Version 2 – 28.05.
2017, replaces
version 1 – 15.01.2013
SAFETY DATA SHEET
FOR LPG
1. Product and company 1.1 Product Identifier
identification Product name
LPG
Registry code (DK)
Propane 1892267
Butane 1892275
Synonyms
Kosangas, Kosan Autogas, Kosan Propane, Kosan Butane, Kosan Mix, Kosan Isobutane,
bottled gas, F gas.
Index No.
Propane: 601-003-00-5
Butane/Isobutane: 601-004-00-0
LPG mix: 601-003-00-5/601-004-00-0
This product is exempted for registration under REACH re article 2(7)(b).
1.2 The product should only be used as described in section 1.2
Relevant identified uses: Fuel for domestic, commercial and industrial purposes and for combustion
engines. Can also be used for aerosol propellant.
1.3 Details of the supplier of the safety data sheet
Kosan Gas a/s Telephone
Hasselager Centervej 19-21 +45 8948 7700
DK-8260 Viby J
Email
www.kosangas.dk post@kosangas.dk
1.4 Emergency telephone number
Kosan Gas emergency telephone Poison Information Centre (Bispebjerg Hospital)
+45 8948 7700 +45 8212 1212
2. Hazard 2.1 Classification of the substance or mixture
identification Classification in accordance with regulation 1272/2008 (CLP): Flam. Gas 1 Press. Gas.
Hazard statements
H220 Extremely flammable gas
H280 Contains pressurised gas, may explode when heated
2.2 Label elements
CLP
SAFETY DATA SHEET FOR LPG 1/9
Hazard symbols
Flammable Gas under pressure
Signal word
Danger
Precautionary statements – general
P102 Keep out of reach of children.
Precautionary statements – preventive measures
P210 Keep away from heat/sparks/open fire/hot surfaces. No smoking.
P243 Take precautionary measures against static discharge.
Precautionary statements – response
P377 Fire from leaking gas: Do not extinguish, unless leak can be stopped safely.
P381 Eliminate all ignition sources if safe to do so.
Precautionary statements – storage
P410 + P403 Protect from sunlight. Store in a well-ventilated place.
Precautionary statements – disposal
P501 Dispose of contents/container in accordance with local
waste regulations.
2.3 Other hazards
High concentrations of gas will displace oxygen in air. This may lead to sudden loss of conscious-
ness and death due to oxygen deficiency. Exposure to liquid LPG may cause cold burns on eyes
and/or skin.Vapour is heavier than air and may drift along the ground and reach distant ignition
sources which may lead to back firing. Static electricity may accumulate during pumping. Static
electricity may result in fire.
3. Composition and 3.1 Substances
ingredient information LPG is treated under item 3.2.
3.2 Mixtures
Substances Index no. CAS/EC no. CLP – 1272/2008 W/W %
Propane* 601-003-00-5 74-98-6 Flam. Gas 1 Press. >92.5
200-827-9 Gas; H220, H280
Butane* 601-004-00-0 106-97-8 Flam. Gas 1 Press. >92.5
203-448-7 Gas; H220, H280
LPG mix* 601-003-00-5 74-98-6 Flam. Gas 1 Press. 20-40
(Propane/butane) 601-004-00-0 106-97-8 Gas; H220 60-80
Isobutane 601-004-00-0 75-28-5 Flam. Gas 1 Press. >95
200-857-2 Gas; H220
1,3-Butadiene 203-450-8 Flam. Gas 1, Press <0,1
Gas, Carc. 1A, Muta
1B, H220, H350, H340
*Odorant/ 016-022-00-9 75-08-1 Flam. Liq.2, Aquatic >10 PPM
Ethyl mercaptan Chronic 1, Acute Tox 4
// H225, H332, H400,
H410
*Odorant/Vigileak 200-800-2 75-66-1 Flam. Liq. 2:H225, >6 PPM
2-Methylpropane- 200-846-2 75-18-3 Skin Sens. 1B;H317
2-thiol/Dimethyl Aquatic Chronic 2;
Note: *Either ethyl mercaptan sulphide H411
or Vigileak Eye Irit.2; H319
SAFETY DATA SHEET FOR LPG 2/9
4. First aid measures 4.1 Description of first aid measures
Inhalation
Move to fresh air. Keep the injured person under supervision.
Call the Poison Information Centre or a doctor immediately.
Skin Contact
Remove contaminated clothing, rings, watches etc., but not if they are adhering to the skin.
Wash/rinse with clean water. Seek medical attention if lasting discomfort.
