Search Results (1,910)

A fish processed with red vinasse is a type of Fujian cuisine with regional characteristics. In order to monitor the effect of red vinasse on storage quality and shelf life of blue round scad (Decapterus maruadsi) during storage, the changes in fat content, thiobarbituric acid reactive substances (TBARS), composition of polyunsaturated fatty acids (PUFAs), pH value, texture, and sensory quality were studied at different storage temperatures (4 °C, 25 °C, and 37 °C). By analyzing the correlation between changes in sensory qualities and physical and chemical indexes, a first-order kinetic model and the Arrhenius equation were used to build a shelf-life prediction model for blue round scad during storage. The results showed that processing with red vinasse can significantly reduce the malondialdehyde (MDA) production and the decrease in PUFAs, eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA) (p < 0.05) during storage. Based on partial least squares regression (PLSR), the storage temperature and time have a significant impact on the PUFA composition in blue round scad, which changed less when the samples were stored at 4 °C and 25 °C, and they had better nutritional composition of fatty acids at lower temperatures. Among the PUFAs, DHA (C22:6n-3) and EPA (C20:5n-3) had higher relative contents and significantly decreased during storage (p < 0.05). Additionally, the processing with red vinasse can slow down the increase in total volatile basic nitrogen (TVB-N) value and pH of blue round scad, maintain the appropriate hardness, elasticity, cohesion and chewability, and improve the overall sensory quality of the fish. In addition, according to the results of model prediction based on TBARS value, the storage shelf life of blue round scad with red vinasse added was 55 d, 2.7 d and 28 h at 4 °C, 25 °C and 37 °C, respectively. The accuracy of the forecast model was high, and the relative errors of the measured values and predicted values were less than 10%. Thus, it not only provided a theoretical basis for the processing and application of red vinasse to Chinese traditional food, but also provided innovative ideas for the safe storage and high-value utilization of blue round scad. Full article

In recent decades, the integrity and security of the ecosystem in the Sanjiang Plain have faced severe challenges due to land reclamation. Understanding the impact of paddy field expansion on regional ecosystem services (ESs), as well as revealing the trade-offs and synergies (TOS) between these services to achieve optimal resource allocation, has become an urgent issue to address. This study employs the InVEST model to map the spatial and temporal dynamics of five key ESs, while the Optimal Parameter Geodetector (OPGD) identifies primary drivers of these changes. Correlation analysis and Geographically Weighted Regression (GWR) reveal intricate TOS among ESs at multiple scales. Additionally, the Partial Least Squares-Structural Equation Model (PLS-SEM) elucidates the direct impacts of paddy field expansion on ESs. The main findings include the following: (1) The paddy field area in the Sanjiang Plain increased from 5775 km² to 18,773.41 km² from 1990 to 2020, an increase of 12,998.41 km² in 40 years. And the area of other land use types has generally decreased. (2) Overall, ESs showed a recovery trend, with carbon storage (CS) and habitat quality (HQ) initially decreasing but later improving, and consistent increases were observed in soil conservation, water yield (WY), and food production (FP). Paddy fields, drylands, forests, and wetlands were the main ES providers, with soil type, topography, and NDVI emerging as the main influencing factors. (3) Distinct correlations among ESs, where CS shows synergies with HQ and SC, while trade-offs are noted between CS and both WY and FP. These TOS demonstrate significant spatial heterogeneity and scale effects across subregions. (4) Paddy field expansion enhances regional SC, WY, and FP, but negatively affects CS and HQ. These insights offer a scientific basis for harmonizing agricultural development with ecological conservation, enriching our understanding of ES interrelationships, and guiding sustainable ecosystem management and policymaking. Full article

