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23 pages, 25213 KiB  
Article
Evaluating Flow Characteristics of Ground and Cut Biomass for Industrial Applications
by Birce Dikici, Hussein Awad Kurdi Saad and Bo Zhao
Powders 2024, 3(3), 437-459; https://doi.org/10.3390/powders3030024 - 11 Sep 2024
Abstract
In recent years, biomass utilization has significantly increased, presenting challenges in its incorporation into various systems. Effective handling requires reliable data on biomass flow properties for designing warehouses and processing equipment. This study investigates the physical properties of ground barley grains, ground oak [...] Read more.
In recent years, biomass utilization has significantly increased, presenting challenges in its incorporation into various systems. Effective handling requires reliable data on biomass flow properties for designing warehouses and processing equipment. This study investigates the physical properties of ground barley grains, ground oak leaves, ground straw, and cut jute. Barley grains, oak leaves, and straw bales were milled, and jute was cut into 2–3 mm lengths and oven-dried. Particle size distribution, bulk density, Hausner ratio, Carr’s index, moisture content, static angle of repose, and flowability tests and SEM analysis were conducted. The study found that ground barley, having the smallest particle size and highest bulk density, showed superior flow properties due to its rounded particles and clusters, as reflected by a low Hausner ratio. In contrast, jute fibers had a low bulk density and poor flowability, while ground straw exhibited hindered flow due to its larger, more irregular particles. Additionally, the biomass sliding behavior varied with particle size and surface irregularities, with ground barley adhering well to plywood and ground oak leaves adhering well to aluminum. These findings underscore the pivotal roles of particle shape and interparticle forces in determining the biomass flow properties, pointing towards a future where precise environmental control and advanced analytical methods drive innovations in biomass utilization. Full article
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Figure 1
<p>Illustration depicting various examples of silo flow problems. (<a href="#powders-03-00024-f001" class="html-fig">Figure 1</a> is based on the figures in [<a href="#B12-powders-03-00024" class="html-bibr">12</a>,<a href="#B13-powders-03-00024" class="html-bibr">13</a>,<a href="#B14-powders-03-00024" class="html-bibr">14</a>]).</p>
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<p>Anatomy of barley grain. (<b>A</b>) Transverse and longitudinal sections. (<b>B</b>) Interior sections with labeled parts ((<b>A</b>) is based on Figure 9.1 from Li et al. [<a href="#B29-powders-03-00024" class="html-bibr">29</a>], and (<b>B</b>) is based on Figure 1.1 from Gous [<a href="#B30-powders-03-00024" class="html-bibr">30</a>]; original sources are referenced for inspiration).</p>
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<p>Anatomy of oak leaf: (<b>A</b>) anatomical structures (<b>B</b>,<b>C</b>) and cross-sections with labeled parts ((<b>A</b>) is based on a source from Treehugger [<a href="#B33-powders-03-00024" class="html-bibr">33</a>]; (<b>B</b>,<b>C</b>) are based on Figure 4 from Jankiewicz et al. [<a href="#B34-powders-03-00024" class="html-bibr">34</a>]; original sources are referenced for inspiration).</p>
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<p>Anatomy of straw. (<b>A</b>) Morphology of straw. (<b>B</b>) Cross-section of the stem. (<b>C</b>) Abaxial view with labeled parts ((<b>A</b>) is based on Figure 1 from Khan et al. [<a href="#B38-powders-03-00024" class="html-bibr">38</a>], (<b>B</b>) is based on Figure 3 from Zhang et al. [<a href="#B39-powders-03-00024" class="html-bibr">39</a>], and (<b>C</b>) is based on Figure 1 from Mayer et al. [<a href="#B37-powders-03-00024" class="html-bibr">37</a>]; original sources are referenced for inspiration).</p>
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<p>Anatomy of jute stem. (<b>A</b>) Anatomical structures. (<b>B</b>) Transverse section of jute stem. (<b>C</b>) Cross-section of fibers with labeled parts ((<b>A</b>,<b>C</b>) are based on Figures 2.2 and 2.1 from Krishnan et al. [<a href="#B46-powders-03-00024" class="html-bibr">46</a>], and (<b>B</b>) is based on Figure 4.1 from Chand et al. [<a href="#B47-powders-03-00024" class="html-bibr">47</a>]; original sources are referenced for inspiration).</p>
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<p>Barley grains, oak leaves, straw, and jute before and after the grinding process [<a href="#B49-powders-03-00024" class="html-bibr">49</a>], edited.</p>
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<p>Flowability arrangement.</p>
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<p>The angle of friction arrangement [<a href="#B49-powders-03-00024" class="html-bibr">49</a>], edited.</p>
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<p>SEM images of ground barley grains at 250× and 1000× magnifications.</p>
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<p>SEM images of ground oak leaves at 80× and 400× magnifications.</p>
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<p>SEM images of ground straw at 80× and 250× magnifications.</p>
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<p>SEM images of cut jute at 80× and 250× magnifications.</p>
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<p>Bulk density of ground/cut biomass samples.</p>
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<p>Moisture content of ground/cut biomass samples.</p>
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<p>Hausner ratio results of ground/cut biomass samples.</p>
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<p>Carr’s index results of ground/cut biomass samples.</p>
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<p>Static angle of repose (flowability) results of ground biomass samples.</p>
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<p>Static coefficient comparison on various surfaces for different biomass types.</p>
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21 pages, 4751 KiB  
Article
Green Synthesis of LaMnO3-Ag Nanocomposites Using Citrus limon (L.) Burm Peel Aqueous Extract: Photocatalytic Degradation of Rose Bengal Dye and Antibacterial Applications
by Nazim Hasan
Catalysts 2024, 14(9), 609; https://doi.org/10.3390/catal14090609 - 11 Sep 2024
Abstract
Perovskites can absorb solar energy and are extensively used in various catalytic and photocatalytic reactions. However, noble metal particles may enhance the catalytic, photocatalytic, and antibacterial activities. This study demonstrates the cost-effective green synthesis of the photocatalyst perovskite LaMnO3 and its modification [...] Read more.
Perovskites can absorb solar energy and are extensively used in various catalytic and photocatalytic reactions. However, noble metal particles may enhance the catalytic, photocatalytic, and antibacterial activities. This study demonstrates the cost-effective green synthesis of the photocatalyst perovskite LaMnO3 and its modification with noble metal Ag nanoparticles. The green synthesis of nanocomposite was achieved through a hydrothermal method employing aqueous extract derived from Citrus limon (L.) Burm peels. The properties of fabricated perovskites LaMnO3 and LaMnO3-Ag nanocomposites were evaluated and characterized by Ultraviolet-Visible spectroscopy (UV-Vis), Diffuse Reflectance Spectroscopy (DRS), X-ray diffraction (XRD), Fourier-Transform Infrared Spectroscopy (FT-IR), High-Resolution Transmission Electron Microscopy (HRTEM), Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray spectroscopy (EDX) and Brunauer–Emmett–Teller (BET) surface area techniques. The particle size distribution % of LaMnO3 and LaMnO3-Ag was observed to be 20 to 60 nm after using TEM images. The maximum percentage size distribution was 37 nm for LaMnO3 and 43 nm for LaMnO3-Ag. In addition, LaMnO3-Ag nanocomposite was utilized as a photocatalyst for the degradation of Rose Bengal (RB) dye and its antibacterial activities against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli). The surface area and band gap for perovskite LaMnO3 nanoparticles were calculated as 12.642 m2/g and 3.44 eV, respectively. The presence of noble metal and hydrothermal-bio reduction significantly impacted the crystallinity. The BET surface area was found to be 16.209 m2/g, and band gap energy was calculated at 2.94 eV. The LaMnO3 nanocomposite with noble metal shows enhanced photocatalytic effectiveness against RB dye (20 PPM) degradation (92%, R2 = 0.995) with pseudo-first-order chemical kinetics (rate constant, k = 0.05057 min−1) within 50 min due to the ultimate combination of the hydrothermal and bio-reduction technique. The photocatalytic activity of the LaMnO3-Ag nanocomposite was optimized at different reaction times, photocatalyst doses (0.2, 0.4, 0.6, and 0.8 g/L), and various RB dye concentrations (20, 30, 40, and 50 ppm). The antibacterial activities of green synthesized LaMnO3 and LaMnO3-Ag nanoparticles were explored based on colony-forming unit (cfu) reduction and TEM images of bacterial and nanoparticle interactions for S. aureus and E. coli. An amount of 50 µg/mL LaMnO3-Ag nanocomposite was sufficient to work as the highest antibacterial activity for both bacteria. The perovskite LaMnO3-Ag nanocomposite synthesis process is economically and environmentally friendly. Additionally, it has a wide range of effective and exclusive applications for remediating pollutants. Full article
