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Solution-1

1. Normality of 10.6% (w/v) Na2CO3 solution is

2) 2N

3) 3N

4) 4N

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1) 1N

Hint: N= (w/v)%x10/GEW
=10.6X10/53=2N

2) 1

2) 3

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2. The weight of NaOH(in gm) present in 100ml of 0.5M NaOH solution is

3) 2

4) 4

Solution: Wt=MX GMW X V in lit.=0.5X40X100/1000 =2gm

3. An aqueous solution of 6.3g oxalic acid dihydrate is made upto 250ml. Volume of
0.1N NaOH required to completely neutralize 10ml of this solution is
1)40 ml

2) 20 ml

3) 10 ml

4) 4 ml

Solution: N of oxalic acid N1=(wtX1000)/(GEWX V in ml)=6.3x1000/63X250

=0.4N

hi

VaNa=VbNb i.e 10Xo.4=VbX0.1 Vb=40ml

ks

4. Equivalent weight of hypo in the reaction

Na2 S 2O3 Cl2 H 2O
Na2 SO4 2 HCl S , if M is molecular weight of hypo is

2) M/2

.s
a

1) M

3) M/3

4) 2M

Solution: oxidation state of S in Hypo=+2.5, in Na2SO4 is +6 and in elementary

form is zero. In reactant side total ox. state per molecule=+5

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In product side total ox, state ofs=+6+0=+6

Change in ox. State per molecule=6-5=1 Equivalent weight of hypo=M/1=M

5. Molarity of pure water (density=1gm/ml) is

1)40M

2) 4M

3) 55.6M

4) 25M

Solution: wt of 1lit water=1000gm=1000/18=55.55 moles, M=n/v in lt

=55.55/1=55.55M

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6. Which one of these solutions has highest normality?
1)8g KOH per 100ml
3) 0.5M H 2 SO4
4) 6g NaOH per 100ml

Hint:

wt of solute
1000

Gram equivalent weight Vol of solution in ml

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5) 1N H 3PO 4

solution (in ml) is

1) 50 ml

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7. 10. 6 g Na2CO3 is dissolved in water to get 2 M solution. The volume of the

2) 40 ml

Solution: Molarity (M)

1000
W

G.M.W solute vol.in ml

i.e

4) 10 ml

10.6 1000

106
Vml

hi

Vol. of solution = 50 ml

3) 100 ml

2) 40 ml

3) 100 ml

4) 25 ml

.s
a

1)50 ml

ks

8. The volume of 0.2M H 2 SO4 solution containing 10 milli equivalents of solute is

Solution: N=MX basicity=0.2X2=0.4N, milli equivalents =N X Vin ml

i.e 10=0.4XV V=25ml

9. The number of moles of oxalic acid required to decolourise completely 0.4 mole

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of acidified KMnO4 solution is

1)0.4

2) 0.5

3) 1

4) 2

Solution: 2KMnO4 + 3H2SO4 + 5H2C2O4 K2SO4 + 2MnSO4 + 8H2O +

10CO2

10. Assertion (A): Molarity of 0.05N solution of HNO3 is 0.05M.

Reason (R): Molarity & normality of a solution are always equal.

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The correct answer is
1) Both A and R are true and R is correct explanation of A.
2) Both A and R are true and R is not correct explanation of A.
3) A is true but R is false.

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4) Both A and R are false.

11. Solid solution in the following is
1) NaCl in water

2) Amalgam

3) Soda water

4) Camphor in air

is
1)250 ml

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12. The volume of 0.1N H 2 SO4 solution required to exactly neutralise 5.6g of KOH

2) 500 ml

3) 25 ml

4) 1000 ml

Solution: 5.6gm=5.6/56=0.1gm equivalents of KOH

For complete neutralization, equivalents of KOH= equivalents of H 2 SO4

i.e. 0.1= 0.1X Vin lt. V=1lit

13. Molarity of 0.2% (w/v) NaOH solution is

1)0.2

2) 2

3) 0.05

4) 0.5

1000
0.2 1000
W

G
.
M
.
W
vol
.
in
ml
40 100

solute

= 0.05M.