The scale factor of thermal sensitivity serves as a crucial performance metric for micro-electromechanical system (MEMS) gyroscopes, and is commonly employed to assess the temperature stability of inertial sensors. To improve the temperature stability of the scale factor of MEMS gyroscopes, a self-compensation method is proposed. This is achieved by integrating the primary and secondary relevant parameters of the scale factor using the partial least squares regression (PLSR) algorithm. In this paper, a scale factor prediction model is presented. The model indicates that the resonant frequency and demodulation phase angle are the primary correlation terms of the scale factor, while the drive control voltage and quadrature feedback voltage are the secondary correlation terms of the scale factor. By employing a weighted fusion of correlated terms through PLSR, the scale factor for temperature sensitivity is markedly enhanced by leveraging the predicted results to compensate for the output. The results indicate that the maximum error of the predicted scale factor is 0.124% within the temperature range of −40 °C to 60 °C, and the temperature sensitivity of the scale factor decreases from 6180 ppm/°C to 9.39 ppm/°C. Full article

To enhance lychee quality assessment and address inconsistencies in post-harvest pest detection, this study presents a multi-source fusion approach combining hyperspectral imaging, X-ray imaging, and visible/near-infrared (Vis/NIR) spectroscopy. Traditional single-sensor methods are limited in detecting pest damage, particularly in lychees with complex skins, as they often fail to capture both external and internal fruit characteristics. By integrating multiple sensors, our approach overcomes these limitations, offering a more accurate and robust detection system. Significant differences were observed between pest-free and infested lychees. Pest-free lychees exhibited higher hardness, soluble sugars (11% higher in flesh, 7% higher in peel), vitamin C (50% higher in flesh, 2% higher in peel), polyphenols, anthocyanins, and ORAC values (26%, 9%, and 14% higher, respectively). The Vis/NIR data processed with SG+SNV+CARS yielded a partial least squares regression (PLSR) model with an R² of 0.82, an RMSE of 0.18, and accuracy of 89.22%. The hyperspectral model, using SG+MSC+SPA, achieved an R² of 0.69, an RMSE of 0.23, and 81.74% accuracy, while the X-ray method with support vector regression (SVR) reached an R² of 0.69, an RMSE of 0.22, and 76.25% accuracy. Through feature-level fusion, Recursive Feature Elimination with Cross-Validation (RFECV), and dimensionality reduction using PCA, we optimized hyperparameters and developed a Random Forest model. This model achieved 92.39% accuracy in pest detection, outperforming the individual methods by 3.17%, 10.25%, and 16.14%, respectively. The multi-source fusion approach also improved the overall accuracy by 4.79%, highlighting the critical role of sensor fusion in enhancing pest detection and supporting the development of automated non-destructive systems for lychee stem borer detection. Full article

Accurate estimation of chlorophyll content is essential for understanding the growth status and optimizing the cultivation practices of Ginkgo, a dominant multi-functional tree species in China. Traditional methods based on chemical analysis for determining chlorophyll content are labor-intensive and time-consuming, making them unsuitable for large-scale dynamic monitoring and high-throughput phenotyping. To accurately quantify chlorophyll content in Ginkgo seedlings under different nitrogen levels, this study employed a hyperspectral imaging camera to capture canopy hyperspectral images of seedlings throughout their annual growth periods. Reflectance derived from pure leaf pixels of Ginkgo seedlings was extracted to construct a set of spectral parameters, including original reflectance, logarithmic reflectance, and first derivative reflectance, along with spectral index combinations. A one-dimensional convolutional neural network (1D-CNN) model was then developed to estimate chlorophyll content, and its performance was compared with four common machine learning methods, including Gaussian Process Regression (GPR), Partial Least Squares Regression (PLSR), Support Vector Regression (SVR), and Random Forest (RF). The results demonstrated that the 1D-CNN model outperformed others with the first derivative spectra, achieving higher CV-R² and lower RMSE values (CV-R² = 0.80, RMSE = 3.4). Furthermore, incorporating spectral index combinations enhanced the model’s performance, with the 1D-CNN model achieving the best performance (CV-R² = 0.82, RMSE = 3.3). These findings highlight the potential of the 1D-CNN model in strengthening the chlorophyll estimations, providing strong technical support for the precise cultivation and the fertilization management of Ginkgo seedlings. Full article