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<p>XRD pattern of the green-synthesized (<b>a</b>) LaMnO<sub>3</sub>-Ag and (<b>b</b>) LaMnO<sub>3</sub> nanocomposites (XRD peaks are highlighted and matched), (<b>c</b>) ICPDS reference peaks of LaMnO<sub>3</sub> with card number 00-050-0297, (<b>d</b>) ICPDS reference peaks of Ag with card number 00-004-0783, and W–H plot for (<b>e</b>) LaMnO<sub>3</sub>-Ag and (<b>f</b>) LaMnO<sub>3</sub> nanocomposite.</p>
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<p>UV-Vis DRS spectra of LaMnO<sub>3</sub> and LaMnO<sub>3</sub>-Ag nanocomposites (<b>a</b>), band gap energy (eV) of LaMnO<sub>3</sub> (<b>b</b>), band gap of LaMnO<sub>3</sub>-Ag nanocomposite (<b>c</b>).</p>
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<p>TEM and HRTEM images of LaMnO<sub>3</sub> (<b>a</b>,<b>b</b>), LaMnO<sub>3</sub>-Ag (<b>c</b>,<b>d</b>), and their respective particle size distribution %.</p>
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<p>HRSEM images; (<b>a</b>) LaMnO<sub>3</sub> and (<b>b</b>) LaMnO<sub>3</sub>-EDX, (<b>c</b>) LaMnO<sub>3</sub>-Ag and (<b>d</b>) LaMnO<sub>3</sub>-Ag EDX.</p>
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<p>FTIR spectra of the synthesized LaMnO<sub>3</sub> and LaMnO<sub>3</sub>-Ag nanocomposites.</p>
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<p>N<sub>2</sub> adsorption–desorption isotherms ((<b>a</b>) LaMnO<sub>3</sub> and (<b>b</b>) LaMnO<sub>3</sub>-Ag nanocomposites) and pore size distribution patterns ((<b>c</b>) LaMnO<sub>3</sub> and (<b>d</b>) LaMnO<sub>3</sub>-Ag nanocomposites).</p>
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<p>(<b>a</b>) Photodegradation percentage efficiency, (<b>b</b>) apparent rate constant for the degradation of different ppm of dye, (<b>c</b>) apparent rate constant for the degradation of 20 ppm dye after using various amounts of LaMnO<sub>3</sub> nanocomposite, (<b>d</b>) recyclability of LaMnO<sub>3</sub>-Ag nanocomposite as catalyst, (<b>e</b>) UV-Vis spectra of RB dye (20 PPM, 50 mL) degradation using 40 mg LaMnO<sub>3</sub>-Ag nanocomposite catalyst, (<b>f</b>) scavenging agents effect on RB dye degradation.</p>
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<p>(<b>a</b>) Photodegradation percentage efficiency, (<b>b</b>) apparent rate constant for the degradation of different ppm of dye, (<b>c</b>) apparent rate constant for the degradation of 20 ppm dye after using various amounts of LaMnO<sub>3</sub> nanocomposite, (<b>d</b>) recyclability of LaMnO<sub>3</sub>-Ag nanocomposite as catalyst, (<b>e</b>) UV-Vis spectra of RB dye (20 PPM, 50 mL) degradation using 40 mg LaMnO<sub>3</sub>-Ag nanocomposite catalyst, (<b>f</b>) scavenging agents effect on RB dye degradation.</p>
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<p>Schematic diagram of the reaction mechanism involved in the photocatalytic activity of LaMnO<sub>3</sub>-Ag nanocomposites.</p>
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<p>TEM images of <span class="html-italic">S. aureus</span> and <span class="html-italic">E. coli</span> interaction with LaMnO<sub>3</sub>-Ag nanoparticles. Images (<b>a</b>) and (<b>d</b>) show control bacterial cells, (<b>b</b>,<b>e</b>) represent the interaction of LaMnO<sub>3</sub>-Ag NPs towards <span class="html-italic">S. aureus</span> and <span class="html-italic">E. coli</span>, respectively. In contrast (<b>c</b>,<b>f</b>) represent <span class="html-italic">S. aureus</span> and <span class="html-italic">E. coli</span>. cell debris after the antibacterial effects of LaMnO<sub>3</sub>-Ag NPs.</p>
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<p>Schematic preparation of LaMnO<sub>3</sub> and LaMnO<sub>3</sub>-Ag nanocomposites.</p>
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15 pages, 4552 KiB  
Communication
Research on On-Line Monitoring of Grinding Wheel Wear Based on Multi-Sensor Fusion
by Jingsong Duan, Guohua Cao, Guoqing Ma, Zhenglin Yu and Changshun Shao
Sensors 2024, 24(18), 5888; https://doi.org/10.3390/s24185888 - 11 Sep 2024
Abstract
The state of a grinding wheel directly affects the surface quality of the workpiece. The monitoring of grinding wheel wear state can allow one to efficiently identify grinding wheel wear information and to timely and effectively trim the grinding wheel. At present, on-line [...] Read more.
The state of a grinding wheel directly affects the surface quality of the workpiece. The monitoring of grinding wheel wear state can allow one to efficiently identify grinding wheel wear information and to timely and effectively trim the grinding wheel. At present, on-line monitoring technology using specific sensor signals can detect abnormal grinding wheel wear in a timely manner. However, due to the non-linearity and complexity of the grinding wheel wear process, as well as the interference and noise of the sensor signal, the accuracy and reliability of on-line monitoring technology still need to be improved. In this paper, an intelligent monitoring system based on multi-sensor fusion is established, and this system can be used for precise grinding wheel wear monitoring. The proposed system focuses on titanium alloy, a typical difficult-to-process aerospace material, and addresses the issue of low on-line monitoring accuracy found in traditional single-sensor systems. Additionally, a multi-eigenvalue fusion algorithm based on an improved support vector machine (SVM) is proposed. In this study, the mean square value of the wavelet packet decomposition coefficient of the acoustic emission signal, the grinding force ratio of the force signal, and the effective value of the vibration signal were taken as inputs for the improved support vector machine, and the recognition strategy was adjusted using the entropy weight evaluation method. A high-precision grinding machine was used to carry out multiple sets of grinding wheel wear experiments. After being processed by the multi-sensor integrated precision grinding wheel wear intelligent monitoring system, the collected signals can accurately reflect the grinding wheel wear state, and the monitoring accuracy can reach more than 92%. Full article
(This article belongs to the Section Fault Diagnosis & Sensors)
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<p>KeyenceVXH-200 ultra-depth-of-field microscope.</p>
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<p>Surface morphology of grinding wheel in different wear periods: (<b>a</b>) initial grinding wheel wear; (<b>b</b>) middle grinding wheel wear; (<b>c</b>) late-stage wheel wear.</p>
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<p>Structure of SVM network model for precision grinding wheel wear state identification.</p>
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<p>Experimental setup.</p>
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<p><b>Raw data of acoustic emission signal:</b> (<b>a</b>) Experiment 1-original acoustic emission signal; (<b>b</b>) Experiment 2-original acoustic emission signal; (<b>c</b>) Experiment 3-original acoustic emission signal.</p>
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<p><b>Raw data of acoustic emission signal:</b> (<b>a</b>) Experiment 1-original acoustic emission signal; (<b>b</b>) Experiment 2-original acoustic emission signal; (<b>c</b>) Experiment 3-original acoustic emission signal.</p>
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<p><b>Wavelet packet energy coefficient distribution diagrams:</b> (<b>a</b>) Experiment 1-Wavelet packet energy coefficient distribution diagram ; (<b>b</b>) Experiment 2-Wavelet packet energy coefficient distribution diagram; (<b>c</b>) Experiment 3 Wavelet packet energy coefficient distribution diagram .</p>
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<p>Vibration signal before denoising.</p>
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<p>Vibration signal after denoising signal.</p>
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<p>Chromatogram produced by Leica MAP before the wear of grinding wheel.</p>
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<p>Chromatogram produced by Leica MAP after the wear of the grinding wheel.</p>
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<p>Results of wheel wear status monitoring simulation.</p>
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15 pages, 3753 KiB  
Article
Assessment of Coating Properties in Car Body by Ultrasonic Method
by Dariusz Ulbrich, Grzegorz Psuj, Dariusz Bartkowski and Aneta Bartkowska
Appl. Sci. 2024, 14(18), 8117; https://doi.org/10.3390/app14188117 - 10 Sep 2024
Viewed by 191
Abstract
Adhesive bonds, including car putty coatings, are used in the construction of modern motor vehicles. Therefore, it is important to improve methods that allow nondestructive evaluation of the properties of these joints. The main objective of this study was to evaluate selected properties [...] Read more.