.s
a

Molarity

ks

of solution.

hi

Solution: 0.2% (w/v) NaOH solution means 0.2 g of NaOH is dissolved in 100 ml

14. 20 ml of 0.2 N HCl and 40 ml of 0.4 N HNO3 are mixed and the solution is

diluted up to 100 ml. The normality of the resultant solution is

2) 0.15 N

3) 0.2N

4) 0.4 N

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1)0.1 N

Solution

N Total

N1 V1 N 2 V2
0.2 20 0.4 40
20

0.2N
VTotal
100
100

15. Which of the following is more concentrated?

1)1M H 2 SO4

2) 1m H 2 SO4

3) 1% H 2 SO4

Hint: For poly basic acids the concentration in 1M>1m>1N>1%

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4)1N H 2 SO4

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16. 20ml of 10N HCl and 10ml of 5 N HCl are mixed and made upto 1 litre with
distilled water. The normality of the resulting solution is
1) 0.25 N
Solution:

2) 0.3 N
N Total

N1 V1 N 2 V2
VTotal

3) 0.20 N

4) 0.1 N

10 20 10 5
0.25 N
1000

H 3 PO4 2OH
HPO42 2 H 2O

1) 0.15 N

2) 0.30 N

3) 0.10 N

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Solution: as the acid looses two H+ ions, its basicity is 2.

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17. What is the normality of 0.3 M H 3 PO4 in the following reaction?

4) 0.60 N

N=MX basicity=0.3X2=0.6N

18. Volume of water to be added to 1 litre of a solution of 1.123 N acid solution to

make it 1N solution.
1) 900ml

2) 246 ml

3) 123 ml

4) 100 ml

Solution: volume of water added=V1 (M1- M2)/ M2

=1000(1.123-1)/1=123ml

hi

19. Normality of the acid solution obtained by diluting 250 ml of 0.4N H 2 SO4 with

ks

1000ml of water is
1)0.1

2) 0.16

3) 0.2

4) 0.08

.s
a

Solution: For dilution V1N1 = V2N2

250X0.4=1250XV2

i.e V2=0.08N

20. 10.6g of Na2CO3 was exactly neutralized by 100ml of H 2 SO4 solution. Molarity

w
w

of H 2 SO4 solution is

1)1.0

2) 2

3) 0.5

4) 2.5

Solution: 10.6gm=10.6/53=0.2 gm equivalents of Na2CO3

For complete neutralization, equivalents of Na2CO3 = equivalents of H 2 SO4

i.e 0.2= Na X 100/1000 thus N of H 2 SO4 =2N M=N/basicity=2/2=1M

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21) A volatile solvent can be separated from non volatile solute by
1) Evaporation

2) Distillation

3) Cant be separated

4) Filtration

22) The molarities of two solutions A & B are 0.1M and 0.2M respectively. If 100ml
of A is mixed with 25ml of B there is no change in volume. Then final molarity
of the solution is

Solution:

2) 0.18 M
M 1V1 M 2V2 0.1 100 0.2 25

100 25
V1 V2

3) 0.12 M
=0.12 M

4) 0.28 M

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1) 0.16 M

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23) 200 ml of KMnO4 solution is exactly reduced by 100 ml, 0.5M oxalic acid
solution. The molarity of KMnO4 solution
1)0.1

2) 0.16

3) 0.2

4) 0.08

Solution: 2KMnO4 + 3H2SO4 + 5H2C2O4 K2SO4 + 2MnSO4 + 8H2O +

10CO2
M1 V1
n1

M 2 V2
n2

KMnO 4 H 2 C 2 O 4

M1 200 0.5 100

2
5

, M1 = 0.1M

hi

Molarity of KMnO4 = 0.1 M

ks

24) 250ml of Na2CO3 solution contains 2.65g of Na2CO3 . 10 ml of this solution is

added to xml of water to obtain 0.001M Na2CO3 solution. The value of x in ml
2) 990

.s
a

1)1000

3) 9990

4) 90

Solution: M1=2.65X1000/106X250=0.1

Volume of water added i.e x=V1 (M1- M2)/ M2

w
w

=10 (0. 1-0.001)/0.001=990ml

25) In acidic medium, dichromate ion oxidizes ferrous ion to ferric ion. If the gram
molecular weight of potassium dichromate is 294 gram, its gram equivalent

weight is (in grams)

1)294

2) 147

3) 49

4) 24.5

Solution: in acid medium change in ox. state per molecule of dichromate=6

GEW=GMW/6=294/6=49

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26) Which of the following is more concentrated?