Nitrogen fertilization is a challenging task that usually requires intensive use of resources, such as fertilizers, management and water. This study explored the potential of VIS-NIR-SWIR remote sensing for quantifying leaf nitrogen content (LNC) in sugarcane from different regions and vegetative stages. Conducted in three regions of São Paulo, Brazil (Jaú, Piracicaba and Santa Maria), the research involved three experiments, one per location. The spectral data were obtained at 140, 170, 200, 230 and 260 days after cutting (DAC). From the hyperspectral data, clustering analysis was performed to identify the patterns between the spectral bands for each region where the spectral readings were made, using the Partitioning Around Medoids (PAM) algorithm. Then, the LNC values were used to generate spectral models using Partial Least Squares Regression (PLSR). Subsequently, the generalization of the models was tested with the leave-one-date-out cross-validation (LOOCV) technique. The results showed that although the variation in leaf N was small, the sensor demonstrated the ability to detect these variations. Furthermore, it was possible to determine the influence of N concentrations on the leaf spectra and how this impacted cluster formation. It was observed that the greater the average variation in N content in each cluster, the better defined and denser the groups formed were. The best time to quantify N concentrations was at 140 DAC (R² = 0.90 and RMSE = 0.74 g kg⁻¹). From LOOCV, the areas with sandier soil texture presented a lower model performance compared to areas with clayey soil, with R² < 0.54. The spatial generalization of the models recorded the best performance at 140 DAC (R² = 0.69, RMSE = 1.18 g kg⁻¹ and dr = 0.61), decreasing in accuracy at the crop-maturation stage (260 DAC), R² of 0.05, RMSE of 1.73 g kg⁻¹ and dr of 0.38. Although the technique needs further studies to be improved, our results demonstrated potential, which tends to provide support and benefits for the quantification of nutrients in sugarcane in the long term. Full article

Key soil properties play pivotal roles in shaping crop growth and yield outcomes. Accurate point prediction and interval prediction of soil properties serve as crucial references for making informed decisions regarding fertilizer applications. Traditional soil testing methods often entail laborious and resource-intensive chemical analyses. To address this challenge, this study introduced a novel approach leveraging spectral data fusion techniques to forecast key soil properties. The initial datasets were derived from UV–visible–near-infrared (UV-Vis-NIR) spectral data and mid-infrared (MIR) spectral data, which underwent preprocessing stages involving smoothing denoising and fractional-order derivative[s] (FOD) transform techniques. After extracting the characteristic bands from both types of spectral data, three fusion strategies were developed, which were further enhanced using machine learning techniques. Among these strategies, the outer-product analysis fusion algorithm proved particularly effective in improving prediction accuracy. For point predictions, metrics such as the coefficient of determination (R²) and error metrics demonstrated significant enhancements compared to predictions based solely on single-source spectral data. Specifically, R² values increased by 0.06 to 0.41, underscoring the efficacy of the fusion approach combined with partial least squares regression (PLSR). In addition, based on the coverage width criterion to establish reliable prediction intervals for key soil properties, including soil organic matter (SOM), total nitrogen (TN), hydrolyzed nitrogen (HN), and available potassium (AK). These intervals were developed within the framework of the kernel density estimation (KDE) interval prediction model, which facilitates the quantification of uncertainty in property estimates. For available phosphorus (AP), a preliminary assessment of its concentration was also provided. By integrating advanced spectral data fusion with machine learning, this study paves the way for more informed agricultural decision making and sustainable soil management strategies. Full article

Color is a key indicator for evaluating the quality of tea during processing; various processing procedures can significantly affect the content of fat-soluble pigments of tea, which in turn affects the color and quality of finished tea. Therefore, there is an urgent demand for the fast, non-destructive detection of pigments of stacked tea during processing. This paper presents the use of hyperspectral imaging technology (HSI), combined with machine learning algorithms, to detect chlorophyll a, chlorophyll b, and carotenoids in stacked matcha tea during processing. Firstly, a quantitative relationship between HSI data of tea and their pigment contents was developed based on regression analysis, and the results showed that exceptional prediction performance was achieved by the partial least squares regression (PLSR) algorithm combined with the feature band algorithm of competitive adaptive reweighting (CARS), and the R_p² values of detection models of chlorophyll a, chlorophyll b and carotenoids were 0.90465, 0.92068 and 0.62666, respectively. Then, these quantitative detection models were extended to each pixel in hyperspectral images, achieving point-by-point prediction of pigment components, so the distribution of pigments of stacked tea leaves during processing procedures was successfully visualized on the processing line in situ. By integrating a hyperspectral imaging system into the real-world environment, operators can monitor pigment levels in real time and thus dynamically adjust processing parameters based on real-time data. This study enhances pigment detection efficiency in tea processing, supports process optimization, and aids in quality control. Full article

