Search Results (1,902)

In the last twenty years, nanofabrication progress has allowed for the emergence of a new photodetector family, generally called low-dimensional solids (LDSs), among which the most important are two-dimensional (2D) materials, perovskites, and nanowires/quantum dots. They operate in a wide wavelength range from ultraviolet to far-infrared. Current research indicates remarkable advances in increasing the performance of this new generation of photodetectors. The published performance at room temperature is even better than reported for typical photodetectors. Several articles demonstrate detectivity outperforming physical boundaries driven by background radiation and signal fluctuations. This study attempts to explain these peculiarities. In order to achieve this goal, we first clarify the fundamental differences in the photoelectric effects of the new generation of photodetectors compared to the standard designs dominating the commercial market. Photodetectors made of 2D transition metal dichalcogenides (TMDs), quantum dots, topological insulators, and perovskites are mainly considered. Their performance is compared with the fundamental limits estimated by the signal fluctuation limit (in the ultraviolet region) and the background radiation limit (in the infrared region). In the latter case, Law 19 dedicated to HgCdTe photodiodes is used as a standard reference benchmark. The causes for the performance overestimate of the different types of LDS detectors are also explained. Finally, an attempt is made to determine their place in the global market in the long term. Full article

The lack of positive evidence for Weakly Interacting Massive Particles (WIMPs) as well as the lack of discovery of supersymmetric (SUSY) particles at the LHC may appeal to a non-supersymmetric solution for the Standard Model problem of the Higgs boson mass divergence, the origin of the electroweak energy scale and the physical nature of the cosmological dark matter in the approach of composite Higgs boson. If the Higgs boson consists of charged constituents, their binding can lead to stable particles with electroweak charges. Such particles can take part in sphaleron transitions in the early Universe, which balance their excess with baryon asymmetry. Constraints on exotic charged species leave only stable particles with charge $-2n$ possible, which can bind with n nuclei of primordial helium in neutral dark atoms. The predicted ratio of densities of dark atoms and baryonic matter determines the condition for dark atoms to dominate in the cosmological dark matter. To satisfy this condition of the dark-atom nature of the observed dark matter, the mass of new stable $-2n$ charged particles should be within reach of the LHC for their searches. We discuss the possibilities of dark-atom binding in multi-atom systems and present state-of-the-art quantum mechanical descriptions of dark-atom interactions with nuclei. Annual modulations in such interactions with nuclei of underground detectors can explain the positive results of DAMA/NaI and DAMA/LIBRA experiments and the negative results of the underground WIMP searches. Full article

We assess a scheme for measurement-free quantum teleportation from the perspective of the resources underpinning its performance. In particular, we focus on claims recently made about the crucial role played by the degree of non-Markovianity of the dynamics of the information carrier whose state we aim to teleport. We prove that any link between the efficiency of teleportation and the back-flow of information depends fundamentally on the way the various operations entailed by the measurement-free teleportation protocol are implemented while—in general—no claim of causal link can be made. Our result reinforces the need for the explicit assessment of the underlying physical platform when assessing the performance and resources for a given quantum protocol and the need for a rigorous quantum resource theory of non-Markovianity. Full article

Using a high-precision code, we generate the eigenstates of a PT-symmetric Hamiltonian. We solve the time-dependent Schrödinger equation (TDSE) of the non-Hermitian system based on the eigenset. Since the formulation is relatively new and the observables are calculated differently than conventional quantum mechanics, we justify it with a paradigmatic case in Hermitian quantum mechanics. We present the harmonic generation spectra on some model PT-Hamiltonians driven by an electric pulse. We discuss the physical differences with the harmonic spectra of a pulse-driven atom. Full article

The Fermi–Dirac and Bose–Einstein statistics are considered to be key concepts in quantum mechanics, and they are used to explain the occupancy limit of electron orbitals. We investigate the physical origin of these two statistics and uncover that the key determining factor is whether an individual electron spin is measurable or not. Microscopically, a system with individually measurable electron spins corresponds to the presence of Larmor spin precession in electron–electron interactions, while the non-measurability of individual electron spins corresponds to the absence of Larmor spin precession. Both interaction types are possible, and the favored interaction type is thermodynamically determined. The absence of Larmor spin precession is realized in coherent electron states, and coherent electrons therefore obey Bose–Einstein statistics. Full article

