Search Results (3,196)

The Václav vein (Březové Hory deposit, Příbram ore area, Czech Republic) is a base–metal vein containing minor Cu-Zn-Pb-Ag-Sb sulfidic mineralization in a usually hematitized gangue. A detailed mineralogical study using an electron microprobe revealed a complicated multistage evolution of the vein. Early siderite and Fe-rich dolomite were strongly replaced by assemblages of hematite+rhodochrosite and hematite+kutnohorite/Mn-rich dolomite, respectively. In addition, siderite also experienced strong silicification. These changes were associated with the dissolution of associated sulfides (sphalerite, galena). The following portion of the vein contains low-Mn dolomite and calcite gangue with Zn-rich chlorite, wittichenite, tetrahedrite-group minerals, chalcopyrite, bornite, and djurleite, again showing common replacement textures in case of sulfides. The latest stage was characterized by the input of Ag and Hg, giving rise to Ag-Cu sulfides, native silver (partly Hg-rich), balkanite, and (meta)cinnabar. We explain the formation of hematite-bearing oxidized assemblages at the expense of pre-existing “normal” Příbram mineralization due to repeated episodic infiltration of oxygenated surface waters during the vein evolution. Episodic mixing of ore fluids with surface waters was suggested from previous stable isotope and fluid inclusion studies in the Příbram ore area. Our mineralogical study thus strengthens this genetic scenario, illustrates the dynamics of fluid movement during the evolution of a distinct ore vein structure, and shows that the low content of ore minerals cannot be necessarily a primary feature of a vein. Full article

The safety of sea bass is critical for the global food trade. This study evaluated the effectiveness of atmospheric cold plasma in reducing food safety risks posed by Salmonella Enteritidis and Listeria monocytogenes, which can contaminate sea bass post harvest. Cold plasma was applied to inoculated sea bass for 2 to 18 min, achieving a maximum reduction of 1.43 log CFU/g for S. Enteritidis and 0.80 log CFU/g for L. monocytogenes at 18 min. Longer treatments resulted in greater reductions; however, odor and taste quality declined to a below average quality in samples treated for 12 min or longer. Plasma treatment did not significantly alter the color, texture, or water activity (aw) of the fish. Higher levels of thiobarbituric acid reactive substances (TBARSs) were observed with increased exposure times. Cold plasma was also tested in vitro on S. Enteritidis and L. monocytogenes on agar surfaces. A 4 min treatment eliminated the initial loads of S. Enteritidis (2.71 log CFU) and L. monocytogenes (2.98 log CFU). The findings highlight the potential of cold plasma in enhancing the safety of naturally contaminated fish. Cold plasma represents a promising technology for improving food safety in the global fish trade and continues to be a significant area of research in food science. Full article

The cavitation phenomenon presents a significant challenge in pump operation since the losses incurred by cavitation adversely impact pump performance. The many constraints of conventional anti-cavitation techniques have compelled researchers to explore biological processes for innovative alternatives. Consequently, the use of bionanotechnology for anti-cavitation pumping has emerged as a prominent study domain. Despite the extensive publication of publications on biomimetic technology, research concerning the use of anti-cavitation in pumps remains scarce. This review comprehensively summarizes, for the first time, the advancements and applications of bionic structures, bionic surface texture design, and bionic materials in pump anti-cavitation, addressing critical aspects such as blade leading-edge bionic structures, bionic worm shells, microscopic bionic textures, and innovative bionic coatings. Bionic technology may significantly reduce cavitation erosion and improve pump performance by emulating natural biological structures. This research elucidates the creative contributions of biomimetic designs and their anti-cavitation effects, hence boosting the anti-cavitation performance of pumps. This work integrates practical requirements and anticipates future applications of bionic technology in pump anti-cavitation, offering a significant research direction and reference for scholars in this domain. Full article

Measurements of areal (3D) surface texture using optical methods are very popular because of the short measurement time compared to the stylus tip technique. However, they are very sensitive to measurement errors. In some cases, optical measurements are not recommended. The stylus measurement method is well known and can be the reference technique for surface texture measurement. The main disadvantage is the long measuring time. This time can be shortened using higher speeds of measurement. The effect of the speed of the measurement of stylus profilometer on changes in surface texture parameters was studied. Fifty surface topographies were measured using the stylus profilometer at speeds 0.5, 1, 2, 3, 4, and 5 mm/s in the same places. Surfaces after lapping, polishing, grinding, milling, laser texturing, and two-process random surfaces were measured and analyzed. Changes in parameters caused by the increase in the traverse speed depend on the characteristics and parameters of the surfaces. The random surfaces changed more than the deterministic ones. The increase in the traverse speed from 0.5 to 1 mm/s caused small changes in the parameters. Full article