Adhesive bonds, including car putty coatings, are used in the construction of modern motor vehicles. Therefore, it is important to improve methods that allow nondestructive evaluation of the properties of these joints. The main objective of this study was to evaluate selected properties of putty coatings such as the width of the applied coating and adhesion to the substrate based on changes in ultrasonic wave parameters. The research was carried out in two stages. In the first, the values of the surface wave amplitude were determined as a function of the width of the coating to the substrate. It was found that as the width of the coating increases, the amplitude of the surface wave pulse decreases. The second stage involved correlation studies to relate the reflection coefficient |r| to the adhesion of the coating to the substrate. Based on the results, it was found that as the value of the reflection coefficient decreases, the value of the coating’s adhesion to the substrate increases. The determined values of this parameter range from 0.30 to 0.86, which correspond to the adhesion of the range 1.51 to 18.97 MPa. The obtained test results have practical significance and can be used in evaluating the condition of coatings in vehicle body repair shops. Full article
(This article belongs to the Special Issue Progress in Nondestructive Testing and Evaluation)
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<p>The consecutive stages of the conducted research.</p>
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<p>View of samples with putty coating; (<b>a</b>) coating width from 1 to 6 mm, (<b>b</b>) coating width from 7 to 13 mm.</p>
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<p>Ultrasonic measurement by Rayleigh wave; 1—transmitting transducer, 2—holder, 3—receiving transducer, 4—car putty coating, 5—surface wave, 6—car body sheet.</p>
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<p>View of the sample used during correlation studies; (<b>a</b>) diagram, (<b>b</b>) sample with pin.</p>
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<p>Diagram of the implementation of ultrasonic measurements after the application and curing of the putty coating to the steel substrate; 1—coating, 2—sample, 3—ultrasonic wave beam, 4—ultrasonic transducer, 5—ultrasonic flaw detector, 6—table.</p>
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<p>Relationship between the amplitude of the pulse <span class="html-italic">A</span> for a different putty width <span class="html-italic">W</span>, expressed in reference to the no coating pulse height reading; results given in %.</p>
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<p>Relationship between the reflection coefficient |<span class="html-italic">r</span>| of the wave for a different steel surface roughness <span class="html-italic">R</span><sub>a</sub> and <span class="html-italic">R</span><sub>z</sub> in reference to putty drying temperature (different markers shape) and generalized stress level (different color); the obtained stresses were aggregated by fixing to levels expressed by closed integer; (<b>a</b>) 3D view, (<b>b</b>–<b>d</b>) projections on component planes.</p>
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<p>Assessment of features importance using <span class="html-italic">F</span>-test method.</p>
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<p>Putty coating quality evaluation model based on reflection coefficient |r|.</p>
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<p>Putty coating quality evaluation model based on putty drying temperature <span class="html-italic">T</span> and reflection coefficient |r| of wave.</p>
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19 pages, 4666 KiB  
Article
Quantifying Qiyi Glacier Surface Dirtiness Using UAV and Sentinel-2 Imagery
by Jiangtao Chen, Ninglian Wang, Yuwei Wu, Anan Chen, Chenlie Shi, Mingjie Zhao and Longjiang Xie
Remote Sens. 2024, 16(17), 3351; https://doi.org/10.3390/rs16173351 - 9 Sep 2024
Viewed by 210
Abstract
The glacier surface is composed not only of ice or snow but also of a heterogeneous mixture of various materials. The presence of light-absorbing impurities darkens the glacier surface, reducing local reflectance and thereby accelerating the glacier melting process. However, our understanding of [...] Read more.
The glacier surface is composed not only of ice or snow but also of a heterogeneous mixture of various materials. The presence of light-absorbing impurities darkens the glacier surface, reducing local reflectance and thereby accelerating the glacier melting process. However, our understanding of the spatial distribution of these impurities remains limited, and there is a lack of studies on quantifying the dirty degree of glacier surfaces. During the Sentinel satellite overpass on 21 August 2023, we used an ASD FieldSpec3 spectrometer to measure the reflectance spectra of glacier surfaces with varying degrees of dirtiness on the Qiyi glacier, Qinghai–Tibet Plateau. Using Multiple Endmember Spectral Mixture Analysis (MESMA), the Sentinel imagery was decomposed to generate fraction images of five primary ice surface materials as follows: coarse-grained snow, slightly dirty ice, moderately dirty ice, extremely dirty ice, and debris. Using unmanned aerial vehicle (UAV) imagery with a 0.05 m resolution, the primary ice surface was delineated and utilized as reference data to validate the fraction images. The findings revealed a strong correlation between the fraction images and the reference data (R2 ≥ 0.66, RMSE ≤ 0.21). Based on pixel-based classification from the UAV imagery, approximately 80% of the glacier surface is covered by slightly dirty ice (19.2%), moderately dirty ice (33.3%), extremely dirty ice (26.3%), and debris (1.2%), which significantly contributes to its darkening. Our study demonstrates the effectiveness of using Sentinel imagery in conjunction with MESMA to map the degree of glacier surface dirtiness accurately. Full article
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<p>(<b>a</b>) Location of the Qiyi glacier (red star). (<b>b</b>) A true-color RGB image (10 m resolution) of the glacier, with the blue curve outlining its boundary. Red circles represent spectral sampling points, yellow triangles indicate UAV ground control points, and pink rectangles delineate the validation areas. (<b>c</b>,<b>d</b>) are images of the glacier terminus taken on 31 July 2013, and 15 August 2023, respectively.</p>
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<p>(<b>a</b>) Spectral measurements were collected with a fiber optic probe ~1 m above the ice surface. (<b>b</b>) The actual measured spectral curves are depicted with solid black lines, while colored circles represent the reflectance values at the central wavelengths of Sentinel-2B bands (B2-B8A bands correspond to red to pink hues on the graph).</p>
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<p>Spectral curves after SRF conversion, where solid lines represent mean values and shaded areas denote standard deviations (<b>a</b>). Photographs of the following categories of ice are shown: (<b>b</b>) coarse-grained snow; (<b>c</b>) slightly dirty ice; (<b>d</b>) moderately dirty ice; (<b>e</b>) extremely dirty ice; and (<b>f</b>) supraglacial rivers. The spectrometer’s field of view is a ~50 cm diameter circle; a pen is placed for scale, aiming to provide readers with a sense of proportion for better comprehension.</p>
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<p>A comparison of measured reflectance and satellite products, where red pentagrams denote the sampling positions of the spectrometer. (<b>a</b>,<b>b</b>) represent relatively clean glacier surfaces, while (<b>c</b>,<b>d</b>) depict relatively dirty glacier surfaces. L2A denotes products produced by the ESA, FLAASH (10 m) signifies atmospheric correction through FLAASH, and L2A (Sen2cor) indicates correction via the Sen2cor plugin. SRF refers to spectral response function conversion, the green line represents the measured spectra, and L1C denotes ESA L1C products.</p>
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<p>(<b>a</b>) The UAV image and (<b>b</b>) the SVM-classified image.</p>
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<p>The final spectral endmembers for the following different glacier surface types: (<b>a</b>) coarse-grained snow; (<b>b</b>) slightly dirty ice; (<b>c</b>) moderately dirty ice; (<b>d</b>) extremely dirty ice; and (<b>e</b>) debris.</p>
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<p>Fraction images for the following five distinct ice surface types are presented: (<b>a</b>) coarse-grained snow; (<b>b</b>) slightly dirty ice; (<b>c</b>) moderately dirty ice; (<b>d</b>) extremely dirty ice; and (<b>e</b>) debris.</p>
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<p>A regression model was constructed to examine the relationship between MESMA fraction images and reference fraction (UAV images). The solid line illustrates the degree of fitting, while the shaded area represents the 95% confidence interval. The determination coefficient (R<sup>2</sup>) and root mean square error (RMSE) are presented, <span class="html-italic">n</span> = 330.</p>
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18 pages, 4825 KiB  
Article
Optimization of Bacterial Cellulose Production from Waste Figs by Komagataeibacter xylinus
by Merve Yilmaz and Yekta Goksungur
Fermentation 2024, 10(9), 466; https://doi.org/10.3390/fermentation10090466 - 9 Sep 2024
Viewed by 230
Abstract
This study aimed to use waste figs as an alternative substrate for bacterial cellulose (BC) production by Komagataeibacter xylinus and optimize the identified process parameters to maximize the concentration of BC. Among the nutrients screened by Plackett–Burman (PB) design, yeast extract was found [...] Read more.
