This document contains calculations for determining the amounts of formaldehyde, urea, and ammonia needed to create a buffer solution, as well as analyses of the density, viscosity, pH, and free formaldehyde content of 7 samples of the solution. The calculations find that 44.074g of formaldehyde, 73.51g of urea, 26.14g of ammonia, and 0.327g of Na2CO3 are needed. The analyses show the density, viscosity, and pH of each sample are similar, while the free formaldehyde content decreases from samples 1 to 7.
This document contains calculations for determining the amounts of formaldehyde, urea, and ammonia needed to create a buffer solution, as well as analyses of the density, viscosity, pH, and free formaldehyde content of 7 samples of the solution. The calculations find that 44.074g of formaldehyde, 73.51g of urea, 26.14g of ammonia, and 0.327g of Na2CO3 are needed. The analyses show the density, viscosity, and pH of each sample are similar, while the free formaldehyde content decreases from samples 1 to 7.
This document contains calculations for determining the amounts of formaldehyde, urea, and ammonia needed to create a buffer solution, as well as analyses of the density, viscosity, pH, and free formaldehyde content of 7 samples of the solution. The calculations find that 44.074g of formaldehyde, 73.51g of urea, 26.14g of ammonia, and 0.327g of Na2CO3 are needed. The analyses show the density, viscosity, and pH of each sample are similar, while the free formaldehyde content decreases from samples 1 to 7.
This document contains calculations for determining the amounts of formaldehyde, urea, and ammonia needed to create a buffer solution, as well as analyses of the density, viscosity, pH, and free formaldehyde content of 7 samples of the solution. The calculations find that 44.074g of formaldehyde, 73.51g of urea, 26.14g of ammonia, and 0.327g of Na2CO3 are needed. The analyses show the density, viscosity, and pH of each sample are similar, while the free formaldehyde content decreases from samples 1 to 7.
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LAMPIRAN II
PERHITUNGAN BM Formaldehid
30 gr/ml
BM Urea
60,06 gr/ml
BM Amoniak
17,031 gr./ml
Densitas Amoniak
0,86 kg/ml
A.
Perhitungan Jumlah Formaldehid
Massa larutan formaldehid
m
= v
= 1,10185 gr/ml 100ml
= 110,185 gram
Massa formaldehid
= % massa larutan formaldehid
= 40% 110,185 gram
= 44,074 gram
Mol formaldehid =
massa formaldehid BM formaldehid
mol
44,074 gram 30 gr /mol
mol
= 1,469 mol
B.
Penentuan Jumlah Urea
mol
U F
= 1,2
Mol urea Mol urea
mol formaldehid 1,2
1,469 mol 1,2
= 1,224 mol Massa urea Massa urea Massa urea
= mol urea BM urea
= 1,224 mol 60,06 gr/mol
Massa urea = 73,51 gram
Massa katalis NH3 Massa katalis NH3 = 5% X Massa katalis NH3 = 0,05x Massa buffering agent
Massa buffering agent = 5% 5%
Massa buffering agent = 0,05 0,05 Massa buffering agent = 0, 0025 Massa total Massa total = massa formaldehid + massa urea + massa NH3 + massa Na2CO3 Massa total = 44,074 gr +73,51 gr + 0,05 gr + 0,0025x x-1 = 117,637 0,9x = 117,637 x = 130,707 gram Massa katalis NH3 yang ditambahkan Massa katalis = 5% massa total Massa katalis = 0,05 130,707 gr Massa katalis = 6,535 gram NH3 yang digunakan 25% massa katalis yang ditambahkan Massa NH3 = 25 Massa NH3
6,535 gram 25
Massa NH3 = 26, 14 gram
Volume NH3 massa NH 3 yang digunakan Volume NH3 = 25 Volume NH3 =
26, 14 gram 25
Volume NH3 = 30,395 ml
Massa Na2CO3
Massa Na2CO3 = 5% massa total katalis
Massa Na CO = 0,05 6,535 gr 2
Massa Na2CO3 = 0,327 gram
C. 1.
Analisa Sampel 0 Analisa Densitas
Picnometer kosong
= 12,185 gram
Picnometer + air
= 17,559 gram
(Picnometer + air) - Picnometer kosong
= 17,559 gram - 12,185 gram
= 5,374 gram
Picnometer + sampel 0
= 17,926 gram
(Picnometer + sampel 0) - Picnometer kosong
= 17,926 gram - 12,185 gram
= 5,741 gram
Sampel 0
2.
massa sampel 0 massa air
5,741 gram 5,374 gram
1,0683 gram
Analisa Viskositas
K (air)
= 0,25 sekon
t sampel 0
= 0,24 sekon
Sg sampel 0
densitas sampel densitas air
1,0683 gram 0,99
= 1,079 sampel 0
= k sg sampel t = 0,25 1,079 0,24 = 0,065
3. 4.