The effects of salt–enzyme–alkali progressive tenderization treatments on porcine cortical conformation and collagen properties were investigated, and their effectiveness and mechanisms were analyzed. The tenderization treatment comprised three treatment stages: CaCl₂ (25 °C/0–30 min), papain (35 °C/30–78 min), and Na₂CO₃ (25 °C/78–120 min). The textural, microscopic, and collagenous properties (content, solubility, and structure) of pork skin were determined at the 0th, 30th, 60th, 90th, and 120th min of the treatment process. The results showed that the shear force, hardness, and chewability of the skin decreased significantly (p < 0.05), and the elasticity exhibited a gradual increase with the progression of tenderization. The content and solubility of collagen showed no significant change at the CaCl₂ treatment stage. However, the soluble collagen content increased, the insoluble collagen content decreased, and the collagen solubility increased by 18.04% during the subsequent treatment with papain and Na₂CO₃. Meanwhile, the scanning electron microscopy results revealed that the regular, wavy structure of the pig skin collagen fibers gradually disappeared during the CaCl₂ treatment stage, the overall structure revealed expansion, and the surface microscopic pores gradually increased during the papain and Na₂CO₃ treatment stages. The findings of the Fourier transform infrared spectroscopy analysis indicated that the hydrogen bonding interactions between the collagen molecules and the C=O, N-H and C-N bonds in the subunit structure of collagen were substantially altered during treatment and that the breakage of amino acid chains and reduction in structural ordering became more pronounced with prolonged treatment. In the tertiary structure, the maximum emission wavelength was blue-shifted and then red-shifted, and the fluorescence intensity was gradually weakened. The surface hydrophobicity was slowly increased. The salt–enzyme–alkali tenderization treatment considerably improved the physical properties and texture of edible pork skins by dissolving collagen fibers and destroying the structure of collagen and its interaction force. Full article

Wood surface treatment aims to improve or reduce the surface activity of wood by physical treatment, chemical treatment, biological activation treatment or other methods to achieve the purpose of surface modification. After wood surface modification, the paint film adhesion performance, gluing performance, surface wettability, surface free energy and surface visual properties would be affected. This article aims to explore the effects of different modification methods on the adhesion of wood coating films. Modification of the wood surface significantly improves the adhesion properties of the paint film, thereby extending the service life of the coating. Research showed that physical external force modification improved the hydrophilicity and wettability of wood by changing its surface structure and texture, thus enhancing the adhesion of the coating. Additionally, high-temperature heat treatment modification reduced the risk of coating cracking and peeling by eliminating stress and moisture within the wood. Chemical impregnation modification utilized the different properties of organic and inorganic substances to improve the stability and durability of wood. Organic impregnation effectively filled the wood cell wall and increased its density, while inorganic impregnation enhanced the adhesion of the coating by forming stable chemical bonds. Composite modification methods combined the advantages of the above technologies and significantly improved the comprehensive properties of wood through multiple modification treatments, showing superior adhesion and durability. Comprehensive analysis indicated that selecting the appropriate modification method was key for different wood types and application environments. Full article

High-purity, superhard, binderless polycrystalline cubic boron nitride (BL-PCBN) was obtained by direct hBN to cBN transformation in a toroid-type high-pressure apparatus at a pressure of 8.0 GPa and temperature of 2250 °C (HPHT-DCS; high-pressure, high-temperature direct conversion sintering). X-ray diffraction analysis revealed a prominent [111] axial texture in the sintered material when the axis was oriented perpendicular to the end surface of the sample. Vickers hardness tests conducted at a load of 49 N showed that BL-PCBN possessed an exceptional hardness value of 63.4 GPa. Finally, cutting tools made of BL-PCBN and SN-PCBN (Si₃N₄-doped cBN-based composite) reference materials were tested during the turning of a cemented tungsten carbide workpiece. The results of the cutting tests demonstrated that the wear resistance of the BL-PCBN material obtained with the HPHT-DCS process is 1.5–1.9 times higher compared to the conventional SN-PCBN material, suggesting its significant potential for industrial application. Full article

