Chapter 8

Metal Extraction (Recovery Systems)

Omar A. Muhtadi

8.1 INTRODUCTION

Several methods c u r r e n t l y e x i s t by which g o l d may be recovered from a

p r e g n a n t l e a c h l i q u o r . Two o f t h e s e methods a r e discussed i n t h i s c h a p t e r , t h e
M e r r i l l - C r o w e ( z i n c c e m e n t a t i o n ) process and t h e carbon a d s o r p t i o n process.
These two methods r e p r e s e n t t h e most f r e q u e n t l y used t e c h n i q u e s f o r g o l d
e x t r a c t i o n and a r e , -in f a c t , used almost e x c l u s i v e l y i n U.S. heap l e a c h i n g
o p e r a t i o n s . Because o f t h e e f f i c i e n c y and ease o f use o f t h e s e two methods, i t
i s e x t r e m e l y l i k e l y t h e y w i l l c o n t i n u e t o be q u i t e p r e v a l e n t w i t h i n t h e g o l d
m i n i n g i n d u s t r y i n y e a r s t o come.

The remainder o f t h i s c h a p t e r i n c l u d e s i n f o r m a t i o n on t h e h i s t o r y o f t h e
two processes, d e s c r i p t i o n s o f t h e a c t u a l processes, c r i t e r i a t o c o n s i d e r i n
s e l e c t i n g a r e c o v e r y process, and commercial d e s i g n and c o n s t r u c t i o n
c o n s i d e r a t i o n s f o r b o t h o f t h e g o l d r e c o v e r y methods. As w i t h o t h e r c h a p t e r s
i n t h i s book, some f a i r l y t e c h n i c a l i n f o r m a t i o n i s presented f o r t h e b e n e f i t
o f t h o s e r e a d e r s needing a g r e a t e r l e v e l o f d e t a i l . However, t h e o v e r a l l
i n t e n t o f t h e c h a p t e r i s t o p r o v i d e an o v e r v i e w o f t h e processes l i k e l y t o be
used i n g o l d e x t r a c t i o n , t h u s g i v i n g t h e r e a d e r a f i r m b a s i s f o r more
t e c h n i c a l r e s e a r c h i n t o t h e t o p i c , s h o u l d t h i s be needed.

8.1.1 H i s t o r y o f Zinc Cementation

D u r i n g t h e l a t e 18901s, z i n c c e m e n t a t i o n was i n t r o d u c e d f o r t h e
p r e c i p i t a t i o n o f g o l d and s i l v e r f r o m c y a n i d e s o l u t i o n s . T h i s o c c u r r e d a t
about t h e same t i m e as t h e i n t r o d u c t i o n o f t h e c y a n i d a t i o n process, t h e
h i s t o r y o f which i s recapped i n Chapter 1.

The i n i t i a l c e m e n t a t i o n process i n v o l v e d i n t r o d u c t i o n o f a g o l d - b e a r i n g
c y a n i d e s o l u t i o n o n t o a bed o f z i n c shavings. I t proved t o be q u i t e
i n e f f i c i e n t because t h e r e a c t i o n r a t e was v e r y slow. The z i n c q u i c k l y became
"passive", i n h i b i t i n g f u r t h e r gold deposition. S h o r t l y a f t e r t h i s f i r s t
i n t r o d u c t i o n , z i n c p r e c i p i t a t i o n was improved by a d d i n g a l e a d s a l t ( u s u a l l y
l e a d n i t r a t e ) t o t h e z i n c . T h i s a l l o w e d a z i n c - l e a d c o u p l e t o form on t h e
s u r f a c e o f t h e shavings, e l i m i n a t i n g p a s s i v a t i o n o f z i n c s u r f a c e s and t h e r e b y
a l l o w i n g continued d e p o s i t i o n o f gold.

F u r t h e r improvements were s h o r t l y f o r t h c o m i n g . The f i r s t o f these

i n v o l v e d t h e use o f z i n c d u s t r a t h e r t h a n z i n c shavings. T h i s p r o v i d e d a much
124
 METAL EXTRACTION (RECOVERY SYSTEMS) 125

l a r g e r s p e c i f i c s u r f a c e area f o r p r e c i p i t a t i o n and g r e a t l y speeded t h e

r e a c t i o n k i n e t i c s . The d e a r e a t i o n o f go1 d - b e a r i n g s o l u t i o n s t o an oxygen
c o n c e n t r a t i o n o f l e s s t h a n 1 ppm s i g n i f i c a n t l y reduced z i n c consum~ptioncaused
by o x i d a t i o n , a g a i n r e s u l t i n g i n a s i g n i f i c a n t i n c r e a s e i n process e f f i c i e n c y .
The use o f c l a r i f i e d , deareated l e a c h 1 i q u o r s was a l o g i c a l n e x t s t e p i n t h i s
process which u l t i m a t e l y became known as t h e M e r r i l l - C r o w e p r e c i p i t a t i o n
process, named f o r t h e two men most r e s p o n s i b l e f o r i t s f i n a l e v l o u t i o n t o a
w i d e l y used process.

A c t i v a t e d c a r b o n was used e a r l y - o n i n t h e development o f g o l d e x t r a c t i o n

processes t o adsorb g o l d v a l u e s from leached p u l p s i n which a s o l i d - l i q u i d
s e p a r a t i o n (necessary f o r g o l d e x t r a c t i o n by M e r r i l l -Crowe process) was
d i f f i c u l t . Once t h e a c t i v a t e d carbon was loaded w i t h g o l d , i t was s e n t t o a
s m e l t e r and burned t o r e c o v e r t h e g o l d . The c o s t o f u s i n g t h e carbon o n l y
once, i n c o n ~ b i n a t i o n w i t h t h e c o s t o f s m e l t i n g , rendered t h i s process
economical l y u n a t t r a c t i v e . However, t h e p o t e n t i a l o f t h e process was r e a l i z e d ,
t h u s t r i g g e r i n g a p e r i o d o f i n t e n s i v e r e s e a r c h by t h e U.S. Bureau o f Mines
aimed a t t h e development o f t e c h n i q u e s f o r s t r i p p i n g and r e u s i n g t h e carbon. A
method o f d e s o r p t i o n was q u i c k l y developed u s i n g a c a u s t i c sodium s u l f i d e
solution, followed by e l e c t r o w i n n i n g o f g o l d . This, however, proved
i n e f f e c t i v e i n s t r i p p i n g s i l v e r f r o m t h e carbon.