1)1% H 3 PO4

2) 1M H 3 PO4

3) 1m H 3 PO4

4)1N H 3 PO4

27) Molarity of 1 %( W/V) H 2 SO4 solution is approximately

2) 1

3) 0.18

Solution: M= (w/v) % X10/GMW =1X10/98=0.102M

4) 0.1

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1)2.5.1

28) What volume of 0.8M solution contains 0.4 mole of solute?

1)100 ml

2) 125 ml

3) 500 ml

4) 62.5 ml

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Solution: M=n/V in lit or V in lit=n/M=0.4/0.8=0.5lit=500ml

29) Equivalent weight of a trivalent metal is 9. The molecular weight of its oxide is
1)75

2) 36

3) 51

4) 102

Solution: GAW of metal= GEWX valency =9X3=27, as metal is trivalent, its oxide
is M2O3.

GMW of M2O3 = 2X 27 +3X16=102

30) 0.5 mole of H 3 PO4 is dissolved in sufficient water and made upto 500ml in a

2) 1 m

3) 1 M

4) 1 N

ks

1)0.5 M

hi

standard flask. The concentration of the solution is

Solution: M=nX1000/V in ml=0.5X1000/500 =1M

.s
a

31) Which of the following method of expressing concentration is independent of

temperature and have no units?
2) Mole fraction

3) Molarity

4) Normality

1) Molality

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32) Equivalent weight of KMnO4 in neutral medium is

1) M/3

2) M/1

3) M/5

4) M/6

3) 3

4) 1/2

33) Number of equivalents in 98gm H PO is

3
3
1)2

2) 1

34) With increase in temperature both normality and molarity of a solution

1) Decreases

2) Increases

3) Remains same

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4) Doubles

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35) When a solution is diluted n times, the molarity and normality
1) Decreases by 2n times

2) Decreases by n times

3) Decreases by n/2 times

4) Increases by n times

Hint: N or M inversely proportion to volume.

36) An example for gas in solid solution is
2) Occlusion of H 2 in pd

3) Soda water

4) Iodine in air

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1) Alloy

37) A solution whose concentration is exactly known is called

2) Saturated solution

3) Standard solution

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1) Centimolar solution

4) Any of the above

38) More convenient method of expressing concentration is

1) Molarity

2) Normality

3) % by weight

4) All of these.

39) 100ml of CH 3OH (d = 0.32 g/ml) was taken in a 1000ml flask and water is added
upto the mark to prepare solution. The molarity of solution is (volumes are
additive)
2) 2

3) 0.1

4) 0.5

hi

1)1

ks

Solution: wt of solute=VXd=100X0.32=32gm
M=wt X1000/GMWXV in ml= 32X1000/32X1000 = 1M

.s
a

40) The molarity of resulting solution formed by mixing equal volumes of 1M HCl
and 1M HNO3 are

2) 1

1)2

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Solution:

3) 1.5

4) 2.5

M 1V1 M 2V2 1 V 1 V

1M
V V
V1 V2

41) 0.6g of a metal carbonate is neutralized by 300ml of centimolar HCl solution.

The equivalent weight of metal carbonate is
1)100

2) 50

3) 150

Solution: wt of metal carbonate/GEW =Na XVa in lt

0.6/GEW=0.01X300/1000,

GEW = 200

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4) 200

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42) A solution is labeled as 10N. To prepare 100ml of 0.1N solution, the volume of
water to be added to the concentrated solution is
1) 90 ml

2) 99 ml

3) 990 ml

4) 1 ml

Solution: V1 N1= V2 N2 , V1 =100X0.1/10=1ml

43) The solubility of a gas in liquid increases with

1) Increase in temperature
2) Reduction of gas pressure

4) Amount of liquid taken.