Eye contact
Rinse with large amounts of water. If possible, remove any contact lenses. Protect the eyes with
a sterile dressing. Seek immediate medical attention.
Ingestion
Not a likely exposure. Frostbite on lips and mouth must be rinsed with water.
Other information:
4.2 Most important symptoms and effects, both acute and delayed
Inhalation of gas may cause drowsiness, headache, blurred vision or irritation of the eyes, nose
or throat. Continuous exposure can result in loss of consciousness and/or death.
4.3 Indication of any immediate medical attention and special treatment needed
Symptomatic medical attention. Show this safety data sheet to the doctor or emergency
department.
5. Firefighting measures 5.1 Extinguishing media
Suitable extinguishing media
Shut off the gas supply.
Large fire – water sprinkling/mist for cooling.
Small fire – powder extinguisher type ABC.
Unsuitable extinguishing media
Foam.
Avoid direct water on gas pool which causes a quick evaporation of the gas and an increased
fire risk.
5.2 Special hazards arising from the substance or mixture
Risk of explosion on pressure rise in closed containers.
Risk of explosion (BLEVE) if pressurised containers are exposed to heat from fire. Cool the
container using water or move to a safe place, if possible. Gas is heavier than air and may drift
along the ground, drainage systems or ditches. Complete combustion produces carbon dioxide
and water vapour. Incomplete combustion produces carbon monoxide, which is toxic.
5.3 Advice for firefighters
If there is a risk of exposure to fumes and flue gases, fire fighters should wear all-covering,
fire-resistant clothing and self-contained breathing apparatus. Static electricity may accumulate
during pumping. Static electricity may result in fire.
6. Accidental release 6.1 Personal precautions, protective equipment and emergency procedures
measures
6.1.1 For non-emergency personnel
Evacuate the area. Shut off the gas supply if this can be done without risk.
Remove ignition sources – choose a safe place in relation to the wind direction.
6.1.2 For emergency responders
Evacuate the area. Shut off the gas supply. Remove ignition sources. Avoid gas leakage in
confined areas like basements and drainage systems.
6.2 Environmental precautions
Avoid unnecessary emission to the surroundings – does not cause pollution to soil or water.
SAFETY DATA SHEET FOR LPG 3/9
6.3 Methods and material for containment and clean-up
Shut off the gas supply. Leave the liquefied gas to evaporate so that the gas is rarefied into a
safe concentration in the atmosphere. Check and mix the gas with water spray where appropriate.
Ventilate gas thoroughly from confined spaces.
6.4 Reference to other sections
Information about suitable equipment, see section 8.
7. Handling and storage 7.1 Precautions for safe handling
Smoking and open fires are prohibited. LPG is intended for use in closed systems. Ensure adequate
ventilation. Avoid inhalation of gas. Wear suitable personal protective equipment.
7.2 Conditions for safe storage, including any incompatibilities
The product should be stored safely and out of reach of children. To be kept only in closed and
approved pressure containers. Use explosion-proof equipment. Handling systems must be
earthed and have equipotential bonding. The vapours are heavier than air and can therefore
accumulate in low-lying areas, such as vehicle inspection pits, basements, channels and wells,
and reach sources of ignition far away. Placement below ground level is therefore not permitted.
Empty containers that have not been cleaned should be treated as full containers. Do not remove
labelling.Handling and storage of large amounts of LPG requires authority approval. See the
local/national regulations for gas.
7.3 Specific end use
See point 1.2
Other information
Certain grades of rubber will be damaged by the gas. Contact the gasket supplier regarding the
choice of rubber grade.
8. Exposure controls/ 8.1 Control parameters
personal protection
Substance Limit value – ppm
Propane 1000
Butane 800
LPG mix/Butane/Propane 800/1000
Isobutane 1000
Limit values – comment
The values of the American Conference Governmental Industrial Hygienists have been specified
above as a guide.
8.2 Exposure controls/personal protection
8.2.1 Appropriate exposure control measures
LPG is handled in a closed system. Explosion-proof exhaust ventilation. Gas detectors.
8.2.2 Individual protection measures such as personal protective equipment
Protection of eyes/face
For protection of skin or eyes in case of direct contact with or splashes of gas, a face shield or
protection glasses in line with EN 166 must be worn.
Protection of skin/hands
If there is a risk of direct contact or splashes, gloves in line with EN 374 must be worn.
The gloves must not become stiff at low temperatures and should be easy to remove.
