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Search Results (304)

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36 pages, 13081 KiB  
Article
Domestic and Productive Earthen Architecture Conserved in Situ in Archaeological Sites of the Iberian Peninsula
by Sergio Manzano-Fernández, Camilla Mileto, Fernando Vegas López-Manzanares and Valentina Cristini
Heritage 2024, 7(9), 5174-5209; https://doi.org/10.3390/heritage7090244 (registering DOI) - 14 Sep 2024
Viewed by 211
Abstract
For past societies on the Iberian Peninsula, one of the most prolific architectures was earthen construction, with a wealth of typologies and solutions derived from the legacy of local construction and materials. However, its study within the field of archaeology has been limited. [...] Read more.
For past societies on the Iberian Peninsula, one of the most prolific architectures was earthen construction, with a wealth of typologies and solutions derived from the legacy of local construction and materials. However, its study within the field of archaeology has been limited. The challenges posed by conservation, archaeological identification and social recognition have traditionally limited the dissemination of this type of architecture. Its low profile is perceived as fragile once the original protections collapse. The ethnological information preserved and linked to past ways of life and societies is crucial to the interpretation of the cultural development handed down over generations by different communities and now transmitted to the general public through archaeological sites. This research aims to provide an overview of the main earthen vestiges from domestic, productive and funerary architecture dating from the prehistoric, protohistoric, Roman and medieval periods. For this, a bibliographical review and data collection through fieldwork were conducted for numerous case studies. These included the classification of materials, compositions and construction techniques, creating an integrated comprehensive database with information on geography, measurements and the general state of conservation. Full article
28 pages, 10508 KiB  
Article
Interdisciplinary Analysis and the Role of Experiments in Raw Materials and Technology Identification for Prehistoric Pottery in the Bistrița River Basin (Romania)
by Ana Drob, Neculai Bolohan, Viorica Vasilache, Bogdan-Gabriel Rățoi and Mihai Brebu
Heritage 2024, 7(9), 5120-5147; https://doi.org/10.3390/heritage7090242 - 13 Sep 2024
Viewed by 431
Abstract
The paper presents an interdisciplinary study based on an experimental model for investigating clay sources to identify prehistoric human behavior regarding resources. The study focuses on the Middle Bronze Age (1955/1773–1739/1614 cal. BC) settlement of Siliştea-Pe Cetățuie in eastern Romania, where archaeological [...] Read more.
The paper presents an interdisciplinary study based on an experimental model for investigating clay sources to identify prehistoric human behavior regarding resources. The study focuses on the Middle Bronze Age (1955/1773–1739/1614 cal. BC) settlement of Siliştea-Pe Cetățuie in eastern Romania, where archaeological materials from the Costișa and Monteoru cultures were discovered. Standard criteria for macroscopic analysis and analytical techniques, such as optical microscopy (OM), Scanning Electron Microscopy with Energy Dispersive X-ray Spectroscopy (SEM-EDX), Micro-Fourier Transform Infrared Spectroscopy (µ-FTIR), and thermal analysis (DTA and TG), were used to investigate the ceramic material from multiple points of view. The results showed that there were no significant differences between the ceramics of the two communities. Putting together the data obtained from macroscopic and physico-chemical analyses helped in partially reconstructing ancient human behaviors related to the production and use of ceramic vessels. Full article
(This article belongs to the Special Issue Recent Progress in Cultural Heritage Diagnostics)
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<p>Map showing the clay samples used in the experiment’s source areas: (<b>a</b>)—Sources S1 and S2 (clay deposit); (<b>b</b>)—Sources S3 and S4 (slope of the settlement).</p>
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<p>(<b>I</b>) The clay samples collected: (<b>a</b>) crushed; (<b>b</b>) sieved. (<b>II</b>) The test samples obtained after firing: (<b>a</b>)—450 °C; (<b>b</b>)—700 °C; (<b>c</b>)—900 °C.</p>
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<p>OM images of the Costișa ceramic fragments from Siliștea-<span class="html-italic">Pe Cetățuie</span> (50× magnification).</p>
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<p>OM images of the Monteoru ceramic fragments from Siliștea-<span class="html-italic">Pe Cetățuie</span> (50× magnification).</p>
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<p>Mineralogical section of fragment C9: Q—quartz; Mu—muscovite; Fp—plagioclase feldspar; L—limestone lithoclast; M—amorphic matrix ((<b>a</b>)—parallel nicoli; (<b>b</b>)—cross nicoli).</p>
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<p>Mineralogical section of fragment C23: Q—quartz; Qp—polycrystalline quartz; Mu—muscovite; Fp—plagioclase feldspar; Lc—sandstone lithoclast; M—amorphic matrix ((<b>a</b>)—parallel nicoli; (<b>b</b>)—cross nicoli).</p>
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<p>Mineralogical section of fragment M2: Q—quartz; Mu—muscovite ((<b>a</b>)—parallel nicoli; (<b>b</b>)—cross nicoli).</p>
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<p>Mineralogical section of fragment M15: Q—quartz; Mu—muscovite; Ah—hematite aggregates; Cc—ceramoclaste; Fp—plagioclase feldspar; Pp—primary pores ((<b>a</b>)—parallel nicoli; (<b>b</b>)—cross nicoli).</p>
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<p>SEM micrographs of the Costișa pottery clay matrix (C1–C24) from Siliștea-<span class="html-italic">Pe Cetățuie</span> (200× magnification).</p>
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<p>SEM micrographs of the Monteoru pottery clay matrix (M1–M24) from Siliștea-<span class="html-italic">Pe Cetățuie</span> (200× magnification).</p>
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<p>FTIR spectra for the Costișa pottery clay matrix from Siliștea-<span class="html-italic">Pe Cetățuie</span>.</p>
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<p>FTIR spectra for the Monteoru pottery clay matrix from Siliștea-<span class="html-italic">Pe Cetățuie</span>.</p>
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<p>OM images of the clay samples used in the experimental study: (<b>a</b>) unfired clay; (<b>b</b>) 450 °C; (<b>c</b>) 700 °C; (<b>d</b>) 900 °C (50× magnifications).</p>
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<p>Mineralogical section of sample S2: Q—quartz; Lc—limestone lithoclaste; Mu—muscovite; Fp—plagioclase feldspars; C—calcite; O—oolite; B—foraminifera <span class="html-italic">Ammonia beccarii</span>, <span class="html-italic">Porosononion subranosus</span>, and <span class="html-italic">Bulimina</span> sp. and calcareous algae ((<b>a</b>): parallel nicoli; (<b>b</b>): crossed nicoli).</p>
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<p>Mineralogical sections of sample S4: Q—quartz; Qm—monocrystalline quartz; Qp—polycrystalline quartz; Lt—possible volcanic lithoclast; Mu—muscovite; Fp—plagioclase feldspars; C—calcite; B—plant fragment ((<b>a</b>): parallel nicoli; (<b>b</b>): crossed nicoli).</p>
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<p>FTIR spectra for the clay sources: (<b>a</b>)—450 °C; (<b>b</b>)—700 °C; (<b>c</b>)—900 °C (Blue—S1; Red—S2; Green—S3; Orange—S4).</p>
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<p>DTA (<b>a</b>) and TG/DTG (<b>b</b>) curves for samples C3, M17, and source S2.</p>
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<p>DTA (<b>a</b>) and TG/DTG (<b>b</b>) curves for samples C24, M21, and source S4.</p>
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17 pages, 15568 KiB  
Article
Pleistocene Glacial Transport of Nephrite Jade from British Columbia, Canada, to Coastal Washington State, USA
by George E. Mustoe
Geosciences 2024, 14(9), 242; https://doi.org/10.3390/geosciences14090242 - 9 Sep 2024
Viewed by 268
Abstract
Since prehistoric times, indigenous residents of southwest British Columbia, Canada, collected water-worn nephrite specimens from the gravel bars along the Fraser River, using the stone for the manufacture of tools that were widely traded with other tribes. Allochthonous nephrite occurs in another geologic [...] Read more.
