[go: up one dir, main page]

 
 
Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Article Types

Countries / Regions

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Search Results (298)

Search Parameters:
Keywords = modified textiles

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
17 pages, 4501 KiB  
Article
Preparation and Characterization of Novel Poly(Lactic Acid) Composites Reinforced with “Latxa” Sheep Wool Fibers: The Effect of Peroxide Surface Treatments and Fiber Content
by Aitor Arbelaiz, Telmo Yurramendi, Ander Larruscain, Ane Arrizabalaga, Arantxa Eceiza and Cristina Peña-Rodriguez
Materials 2024, 17(19), 4912; https://doi.org/10.3390/ma17194912 - 8 Oct 2024
Viewed by 561
Abstract
“Latxa” sheep wool is rough, and it is not used in the textile industry because the fiber diameter is high compared with other wool fibers. Nowadays, this wool is considered as disposal and, with the aim to give it value, new uses must [...] Read more.
“Latxa” sheep wool is rough, and it is not used in the textile industry because the fiber diameter is high compared with other wool fibers. Nowadays, this wool is considered as disposal and, with the aim to give it value, new uses must be explored. In the current work, the “Latxa” sheep wool fiber was evaluated as poly(lactic acid) (PLA) polymer reinforcement. With the objective to optimize fiber/matrix adhesion, fibers were surface modified with peroxide. Oxidation treatment with peroxide led to chemical modifications of the wool fibers that improved the fiber/PLA adhesion, but the strength values achieved for the composites were lower compared to the neat PLA ones. The mechanical properties obtained in the current work were compared with the literature data of the PLA composites reinforced with vegetable fibers. The wool fibers showed inferior mechanical properties compared to the vegetable fiber counterparts. However, the preliminary results indicated that the incorporation of wool fibers to PLA reduced the flammability of composites. Full article
(This article belongs to the Section Advanced Composites)
Show Figures

Figure 1

Figure 1
<p>FTIR spectra of studied wool fibers.</p>
Full article ">Figure 2
<p>The possible cleavage of intramolecular disulphide bonds due to oxidation treatment with peroxide: (<b>a</b>) Intramolecular; scission in two molecules with the surface chemically modified and (<b>b</b>) Intramolecular; the surface chemical modification.</p>
Full article ">Figure 3
<p>Photographs used for contact angle values measurements: (<b>a</b>) soap-cleaned wool fibers and (<b>b</b>) peroxide-treated fibers for 24 h.</p>
Full article ">Figure 4
<p>(<b>a</b>) Thermogravimetric analysis and (<b>b</b>) derivative thermogravimetry curves of wool fibers.</p>
Full article ">Figure 5
<p>The fiber loading increased from 5 wt.% (<b>left</b>) up to 30 wt.% (<b>right</b>).</p>
Full article ">Figure 6
<p>Tensile properties as a function of wool fiber loading and fiber treatment: (<b>a</b>) strength; (<b>b</b>) modulus and (<b>c</b>) deformation at break.</p>
Full article ">Figure 7
<p>DSC thermograms of neat PLA and composites with 30 wt% of wool fiber with different surface treatments.</p>
Full article ">Figure 8
<p>Fractured surface SEM micrographs of wool fiber-reinforced PLA composites with a magnification of ×50: (<b>a</b>) soap-cleaned fibers; (<b>b</b>) 30 min peroxide-treated fibers and (<b>c</b>) 24 h peroxide-treated fibers. A magnification of ×200: (<b>d</b>) soap-cleaned fibers; (<b>e</b>) 30 min peroxide-treated fibers and (<b>f</b>) 24 h peroxide-treated fibers.</p>
Full article ">Figure 9
<p>The appearance of PLA/natural fiber specimens with 30 wt.% of fiber loading before, during, and at the end of vertical burn test.</p>
Full article ">Figure 10
<p>The appearance of specimens after vertical burn test with 30 wt.% of peroxide-treated wool: 30 min peroxide-treated (up) and 24 h peroxide-treated (down).</p>
Full article ">
22 pages, 9075 KiB  
Article
Textile Organic Electrochemical Transistor for Non-Invasive Glucose Sensing
by Rike Brendgen, Thomas Grethe and Anne Schwarz-Pfeiffer
Micro 2024, 4(4), 530-551; https://doi.org/10.3390/micro4040033 - 30 Sep 2024
Viewed by 433
Abstract
The global rise in diabetes has highlighted the urgent need for continuous, non-invasive health monitoring solutions. Traditional glucose monitoring methods, which are invasive and often inconvenient, have created a demand for alternative technologies that can offer comfort, accuracy, and real-time data. In this [...] Read more.
The global rise in diabetes has highlighted the urgent need for continuous, non-invasive health monitoring solutions. Traditional glucose monitoring methods, which are invasive and often inconvenient, have created a demand for alternative technologies that can offer comfort, accuracy, and real-time data. In this study, the development of a textile-based organic electrochemical transistor (OECT) is presented, designed for non-invasive glucose sensing, aiming to integrate this technology seamlessly into everyday clothing. The document details the design, optimization, and testing of a one-component textile-based OECT, featuring a porous PEDOT:PSS structure and a glucose oxidase-modified electrolyte for effective glucose detection in sweat. The research demonstrates the feasibility of using this textile-based OECT for non-invasive glucose monitoring, with enhanced sensitivity and specificity achieved through the integration of glucose oxidase within the electrolyte and the innovative porous PEDOT:PSS design. These findings suggest a significant advancement in wearable health monitoring technologies, providing a promising pathway for the development of smart textiles capable of non-invasively tracking glucose levels. Future work should focus on refining this technology for clinical use, including individual calibration for accurate blood glucose correlation and its integration into commercially available smart textiles. Full article
Show Figures

