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36 pages, 8543 KiB  
Review
A Review—Durability, Mechanical and Hygrothermal Behavior of Building Materials Incorporating Biomass
by Houssam Affan, Badreddine El Haddaji, Soukaina Ajouguim and Fouzia Khadraoui
Eng 2024, 5(2), 992-1027; https://doi.org/10.3390/eng5020055 - 1 Jun 2024
Viewed by 665
Abstract
The growing importance of environmental efficiency in reducing carbon emissions has prompted scientists around the world to intensify their efforts to prevent the destructive effects of a changing climate and a warming planet. Global carbon emissions rose by more than 40% in 2021, [...] Read more.
The growing importance of environmental efficiency in reducing carbon emissions has prompted scientists around the world to intensify their efforts to prevent the destructive effects of a changing climate and a warming planet. Global carbon emissions rose by more than 40% in 2021, leading to significant variations in the planet’s weather patterns. Nevertheless, a significant proportion of natural resources continue to be exploited. To prepare for this challenge, it is essential to implement a sustainable approach in the construction industry. Biobased materials are made primarily from renewable raw materials like hemp, straw, miscanthus, and jute. These new materials provide excellent thermal and acoustic performance and make optimum use of local natural resources such as agricultural waste. Nowadays, cement is one of the most important construction materials. In an attempt to meet this exciting challenge, biobased materials with low-carbon binders are one of the proposed solutions to create a more insulating and less polluting material. The aim of this review is to investigate and to analyze the impact of the incorporation of different types of biobased materials on the mechanical, thermal, and hygric performance of a mix using different types of binder. Full article
(This article belongs to the Section Materials Engineering)
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Figure 1

Figure 1
<p>Evolution of the use of metal and ceramic fibers towards synthetic fibers and now towards natural fibers [<a href="#B18-eng-05-00055" class="html-bibr">18</a>].</p>
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<p>Comparing the carbon footprints of natural fibers of 4 different natural fibers: hemp, flax, jute, and kenaf [<a href="#B24-eng-05-00055" class="html-bibr">24</a>].</p>
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<p>Examples of several natural fibers currently used in the construction field [<a href="#B25-eng-05-00055" class="html-bibr">25</a>].</p>
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<p>Hemp thrives in the wild [<a href="#B32-eng-05-00055" class="html-bibr">32</a>].</p>
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<p>Hemp shives in bulk with a diameter of 1 cm [<a href="#B50-eng-05-00055" class="html-bibr">50</a>].</p>
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<p>Flax thrives in the wild [<a href="#B58-eng-05-00055" class="html-bibr">58</a>].</p>
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<p><span class="html-italic">Sargassum muticum</span>. (<b>a</b>) Collection; (<b>b</b>) washing; and (<b>c</b>) drying, with color change [<a href="#B27-eng-05-00055" class="html-bibr">27</a>].</p>
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<p>Date palm fiber with two different dimensions, DPF 3 (3 mm) and DPF 6 (6 mm) [<a href="#B77-eng-05-00055" class="html-bibr">77</a>].</p>
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<p>(<b>a</b>) Raw miscanthus, (<b>b</b>) miscanthus powder, and (<b>c</b>) heat-treated miscanthus [<a href="#B85-eng-05-00055" class="html-bibr">85</a>].</p>
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<p>Variation in density with respect to the mass percentages of palm waste fibers [<a href="#B88-eng-05-00055" class="html-bibr">88</a>].</p>
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<p>Compressive strength development of hemp composites (CL90H10—10% hemp; CL90H50—50% hemp; CL90H75—75% hemp with 90% calcic lime binder; TH10—10% hemp; TH50—50% hemp; TH75—75% hemp with Tradical binder) [<a href="#B115-eng-05-00055" class="html-bibr">115</a>].</p>
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<p>Split tensile strength and compressive strength of the composite modified with seaweed powder [<a href="#B75-eng-05-00055" class="html-bibr">75</a>].</p>
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<p>Comparison of the compressive strength of formulations manufactured with 3 different diameters at different rates [<a href="#B77-eng-05-00055" class="html-bibr">77</a>].</p>
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<p>Compressive and flexural strength at 28 days for all mixtures (RM: raw miscanthus; HM: heat-treated miscanthus, and MP: powder miscanthus) [<a href="#B85-eng-05-00055" class="html-bibr">85</a>].</p>
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<p>At the left, the water vapor permeability measured in dry cup and at the right, the same measured in wet cup [<a href="#B138-eng-05-00055" class="html-bibr">138</a>].</p>
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<p>Moisture accumulation in the test room resulting from moisture generation and removal by ventilation, air leakage, and diffusion through test walls [<a href="#B144-eng-05-00055" class="html-bibr">144</a>].</p>
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<p>Classes of moisture buffer values from negligible to excellent [<a href="#B147-eng-05-00055" class="html-bibr">147</a>].</p>
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<p>Sorption/desorption curves obtained at 23 °C and 40 °C for the formulation (HC1: hemp/binder = 0.33; HC2: hemp/binder = 0.42) [<a href="#B158-eng-05-00055" class="html-bibr">158</a>].</p>
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<p>Apparatus used to measure the thermal conductivity [<a href="#B170-eng-05-00055" class="html-bibr">170</a>].</p>
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<p>Thermal conductivity of mixtures with 3 different sizes; MDP3: (diameter of 3 mm), MDP6: (diameter of 3 mm), and MDP mix: (diameters between 3 and 6 mm) and several percentages of date palm fiber [<a href="#B77-eng-05-00055" class="html-bibr">77</a>].</p>
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<p>Total porosity of weathered and unweathered hemp concrete [<a href="#B170-eng-05-00055" class="html-bibr">170</a>].</p>
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<p>Typical failure of hemp–lime concrete under an axial compressive load [<a href="#B92-eng-05-00055" class="html-bibr">92</a>].</p>
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<p>Loosely filled bulk specimen above left and plate-shaped bio-composite specimen above right, ready for measurements in a Netzsch HFM 446 Lambda Small instrument. The graph at the bottom presents the λ values as measured at different average temperatures [<a href="#B178-eng-05-00055" class="html-bibr">178</a>].</p>
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<p>Results of freeze/thaw test on alkali aluminosilicate and Portland cement concrete [<a href="#B182-eng-05-00055" class="html-bibr">182</a>].</p>
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<p>Diagram of the semi-immersion and dry/wet test for sulfate attack on shotcrete [<a href="#B183-eng-05-00055" class="html-bibr">183</a>].</p>
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<p>A sample of the concrete before (<b>A</b>) and after (<b>B</b>) eight cycles of the microbiological test. A loss of cement paste is clearly visible, while the aggregate remains relatively unaffected [<a href="#B184-eng-05-00055" class="html-bibr">184</a>].</p>
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18 pages, 4421 KiB  
Article
Anomalous Warm Temperatures Recorded Using Tree Rings in the Headwater of the Jinsha River during the Little Ice Age
by Chaoling Jiang, Haoyuan Xu, Yuanhe Tong and Jinjian Li
Forests 2024, 15(6), 972; https://doi.org/10.3390/f15060972 - 31 May 2024
Viewed by 507
Abstract
As a feature of global warming, climate change has been a severe issue in the 21st century. A more comprehensive reconstruction is necessary in the climate assessment process, considering the heterogeneity of climate change scenarios across various meteorological elements and seasons. To better [...] Read more.