F o l l o w i n g f u r t h e r m o d i f i c a t i o n , a process was developed (Zadra e t a1 , .

1952) t o e f f e c t i v e l y s t r i p b o t h g o l d and s i l v e r . I t employed a h o t NaOH-NaCN
s o l u t i o n t o desorb t h e l o a d e d p r e c i o u s metal s. E l e c t r o w i n n i n g o f t h e s t r i p p i n g
s o l u t i o n t o r e c o v e r t h e m e t a l s was f o l l o w e d by r e a c t i v a t i o n o f t h e carbon
t h r o u g h h e a t i n g i n t h e absence o f a i r . The process was used s u c c e s s f u l l y on a
s m a l l s c a l e a t t h e G e t c h e l l Mine, Nevada, and a t t h e Golden Cycle Mine,
C r i p p l e Creek, CO, i n t h e 1950's. The f i r s t m a j o r s u c c e s s f u l commercial use o f
t h i s process o c c u r r e d a t Homestake's South Dakota o p e r a t i o n s i n t h e e a r l y
1970's.

8.2 PROCESS DESCRIPTION

C h e m i s t r y o f Process. The c h e m i s t r y o f z i n c p r e c i p i t a t i o n depends m a i n l y

on t h e f a c t t h a t g o l d and s i l v e r m e t a l s a r e more n o b l e t h a n z i n c . T h i s means
t h a t t h e y a r e more a p t t o reduce t o t h e i r n a t i v e s t a t e s ( i .e., AuO and Ago)
t h a n remain i n a g o l d o r s i l v e r - c y a n i d e complex. A g e n e r a l i z e d c e m e n t a t i o n
.
r e a c t i o n may be w r i t t e n as f o l l o w s (Zadra e t a1 , 1952) :

As t h e g o l d i s p r e c i p i t a t e d , t h e z i n c combines w i t h t h e c y a n i d e t o form
a z i n c - c y a n i d e complex. H i g h pH (10.0+) i s r e q u i r e d t o p r e c i p i t a t e p r e c i o u s
m e t a l s and t o m i n i m i z e p r e c i p i t a t i o n o f copper which i s a t t i m e s p r e s e n t i n
solution.

D e t a i l e d fundamental s t u d i e s o f t h e k i n e t i c s and mechanisms o f g o l d

p r e c i p i t a t i o n were p u b l i s h e d by N i c o l e t a l . (1979). T h e i r paper i s an
e x c e l l e n t reference f o r i n f o r m a t i o n concerning p r e c i p i t a t i o n o f precious
m e t a l s by z i n c d u s t .
126 PRECIOUS METAL HEAP LEACHING PROJECTS

Flowsheet. M e r r i l l - C r o w e z i n c p r e c i p i t a t i o n i s t h e most commonly used

c e m e n t a t i o n process f o r g o l d r e c o v e r y , and c o n s i s t s o f f o u r b a s i c s t e p s
( F i g u r e 8.1):

Clarificationoftheleachliquor;
Deareat i o n ;
Additionofzinc (andleadsa1ts);and
Recovery o f Zn/Au p r e c i p i t a t e .

The p r e c i p i t a t e i s t h e n smelted t o r e c o v e r t h e p r e c i o u s m e t a l s .

Solution Characteristics for E f f i c i e n t Precipitation. Three t y p e s o f

s o l u t i o n c o n s t i t u e n t s ( o r ~ o t e n t i a l c o n s t i t u e n t s ) can have a m a i o r e f f e c t on
t h e e f f i c i e n c y o f t h e z i n c ' p r e c i p i t a t i o n process.: suspended s o l i ' b s , d i s s o l v e d
oxygen, and i n t e r f e r i n g m e t a l l i c i o n s .

Suspended s o l i d s can d r a s t i c a l l y reduce process e f f i c i e n c y , t h u s making

clarification (i.., t h e process o f removing suspended m a t e r i a l from a
solution) the most important single factor i n obtaining efficient
p r e c i p i t a t i o n . Through l o n g e x p e r i e n c e , p r e - c o a t p r e s s u r e c l a r i f i c a t i o n i s
know t o p r o v i d e t h e b e s t o p e r a t i o n a l results. When t h i s method o f
c l a r i f i c a t i o n i s f o l l o w e d , p a r t i a l removal o f d i s s o l v e d oxygen has a l r e a d y
been achieved when t h e s o l u t i o n e n t e r s t h e Crowe r e c e i v e r ( o r vacuum t o w e r ) ,
where t h e deoxygenation i s completed . By c l a r i f y i n g and deaerating
s i m u l t a n e o u s l y , a v a i l a b l e vacuum i s used more e f f i c i e n t l y .

E f f i c i e n t and c o m p l e t e p r e c i p i t a t i o n o f m e t a l s from c y a n i d e l e a c h
1i q u o r s r e q u i r e s t h a t t h e s o l u t i o n , after clarification, be f u r t h e r
c o n d i t i o n e d by t h e removal o f d i s s o l v e d oxygen. Even m i n u t e t r a c e s o f
d i s s o l v e d oxygen have a d e l e t e r i o u s e f f e c t on complete p r e c i p i t a t i o n because
o f p a s s i v a t i o n o f t h e z i n c s u r f a c e . Vacuum d e a r e a t i o n removes d i s s o l v e d oxygen
from s o l u t i o n and appears t o be t h e b e s t process because i t a l s o removes
carbon d i o x i d e . Carbon d i o x i d e can r e a c t t o f o r m c a l c i u m c a r b o n a t e and b l i n d
precipitate f i l t e r s .