The upcoming Landsat Next will provide more frequent land surface observations at higher spatial and spectral resolutions that will greatly benefit the agricultural sector. Early modeling of the upcoming Landsat Next products for soybean yield prediction is essential for long-term satellite monitoring strategies. In this context, this article evaluates the contribution of Landsat Next’s improved spectral resolution for soybean yield prediction under varying levels of water availability. Ground-based hyperspectral data collected over five cropping seasons at the Brazilian Agricultural Research Corporation were resampled to Landsat Next spectral resolution. The spectral dataset (n = 384) was divided into calibration and external validation datasets and investigated using three strategies for soybean yield prediction: (1) using the reflectance from each spectral band; (2) using existing and new vegetation indices developed based on three general equations: Normalized Difference Vegetation Index (NDVI-like), Band Ratio Vegetation Index (RVI-like), and Band Difference Vegetation Index (DVI-like), replacing the traditional spectral bands by all possible combinations between two bands for index calculation; and (3) using a partial least squares regression (PLSR) model composed of all Landsat Next spectral bands, in comparison to PLSR models using Landsat OLI and Sentienel-2 MSI bands. The results show the distribution of the new spectral bands over the most prominent changes in leaf reflectance due to water deficit, particularly in the visible and shortwave infrared spectrum. (1) Band 18 (centered at 1610 nm) had the highest correlation with yield (R² = 0.34). (2) A new vegetation index, called Normalized Difference Shortwave Vegetation Index (NDSWVI), is proposed and calculated from bands 19 and 20 (centered at 2028 and 2108 nm). NDSWVI showed the best performance (R² = 0.37) compared to traditional existing and new vegetation indices. (3) The PLSR model gave the best results (R² = 0.65), outperforming the Landsat OLI and Sentinel-2 MSI sensors. The improved spectral resolution of Landsat Next is expected to contribute to improved crop monitoring, especially for soybean crops in Brazil, increasing the sustainability of the production systems and strengthening food security in Brazil and globally. Full article

Indomethacin (INDO) is a synthetic non-steroidal antipyretic, analgesic, and anti-inflammatory drug that commonly exists in both amorphous and crystalline states. Its amorphous state (A-INDO) is utilized by pharmaceutical companies as an active pharmaceutical ingredient (API) in the production of INDO drugs due to its higher apparent solubility and bioavailability. The crystal state also encompasses various crystal forms such as the α-crystal form (α-INDO) and γ-crystal form (γ-INDO), with the highly crystalline and insoluble γ-INDO being commercially available. A-INDO, existing in a thermodynamically high-energy state, is susceptible to several factors during the preparation, storage, and transportation of API leading to its conversion into γ-INDO, thus impacting the bioavailability and efficacy of INDO drugs. Therefore, quantitative analysis of the A-INDO/γ-INDO content in INDO API becomes essential for controlling the production quality of INDO. The primary objective of this study is to investigate the feasibility of NIR for the quantitative analysis of A-INDO in INDO API, and to further elucidate its quantitative analysis mechanism. The NIR spectral data were collected for A-INDO and γ-INDO binary mixture samples with different resolutions, and these spectra were then selected and reconstructed using the interval partial least square (iPLS) method. Different pretreatment methods were employed to enhance the reconstructed spectra by highlighting relevant eigen information while eliminating invalid information caused by environmental factors or physical characteristics of samples. The most suitable PLSR model for quantitative analysis of A-INDO within the range of 0.0000–100.0000% w/w% was established, screened, and validated. From various perspectives, including distribution of spectral effective information, impact of resolution on PLSR model performance, variance contribution/cumulative variance contribution of PLSR model principal components (PCs), PC_I loadings, relationship between spectral scores, and A-INDO content, feasibility assessment was conducted for the quantitative analysis of A-INDO in INDO using NIR spectroscopy. Additionally, a detailed investigation on the quantitative analysis mechanism of the optimal PLSR model was undertaken including the correlation between the characteristic peaks of spectra and information regarding hydrogen groups or hydrogen bonds in A-INDO or γ-INDO molecules. This study aims to provide theoretical support for the quantitative analysis of A-INDO in INDO API as well as serve as a reliable reference method for API quantification and quality control in similar drugs. Full article