As a feature of global warming, climate change has been a severe issue in the 21st century. A more comprehensive reconstruction is necessary in the climate assessment process, considering the heterogeneity of climate change scenarios across various meteorological elements and seasons. To better comprehend the change in minimum temperature in winter in the Jinsha River Basin (China), we built a standard tree-ring chronology from Picea likiangensis var. balfouri and reconstructed the regional mean minimum temperature of the winter half-years from 1606 to 2016. This reconstruction provides a comprehensive overview of the changes in winter temperature over multiple centuries. During the last 411 years, the regional climate has undergone seven warm periods and six cold periods. The reconstructed temperature sensitively captures the climate warming that emerged at the end of the 20th century. Surprisingly, during 1650–1750, the lowest winter temperature within the research area was about 0.44 °C higher than that in the 20th century, which differs significantly from the concept of the “cooler” Little Ice Age during this period. This result is validated by the temperature results reconstructed from other tree-ring data from nearby areas, confirming the credibility of the reconstruction. The Ensemble Empirical Mode Decomposition method (EEMD) was adopted to decompose the reconstructed sequence into oscillations of different frequency domains. The decomposition results indicate that the temperature variations in this region exhibit significant periodic changes with quasi-3a, quasi-7a, 15.5-16.8a, 29.4-32.9a, and quasi-82a cycles. Factors like El Niño–Southern Oscillation (ENSO), Pacific Decadal Oscillation (PDO), and solar activity, along with Atlantic Multidecadal Oscillation (AMO), may be important driving forces. To reconstruct this climate, this study integrates the results of three machine learning algorithms and traditional linear regression methods. This novel reconstruction method can provide valuable insights for related research endeavors. Furthermore, other global climate change scenarios can be explored through additional proxy reconstructions. Full article
(This article belongs to the Special Issue Response of Tree Rings to Climate Change and Climate Extremes)
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Figure 1

Figure 1
<p>(<b>a</b>) The specific location of the tree-ring sampling site and meteorological stations utilized in this research, along with (<b>b</b>) the average climatic factors (including the minimum temperature, the average temperature, the maximum temperature, and precipitation) for each month acquired at five meteorological stations from 1961 to 2016.</p>
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<p>The tree ring index and their count shows a red arrow highlighting the first year where the EPS exceeds a value of 0.85.</p>
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<p>The coefficients of the correlation between the tree-ring index and the climatic factors (pre, <span class="html-italic">T</span><sub>min</sub>, <span class="html-italic">T</span><sub>max</sub>, and <span class="html-italic">T</span><sub>mean</sub> indicate the monthly precipitation, minimum temperature, maximum temperature, and mean temperature, respectively). The statistical relationship of the tree-ring index with the climatic indicators, namely monthly precipitation (pre), and the trio of temperatures (minimum (<span class="html-italic">T<sub>min</sub></span>), maximum (<span class="html-italic">T<sub>max</sub></span>), and mean (<span class="html-italic">T<sub>mean</sub></span>)) is delineated by their correlation coefficients. Here, “Winter” represents the winter half-year (from last November to this April), and the correlation coefficients used are Pearson correlation coefficients. The symbols ** and * display the significance levels of 0.01 and 0.05, respectively.</p>
Full article ">Figure 4
<p>(<b>a</b>) Comparison of four reconstruction results; (<b>b</b>) the constructed and observed temperatures during the calibration period of 1960–2016; and (<b>c</b>) the average minimum temperatures for the winter months reconstructed using the chronological data ranging from 1606 to 2016. The red line shows the moving average for 11 years, while the horizontal line signifies the average temperature across the entire reconstructed timeline.</p>
Full article ">Figure 5
<p>The spatial correlations between the observed (<b>a</b>) and reconstructed (<b>b</b>) minimum winter temperatures of the southeastern Tibetan Plateau were assessed against the winter gridded temperatures provided by the Climatic Research Unit (CRU TS 4.07) for the period from 1962 to 2016. The stippled areas indicate statistical significance at the <span class="html-italic">p</span> &lt; 0.01 level.</p>
Full article ">Figure 6
<p>Comparison of the winter minimum temperature reconstruction in this research (<b>a</b>), the winter temperature reconstruction of the southeastern Tibetan Plateau [<a href="#B27-forests-15-00972" class="html-bibr">27</a>] (<b>b</b>), the reconstruction of the warm period temperatures in the southeastern Tibetan Plateau [<a href="#B30-forests-15-00972" class="html-bibr">30</a>] (<b>c</b>), and the reconstructed minimum winter temperatures in the western Sichuan Plateau [<a href="#B66-forests-15-00972" class="html-bibr">66</a>] (<b>d</b>). The regions with shading signify the durations when the reconstructions align in their trend movements.</p>
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<p>Extracted components of reconstructed minimum winter half-year temperatures using Ensemble Empirical Mode Decomposition.</p>
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<p>Spatial correlations of reconstructed (<b>a</b>) and observed (<b>b</b>) minimum winter half-year temperatures with SST data during the period of 1845–2016 and during the period of 1961–2016, respectively. The 95% confidence interval is shown by the dotted region.</p>
Full article ">
16 pages, 3875 KiB  
Article
Effects of Ratoon Rice Cropping Patterns on Greenhouse Gas Emissions and Yield in Double-Season Rice Regions
by Jinbiao Xiang, Liusheng Zhong, Zhixiong Yuan, Liqin Liang, Zhangzhen Yang, Yanmei Xiao, Zhiqiang Fu, Pan Long, Cheng Huang and Ying Xu
Plants 2024, 13(11), 1527; https://doi.org/10.3390/plants13111527 - 31 May 2024
Viewed by 507
Abstract
The ratoon rice cropping pattern is an alternative to the double-season rice cropping pattern in central China due to its comparable annual yield and relatively lower cost and labor requirements. However, the impact of the ratoon rice cropping pattern on greenhouse gas (GHG) [...] Read more.
The ratoon rice cropping pattern is an alternative to the double-season rice cropping pattern in central China due to its comparable annual yield and relatively lower cost and labor requirements. However, the impact of the ratoon rice cropping pattern on greenhouse gas (GHG) emissions and yields in the double-season rice region requires further investigation. Here, we compared two cropping patterns, fallow-double season rice (DR) and fallow-ratoon rice (RR), by using two early-season rice varieties (ZJZ17, LY287) and two late-season rice varieties (WY103, TY390) for DR, and two ratoon rice varieties (YLY911, LY6326) for RR. The six varieties constituted four treatments, including DR1 (ZJZ17 + WY103), DR2 (LY287 + TY390), RR1 (YLY911), and RR2 (LY6326). The experimental results showed that conversion from DR to RR cropping pattern significantly altered the GHG emissions, global warming potential (GWP), and GWP per unit yield (yield-scaled GWP). Compared with DR, the RR cropping pattern significantly increased cumulative methane (CH4), nitrous oxide (N2O), and carbon dioxide (CO2) emissions by 65.73%, 30.56%, and 47.13%, respectively, in the first cropping season. Conversely, in the second cropping season, the RR cropping pattern effectively reduced cumulative CH4, N2O, and CO2 emissions by 79.86%, 27.18%, and 30.31%, respectively. RR led to significantly lower annual cumulative CH4 emissions, but no significant difference in cumulative annual N2O and CO2 emissions compared with DR. In total, the RR cropping pattern reduced the annual GWP by 7.38% and the annual yield-scaled GWP by 2.48% when compared to the DR cropping pattern. Rice variety also showed certain effects on the yields and GHG emissions in different RR cropping patterns. Compared with RR1, RR2 significantly increased annual yield while decreasing annual GWP and annual yield-scaled GWP. In conclusion, the LY6326 RR cropping pattern may be a highly promising strategy to simultaneously reduce GWP and maintain high grain yield in double-season rice regions in central China. Full article
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Figure 1

Figure 1
<p>Crop grain yields during crop growing seasons under different cropping patterns. DR, fallow-double season rice; RR, fallow-ratoon rice. Early-season varieties Zhongjiazao 17 (ZJZ17) and Liangyou 287 (LY287); late-season varieties Wuyou 103 (WY103) and Taiyou 390 (TY390); ratoon rice varieties of Y Liangyou 911 (YLY911) and Liangyou 6326 (LY6326). DR1, ZJZ17 + WY103; DR2, LY287 + TY390; RR1, YLY911; and RR2, LY6326. The vertical bars above the columns represent standard errors (<span class="html-italic">n</span> = 3). Different lowercase letters indicate significant differences in the same season (annual) across cropping patterns at the <span class="html-italic">p</span> &lt; 0.05 level.</p>
Full article ">Figure 2
<p>Seasonal variation and mean flux emissions of CH<sub>4</sub> (<b>a</b>,<b>b</b>), N<sub>2</sub>O (<b>c</b>,<b>d</b>), and CO<sub>2</sub> (<b>e</b>,<b>f</b>) under different cropping patterns. DR, fallow-double season rice; RR, fallow-ratoon rice. Early-season varieties Zhongjiazao 17 (ZJZ17) and Liangyou 287 (LY287); late-season varieties Wuyou 103 (WY103) and Taiyou 390 (TY390); ratoon rice varieties of Y Liangyou 911 (YLY911) and Liangyou 6326 (LY6326). DR1, ZJZ17+ WY103; DR2, LY287 + TY390; RR1, YLY911; and RR2, LY6326. The data are presented as mean (±standard errors). Different lowercase letters indicate significant differences across cropping patterns at the <span class="html-italic">p</span> &lt; 0.05 level. Black and red arrows represent the fertilization timing for early rice and late rice, respectively, while blue and green arrows represent the fertilization timing for the main season and ratoon season, respectively.</p>
Full article ">Figure 3
<p>The cumulative emissions of CH<sub>4</sub> (<b>a</b>), N<sub>2</sub>O (<b>b</b>), and CO<sub>2</sub> (<b>c</b>) under different cropping patterns. DR, fallow-double season rice; RR, fallow-ratoon rice. Early-season varieties Zhongjiazao 17 (ZJZ17) and Liangyou 287 (LY287); late-season varieties Wuyou 103 (WY103) and Taiyou 390 (TY390); ratoon rice varieties of Y Liangyou 911 (YLY911) and Liangyou 6326 (LY6326). DR1, ZJZ17 + WY103; DR2, LY287 + TY390; RR1, YLY911; and RR2, LY6326. The vertical bars above the columns represent standard errors (<span class="html-italic">n</span> = 3). Different lowercase letters indicate significant differences in the same season (annual) across cropping patterns at the <span class="html-italic">p</span> &lt; 0.05 level.</p>
Full article ">Figure 4
<p>The GWP under different cropping patterns. DR, fallow-double season rice; RR, fallow-ratoon rice. Early-season varieties Zhongjiazao 17 (ZJZ17) and Liangyou 287 (LY287); late-season varieties Wuyou 103 (WY103) and Taiyou 390 (TY390); ratoon rice varieties of Y Liangyou 911 (YLY911) and Liangyou 6326 (LY6326). DR1, ZJZ17 + WY103; DR2, LY287 + TY390; RR1, YLY911; and RR2, LY6326. The vertical bars above the columns represent standard errors (<span class="html-italic">n</span> = 3). Different lowercase letters indicate significant differences in the same season (annual) across cropping patterns at the <span class="html-italic">p</span> &lt; 0.05 level.</p>
Full article ">Figure 5
<p>The yield-scaled GWP under different cropping patterns. DR, fallow-double season rice; RR, fallow-ratoon rice. Early-season varieties Zhongjiazao 17 (ZJZ17) and Liangyou 287 (LY287); late-season varieties Wuyou 103 (WY103) and Taiyou 390 (TY390); ratoon rice varieties of Y Liangyou 911 (YLY911) and Liangyou 6326 (LY6326). DR1, ZJZ17 + WY103; DR2, LY287 + TY390; RR1, YLY911; and RR2, LY6326. The vertical bars above the columns represent standard errors (<span class="html-italic">n</span> = 3). Different lowercase letters indicate significant differences across cropping patterns at the <span class="html-italic">p</span> &lt; 0.05 level.</p>
Full article ">Figure 6
<p>Daily total precipitation, maximum and minimum air temperature during the experimental period in Yanxi, China. TP, total precipitation; AT, average air temperature.</p>
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<p>Correlation analysis of greenhouse gas fluxes with soil temperature (ST) and air temperature (AT). The numbers represent the correlation coefficients. *** <span class="html-italic">p</span> &lt; 0.001.</p>
Full article ">Figure 8
<p>Changes in the soil temperature under different cropping patterns. DR, fallow-double season rice; RR, fallow-ratoon rice. Early-season varieties Zhongjiazao 17 (ZJZ17) and Liangyou 287 (LY287); late-season varieties Wuyou 103 (WY103) and Taiyou 390 (TY390); ratoon rice varieties of Y Liangyou 911 (YLY911) and Liangyou 6326 (LY6326). DR1, ZJZ17 + WY103; DR2, LY287 + TY390; RR1, YLY911; RR2, LY6326. The vertical bars above the columns represent standard errors (<span class="html-italic">n</span> = 3). Different lowercase letters indicate significant differences across cropping patterns at the <span class="html-italic">p</span> &lt; 0.05 level.</p>
Full article ">
30 pages, 6252 KiB  
Article
Comprehensive Transcriptome and Proteome Analyses Reveal the Drought Responsive Gene Network in Potato Roots
by Tianyuan Qin, Yihao Wang, Zhuanfang Pu, Ningfan Shi, Richard Dormatey, Huiqiong Wang and Chao Sun
Plants 2024, 13(11), 1530; https://doi.org/10.3390/plants13111530 - 31 May 2024
Viewed by 575
Abstract
The root system plays a decisive role in the growth and development of plants. The water requirement of a root system depends strongly on the plant species. Potatoes are an important food and vegetable crop grown worldwide, especially under irrigation in arid and [...] Read more.
