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Phoenix dactylifera L. leaf extract phytosynthesized gold nanoparticles; controlled synthesis and catalytic activity

Spectrochim Acta A Mol Biomol Spectrosc. 2014:121:238-44. doi: 10.1016/j.saa.2013.10.092. Epub 2013 Nov 1.

Abstract

A green synthesis route was reported to explore the reducing and capping potential of Phoenix dactylifera extract for the synthesis of gold nanoparticles. The processes of nucleation and growth of gold nanoparticles were followed by monitoring the absorption spectra during the reaction. The size and morphology of these nanoparticles was typically imaged using transmission electron microscopy (TEM). The particle size ranged between 32 and 45 nm and are spherical in shape. Fourier transform infrared (FTIR) analysis suggests that the synthesized gold nanoparticles might be stabilized through the interactions of hydroxyl and carbonyl groups in the carbohydrates, flavonoids, tannins and phenolic acids present in P. dactylifera. The as-synthesized Au colloids exhibited good catalytic activity for the degradation of 4-nitrophenol.

Keywords: 4-Nitrophenol; Gold nanoparticles; Green synthesis; Phoenix dactylifera.

MeSH terms

  • Aminophenols / chemistry
  • Arecaceae / chemistry
  • Arecaceae / physiology*
  • Catalysis
  • Gold / chemistry*
  • Metal Nanoparticles / chemistry*
  • Metal Nanoparticles / ultrastructure
  • Nitrophenols / chemistry
  • Oxidation-Reduction
  • Photosynthesis*
  • Plant Extracts / chemistry*
  • Plant Leaves / physiology*
  • Plant Leaves / ultrastructure
  • Solutions
  • Spectrophotometry, Ultraviolet
  • Spectroscopy, Fourier Transform Infrared

Substances

  • Aminophenols
  • Nitrophenols
  • Plant Extracts
  • Solutions
  • Gold
  • 4-aminophenol
  • 4-nitrophenol