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS UG/CM**2/MIN DEG C eM NUM

Propylene Glycol
000575560 NATURAL RUBBER 001 503 > 3.00 23. .06 086
017 120 > 3.00 23. .05 086
NEOP/NAT RUBBER 008 114 > 3.00 23. .06 086
NITRILE+PVC 058 100 > 6.00 23. 107
PE 006 512 > 3.00 23. .01 086
076 100 > 6.00 23. 107
PVC 077 100 > 6.00 23. 107
> 6.00 23. 107

Propylene Oxide
000755690 BUTYL 014 118 2.20 42.08 23. .06 323
NATURAL RUBBER 001 506 < .01 1,973.14 23. .02 323
PE 076 100 .05 9.02 . 90.18 23. 107
PV ALCOHOL 004 100 •58 9.02 90.18 23. 107
102 100 .07 •90 23 • .03 323
TEFLON. 069 510 2.28 •02 23 • .03 303
2.83 •02 23 • .05 303
VITON 009 118 .02 10,769.30 23. .03 323

',3'Propylene Oxide
005033000 BUTYL 014 118 1.13 561.12 23. .07 323
NATURAL RUBBER 001 250 < .01 30.06 23. .02 323
PV ALCOHOL 004 100 .17 3.01 23. .03 323
VITON 009 118 .03 30.06 23. .03 323

Propylmethacrylate
022102880 BUTYL 014 118 6.83 48.10 23. .08 323
IIITRILE 019 100 1.00 150.30 23. .04 323
PV ALCOHOL 004 100 > 8.00 < • 02 23 • .07 323
PVC 003 100 .03 462.92 23. .02 323

Pyridine
001108610 NATURAL RUBBER 017 100 .04 701.40 25. .03 222
120 .03 1,202.40 25. .02 222
502 .13 400.80 25. .05 222
504 .20 501.00 25. .05 222
.43 300.60 25. .06 222
IIEOP+NAT RUBBER 026 102 .14 400.80 25. .05 222
IIEOP/IIAT RUBBER 008 114 .23 300.60 25. .05 222
IIEOPREIIE 002 100 .65 200.40 25. .08 222
120 .03 701.40 25. .07 222
018 118 .85 400.80 25. .08 222
120 .33 901.80 25. .05 222
.63 601.20 25. .07 222
.43 701.40 25. .05 222
.07 1,703.40 25. .03 222
NITRILE 019 100 .18 3,206.40 25. .04 222
.25 3,006.00 25. .06 222
•16 3,507.00 25 • .04 222
181 .09 4,0011,00 25. .03 222
503 .17 2,404.80 25. .03 222

A-73
SUMMARY OF PERFORMANCE DETAIL TESTS
PEIlNEATlON TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE IIClJRS UG/CM**21MIII OEG C CM NUM

001108610 PE 006 100 > 1-(10 < 100.20 25. .01 222
505 > 1_00 < 10.02 25. .01 222

Socliln Cyanide, <3OX


001433391 PE 076 127 6.00 < .02 60. 104

Socliln Cyanide, 30-7OX


001433392 PE 076 127 < 4_00 < .02 70. 104

Sodiln Hydroxide
013107320 CPE 060 113 > 3_00 25. .07 302
NITRllE+PVC 058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC 077 100 > 6.00 23. 107
> 6.00 23. 107
SILVER SHIElD 122 118 > 6_00 23. .01 227
VITON/CHlOROBUTYl 112 113 > 3_00 25. .04 302

Socliln Hydroxide, <lOX


013107321 NEOP+NAT RUBBER 026 121 > 8_00 < .02 23. .05 237

Socliln Hydroxide, 30-7OX


013107322 BUTYL 064 117 > 8.00 23. .02 213
> 8_00 23. .01 213
BUTYl/NEOPRENE
NAJURAL RUBBER
110
001

015
017
....
117
210

100
>

>
>
>
8.00
6_00
1.00
1.00
6.00
< .02
23.
23.
23.
23.
23.
.02

.04
.05
213
080
052
052
107
NEOP/NAT RUBBER OOIS UNIC > 1.00 23. 052
IIEOPREIIE 002 100 > 6.00 23. 107
210 6.00 < .02 23. 080
018 100 > 6.00 23. .04 107
UNIe > 1.00 23. .09 052
> 1.00 23. .06 052
093 117 > 8.00 23. .02 213
138 117 > 8.00 23. .03 213
139 117 > 8.00 23. .01 213
IIEOPRENE+PVC 127 117 > 8.00 23. .02 213
IIITRllE 005 210 6.00 < .02 23. 080
019 100 > 6.00 23. .06 107
UNK > 1.00 23.- .05 052
IIITRllE+PVC 057 210 6.00 < .02 23. 080
058 117 > 8.00 23. .01 213
tIONWOVElI PE 071 127 < .17 .63 23. 104
PE 076 117 > 8.00 23. .01 213
127 > 8.00 < .02 23. 104
PVC 003 UNK > 1.00 23. .02 052
007 100 > 6.00 23. 107
210 6.00 < .02 23. 080
UNK > 1.00 23. 052
049 117 > 8.00 23. .01 213
> 8.00 23. .01 213

A-74
SUMMARY OF PERFORMANCE ~E1AIL TESTS
PERMEATION TEST

CHEMI::AL NAME; RE~ISTANT PROOUC"r VENOOR BREAKTHROUGH liME PERMEATION R~, TEMP THIC"HE~:' "to
CASNO MATERIAL DESC COOE HWRS UG/CM**Z/MIN OEG C CM NUk

013107322 PVC OS3 117 > 8.00 23. .02 213


144 117 > 8.00 23. .02 213
SARAIIEX 061 117 > 8.00 23. .01 213
127 > 8.00 23. 104
TEFLON 069 510 > 71.00 < .02 16. .05 303
VITON 009 UNIC > 1.00 23. .03 052
145 117 > 8.00 23. .01 213
VITON/NEOPRENE 111 117 > 8.00 23. .02 213

Sodium Hypochlorite, 30·70%


076815292 NATURAL RUBBER 001 210 6.00 < .02 23. 080
NEOPRENE 002 210 6.00 < .02 23. 080
NITRILE 005 210 6.00 < .02 23. 080
NITRILE+PVC 057 210 6.00 < .02 23. 080
PVC 007 210 6.00 < .02 23. 080

Styrene
001004250 CPE 060 113 1.00 • 1.17 25. .07 302
NATURAL RUBBER 001 210 .17 348.70 23. 080
NEOPRENE 002 210 .20 517.03 23. 080
125 103 30.06 23. 045
JUTRILE OOS 210 .50 733.46 23. 080
019 103 456.91 23. 045
NITRILE+PVC 057 210 .67 186.37 23. 080
058 100 . 07 9.02 90.111 23 . 107
PE 076 100 .17 9.02 90.111 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
PVC 007 103 156.31 23. 045
210 •33 216.43 23 • 080
SARAIIEX 061 127 .n 69.74 23 • 104
TEFLON 069 510 > 4.00 < .02 23. .05 303
VITON/CHLOROBUTYL 112 113 > 3.00 25. .04 302

Sulfuric Acid
076649390 BUTYL 064 117 > 8.00 23. .02 213
> 8.00 23. .01 213
> 8.00 23. .02 213
BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213
CPE 060 113 > 3.00 25. .07 302
070 UNIC > 3.00 23. .05 004
NATURAL RUBBER 001 210 1.D 23. 080
NEOP+NAT RUBBER 026 121 1.5] 462.92 23. .05 237
NEOPRENE 002 210 2.50 23. 080
093 117 1.17 23. .02 213
138 117 2.25 23. .03 213
139 117 3.67 23. .02 213
NEOPRENE+PVC 127 117 1.33 23. .02 213
NITRILE OOS 210 6.00 < .02 23. 080
NITRILE+PVC 057 210 4.00 23. 080
058 117 .42 23. .01 213
NONWOVEN PE 071 127 < .08 3,006.00 23. 104
PE 076 117 > 8.00 23. .01 213
PVC 007 210 1.75 23. 080

A-75
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATlOli TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UGfCM*·21MIIi DEG C CM NUM

076649390 PVC 049 117 1.33 23. .01 213


•42 23 • .01 213
053 117 .42 23. .02 213
< .42 23. .02 213
077 117 < •08 23 • .01 213
• 33 23 • .01 213
144 117 •42 23 • .02 213
SAlWIEX 061 111 > 8.00 23. .01 213
127 > 8.00 23. 104
SILVER SHIELD 122 118 > 6.00 23. .01 227
VITON 145 117 > 8.00 23. .01 213
VITON/CHLOROBUTYL 112 113 > 3.00 25. .04 302
VITON/IIEOPREIiE 111 117 > 8.00 23. .02 213

Sulfuric Acid, <3OX


076649391 IIITRILE+PVC 058 100 2.00 23. 107
NONWOVEII PE 071 127 .50 .92 23. 104
PE 076 100 > 5.00 23. 107
127 > 8.00 < .02 23. 104
PVC 077 100 3.00 23. 107
2.33 23. 107
SAlWIEX 061 127 > 8.00 < .02 23. 104

Sulfuric Acid, 30·7OX


076649392 CPE 070 UNK > 3.00 23. .05 004
NATURAL RUBBER 017 102 > 6.00 23. .05 026
> 6.00 23. .05 026
> 6.00 23. .05 026
> 6.00 23. .05 026
IIEOP+NAT RUBBER 026 102 > 6.00 23. .06 026
> 6.00 23. .04 026
> 6.00 23. .05 026
IIEOP/IiAT RUBBER 008 102 > 6.00 23. 026
IIONWOVEII PE 011 121 .10 4.51 23. 104
PE 076 127 > 8.00 < .02 23. 104
SARAIIEX 061 127 > 8.00 < .02 23. 104

Sulfuric Acid, >7OX


076649393 IIATURAL RUBBER 001 UNK > 1.00 23. 052
015 UIIK > 1.00 23. .04 052
IIEOP/IiAT RUBBER 008 UNK > 1.00 23. 052
IIEOPRENE 002 100 > 6.00 23. 107
018 100 3.00 23. .04 107
UNK > 1.00 23. .09 052
> 1.00 23. .06 052
II ITR ILE 019 UNK > 1.00 23. .05 052
IIITRILE+PVC 058 100 .62 23. 107
IIOIIYOVEII PE 071 127 < .08 38.38 23. 104
P£ 016 100 > 6.00 23. 107
127 > 8.00 < .02 23. 104
> 2.00 < .02 65. 104
PVC 003 UIIK .15 23. .02 052
007 100 3.67 23. 107

A-76
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM

076649393 PVC 007 UNK > 1.00 23. 052


077 100 .25 23. 107
1.00 23. 107
SARANEX 061 127 5.50 65. 104
> 8.00 < _02 23. 104
TEFLON 069 510 > n.oo < .02 25. .05 303
VITON 009 UNK > 1.00 23. .03 052

Tamic Acid
014015540 NITRILE+PVC 058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PVC 077 100 > 6.00 23. 107
> 6.00 23. 107

Tamic Acid, 30-7OX


014015542 NATURAL RUBBER 017 100 > 6.00 < .90 23. .05 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
018 100 > 6.00 < .90 23. .04 107
NITRILE 019 100 > 6.00 < .90 23. .06 107
PVC 007 100 > 6.00 < .90 23. 107

" " 1,2-Tetrachloroethane


006302060 BUTYL 014 118 2.30 138.28 23. .07 323
PV ALCOHOL 102 100 > 8.00 23. .08 323
PVC 007 100 .05 330.66 23. .02 323
VITON 009 118 > 8.00 23. .03 323

1,1,2,2-Tetrachloroethane
000793450 BUTYL 014 118 4.60 70.14 23. .07 323
NATURAL RUBBER 017 100 .11 2,605.20 25. .03 222
120 .03 5,611.20 25. .02 222
502 .09 2,905.80 25. .05 222
504 .17 1,402.80 25. .04 222
.35 1,302.60 25. .06 222
NEOP+NAT RUBBER 026 102 .15 3,206.40 25. .05 222
NEOPRENE 002 100 .10 501.00 25. .08 222
120 .09 601.20 25. .07 222
018 118 > 1.07 < 20.04 25. .08 222
120 .53 1,102.20 25. .05 222
.83 1,002.00 25. .07 222
.30 1,402.80 25. .05 222
.16 2,204.40 25. .03 222
NITRILE 019 100 .37 3,206.40 25. .04 222
1.23 > 300.60 25. .06 222
.22 3,106.20 25. .04 222
503 .32 2,204.40 25. _03 222
PE 006 100 .07 10.02 25. .01 222
114 .31 1,402.80 25. .05 222
505 > 1.00 < 2.00 25. _01 222
PV ALCOHOL 004 100 > 8.00 < .02 23. _04 323
PVC 003 120 .02 5,410.80 25. _01 222
.02 6,012.00 25. _01 222
.10 2,505.00 25. .03 222

)..-77
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATlOII TEST

CHEMICAL NAMEI RESISTANT PRODUCT VEIIDOR BREAIClHROOGH TINE PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE IIOORS UG/CM**2/MIN DEG C CM lUI

000793450 PVC 003 120 .04 4,008.00 25. .02 222


500 .01 25. .01 222
501 •02 4,108.20 25 . .01 222
• 03 3,106.20 25 • .01 222
007 100 < • 01 70.14 23 • .02 323
TEFLON 069 510 > 15.20 < .02 23. .05 303
VITOII 009 118 > 8.00 < .02 23. .03 323

Tetrachloroethylene (Perchloroethylene)
001271840 BUTYL 014 118 • 17 > 751.50 23 • .04 291
• 17 > 751.50 23 • .04 291
.13 895.12 25. .04 Z88
UIIIC • 13 895.79 23 • .04 100
CPE 070 UIIIC 1.07 23. .05 004
NATURAL RUBBER 001 210 • 10 601.20 23 • 080
017 UIIIC < .02 > 751.50 23. .02 291
< .02 > 751.50 23. .02 291
NEOP+tIAT RUBBER 026 121 .05 1,478.95 23. .05 237
NEOPRENE 002 210 .12 571.14 23. 080
010 100 .20 980.29 25. .05 288
018 100 .10 > 641.28 23. .04 291
.13 > 641.28 23. .04 291
UIIIC .20 979.96 23. .05 100
NITRILE 005 210 4.00 6.01 23. 080
019 100 5.00 •90 • 9.02 23 • .06 107
118 1.28 33.07 23. .04 323
1.30 33.07 23. .04 227
UIIIC 3.52 28.26 23. .03 100
020 100 3.52 28.22 25. .03 Z88
191 7.25 47.09 23. .04 291
5.33 41.08 23. .04 291
MITRILE+PVC 057 210 6.20 90.18 23. 080
058 100 • 08 90.18' 901.80 23 • 107
PE 006 100 < .02 > 686.37 23. .01 291
< .02 > 686.37 23. .01 291
< • 02 769.87 25 • .01 288
UIIIC < •02 769.54 23 • .01 100
076 100 • 08 90.18' 901.80 23 • 107
PV ALCOHOL 004 100 5.00 < .90 23. 107
102 100 > 16.00 23. .04 323
.60 2.00 23. .05 291
• 35 11.62' 23 • .05 291
.80 1.20 23. .05 291
> 6.00 25. .05 288
UIIIC > 8.00 23. .05 100
PVC 003 100 < .01 180.96 23. .02 323
118 < .02 744.82 25. .01 288
UIIIC < .02 745.49 23. .01 100
007 210 .75 114.23 23. 080
SARAIIEX 061 127 .27 1.14 23. 104
.08 10.02 23. .02 291
• 03 20.04 23 . .02 291
SILVER SHIELD 122 118 > 6.00 23. .01 227

A-78
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM

001271840 TEFLON 036 214 •43 2.30 23 • .01 291


> 24.00 23. .01 291
069 510 > 10.40 < .02 23. .05 303
1.80 25. .05 303
VITON 009 118 > 17.00 23. .03 323
> 17.00 23. .02 227
3.17 4.21 45. .02 291
3.00 4.21 45. .02 291
> 24.00 23. .02 291
> 24.00 23. .02 291
> 24.00 10. .02 291
> 24.00 10. .02 291
> 6.00 25. .02 288
UNK > 8.00 23. .02 100

Tetraethylenepentemine
001125720 BUTYL 012 118 > 8.00 25. .09 323
NATURAL RUBBER 017 506 1.77 12.02 28. .02 323
NEOPRENE 018 100 > 8.00 27. .05 323
VITON 009 118 > 8.00 23. .04 323

Tetrafluoroethylene
001161430 BUTYL 014 118 > 8.00 23. .06 323
NEOPRENE 018 100 > 8.00 23. .06 323
PV ALCOHOL 102 100 > 8.00 23. .03 323
VITON 009 118 > 8.00 23. .03 323

Tetrahydrofuran
001099990 BUTYL 014 118 .45 671.54 23. .07 323
.52 673.34 23. .04 227
064 117 .12 23. .02 213
.10 23 • .01 213
•08 23. .02 213
BUTYL/NEOPRENE 110 117 < .08 23. .02 213
CPE 060 113 .45 • .05 25. .07 302
070 UNK .20 23. .05 004
NATURAL RUBBER 017 100 .04 >16,699.98 25. .03 222
120 .02 >16,699.98 25. .02 222
502 .06 > 16,699.98 25. .05 222
504 .04 3,507.00 25. .05 222
.11 2,404.80 25. .06 222
NEOP+NAT RUBBER 026 102 .06 > 16,699.98 25. .05 222
NEOPINAT RUBBER DDS 114 .02 > 16,699.98 25.· .05 222
NEOPRENE 002 100 .03 8,016.00 25. .08 222
120 .02 9,619.20 25. .07 222
018 118 .33 9,018.00 25. .08 222
120 .09 16,032.00 25. .05 222
.23 11,022.00 25. .07 222
.08 14,028.00 25. .05 222
.05 > 16,699.98 25. .03 222
D93 117 .03 23. .02 213
125 103 829.66 23. 045
138 117 < .08 23. .03 213

A-79
SUMMARY OF PERFORMANCE DETAil TESTS
PERMEATION TEST

CHEMICAL NAME/
CASNO
RESISTANT
MATERIAL
PRODUCT VENDOR
DESC CODE
BREAKTHROUGH TIME
HOURS
PERMEATION RATE
UG/CM**2/MIN DEG C eM ...
TEMP THICKNESS REf

001099990 NEOPRENE 139 117 .10 23. .02 213


NITRILE 019 100 .10 3,707.40 25. .04 222
.10 2,705.40 25. .06 m
•08 4,308.60 25 • .04 m
103 931.86 23. 045
118 < .01 1,005.81 23. .04 323
.07 1,004.00 23. .04 227
503 •04 3,507.00 25 • .03 222
PE 006 100 .01 200.40 25. .01 2ZZ
505 .05 4.01 25. .01 222
076 100 .25 . 90 9.02 23 • 107
117 .10 23. .01 213
PV ALCOHOL 102 100 4.72 2.52 23. .03 323
PVC 003 120 .01 25. .01 222
.01 25. .01 2ZZ
.03 25 • .03 222
•02 25. .02 222
500 .01 25. .01 m
501 .01 25. .01 m
049 117 < .16 23. .01 213
SARANEX 061 117 .03 23. .01 213
TEFLON 069 510 > 5.50 < •02 25 • .05 303
VITON 009 118 < .01 1,964.09 23. .03 323
.07 1,965.92 23. .02 227
145 117 .08 23. .01 213
VITON/CHLOROBUTYL 112 113 .15 .18 25. .04 302
VITON/NEOPRENE 111 117 .17 23. .02 213

N,N,N',N'·TetramethylenedfaMine
001101890 BUTYL 012 118 1.08 48.10 20. .07 323
014 118 1.08 48.10 23. .07 323
IIITRILE 019 100 1.80 90.18 23. .05 323
1.80 90.18 24. .05 323
PVC 003 100 .03 1,923.84 23. .02 323
VITON 009 118 .43 1,725.44 23. .04 323
.43 1,725.44 24. .04 323

Thiophenol (Benzenethiol)
001089850 BUTYL 014 118 .28 2,024.04 21. .05 124
PV ALCOHOL 004 100 > 4.00 21. 124

Toluene
001088830 BUTYL 012 UNIC .17 273.55 25. .04 273
.n 254.31 25. .04 273
.50 2n.75 25. .06 273
.50 276.55 25. .06 273
.17 267.53 25. .04 273
.25 304.81 25. .04 273
.50 281.36 25. .06 273
.67 251.30 25. .06 273
.17 245.29 25. .04 273
.17 253.71 25. .04 273
.33 300.60 25. .06 273

A-80
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE .EMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM

001088830 BUTYL 012 UNK .50 281.36 25. .06 273


014 118 .35 132.87 23. .06 323
.28 1,503.00 22. .05 122
216 . 15 37 . .06 122
107 UNK .18 59.12 25. .04 149
.47 69.14 25. .04 149
.18 1,503.00 25. .04 149
.15 167.33 25. .04 149
• 70 141.28 25 • .04 149
CPE 060 113 1.15 . 1.25 25. .07 302
NATURAL RUBBER 001 210 .15 637.27 23. 080
UNK .01 > 521.04 23. .12 274
.28 649.30 25. .19 088
.30 913.82 25. .24 088
017 100 .03 4,709.40 25. .03 222
120 .01 9,218.40 25. .02 222
502 •06 2,705.40 25 . .05 222
504 .05 3,607.20 25. .05 222
.07 2,805.60 25. .06 222
lINK .01 > 521.04 23. .04 274
NEOP/NAT RUBBER 008 114 .08 4,709.40 25. .05 222
UNK .07 > 541.08 23. .05 274
NEOPRENE 002 100 .03 1,002.00 25. .08 222
120 .02 2,605.20 25. .07 222
210 .1S 499.00 23. 080
UNK .21 23. .05 186
018 100 .20 131.06 23. .OS 323
118 .53 701.40 25. .08 222
120 .23 1,402.80 25. .OS 222
.43 ',302.60 25. .O? 222
.28 901.80 25. .05 222
.07 2,505.00 25. .03 222
509 .52 > 1,503.00 22. .09 122
lINK .46 > 526.05 23. .09 274
.21 > 531.06 23. .06 274
.08 274.75 25. .04 273
.08 240.48 25. .04 273
.25 274.75 25. .06 273
.33 235.67 25. .06 273
031 lINlC .08 3,509.00 25. .04 149
.12 767.53 25. .04 149
.02 400.80 25. .04 149
.37 2,143.28 25. .04 149
.12 2,732.45 25. .04 149
.31 23. .04 187
NITRILE 005 210 1.00 330.66 23. 080
019 100 .38 300.60 22. .04 122
.32 701.40 25. .04 222
.17 90.18 . 901.80 23. .06 107
.45 37. .06 122
.35 37. .06 122
1.20 400.80 37. .06 122
> 1.00 < 300.60 25. .06 222

A-81
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME I RESISTANT PRODUCT VENDOR B~EAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOORS UG/CM**2/MIN DEG C eM NUM

001088830 II ITRI lE 019 100 •24 200.40 34 • .04 122


.25 300.60 22. .04 122
• 16 37 • .04 122
.60 501.00 25. .04 222
118 .18 409.42 23. .04 227
.25 200.40 22. .03 122
.13 37. .04 122
•28 200.40 22 • .04 122
181 400.80 25. .03 222
503 .17 801.60 25. .03 222
509 .55 300.60 22. .06 122
UNIC .36 > 526.05 23. .05 274
> 1.00 23. .05 274
.33 260.32 25. .04 273
.33 201.40 25. .04 273
.58 211.62 25. .06 273
.67 238.68 25. .06 273
020 216 .12 601.20 22. .03 122
.10 37. .04 122
.11 701.40 34. .04 122
.68 501.00 22. .09 122
UNIC .13 1,184.36 25. .03 088
.13 1,244.48 25. .03 088
033 UIIIC .23 23. .05 187
IIITRILE+PVC 057 210 .67 365.73 23. 080
PE 006 100 .01 2,204.40 25. .01 222
505 .03 601.20 25. .01 222
D56 UIIlC .12 23. .01 187
076 100 .02 .90 . 9.02 23. 107
127 < .08 165.33 23. 104
Py ALCCIIOL 004 100 > 25.00 22. .04 122
.25 .90 . 9.02 23. 107
UIIlC > 1.00 23. .12 274
035 UNIC 1.02 11.02 25. .07 149
2.30 90.18 25. .07 149
.02 4.01 25. .07 149
.02 317.63 25. .07 149
PVC 003 120 < .01 8,817.60 25. .01 222
< .01 5,110.20 25. .01 222
.05 2;104.20 25. .03 222
.06 1,803.60 25. .02 222
215 .20 > 1,503.00' 22. .06 122
500 < .01 5,310.60 25. .01 222
S01 < .01 5,911.80 25. .01 222
.01 4,809." 25. .02 22Z
007 129 .20 37. .05 122
.13 300.60 22. .06 122
.47 200.40 22. .07 122
.13 300.60 34. .05 122
210 .50 426.85 23. 080
UNK .23 > 526.05 23. .16 274
.28 23. .07 186
.14 23. .05 186

A-82
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM

001088830 PVC 007 UNK . 15 829.66 25 . .13 088


.15 859.72 25,- .13 088
• 09 898.79 25 . .10 088
• 08 829.66 25 • .11 088
049 UNK •38 23 . .03 187
SARANEX 061 127 < .08 20.04 23. 104
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEFLQN 069 510 > 3.00 < .02 23. .05 303
> 18.50 < .02 25. .05 303
VITON 009 118 > 16.00 < .02 23. .02 227
•58 37 • .02 122
> 3.30 34. .03 122
> 4.50 22. .03 122
> 7.00 22. .03 122
UNK > 1.00 23. .03 274
VITON/CHLOROBUTYL 112 113 > 3.00 25. .04 302
VITON/NEOPRENE 022 216 1.67 37. .06 122
4.20 200.40 22. .06 122

Toluene Diisocyanate
264716250 BUTYL 014 118 > 8.00 23. .04 323
> 8.00 23. .04 227
CPE 070 UNIC > 3.00 23. .05 004
NATURAL RUBBER 017 100 • 12 9.02 . 90.18 23. .05 107
NITRILE 005 120 > 8.00 23. .06 236
019 118 3.86 10.82 23. .03 323
3.70 10.82 23. .04 227
PE 076 100 1.00 .90 • 9.02 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
102 100 > 16.00 23. .03 323
SILVER SHIELD 122 118 > 8.00 23. .01 227
TEFLON 069 510 > 3.30 < .02 23. .05 303
VITON 009 118 > 16.00 23. .03 323
> 16.00 23. .02 227

p'Toluenesulfonic Acid
001041540 CPE 070 UNK > 3.00 23. .05 004
NEOPRENE 018 100 > 4.00 23. .05 123
PVC OOJ 215 > 4.00 23. .05 123

o'Toluidine
000955340 TEFLON 069 510 > 3.30 < .02 23. .05 303

Triallylamine
001027050 NEOPRENE 018 100 1.05 561.12 19. .05 323
NITRILE 019 100 > 8.00 < .02 22. .04 323
PVC 007 100 .08 621.24 20. .02 323
VITON 009 118 > 8.00 < .02 17. .03 323

Trichloroacetaldehyde (Chloral)
000758760 BUTYL 014 118 3.32 50.10 23. .07 323
PV ALCOHOL 102 100 > 8.00 < .02 23. .08 323
PVC 007 100 .07 2,845.68 23. .02 323

A-B3
SUMMARY OF PERFORMANCE DETAIL TeSTS
PERMEATION TEST

CHEMICAL NAME! RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS UG!CM**2/MIN DEG C eM NUM

000758760 VITON 009 118 7.28 < .02 23. .03 323

Trichloroacetonitrile
005450620 BUTYL 014 118 1.98 316.23 23. .06 323
IIEOPRENE 018 100 1.12 927.65 23. .06 323
PV ALCOHOL 102 100 > 8.00 23. .06 323
VITOII 009 118 1.00 184.57 23. .03 323

1,Z,4'Trichlorobenzene
001208210 BUTYL 014 UNK .08 23. .04 290
.08" 23. .04 290
IIATURAL RUBBER 017 UNK .08 23. .02 290
.08 23. .02 290
1lE000ENE 010 UNK 4.00 23. .03 290
5.00 23. .03 290
018 UNK 1.00 23. .04 290
PE 006 UNK .17 23. .01 290
.17 23. .01 290
076 127 < .25 5.01 23. 104
PV ALCOHOL 102 UNK 1.00 23. .05 290
1.00 23. .05 290
SARANEX 061 127 .25 . 1.00 •10 23 • 104
UNK 1.00 23. .02 290
1.00 23. .02 290
TEFLON 036 UNK 1.00 23. .01 290
8.00 23. .01 290
VITON 009 UNK .17 23. .02 290
.17 23. .02 290

1,l,2'Trichloroeth_
000790050 BUTYL 014 118 5.78 42.08 23. .09 323
UNK .83 23. .06 326
064 UNK .75 23. .04 326
IIATlIIAL RUBBER 017 lINK .02 23. .02 326
IIEOPRENE 018 UNK .12 23. .06 326
IIITRILE 019 utlK .03 23. .02 326
PE 042 UNK .06 23. .01 326
POL \'URETHANE 050 UNK < .02 23. .01 326
PV ALCOHOL 102 100 > 8.00 23. .07 323
UNK .25 23. .04 326
PVC 003 118 .03 1,238.47 23. .02 323
TEFLON 036 UNK > 24.00 23. .01 326
044 UNIe 2.92 23. .01 326
VITON 009 118 > 8.00 23. .05 323
UNK > 24.00 23. .03 326

2,2,2' Trichloroethanol
001152080 SARANEX 061 127 .32 13.23 23. 104

Trichloroethylene (Trichloroethene)
000790160 BUTYL 014 118 .23 3,308.40 23. .06 323
.08 > 826.65 23. .04 291
.08 > 826.65 23. .04 291

A-84
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C eM HUM

000790160 BUTYL 014 118 •08 2,037.40 25 • .04 288


•22 3,306.60 23 . .04 227
UNK •08 2,044.08 23 . .04 100
CPE 070 UNK .20 23. .05 004
NATURAL RUBBER 001 210 .1D 1,262.52 23. 080
017 100 .03 9,418.80 25. .03 222
120 .01 > 16,699.98 25. .02 222
502 .05 7,615.20 25. .05 222
504 .05 6,813.60 25. .05 222
.08 5,310.60 25. .06 222
UNK < .02 > 656.31 23. .02 291
< .02 > 656.31 23. .02 291
NEOP+NAT RUBBER 026 102 .05 7,314.60 25. .05 222
NEOP/NAT RUBBER 008 114 .08 5,911.80 25. .05 222
NEOPRENE 002 100 .03 1,903.80 25. .08 222
120 .03 1,803.60 25. .07 222
210 .13 1,160.32 23. 080
tlNK .23 23. .05 186
010 100 .08 2,187.70 25. .05 288
018 100 .05 > 566.13 23. .04 291
< .07 > 566.13 23. .04 291
118 .38 1,302.60 25. .08 222
120 .14 2,304.60 25. .05 222
.25 2,104.20 25. .07 222
.20 1,903.80 25. .05 222
.06 4,208.40 25. .03 222
UNK .78 2,194.38 23. .05 100
031 tlNK .17 • .25 53.11 22. .08 078
125 103 823.64 23. 045
NITRILE 005 210 .33 1,106.21 23. 080
019 100 .15 2,004.00 25. .04 222
.43 901.80 25. .06 222
.16 2,104.20 25. .04 222
103 1,791.58 23. 045
118 .07 1,701.40 23. .04 323
.13 1,701.40 23. .04 227
503 .13 1,603.20 25. .03 222
UNK .16 1,647.29 23. .03 100
020 100 .16 1~646.62 25. .03 288
503 < .25 > 826.65 23. .04 291
.18 > 826.65 23. .04 291
033 tlNK .17 . .25 60.12 22. .09 078
NITRILE+PVC 057 210 .50 1,244.48 23. 080
058 100 .05 901.80 9,018.00 23. 107
PE 006 100 < .02 > 657.31 23. .01 291
< .02 > 657.31 23. .01 291
.01 1,503.00 25. .01 222
< .02 1,394.45 25. .01 288
tlNK 1,394.78 23. .01 100
076 100 .08 9.02' 90.18 23. 107
PV ALCOHOL 004 100 .50 < .90 23. 107
035 tlNK < .25 8.02 22. .01 078
102 100 > 16.00 23. .04 323

A-85
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME I RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEJIP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/eM**2/MIN DEG C eM NUM

000790160 PV ALCOHOL 102 100 24.00 23. .05 291


24.00 23. .os 291
24.00 10. .OS 291
24.00 10. .os 291
24.00 45. .os 291
24.00 45. .OS 291
> 6.00 25. .OS 288
UNIC > 8.00 23. .05 100
PVC 003 118 < .02 1,015.36 25. .01 288
120 •01 11,022.00 25 • .01 222
•01 9,018.00 25 • .01 222
•05 3,807.60 25 • .03 222
.01 8,216.40 25. .02 222
500 .01 13,026.00 25. .01 222
501 .01 13,026.00 25. .01 222
.01 6,212.40 25. .02 222
UNK < •02 1,016.03 23 • .01 100
007 103 901.80 23. 045
210 •33 1,256.51 23 • 080
UNK .16 23. .07 186
.08 23. .05 186
077 100 •07 90.18 . 901.80 23 • 107
•05 901.80 9,018.00 23 • 107
SARAIIEX 061 127 < .02 > 310.62 23. .02 291
< •02 > 290.58 23 • .02 291
SILVER SHIELD 122 118 > 6.00 23. .01 227
TEFLON 036 214 > 24.00 23. .01 291
> 24.00 23. .01 291
069 510 2.38 .03 23. .05 303
2.43 .03 23. .OS 303
2.60 .03 23. .05 303
VITON 009 118 7.35 1.44 23. .03 123
> 24.00 10. .02 291
> 24.00 10. .02 291
•80 23.05 45 • .02 291
•80 21.04 45 • .02 291
7.40 1.40 23. .02 227
10.00 > 1.60 23. .02 291
12.00 > 1.70 23. .02 291
> 6.00 25. .02 288
UNK > 8.00 23. .02 100

1,2,3·Trichloropropene
000961840 BUTYL 014 118 > 8.00 < .02 23. .06 323
NITRILE 019 100 •35 20.04 23 • .04 323
PVALCOHOl 004 100 > 8.00 < .02 23. .03 323
VITON 009 118 > 8.00 < .02 23. .03 323

Tricresyl Phosphate (Tritolyl Phosphate)


013307850 BUTYL 012 118 > 8.00 23. .07 323
NATURAL RUBBER 017 100 •75 < .90 23 • .05 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
018 100 > 6.00 < .90 23. .04 107

A-86
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATIOH RATE TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN OEG C CM NUM

013307850 NITRILE 019 100 > 6.00 < .90 23. .06 107
NITRILE+PVC 058 100 > 6.00 23. 107
PE 076 100 > 6.00 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
> 8.00 23. .08 323
PVC 003 100 > 8.00 23. .02 323
007 100 > 6.00 < .90 23. 107
on 100 > 6.00 23. 107
> 6.00 23. 107
VITON 009 118 > 8.00 23. .04 323

Triethanolamine
001027160 NITRILE+PVC 058 100 > 6.00 21. 107
PE 076 100 > 6.00 23. 107
PVC on 100 > 6.00 23. 107
> 6.00 23. 107

Triethanolamine, >7OX
001027163 NATURAL RUBBER 017 100 1.00 < .90 21. .OS 107
NEOPRENE 002 100 > 6.00 < .90 23. 107
018 100 > 6.00 < .90 21. .04 107
NITRILE 019 100 > 6.00 < .90 23. .06 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
PVC 007 100 > 6.00 < .90 21. 107

Triethylllline
001214480 CPE 070 lINlC > 3.00 21. .os 004
NEOPRENE 018 100 .62 811.62 20. .05 323
NITRILE 019 118 > 8.00 < .02 19. .04 323
020 216 > 4.00 21. .04 123
PVC 007 100 .07 290.58 20. .02 323
VITON 009 118 > 8.00 < .02 24. .03 323

TriethyLenetetraaaine
001122430 BUTYL 014 118 > 8.00 < .02 20. .06 323
NEOPRENE 018 100 > 8.00 < .02 19. .05 323
NITRILE 019 100 > 8.00 < .02 16. .04 323
VITON 009 118 > 8.00 < .02 20. .03 323

Trifluoroethanol
000758980 NATURAL RUBBER 017 100 > 1.00 < 4.01 25. .03 222
120 > 1. 10 < 4.01 25. .02 222
502 > 1.33 < 4.01 25. .05 222
504 > 1.07 < 4.01 25. .05 222
> 1.65 < 4.01 25. .06 222
NEOP+NAT RUBBER 026 102 > 1.65 < 4.01 25. .05 222
NEOP/NAT RUBBER 008 114 > 1.02 < 4.01 25. .05 222
NEOPRENE 002 100 > 1.00 < 4.01 25. .08 222
120 > 1.00 < 4.01 25. .07 222
018 118 > 1.00 < 4.01 25. .08 222
120 1.00 < 4.01 25. .05 222
> 1.00 < 4.01 25. .07 222
> 1.00 < 4.01 25. .05 222

A-87
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEtI' THICKNESS REF
CASNO MATERIAL DESC CODE HOURS UG/CM**Z/MIN DEG C CM NUt

000758980 NEOPRENE 018 120 > 1.00 < 4.01 25. .03 222
NITRILE 019 100 .33 1,903.80 25. .04 222
.97 1,102.20 25. .06 222
.28 2,304.60 25. .04 222
503 .12 3,106.20 25. .03 222
PE 006 100 > 1.00 < 4.01 25. .01 222
505 > 1.00 < 4.01 25. .01 222
076 127 > 8.00 < .02 23. 104
PVC 003 120 .os 1,202.40 25. .01 222
.12 1,903.80 25. .01 222
.25 1,302.60 25. .03 222
.11 1,102.20 25. .02 222
500 .04 1,002.00 25. .01 222
501 .07 300.60 25. .01 222
.05 901.80 25. .02 222

Tri·n·propylamine
001026920 NEOPRENE 018 100 > 8.00 23. .05 323
NITRILE 019 100 > 8.00 23. .04 323
PV ALCOHOL 102 100 > 8.00 23. .06 323
VITON 009 118 > 8.00 23. .04 323

Turpentine
OS0066420 NEOP+NAT RUBBER 026 121 .07 264.53 23. .05 237
NITRILE 019 100 .50 < .90 23. .06 107
PV ALCOHOl 004 100 6.00 < •90 23 • 107
TEFLON 069 510 > 3.60 < .02 23. .05 303

valeronltri le
001105980 BUTYL 014 118 > 8.00 < •02 23 • .07 323
NATURAL RUBBER 017 506 .03 126.25 23. .02 323
NEOPRENE 018 100 .68 126.25 23. .05 323
PV ALCOIIOL 004 100 > 8.00 < •02 23 • .07 323

Vinyl Acetate
001080540 TEFLON 069 510 1.23 •05 23 • .05 303
2.28 •05 23 • .05 303

Vinyl Chloride (Chloroethene)


000750140 CPE 070 lINK > 3.00 23. .05 004
NITRILE 019 103 •02 23 • 045
118 5.70 •84" 23 • .04 227
SILVER SHIELD 122 118 > 6.00 23. .01 227
VITON 009 118 4.40 • 58 23 • .04 227

4·Vinyl·1·cyclohexane
001004030 BUTYL 012 118 .52 354.71 23. .07 323
NITRILE 019 100 6.53 1.20 23. .04 323
PV ALCOHOL 004 100 .90 23. .09 323
VITON 009 118 > 8.00 23. .04 323

Vinyl iciene Fluoride


000753870 BUTYL 014 UNK > 8.00 23. .07 323

A-8S
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REf
CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM

000753870 NATURAL RUBBER 001 250 < .02 6.01 23. .02 323
NEOPRENE 018 100 > 5.00 23. .05 323
< .02 .37 23. .05 323
PVC 003 100 < .02 1.80 23. .02 323
VITON 009 118 > 8.00 23. .04 323

