Search Results (162)

A disruptive Electric Propulsion system is proposed for next-generation Low-Earth-Orbit (LEO) small satellite constellations, utilizing an RF-powered Helicon Plasma Thruster (HPT). This system is built around a Magnetically Enhanced Inductively Coupled Plasma (MEICP) reactor, which enables acceleration of quasi-neutral plasma through a magnetic nozzle. The MEICP reactor features an innovative design with a multi-dipole magnetic confinement system, generated by neodymium iron boron (NdFeB) permanent magnets, combined with an azimuthally asymmetric half-wavelength right (HWRH) antenna and a variable-section ionization chamber. The plasma reactor is followed by a solenoid-free magnetic nozzle (MN), which facilitates the formation of an ambipolar potential drop, enabling the conversion of electron thermal energy into ion beam energy. This study explores the impact of an inhomogeneous magnetic field on the heating mechanism of the HPT and highlights its multi-mode operation within a pulsed power range of 200 to 500 W of RF. The discharge state, characterized by high-energy electron-excited ions and low-energy excited neutral particles in the plasma plume, was analyzed using optical emission spectroscopy (OES). The experimental testing campaign, conducted under pulsed power excitation, reveals that, as RF input power increases, the MEICP reactor transitions from inductive (H-mode) to wave coupling (W-mode) discharge modes. Spectrograms, electron temperature, and plasma density measurements were obtained for the Helicon Plasma Thruster within its operational envelope. Based on OES data, the ideal specific impulse was estimated to exceed 1000 s, highlighting the significant potential of this technology for future LEO/VLEO space missions. Full article

Three-dimensional plasma nanostructures with high light–thermal conversion efficiency show the prospect of industrialization in various fields and have become a research hotspot in areas of light–heat utilization, solar energy capture, and so on. In this paper, a simple chemical synthesis method is proposed to prepare gold nanoparticles, and the electrophoretic deposition method is used to assemble large-area three-dimensional gold nanostructures (3D-GNSs). The light–thermal water evaporation monitoring and surface-enhanced Raman scattering (SERS) measurements of 3D-GNSs were performed via theoretical simulation and experiments. We reveal the physical processes of local electric field optical enhancement and the light–thermal conversion of 3D-GNSs. The results show that with the help of the efficient optical trapping and super-hydrophilic surface properties of 3D-GNSs, they have a significant effect in accelerating water evaporation, which was increased by nearly eight times. At the same time, the three-dimensional SERS substrates based on gold nanosphere particles (GNSPs) and gold nanostar particles (GNSTs) had limited sensitivities of 10⁻¹⁰ M and 10⁻¹² M to R6G molecules, respectively. Therefore, 3D-GNSs show strong competitiveness in the fields of solar-energy-induced water purification and the Raman trace detection of organic molecules. Full article

Defects such as interconnected pores and cracks can improve the abradability of ceramic-based abradable sealing coatings (ASCs) but may reduce the lifetime. Self-healing can potentially close cracks and transform interconnected pores into isolated ones through filling and sintering effects. Ti₃AlC₂ (TAC) was incorporated into LaMgAl₁₁O₁₉ (LMA) as both the self-healing agent and sintering aid, and plasma-sprayed LMA-based composite coatings were annealed at 1200 °C to assess their self-healing capabilities and then subjected to oxidation in air and corrosion in steam at 1300 °C to study their long-term stability. Results indicated that increasing TAC content significantly enhances self-healing effectiveness, evidenced by the closure of cracks and the isolation of pores. Oxidation and corrosion at 1300 °C led to significant grain growth and the formation of equiaxed grains with an aspect ratio of approximately 3, which may impair the toughening mechanism. Meanwhile, due to the preferential volatilization of Al in a steam environment, LTA decomposed into α-La_2/3TiO₃ and La₄Ti₃O₁₂ phases, and the accelerated mass transfer also resulted in grain coarsening. Interestingly, the L20T composite coating with a porosity of 32.17 ± 0.94% and a hardness of 74.88 ± 1.55 HR15Y showed great potential for abradable applications due to its stable phase composition and uniform pore distribution. Full article