Figure 1

Figure 1
<p>Chemical reaction of glucose with glucose oxidase (<span class="html-italic">GOx</span>) (own illustration in accordance with [<a href="#B13-micro-04-00033" class="html-bibr">13</a>]).</p>
Full article ">Figure 2
<p>Bending of textile one-component OECT between fingers.</p>
Full article ">Figure 3
<p>Schematic measurement set-up for the electrical characterization of OECTs.</p>
Full article ">Figure 4
<p>SEM images and EDS mapping of ready-made OECTs 7–9 with PUP1S2 as source-drain electrode. (<b>A</b>) Longitudinal view; (<b>B</b>) cross-sectional view with thickness measurements; (<b>C</b>) EDS mapping.</p>
Full article ">Figure 5
<p>SEM images and EDS mapping of ready-made OECTs 4–6 with TS1P4 as source-drain electrode. (<b>A</b>) Longitudinal view; (<b>B</b>): cross-sectional view with thickness measurements; (<b>C</b>) EDS mapping.</p>
Full article ">Figure 6
<p>SEM images and EDS mapping of ready-made OECTs 1–3 with NWP8 as source-drain electrode. (<b>A</b>) Longitudinal view; (<b>B</b>) cross-sectional view with thickness measurements; (<b>C</b>) EDS mapping.</p>
Full article ">Figure 7
<p>Different colors of porous PEDOT:PSS samples observed during OECT measurements. (<b>A</b>) Dark blue PEDOT:PSS at constant +0.5 Vsd and +1.0 Vg; (<b>B</b>) bright blue PEDOT:PSS at constant +0.5 Vsd and −1.0 Vg.</p>
Full article ">Figure 8
<p>Electrical characterization of OECT samples 7–9 with PUP1S2 electrode applying a source-drain voltage but no gate voltage.</p>
Full article ">Figure 9
<p>Electrical characterization of OECT samples 4–6 with TS1P4 electrode applying a source-drain voltage but no gate voltage.</p>
Full article ">Figure 10
<p>Electrical characterization of OECT samples 1–3 with NWP8 electrode applying a source-drain voltage but no gate voltage.</p>
Full article ">Figure 11
<p>Electrical characterization of OECT samples 7–9 with PUP1S2 electrode applying a constant source-drain voltage (+0.5 V) and an increasing gate voltage (−1.0 V–+1.0 V).</p>
Full article ">Figure 12
<p>Electrical characterization of OECT samples 4–6 with TS1P4 electrode applying a constant source-drain voltage (+0.5 V) and an increasing gate voltage (−1.0 V–+1.0 V).</p>
Full article ">Figure 13
<p>Electrical characterization of OECT samples 1–3 with NWP8 electrode applying a constant source-drain voltage (+0.5 V) and an increasing gate voltage (−1.0 V–+1.0 V).</p>
Full article ">Figure 14
<p>Measurement of change in source-drain current upon application of different analytes onto OECTs with PUP1S2 electrode (OECTs 16–18).</p>
Full article ">Figure 15
<p>Measurement of change in source-drain current upon application of different analytes onto OECTs with TS1P4 electrode (OECTs 13–15).</p>
Full article ">Figure 16
<p>Measurement of change in source-drain current upon application of different analytes onto OECTs with NWP8 electrode (OECTs 10–12).</p>
Full article ">
16 pages, 2845 KiB  
Article
Enhancing Energy Efficiency in Moroccan Construction through Innovative Materials: A Case Study in a Semiarid Climate
by Oumaima Imghoure, Naoual Belouaggadia, Abdelkabir Zaite, Mohammed Ezzine, Rachid Lbibb and Nassim Sebaibi
Buildings 2024, 14(10), 3087; https://doi.org/10.3390/buildings14103087 - 26 Sep 2024
Viewed by 487
Abstract
Rising global energy demand has intensified the need for sustainable building practices and reduced energy consumption in the construction sector. This study investigates the energy-saving potential of integrating innovative materials into building wall structures in semiarid climates. Specifically, we examine the combination of [...] Read more.
Rising global energy demand has intensified the need for sustainable building practices and reduced energy consumption in the construction sector. This study investigates the energy-saving potential of integrating innovative materials into building wall structures in semiarid climates. Specifically, we examine the combination of thermal insulation made from recycled textile waste and phase change materials (PCMs) in exterior walls. Using the dynamic simulation tool TRNSYS, we analyzed heat transfer through the modified wall assembly under semiarid climate conditions typical of Marrakech, Morocco. Our results show that this “bioclimatic” design significantly impacts cooling loads more than heating demands. The modified building achieved a 52% reduction in summer energy usage compared to a conventional reference building. This energy saving translates to a 39% decrease in greenhouse gas emissions. Importantly, this study confirms that this configuration maintains thermal comfort for occupants, with particular effectiveness during the hot summer months when cooling demands are highest. Full article
Show Figures