Since prehistoric times, indigenous residents of southwest British Columbia, Canada, collected water-worn nephrite specimens from the gravel bars along the Fraser River, using the stone for the manufacture of tools that were widely traded with other tribes. Allochthonous nephrite occurs in another geologic setting. Late Pleistocene continental glaciers transported nephrite and many other rock types from western Canada to northwest Washington State, producing extensive sediment deposits that border the Salish Sea coast in Whatcom and Island Counties, Washington. This material was little utilized by indigenous residents, but “black jade” specimens are prized by modern collectors. The depositional history and mineralogy of this material has received little attention. X-ray diffraction and SEM/EDS analyses indicate that the Salish Sea “black jade” is a form of impure nephrite that probably originated from metamorphism of a mafic igneous parent material (metabasite). The texture consists of prismatic amphibole crystals (ferro-actinolite) set in a matrix rich in plagioclase feldspar. Pyrite inclusions are locally present. A second material, sometimes erroneously labelled “muttonfat jade” by amateur collectors, consists of an intermixture of quartz and sillimanite. Full article
(This article belongs to the Section Cryosphere)
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<p>Tectonic setting of the western Washington and Canada. (<b>A</b>) Ophiolite complex geologic sequence (not to scale). (<b>B</b>). Cascadia Subduction Zone. Both images have been adapted from Creative Commons 3.0 licensed mages: (<b>A</b>) Wikipedia.org file: Ofioliti.org.svg). (<b>B</b>) U.S. Geological Survey graphics.</p>
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<p>Occurrences of ultramafic bedrock in western Washington, USA.</p>
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<p>Regional map of the Salish Sea, which includes the Straits of Georgia and Juan de Fuca and the complex channels and embayments of Puget Sound.</p>
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<p>Maps of Salish Sea coast showing cobblestone beaches where erosion of glacial sediment releases nephrite and related materials.</p>
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<p>Naturally polished pebble and cobble of Salish Sea “black jade”.</p>
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<p>The author with a “black jade” boulder exposed in the intertidal zone, Swantown beach, Whidbey Island, WA. This specimen was transported as a glacial erratic, eroded in modern time from late Pleistocene sediment that forms a cliff bordering the coastline (visible in background). 2024 photo by Wendy Walker, used with permission.</p>
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<p>Late Pleistocene advance of the continental glacier was dominantly from north to south. During interglacial intervals, sediment was transported southwest by the Thompson River and the Fraser River Red arrows show ice flow directions, as determined from glacial striations and geomorphic features. Map adapted from [<a href="#B11-geosciences-14-00242" class="html-bibr">11</a>,<a href="#B25-geosciences-14-00242" class="html-bibr">25</a>].</p>
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<p>Granitic glacial erratics at Point Whitehorn. A large angular erratic is weathering out of the coastal bluff, evidence that the sediment at this location arrived as ice-transported material, not from fluvial transport.</p>
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<p>“Black jade” (nephrite) occurs along the Salish Sea coast on cobbled beaches adjacent to high banks of Pleistocene sediment. (<b>A</b>) Point Whitehorn coast in northwestern Whatcom County, Washington. (<b>B</b>) Cobblestone beach at Libbey Beach County Park, Whidbey Island, Island County, Washington. (<b>C</b>) Nephrite pebble (red arrow) can be seen eroding from a stratum that contains water-worn clasts set in a matrix of outwash sand, Point Whitehorn. (<b>D</b>) Nephrite cobble partially encrusted with barnacles in the upper intertidal zone at Swantown beach, Whidbey Island. 2024 photos by the author.</p>
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<p>Typical XRD pattern for the Salish Sea “black jade”.</p>
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<p>Backscattered electron (BSE) images of the Salish Sea “black jade”. (<b>A</b>) Prismatic amphibole crystals in an albite-rich matrix. (<b>B</b>) Amphibole crystal cluster showing deformation curvature. Smaller angular crystals are albite. (<b>C</b>) Polished surface showing radiating amphibole crystals in an albite-rich matrix that contains small silicate mineral inclusions. A small pyrite inclusion is marked with an arrow. (<b>D</b>) High magnification view of albite crystals with scattered flakes of biotite. (<b>E</b>) Large pyrite inclusions bordered by quartz (dark gray). Medium gray zones are albite-rich matrix, with radiating needles of amphibole visible at right. (<b>F</b>) Close-up view of a pyrite inclusion showing linear morphology. Pyrite was identified based on EDS spectra that showed Fe and S as the components.</p>
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<p>Salish Sea specimen showing blocky morphology of amphibole. (<b>A</b>) Light areas are amphibole; dark areas are albite rich. (<b>B</b>) Magnetite inclusion in an amphibole crystal.</p>
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<p>SEM/EDS maps showing distribution of major elements. Amphibole crystal clusters contain abundant Fe and Mg. Elevated Na levels indicate that the plagioclase is albite. Small inclusions are presumed to be biotite because of their high K content and tabular shape.</p>
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<p>Mg/(Mg + Fe) atomic ratios for six Salish Sea amphibole crystals show the ferro-actinolite composition.</p>
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<p>Felted microtexture of Washington nephrite. (<b>A</b>) Backscattered electron image of polished nephrite, specimen WWU-DC-3. Felted microtexture of Washington nephrite. (<b>B</b>) SEM image, nephrite specimen WWU-DC-4. (<b>C</b>) Specimen DC-4, showing partial alignment of tremolite microcrystals. (<b>D</b>) Specimen WWU-DC-2 has randomly ordered bladed microcrystals.</p>
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<p>BSE images of black nephrite from Perth region of Western Australia. (<b>A</b>) Secondary image showing interlocking prismatic crystals of actinolite. (<b>B</b>) Secondary electron image of another area in the same small specimen.</p>
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<p>Sillimanite/quartz assemblage. (<b>A</b>) Sawn surface of a typical specimen. (<b>B</b>) Thin section photographs showing quartz (white) and sillimanite (yellowish brown). The parallel alignment of crystals is a result of metamorphic foliation. Specimen WWU-SILL-1.</p>
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18 pages, 4239 KiB  
Article
The Role of Mineral and Organic Composition on the Phosphorus Content of Prehistoric Pottery (Middle Neolithic to Late Bronze Age) from NW Spain
by María Guadalupe Castro González, María Pilar Prieto Martínez and Antonio Martínez Cortizas
Minerals 2024, 14(9), 880; https://doi.org/10.3390/min14090880 - 29 Aug 2024
Viewed by 342
Abstract
Phosphorus is a key element for identifying past human activity. Recently, phosphorus analyses have been extended to archaeological objects, aiming at distinguishing how depositional contexts contribute to its enrichment. In archaeological pottery, phosphorus might depend on several manufacturing and postdepositional processes (i.e., addition [...] Read more.
Phosphorus is a key element for identifying past human activity. Recently, phosphorus analyses have been extended to archaeological objects, aiming at distinguishing how depositional contexts contribute to its enrichment. In archaeological pottery, phosphorus might depend on several manufacturing and postdepositional processes (i.e., addition of organic temper, pigments, diagenetic incorporation). We analyzed by XRD, XRF, and mid-infrared (FTIR-ATR) spectroscopy 178 pots from eight NW Spain archaeological sites. These sites encompass different chronologies, contexts, and local geology. The phosphorus content was highly variable (224–27,722 mg kg−1) overall but also between archeological sites (1644 ± 487 to 13,635 ± 6623 mg kg−1) and within archaeological sites (4–36, max/min ratio). No phosphate minerals were identified by XRD nor FTIR-ATR, but correlations between phosphorus content and MIR absorbances showed maxima at 1515 and 980 cm−1, suggesting the presence of two sources: one organic (i.e., phosphorylated aromatic compounds) and another inorganic (i.e., albite and K-feldspar). Phosphorylated aromatics were most likely formed during pottery firing and were preserved due to their high resistance to temperature and oxidation. Meanwhile, albite and K-feldspar are among the P-bearing minerals with higher P concentrations. Our results suggest that P content is related to intentional and non-intentional actions taken in the pottery production process. Full article
(This article belongs to the Special Issue The Significance of Applied Mineralogy in Archaeometry)
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<p>Location of the selected sites in Galicia (NW Spain). The symbols represent the functional features of each site. Base maps: CNIG—<a href="https://centrodedescargas.cnig.es/CentroDescargas/busquedaSerie.do?codSerie=02102-BTN25" target="_blank">https://centrodedescargas.cnig.es/CentroDescargas/busquedaSerie.do?codSerie=02102-BTN25</a> (accessed on 17 May 2024) and Eurostat/GISCO—<a href="https://ec.europa.eu/eurostat/web/gisco/geodata/administrative-units/countries" target="_blank">https://ec.europa.eu/eurostat/web/gisco/geodata/administrative-units/countries</a> (accessed on 04/06/2024). Figure created using QGIS 3.28.12. QGIS.org, 2023. QGIS Geographic Information System. QGIS Association. <a href="http://www.qgis.org" target="_blank">http://www.qgis.org</a> (accessed on 24 August 2024).</p>
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<p>Mineralogy of the studied sherds (number of sherds samples of each site in which the mineral was present). QZ: quartz; PG: plagioclase; KF: K feldspar; MC: micas; AM: amphibole; CH: chlorite; KA: kaolinite; TA: talc; IOX: iron oxides; SP: serpentine; EP: epidote. Yellow: sites on areas of felsic lithologies; orange: sites on areas of mafic lithologies.</p>
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<p>Phosphorus concentration (log scale) of the studied sherds (mg kg<sup>−1</sup>). Upper panel, sites on areas dominated by felsic geological materials; lower panel, sites from areas dominated by mafic materials.</p>
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<p>Projections of the loadings of chemical elements (<b>left</b>) and the scores of the samples (<b>right</b>). Yellow: pots from archaeological sites on areas of felsic lithologies; orange: pots from sites on areas of mafic lithologies.</p>
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<p>Scores of the analyzed sherds for the three extracted components. Left, sites on areas dominated by felsic geologic materials; right, sites from areas dominated by mafic materials. Sites: AD, A Devesa de Abaixo; FZ, Fraga do Zorro; GD: Guidoiro Areoso; AM: AS Mamelas; AL: A Lagoa; DR: Devesa do Rei; OE: Os Escurros; RQ: Requeán. Yellow: sites on areas of felsic lithologies; orange: sites on areas of mafic lithologies.</p>
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<p>Mid-infrared spectra of the samples analyzed in each archaeological site. Sites: AD: A Devesa de Abaixo; FZ: Fraga do Zorro; GD: Guidoiro Areoso; AM: AS Mamelas; AL: A Lagoa; DR: Devesa do Rei; OE: Os Escurros; RQ: Requeán.</p>
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<p>(<b>A</b>) Correlation spectra for P (light gray line) and G-Cp2 (black line). (<b>B</b>) FreeViz graphs using as target variables P (log)concentrations and G-Cp2 scores, and selected bands of the correlation spectra (normalized absorbances) as influencing variables. (<b>C</b>) Spectra of albite and microcline (a.u., absorbance units) obtained from the RRUFF database—<a href="https://rruff.info/" target="_blank">https://rruff.info/</a> (accessed on 24 August 2024).</p>
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<p>Left, scatterplot of observed and expected G-Cp2 scores. Right, distribution of weights of the four contributors (wOM: organic compounds; wAb: albite; wSrRb: Sr/Rb ratio; wKF: K-feldspar) to the G-Cp2 modeled by multilinear regression. Sites: AD: A devesa de Abaixo; FZ: Fraga do Zorro; GD: Guidoiro Areoso; AM: AS Mamelas; AL: A Lagoa; DR: Devesa do Rei; OE: Os Escurros; RQ: Requeán.</p>
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14 pages, 11864 KiB  
Article
Prehistoric Recycling Explained in a Playful Way: The Pfahlbauten Wimmelbild—An Interactive Digital Mediation Tool Designed by Young People
by Helena Seidl da Fonseca, Fiona Leipold and Karina Grömer
Heritage 2024, 7(9), 4617-4630; https://doi.org/10.3390/heritage7090217 - 23 Aug 2024
Viewed by 950
Abstract
With the “Talents Internship program” established by the Austrian Research Promotion Agency (FFG, Österreichische Forschungsförderungsgesellschaft), 14- to 17-year-old students from various school types visited the Natural History Museum and the Kuratorium Pfahlbauten in summer 2022 to gain practical experience in research. The internship [...] Read more.