Xylene
001332070 NATURAL RUBBER 001 210 .12 444.89 23. 080
017 100 .04 3,406.80 25 • .03 222
120 • 02 5,811.60 25. .02 222
502 .08 3,707.40 25. .05 222
504 .08 2,805.60 25. .05 222
.13 2,404.80 25. .06 222
NEOP+NAT RUBBER 026 102 .07 30.06 23. .06 026
.07 30.06 23. .05 026
NEOP/NAT RUBBER 008 102 .07 30.06 23. 026
114 .12 2,505.00 25. .05 222
NEOPRENE 002 100 .06 501.00 25. .08 222
120 .05 601.20 25. .07 222
210 .13 408.82 23. 080
018 118 .73 701.40 25. .08 222
120 .23 1,302.60 25. .05 222
.30 1,402.80 25. .07 222
.38 801.60 25. .05 222
.09 3,406.80 25. .03 222
031 511 .27 492.98 23. 323
125 103 30.06 23. 045
NITRILE 005 210 1.67 300.60 23. 080
019 100 .80 100.20 25. .04 222
1.25 90.18 • 901.80 23. .06 107
> 1.00 < 50.10 25. .06 222
.95 100.20 25. .04 222
.45 168.34 23. .05 323
103 84.17 23. 045
503 .47 300.60 25. .03 222
NITRILE+PVC 057 210 .75 330.66 23. 080
058 100 > .05 9.02 90.18 23. 107
PE 006 505 .07 100.20 25. .01 222
076 100 .08 9.02 90.18 23. 107
PV ALCOHOL 004 100 > 6.00 < .90 23. 107
102 100 > 8.00 23. .09 323
PVc 003 100 .02 192.38 23. .02 323
120 .03 3,006.00 25. .01 222
.02 3,507.00 25. .01 222
.08 1,703.40 25. .02 222
500 .01 4,509.00 25. .01 222
501 .01 3,507.00 25. .01 222
.03 2,104.20 25. .02 222
007 103 n.14 23. 045
210 .66 389.11 23. 080
TEFLON 069 510 > 3.00 < .02 23. .05 303
VITON 009 118 > 8.00 23. .04 323

A-89
SUMMARY OF PERFORMANCE DETAIL TESTS
PERMEATION TEST

CHEMICAL IIAME/ RESISTANT PRODUCT VEIIDQR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF
CASIIO MATERIAL DESC COOE HOURS UG/CM**2!MIN DEC C CM NUM

..-Xylene
001083830 BUTYl 014 118 _65 87.78 23. .06 323
.17 228.79 23. .05 086
NEOPRENE 018 100 .23 198.55 23. .06 086
NITRILE 019 100 1.03 188.78 23. .04 323
1.62 n.14 23. .06 086
118 .27 396.79 23. .04 086
120 .65 198.73 23. .05 086
020 503 •55 180.36 23 • .04 086
PY ALCOIIOl 102 100 > 12.67 23. .03 323
VITON 009 118 > 16.00 23. .03 323
8.00 23. .04 086

o-Xylene
000954760 BUTYL 014 118 .87 116.63 23. .07 323
CPE 060 113 1.20 23. .05 204
1.05 186.37 23. .05 204
IIITItILE 019 100 .20 179.76 23. .04 323
PV ALCOHOL 102 100 > 12.67 23. .03 323
VITON 009 118 > 8.00 23. .03 323

p-Xylene
001064230 BUTYl 014 118 .45 90.78 23. .07 323
II ITR IlE 019 100 .87 85.97 23. .04 323
PV ALCOtIOL 102 100 > 14.00 23. .03 323
PVC 003 100 < .01 185.17 23. .02 323
YITON 009 118 > 16.00 23. .03 323

A-90
APPENDIX B

WEIGHT CHANGE DATA

B-1
SUMMARY OF PERFORMANCE DETAil TESTS
IMMERSION UEIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM

076644171 PE 041 UNK < .01 8,760.00 23. 305


042 UNK < .01 8,760.00 23. 305
048 UNK < .01 8,760.00 23. 305

Acetic Acid
000641970 CPE 060 113 27.00 24.00 23. .05 204
28.00 24.00 23. .05 204
31.00 24.00 23. .05 204
NATURAL RUBBER 001 UNK '1.00 1.00 25. 208
NEOPRENE 002 UNK 4.00 1.00 25. 208
NITRILE 005 UNK '2.00 1.00 25. 208

Acetic Acid, <30X


000641971 PE 041 UNK .90 8,760.00 23. 305
042 UNK .80 8,760.00 23. 305
048 UNK .80 8,760.00 23. 305

Acetic Acid, 30'70%


0006419n NATURAL RUBBER 001 120 1.00 .50 23. .05 236
< .01 .08 23. .05 236
1.00 1.00 23. .05 236
8.00 4.00 23. .05 236
NEOPRENE 010 120 < .01 .08 23. .06 236
2.00 .50 23. .06 236
< .01 1.00 23. .06 236
2.00 4.00 23. .06 236
NITRILE 005 120 1.00 .08 23. .06 236
3.00 .50 23. .06 236
4.00 1.00 23. .06 236
10.00 4.00 23. .06 236
PVC 003 120 3.00 4.00 23. .08 236
1.00 1.00 23. .08 236
< .01 .50 23. .08 236
1.00 .08 23. .08 236

Acetic Anhydride
001082470 BUTYL 014 118 1.00 8.00 23. .09 323
CPE 060 113 6.10 24.00 23. .05 204
2.70 24.00 23. .05 204
8.20 24.00 23. .05 204
NATURAL RUBBER 001 250 4.00 8.00 20. .02 323
NEOPRENE 018 100 16.00 8.00 20. .05 323
PVC 007 100 -12.00 8.00 20. .02 323

Acetone
000676410 BUTYL 014 UNK .90 24.00 22. 201
CPE 060 113 50.00 .58 23. .05 204
58.00 .25 23. .05 204
64.00 .25 23. .05 204
NATURAL RUBBER 001 120 3.00 .08 23. .05 236
4.00 .50 23. .05 236

B-2
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM

000676410 NATURAL RUBBER 001 120 4.00 1.00 23. .05 236
3.00 4.00 23. .05 236
UNK ·2.00 1.00 25. 208
017 UNK ·2.00 24.00 22. 201
NEOPRENE 002 UNK -3.00 1.00 25. 208
010 120 1.00 •08 23 • .06 236
7.00 .50 23. .06 236
8.00 1.00 23. .06 236
4.00 4.00 23. .06 236
018 UNK -1.40 24.00 22. 201
- .30 24.00 22. 201
-8.00 24.00 22. 201
-.70 24.00 22. 201
NITRILE 005 120 9.00 4.00 23. .06 236
55.00 1.00 23. .06 236
32.00 • 50 23 • .06 236
17.00 .08 23. .06 236
UNK -3.00 1.00 25. 208
020 UNK 2.70 24.00 22. 201
PE 041 UNK 1.00 8,760.00 23. 305
042 UNIC 1.20 8,760.00 23. 305
048 UNK 1.20 8,760.00 23. 305
PV ALCOHOL 102 UNK -15.70 24_00 22. 201
PVC 003 120 2.00 4.00 23. .08 236
29.00 1.00 23. .08 236
30.00 •50 23 • .08 236
14.00 .08 23. .08 236
UNK -16.10 24.00 22. 201

Acetonitrile
000750580 NEOPRENE 010 120 < .01 .08 23. .06 236
1.00 .50 23. .06 236
< .01 1.00 23. .06 236
1.00 4.00 23. .06 236

Allylamine
001071190 BUTYL 014 118 15.00 8.00 20. .06 323
NATURAL RUBBER 001 250 34.00 8.00 20. .01 323
PV ALCOHOL 102 100 14.00 8.00 23. .07 323
PVC 007 100 ·6.00 8.00 20. .02 323

Allyl Glycidyl Ether


001069230 BUTYl 014 UNK 1.00 24.00 22. 201
NATURAL RUBBER 017 UNK 7.00 24.00 22. 201
NEOP/NAT RUBBER 008 UNK 9.40 24.00 22. 201
NEOPRENE 018 UNK 1.40 24.00 22. 201
12.90 24.00 22. 201
·.50 .50 24.00 22. 201
NITRILE 020 UNK 3.20 24.00 22. 201
PV ALCOHOL 102 UNK 5.20 24.00 22. 201
PVC 003 UNK ~ .40 24.00 22. 201

Anmoniun Hydroxide, <3OX

B-3
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS DEG C CM NUM

013362161 NATURAL RUBBER 001 120 1.00 4.00 23. .05 236
1.00 1.00 23. .05 236
< .01 .50 23. .05 236
< .01 . 08 23 • .05 236
NEOPRENE 010 120 1.00 •08 23 • .06 236
< .01 .50 23. .06 236
1.00 1.00 23. .06 236
1.00 4.00 23. .06 236
NITRILE 005 120 2.00 4.00 23. .06 236
2.00 1.00 23. .06 236
1.00 .50 23. .06 236
1.00 .08 23. .06 236
PVC 003 120 < .01 .08 23. .08 236
1.00 •50 23 • .08 236
1.00 1.00 23. .08 236
1.00 4.00 23. .08 236

AnmonilD Hydroxide, 30'7OX


013362162 NATURAL RUBBER 001 UNK '1.00 1.00 25. 208
NEOPRENE 002 UNK < .01 1.00 25. 208
NITRILE 005 UNK < .01 1.00 25. 208

Amyl Acetate (Pentyl Acetate)


006286370 NATURAL RUBBER 001 UNK '2.00 1.00 25. 208
NEOPRENE 002 UNK '4.00 1.00 25. 208
NITRILE 005 UNK ·1.00 1.00 25. 208

Amyl Alcohol (Pentanol)


000714100 BUTYL 014 118 .40 8.00 23. .07 323
NEOPRENE 018 100 4.00 8.00 23. .05 323
NITRILE 019 100 9.00 8.00 23. .04 323
YITON 009 118 4.00 8.00 23. .05 323

Ani line (Benzamine)


000625330 NATURAL RUBBER 001 120 2.00 •50 23 • .05 236
3.00 1.00 23. .05 236
5.00 4.00 23. .OS 236
2.00 .08 23. .05 236
NEOPRENE 010 120 9.00 4.00 23. .06 236
5.00 1.00 23. .06 236
4.00 .50 23. .06 236
5.00 .08 23. .06 236
NITRILE 005 120 38.00 1.00 23. .06 236
126.00 4.00 23. .06 236
24.00 .50 23. .06 236
15.00 .08 23. .06 236
PVC 003 120 4.00 .08 23. .08 236
12.00 1.00 23. .08 236
20.00 4.00 23. .08 236
10.00 .50 23. .08 236

Benzene
000714320 BUTYL 014 118 117.00 168.00 23. 327

B-4
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CAS NO MATERIAL DESC CODE HOURS DEG C CM NUM

000714320 BUTYL 034 UNK 60.00 168.00 22. 078


12.00 3.00 25. 126
064 UNIC 55.50 168.00 23. 327
EVA 074 100 254.00 168.00 23. 327
NATURAL RUBBER 017 100 309.00 168.00 23. 327
310.00 168.00 23. 327
214 286.00 168.00 23. 327
508 320.00 168.00 22. 078
UNK 362.00 168.00 23. 327
351.00 168.00 23. 327
346.00 168.00 23. 327
NEOP/NAT RUBBER 008 114 280.00 168.00 22. 078
NEOPRENE 018 100 262.00 168.00 23. 327
120 190.00 168.00 23. 327
UNIC 176.00 168.00 23. 327
031 UNIC 90.00 168.00 22. 078
NITRILE 019 100 161.00 168.00 23. 327
120 150.00 168.00 23. 327
166 165.00 168.00 23. 327
020 UNIC 104.00 168.00 23. 327
104.00 168.00 23. 327
033 UNIC 110.00 168.00 22. 078
NONWOVEN PE 071 100 218.00 168.00 23. 327
UNIC 162.00 168.00 23. 327
PE 006 209 30.00 168.00 22. 078
042 100 32.70 168.00 23. 327
113.00 168.00 23. 327
075 100 257.00 168.00 23. 327
POLYURETHANE 050 178 60.00 168.00 22. 078
PV ALCOHOL 004 100 3.00 168.00 22. 078
PVC 003 100 ·15.10 168.00 23. 327
120 '8.00 168.00 23. 327
'12.40 168.00 23. 327
·8.10 168.00 23. 327
214 .• 50 168.00 23. 327
SARANEX 061 200 93.00 168.00 23. 327
TEFLON 036 214 4.90 168.00 23. 327
VITON 009 118 20.00 168.00 23. 327
032 UNIC 4.00 1.68.00 22. 078

Boric Acid
100433530 BUTYL 014 118 2.00 8.00 20. .07 323
NEOPRENE 018 100 2.00 8.00 19. .05 323
NITRILE 019 100 2.00 8.00 21. .04 323
VITON 009 118 .20 8.00 20. .03 323

2· Bromoethanol
005405120 BUTYL 014 118 .20 8.00 23. .09 323
NATURAL RUBBER 001 250 2.00 8.00 23. .02 323
PVC 003 100 •• 20 8.00 23. .02 323
VITON 009 118 .60 8.00 23. .05 323

Butyl Acetate
B-5
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION ~EIGHT CHANGE TEST

CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT ~IGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM

001238640 PE 041 UNK 3.40 8,760.00 23. 305


042 UNK 3.40 8,760.00 23. 305
048 UNK 4.10 8,760.00 23. 305

Butylamine
001097390 BUTYL 014 118 62.00 8.00 15. .10 323
NATURAL RUBBER 001 250 148.00 8.00 20. .02 323
NEOPRENE 018 100 166.00 8.00 18. .05 323
PVC 007 100 62.00 8.00 18. .02 323

iso'Butylamine (Methylpropylamine, 2·)


000788190 BUTYL 014 118 37.00 8.00 28. .09 323
NEOPRENE 018 100 50.00 8.00 26. .05 323
PV ALCOHOL 102 100 '8.00 8.00 23. .07 323
PVC 007 100 13.00 8.00 28. .02 323

sec'Butylamine
139528460 BUTYL 014 118 83.00 8.00 21. .09 323
NEOPRENE 018 100 122.00 8.00 25. .05 323
NITRILE 019 100 108.00 8.00 14. .04 323
PVC 007 100 ·4.00 8.00 24. .02 323

tert'Butylamine
000756490 BUTYL 014 118 23.00 8.00 15. .09 323
NEOPRENE 018 100 55.00 8.00 23. .05 323
NITRILE 019 100 69.00 8.00 21. .04 323
PVC 007 100 ·20.00 8.00 20. .02 323

n'Butyl Chloride (Chlorobutane,1·)


001096930 NITRILE 019 100 100.00 8.00 23. .05 323
PV ALCOHOL 004 100 '5.00 8.00 23. .80 323
PVC 003 100 '11.00 8.00 23. .20 323
VITON 009 118 6.00 8.00 23. .05 323

Butyraldehyde
001237280 BUTYL 034 UNK 7.70 3.00 25. 126
12.50 20.00 25. 126

Carbon Disulfide (Carbon Bisulfide)


000751500 BUTYL 034 UNK 74.00 3.00 25. 126
NITRILE 005 120 7.00 4.00 23. .06 236
21.00 1.00 23. .06 236
16.00 .50 23. .06 236
8.00 . 08 23 • .06 236
PE 041 UNK 12.90 8,760.00 23. 305
042 UNK 21.40 8,760.00 23. 305
048 UNK 36.80 8,760.00 23. 305

Carbon Tetrachloride (Tetrachloromethane)


000562350 CPE 060 113 107.00 1.83 23. .05 204
116.00 1.83 23. .05 204
106.00 1.83 23. .05 204
NEOPRENE 010 120 38.00 1.00 23. .06 236

B-6
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM

000562350 NEOPRENE 010 120 28.00 .50 23. .06 236


13.00 .08 23. .06 236
18.00 4.00 23. .06 236
NITRILE 005 120 21.00 4.00 23. .06 236
11.00 1.00 23. .06 236
5.00 .50 23. .06 236
3.00 .08 23. .06 236
PE 041 UNK 16.30 8,760.00 23. 305
042 UNK 22.80 8,760.00 23. 305
048 UNK 37.90 8,760.00 23. 305

Chlorobenzene
001089070 BUTYL 014 118 169.00 8.00 23. .07 323
PV ALCOHOL 102 100 ·4.00 8.00 23. .08 323
PVC 007 100 101.00 8.00 23. .02 323
VITON 009 118 2.00 8.00 23. .03 323

Chlorodibromomethane
001244810 BUTYL 012 118 382.00 8.00 23. .10 323
PV ALCOHOL 004 100 ·.30 8.00 23. .07 323
PVC 003 100 385.00 8.00 23. .02 323
VITON 009 118 1.00 8.00 23. .04 323

Chloroform (Trichloromethane)
000676630 BUTYL 034 UNK 9.00 3.00 25. 126
NEOPRENE 010 120 23.00 .08 23. .06 236
39.00 .50 23. .06 236
110.00 1.00 23. .06 236
35.00 4.00 23. .06 236
PE 041 UNK 12.00 8,760.00 23. 305
042 UNK 16.20 8,760.00 23. 305
048 UNK 25.10 8,760.00 23. 305

3·Chloro·2·methylpropene
005634730 BUTYL 014 118 142.00 8.00 23. .06 323
PV ALCOHOL 004 100 28.00 8.00 23. .04 323
PVC 007 100 2.00 8.00 23. .02 323
VIT ON 009 118 7.00 8.00 23. .03 323

2· Chloro·2·ni tropropane
005947180 BUTYL 012 118 2.00 8.00 23. .09 323
NATURAL RUBBER 017 506 94.00 8.00 23. .02 323
PV ALCOHOL 004 100 '.80 8.00 23. .07 323
VITON 009 118 70.00 8.00 23. .04 323

Chromic Acid, 30·70X


111157452 NITRILE 005 120 < .01 .08 23. .06 236
4.00 .50 23. .06 236
3.00 1.00 23. .06 236
4.00 4.00 23. .06 236
PVC 003 121' 18.00 4.00 23. .08 236
1.00 1.00 23. .08 236
< .01 .50 23. .08 236

B-7
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAME! RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS DEG C eM MUM

111157452 PVC 003 120 < .01 .08 23. .08 236

Citric Acid, <lOX


000779291 PE 041 UNK < .01 8,760.00 23. 305
042 UNK < .01 8,760.00 23. 305
048 UNK < .01 8,760.00 23. 305

Cyclohexylamine
001089180 BUTYL 014 118 95.00 8.00 20. .06 323
NATURAL RUBBER 001 250 299.00 8.00 20. .02 323
NEOPRENE 018 100 294.00 8.00 22. .05 323
NITRILE 019 100 247.00 8.00 24. .04 323

Diall yamine
001240270 BUTYL 014 118 44.00 8.00 21. .09 323
PV ALCOHOL 004 100 '20.00 8.00 23. .08 323
PVC 007 100 '26.00 8.00 22. .02 323
VITON 009 118 4.00 8.00 19. .03 323

1,3'Oiaminopropane
001097620 BUTYL 014 118 30.00 8.00 22. .06 323
NATURAL RUBBER 001 250 18.00 8.00 25. .02 323
NEOPRENE 018 100 22.00 8.00 23. .05 323
PVC 007 100 24.00 8.00 21. .02 323

Oi ·n·amylami ne
020509220 NEOPRENE 018 100 74.00 8.00 16. .OS 323
NITRILE 019 100 2.00 8.00 20. .04 323
PVC 007 100 '23.00 8.00 13. .02 323
VITON 009 118 .20 8.00 16. .03 323

Oichloroacetyl Chloride
000793670 BUTYL 014 118 164.00 8.00 23. .09 323
PV ALCOHOL 102 100 '8.00 8.00 23. .07 323
PVC 003 100 230.00 8.00 23. .02 323
VITON 009 118 '9.00 8.00 23. .03 323

Oichlorobromomethane
000752740 BUTYL 014 118 347.00 8.00 23. .07 323
PVC 007 100 328.00 8.00 23. .02 323
VITON 009 118 2.00 8.00 23. .03 323
VITON!BUTYL 100 102 '2.00 8.00 23. .08 323

1,4·Oichloro·2·butene
001105760 BUTYL 034 UNIC 19.00 20.00 25. 126
17.00 3.00 25. 126

cis'Oichloroethylene
001565920 BUTYL 014 118 198.00 8.00 23. .07 323
PV ALCOHOL 004 100 358.00 8.00 23. .05 323
VITON 009 118 9.00 8.00 23. .03 323

l,2'Oichloroethylene
B-8
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENOOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HooRS DEG C eM NUM

005405900 NITRILE 019 100 265.00 8.00 29. .04 323


PV ALCOHOL 004 100 '29.00 8.00 23. .04 323
PVC 007 100 .50 8.00 23. .02 323
VITON 009 118 9.00 8.00 23. .03 323

trans' 1,2'Oichloroethylene
001566050 BUTYL 014 118 3.00 8.00 23. .06 323
PV ALCOHOL 004 100 '30.00 8.00 23. .09 323
PVC 007 100 '7.00 8.00 23. .02 323
VITON 009 118 8.00 8.00 23. .03 323

2,2"Oichloroethyl Ether
001114440 BUTYL 034 UNK 11.00 20.00 25. 126
3.80 3.00 25. 126
CPE 060 113 129.00 .83 23. .05 204
125.00 .83 23. .05 204
123.00 •83 23 • .05 204

2,3·Oichloro·1·propene
000788860 BUTYL 014 118 66.00 8.00 23. .09 323
PV ALCOHOL 102 100 2.00 8.00 23. .09 323
PVC 007 100 76.00 8.00 23. .02 323
VITON 009 118 4.00 8.00 23. .03 323

