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17 pages, 5549 KiB  
Article
Fatigue Damage Monitoring of Composite Structures Based on Lamb Wave Propagation and Multi-Feature Fusion
by Feiting Zhang, Kaifu Zhang, Hui Cheng, Dongyue Gao and Keyi Cai
J. Compos. Sci. 2024, 8(10), 423; https://doi.org/10.3390/jcs8100423 (registering DOI) - 14 Oct 2024
Viewed by 157
Abstract
To address the challenges associated with fatigue damage monitoring in load-bearing composite structures, we developed a method that utilizes Lamb wave propagation and partial least squares regression (PLSR) for effective monitoring. Initially, we extracted diverse characteristics from both the time and frequency domains [...] Read more.
To address the challenges associated with fatigue damage monitoring in load-bearing composite structures, we developed a method that utilizes Lamb wave propagation and partial least squares regression (PLSR) for effective monitoring. Initially, we extracted diverse characteristics from both the time and frequency domains of the Lamb wave signal to capture the essence of the damage. Subsequently, we constructed a PLSR model, leveraging Lamb wave multi-feature fusion, specifically tailored for in-service fatigue damage monitoring. The efficacy of our proposed approach in quantitatively monitoring fatigue damage was thoroughly validated through rigorous standard fatigue tests. In practical applications, our model effectively mitigated the impact of multicollinearity among feature variables on model accuracy. Furthermore, the PLSR model demonstrated superior accuracy compared to the PCR model, given an equal number of principal components. To strike a harmonious balance between efficiency and precision, we optimized the size of the feature variable. The results show that the optimized PLSR model achieved an R-squared value exceeding 97% in predicting the in-service damage area. This underscores the robustness and reliability of our method in accurately monitoring fatigue damage in load-bearing composite structures. Full article
(This article belongs to the Special Issue Advances in Continuous Fiber Reinforced Thermoplastic Composites)
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<p>Flowchart of structural fatigue damage prediction based on Lamb wave signal and PLSR.</p>
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<p>Schematic diagram of the fatigue test specimen and sensor network.</p>
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<p>Test results of the test X-ray under different cycles.</p>
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<p>Fatigue damage expansion trend of a typical specimen.</p>
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<p>Time domain signal and frequency domain signal of representative paths under different cycle loading numbers.</p>
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<p>Multi-collinearity matrix of typical path signal features.</p>
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<p>Principal component contribution rate.</p>
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<p>Observed–fitted response maps of the PLSR and PCR models (five components).</p>
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<p>Percentage variance explained of PLSR and PCR models under different numbers of components.</p>
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<p>Observed–fitted response maps of the PLSR and PCR models (ten components).</p>
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<p>Comparison of prediction results of damage size values in the test set.</p>
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<p>VIP scores of signal features for the PLSR regression model (the × symbol represents the VIP score of the signal feature, and the circle represents the feature whose VIP score is close to or greater than 1, that is, the selected feature value).</p>
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<p>Comparison of the optimization model prediction results of damage size values.</p>
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32 pages, 940 KiB  
Article
Modeling and Optimization of the Inland Container Transportation Problem Considering Multi-Size Containers, Fuel Consumption, and Carbon Emissions
by Yujian Song and Yuting Zhang
Processes 2024, 12(10), 2231; https://doi.org/10.3390/pr12102231 (registering DOI) - 13 Oct 2024
Viewed by 418
Abstract
This paper investigates the inland container transportation problem with a focus on multi-size containers, fuel consumption, and carbon emissions. To reflect a more realistic situation, the depot’s initial inventory of empty containers is also taken into consideration. To linearly model the constraints imposed [...] Read more.
This paper investigates the inland container transportation problem with a focus on multi-size containers, fuel consumption, and carbon emissions. To reflect a more realistic situation, the depot’s initial inventory of empty containers is also taken into consideration. To linearly model the constraints imposed by the multiple container sizes and the limited number of empty containers, a novel graphical representation is presented for the problem. Based on the graphical representation, a mixed-integer programming model is presented to minimize the total transportation cost, which includes fixed, fuel, and carbon emission costs. To efficiently solve the model, a tailored branch-and-price algorithm is designed, which is enhanced by improvement schemes including a heuristic label-setting algorithm, decremental state-space relaxation, and the introduction of a high-quality upper bound. Results from a series of computational experiments on randomly generated instances demonstrate that (1) the proposed branch-and-price algorithm demonstrates a superior performance compared to the tabu search algorithm and the genetic algorithm; (2) each additional empty container in the depot reduces the total transportation cost by less than 1%, with a diminishing marginal effect; (3) the rational configuration of different types of trucks improves scheduling flexibility and reduces fuel and carbon emission costs as well as the overall transportation cost; and (4) extending customer time windows also contributes to lower the total transportation cost. These findings not only deepen the theoretical understanding of inland container transportation optimization but also provide valuable insights for logistics companies and policymakers to improve efficiency and implement more sustainable operational practices. Additionally, our research paves the way for future investigations into the integration of dynamic factors and emerging technologies in this field. Full article
(This article belongs to the Section Sustainable Processes)
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<p>The flowchart of this paper.</p>
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<p>Visualization of transportation operations for 20 ft containers.</p>
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<p>An illustrative example.</p>
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<p>Node definitions for container transportation requests.</p>
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<p>Nodes representing empty container storage and retrieval from the depot.</p>
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<p>Workflow diagram for the proposed branch-and-price algorithm.</p>
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<p>Time window branching.</p>
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<p>Comparison of Gap values for different algorithms.</p>
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<p>Relationship between total cost and the initial number of 40 ft empty containers at the depot.</p>
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<p>Heatmap of total transportation cost under different truck fleet configurations.</p>
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<p>Heatmap of fuel and carbon emission costs under different truck fleet configurations.</p>
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<p>Relationship between time window length and costs.</p>
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29 pages, 13487 KiB  
Article
Real-Time Tracking Target System Based on Kernelized Correlation Filter in Complicated Areas
by Abdel Hamid Mbouombouo Mboungam, Yongfeng Zhi and Cedric Karel Fonzeu Monguen
Sensors 2024, 24(20), 6600; https://doi.org/10.3390/s24206600 (registering DOI) - 13 Oct 2024
Viewed by 299
Abstract
The achievement of rapid and reliable image object tracking has long been crucial and challenging for the advancement of image-guided technology. This study investigates real-time object tracking by offering an image target based on nuclear correlation tracking and detection methods to address the [...] Read more.