With the “Talents Internship program” established by the Austrian Research Promotion Agency (FFG, Österreichische Forschungsförderungsgesellschaft), 14- to 17-year-old students from various school types visited the Natural History Museum and the Kuratorium Pfahlbauten in summer 2022 to gain practical experience in research. The internship focused on a sustainability approach, discussing recycling methods, the sustainable use of resources and the circular economy in prehistory. The UNESCO World Heritage “Prehistoric Pile Dwellings around the Alps” was used as a research area for the project. The project also aimed to make the content developed by the students available to the public as a digital media tool. The pupils brought an illustration of a prehistoric lake shore settlement to life and created an interactive image available at the website of Kuratorium Pfahlbauten. Various scenes of the illustration have been augmented with animations created by the students of HTL Spengergasse in Vienna. Students from federal secondary schools from Vienna (Stubenbastei) and Upper Austria (Traun) researched the information about the objects and wrote texts that, as a description of the animated videos, introduce the users to the prehistoric artifact and explain the recycling process behind it. The students worked independently using the scientific literature, 140-year-old inventory books and 6000-year-old objects from the collection of the Natural History Museum Vienna. The activities and the supporting program within the internship were recorded by the students in blog posts, available at the Pfahlbauten-Blog. The co-creative approach of the FFG Talent Internship made it possible to introduce a group of school students to the process of scientific work and the communication of results. It was honored with the Creative App Award at CHNT 2023. Full article
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<p>“Deck 50”—a new dissemination room at the Natural History Museum Vienna ©. Natural History Museum Vienna.</p>
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<p>Visitors come into contact with scientists at the event “<span class="html-italic">Archäologie am Berg</span>” in Hallstatt ©. Kuratorium Pfahlbauten.</p>
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<p>UNESCO World Heritage Site <span class="html-italic">See am Mondsee</span> at Lake Mondsee in Upper Austria. © Kuratorium Pfahlbauten.</p>
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<p>Information pavilion of the UNESCO World Heritage “Prehistoric Pile dwellings around the Alps” at Lake Attersee, Upper Austria. © Kuratorium Pfahlbauten.</p>
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<p>The graphic basis—a playful illustration about Neolithic life in a pile-dwelling village. © Kuratorium Pfahlbauten. Illustrator: Leopold Maurer.</p>
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<p>The <span class="html-italic">Pfahlbauten Wimmelbild</span>—<a href="https://www.pfahlbauten.at/wimmelbild" target="_blank">https://www.pfahlbauten.at/wimmelbild</a> (accessed on 22 August 2024) illustration © Kuratorium Pfahlbauten, illustrator: Leopold Maurer, object images © Study Collection of the Institute of Prehistory and Early History of the University of Vienna, photographer: Violetta Reiter.</p>
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<p>Student digging up interesting information about prehistoric objects from scientific publications. © Kuratorium Pfahlbauten.</p>
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<p>The mind board—putting all of the puzzle pieces together. © Kuratorium Pfahlbauten.</p>
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<p>Scenes from the illustration were redrawn by the students and served as the basis for the animations. © Kuratorium Pfahlbauten.</p>
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<p>The students created the short animations independently using the software Toon Boom. © Kuratorium Pfahlbauten.</p>
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<p>Students presenting the final product and their working steps. © Natural History Museum Vienna.</p>
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<p>The publication of the web application was presented in the science communication room “Deck 50” of the Natural History Museum. © Natural History Museum Vienna.</p>
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13 pages, 5316 KiB  
Review
The Use of Heterocyclic Azo Dyes on Different Textile Materials: A Review
by Lucia Emanuele and Maurizio D’Auria
Organics 2024, 5(3), 277-289; https://doi.org/10.3390/org5030015 - 20 Aug 2024
Viewed by 351
Abstract
The art of dyeing textiles has a long history, as natural dyes have been used since prehistoric times. With the development of synthetic dyes in the 19th century, the focus shifted from natural to synthetic dyes due to their superior properties. Recently, however, [...] Read more.
The art of dyeing textiles has a long history, as natural dyes have been used since prehistoric times. With the development of synthetic dyes in the 19th century, the focus shifted from natural to synthetic dyes due to their superior properties. Recently, however, interest in natural dyes has increased again due to environmental and health concerns. Among industrial dyes, heterocyclic dyes, especially azo dyes, are of great importance due to their color brilliance and fastness. This review examines the synthesis, application, and analysis of azo dyes, especially heterocyclic dyes. It deals with monoazo, diazo, and polyazo dyes and highlights their structures, synthesis methods, and fastness properties. In addition, the ecological impact of azo dyes and practical solutions for their synthesis and application are discussed. Full article
(This article belongs to the Special Issue Chemistry of Heterocyclic Compounds)
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<p>Structure of indigo and Tyrian purple.</p>
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<p>Synthesis of azo compounds.</p>
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<p>Scheme of D-π-A azo compounds.</p>
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<p>Energy profile for the interconversion between the two isomers A and B [<a href="#B9-organics-05-00015" class="html-bibr">9</a>].</p>
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<p>Isomerization E–Z for azo compounds.</p>
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<p>The E and Z isomers of azobenzene<b>.</b></p>
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<p>Structures of heteroaromatic amines.</p>
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<p>General structure of dyes <b>7a</b>–<b>k</b>.</p>
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<p>The general structure of dyes <b>8a</b>–<b>g</b>.</p>
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<p>The general structure of dyes <b>9a</b>–<b>c</b>.</p>
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<p>Structure of: (<b>a</b>) a brown dye, (<b>b</b>) a blue dye, (<b>c</b>) an orange dye.</p>
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<p>Synthesis process of diazo dyes <b>12a</b>–<b>j</b>.</p>
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<p>Tautomeric forms ketone–enol for diazo compounds <b>12a</b>–<b>b</b>.</p>
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<p>Tautomeric forms enamine–imine for diazo compounds <b>12a</b>, <b>12c</b>, <b>12e</b>, <b>12g</b>, and <b>12i</b>.</p>
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<p>Synthesis and molecular structures of pyrazole disperse dyes <b>13a</b>–<b>c</b> and <b>14a</b>–<b>c</b>.</p>
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<p>Structure of a trisazo pyridone dye<b>.</b></p>
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<p>Synthesis of the azocoumarin <b>17</b>.</p>
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<p>Structure of amberlyst-15.</p>
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24 pages, 19885 KiB  
Review
Rapid Climate Change, Integrated Human–Environment–Historical Records and Societal Resilience in Georgia
by Christopher P. Loveluck, Levan G. Tielidze, Mikheil Elashvili, Andrei V. Kurbatov, Lela Gadrani, Nathaniel Erb-Satullo, Hans von Suchodoletz, Anca Dan, Hannes Laermanns, Helmut Brückner, Udo Schlotzhauer, Nino Sulava and Rusudan Chagelishvili
Sustainability 2024, 16(16), 7116; https://doi.org/10.3390/su16167116 - 19 Aug 2024
Viewed by 1184
Abstract
In the midlatitudes of the planet, we are facing the imminent disappearance of one of our best high-resolution (pre)historic climate and anthropogenic pollution archives, namely the loss of glacial ice, through accelerated global warming. To capture these records and interpret these vanishing archives, [...] Read more.