The objective of this research work is the study of the inhibitory effect of Warionia saharea essential oil (WSEO) on the corrosion of mild steel (MS) in molar HCl solution, employing both experimental and theoretical methods. This inhibitory effect (IE) has been evaluated by using a combination of weight loss measurements (LW) and various electrochemical methods, such as open circuit potential (OCP), potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) experiments. The LW results indicated that IE increased with inhibitor concentration, reaching 83.34% at 3.00 g/L. The PDP analysis suggested that WSEO functions as a mixed inhibitor, while in the EIS results the R_ct values increased with inhibitor concentration to reach 165.8 Ω cm² at 2.00 g/L, suggesting a defensive film formation by WSEO molecules over the metallic surface. The thermodynamic study demonstrated that the WSEO molecules adsorption on the MS surface followed a Langmuir isotherm, involving mixed physical and chemical (physicochemical) adsorption on the MS surface. Theoretical methods, including density functional theory (DFT) and molecular dynamics (MD) simulations, were employed to elucidate the inhibition mechanisms of the three main components of WSEO. The quantum chemical analysis, using density functional theory (DFT) and molecular dynamics (MD) simulations, showed a low ΔE_gap value of 6.30 eV and a low adsorption energy (E_ads) value on an Fe (110) substrate of −258 Kcal/mol for (E)-Nerolidol, indicating the significant contribution of this molecule to the overall corrosion inhibition effect of WSEO. The scanning electron microscope (SEM) analysis verified the presence of a protective film formed by the inhibitor on the MS surface. This study highlights the potential of WSEO as a sustainable and green corrosion inhibitor in acidic environments. Full article

In recent years, near-infrared (NIR) phosphors have attracted great research interest due to their unique physical properties and broad application prospects. However, obtaining NIR phosphors with both high quantum efficiency and excellent thermal stability remains a great challenge. In this study, novel NIR Ca₃Mg₂ZrGe₃O₁₂:Cr³⁺ phosphors were successfully prepared using a high-temperature solid-phase method, and the structure and luminescent properties of the material were systematically investigated. Ca₃Mg₂ZrGe₃O₁₂:0.01Cr³⁺ emits NIR light in the range of 600 to 900 nm with a peak at 758 nm and a half-height width of 89 nm under the excitation of 457 nm blue light. NIR luminescence shows considerable quantum efficiency, and the internal quantum efficiency of the optimized sample is up to 68.7%. Remarkably, the Ca₃Mg₂ZrGe₃O₁₂:0.01Cr³⁺ phosphor exhibits a near-zero thermal quenching behavior, and the luminescence intensity of the sample at 250 °C maintains 92% of its intensity at room temperature. The mechanism of high thermal stability has been elucidated by calculating the Huang Kun factor and activation energy. Finally, NIR pc-LED devices prepared from Ca₃Mg₂ZrGe₃O₁₂:0.01Cr³⁺ phosphor with commercial blue LED chips have good performance, proving that this Ca₃Mg₂ZrGe₃O₁₂:0.01Cr³⁺ NIR phosphor has potential applications in night vision and biomedical imaging. Full article

In this paper, we review and compare the stochastic quantum mechanics of Nelson and the scale relativity theory of Nottale. We consider both nonrelativistic and relativistic frameworks and include the electromagnetic field. These theories propose a derivation of the Schrödinger and Klein–Gordon equations from microscopic processes. We show their formal equivalence. Specifically, we show that the real and imaginary parts of the complex Lorentz equation in Nottale’s theory are equivalent to the Nelson equations, which are themselves equivalent to the Madelung and de Broglie hydrodynamical representations of the Schrödinger and Klein–Gordon equations, respectively. We discuss the different physical interpretations of the Nelson and Nottale theories and stress their strengths and weaknesses. We mention potential applications of these theories to dark matter. Full article