1,3-0ichloropropene
005427560 BUTYL 014 118 65.00 8.00 23. .07 323
PV ALCOHOL 102 100 '2.00 8.00 23. .07 323
PVC 007 100 199.00 8.00 23. .02 323
VITON 009 118 3.00 8.00 23. .03 323

Oiethanolamine
001114220 BUTYL 014 118 2.00 8.00 24. .09 323
NEOPRENE 018 100 5.00 8.00 22. .05 323
NITRILE 019 100 14.00 8.00 26. .04 323
VITON 009 118 3.00 8.00 27. .03 323

Diethylamine
001098970 BUTYL 014 118 88.00 8.00 23. .09 323
NITRILE 019 100 55.00 8.00 24. .04 323
PVC 001 100 '26.00 8.00 24. .02 323
VITON 009 118 83.00 8.00 20. .03 323

Diethylaminoethanol
001003780 BUTYL 014 118 2.00 8.00 22. .07 323
NITRILE 019 118 12.00 8.00 22. .04 323
PV ALCOHOL 102 100 '19.00 8.00 23. .09 323
VITON 009 118 5.00 8.00 22. .03 323

Diethylenetriamine
001114000 BUTYL 014 118 8.00 8.00 24. .08 323
NEOPRENE 018 100 12.00 8.00 22. .05 323
PVC 007 100 19.00 8.00 22. .02 323
VIT ON 009 118 8.00 8.00 23. .03 323

B-9
SUMMARY OF PERFORMANCE DETAil TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HooRS DEG C CM NlI4

Oiisobutylamine
001109630 NEOPRENE 018 100 57.00 8.00 22. .05 323
NITRilE 019 100 -1.00 8.00 20. .04 323
PV ALCOHOL 102 100 4.00 8_00 23. .08 323
VITON 009 118 -2.00 8.00 22. .02 323

Oiisopropylamine
001081890 NEOPRENE 018 100 51.00 8.00 12. .05 323
NITRilE 019 100 6.00 8.00 10. .04 323
PVC 007 100 -23.00 8.00 11. .02 323
VITON 009 118 1.00 8.00 12. .03 323

N,N-Oimethylacetamide
001271950 NATURAL RUBBER 001 120 18.00 4.00 23. .05 236
15.00 1.00 23. .05 236
21.00 .50 23. .05 236
32.00 •OS 23 • .05 236
NEOPRENE 010 120 36.00 4.00 23. .06 236
12.00 1.00 23. .06 236
12.00 .50 23. .06 236
5.00 •08 23 • .06 236
005 _OS 23 _
NITRILE 120 18.00 .06 236
53.00 • 50 23 • .06 236
21.00 1.00 23. .06 236
186.00 4.00 23. .06 236

oimethyl ami ne
001244030 BUTYL 014 118 .80 8.00 22. .06 323
NATURAL RUBBER 001 250 10.00 8.00 20. .02 323
NEOPRENE 018 100 12.00 8.00 22. .05 323
PV ALCOHOL 102 100 '6.00 8.00 23. .07 323
PVC 007 100 3.00 8_00 20. .02 323

oimethyl ami nopropyl amine


001095570 BUTYl 014 118 22.00 8.00 16. .09 323
NATURAL RUBBER 001 250 114.00 8.00 16. .02 323
NEOPRENE 018 100 184.00 8.00 ZO. .OS 323
PVC on 100 126.00 8.00 20. .02 323

oimethyl butylamine
001080980 BUTYL 014 118 67.00 8.00 24. .06 323
NITRilE 019 100 76.00 8.00 19. .04 323
PV ALCOHOL 102 100 ·22.00 8.00 23. .08 323
PVC 007 100 -3.00 8.00 21. .02 323

Dimethylethanolamine
001080100 BUTYl 014 118 .80 8.00 12. .09 323
NATURAL RUBBER 001 250 17.00 8.00 19. .02 323
NEOPRENE 018 100 57.00 8.00 21. .05 323
;iTRILE 019 100 34.00 8.00 9. .04 323

Oimethylformamide
B-IO
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS OEG C CM NUM

000681220 NATURAL RUBBER 001 120 1.00 .08 23. .05 236
2.00 . 50 23 . .05 236
4.00 1.00 23. .05 236
4.00 4.00 23. .05 236
NEOPRENE 010 120 2.00 .08 23. .06 236
7.00 •50 23 . .06 236
9.00 1.00 23. .06 236
9.00 4.00 23. .06 236

1.1·Oimethylhydrazine (Dimethylhydrazine.unsym·)
000571470 BUTn 034 UNK 10.00 168.00 22. 078
NEOPRENE 031 UNK 30.00 168.00 22. 078
NITRILE 033 UNK 38.00 168.00 22. 078
PVC 077 168 35.00 168.00 22. 078

Dimethyl Sulfoxide
000676850 NA ruRAL RUBBER 001 120 2.00 4.00 23. .05 236
2.00 .08 23. .05 236
2.00 .50 23. .05 236
3.00 1.00 . 23. .05 236
NEOPRENE 010 120 1.00 .08 23. .06 236
1.00 .50 23. .06 236
1.00 1.00 23. .06 236
3.00 4.00 23. .06 236
NITRilE 005 120 39.00 4.00 23. .06 236
19.00 1.00 23. .06 236
9.00 .50 23. .06 236
4.00 .08 23. .06 236
PVC 003 120 14.00 4.00 23. .08 236
12.00 1.00 23. .08 236
9.00 .50 23. .08 236
8.00 .08 23. .08 236

Oimethylvinylchloride
005133710 NITRILE 019 100 100.00 8.00 23. .05 323
PV ALCOHOL 004 100 '10.00 8.00 23. .08 323
PVC 003 100 '23.00 8.00 23. .02 323
VIT ON 009 118 8.00 8.00 23. .04 323

Dipropylamine
001428470 BUTYL 034 UNK 61.00 3.00 25. 126
POLYCARBONATE 098 UNK .. 10 3.00 25. 126

Epi ch l orohydr i n
001068980 BUTYL 014 118 3.00 24.00 23. .04 291
1.00 8.00 23. .07 323
1.00 8.00 23. .07 323
034 UNIC 5.00 168.00 22. 078
NATURAL RUBBER 001 250 13.00 8.00 23. .02 323
13.00 8.00 23. .02 323
017 UNK 30.00 24.00 23. .02 291
NEOPRENE 018 100 100.00 24.00 23. .04 291
031 UNK 44.00 168.00 22. 078

B-ll
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAME I RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEC C CM NUH

001068980 . NITRILE 020 503 340.00 24.00 23. .04 291


033 UN!: 28.00 168.00 22. 078
PE 006 100 < •01 24.00 23 • .01 291
209 12.00 168.00 22. 078
POLYURETHANE 050 178 270.00 168.00 22. 078
PV ALCOHOL 035 UN!: < 1.00 168.00 22. 078
102 100 ·7.00 24.00 23. .05 291
·3.00 8.00 23. .07 323
'3.00 8.00 23. .07 323
PVC 077 168 103.00 168.00 22. 078
TEFLON 036 214 < • 01 24.00 23 • .01 291
VIT ON 009 118 20.00 24.00 23. .02 291
16.00 8.00 23. .03 323
16.00 8.00 23. .03 323
032 UNK 42.00 168.00 22. 078

1,2'Epoxybutane
001068870 BUTYL 014 118 50.00 8.00 23. .06 323
NEOPRENE 018 100 150.00 8.00 23. .05 323
PV ALCOHOL 004 100 ·3.00 8.00 23. .04 323
VITON 009 118 94.00 8.00 23. .03 323

Ethanol, 30· 70%


000641752 PE 041 UNK • 10 8,760.00 23 • 305
042 UN!: .10 8,760.00 23. 305
048 UN!: . 10 8,760.00 23 • 305

Ethanol, >70%
000641753 PE 041 UNK .20 8,760.00 23. 305
042 UNK .20 8,760.00 23. 305
048 UNK < .01 8,760.00 23. 3C5

Ethanolamine (Aminoethanol,2)
001414350 BUTYL 014 118 2.00 8.00 26. .07 323
NEOPRENE 018 100 7.00 8.00 20. .05 323
PVC 007 100 12.00 8.00 25. .02 323
VITON 009 118 6.00 8.00 22. .05 323

2·Ethoxyethyl Acetate (Cellosolve Acetate)


001111590 NATURAL RUBBER 001 120 12.00 4.00 23. .05 236
11.00 1.00 23. .05 236
6.00 .50 23. .05 236
5.00 .08 23. .05 236
NEOPRENE 010 120 17.00 4.00 23. .06 236
12.00 1.00 23. .06 236
4.00 .50 23. .06 236
3.00 .08 23. .06 236
NITRILE 005 120 10.00 .08 23. .06 236
16.00 .50 23. .06 236
23.00 1.00 23. .06 236
36.00 4.00 23. .06 236

Ethyl Acetate

B-12
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION UEIGHT CHANGE TEST

CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS OEG C CM NUM

001417860 NEOPRENE 010 120 11.00 4.00 23. .06 236


16.00 1.00 23. .06 236
13.00 .50 23. .06 236
3.00 .08 23. .06 236
PE 041 UNIC 2.50 8,760.00 23. 305
042 UNIC 2.50 8,760.00 23. 305
048 UNK 2.80 8,760.00 23. 305

Ethyl Cellosolve (Ethoxyethanol, 2)


001108050 BUTYL 014 118 • 70 8.00 23 . .08 323
NATURAL RUBBER 001 250 17.00 8.00 23. .02 323
PV ALCOHOL 102 100 ·19.00 8.00 23. .08 323
PVC 007 100 17.00 8.00 23. .02 323

Ethyl Acrylate
001408850 250 250 67.00 8.00 23. .02 323
BUTYl 014 118 13.00 8.00 23. .09 323
PV ALCOHOL 102 100 '9.00 8.00 23. .08 323
PVC 003 100 74.00 8.00 23. .02 323

Ethyl Alcohol (Ethanol)


000641750 NATURAL RUBBER 001 120 1.00 •08 23 . .05 236
< .01 .50 23. .05 236
1.00 1.00 23. .05 236
1.00 4.00 23. .05 236
NEOPRENE 010 120 1.00 4.00 23. .06 236
< .01 1.00 23. .06 236
< .01 •50 23 • .06 236
< • 01 .08 23 • .06 236
NITRILE 005 120 2.00 . 08 23 . .06 236
4.00 4.00 23. .06 236
8.00 1.00 23. .06 236
3.00 .50 23. .06 236
PVC 003 120 1.00 •08 23 . .08 236
< .01 . 50 23 . .08 236
1.00 1.00 23. .08 236
1.00 4.00 23. .08 236

Ethyl Benzene
001004140 PV ALCOHOL 102 100 .40 8.00 23. .08 323

Ethyl Bromide
000749640 NEOPRENE 018 100 231.00 8.00 23. .04 323
PV ALCOHOL 102 100 ·14.00 8.00 23. .08 323
PVC 003 100 132.00 8.00 23. .02 323
VITON 009 118 13.00 8.00 23. .04 323

Ethyl·n·butylamine
133606390 NITRILE 019 100 36.00 8.00 24. .04 323
PV ALCOHOL 102 100 '24.00 8.00 23. .09 323
PVC 007 100 -31.00 8.00 24. .02 323
VITON 009 118 17.00 8.00 23. .03 323

B-13
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION ~EIGHT CHANGE TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM MUM

Ethylene Chlorohydrin (Chloroethanol)


001070730 BUTYL 014 118 .10 8.00 23. .06 323
NEOPRENE 018 100 6.00 8.00 23. .05 323
PV ALCOHOL 102 100 -7.00 8.00 23. .09 323
VITON 009 118 .60 8.00 23. .05 323

Ethylenediamine (Diaminoethane,1,2)
001071530 BUTYL 014 118 2.00 8.00 18. .07 323
CPE 060 113 ·5.00 24.00 23. .05 204
13.00 24.00 23. .05 204
·6.40 24.00 23. .05 204
NATURAL RUBBER 001 250 9.00 8.00 20. .01 323
NEOPRENE 018 100 9.00 8.00 18. .05 323
PVC 007 100 .80 8.00 16. .02 323

Ethylene Dibromide (Dibromoethane,1,2)


001069340 BUTYL 014 118 65.00 24.00 23. .04 291
59.00 8.00 23. .07 323
NATURAL RUBBER 017 UNK 480.00 24.00 23. .02 291
NEOPRENE 018 100 500.00 24.00 23. .04 291
NITRILE 020 503 580.00 24.00 23. .04 291
PE 006 100 20.00 24.00 23. .01 291
PV ALCOHOl 102 100 4.00 24.00 23. .05 291
•80 8.00 23 • .08 323
PVC 007 100 258.00 8.00 23. .02 323
TEFLON 036 214 2.00 24.00 23. .01 291
VITON 009 118 3.00 24.00 23. .02 291
2.00 8.00 23. .03 323

Ethylene Dichloride (Dichloroethane, 1,2)


001070620 BUTYL 014 118 36.00 8.00 23. .06 323
UNit 34.00 24.00 23. 326
34.00 168.00 23. 326
064 UUIt 24.00 24.00 23. 326
27.00 168.00 23. 326
NATURAL RUBBER 001 250 213.00 8.00 23. .02 323
017 UIIIC 226.00 168.00 23. 326
211.00 24.00 23. 326
NEOPRENE 018 UNit 190.00 168.00 23. 326
182.00 24.00 23. 326
NITRILE 019 UNIC 655.00 24.00 23. 326
> 1,000.00 168.00 23. 326
020 UNit 440.00 168.00 23. 326
340.00 24.00 23. 326
PE 041 UNit 5.00 8,760.00 23. 305
042 UNit 16.00 168.00 23. 326
.20 24.00 23. 326
5.40 8,760.00 23. 305
048 UNK 6.90 8,760.00 23. 305
076 UNK 74.00 24.00 23. 326
100.00 168.00 23. 326
POLYURETHANE 050 UNK 26.00 24.00 23. 326

B-14
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION UEIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT UEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS OEG C CM NUM

001070620 POLYURETHANE 050 UNK 86.00 168.00 23. 326


PV ALCOHOL 004 100 .40 8.00 23. .03 323
102 UNK .30 24.00 23. 326
.40 168.00 23. 326
PVC on UNK 265.00 168.00 23. 326
251.00 24.00 23. 326
TEFLON 036 UNK 1.00 168.00 23. 326
.20 24.00 23. 326
VITON 009 118 5.00 8.00 23. .03 323
UNK 6.00 168.00 23. 326
6.00 24.00 23. 326

Ethylene Glycol
0010nl10 NATURAL RUBBER 001 120 1.00 .50 23. .05 236
1.00 .08 23. .05 236
2.00 1.00 23. .05 236
< .01 4.00 23. .05 236
NEOPRENE 010 120 18.00 4.00 23. .06 236
< .01 1.00 23. .06 236
6.00 .50 23. .06 236
< .01 .08 23. .06 236
NITRILE 005 120 2.00 4.00 23. .06 236
1.00 1.00 23. .06 236
1.00 .50 23. .06 236
1.00 .08 23. .06 236
PE 041 UNIC < .01 8,760.00 23. 305
042 UNIC < .01 8,760.00 23. 305
048 UNIC < .01 8,760.00 23. 305
PVC 003 120 3.00 4.00 23. .08 236
2.00 1.00 23. .08 236
", 8.00 .50 23. .08 236
< .01 .08 23. .08 236

Ethylenimine (Azi ridine)


001515640 BUTYL 034 UNIC 14.00 168.00 22. 078
NATURAL RUBBER 017 508 15.00 168.00 22. 078

2·Ethyl·I·Hexanol
001047670 BUTYL 014 118 4.00 8.cio 23. .07 323
NEOPRENE 018 100 3.00 8.00 23. .05 323
PV ALCOHOL 102 100 '.30 8.00 23. .09 323
VITON 009 118 3.00 8.00 23. .03 323

Ethylidene Dichloride (Dichloroethane,I,I)


000753430 BUTYL 012 118 66.00 8.00 23. .09 323
PV ALCOHOL 004 100 ·5.00 8.00 23. .08 323
PVC 003 100 65.00 8.00 23. .02 323
3.00 8.00 23. .02 323
VITON 009 118 12.00 8.00 23. .04 323

Ethyl Methacrylate
000976320 BUTYL 014 118 33.00 8.00 23. .09 323
NITRILE 019 100 109.00 8.00 23. .05 323

B-15
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL OESC COOE HOURS OEG C CM NUM

000976320 PV ALCOHOL 102 100 '4.00 8.00 23. .06 323


PVC 003 100 115.00 8.00 23. .02 323

Formaldehyde, <37% (Formal in)


000500000 NATURAL RUBBER 001 120 2.00 4.00 23. .05 236
1.00 1.00 23. .05 236
1.00 •50 23 . .05 236
< .01 .08 23. .05 236
NEOPRENE 010 120 2.00 .08 23. .06 236
2.00 . 50 23 . .06 236
2.00 1.00 23. .06 236
1.00 4.00 23. .06 236
NITRILE 005 120 2.00 1.00 23. .06 236
2.00 •50 23 • .06 236
1.00 .08 23. .06 236
2.00 4.00 23. .06 236
PE 048 UNIC • 10 8,760.00 23 • 305
PVC 003 120 < .01 •50 23 • .08 236
17.00 .08 23. .08 236
1.00 1.00 23. .08 236
2.00 4.00 23. .08 236

Freon TF
000761310 NEOPRENE 010 120 4.00 4.00 23. .06 236
1.00 1.00 23. .06 236
< .01 .08 23. .06 236
1.00 •50 23 • .06 236
NITRILE 005 120 1.00 4.00 23. .06 236
1.00 1.00 23. .06 236
< .01 .50 23. .06 236
1.00 .08 23. .06 236

Furan (Furfuran)
001100090 BUTYL 014 118 46.00 8.00 23. .09 323
PV ALCOHOL 102 100 '22.00 8.00 23. .09 323
PVC 003 100 '49.00 8.00 23. .02 323
VITON 009 118 17.00 8.00 23. .05 323

Gasoline
080066190 NEOPRENE 010 120 2.00 •08 23 • .06 236
8.00 .50 23. .06 236
7.00 1.00 23. .06 236
9.00 4.00 23. .06 236
NITRILE 005 120 1.00 .08 23. .06 236
2.00 .50 23. .06 236
2.00 1.00 23. .06 236
4.00 4.00 23. .06 236
PE 041 UNIC 6.70 8,760.00 23. 305
042 UNIC 8.80 8,760.00 23. 305
048 UNIC 13.50 8,760.00 23. 305

Glutaraldehyde
001113080 BUTYL 014 118 1.00 6.00 23. .09 323

B-16
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION ~IGHT CHANGE TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM

001113080 NEOPRENE 018 100 4.00 8.00 23. .05 323


PVC 003 100 7.00 8.00 23. .02 323
VITON 009 118 4.00 8.00 23. .04 323

Halothane
001516nO BUTYL 014 118 210.00 8.00 23. .09 323
PV ALCOHOL 102 100 ·22.00 8.00 23. .07 323
PVC 007 100 ·35.00 8.00 23. .02 323
VIT ON 009 118 81.00 8.00 23. .05 323

Heptane
001428250 PE 041 UNK .70 8,760.00 23. 305
042 UNK 6.90 8,760.00 23. 305
048 UNK 10.00 8,760.00 23. 305

Hexachlorocyclopentadiene
000n4740 BUTYL 014 118 26.00 8.00 23. .06 323
NITRILE 019 100 19.00 8.00 23. .04 323
PV ALCOHOL 102 100 2.00 8.00 23. .08 323
VITON 009 118 2.00 8.00 23. .03 323

Hexamethylphosphoamide
006803190 BUTYl 034 UNK 8.00 168.00 22. 078
NEOPRENE 031 UNK 272.00 168.00 22. 078
NITRILE 033 UNK 78.00 168.00 22. 078
PE 006 209 22.00 168.00 22. 078
POLYURETHANE 050 178 242.00 168.00 22. 078
VITON 032 UNK 250.00 168.00 22. 078

Hexane
001105430 NEOPRENE 010 120 4.00 4.00 23. .06 236
28.00 1.00 23. .06 236
1.00 .50 23. .06 236
1.00 .08 23. .06 236
NITRILE 005 120 1.00 .08 23. .06 236
< .01 .50 23. .06 236
< .01 1.00 23. .06 236
1.00 4.00 23. .06 236

Hydrochloric Acid
076470100 BUTYL 034 UNK 11.00 20.00 25. 126
.90 3.00 25. 126
POLYCARBONATE 098 UNK < .01 3.00 25. 126
< .01 20.00 25. 126