Analisa pH nilai pH = 10 yang menandakan larutan bersifat basa Analisa Kadar Formaldehid Bebas Gr CH 2 O 3 x ml HCl x HCl = ml sampe 0 ml larutan Gr CH 2 O 40 ml Gr CH2O
m HCl = ml titrasi = 18,3 ml
3 x 0,6 ml x 0,5 N 10 ml
= =
0,09 40
3,6 gram
ml titrasi blanko
17,7 ml
= 0,6 ml D. 1.
Analisa Sampel 1 Analisa Densitas
Picnometer kosong
= 12,185 gram
Picnometer + air
= 17,559 gram
(Picnometer + air) - Picnometer kosong
= 17,559 gram - 12,185 gram
= 5,374 gram
Picnometer + sampel 1
= 18,329 gram
(Picnometer + sampel 1) - Picnometer kosong
= 18,329 gram - 12,185 gram
= 6,144 gram
Sampel 1
2.
massa sampel 1 massa air
6,144 gram 5,374 gram
1,1432 gram
Analisa Viskositas
K (air)
= 0,25 sekon
t sampel 1
= 0,22 sekon
Sg sampel 1
densitas sampel densitas air
1,1432 gram 0,99
=1,155 sampel 1
= k sg sampel t = 0,25 1,155 0,22 = 0,0635
3. 4.
Analisa pH nilai pH = 10 yang menandakan larutan bersifat basa Analisa Kadar Formaldehid Bebas Gr CH 2 O 3 x ml HCl x HCl = ml sampe1 ml larutan Gr CH 2 O 40 ml Gr CH2O
m HCl = ml titrasi = 18 ml
3 x 0,5 ml x 0,5 N 10 ml
= =
0,075 40
3 gram
ml titrasi blanko
17,5 ml
= 0,5 ml E. 1.
Analisa Sampel 2 Analisa Densitas
Picnometer kosong
= 12,185 gram
Picnometer + air
= 17,559 gram
(Picnometer + air) - Picnometer kosong
= 17,559 gram - 12,185 gram
= 5,374 gram
Picnometer + sampel 2
= 18,367 gram
(Picnometer + sampel 2) - Picnometer kosong
= 18,367 gram - 12,185 gram
= 6,182 gram
Sampel 2
massa sampel 2 massa air
6,182 gram 5,374 gram
= = 2.
1,150 gram
Analisa Viskositas
K (air)
= 0,25 sekon
t sampel 2
= 0,33 sekon
Sg sampel 2
densitas sampel densitas air
1,1432 gram 0,99
=1,155 sampel 2
= k sg sampel t = 0,25 1,150 0,22 =0,096
3. 4.
Analisa pH nilai pH = 8 yang menandakan larutan bersifat basa Analisa Kadar Formaldehid Bebas Gr CH 2 O 3 x ml HCl x HCl = ml sampe2 ml larutan Gr CH 2 O 40 ml Gr CH2O
m HCl = ml titrasi = 18 ml
3 x 0,4 ml x 0,5 N 10 ml
0,06 40
2,4 gram
ml titrasi blanko
17,6 ml
= 0,4 ml
F. 1.
Analisa Sampel 3 Analisa Densitas
Picnometer kosong
= 12,185 gram
Picnometer + air
= 17,559 gram
(Picnometer + air) - Picnometer kosong
= 17,559 gram - 12,185 gram
= 5,374 gram
Picnometer + sampel 3
= 18,370 gram
(Picnometer + sampel 3) - Picnometer kosong
= 18,370 gram - 12,185 gram
= 6,185 gram
Sampel 3
massa sampel 3 massa air
6,185 gram 5,374 gram
= 2.
1,151 gram
Analisa Viskositas
K (air)
= 0,25 sekon
t sampel 3
= 0,34 sekon
Sg sampel 3
densitas sampel densitas air
1,151 gram 0,99
= 1,163 sampel 3
= k sg sampel t = 0,25 1,163 0,34 = 0,098
3. 4.
Analisa pH nilai pH = 8 yang menandakan larutan bersifat basa Analisa Kadar Formaldehid Bebas Gr CH 2 O 3 x ml HCl x HCl ml sampe 3 ml larutan = Gr CH 2 O 40,5 ml Gr CH2O
= =
3 x 0,5 ml x 0,5 N 10 ml 3,038 40,5
m HCl = ml titrasi = 19 ml
3,038 gram
ml titrasi blanko
18,5 ml
= 0,5 ml G. 1.
Analisa Sampel 4 Analisa Densitas
Picnometer kosong
= 12,185 gram
Picnometer + air
= 17,559 gram
(Picnometer + air) - Picnometer kosong
= 17,559 gram - 12,185 gram
= 5,374 gram
Picnometer + sampel 4
= 18,378 gram
(Picnometer + sampel 4) - Picnometer kosong
= 18,378 gram - 12,185 gram
= 6,193 gram
Sampel 4
massa sampel 4 massa air
6,193 gram 5,374 gram
= 2.