The achievement of rapid and reliable image object tracking has long been crucial and challenging for the advancement of image-guided technology. This study investigates real-time object tracking by offering an image target based on nuclear correlation tracking and detection methods to address the challenge of real-time target tracking in complicated environments. In the tracking process, the nuclear-related tracking algorithm can effectively balance the tracking performance and running speed. However, the target tracking process also faces challenges such as model drift, the inability to handle target scale transformation, and target length. In order to propose a solution, this work is organized around the following main points: this study dedicates its first part to the research on kernelized correlation filters (KCFs), encompassing model training, object identification, and a dense sampling strategy based on a circulant matrix. This work developed a scale pyramid searching approach to address the shortcoming that a KCF cannot forecast the target scale. The tracker was expanded in two stages: the first stage output the target’s two-dimensional coordinate location, and the second stage created the scale pyramid to identify the optimal target scale. Experiments show that this approach is capable of resolving the target size variation problem. The second part improved the KCF in two ways to meet the demands of a long-term object tracking task. This article introduces the initial object model, which effectively suppresses model drift. Secondly, an object detection module is implemented, and if the tracking module fails, the algorithm is redirected to the object detection module. The target detection module utilizes two detectors, a variance classifier and a KCF. Finally, this work includes trials on object tracking experiments and subsequent analysis of the results. Initially, this research provides a tracking algorithm assessment system, including an assessment methodology and the collection of test videos, which helped us to determine that the suggested technique outperforms the KCF tracking method. Additionally, the implementation of an evaluation system allows for an objective comparison of the proposed algorithm with other prominent tracking methods. We found that the suggested method outperforms others in terms of its accuracy and resilience. Full article
(This article belongs to the Section Sensing and Imaging)
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<p>Typical target tracker composition [<a href="#B16-sensors-24-06600" class="html-bibr">16</a>].</p>
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<p>Function mapping the original linearly inseparable data to the linearly separable high-dimensional space [<a href="#B12-sensors-24-06600" class="html-bibr">12</a>].</p>
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<p>PA algorithm method’s flow.</p>
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<p>Cycle shift (one dimension).</p>
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<p>Cyclic shifting training samples.</p>
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<p>Typical correlation filter tracking algorithm flow.</p>
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<p>KCF tracking with target scale changing.</p>
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<p>KCF tracking of the PSR in a sequence of low-level images of Dudek’s facial expressions.</p>
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<p>KCF tracking of the PSR in a sequence of low-level images of Dudek’s facial expressions.</p>
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<p>Stage detectors for a variance classifier applied to an image to obtain and filter background information.</p>
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<p>Flow chart of tracking algorithm combined with detection.</p>
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<p>Schematic diagram of CLE and overlap of the tracking effect in a single frame.</p>
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<p>(<b>a</b>) Attribute distribution of the entire test set and (<b>b</b>) distribution of the sequences in terms of the occlusion (OCC) attribute [<a href="#B20-sensors-24-06600" class="html-bibr">20</a>].</p>
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<p>Results of tracking experiment carried out on two test video sets: (<b>a</b>) precision plot of OPE and (<b>b</b>) success plot of OPE.</p>
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<p>Results of tracking experiment carried out on two test video sets: (<b>a</b>) precision plot of TRE and (<b>b</b>) success plot of TRE.</p>
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<p>Results of tracking experiment carried out on two test video sets: (<b>a</b>) precision plot of SRE and (<b>b</b>) success plots of SRE.</p>
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<p>Tracking process with the center location error (CLE) and overlap distribution.</p>
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<p>Effect in tracking a video set of Sylvester.</p>
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<p>Results of tracking process on Sylvester videos in terms of CLE (<b>left</b>) and overlap distribution (<b>right</b>).</p>
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<p>Tracking results of two trackers (the KCF and ours) on Tiger2.</p>
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<p>Tiger2 tracking results in terms of CLE in tracking process (<b>a</b>) and overlap distribution (<b>b</b>).</p>
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<p>Results of OPE of the tracking algorithms on 50 video collections: (<b>a</b>) precision plot of OPE and (<b>b</b>) success plot of OPE.</p>
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<p>Results of TRE of the tracking algorithms on 50 video collections: (<b>a</b>) precision plot of TRE and (<b>b</b>) success plot of TRE.</p>
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<p>Results of SRE of the tracking algorithms on 50 video collections: (<b>a</b>) precision plot of SRE and (<b>b</b>) success plot of SRE.</p>
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<p>OPE of tracking algorithms on target scale variation sets: (<b>a</b>) precision plot of OPE and (<b>b</b>) success plot of OPE.</p>
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<p>TRE of tracking algorithms on target scale variation sets: (<b>a</b>) precision plot of TRE and (<b>b</b>) success plot of TRE.</p>
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<p>SRE of tracking algorithms on target scale variation sets: (<b>a</b>) precision plots of SRE and (<b>b</b>) success plot of SRE.</p>
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<p>Tracking algorithms on the target occlusion video sets: (<b>a</b>) precision plot of OPE and (<b>b</b>) success plot of OPE.</p>
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<p>Tracking algorithms on the target occlusion video sets: (<b>a</b>) precision plot of TRE and (<b>b</b>) success plot of TRE.</p>
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<p>Tracking algorithms on the target occlusion video set: (<b>a</b>) precision plot of SRE and (<b>b</b>) success plot of SRE.</p>
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<p>The tracking algorithms on the test set with the target out of view: (<b>a</b>) precision plot of OPE and (<b>b</b>) success plot of OPE.</p>
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<p>The tracking algorithms on the test set with the target out of view: (<b>a</b>) precision plot of TRE and (<b>b</b>) success plot of TRE.</p>
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<p>The tracking algorithms on the test set with the target out of view: (<b>a</b>) precision plot of SRE and (<b>b</b>) success plot of SRE.</p>
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17 pages, 10026 KiB  
Article
Tailoring of Ultrasmall NiMnO3 Nanoparticles: Optimizing Synthesis Conditions and Solvent Effects
by Svetlana Saikova, Diana Nemkova, Anton Krolikov, Aleksandr Pavlikov, Mikhail Volochaev, Aleksandr Samoilo, Timur Ivanenko and Artem Kuklin
Molecules 2024, 29(20), 4846; https://doi.org/10.3390/molecules29204846 (registering DOI) - 13 Oct 2024
Viewed by 370
Abstract
Nickel manganese oxide (NiMnO3) combines magnetic and dielectric properties, making it a promising material for sensor and supercapacitor applications, as well as for catalytic water splitting. The efficiency of its utilization is notably influenced by particle size. In this study, we [...] Read more.
Nickel manganese oxide (NiMnO3) combines magnetic and dielectric properties, making it a promising material for sensor and supercapacitor applications, as well as for catalytic water splitting. The efficiency of its utilization is notably influenced by particle size. In this study, we investigate the influence of thermal treatment parameters on the phase composition of products from alkali co-precipitation of nickel and manganese (II) ions and identify optimal conditions for synthesizing phase-pure nickel manganese oxide. Ultrafine nanoparticles of NiMnO3 (with sizes as small as 2 nm) are obtained via liquid-phase ultrasonic dispersion, exhibiting a narrow size distribution. A systematic exploration of the solvent nature (water, N-methyl-2-pyrrolidone, dimethyl sulfoxide, dimethylformamide) on the efficiency of ultrasonic dispersion of NiMnO3 nanoparticles is provided. It is demonstrated that particle size is influenced not only by absorbed acoustic power, dependent on the physical properties of the used solvent (boiling temperature, gas solubility, viscosity, density) but also by the chemical stability of the solvent under prolonged ultrasonic treatment. Our findings provide insights for designing ultrasonic treatment protocols for nanoparticle dispersions with tailored particle sizes. Full article
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<p>Atomic structure of NiMnO<sub>3</sub>. The unit cell is depicted by dashed lines. Nickel, oxygen, and manganese atoms are represented by gray, red, and violet colors, respectively.</p>
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<p>Thermogravimetry and differential scanning calorimetry (TG−DSC) curves (<b>a</b>) and X-ray diffraction pattern of the NiMnO<sub>3</sub> precursor (<b>b</b>) annealed at different annealing temperatures (for 3 h) and annealed for different times: (<b>c</b>) at 450 °C; (<b>d</b>) at 600 °C +—NiMnO<sub>3</sub>, * NiMn<sub>2</sub>O<sub>4</sub>, □ NiO, ◊ Mn<sub>2</sub>O<sub>3</sub>, ○ Ni<sub>6</sub>MnO<sub>8</sub>, # MnO<sub>2</sub>, ♦ Ni(OH)<sub>2</sub>*NiOOH, ▲ MnOOH, ■ Mn<sub>3</sub>O<sub>4</sub>.</p>
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<p>Morphological characterizations and physical properties of NiMnO<sub>3</sub> nanoparticles: (<b>a</b>) low-resolution TEM image; (<b>b</b>–<b>d</b>) diagrams of the size distribution of spherical (<b>b</b>) and rod-shaped (<b>c</b>,<b>d</b>) nanoparticles; (<b>e</b>) SEM image; (<b>f</b>) UV–Vis spectra.</p>
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<p>TEM images and diagrams of the size distribution of (<b>a</b>,<b>b</b>) NiMnO<sub>3</sub>-NMP; (<b>c</b>,<b>d</b>) NiMnO<sub>3</sub>-DMSO; (<b>e</b>,<b>f</b>) NiMnO<sub>3</sub>-DMF; (<b>g</b>,<b>h</b>) NiMnO<sub>3</sub>-H<sub>2</sub>O.</p>
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<p>FT−IR-spectra of DMSO, DMF and NMP before and after US treatment of NiMnO<sub>3</sub> in the spectral region of 4000–500 cm<sup>−1</sup>.</p>
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<p>1H (<b>a</b>) and 13C (<b>b</b>) NMR spectra of NMP before (bottom line) and after (top line) ultrasound treatment; 1H-1H-DQF-COSY (<b>c</b>) and 1H-13C-HMBC (<b>d</b>) NMR spectra for NMP.</p>
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<p>UV–Vis spectra of nanoparticles (nps) and solvents after heating (H) and ultrasound treatment (US) (recorded with pure DMSO or NMP as a reference) for (<b>a</b>) NMP, (<b>b</b>) DMSO, (<b>c</b>) DMF and (<b>d</b>) H<sub>2</sub>O; (<b>e</b>) UV–Vis spectra of pure solvents (recorded with empty cuvette as a reference).</p>
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<p>UV-vis spectra of Al sols (<b>a</b>). Histogram showing foil mass loss (<b>b</b>). Photos displaying Tyndall effect (<b>c</b>–<b>f</b>) for precipitates in: (<b>c</b>)—DMF, (<b>d</b>)—DMSO, (<b>e</b>)—NMP, (<b>f</b>)—H<sub>2</sub>O. Particle sizes in precipitates determined by DLS method (<b>g</b>).</p>
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19 pages, 4730 KiB  
Article
Inversion of Crop Water Content Using Multispectral Data and Machine Learning Algorithms in the North China Plain
by Zhenghao Zhang, Gensheng Dou, Xin Zhao, Yang Gao, Saisai Liu and Anzhen Qin
Agronomy 2024, 14(10), 2361; https://doi.org/10.3390/agronomy14102361 (registering DOI) - 13 Oct 2024
Viewed by 258
Abstract
(1) Background: Accurate inversion of crop water content is key to making an intelligent irrigation decision. However, little effort has been devoted to accurately estimating the crop water content of winter wheat in the North China Plain. (2) Method: The crop water content [...] Read more.