The root system plays a decisive role in the growth and development of plants. The water requirement of a root system depends strongly on the plant species. Potatoes are an important food and vegetable crop grown worldwide, especially under irrigation in arid and semi-arid regions. However, the expected impact of global warming on potato yields calls for an investigation of genes related to root development and drought resistance signaling pathways in potatoes. In this study, we investigated the molecular mechanisms of different drought-tolerant potato root systems in response to drought stress under controlled water conditions, using potato as a model. We analyzed the transcriptome and proteome of the drought-sensitive potato cultivar Atlantic (Atl) and the drought-tolerant cultivar Qingshu 9 (Q9) under normal irrigation (CK) and weekly drought stress (D). The results showed that a total of 14,113 differentially expressed genes (DEGs) and 5596 differentially expressed proteins (DEPs) were identified in the cultivars. A heat map analysis of DEGs and DEPs showed that the same genes and proteins in Atl and Q9 exhibited different expression patterns under drought stress. Weighted gene correlation network analysis (WGCNA) showed that in Atl, Gene Ontology (GO) terms and Kyoto Encyclopedia of Genes and Genomes (KEGG)-enriched pathways were related to pyruvate metabolism and glycolysis, as well as cellular signaling and ion transmembrane transporter protein activity. However, GO terms and KEGG-enriched pathways related to phytohormone signaling and the tricarboxylic acid cycle were predominantly enriched in Q9. The present study provides a unique genetic resource to effectively explore the functional genes and uncover the molecular regulatory mechanism of the potato root system in response to drought stress. Full article
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Figure 1

Figure 1
<p>Pairwise comparative analysis of DEGs (<b>A</b>) and DEPs (<b>B</b>) in Atl and Q9 roots under drought stress.</p>
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<p>Heatmap of DEG (<b>A</b>) and DEP (<b>B</b>) expression in Atl and Q9 roots under drought stress. The order of the genes from top to bottom is the same on the left and right panels of both figures.</p>
Full article ">Figure 3
<p>Venn analysis of DEGs (<b>A</b>,<b>B</b>) and DEPs (<b>C</b>,<b>D</b>) in Atl and Q9 roots under drought stress. (<b>A</b>,<b>B</b>) represent the number of DEGs in the Atl and Q9 roots; (<b>C</b>,<b>D</b>) represent the number of DEPs in the Atl and Q9 roots. The pink bar represents the total number of proteins expressed in the sample; the yellow bar represents the number of proteins expressed in the sample in the Atl and Q9 roots; the pink bar represents the total number of proteins expressed in the sample; the yellow bar represents the number of DEPs in the sample corresponds to the orange dot.</p>
Full article ">Figure 4
<p>Association analysis of DEGs and DEPs in Atl (<b>A</b>) and Q9 (<b>B</b>) roots (R) under control or drought stress at 65 or 90 d. In red parenthesis are the number of genes identified in the nine quadrants.</p>
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<p>KEGG enrichment of genes in Atl (<b>A</b>–<b>D</b>) and Q9 (<b>E</b>–<b>H</b>) candidate modules.</p>
Full article ">Figure 5 Cont.
<p>KEGG enrichment of genes in Atl (<b>A</b>–<b>D</b>) and Q9 (<b>E</b>–<b>H</b>) candidate modules.</p>
Full article ">Figure 6
<p>Gene co-expression network and hub gene mining in Atl and Q9 candidate modules. (<b>A</b>–<b>D</b>) refer to the brown, green, turquoise, and yellow modules in Atl, respectively; (<b>E</b>–<b>H</b>) refer to the brown, blue, turquoise, and yellow modules in Q9, respectively.</p>
Full article ">Figure 7
<p>RT-qPCR Validation of Hub Genes.</p>
Full article ">Figure 7 Cont.
<p>RT-qPCR Validation of Hub Genes.</p>
Full article ">Figure 8
<p>Effect of drought on the morpho-physiological indices of two potato genotypes: (<b>A</b>) Shows the effect on root length; (<b>B</b>) shows the effect on fresh root moisture content; (<b>C</b>) shows dry root matter content; (<b>D</b>) shows root crown ratio. Values represent the mean of 3 replicates; ±standard deviation (SD). Bars with different lowercase letters show significant differences by Duncan’s Multiple Range Test (<span class="html-italic">p</span> ≤ 0.05).</p>
Full article ">Figure 9
<p>Effect of drought on the biochemical indices of two potato genotypes: (<b>A</b>) Shows the effect on MDA content; (<b>B</b>) shows the effect on proline content; (<b>C</b>) shows catalase activity; (<b>D</b>) shows peroxidase activity. Values represent the mean of 3 replicates; ± standard deviation (SD). Bars associated with different lowercase letters indicate significant differences by Duncan’s Multiple Range Test (<span class="html-italic">p</span> ≤ 0.05).</p>
Full article ">
19 pages, 3215 KiB  
Article
Responses of Soil Carbon and Microbial Residues to Degradation in Moso Bamboo Forest
by Shuhan Liu, Xuekun Cheng, Yulong Lv, Yufeng Zhou, Guomo Zhou and Yongjun Shi
Plants 2024, 13(11), 1526; https://doi.org/10.3390/plants13111526 - 31 May 2024
Viewed by 437
Abstract
Moso bamboo (Phyllostachys heterocycla cv. Pubescens) is known for its high capacity to sequester atmospheric carbon (C), which has a unique role to play in the fight against global warming. However, due to rising labor costs and falling bamboo prices, many [...] Read more.
Moso bamboo (Phyllostachys heterocycla cv. Pubescens) is known for its high capacity to sequester atmospheric carbon (C), which has a unique role to play in the fight against global warming. However, due to rising labor costs and falling bamboo prices, many Moso bamboo forests are shifting to an extensive management model without fertilization, resulting in gradual degradation of Moso bamboo forests. However, many Moso bamboo forests are being degraded due to rising labor costs and declining bamboo timber prices. To delineate the effect of degradation on soil microbial carbon sequestration, we instituted a rigorous analysis of Moso bamboo forests subjected to different degradation durations, namely: continuous management (CK), 5 years of degradation (D-5), and 10 years of degradation (D-10). Our inquiry encompassed soil strata at 0–20 cm and 20–40 cm, scrutinizing alterations in soil organic carbon(SOC), water-soluble carbon(WSOC), microbial carbon(MBC)and microbial residues. We discerned a positive correlation between degradation and augmented levels of SOC, WSOC, and MBC across both strata. Furthermore, degradation escalated concentrations of specific soil amino sugars and microbial residues. Intriguingly, extended degradation diminished the proportional contribution of microbial residuals to SOC, implying a possible decline in microbial activity longitudinally. These findings offer a detailed insight into microbial C processes within degraded bamboo ecosystems. Full article
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<p>The content of soil organic carbon (SOC), microbial carbon (MBC) and water-soluble carbon (WSOC) in CK, D-5 and D-10. <span class="html-italic">p</span> represents a significant difference between groups. *, ** and *** respectively represent <span class="html-italic">p &lt;</span> 0.05, <span class="html-italic">p &lt;</span> 0.01 and <span class="html-italic">p &lt;</span> 0.001. The letters represent differences between different degradation time in the same group. (<b>a</b>–<b>c</b>) are WSOC, MBC and SOC Pearson correlation analysis at 0–20 cm soil depth, (<b>d</b>–<b>f</b>) are WSOC, MBC and SOC Pearson correlation analysis at 20–40 cm soil depth.</p>
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<p>The content of glucosamine, galactosamine, muramic acid and epichitosamine in CK, D-5 and D-10. <span class="html-italic">p</span> represents a significant difference between groups. *, and *** respectively represent <span class="html-italic">p &lt;</span> 0.05 and <span class="html-italic">p &lt;</span> 0.001. The letters represent differences between different degradation time in the same group. (<b>a</b>–<b>d</b>) are WSOC, MBC and SOC Pearson correlation analysis at 0–20 cm soil depth, (<b>e</b>–<b>h</b>) are WSOC, MBC and SOC Pearson correlation analysis at 20–40 cm soil depth.</p>
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<p>Changes in the influences of degradation on microbial residues (<b>a</b>,<b>b</b>) and the contribution of microbial residues to Moso bamboo soil (<b>c</b>,<b>d</b>). MR means microbial residues; FR means fungal residues; BR means bacterial residues. MR/SOC, FR/SOC and BR/SOC mean their contribution to soil organic C, and show their contribution to soil organic C. The letters represent differences between different degradation time in the same group.</p>
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<p>Pearson correlation analysis of soil carbon and microbial residues. *, ** and *** respectively represent <span class="html-italic">p &lt;</span> 0.05, <span class="html-italic">p &lt;</span> 0.01 and <span class="html-italic">p &lt;</span> 0.001, represent the correlation significance. (<b>a</b>–<b>c</b>) are WSOC, MBC and SOC Pearson correlation analysis at 0–20 cm soil depth, (<b>d</b>–<b>f</b>) are WSOC, MBC and SOC Pearson correlation analysis at 20–40 cm soil depth.</p>
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<p>Effect of degradation time on contribution of microbial residues to SOC (the whole circle represents the SOC).</p>
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<p>Location of the studied Moso bamboo forest. The base image is from National Geographic Information Public Service Platform (<a href="https://www.tianditu.gov.cn" target="_blank">https://www.tianditu.gov.cn</a> (accessed on 12 April 2023)). Image processing using ArcMap (10.8).</p>
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22 pages, 7410 KiB  
Article
Bond Stress Behavior of a Steel Reinforcing Bar Embedded in Geopolymer Concrete Incorporating Natural and Recycled Aggregates
by Qasim Shaukat Khan, Haroon Akbar, Asad Ullah Qazi, Syed Minhaj Saleem Kazmi and Muhammad Junaid Munir
Infrastructures 2024, 9(6), 93; https://doi.org/10.3390/infrastructures9060093 - 31 May 2024
Cited by 1 | Viewed by 566
Abstract
The rise in greenhouse gases, particularly carbon dioxide (CO2) emissions, in the atmosphere is one of the major causes of global warming and climate change. The production of ordinary Portland cement (OPC) emits harmful CO2 gases, which contribute to sporadic [...] Read more.