Hydrochloric Acid, <30X


076470101 PE 041 UNK < .01 8,760.00 23. 305
042 UNK < .01 8,760.00 23. 305
048 UNK ·.20 8,760.00 23. 305

Hydrochloric Acid, 30·7OX


076470102 NATURAL RUBBER 001 120 1.00 .08 23. .05 236
2.00 .50 23. .05 236

B-17
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NIJ4

076470102 NATURAL RUBBER 001 120 3.00 1.00 23. .05 236
5.00 4.00 23. .OS 236
NEOPRENE 010 120 1.00 .08 23. .06 236
1.00 .50 23. .06 236
1.00 1.00 23. .06 236
2.00 4.00 23. .06 236
NITRILE 005 120 1.00 .08 23. .06 236
2.00 .50 23. .06 236
2.00 1.00 23. .06 236
3.00 4.00 23. .06 236
PVC 003 120 < .01 .08 23. .08 236
1.00 .50 23. .08 236
1.00 1.00 23. .08 236
2.00 4.00 23. .08 236

Hydrofluoric Acid (Hydrogen Fluoride)


076643930 BUTYL 034 UN" 123.00 3.00 25. 126
POLYCARBONATE 098 UN" .30 3.00 25. 126
1.00 20.00 25. 126

Hydrofluoric Acid, 30·70%


076643932 NATURAL RUBBER 001 120 < .01 4.00 23. .OS 236
< .01 1.00 23. .05 236
1.00 .50 23. .05 236
1.00 .08 23. .05 236
NEOPRENE 010 120 2.00 .08 23. .06 236
4.00 .50 23. .06 236
4.00 1.00 23. .06 236
8.00 4.00 23. .06 236
NITRILE OOS 120 2.00 .08 23. .06 236
6.00 .50 23. .06 236
7.00 1.00 23. .06 236
11.00 4.00 23. .06 236
PVC 003 120 1.00 .08 23. .08 236
2.00 .50 23. .08 236
2.00 1.00 23. .08 236
2.00 4.00 23. .08 236

Hydrogen Peroxide, 30·70%


Om28412 PE 041 UN" < .01 8,760.00 23. 30S
042 UN" .10 8,760.00 23. 30S
048 UN" < •01 8,760.00 23 • 305

Iminobispropylamine
000561880 BUTYL 014 118 4.00 8.00 28. .09 323
NATURAL RUBBER 001 250 21.00 8.00 26. .02 323
NEOPRENE 018 100 24.00 8.00 27. .os 323
VITON 009 118 3.00 8.00 27. .04 323

Isobutyl Acrylate
001066380 BUTYL 014 118 16.00 8.00 23. .09 323
NITRILE 019 100 103.00 8.00 23. .05 323
PV ALCOHOL 102 100 ·2.00 8.00 23. .08 323

B-18
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION ~IGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME fEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS OEG C CM NUM

001066380 PVC 003 100 94.00 8.00 23. .02 323

Isobutyl Alcohol
000788310 BUTYL 014 118 •06 8.00 23 . .07 323
NEOPRENE 018 100 ·3.00 8.00 23. .05 323
NITRILE 019 118 7.00 8.00 23. .05 323
VIT ON 009 118 .02 8.00 23. .05 323

Isobutyl Nitrite
005425630 BUTYL 014 118 81.00 8.00 23. .04 323
NITRILE 019 100 38.00 8.00 23. .06 323
PVC 003 100 ·31.00 8.00 23. .02 323
VITON 009 118 50.00 8.00 23. .04 323

Isopropyl Alcohol (Propanol, 2·)


000676300 CPE 060 113 3.10 24.00 23. .05 204
3.70 24.00 23. .05 204
3.50 24.00 23. .05 204
NATURAL RUBBER 001 120 1.00 •OS 23 • .05 236
1.00 •50 23 • .05 236
1.00 1.00 23. .05 236
1.00 4.00 23. .05 236
NEOPRENE 010 120 < .01 .08 23. .06 236
1.00 •50 23 • .06 236
< .01 1,00 23. .06 236
< .01 4.00 23. .06 236
NITRILE 005 120 2.00 4.00 23. .06 236
2.00 1.00 23. .06 236
2.00 •50 23 • .06 236
1.00 •OS 23 • .06 236
PVC 003 120 < .01 4.00 23. .08 236
< .01 1.00 23. .08 236
1.00 • 50 23 • .08 236
< .01 •08 23 • .OS 236

Isopropyl8llline
000753100 BUTYL 014 118 28.00 8.00 24. .09 323
NEOPRENE 018 100 60.00 8.00 21. .05 323
PVC 007 100 ·18.00 8.00 18. .02 323
VITON 009 118 67.00 8.00 26. .04 323

Isopropylmethacrylate
046553490 BUTYL 014 118 36.00 8.00 23. .09 323
NITRILE 019 100 69.00 8.00 23. .05 323
PV ALCOHOL 102 100 ·3.00 8.00 23. .09 323
PVC 003 100 63.00 8.00 23. .02 323

Kerosene
OS0082060 NEOPRENE OlD 120 1.00 •OS 23 . .06 236
1.00 .50 23. • (V, 236
1.00 1.00 23. .06 236
3.00 4.00 23. .06 236
NITRILE DOS 120 1.00 .OS 23. .06 236

B-19
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAME/ RESISTANT PRooUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CooE HClJRS DEG C CM NUM

080082060 NITRILE 005 120 1.00 •50 23 . .06 236


1.00 1.00 23. .06 236
2.00 4.00 23. .06 236

Methacryloni tri le
001269870 BUTYL 014 118 ·1.00 8.00 23. .09 323
NATURAL RUBBER 001 250 7.00 8.00 23. .02 323
PV ALCOHOL 102 100 -6.00 8.00 23. .06 323
PVC 003 100 10.00 8.00 23. .02 323

Methanol (Methyl Alcohol)


000675610 NATURAL RlIBBER 001 120 1.00 .08 23. .05 236
2.00 1.00 23. .05 236
2.00 4.00 23. .05 236
1.00 .50 23. .05 236
NEOPRENE 010 120 < .01 •08 23 • .06 236
< .01 .50 23. .06 236
1.00 1.00 23. .06 236
1.00 4.00 23. .06 236
NITRILE ODS 120 7.00 4.00 23. .06 236
6.00 1.00 23. .06 236
3.00 .50 23. .06 236
3.00 .08 23. .06 236

Methanol, <3OX
000675611 PE 041 UNK .10 8,760.00 23. 305
042 UNK < .01 8,760.00 23. 305
048 UII1C < •01 8,760.00 23 • 305

Nethanol, >701
000675613 PE 041 UNK .10 8,760.00 23. 305
042 UNK .10 8,760.00 23. 305
048 UNK < .01 8,760.00 23. 305

Methyl Acetate
000792090 BUTYL 014 118 1.00 8.00 23. .09 323
NATURAL RUBBER 001 250 ·20.00 8.00 23. .02 323
PV ALCOHOl t02 tOO ·25.00 8.00 23. .07 323
PVC 003 100 t2.00 8.00 23. .02 323

Methyl Acrylate
000963330 BUTYL 014 118 5.00 8.00 23. .09 323
NATURAL RUBBER 001 250 54.00 8.00 23. .02 323
NEOPRENE 018 100 50.00 8.00 23. .05 323
PV ALCOHOL 102 100 -4.00 8.00 23. .07 323

3· Methyl aminopropyl a.i ne


062918450 BUTYL Ot4 118 5.00 8.00 20. .07 323
NATURAL RUBBER 001 250 30.00 8.00 16. .02 323
NEOPRENE 018 100 70.00 8.00 16. .05 323
PVC 007 tOO 45.00 8.00 14. .02 323

Methyl Chlorofonm (Trichloroethane,1,t,1)

B-20
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION ~IGHT CHANGE TEST

CHEMICAL NAME! RESISTANT PROOUCT VENDOR PERCENT ~IGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM

0.0.0.715560. BUTYL 0.14 UN!:: 80..0.0. 168.0.0. 25. 326


80..0.0. 24.0.0. 25. 326
5.50. 24.0.0. 22. 20.1
064 UN!:: 47.0.0. 24.0.0. 25. 326
49.0.0. 168.0.0. 25. 326
NATURAL RUBBER 0.17 UN!:: 464.0.0. 24.0.0. 25. 326
.30. 24.0.0. 22. 20.1
473.0.0. 168.0.0. 25. 326
NEOP/NAT RUBBER 0.08 UN!:: ·.30. .30. 24.0.0. 22. 20.1
NEOPRENE 0.10. 120. 21.0.0. .0.8 23. .0.6 236
78.0.0. .50. 23. .0.6 236
86.0.0. 1.0.0. 23. .0.6 236
92.0.0. 4.00. 23. .0.6 236
0.18 UN!:: 291.0.0. 168.0.0. 25. 326
290.0.0. 24.0.0. 25. 326
15.50. 24.0.0. 22. 20.1
·.50. . .50. 24.0.0. 22 • 20.1
2.80 24.0.0. 22. 20.1
NITRILE 0.0.5 120. 36.0.0. 4.0.0. 23. .06 236
82.00 1.0.0. 23. .06 236
62.00 .50. 23. .0.6 236
25.00 .08 23. .06 236
0.19 UN!:: > 1,0.0.0..00 24.0.0. 25. 326
0.20. UN!:: 2.50. 24.00 22. 20.1
PE 042 UN!:: 16.00 168.0.0. 25. 326
5.00 24.0.0. 25. 326
0.76 UN!:: 131.00 24.0.0. 25. 326
147.0.0. 168.0.0. 25. 326
POLYURETHANE 0.50. UN!:: 58.0.0. 24.0.0. 25. 326
7'9.0.0. 168.0.0. 25. 326
PV ALCOHOL 10.2 UN!:: .80 24.0.0. 25. 326
6.90 24.0.0. 22. 201
.90 168.0.0. 25. 326
PVC 00.3 UNIC '2.50 24.0.0. 22. 20.1
0.77 UN!:: 227.0.0. 24.0.0 25. 326
273.0.0. 168.0.0. 25. 326
TEFLON 0.36 UN!:: .30. 24.0.0. 25. 326
.40. 168.0.0. 25. 326
VITON 0.09 UN!:: 4.00 24.00 25. 326
5.00 168.0.0. 25. 326

Methyl Chloroformate
0.0.0.7'92210. BUTYL 0.34 UN!:: 13.0.0. 20.0.0. 25. 126
11.0.0. 3.0.0. 25. 126

Methylene Chloride (Dichloromethane)


0.0.0.750920. NATURAL RUBBER 0.0.1 UNIC ·3.00. 1.00. 25. 20.8
NEOPRENE 0.0.2 UN!:: ·3.00 1.0.0. 25. 20.8
010. 120. 17.0.0. .0.8 23. .06 236
25.0.0. .50. 23. .0.6 236
20..0.0. 1.0.0. 23. .06 236
4.0.0. 4.0.0. 23. .0.6 236
NITRilE DDS UNIC ·3.0.0. 1.0.0. 25. 20.8

13-21
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C eM NUM

n-Methylethanolamine
001098310 BUTYL 014 118 2.00 8.00 19. .07 323
CELLULOSE ACETATE 099 118 9.00 8.00 20. .03 323
NATURAL RUBBER 001 250 8.00 8.00 20. .02 323
NEOPRENE 018 100 4.00 8.00 20. .06 323

Methyl Ethyl Ketone (Butanone,2)


000789330 BUTYL 014 118 6.00 8.00 23. .06 323
NATURAL RUBBER 001 120 10.00 .50 23. .05 236
6.00 4.00 23. .05 236
8.00 •08 23 • .05 236
12.00 1.00 23. .05 236
250 37.00 8.00 23. .01 323
UNK -2.00 1.00 25. 20B
NEOPRENE 002 UNK ·3.00 1.00 25. 20B
010 120 8.00 4.00 23. .06 236
16.00 1.00 23. .06 236
14.00 .50 23. .06 236
5.00 .08 23. .06 236
018 100 88.00 8.00 23. .05 323
NITRILE 005 UNK ·2.00 1.00 25. 208
PV ALCOHOL 102 100 ·14.00 8.00 23. .07 323

Methylhydrazine
000603440 BUTYL 034 UNK 6.70 20.00 25. 126
3.40 3.00 25. 126

Methyl Iodide
000748840 BUTYL 014 118 2OB.00 8.00 23. .09 323
NEOPRENE 018 100 511.00 8.00 23. .05 323
PV ALCOHOL 102 100 ·18.00 8.00 23. .07 323
VITON 009 118 4.00 8.00 23. .04 323

Methyl Isocyanate
006248390 BUTYL 014 118 32.00 8.00 13. .06 323
32.00 8.00 23. .07 323
NATURAL RUBBER 001 250 49.00 8.00 20. .02 323
49.00 8.00 23. .01 323
NEOPRENE 018 100 90.00 8.00 20. .05 323
PV ALCOHOL 004 100 6.00 8.00 23. .03 323
VITON 009 118 74.00 8.00 21. .03 323
74.00 8.00 23. .03 323

Methyl Methacrylate
00OB06260 BUTYL 014 118 23.00 8.00 23. .09 323
NATURAL RUBBER 001 250 112.00 8.00 23. .02 323
PV ALCOHOL 102 100 ·7.00 8.00 23. .06 323
PVC 003 100 102.00 8.00 23. .02 323

Monoisopropanolamine
000789660 BUTYL 014 118 2.00 8.00 25. .07 323
NEOPRENE 018 100 6.00 8.00 24. .05 323

B-22
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAME I RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS OEG C CM NUM

000789660 PVC 007 100 6.00 8.00 25. .02 323


VITON 009 118 7.00 8.00 25. .04 323

Nitric Acid, >70%


076973n3 NATURAL RUBBER DOl 120 6.00 .50 23. .05 236
3.00 .08 23. .05 236
8.00 1.00 23. .05 236
12.00 4.00 23. .05 236
NEOPRENE 010 120 1.00 .08 23. .06 236
2.00 .50 23. .06 236
3.00 1.00 23. .06 236
7.00 4.00 23. .06 236
NITRILE 005 120 9.00 .08 23. .06 236
17.00 .50 23. .06 236
20.00 1.00 23. .06 236
34.00 4.00 23. .06 236
PE 041 UNK 1.40 8,760.00 23. 305
042 UNIC 1.90 8,760.00 23. 305
048 UNIC 4.80 8,760.00 23. 305
4.80 8,760.00 23. 305
PVC 003 120 2.00 .08 23. .08 236
3.00 •50 23 . .08 236
4.00 1.00 23. .08 236
5.00 4.00 23. .08 236

Nit robenzene
000989530 BUTYL 034 UNK 15.00 20.00 25. 126
4.20 3.00 25. 126

Nitroethane
000792430 BUTYL 014 118 •30 8.00 23 • .09 323
NATURAL RUBBER 001 250 2.00 8.00 23. .02 323
NEOPRENE 018 100 23.00 8.00 23. .04 323
PV ALCOHOL 102 100 ·1.00 8.00 23. .07 323

Nitromethane
000755250 BUTYL 014 118 ·.50 8.00 23. .09 323
NATURAL RUBBER 001 250 ·4.00 8.00 23. .02 323
NEOPRENE 018 100 4.00 ·8.00 23. .05 323
PV ALCOHOL 102 100 ·2.00 8.00 23. .07 323

Nitropropane
253220140 BUTYL 034 UNK 2.00 168.00 22. 078
NEOPRENE 031 UNK 23.00 168.00 22. 078
NITRILE 033 UNK n.oo 168.00 22. 078
PE 006 209 7.00 168.00 22. 078
POLYURETHANE 050 178 99.00 168.00 22. 078
PV ALCOHOL 035 UNIC < 1.00 168.00 22. 078
PVC 077 168 42.00 168.00 22. 078
VITON 032 UNK 107.00 168.00 22. 078

2-Nitropropane
000794690 BUTYL 014 118 -.50 8.00 23. .08 323

B-23
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HOURS DEG C CM NUN

000794690 NATURAL RUBBER 001 250 18.00 8.00 23. .02 323
NEOPRENE 018 100 53.00 8.00 23. .04 323
PV ALCOHOL 102 100 '2.00 8.00 23. .06 323

n-Nitrosodimethylamine
000551850 CPE 060 113 115.00 .83 23. .05 204
112.00 .83 23. .05 204
109.00 .33 23. .05 204

o-Nitrotoluene
000SSn20 BUTYL 034 UNK 15.20 20.00 25. 126
9.90 3.00 25. 126

p-Nitrotoluene
000999900 BUTYL 034 lINK .10 3.00 25. 126
.20 20.00 25. 126
POLYCARBOIIATE 098 UNK .20 3.00 25. 126
2.00 20.00 25. 126

Oleic Acid
001128010 PE 041 UNIC 1.40 8,760.00 23. 305
042 UNIC 1.70 8,760.00 23. 305
048 lINK 2.40 8,760.00 23. 305

Oxalic Acid
001446270 BUTYl 014 118 1.00 8.00 19. .07 323
NEOPRENE 018 100 3.00 8.00 19. .05 323
NITRILE 019 100 2.00 8.00 19. .04 323
VITOII 009 118 .90 8.00 20. .03 323

Phenol (Carbolic Acid)


001089520 CPE 060 113 9.10 24.00 23. .05 204
68.00 24.00 23. .05 204
25.00 24.00 23. .05 204
NATURAL RUBBER 001 120 12.00 4.00 23. .05 236
2.00 1.00 23~ .05 236
3.00 .50 23. .05 236
2.00 .08 23. .05 236
NEOPRENE 010 120 5.00 4.00 23. .06 236
1.00 1.00 23. .06 236
2.00 .50 23. .06 236
2.00 .08 23. .06 236

Phenol, <3OX
001089521 PE 041 UNK .20 8,760.00 23. 305
042 lINK .10 8,760.00 23. 305
048 UNIC .20 8,760.00 23. 305

Phenyl Glycidyl Ether


001226010 BUTYL 014 UNK .40 24.00 22. 201
NATURAl RUBlER 017 UNIC 6.00 24.00 22. 201
NEOP/NAT RUBBER 008 UNIC 30.00 24.00 22. 201
NEOPRENE 018 UNIC 37.70 24.00 22. 201

B-24
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HOURS OEG C CM NUM

001226010 NEOPRENE 018 UNK 23.00 24.00 22. 201


33.10 24.00 22. 201
NITRILE 020 UNK 103.50 24.00 22. 201
PV ALCOHOL 102 UNK 3.80 24.00 22. 201
PVC 003 UNK 41.40 24.00 22. 201

Phosphoric Acid, >70%


076643823 NATURAL RUBBER 001 120 3.00 4.00 23. .05 236
3.00 1.00 23. .05 236
2.00 .50 23. .05 236
1.00 .08 23. .05 236
NEOPRENE 010 120 < .01 .08 23. .06 236
< •01 .50 23 • .06 236
< .01 1.00 23. .06 236
< • 01 4.00 23 • .06 236
NITRILE 005 120 < .01 .08 23. .06 236
1.00 .50 23. .06 236
4.00 1.00 23. .06 236
5.00 4.00 23. .06 236
PVC 003 120 1.00 .08 23. .08 236
2.00 .50 23. .08 236
2.00 1.00 23. .08 236
2.00 4.00 23. .08 236

Potassium Hydroxide, 30·70%


013105832 NATURAL RUBBER 001 120 2.00 4.00 23. .05 236
2.00 1.00 23. .05 236
2.00 .50 23. .05 236
1.00 .01 .08 23. .05 236
NEOPRENE 010 120 < .01 4.00 23. .06 236
< .01 1.00 23. .06 236
< .01 .50 23. .06 236
< .01 .08 23. .06 236
NITRILE 005 120 1.00 .08 23. .06 236
1.00 .50 23. .06 236
1.00 1.00 23. .06 236
< .01 4.00 23. .06 236
PVC 003 120 1.00 4.00 23. .08 236
< .01 1.00 23. .08 236
1.00 .50 23. .08 236
1.00 .08 23. .08 236

beta'Propiolactone
000575780 BUTYL 034 UNIC 1.00 168.00 22. 078
NATURAL RUBBER 017 508 9.00 168.00 22. 078
NEOPRENE 031 UNIC 31.00 168.00 22. 078
NITRILE 033 UNIC 29.00 168.00 22. 078
PE 006 209 18.00 168.00 22. 078
POLYURETHANE 050 178 185.00 168.00 22. 078
PVC 077 168 15.00 168.00 22. 078
VITON 032 UNIC 69.00 168.00 22. 078

n'Propylamine

B-25
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL OESC CODE HOURS OEG C eM NUM