(1) Background: Accurate inversion of crop water content is key to making an intelligent irrigation decision. However, little effort has been devoted to accurately estimating the crop water content of winter wheat in the North China Plain. (2) Method: The crop water content of winter wheat was measured at jointing, flowering and grain-filling stages, respectively. UAV-based multispectral remote sensing images were used to calculate thirteen vegetation indices, including SAVI, EVI, R-M, NDRE, OSAVI, GOSAVI, REOSAVI, GBNDVI, NDVI, RVI, DVI, GNDVI, and TVI. Five machine learning (ML) algorithms (i.e., MLR, RF, PLSR, ElasticNet, and ridge regression) were adopted to estimate the crop water content of winter wheat at the three growth stages. The benchmark datasets, which include CWC as well as vegetation indices calculated based on spectral indices, were adopted to validate the performance of the ML models. (3) Results: The correlation coefficients ranged from 0.64 to 0.82 at different growth stages. The optimal vegetation indices were GNDVI for the jointing stage, NDRE for the flowering and the grain-filling stage, respectively. Among the five machine learning methods, random forest (RF) showed the best performance across the three growth stages, with its coefficient of determination (R2) of 0.80, or an increase by 20.1% than those of other models. In addition, the RMSE and RPD of the RF model at the flowering stage were 3.00% and 2.01, which significantly outperformed other models and growth stages. (4) Conclusion: This study may provide theoretical support and technical guidance for monitoring current water status in wheat crops, which is useful to develop a precise irrigation prescription map for local farmers. (5) Limitation: The main limitation of this study is that the sample size is relatively small and may not fully reflect the characteristics of the target groups. At the same time, subjectivity and bias may exist in the data collection, which may have a certain impact on the accuracy of the results. Future studies could consider expanding sample sizes and improving data collection methods to overcome these limitations. Full article
(This article belongs to the Special Issue Plant–Water Relationships for Sustainable Agriculture)
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<p>The schematic map of the experimental station and the experimental plots at the station.</p>
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<p>The specific flowchart of data analysis and processing using different vegetation indices and machine learning algorithms.</p>
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<p>Correlation analysis between crop water content (%) and vegetation indices at (<b>A</b>) jointing, (<b>B</b>) flowering, and (<b>C</b>) filling stages of winter wheat in 2024.</p>
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<p>Vegetation index maps of (<b>A</b>) DVI, (<b>B</b>) EVI, (<b>C</b>) GBNDVI, (<b>D</b>) GNDVI, (<b>E</b>) GOSAVI, (<b>F</b>) NDRE, (<b>G</b>) NDVI, (<b>H</b>) OSAVI, (<b>I</b>) REOSAVI, (<b>J</b>) R-M, (<b>K</b>) RVI, (<b>L</b>) SAVI, and (<b>M</b>) TVI at the flowering stage of winter wheat in 2024.</p>
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<p>Vegetation index maps of (<b>A</b>) DVI, (<b>B</b>) EVI, (<b>C</b>) GBNDVI, (<b>D</b>) GNDVI, (<b>E</b>) GOSAVI, (<b>F</b>) NDRE, (<b>G</b>) NDVI, (<b>H</b>) OSAVI, (<b>I</b>) REOSAVI, (<b>J</b>) R-M, (<b>K</b>) RVI, (<b>L</b>) SAVI, and (<b>M</b>) TVI at the flowering stage of winter wheat in 2024.</p>
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<p>Correlation analysis between measured crop water content (CWC, %) and predicted CWC based on (<b>A</b>) ridge regression, (<b>B</b>) multiple linear regression (MLR), (<b>C</b>) partial least squares regression (PLSR), (<b>D</b>) ElasticNet regression, and (<b>E</b>) random forest (RF) models at the jointing stage of winter wheat in 2024. The dashed lines are 1:1 lines.</p>
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<p>Correlation analysis between measured crop water content (CWC, %) and predicted CWC based on (<b>A</b>) ridge regression, (<b>B</b>) multiple linear regression (MLR), (<b>C</b>) partial least squares regression (PLSR), (<b>D</b>) ElasticNet regression, and (<b>E</b>) random forest (RF) models at the flowering stage of winter wheat in 2024. The dashed lines are 1:1 lines.</p>
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<p>Correlation analysis between measured crop water content (CWC, %) and predicted CWC based on (<b>A</b>) ridge regression, (<b>B</b>) multiple linear regression (MLR), (<b>C</b>) partial least squares regression (PLSR), (<b>D</b>) ElasticNet regression, and (<b>E</b>) random forest (RF) models at the filling stage of winter wheat in 2024. The dashed lines are 1:1 lines.</p>
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<p>Inversion maps of crop water content in winter wheat at (<b>A</b>) the jointing stage based on GNDVI, and (<b>B</b>) the flowering stage based on NDRE using RF model.</p>
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21 pages, 4007 KiB  
Article
Lightweight Detection of Broccoli Heads in Complex Field Environments Based on LBDC-YOLO
by Zhiyu Zuo, Sheng Gao, Haitao Peng, Yue Xue, Lvhua Han, Guoxin Ma and Hanping Mao
Agronomy 2024, 14(10), 2359; https://doi.org/10.3390/agronomy14102359 (registering DOI) - 13 Oct 2024
Viewed by 295
Abstract
Robotically selective broccoli harvesting requires precise lightweight detection models to efficiently detect broccoli heads. Therefore, this study introduces a lightweight and high-precision detection model named LBDC-YOLO (Lightweight Broccoli Detection in Complex Environment—You Look Only Once), based on the improved YOLOv8 (You Look Only [...] Read more.
Robotically selective broccoli harvesting requires precise lightweight detection models to efficiently detect broccoli heads. Therefore, this study introduces a lightweight and high-precision detection model named LBDC-YOLO (Lightweight Broccoli Detection in Complex Environment—You Look Only Once), based on the improved YOLOv8 (You Look Only Once, Version 8). The model incorporates the Slim-neck design paradigm based on GSConv to reduce computational complexity. Furthermore, Triplet Attention is integrated into the backbone network to capture cross-dimensional interactions between spatial and channel dimensions, enhancing the model’s feature extraction capability under multiple interfering factors. The original neck network structure is replaced with a BiFPN (Bidirectional Feature Pyramid Network), optimizing the cross-layer connection structure, and employing weighted fusion methods for better integration of multi-scale features. The model undergoes training and testing on a dataset constructed in real field conditions, featuring broccoli images under various influencing factors. Experimental results demonstrate that LBDC-YOLO achieves an average detection accuracy of 94.44% for broccoli. Compared to the original YOLOv8n, LBDC-YOLO achieves a 32.1% reduction in computational complexity, a 47.8% decrease in parameters, a 44.4% reduction in model size, and a 0.47 percentage point accuracy improvement. When compared to models such as YOLOv5n, YOLOv5s, and YOLOv7-tiny, LBDC-YOLO exhibits higher detection accuracy and lower computational complexity, presenting clear advantages for broccoli detection tasks in complex field environments. The results of this study provide an accurate and lightweight method for the detection of broccoli heads in complex field environments. This work aims to inspire further research in precision agriculture and to advance knowledge in model-assisted agricultural practices. Full article
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<p>Different conditions of broccoli heads. (<b>a</b>) Broccoli heads in direct sunlight; (<b>b</b>) broccoli heads in soft and even light; (<b>c</b>) occluded broccoli heads; (<b>d</b>) broccoli heads in partial shadows; (<b>e</b>) broccoli heads in complete shadow; (<b>f</b>) wet broccoli heads.</p>
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<p>Network structure of LBDC-YOLO. Red rectangles in the output image indicate broccoli heads detected by the model. The different colored boxes in the figure represent modules with different functions.</p>
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<p>Schematic diagram of GSConv principle.</p>
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<p>Structure of Triplet.</p>
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<p>Structure of BiFPN. (<b>a</b>) Simplified structure of BiFPN; (<b>b</b>) BiFPN structure in LBDC-YOLO.</p>
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<p><span class="html-italic">AP</span><sub>0.5–0.95</sub> curve of LBDC-YOLO.</p>
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<p>Visualization results of the model. (<b>a</b>) Original image; (<b>b</b>) original image with annotations; (<b>c</b>–<b>e</b>) are visualization heatmaps of shallow, intermediate, and deep feature maps of the YOLOv8n model, respectively; (<b>f</b>–<b>h</b>) are visualization heatmaps of shallow, intermediate, and deep feature maps of the YOLOv8n model with Slim-neck, respectively; (<b>i</b>–<b>k</b>) are visualization heatmaps of shallow, intermediate, and deep feature maps of the YOLOv8n model with Slim-neck and Triplet, respectively; (<b>l</b>–<b>n</b>) are visualization heatmaps of shallow, intermediate, and deep feature maps of the LBDC-YOLO model, respectively.</p>
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<p>LBDC-YOLO and YOLOv8n model detection results. (<b>a</b>,<b>c</b>,<b>e</b>,<b>g</b>,<b>i</b>,<b>k</b>) show the detection results using the LBDC-YOLO model; (<b>b</b>,<b>d</b>,<b>f</b>,<b>h</b>,<b>j</b>,<b>l</b>) show the detection results using the YOLOv8n model. The environmental effects on the broccoli head in each image are listed in the first column. The red squares in the figures are model detection results, and the red arrows are used to indicate the position of the local zoom in the original figure.</p>
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27 pages, 5968 KiB  
Article
Marine Microplastic Classification by Hyperspectral Imaging: Case Studies from the Mediterranean Sea, the Strait of Gibraltar, the Western Atlantic Ocean and the Bay of Biscay
by Roberta Palmieri, Silvia Serranti, Giuseppe Capobianco, Andres Cózar, Elisa Martí and Giuseppe Bonifazi
Appl. Sci. 2024, 14(20), 9310; https://doi.org/10.3390/app14209310 (registering DOI) - 12 Oct 2024
Viewed by 351
Abstract
In this work, a comprehensive characterization of microplastic samples collected from unique geographical locations, including the Mediterranean Sea, Strait of Gibraltar, Western Atlantic Ocean and Bay of Biscay utilizing advanced hyperspectral imaging (HSI) techniques working in the short-wave infrared range (1000–2500 nm) is [...] Read more.