The rise in greenhouse gases, particularly carbon dioxide (CO2) emissions, in the atmosphere is one of the major causes of global warming and climate change. The production of ordinary Portland cement (OPC) emits harmful CO2 gases, which contribute to sporadic heatwaves, rapid melting of glaciers, flash flooding, and food shortages. To address global warming and climate change challenges, this research study explores the use of a cement-less recycled aggregate concrete, a sustainable approach for future constructions. This study uses fly ash, an industrial waste of coal power plants, as a 100% substitute for OPC. Moreover, this research study also uses recycled coarse aggregates (RCAs) as a partial to complete replacement for natural coarse aggregates (NCAs) to preserve natural resources for future generations. In this research investigation, a total of 60 pull-out specimens were prepared to investigate the influence of steel bar diameter (9.5 mm, 12.7 mm, and 19.1 mm), bar embedment length, db (4db and 6db), and percentage replacements of NCA with RCA (25%, 50%, 75%, and 100%) on the bond stress behavior of cement-less RA concrete. The test results exhibited that the bond stress of cement-less RCA concrete decreased by 6% with increasing steel bar diameter. Moreover, the bond stress decreased by 5.5% with increasing bar embedment length. Furthermore, the bond stress decreased by 7.6%, 7%, 8.8%, and 20.4%, respectively, with increasing percentage replacements (25%, 50%, 75%, and 100%) of NCA with RCA. An empirical model was developed correlating the bond strength to the mean compressive strength of cement-less RCA concrete, which matched well with the experimental test results and predictions of the CEB-FIP model for OPC. The CRAC mixes exhibited higher costs but significantly lower embodied CO2 emissions than OPC concrete. Full article
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<p>The materials used in GPC are (<b>a</b>) fly ash, (<b>b</b>) sand, (<b>c</b>) NCA, and (<b>d</b>) RCA.</p>
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<p>Concrete crusher machine.</p>
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<p>Stages in the preparation of alkaline activator solution used in GPC.</p>
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<p>Detail of pull-out test specimen.</p>
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<p>Steel bars enveloped with PVC tubes.</p>
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<p>Cylindrical molds placed on a mechanical vibrating table before concrete pouring.</p>
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<p>Demolded samples stored at room temperature.</p>
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<p>Pull-out test setup.</p>
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<p>Yielding/bond failure in tested pull-out specimens.</p>
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<p>Splitting failure in pull-out test specimens.</p>
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<p>Influence of embedment lengths on bond stress of CRAC mixes.</p>
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<p>Influence of varying diameters of embedded steel bar in CRAC mixes.</p>
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<p>Influence of varying percentage replacements of NCA with RCA in the CRAC mix.</p>
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<p>Stress–slip curves of tested pull-out specimens.</p>
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<p>Analytical predictions of bond stress with varying compressive strength using existing models and the proposed model [<a href="#B25-infrastructures-09-00093" class="html-bibr">25</a>,<a href="#B48-infrastructures-09-00093" class="html-bibr">48</a>,<a href="#B49-infrastructures-09-00093" class="html-bibr">49</a>,<a href="#B51-infrastructures-09-00093" class="html-bibr">51</a>,<a href="#B52-infrastructures-09-00093" class="html-bibr">52</a>].</p>
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51 pages, 13880 KiB  
Review
Towards Reliable Prediction of Performance for Polymer Electrolyte Membrane Fuel Cells via Machine Learning-Integrated Hybrid Numerical Simulations
by Rashed Kaiser, Chi-Yeong Ahn, Yun-Ho Kim and Jong-Chun Park
Processes 2024, 12(6), 1140; https://doi.org/10.3390/pr12061140 - 31 May 2024
Viewed by 649
Abstract
For mitigating global warming, polymer electrolyte membrane fuel cells have become promising, clean, and sustainable alternatives to existing energy sources. To increase the energy density and efficiency of polymer electrolyte membrane fuel cells (PEMFC), a comprehensive numerical modeling approach that can adequately predict [...] Read more.
For mitigating global warming, polymer electrolyte membrane fuel cells have become promising, clean, and sustainable alternatives to existing energy sources. To increase the energy density and efficiency of polymer electrolyte membrane fuel cells (PEMFC), a comprehensive numerical modeling approach that can adequately predict the multiphysics and performance relative to the actual test such as an acceptable depiction of the electrochemistry, mass/species transfer, thermal management, and water generation/transportation is required. However, existing models suffer from reliability issues due to their dependency on several assumptions made for the sake of modeling simplification, as well as poor choices and approximations in material characterization and electrochemical parameters. In this regard, data-driven machine learning models could provide the missing and more appropriate parameters in conventional computational fluid dynamics models. The purpose of the present overview is to explore the state of the art in computational fluid dynamics of individual components of the modeling of PEMFC, their issues and limitations, and how they can be significantly improved by hybrid modeling techniques integrating with machine learning approaches. Furthermore, a detailed future direction of the proposed solution related to PEMFC and its impact on the transportation sector is discussed. Full article
(This article belongs to the Special Issue Modeling, Simulation and Control in Energy Systems)
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<p>Schematic and operation of a conventional PEMFC.</p>
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<p>(<b>a</b>) Polarization curve of the statistical simulation model of the baseline MEA with experimental validation. (<b>b</b>) Liquid water distribution across the nondimensional distance (t*) of MEA where colored line indicates different saturation level; reproduced with permission [<a href="#B84-processes-12-01140" class="html-bibr">84</a>]; copyright 2013, IOP publishers. (<b>c</b>) Snapshots of equilibrated systems comprising the Pt (111) surface, hydrated Nafion ionomers, and O<sub>2</sub> molecules with different λ (water molecules per sulfonic acid group). Illustrations show the hydrated Nafion thin film (<b>A</b>–<b>D</b>) and hydrated Aquivion thin film (<b>E</b>–<b>H</b>) on a Pt surface; reproduced with permission [<a href="#B85-processes-12-01140" class="html-bibr">85</a>]; copyright 2021, Springer Nature. (<b>d</b>) Mean square displacement of water at 300 and 350 K measured from MD simulation; reproduced with permission [<a href="#B83-processes-12-01140" class="html-bibr">83</a>]; copyright 2018, Elsevier Ltd.</p>
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<p>Transformation of membrane structure due to change in water content <math display="inline"><semantics> <mrow> <mi>λ</mi> </mrow> </semantics></math> (<b>a</b>–<b>d</b>) reproduced with permission [<a href="#B100-processes-12-01140" class="html-bibr">100</a>]; 2003 The Electrochemical Society, Inc.</p>
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<p>(<b>a</b>) The architecture of trained NARX network for membrane water content, λ prediction; reproduced with permission [<a href="#B43-processes-12-01140" class="html-bibr">43</a>]; 2012 Elsevier Ltd. (<b>b</b>) Simulink dynamic model with GA-BP to estimate real-time water content of membrane; reproduced with permission [<a href="#B154-processes-12-01140" class="html-bibr">154</a>]; 2023 MDPI (<b>c</b>) performance prediction model by CNN, where membrane thickness, hot press time, and pressure for making catalyst coated membrane (CCM) are some of the input parameters; reproduced with permission [<a href="#B145-processes-12-01140" class="html-bibr">145</a>]; 2021 Elsevier Ltd.; (<b>d</b>) input vectors of LSTM that are responsible for PEMFC water transport across the membrane; and (<b>e</b>) comparison of flooding fault diagnosis by experiment and LSTM network; reproduced with permission [<a href="#B155-processes-12-01140" class="html-bibr">155</a>]; 2021 Elsevier Ltd.</p>
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<p>(<b>a</b>) The architecture of trained NARX network for membrane water content, λ prediction; reproduced with permission [<a href="#B43-processes-12-01140" class="html-bibr">43</a>]; 2012 Elsevier Ltd. (<b>b</b>) Simulink dynamic model with GA-BP to estimate real-time water content of membrane; reproduced with permission [<a href="#B154-processes-12-01140" class="html-bibr">154</a>]; 2023 MDPI (<b>c</b>) performance prediction model by CNN, where membrane thickness, hot press time, and pressure for making catalyst coated membrane (CCM) are some of the input parameters; reproduced with permission [<a href="#B145-processes-12-01140" class="html-bibr">145</a>]; 2021 Elsevier Ltd.; (<b>d</b>) input vectors of LSTM that are responsible for PEMFC water transport across the membrane; and (<b>e</b>) comparison of flooding fault diagnosis by experiment and LSTM network; reproduced with permission [<a href="#B155-processes-12-01140" class="html-bibr">155</a>]; 2021 Elsevier Ltd.</p>
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<p>Framework of the PEMFC membrane model integrated with ML. (MSD—mean square displacement, HPT—hot press time (min), HPP—hot press pressure, MHA—meta-heuristic algorithms).</p>
