Effect of inorganic nanoparticles on 17β-estradiol and 17α-ethynylestradiol adsorption by multi-walled carbon nanotubes

With extensive application of diverse engineered nanoparticles (NPs), multiple NPs would inevitably be released into the environment. However, much emphasis in most previous studies on the interactions of pollutants with NPs has been placed on only one type of NPs at a time. This study investigated the impact of inorganic NPs (I-NPs) on the adsorption of 17β-estradiol (E2) and 17α-ethynylestradiol (EE2) by multi-walled carbon nanotubes (CNTs). The presence of I-NPs inhibited the adsorption and increased the equilibrium time of E2 and EE2 by CNTs. Moreover, the effect of Al2O3 was stronger than that of SiO2, because electrostatic attraction enhanced the interaction between oppositely charged Al2O3 and CNTs. The addition sequence of I-NPs and pollutant also influences adsorption. This is among the first studies investigating the effect of I-NPs on pollutants adsorption by CNTs, which is useful for understanding the transport and fate of CNTs and contaminants in natural aquatic systems.