This study aimed to use waste figs as an alternative substrate for bacterial cellulose (BC) production by Komagataeibacter xylinus and optimize the identified process parameters to maximize the concentration of BC. Among the nutrients screened by Plackett–Burman (PB) design, yeast extract was found to be significant in BC production. Response surface methodology was used to investigate the effect of fermentation parameters on BC production. A maximum BC concentration of (8.45 g/L), which is among the highest BC concentrations reported so far, was achieved at the optimum levels of fermentation variables (initial pH 6.05, initial sugar concentration 62.75 g/L, temperature 30 °C). The utilization of response surface methodology (RSM) proved valuable in both optimizing and finding the interactions between process variables during BC production. Scanning electron microscope (SEM) analysis showed a dense structure of BC, characterized by ribbon-like nanofibrils with diameters ranging from 23 to 90 nm while the attenuated total reflection–Fourier transform infrared (ATR-FTIR) spectrum of BC confirmed that the material obtained was cellulose. The X-ray diffraction (XRD) analysis showed that the crystallinity of the BC samples was 70% for BC produced on waste fig medium and 61% for BC produced on Hestrin–Schramm (HS) medium. This is the first detailed study on the production of BC from waste figs, and the findings of this study demonstrated that waste figs can be used as an effective substrate for the production of BC. Full article
(This article belongs to the Special Issue Strategies for Optimal Fermentation by Using Modern Tools and Methods)
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<p>Effect of various parameters on BC synthesis by <span class="html-italic">Komagataeibacter xylinus</span> ATCC 700178: (<b>a</b>) yeast extract concentration; (<b>b</b>) initial pH; (<b>c</b>) sugar concentration; (<b>d</b>) temperature. Different letters indicate significant differences, and the same letters or no letters indicate no significant differences (<span class="html-italic">p</span> &gt; 0.05).</p>
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<p>Response surface plot (<b>a</b>) and contour plot (<b>b</b>) of temperature and initial pH on BC cellulose synthesis by <span class="html-italic">Komagataeibacter xylinus</span> ATCC 700178 with constant initial sugar concentration (60 g/L).</p>
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<p>Response surface plot (<b>a</b>) and contour plot (<b>b</b>) of initial sugar concentration and temperature on BC synthesis by <span class="html-italic">Komagataeibacter xylinus</span> ATCC 700178 with constant initial pH (6.5).</p>
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<p>Response surface plot (<b>a</b>) and contour plot (<b>b</b>) of initial sugar concentration and initial pH on BC synthesis by <span class="html-italic">Komagataeibacter xylinus</span> ATCC 700178 with constant temperature (30 °C).</p>
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<p>SEM micrographs and fiber diameter histograms of BC produced by <span class="html-italic">Komagataeibacter xylinus</span> ATCC 700178 from (<b>a</b>) HS medium and (<b>b</b>) waste fig medium.</p>
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<p>ATR-FTIR spectra of BC by <span class="html-italic">Komagataeibacter xylinus</span> from HS medium and from waste fig medium.</p>
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<p>X-ray diffraction patterns of BC produced by <span class="html-italic">Komagataeibacter xylinus</span> from HS medium and waste fig medium.</p>
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15 pages, 4447 KiB  
Article
Spectral Reflectance Estimation from Camera Response Using Local Optimal Dataset and Neural Networks
by Shoji Tominaga and Hideaki Sakai
J. Imaging 2024, 10(9), 222; https://doi.org/10.3390/jimaging10090222 - 9 Sep 2024
Viewed by 252
Abstract
In this study, a novel method is proposed to estimate surface-spectral reflectance from camera responses that combine model-based and training-based approaches. An imaging system is modeled using the spectral sensitivity functions of an RGB camera, spectral power distributions of multiple light sources, unknown [...] Read more.
In this study, a novel method is proposed to estimate surface-spectral reflectance from camera responses that combine model-based and training-based approaches. An imaging system is modeled using the spectral sensitivity functions of an RGB camera, spectral power distributions of multiple light sources, unknown surface-spectral reflectance, additive noise, and a gain parameter. The estimation procedure comprises two main stages: (1) selecting the local optimal reflectance dataset from a reflectance database and (2) determining the best estimate by applying a neural network to the local optimal dataset only. In stage (1), the camera responses are predicted for the respective reflectances in the database, and the optimal candidates are selected in the order of lowest prediction error. In stage (2), most reflectance training data are obtained by a convex linear combination of local optimal data using weighting coefficients based on random numbers. A feed-forward neural network with one hidden layer is used to map the observation space onto the spectral reflectance space. In addition, the reflectance estimation is repeated by generating multiple sets of random numbers, and the median of a set of estimated reflectances is determined as the final estimate of the reflectance. Experimental results show that the estimation accuracies exceed those of other methods. Full article
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<p>Conceptual diagram of our image acquisition system [<a href="#B14-jimaging-10-00222" class="html-bibr">14</a>].</p>
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<p>Database of surface-spectral reflectance.</p>
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<p>Architecture of the feedforward neural network with a structure of <span class="html-italic">m-N-n.</span>.</p>
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<p>Overall flow of the proposed method for estimating spectral reflectance in three steps.</p>
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<p>Relative RGB spectral sensitivity functions of the Apple iPhone 6s [<a href="#B14-jimaging-10-00222" class="html-bibr">14</a>].</p>
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<p>Spectral power distributions of seven LED light sources used in current experiments [<a href="#B14-jimaging-10-00222" class="html-bibr">14</a>].</p>
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<p>Estimation results of the spectral reflectances for the 24 color checkers when applying the proposed method to the observations using the iPhone 6s. The bold and broken curves indicate, respectively, the estimated and directly measured spectral reflectances for the 24 color checkers.</p>
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<p>Comparison of the average RMSEs between the proposed method and the other methods. The symbols of Wiener, LMMSE, L_Wiener, L_LMMSE, Lp, and Qp represent the six estimation methods of (1) original Wiener [<a href="#B13-jimaging-10-00222" class="html-bibr">13</a>], (2) original LMMSE [<a href="#B13-jimaging-10-00222" class="html-bibr">13</a>], (3) local Wiener [<a href="#B14-jimaging-10-00222" class="html-bibr">14</a>], (4) local LMMSE [<a href="#B14-jimaging-10-00222" class="html-bibr">14</a>], (5) linear programming [<a href="#B14-jimaging-10-00222" class="html-bibr">14</a>], and (6) quadratic programming [<a href="#B14-jimaging-10-00222" class="html-bibr">14</a>], respectively.</p>
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<p>Estimation results of the spectral reflectances for the 24 color checkers when applying the network method (2) to the observations using the iPhone 6s without using the local optimal dataset. The bold and broken curves indicate, respectively, the estimated and directly measured spectral reflectances for the 24 color checkers.</p>
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<p>Comparison of the average RMSEs between the proposed method and the other methods when using iPhone 8.</p>
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<p>Comparison of the average RMSEs between the proposed method and the other methods when using Huawei P10 lite.</p>
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13 pages, 463 KiB  
Article
Deep Learning-Based Joint Beamforming Design for Multi-Hop Reconfigurable Intelligent Surface (RIS)-Aided Communication Systems
by Xiao Chen, Jiaoyang Ye, Yuxuan Wei, Jianfeng Shi and Jianyue Zhu
Electronics 2024, 13(17), 3570; https://doi.org/10.3390/electronics13173570 - 8 Sep 2024
Viewed by 338
Abstract
Reconfigurable intelligent surface (RIS) is one of the promising technologies for sixth generation communications due to its advantages including energy saving, high spectral efficiency, etc. However, the non-convex joint beamforming design is a challenge, especially in the multi-hop RIS-assisted communication system. This paper [...] Read more.
Reconfigurable intelligent surface (RIS) is one of the promising technologies for sixth generation communications due to its advantages including energy saving, high spectral efficiency, etc. However, the non-convex joint beamforming design is a challenge, especially in the multi-hop RIS-assisted communication system. This paper proposes a deep learning-based joint beamforming (DLBF) design, aiming to maximize the system data rate for multi-hop RIS-aided communication systems. The proposed DLBF design consists of the reflection matrices design of all RISs and the transmit beamforming design at the base station, which has a reduced computational complexity. Numerical results show that the proposed DLBF can achieve 1.8 bit/s/Hz sum rate gain compared to the conventional beamforming method for the two-user scenario, which can be enhanced by large-scale users. The sum rate performance can be improved by increasing the number of RISs due to the reflection gain, and corresponding results provide a guidance of the multi-hop number selection for further investigation. Full article
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<p>A multi-hop RIS-enhanced system.</p>
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<p>The DNN-based equivalent beamforming framework.</p>
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<p>Simulated sum rate performance for 2RIS-aided systems with the number of batch size being 50, 100, 150, and 300.</p>
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<p>Simulated sum rate performance for 2RIS-aided systems with different number of training sample size.</p>
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<p>Simulated sum rate performance for 2RIS-aided systems with the number of reflecting elements being <math display="inline"><semantics> <mrow> <mi>N</mi> <mo>=</mo> <mn>64</mn> <mo>,</mo> <mn>100</mn> <mo>,</mo> <mn>144</mn> <mo>,</mo> <mn>196</mn> <mo>,</mo> <mn>256</mn> </mrow> </semantics></math>.</p>
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<p>Simulated sum rate performance for multiple-RIS-aided systems with the number of reflecting elements being <math display="inline"><semantics> <mrow> <mi>N</mi> <mo>=</mo> <mn>64</mn> <mo>,</mo> <mn>100</mn> <mo>,</mo> <mn>144</mn> <mo>,</mo> <mn>196</mn> <mo>,</mo> <mn>256</mn> </mrow> </semantics></math>.</p>
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<p>Simulated sum rate performance versus SNR for multiple-RIS-aided systems with the number of UEs being <math display="inline"><semantics> <mrow> <mi>K</mi> <mo>=</mo> <mn>2</mn> <mo>,</mo> <mn>3</mn> <mo>,</mo> <mn>4</mn> </mrow> </semantics></math>.</p>
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24 pages, 15733 KiB  
Article
Evolution Patterns and Dominant Factors of Soil Salinization in the Yellow River Delta Based on Long-Time-Series and Similar Phenological-Fusion Images
by Bing Guo, Mei Xu and Rui Zhang
Remote Sens. 2024, 16(17), 3332; https://doi.org/10.3390/rs16173332 - 8 Sep 2024
Viewed by 352
Abstract
Previous studies were mostly conducted based on sparse time series and different phenological images, which often ignored the dramatic changes in salinization evolution throughout the year. Based on Landsat and moderate-resolution-imaging spectroradiometer (MODIS) images from 2000 to 2020, this study applied the Enhanced [...] Read more.