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<p>Distinctive features of different CL models.</p>
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<p>(<b>a</b>) Network architecture of the U-ResNet (bottom), for image feature extraction and useful feature decoding for various components of PEMFC, including CL; reproduced with permission [<a href="#B244-processes-12-01140" class="html-bibr">244</a>]; 2023 Springer Nature, (<b>b</b>) ANN architecture for PEMFC performance prediction where CL properties are some of the input parameters; reproduced with permission [<a href="#B147-processes-12-01140" class="html-bibr">147</a>]; 2020 John Wiley and Sons, (<b>c</b>) prediction of the CCL performance of a PEMFC by data-driven ML model where various structure parameters of CCL are utilized; reproduced with permission [<a href="#B253-processes-12-01140" class="html-bibr">253</a>]; 2022 Elsevier Ltd., (<b>d</b>) architecture for ANN model for predicting electrocatalyst performance regarding EASA and reduction of Pt in CL surface where columns of circular nodes represents the layers for inputs, hidden and outputs; reproduced with permission [<a href="#B247-processes-12-01140" class="html-bibr">247</a>]; 2022 John Wiley and Sons; (<b>e</b>) framework for CL parameter optimization, combining RSM and ANN model; reproduced with permission [<a href="#B245-processes-12-01140" class="html-bibr">245</a>]; 2023 Elsevier Ltd. and (<b>f</b>) the structure of the G-LSTM with RNN for predicting voltage degradation due to carbon corrosion, Pt loss of CL, and membrane degradation.; reproduced with permission [<a href="#B256-processes-12-01140" class="html-bibr">256</a>]; 2018 Elsevier Ltd.</p>
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<p>(<b>a</b>) Network architecture of the U-ResNet (bottom), for image feature extraction and useful feature decoding for various components of PEMFC, including CL; reproduced with permission [<a href="#B244-processes-12-01140" class="html-bibr">244</a>]; 2023 Springer Nature, (<b>b</b>) ANN architecture for PEMFC performance prediction where CL properties are some of the input parameters; reproduced with permission [<a href="#B147-processes-12-01140" class="html-bibr">147</a>]; 2020 John Wiley and Sons, (<b>c</b>) prediction of the CCL performance of a PEMFC by data-driven ML model where various structure parameters of CCL are utilized; reproduced with permission [<a href="#B253-processes-12-01140" class="html-bibr">253</a>]; 2022 Elsevier Ltd., (<b>d</b>) architecture for ANN model for predicting electrocatalyst performance regarding EASA and reduction of Pt in CL surface where columns of circular nodes represents the layers for inputs, hidden and outputs; reproduced with permission [<a href="#B247-processes-12-01140" class="html-bibr">247</a>]; 2022 John Wiley and Sons; (<b>e</b>) framework for CL parameter optimization, combining RSM and ANN model; reproduced with permission [<a href="#B245-processes-12-01140" class="html-bibr">245</a>]; 2023 Elsevier Ltd. and (<b>f</b>) the structure of the G-LSTM with RNN for predicting voltage degradation due to carbon corrosion, Pt loss of CL, and membrane degradation.; reproduced with permission [<a href="#B256-processes-12-01140" class="html-bibr">256</a>]; 2018 Elsevier Ltd.</p>
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<p>Framework of the PEMFC CL model integrated with ML.</p>
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<p>(<b>a</b>) Workflow for developing deep learning-based model for segmentation from wet images of GDL (top), original GDL images at a resolution of 384 × 384 pixels, along with the segmented images produced using trainable 3D Weka segmentation (down). The aqueous phase is shown in blue, air in red, and fibers in green in the segmented images whereas rectangles highlight examples of potential segmentation errors; reproduced with permission [<a href="#B297-processes-12-01140" class="html-bibr">297</a>]; 2023 Elsevier Ltd., (<b>b</b>) ML approach for predicting the permeability of GDL from image data from previous lattice Boltzmann (LB) simulations; reproduced with permission [<a href="#B298-processes-12-01140" class="html-bibr">298</a>]; 2022 MDPI, (<b>c</b>) architecture of neural network to investigate effect of GDL properties on PEMFC; reproduced with permission [<a href="#B299-processes-12-01140" class="html-bibr">299</a>]; 2010 Elsevier Ltd., and (<b>d</b>) schematic of ML-based prognostics of PEMFC where carbon corrosion and hydrophobic loss of GDL are among the reasons for degradation; reproduced with permission [<a href="#B302-processes-12-01140" class="html-bibr">302</a>]; 2023 Elsevier Ltd.</p>
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<p>(<b>a</b>) Workflow for developing deep learning-based model for segmentation from wet images of GDL (top), original GDL images at a resolution of 384 × 384 pixels, along with the segmented images produced using trainable 3D Weka segmentation (down). The aqueous phase is shown in blue, air in red, and fibers in green in the segmented images whereas rectangles highlight examples of potential segmentation errors; reproduced with permission [<a href="#B297-processes-12-01140" class="html-bibr">297</a>]; 2023 Elsevier Ltd., (<b>b</b>) ML approach for predicting the permeability of GDL from image data from previous lattice Boltzmann (LB) simulations; reproduced with permission [<a href="#B298-processes-12-01140" class="html-bibr">298</a>]; 2022 MDPI, (<b>c</b>) architecture of neural network to investigate effect of GDL properties on PEMFC; reproduced with permission [<a href="#B299-processes-12-01140" class="html-bibr">299</a>]; 2010 Elsevier Ltd., and (<b>d</b>) schematic of ML-based prognostics of PEMFC where carbon corrosion and hydrophobic loss of GDL are among the reasons for degradation; reproduced with permission [<a href="#B302-processes-12-01140" class="html-bibr">302</a>]; 2023 Elsevier Ltd.</p>
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<p>Framework of the PEMFC GDL model integrated with ML. Inset picture represents reproduced with permission [<a href="#B297-processes-12-01140" class="html-bibr">297</a>]; 2023 Elsevier Ltd images from LB simulation (top left); reproduced with permission [<a href="#B298-processes-12-01140" class="html-bibr">298</a>].</p>
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<p>(<b>a</b>) Schematic of ANN model (top) for predicting current densities (bottom) of different types of flow channels where <math display="inline"><semantics> <mrow> <msubsup> <mrow> <mi>w</mi> </mrow> <mrow> <mi>i</mi> <mi>j</mi> </mrow> <mrow> <mn>1</mn> </mrow> </msubsup> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <msubsup> <mrow> <mi>w</mi> </mrow> <mrow> <mi>i</mi> <mi>j</mi> </mrow> <mrow> <mn>2</mn> </mrow> </msubsup> </mrow> </semantics></math> represent the weights between the input and the first hidden layer, and the weights between the first and second hidden layers, respectively; reproduced with permission [<a href="#B40-processes-12-01140" class="html-bibr">40</a>]; 2017 Elsevier Ltd.; (<b>b</b>) ANN structure to improve the 3D fine-mesh flow field; (<b>c</b>) comparison of performance for 2 optimized flow configuration with the base model regarding molar concentration of O<sub>2</sub>; reproduced with permission [<a href="#B322-processes-12-01140" class="html-bibr">322</a>]; 2022 Elsevier Ltd.; (<b>d</b>) diagram of bagging ensemble algorithm to predicting the performance of PEMFC using different block arrangements in the flow channel; and (<b>e</b>) corresponding polarization in comparison to BP and simulation; reproduced with permission [<a href="#B327-processes-12-01140" class="html-bibr">327</a>]; 2022 Elsevier Ltd.</p>
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<p>(<b>a</b>) Schematic of ANN model (top) for predicting current densities (bottom) of different types of flow channels where <math display="inline"><semantics> <mrow> <msubsup> <mrow> <mi>w</mi> </mrow> <mrow> <mi>i</mi> <mi>j</mi> </mrow> <mrow> <mn>1</mn> </mrow> </msubsup> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <msubsup> <mrow> <mi>w</mi> </mrow> <mrow> <mi>i</mi> <mi>j</mi> </mrow> <mrow> <mn>2</mn> </mrow> </msubsup> </mrow> </semantics></math> represent the weights between the input and the first hidden layer, and the weights between the first and second hidden layers, respectively; reproduced with permission [<a href="#B40-processes-12-01140" class="html-bibr">40</a>]; 2017 Elsevier Ltd.; (<b>b</b>) ANN structure to improve the 3D fine-mesh flow field; (<b>c</b>) comparison of performance for 2 optimized flow configuration with the base model regarding molar concentration of O<sub>2</sub>; reproduced with permission [<a href="#B322-processes-12-01140" class="html-bibr">322</a>]; 2022 Elsevier Ltd.; (<b>d</b>) diagram of bagging ensemble algorithm to predicting the performance of PEMFC using different block arrangements in the flow channel; and (<b>e</b>) corresponding polarization in comparison to BP and simulation; reproduced with permission [<a href="#B327-processes-12-01140" class="html-bibr">327</a>]; 2022 Elsevier Ltd.</p>
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<p>Framework of the PEMFC BP model integrated with ML.</p>
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<p>Cycle of PEMFC development through experiment, CFD and ML.</p>
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16 pages, 1161 KiB  
Article
Preventing through Sustainability Education: Training and the Perception of Floods among School Children
by Álvaro-Francisco Morote and Jorge Olcina
Sustainability 2024, 16(11), 4678; https://doi.org/10.3390/su16114678 - 30 May 2024
Viewed by 453
Abstract
The global warming process is altering the atmospheric dynamics at mid-latitudes, fostering an increase in the frequency of extreme events. Of these events, floods are those that cause the greatest loss of human life and economic damage in Spain. Education is a key [...] Read more.
