Search Results (388)

Plant architecture is an important agronomic trait that impacts crop yield. The tiller angle is a critical aspect of the plant’s structural organization, which is influenced by both internal and external factors. The genetic mechanisms underlying the tiller angle have been extensively investigated in other plants. However, research on wheat is relatively limited. Additionally, mechanics has emerged as a connection between biochemical signaling and the development of three-dimensional biological forms. It not only reveals how physical interactions at the cellular level influence overall morphogenesis but also elucidates the interplay between these mechanical processes and molecular signaling pathways that collectively determine plant morphology. This review examines the recent advancements in the study of tillering angle in wheat and other plants. It discusses progress in research ranging from observable characteristics to the regulation of genes, as well as the physiological and biochemical aspects, and the adaptability to environmental factors. In addition, this review also discusses the effects of mechanical on plant growth and development, and provides ideas for the study of mechanical regulation mechanism of tillering angle in wheat. Consequently, based on the research of other plants and combined with the genetic and mechanical principles, this approach offers novel insights and methodologies for studying tillering in wheat. This interdisciplinary research framework not only enhances our understanding of the mechanisms underlying wheat growth and development but may also uncover the critical factors that regulate tillering angle, thereby providing a scientific foundation for improving wheat yield and adaptability. Full article

This study presents three-dimensional finite element analyses of two marine structures subjected to lateral loading to approximate environmental forces (e.g., wind, waves, currents, earthquakes). The first structure is a marine jetty supported by twenty-four piles, representative of an existing structure in Cyprus, while the second is a simplified four-pile marine structure. Soil–pile interaction is modelled using nonlinear p-y, τ-z, and q-z springs that are distributed along the piles, while steel plasticity is also considered. This study examines the relationship between failure modes, deformation modes, and plastic hinge locations with soil behaviour and soil reaction forces. It also aims at investigating the behaviour of the above structures in lateral loading and quantifying the consequences of unrealistic assumptions such as soil and steel linearity or tension-resistant q-z springs. The results indicate that such assumptions can lead to the wrong prediction of failure modes, plastic hinges, and critical elements while emphasising the crucial role of soil nonlinearity and axial pile–soil behaviour on the structural response. It is demonstrated that the dominant nonlinear sources relevant to this study, whether soil nonlinearity, plastic hinge formation, or a combination of the two, are primarily influenced by the axial capacity of soil–pile foundation systems, particularly their tensile component. Full article

Porous nitrogen-doped graphene (PNG) materials with high conductivity, high surface area, and chemical stability have displayed superior performance in electrochemical capacitors. However, previously reported methods for fabricating PNG render the processes expensive, hard to control, limited in production, and unsafe as well, thus largely restricting their practical applications. Herein, we present a facile two-step calcination method to prepare PNG using petroleum asphalt as the carbon source to provide the original three-dimensional porous structure directly and using environmentally friendly and high nitrogen content urea as the nitrogen source without adding any etching agent. The porous structure in PNG can largely increase its specific surface area, and the introduction of nitrogen atoms can effectively increase the degree of defects and improve the wettability of PNG. As a result, PNG displays a high specific capacitance of 157 F g⁻¹ at a current density of 1 A g⁻¹ and cycling stability while maintaining 98.68% initial capacitance after 10,000 cycles. Full article

Industrialization activities have increased the discharge of wastewater that is polluted with hexavalent chromium (Cr(VI)), posing risks to ecosystems and humans. The photocatalytic reduction of Cr(VI) is viewed as a promising method for the removal of Cr(VI) species. However, developing photocatalysts with the desired catalytic activity, recyclability, and reusability remains a challenge. Herein, a composite aerogel was designed and fabricated with a Ti-based metal–organic framework (MIL-125-NH₂) and carboxylated nanocellulose. MIL-125-NH₂ presents a strong visible-light response, and the interactions between the amino groups of MIL-125-NH₂ and the carboxyl groups of cellulose produce a strong interface affinity in the composites. The as-prepared aerogels exhibited a micro/macroporous structure. At an optimal MIL-125-NH₂ loading of 55 wt%, the MC-5 sample showed a specific surface area of 582 m²·g⁻¹. MC-5 achieved a photocatalytic Cr(VI) removal efficiency of 99.8%. Meanwhile, the aerogel-type photocatalysts demonstrated good stability and recycling ability, as MC-5 maintained a removal rate of 82% after 10 cycles. This work sheds light on the preparation of novel photocatalysts with three-dimensional structures for environmental remediation. Full article

