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The document discusses vapor-liquid equilibrium (VLE) calculations using the Antoine equation for various components. It provides Antoine constants (A, B, C) and normal boiling points for triglycerides, fatty acid methyl esters (FAME), methanol, water, and glycerol. Tables of vapor pressure and mole fraction data are given for VLE calculations of methanol-air, triglyceride-methanol, triglyceride-air, and glycerol-air systems over temperature ranges from 290-770 K.

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565 views37 pages
The document discusses vapor-liquid equilibrium (VLE) calculations using the Antoine equation for various components. It provides Antoine constants (A, B, C) and normal boiling points for triglycerides, fatty acid methyl esters (FAME), methanol, water, and glycerol. Tables of vapor pressure and mole fraction data are given for VLE calculations of methanol-air, triglyceride-methanol, triglyceride-air, and glycerol-air systems over temperature ranges from 290-770 K.

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The document discusses vapor-liquid equilibrium (VLE) calculations using the Antoine equation for various components. It provides Antoine constants (A, B, C) and normal boiling points for triglycerides, fatty acid methyl esters (FAME), methanol, water, and glycerol. Tables of vapor pressure and mole fraction data are given for VLE calculations of methanol-air, triglyceride-methanol, triglyceride-air, and glycerol-air systems over temperature ranges from 290-770 K.

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© All Rights Reserved
Download as XLSX, PDF, TXT or read online from Scribd
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565 views37 pages

WH

Uploaded by

Riska_P1023
The document discusses vapor-liquid equilibrium (VLE) calculations using the Antoine equation for various components. It provides Antoine constants (A, B, C) and normal boiling points for triglycerides, fatty acid methyl esters (FAME), methanol, water, and glycerol. Tables of vapor pressure and mole fraction data are given for VLE calculations of methanol-air, triglyceride-methanol, triglyceride-air, and glycerol-air systems over temperature ranges from 290-770 K.

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PERSAMAAN ANTOINE MASING-MASING KOMPONEN US PATENT NO.

US20150065
KONSTANTA PERSAMAAN ANTOINE MASING-MASING KOMPONEN
(Data Physical Properties from : Coulson & Richardson's Chemical Engineering Vol.6, Appendix D)
Komponen
Trigliserida
FAME
Metanol
Air
Gliserol

A
18.2445
9.4297
18.5875
18.3036
17.2392

B
5884.4900
1958.7700
3626.5500
3816.4400
4487.0400

C
-127.2600
-96.9900
-34.2900
-46.1300
-140.2000

Td (0C)
362.3000
212.0000
64.6000
100.0000
289.8000

Rumus Persamaan Antoine:


172.3689 bar

Keterangan = T dalam kelvin dan P dalam mmHg


P
ti sat =

ln P =

175.0000 atm
Bi /
Ai-lnP

*Ci

11.7981

133000.0000

ENT NO. US20150065745

ering Vol.6, Appendix D)


Td (K)
635.3000 *oleic acid
485.0000
337.6000
373.0000
562.8000

mmHg

175.0000 atm

VLE Metanol-Air
Komponen
Metanol (1)
Air (2)

B
3626.5500
3816.4400

18.5875
18.3036

P
ln P

C
-34.2900
-46.1300

Td (0C)
64.6000
100.0000

11.7981
K

T1 sat
T2 sat
P1 sat

290.0000
300.0000
310.0000
320.0000
330.0000
340.0000
350.0000
360.0000

563.1500
573.1500
583.1500
593.1500
603.1500
613.1500
623.1500
633.1500

568.4388
632.7782
mmHg
11.7302 124268.9159
11.8575 141133.1150
11.9801 159544.3696
12.0983 179567.7253
12.2124 201265.7276
12.3225 224698.2450
12.4289 249922.3197
12.5317 276992.0443

P2 sat

290.0000
300.0000
310.0000
320.0000
330.0000
340.0000
350.0000
360.0000

563.1500
573.1500
583.1500
593.1500
603.1500
613.1500
623.1500
633.1500

10.9220
11.0621
11.1969
11.3268
11.4521
11.5729
11.6895
11.8022

T(c)

Tabel
X

T(k)

