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Chemistry Thermodynamics Worksheet

This document provides a chemistry worksheet with questions about chemical thermodynamics concepts including spontaneity, entropy, Gibbs free energy, and calculating standard entropy, enthalpy, and free energy changes for various chemical reactions. The 20-question worksheet covers topics like identifying spontaneous processes, calculating entropy of phase changes, predicting entropy signs of reactions, and determining Gibbs free energy changes using standard entropy and enthalpy values provided.

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174 views2 pages

Chemistry Thermodynamics Worksheet

This document provides a chemistry worksheet with questions about chemical thermodynamics concepts including spontaneity, entropy, Gibbs free energy, and calculating standard entropy, enthalpy, and free energy changes for various chemical reactions. The 20-question worksheet covers topics like identifying spontaneous processes, calculating entropy of phase changes, predicting entropy signs of reactions, and determining Gibbs free energy changes using standard entropy and enthalpy values provided.

Uploaded by

Stupid Rice
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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LAGUNA BELAIR SCIENCE SCHOOL

City of Santa Rosa, Laguna


www.lagunabelairschool.com.ph

Worksheet in General Chemistry 2

Chemical Thermodynamics

Directions: Provide the needed information. Answer the following using MS Word. For the
computation part, you may do it on a separate paper then take a picture and attach it on your
word file. Upload your files on the assignment drop box provided in Schoology following this
format:

Surname,Firstname_Worksheet#

A. Spontaneity
Directions: Identify whether each process or reaction is spontaneous or non –
spontaneous.
1. Converting liquid water to steam at room temperature.
2. Hydrogen gas and oxygen gas will form water.
3. Process of photosynthesis in plants.
4. Oxidation of gold.
5. Growing of molds in bread.
B. Entropy and Phase Change
6. Calculate the standard entropy of vaporization of argon at its boiling point of 87.3 K.
(∆Hvap = 6.5 kJ/mol).
7. Calculate the change in entropy of a solid when 187J of energy is removed reversibly
from it as heat at 34°C.
8. Calculate the ∆S for the melting point of ice at 0℃. (∆Hfusion = 6.01 kJ/mol)

C. Entropy in Chemical Reactions


Directions: Predict the entropy sign of each equation.
9. Hg (l)  Hg (g)
10. CaO(s) + CO2 (g)  CaCO3 (s)
11. 2SO3 (g)  2SO2 (g) + O2 (g)
12. Ag+ (aq) + Br- (aq)  AgBr (s)
13. 2NO (g) + O2 (g)  2NO2 (g)
14. Metallic iron is produced by a high temperature process through a series of chemical
reactions. The equation is as follows:
3Fe2O3 (s) + CO (g)  2Fe3O4 (s) + CO2 (g)
What is the standard entropy change for the reaction?

Compound J
S° ( )
mol ∙ K
Fe2O3 (s) 87.40
Fe3O4 (s) 145.3
CO2 (g) 213.7
CO (g) 197.5

15. Calculate the standard entropy change for the formation of one mole nitrogen dioxide
from its elements.

½ N2 (g) + O2 (g)  NO2 (g)

Compound J
S° ( )
mol ∙ K
NO2 (g) 191.5

Stewards for a Better World


O2 (g) 205.0
N2 (g) 240.5

D. Gibbs Free Energy


16. A reaction with a low enthalpy of reaction value is not spontaneous at low
temperature but becomes spontaneous at high temperature. What are the signs for
ΔH° and ΔS°?
17. Calculate the ∆𝐺° for this reaction:
CH4 (g) + 2O2 (g)  CO2 (g) + 2H2O (g)

Compound 𝑮° (𝒌𝑱/𝒎𝒐𝒍)
CH4 (g) 50.8
CO2 (g) 394.4
O2 (g) 0
H2O (g) -288.57

18. Hydrogen reacts with nitrogen to form ammonia (NH3) according to the reaction:
3H2 (g) + N2 (g)  2NH3 (g)
J
The value of ∆H° is -92.38 kJ/mol and the ∆S° is -198.2 . Determine ∆G° at
mol ∙ K
25℃.
19. Calculate the free energy change of combustion of propane gas, C3H8.
C3H8 (g) + 5O2 (g)  3CO2 (g) + 4H2O (g)

Compound 𝑮° (𝒌𝑱/𝒎𝒐𝒍)
C3H8 (g) 23.5
CO2 (g) 394.4
O2 (g) 0
H2O (g) -288.57

20. Hydrochloric acid (HCl) reacts with sodium hydroxide (NaOH) to form sodium
J
chloride (NaCl) and water. If ΔH° = –56.13 kJ/mol and ΔS° = 79.11 ,
mol ∙ K
calculate the ΔG° for this reaction at 20°C?

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