Potatoes are a staple food crop consumed worldwide, with their significance extending from household kitchens to large-scale food processing industries. Their market value and quality are often compromised by various internal defects such as pythium, bruising, internal browning, hollow heart, gangrene, blackheart, internal sprouting, and dry rot. This study aimed to classify internal-based defects and investigate the quantification of internal defective areas in potatoes using visible and short-wavelength near-infrared spectroscopy. The acquisition of the spectral data of potato tubers was performed using a spectrometer with a wavelength range of 400–1100 nm. The classification of internal-based defects was performed using partial least squares discriminant analysis (PLS-DA), while the quantification of the internal defective area was based on partial least squares regression (PLSR). The PLS-DA double cross-validation accuracy for the distinction between non-defective and all internally defective potatoes was 90.78%. The double cross-validation classification accuracy achieved for pythium, bruising, and non-defective categories was 91.03%. The internal defective area model based on PLSR achieved a correlation coefficient of double cross-validation of 0.91 and a root mean square error of double cross-validation of 0.85 cm². This study makes a valuable contribution to advancing nondestructive techniques for evaluating internal defects in potatoes. Full article

Metabolic dysfunction-associated steatotic liver disease (MASLD) is often asymptomatic and underdiagnosed; consequently, there is a demand for simple, non-invasive diagnostic tools. In this study, we developed a method to quantify liver steatosis based on miRNAs, present in liver and serum, that correlate with liver fat. The miRNAs were analyzed by miRNAseq in liver samples from two cohorts of patients with a precise quantification of liver steatosis. Common miRNAs showing correlation with liver steatosis were validated by RT-qPCR in paired liver and serum samples. Multivariate models were built using partial least squares (PLS) regression to predict the percentage of liver steatosis from serum miRNA levels. Leave-one-out cross validation and external validation were used for model selection and to estimate predictive performance. The miRNAseq results disclosed (a) 144 miRNAs correlating with triglycerides in a set of liver biobank samples (n = 20); and (b) 124 and 102 miRNAs correlating with steatosis by biopsy digital image and MRI analyses, respectively, in liver samples from morbidly obese patients (n = 24). However, only 35 miRNAs were common in both sets of samples. RT-qPCR allowed to validate the correlation of 10 miRNAs in paired liver and serum samples. The development of PLS models to quantitatively predict steatosis demonstrated that the combination of serum miR-145-3p, 122-5p, 143-3p, 500a-5p, and 182-5p provided the lowest root mean square error of cross validation (RMSECV = 1.1, p-value = 0.005). External validation of this model with a cohort of mixed MASLD patients (n = 25) showed a root mean squared error of prediction (RMSEP) of 5.3. In conclusion, it is possible to predict the percentage of hepatic steatosis with a low error rate by quantifying the serum level of five miRNAs using a cost-effective and easy-to-implement RT-qPCR method. Full article