Light non-aqueous phase liquids (LNAPLs), which include various petroleum products, are a significant source of groundwater contamination globally. Once introduced into the subsurface, these contaminants tend to accumulate in the vadose zone, causing chronic soil and water pollution. The vadose zone often contains lens-shaped bodies with diverse properties that can significantly influence the migration and distribution of LNAPLs. Understanding the interaction between LNAPLs and these lens-shaped bodies is crucial for developing effective environmental management and remediation strategies. Prior research has primarily focused on LNAPL behavior in homogeneous media, with less emphasis on the impact of heterogeneous conditions introduced by lens-shaped bodies. To investigate the impact of lens-shaped structures on the migration of LNAPLs and to assess the specific effects of different types of lens-shaped structures on the distribution characteristics of LNAPL migration, this study simulates the LNAPL leakage process using an indoor two-dimensional sandbox. Three distinct test groups were conducted: one with no lens-shaped aquifer, one with a low-permeability lens, and one with a high-permeability lens. This study employs a combination of oil front curve mapping and high-density resistivity imaging techniques to systematically evaluate how the presence of lens-shaped structures affects the migration behavior, distribution patterns, and corresponding resistivity anomalies of LNAPLs. The results indicate that the migration rate and distribution characteristics of LNAPLs are influenced by the presence of a lens in the gas band of the envelope. The maximum vertical migration distances of the LNAPL are as follows: high-permeability lens (45 cm), no lens-shaped aquifer (40 cm), and low-permeability lens (35 cm). Horizontally, the maximum migration distances of the LNAPL to the upper part of the lens body decreases in the order of low-permeability lens, high-permeability lens, and no lens-shaped aquifer. The low-permeability lens impedes the vertical migration of the LNAPL, significantly affecting its migration path. It creates a flow around effect, hindering the downward migration of the LNAPL. In contrast, the high-permeability lens has a weaker retention effect and creates preferential flow paths, promoting the downward migration of the LNAPL. Under conditions with no lens-shaped aquifer and a high-permeability lens, the region of positive resistivity change rate is symmetrical around the axis where the injection point is located. Future research should explore the impact of various LNAPL types, lens geometries, and water table fluctuations on migration patterns. Incorporating numerical simulations could provide deeper insights into the mechanisms controlling LNAPL migration in heterogeneous subsurface environments. Full article

This study investigates and evaluates methods for the three-dimensional thermohaline reconstruction of the Arctic Ocean using multi-source observational data. A multivariate statistical regression model based on sea ice seasonal variation is developed, driving by satellite data, and in situ data is used to validate the model output. The study indicates that the multivariate statistical regression model effectively captures the characteristics of the three-dimensional thermohaline structure of the Arctic Ocean. Areas with large reconstruction errors are primarily observed in the salinity values of ice-free regions and the temperature values of ice-covered regions. The statistical regression experiments reveal that salinity errors in ice-free regions are caused by inaccuracies in the satellite salinity data, while temperature errors in ice-covered areas mainly result from the inadequate representation of the under-ice temperature structure of the reanalysis data. The continuous and stable thermohaline data produced using near real-time satellite data as input provide an important foundation for studying Arctic marine environmental characteristics and assessing climate change. Full article

Heterogeneous photocatalysis is an advanced, efficient oxidation process that uses solar energy to be sustainable and low-cost compared to conventional wastewater treatments. This study synthesized BiOI/Fe₃O₄ using the solvothermal technique, evaluating stoichiometric ratios of Bi/Fe (2:1, 3:1, 5:1, and 7:1) under simulated solar irradiation to optimize the degradation of caffeic acid, a pollutant found in wastewater from the wine and pisco industry. The nanomaterial with a 5:1 ratio (BF-5) was the most effective, achieving a degradation of 77.2% in 180 min. Characterization by X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM), Brunauer–Emmett–Teller (BET), Barrett–Joyner–Halenda (BJH), Fourier Transform Infrared Spectroscopy (FTIR), Diffuse Reflectance Spectroscopy (DRS), and Vibrating Sample Magnetometry (VSM) showed that BF-5 has a porous three-dimensional structure with BiOI nanosheets coating the Fe₃O₄ surface, while retaining the pristine BiOI properties. The magnetite provided magnetic properties that facilitated the recovery of the photocatalyst, reaching 89.4% recovery. These findings highlight the potential of BF-5 as an efficient and recoverable photocatalyst for industrial applications. The technical, economic, and environmental feasibility were also evaluated at the technological readiness level (TRL) to project solar photocatalysis in real applications. Full article