Y
0.00
0.10
0.23
0.36
0.52
0.69
0.89
1.00

Ln P

T
0.00
0.20
0.38
0.55
0.70
0.83
0.95
1.00

295.2888
300
310
320
330
340
350
359.6282

55380.8976
63707.2207
72904.0931
83018.3296
94095.7949
106181.2342
119318.1214
133548.5217

Td (K)
Tc
337.6000 512.6000
373.0000 647.3000

Tabel

295.2888
359.6282
atm
163.5117
185.7015
209.9268
236.2733
264.8233
295.6556
328.8452
364.4632

atau
560 min
640 max

X1
X2
X3
X4
X5
X6
X7
X8

290 C
360 C

1.1267 Y1
0.8950 Y2
0.6936 Y3
0.5177 Y4
0.3630 Y5
0.2263 Y6
0.1048 Y7
-0.0038 Y8

11.7981
11.7981
1.0528
0.9497
0.8321
0.6989
0.5493
0.3823
0.1969
-0.0080

72.8696
83.8253
95.9264
109.2346
123.8103
139.7122
156.9975
175.7217

1.20
1.00
0.80
X

0.60

Y
0.40
0.20
0.00
1

0.20
0.00
1

Psat
132999.4 174.9992

X
Y

VLE Trigliserida-Metanol
Komponen
Trigliserida (1)
Metanol (2)

A
18.2445
18.5875

P
ln P

B
5884.4900
3626.5500

C
-127.2600
-34.2900

175
11.7981

T1 sat
T2 sat
T(c)

T(k)

ln P

P1 sat

290.0000
350.0000
410.0000
470.0000
530.0000
590.0000
650.0000
710.0000

563.1500
623.1500
683.1500
743.1500
803.1500
863.1500
923.1500
983.1500

4.7446
6.3780
7.6588
8.6901
9.5382
10.2481
10.8509
11.3692

P2 sat

290.0000
350.0000
410.0000
470.0000
530.0000
590.0000
650.0000
710.0000

563.1500
623.1500
683.1500
743.1500
803.1500
863.1500
923.1500
983.1500

11.7302
12.4289
12.9984
13.4715
13.8707
14.2122
14.5075
14.7655

Tabel
X

Y
0.0000
0.4689
0.7023
0.8193
0.8858
0.9282
0.9582
0.9814
1.0000

T
0.0000
0.0021
0.0112
0.0366
0.0924
0.1970
0.3716
0.6391
1.0000

295.2888
350
410
470
530
590
650
710
766.9435

Td (0C)
362.3000
64.6000

Td (K)
635.3000
337.6000

C
1040.0935
568.4388

mmHg

Tabel
766.9435
295.2888

atm

114.9569
588.7356
2119.1929
5943.4814
13880.1693
28228.1194
51580.7023
86613.6140

0.1513
0.7747
2.7884
7.8204
18.2634
37.1423
67.8693
113.9653

124268.9159
249922.3197
441701.6214
708899.2017
1056752.9478
1486824.4144
1997683.1658
2585663.0664

163.5117
328.8452
581.1863
932.7621
1390.4644
1956.3479
2628.5305
3402.1882

Daerah Tabel
Tmin
Tmax

1040 max
560 min

290.0000
770.0000

X1
350.0000 X2
410.0000 X3
470.0000 X4
530.0000 X5
590.0000 X6
650.0000 X7
710.0000 X8

-0.0703
0.4689
0.7023
0.8193
0.8858
0.9282
0.9582
0.9814

atau

Psat
11.7981 132999.4 174.9992
11.7981

770 C
290 C
Y1
Y2
Y3
Y4
Y5
Y6
Y7
Y8

-0.0001
0.0021
0.0112
0.0366
0.0924
0.1970
0.3716
0.6391

VLE Trigliserida-Air
Komponen
Trigliserida (1)
Air (2)

A
18.2445
18.3036

P
ln P

B
5884.4900
3816.4400

C
-127.2600
-46.1300

175
11.7981

T1 sat
T2 sat
T(c)