In the midlatitudes of the planet, we are facing the imminent disappearance of one of our best high-resolution (pre)historic climate and anthropogenic pollution archives, namely the loss of glacial ice, through accelerated global warming. To capture these records and interpret these vanishing archives, it is imperative that we extract ice-cores from midlatitude regions where glaciers still survive and analyse them within frameworks of inter-disciplinary research. In this paper, we focus on Georgia, part of the Greater Caucasus. Results of ice-core analyses from the region have never, to date, been integrated with its other abundant palaeo-environmental, archaeological and historical sources. We review the results of international projects on palaeo-environmental/geoarchaeological sediment archives, the archaeology of metal economies and preliminary ice-core data in Georgia. Collectively, we show that the different strands need to be integrated to fully explore relationships between climate/landscape change and human societal transformations. We then introduce an inclusive interdisciplinary framework for ongoing research on these themes, with an ultimate future goal of using data from the past to inform societal resilience strategies in the present. Full article
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<p>(<b>a</b>)—Location map of Georgia relative to the Caucasus Region and the location of the ice core drilling sites. A physical map of the Caucasus ecoregion was used and modified for the background [<a href="#B31-sustainability-16-07116" class="html-bibr">31</a>]. The insert map in the upper right shows the location of Georgia relative to Eurasia. (<b>b</b>)—Midlatitude global ice-core locations. (© Google Earth).</p>
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<p>Mount Kazbegi 2021 ice-core pilot project. (<b>a</b>)—ascending to the camping site (4100 m a.s.l.), (<b>b</b>)—Ice sampling site 4300 m a.s.l., (<b>c</b>)—Transportation of the ice samples. (<b>d</b>)—transported ice samples in the laboratory at the Climate Change Institute, University of Maine.</p>
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<p>Temperature anomaly plot of observed surface temperature increase in western Eurasia between 2000 and 2023, which has had a very negative impact on many glaciers in the region. The ECMWF European Reanalysis V5 (ERA5) [0.25° × 0.25°] 2-m surface temperature data files were re-gridded and generated to 0.5° × 0.5° using bilinear interpolation function. Climate Reanalyzer 2024. [Monthly Reanalysis Maps]. Climate Change Institute, University of Maine. Retrieved [17 January 2024], from <a href="https://climatereanalyzer.org/" target="_blank">https://climatereanalyzer.org/</a>.</p>
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<p>Moraines from the Roshka River valley. Future moraine sampling site. Google Earth image was used as a background. (© Google Earth).</p>
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<p>Approximately 3-metre-thick layered, fine-grained Rioni river sediments near Samtredia town, forming a potential Late Holocene palaeo–environmental archive.</p>
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<p>Plot visualising predominant wind directions and wind speed (m/s) in western Eurasia between 2000 and 2023, governing air-mass movement. The ECMWF European Reanalysis V5 (ERA5) [0.5° × 0.5°] annual data. Climate Reanalyzer™, Climate Change Institute, University of Maine.</p>
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<p>Lake Ugviri (Svaneti region, western Georgia) is one of the possible sources of lake sediment cores. Aerial orthophoto taken from a drone.</p>
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<p>Map of prehistoric and historic metal production sites in western Georgia. Digital elevation data is from the Shuttle Radar Topography Mission (SRTM) and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) (a product of METI and NASA) (developed from Erb-Satullo et al. [<a href="#B68-sustainability-16-07116" class="html-bibr">68</a>]).</p>
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<p>Map of the Caucasus (Tabula III Asiae) and its position on the world map, in Nicolaus Germanus’ Latin edition of Claudius Ptolemy’s Geography, Florence, 1467.</p>
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<p>Geoarchaeological coring survey in the coastal plain of western Georgia, conducted by the University of Cologne and Ilia State University, Tbilisi, to establish a new palaeo–climate/palaeo–environment reconstruction.</p>
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<p>(<b>a</b>)—Kazbegi Plateau—preliminary ice-core drilling site in 2021. (<b>b</b>)—Adishi Plateau—future electrothermal drilling site. Google Earth images were used for backgrounds. (© Google Earth).</p>
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<p>Flowchart of the integrated palaeo–environmental–archaeological–historical research design (after Brückner [<a href="#B99-sustainability-16-07116" class="html-bibr">99</a>], Table 1).</p>
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<p>Composite graphic of a transect from the Georgian Greater Caucasus to the Black Sea coast, showing images of the different records at their locations along the transect.</p>
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26 pages, 3377 KiB  
Article
Investigating the Influence of Vessel Shape on Spontaneous Fermentation in Winemaking
by Manuel Malfeito-Ferreira, Joana Granja-Soares, Mahesh Chandra, Arman Asryan, Joana Oliveira, Victor Freitas, Iris Loira, Antonio Morata, Jorge Cunha and Mkrtich Harutyunyan
Fermentation 2024, 10(8), 401; https://doi.org/10.3390/fermentation10080401 - 2 Aug 2024
Viewed by 950
Abstract
The earliest archaeological evidence of wine came from ceramic vessels of the Transcaucasian ‘Shulaveri-Shomutepe’ or ‘Aratashen-Shulaveri-Shomutepe culture’ (SSC/AShSh: c. 6000–5200 BC). Western European ‘Bell Beaker culture’ (BB: c. 2500–2000 BC) is characterized by bell-shaped pottery vessels but has so far not been found [...] Read more.
The earliest archaeological evidence of wine came from ceramic vessels of the Transcaucasian ‘Shulaveri-Shomutepe’ or ‘Aratashen-Shulaveri-Shomutepe culture’ (SSC/AShSh: c. 6000–5200 BC). Western European ‘Bell Beaker culture’ (BB: c. 2500–2000 BC) is characterized by bell-shaped pottery vessels but has so far not been found with residues consistent with wine. Knowing that wild grapes populated both habitats, the absence of wine during the Bell Beaker period remains to be explained. The main goal of this work was to investigate whether the shape of the vessels could influence the performance of spontaneous fermentation, specifically regarding the production of volatile acidity. Crushed grapes or juices from various grape cultivars were fermented in two types of vessels: (i) borosilicate glass beakers (4–5 L) to imitate bell beakers and (ii) Erlenmeyer flasks (5 L) to imitate SSC/AShSh vessels. Fermentations occurred spontaneously, and the wines were analyzed for their conventional physical–chemical parameters (e.g., ethanol content, total acidity, volatile acidity, pH), chromatic characteristics (e.g., wine color intensity, wine hue), and volatile composition by gas-chromatography-flame ionization detection (GC-FID). At the end of fermentation, the yeast species were identified by molecular methods. In addition, wine yields and phenolic composition (e.g., total phenols, anthocyanins, total pigments) were determined for wild grapes in comparison with six red varieties Vitis vinifera L. subsp. sativa (Vinhão, Marufo, Branjo, Melhorio, Castelão and Tempranillo Tinto), chosen as a function of their genetic relatedness with the wild counterpart. Wines produced from V. sylvestris grapes showed higher total acidity and color intensity when compared to the cultivated varieties. Saccharomyces cerevisiae dominated at the end of all spontaneous fermentations in all types of vessels and conditions. Wines fermented in Erlenmeyers showed ethanol concentrations as high as 14.30% (v/v), while the highest ethanol level was 12.30% (v/v) in beakers. Volatile acidity increased to a maximum of 4.33 g/L (acetic acid) in Erlenmeyers and 8.89 g/L in beakers. Therefore, the shape of the vessels influenced the performance of fermentation, probably due to the different exposures to air, leading to vinegary ferments more frequently in open mouths than in conical-shaped flasks. These results provide a hypothesis based on fermentation performance for the absence of wine produced in the Iberian Peninsula until the arrival of Phoenician settlers. Full article
(This article belongs to the Special Issue Fermentation and Biotechnology in Wine Making)
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<p>Flowchart of the white and red winemaking processes.</p>
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<p>Illustration of the different winemaking processes performed in beakers and Erlenmeyer flasks: (<b>a</b>) skin-contact macerated red wines; (<b>b</b>) no skin-contact fermented white wines with and without the addition of sulfur dioxide. For sample descriptions, see <a href="#fermentation-10-00401-t001" class="html-table">Table 1</a>.</p>
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<p>Bi-plot of the Principal Component Analysis (PCA) with the main physicochemical parameters of the 2020 wines (sample description in <a href="#fermentation-10-00401-t001" class="html-table">Table 1</a>). The small and large angles between the corresponding variables represent the degree of relationships. The vector lengths indicate the strength of the correlation (closeness) of the corresponding parameter with the experimental samples. The percentage values (in parentheses) represent the proportion of explained variance for each principal component.</p>
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<p>Bi-plot of the Principal Component Analysis (PCA) with the main physicochemical parameters of the 2021 wines (sample description in <a href="#fermentation-10-00401-t001" class="html-table">Table 1</a>). The small and large angles between corresponding variables represent the degree of relationships. The vector lengths indicate the strength of the correlation (the closeness) of the corresponding parameter with the experimental samples. The percentage values (in parentheses) represent the proportion of explained variance for each principal component.</p>
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<p>Bi-plot of the Principal Component Analysis (PCA) of chromatic analysis for the 2020 wines without WCES (sample description in <a href="#fermentation-10-00401-t001" class="html-table">Table 1</a>). The small and large angles between corresponding variables represent the degree of relationships. The vector lengths indicate the strength of the correlation (the closeness) of the corresponding parameter with the experimental samples. The percentage values (in parentheses) represent the proportion of explained variance for each principal component.</p>