When m e t a l l i c z i n c d i s s o l v e s i n a l k a l i n e c y a n i d e s o l u t i o n s , hydrogen i s
formed. P r o v i d e d t h e d i s s o l v e d oxygen has been s u b s t a n t i a l l y removed
( g e n e r a l l y t h r o u g h vacuum d e a r a t i o n , as d i s c u s s e d above), t h e hydrogen w i 11
combine w i t h and n u l l i f y t h e e f f e c t o f any oxygen r e m a i n i n g i n s o l u t i o n . Z i n c
and c y a n i d e consumption t h e n decreases and t h e f o r m a t i o n o f troublesome by-
products i s minimized.

Several m e t a l l i c i o n s a r e known t o have v a r y i n g degrees o f d e t r - i m e n t a l

(i.e., i n t e r f e r i n g ) e f f e c t s on z i n c c e m e n t a t i o n . The most troublesome i o n s a r e
t h o s e o f antimony and a r s e n i c ( F i n k e l s t e i n , 1972). C o n c e n t r a t i o n s o f t h e s e
i o n s as l o w as 1 ppm can reduce t h e r a t e o f c e m e n t a t i o n by 20 p e r c e n t . High
v a l u e s o f t h e s e i o n s may be reduced by t r e a t i n g t h e m i l l s o l u t i o n w i t h sodium
s u l f i d e and f i l t e r i n g t h e r e s u l t i n g i n s o l u b l e antimony and a r s e n i c s u l f i d e s .
However, a l l s i l v e r i n t h e m i l l s o l u t i o n i s l o s t when t h i s process i s used.

The presence o f copper i n c y a n i d e s o l u t i o n s u s u a l l y causes h i g h c y a n i d e

consumption, and a l s o decreases p r e c i p i t a t i o n e f f i c i e n c y b y p a s s i v a t i o n o f t h e
z i n c , i f a l l o w e d t o accumulate beyond c e r t a i n l i m i t s . However, w i t h t h e use o f
powdered z i n c , f r e s h s u r f a c e i s exposed on a c o n t i n u o u s b a s i s , and hence g o l d
 METAL EXTRACTION (RECOVERY SYSTEMS)

I PREQNANT
SOLUTION I N

PLANT LEACH LIQUOR

CLARIFIER
ADD MAKE-UP
SOLUTION I F NEEDED I
I
r"l
DEAREATOR

ZlNC POWDER a
LEAD S A L T S
QOLD E X T R A C T I O N
PROCESS
ZlNC PRECIPITATE
PRESSES

I
I BARREN LEACH

I
BARREN
SOLUTION O U T
t

FIGURE 8.1
GENERALIZED FLOWSHEET OF A
MERRILL-CROWE PRECIPITATION PLANT
128 PRECIOUS METAL HEAP LEACHING PROJECTS

and s i l v e r p r e c i p i t a t i o n i s u s u a l l y complete. M a i n t a i n i n g h i g h e r f r e e c y a n i d e
c o n c e n t r a t i o n i n t h e p r e c i p i t a t i o n c i r c u i t normal l y keeps t h e copper from
p r e c i p i t a t i n g , thereby reducing passivation o f the zinc surface.

The presence o f small amounts o f l e a d i n s o l u t i o n has been found t o be

b e n e f i c i a l t o p r e c i p i t a t i o n . However, i f l e a d c o n c e n t r a t i o n s a r e t o o h i g h
( i . e . , g r e a t e r t h a 20 ppm), subsequent consumption o f z i n c i s i n c r e a s e d .

8.2.2 Carbon A d s o r p t i o n

A d s o r p t i o n Mechanism. Most t y p e s o f c h a r c o a l w i l l adsorb g o l d t o some

e x t e n t ; however, t h e most e f f e c t i v e c h a r c o a l i s produced s p e c i f i c a l 1y f o r
a d s o r p t i o n by c h a r r i n g coconut s h e l l s o r peach p i t s a t around 700 t o 800
degrees C e l s i u s i n t h e presence o f steam ( M u i r , 1982).

During the l a s t decade, a number o f i n v e s t i g a t i o n s aimed a t

u n d e r s t a n d i n g t h e mechanism o f a d s o r p t i o n o n t o carbon have been undertaken.
Although t h e r e i s much c o n f u s i o n and l i t t l e agreement amoug t h e v a r i o u s
r e s e a r c h e r s , a l l seem t o agree on t h e f o l l o w i n g p o s t u l a t e :

The a d s o r p t i o n o f g o l d c y a n i d e i n t o a porous c h a r c o a l p a r t i c l e
i n v o l v e s t h e simultaneous phenomena o f p o r e d i f f u s i o n and
a d s o r p t i o n o n t o " a c t i v e s i t e s 1 ' o r areas o f t h e carbon h a v i n g an
a f f i n i t y f o r g o l d and s i l v e r (Davidson, 1982; Ha Cho, 1979a and
1979b; McDougall , 1981).

I n v e s t i g a t i o n s on t h e a d s o r p t i o n process usual l y employ a p o r e d i f f u s i o n

model which i s t h e a d s o r p t i o n i s o t h e r m s t o F r e u n d l i c h isotherms. Study o f
carbon a d s o r p t i o n k i n e t i c s r e v e a l s t h a t t h e a c t i v a t i o n energy f o r d i f f u s i o n
demonstrates t h a t t h e l i m i t i n g s t e p i n t h e r a t e o f a d s o r p t i o n i s d i f f u s i o n .
W i t h o u t b e n e f i t o f f u r t h e r t h e o r e t i c a l development, s u f f i c e i t t o say t h a t a l l
t h e r e f e r e n c e s 1 i s t e d above a r e e x c e l l e n t sources f o r more complete coverage
o f the subject matter.