001071080 BUTYL 034 UNK 17.00 20.00 25. 126


14.00 3.00 25. 126

Propylenedi ami ne
000789000 BUTYL 014 118 ·3.00 8.00 17. .07 323
NEOPRENE 018 100 1.00 8.00 24. .05 323
PVC 007 100 5.00 8.00 17. .02 323
VITON 009 118 8.00 8.00 25. .02 323

Propylene Dichloride COichloropropane 1,2)


000788750 BUTYL 014 118 70.00 8.00 23. .08 323
PV ALCOHOL 102 100 ·2.00 8.00 23. .07 323
PVC 007 100 105.00 8.00 23. .02 323
VITON 009 118 7.00 8.00 23. .03 323

l,3'Propylene Oxide
005033000 BUTYL 014 118 21.00 8.00 23. .07 323
NATURAL RUBBER 001 250 58.00 8.00 23. .02 323
PV ALCOHOL 004 100 ·9.00 8.00 23. .03 323
VITON 009 118 94.00 8.00 23. .03 323

Propyl.ethacrylate
022102880 BUTYL 014 118 38.00 8.00 23. .08 323
NITRILE 019 100 152.00 8.00 23. .04 323
PV ALCOHOL 004 100 .• 60 8.00 23. .07 323
PVC 003 100 106.00 8.00 23. .02 323

SodiUII Hydroxide, <3OX


013107321 PE 041 UtIle .10 8,760.00 23. 305
.10 8,760.00 23. 305
042 UtlIC < .01 8,760.00 23. 305
< .01 8,760.00 23. 305
048 UNIC < .01 8,760.00 23. 30S
.10 8,760.00 23. 305

Sodhlll Hydroxide, 30·m


013107322 NATURAL RUBBER 001 120 2.00 4.00 23. .05 236
1.00 1.00 23. .05 236
2.00 .50 23. .OS 236
2.00 .08 23. .05 236
UtlIC -1.00 1.00 25. 208
NEOPRENE 002 UNIe -1.00 1.00 25. 208
010 120 2.00 4.00 23. .06 236
4.00 1.00 23. .06 236
3.00 .50 23. .06 236
1.00 .08 23. .06 236
NITRILE 005 120 2.00 .08 23. .06 236
7.00 .50 23. .06 236
3.00 1.00 23. .06 236
3.00 4.00 23. .06 236
lINlC 1.00 1.00 25. 208
PVC 003 120 8.00 .08 23. .08 236
6.00 .50 23. .08 236

B-26
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HooRS DEG C CM NUM

013107322 PVC 003 120 7.00 1.00 23. .08 236


3.00 4.00 23. .08 236

Sul furic Acid, <30%


076649391 PE 041 UNK .10 8,760.00 23. 305
042 UNK < .01 8,760.00 23. 305
048 UNK < .01 8,760.00 23. 305

Sulfuric Acid, 30·7OX


076649392 NATURAL RUBBER 001 120 2.00 4.00 23. .05 236
1.00 1.00 23. .05 236
2.00 .50 23. .05 236
1.00 .08 23. .05 236
NEOPRENE 010 120 2.00 .08 23. .06 236
3.00 .50 23. .06 236
1.00 1.00 23. .06 236
1. DO 4.00 23. .06 236
NITRILE 005 120 1.00 .08 23. .06 236
2.00 .50 23. .06 236
< .01 1.00 23. .06 236
1.00 4.00 23. .06 236
PE 041 UNK < .01 8,760.00 23. 305
042 UNK < .01 8,760.00 23. 305
048 UNK < .01 8,760.00 23. 305
PVC 003 120 1.00 .08 23. .08 236
< .01 .50 23. .08 236
1.00 1.00 23. .08 236
1.00 4.00 23. .08 236

Tannic Acid, >70%


014015543 NATURAL RUBBER 001 UNK 10.00 1.00 25. 208
NEOPRENE 002 UNK 7.00 1.00 25. 208
NITRILE 005 UNK 56.00 1.00 25. 208

1,1,1,2·Tetrachloroethane
006302060 BUTYL 014 118 128.00 8.00 23. .07 323
PV ALCOHOL 102 100 ·3.00 8.00 23. .08 323
PVC 007 100 83.00 8.00 23. .02 323
VIT ON 009 118 2.00 8.00 23. .03 323

1,1,2,2·Tetrachloroethane
000793450 BUTYL 014 118 167.00 8.00 23. .07 323
PV ALCOHOL 004 100 .10 8.00 23. .04 323
PVC 007 100 247.00 8.00 23. .02 323
VITON 009 118 .80 8.00 23. .03 323

Tetrachloroethylene (Perchloroethylene)
001271840 BUTYL 014 118 510.00 24.00 23. .04 291
NATURAL RUBBER 017 UNK no.oo 24.00 23. .02 291
NEOPRENE 018 100 360.00 24.00 23. .04 291
NITRILE 005 120 8.00 .08 23. .06 236
11.00 .50 23. .06 236
11.00 1.00 23. .06 236

B-27
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAME/ RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HooRS DEG C CM NUM

001271840 NITRILE 005 120 22.00 4.00 23. .06 236


020 191 95.00 24.00 23. .04 291
PE 006 100 15.00 24.00 23. .01 291
PV ALCOHOL 102 100 '6.00 24.00 23. .05 291
TEFLON 036 214 < .01 24.00 23. .01 291
VITON 009 118 4.00 24.00 23. .02 291

Tetraethyl enepentami ne
001125720 BUTYL 012 118 3.00 8.00 25. .09 323
NATURAL RUBBER 017 506 17.00 8.00 28. .02 323
NEOPRENE 018 100 11.00 8.00 27. .05 323
VITON 009 118 3.00 8.00 23. .04 323

N,N,N',N"Tetramethylenediamine
001101890 BUTYL 012 118 156.00 8.00 20. .07 323
014 118 156.00 8.00 23. .07 323
NITRILE 019 100 37.00 8.00 23. .05 323
37.00 8.00 24. .05 323
PVC 003 100 3.00 8.00 23. .02 323
VITON 009 118 31.00 8.00 23. .04 323
31.00 8.00 24. .04 323

Toluene
001088830 BUTYL 014 UNIC 2~00 24.00 22. 201
IIAJURAL RUBBER 001 UNIC '2.00 1.00 25. 208
017 UNK •04 24.00 22 • 201
IIEOP/NAT RUBBER 008 UNK •• 04 24.00 22. 201
NEOPRENE 002 UNIC '3.00 1.00 25. 208
018 UNIC .50 24.00 22. 201
'.50 . •50 24.00 22 • 201
.80 24.00 22. 201
NITRILE 005 120 25.00 1.00 23. .06 236
33.00 .50 23. .06 236
17.00 .08 23. .06 236
27.00 4.00 23. .06 236
UNIC '1.00 1.00 25. 208
020 UNIC 2.50 24.00 22. 201
PE 041 UNIC 7.50 8,760.00 23. 305
042 UNIC 9.80 8,760.00 23. 305
048 UNIC 15.10 8,760.00 23. 305
PV ALCOHOL 102 UNIC 10.50 24.00 22. 201
PVC 003 UNIC '29.00 24.00 22. 201

Toluene Diisocyanate
264716250 NATURAL RUBBER 001 120 25.00 4.00 23. .05 236
15.00 1.00 23. .05 236
9.00 •50 23 • .05 236
4.00 • 08 23 • .05 236
PVC 003 120 32.00 4.00 23. .08 236
26.00 1.00 23. .08 236
14.00 .50 23. .08 236
6.00 .08 23. .08 236

B-28
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HOURS DEG C CM NUM

Triallylamine
001027050 NEOPRENE 018 100 31.00 8.00 19. .05 323
NITRILE 019 100 4.00 8.00 22. .04 323
PVC 007 100 ·20.00 8.00 20. .02 323
VIT ON 009 118 1.00 8.00 17. .03 323

Trichloroacetaldehyde ·(Chloral)
000758760 BUTYL 014 118 105.00 8.00 23. .07 323
PV ALCOHOL 102 100 '.30 8.00 23. .08 323
PVC 007 100 125.00 8.00 23. .02 323
VITON 009 118 19.00 8.00 23. .03 323

1, 1, 2'Trichloroethane
000790050 BUTYL 014 118 so.oo 8.00 23. .09 323
UNIC SO.OO 24.00 23. 326
SO.OO 168.00 23. 326
064 UNIC 49.00 168.00 23. 326
47.00 24.00 23. 326
NATURAL RUBBER 001 UNIC '2.00 1.00 25. 208
017 UNIC 473.00 168.00 23. 326
464.00 24.00 23. 326
NEOPRENE 002 UNIC '3.00 1.00 25. 208
018 UNIC 290.00 24.00 23. 326
291.00 168.00 23. 326
NITRILE 005 UNIC ·3.00 1.00 25. 208
019 UNIC > 1, 000.00 168.00 23. 326
> 1,000.00 24.00 23. 326
PE 042 UNIC 5.00 24.00 23. 326
16.00 168.00 23. 326
076 UNIC 131.00 24.00 23. 326
147.00 168.00 23. 326
POLYURETHANE 050 UNIC 7'9.00 168.00 23. 326
58.00 24.00 23. 326
PV ALCOHOL 102 100 '2.00 8.00 23. .07 323
UNIC .SO 24.00 23. 326
.90 168.00 23. 326
PVC 003 118 238.00 8.00 23. .02 323
on UNIC 227.00 24.00 23. 326
273.00 168.00 23. 326
TEFLON 036 UNIC .40 168.00 23. 326
.30 24.00 23. 326
VITON 009 118 3.00 8.00 23. .05 323
UNIC 5.00 168.00 23. 326
4.00 24.00 23. 326

Trichloroethylene (Trichloroethene)
000790160 BUTn 014 118 440.00 24.00 23. .04 291
034 UNIC 148.00 168.00 22. 078
NATURAL RUBBER 001 UNIC '3.00 1.00 25. 208
017 UNIC 700.00 24.00 23. .02 291
NEOPRENE 002 UNIC '3.00 1.00 25. 208
018 100 .400.00 24.00 23. .04 291

B-29
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION WEIGHT CHANGE TEST

CHEMICAL NAME I RESISTANT PROOUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC COOE HooRS DEG C CM NUM

000790160 NEOPRENE 031 UNK 118.00 168.00 22. 078


NITRILE 005 120 29.00 4.00 23. .06 236
51.00 1.00 23. .06 236
58.00 .50 23. .06 236
40.00 .08 23. .06 236
UNK -'.00 1.00 25. 208
020 503 310.00 24.00 23. .04 291
033 UNK 217.00 168.00 22. 078
PE 006 100 20.00 24.00 23. .01 291
209 6.00 168.00 22. 078
POLYURETHANE 050 178 115.00 168.00 22. 078
PV ALCOHOL 035 UNK 3.00 168.00 22. 078
102 100 -2.00 24.00 23. .05 291
PVC 077 168 14.00 168.00 22. 078
TEFLON 036 214 < .01 24_00 23. .01 291
VITON 009 118 8.00 24.00 23. .02 291
032 UNIC 2.00 168.00 22. 078

1,2,3'Trichloropropane
000961840 BUTYL 014 118 19.00 8.00 23. .06 323
NITRILE 019 100 182.00 8.00 23. .04 323
PV ALCOHOL 004 100 4_00 8.00 23. .03 323
VITON 009 118 .50 8.00 23. .03 323

Tricresyl Phosphate (Tritolyl Phosphate)


013307850 BUTYL 012 118 1.00 8.00 23. .07 323
PVC 003 100 .40 8.00 23. .02 323
VITON 009 118 2.00 8.00 23. .04 323

Triethylamine
001214480 NEOPRENE 018 100 70.00 8.00 20. .05 323
NITRILE 019 118 6.20 8.00 19. .04 323
PVC 007 100 '28.00 8.00 20. .02 323
VITON 009 118 2.00 8.00 24. .03 323

Triethylenetetraamine
001122430 BUTYL 014 118 3.00 8.00 20. .06 323
NEOPRENE 018 100 6.00 8.00 19. .05 323
NITRILE 019 100 23.00 8.00 16. .04 323
VITON 009 118 6.00 8.00 20. .03 323

Tri-n'propylamine
001026920 NEOPRENE 018 100 15.00 8.00 23. .05 323
NITRILE 019 100 .70 8.00 23. .04 323
PV ALCOHOL 102 100 -14.00 8.00 23. .06 323
VITON 009 118 '1.00 8.00 23. .04 323

Turpentine
080066420 NEOPRENE 010 120 1.00 .08 23. .06 236
3.00 .50 23. .06 236
4.00 1.00 23. .06 236
10.00 4.00 23. .06 236
NITRILE 005 120 < .01 .08 23. .06 236

B-30
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION ~EIGHT CHANGE TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT ~IGHT CHANGE IMMERSION TIM, -EMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM HUM

080066420 NITRILE 005 120 1.00 . 50 23 • .06 236


1.00 1.00 23. .06 236
1.00 4.00 23. .06 236
PE 041 UNIC 7.20 8,760.00 23. 305
042 UNIC 9.10 8,760.00 23. 305
048 UNIC 14.50 8,760.00 23. 305

Valeroni tri le
001105980 BUTYL 014 118 .70 8.00 23. .07 323
NATURAL RUBBER 017 506 32.00 8.00 23. .02 323
NEOPRENE 018 100 58.00 8.00 23. .05 323
PV ALCOHOL 004 100 ·4.00 8.00 23. .07 323

4·Vinyl·l·cyclohexane
001004030 BUTYL 012 118 102.00 8.00 23. .07 323
NITRILE 019 100 21.00 B.OO 23. .04 323
PV ALCOHOL 004 100 ·1.00 8.00 23. .09 323
VITON 009 118 .60 8.00 23. .04 323

Xylene
001332070 NITRILE 005 1Z0 10.00 .08 23. .06 236
19.00 .50 23. .06 236
27.00 1.00 23. .06 236
35.00 4.00 23. .06 236
019 100 82.00 8.00 23. .05 323
PE 041 UNIC 7.90 8,760.00 23. 305
042 UIIIC 10.30 8,760.00 23. 305
048 UIIIC 15.40 8,760.00 23. 305
PV ALCOHOL 102 100 ·4.00 8.00 23. .09 323
PVC 003 100 ·7.00 8.00 23. .02 323
VITON 009 118 1.00 8.00 23. .04 323

o·Xylene
000954760 CPE 060 113 116.00 .60 23. .05 204
112.00 .60 23. .05 204
109.00 .73 23. .05 204

B-31
AP·PENDIX C

SWELLING DATA

C-I
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION SWELLING TEST

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR SWELL (PERCENT VOLUME) IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM

Benzene
000714320 BUTYL 014 UNK 124.00 24.00 23. 327
064 UNK 82.00 24.00 23. 327
NATURAL RUBBER 017 UNK 377.00 24.00 23. 327
383.00 24.00 23. 327
NEOPRENE 018 UNK 284.00 24.00 23. 327
NITR.IlE 019 UNK 182.00 24.00 23. 327
NONIoIOVEN PE 071 UNK 166.00 24.00 23. 327
PE 042 UNK 37.00 24.00 23. 327
076 UNa: 14.00 24.00 23. 327
PVC 003 UNK '18.00 24.00 23. 327
SARANEX 061 UNK 71.00 24.00 23. 327
TEFLON 036 UNa: 6.40 24.00 23. 327
VITOH 009 UNK 18.00 24.00 23. 327
Dibutylamine
001119220 NITRILE 019 100 28.00 8.00 24. .04 323
PV ALCOHOL 102 100 ·26.00 8.00 23. .08 323
PVC 007 100 '26.00 8.00 20. .02 323
VITOH 009 118 .40 8.00 20. .03 323
Eptchlorohydrin
001068980 BUTYL 014 118 < .01 24.00 23. .04 291
. NATURAL RUBBER 017 UNK 30.00 24.00 23. .02 291
NEOPRENE 018 100 120.00 24.00 23. .04 291
NITRILE 020 503 240.00 24.00 23. .04 291
PE 006 100 15.00 24.00 23. .01 291
PV ALCOHOL 102 100 ·7.00 24.00 23. .05 291
TEFLON 036 214 < .01 24.00 23. .01 291
VITON 009 118 35.00 24.00 23. .02 291
Ethylene Dibromide ...(O"tbromoethane,1 ,2)
001069340 BUTYL 014 118 30.00 24.00 23. .04 291
NA ruRAL RUBBER 017 UNK 240.00 24.00 23. .02 291
NEOPRENE 018 100 > 1,000.00 24.00 23. .04 291
NITRILE· 020 503 230.00 24.00 23. .04 291
PE 006 100 35.00 24:00 23. .01 291
PV ALCOHOL 102 100 .< .01 24.00 23. .05 291
TEFLON 036 214 < .01 24.00 23. .01 291
VIT ON 009 118 < .01 24.00 23. .02 291
Ethylene Dichloride (Dichloroethane,1,2)
001070620 BUTYL 014 UNK 19.00 24.00 23. 326
19.00 4.00 23. 326
19.00 1.00 23. 326
064 UNa: 25.00 24.00 23. 326
25.00 4.00 23. 326
25.00 1.00 23. 326
NATURAL RUBBER 017 UNK 118.00 1.00 23. 326
124.00 24.00 23. 326
118.00 4.00 23. 326
NEOPRENE 018 UNK 141.00 4.00 23. 326

C-2
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION SYELLING TEST

CHEMICAL NAMEI RESISTANT PRCl)tJCT VENDOR SYELL (PERCENT VOLUME) IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC talE HooRS DEG C 04 NUM
001070620 NEOPRENE 018 UNIC . 142.00 24.00 23. 326
123.00 1.00 23. 326
NITRILE 019 UNIC 275.00 4.00 23. 326
286.00 24.00 23. 326
259.00 1.00 23. 326
020 UNIC 252.00 1.00 23. 326
254.00 24.00 23. 326
252.00 4.00 23. 326
PE 042 UNIC 8.00 1.00 23. 326
20.00 24.00 23. 326
20.00 4.00 23. 326
076 UNIC 4.30 1.00 23. 326
9.00 4.00 23. 326
9.00 24.00 23. 326
POlYURETHANE 050 UNIC < • 01 24.00 23 • 326
1.50 4.00 23. 326
•30 1.00 23 • 326
PV ALCOHOL 102 UNIC .30 1.00 23. 326
1.50 4.00 23. 326
1.00 24.00 23. 326
PVC 077 UNIC > 1,000.00 1.00 23. 326
TEFLON 036 UNIC < • 01 24.00 23 • 326
< .01 1.00 23. 326
< •01 4.00 23 • 326
VITON 009 UNIC 9.00 4.00 23. 326
< •01 1.00 23 • 326
11.00 24.00 23. 326
Methyl Chloroform (Trlchloroethane,1,1,'>
000715560 BUTYL 014 UNIC 249.00 1.00 25. 326
260.00 4.00 25. 326
263.00 24.00 25. 326
064 UNIC 11.00 1.00 25. 326
153.00 4.00 25. 326
1S1.00 24.00 25. 326
NATURAL RUBBER 017 UNIC 334.00 1.00 25. 326
429.00 4.00 25. 326
425.00 24.00 25. 326
NEOPRENE 018 UNIC . 213.00 1.00 25 • 326
239.00 4.00 25. 326
246.00 24.00 25. 326
NITRILE 019 UNIC 182.00 1.00 25. 326
208.00 4.00 25. 326
214.00 24.00 25. 326
PE 042 UNIC 9.60 1.00 25. 326
9.60 4.00 25. 326
9.60 24.00 25. 326
076 UNIC ·5.00 1.00 25. 326
13.30 4.00 25. 326
12.30 24.00 25. 326
POLYURETHANE 050 UNIC 14.30 1.00 25. 326
15.70 4.00 25. 326
13.70 24.00 25. 326
C-3
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION SWELLING TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR SWELL (PERCENT VOLUME) IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOORS DEG C CM NUM

000715560 PV ALCOHOL 102 UNK < •01 1.00 25 • 326


3.00 4.00 25. 326
4.00 24.00 25. 326
PVC 077 UNK < .01 1.00 25. 326
< .01 4.00 25. 326
22.00 24.00 25. 326
TEFLON 036 UNK < .01 1.00 25. 326
< •01 4.00 25 • 326
< .01 24.00 25. 326
VITON 009 UNK < .01 1.00 25. 326
8.60 4.00 25. 326
20.50 24.00 25. 326

Polychlorinated Biphenyls (PCBs) (Aroclor)


013363630 BUTYL 014 118 14.00 24.00 23. 290
NATURAL RUBBER 017 UNK 200.00 24.00 23. 290
NEOPRENE 018 100 10.00 24.00 23. 290
PE 006 100 35.00 24.00 23. 290
PV ALCOHOL 102 100 4.00 24.00 23. 290