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<p>Bi-plot of the Principal Component Analysis of chromatic analysis (PCA) for the 2021 wines without WAES (sample description in <a href="#fermentation-10-00401-t001" class="html-table">Table 1</a>). The small and large angles between corresponding variables represent the degree of relationships. The vector lengths indicate the strength of the correlation (the closeness) of the corresponding parameter with the experimental samples. The percentage values (in parentheses) represent the proportion of explained variance for each principal component.</p>
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<p>Bi-plot of the Principal Component Analysis (PCA) with volatile aroma composition of the 2020 wines (sample description in <a href="#fermentation-10-00401-t001" class="html-table">Table 1</a>). The small and large angles between corresponding variables represent the degree of relationships. The vector lengths indicate the strength of the correlation (the closeness) of the corresponding parameter with the experimental samples. The percentage values (in parentheses) represent the proportion of explained variance for each principal component. The colored lines are used to connect some data labels to their respective points in order to avoid overlapping (SB, MB, and ME).</p>
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<p>Bi-plot of the Principal Component Analysis (PCA) with volatile aroma composition of the 2021 wines (sample description in <a href="#fermentation-10-00401-t001" class="html-table">Table 1</a>). The small and large angles between corresponding variables represent the degree of relationships. The vector lengths indicate the strength of the correlation (the closeness) of the corresponding parameter with the experimental samples. The percentage values (in parentheses) represent the proportion of explained variance for each principal component. The colored lines are used to connect some data labels to their respective points in order to avoid overlapping (SB and AE).</p>
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12 pages, 5787 KiB  
Article
Comparison of Quantitative and Qualitative EDXRF Analysis for Provenance Study of Archaeological Ceramics
by Maja Gajic-Kvascev, Velibor Andric, Radmila Jancic-Heinemann, Ognjen Mladenovic and Aleksandar Bulatovic
Materials 2024, 17(15), 3725; https://doi.org/10.3390/ma17153725 - 27 Jul 2024
Viewed by 487
Abstract
The most common scientific analysis of archaeological ceramics aims to determine the raw material source and/or production technology. Scientists and archaeologists widely use XRF-based techniques as a tool in a provenance study. After conducting XRF analysis, the results are often analyzed using multivariate [...] Read more.
The most common scientific analysis of archaeological ceramics aims to determine the raw material source and/or production technology. Scientists and archaeologists widely use XRF-based techniques as a tool in a provenance study. After conducting XRF analysis, the results are often analyzed using multivariate analysis in addition to interpretation and conclusions. Various multivariate techniques have already been applied in archaeological ceramics provenance studies to reveal different raw material sources, identify imported pieces, or determine different production recipes. This study aims to evaluate the results of multivariate analysis in the provenance study of ceramics that belong to three cultures that settled in the same area during various prehistoric periods. Portable energy-dispersive X-ray fluorescence spectrometry (pEDXRF) was used to determine the elemental composition of the ceramic material. The ceramic material was prepared in two different ways. The ceramic body material was ground into powder, homogenized, and then pressed into tablets. After that, the same fragments are polished in suitable places. Quantitative and qualitative analyses were performed on the tablets and polished pieces. The results were subjected to both unsupervised and supervised multivariate analysis. Based on the results, it was concluded that qualitative analysis of the well-prepared shards’ surface using EDXRF spectrometry could be utilized in provenance studies, even when the ceramic assemblages were made of similar raw materials. Full article
(This article belongs to the Special Issue Materials in Cultural Heritage: Analysis, Testing, and Preservation)
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<p>(<b>a</b>) Location of the site of Bubanj, Serbia (drawing: A. Bulatović); (<b>b</b>) Representative ceramic fragments from the Bubanj Hum I (A), Cernavoda III (B) and Coţofeni–Kostolac (C) culture.</p>
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<p>(<b>a</b>) EDXRF spectra aligned using original spectra alignment procedure; (<b>b</b>) Radial basis neural network spectra reconstruction for feature selection.</p>
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<p>(<b>a</b>) PCA dimension reduction of the tablet’s quantified elemental composition (QT dataset); (<b>b</b>) SMB dimension reduction of the tablet’s quantified elemental composition (QT dataset).</p>
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<p>(<b>a</b>) PCA dimension reduction of the tablet’s RBNN selected elemental composition (NT dataset); (<b>b</b>) SMB dimension reduction of the tablet’s RBNN selected elemental composition (NT dataset).</p>
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<p>(<b>a</b>) PCA dimension reduction of the ceramic fragment’s RBNN selected elemental composition (NF dataset); (<b>b</b>) SMB dimension reduction of the ceramic fragment’s RBNN selected elemental composition (NF dataset).</p>
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<p>PCA dimension reduction of the raw EDXRF spectral data for (<b>a</b>) tablets (RT dataset) and (<b>b</b>) ceramic fragments (RF dataset).</p>
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<p>PCA dimension reduction of the raw EDXRF spectral data (<b>a</b>) for Bubanj Hum I and Coţofeni–Kostolac dataset; (<b>b</b>) for Cernavoda III and Coţofeni–Kostolac dataset.</p>
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22 pages, 6154 KiB  
Article
Per Capita Land Use through Time and Space: A New Database for (Pre)Historic Land-Use Reconstructions
by Chad Hill, Marco Madella, Nicki J. Whitehouse, Carolina Jiménez-Arteaga, Emily Hammer, Jennifer Bates, Lynn Welton, Stefano Biagetti, Johanna Hilpert and Kathleen D. Morrison
Land 2024, 13(8), 1144; https://doi.org/10.3390/land13081144 - 26 Jul 2024
Viewed by 633
Abstract
Anthropogenic land cover change (ALCC) models, commonly used for climate modeling, tend to utilize relatively simplistic models of human interaction with the environment. They have historically relied on unsophisticated assumptions about the temporal and spatial variability of the area needed to support one [...] Read more.
Anthropogenic land cover change (ALCC) models, commonly used for climate modeling, tend to utilize relatively simplistic models of human interaction with the environment. They have historically relied on unsophisticated assumptions about the temporal and spatial variability of the area needed to support one person: per capita land use (PCLU). To help refine ALCC models, we used a range of data sources to build a new database that attempts to bring together PCLU data with significant time depth and a global perspective. This new database can provide new nuance for our understanding of the variability in land use among and between time periods and regions, data that will have wide applicability for continued research into past human land use and present land-use change, and can hopefully help improve existing ALCC models. An example is provided, showing the potential impact of new PCLU data on land-use mapping in the Middle East at 6000 BP. Full article
(This article belongs to the Special Issue Advances in Land Use and Land Cover Mapping)
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<p>Sample of cropland estimates (in km<sup>2</sup> per grid cell) from HYDE 3.2 [<a href="#B1-land-13-01144" class="html-bibr">1</a>] from 8000 BCE to 1500 AD. The border between Israel and Egypt has a real land cover difference in the present along the modern-day border, as visible in the satellite basemap, but this difference incorrectly persists backwards in time through at least 4000 BCE in the HYDE model. Microsoft product screen shot(s) reprinted with permission from Microsoft Corporation, Redmond, WA, USA.</p>
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<p>Köppen–Geiger global climate classification data visualization from [<a href="#B14-land-13-01144" class="html-bibr">14</a>]. Classes (and visualization) following Beck et al. (2018) [<a href="#B14-land-13-01144" class="html-bibr">14</a>]: Table 2. The purpose here is to show the variability and distribution of climate classes; see [<a href="#B14-land-13-01144" class="html-bibr">14</a>] for specific definitions.</p>
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<p>Density plot for all pastoralism, hunter/gatherer/fishing/foraging (HGFF), and agriculture per capita land-use (PCLU) values.</p>
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<p>Comparison of mean PCLU per country (all dates): agriculture (<b>top</b>), pastoralism (<b>middle</b>), HGFF (<b>bottom</b>).</p>
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<p>Comparison of second-level land-use (LU2) PCLU distributions for all pre-1960 entries.</p>
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<p>Comparison of total PCLU values per country (<b>top</b>), total PCLU values before 1960 per country (<b>middle</b>), and the total number of Köppen–Geiger classes per country (<b>bottom</b>).</p>
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<p>Density plot for PCLU values based on Köppen–Geiger class.</p>
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<p>Mean HGFF PCLU value per modern US state and Canadian province.</p>
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<p>Plot of time ranges in PCLU database.</p>
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<p>PCLU database values vs. time for China. Each dot represents one PCLU entry in the database.</p>
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<p>PCLU database values vs. time for all of Northern Europe. Each dot represents a PCLU value in the database.</p>
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<p>(<b>1</b>) HYDE 3.2 baseline total land rainfed agricultural land at 6k; (<b>2</b>) HYDE 3.2 baseline total irrigated agricultural land at 6k; (<b>3</b>) Total rainfed agriculture land area using HYDE 3.2 baseline population data and PCLU from lookup table above; (<b>4</b>) Total irrigated agriculture land area using HYDE 3.2 baseline population data and PCLU estimates above.</p>
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17 pages, 2169 KiB  
Article
Ecotoxicological and Microbiological Risk Assessment of Groundwater from Dimba Cave, Democratic Republic of the Congo
by Daniel M. Mudinga, Archal M. Ngandote, John M. Kayembe, Séraphin N. Lusamba, Emmanuel K. Atibu, Fernando P. Carvalho and John Poté
Int. J. Environ. Res. Public Health 2024, 21(8), 962; https://doi.org/10.3390/ijerph21080962 - 23 Jul 2024
Viewed by 780
Abstract
Dimba Cave is a large array of natural galleries in limestone mountains of the Democratic Republic of the Congo that contains highly valued pre-historic archaeological artifacts. The cave attracts a high number of tourists every year and is used by local populations as [...] Read more.