Carbon S p e c i f i c a t i o n . Commercially a v a i l a b l e carbon which i s used i n

s o l d e x t r a c t i o n from l e a c h l i q u o r s u s u a l l y comes i n two s i z e s ( i . e . , minus 6
p l u s 16 mesh o r minus 12 - 30 mesh). These p r o d u c t s a r e a v a i l a b l e from
s e v e r a l suppl i e r s . The f o l l o w i n g i s a t y p i c a l s p e c i f i c a t i o n 1 i s t f o r a c t i v a t e d
carbon :

Surface area, m21gm 1050 - 1150

Apparent d e n s i t y , g/cc 0.48
1b / f t 3 30.0
P a r t i c l e d e n s i t y , g/cc 0.85
Voids i n d e n s e l y packed column, % 40

T y p i c a l l y , t h e p r o d u c t i s a v a i l a b l e i n 5 5 - g a l l o n drums.

U n i t Operation. The carbon a d s o r p t i o n process f o r r e c o v e r y o f g o l d and

s i l v e r can be separated i n t o t h r e e m a j o r s t e p s :

Loadin - Gold and s i l v e r i s adsorbed from t h e l e a c h l i q u o r o n t o

_ 6 9p a r t i c l e s ;
c a r on
 METAL EXTRACTION (RECOVERY SYSTEMS) 129

E l u t i o n and r e a c t i v a t i o n - Gold and s i l v e r a r e desorbed from t h e

carbon i n t o a c o n c e n t r a t e d s o l u t i o n w i t h t h e s t r i p p e d carbon b e i n g
r e g e n e r a t e d and r e t u r n e d t o s t e p 1; and

+
Recover - Gold and s i l v e r a r e recovered from t h e c o n c e n t r a t e d
s o u t i o n by e l e c t r o w i n n i n g o r p r e c i p i t a t i o n on z i n c d u s t ; t h e
r e s u l t i n g barren s o l u t i o n
reactivation,
i s r e t u r n e d t o t h e e l u t i o n and
and t h e r e c o v e r e d p r e c i o u s m e t a l s a r e f i r e - r e f i n e d
t o dore b u l l i o n .

F i g u r e 8.2 ( f r o m Jha, 1979) i l l u s t r a t e s a t y p i c a l f l o w s h e e t f o r r e c o v e r y

o f g o l d and s i l v e r u s i n g carbon a d s o r p t i o n . T h i s f i g u r e h i g h l i g h t s t h e
l o a d i n g , e l u t i o n , and r e c o v e r y s t e p s o f t h e process.

Commercial o r m i n e - s i t e l a b o r a t o r y u n i t s can use s e v e r a l carbon

a d s o r p t i o n methods t o p e r f o r m t h e t h r e e s t e p s i d e n t i f i e d above. The paragraphs
which f o l l o w deal p r i m a r i l y w i t h t h e l o a d i n g s t e p and t h e v a r i o u s t e c h n i q u e s
a v a i l a b l e t o e f f e c t t h e a c t u a l a d s o r p t i o n o n t o carbon p a r t i c l e s . Chapter 9
d i s c u s s e s i n some d e t a i l t h e e l u t i o n and r e a c t i v a t i o n s t e p as w e l l as t h e
a c t u a l r e c o v e r y step.

Three methods o f l o a d i n g a r e commonly used and a r e r e f e r r e d t o as: 1 )

c a r b o n - i n - c o l umn l o a d i n g (CIC); 2 ) c a r b o n - i n - p u l p l o a d i n g (CIP) ; and carbon-
in-leach l o a d i n g (CIL).

C I C l o a d i n g r e s u l t s when l e a c h l i q u o r i s c o n t a c t e d w i t h carbon v i a a
carbon-packed column. The l i q u o r i s passed t h r o u g h t h e carbon i n an upward
d i r e c t i o n , c a u s i n g t h e carbon column t o expand v e r t i c a l l y . As a r e s u l t o f t h i s
v e r t i c a l expansion, t h e t e r m "expanded carbon bed" i s a l s o used t o d e s c r i b e
t h e process.

CIP l o a d i n g i n v o l v e s t h e i n t r o d u c t i o n o f l e a c h l i q u o r o r o r e p u l p i n t o
an a g i t a t i o n t a n k h a v i n g c o u n t e r - c u r r e n t a c t i o n ( i . e . , t h e carbon f l o w s i n one
d i r e c t i o n , w h i l e t h e 1i q u o r o r p u l p f l o w s i n a n o t h e r ) .

C I L l o a d i n g i s a c t u a l l y a l e a c h c i r c u i t v a r i a n t t h a t serves t o enhance
s i m u l t a n e o u s d i s s o l u t i o n and a d s o r p t i o n .

8.3 SELECTING A SOLUTION RECOVERY SYSTEM

T h i s s e c t i o n o u t l i n e s c o n s i d e r a t i o n s and g u i d e l i n e s f o r use i n t h e
s e l e c t i o n o f an a p p r o p r i a t e m e t a l r e c o v e r y system. As w i t h t h e o t h e r p a r t s o f
t h i s c h a p t e r , t h e d i s c u s s i o n focuses on two processes - z i n c p r e c i p i t a t i o n and
carbon a d s o r p t i o n . T a b l e 8.1 p r e s e n t s a summary comparison o f t h e two
processes.