In this work, a comprehensive characterization of microplastic samples collected from unique geographical locations, including the Mediterranean Sea, Strait of Gibraltar, Western Atlantic Ocean and Bay of Biscay utilizing advanced hyperspectral imaging (HSI) techniques working in the short-wave infrared range (1000–2500 nm) is presented. More in detail, an ad hoc hierarchical classification approach was developed and applied to optimize the identification of polymers. Morphological and morphometrical attributes of microplastic particles were simultaneously measured by digital image processing. Results showed that the collected microplastics are mainly composed, in decreasing order of abundance, by polyethylene (PE), polypropylene (PP), polystyrene (PS) and expanded polystyrene (EPS), in agreement with the literature data related to marine microplastics. The investigated microplastics belong to the fragments (86.8%), lines (9.2%) and films (4.0%) categories. Rigid (thick-walled) fragments were found at all sampling sites, while film-type microplastics and lines were absent in some samples from the Mediterranean Sea and the Western Atlantic Ocean. Rigid fragments and lines are mainly made of PE, whereas PP is the most common polymer for the film category. Average Feret diameter of microplastic fragments decreases from EPS (3–4 mm) to PE (2–3 mm) and PP (1–2 mm). The setup strategies illustrate that the HSI-based approach enables the classification of the polymers constituting microplastic particles and, at the same time, to measure and classify them by shape. Such multiple characterization of microplastic samples at the individual level is proposed as a useful tool to explore the environmental selection of microplastic features (i.e., composition, category, size, shape) and to advance the understanding of the role of weathering, hydrodynamic and other phenomena in their transport and fragmentation. Full article
13 pages, 6880 KiB  
Article
The Evolution of Dilatant Shear Bands in High-Pressure Die Casting for Al-Si Alloys
by Jingzhou Lu, Ewan Lordan, Yijie Zhang, Zhongyun Fan, Wanlin Wang and Kun Dou
Materials 2024, 17(20), 5001; https://doi.org/10.3390/ma17205001 (registering DOI) - 12 Oct 2024
Viewed by 254
Abstract
Bands of interdendritic porosity and positive macrosegregation are commonly observed in pressure die castings, with previous studies demonstrating their close relation to dilatant shear bands in granular materials. Despite recent technological developments, the micromechanism governing dilatancy in the high-pressure die casting (HPDC) process [...] Read more.
Bands of interdendritic porosity and positive macrosegregation are commonly observed in pressure die castings, with previous studies demonstrating their close relation to dilatant shear bands in granular materials. Despite recent technological developments, the micromechanism governing dilatancy in the high-pressure die casting (HPDC) process for alloys between liquid and solid temperature regions is still not fully understood. To investigate the influence of fluid flow and the size of externally solidified crystals (ESCs) on the evolution of dilatant shear bands in HPDC, various filling velocities were trialled to produce HPDC samples of Al8SiMnMg alloys. This study demonstrates that crystal fragmentation is accompanied by a decrease in dilatational concentration, producing an indistinct shear band. Once crystal fragmentation stagnates, the enhanced deformation rate associated with a further increase in filling velocity (from 2.2 ms−1 to 4.6 ms−1) localizes dilatancy into a highly concentrated shear band. The optimal piston velocity is 3.6 ms−1, under which the average ESC size reaches the minimum, and the average yield stress and overall product of strength and elongation reach the maximum values of 144.6 MPa and 3.664 GPa%, respectively. By adopting the concept of force chain buckling in granular media, the evolution of dilatant shear bands in equiaxed solidifying alloys can be adequately explained based on further verification with DEM-type modeling in OpenFOAM. Three mechanisms for ESC-enhanced dilation are presented, elucidating previous reports relating the presence of ESCs to the subsequent shear band characteristics. By applying the physics of granular materials to equiaxed solidifying alloys, unique opportunities are presented for process optimization and microstructural modeling in HPDC. Full article
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<p>Casting region with gating system and 8 tensile samples of HPDC tensile.</p>
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<p>Shot profile highlighting filling velocities used to produce HPDC tensile specimens.</p>
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<p>Infrared image and the temperature readings during various cycles of the HPDC process.</p>
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<p>Dilatant shear bands observed in HPDC samples produced with filling velocities of 2.2 ms<sup>−1</sup> (<b>i</b>), 3.6 ms<sup>−1</sup> (<b>ii</b>) and 4.2 ms<sup>−1</sup> (<b>iii</b>). Typical macrostructure of etched samples from the center of the gage section are shown (left) and corresponding EDX maps highlighting the eutectic fraction are shown (right).</p>
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<p>Optical micrographs taken from zone A, showing how dilatancy varies with filling velocities of (<b>i</b>) 2.2 ms<sup>−1</sup>, (<b>ii</b>) 3.6 ms<sup>−1</sup>, and (<b>iii</b>) 4.2 ms<sup>−1</sup>. Outlined in (<b>ii</b>) is a potential force chain that has persisted through deformation. The bulk filling direction was out of the page.</p>
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<p>Typical high-contrast secondary electron SEM micrographs used to obtain average ESC and in-cavity solidified grain size (<a href="#materials-17-05001-t001" class="html-table">Table 1</a>) for filling velocities of (<b>i</b>) 2.2 ms<sup>−1</sup>, (<b>ii</b>) 3.6 ms<sup>−1</sup> and (<b>iii</b>) 4.2 ms<sup>−1</sup>.</p>
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<p>The yield stress, elongation and ultimate tensile stress of various tensile samples.</p>
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<p>Graphical illustration highlighting the three mechanisms governing ESC enhanced dilation within the shear band: (i) “Stacking faults” introduced by the presence of ESCs along the force chain; (ii) ESCs located on the outermost regions of the band effectively acting as pivots; (iii) ESCs propelled by highly turbulent flow conditions, potentially dislodging crystals from the force chain. σ denotes the major principle stress axis.</p>
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<p>(<b>i</b>) Calculation domain and mesh for the model. (<b>ii</b>) The fluid velocity distribution of melt. (<b>iii</b>) The ESC motion and velocity distribution in the tensile sample during filling.</p>
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<p>The ESCs’ aggregation tendency in the tensile sample during filling.</p>
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26 pages, 5090 KiB  
Article
Analysis and Optimization of a s-CO2 Cycle Coupled to Solar, Biomass, and Geothermal Energy Technologies
by Orlando Anaya-Reyes, Iván Salgado-Transito, David Aarón Rodríguez-Alejandro, Alejandro Zaleta-Aguilar, Carlos Benito Martínez-Pérez and Sergio Cano-Andrade
Energies 2024, 17(20), 5077; https://doi.org/10.3390/en17205077 (registering DOI) - 12 Oct 2024
Viewed by 249
Abstract
This paper presents an analysis and optimization of a polygeneration power-production system that integrates a concentrating solar tower, a supercritical CO2 Brayton cycle, a double-flash geothermal Rankine cycle, and an internal combustion engine. The concentrating solar tower is analyzed under the weather [...] Read more.