Previous studies were mostly conducted based on sparse time series and different phenological images, which often ignored the dramatic changes in salinization evolution throughout the year. Based on Landsat and moderate-resolution-imaging spectroradiometer (MODIS) images from 2000 to 2020, this study applied the Enhanced Spatial and Temporal Adaptive Reflectance Fusion Model (ESTARFM) algorithm to obtain similar phenological images for the month of April for the past 20 years. Based on the random forest algorithm, the surface parameters of the salinization were optimized, and the feature space index models were constructed. Combined with the measured ground data, the optimal monitoring index model of salinization was determined, and then the spatiotemporal evolution patterns of salinization and its driving mechanisms in the Yellow River Delta were revealed. The main conclusions were as follows: (1) The derived long-time-series and similar phenological-fusion images enable us to reveal the patterns of change in the dramatic salinization in the year that we examined using the ESTARFM algorithm. (2) The NDSI-TGDVI feature space salinization monitoring index model based on point-to-point mode had the highest accuracy of 0.92. (3) From 2000 to 2020, the soil salinization in the Yellow River Delta showed an aggravating trend. The average value of salinization during the past 20 years was 0.65, which is categorized as severe salinization. The degree of salinization gradually decreased from the northeastern coastal area to the southwestern inland area. (4) The dominant factors affecting soil salinization in different historical periods varied. The research results could provide support for decision-making regarding the precise prevention and control of salinization in the Yellow River Delta. Full article
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<p>The location of the study area and the distribution of the observed samples from the field. (<b>a</b>) the location of the study area in China; (<b>b</b>) the location of the study area in Shandong Province; (<b>c</b>) the location of the study area.</p>
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<p>The flowchart of the entire paper.</p>
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<p>Principle of feature space method: (<b>a</b>) TGDVI-NDSI; (<b>b</b>) EDVI-Albedo.</p>
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<p>Types of interactive dominant factors affecting salinization changes.</p>
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<p>Comparison details of ESTARFM fusion results: (<b>a</b>) coarse-resolution image; (<b>b</b>) fusion image; (<b>c</b>) actual image; (<b>d</b>) enlarged area from coarse-resolution image; (<b>e</b>) enlarged area from fine-resolution image; and (<b>f</b>) enlarged area from actual-resolution image.</p>
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<p>ESTARFM fusion results and 2D scatter plot of actual images.</p>
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<p>Optimization of salinization characterization parameters in the Yellow River Delta.</p>
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<p>Characteristic space salinization monitoring indicator models: (<b>a</b>) GNDVI-NDSI; (<b>b</b>) NDSI-EDVI; (<b>c</b>) NDSI-RVI; (<b>d</b>) NDSI-TGDVI; (<b>e</b>) SI2-Albedo; (<b>f</b>) WI-Albedo; (<b>g</b>) WI-SI2; (<b>h</b>) EDVI-Albedo; (<b>i</b>) GNDVI-Albedo; (<b>j</b>) NDSI-Albedo; (<b>k</b>) TGDVI-Albedo; and (<b>l</b>) TGDVI-SI2.</p>
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<p>Construction of NDSI-TGDVI feature space salinization monitoring model based on point-to-point mode.</p>
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<p>Construction of EDVI-Albedo feature space salinization monitoring model based on point-to-line mode.</p>
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<p>Temporal variations in average salinization monitoring model from 2000 to 2020.</p>
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<p>Spatial distribution of salinization at different levels: (<b>a</b>) 2000; (<b>b</b>) 2005; (<b>c</b>) 2010; (<b>d</b>) 2015; and (<b>e</b>) 2020.</p>
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<p>Migration trajectory of salinization gravity center in the Yellow River Delta at different timescales.</p>
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<p>Q values of different driving factors in different years.</p>
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<p>The dominant interactive factors of soil salinization in the Yellow River Delta. (<b>a</b>) 2000; (<b>b</b>) 2005; (<b>c</b>) 2010; (<b>d</b>) 2015; (<b>e</b>) 2020.</p>
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<p>The dominant interactive factors of soil salinization in the Yellow River Delta. (<b>a</b>) 2000; (<b>b</b>) 2005; (<b>c</b>) 2010; (<b>d</b>) 2015; (<b>e</b>) 2020.</p>
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19 pages, 4999 KiB  
Article
Study on Downscaling Correction of Near-Surface Wind Speed Grid Forecasts in Complex Terrain
by Xin Liu, Zhimin Li and Yanbo Shen
Atmosphere 2024, 15(9), 1090; https://doi.org/10.3390/atmos15091090 - 8 Sep 2024
Viewed by 291
Abstract
Accurate forecasting of wind speeds is a crucial aspect of providing fine-scale professional meteorological services (such as wind energy generation and transportation operations etc.). This article utilizes CMA-MESO model forecast data and CARAS-SUR_1 km ground truth grid data from January, April, July, and [...] Read more.
Accurate forecasting of wind speeds is a crucial aspect of providing fine-scale professional meteorological services (such as wind energy generation and transportation operations etc.). This article utilizes CMA-MESO model forecast data and CARAS-SUR_1 km ground truth grid data from January, April, July, and October 2022, employing the random forest algorithm to establish and evaluate a downscaling correction model for near-surface 1 km resolution wind-speed grid forecast in the complex terrain area of northwestern Hebei Province. The results indicate that after downscaling correction, the spatial distribution of grid forecast wind speeds in the entire complex terrain study area becomes more refined, with spatial resolution improving from 3 km to 1 km, reflecting fine-scale terrain effects. The accuracy of the corrected wind speed forecast significantly improves compared to the original model, with forecast errors showing stability in both time and space. The mean bias decreases from 2.25 m/s to 0.02 m/s, and the root mean square error (RMSE) decreases from 3.26 m/s to 0.52 m/s. Forecast errors caused by complex terrain, forecast lead time, and seasonal factors are significantly reduced. In terms of wind speed categories, the correction significantly improves forecasts for wind speeds below 8 m/s, with RMSE decreasing from 2.02 m/s to 0.59 m/s. For wind speeds above 8 m/s, there is also a good correction effect, with RMSE decreasing from 2.20 m/s to 1.65 m/s. Selecting the analysis of the Zhangjiakou strong wind process on 26 April 2022, it was found that the downscaled corrected forecast wind speed is very close to the observed wind speed at the station and the ground truth grid points. The correction effect is particularly significant in areas affected by strong winds, such as the Bashang Plateau and valleys, which has significant reference value. Full article
(This article belongs to the Special Issue Solar Irradiance and Wind Forecasting)
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<p>The topography and distribution of national meteorological stations in the study area. M1—Shangyi, M2—Zhangbei, M3—Tianzhen, M4—Huai’an, M5—Yangyuan, M6—Xuanhua, M7—Wanquan, M8—Chongli, M9—Qiaodong, M10—Huailai, M11—Zhuolu.</p>
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<p>Flowchart of the wind speed gridded downscaling correction model using the random forest algorithm.</p>
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<p>Spatial distributions of the mean wind speed by CARAS-SUR_1 km (<b>a</b>), CMA-MESO 3 km (<b>b</b>), downscaling corrected forecast (<b>c</b>), the root mean square error (RMSE) of forecasting wind speed (<b>d</b>), and downscaling corrected wind speed (<b>e</b>) in the study area in 2022 (unit: m/s).</p>
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<p>The root mean square error (RMSE) (<b>a</b>), mean bias (BIAS) (<b>b</b>), and correlation coefficient (R) (<b>c</b>) of wind speed forecasts for representative months in each season in the study area in 2022.</p>
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<p>The root mean square error (RMSE) (<b>a</b>), mean bias (BIAS) (<b>b</b>), and correlation coefficient (R) (<b>c</b>) of wind speed forecasts for 1 to 24 h in the study area in 2022.</p>
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<p>The root mean square error (RMSE) (<b>a</b>), mean bias (BIAS) (<b>b</b>), and correlation coefficient (R) (<b>c</b>) of wind speed forecasts for 1 to 24 h in the study area in 2022.</p>
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<p>The root mean square error (RMSE) (<b>a</b>), mean bias (BIAS) (<b>b</b>), and correlation coefficient (R) (<b>c</b>) of wind speed forecasts for different wind speed categories in the study area in 2022.</p>
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<p>The root mean square error (RMSE) (<b>a</b>), mean bias (BIAS) (<b>b</b>), and correlation coefficient (R) (<b>c</b>) of wind speed forecasts for different wind speed categories in the study area in 2022.</p>
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<p>Spatial distributions of near-surface observed wind speed from CARAS-SUR_1 km (<b>a1</b>,<b>a2</b>,<b>a3</b>,<b>a4</b>), forecasted wind speed from CMA-MESO 3 km (<b>b1</b>,<b>b2</b>,<b>b3</b>,<b>b4</b>), and downscaling corrected forecasted wind speed (<b>c1</b>,<b>c2</b>,<b>c3</b>,<b>c4</b>) at 02:00, 07:00, 13:00, and 19:00 on 26 April 2022 in the study area (unit: m/s).</p>
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<p>The time series plot of wind speeds at representative meteorological stations on 26 April 2022. M2—Zhangbei, M9—Qiaodong, M6—Xuanhua, M10—Huailai.</p>
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<p>The time series plot of wind speeds at representative meteorological stations on 26 April 2022. M2—Zhangbei, M9—Qiaodong, M6—Xuanhua, M10—Huailai.</p>
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15 pages, 851 KiB  
Article
Changes in the Fatty Acid Composition of Vegetable Oils Affect the Feeding Behavior, Feed Preference, and Thermoregulatory Responses of Sheep
by Évyla Layssa G. Andrade, José M. Pereira Filho, Kevily Henrique de O. S. de Lucena, Yuri C. S. Barreto, Ronaldo L. Oliveira, Bonifácio B. de Sousa, Antônio Fernando de M. Vaz, Juliana Paula F. de Oliveira, Mozart A. Fonseca and Leilson R. Bezerra
Ruminants 2024, 4(3), 433-447; https://doi.org/10.3390/ruminants4030031 - 7 Sep 2024
Viewed by 340
Abstract
This research evaluated the effects of energy supplementation on sheep’s feeding behavior, feed preference, and thermoregulatory responses using technical cashew nutshell liquid (CNSL) and different vegetable oils with different unsaturated fatty acid (UFA) compositions. The experiment was completely randomized with five treatments: a [...] Read more.