Ongoing investments in irrigation technologies highlight the need to accurately estimate the longevity and magnitude of water savings at the watershed level to avoid the paradox of irrigation efficiency. This paradox arises when irrigation pumping exceeds crop water demand, leading to excess water that is not recovered by the watershed. Comprehensive water accounting from farm to watershed scales is challenging due to spatial variability and inadequate socio-hydrological data. We hypothesize that water savings are short term, as prior studies show rapid recharge responses to surface changes. Precise estimation of these time scales and water savings can aid water managers making decisions. In this study, we examined water savings at three 65-hectare sites in Nebraska with diverse soil textures, management practices, and groundwater depths. Surface geophysics effectively identified in-field variability in soil water content and water flux. A one-dimensional model showed an average 80% agreement with chloride mass balance estimates of deep drainage. Our findings indicate that groundwater response times are short and water savings are modest (1–3 years; 50–900 mm over 10 years) following a 120 mm/year reduction in pumping. However, sandy soils with shallow groundwater show minimal potential for water savings, suggesting limited effectiveness of irrigation efficiency programs in such regions. Full article

TiO₂ used for photocatalytic water purification is most active in the form of nanoparticles (NP), but their use is fraught with difficulties in separation from solution or/and a tendency to agglomerate. The novel materials designed in this work circumvent these problems by immobilizing TiO₂ NPs on the surface of exfoliated clay minerals. A series of TiO₂/clay mineral composites were obtained using five different clay components: the Na-, CTA-, or H-form of montmorillonite (Mt) and Na- or CTA-form of laponite (Lap). The TiO₂ component was prepared using the inverse microemulsion method. The composites were characterized with X-ray diffraction, scanning/transmission electron microscopy/energy dispersive X-ray spectroscopy, FTIR spectroscopy, thermal analysis, and N₂ adsorption–desorption isotherms. It was shown that upon composite synthesis, the Mt interlayer became filled by a mixture of CTA⁺ and hydronium ions, regardless of the nature of the parent clay, while the structure of Lap underwent partial destruction. The composites displayed high specific surface area and uniform mesoporosity determined by the size of the TiO₂ nanoparticles. The best textural parameters were shown by composites containing clay components whose structure was partially destroyed; for instance, Ti/CTA-Lap had a specific surface area of 420 m²g⁻¹ and a pore volume of 0.653 cm³g⁻¹. The materials were tested in the photodegradation of methyl orange and humic acid upon UV irradiation. The photocatalytic activity could be correlated with the development of textural properties. In both reactions, the performance of the most photoactive composites surpassed that of the reference commercial P25 titania. Full article

The high surface area and transfer-less growth of graphene on dielectric materials is still a challenge in the production of novel sensing devices. We demonstrate a novel approach to graphene synthesis on a C-plane sapphire substrate, involving the microwave plasma-enhanced chemical vapor deposition (MW-PECVD) technique. The decomposition of methane, which is used as a precursor gas, is achieved without the need for remote plasma. Raman spectroscopy, atomic force microscopy and resistance characteristic measurements were performed to investigate the potential of graphene for use in sensing applications. We show that the thickness and quality of graphene film greatly depend on the CH₄/H₂ flow ratio, as well as on chamber pressure during the synthesis. By varying these parameters, the intensity ratio of Raman D and G bands of graphene varied between ~1 and ~4, while the 2D to G band intensity ratio was found to be 0.05–0.5. Boundary defects are the most prominent defect type in PECVD graphene, giving it a grainy texture. Despite this, the samples exhibited sheet resistance values as low as 1.87 kΩ/□. This reveals great potential for PECVD methods and could contribute toward efficient and straightforward graphene growth on various substrates. Full article

Titanium and titanium alloys are the prevailing dental implant materials owing to their favorable mechanical properties and biocompatibility, but how roughness dictates the biological response is still a matter of debate. In this study, laser texturing was used to generate eight paradigmatic roughened surfaces, with the aim of studying the early biological response elicited on MC3T3-E1 pre-osteoblasts. Prior to cell tests, the samples underwent SEM analysis, optical profilometry, protein adsorption assay, and optical contact angle measurement with water and diiodomethane to determine surface free energy. While all the specimens proved to be biocompatible, supporting similar cell viability at 1, 2, and 3 days, surface roughness could impact significantly on cell adhesion. Factorial analysis and linear regression showed, in a robust and unprecedented way, that an isotropic distribution of deep and closely spaced valleys provides the best condition for cell adhesion, to which both protein adsorption and surface free energy were highly correlated. Overall, here the authors provide, for the first time, a thorough investigation of the relationship between roughness parameters and osteoblast adhesion that may be applied to design and produce new tailored interfaces for implant materials. Full article