The global warming process is altering the atmospheric dynamics at mid-latitudes, fostering an increase in the frequency of extreme events. Of these events, floods are those that cause the greatest loss of human life and economic damage in Spain. Education is a key element in preventing these hazards. The objective of this study is to analyze the training, knowledge, and perception that school children (Primary and Secondary education, Baccalaureate) in the Region of Valencia (Spain) have of floods. The research was based on a questionnaire that was administered in different schools and in which 926 students participated. The main results show that only 36.1% have received training in these phenomena, and more than half (54.2%) do not know whether floods are explained in the textbooks. With respect to the perception of these risks, half of the respondents indicate that climate change is increasing the damage caused by floods, and 57.6% believe that it will accelerate them in the future. The study advances the knowledge necessary to establish learning contents and guidelines at the basic levels of education on natural hazards and disaster prevention. Full article
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<p>Responses of students on their knowledge about DANAs (Item 6). Source: results of the questionnaire. Coding of the answers to Item 6: 1 (“Very heavy rain and storms”); 2 (“Hurricanes, tornadoes, strong winds”); 3 (“Cold drop”, High-level Isolated Depression); 4 (“Cold weather situations”); 5 (“Other”). Own elaboration.</p>
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<p>Changes in the way it rains (Item 8). Source: questionnaire results. Answers to Item 8: 0 (“Do not know/No answer”); 1 (“It rains less than before but with more intensity”); 2 (“It rains more than before and with more intensity”); 3 (“It rains the same as before but with greater intensity”); 4 (“The way it rains has not changed”). Own elaboration.</p>
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<p>“Why do floods cause increasingly more damage?” (Item 9). Source: questionnaire results. Answers to item 9: 0 (“Do not know/No answer”); 1 (“Because it rains a lot”); 2 (“Because the water in the rivers circulates more rapidly”); 3 (“Because the houses are constructed in floodable areas”); 4 (“Because climate change is causing it”). Own elaboration.</p>
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19 pages, 6091 KiB  
Article
Agroclimatic Indicators for Grapevines in the Zielona Góra Wine Region (Poland) in the Era of Advancing Global Warming
by Dominika Jaster, Arkadiusz Marek Tomczyk, Iwona Hildebrandt-Radke and Paweł Matulewski
Atmosphere 2024, 15(6), 657; https://doi.org/10.3390/atmos15060657 - 30 May 2024
Viewed by 290
Abstract
Grapevine is a highly climate-sensitive plant. In the last few decades, an increase in the number and area of vineyards has been observed in the country, with the Zielona Góra region pioneering this revival. A comprehensive analysis of climatic and agroclimatic indicators for [...] Read more.
Grapevine is a highly climate-sensitive plant. In the last few decades, an increase in the number and area of vineyards has been observed in the country, with the Zielona Góra region pioneering this revival. A comprehensive analysis of climatic and agroclimatic indicators for grapevines was conducted to assess the possibilities and limitations in this region. Based on data obtained from the Institute of Meteorology and Water Management—National Research Institute (IMGW-PIB) for stations in Zielona Góra, nine key indicators were identified. The analysis of agroclimatic conditions for the Zielona Góra winegrowing region from 1951 to 2022 revealed significant changes in air temperature, length of the vegetative period, and number of frosts. The average annual air temperature increased, while the number of days with temperatures below 8 °C decreased. The extension of the vegetative period (starting earlier and ending later) favours grapevine cultivation. The increase in temperature during the vegetative period and the lengthening of the frost-free period have a beneficial effect on grape production in the Zielona Góra region. Full article
(This article belongs to the Section Biometeorology)
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<p>Location of the Zielona Góra wine region showing currently existing vineyards.</p>
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<p>Average annual air temperature in Zielona Góra from 1951 to 2022.</p>
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<p>Average air temperature of the warmest month in Zielona Góra from 1951 to 2022.</p>
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<p>Average January temperature in Zielona Gora from 1951 to 2022.</p>
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<p>Total precipitation from April to October in Zielona Góra from 1951 to 2022.</p>
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<p>Date of first spring frost (blue line) and first autumn frost (orange line) and length of frost-free period (grey bars) for Zielona Góra station in 1951–2022.</p>
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<p>Number of days with frost by month in Zielona Góra from 1951 to 2022.</p>
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<p>Intensity of frost in April in Zielona Góra from 1951 to 2022.</p>
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<p>Intensity of frost in October in Zielona Góra from 1951 to 2022.</p>
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<p>Comparison of SAT and GDD values in Zielona Góra between 1951 and 2022.</p>
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19 pages, 1853 KiB  
Review
Biological Carbon Sequestration: From Deep History to the Present Day
by Denis J. Murphy
Earth 2024, 5(2), 195-213; https://doi.org/10.3390/earth5020010 - 30 May 2024
Cited by 2 | Viewed by 1131
Abstract
In the global carbon cycle, atmospheric carbon emissions, both ‘natural’ and anthropogenic, are balanced by carbon uptake (i.e., sequestration) that mostly occurs via photosynthesis, plus a much smaller proportion via geological processes. Since the formation of the Earth about 4.54 billion years ago, [...] Read more.
In the global carbon cycle, atmospheric carbon emissions, both ‘natural’ and anthropogenic, are balanced by carbon uptake (i.e., sequestration) that mostly occurs via photosynthesis, plus a much smaller proportion via geological processes. Since the formation of the Earth about 4.54 billion years ago, the ratio between emitted and sequestered carbon has varied considerably, with atmospheric CO2 levels ranging from 100,000 ppm to a mere 100 ppm. Over this time, a huge amount of carbon has been sequestered due to photosynthesis and essentially removed from the cycle, being buried as fossil deposits of coal, oil, and gas. Relatively low atmospheric CO2 levels were the norm for the past 10 million years, and during the past million years, they averaged about 220 ppm. More recently, the Holocene epoch, starting ~11,700 years ago, has been a period of unusual climatic stability with relatively warm, moist conditions and low atmospheric CO2 levels of between 260 and 280 ppm. During the Holocene, stable conditions facilitated a social revolution with the domestication of crops and livestock, leading to urbanisation and the development of complex technologies. As part of the latter process, immense quantities of sequestered fossil carbon have recently been used as energy sources, resulting in a particularly rapid increase in CO2 emissions after 1950 CE to the current value of 424 ppm, with further rises to >800 ppm predicted by 2100. This is already perturbing the previously stable Holocene climate and threatening future food production and social stability. Today, the global carbon cycle has been shifted such that carbon sequestration is no longer keeping up with recent anthropogenic emissions. In order to address this imbalance, it is important to understand the roles of potential biological carbon sequestration systems and to devise strategies to facilitate net CO2 uptake; for example, via changes in the patterns of land use, such as afforestation, preventing deforestation, and facilitating agriculture–agroforestry transitions. Full article
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<p>Global carbon budget showing the imbalance between emissions and sinks. The main sinks are terrestrial and oceanic sequestration of CO<sub>2</sub>. Due to this imbalance, atmospheric CO<sub>2</sub> concentrations are now at a 16-million-year high. Graphic from Ref. [<a href="#B17-earth-05-00010" class="html-bibr">17</a>].</p>
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<p>Changes in the atmospheric composition since 4.0 Ga. At the start of the Archaean, about 4.0 Ga of the Earth’s atmosphere was dominated by methane (orange), CO<sub>2</sub> (yellow), and nitrogen (blue). Oxygen (green) was less than one-millionth of current levels and remained low from 4.0 to 2.4 Ga. Graphic from Ref. [<a href="#B25-earth-05-00010" class="html-bibr">25</a>].</p>
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<p>Low concentrations of atmospheric CO<sub>2</sub> were the norm for the past 800,000 years until recent decades. Graphic from Ref. [<a href="#B12-earth-05-00010" class="html-bibr">12</a>].</p>
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<p>The climate over the past 100,000 years was highly erratic until the onset of the Holocene about 11,700 years ago (X), and since then, it has been relatively warm and moist—the so-called Holocene Climatic Optimum (red bar). Despite their small size and duration, the two minor oscillations at ~8200 years (Y) and ~4200 years ago (Z) caused significant, albeit localised, social collapses, emphasising the narrow climatic range required for agriculture-based human life. Graphic from Ref. [<a href="#B77-earth-05-00010" class="html-bibr">77</a>].</p>
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<p>Changes in agricultural land use and atmospheric CO<sub>2</sub> concentrations over the past 8 millennia of the mid-late Holocene. (<b>a</b>) Global area of crop and pasture land (million km<sup>2</sup>). (<b>b</b>) Atmospheric CO<sub>2</sub> concentration (ppm). CE, common era. Graphic from Ref. [<a href="#B85-earth-05-00010" class="html-bibr">85</a>].</p>
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<p>Annual total CO<sub>2</sub> emissions by world region. At about 1950, there was an inflection point (red arrow) as CO<sub>2</sub> emissions entered a period of more rapid and sustained increases. Graphic from the Carbon Dioxide Information Analysis Center (CDIAC); Global Carbon Project (GCP).</p>
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17 pages, 945 KiB  
Article
Potential Strengthening of the Madden–Julian Oscillation Modulation of Tropical Cyclogenesis
by Patrick Haertel and Yu Liang
Atmosphere 2024, 15(6), 655; https://doi.org/10.3390/atmos15060655 - 30 May 2024
Viewed by 435
Abstract
A typical Madden–Julian Oscillation (MJO) generates a large region of enhanced rainfall over the equatorial Indian Ocean that moves slowly eastward into the western Pacific. Tropical cyclones often form on the poleward edges of the MJO moist-convective envelope, frequently impacting both southeast Asia [...] Read more.