This research evaluated the effects of energy supplementation on sheep’s feeding behavior, feed preference, and thermoregulatory responses using technical cashew nutshell liquid (CNSL) and different vegetable oils with different unsaturated fatty acid (UFA) compositions. The experiment was completely randomized with five treatments: a mixture of CNSL (0.5%) + vegetable oils [canola (high in monounsaturated fatty acids—MUFA), and corn, soybean, sunflower, or cottonseed oil (high in polyunsaturated fatty acids-PUFA) at 1.5%] based on total diet dry matter, with eight replications. Forty uncastrated male sheep, with an average initial BW of 24.44 ± 1.5 kg, were evaluated for 70 days. The CNSL + vegetable oil blend did not affect DM and neutral detergent fiber (aNDF) intake (p > 0.05). However, diets with canola oil resulted in higher SFA intake (p < 0.05) than other oils. The canola oil + CNSL blend led to a higher intake of UFA and MUFA and lower PUFA intake than other oil blends (p < 0.05). Sheep fed canola oil ruminated fewer boli per day than those fed soybean and sunflower oils. Using three sieves (pef1.18) reflected in higher sheep aNDF intake. Respiratory frequency and surface temperature of sheep were lower before feeding than 3 h after, without effects of the type of oil. Higher serum creatinine and cholesterol levels were observed in sheep fed CNSL with corn and canola oils compared to other oils. Serum calcium was lower in sheep fed CNSL with soybean and canola compared to sunflower and corn. Including CNSL with vegetable oils with different FA compositions did not affect physiological and thermographic variables. However, sheep showed better diet selectivity and lower bolus rumination with higher MUFA (canola oil) content. Including CNSL with canola oil in sheep diets is recommended, as it increases dietary energy content, enhances diet selectivity, reduces PUFA intake, and does not impact animal health. Full article
(This article belongs to the Special Issue Feature Papers of Ruminants 2024–2025)
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<p>Averages of meteorological data: environmental temperature (AT), relative humidity (RH), black globe temperature in the sun (BGTsun), black globe temperature in the shade (BGTshade), black globe temperature and humidity index in the sun (BTGHsun) and in the shade (BTGHshade), before (0 h or at feeding moment) and 3 h after the feeding. (SEM = 7.86).</p>
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<p>Thermographic variables (maximum, minimum, and medium surface temperatures) selected in the left flank region of the sheep fed diets containing mixtures of 0.5% of cashew nut shell liquid (of total DM) and 1.5% of soybean (<b>a</b>), cottonseed (<b>b</b>), sunflower (<b>c</b>), corn (<b>d</b>), or (<b>e</b>) canola oil (of total DM).</p>
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11 pages, 13353 KiB  
Article
In Situ Studies on the Influence of Surface Symmetry on the Growth of MoSe2 Monolayer on Sapphire Using Reflectance Anisotropy Spectroscopy and Differential Reflectance Spectroscopy
by Yufeng Huang, Mengjiao Li, Zhixin Hu, Chunguang Hu, Wanfu Shen, Yanning Li and Lidong Sun
Nanomaterials 2024, 14(17), 1457; https://doi.org/10.3390/nano14171457 - 7 Sep 2024
Viewed by 302
Abstract
The surface symmetry of the substrate plays an important role in the epitaxial high-quality growth of 2D materials; however, in-depth and in situ studies on these materials during growth are still limited due to the lack of effective in situ monitoring approaches. In [...] Read more.
The surface symmetry of the substrate plays an important role in the epitaxial high-quality growth of 2D materials; however, in-depth and in situ studies on these materials during growth are still limited due to the lack of effective in situ monitoring approaches. In this work, taking the growth of MoSe2 as an example, the distinct growth processes on Al2O3 (112¯0) and Al2O3 (0001) are revealed by parallel monitoring using in situ reflectance anisotropy spectroscopy (RAS) and differential reflectance spectroscopy (DRS), respectively, highlighting the dominant role of the surface symmetry. In our previous study, we found that the RAS signal of MoSe2 grown on Al2O3 (112¯0) initially increased and decreased ultimately to the magnitude of bare Al2O3 (112¯0) when the first layer of MoSe2 was fully merged, which is herein verified by the complementary DRS measurement that is directly related to the film coverage. Consequently, the changing rate of reflectance anisotropy (RA) intensity at 2.5 eV is well matched with the dynamic changes in differential reflectance (DR) intensity. Moreover, the surface-dominated uniform orientation of MoSe2 islands at various stages determined by RAS was further investigated by low-energy electron diffraction (LEED) and atomic force microscopy (AFM). By contrast, the RAS signal of MoSe2 grown on Al2O3 (0001) remains at zero during the whole growth, implying that the discontinuous MoSe2 islands have no preferential orientations. This work demonstrates that the combination of in situ RAS and DRS can provide valuable insights into the growth of unidirectional aligned islands and help optimize the fabrication process for single-crystal transition metal dichalcogenide (TMDC) monolayers. Full article
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<p>MoSe<sub>2</sub> thin film growth on Al<sub>2</sub>O<sub>3</sub> (<math display="inline"><semantics> <mrow> <mn>11</mn> <mover accent="true"> <mrow> <mn>2</mn> </mrow> <mo>¯</mo> </mover> <mn>0</mn> </mrow> </semantics></math>) at 530 °C monitored using optical reflection measurement is schematically presented in (<b>a</b>). The setup allows the simultaneous determination of the RA and DR spectrum in real time during the growth. (<b>b</b>) Two-dimensional contour map of the RA signal over photon energy (the horizontal axis) and deposition time (the vertical axis). The RA spectra recorded at selected deposition times of <span class="html-italic">t<sub>a</sub></span>~31 min, <span class="html-italic">t<sub>b</sub></span>~47 min, <span class="html-italic">t<sub>c</sub></span>~63 min, <span class="html-italic">t<sub>d</sub></span>~87 min, and <span class="html-italic">t<sub>e</sub></span>~140 min (indicated by the horizontal dashed lines in (<b>b</b>)), are presented in (<b>c</b>), whereas the black dotted line represents the initial RA spectrum of bare Al<sub>2</sub>O<sub>3</sub> (<math display="inline"><semantics> <mrow> <mn>11</mn> <mover accent="true"> <mrow> <mn>2</mn> </mrow> <mo>¯</mo> </mover> <mn>0</mn> </mrow> </semantics></math>) substrate. The evolution of the RA intensity at 2.5 eV (along the vertical dashed line in (<b>b</b>)) is plotted in (<b>d</b>) as a function of deposition time (solid blue line). In a similar fashion, the corresponding DR spectra are exhibited, namely, 2D contour map for an overview in (<b>e</b>), spectra recorded at <span class="html-italic">t<sub>a</sub></span>, <span class="html-italic">t<sub>b</sub></span>, <span class="html-italic">t<sub>c</sub></span>, <span class="html-italic">t<sub>d</sub></span>, and <span class="html-italic">t<sub>e</sub></span> in (<b>f</b>), and the variation of the DR signals as a function of the deposition time at 2.3 eV and 3.1 eV in (<b>d</b>). The first derivative curve of the change in RA intensity at 2.5 eV is also shown in (<b>d</b>).</p>
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<p>(<b>a</b>) The band structure of monolayer MoSe<sub>2</sub> calculated by DFT. The arrows indicate the transition in C and D from the valance band to the conduction band. (<b>b</b>) The imaginary part of the calculated dielectric function for monolayer MoSe<sub>2</sub>. The main features are labeled as A to D. (<b>c</b>) Representative DR spectra recorded from the growth of MoSe<sub>2</sub> on Al<sub>2</sub>O<sub>3</sub> (<math display="inline"><semantics> <mrow> <mn>11</mn> <mover accent="true"> <mrow> <mn>2</mn> </mrow> <mo>¯</mo> </mover> <mn>0</mn> </mrow> </semantics></math>) surface. The dark circles and blue lines represent the Lorentz fit of DR spectra recorded at different times. (<b>d</b>) The evolutions of center energy and integral area of peaks C and D as a function of deposition time.</p>