This review provides a summary of the existing literature on a crucial raw material for the production of isotopically pure semiconductors, which are essential for the development of second-generation quantum systems. Silicon-28-tetrafluoride (²⁸SiF₄) is used as an educt for several isotope-engineered chemicals, such as silane-28 (²⁸SiH₄) and silicon-28-trichloride (²⁸SiHCl₃), which are needed in the pursuit of various quantum technologies. We are exploring the entire chain from the synthesis of ²⁸SiF₄ to quantum applications. This includes the chemical properties of SiF₄, isotopic enrichment, conversion to silanes, conversion to bulk ²⁸Si and thin films, the physical properties of ²⁸Si (spin neutrality, thermal conductivity, optical properties), and the applications in quantum computing, photonics, and quantum sensing techniques. Full article

Mercury ion (Hg²⁺) is one of the most toxic pollutants that can exist throughout the environment and be diffused into water, soil, air, and eventually the food chain. Even a very low level of Hg²⁺ diffused in living organisms can hurt their DNA and cause the permanent damage of the central nervous system and a variety of consequential disorders. Hence, the development of a sensitive and specific method for the detection of Hg²⁺ at trace ranges is extremely important as well as challenging. Fluorometric detection assays based on graphene quantum dots (GQDs) and carbon quantum dots (CQDs) offer considerable potential for the determination and monitoring of heavy metals due to their fascinating properties. Although the quantum yield of GQDs and CQDs is sufficient for their use as fluorescent probes, doping with heteroatoms can significantly improve their optical properties and selectivity toward specific analytes. This review explores the primary advances of CQDs and GQDs in their great electronic, optical, and physical properties, their synthetic methods, and their use in Hg²⁺ fluorimetry detection. Full article

Carbon dots (CDs) have garnered extensive interest in basic physical chemistry as well as in biomedical applications due to their low cost, good biocompatibility, and great aqueous solubility. However, the synthesis of multi-functional carbon dots has always been a challenge for researchers. Here, we synthesized novel CDs with a high quantum yield of 28.2% through the straightforward hydrothermal method using Diaminomaleonitrile and Boc-D-2, 3-diaminopropionic acid. The size, chemical functional group, and photophysical properties of the CDs were characterized by TEM, FTIR, XPS, UV, and fluorescence. It was demonstrated in this study that the prepared CDs have a high quantum yield, excellent photostability, and low cytotoxicity. Regarding the highly water-soluble property of CDs, they were proven to possess selective and sensitive behavior against Cu²⁺ ions (linear range = 0–9 μM and limit of detection = 1.34 μM). Moreover, the CDs were utilized in fluorescent ink in anti-counterfeiting measures. Because of their low cytotoxicity and good biocompatibility, the CDs were also successfully utilized in cell imaging. Therefore, the as-prepared CDs have great potential in fluorescence sensing, anti-counterfeiting, and bioimaging. Full article

In this study, self-assembled halide perovskite quantum wire bundles (QWBs)/quantum dots (QDs) are fabricated using a room temperature-based formation method. The one-dimensional (1D) perovskite-based QWB structures incorporate zero-dimensional QDs within a composite quantum structure. Transmission electron microscopy reveals that quantum wires with diameters ranging from tens of nanometers to approximately 200 nm maintain a single-crystal atomic arrangement in a bundle form. Conversely, QDs are uniformly distributed within the single-phase wire and appear as black dots < 10 nm. Photoluminescence analysis identifies the multiband characteristics of the emissions. The 420–440 nm band is attributed to 1D QWB, whereas the peak appearing in the 530–550 nm range corresponds to lead halide PbBr₂ QDs. Thus, the proposed self-assembled 1D QWB/QD composite structure exhibits novel multiband physical properties in the 420–440 and 530–550 nm bands; it offers new opportunities for designing materials with potential applications in optoelectronic devices. Full article