The leaf area index (LAI) and leaf chlorophyll content (LCC) are key indicators of crop photosynthetic efficiency and nitrogen status. This study explores the integration of UAV-based multispectral (MS) and thermal infrared (TIR) data to improve the estimation of maize LAI and LCC across different growth stages, aiming to enhance nitrogen (N) management. In field trials from 2022 to 2023, UAVs captured canopy images of maize under varied water and nitrogen treatments, while the LAI and LCC were measured. Estimation models, including partial least squares regression (PLS), convolutional neural networks (CNNs), and random forest (RF), were developed using spectral, thermal, and textural data. The results showed that MS data (spectral and textural features) had strong correlations with the LAI and LCC, and CNN models yielded accurate estimates (LAI: R² = 0.61–0.79, RMSE = 0.02–0.38; LCC: R² = 0.63–0.78, RMSE = 2.24–0.39 μg/cm²). Thermal data reflected maize growth but had limitations in estimating the LAI and LCC. Combining MS and TIR data significantly improved the estimation accuracy, increasing R² values for the LAI and LCC by up to 23.06% and 19.01%, respectively. Nitrogen dilution curves using estimated LAIs effectively diagnosed crop N status. Deficit irrigation reduced the N uptake, intensifying the N deficiency, while proper water and N management enhanced the LAI and LCC. Full article

Due to the current and predicted increase in the global demand for water–energy–food (WEF) resources, as well as the inevitable linkages between the WEF sectors and sustainable development, the WEF nexus is rapidly being recognized as a method to effectively manage sustainable development. Many African countries still face challenges in terms of the demand for and accessibility of WEF resources. For this reason, a comparative study of two sites (Narok County and Vhembe District Municipality), which exhibit similar socio-economic, environmental, and technological circumstances, was undertaken. In the present study, we considered 218 questionnaire responses, which we analyzed using partial least squares structural equation modeling (SEM) based on the WEF nexus constructs. This study is anchored on the null hypothesis (H0), whereby no interdependencies exist between the state of the climate and WEF resources, as constrained by sustainable development options. The results show that the proposed hypothesis does not hold, but rather, an alternative hypothesis (Ha)—there exist linkages between climate change and WEF resources—holds. This is demonstrated by the descriptive statistics indicating p values < 0.05 for both the t-test and the Bartlett test. Furthermore, analysis from the multi-regression, particularly for the model where we combined the sites, showed p values < 0.05 and higher adjusted r-squared values, which denoted a better fit. The communities in both study sites agree that the regions have experienced a scarcity of WEF resources due to climate change. The results show that climate change is an intrinsic part of the developmental options for the sustainable livelihood of both study sites, which aligns with the 2030 UN agenda on sustainable development goals targets. Moreover, the sustainable management of natural resources that are people- and planet-centric is crucial to climate change adaptation and mitigation, social justice, equity, and inclusion. The SEM results showed with significant confidence that the water, energy, and food sectors are closely interconnected; however, their impact on climate and sustainability is significantly different. Food has a direct positive impact on climate and sustainability, while both water and energy have an indirect negative impact. Moreover, the climate construct indicated a significant direct link to sustainability for all the relationships explored. This is particularly true because, in most underdeveloped countries, sustainable development and societal wellbeing heavily rely on goods and services derived from natural resources and the environment. This study contributes to the nexus modeling research field by introducing SEM as an innovative methodology over a single equation modeling framework in analyzing variables that have complex interrelationships, facilitating advanced WEF nexus resource governance. Full article

Carbon fiber-reinforced polymer (CFRP) structures have been increasingly used in various aerospace sectors due to their outstanding mechanical properties in recent years. However, the poor machinability of CFRP plates, combined with the inhomogeneous behavior of fibers, poses a challenge for manufacturers and researchers to define the critical factors and conditions necessary to ensure the quality of holes in CFRP structures. This study aims to analyze the effect of drilling parameters on CFRP delamination and to predict hole quality using a regression-based approach. The design of the experiment (DOE) was conducted using Taguchi’s L9 3-level orthogonal array. The input drilling variables included the feed rate, spindle speed, and three different drill types. A regression-based model using partial least squares (PLS) was developed to predict delamination defects during the drilling of CFRP plates. The PLS model demonstrated high accuracy in predicting delamination defects, with a Mean Squared Error (MSE) of 0.0045, corresponding to an accuracy of approximately 99.6%, enabling the rapid estimation of delamination. The model’s predictions were closely aligned with the experimental results, although some deviations were observed due to tool inefficiencies, particularly with end mill cutters. These findings offer valuable insights for researchers and practitioners, enhancing the understanding of delamination in CFRPs and identifying areas for further investigation. Full article