8.3.1 When t o Use Z i n c P r e c i p i t a t i o n

Z i n c d u s t cementation, o r M e r r i l l - C o w e p r e c i p i t a t i o n i s t h e most w i d e l y
used method f o r g o l d and s i l v e r r e c o v e r y . Because o f i t s s i m p l e and e f f i c i e n t
o p e r a t i o n , t h e M e r r i l l - C r o w e process i s c u r r e n t l y used a t t h e 10 l a r g e s t g o l d
p r o d u c i n g mines i n t h e f r e e w o r l d , a l l o f which a r e i n South A f r i c a . This
process i s a t t r a c t i v e f o r use a t new mines where t h e o r e e x h i b i t s a h i g h
s i l v e r t o g o l d r a t i o ( r a n g i n g from 5 : l t o 2 0 : l ) . Ores w i t h h i g h s i l v e r values
 PRECIOUS METAL HEAP LEACHING PROJECTS

LEACHINQ

LEACHING CRUSHINQ
QRlNDlNQ
BENEFICATION
TAlLlNQS CALCINATION

CLEAN SOLUTION AQITATION

LEACHINQ

\I

CARBON-IN- CARBON-IN-
LOADINQ
\r LEACH

CARBON-IN-
COLUMN
TAILINQS

L O A D E D CARBON

PRESSURE ATMOSPHERIC ORQANIC

STRIPPINQ STRIPPINQ STRIPPINQ

1r

CONC. SOLUTION

RECOVERY m
Z I N C DUST
CEMENT ATION

u D O R E BULLION

FIGURE 8.2
FLOWSHEET FOR RECOVERY OF GOLD AND SILVER
USING CARBON ADSORPTION
 METAL EXTRACTION (RECOVERY SYSTEMS)

TABLE 8.1 - SUMMARY OF ADVANTAGES AND DISADVANTAGES OF

CARBON ADSORPTION AND MERRILL-CROWE PRECIPITATION

MERRZLL-CROWE

ADVANTAGES DISADVANTAGES

Low l a b o r c o s t s f o r o p e r a t i o n Pregnant s o l u t i o n needs pre-

and maintenance; treatment p r i o r t o p r e c i p i -
tation.

Low c a p i t a l c o s t ; and Process i s s e n s i t i v e t o i n t e r -

f e r i n g i o n s ; and

Can handle l a r g e s i l v e r t o Low p r e c i o u s metal concentra-

g o l d r a t i o s i n t h e pregnant t i o n i n s o l u t i o n increases the
1i q u o r . quantity o f zinc required t o
p r e c i p i t a t e an ounce o f m e t a l .

CARBON SYSTEMS

ADVANTAGES DISADVANTAGES

No p r e - t r e a tment o f pregnant High s i l v e r grade i n pregnant-

1 iquor r e q u i r e d ; l i q u o r r e s u l t s i n h i g h carbon
movement;

Process handles s l imy and Carbon i s s u s c e p t i b l e t o f o u l -

carbonaceous o r e s ; and i n g b y c a l c i u m and magnesium
salts;

Very e f f i c i e n t r e c o v e r i e s , Carbon r e g e n e r a t i o n and s t r i p -

i r r e s p e c t i v e o f incoming p i n g i s l a b o r i n t e n s i v e ; and
precious metal concentration.
A d s o r p t i o n processes have a
h i g h e r c a p i t a l c o s t than z i n c
cementation o p e r a t i o n s .
132 PRECIOUS METAL HEAP LEACHING PROJECTS

p r e s e n t s i g n i f i c a n t problems t o c a r b o n a d s o r p t i o n c i r c u i t s because t h e s i l v e r
causes h i g h c a r b o n s t r i p p i n g r e q u i r e m e n t s w h i c h may be e c o n o m i c a l l y
prohibitive. Several of the e x i s t i n g operations using Merrill-Crowe
p r e c i p i t a t i o n a c t u a l l y experience higher s i l v e r recoveries than gold.

One o t h e r advantage t o t h e z i n c c e m e n t a t i o n system i s t h a t once dyamic

e q u i l i b r i u m ( s t e a d y s t a t e ) i s reached i n t h e p r o c e s s p l a n t s , r e l a t i v e l y few
p e o p l e a r e r e q u i r e d f o r o p e r a t i o n and m a i n t a i n e n c e ( i . e . , o n l y simple valve
o p e r a t i o n and m e t e r r e a d i n g t a s k s a r e r e q u i r e d ) .

The p r o c e s s does, however, have some d i s a d v a n t a g e s . The l e a c h l i q u o r

must be t r e a t e d ( i e . , c l a r i f i e d and d e a r e a t e d ) p r i o r t o p r e c i p i t a t i o n .
Indeed, as n o t e d i n a p r e c e d i n g s e c t i o n , i n e f f i c i e n t pretreatment i s
d e t r i m e n t a l t o s u c c e s s f u l p r e c i p i t a t i o n . O t h e r d i s a d v a n t a g e s stem f r o m t h e
p r o c e s s b e i n g q u i t e dependent on and s e n s i t i v e t o t h e p r e g n a n t l i q u o r
composition. Lower go1 d c o n c e n t r a t i o n s i n t h e f e e d s o l u t i o n r e s u l t i n h i g h e r
z i n c consumption. T h i s i s because t h e z i n c i s m o s t l y used t o p r e c i p i t a t e a l l
o f t h e o t h e r m e t a l s i n s o l u t i o n b e f o r e g o l d and s i l v e r a r e r e c o v e r e d . A l s o ,
i n t e r f e r i n g i o n s such as a r s e n i c and a n t i m o n y can be p r o b l e m a t i c , l e a d i n g , i n
some cases, t o t h e c o n s i d e r a t i o n o f o t h e r r e c o v e r y methods.

8.3.2 When t o Choose Carbon A d s o r p t i o n

A c t i v a t e d c a r b o n r e c o v e r y systems have g a i n e d a w i d e a c c e p t a n c e i n t h e
g o l d i n d u s t r y w i t h i n t h e l a s t 1 0 y e a r s . As a l l u d e d t o e a r l i e r , one o f t h e
m a j o r advantages o f t h i s process i s r e l a t e d t o t h e f a c t t h a t l e a c h l i q u o r does
n o t have t o be t r e a t e d p r i o r t o r e c o v e r y . I n t h e C I C p r o c e s s ( w h i c h i s
commonly used i n c o n j u n c t i o n w i t h heap l e a c h i n g ) t h e p r e g n a n t l i q u o r i s r u n
t h r o u g h a bed o f c a r b o n w i t h o u t p r e t r e a t m e n t .