Autologous platelet-rich plasma (PRP) preparations are prepared at the point of care. Centrifugation cellular density separation sequesters a fresh unit of blood into three main fractions: a platelet-poor plasma (PPP) fraction, a stratum rich in platelets (platelet concentrate), and variable leukocyte bioformulation and erythrocyte fractions. The employment of autologous platelet concentrates facilitates the biological potential to accelerate and support numerous cellular activities that can lead to tissue repair, tissue regeneration, wound healing, and, ultimately, functional and structural repair. Normally, after PRP preparation, the PPP fraction is discarded. One of the less well-known but equally important features of PPP is that particular growth factors (GFs) are not abundantly present in PRP, as they reside outside of the platelet alpha granules. Precisely, insulin-like growth factor-1 (IGF-1) and hepatocyte growth factor (HGF) are mainly present in the PPP fraction. In addition to their roles as angiogenesis activators, these plasma-based GFs are also known to inhibit inflammation and fibrosis, and they promote keratinocyte migration and support tissue repair and wound healing. Additionally, PPP is known for the presence of exosomes and other macrovesicles, exerting cell–cell communication and cell signaling. Newly developed ultrafiltration technologies incorporate PPP processing methods by eliminating, in a fast and efficient manner, plasma water, cytokines, molecules, and plasma proteins with a molecular mass (weight) less than the pore size of the fibers. Consequently, a viable and viscous protein concentrate of functional total proteins, like fibrinogen, albumin, and alpha-2-macroglobulin is created. Consolidating a small volume of high platelet concentrate with a small volume of highly concentrated protein-rich PPP creates a protein-rich, platelet-rich plasma (PR-PRP) biological preparation. After the activation of proteins, mainly fibrinogen, the PR-PRP matrix retains and facilitates interactions between invading resident cells, like macrophages, fibroblast, and mesenchymal stem cells (MSCs), as well as the embedded concentrated PRP cells and molecules. The administered PR-PRP biologic will ultimately undergo fibrinolysis, leading to a sustained release of concentrated cells and molecules that have been retained in the PR-PRP matrix until the matrix is dissolved. We will discuss the unique biological and tissue reparative and regenerative properties of the PR-PRP matrix. Full article

Supercapacitor electrode materials play a decisive role in charge storage and significantly affect the cost and capacitive performance of the final device. Engineering of the heterostructure of metal–organic framework (MOF)-derived transition metal nitrides (TMNs) can be conducive to excellent electrochemical performance owing to the synergistic effect, optimized charge transport/mass transfer properties, and high electrical conductivity. In this study, a Co₄N/CoN heterostructure was incorporated into a nitrogen-doped support by radio-frequency (RF) plasma after simple pyrolysis of Co-based formate frameworks (Co-MFFs), with the framework structure well retained. Plasma engineering can effectively increase the ratio of Co₄N in the Co₄N/CoN heterostructure, accelerating the electron transfer rate and resulting in a rough surface due to the reduction effect of high-energy electrons and the etching effect of ions. Benefiting from the plasma modification, the obtained electrode material Co₄N/CoN@C-P exhibits a high specific capacitance of 346.2 F·g⁻¹ at a current density of 1 A·g⁻¹, approximately 1.7 times that of CoN/Co₄N@C prepared by pyrolysis. The specific capacitance of Co₄N/CoN@C-P reaches 335.6 F·g⁻¹ at 10 A·g⁻¹, approximately 96.9% of that at 1 A·g⁻¹, indicating remarkable rate capability. Additionally, the capacitance retention remains at 100% even after 1000 cycles, suggesting excellent cycling stability. The rational design and plasma engineering of the TMN heterostructures at the nanoscale are responsible for the excellent electrochemical performance of this novel composite material. Full article