Protection of skin/other
If there is a risk of direct contact or splashes, all-covering fire resistant clothing must be worn, to
protect against frostbite and fire injuries.
8.2.3 Environmental exposure controls
None, since LPG is handled in closed systems.
SAFETY DATA SHEET FOR LPG 4/9
9. Physical and chemical 9.1 Information on basic physical and chemical properties
properties LEL = Lower Explosion Limit
Properties Propane Butane LPG mix Isobutane
Appearance Colourless Colourless Colourless Colourless
Odour Odourless – distinct Odourless – distinct Odourless – distinct Odourless – distinct
and unpleasant odour and unpleasant odour and unpleasant odour and unpleasant odour
added added added added
Odour threshold Typically 20% of LEL Typically 20% of LEL Typically 20% of LEL Not relevant
pH value Not relevant Not relevant Not relevant Not relevant
Melting/freezing point Typically -187.6 to Typically -187.6 to Typically -187.6 to Typically -187.6 to
-138.3°C -138.3°C -138.3°C -138.3°C
Boiling Point Typically -42°C Typically -0.5°C Typically -20°C Typically -11°C
Flash Point Typically -104°C Typically < -50°C Typically -104°C Typically < -50°C
Evaporation Rate Not relevant Not relevant Not relevant Not relevant
Flammability Inflammable Inflammable Inflammable Inflammable
Upper-lower flammability or ex- 2.2-9.5 vol% gas in air 1.8-9 vol% gas in air 2.2-10 vol% gas in air 1.8-8.5 vol% gas in air
plosion limit
Vapour pressure at +40°C Typically 13 bar (g) Typically 3.2 bar (g) Typically 9 bar (g) Typically 4.8 bar (g)
Density, vapour kg/m3 at 0°C Typically 2.0 Typically 2.7 Typically 2.3 Typically 2.7
and 1013 mbar
Relative density (air = 1) Typically 1.6 Typically 2.1 Typically 1.9 Typically 2.1
Density, liquid kg/m3 at 15°C Typically 507 Typically 585 Typically 550 Typically 565
Solubility Insignificant in water Insignificant in water Insignificant in water Insignificant in water
Distribution coefficient Typically 1.815 Not determined Typically 1.815 Not determined
(n-octanol-water)
Self-ignition temperature Typically 450°C Typically 420°C Typically 450°C Typically 494°C
Decomposition temperature Not relevant Not relevant Not relevant Not relevant
Gaseous viscosity Not relevant Not relevant Not relevant Not relevant
Explosive properties Not relevant Not relevant Not relevant Not relevant
Oxidising properties Not relevant Not relevant Not relevant Not relevant
9.2 Other information
Not relevant.
SAFETY DATA SHEET FOR LPG 5/9
10. S
tability and 10.1 Reactivity
reactivity Not reactive.
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Extremely flammable.
10.4 Conditions to avoid
Ignition sources – heat, flames, sparks.
10.5 Materials to avoid
Materials not approved for use with LPG.
Only use sealants and sealing materials documented to withstand LPG.
10.6 Hazardous decomposition products
Not relevant.
11. Toxicological 11.1 Information on toxicological effects
information
Substance Exposure Species Test Result
Propane/Butane/Iso- Inhalation Mouse LC50/2hr 1237 mg/L air
butane
Inhalation
Non-irritating. Inhalation of concentrations above 10% may cause narcotic effects, headaches,
nausea, visual disturbance and dizziness. Inhalation of high concentrations may affect the central
nervous system and cardiac function. May cause loss of consciousness and death.
Skin
Non-irritating (vapour form). Frostbite from evaporation of liquefied gas.
Eyes
Non-irritating (vapour form). Frostbite from evaporation of liquefied gas.
Ingestion
Not relevant.
Repeated dose toxicity
Not known.
Carcinogenic
Not classified as a carcinogenic material (1,3-butadiene < 0.1%).
Mutagenic effects
Not considered mutagenic.
Reproductive toxicity
Not known.
11.2 Other information
LC50 (inhalation) low toxicity > 20 mg/l.
SAFETY DATA SHEET FOR LPG 6/9
12. Ecological information 12.1 Toxicity
Substance Test Species Test Result
duration
Propane/Butane/Iso- 96 h Fish LC50 27.98 mg/L
butane
Propane/Butane/Iso- 48 h Daphnia LC50 14.22 mg/L
butane
Propane/Butane/Iso- 96 h Algae EC50 7.71 mg/L
butane
LPG evaporates quickly on contact with water. No acute or chronic impact in practice.