S l i m y and carbonaceous o r e s p r e s e n t few problems t o c a r b o n a d s o r p t i o n

systems, u n l i k e t h e M e r r i l l - C r o w e system w h i c h i s s e n s i t i v e t o t h e s e . The CIP
o r C I L p r o c e s s e s e l i m i n a t e t h e need f o r compl i c a t e d s o l i d - 1 i q u i d s e p a r a t i o n .
Carbon systems seem t o o p e r a t e a t a maximum e f f i c i e n c y , i r r e s p e c t i v e o f f e e d
s o l u t i o n grade. Thus, r e c o v e r i e s may be b e t t e r w i t h c a r b o n systems i f none o f
t h e c o m p l i c a t i n g f a c t o r s d i s c u s s e d below o r l i s t e d on T a b l e 8.1 a r e i n v o l v e d .
However, t h e c a r b o n can e a s i l y be f o u l e d by d i s s o l v e d s a l t s , i n p a r t i c u l a r
c a l c i u m o r magnesium c a r b o n a t e s . Carbon can a l s o be f o u l e d b y o r g a n i c
compounds 1 ik e o i l s and f l o t a t i o n r e a g e n t s .

Carbon systems t e n d t o be more l a b o r i n t e n s i v e , o f t e n r e q u i r i n g f r e q u e n t

a c i d washing o r r e a c t i v a t i o n . The e l u t i o n and r e g e n e r a t i o n s t e p s a r e t h e m o s t
e x p e n s i v e p a r t s o f t h e f l o w s h e e t . P r e s s u r e s t r i p p i n g appears t o be t h e most
p o p u l a r method i n c u r r e n t use, a l t h o u g h work i s c o n t i n u i n g on development o f
s e v e r a l o r g a n i c s t r i p p i n g methods. F o l l o w i n g c a r b o n s t r i p p i n g , a process such
as z i n c c e m e n t a t i o n o r e l e c t r o w i n n i n g m u s t be used t o t r e a t t h e c o n c e n t r a t e d
l i q u o r ; each o f t h e s e s u p p l e m e n t a r y processes p r e s e n t s i t s own o p e r a t i o n a l
c o ~ n pilc a t i o n s .

W i t h b o t h M e r r i l l - C r o w e and c a r b o n systems, i t i s p r u d e n t t o i n v e s t i g a t e
t h e e x i s t e n c e and e f f e c t o f m e r c u r y i n t h e p r e g n a n t s o l u t i o n . I n c r e a s i n g l y ,
o p e r a t i o n s a r e having t o deal w i t h o p e r a t i o n a l d i f f i c u l t i e s associated w i t h
t h e e x i s t e n c e o f m e r c u r y . M e r c u r y t e n d s t o be d e t r i m e n t a l t o t h e o p e r a t i o n ,
c a u s i n g an i n c r e a s e i n t h e consumption o f z i n c on t h e one hand, and d e c r e a s i n g
 METAL EXTRACTION (RECOVERY SYSTEMS)

t h e u l t i m a t e l o a d i n g o f g o l d o n t o t h e carbon, on t h e o t h e r . M e r c u r y p a s s i f i e s
t h e z i n c i n t h e M e r r i l l - C r o w e p r o c e s s , and o c c u p i e s v a l u a b l e a c t i v e s u r f a c e
space i n c a r b o n a d s o r p t i o n .

8.3.3 Economic C o n s i d e r a t i o n s

S e v e r a l economic comparisons have been made between c a r b o n systems and

M e r r i l 1-Crowe systems. One o f t h e s e , a s y s t e m a t i c comparison c o m p l e t e d b y
DeMent and K i n g ( 1 9 8 2 ) i s summarized below.

F i v e s e p a r a t e c o n v e n t i o n a l m i l 1 s i n v o l v i n g b o t h M e r r i l l -Crowe and t h e
CIP p r o c e s s e s were compared from an economic v i e w p o i n t . The go1 d c o n c e n t r a t i o n
on t h e f e e d l e a c h l i q u o r ranged from 0.428 t o 0.054 oz o f g o l d p e r t o n (14.6
t o 1.8 g/mt) o f s o l u t i o n .

C a p i t a l c o s t s a t t h e f r o n t end o f a CIP p l a n t a r e based on i n c o m i n g f l o w

r a t e , and a r e n o t a f u n c t i o n o f t h e g o l d grade. However, t h e c a p i t a l c o s t s o f
c a r b o n s t r i p p i n g r e c o v e r y p o r t i o n s do v a r y , as t h e y a r e dependent on t h e grade
o f g o l d i n t h e s o l u t i o n . Carbon r e g e n e r a t i o n i s a l s o dependent on t h e amount
o f c a r b o n processed. On t h e o t h e r hand, w i t h a M e r r i l l - C r o w e process, t h e
total capital cost i s solely a function o f the i n i t i a l flow rate.

O p e r a t i n g c o s t s v a r y i n t h e CIP p l a n t a c c o r d i n g t o t h e grade o f g o l d i n
t h e l e a c h l i q u o r . T h i s c o s t does n o t v a r y w i t h t h e M e r r i l l - C r o w e e x c e p t i n t h e
case o f z i n c usage w h i c h i n c r e a s e s w i t h h i g h e r i n p u t c o n c e n t r a t i o n s .

G o l d l o s s e s i n c o n v e n t i o n a l CIP p l a n t s r e s u l t f r o m p r e g n a n t v a l u e s w h i c h
are n o t adsorbed o n t o c a r b o n and a r e t h e r e f o r e d i s c a r d e d t o t a i l s . Another
gold l o s s o c c u r s whenever g o l d i s l o a d e d o n t o v e r y f i n e c a r b o n p a r t i c l e s . T h i s
fine c a r b o n passes a l l s c r e e n s and a l s o ends u p i n t a i l i n g s . The main g o l d
loss i n a M e r r i l l - C r o w e c i r c u i t has a much d i f f e r e n t s o u r c e (i.e., it results
from i n c o m p l e t e washing o f t h e f i l t e r cake on t h e p r e c i p i t a t e p r e s s e s ) .

