1805-B Clement Ave, Bldg.

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analyzers, inc.

White Paper No. 9

Voice (510) 337-1605 Fax (510) 337-0388

Rev. 021007A

Lambda Calculation The Brettschneider Equation, general principles and methods,

and its use with alternate fuels.
The Brettschneider equation is the de-facto standard method used to calculate the normalized
air/fuel balance (Lambda) for domestic and international I&M inspection programs. It is taken
from a paper written by Dr. Johannes Brettschneider, at Robert Bosch in 1979 and published in
Bosch Technische Berichte, Vol 6 (1979) N0. 4, Pgs 177-186. In the paper, Dr. Brettschneider
established a method to calculate Lambda (Balance of Oxygen to Fuel) by comparing the ratio of
oxygen molecules to carbon and hydrogen molecules in the exhaust. The equation is a little
complex, but is relatively easily calculated from the measured values of CO, CO2, unburned HC,
and unconsumed O2 in the exhaust:

3.5
OCV
CO
NO HCV

[CO 2 ] + + [O 2 ] + +

([CO 2] + [CO ])
[
CO ]
4
2
2
2
3. 5 +

[CO 2 ]

=
HCV OCV

1 +
([CO 2] + [CO ] + (Cfactor [HC ]) )
4
2

Where :
[XX ] = Gas Concentrat ion in % Volume.
Hcv = Atomic ratio of Hydrogen t o Carbon in the fuel.
Ocv = Atomic ratio of Oxygen to Carbon in the fuel.
Cfactor = Number of Carbon atoms in each of the HC molecules being measured.

The equation above compares all of the oxygen in the numerator, and all of the sources of carbon
and hydrogen in the denominator. (Water concentration is determined by as a fraction of the sum
of CO2 and CO, and the ratio of CO to CO2 by the 3.5 term in the numerator). The result of the
Brettschneider equation is the term Lambda () a dimensionless term that relates nicely to the
stoichometric value of air to fuel. At the stoichometric point, Lambda = 1.000. A Lambda value
of 1.050 is 5.0% lean, and a Lambda value of 0.950 is 5.0% rich. Once Lambda is calculated,
A/F ratio can be easily determined by simply multiplying Lambda times the stoichometric A/F
ratio for the fuel used - e.g. 14.71 for gasoline.

No. 9 -Alt Fuels Brettschneider 021007A.doc

June 8, 2003

Details of the Brettschneider Equation:

Although this equation may be difficult to understand in theory, it is simple to use in practice.
The equation directly reflects the degree of lean-ness of the air/fuel mixture and is largely
independent how efficiently the fuel is oxidized a very important factor to consider when
dealing specifically with air / fuel balance issues. The manner in which this equation is to be
used is strictly a function of the application though, and it is an excellent replacement for more
commonly used conventions, such as CO measurement for rich-side applications (performance
tuning), wide range lambda sensors, which are not only very non-linear, but also very sensitive
to combustibles in the exhaust stream, or EGT, which is a combination of flame temperature and
volume (power).
The only stable air/fuel ratio measurement that we have found to date is one that first makes an
accurate measure of the constituent gases in the exhaust stream (at least the four gases of HC,
CO, CO2 and O2) and calculates the oxygen and combustibles content and then the lambda and
A/F value as above.
The Relationship between Lambda and A/F ratio:
Because Lambda = 1.000 when the oxygen and combustibles are in perfect stoichometric balance,
Lambda can easily be used to calculate A/F ratio for particular fuels.
The active A/F ratio is simply the calculated Lambda times the stoichometric A/F ratio for the
specific fuel used (14.71 for gasoline, but other fuels have different values see below) This
method is far superior to other approaches which use only one gas (CO or Oxygen) to
approximate A/F ratio as the Brettschneider method uses all of the oxygen and carbon-bearing
gases to calculate the ratio of air to fuel.
We have found that providing a uniform method to relate the specific exhaust gas constituents to
air/fuel balance (independent of the quality of the combustion process or the power produced)
makes the engine tuners job much easier and easier to understand as well.
It is important to actually use the Lambda value as calculated above in practice to see how well it
correlates to the real world. A little experience goes a long way in building confidence as to the
efficacy of this parameter.
The effect of NOx on Lambda:
NO has a relatively immaterial effect on the lambda calculation, as 1,000 ppm NO is only
equivalent to 0.05% Oxygen utilization. A 4-gas analyzer is adequate for lambda calculation but at least 4 gases must be measured.
The effect of Oxygenated fuels on Lambda:
Oxygenated fuels release oxygen contained a very small amount of oxygen in the fuel, which is
released as the fuel is burned. The total O2 equivalence in typical oxygenated fuel is on the order
of 0.1% O2, so this effect is small.
The effect of various octane fuel mixes on Lambda:
Various mixes of gasoline contain differing ratios of short and long hydrocarbon chains, resulting
in a variation of octane rated fuels. This has a small effect on the ratio of hydrogen to carbon in
the fuel, but these variations have a trivial effect on the lambda calculation.