12.2 Persistence and degradability
Substance Biodegradability in Test Result
the
aquatic environment
Propane/Butane/Isobu- Yes Biodegradation test 100% after 385.5 h
tane
Quick oxidation by photochemical reaction in air.
12.3 Bioaccumulative potential
Substance Potentially LogPow BCF
bioaccumulative
Propane/Butane/Isobu- No 1.09 -
tane
Not expected to bioaccumulate.
12.4 Mobility in soil
Not relevant since LPG is extremely volatile.
12.5 Results of PBT and vPvB assessment
Hydrocarbons in the product do not meet the criteria for PBT or vPvB evaluation.
12.6 Other adverse effects
Global warming potential (GWP100) for non-combusted gas 3.3
13. Disposal 13.1 Waste treatment methods
considerations
Chemical waste group EWC code Waste type
Z 16 05 04 Gases in pressure containers (including
halons) containing substances
The properties and applications of the product result in no waste being generated.
Special labelling
Used or empty containers should be returned to Kosan Gas.
Returned containers must be labelled in accordance with ADR rules.
NB: Returned containers must be labelled with:
SAFETY DATA SHEET FOR LPG 7/9
14. T
ransport information
Road transport – ADR
Propane Butane LPG mix Isobutane
UN number 1965 1965 1965 1969
UN shipping name Hydrocarbon gas mix- Hydrocarbon gas mix- Hydrocarbon gas mix- Isobutane
ture, liquefied n.o.s. ture, liquefied n.o.s. ture, liquefied n.o.s.
(Mixture C) (Mixture A) (Mixture A1)
Hazard class/label 2.1
Hazard number 23
Packing group Not relevant
Environment hazard No
Special precautionary meas- Do not throw containers or expose to shock.
ures for the user During use the container must be placed in the correct position.
Railway transport – RID
Propane Butane LPG mix Isobutane
UN number 1965 1965 1965 1969
UN shipping name Hydrocarbon gas mix- Hydrocarbon gas mix- Hydrocarbon gas mix- Isobutane
ture, liquefied n.o.s. ture, liquefied n.o.s. ture, liquefied n.o.s.
(Mixture C) (Mixture A) (Mixture A1)
Hazard class/label 2.1
Hazard number 23
Railway classification Hazard label 13
Packing group Not relevant
Environment hazard No
Special precautionary meas- Do not throw containers or expose to shock.
ures for the user During use the container must be placed in the correct position.
Transport by ship – IMDG
Propane Butane LPG mix Isobutane
UN number 1965 1965 1965 1969
Proper shipping name Hydrocarbon gas, Hydrocarbon gas mix- Hydrocarbon gas mix- Isobutane
mixture, liquefied, ture, liquefied n.o.s. ture, liquefied n.o.s.
n.o.s. (Mixture A) (Mixture A1)
(Mixture C)
Hazard class/label 2.1
Packing group Not relevant
EMS F-D, S-U
Segregation group None
Sea polluting No
Special precautionary meas- Do not throw containers or expose to shock.
ures for the user During use the container must be placed in the correct position.
Bulk transport Not relevant
SAFETY DATA SHEET FOR LPG 8/9
Air transport – IATA
Propane Butane LPG mix Isobutane
UN number 1965 1965 1965 1969
UN shipping name Hydrocarbon gas, Hydrocarbon gas mix- Hydrocarbon gas mix- Isobutane
mixture, liquefied, n.o.s. ture, liquefied n.o.s. ture, liquefied n.o.s.
(Mixture C) (Mixture A) (Mixture A1)
Hazard class/label 2.1
Packing group Not relevant
Sea polluting No
Special precautionary meas- Do not throw containers or expose to shock.
ures for the user During use the container must be placed in the correct position.
Bulk transport Not relevant
15. R
egulatory information 15.1 Safety, health and environmental regulations/legislation specific to the
substance or mixture
Must not be used by people under 18 years of age (see local laws and regulations).
15.2 Chemical safety assessment
No chemical safety assessment has been made.
16. O
ther information Explanation of hazard statements
H220 Extremely flammable gas
H225 Highly flammable liquid and vapour
H280 Contains pressurised gas, may explode when heated
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful if inhaled
H340 May cause genetic defects
H350 May cause cancer
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long-lasting effects
H411 Toxic to aquatic life with long-lasting effects
This information is based on our existing knowledge and is intended to describe LPG in
relation to health, safety, security and environmental requirements.
SAFETY DATA SHEET FOR LPG 9/9