This paper presents an analysis and optimization of a polygeneration power-production system that integrates a concentrating solar tower, a supercritical CO2 Brayton cycle, a double-flash geothermal Rankine cycle, and an internal combustion engine. The concentrating solar tower is analyzed under the weather conditions of the Mexicali Valley, Mexico, optimizing the incident radiation on the receiver and its size, the tower height, and the number of heliostats and their distribution. The integrated polygeneration system is studied by first and second law analyses, and its optimization is also developed. Results show that the optimal parameters for the solar field are a solar flux of 549.2 kW/m2, a height tower of 73.71 m, an external receiver of 1.86 m height with a 6.91 m diameter, and a total of 1116 heliostats of 6 m × 6 m. For the integrated polygeneration system, the optimal values of the variables considered are 1437 kPa and 351.2 kPa for the separation pressures of both flash chambers, 753 °C for the gasification temperature, 741.1 °C for the inlet temperature to the turbine, 2.5 and 1.503 for the turbine pressure ratios, 0.5964 for the air–biomass equivalence ratio, and 0.5881 for the CO2 mass flow splitting fraction. Finally, for the optimal system, the thermal efficiency is 38.8%, and the exergetic efficiency is 30.9%. Full article
(This article belongs to the Section B2: Clean Energy)
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<p>Schematic diagram of the integrated polygeneration power system under study.</p>
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<p>DNI observed in the Mexicali Valley, Mexico [<a href="#B36-energies-17-05077" class="html-bibr">36</a>].</p>
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<p>Cosine efficiency of the heliostat field.</p>
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<p>Optical efficiency of the heliostat field.</p>
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<p>Solar flux profile at the receiver.</p>
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<p>Effect of the gasification temperature on the syngas LHV and production rate m<sup>3</sup> of syngas/kg of biomass.</p>
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<p>Effect of the gasification temperature on the first and second law efficiencies of the gasification system.</p>
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<p>Effect of <math display="inline"><semantics> <mi>ξ</mi> </semantics></math> on the syngas LHV and production rate of the gasification system.</p>
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<p>Effect of <math display="inline"><semantics> <mi>ξ</mi> </semantics></math> on the energetic and exergetic efficiencies of the gasification system.</p>
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<p>Effect of <math display="inline"><semantics> <msub> <mi>T</mi> <mi>GTI</mi> </msub> </semantics></math> on the energetic and exergetic efficiencies of the Brayton cycle.</p>
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<p>Effect of <math display="inline"><semantics> <mi>γ</mi> </semantics></math> on the energetic and exergetic efficiencies of the Brayton cycle.</p>
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<p>Effect of <math display="inline"><semantics> <msub> <mi>ϕ</mi> <mn>1</mn> </msub> </semantics></math> on the energetic and exergetic efficiencies of the Brayton cycle.</p>
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<p>Effect of <math display="inline"><semantics> <msub> <mi>ϕ</mi> <mn>2</mn> </msub> </semantics></math> on the energetic and exergetic efficiencies of the Brayton cycle.</p>
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<p>Effect of <math display="inline"><semantics> <mrow> <msub> <mi>P</mi> <mrow> <mi>sep</mi> <mn>1</mn> </mrow> </msub> </mrow> </semantics></math> on the energetic and exergetic efficiencies of the Rankine cycle.</p>
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<p>Effect of <math display="inline"><semantics> <mrow> <msub> <mi>P</mi> <mrow> <mi>sep</mi> <mn>2</mn> </mrow> </msub> </mrow> </semantics></math> on the energetic and exergetic efficiencies of the Rankine cycle.</p>
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<p>Percentage of exergy destruction rates by component.</p>
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23 pages, 19550 KiB  
Article
Bio-Pesticidal Potential of Nanostructured Lipid Carriers Loaded with Thyme and Rosemary Essential Oils against Common Ornamental Flower Pests
by Alejandro Múnera-Echeverri, José Luis Múnera-Echeverri and Freimar Segura-Sánchez
Colloids Interfaces 2024, 8(5), 55; https://doi.org/10.3390/colloids8050055 (registering DOI) - 12 Oct 2024
Viewed by 235
Abstract
The encapsulation of essential oils (EOs) in nanostructured lipid carriers (NLCs) represents a modern and sustainable approach within the agrochemical industry. This research evaluated the colloidal properties and insecticidal activity of NLCs loaded with thyme essential oil (TEO-NLC) and rosemary essential oil (REO-NLC) [...] Read more.
The encapsulation of essential oils (EOs) in nanostructured lipid carriers (NLCs) represents a modern and sustainable approach within the agrochemical industry. This research evaluated the colloidal properties and insecticidal activity of NLCs loaded with thyme essential oil (TEO-NLC) and rosemary essential oil (REO-NLC) against three common arthropod pests of ornamental flowers: Frankliniella occidentalis, Myzus persicae, and Tetranychus urticae. Gas chromatography–mass spectrometry (GC-MS) analysis identified the major chemical constituents of the EOs, with TEO exhibiting a thymol chemotype and REO exhibiting an α-pinene chemotype. NLCs were prepared using various homogenization techniques, with high shear homogenization (HSH) providing the optimal particle size, size distribution, and surface electrical charge. A factorial design was employed to evaluate the effects of EO concentration, surfactant concentration, and liquid lipid/solid lipid ratio on the physicochemical properties of the nanosuspensions. The final TEO-NLC formulation had a particle size of 347.8 nm, a polydispersity index of 0.182, a zeta potential of −33.8 mV, an encapsulation efficiency of 71.9%, and a loading capacity of 1.18%. The REO-NLC formulation had a particle size of 288.1 nm, a polydispersity index of 0.188, a zeta potential of −34 mV, an encapsulation efficiency of 80.6%, and a loading capacity of 1.40%. Evaluation of contact toxicity on leaf disks showed that TEO-NLC exhibited moderate insecticidal activity against the western flower thrips and mild acaricidal activity against the two-spotted spider mite, while REO-NLC demonstrated limited effects. These findings indicate that TEO-NLCs show potential as biopesticides for controlling specific pests of ornamental flowers, and further optimization of the administration dosage could significantly enhance their effectiveness. Full article
(This article belongs to the Special Issue Biocolloids and Biointerfaces: 2nd Edition)
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<p>Scheme of extraction process to obtain TEO and REO: (<b>a</b>) thyme and rosemary freshly harvested plant material; (<b>b</b>) grinding step by agro-industrial chopper; (<b>c</b>) distillation equipment: boiler–extractor vessel–condenser–collector; (<b>d</b>) thyme EO and rosemary EO.</p>
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<p>Experimental scheme of NLCs production: (<b>a</b>) heating aqueous phase and organic phase separately; (<b>b</b>) mixing and homogenization of both phases by HSH; (<b>c</b>) homogenization of hot pre-emulsion by HHPH; (<b>d</b>) homogenization of hot pre-emulsion by USH.</p>
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<p>Particle size distributions of REO-NLC HHPH (red line); REO-NLC USH (green line); REO-NLC HSH (blue line).</p>
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<p>Surface response charts and contour plots of experimental design at EO low concentration: (<b>a</b>) particle size, (<b>b</b>) polydispersity index, and (<b>c</b>) zeta potential; and at EO high concentration: (<b>d</b>) particle size, (<b>e</b>) polydispersity index, and (<b>f</b>) zeta potential.</p>
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<p>Particle size distributions of FEO-NLC (red line); TEO-NLC (green line); REO-NLC (blue line).</p>
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<p>TEM and SEM images: (<b>a</b>) TEO-NLC TEM micrography; (<b>b</b>) REO-NLC TEM micrography; (<b>c</b>) TEO-NLC SEM micrography; (<b>d</b>) REO-NLC SEM micrography.</p>
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<p>DSC and TGA thermograms: (<b>a</b>) DSC curves: blue line for CW; green line for CW + MIG physical mixture; orange line for FEO-NLC; red line for TEO-NLC; pink line for REO-NLC; (<b>b</b>) TGA curve for NLC formulation with a TEO:REO 50:50 mixture.</p>
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<p>Mortality percentage of solutions of EOs and suspensions of EO-NLC: FEO-NLC (pink triangles), REO-NLC (green triangles), REO (red rectangles), TEO-NLC (blue rhombuses), and TEO on (green octahedron) (<b>a</b>) <span class="html-italic">M. persicae</span>, (<b>b</b>) <span class="html-italic">T. urticae</span>, and (<b>c</b>) <span class="html-italic">F. occidentalis</span>.</p>
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19 pages, 1424 KiB  
Article
Development and Testing of a Dual-Driven Piezoelectric Microgripper with High Amplification Ratio for Cell Micromanipulation
by Boyan Lu, Shengzheng Kang, Luyang Zhou, Dewen Hua, Chengdu Yang and Zimeng Zhu
Machines 2024, 12(10), 722; https://doi.org/10.3390/machines12100722 (registering DOI) - 12 Oct 2024
Viewed by 207
Abstract
Cell micromanipulation is an important technique in the field of biomedical engineering. Microgrippers play a crucial role in connecting macroscopic and microscopic objects in micromanipulation systems. However, since the operated biological cells are deformable, vulnerable, and typically distributed in sizes ranging from micrometers [...] Read more.