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3) Decrease in temperature and increase in gas pressure

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Volume of water added=V2-V1 =100-1=99ml

44) The volume of water that must be added to a mixture of 250ml of 6M HCl and
650ml of 3M HCl to obtain 3M solution is
1) 75ml
Solution:

2) 150ml
M

3) 300ml

4) 250ml

M 1V1 M 2V2

V2 vol.ofwater
1

45) Equal volumes of 0.1 M NaNO3 and 0.2 M NaCl solutions are mixed. The

2) 0.2 M

ks

1) 0.1 M

hi

concentration of nitrate ions in the resultant mixture will be

3) 0.05 M

4) 0.15 M

.s
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Solution: As equal volumes are mixed the vol. of solution is doubled.

[NO3 -]=0.1/2= 0.05N or M

46) The following are some statements about solution

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i) In a binary solution, two components are present

ii) A homogenous solution consists of two phases

iii) In a binary solution, component generally present in higher amount is

known as solvent
1) All are correct

2) Only (i) and (ii) are correct

3) Only (i) and (iii) are correct

4) (ii) and (iii) are correct

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List-I

List-II

A. Gas in Liquid

1. Camphor in Air

B. Liquid in Gas

2. Bronze

C. Liquid in Solid

3. Water in Air

D. Solid in Solid

4. Oxygen in Water

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47) Match the following.

The correct answer is

B

1) 5

2) 1

4) 4

3) 2

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5. Amalgam

ks

48) 0.84g of metal carbonate reacts exactly with 40ml of

N
H 2 SO4 solution.
2

.s
a

Equivalent weight of metal is

1) 84g

2) 21g

3) 42g

Solution: wt of metal carbonate/GEW =Na XVa in lt

w
w

0.84/GEW=0.5X40/1000,

GEW of metal carbonate = 42

GEW of METAL= 42- GEW of CO3-2=42-30=12g.

49) Solubility of a solute in a solvent depends on

1) Nature of solute

2) Nature of solvent

3) Temperature

4) All the above

50) Correct relation is

1. Molarity x Eq. Wt = Normality x Mol. Wt

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4) 12g

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2. Molarity x Mol.wt = Normality x Eq. Wt
3. Molarity x Normality = M.wt x Eq. Wt
Molarity Normality

M
.
wt
Eq.wt
4.

51) In acidic medium, molarity of 0.3N K 2Cr2O7 solution is

2) 0.05

3) 1.8

4) 0.15

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1)0.3

Solution: N=MX change in ox. State per mole, M=0.3/6=0.05

52) The concentration of sulphate ions in 0.1M potash alum solution is

2) 0.3 M

3) 0.2 M

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1) 0.4M

4) 0. 1 M

S0lution; Formula of potash alum is K2SO4 Al2 (SO4 )3 24H O.i molecule
2
-2
contains 4 sulphate ions. [ SO4 ]=0.1X4=0.4

53) In 46% (w/w) aqueous solution of ethyl alcohol the mole fraction of alcohol is
1)0.5

2) 0.25

3) 0.75

4) 0.65

Solution: 46%w/w means 100gm solution contains 46gm of alcohol

Wt of alcohol= 46gm. Wt of water =100-46=54gm.

Mole fraction of alcohol =n/n+N =1/1+3=0.25

ks

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Moles of alcohol=n=46/46=1 and moles of water i.e N=54/18=3

54) If 0.46g of Ethanol is dissolved in 1000 g of H2O, the molality of the ethanol

.s
a

solution is
1)0.1m

2) 0.02m

3) 0.2m

4) 0.01m

Solution: Wt of ethanol (solute) =0.46g, Wt. of water (solvent) = 1000 g

w
w

G.M. W of ethanol = 46 g
Molality =

1000
W
0.46 1000

G.M.W solute wt of solvent in gms 46 1000 0.01m

55) The molality of a 9.8% (w/w) solution of H2SO4 is

1)1.1m

2) 2.2m

3)1m

4)2m

Solution: 9.8% (w/w) solution means 9.8 g of the solute are present in 100g of
solution.