Background: Data show that due to endothelial damage and thrombogenic effects, severe acute respiratory syndrome coronavirus-2 (SARS-CoV-2) infection may accelerate the development of atherosclerosis and increase the risk of cardiovascular diseases (CVDs). The impaired metabolism of aminothiols increases oxidative stress, as these molecules are involved in antioxidant defense as well as in thiol redox control. In this study, total levels of selected aminothiols (i.e., cysteine (Cys), homocysteine (HCy), and glutathione) in convalescents after coronavirus disease of 2019 (COVID-19) were evaluated. The analyses were made according to the sex of the patients, time from COVID-19 onset, and COVID-19 severity. Methods: The study group consisted of 212 patients after COVID-19. Levels of total aminothiols were assessed in the blood plasma using high-performance liquid chromatography (HPLC). Results: The mean Cys concentrations were higher in men than in women (229.92 µmol/L ± 51.54 vs. 210.35 µmol/L ± 41.90, respectively; p = 0.003). Differences in Cys levels were also noticed in the total study group between patients distinguished due to time from disease onset (226.82 µmol/L ± 40.57 in <12 weeks, 232.23 µmol/L ± 47.99 in patients 12–24 weeks, and 208.08 µmol/L ± 48.43 in patients >24 weeks; p = 0.005). In addition, over 11% of total patients 12–24 weeks from disease onset had Cys levels above 300 µmol/L compared to almost 4% of patients <12 weeks and 2% of patients >24 weeks (p = 0.046). In sex-adjusted subgroups, significant differences due to time from COVID-19 were found in Cys levels in women (p = 0.004) and in glutathione levels in men (p = 0.024). None of the aminothiol levels differed between the subgroups based on the severity of COVID-19. Conclusions: Men had overall higher Cys levels than women. Cys levels were lower >24 weeks after COVID-19 onset than in the earlier period after disease onset. A partial elevation in Cys levels 12–24 weeks after the disease onset may contribute to the increase in CVD risk in the post-COVID-19 period. Full article

Zinc is known for its role in enhancing bone metabolism, cell proliferation, and tissue regeneration. Several studies proposed the incorporation of zinc into hydroxyapatite (HA) to produce biomaterials (ZnHA) that stimulate and accelerate bone healing. This systematic review aimed to understand the physicochemical characteristics of zinc-doped HA-based biomaterials and the evidence of their biological effects on osteoblastic cells. A comprehensive literature search was conducted from 2022 to 2024, covering all years of publications, in three databases (Web of Science, PUBMED, Scopus), retrieving 609 entries, with 36 articles included in the analysis according to the selection criteria. The selected studies provided data on the material’s physicochemical properties, the methods of zinc incorporation, and the biological effects of ZnHA on bone cells. The production of ZnHA typically involves the wet chemical synthesis of HA and ZnHA precursors, followed by deposition on substrates using processes such as liquid precursor plasma spraying (LPPS). Characterization techniques confirmed the successful incorporation of zinc into the HA lattice. The findings indicated that zinc incorporation into HA at low concentrations is non-cytotoxic and beneficial for bone cells. ZnHA was found to stimulate cell proliferation, adhesion, and the production of osteogenic factors, thereby promoting in vitro mineralization. However, the optimal zinc concentration for the desired effects varied across studies, making it challenging to establish a standardized concentration. ZnHA materials are biocompatible and enhance osteoblast proliferation and differentiation. However, the mechanisms of zinc release and the ideal concentrations for optimal tissue regeneration require further investigation. Standardizing these parameters is essential for the effective clinical application of ZnHA. Full article

Recycled soda-lime glass powder is a sustainable material that is also often considered a filler in cement-based composites. The changes in the surface properties of the glass particles due to the treatments were analyzed by X-ray photoelectron spectroscopy (XPS) and optical spectroscopy. We have found that there is a relatively high level of carbon contamination on the surface of the glass particles (around 30 at.%), so plasma technology and thermal annealing were tested for surface cleaning. Room temperature plasma treatment was not sufficient to remove the carbon contamination from the surface of the recycled glass particles. Instead, the room temperature plasma treatment of recycled soda-lime glass particles leads to a significant enhancement in their room temperature photoluminescence (PL) by increasing the intensity and accelerating the decay of the photoluminescence. The enhanced blue PL after room-temperature plasma treatment was attributed to the presence of carbon contamination on the glass surface and associated charge surface and interfacial defects and interfacial states. Therefore, we propose blue photoluminescence under UV LED as a fast and inexpensive method to indicate carbon contamination on the surface of glass particles. Full article