A typical Madden–Julian Oscillation (MJO) generates a large region of enhanced rainfall over the equatorial Indian Ocean that moves slowly eastward into the western Pacific. Tropical cyclones often form on the poleward edges of the MJO moist-convective envelope, frequently impacting both southeast Asia and northern Australia, and on occasion Eastern Africa. This paper addresses the question of whether these MJO-induced tropical cyclones will become more numerous in the future as the oceans warm. The Lagrangian Atmosphere Model (LAM), which has been carefully tuned to simulate realistic MJO circulations, is used to study the sensitivity of MJO modulation of tropical cyclogenesis (TCG) to global warming. A control simulation for the current climate is compared with a simulation with enhanced radiative forcing consistent with that for the latter part of the 21st century under Shared Socioeconomic Pathway (SSP) 585. The LAM control run reproduces the observed MJO modulation of TCG, with about 70 percent more storms forming than monthly climatology predicts within the MJO’s convective envelope. The LAM SSP585 run suggests that TCG enhancement within the convective envelope could reach 170 percent of the background value under a high greenhouse gas emissions scenario, owing to a strengthening of Kelvin and Rossby wave components of the MJO’s circulation. Full article
(This article belongs to the Section Meteorology)
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<p>Time-longitue series of rainfall for composite MJOs based on (<b>a</b>) observations and (<b>b</b>) the LAM control run. The contour interval is 0.4 mm/day and values greater than 0.4 (1.2) mm/day are shaded light (dark) gray. The path of the center of the convective envelope is shown with a color coded line for each stage. Panel (<b>a</b>) is from [<a href="#B52-atmosphere-15-00655" class="html-bibr">52</a>].</p>
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<p>The horizontal structure of the composite MJO based on (<b>a</b>–<b>c</b>) observations and (<b>d</b>–<b>f</b>) the LAM control run for the developing, mature, and dissipating stages, respectively. Mean 200–850 hPa temperature is contoured, vectors indicate the difference between 850 and 200 hPa flow, and rainfall greater than 1 mm/day (less than −1 mm/day) is shaded dark (light) gray. Panels (<b>a</b>–<b>c</b>) are from from [<a href="#B52-atmosphere-15-00655" class="html-bibr">52</a>].</p>
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<p>Locations of TCG (green dots) from (<b>a</b>,<b>b</b>) observations from 1979 to 2014 and (<b>c</b>,<b>d</b>) the 38-year LAM control run. Panels (<b>a</b>,<b>c</b>) are for the northern hemisphere tropical storm season (May through November) and panels (<b>b</b>,<b>d</b>) are for the southern hemisphere tropical storm season (December through March). In panels (<b>a</b>,<b>c</b>), blue contours are shown for 1, 5, and 10 storms per latitude/longitude bin (dotted, dashed, solid lines respectively). In panels (<b>b</b>,<b>d</b>), blue contours are shown for 1, 3, and 7 storms per lattitude/longitude bin (dotted, dashed, solid lines respectively). Bins span 10 degrees in longitude and 5 degrees in latitude. Panels (<b>a</b>,<b>b</b>) are adapted from [<a href="#B52-atmosphere-15-00655" class="html-bibr">52</a>].</p>
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<p>Locations of TCG (green dots) from (<b>a</b>,<b>b</b>) observations from 1979 to 2014 and (<b>c</b>,<b>d</b>) the 38-year LAM control run. Panels (<b>a</b>,<b>c</b>) are for the northern hemisphere tropical storm season (May through November) and panels (<b>b</b>,<b>d</b>) are for the southern hemisphere tropical storm season (December through March). In panels (<b>a</b>,<b>c</b>), blue contours are shown for 1, 5, and 10 storms per latitude/longitude bin (dotted, dashed, solid lines respectively). In panels (<b>b</b>,<b>d</b>), blue contours are shown for 1, 3, and 7 storms per lattitude/longitude bin (dotted, dashed, solid lines respectively). Bins span 10 degrees in longitude and 5 degrees in latitude. Panels (<b>a</b>,<b>b</b>) are adapted from [<a href="#B52-atmosphere-15-00655" class="html-bibr">52</a>].</p>
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<p>The Kelvin wave circulation component for the composite MJO based on (<b>a</b>–<b>c</b>) observations and (<b>d</b>–<b>f</b>) the LAM control run for each of the developing, mature, and dissipating stages of the convective envelope (contoured and shaded as in <a href="#atmosphere-15-00655-f002" class="html-fig">Figure 2</a>). Locations of TCG are shown with green dots in the frame of reference of the MJO for each stage. Panels (<b>a</b>–<b>c</b>) are adapted from [<a href="#B52-atmosphere-15-00655" class="html-bibr">52</a>].</p>
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<p>The Rossby wave circulation component for the composite MJO based on (<b>a</b>–<b>c</b>) observations and (<b>d</b>–<b>f</b>) the LAM control run for each of the developing, mature, and dissipating stages of the convective envelope (contoured and shaded as in <a href="#atmosphere-15-00655-f002" class="html-fig">Figure 2</a>). Locations of TCG are denoted with green dots in the frame of reference of the MJO for each stage. Panels (<b>a</b>–<b>c</b>) are adapted from [<a href="#B52-atmosphere-15-00655" class="html-bibr">52</a>].</p>
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<p>The number of TCG points divided by the expected number based on monthly climatology for (<b>a</b>) observations from 1979 to 2014 and (<b>b</b>) the LAM control run for each of the developing (dotted), mature (dashed), and dissipating (black) stages of the MJO. The blue line shows the average over all of the stages, with points significant at the 95 percent confidence level marked with blue boxes. TCG counts and climatologies are counted over 30-degree wide longitude bins (including all latitudes). Panel (<b>a</b>) is adapted from [<a href="#B52-atmosphere-15-00655" class="html-bibr">52</a>].</p>
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<p>Time-longitude series of rainfall for the composite MJO based on the LAM SSP585 run (contoured and shaded as in <a href="#atmosphere-15-00655-f001" class="html-fig">Figure 1</a>).</p>
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<p>Locations of TCG events (green dots) for the LAM SSP585 run. Panel (<b>a</b>) is for the northern hemisphere tropical storm season (May through November) and panel (<b>b</b>) is for the southern hemisphere tropical storm season (December through March). In panel (<b>a</b>), blue contours are shown for 1, 5, and 10 storms per latitude/longitude bin (dotted, dashed, and solid contours respectively). In panel (<b>b</b>), blue contours are shown for 1, 3, and 7 storms per lattitude/longitude bin (dotted, dashed, and solid contours respectively). Bins span 10 degrees in longitude and 5 degrees in latitude.</p>
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<p>(<b>a</b>–<b>c</b>) The horizontal structure of the composite MJO for the LAM SSP585 run for the developing, mature, and dissipating stages of the convective envelope, respectively (contoured and shaded as in <a href="#atmosphere-15-00655-f002" class="html-fig">Figure 2</a>).</p>
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<p>(<b>a</b>–<b>c</b>) The Kelvin wave circulation component for the composite MJO based on the LAM SSP585 run for each of the developing, mature, and dissipating stages of the convective envelope (contoured and shaded as in <a href="#atmosphere-15-00655-f002" class="html-fig">Figure 2</a>). Locations of TCG are shown with green dots in the frame of reference of the MJO for each stage.</p>
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<p>(<b>a</b>–<b>c</b>) The Rossby wave circulation component for the composite MJO based on the LAM SSP585 run for each of the developing, mature, and dissipating stages of the convective envelope (contoured and shaded as in <a href="#atmosphere-15-00655-f002" class="html-fig">Figure 2</a>). Locations of TCG are denoted with green dots in the frame of reference of the MJO for each stage.</p>
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<p>The number of TCG points divided by the expected number based on monthly climatology for the LAM SSP585 run for each of the developing (dotted), mature (dashed), and dissipating (black) stages of the MJO. The blue line shows the average over all of stages, with points significant at the 95 percent confidence level marked with blue boxes. TCG counts and climatologies are counted over 30-degree wide longitude bins (including all latitudes).</p>
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20 pages, 2533 KiB  
Review
The Easily Overlooked Effect of Global Warming: Diffusion of Heavy Metals
by Wenqi Xiao, Yunfeng Zhang, Xiaodie Chen, Ajia Sha, Zhuang Xiong, Yingyong Luo, Lianxin Peng, Liang Zou, Changsong Zhao and Qiang Li
Toxics 2024, 12(6), 400; https://doi.org/10.3390/toxics12060400 - 30 May 2024
Cited by 1 | Viewed by 792
Abstract
Since industrialization, global temperatures have continued to rise. Human activities have resulted in heavy metals being freed from their original, fixed locations. Because of global warming, glaciers are melting, carbon dioxide concentrations are increasing, weather patterns are shifting, and various environmental forces are [...] Read more.
Since industrialization, global temperatures have continued to rise. Human activities have resulted in heavy metals being freed from their original, fixed locations. Because of global warming, glaciers are melting, carbon dioxide concentrations are increasing, weather patterns are shifting, and various environmental forces are at play, resulting in the movement of heavy metals and alteration of their forms. In this general context, the impact of heavy metals on ecosystems and organisms has changed accordingly. For most ecosystems, the levels of heavy metals are on the rise, and this rise can have a negative impact on the ecosystem as a whole. Numerous studies have been conducted to analyze the combined impacts of climate change and heavy metals. However, the summary of the current studies is not perfect. Therefore, this review discusses how heavy metals affect ecosystems during the process of climate change from multiple perspectives, providing some references for addressing the impact of climate warming on environmental heavy metals. Full article
(This article belongs to the Section Metals and Radioactive Substances)
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<p>Migration of heavy metals in the environment.</p>
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<p>Translational pathways of heavy metal transfer in cells.</p>
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<p>Climate-driven impacts of heavy metals on crops. Note: ↑ indicates an increase, ↓ indicates a decrease.</p>
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18 pages, 5229 KiB  
Article
Economic Consequences Based on Reversible and Irreversible Degradation of PV Park in the Harsh Climate Conditions of Iraq
by Mohammed Adnan Hameed, David Daßler, Qais Matti Alias, Roland Scheer and Ralph Gottschalg
Energies 2024, 17(11), 2652; https://doi.org/10.3390/en17112652 - 30 May 2024
Viewed by 366
Abstract
Photovoltaic (PV) system reliability and durability investigations are essential for industrial maturity and economic success. Recently, PV systems received much interest in Iraq due to many reasons—for instance, power shortage, global warming and pollution. Despite this interest, the precise economic implications of PV [...] Read more.