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<p>LEED results of as-grown MoSe<sub>2</sub> sample. (<b>a</b>) LEED pattern of MoSe<sub>2</sub> thin film (after the deposition time of <span class="html-italic">t<sub>e</sub></span>) using an electron beam energy of 135 eV. (<b>b</b>) The line profiles (dotted lines) taken across the six first-order diffraction spots on LEED patterns (indicated by the arrowed gray circle in (<b>a</b>)) obtained after various deposition times of <span class="html-italic">t<sub>b</sub></span>, <span class="html-italic">t<sub>c</sub></span>, <span class="html-italic">t<sub>d</sub></span>, and <span class="html-italic">t<sub>e</sub></span>, respectively. The lines are normalized and offset for clarity. (<b>c</b>) The variation of the FWHM obtained by fitting the experimental profiles (solid lines) in (<b>b</b>) as a function of the deposition time.</p>
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<p>AFM images of MoSe<sub>2</sub> films obtained after deposition times from <span class="html-italic">t<sub>a</sub></span> to <span class="html-italic">t<sub>e</sub></span> are displayed in (<b>a</b>–<b>e</b>), respectively. The white circle in (<b>b</b>) represents the coalescence of islands. (<b>f</b>) Height profiles for the green line in (<b>c</b>), the red line in (<b>d</b>), and the blue line in (<b>e</b>).</p>
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<p>Real-time monitoring for the MBE growth of MoSe<sub>2</sub> layer on Al<sub>2</sub>O<sub>3</sub> (0001) substrate at 530 °C. (<b>a</b>) Two-dimensional contour map of the RA signal over photon energy (the horizontal axis) and deposition time (the vertical axis). (<b>b</b>) RA spectra recorded during the growth of MoSe<sub>2</sub> layer on the bare Al<sub>2</sub>O<sub>3</sub> (0001) surface (marked by black dot line) from the beginning to the end (marked by black solid line) of the growth process. The time interval is about 5 min. The evolution of the RA intensity at 2.5 eV (along the vertical dashed line in (<b>a</b>)) as a function of the deposition time is plotted in (<b>c</b>) (solid green line). The inset shows the LEED pattern of MoSe<sub>2</sub> measured at an electron energy of 135 eV. The corresponding 2D contour map of DRS, the DR spectra over photon energy with about 5 min interval, and the evolution of DR intensity at 2.4 eV and 3.0 eV are shown in (<b>c</b>–<b>e</b>), respectively. (<b>f</b>) The corresponding Raman spectrum and the AFM image. The green curve represents the height profile across the green line.</p>
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21 pages, 7794 KiB  
Article
Spatial–Temporal Variations and Driving Factors of the Albedo of the Qilian Mountains from 2001 to 2022
by Huazhu Xue, Haojie Zhang, Zhanliang Yuan, Qianqian Ma, Hao Wang and Zhi Li
Atmosphere 2024, 15(9), 1081; https://doi.org/10.3390/atmos15091081 - 6 Sep 2024
Viewed by 245
Abstract
Surface albedo plays a pivotal role in the Earth’s energy balance and climate. This study conducted an analysis of the spatial distribution patterns and temporal evolution of albedo, normalized difference vegetation index (NDVI), normalized difference snow index snow cover (NSC), and land surface [...] Read more.
Surface albedo plays a pivotal role in the Earth’s energy balance and climate. This study conducted an analysis of the spatial distribution patterns and temporal evolution of albedo, normalized difference vegetation index (NDVI), normalized difference snow index snow cover (NSC), and land surface temperature (LST) within the Qilian Mountains (QLMs) from 2001 to 2022. This study evaluated the spatiotemporal correlations of albedo with NSC, NDVI, and LST at various temporal scales. Additionally, the study quantified the driving forces and relative contributions of topographic and natural factors to the albedo variation of the QLMs using geographic detectors. The findings revealed the following insights: (1) Approximately 22.8% of the QLMs exhibited significant changes in albedo. The annual average albedo and NSC exhibited a minor decline with rates of −0.00037 and −0.05083 (Sen’s slope), respectively. Conversely, LST displayed a marginal increase at a rate of 0.00564, while NDVI experienced a notable increase at a rate of 0.00178. (2) The seasonal fluctuations of NSC, LST, and vegetation collectively influenced the overall albedo changes in the Qilian Mountains. Notably, the highly similar trends and significant correlations between albedo and NSC, whether in intra-annual monthly variations, multi-year monthly anomalies, or regional multi-year mean trends, indicate that the changes in snow albedo reflected by NSC played a major role. Additionally, the area proportion and corresponding average elevation of PSI (permanent snow and ice regions) slightly increased, potentially suggesting a slow upward shift of the high mountain snowline in the QLMs. (3) NDVI, land cover type (LCT), and the Digital Elevation Model (DEM, which means elevation) played key roles in shaping the spatial pattern of albedo. Additionally, the spatial distribution of albedo was most significantly influenced by the interaction between slope and NDVI. Full article
(This article belongs to the Special Issue Vegetation and Climate Relationships (3rd Edition))
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<p>Geographic location and elevation of the QLMs.</p>
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<p>(<b>a</b>) Slope, (<b>b</b>) aspect, and (<b>c</b>) land cover types of the QLMs (the explanation of the abbreviation is included in <a href="#atmosphere-15-01081-t001" class="html-table">Table 1</a>).</p>
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<p>The multi-year average (<b>a</b>) albedo, (<b>b</b>) NSC, (<b>c</b>) NDVI, and (<b>d</b>) LST.</p>
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<p>Trends in the annual average albedo of the QLMs from 2001 to 2022 in relation to (<b>a</b>) annual average NSC, (<b>b</b>) annual average NDVI, (<b>c</b>) annual average LST; (<b>d</b>) trends in the average elevation and area percentage of PSI regions in the QLMs.</p>
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<p>The spatial distribution of significant or non-significant changes in (<b>a</b>) albedo, (<b>b</b>) NSC, (<b>c</b>) NDVI, and (<b>d</b>) LST in the QLMs from 2001 to 2022.</p>
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<p>Comparison of the multi-year monthly average values of albedo with (<b>a</b>) NSC, (<b>b</b>) NDVI, and (<b>c</b>) LST in the QLM region from 2001 to 2022.</p>
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<p>Monthly albedo anomalies (<b>a</b>) and monthly NSC anomalies, (<b>b</b>) and monthly NDVI anomalies, (<b>c</b>) and monthly LST anomalies in the QLMs from 2001 to 2022.</p>
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<p>(<b>a</b>–<b>e</b>) Changes in explanatory power (q values) in 2001, 2006, 2011, 2016, and 2021.</p>
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<p>Striking differences in the driving factors (At a confidence level of 95%, “Y” indicates a significant difference in the spatial distribution of albedo due to the two factors, while “N” indicates the opposite).</p>
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<p>(<b>a</b>–<b>e</b>) Changes in interactive explanatory power (q values) in 2001, 2006, 2011, 2016, and 2021; (<b>f</b>) average interactive explanatory power (q values) of 5 years (Bi: Enhance, bivariate, ENL: Enhance, nonlinear. The annotations inside parentheses indicate a higher frequency of occurrence of interaction types within five years. Without annotations, it indicates that the interaction types remained consistent over the 5 years).</p>
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25 pages, 5696 KiB  
Article
A Space Object Optical Scattering Characteristics Analysis Model Based on Augmented Implicit Neural Representation
by Qinyu Zhu, Can Xu, Shuailong Zhao, Xuefeng Tao, Yasheng Zhang, Haicheng Tao, Xia Wang and Yuqiang Fang
Remote Sens. 2024, 16(17), 3316; https://doi.org/10.3390/rs16173316 - 6 Sep 2024
Viewed by 303
Abstract
The raw data from ground-based telescopic optical observations serve as a key foundation for the analysis and identification of optical scattering properties of space objects, providing an essential guarantee for object identification and state prediction efforts. In this paper, a spatial object optical [...] Read more.