In this study, a wear-resistant ultra-thin wear layer was fabricated with polyurethane as an adhesive to investigate its durability for pavement applications. Its road performance was investigated based on indoor tests. First, the abrasion test was performed using a tire–pavement dynamic friction analyzer (TDFA), and the surface elevation information of the wear layer was obtained by laser profile scanning. The relationship between the anti-skid properties of the wear layer and the macro-texture was analyzed. Second, a Fourier infrared spectrometer and scanning electron microscope were employed to analyze the evolution of polyurethane aging properties in the pull-out test and accelerated ultraviolet (UV) aging test. The results showed that the mean profile depth (MPD), arithmetic mean wavelength of contour (λa), surface wear index (SBI), stage mass loss rate (σ), and total stage mass loss rate (ω) of the abrasive layer aggregate had significant multivariate quadratic polynomial relationships with the skidding performance of the abrasive layer. The tensile strength of the polyurethane ultra-thin abrasive layer decreased by only 2.59% after 16 days of UV aging, indicating a minimal effect of UV action on the aggregate and structural spalling of the polyurethane abrasive layer. Full article

Magnesium and its alloys, valued for their lightweight and durable characteristics, have garnered increasing attention for biomedical applications due to their exceptional biocompatibility and biodegradability. This work introduces a comparison of advanced and basic methods—laser texturing and sandblasting—on magnesium surfaces to enhance bioactivity for biomedical applications. Employing a comprehensive analysis spanning surface morphology, hardness, wettability, tribological performance, and corrosion behavior, this study elucidates the intricate relationship between varied surface treatments and magnesium’s performance. Findings reveal that both laser texturing and sandblasting induce grain refinement. Notably, sandblasting, particularly with a duration of 2 s, demonstrates superior wear resistance and reduced corrosion rates compared to untreated magnesium, thereby emerging as a promising approach for enhancing magnesium bioactivity in biomedical contexts. This investigation contributes to a deeper understanding of the nuanced interactions between diverse surface treatments and their implications for magnesium implants in chloride-rich environments, offering valuable insights for prospective biomedical applications. Full article

This study presents an exhaustive exploration into the development and rigorous evaluation of nano-TiO₂-modified recycled aggregates (NT@RAs) as an environmentally sustainable substitute for natural aggregates in concrete applications. A methodical framework was devised for the synthesis and thorough characterization of NT@RAs, emphasizing the optimization of nano-TiO₂ loading onto the RA surface and within its intricate porous structure. The investigation encompassed three distinct types of recycled aggregates: recycled glass sands (RGSs), recycled clay brick sands (RCBSs), and recycled concrete sands (RCSs). Of particular interest, NT@RGS, with its properties of an inherently smooth surface texture and low water absorption, was found to exert a favorable influence on the rheological behavior of concrete, manifested in reduced yield stress, thereby underscoring the potential for fine-tuning mix designs to enhance workability. As the substitution levels of NT@RGS and NT@RCBS escalated, an initial decrement in compressive strength was discernible, which subsequently reversed to strength restoration at optimized substitution ratios. This phenomenon is attributed to the synergistic interplay among NT@RA components. Remarkably, NT@RA-incorporated concrete demonstrated unparalleled self-cleaning abilities, surpassing the performance of concrete with direct nano-TiO₂ powder incorporation. This comprehensive research contributes significantly to the advancement in sustainable, high-performance photocatalytic construction materials within the realm of concrete technology. It underscores the potential for enhancing not only the rheological and mechanical properties but also the environmental responsiveness of concrete through the innovative utilization of NT@RAs. Full article

This research, which involved a comprehensive methodology, including depositing electroplated copper on a copper seed layer and Al-doped ZnO (AZO) thin films on textured silicon substrates using DC magnetron sputtering with varying substrate heating, has yielded significant findings. The study thoroughly investigated the effects of substrate temperature (Ts) on copper adhesion strength and morphology using the peel force test and electron microscopy. The peel force test was conducted at angles of 90°, 135°, and 180°. The average adhesion strength was about 0.2 N/mm for the samples without substrate heating. For the samples with substrate heating at 100 °C, the average peeling force of the electroplated copper film was about 1 N/mm. The average peeling force increased to 1.5 N/mm as the substrate heating temperature increased to 200 °C. The surface roughness increases as the annealing temperature of the Cu/AZO/Si sample increases. These findings not only provide a reliable and robust method for applying AZO transparent conductive films onto silicon solar cells but also underscore its potential to significantly enhance the efficiency and durability of solar cells significantly, thereby instilling confidence in the field of solar cell technology. Full article