T(k)

ln P

P1 sat

350.0000
410.0000
470.0000
530.0000
590.0000
650.0000
710.0000
770.0000

623.1500
683.1500
743.1500
803.1500
863.1500
923.1500
983.1500
1043.1500

6.3780
7.6588
8.6901
9.5382
10.2481
10.8509
11.3692
11.8196

P2 sat

350.0000
410.0000
470.0000
530.0000
590.0000
650.0000
710.0000
770.0000

623.1500
683.1500
743.1500
803.1500
863.1500
923.1500
983.1500
1043.1500

11.6895
12.3125
12.8282
13.2622
13.6324
13.9520
14.2306
14.4758

Tabel
X

Y
0.0000
0.4060
0.6535
0.7877
0.8698
0.9256
0.9675
1.0000

T
0.0000
0.0065
0.0292
0.0822
0.1846
0.3590
0.6301
1.0000

359.6282
410
470
530
590
650
710
766.9435

Td (0C)
362.3000
100.0000

Td (K)
635.3000
373.0000

1040.0935
632.7782
mmHg
atm
588.7356
2119.1929
5943.4814
13880.1693
28228.1194
51580.7023
86613.6140
135891.5924
119318.1214
222463.0985
372589.8290
575043.4198
832700.3726
1146243.0789
1514574.8248
1935261.4972

Daerah Tabel
Tmin
Tmax

647.3000

Tabel
766.9435
359.6282
0.7747
2.7884
7.8204
18.2634
37.1423
67.8693
113.9653
178.8047
156.9975
292.7146
490.2498
756.6361
1095.6584
1508.2146
1992.8616
2546.3967

350.0000
770.0000

1040 max
630 min
X1
410.0000 X2
470.0000 X3
530.0000 X4
590.0000 X5
650.0000 X6
710.0000 X7
X8

-0.1152
0.4060
0.6535
0.7877
0.8698
0.9256
0.9675
1.0016

atau
770 C
350 C
Y1
Y2
Y3
Y4
Y5
Y6
Y7
Y8

11.7981
11.7981
-0.0005
0.0065
0.0292
0.0822
0.1846
0.3590
0.6301
1.0234

VLE Gliserol-Air
Komponen
Gliserol (1)
Air (2)

A
17.2392
18.3036

P
ln P

B
4487.0400
3816.4400

C
-140.2000
-46.1300

175
11.7981

T1 sat
T2 sat
T(c)

T(k)

ln P

P1 sat

350.0000
400.0000
450.0000
500.0000
550.0000
600.0000
650.0000
700.0000

623.1500
673.1500
723.1500
773.1500
823.1500
873.1500
923.1500
973.1500

7.9483
8.8199
9.5421
10.1501
10.6691
11.1173
11.5083
11.8523

P2 sat

350.0000
400.0000
450.0000
500.0000
550.0000
600.0000
650.0000
700.0000

623.1500
673.1500
723.1500
773.1500
823.1500
873.1500
923.1500
973.1500

11.6895
12.2170
12.6665
13.0542
13.3920
13.6889
13.9520
14.1867

Tabel
X

Y
0.0000
0.3541
0.6071
0.7567
0.8529
0.9193
0.9680
1.0000

T
0.0000
0.0180
0.0636
0.1456
0.2758
0.4654
0.7245
1.0000

359.6282
400
450
500
550
600
650
691.7068

Td (0C)
289.8000
100.0000

Td (K)
562.8000
373.0000

C
964.8568
632.7782

mmHg

Tabel
691.7068
359.6282

max
min

atm

2830.7595
6767.9172
13933.8069
25593.8978
43006.8353
67326.4875
99534.4731
140403.2634

3.7247
8.9052
18.3340
33.6762
56.5879
88.5875
130.9664
184.7411

119318.1214
202190.9839
316945.2754
467040.2976
654720.1909
881086.5291
1146243.0789
1449471.1417

156.9975
266.0408
417.0333
614.5267
861.4739
1159.3244
1508.2146
1907.1989

Daerah Tabel
Tmin
Tmax

647.3000

350.0000
700.0000

350 X1
400.0000 X2
450.0000 X3
500.0000 X4
550.0000 X5
600.0000 X6
650.0000 X7
X8

-0.1175
0.3541
0.6071
0.7567
0.8529
0.9193
0.9680
1.0057

700 C
350 C
Y1
Y2
Y3
Y4
Y5
Y6
Y7
Y8

11.7981
11.7981
-0.0025
0.0180
0.0636
0.1456
0.2758
0.4654
0.7245
1.0616

350

VLE Gliserol-Metanol
Komponen
Gliserol (1)
Metanol (2)