Dimba Cave is a large array of natural galleries in limestone mountains of the Democratic Republic of the Congo that contains highly valued pre-historic archaeological artifacts. The cave attracts a high number of tourists every year and is used by local populations as a water supply source. The main objective of the research undertaken in Dimba Cave consisted of assessing the quality of water and sediments from Dimba Cave ponds through evaluating contamination by heavy metals (15 elements analyzed, including As, Cd, Pb, and Hg) and by microbial populations (including Escherichia coli and total coliforms) in order to estimate the ecotoxicological risk to humans and to non-human biota. All water samples collected in the cave ponds showed very high metal concentrations exceeding the internationally recommended limits for drinking water, particularly for Cr, Mn, As, Pb, and Hg. Most sediment samples from cave ponds also displayed high heavy metal concentrations. The calculated pollution parameters, such as the enrichment factor (EF), and ecological risk parameters, such as the ecological risk index (Eri), indicated that the sediment may be toxic to aquatic biota. Furthermore, the microbiological analysis of pond waters indicated a widespread contamination with bacteria such as Escherichia coli, Enterococcus spp., total coliforms, and Pseudomonas spp., probably from anthropogenic and/or animal sources. Therefore, the consumption of Dimba Cave water as a drinking water represents a threat to public health. Urgent management measures should be enforced to protect public health and the cave ecosystem. Full article
(This article belongs to the Section Environmental Sciences)
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<p>(<b>A</b>) Mbanza-Ngungu territory located in Kongo central province of the DR Congo, (<b>B</b>) location of the Dimba Cave (red dot).</p>
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<p>Dimba Cave plan (based on Quinif et al. [<a href="#B3-ijerph-21-00962" class="html-bibr">3</a>]).</p>
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30 pages, 40439 KiB  
Article
Earthen Architectural Heritage in the Gourara Region of Algeria: Building Typology, Materials, and Techniques
by Younes Kassou, Djamel Alkama and Soumia Bouzaher
Heritage 2024, 7(7), 3821-3850; https://doi.org/10.3390/heritage7070181 - 19 Jul 2024
Viewed by 713
Abstract
This article investigates the status of earthen architectural heritage (EAH) in the Gourara region of Algeria in light of contemporary developments and the sovereign decisions taken by the Algerian state, specifically the upgrading of the region to a wilaya (province) in 2019, and [...] Read more.
This article investigates the status of earthen architectural heritage (EAH) in the Gourara region of Algeria in light of contemporary developments and the sovereign decisions taken by the Algerian state, specifically the upgrading of the region to a wilaya (province) in 2019, and the accompanying direct impact on the oasis system, which is renowned for its fragile character. The research started by focusing on perplexing questions: What factors contribute to the region’s abandonment of earthen architecture? Moreover, could documentation serve as the optimal method for its preservation? In an attempt to explore and comprehend this distinctive heritage, characterized by its diversity, durability, and sustainability, this heritage has been linked to identity and local civilization dating back to prehistoric times, with evidence of their existence still present. Following a research approach and with the prospective purpose of preserving these buildings and what remains of them, the associated skills, materials, and construction techniques used in their development were investigated based on a descriptive, analytical, and documentary historical approach. Finally, the authors interviewed several qualified builders to collect knowledge of the local indigenous building practices. The research findings suggest that there is an urgency to consider a new perspective and strategies to preserve and protect EAH. Full article
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<p>The location of the study region: (<b>a</b>) Gourara region’s location in Algeria; (<b>b</b>) Gourara and its borders.</p>
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<p>The temperature in Gourara during the period 2003–2023: (<b>a</b>) average temperatures; (<b>b</b>) the highest temperatures recorded in each month.</p>
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<p>Winds in Gourara: (<b>a</b>) average monthly wind rose during 2019–2023; (<b>b</b>) average wind rose during 2003–2023; (<b>c</b>) average percentages of wind direction during 2003–2023; (<b>d</b>) average percentages of monthly wind direction during 2019–2023; (<b>e</b>) average monthly wind intensity during 2003–2023.</p>
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<p>The traditional methods of Afrag in Gourara: (<b>a</b>) sand blocking with the ability to change the wind direction, palm groves, Ifka-Kali, Ouled Said; (<b>b</b>) sand encroachment after neglecting Afrag in Tgaza-Badrian, Timimoun (photos by Y. Kassou).</p>
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<p>Humidity in Gourara during 2003–2023: (<b>a</b>) average temperatures; (<b>b</b>) the highest monthly humidity.</p>
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<p>Rainfall in Gourara during the period 2003–2023: (<b>a</b>) height of monthly rainfall; (<b>b</b>) average height distribution of rainfall.</p>
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<p>The E-W cross section in the North of Timimoun shows the geomorphologic sets [<a href="#B42-heritage-07-00181" class="html-bibr">42</a>].</p>
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<p>The oasis system at Beni Mahlal Timimoun [<a href="#B46-heritage-07-00181" class="html-bibr">46</a>].</p>
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<p>Research methodology.</p>
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<p>Military architecture in Gourara: Agham Ouled Mahmoud, Metarfa-Aougrout (photos by Y. Kassou).</p>
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<p>Civil architecture in Gourara: (<b>a</b>) expansion beyond the walls of the Agham Tagalzi-Charouine; (<b>b</b>) Souk Sidi Moussa (market) in Ksar Timimoun (photos by Y. Kassou).</p>
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<p>Religious architecture in Gourara: (<b>a</b>) Sidi Ahmed Outhmane mosque in Tadmait Ksar Timimoun; (<b>b</b>) Sid El Hadj Sofi worship retreats in Badrian Timimoun (photos by Y. Kassou).</p>
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<p>Funerary architecture in Gourara: (<b>a</b>) the mausoleums of Sidi Abdel Rahman in Igosten, Deldoul—Aougrout; (<b>b</b>) the shrine of Moulay Abdelkader Al-Jilani in Oulad Saïd Timimoun (photos by Y. Kassou).</p>
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<p>Stone kinds in Gourara: (<b>a</b>) sandstone; (<b>b</b>) flat stones; (<b>c</b>) quartzite stones (photos by Y. Kassou).</p>
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<p>Clayey soils in Gourara: (<b>a</b>) the red range; (<b>b</b>) the green range (photos by Y. Kassou).</p>
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<p>Date palm tree components (photos by Y. Kassou).</p>
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<p>Different types of trees and plants used in Gourara: (<b>a</b>) <span class="html-italic">Tamarix aphylla</span> tree; (<b>b</b>) <span class="html-italic">Tamarix gallica</span> tree; (<b>c</b>) <span class="html-italic">Retama raetam</span> tree; (<b>d</b>) <span class="html-italic">Aristida pungens</span> Desf. plants (photos by Y. Kassou).</p>
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<p>Rocky plateau as foundation in Gourara: (<b>a</b>) without earthworks in Ighamawen of Aghlad-Ouled Said; (<b>b</b>) built foundations in Agham Basamad-Daldoul Aougrout (photos by Y. Kassou).</p>
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<p>Stone foundations: (<b>a</b>) the usual foundations, Ksar Timimoun; (<b>b</b>) built on rocky soil at Agham Aourir-Daldoul Aougrout (photos by Y. Kassou).</p>