Figure 1

Figure 1
<p>Sketch of the studied building.</p>
Full article ">Figure 2
<p>Climate data of the Marrakech region for an entire year [<a href="#B35-buildings-14-03087" class="html-bibr">35</a>].</p>
Full article ">Figure 3
<p>TRNSYS system layout diagram.</p>
Full article ">Figure 4
<p>Comparison of our numerical results with those of Gounni et al. [<a href="#B29-buildings-14-03087" class="html-bibr">29</a>].</p>
Full article ">Figure 5
<p>Comparison between our numerical results and experiment data obtained by Mourid et al. [<a href="#B38-buildings-14-03087" class="html-bibr">38</a>].</p>
Full article ">Figure 6
<p>Evolution of ambient temperature and indoor air temperature for the two studied configurations over the course of a full year.</p>
Full article ">Figure 7
<p>Evolution of indoor air temperature during the periods between 15 and 17 December (<b>A</b>) and between 15 and 17 July (<b>B</b>).</p>
Full article ">Figure 8
<p>Heating and cooling needs (<b>a</b>) and energy consumption (<b>b</b>) for the two studied buildings.</p>
Full article ">Figure 9
<p>Monthly evolution of CO<sub>2</sub> emissions from the building for the two configurations.</p>
Full article ">
15 pages, 6449 KiB  
Article
The Application of Wood Biowaste Chemically Modified by Bi2O3 as a Sorbent Material for Wastewater Treatment
by Nena Velinov, Miljana Radović Vučić, Ivan Jerman, Dragana Marković Nikolić, Goran Nikolić, Danijela Bojić and Aleksandar Bojić
Processes 2024, 12(9), 2025; https://doi.org/10.3390/pr12092025 - 20 Sep 2024
Viewed by 909
Abstract
Textile dyes discharged into aquatic systems can have significant environmental impacts, causing water pollution and toxicity to aquatic life, and constituting a human health risk. To manage these effects, the sorption ability of wood biowaste chemically modified by Bi2O3 for [...] Read more.
Textile dyes discharged into aquatic systems can have significant environmental impacts, causing water pollution and toxicity to aquatic life, and constituting a human health risk. To manage these effects, the sorption ability of wood biowaste chemically modified by Bi2O3 for textile dye removal was investigated. Sorbent characterization was performed using scanning electron microscopy, and elemental analysis by energy dispersive X-ray spectroscopy (SEM-EDX), X-ray diffraction (XRD), the Brunauer–Emmett–Teller (BET) method for the specific surface area, and Fourier transform infrared spectroscopy–attenuated total reflectance (FTIR-ATR). The optimization of the sorption process was carried out, and optimal parameters, such as contact time, pH, the dose of sorbent, the concentration of dye, and temperature, were defined. Also, desorption studies were conducted. Kinetics and isotherms studies were carried out, and the data fits to a pseudo-second order model (r2 ≥ 0.99) and Langmuir model (r2 ≥ 0.99), indicating that the process occurs in the monolayer form and the dye sorption depends on the active sites of the sorbent surface. The maximal sorption capacity of the sorbent was 434.75 mg/g. Full article
(This article belongs to the Special Issue Sustainable Adsorbent Materials for Wastewater Treatment)
Show Figures