Since its inception, the intricate mathematical formalism of quantum mechanics has empowered physicists to describe and predict specific physical events known as quantum processes. However, this success in probabilistic predictions has been accompanied by a profound challenge in the ontological interpretation of the theory. This interpretative complexity stems from two key aspects. Firstly, quantum mechanics is a fundamental theory that, so far, is not derivable from any more basic scientific theory. Secondly, it delves into a realm of invisible phenomena that often contradicts our intuitive and commonsensical notions of matter and causality. Despite its notorious difficulties of interpretation, the most widely accepted set of views of quantum phenomena has been known as the Copenhagen interpretation since the beginning of quantum mechanics. According to these views, the correct ontological interpretation of quantum mechanics is incompatible with ontological realism in general and with philosophical materialism in particular. Anti-realist and anti-materialist interpretations of quantum matter have survived until today. This paper discusses these perspectives, arguing that materialistic interpretations of quantum mechanics are compatible with its mathematical formalism, while anti-realist and anti-materialist views are based on wrong philosophical assumptions. However, although physicalism provides a better explanation for quantum phenomena than idealism, its downward reductionism prevents it from accounting for more complex forms of matter, such as biological or sociocultural systems. Thus, the paper argues that neither physicalism nor idealism can explain the universe. I propose then a non-reductionistic form of materialism called inclusive materialism. The conclusion is that the acknowledgment of the qualitative irreducibility of ontological emergent levels above the purely physical one does not deny philosophical materialism but enriches it. Full article

Rudolf Haag’s Local Quantum Physics (LQP) is an alternative framework to conventional relativistic quantum field theory for combining special relativity and quantum theory based on first principles, making it of great interest for the purposes of conceptual analysis despite currently being relatively limited as a tool for making experimental predictions. In LQP, the elementary particles are defined as species of causal link between interaction events, together with which they comprise its most fundamental entities. This notion of particle has yet to be independently assessed as such. Here, it is captured via a set of propositions specifying particle characteristics and then compared to previous particle notions. Haag’s particle differs decisively with respect to mechanical intuitions about particles by lacking, among other things, even an approximate independent space–time location. This notion is thus found to differ greatly even from those of relativistic quantum mechanics and quantum field theory, which have been applied to the known elementary particles. Full article

The purpose of this work is to examine the nature of the historically observed and empirically described by the Pareto law inequality in the distribution of wealth and income in an economic system. This inequality is presumed to be the result of unequal opportunity by its members. An analytical model of the economic system consisting of a large number of actors, all having equal access to its total wealth (or income) has been developed that is formally represented by a scale-free network comprised of nodes (actors) and links (states of wealth or income). The dynamic evolution of the complex network can be mapped in turn, as is known, into a system of quantum particles (links) distributed among various energy levels (nodes) in thermodynamic equilibrium. The distribution of quantum particles (photons) at different energy levels in the physical system is then derived based on statistical thermodynamics with the attainment of maximal entropy for the system to be in a dynamic equilibrium. The resulting Planck-type distribution of the physical system mapped into a scale-free network leads naturally into the Pareto law distribution of the economic system. The conclusions of the scale-free complex network model leading to the analytical derivation of the empirical Pareto law are multifold. First, any complex economic system behaves akin to a scale-free complex network. Second, equal access or opportunity leads to unequal outcomes. Third, the optimal value for the Pareto index is obtained that ensures the optimal, albeit unequal, outcome of wealth and income distribution. Fourth, the optimal value for the Gini coefficient can then be calculated and be compared to the empirical values of that coefficient for wealth and income to ascertain how close an economic system is to its optimal distribution of income and wealth among its members. Fifth, in an economic system with equal opportunity for all its members there should be no difference between the resulting income and wealth distributions. Examination of the wealth and income distributions described by the Gini coefficient of national economies suggests that income and particularly wealth are far off from their optimal value. We conclude that the equality of opportunity should be the fundamental guiding principle of any economic system for the optimal distribution of wealth and income. The practical application of this conclusion is that societies ought to shift focus from policies such as taxation and payment transfers purporting to produce equal outcomes for all, a goal which is unattainable and wasteful, to policies advancing among others education, health care, and affordable housing for all as well as the re-evaluation of rules and institutions such that all members in the economic system have equal opportunity for the optimal utilization of resources and the distribution of wealth and income. Future research efforts should develop the scale-free complex network model of the economy as a complement to the current standard models. Full article