Tetrachloroethylene (Perchloroethylene)
001271840 BUTYL 014 118 280.00 24.00 23. .04 291
NATURAL RUBBER 017 UNK 530.00 24.00 23. .02 291
NEOPRENE 018 100 320.00 24.00 23. .04 .2~
NITRILE 020 191 60.00 24.00 23. .04 29.
PE 006 100 85.00 24.00 23. .01 291
PV ALCOHOL 102 100 '12.00 24.00 23. .05 291
TEFLON 036 214 < .01 24.00 23. .01 291
VITON 009 118 < .01 24.00 23. .02 291
1,1,2'Trlchloroethane
000790050 BUTYL 014 UNIC '1.00 24.00 23. 326
10.00 1.00 23. 326
7.00 4.00 23. 326
064 UNK 44.00 24.00 23. 326
44.00 4.00 23. 326
42.00 1.00 23. 326
NATURAL RUBBER 017 UNK 146.00 1.00 23. 326
154.00 24.00 23. 326
154.00 4.00 23. 326\· ..
NEOPRENE 018 UNIC 158.00 1.00 23. 326
140.00 4.00 23. 316
158.00 24.00 23. 326
NITRILE 019 UNK 355.00 24.00 23. 326
339.00 4.00 23. 326
277.00 1.00 23. 326
PE 042 UNK '16.00 4.00 23. 326
'23.00 1.00 23. 326
'20.00 24.00 23. 326
076 UNI( '1.00 24.00 23. 326
4.00 4.00 23. 32"
'4.00 1.00 23. 3;
POLYURETHANE 050 UNK '5.00 4.00 23. 326
C-4'
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION SWELLING TEST
" -
CHEMICAL NAMEI RESISTANT PRODUCT VENDOR SWELL (PERCENT VOLUME) IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM

000790050 POLYURETHANE 050 UNK -5.00 1.00 23. 326


'5.00 24.00 23. 326
PV ALCOHOL 102 UNK 5.00 24~00 23. 326
5.00 4.00 23. 326
< .01 1.00 23. 326
PVC on UNK > 1,000.00 1.00 23. 326
TEFLON 036 UNK < .01 1.00 23. 326
< .01 4.00 23. 326
< .01 24.00 23. 326
VITON 009 lJNIC 16.00 4.00 23. 326
16.00 1.00 23. 326
19.00 24.00 23. 326

Trichloroethylene (Trlchloroethene)
000790160 BUTYL 014 118 320.00 24.00 23. .04 291
NATURAL RUBBER 017 UNK 580.00 24.00 23. .02 291
NEOPltENE 018 100 410.00 24.00 23. .04 291
NITRILE 020 503 220.00 24.00 23. .04 291
PE 006 100 70.00 24.00 23. .01 291
PV ALCOHOL 102 100 -10.00 24.00 23. .05 291
TEFLON 036 214 < .01 24.00 23. .01 291
VITON 009 118 20.00 24.00 23. .02 291

C-5
APPENDIX D

DIFFUSION COEFFICIENTS

D-l
SUMMARY OF PERFORMANCE DETAIL TESTS
DIFFUSION COEFFICIENTS

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR DIFFUSION COEFFICIENT CH**2/SEC TEMP THICKNESS REF
CASNO MATERIAL DESC CODE b DEG C CH NUM

Acetone
000676410 PV ACETATE 124 UNK 1.30 -11.00 40_ 178

Allyl Chloride
001070510 PV ACETATE 124 UNK 1.30 -11.00 40. 178

Benzene
000714320 BUTYL 014 UNK 4.33 '8_00 23. 327
064 UNK 5.30 -7.00 23. 327
EVA 074 UNK 1.90 -6.00 23. 327
NATURAL RUBBER 017 UNK 1.45 -6.00 23. 327
1.60 -5.00 23. 327
045 UNK 1.50 -7.00 25. 225
NEOPRENE 018 UNK 5.70 -7.00 23. 327
NITRILE 019 UNK 3.50 -7.00 23. 327
NONWOVEN PE 071 UNK 1.13 -6.00 23. 327
PE 042 UNK 8.33 -9.00 23. 327
048 UNK 1.90 '9.00 O. 253
076 UNK 8.80 -7.00 23. 327
PV ACETATE 124 UNK 4.80 '13.00 40. 178
PV ALCOHOL 004 UNK 7.30 -7.00 23. 327
PVC 003 UNK 4.50 -7.00 23. 327
SARAN EX 061 UNK 1.67 -8.00 23. 327
TEFLON 036 UNK 6.n -9.00 23. 327
VITON 009 UNK 6.00 -8.00 23. 327

Butyl Cellosolve (Butoxyethanol. 2)


001117620 NITRILE 019 100 3.45 ·7.00 37. .06 107
2.57 -7.00 37. .06 107
PVC 007 129 7.00 ·7.00 22. 122

Carbon Tetrachloride (Tetrachloromethane)


000562350 PV ACETATE 124 UNK 3.00 -16.00 40. 178

Chlorobenzene
001089070 NEOPRENE 002 UNK 6.61 ·5.00 23. 186
PVC 007 UNK 7.36 '5.00 23. 186

Dimethyl Sulfoxide
000676850 NEOPRENE 002 UNK 6.60 -4.00 23. 186

Ethane
000748400 PE 048 UNK 8.15 -8.00 25. 193

Ethylene Dichloride (Dichloroethane.l.2)


001070620 BUTYL 014 UNK 6.23 -8.00 23. 326
064 UNK 5.83 -8.00 23. 326
NATURAL RUBBER 017 UNK 7.50 -7.00 23. 326
NEOPRENE 018 UNK 4.67 '7.00 23. 326
NITRILE 019 UNK 4.50 -7.00 23. 326
020 UNK 1.00 -6.00 23. 326
PE 042 UNK 3.33 '8.00 23. 326

D-2
SUMMARY OF PERFORMANCE DETAIL TESTS
DIFFUSION COEFFICIENTS

CHEMICAL NAMEI RESISTANT PROOUCT VENDOR DIFFUSION COEFFICIENT CM**2/SEC TEMP THICKNESS REF
CASNO MATERIAL DESC COOE a b DEG C CM NUM

001070620 PV ALCOHOL 102 UNIC 1.83 -7.00 23. 326


TEFLON 036 UNIC < 5.00 -8.00 23. 326
044 UNIC 8.33 -10.00 23. 326
VITON 009 UNIC < 8.33 -11.00 23. 326

Hexane
001105430 NEOPRENE 002 UNI( 1.35 -5.00 23. 186
PE 041 UN" 7.50 '11.00 O. 253
042 UN" 1.50 -10.00 O. 253
048 UNIC 1.20 '9.00 O. 253
2.50 -8.00 30. 253
PVC 007 UN" 3.68 -5.00 23. 186

Isobutylene (Isobutene)
001151170 PE 048 UNIC 4.70 -8.00 30. 253
3.10 -9.00 O. 253
1.25 -9.00 -8. 253

Isopropylamine
000753100 PV ACETATE 124 UNIC 1.70 -12.00 40. 178

Methane
000748280 PE 048 UN" 1.96 -7.00 25. 193

Methanol (Methyl Alcohol)


000675610 PV ACETATE 124 UNIC 1.40 -9.00 40. 178
PVC 007 UNIC 1.51 -5.00 23. 186

Methyl Bromide (Bromomethane)


000748390 PE 041 UN" 1.40 '9.00 O. 253
042 UNIC 2.90 -8.00 O. 253
048 UN" 7.30 . 10.00 -9.00 O. 253
8.30 '8.00 30. 253

Methyl Chloroform (Trichloroethane,1,1,1)


000715560 BUTYL 014 UN" 1.45 -7.00 25. 326
064 UNIC 1.67 -7.00 25. 326
NATURAL RUBBER 017 UNIC 2.78 -7.00 25. 326
NEOPRENE 018 UN" 2.08 -7.00 25. 326
NITRILE 019 UNIC 3.67 '8.00 25. 326
PE 042 UNIC 2.33 '8.00 25. 326
076 UNIC 3.83 -8.00 ·25. 326
POLYURETHANE 050 UNIC 1.38 -7.00 25. 326
PVC 077 UNIC 6.33 -7.00 25. 326
VITON 009 UNIC < 1.17 -9.00 25. 326

Propane
000749860 PE 048 UNIC 2.00 -8.00 25. 193

Propyl Alcohol (Propanol)


000712380 PV ACETATE 124 UNIC 1. 10 '12.00 40. 178

n-Propylami ne

Ir3'
SUMMARY OF PERFORMANCE DETAIL TESTS
01 FFUSION COEFFICIENTS

CHEMICAL NAME/ RESISTANT PRODUCT VENDOR DIFFUSION COEFFICIENT CM**2/SEC TEMP THICKNESS REF
CASNO MATERIAL DESC CODE a b DEG C CM NUN

001071080 PV ACETATE 124 UNK 5.10 -12.00 40. 178

Propyl Chloride (Chloropropane, 1)


005405450 PV ACETATE 124 UNK 1.30 ·12.00 40. 178

Toluene
001088830 BUTYl 014 118 3.67 -7.00 22. 122
216 1.02 ·6.00 37. 122
NEOPRENE 002 UNK 5.56 ·5.00 23. 186
018 509 6.17 -7.00 22. 122
NITRILE 019 100 3.45 -7.00 37. _06 122
2.57 ·7.00 37. .06 122
1.50 -7.00 22_ 122
2.95 ·7.00 37. .04 122
118 1.17 -7.00 22. 122
4.15 -7.00 37. 122
1.67 ·7.00 22. 122
509 2.67 ·7.00 22. 122
020 216 3.50 -7.00 22. 122
6.95 ·7.00 37. 122
5.17 ·7.00 22. 122
PVC 003 215 5.50 -7.00 22. 122
007 129 3.33 ·7.00 22. 122
3.27 ·7.00 37. 122
UNK 8.10 -5.00 23. 186
VITON 009 118 2.33 -8.00 37. 122
VITON/NEOPRENE 022 216 3.33 ·8.00 22. 122
5.17 -8.00 37. 122

1,1,2-Trichloroethane
000790050 BUTYL 014 UNK 1.67 -7.00 23. 326
064 UNK 8.33 ·8.00 23. 326
NATURAL RUBBER 017 UNK 1.47 ·6.00 23. 326
NEOPRENE 018 UNK 1.35 -6.00 23. 326
NITRILE 019 UNK 5.50 ·7.00 23. 326
PE 042 UNK 2.00 ·8.00 23. 326
POLYURETHANE 050 UNK > 2.83 ·7.00 23. 326
PV ALCOHOL 102 lJNIC 2.67 ·7.00 23. 326
TEFLON 036 UNIC < 4.83 -11.00 23. 326
044 UNK 4.00 -10.00 23. 326
VITON 009 UNK < 1.20 -9.00 23. 326

Trichloroethylene (Trichloroethene)
000790160 NEOPRENE 002 UNK 5.03 -5_00 23. 186
PVC 007 UNK 1.45 -6.00 23. 186
APPENDIX E

TENSILE DATA

E-l
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION TENSILE STRENGTH CHANGE TEST

CHEMICAL NAME I RESISTANT PROOUCT VENDOR PERCENT TENSILE CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUH

" 1-Dimethylhydrazine (Dimethylhydrazine,unsym-)


000571470 BUTYL 064 113 .01 •08 23 • 321
085 211 -13.64 _08 23. 321
CHLOROBUTYL 052 205 • 01 .08 23 . 321
CPE 060 113 -20.63 . 08 23 . 321
070 113 -10.00 . 08 23 . 321
PVC 053 126 29.03 . 08 23 . 321
TEFLON 055 210 85.19 •08 23 . 321

Freon TMC
577623190 BUTYL 064 113 6.82 .08 23. 321
085 211 2.27 .08 23. 321
CHLOROBUTYL 052 205 B.38 •08 23 . 321
CPE 060 113 -12.70 • 08 23 • 321
070 113 -20.00 •08 23 . 321
PVC 053 126 16.13 . 08 23 • 321
TEFLON 055 210 48.15 . 08 23 • 321

Hydrazine (Diamine)
003020120 BUTYL 064 113 -25.00 . 08 23 . 321
085 211 -15.91 .08 23. 321
CHLOROBUTYL 052 205 '2.78 • 08 23 • 321
CPE 060 113 < .01 . 08 23 • 321
070 113 -15.00 .08 23. 321
PVC 053 126 9.68 . 08 23 • 321
TEFLON 055 210 166.67 .08 23. 321

Hydrochloric Acid
076470100 BUTYL 064 113 15.91 .08 23. 321
085 211 '4.55 .08 23. 321
CHLOROBUTYL 052 205 '13.89 .08 23. 321
CPE 060 113 . I 1.11 .08 23. 321
070 113 '62.50 .08 23. 321
PVC 053 126 35.48 . 08 23 . 321
TEFLON 055 210 174.07 • 08 23 • 321

Hydrogen Peroxide
077228410 BUTYL 064 ,,3 36.36 • 08 23 . 321
085 211 '4.55 • 08 23 . 321
CPE 060 113 '9.52 . 08 23 . 321
070 113 ·45.00 .08 23. 321
PVC 053 126 35.48 .08 23. 321
TEFLON 055 210 29.63 .08 23. 321

Hydrogen Peroxide, <30X


077228411 CHLOROBUTYL 052 205 2.78 • 08 23 . 321

Isopropyl Alcohol (Propanol, 2·)


000676300 BUTYl 064 In '2.27 .08 23. 321
085 211 < .01 • 08 23 • 321
CHLOROBUTYL 052 205 '6.94 . 08 23 • 321
CPE 060 113 -1.59 •08 23 • 321

E-2
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION TENSILE STRENGTH CHANGE TEST

C~,~lI CAi_ ~A~1(/ REST:;;;"'" PRODUCi VENDOR PERCENT T~h~ILE CHANGE IMMERSION TIME iHIP TiliCK""S'; -<t.r
CASNO MATERIAL DESC COOE HooRS OEG C eM NUM

000676300 CPE 070 113 ·10.00 •08 23 • 321


PVC 053 126 12.90 •08 23 . 321
TEFLON OS5 210 129.63 . 08 23 • 321

Methyl Ethyl Ketone (Butanone,2)


000789330 BUTYL 064 113 6.82 . 08 23 . 321
085 211 ·4.55 •08 23 . 321
CHLOROBUTYL 052 205 5.56 . 08 23 • 321
CPE 060 ,,3 ·4.76 •08 23 • 321
070 113 ·20.00 •08 23 • 321
PVC 053 126 ·67.74 .08 23. 321
TEFLON 055 210 159.26 •08 23 • 321

Methylhydrazine
000603440 BUTYL 064 113 ·4.55 • 08 23 • 321
085 211 ·4.55 .08 23. 321
CHLOR08UTYL 052 205 ·11.11 .08 23. 321
CPE 060 113 ·7.94 •08 23 • 321
070 113 -12.50 .08 23. 321
PVC 053 126 ·22.58 •08 23 . 321
TEFLON 055 210 85.19 •08 23 . 321

Nitric Acid
076973720 BUTYL 064 113 2.27 •08 23 • 321
085 211 4.55 •08 23 • 321
CHLOROBUTYL 052 20S ·27.78 •08 23 . 321
CPE 060 113 1.59 • 08 23 • 321
070 113 ·40.00 •08 23 • 321
PVC 053 126 ·16.13 • 08 23 • 321
TEFLON 055 210 133.33 •08 23 • 321

Nitric Acid, Funing Red


080075870 BUTYL 064 113 25.00 •08 23 • 321
085 2" ·6.B2 •08 23 • 321
CHLOR08UTYL 052 20S ·19.44 •08 23 • 321
CPE 060 113 3.17 •08 23 • 321
070 113 ·62.50 •08 23 • 321
PVC 053 126 16.13 •08 23 • 321
TEFLOH 055 210 44.44 •08 23 • 321

Nitrogen Tetroxide
105447260 BUTYL 064 113 36.36 •08 23 . 321
085 211 ·20.45 . 08 23 • 321
CHLOROBUTYL 052 205 ·47.22 •08 23 • 321
CPE 060 113 ·26.98 •08 23 • 321
070 113 ·52.50 •08 23 • 321
PVC 053 126 ·19.35 •08 23 • 321
TEFLON 055 210 207.41 .08 23. 321

Sulfuric Acid
076649390 BUTYL 064 113 2.27 .08 23. 321
085 211 -9.09 •08 23 • 321
CHLOROBUTYL OS2 20S '5.56 •08 23 • 321

E-3
SUMMARY OF PERFORMANCE DETAIL TESTS
IMMERSION TENSILE STRENGTH CHANGE TEST

CHEMICAL NAMEI RESISTANT PRODUCT VENDOR PERCENT TENSILE CHANGE IMMERSION TIME TEMP THICKNESS REF
CASNO MATERIAL DESC CODE HOURS DEG C CM NUM

076649390 CPE 060 113 6.35 •08 23 • 321


070 113 '22.50 . 08 23 . 321
PVC 053 126 < .01 .08 23. 321
TEFLON 055 210 92.59 •08 23 . 321

"
APPENDIX F

PERMEATION DATA FOR


MULTI-COMPONENT LIQUIDS

F-l
CROSS-REFERENCE OF CHEMICALS IN MIXTURES

COMPONENT MIXTURE

Acetone
000676410 000400029
000400079
000400169
000400179
000400189
000400199
000400209
000400219
000400229

Acetonitrile
000750580 000400059

Atlox 3403F
000300060 000400389
000400399

Atlox 3404F
000300070 000400389
000400399

Butadiene
001069900 000400059

Butyl Acetate
001238640 000400089
000400109

Butyl Alcohol
000713630 000400089
000400109

Cyc1ohexano1
001089300 000400359
000400369
000400379

Diesel Oil
000300020 000400149

Epoxy Resin
000300010 000400079
000400099

Ethyl Acetate
001417860 000400019
000400029
000400109

F-2
CROSS-REFERENCE OF CHEMICALS IN MIXTURES

COMPONENT MIXTURE

Ethyl Alcohol
000641750 000400019
000400029
000400039
000400089
000400299
000400309
000400319
000400329
000400339
000400349
000400359
000400369
000400379

Ethylene Glycol Monoacetate


005245960 000400069

Hexane
001105430 000400169
000400179
000400189
000400199
000400209
000400219
000400229
000400239

Isobutyl Alcohol
000788310 000400049

Isopropyl Alcohol
000676300 000400049
000400059
000400069

Methanol
000675610 000400029
000400109

Methyl Acetate
000792090 000400039

Methyl Ce11oso1ve
001098640 000400079

Methylene Chloride
000750920 000400139
000400239
000400249

F-3
CROSS-REFERENCE OF CHEMICALS IN MIXTURES

COMPONENT MIXTURE

Methyl Ethyl Ketone


000789330 000400059
000400069
000400089

Methyl Isobutyl Ketone


001081010 000400049
000400059
000400069
000400099
000400119
000400129

Methyl Parathion
002980000 000400389
000400399

Nitrobenzene
000989530 000400329
000400339
000400349

Organophosphate
000300030 000400159

Pentachlorophenol
000878650 000400149

Phenol
001089520 000400139

Polyamide
000300000 000400049

Propylene Glycol
000575560 000400159

Sodium Hydroxide
013107320 000400289

Sodium Pentachlorophenate
001315220 000400289

Tenneco 500-100
000300050 000400389
000400399

F-4
CROSS-REFERENCE OF CHEMICALS IN MIXTURES

COMPONENT MIXTURE
--------- -------
Toluene
001088830 000400049
000400089
000400099
000400109
000400119
000400249

Water
077321850 000400389

Xylene
001332070 000400089
000400099
000400129
000400299
000400309
000400319

F-5
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS

MIXTURE: 000400019 REFERENCE: 124


001417860 > 70X by vol Ethyl Acetate
000641750 Ethyl Alcohol

PROO TEMP BREAKTHROUGH PERMEATION RATE THICK


COOE (C) (HOURS) (UG/CM A 2/MIN) (CM)
BUTYL
000400019 014 21.00 > 4.00 .07
PV ALCOHOL
000400019 004 21.00 > 4.00
PVC
000400019 003 21.00 .03 1,102.20 .05
VI TON/NEOPRENE
000400019 022 21.00 .13 280.56 .05

MIXTURE: 000400029 REFERENCE: 124


001417860 > 70X by vol Ethyl Acetate
000676410 Acetone
000641750 Ethyl Alcohol
000675610 Methanol