Figure 1

Figure 1
<p>SEM image of (<b>a</b>) wood biowaste at 5.00 K and W-Bi sorbent at (<b>b</b>) 35.00 K, (<b>c</b>) 35.00 K and (<b>d</b>) 70.00 K.</p>
Full article ">Figure 2
<p>EDX spectrum of (<b>a</b>) wood biowaste and (<b>b</b>) W-Bi sorbent.</p>
Full article ">Figure 3
<p>XRD pattern of (<b>a</b>) wood biowaste and (<b>b</b>) W-Bi sorbent.</p>
Full article ">Figure 4
<p>Adsorption–desorption plot for BET method of (<b>a</b>) wood biowaste and (<b>b</b>) W-Bi sorbent.</p>
Full article ">Figure 5
<p>(<b>a</b>) FTIR−ATR spectrum of wood biowaste and W-Bi sorbent; (<b>b</b>) PZC plot for W-Bi sorbent.</p>
Full article ">Figure 6
<p>Sorption process optimization: (<b>a</b>) effect of contact time; (<b>b</b>) effect of pH; (<b>c</b>) effect of sorbent dose, (<b>d</b>) effect of dye concentration; (<b>e</b>) effect of temperature, and (<b>f</b>) desorption study.</p>
Full article ">Figure 6 Cont.
<p>Sorption process optimization: (<b>a</b>) effect of contact time; (<b>b</b>) effect of pH; (<b>c</b>) effect of sorbent dose, (<b>d</b>) effect of dye concentration; (<b>e</b>) effect of temperature, and (<b>f</b>) desorption study.</p>
Full article ">Figure 7
<p>Sorption kinetic study: (<b>a</b>) pseudo-first order model, and (<b>b</b>) pseudo-second order model.</p>
Full article ">Figure 8
<p>Sorption isotherm study: (<b>a</b>) Langmuir model, and (<b>b</b>) Freundlich model.</p>
Full article ">
16 pages, 4934 KiB  
Article
Modified Cellulose-Based Waste for Enhanced Adsorption of Selected Heavy Metals from Wastewater
by Katarina Trivunac, Snežana Mihajlović, Marija Vukčević, Marina Maletić, Biljana Pejić, Ana Kalijadis and Aleksandra Perić Grujić
Polymers 2024, 16(18), 2610; https://doi.org/10.3390/polym16182610 - 14 Sep 2024
Viewed by 733
Abstract
Due to industrial growth and its impact on the environment, the increasing amount of industrial waste requires a comprehensive approach aligned with the principles of sustainable development. The main goals are not only to preserve natural resources but also to encourage innovation in [...] Read more.
Due to industrial growth and its impact on the environment, the increasing amount of industrial waste requires a comprehensive approach aligned with the principles of sustainable development. The main goals are not only to preserve natural resources but also to encourage innovation in the reuse of waste materials. In an attempt to reduce the problems regarding waste disposal and wastewater treatment in the textile industry, fibrous textile waste was used as a starting material to obtain carbon adsorbents for the removal of pollutants from wastewater. Waste cotton and mixed yarns, mainly consisting of polysaccharide cellulose, were hydrothermally carbonized and activated with KOH to convert them into efficient carbon adsorbents for heavy metal removal from water. Characterization of carbonized material showed that after activation, an increase in specific surface area (up to 872 m2/g) and content of surface oxygen groups (6.04 mmol/g) leads to a higher affinity towards heavy metal ions, especially lead ions, and high adsorption capacity of 19.98 mg/g obtained for activated cotton yarns. The results of this research represent a contribution to the reduction of waste materials by modifying them into adsorbents, while the regeneration of adsorbents is an example of the practical application of polysaccharide-based materials in the purification of wastewater containing various heavy metal ions. Full article
(This article belongs to the Special Issue Polysaccharide-Based Materials: Developments and Properties)
Show Figures