DeMent and K i n g ' s r e s u l t s a r e based on e s t i m a t e d c o s t s o f a CIP and

M e r r i l l - C r o w e p l a n t , b e a r i n g i n m i n d t h a t c o s t s a r e dependent on t h e
p a r t i c u l a r c h a r a c t e r i s t i c s o f each o r e . However, i t seems p e r t i n e n t t o p o i n t
o u t t h a t w i t h i n one o p e r a t i o n u s i n g M e r r i l l - C r o w e p r e c i p i t a t i o n , t h e a u t h o r ' s
p e r s o n a l e x p e r i e n c e showed t h a t f o r a 1ower g r a d e 1each 1 i q u o r , M e r r i 11 -Crowe
was s e l e c t e d . I n t h e p l a n t i n q u e s t i o n , t h e d e c i s i o n was made t o u s e z i n c
p r e c i p i t a t i o n based on t h e v a r y i n g g r a d e o f p r e g n a n t 1 i q u o r ( f r o m 0.075 ounces
p e r t o n t o 0.010 ounces p e r t o n (2.6 t o 0.3 g/mt) g o l d ) . As o p e r a t i n g c o s t s
were n e g l i g i b l y a f f e c t e d b y t h i s v a r i a t i o n , t h e d e s i g n d e c i s i o n p r o v e d
profitable.

I t i s w o r t h n o t i n g t h a t o p e r a t i o n s do e x i s t w h i c h combine c a r b o n
adsorption with zinc precipitation. Usually a zinc precipitation plant i s
f o l l o w e d b y a C I C s e t up. T h i s i s done t o enchance t h e removal o f g o l d f r o m
b a r r e n s o l u t i o n coming f r o m t h e z i n c c i r c u i t . V e r y f r e q u e n t l y , i f no c l e a r
d i s t i n c t i o n i s e v i d e n t as t o w h e t h e r z i n c o r c a r b o n i s t h e b e s t c h o i c e , t h e
f i n a l d e c i s i o n i s based on t h e p a r t i c u l a r e x p e r i e n c e o f t h e p r o j e c t p e r s o n n e l
who w i l l be o p e r a t i n g t h e proposed p l a n t .
134 PRECIOUS METAL HEAP LEACHING PROJECTS

8.4 COMMERCIAL DESIGN & CONSTRUCTION

8.4.1 Zinc P r e c i p i t a t i o n

Portable Units/Shelf Units. Depending on t h e e x p e c t e d f l o w r a t e and t h e

s i z e o f o p e r a t i o n , M e r r i l l - C r o w e z i n c p r e c i p i t a t i o n u n i t s c a n come i n a
v a r i e t y o f . s i z e s . These r a n g e f r o m 20 g a l - l o n s m i n u t e (1.3 l l s e c ) i n s m a l l
s e l f - c o n t a i n e d u n i t s t o 4,000 - 5,000 gpm (250 t o 315 l l s e c ) t h r o u g h p u t i n
custom p l a n t s .

S m a l l e r skid-mounted u n i t s a r e a v a i l a b l e f r o m s e v e r a l s u p p l i e r s . Each
u n i t comes equipped w i t h a l l t h e n e c e s s a r y pumps and p i p i n g . A l l t h e u s e r must
p r o v i d e i s a feed l i n e t o t h e u n i t , an e f f l u e n t ( b a r r e n ) l i n e o u t , and
e l e c t r i c a l s u p p l y . These u n i t s a r e v e r y u s e f u l f o r ranges o f f l o w s f r o m 50 t o
250 gpm ( 3 t o 16 l l s e c ) . They a r e e a s i l y assembled o r d i s m a n t l e d and o f t e n a r e
mounted on t r a i l e r s f o r easy t r a n s p o r t a t i o n . However, beyond a c e r t a i n p o i n t ,
i t becomes a p p a r e n t t h a t t h e f i l t r a t i o n s u p p l i e d w i t h t h e s e u n i t s i s
i n s u f f i c i e n t f o r optimum o p e r a t i o n . The o p e r a t o r may spend more t i m e c l e a n i n g
t h e c l a r i f i e r f i l t e r s t h a n a c t u a l l y t r e a t i n g s o l u t i o n . I t i s f o r t h i s reason
t h a t o p e r a t i o n s a r e custom d e s i g n e d f o r h a n d l i n g l a r g e d a i l y volumes o f
pregnant s o l u t i o n .

Custom Designed U n i t s . Here t h e c h o i c e o f s i z e and volume t h r o u g h p u t i s

n o t l i m i t e d . T y p i c a l l y , t h e d e s i g n s a r e based on an e x p e c t e d volume o f
requirements, w i t h a b u i l t - i n over-design included. S t a t i o n a r y pressure
filters, o r t h e l e a f - v a c u u m t y p e , a r e i n c o r p o r a t e d as w e l l as vacuum
d e a r e a t o r s . P l a t e and frame p r e s s e s a r e o f t e n a s t a n d a r d . L a r g e r t h r o u g h p u t s
o f t h e s e p l a n t s j u s t i f y i n s t r u m e n t a t i o n such as t u r b i d i m e t e r s o r c o n t i n u o u s
f l o w ( i n - l i n e ) oxygen p r o b e d e t e c t o r s t o f a c i l i t a t e t h e o p e r a t i o n and improve
efficiency.

Disadvantages a r e i n h e r e n t w i t h t h e s i z e o f t h e p l a n t s . They a r e u s u a l l y
permanent i n s t a l l a t i o n s and a r e e x p e n s i v e t o r e l o c a t e .