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Sample Dilution and Air Injection Effects on Lambda:

As a side note, it is important to understand the effect that sampling air leaks or outright air
injection may have on lambda calculation. The percentage of extra air in the exhaust gases
will result in the same percentage error in the Lambda calculation.
I.E, a 5% air leak will not only dilute (lower) the CO, HC, CO2 and NOx gas readings by 5%, but
will increase the Oxygen reading by about 1.00% (5% of 20.9%) and will result in the calculated
Lambda being 5% leaner than it should. That means that a perfect Lambda of 1.000 will be
reported as 1.050 if there is 5% air leak or injection.
This is a significant error, and can occur relatively easily. It should be noted that air leaks or
injection will always bias the lambda calculation toward the lean side so they should be dealt
with and corrected before any lambda calculations using measured gases are attempted.
Air injection should be disabled for Lambda to be calculated correctly.
Pre and Post CAT gases the effect of Combustion Efficiency on Lambda:
Because the Brettschneider equation calculates the balance between Oxygen and Combustibles by
looking at all the oxygen and carbon-bearing gases it is relatively insensitive to the degree to
which the combustibles have been oxidized. Thus, the gas stream before the CAT should
calculate at the same Lambda value as the gases after the CAT.
This ability to calculate Lambda independent of Combustion Efficiency is a very valuable feature
of the Brettschneider equation as fuel management control may be verified independent of other
mitigating factors during engine diagnostics by this method.

Alternative Fuels Considerations

Lambda and A/F Ratio factors as a function of Fuel:
Various fuels have differing factors used to calculate Lambda and A/F Ratio. The Lambda
calculation factors as defined above vary by the gasoline blend, (and are actually different from
season to season), and are significantly different for LPG and CNG as shown below.
Fuel Parameters their values and effect on Lambda and A/F Ratio Calculation:

Fuel
Factor

NonOxygenated
Gasoline
(Hexane)

American
(BAR)
Oxygenated
Gasoline
(Hexane)

European
(OIML)
Oxygenated
Gasoline
(Hexane)

Propane
(LPG)

Methane
(CNG)

Hcv

1.800

1.9800

1.7621

2.667

4.000

Ocv

0.000

0.0170

0.0176

0.000

0.000

Cfactor

6.000

6.000

6.000

3.000

1.000

A/F Nom

14.71

14.71

14.71

15.87

17.45

The Bridge Analyzers use the American (BAR) Gasoline factors above, calculate Lambda using
the Brettschneider equation, and report it in the Lambda display mode. When A/F Ratio display

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June 8, 2003

mode is selected, the lambda value calculated by this method is multiplied by 14.71 and the result
is displayed.
Lambda and A/F Ratio Errors with alternative fuels, Lambda calculated with Gasoline
constants:
The Lambda value calculated by the Brettschneider method is accurate within 1%,
independent of the fuelused.
However, as the Stoichometric A/F ratio varies by the fuel, the nominal A/F value appropriate for
each fuel must be multiplied by Lambda in order to be accurate. Multiplying the displayed value
of A/F Ratio (Gasoline = 14.71) by the factors below will yield the correct A/F ratio:
Multiplying Factors for Lambda and A/F Ratio:
Multiplying
Factor

Gasoline
(Hexane Default Display)

LPG
(Propane

CNG
(Methane)

Lambda

1.00

1.00

0.99

A/F Ratio

1.00

1.08

1.18

The correct use for the table above using real displayed values is as follows:

Parameter

Displayed
Value
Gasoline
(Hexane)

Corrected
Value
LPG
(Propane

Corrected
Value
CNG
(Methane)

Lambda

1.02

1.02

1.01

A/F Ratio

15.0

16.2

17.7

This allows the Lambda and A/F calculation features of the analyzer to be applied to alternative
fuels with relative ease.

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