A
17.2392
18.5875

P
ln P

175
11.7981

B
C
4487.0400 -140.2000
3626.5500 -34.2900

Td (0C)
289.8000
64.6000

K
T1 sat
T2 sat

Td (K)
562.8000
337.6000

C
964.8568
568.4388

T(c)
P1 sat

280.0000
340.0000
400.0000
460.0000
520.0000
580.0000
640.0000
700.0000

ln P
mmHg
atm
553.1500
6.3734
586.0358
613.1500
7.7519
2325.8820
673.1500
8.8199
6767.9172
733.1500
9.6719
15865.2115
793.1500 10.3672
31800.8921
853.1500 10.9456
56702.5760
913.1500 11.4341
92421.5618
973.1500 11.8523
140403.2634

P2 sat

280.0000
340.0000
400.0000
460.0000
520.0000
580.0000
640.0000
700.0000

553.1500
613.1500
673.1500
733.1500
793.1500
853.1500
913.1500
973.1500

Tabel
X

T(k)

Y
0.0000
0.4124
0.6828
0.8178
0.8947
0.9436
0.9776
1.0000

T
0.0000
0.0072
0.0347
0.0976
0.2139
0.4023
0.6794
1.0000

295.2888
340
400
460
520
580
640
691.7068

11.5980
12.3225
12.9109
13.3983
13.8086
14.1587
14.4611
14.7248

108884.4321
224698.2450
404701.1566
658857.9544
993068.8412
1409465.2932
1907062.8820
2482516.9782

Daerah Tabel
Tmin
Tmax

691.7068
295.2888
0.7711
3.0604
8.9052
20.8753
41.8433
74.6087
121.6073
184.7411
143.2690
295.6556
532.5015
866.9184
1306.6695
1854.5596
2509.2933
3266.4697

280.0000
700.0000

Tabel
max
min
280 X1
340.0000 X2
400.0000 X3
460.0000 X4
520.0000 X5
580.0000 X6
640.0000 X7
X8

-0.2227 Y1
0.4124 Y2
0.6828 Y3
0.8178 Y4
0.8947 Y5
0.9436 Y6
0.9776 Y7
1.0032 Y8

700 C
280 C

11.7981
11.7981
-0.0010
0.0072
0.0347
0.0976
0.2139
0.4023
0.6794
1.0590

VLE FAME-Metanol
Komponen
FAME (1)
Metanol (2)

A
9.4297
18.5875

P
ln P

B
1958.7700
3626.5500

C
-96.9900
-34.2900

175
11.7981

T1 sat
T2 sat
T(c)
P1 sat

P2 sat

Tabel
X
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
0.0000
-42853323.4467
-502.1851

T(k)
ln P
-1000.0000
-726.8500
11.8073
-870.0000
-596.8500
12.2528
-740.0000
-466.8500
12.9037
-610.0000
-336.8500
13.9447
-480.0000
-206.8500
15.8764
-350.0000
-76.8500
20.6974
-220.0000
53.1500
54.1097
-90.0000
183.1500
-13.3044
40.0000
313.1500
0.3680
170.0000
443.1500
3.7711
300.0000
573.1500
5.3160
-1000.0000
-870.0000
-740.0000
-610.0000
-480.0000
-350.0000
-220.0000
-90.0000
40.0000
170.0000
300.0000

-726.8500
-596.8500
-466.8500
-336.8500
-206.8500
-76.8500
53.1500
183.1500
313.1500
443.1500
573.1500

23.3521
24.3335
25.8241
28.3589
33.6267
51.2180
-173.7004
-5.7747
5.5826
9.7176
11.8575

T
1.0000 -1003.2036 t1 sat
1.5757 -870.0000
3.0210 -740.0000
8.5553 -610.0000
59.0457 -480.0000
7326.5170 -350.0000
1.0000 -220.0000
-0.0005
-90.0000
-0.0055
40.0000

-7.0269
0.0000

-0.0023
0.0000

170.0000
295.2888 t2 sat

Td (0C)