The issue of aircraft icing poses a substantial threat to flight safety. In order to investigate more efficient anti-icing and de-icing technologies, a comparative analysis was conducted on the de-icing characteristics of three types of actuator materials under varying conditions. Initially, experimental research was undertaken to analyze the temperature traits of three actuators under ice-free conditions. Three power densities were chosen for the experiment: 0.170 W/cm², 0.727 W/cm², and 1.427 W/cm². The research findings revealed distinct characteristics: plasma actuators and resistance wire actuators exhibited a strip-like high-temperature region during operation, with well-defined boundaries between the high-temperature and low-temperature zones, whereas ceramic-based semiconductor actuators showcased a uniform high-temperature region. As energy consumption rose, the thermal equilibrium temperatures of all three types tended to converge, with resistance wire actuators operating at 1.427 W/cm², showing the highest temperature rise rate at that power density. Subsequently, experimental research was carried out on the de-icing performance of three actuators under icing conditions at a specific power density. Following 120 s of de-icing, the ice layer covering the surface of the plasma actuator completely melted, forming a cavity. Conversely, the ice layer on the ceramic-based semiconductor actuator remained partially intact in a strip shape. Ice deposits were still visible on the surface of the resistance wire actuator. This observation highlights the remarkable de-icing speed of the plasma actuator. The propulsive force of plasma generated on the fluid inside the ice layer enhances heat transfer efficiency, thereby accelerating the de-icing process of the plasma actuator at the same power density. The analysis of the de-icing performance of these three novel types of actuators establishes a robust groundwork for exploring more effective aircraft de-icing methods. Furthermore, it furnishes theoretical underpinning for the advancement of composite anti-icing and de-icing strategies. Full article

Bulk metallic glasses are modern engineering materials with unique functional properties. Zr-based alloys are particularly attractive as they exhibit high glass forming ability as well as good mechanical properties. Due to their relatively high thermal stability, reaching as much as 400 °C, they can be surface-treated in low-temperature plasma to further improve their mechanical properties. The subject of this study was to determine the influence of the technological parameters of nitriding in low-temperature plasma on the structure and mechanical properties of Zr₄₈Cu₃₆Al₈Ag₈ bulk metallic glass. In the course of this study, the influence of the ion accelerating voltage on the structure and micromechanical properties of the bulk metallic glass was analyzed. The produced samples were characterized in terms of nanohardness, layer adhesion by using the scratch test, and wear resistance by using the ball-on-disc method. As a result of low-temperature plasma nitriding, a significant increase in the surface nanohardness of the Zr₄₈Cu₃₆Al₈Ag₈ bulk metallic glass was obtained. The produced layers exhibited high adhesion to the substrate and they improved the wear resistance of the glass. The present study indicates the possibility of modifying the surface properties of bulk metallic glasses by using diffusion processes in low-temperature plasma without substrate crystallization. Full article

Haemorrhage control during surgery and following traumatic injury remains a critical, life-saving challenge. Cellulose products are already employed in commercially available haemostatic dressings. This work explores sourcing cellulose from sugarcane trash pulp to produce micro- and nanosized fibres with hydroxyl, carboxylic acid, and trimethylamine functional groups, resulting in either positive or negative surface charges. This paper assesses the influence of these fibres on multiple blood clotting parameters in both dispersed solutions and dry gauze applications. In vitro blood clotting studies demonstrated the significant haemostatic potential of cellulose fibres derived from sugarcane waste to initiate clotting. Plasma absorbance assays showed that the 0.25 mg/mL cellulose microfibre dispersion had the highest clotting performance. It was observed that no single property of surface charge, functionality, or fibre morphology exclusively controlled the clotting initiation measured. Instead, a combination of these factors affected clot formation, with negatively charged cellulose microfibres comprising hydroxyl surface groups providing the most promising result, accelerating the coagulation cascade mechanism by 67% compared to the endogenous activity. This difference in clot initiation shows the potential for the non-wood agricultural waste source of cellulose in haemostatic wound healing applications, contributing to the broader understanding of cellulose-based materials’ versatility and their applications in biomedicine. Full article

Dielectric barrier discharge plasma actuators (DBD-PAs) have the potential to improve the performance of fluid machineries such as aircrafts and wind turbines by preventing flow separation. In this study, to identify the multiple flow control mechanisms in high Reynolds number flow, parametric experiments for an actuation parameter $F^{+}$ with a wide range of Re values (10⁵–10⁶) for NACA0015 airfoil was conducted. We conducted wind tunnel tests by applying a DBD-PA to the flow field around a wing model at the leading edge. Lift characteristics, turbulent kinetic energy in the flow field, shear layer height, and the separation point of the boundary layer were evaluated based on pressure distributions on the wing surface and velocity of the flow field, with the effect of DBD-PA on the post-stall flow around the wing and the mechanism behind the increase in the lift coefficient $C_L$ analyzed based on these evaluation results. The following phenomena contributed to the increase in $C_L$: (1) increase in turbulent kinetic energy; (2) increase in circulation; and (3) acceleration of the flow near the leading edge. Thus, this study effectively investigated the dependence of the increase in lift on $F^{+}$ and the lift-increasing mechanism for a wide range of Re values. Full article