Pharmaceutical and veterinary products are a class of contaminants of emerging concern, and their presence in the environment is due to continuous and incorrect disposal. Environmental scientists have been accumulating data on their adverse effects on animal populations since toxicological effects on wildlife were first published. Therefore, recycling strategies are needed. Valuable active ingredients can be extracted from expired pharmaceuticals and recycled according to various strategies. In an effort to reveal the potential of the chemical upcycling of expired pharmaceuticals, the active ingredients gabapentin and pregabalin were extracted and used as starting materials to prepare a small collection of promising substrates endowed with functionalities and structural three-dimensionality. Gabapentin 1 was transformed into aminoalcohol 3, spiroamine 4, and the bioactive azaspirolactam 5. The lactam analog 6 was synthesized from pregabalin 2. Due to the biological profile of 5 and the structural similarity of the N-alkylated derivatives 5l and 6b with the drug piracetam, a collection of potentially bioactive structural analogs 5a-l and 6a-b were also prepared. Simple extraction, synthesis, and purification procedures were used as a means of chemical and economic revaluation, resulting in moderate to good yields at a low cost. Full article

As an alternative to cotton, viscose and lyocell fibers are suitable for the production of knitted next-to-skin underwear. Despite the advantages of a more environmentally friendly production process and valuable properties, the consumption of lyocell fibers is significantly lower compared to viscose fibers. The applicability of viscose and lyocell fibers in the production of ribbed knits for underwear is insufficiently researched, as is the influence of unconventionally spun yarns on their wearing properties. This study, therefore, investigates the possibilities of using lyocell fibers in the production of novel knitwear with improved properties compared to viscose and conventional cotton knitwear and determines their wearing quality. In this context, two sets of circular 1 × 1 rib jersey fabrics were produced from three types of differently spun viscose and lyocell yarns. The quality of the dry relaxed and wet processed knitted fabrics was evaluated by determining their structure, absorbency, air permeability, and dimensional stability, as well as their tensile, abrasion, and pilling properties, all in comparison to cotton knitted fabric produced under the same conditions. The results showed that lyocell rib knits have better structural uniformity, tensile properties, dimensional stability, air permeability, lower abrasion resistance, and comparable moisture absorbency and pilling propensity compared to viscose knits. Full article

Converting solar energy into fuels/chemicals through photochemical approaches holds significant promise for addressing global energy demands. Currently, semiconductor photocatalysis combined with redox techniques has been intensively researched in pollutant degradation and secondary energy generation owing to its dual advantages of oxidizability and reducibility; however, challenges remain, particularly with improving conversion efficiency. Since graphene’s initial introduction in 2004, three-dimensional (3D) graphene-based photocatalysts have garnered considerable attention due to their exceptional properties, such as their large specific surface area, abundant pore structure, diverse surface chemistry, adjustable band gap, and high electrical conductivity. Herein, this review provides an in-depth analysis of the commonly used photocatalysts based on 3D graphene, outlining their construction strategies and recent applications in photocatalytic degradation of organic pollutants, H₂ evolution, and CO₂ reduction. Additionally, the paper explores the multifaceted roles that 3D graphene plays in enhancing photocatalytic performance. By offering a comprehensive overview, we hope to highlight the potential of 3D graphene as an environmentally beneficial material and to inspire the development of more efficient, versatile graphene-based aerogel photocatalysts for future applications. Full article

Numerical simulation technology is a crucial tool for reducing costs and increasing efficiency in the wind power industry. However, with the development of large-scale wind turbines, the computational cost of numerical simulation has gradually increased. This paper uses the geometric similarity, structural similarity criterion, Reynolds similarity and boundary layer theory to establish a scaled model of the geometric three-dimensional shape, composite material, and finite element mesh of large wind turbine blades. The study analyzes the aerodynamic, gravitational, and centrifugal load variations within the scaled model. The proportional relationship between the scaled model’s operating parameters, the numerical simulation’s environmental parameters, and the mechanical response parameters is established. These parameters are coordinated to ensure the similarity of the blade structure and the fluid dynamics. For a geometric scale factor of 0.316, the relative difference in maximum deflection is 4.52%, with a reduction in calculation time by 48.1%. On the premise of ensuring the calculation accuracy of the aerodynamic and structural response of the blade, the calculation efficiency is effectively improved. Full article