Td (K)
212.0000
64.6000

485.0000
337.6000

C
-730.0536
568.4388

mmHg

-1003.2036
295.2888
atm

134229.9603
209564.3255
401788.8499
1137859.5093
7853072.2020
974426759.5793
315887353845559000000000.0000
0.0000
1.4449
43.4292
203.5720

176.6184
275.7425
528.6695
1497.1836
10332.9897
1282140.4731
415641255059946000000.0000
0.0000
0.0019
0.0571
0.2679

13858011801.2045
36975855833.1009
164158875805.8790
2070642522136.4200
401684814281540.0000
17525888417761700000000.0000
0.0000
0.0031
265.7583
16607.2301
141133.1150

18234226.0542
48652441.8857
215998520.7972
2724529634.3900
528532650370.4470
23060379497054900000.0000
0.0000
0.0000
0.3497
21.8516
185.7015

Tabel
max
min
-1000.0000 X1
-870.0000 X2
-740.0000 X3
-610.0000 X4
-480.0000 X5
-350.0000 X6
-220.0000 X7
-90.0000 X8
40.0000 X9
170.0000 X10
300.0000 X11

-1000 C
300 C
1.0000000888 Y1
1.0000020707 Y2
1.0000016374 Y3
1.0000004853 Y4
1.0000000192 Y5
1.0000000000 Y6
0.0000000000 Y7
-42853323.4467311000 Y8
-502.1850986501 Y9
-7.0269360355 Y10
0.0577105042 Y11

1.0092
1.5757
3.0210
8.5553
59.0457
7326.5170
1.0000
-0.0005
-0.0055
-0.0023
0.0001

11.7981
11.7981
180

VLE FAME-Air
Komponen
FAME (1)
Air (2)

A
9.4297
18.3036

P
ln P

175
11.7981

B
1958.7700
3816.4400

C
-96.9900
-46.1300

T1 sat
T2 sat
P1 sat

P2 sat

Tabel
X

T(c)
T(k)
-1000.0000
-864.0000
-728.0000
-592.0000
-456.0000
-320.0000
-184.0000
-48.0000
88.0000
224.0000
360.0000
-1000.0000
-864.0000
-728.0000
-592.0000
-456.0000
-320.0000
-184.0000
-48.0000
88.0000
224.0000
360.0000

ln P
-726.8500
-590.8500
-454.8500
-318.8500
-182.8500
-46.8500
89.1500
225.1500
361.1500
497.1500
633.1500

11.8073
12.2774
12.9792
14.1401
16.4293
23.0474
259.2728
-5.8541
2.0146
4.5347
5.7764

-726.8500
-590.8500
-454.8500
-318.8500
-182.8500
-46.8500
89.1500
225.1500
361.1500
497.1500
633.1500

23.2409
24.2951
25.9215
28.7602
34.9707
59.3494
-70.4096
-3.0149
6.1887
9.8418
11.8022

Y
T
1.0000
1.0000 -1003.2036 t1 sat
1.0000
1.6150
-864.0000
1.0000
3.2580
-728.0000
1.0000
10.4019
-592.0000
1.0000
102.6374
-456.0000
1.0000 76825.8012
-320.0000

0.0000
###
-276.2364
-6.1034
0.0000

1.0000
-0.0621
-0.0156
-0.0043
0.0000

-184.0000
-48.0000
88.0000
224.0000
359.6282 t2 sat

Td (0C)

mmHg

3987968006257560000000000000000000000000000000000000000000000000

Td (K)

atm

52473263240231100000000000000000000000000000000000000000000000

Tabel
max
min
-1000.0000 X1
-864.0000 X2
-728.0000 X3
-592.0000 X4
-456.0000 X5
-320.0000 X6
-184.0000 X7
-48.0000 X8
88.0000 X9
224.0000 X10
360.0000 X11

1.0000000992 Y1
1.0000022987 Y2
1.0000016596 Y3
1.0000004043 Y4
1.0000000088 Y5
1.0000000000 Y6
0.0000000000 Y7
-2879908.8281926300 Y8
-276.2363581408 Y9
-6.1033739689 Y10
0.0041172291 Y11

-1000
300

C
C

11.7981
11.7981
180
1.0092
1.6150
3.2580
10.4019
102.6374
76825.8012
1.0000
-0.0621
-0.0156
-0.0043
0.0000

1360

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