The raw data from ground-based telescopic optical observations serve as a key foundation for the analysis and identification of optical scattering properties of space objects, providing an essential guarantee for object identification and state prediction efforts. In this paper, a spatial object optical characterization model based on Augmented Implicit Neural Representations (AINRs) is proposed. This model utilizes a neural implicit function to delineate the relationship between the geometric observation model and the apparent magnitude arising from sunlight reflected off the object’s surface. Combining the dual advantages of data-driven and physical-driven, a novel pre-training procedure method based on transfer learning is designed. Taking omnidirectional angle simulation data as the basic training dataset and further introducing it with real observational data from ground stations, the Multi-Layer Perceptron (MLP) parameters of the model undergo constant refinement. Pre-fitting experiments on the newly developed S−net, R−net, and F−net models are conducted with a quantitative analysis of errors and a comparative assessment of evaluation indexes. The experiment demonstrates that the proposed F−net model consistently maintains a prediction error for satellite surface magnitude values within 0.2 mV, outperforming the other two models. Additionally, preliminary accomplishment of component-level recognition has been achieved, offering a potent analytical tool for on-orbit services. Full article
(This article belongs to the Section Satellite Missions for Earth and Planetary Exploration)
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Graphical abstract

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<p>Schematic diagram of the relative geometric relationship and coordinate transformation between the Sun, the satellite, and the probe.</p>
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<p>Diagram of the AINRs model and the mapping relationships for geometric and photometric transformations. According to the star maps captured by the ground-based telescope, the red squares indicate the space objects matched using the AINR model.</p>
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<p>Diagram of the solid angle and a locally enlarged view showing the relationship between the solid angle and the surface element.</p>
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<p>Schematic diagram of the ray geometry transformations and divergence, where <math display="inline"><semantics> <mrow> <mstyle mathvariant="bold" mathsize="normal"> <mi>p</mi> </mstyle> <mo>=</mo> <mo stretchy="false">(</mo> <mstyle mathvariant="bold" mathsize="normal"> <mi>s</mi> </mstyle> <mo>,</mo> <mstyle mathvariant="bold" mathsize="normal"> <mi>d</mi> </mstyle> <mo stretchy="false">)</mo> </mrow> </semantics></math> is considered as the geometric observation model, <math display="inline"><semantics> <mi>ω</mi> </semantics></math> as the solid angle, <math display="inline"><semantics> <mrow> <msub> <mi>L</mi> <mi>s</mi> </msub> </mrow> </semantics></math> as the incident radiance, and <math display="inline"><semantics> <mrow> <msub> <mi>L</mi> <mi>d</mi> </msub> </mrow> </semantics></math> as the reflected radiance.</p>
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<p>Schematic diagram of MLP architecture.</p>
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<p>Schematic diagram of the pre-training process based on TL and optical scattering characteristics analysis of space objects.</p>
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<p>Flowchart of the Algorithmic Process for Photometric Calculations of Complex Space Objects Based on Omnidirectional Angles.</p>
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<p>When predicting the curve using only 4D angular data as input, anomalous phenomena such as “jumps” and “sharp increases” may occur. By time information, they can be listed as: (<b>a</b>) 18 February 2024; (<b>b</b>) 21 February 2024; (<b>c</b>) 27 February 2024; (<b>d</b>) 19 April 2024.</p>
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<p>S−net model projections across selected dates. The temporal distribution of the data is detailed as follows: (<b>a</b>) 18 February 2024; (<b>b</b>) 19 February 2024; (<b>c</b>) 21 February 2024; (<b>d</b>) 19 April 2024.</p>
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<p>R−net model projections across selected dates. The data are presented chronologically as follows: (<b>a</b>) 18 February 2024; (<b>b</b>) 19 February 2024; (<b>c</b>) 21 February 2024; (<b>d</b>) 19 April 2024.</p>
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<p>F−net model projections across selected dates. The data are presented chronologically: (<b>a</b>) 18 February 2024; (<b>b</b>) 19 February 2024; (<b>c</b>) 21 February 2024; (<b>d</b>) 19 April 2024.</p>
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<p>The KDE scatter plots for the three models. The models are categorized as follows: (<b>a</b>) S−net; (<b>b</b>) R−net; (<b>c</b>) F−net.</p>
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21 pages, 16002 KiB  
Article
Comparative Studies on Nanocellulose as a Bio-Based Consolidating Agent for Ancient Wood
by Anastasia Fornari, Daniele Rocco, Leonardo Mattiello, Martina Bortolami, Marco Rossi, Laura Bergamonti, Claudia Graiff, Stefania Bani, Fabio Morresi and Fabiana Pandolfi
Appl. Sci. 2024, 14(17), 7964; https://doi.org/10.3390/app14177964 - 6 Sep 2024
Viewed by 285
Abstract
In this work, nanocellulose aqueous dispersions were studied as a bio-inspired consolidating agent for the recovery and conservation of ancient wood and compared with two of the most used traditional consolidants: the synthetic resins Paraloid B-72 and Regalrez 1126. The morphology of crystalline [...] Read more.
In this work, nanocellulose aqueous dispersions were studied as a bio-inspired consolidating agent for the recovery and conservation of ancient wood and compared with two of the most used traditional consolidants: the synthetic resins Paraloid B-72 and Regalrez 1126. The morphology of crystalline nanocellulose (CNC), determined using Scanning Electron Microscopy (SEM), presents with a rod-like shape, with a size ranging between 15 and 30 nm in width. Chemical characterization performed using the Fourier-Transform Infrared Spectroscopy (FT-IR) technique provides information on surface modifications, in this case, demonstrating the presence of only the characteristic peaks of nanocellulose. Moreover, conductometric, pH, and dry matter measurements were carried out, showing also in this case values perfectly conforming to what is found in the literature. The treated wood samples were observed under an optical microscope in reflected light and under a scanning electron microscope to determine, respectively, the damage caused by xylophages and the morphology of the treated surfaces. The images acquired show the greater similarity of the surfaces treated with nanocellulose to untreated wood, compared with other consolidating agents. Finally, a colorimetric analysis of these samples was also carried out before and after a first consolidation treatment, and after a second treatment carried out on the same samples three years later. The samples treated with CNC appeared very homogeneous and uniform, without alterations in their final color appearance, compared to other traditional synthetic products. Full article
(This article belongs to the Special Issue Advanced Technologies in Cultural Heritage)
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<p>SEM micrograph of CNC.</p>
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<p>FTIR spectrum of CNC.</p>
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<p>Wood samples treated with CNC (A), Paraloid B-72 (B), and Regalrez 1126 (C), and samples untreated (NT) during the processes of impregnation: (<b>1</b>) before treatment; (<b>2</b>) immediately after; (<b>3</b>) after 19 h; and (<b>4</b>) after 50 days.</p>
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<p>Detailed images of samples treated with (<b>a</b>) CNC, (<b>b</b>) Paraloid B-72, and (<b>c</b>) Regalrez 1126, immediately after application.</p>
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<p>Reflected light microscope images of samples that were not-treated (NT) and those treated with CNC (A), Paraloid B-72 (B), and Regalrez 1126 (C). Images with UV light and 5× magnification (<b>a</b>,<b>c</b>,<b>e</b>,<b>g</b>); images with visible light and 2.5× magnification (<b>b</b>,<b>d</b>,<b>f</b>,<b>h</b>). White arrows indicate in all samples the signs of degradation due to the action of xylophagous insects.</p>
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<p>Reflectance spectra of untreated (NT) and treated samples (CNC, Paraloid B-72, Regalrez 1126), acquired in SCI and SCE mode 24 h after the consolidation treatment.</p>
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<p>Reflectance spectra of untreated (NT) and treated samples (CNC, Paraloid B-72, Regalrez 1126), acquired in SCI and SCE mode, one month after the consolidation treatment.</p>
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<p>Reflectance spectra of untreated (NT) and treated samples (CNC, Paraloid B-72, Regalrez 1126), acquired in SCI and SCE mode, three years after the first consolidating treatment.</p>
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<p>Reflectance spectra of untreated (NT) and treated samples (CNC, Paraloid B-72, Regalrez 1126), acquired in SCI and SCE mode, one week after the second consolidating treatment, carried out three years after the first treatment.</p>
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<p>SEM images of untreated wood sample; cross section in correspondence of a woodworm hole (<b>a</b>); longitudinal sections (<b>b</b>,<b>c</b>); magnification of a fiber channel (<b>c</b>).</p>
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<p>SEM images of untreated sample (<b>1</b>) and of the consolidant coating films of CNC (<b>2</b>), Paraloid B-72 (<b>3</b>), and Regalrez 1126 (<b>4</b>).</p>
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<p>SEM images of longitudinal section of wood samples, where it is possible to see the fibers channels: untreated sample (<b>1</b>); sample treated with CNC (<b>2</b>), Paraloid B-72 (<b>3</b>), Regalrez 1126 (<b>4</b>).</p>
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