8.4.2 Carbon A d s o r p t i o n

Small Commercial O p e r a t i o n s . As w i t h z i n c c e m e n t a t i o n u n i t s , a l a r g e
v a r i e t y o f s i z e s o f c a r b o n a d s o r p t i o n u n i t s a r e a v a i l a b l e . A l t h o u g h o n l y a few
s h e l f u n i t s a r e a v a i l a b l e , columns a r e designed f o r s p e c i f i c l e a c h l i q u o r f l o w
rates .
S m a l l e r u n i t s a r e designed t y p i c a l l y w i t h f o u r o r f i v e columns i n
s e r i e s . The p r e g n a n t l i q u o r f l o w s t h r o u g h a bed o f a c t i v a t e d carbon. The
s o l u t i o n i s t h e n r o u t e d f r o m t h e t o p o f t h e f i r s t column, t h r o u g h a n o t h e r bed
o f c a r b o n i n t h e b o t t o m o f column 2, i n t h e f o l l o w i n g f a s h i o n ( F i g u r e 8.3).
The c a r b o n i s eductedl c o u n t e r c u r r e n t l y f r o m t h e f l o w o f t h e l e a c h 1 i q u o r .
Thus, i n t h e F i g u r e 8.3 example, t h e c a r b o n f l o w s f r o m t h e l a s t column ( # 3 ) t o
t h e second, and t h e n t o column # l . Fresh c a r b o n i s i n t r o d u c e d t o column #3 and
f u l l y l o a d e d c a r b o n i s removed f r o m column # l .

l ~ d u c t i o nr e f e r s t o t h e t r a n s p o r t a t i o n o f c a r b o n i n a s l u r r y .
 METAL EXTRACTION (RECOVERY SYSTEMS)

Large Commercial Operations. L a r g e r p l a n t s i n c o r p o r a t e l a r g e r columns

t o handle t h e l a r g e r volume throughputs. Most p l a n t s o p e r a t e w i t h a carbon bed
expansion approaching 60 t o 70 p e r c e n t . Therefore, t h e bottom 113 o f t h e
column i s loaded w i t h carbon, such t h a t a f t e r expansion t h e carbon column
depth amounts t o r o u g h l y t w o - t h i r d s o f t h e t a n k depth; o n e - t h i r d o f t h e depth
i s a v a i l a b l e f o r free-board.

FIGURE 8.3 TYPICAL CONFIGURATION OF A

CARBON-IN-COLUMN PLANT

COLUMN

S O L U T I O N FLOW- t rl
COLUMN

Generally, t h e s o l u t i o n f l o w r a t e r e q u i r e d t o m a i n t a i n f l u i d i z a t i o n i n a
bed o f carbon c o n t a i n i n g minus 6 - p l u s 16 mesh p a r t i c l e s i s about 25 g p m / f t 2
(17 l/s/m2) o f c r o s s - s e c t i o n a l area o f t h e column, whereas f o r t h e minus 12 -
p l u s 30 mesh carbon, t h e r e q u i r e d flow i s 15 gpm/ft2 (10 l/s/m2). Under these
c o n d i t i o n s , t h e carbon bed expands about 60 p e r c e n t .

As can be seen, t h e column d i a m e t e r requirements a r e dependent on t h e

f l o w r a t e requirements. Whereas s m a l l e r o p e r a t i o n s m i g h t s t o c k p i l e t h e i r
loaded carbon and t r e a t i t elsewhere i n b u l k , l a r g e r o p e r a t i o n s would have
e l u t i o n - r e g e n e r a t i o n - r e c o v e r y u n i t o p e r a t i o n s on s i t e .
136 PRECIOUS METAL HEAP LEACHING PROJECTS

8.5 REFERENCES

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g r a n u l a r a c t i v a t e d c a r b o n f o r use i n a c a r b o n - i n - p u l p o p e r a t i o n , i n
C a r b o n - i n - p u l p t e c h n o l o g y f o r t h e e x t r a c t i o n o f g o l d , A u s t r . I n s t . i in.
Met., P a r k v i l l e , A u s t r a l i a , pp. 199-218.

DeMent , E.R., and N. D. K i n g (1982). M e r r i l 1 -Crowe/carbon-in-pul p, an economic

evaluation, The Aust .
P e r t h and Ka1 g o o r l i e Branches and Murdoc k
Un iv e r s it y , J u l y .

F i n k e l s t e i n , N.P. ( 1 9 7 2 ) . The c h e m i s t r y o f t h e e x t r a c t i o n o f g o l d from i t s

o r e s , in Gold m e t a l l u r g y i n South A f r i c a , ed. R.J. Adamson, Chamber o f
Mines o f South A f r i c a , Johannesburg, pp. 284-351.

Ha Cho, E., and C.H. P i t t (1979a). The a d s o r p t i o n o f s i l v e r c y a n i d e on

a c t i v a t e d c h a r c o a l , The Metal 1 u r g i c a l S o c i e t y o f AIME.

Ha Cho, E., and C.H. P i t t (1979b). K i n e t i c s and thermodynamics o f s i l v e r

c y a n i d e a d s o r p t i o n on a c t i v a t e d c h a r c o a l , 'The M e t a l l u r g i c a l S o c i e t y o f
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Heinen, H.J., D.G. Peterson, and R.E. L i n d s t r o m ( 1 9 7 6 ) . Gold d e s o r p t i o n f o r

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c o m p a r a t i v e s t u d y o f v a r i o u s processes, AMAX E x t r a c t i v e Research and
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McDougal1 , G. J., and R.D. Hancock (1981). Gold complexes and activated
carbon, J. South A f r i c a n I n s t . Min. Met., pp. 138-152, A p r i l .

Muir, D.M. ( 1 9 8 2 ) . Recovery o f g o l d from c y a n i d e s o l u t i o n s u s i n g a c t i v a t e d

c a r b o n : a r e v i e w , in Carbon- i n - p u l p t e c h n o l o g y f o r t h e e x t r a c t i o n o f
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N i c o l , M.J., E. Schalch, P. B a l e s t r a , and H. Hegedus (1979). A modern s t u d y

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Zadra, J.B., A.L. Engel, and H.J. Heinen ( 1 9 5 2 ) . Process f o r r e c o v e r i n g g o l d

and s i l v e r from a c t i v a t e d c a r b o n b y l e a c h i n g and e l e c t r o l y s i s , R e p o r t o f
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