PROO TEMP BREAKTHROUGH PERMEATION RATE THICK


COOE (C) (HOURS) (UG/CM A 2/MIN) (CM)
BUTYL
000400029 014 21.00 > 4.00 .07
PV ALCOHOL
000400029 004 21.00 > 4.00

MIXTURE: 000400039 REFERENCE: 124


000792090 50X by vol Methyl Acetate
000641750 SOX by vol Ethyl Alcohol

PROO TEMP BREAKTHROUGH PERMEATION RATE THICK


COOE (C) (HOURS) (UG/CM A 2!MIN) (CM) .
BUTYL
000400039 014 21.00 > 4.00 .04
NITRILE
000400039 019 21.00 .12 105.21 .03
VITON
000400039 009 21.00 .07 62.29 .03

F-6
SUMMARY OF PERFORMANCE DETAil FOR MIXTURE COMPONENTS

MIXTURE: 000400049 REFERENCE: 124


000788310 30 - 70X by vol Isobutyl Alcohol
000676300 < 30X by vol Isopropyl Alcohol
001081010 < 30% by vol Methyl Isobutyl Ketone
001088830 < 30X by vol Toluene
000300000 Polyamide

PROO TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (C) (HOURS) (UG/CM"2/MIN) (CM)
PV ALCOHOL
000400049 004 21.00 > 4.00

MIXTURE: 000400059 REFERENCE: 124


000789330 30 - 70X by vol Methyl Ethyl Ketone
001081010 < 30X by vol Methyl Isobutyl Ketone
000676300 < 30X by vol Isopropyl Alcohol
001069900 Butadiene
000750580 Acetonitrile

PROO TEMP BREAKTHROUGH PERMEATION RATE THICK


COOE (C) (HooRS) (UG/at 2!MIN)
A
(at)
BUTYL
000400059 014 21.00 > 4.00
NITRILE
000400059 019 21.00 .32 260.52 .04
PVC
000400059 003 21.00 .15

MIXTURE: 000400069 REFERENCE: 124


000789330 30 - 70X by vol Methyl Ethyl Ketone
005245960 30 - 70X by vol Ethylene Glycol Monoacetate
001081010 < 30% by vol Methyl Isobutyl Ketone
000676300 < 30X by vol Isopropyl Alcohol

PROD TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (C) (HOURS) (UG/CM"2/MIN) (CM)
BUTYL
000400069 014 21.00 > 4.00 .07
NATURAL RUBBER
000400069 017 21.00 .33 24.05 .05

F-7
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS

MIXTURE: 000400079 REFERENCE: 124


000676410 < 30X by vol Acetone
001098640 30X by vol Methyl Cellosolve
000300010 Epoxy Resin

PROD TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (C) (HOURS) (UG/CM A 2/MIN) (CM)
BUTYl
000400079 014 21.00 > 4.00 .07
PV ALCOHOL
000400079 004 21.00 > 4.00
PVC
000400079 003 21.00 .02 1,490.98 .05

MIXTURE: 000400089 REFERENCE: 124


001088830 5 · 20X by vol Toluene
000713630 5 · 20X by vol Butyl Alcohol
001238640 5 · 20X by vol Butyl Acetate
000641750 5 · 20X by vol Ethyl Alcohol
000789330 5 · 20X by vol Methyl Ethyl Ketone
001332070 5 · 20X by vol Xylene

PROD TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (C) (HOURS) (UG/CM"2/MIN) (CM)
BUTYL
000400089 014 21.00 2.65 6.61 .04
NITRILE
000400089 019 21.00 .10 916.83 .04
000400089 020 21.00 .23 842.68 .04
PE/EVOH/PE
000400089 109 21.00 .43 410.82 .06
PV ALCOHOL
000400089 004 21.00 > 4.00
PVC
000400089 003 21.00 .07 855.71 .06
VITON
000400089 009 21.00 .08 671.34 .03

F-8
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS

MIXTURE: 000400099 REFERENCE: 124


001088830 30· 70% by vol Toluene
001081010 < 30% by vol Methyl Isobutyl Ketone
001332070 < 30% by vol XyJene
000300010 Epoxy Resin

PROD TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (C) (HOURS) (UG/CM~2!MIN) (CM)
PV ALCOHOL
000~00099 004 21.00 > 4.00

MIXTURE: 000400109 REFERENCE: 124


001088830 30· 70% by vol Toluene
000713630 Butyl Alcohol
001238640 Butyl Acetate
001417860 Ethyl Acetate
000675610 Methanol

PROD TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE eC) (HOURS) (UG/CM"2/MIN) (CM)
PV ALCOHOL
000400109 004 21.00 .43 42.08
VITON/NEOPRENE
000400109 022 21.00 .27 300.60 .05

MIXTURE: 000400119 REFERENCE: 124


001088830 50% by vol Toluene
001081010 50% by vol Methyl Isobutyl Ketone

PROD TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (C) (HOURS) (UG/CM"2/MIN) (CM)
PV ALCOHOL
000400119 004 21.00 > 4.00

F-9
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS

MIXTURE: 000400129 REFERENCE: 124


001332070 SOX by vol Xylene
001081010 SOX by vol Methyl Isobutyl Ketone

PROD TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (C) (HClJRS) (UG/CM"'21MIN) (CM)
NITRILE
000400129 019 21.00 .20 2,705.40 .03
VITON
000400129 009 21.00 .33 3,006.00 .03

MIXTURE: 000400139 REFERENCE: 124


000750920 > 70X by vol Methylene Chloride
001069520 Phenol

PROD TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (C) (KOORS) (UG/CM"'21MIN) (CM)
NEOPRENE
000400139 018 21.00 .30 1.34 .11
PV ALCOHOL
000400139 004 21.00 > 4.00

MIXTURE: 000400149 REFERENCE: 278


000878650 4X by vol Pentachlorophenol
000300020 Diesel Oil

PROD TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE ec) (HOURS) (UG/CM"'21MIN) (CM)
NATURAL RUBBER
000400149 001 23.00 .01 .02 .16
NEOPRENE
000400149 018 23.00 1.00 1.35 .04
NITRilE
000400149 019 23.00 > 8.00 .06
PVC
000400149 003 23.00 .01 .27 .02

F-IO
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS

MIXTURE: 000400169 REFERENCE: 302


000676410 95% by voL Acetone
001105430 5% by voL Hexane

' :" t~~i

PROD TEMP BREAICTHRooGH PERMEATION RATE THICK


CODE (C) (HooRS) (UG/CM"2!MIN) (CM)
VITON/CHlOROBUTYL
000676410 112 25.00 .08 .04
001105430 112 25.00 .08 .04

MIXTURE: 000400179 REFERENCE: 302


000676410 86X by voL Acetone
001105430 14X by voL Hexane

PROD TEMP BREAKTHROOGH PERMEATION RATE THICK


CODE (C) (HooRS) (UG/CM"2/MIN) (CM)
VITON/CHLOROBUTYL
000676410 112 25.00 .10 .04
001105430 112 25.00 .10 • .18 .04

MIXTURE: 000400189 REFERENCE: 302


000676410 50X by vol Acetone
001105430 50X by voL Hexane

PROD TEMP BREAKTHRooGH PERMEATION RATE THICK


CODE (e) (HOORS) (UG/CM"2/MIN) (CM)
VITON/CHLOROBUTYL
000676410 112 25.00 .03 •• 10 .04
001105430 112 25.00 .03 .• 10 .04

F-ll
SUMMARY OF PERFORMANCE DETAil FOR MIXTURE COMPONENTS

MIXTURE: 000400199 REFERENCE: 302


000676410 35% by vol Acetone
001105430 65% by vol Hexane

PROD TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (C) (HOURS) (UG/CW2!MIN) (CM)
VITON/CHlOROBUTYl
000676410 112 25.00 .10 .04
001105430 112 25.00 .10 .04

MIXTURE: 000400209 REFERENCE: 302


000676410 15% by vol Acetone
001105430 85% by vol Hexane

PROD TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (C) (HOURS) (UG/CM"2!MIN) (CM)
VITON/CHLOROBUTYl
000676410 112 25.00 .10 • .18 .04
001105430 112 25.00 .10 . .18 .04

MIXTURE: 000400219 REFERENCE: 302


000676410 5% by vol Acetone
001105430 95% by voL Hexane

PROD TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (C) (HOURS) (UG/CM"2!MIN) (CM)
VITON/CHlOROBUTYl
000676410 112 25.00 .08 .04
001105430 112 25.00 .08 .04

F-12
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS

MIXTURE: 000400229 REFERENCE: 302


000676410 1% by vol Acetone
001105430 99% by vol Hexane

PROO TEMP BREAKTHROUGH PERMEATION RATE THICK


COOE (C) (HOURS) (UG/CM A 2/MIN) (CM)
VITON/CHLOROBUTYL
000676410 112 25.00 .08 .04
001105430 112 25.00 .08 .04

MIXTURE: 000400239 REFERENCE: 302


001105430 50X by vol Hexane
000750920 sox by vol MethyLene ChLoride

PROO TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (e) (HOURS) (UG/CM A 2/MIN) (CM)
VITON/eHLOROBUTYL
000750920 112 25.00 .70· .78 .04
00',05430 112 25.00 .95 • 1.03 .04

MIXTURE: 000400249 REFERENCE: 302


000750920 50X by vol Methylene Chloride
001088830 50X by vol Toluene

PROO TEMP BREAKTHROUGH PERMEATION RATE THICK


CODE (e) (HOURS) (UG/CM"2/MIN) (CM)
VITON/eHLOROBUTYL
000750920 112 25.00 .75· .92 .04
001088830 112 25.00 .97 • 1.10 .04

F-13
SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS

MIXTURE: 000400289 REFERENCE: 278


001315220 4% by vol Sodium Pentachlorophenate
013107320 Sodium Hydroxide

PROO TEMP BREAKTHROOGH PERMEATION RATE THICK


COOE (C) (HOORS) (UG/CM''2IM IN) (CN)
NATURAL RUBBER
000400289 001 23.00 .01 .02 .16
NEOPRENE
000400289 018 23.00 > 7.50 .04
NITRILE
000400289 019 23.00 > 15.50 .06
PVC
000400289 003 23.00 > 5.00 .02
000400289 007 23.00 > 15.50 .11

MIXTURE: 000400389 REFERENCE: 104


002980000 10% by Nt Methyl Parathion
000300050 6% by Nt Tenneco 500·100
000300060 Atlox 3403F
000300070 Atlox 3404F
Om21850 83% by wt Water

PROO TEMP BREAKTHROOGH PERMEATION RATE THICK


COOE (C) (HOURS) (UG/CM"2/MIN) (CM)
NONWOVEN PE
002980000 071 23.00 < .08 20.04 • 60.12
PE
002980000 076 23.00 .50 . .75 .20

MIXTURE: 000400399 REFERENCE: 104


002980000 S7% by Nt Methyl Parathion
oo030ooS0 36% by wt Tenneco SOO·100
000300060 S% by wt Atlox 3403F
000300070 2% by Nt Atlox 3404F

PROO TEMP BREAKTHRt'lIGH PERMEATION RATE THICK


COOE (C) (HOURS) (UG/CM"2/MIN) (CM)
PE
002980000 076 23.00 .25 .08
SARANEX
002980000 061 23.00 2.00 . 3.00 .02

F-14
APPENDIX G

VENDOR CODES FOR USE WITH


DATA SUMMARIES IN APPENDICES
A THROUGH E

G-l
VENDOR CODES FOUND IN APPENDICES A THROUGH E

VENDOR
CODE VENDOR NAME

100 Edmont Div. Becton, Dickinson & Co.


101 Granet
102 Ansell Industrial Products
103 Best Manufacturing Company
104 Boss Manufacturing Company
106 Disposables Inc.
107 Durafab Disposables, Inc.
108 Keystone Protection Corp.
110 Glover Latex, Inc.
112 Greene Rubber Co., Inc.
113 ILC Dover
114 International P1aytex, Inc.
115 Major Safety Service, Inc.
116 Melco, Inc.
117 Mine Safety Appliances Co.
118 North Hand Protection
119 OKI Supply Co.
120 Pioneer Industrial Products Co.
121 P1astex Protective Products, Inc.
122 PPG Industries, Inc.
123 Protexal1 Company
124 Safety First Industries
125 SGL Homalite Industries
126 Wheeler Protective Apparel, Inc.
127 E.I. du Pont de Nemours & Co., Inc.
128 Jordan David Safety Products
129 KID AB
140 Allied Glove & Safety Products Corp.
141 The Sager Corporation
142 American Scientific Products
144 Arbill Inc.
145 Body-Guard
146 Cesco Safety Products
147 Charkate
150 Dayton Flexible Products
151 Defense Apparel
153 Direct Safety Company
155 Eastco Industrial Safety Corp.
156 Encon Manufacturing Co.
157 Fairway Products
158 General Scientific Safety Equipment Company
159 Frommelt Industries, Inc.
160 Goodyear Rubber Products Corp.
162 Holcomb Safety Garment Co.
164 Industrial Products Co., Inc.
165 Industrial Safety and Security Co.
166 Interex Corp.
168 Jomac Products Inc.
169 Kappler Disposables, Inc.
170 Kimberly-Clark Corp.
172 Lehigh Safety Shoe Co.
G-2
VENDOR CODES FOUND IN APPENDICES A THROUGH E

VENDOR
CODE VENDOR NAME

173 Magid Glove and safety Mfg. Co.


174 Neese Industries Inc.
175 Pendergast Safety Equipment Co.
176 P1astimayd Corp.
177 Pulmosan Safety Equipment Corp.
178 Rainfair, Inc.
179 Ranger
180 Record Industrial Co.
181 Renco Corp
185 W.H. Salisbury & Co.
187 Singer Safety Co.
188 Standard Glove & Safety Equip. Corp.
189 Standard Safety Equipment Co.
191 LRC Safety Products Co.
192 H. Texier Glove Company Inc.
193 Tingley Rubber Corp.
194 The Tracies Co.
196 United States Safety Service Co.
197 Angelica Uniform Group
198 Vidaro Corp.
201 Falcon Industries, Inc.
202 Oak Medical Supply Co.
203 Colonial Glove & Garment Inc.
204 Monte Glove Company
205 Arrowhead Products
206 Hub Safety Equipment, Inc.
207 Miller Products Co., Inc.
208 Robar Protective Products
209 Fisher Scientific Company
210 Comasec
211 Barry Manufacturing Co. Ltd.
212 Rich Industries
214 Clean Room Products, Inc.
215 Vinylprodukter
216 Erista
220 National Draeger, Inc.
223 Bel-Art Products
225 Coyne Safety Equipment, Inc.
227 Halprin Supply Co.
229 Inco Safety Products Co.
231 Keller Glove Mfg. Co.
232 Latex Glove Co., Inc
233 Leonard Safety Epuipment, Inc.
234 Lion Uniform, Inc.
235 Mar-Mac Manufacturing Co., Inc.
236 National Safety Wear, Inc.
238 Rockford Medical & Safety Co.
239 Safety Engineering & Supply Co.
242 3M Company
244 Intermarket Latex, Inc.
245 Protech Safety Equipment Inc.

G-3
VENDOR CODES FOUND IN APPENDICES A THROUGH E

VENDOR
CODE VENDOR NAME

246 Broner Glove Co.


247 Trelleborg, Inc.
248 Masterman's
249 Goodall Rubber Company
500 Oak Technical, Inc.
501 Bard Parker
502 Seiberling
503 Surety-Sure Seal
504 California Safety
505 Handgards Inc.
506 Ackwell
507 Converse Inc.
508 Pharmaseal Laboratories Inc.
509 Nolato
510 Chemical Fabrics Corporation
511 Dow Chemical Company
512 Lab Safety Supply Company
513 Andover Industries, Inc.
514 Acme Mills Company
515 E.D. Bullard Company
516 Cofish International, Inc.
517 Dorsey Safety Products Co.
518 Elliott Glove Company, Inc.
519 Exxon Chemical Company
520 Fyrepel Products Inc.
521 Hy-Test Safety Shoes
522 Iron Age Protective Company
523 La Crosse Footwear, Inc.
524 Panelgraphic Corporation
525 Shelby-Wolverine Glove Company
526 Steele & Associates, Inc.
527 Steel Grip Safety Apparel Co., Inc.
529 United States Plastic Corp.
531 Superior Surgical Mfg. Co., Inc.
532 Willson Safety Products
534 Daffin Disposables, Inc.
535 Aramsco
536 Alliance Supply, Inc.
537 Holland Safety Supply Co.
538 Memphis Glove Company
539 Jones Safety Supply, Inc.
540 Ronco Textile Products, Inc.
541 Safeco Inc.
542 Armin Corporation
543 IPESCo" Inc.
544 Marathon Rubber
545 Stauffer Manufacturing Company
547 Sawyer-Tower
548 E.I. du Pont de Nemours & Company

G-4
APPENDIX H

RATIONALE FOR RECOMMENDATIONS


IN MATRIX A

R-l
1. overview
CPC chemical resistance information was formed into two data bases:

• Test data including breakthrough times, permeation rates,


percent swell, percent elongation, percent weight change and
calculated diffusion coefficients from the technical literature
and CPC vendors.

• Qualitative ratings (e.g., "excellent," "good," etc.) from CPC


vendors, raw materials suppliers and a variety of publications.

There was a separate field for each test and each qualitative rating for
each chemical/material pair. The total number of fields was about
10,000.

Algorithms were developed to analyze the information in each data base


separately. The results of the analyses were then combined by means of
another algorithm to produce the recommendations in Matrix A. The
algorithms for each analysis are summarized in the following paragraphs.

2. Test Data
Five types of data were considered: breakthrough time, % swell (volume),
% change in elongation, % change in weight due to immersion, and diffu-
sion coefficient. The data were scanned and classified as follows:

Breakthrough Time Good >1 hour


Fair 0.2-1 hour
Poor <0.2 hour

% Swell (Volume) Good <10%


Poor >10%

% Elongation Change Good <20%


Poor >20%

% Yeight Change Good <10%


Poor >10%

Diffusion Coefficient Good <10-


10
10
cm~/sec
Poor >10- cm /sec

Tensile Strength Good <10%


Poor >10%

On a resistant material by resistant material basis for each chemical,


the number of individual products in each classification was totaled.
(See Appendix E of Volume I for a listing of the resistant materials.)

H-2
The totals in each classification were compared and the resistant material
put i.nto one of the following four groups:

I. Significant number of test data indicating excellent


resistance to the particular chemical.

II. Relatively few test data showing excellent resistant, or many


data indicating good resistance.

III. Many data indicating fair resistance, or a few data indicating


poor resistance.

IV. Significant number of test data indicating poor resistance.

The criteria for Group I were at least two tests with breakthrough times
grea ~er than 1 hour; no breakthrough times less than 1 hour and no data
indiating "poor" resistance in either swelling, weight change, elonga-
tion, or diffusion coefficient.

The. riterion for Group II was one or more "good" and no "fair" or "poor"
in alY of the five tests. Alternatively, the material would be put in
Group II if there were two breakthrough times greater than 1 hour (with
none less than 1 hour) and two or less "poor" in the other four tests.

The criterion for Group III was one or more "fair" or "poor" test results,

The criteria for Group IV were one or more breakthrough times less than
0.2 Lour or two breakthrough times less than 1 hour.

3. Qualitative Information

As described in Volume I, Chapter 7, Part 4, qualitative information was


norm~lized to a four grade scale: A, B, C, D, "A" represented excellent
resi~tance and "D" represented poor resistance, Similar to the tesc data
base, the qualitative information was analyzed on a resistant material by
resistant material basis for each chemical. The number of ratings in
each grade were tabulated and compared :n order ::0 assign each d,8Tl:i-
cal/material pair to one of four groups with descriptior;s analogouscc,
t:hesE, given aoove for the t:E.st data. In this c.ase, hN;e'.:eJ:. (pali t£i', ~.:,:
rat~er than quantitative iLformation is of concern.

"'he ,-riteria for ,:;rolJp 1::: were less ~han c:hree A or B ra::i;'~~'s a~,ci ,:c·
.::; 01: D i'atings. .:;''..ts'rnativel:l, Group II conditior:s would be ;ne;~ 'C:' d.
t:<Jc.dl. of three or more A. or B 0:::- C ratings, the nwnber of. A. pi.us 3
rati~gs greater than the number of C ratir.gs, ar:d no D ratings,

The criteria for Group III were less than a total of three C or D ratings
or, alternatively, a total of three or more B, C or D ratings with the
number of C plus D ratings greater than the number of B ratings.

H-3
'l'~e c-ciceri0n for Grcup Iii "la'; ;:] total of three or more c:: and D L.1,-"icg,"'.

4. Matrix A Recommendations

The results of the activities described in the two preceding sections


were combined to yield the overall recommendations listed in Matrix A of
Volume I. The rationale for the combination is described in Volume I,
Chapter 7, Part B.

H-4

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