Figure 1

Figure 1
<p>SEM photographs of samples: (<b>a</b>) C<sub>HTC</sub>, (<b>b</b>) C<sub>aHTC</sub>, (<b>c</b>) C/P<sub>HTC</sub>, and (<b>d</b>) C/P<sub>aHTC</sub>.</p>
Full article ">Figure 2
<p>XRD spectra of hydrothermally treated and activated cotton and cotton/polyester yarn.</p>
Full article ">Figure 3
<p>Adsorption–desorption isotherm of N<sub>2</sub> on different adsorbents.</p>
Full article ">Figure 4
<p>FTIR spectra of untreated cotton and mixed cotton/polyester yarns, and hydrothermally carbonized and activated samples.</p>
Full article ">Figure 5
<p>The influence of contact time on adsorption of (<b>a</b>) Pb and (<b>b</b>) Cd onto hydrothermally carbonized and activated cotton and mixed cotton/polyester.</p>
Full article ">Figure 6
<p>The influence of initial adsorbate concentration on adsorption of (<b>a</b>) Pb and (<b>b</b>) Cd onto hydrothermally carbonized and activated cotton and mixed cotton/polyester yarns.</p>
Full article ">Figure 7
<p>Scheme of lead ions desorption (<b>a</b>) and adsorption and desorption efficiency (%) of the C<sub>aHTC</sub> sample (<b>b</b>).</p>
Full article ">
16 pages, 2479 KiB  
Article
Recycled Jute Non-Woven Material Coated with Polyaniline/TiO2 Nanocomposite for Removal of Heavy Metal Ions from Water
by Aleksandar Kovačević, Marija Radoičić, Darka Marković, Zoran Šaponjić and Maja Radetić
Molecules 2024, 29(18), 4366; https://doi.org/10.3390/molecules29184366 - 14 Sep 2024
Viewed by 802
Abstract
Growing volumes of textile waste and heavy metal pollution of water are emerging environmental challenges. In an attempt to tackle these issues, a non-woven sorbent based on jute fibers was fabricated by recycling the textile waste from the carpet industry. The influence of [...] Read more.
Growing volumes of textile waste and heavy metal pollution of water are emerging environmental challenges. In an attempt to tackle these issues, a non-woven sorbent based on jute fibers was fabricated by recycling the textile waste from the carpet industry. The influence of contact time, concentration, pH and temperature on the sorption of lead and copper ions from aqueous solutions was studied. In order to enhance the sorption capacity of the non-woven material, in situ synthesis of polyaniline (PANI) in the presence of TiO2 nanostructures was performed. The contribution of TiO2 nanoparticles and TiO2 nanotubes to the uniformity of PANI coating and overall sorption behavior was compared. Electrokinetic measurements indicated increased swelling of modified fibers. FTIR and Raman spectroscopy revealed the formation of the emeraldine base form of PANI. FESEM confirmed the creation of the uniform nanocomposite coating over jute fibers. The modification with PANI/TiO2 nanocomposite resulted in a more than 3-fold greater sorption capacity of the material for lead ions, and a 2-fold greater absorption capacity for copper ions independently of applied TiO2 nanostructure. The participation of both TiO2 nanostructures in PANI synthesis resulted in excellent cover of jute fibers, but the form of TiO2 had a negligible effect on metal ion uptake. Full article
(This article belongs to the Special Issue Polymer Composites: Chemical Synthesis and Applications)
Show Figures