Cell micromanipulation is an important technique in the field of biomedical engineering. Microgrippers play a crucial role in connecting macroscopic and microscopic objects in micromanipulation systems. However, since the operated biological cells are deformable, vulnerable, and typically distributed in sizes ranging from micrometers to millimeters, it poses a huge challenge to microgripper performance. To solve this problem, this paper develops a dual-driven piezoelectric microgripper with a high displacement amplification ratio, large stroke, and parallel gripping. By adopting modular configuration, three kinds of flexure-based mechanisms, including the lever mechanism, Scott–Russell mechanism, and parallelogram mechanism are connected in series to realize three-stage amplification, which effectively makes up for the shortage of small output displacement of the piezoelectric actuator. At the same time, the use of the parallelogram mechanism also isolates the parasitic rotation movement, and realizes the parallel movement of the gripping jaws. In addition, the kinematics, statics, and dynamics models of the microgripper are established by using the pseudo-rigid body and Lagrange methods, and the key geometric parameters are also optimized. Finite element simulation and experimental tests verify the effectiveness of the developed microgripper. The results show that the developed microgripper allows an amplification ratio of 46.4, a clamping stroke of 2180 μm, and a natural frequency of 203.1 Hz. Based on the developed microgripper, the nondestructive micromanipulation of zebrafish embryos is successfully realized. Full article
(This article belongs to the Special Issue Optimization and Design of Compliant Mechanisms)
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<p>Schematic diagram of the developed dual-driven piezoelectric microgripper.</p>
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<p>(<b>a</b>) Distribution of the flexure hinges in the microgripper. (<b>b</b>) Equivalent model of half of the microgripper and its geometric parameters.</p>
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<p>Motion vector diagram of three amplification mechanisms.</p>
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<p>Diagram of changes in displacements and angles of the microgripper.</p>
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<p>Static analysis of the microgripper.</p>
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<p>Static analysis results: (<b>a</b>) <span class="html-italic">X</span>-direction deformation; (<b>b</b>) <span class="html-italic">Y</span>-direction deformation.</p>
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<p>Stress distribution of the microgripper.</p>
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<p>Finite element analysis results for first six modes of the microgripper.</p>
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<p>(<b>a</b>) Experimental setup for cell microgripping. (<b>b</b>) Structure of the developed microgripper. (<b>c</b>) Schematic diagram of cell immobilization.</p>
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<p>Output displacement responses of the microgripper with the applied voltage. (<b>a</b>) The input end. (<b>b</b>) The output end.</p>
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<p>Frequency response of the developed microgripper.</p>
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<p>Closed-loop tracking results of the microgripper. (<b>a</b>,<b>b</b>) Step signal tracking results. (<b>c</b>,<b>d</b>) 1-Hz sinusoidal signal tracking results.</p>
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<p>Microscopic images of cell micromanipulation by the developed microgripper. (<b>a</b>) Before gripping the cell. (<b>b</b>) After gripping the cell. (<b>c</b>) Releasing the cell. From the figure, it is observed that the gripper can clamp and release the cell successfully without mechanical damage.</p>
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<p>(<b>a</b>) Closed -loop control bandwidth of the developed microgripper, where the red dashed lines represent that the bandwidth is 23.1 Hz under the magnitude of −3 dB. (<b>b</b>) Statistical results of cell grasping experiments under different frequencies, where each frequency is repeatedly tested for ten times.</p>
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39 pages, 10014 KiB  
Article
Navigating Economies of Scale and Multiples for Nuclear-Powered Data Centers and Other Applications with High Service Availability Needs
by Botros N. Hanna, Abdalla Abou-Jaoude, Nahuel Guaita, Paul Talbot and Christopher Lohse
Energies 2024, 17(20), 5073; https://doi.org/10.3390/en17205073 (registering DOI) - 12 Oct 2024
Viewed by 188
Abstract
Nuclear energy is increasingly being considered for such targeted energy applications as data centers in light of their high capacity factors and low carbon emissions. This paper focuses on assessing the tradeoffs between economies of scale versus mass production to identify promising reactor [...] Read more.
Nuclear energy is increasingly being considered for such targeted energy applications as data centers in light of their high capacity factors and low carbon emissions. This paper focuses on assessing the tradeoffs between economies of scale versus mass production to identify promising reactor sizes to meet data center demands. A framework is then built using the best cost estimates from the literature to identify ideal reactor power sizes for the needs of the given data center. Results should not be taken to be deterministic but highlight the variability of ideal reactor power output against the required demand. While certain advocates claim that with the gigawatts of clean, firm energy needed, large plants are ideal, others advocate for SMRs that can be deployed in large quantities and reap the benefits from learning effects. The findings of this study showcase that identifying the optimal size for a reactor is likely more nuanced and dependent on the application and its requirements. Overall, the study does show potential economic promise for coupling nuclear reactors to data centers and industrial heat applications under certain key conditions and assumptions. Full article
(This article belongs to the Section B4: Nuclear Energy)
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<p>The economies-of-scale penalty crossover point is illustrated here. The levelized capital cost on the <span class="html-italic">y</span>-axis is relative to the levelized capital cost of a 1000 MWe reactor.</p>
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<p>The dependence of the crossover points for economies-of-scale penalties on the LR at a total demand of 1000 MWe is analyzed, with individual reactor sizes varying from 1 to 500 MWe. The number of deployed units to satisfy the demand, is calculated by dividing the demand by the reactor size (e.g., 1000 units of 1 MWe reactors or 10 units of 100 MWe reactors).</p>
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<p>The dependence of the crossover points for economies-of-scale penalties on both the LR and total demand (2000 MWe or 10,000 MWe) is analyzed, with individual reactor sizes varying from 1 to 500 MWe. The shaded region indicates the impact of uncertainty in the LRs for large reactors.</p>
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<p>Literature on LRs is used to develop an equation to describe LR dependencies on reactor capacity.</p>
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<p>The dependence of the crossover points of economies-of-scale penalties on the total demand (ranging from 1000 to 10,000 MWe) is analyzed, with individual reactor sizes (reactor power) of 5 MWe and 500 MWe. The dark- and light-shaded regions indicate the impact of uncertainty in LRs for large reactors and individual reactors (small or microreactors), respectively.</p>
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<p>The refueling schedule for eight reactors shows that all reactors are brought online within the first year. After that, the number of offline reactors is minimized (<b>top</b>). As a result, the daily aggregate capacity factor fluctuates between 0.87 and 1 (<b>bottom</b>), with an overall lifetime capacity factor of 0.986.</p>
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<p>An approximation of how the refueling interval varies with reactor power.</p>
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<p>Data center availability requirements, which demand higher capacity factors, lead to the overbuilding of nuclear reactors. Targeting the daily availability ctieria (<b>top</b>) rather than the lifetime availability criteria (<b>bottom</b>) exacerbates this overbuilding, especially for larger reactors. The data center demand is assumed to be 1000 MWe, with a levelization period of 40 years.</p>
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<p>The dependence of the crossover points for economies-of-scale penalties on both the LR) and total demand (ranging from 1000 MWe to 10,000 MWe) is analyzed, with individual reactor sizes (power outputs) varying between 1 and 500 MWe. The daily availability criterion is assumed to be 99%. The shaded region indicates the impact of uncertainty in the LRs for large reactors.</p>
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<p>The dependence of the crossover points on economies-of-scale penalties on the total demand (ranging from 1000 to 10,000 MWe) is analyzed, with individual reactor sizes of 5 MWe or 500 MWe. The required availability is 99%. The dark- and light-shaded regions indicate the impact of uncertainty in LRs for large reactors and individual reactors (small or microreactors), respectively.</p>
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<p>Curve fitting based on literature data for the OCC [<a href="#B27-energies-17-05073" class="html-bibr">27</a>,<a href="#B28-energies-17-05073" class="html-bibr">28</a>], O&amp;M cost [<a href="#B42-energies-17-05073" class="html-bibr">42</a>,<a href="#B43-energies-17-05073" class="html-bibr">43</a>,<a href="#B44-energies-17-05073" class="html-bibr">44</a>,<a href="#B45-energies-17-05073" class="html-bibr">45</a>], and construction duration [<a href="#B27-energies-17-05073" class="html-bibr">27</a>,<a href="#B46-energies-17-05073" class="html-bibr">46</a>].</p>
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<p>Estimation of the TCI at different reactor power levels (reactor sizes), assuming target daily availability criteria between 90% and 100%, with an assumed interest rate of 6%.</p>
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<p>Estimation of the LCOE at different reactor power levels (reactor sizes), assuming target daily availability criteria between 90% and 100%, with an assumed interest rate of 6%. The plots assume no electricity sold externally to the grid (<b>left</b>) or that the surplus electricity is exported to the grid at a price of USD 20/MWh (<b>right</b>).</p>
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<p>Optimized refueling outage for a system with six different reactor sizes.</p>
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<p>Reactors mix in the different iterations (different scenarios) estimates (<b>top</b>) and their corresponding capacity factor (availability) and LCOE (<b>bottom</b>). The dots colored in green are the ones for single reactor types.</p>
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<p>Reactors mix in the different iterations (different scenarios) estimates (<b>top</b>) and their corresponding capacity factor (availability) and LCOE (<b>bottom</b>). The dots colored in green are the ones for single reactor types.</p>
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<p>Breakdown of SMRs vs. microreactors under different demand sizes and availability requirements.</p>
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<p>Breakdown of large reactor vs. SMR vs microreactors under different demand sizes and lifetime availability requirements.</p>
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<p>Estimation of the LCOH at different reactor power outputs (reactor sizes). The plots assume an interest rate of 6%.</p>
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<p>SMR vs. microreactor mix for different heat demand sizes and lifetime availability requirements.</p>
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<p>Large reactor vs. SMR vs. microreactor mixes for various heat demand sizes and lifetime availability requirements.</p>
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<p>The dependence of the crossover points for economies-of-scale penalties on total demand (ranging from 1000 to 10,000 MWe) is analyzed, with individual reactor sizes varying from 1 to 500 MWe. The dark- and light-shaded regions indicate the impact of uncertainty in LRs for large reactors and individual reactors (small or microreactors), respectively.</p>
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<p>The dependence of the crossover points on economies-of-scale penalties on the total demand (ranging from 1000 to 10,000 MWe) is analyzed, with individual reactor capacities varying from 1 to 500 MWe. The dark- and light-shaded regions indicate the impact of uncertainty in LRs for large reactors and individual reactors (small or microreactors), respectively.</p>
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<p>Estimating the economies-of-scale crossover points for different demand targets at a 99% required availability. The dark- and light-shaded regions indicate the impact of uncertainty in LRs for large reactors and individual reactors (small or microreactors), respectively.</p>
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12 pages, 2249 KiB  
Article
Combining Activated Carbon Adsorption and CO2 Carbonation to Treat Fly Ash Washing Wastewater and Recover High-Purity Calcium Carbonate
by Weifang Chen, Yifan Chen, Yegui Wang and Na Zhao
Water 2024, 16(20), 2896; https://doi.org/10.3390/w16202896 (registering DOI) - 12 Oct 2024
Viewed by 356
Abstract
Fly ash washing wastewater was carbonated with carbon dioxide (CO2) to remove calcium (Ca) by forming a calcium carbonate (CaCO3) precipitate. An investigation of the factors affecting carbonation showed that Ca removal was highly dependent on the initial pH [...] Read more.