Three-dimensional printing of cementitious materials for construction has been extensively investigated in recent years, with several demonstration projects successfully carried out. These efforts aim to leverage the printing process to achieve more efficient production of components compared to conventional concrete technologies. This includes both the process itself (eliminating the formwork stage) and the flexibility in producing complexly shaped elements. To maximize the potential of 3D printing in the construction industry, additional steps must be taken, grounded in a holistic view of the entire process. This involves integration of the production chain, including design, materials, and manufacturing of components, to create elements with optimal performance, encompassing structural, environmental, and architectural aspects. Such multi-functionality requires the viewing of 3D printing not just as a production technology but as a platform enabling the integration of all these components. To advance this approach, quantitative tools are developed to optimize the following three key components: material composition; manufacturing parameters to ensure buildability; and design tools to optimize multiple performance criteria, particularly structural and architectural shape. A demonstration component, namely a post-tensioned beam, featuring two multi-functional characteristics—structural and architectural—is designed, produced, and evaluated. The scientific concepts and research tools used to develop these quantitative design tools are multidisciplinary, including rheological characterization, control of the internal structure and composition of granular materials, simulation of the mechanical behavior of green material during printing, and the hardened properties of the components, all utilizing structural optimization to enhance performance. Full article

Additive manufacturing, better known as 3D printing, is an innovative manufacturing technique which allows the production of parts, with complex and challenging shapes, layer by layer mainly through melting powder particles (metallic, polymeric, or composite) or extruding material in the form of wire, depending on the specific technique. Three-dimensional printing is already widely employed in several sectors, especially aerospace and automotive, although its large-scale use still requires the gain of know-how and to overcome certain limitations related to the production process and high costs. In particular, this innovative technology aims to overtake some of the shortcomings of conventional production methods and to obtain many additional advantages, such as reduction in material consumption and waste production, high level of customisation and automation, environmental sustainability, great design freedom, and reduction in stockpiles. This article aims to give a detailed review of the state of scientific research and progress in the industrial field of metal additive manufacturing, with a detailed view to its potential use in civil engineering and construction. After a comprehensive overview of the current most adopted additive manufacturing techniques, the fundamental printing process parameters to achieve successful results in terms of quality, precision, and strength are debated. Then, the already existing applications of metal 3D printing in the field of construction and civil engineering are widely discussed. Moreover, the strategic potentiality of the use of additive manufacturing both combined with topological optimisation and for the eventual repair of existing structures is presented. It can be stated that the discussed findings led us to conclude that the use of metal additive manufacturing in the building sector is very promising because of the several benefits that this technology is able to offer. Full article

Water scarcity is a serious threat to the survival and development of mankind. Interfacial solar steam generation (ISSG) can alleviate the global freshwater shortage by converting sustainable solar power into thermal energy for desalination. ISSG possesses many advantages such as high photothermal efficiency, robust durability, and environmental friendliness. However, conventional evaporators suffered from huge heat losses in the evaporation process due to the lack of efficient thermal management. Herein, hydrophilic Tencel yarn is applied to fabricate a three-dimensional double-layer fabric evaporator (DLE) with efficient multi-stage thermal management. DLE enables multiple solar absorptions, promotes cold evaporation, and optimizes thermal management. The airflow was utilized after structure engineering for enhanced energy evaporation efficiency. The evaporation rate can reach 2.86 kg·m⁻²·h⁻¹ under 1 sun (1 kW·m⁻²), and 6.26 kg·m⁻²·h⁻¹ at a wind speed of 3 m·s⁻¹. After a long duration of outdoor operation, the average daily evaporation rate remains stable at over 8.9 kg·m⁻², and the removal rate of metal ions in seawater reaches 99%. Overall, DLE with efficient and durable three-dimensional multi-stage thermal management exhibits excellent practicality for solar desalination. Full article

Ulvan is a water-soluble sulfated polysaccharide extracted from the green algae cell wall. Compared with polysaccharides, oligosaccharides have drawn increasing attention in various industries due to their enhanced biocompatibility and solubility. Ulvan lyase degrades polysaccharides into low molecular weight oligosaccharides through the β-elimination mechanism. The elucidation of the structure, catalytic mechanism, and molecular modification of ulvan lyase will be helpful to obtain high value-added products from marine biomass resources, as well as reduce environmental pollution caused by the eutrophication of green algae. This review summarizes the structure and bioactivity of ulvan, the microbial origin of ulvan lyase, as well as its sequence, three-dimensional structure, and enzymatic mechanism. In addition, the molecular modification of ulvan lyase, prospects and challenges in the application of enzymatic methods to prepare oligosaccharides are also discussed. It provides information for the preparation of bioactive Ulva oligosaccharides through enzymatic hydrolysis, the technological bottlenecks, and possible solutions to address these issues within the enzymatic process. Full article