1,152 gram
Analisa Viskositas
K (air)
= 0,25 sekon
t sampel 4
= 0,32 sekon
Sg sampel 4
densitas sampel densitas air
1,152 gram 0,99
= 1,164 sampel 4
= k x sg sampel x t = 0,25 x 1,164 x 0,32 = 0,093
3.
Analisa pH
4.
nilai pH = 8 yang menandakan larutan bersifat basa
Analisa Kadar Formaldehid Bebas Gr CH 2 O 3 x ml HCl x HCl = ml sampe 4 ml larutan Gr CH 2 O 40,5 ml Gr CH2O
m HCl = ml titrasi = 18 ml
3 x 0,3 ml x 0,5 N 10 ml
= = =
0,045 x 40,5 1,823 gram
ml titrasi blanko
17,7 ml
= 0,3 ml H. 1.
Analisa Sampel 5 Analisa Densitas
Picnometer kosong
= 12,185 gram
Picnometer + air
= 17,559 gram
(Picnometer + air) - Picnometer kosong
= 17,559 gram - 12,185 gram
= 5,374 gram
Picnometer + sampel 5
= 18,383 gram
(Picnometer + sampel 5) - Picnometer kosong
= 18,383 gram - 12,185 gram
= 6,198 gram
Sampel 5
massa sampel 5 massa air
6,198 gram 5,374 gram
= 2.
1,153 gram
Analisa Viskositas
K (air)
= 0,25 sekon
t sampel 5
= 0,32 sekon
Sg sampel 5
densitas sampel densitas air
1,153 gram 0,99
= 1,165 sampel 5
= k sg sampel t = 0,25 1,165 0,32 = 0,093
3. 4.
Analisa pH nilai pH = 8 yang menandakan larutan bersifat basa Analisa Kadar Formaldehid Bebas Gr CH 2 O 3 x ml HCl x HCl = ml sampe 5 ml larutan Gr CH 2 O 41ml Gr CH2O
m HCl = ml titrasi = 18 ml
3 x 0,3 ml x 0,5 N 10 ml
= = =
0,045 x 41 1,845 gram
ml titrasi blanko
17,7 ml
= 0,3 ml I. 1.
Analisa Sampel 6 Analisa Densitas
Picnometer kosong
= 12,185 gram
Picnometer + air
= 17,559 gram
(Picnometer + air) - Picnometer kosong
= 17,559 gram - 12,185 gram
= 5,374 gram
Picnometer + sampel 6
= 18,391 gram
(Picnometer + sampel 6) - Picnometer kosong
= 18,391 gram - 12,185 gram
= 6,206 gram
Sampel 6
massa sampel 6 massa air
6,206 gram 5,374 gram
= 2.
1,155 gram
Analisa Viskositas
K (air)
= 0,25 sekon
t sampel 6
= 0,36 sekon
Sg sampel 6
densitas sampel densitas air
1,155 gram 0,99
= 1,166 sampel 6
= k sg sampel t = 0,25 1,166 0,33 = 1,105
3. 4.
Analisa pH nilai pH = 8 yang menandakan larutan bersifat basa Analisa Kadar Formaldehid Bebas Gr CH 2 O 3 x ml HCl x HCl = ml sampe 6 ml larutan Gr CH 2 O 40,5 ml Gr CH2O
m HCl = ml titrasi = 18 ml
3 x 0,2 ml x 0,5 N 10 ml
0,045 40,5
1,823 gram
ml titrasi blanko
17,8 ml
= 0,2 ml J. 1.
Analisa Sampel 7 Analisa Densitas
Picnometer kosong
= 12,185 gram
Picnometer + air
= 17,559 gram
(Picnometer + air) - Picnometer kosong
= 17,559 gram - 12,185 gram
= 5,374 gram
Picnometer + sampel 7
= 18,398 gram
(Picnometer + sampel 7) - Picnometer kosong
= 18,398 gram - 12,185 gram
= 6,213 gram
Sampel 7
massa sampel 7 massa air
6,213 gram 5,374 gram
= 2.
1,156 gram
Analisa Viskositas
K (air)
= 0,25 sekon
t sampel 7
= 0,36 sekon
Sg sampel 7
densitas sampel densitas air
1,156 gram 0,99
= 1,168 sampel 7
= k sg sampel t = 0,25 1,168 0,36 = 1,105
3. 4.
Analisa pH nilai pH = 8 yang menandakan larutan bersifat basa Analisa Kadar Formaldehid Bebas Gr CH 2 O 3 x ml HCl x HCl = ml sampe 6 ml larutan Gr CH 2 O 40 ml Gr CH2O