Photovoltaic (PV) system reliability and durability investigations are essential for industrial maturity and economic success. Recently, PV systems received much interest in Iraq due to many reasons—for instance, power shortage, global warming and pollution. Despite this interest, the precise economic implications of PV system reliability in harsh climates like Iraq remain uncertain. This work assesses the economic implications of PV system component reliability and soiling in Iraq using field experience and historical data. This study identifies the most common failure modes of PV systems installed in Iraq and similar climatic regions, and also ranks their severity. Simulations explore scenarios of PV module degradation rates, inverter lifetimes, soiling rates, and cleaning intervals, revealing that soiling has the most detrimental effect, with cleaning frequency leading to Levelized Cost of Electricity (LCOE) losses of over 30%, depending on the location. Inverter lifetime contributes to LCOE losses between 4 and 6%, depending on the PV system’s location. This study also evaluates the impact of tilt angle as a mitigation strategy for reducing soiling loss and its economic implications, finding that installing PV modules at higher tilt angles could reduce the economic impact of soiling by approximately 4.4%. Additionally, the optimal cleaning strategy identified is fully automated dry cleaning with robots, outperforming other strategies economically. Overall, the findings highlight that the LCOE in Iraq is relatively high compared to the global weighted average for utility-scale PV systems, primarily due to high soiling and degradation rates. The LCOE varies within the country, influenced by different degradation rates. This study aims to assist PV stakeholders in Iraq and the Middle East and North Africa (MENA) region in accurately estimating solar bankability; moreover, increasing reliability by minimizing the technical and financial risks by considering key parameters specific to these regions. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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<p>Monthly boxplots showing rainfall/precipitation (<b>A</b>), PM2.5 (<b>B</b>) and PM10 (<b>C</b>). All data represent a 5-year timeseries of the years 2015 to 2020. (During the boxplot, outliers were removed).</p>
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<p>Distribution of degradation rates based on the degradation rate zones (<b>Z1</b>–<b>Z4</b>).</p>
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<p>Schematic showing the steps for modelling the impact of tilt angle on soiling accumulation/loss. The degradation models based on Kaaya et al. [<a href="#B44-energies-17-02652" class="html-bibr">44</a>], and the soiling models based on Coell et al. and Boyle et al. [<a href="#B38-energies-17-02652" class="html-bibr">38</a>].</p>
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<p>Example of inverter malfunction due to soiling accumulation leading to fan failure and hence overheating.</p>
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<p>(<b>A</b>) Boxplots of the degradation rates in the four degradation rate zones and (<b>B</b>) the corresponding lifetime in the four zones. The dotted point are outliers.</p>
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<p>Spider chart showing the dependence of the different LCOE input variables. EY is the energy yield and DR is the degradation rate.</p>
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<p>(<b>A</b>) Boxplots of evaluated lifetime OPEX considering different inverter lifetime. (<b>B</b>) Boxplots of the evaluated LCOE considering different inverter lifetime. (<b>C</b>) Percentage difference in OPEX with respect to (wrt) 4 years inverter lifetime (<b>D</b>) Percentage difference in LCOE with respect to (wrt) 4 years inverter lifetime. The dotted point are outliers.</p>
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<p>(<b>A</b>) Boxplots of evaluated LCOE considering different soiling rate. (<b>B</b>) Boxplots of evaluated LCOE considering different cleaning schedules. (<b>C</b>) Percentage difference in LCOE with respect to (wrt) 0.0 soiling rate. (<b>D</b>) Percentage difference in LCOE wrt 2 weeks cleaning period.</p>
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<p>Boxplot showing module temperature variation with tilt angle (<b>A</b>) and the global plane of array irradiance (Gpoa) (<b>B</b>). The corresponding effect on the degradation rate is shown in (<b>C</b>) and the effect on lifetime is shown in (<b>D</b>).</p>
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<p>Soiling ratio at different tilt angles (<b>A</b>), energy yield evaluated with and without considering soiling (<b>B</b>), percentage loss due to soiling at different tilt angles (<b>C</b>), and change in LCOE at different tilt angles for modules with and without soiling effect (<b>D</b>).</p>
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18 pages, 3136 KiB  
Article
Qualtra Geothermal Power Plant: Life Cycle, Exergo-Economic, and Exergo-Environmental Preliminary Assessment
by Claudio Zuffi, Pietro Ungar, Daniele Fiaschi, Giampaolo Manfrida and Fausto Batini
Sustainability 2024, 16(11), 4622; https://doi.org/10.3390/su16114622 - 29 May 2024
Viewed by 468
Abstract
Qualtra, an innovative 10 MW geothermal power plant proposal, employs a closed-loop design to mitigate emissions, ensuring no direct release into the atmosphere. A thorough assessment utilizing energy and exergy analysis, life cycle assessment (LCA), exergo-economic analysis, and exergo environmental analysis (EevA) was [...] Read more.
Qualtra, an innovative 10 MW geothermal power plant proposal, employs a closed-loop design to mitigate emissions, ensuring no direct release into the atmosphere. A thorough assessment utilizing energy and exergy analysis, life cycle assessment (LCA), exergo-economic analysis, and exergo environmental analysis (EevA) was conducted. The LCA results, utilizing the ReCiPe 2016 midpoint methodology, encompass all the spectrum of environmental indicators provided. The technology implemented makes it possible to avoid direct atmospheric emissions from the Qualtra plant, so the environmental impact is mainly due to indirect emissions over the life cycle. The result obtained for the global warming potential indicator is about 6.6 g CO2 eq/kWh, notably lower compared to other conventional systems. Contribution analysis reveals that the construction phase dominates, accounting for over 90% of the impact for almost all LCA midpoint categories, excluding stratospheric ozone depletion, which is dominated by the impact from the operation and maintenance phase, at about 87%. Endpoint indicators were assessed to estimate the single score value using normalization and weighting at the component level. The resulting single score is then used in an Exergo-Environmental Analysis (EEvA), highlighting the well system as the most impactful contributor, constituting approximately 45% of the total impact. Other substantial contributions to the environmental impact include the condenser (21%), the turbine (17%), and the HEGeo (14%). The exergo-economic analysis assesses cost distribution across major plant components, projecting an electricity cost of about 9.4 c€/kWh. Full article
(This article belongs to the Section Energy Sustainability)
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<p>Diagram of the Qualtra power plant configuration. MHE—main heat exchanger; RHE—regenerative heat exchanger; T—turbine; CON—air-cooled condenser; P—pump; RGLV—reverse gas lift valve; PreC—pre-cooler; C1—compressor 1; IC—intercooler; C2—compressor 2; PoC—post-cooler.</p>
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<p>Qualtra contribution analysis macroprocesses (phases).</p>
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<p>Qualtra contribution analysis in subprocess (C = construction phase).</p>
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<p>Qualtra contribution analysis—power equipment.</p>
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<p>Qualtra contribution analysis wells (WH = wellhead; WD = well drilling).</p>
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<p>Qualtra single score (ReCiPe 2016 endpoint) subprocess (C = construction phase).</p>
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<p>Single score results—power plant components.</p>
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<p>Exergy destruction and losses for each component.</p>
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<p>Sankey exergy conversion diagram. Color code: yellow = standard exergy fluxes, red = exergy destruction, blue = exergy losses. The thickness of the connecting lines is proportional to the exergy flux (in kW).</p>
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<p>Schematic of k-th component.</p>
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<p>Economic stream cost contribution for each component (self and share from all others).</p>
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<p>Environmental stream cost contribution to each component (self and from all others).</p>
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19 pages, 2776 KiB  
Article
Empirical Modeling of Synthetic Fuel Combustion in a Small Turbofan
by Andrzej Kulczycki, Radoslaw Przysowa, Tomasz Białecki, Bartosz Gawron, Remigiusz Jasiński, Jerzy Merkisz and Ireneusz Pielecha
Energies 2024, 17(11), 2622; https://doi.org/10.3390/en17112622 - 29 May 2024
Cited by 1 | Viewed by 521
Abstract
Drop-in fuels for aviation gas-turbine engines have been introduced recently to mitigate global warming. Despite their similarity to the fossil fuel Jet A-1, their combustion in traditional combustors should be thoroughly analyzed to maintain engine health and low emissions. The paper introduces criteria [...] Read more.
Drop-in fuels for aviation gas-turbine engines have been introduced recently to mitigate global warming. Despite their similarity to the fossil fuel Jet A-1, their combustion in traditional combustors should be thoroughly analyzed to maintain engine health and low emissions. The paper introduces criteria for assessing the impact of the chemical composition of fuels on combustion in the DEGN 380 turbofan. Based on previous emission-test results, the power functions of carbon monoxide and its emission index were adopted as the model of combustion. Based on the general notation of chemical reactions leading to the production of CO in combustion, the regression coefficients were given a physical meaning by linking them with the parameters of the kinetic equations, i.e., the reaction rate constant of CO and CO2 formation expressed as exponential functions of combustor outlet temperature and the concentration of O2 in the exhaust gas, as well as stoichiometric combustion reactions. The obtained empirical functions show that, in the entire range of engine operating parameters, synthetic components affect the values of the rate constants of CO and CO2 formation. It can be explained by the change in activation energy determined for all chain-of-combustion reactions. The activation energy for the CO formation chain changes in the range between 8.5 kJ/mol for A0 and 24.7 kJ/mol for A30, while for the CO2 formation chain between 29.8 kJ/mol for A0 and 30.8 kJ/mol for A30. The reactivity coefficient lnαiCOACODCO changes between 2.29 for A0 and 6.44 for A30, while lnαiCO2ACO2DCO2 changes between 7.90 for A0 and 8.08 for A30. Full article
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<p>Variables used to estimate E<sub>aCO2ch</sub> and αi<sub>CO2ch</sub>.</p>
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<p>Variables used to estimate E<sub>aCO2meas</sub>, E<sub>aCOch,</sub> and αi<sub>COch</sub>.</p>
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<p>Price Induction DGEN 380 turbofan [<a href="#B32-energies-17-02622" class="html-bibr">32</a>].</p>
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<p>Thrust F as a function of fuel flow m<sub>f</sub> for the tested blends.</p>
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<p>Fuel flow vs. inverted temperature.</p>
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<p>CO<sub>2</sub> concentration vs. inverted temperature.</p>
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<p>The relationship between E<sub>aCO2ch</sub>/E<sub>aCO2meas</sub> and SAF concentration in the tested fuels.</p>
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<p>Relationship between [CO]<sub>meas</sub> and m<sub>f</sub> for various concentrations of SAF.</p>
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<p>CO concentration vs. inverted combustion temperature.</p>
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<p>The relationship between E<sub>aCO</sub>/RT<sub>4</sub> and ln am<sub>f</sub>.</p>
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<p>The relationship between E<sub>a</sub>/R and SAF content in the tested fuel.</p>
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<p>The impact of SAF content in tested fuels on the values of coefficient of reactivity α<sub>i</sub> related to CO<sub>2</sub> and CO formation.</p>
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