Fly ash washing wastewater was carbonated with carbon dioxide (CO2) to remove calcium (Ca) by forming a calcium carbonate (CaCO3) precipitate. An investigation of the factors affecting carbonation showed that Ca removal was highly dependent on the initial pH of the wastewater. The Ca removal was 10%, 61%, 91% and more than 99% at initial wastewater pH levels of 11.8, 12.0, 12.5 and 13.0, respectively. The optimal conditions for carbonation were initial pH of 13.0, carbonation time of 30 min and CO2 flow rate of 30 mL/min. The Ca concentration in the wastewater decreased to <40 mg/L, while 73 g of CaCO3 precipitate was produced per liter of wastewater. However, heavy metals, specifically Pb and Zn, co-precipitated during carbonation, which resulted in a CaCO3 product that contained as much as 0.61 wt% of Pb and 0.02 wt% of Zn. Activated carbon modified by a quaternary ammonium salt was used to selectively adsorb the Pb and Zn first. The Pb- and Zn-free water was then carbonated. By combining adsorption with carbonation, the Ca concentration in the treated wastewater was decreased to about 28 mg/L, while the Na, Cl and K were retained. The wastewater thus treated was ready for NaCl and KCl recovery. In addition, the precipitate had a Ca content of more than 38 wt% and almost no heavy metals. The average particle size of the precipitate was 47 μm, with a uniform cubic shape. The quality of the precipitate met the requirements for the industrial reuse of CaCO3. In summary, adsorption and carbonation combined were able to remove pollutants from wastewater while recovering useful resources. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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<p>Changes in wastewater pH and Ca removal efficiency at different initial pH: (<b>a</b>) pH = 11.8; (<b>b</b>) pH = 12.0; (<b>c</b>) pH = 12.5; (<b>d</b>) pH = 13.0.</p>
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<p>Mass of precipitate per liter of wastewater at different initial pH and carbonation times.</p>
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<p>Changes in wastewater pH, Ca removal efficiency and mass of precipitate at different CO<sub>2</sub> flow rates: (<b>a</b>) pH and Ca removal efficiency; (<b>b</b>) mass of precipitate.</p>
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<p>XRD patterns of precipitate at different carbonation times.</p>
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<p>Particle size and SEM analysis of precipitate: (<b>a</b>) particle size distribution; (<b>b</b>) SEM image.</p>
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27 pages, 12606 KiB  
Article
Dynamic Wireless Charging of Electric Vehicles Using PV Units in Highways
by Tamer F. Megahed, Diaa-Eldin A. Mansour, Donart Nayebare, Mohamed F. Kotb, Ahmed Fares, Ibrahim A. Hameed and Haitham El-Hussieny
World Electr. Veh. J. 2024, 15(10), 463; https://doi.org/10.3390/wevj15100463 (registering DOI) - 12 Oct 2024
Viewed by 213
Abstract
Transitioning from petrol or gas vehicles to electric vehicles (EVs) poses significant challenges in reducing emissions, lowering operational costs, and improving energy storage. Wireless charging EVs offer promising solutions to wired charging limitations such as restricted travel range and lengthy charging times. This [...] Read more.
Transitioning from petrol or gas vehicles to electric vehicles (EVs) poses significant challenges in reducing emissions, lowering operational costs, and improving energy storage. Wireless charging EVs offer promising solutions to wired charging limitations such as restricted travel range and lengthy charging times. This paper presents a comprehensive approach to address the challenges of wireless power transfer (WPT) for EVs by optimizing coupling frequency and coil design to enhance efficiency while minimizing electromagnetic interference (EMI) and heat generation. A novel coil design and adaptive hardware are proposed to improve power transfer efficiency (PTE) by defining the optimal magnetic resonant coupling WPT and mitigating coil misalignment, which is considered a significant barrier to the widespread adoption of WPT for EVs. A new methodology for designing and arranging roadside lanes and facilities for dynamic wireless charging (DWC) of EVs is introduced. This includes the optimization of transmitter coils (TCs), receiving coils (RCs), compensation circuits, and high-frequency inverters/converters using the partial differential equation toolbox (pdetool). The integration of wireless charging systems with smart grid technology is explored to enhance energy distribution and reduce peak load issues. The paper proposes a DWC system with multiple segmented transmitters integrated with adaptive renewable photovoltaic (PV) units and a battery system using the utility main grid as a backup. The design process includes the determination of the required PV array capacity, station battery sizing, and inverters/converters to ensure maximum power point tracking (MPPT). To validate the proposed system, it was tested in two scenarios: charging a single EV at different speeds and simultaneously charging two EVs over a 1 km stretch with a 50 kW system, achieving a total range of 500 km. Experimental validation was performed through real-time simulation and hardware tests using an OPAL-RT platform, demonstrating a power transfer efficiency of 90.7%, thus confirming the scalability and feasibility of the system for future EV infrastructure. Full article
(This article belongs to the Special Issue Wireless Power Transfer Technology for Electric Vehicles)
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<p>DWC station block diagram.</p>
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<p>Equivalent circuit of PV.</p>
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<p>Station control loop flowchart.</p>
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<p>Types of coil systems.</p>
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<p>Magnetically coupled ideal coils.</p>
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<p>Compensation circuit types: (<b>a</b>) series–series “SS”; (<b>b</b>) parallel–parallel “PP”; (<b>c</b>) series–parallel “SP”; (<b>d</b>) parallel–series “PS”.</p>
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<p>Design procedure for DWC for EVB.</p>
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<p>The spiral coil arrangement design using pdetool.</p>
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<p>The spiral coil arrangement design using pdetool.</p>
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<p>The dominant magnetic field component.</p>
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<p>Two identical resonators for transmitter and receiver coils modeled as linear arrays at a specific distance.</p>
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<p>Changing the frequency with different S21 values.</p>
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<p>Changing the frequency against different S21 values and distance.</p>
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<p>Prototype setup layout.</p>
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<p>Prototype operation process.</p>
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<p>PV power generated on testing days.</p>
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<p>Source voltage and current.</p>
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<p>System battery voltage.</p>
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<p>DC link voltage and current.</p>
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<p>Roadside winding voltage and current.</p>
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<p>Vehicle side winding voltage and current.</p>
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<p>Car battery SOC.</p>
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<p>Sending and receiving power.</p>
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<p>Consumed active and reactive power.</p>
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16 pages, 16982 KiB  
Article
Numerical Modeling of Vortex-Based Superconducting Memory Cells: Dynamics and Geometrical Optimization
by Aiste Skog, Razmik A. Hovhannisyan and Vladimir M. Krasnov
Nanomaterials 2024, 14(20), 1634; https://doi.org/10.3390/nano14201634 (registering DOI) - 12 Oct 2024
Viewed by 220
Abstract
The lack of dense random-access memory is one of the main obstacles to the development of digital superconducting computers. It has been suggested that AVRAM cells, based on the storage of a single Abrikosov vortex—the smallest quantized object in superconductors—can enable drastic miniaturization [...] Read more.