Machine learning deals with creating algorithms capable of learning from the provided data. These systems have a wide range of applications and can also be a valuable tool for scientific research, which in recent years has been focused on finding new diagnostic techniques for particle accelerator beams. In this context, SPARC_LAB is a facility located at the Frascati National Laboratories of INFN, where the progress of beam diagnostics is one of the main developments of the entire project. With this in mind, we aim to present the design of two neural networks aimed at predicting the spot size of the electron beam of the plasma-based accelerator at SPARC_LAB, which powers an undulator for the generation of an X-ray free electron laser (XFEL). Data-driven algorithms use two different data preprocessing techniques, namely an autoencoder neural network and PCA. With both approaches, the predicted measurements can be obtained with an acceptable margin of error and most importantly without activating the accelerator, thus saving time, even compared to a simulator that can produce the same result but much more slowly. The goal is to lay the groundwork for creating a digital twin of linac and conducting virtualized diagnostics using an innovative approach. Full article

Si-based anode is considered one of the ideal anodes for high energy density lithium-ion batteries due to its high theoretical capacity of 4200 mAh g⁻¹. To accelerate the commercial progress of Si material, the multi-issue of extreme volume expansion and low intrinsic electronic conductivity needs to be settled. Herein, a series of nano-sized Si particles with conductive networks are synthesized via the dielectric barrier discharge plasma (DBDP) assisted milling. The p-milling method can effectively refine the particle sizes of pristine Si without destroying its crystal structure, resulting in large Brunauer–Emmett–Teller (BET) values with more active sites for Li⁺ ions. Due to their unique structure and flexibility, CNTs can be uniformly distributed among the Si particles and the prepared Si electrodes exhibit better structural stability during the continuous lithiation/de-lithiation process. Moreover, the CNT network accelerates the transport of ions and electrons in the Si particles. As a result, the nano-sized Si anodes with CNTs conductive network can deliver an extremely high average initial Coulombic efficiency (ICE) reach of 90.2% with enhanced cyclic property and rate capability. The C-PMSi-50:1 anode presents 615 mAh g⁻¹ after 100 cycles and 979 mAh g⁻¹ under the current density of 5 A g⁻¹. Moreover, the manufactured Si||LiNi_0.8Co_0.1Mn_0.1O₂ pouch cell maintains a high ICE of >85%. This work may supply a new insight for designing the nano-sized Si and further promoting its commercial applications. Full article

Apatite, as a common accessory mineral found in magmatic–hydrothermal deposits, effectively yields geochemical insights that facilitate our understanding of the mineralization process. In this research, multiple generations of magmatic and hydrothermal apatite were observed in the Hongshan porphyry–skarn Cu–Mo deposit in the Yidun Terrane in SW China. The geochemical compositions of the apatite were studied using in situ laser ablation–inductively coupled plasma mass spectrometry and an electron probe microanalysis to understand the magmatic–hydrothermal processes leading to ore formation. The apatite (Ap1a) occurs as subhedral to euhedral inclusions hosted in the phenocrysts of the granite porphyry. The Ap1b occurs later than Ap1a in a fine-grained matrix that intersects the earlier phenocrysts. Increases in F/Cl, F/OH, and F/S and decreases in ΣREE and (La/Yb)_N from Ap1a to Ap1b suggest the exsolution of a volatile-rich phase from the magma. The skarn hosts three types of hydrothermal apatite (Ap2a, Ap2b, and Ap3), marking the prograde, retrograde, and quartz–sulfide stages of mineralization, respectively. The elemental behaviors of hydrothermal apatite, including the changes in Cl, Eu, As, and REE, were utilized to reflect evolutions in salinity, pH, oxygen fugacity, and fluid compositions. The composition of Ap2a, which occurs as inclusions within garnet, indicates the presence of an early acidic magmatic fluid with high salinity and oxygen fugacity at the prograde skarn stage. The composition of Ap2b, formed by the coupled dissolution-reprecipitation of Ap2a, indicates the presence of a retrograde fluid that is characterized by lower salinity, higher pH, and a significant decrease in oxygen fugacity compared to the prograde fluid. The Ap3 coexists with quartz and sulfide minerals. Based on studies of Ap3, the fluids in the quartz–sulfide stage exhibit relatively reducing conditions, thereby accelerating the precipitation of copper and iron sulfides. This research highlights the potential of apatite geochemistry for tracing magmatic–hydrothermal evolution processes and identifying mineral exploration targets. Full article