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<p>Similar steps of adobe production in the Gourara region [<a href="#B61-heritage-07-00181" class="html-bibr">61</a>].</p>
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<p>Rubble stone walls: (<b>a</b>) built with sandstone in Agham N’tihdayine Faoun-Ouled Said; (<b>b</b>) built with flat stones in Agham At-Youcef Aghlad-Ouled Said (photos by Y. Kassou).</p>
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<p>Wheat spike walls in Agham N’khzin Aghlad-Ouled Said (photos by Y. Kassou).</p>
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<p>Triangular prism mud walls, Agham Tidji Kali-Ouled Said (photos by Y. Kassou).</p>
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<p>Shapes of adobe brick walls: (<b>a</b>) stretcher bond; (<b>b</b>) header bond; (<b>c</b>) English bond with one brick wall; (<b>d</b>) English bond with one and a half brick walls (photos by Y. Kassou).</p>
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<p>Mixed walls: (<b>a</b>) using salt stone in Agham Sidi Belkacem Ouled Abou-Daldoul Aougrout; (<b>b</b>) using stone and adobe bricks in Agham Am’zaghakh Massine Timimoun (photos by Y. Kassou).</p>
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<p>Buttress construction technique: (<b>a</b>) added buttress on the higher walls of Agham N’Tini Kali-Ouled Said; (<b>b</b>) buttress on the entrance of Agham Amaro N‘amaro in Aghlad-Ouled Said; (<b>c</b>) buttressed the entrance of the Ksar’s house in Timimoun (photos by Y. Kassou).</p>
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<p>Column and arch construction methods in CAPTERRE: (<b>a</b>) possible ways of constructing columns; (<b>b</b>) square columns; (<b>c</b>) square columns with one and a half bricks (photos by Y. Kassou).</p>
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<p>The Gourara’s arches’ varieties: (<b>a</b>) local arch (round) in Agham Tala Aougrout; (<b>b</b>) semicircular arch in the mosque El-Boulghitia in Agham Sidi Belkacem Ouled Abou-Daldoul Aougrout; (<b>c</b>) keyhole arch in the mosque El-Boulghitia in Agham Sidi Belkacem Ouled Abou; (<b>d</b>) horseshoe arch in the mosque of Agham Da Ou-Ali Kali-Ouled Said; (<b>e</b>) stilted arch in mosque of Souk Sidi Mousa Timimoun; (<b>f</b>) multifoil arch in mosque of Agham Baglaghi Ouled Tahar Timimoun (photos by Y. Kassou).</p>
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<p>Door installation: (<b>a</b>) door constituents; (<b>b</b>) fixing in the threshold; (<b>c</b>) fixing in the lintel (photos by Y. Kassou).</p>
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<p>A built staircase: (<b>a</b>) between two walls in Ksar Faoun-Ouled Said; (<b>b</b>,<b>c</b>) between the wall building and half wall in the mosque of Agham Al-Gabli-Talmine Charouine (photos by Y. Kassou).</p>
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<p>A built staircase on an inclined roof of date palm trunks: (<b>a</b>) a component of the staircase; (<b>b</b>) a traditional bread oven under the staircase (photos by Y. Kassou).</p>
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<p>Date palm trunk roof: (<b>a</b>) fixation date palm trunks using stones; (<b>b</b>) a view in a thick layer of mud; (<b>c</b>) adjacent date palm midribs; (<b>d</b>) using date palm midribs and date palm blades; (<b>e</b>) using pieces of date palm trunks; (<b>f</b>) using petioles; (<b>g</b>) adjacent date palm trunks; (<b>h</b>) using flat stones; (<b>i</b>) using tree branches (photos by Y. Kassou).</p>
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<p>Tree trunk roof: (<b>a</b>) using tree trunks and stones in Ksar Timimoun; (<b>b</b>) using date palm trunks and tree trunks in Ksar Faoun-Ouled Said (photos by Y. Kassou).</p>
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<p>Stone roof, Agham N’khzin Aghlad-Ouled Said (photos by Y. Kassou).</p>
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<p>Domed roof: (<b>a</b>) Amghayr foggara; (<b>b</b>) Tyouchiet foggara; (<b>c</b>) Lalla Zahia’s tomb; (<b>d</b>) corbelled walls on the pyramidal dome of Sidi Mohamed Cherif’s mausoleum at Touki-Deldoul Aougrout; (<b>e</b>) a pyramidal dome on Sidi Othmane’s mausoleum in Timimoun; (<b>f</b>) a twin pyramidal dome on Moulay Cherif’s mausoleum in Tinkline-Aougrout (photos by Y. Kassou).</p>
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<p>Mud plaster techniques: (<b>a</b>) hand float; (<b>b</b>) sculpture mural; (<b>c</b>) hand fingers; (<b>d</b>) date palm spadix stems; (<b>e</b>) throwing earthen hand-balls; (<b>f</b>) trowel earthen balls (photos by Y. Kassou).</p>
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<p>The sand-covered floors, Dar Zawaya Sidi Omar Aougrout (photos by Y. Kassou).</p>
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11 pages, 7431 KiB  
Article
Terminal Pleistocene Human Occupation of the Qomolangma Region: New Evidence from the Su-re Site
by Ziyi Yang, Yingshuai Jin, Yunyao Tan, Junyi Ge, Shejiang Wang, Xing Gao, John W. Olsen and Xiaoling Zhang
Land 2024, 13(7), 1064; https://doi.org/10.3390/land13071064 - 16 Jul 2024
Viewed by 600
Abstract
Lithic artifacts are crucial for elucidation of the temporal and spatial patterns of prehistoric human occupation of the Tibetan Plateau. Core-and-flake technology is particularly noteworthy, as it is distinguished by its broad temporal span and widespread distribution across the plateau. In this study, [...] Read more.
Lithic artifacts are crucial for elucidation of the temporal and spatial patterns of prehistoric human occupation of the Tibetan Plateau. Core-and-flake technology is particularly noteworthy, as it is distinguished by its broad temporal span and widespread distribution across the plateau. In this study, we present the results of a reassessment of the lithic assemblage from the Su-re site in Tingri County, Shigatse City, Xizang Autonomous Region, China. Its resemblance to lithic assemblages from Southwestern China implies a close relationship between the plateau and its southeastern vicinity, contributing to the diversification of technology and prehistoric humans on the Tibetan Plateau. Moreover, gneissic pebbles transported by glacial meltwater in the Tingri Graben—the most suitable raw material available in the vicinity—explains the presence of prehistoric humans in the inhospitable Qomolangma region. Full article
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<p>(<b>a</b>) The distribution of core-and-flake industries on the Tibetan Plateau; (<b>b</b>) location of the Su-re site; (<b>c</b>) oblique aerial view of the Tingri Graben and Qomolangma-Cho Oyu massif (Google Earth). Blue lines refer to two rivers, Ragqu Tsangpo and Kang qu.</p>
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<p>Section and sedimentary sequence at the Su-re site.</p>
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<p>Cores from the Su-re site: 1, 6, narrow-faced cores; 2–3, 8, broad-faced cores; 4–5, cores produced by alternating knapping; 7, 9, multi-platform cores.</p>
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<p>Flakes and retouched pieces from the Su-re site: 1–2, triangular flakes; 3, side-scraper; 4–6, denticulates made on triangular flakes; 7–9, elongated flakes; 10, notch made on elongated flake; 11–12, core rejuvenation flakes; 13, point with truncation.</p>
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41 pages, 10492 KiB  
Review
Water Dams: From Ancient to Present Times and into the Future
by Andreas N. Angelakis, Alper Baba, Mohammad Valipour, Jörg Dietrich, Elahe Fallah-Mehdipour, Jens Krasilnikoff, Esra Bilgic, Cees Passchier, Vasileios A. Tzanakakis, Rohitashw Kumar, Zhang Min, Nicholas Dercas and Abdelkader T. Ahmed
Water 2024, 16(13), 1889; https://doi.org/10.3390/w16131889 - 1 Jul 2024
Viewed by 1338
Abstract
Since ancient times, dams have been built to store water, control rivers, and irrigate agricultural land to meet human needs. By the end of the 19th century, hydroelectric power stations arose and extended the purposes of dams. Today, dams can be seen as [...] Read more.