The lack of dense random-access memory is one of the main obstacles to the development of digital superconducting computers. It has been suggested that AVRAM cells, based on the storage of a single Abrikosov vortex—the smallest quantized object in superconductors—can enable drastic miniaturization to the nanometer scale. In this work, we present the numerical modeling of such cells using time-dependent Ginzburg–Landau equations. The cell represents a fluxonic quantum dot containing a small superconducting island, an asymmetric notch for the vortex entrance, a guiding track, and a vortex trap. We determine the optimal geometrical parameters for operation at zero magnetic field and the conditions for controllable vortex manipulation by short current pulses. We report ultrafast vortex motion with velocities more than an order of magnitude faster than those expected for macroscopic superconductors. This phenomenon is attributed to strong interactions with the edges of a mesoscopic island, combined with the nonlinear reduction of flux-flow viscosity due to the nonequilibrium effects in the track. Our results show that such cells can be scaled down to sizes comparable to the London penetration depth, ∼100 nm, and can enable ultrafast switching on the picosecond scale with ultralow energy per operation, ∼1019 J. Full article
(This article belongs to the Special Issue Quantum Computing and Nanomaterial Simulations)
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<p>SEM image of an Nb-based AVRAM cell prototype from Ref. [<a href="#B24-nanomaterials-14-01634" class="html-bibr">24</a>] The cell contains a superconducting island ∼1 × 1 μm<sup>2</sup>, a vortex trap (a hole in the film), a vortex-guiding track, and two readout Josephson junctions.</p>
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<p>Optimization of the notch and the track. (<b>a</b>) Structure of the considered AVRAM cell: a rectangular superconducting film 1 × 2 μm<sup>2</sup> with a circular vortex trap in the middle with a diameter <span class="html-italic">D</span>, a guiding track with a width <span class="html-italic">W</span>, and a notch on the right edge and at a vertical position <math display="inline"><semantics> <msub> <mi>z</mi> <mi>n</mi> </msub> </semantics></math>. Panels (<b>b</b>,<b>c</b>) show calculated vortex trapping time, <math display="inline"><semantics> <msub> <mi>τ</mi> <mn>01</mn> </msub> </semantics></math>, (<b>b</b>) as a function of the notch position, <math display="inline"><semantics> <msub> <mi>z</mi> <mi>n</mi> </msub> </semantics></math>, for a fixed <math display="inline"><semantics> <mrow> <mi>W</mi> <mo>=</mo> <mn>0.97</mn> <msub> <mi>λ</mi> <mi>L</mi> </msub> </mrow> </semantics></math>; and (<b>c</b>) as a function of the track width, <span class="html-italic">W</span>, for <math display="inline"><semantics> <mrow> <msub> <mi>z</mi> <mi>n</mi> </msub> <mo>=</mo> <mo>−</mo> <mn>500</mn> <mspace width="0.166667em"/> <mi>nm</mi> </mrow> </semantics></math>. Simulations are made at a constant applied current <math display="inline"><semantics> <mrow> <mi>I</mi> <mo>/</mo> <msub> <mi>I</mi> <mrow> <mi>d</mi> <mi>p</mi> </mrow> </msub> <mo>=</mo> <mn>0.78</mn> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>D</mi> <mo>≃</mo> <msub> <mi>λ</mi> <mi>L</mi> </msub> </mrow> </semantics></math>.</p>
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<p>Characteristic times in the optimized cell. (<b>a</b>–<b>c</b>) Current dependencies of (<b>a</b>) write time by a positive current, (<b>b</b>) residence time in the presence of a positive current and (<b>c</b>) erase time by a negative current. Insets illustrate directions of vortex motion. Panels (<b>d</b>–<b>f</b>) show color maps of the order parameter (left) and current density (right) in the corresponding cases. (<b>d</b>) At positive current without a vortex in the trap. (<b>e</b>) At a positive current with a trapped vortex. (<b>f</b>) At a negative current with a trapped vortex. Simulations are performed for a cell with <math display="inline"><semantics> <mrow> <msub> <mi>z</mi> <mi>n</mi> </msub> <mo>=</mo> <mn>0</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mi>W</mi> <mo>≃</mo> <mn>1.06</mn> <mspace width="3.33333pt"/> <msub> <mi>λ</mi> <mi>L</mi> </msub> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>D</mi> <mo>≃</mo> <mn>1.5</mn> <mspace width="3.33333pt"/> <msub> <mi>λ</mi> <mi>L</mi> </msub> </mrow> </semantics></math>.</p>
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<p>Determination of geometrical parameters for controllable operation. (<b>a</b>) Current dependence of the write (top) and residence (bottom) times for different track widths and <math display="inline"><semantics> <mrow> <mi>D</mi> <mo>≃</mo> <mn>1.5</mn> <msub> <mi>λ</mi> <mi>L</mi> </msub> </mrow> </semantics></math>. (<b>b</b>) A correlation between <math display="inline"><semantics> <msub> <mi>τ</mi> <mi>r</mi> </msub> </semantics></math> and <math display="inline"><semantics> <msub> <mi>τ</mi> <mn>01</mn> </msub> </semantics></math> for the data from (<b>a</b>). (<b>c</b>) A correlation between <math display="inline"><semantics> <msub> <mi>τ</mi> <mi>r</mi> </msub> </semantics></math> and <math display="inline"><semantics> <msub> <mi>τ</mi> <mn>01</mn> </msub> </semantics></math> for different trap diameters and <math display="inline"><semantics> <mrow> <mi>W</mi> <mo>=</mo> <mn>1.09</mn> <mspace width="3.33333pt"/> <msub> <mi>λ</mi> <mi>L</mi> </msub> </mrow> </semantics></math>. Dashed lines in (<b>b</b>,<b>c</b>) correspond to <math display="inline"><semantics> <mrow> <msub> <mi>τ</mi> <mi>r</mi> </msub> <mo>=</mo> <msub> <mi>τ</mi> <mn>01</mn> </msub> </mrow> </semantics></math>. A reliable cell operation can be achieved above these lines.</p>
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<p>Vortex velocimetry in the track without a trap. (<b>a</b>,<b>b</b>) Color maps of the order parameter (<b>a</b>) without a vortex and (<b>b</b>) with a moving vortex from the notch to the left edge at <math display="inline"><semantics> <mrow> <mi>I</mi> <mo>/</mo> <msub> <mi>I</mi> <mrow> <mi>d</mi> <mi>p</mi> </mrow> </msub> <mo>=</mo> <mn>0.31</mn> </mrow> </semantics></math>. (<b>c</b>) A cross-section of the core along the track from (<b>b</b>). A significant reduction of the order parameter occurs in front (at the left) of the vortex. (<b>d</b>) Average vortex velocities in four sections of the track, <math display="inline"><semantics> <mrow> <msub> <mi>x</mi> <mn>4</mn> </msub> <mo>=</mo> <mrow> <mo>[</mo> <mo>−</mo> <mn>500</mn> <mo>,</mo> <mo>−</mo> <mn>365.8</mn> <mo>]</mo> </mrow> </mrow> </semantics></math> nm, <math display="inline"><semantics> <mrow> <msub> <mi>x</mi> <mn>3</mn> </msub> <mo>=</mo> <mrow> <mo>[</mo> <mo>−</mo> <mn>365.8</mn> <mo>,</mo> <mo>−</mo> <mn>190</mn> <mo>]</mo> </mrow> </mrow> </semantics></math> nm, <math display="inline"><semantics> <mrow> <msub> <mi>x</mi> <mn>2</mn> </msub> <mo>=</mo> <mrow> <mo>[</mo> <mo>−</mo> <mn>190</mn> <mo>,</mo> <mn>0</mn> <mo>]</mo> </mrow> </mrow> </semantics></math> nm, <math display="inline"><semantics> <mrow> <msub> <mi>x</mi> <mn>1</mn> </msub> <mo>=</mo> <mrow> <mo>[</mo> <mn>0</mn> <mo>,</mo> <mn>255.8</mn> <mo>]</mo> </mrow> </mrow> </semantics></math> nm, at three different currents. (<b>e</b>) Average velocities in the same sections as a function of current. A strong increase in velocity at the left edge is due to interaction with an image antivortex. (<b>f</b>) The net average vortex velocity in the track as a function of current (blue circles). The red line show the linear Bardeen–Stephen approximation.</p>
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<p>Stroboscopic behavior in the flux-flow state. The time dependence of the flux in the trap after application of constant current. (<b>a</b>) At low current, <math display="inline"><semantics> <mrow> <msub> <mi>I</mi> <mn>01</mn> </msub> <mo>&lt;</mo> <mi>I</mi> <mo>≃</mo> <mn>0.42</mn> </mrow> </semantics></math><math display="inline"><semantics> <mrow> <msub> <mi>I</mi> <mrow> <mi>d</mi> <mi>p</mi> </mrow> </msub> <mo>&lt;</mo> <msub> <mi>I</mi> <mi>p</mi> </msub> </mrow> </semantics></math>, the vortex slowly arrives at the trap and stays there indefinitely long despite the applied current. At higher currents, the cell enters in the fast flux-flow state, which is (<b>b</b>) periodic at not very large <span class="html-italic">I</span> but becomes (<b>c</b>) ultrafast and aperiodic at larger <span class="html-italic">I</span>. In the flux-flow state, the cell exhibits a stroboscopic effect with respect to the duration of the current pulse.</p>
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<p>Demonstration of vortex manipulation by current pulses. Deterministic switching between states using positive and negative current pulses, optimized for the chosen geometry to write and erase the vortex from the trap. (<b>a</b>) Low current with long switching time. (<b>b</b>) High current with short switching time.</p>
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<p>An example of a mesh structure used for calculations.</p>
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