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Wt of solute = 9.8g,

wt of solvent = 100-9.8 = 90. 2g

Molality =
1000
9.8 1000
W

1.1m

G.M.W Solute wt.of solvent in gm

98 90.2

1)1.2m

2) 0.98m

3)1.02m

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56) The molality of 4% (w/v) NaOH solution having the density 1.02 g/ml. is
4)1m

Solution: 4% (w/v) NaOH solution contains 4g of NaOH is 100ml of the

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solution.
Density of the solution = 1.02 g/ml

Wt of the solute in 100 ml of the solution = 4g

100 1.02 102 g

Wt of 100 ml of the solution =

Wt. of solvent = Wt of solution - Wt of solute = 102-4= 98 g.

1000
W
Molality

G.M.W Solute wt of solvent in gms

4 1000

1.02m
40
98

57) 6 g of urea is mixed with 16. 2g of H2O the mole fraction of urea in the

hi

mixture is

2) 22.2/6

3) 0.9

4) 0.1

ks

1) 6/22.2

.s
a

Solution: Mole fraction of

6
0.1

0.1
nurea
60

0.1
0.9
urea

nurea nH O 6 16.2

60 18
2

58) In a normal solution of BaCl2, normalities of Ba+2 and Cl - are in the ratio

w
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1) 2:1

2) 1:2

3) 1:1

Solution: BaCl2. Ba+2 +2 Cl 1N

1N

2N

59) Match List-I with List-II

List-I
A. Molarity

List-II
i) no units

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4) 2:3

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B. Molality

ii) gm. equivalents/lit

C. Normality

iii) mol/lit

D. Mole fraction

iv) moles/ kg. Solvent

v) gm. equivalents/ kg. Solvent

(iv)

(iii)

(ii)

(i)

2)

(iv)

(v)

(ii)

(i)

3)

(iii)

(iv)

(i)

(ii)

4)

(iii)

(iv)

(ii)

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1)

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The correct match is

(i)

60) If 20 ml of 1M HCl solution is exactly neutralised by 10 ml of Ca (OH)2

solution, the strength of Ca(OH)2 in grams per litre of the solution is
1) 37

2) 74

4)148

2HCl Ca OH 2
CaCl2 2H 2 O

M1 V1 M 2 V2

n1
n2

CaOH2

1 20 M 2 10

, M 2 1.0M
2
1

ks

HCl

hi

Solution:

3)111

.s
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Molarity of Ca (OH)2 = 1.0 M

Strength of Ca (OH)2 solution = Molarity X M.wt = 1X74= 74 g/litre .

61) A gaseous mixture contains four gases A, B, C and D. The mole fraction of "B"

w
w

is 0.5. The mole fraction of "A" is

1) 0.5252) 0.375

3) 0.625

4) 0.732

Solution: As XB=0.5, XA+XC+XD=1-0.5=0.5 XA<0.5

62) The maximum allowable level of carbon monoxide in air is 9mg per dm3, the
level in ppm is
1) 9
Solution: 1 dm3=1lit,

2) 18

3) 90

1mg/lit=1ppm

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4) 900

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Key

3) 1

4) 1

5) 3

11)2

12)4

13) 3

14)3

21)2

22) 3

23)1

24)2

31) 2

32)1 33) 1

41)4

42)2

43) 3

44)4

51)2

52) 1

53)2

54)4

15)1

7) 1

16) 1

25)3

8)4

9)3

17)4 18) 3

35) 2

45)3

26)2

36)2

46) 3

56)3

28)3

38)1

57)4

58)2

.s
a

62)1

w
w

61) 2

10)3

19) 4

29)4

39)1

47)3 48) 4 49) 4

ks

55)1

27)4

37) 3

hi

34) 1

6)3

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2)3

20) 1

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1) 2

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59)4

30)3

40)2

50) 2

60)2