Since ancient times, dams have been built to store water, control rivers, and irrigate agricultural land to meet human needs. By the end of the 19th century, hydroelectric power stations arose and extended the purposes of dams. Today, dams can be seen as part of the renewable energy supply infrastructure. The word dam comes from French and is defined in dictionaries using words like strange, dike, and obstacle. In other words, a dam is a structure that stores water and directs it to the desired location, with a dam being built in front of river valleys. Dams built on rivers serve various purposes such as the supply of drinking water, agricultural irrigation, flood control, the supply of industrial water, power generation, recreation, the movement control of solids, and fisheries. Dams can also be built in a catchment area to capture and store the rainwater in arid and semi-arid areas. Dams can be built from concrete or natural materials such as earth and rock. There are various types of dams: embankment dams (earth-fill dams, rock-fill dams, and rock-fill dams with concrete faces) and rigid dams (gravity dams, rolled compacted concrete dams, arch dams, and buttress dams). A gravity dam is a straight wall of stone masonry or earthen material that can withstand the full force of the water pressure. In other words, the pressure of the water transfers the vertical compressive forces and horizontal shear forces to the foundations beneath the dam. The strength of a gravity dam ultimately depends on its weight and the strength of its foundations. Most dams built in ancient times were constructed as gravity dams. An arch dam, on the other hand, has a convex curved surface that faces the water. The forces generated by the water pressure are transferred to the sides of the structure by horizontal lines. The horizontal, normal, and shear forces resist the weight at the edges. When viewed in a horizontal section, an arch dam has a curved shape. This type of dam can also resist water pressure due to its particular shape that allows the transfer of the forces generated by the stored water to the rock foundations. This article takes a detailed look at hydraulic engineering in dams over the millennia. Lessons should be learned from the successful and unsuccessful applications and operations of dams. Water resource managers, policymakers, and stakeholders can use these lessons to achieve sustainable development goals in times of climate change and water crisis. Full article
(This article belongs to the Section Soil and Water)
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<p>Bahman Dam, Iran. Constructed approximately 2200 years ago (adapted from [<a href="#B11-water-16-01889" class="html-bibr">11</a>]).</p>
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<p>Akhlemad Dam (adapted from [<a href="#B9-water-16-01889" class="html-bibr">9</a>]).</p>
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<p>A view of Fariman Dam. An ancient dam possibly dating back to the reigns of the Sassanid kings of Persia (224–710 AD), it was rebuilt during the Timurid and the Qajar eras in its current form (adapted from [<a href="#B9-water-16-01889" class="html-bibr">9</a>]).</p>
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<p>The Amir Dam, 1000 years old and still in operation, is an example of the exceptional water designing works accomplished by the architects of the Persian Empire [<a href="#B12-water-16-01889" class="html-bibr">12</a>].</p>
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<p>Choiromandres Dam and irrigation system: (<b>a</b>) view of the major dam; and (<b>b</b>) irrigation practices in the small valley (with the permission of A. Angelakis).</p>
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<p>Aerial view of part of the Dujiangyan Project [<a href="#B28-water-16-01889" class="html-bibr">28</a>].</p>
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<p>The dam of Alyzia: (<b>a</b>) the dam and the spillway with its irregular shape formed by erosion through the centuries; and (<b>b</b>) the spillway under operation [<a href="#B36-water-16-01889" class="html-bibr">36</a>].</p>
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<p>Roman dams: (<b>a</b>) ruined dam of Alcantarilla, Toledo, seen from the reservoir side (the reservoir wall collapsed into the basin at some stage, possibly due to the absence of buttresses; photograph: Cees Passchier); and (<b>b</b>) the Cornalvo Dam in Spain, which was erected in the first to second centuries AD.</p>
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<p>The flat cave at the west exit of Longshou Canal [<a href="#B63-water-16-01889" class="html-bibr">63</a>]).</p>
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<p>Devrajpur Dam: (<b>a</b>) horizontally laid dam facing; and (<b>b</b>) interlocked stone facing (adapted from [<a href="#B73-water-16-01889" class="html-bibr">73</a>]).</p>
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<p>Oderteich Dam (with the permission of J. Dietrich).</p>
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<p>Dams are the major water supply projects in Athens, Greece.</p>
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<p>General view: (<b>a</b>) map; and (<b>b</b>) view of the main part of the dam.</p>
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<p>Number of dams in 2016 [<a href="#B97-water-16-01889" class="html-bibr">97</a>].</p>
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<p>Atatürk Dam fill rate year by year [<a href="#B107-water-16-01889" class="html-bibr">107</a>].</p>
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<p>Keban Dam fill rate year by year [<a href="#B107-water-16-01889" class="html-bibr">107</a>].</p>
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<p>Delta Barrage in Cairo.</p>
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<p>Aswan Low Dam [<a href="#B119-water-16-01889" class="html-bibr">119</a>].</p>
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<p>Aswan High Dam.</p>
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<p>Diamer Bhasha Dam [<a href="#B128-water-16-01889" class="html-bibr">128</a>].</p>
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<p>The Nova Kakhovka hydroelectric power dam.</p>
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<p>Produced and expected hydroelectric power in the world [<a href="#B138-water-16-01889" class="html-bibr">138</a>].</p>
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27 pages, 6545 KiB  
Article
Compositional and Microstructural Investigations of Prehistoric Ceramics from Southern Romania (Middle Neolithic Pottery)
by Rodica-Mariana Ion, Ancuta-Elena Pungoi, Lorena Iancu, Ramona Marina Grigorescu, Gabriel Vasilievici, Anca Irina Gheboianu, Sofia Slamnoiu-Teodorescu and Elvira Alexandrescu
Appl. Sci. 2024, 14(13), 5755; https://doi.org/10.3390/app14135755 - 1 Jul 2024
Viewed by 733
Abstract
In this paper, based on our previous expertise on ceramic artifacts, several archaeometric methods applied to some samples collected from the Dudești archaeological site (Oltenia region, Romania) are reported for the first time in the literature. The chemical composition, and microstructural and morphological [...] Read more.
In this paper, based on our previous expertise on ceramic artifacts, several archaeometric methods applied to some samples collected from the Dudești archaeological site (Oltenia region, Romania) are reported for the first time in the literature. The chemical composition, and microstructural and morphological characterization of these samples offer important conclusions about the processing conditions. Some specific techniques such as X-ray diffraction (XRD), wavelength-dispersive X-ray fluorescence (WDXRF), optical microscopy (OM), stereomicroscopy, environmental scanning electron microscopy (ESEM), Fourier-transform infrared spectroscopy (FTIR), and Raman spectroscopy provide compositional information about composition and the decay processes. Additionally, the Brunauer–Emmett–Teller (BET) method helps to estimate pore sizes and specific surface areas. A thermogravimetric analysis (TGA/TDG) was used to establish details regarding the production technology and also the raw materials source used to make the ceramics. The obtained results indicated that the ceramics are based on a paste of muscovite and feldspar, with high plasticity, together with quartz and hematite/goethite and calcite, the latter in very low concentrations. According to the obtained results, we could assume that clays from the investigated samples had a low concentration of calcium. Gypsum is present as paste in a very low concentration, identified by the presence of a sulphate group in WDXRF. In the same context, iron oxides have a significant impact on the firing atmosphere of iron-rich clay, resulting in blackening under reducing conditions and a reddish coloration under oxidative conditions. The use of hematite and gypsum as pigments further contributes to the color variations in the pottery. The consistent firing temperature range of 200–600 °C in Dudești pottery implies a standardized production process, the variation in color being dependent on the specific reducing/oxidative regime conditions (reducing atmosphere followed by rapid oxidation). This relationship between clay composition and local sources suggests a connection to Neolithic pottery production in the region and their color depending on the reducing/oxidative regime conditions. Full article
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<p>Fragment of vessel, Dudeşti Culture, Milcov, Olt (<b>1</b>), and Supply vessel, Dudeşti culture, Milcov, Olt (<b>2</b>); and cross-section images of P1 sample (<b>3</b>).</p>
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<p>Fragment of vessel, Dudeşti Culture, Milcov, Olt (<b>1</b>), and Supply vessel, Dudeşti culture, Milcov, Olt (<b>2</b>); and cross-section images of P1 sample (<b>3</b>).</p>
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<p>Vessel before restoration.</p>
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<p>The locations where the samples have been collected (Cx means Complex; Cx 063 and Cx 160 mean the location position where these samples were collected).</p>
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<p>XRD of P1 sample (blue) and P2 sample (red).</p>
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<p>Optical microscopy images ((<b>a</b>,<b>b</b>) for red part of P1 sample; (<b>c</b>,<b>d</b>) for black part of P1 sample; and (<b>e</b>,<b>f</b>) for P2 sample); stereomicroscopy ((<b>g</b>,<b>h</b>) for P1 sample; and (<b>i</b>,<b>j</b>) for P2 sample), and SEM ((<b>k</b>–<b>n</b>) for P1 sample; and (<b>o</b>,<b>p</b>) for P2 sample).</p>
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<p>Optical microscopy images ((<b>a</b>,<b>b</b>) for red part of P1 sample; (<b>c</b>,<b>d</b>) for black part of P1 sample; and (<b>e</b>,<b>f</b>) for P2 sample); stereomicroscopy ((<b>g</b>,<b>h</b>) for P1 sample; and (<b>i</b>,<b>j</b>) for P2 sample), and SEM ((<b>k</b>–<b>n</b>) for P1 sample; and (<b>o</b>,<b>p</b>) for P2 sample).</p>
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<p>Optical microscopy images ((<b>a</b>,<b>b</b>) for red part of P1 sample; (<b>c</b>,<b>d</b>) for black part of P1 sample; and (<b>e</b>,<b>f</b>) for P2 sample); stereomicroscopy ((<b>g</b>,<b>h</b>) for P1 sample; and (<b>i</b>,<b>j</b>) for P2 sample), and SEM ((<b>k</b>–<b>n</b>) for P1 sample; and (<b>o</b>,<b>p</b>) for P2 sample).</p>
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<p>The FTIR spectra of P1 (<b>up</b>) and P2 (<b>down</b>) samples.</p>
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<p>The FTIR spectra of P1 (<b>up</b>) and P2 (<b>down</b>) samples.</p>
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<p>The Raman spectra of P1 (<b>up</b>) and P2 (<b>down</b>) samples.</p>
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<p>TGA (red line) (<b>left</b>) and blue line (<b>right</b>) and DTG (black line) for the samples P1 and P2 (heating rate 10 °C/min).</p>
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<p>The chromatic parameters of the investigated samples.</p>
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