Figure 1

Figure 1
<p>Scheme of NWS fabrication, coating with the PANI/TiO<sub>2</sub> nanocomposite and proposed sorption mechanism.</p>
Full article ">Figure 2
<p>Chemistry, morphology and electrokinetic properties of control and modified NWSs: FTIR spectra of NWS, NWS_TP_NP, and NWS_TP_NT (<b>a</b>), Raman spectra of NWS, NWS_TP_NP, and NWS_TP_NT (<b>b</b>), FESEM micrographs of NWS (<b>c</b>,<b>d</b>), NWS_TP_NP (<b>e</b>,<b>f</b>), and NWS_TP_NT (<b>g</b>,<b>h</b>) under different magnifications (×10,000 and ×50,000), electrokinetic properties of NWS, NWS_TP_NP and NWS_TP_NT (<b>i</b>).</p>
Full article ">Figure 3
<p>Adsorption kinetics of (<b>a</b>) Pb<sup>2+</sup> ions, (<b>b</b>) Cu<sup>2+</sup> ions (C<sub>0</sub> = 500 mg/L, 20 °C, pH 5.0), and pseudo-second-order plots for the sorption of (<b>c</b>) Pb<sup>2+</sup> ions and (<b>d</b>) Cu<sup>2+</sup> ions by NWS, NWS_TP_NP, and NWS_TP_NT.</p>
Full article ">Figure 4
<p>The influence of the initial concentration of metal ions on the sorption capacity of NWS, NWS_TP_NP, and NWS_TP_NT: (<b>a</b>) Pb<sup>2+</sup> ions and (<b>b</b>) Cu<sup>2+</sup> ions (pH 5.0, 20 °C, 24 h).</p>
Full article ">Figure 5
<p>The influence of pH on the sorption of (<b>a</b>) Pb<sup>2+</sup> ions and (<b>b</b>) Cu<sup>2+</sup> ions (<span class="html-italic">C</span><sub>0</sub> = 500 mg/L, 20 °C, 24 h) and influence of temperature on the sorption of (<b>c</b>) Pb<sup>2+</sup> ions and (<b>d</b>) Cu<sup>2+</sup> ions (<span class="html-italic">C</span><sub>0</sub> = 500 mg/L, pH 5.0, 60 min) by NWS, NWS_TP_NP, and NWS_TP_NT.</p>
Full article ">Figure 6
<p>Reusability of NWS, NWS_TP_NP, and NWS_TP_NT for the sorption of (<b>a</b>) Pb<sup>2+</sup> ions and (<b>b</b>) Cu<sup>2+</sup> ions (<span class="html-italic">C</span><sub>0</sub> = 500 mg/L, 20 °C, pH 5.0, 24 h).</p>
Full article ">
26 pages, 6368 KiB  
Review
Review of Fiber-Reinforced Composite Structures with Multifunctional Capabilities through Smart Textiles
by Birendra Chaudhary, Thomas Winnard, Bolaji Oladipo, Sumanta Das and Helio Matos
Textiles 2024, 4(3), 391-416; https://doi.org/10.3390/textiles4030023 - 12 Sep 2024
Viewed by 837
Abstract
Multifunctional composites and smart textiles are an important advancement in material science, offering a variety of capabilities that extend well beyond traditional structural functions. These advanced materials are poised to revolutionize applications across a wide range of industries, including aerospace, healthcare, military, and [...] Read more.
Multifunctional composites and smart textiles are an important advancement in material science, offering a variety of capabilities that extend well beyond traditional structural functions. These advanced materials are poised to revolutionize applications across a wide range of industries, including aerospace, healthcare, military, and consumer electronics, by embedding functionalities such as structural health monitoring, signal transmission, power transfer, self-healing, and environmental sensing. This review, which draws on insights from various disciplines, including material science, engineering, and technology, explores the manufacturing techniques employed in creating multifunctional composites, focusing on modifying textiles to incorporate conductive fibers, sensors, and functional coatings. The various multifunctional capabilities that result from these modifications and manufacturing techniques are examined in detail, including structural health monitoring, power conduction, power transfer, wireless communication, power storage, energy harvesting, and data transfer. The outlook and potential for future developments are also surveyed, emphasizing the need for improved durability, scalability, and energy efficiency. Key challenges are identified, such as ensuring material compatibility, optimizing fabrication techniques, achieving reliable performance under diverse conditions, and modeling multifunctional systems. By addressing these challenges through ongoing research and further innovation, we can significantly enhance the performance and utility of systems, driving advancements in technology and improving quality of life. Full article
Show Figures

Figure 1

Figure 1
<p>(<b>a</b>) Global industry trends for multifunctional composites [<a href="#B12-textiles-04-00023" class="html-bibr">12</a>] and (<b>b</b>) recent journal articles for multifunctional composites (data collected from Scopus).</p>
Full article ">Figure 2
<p>Schematic illustration of reinforced composite systems.</p>
Full article ">Figure 3
<p>Smart textiles utilizing different configurations and techniques to achieve multifunctionality.</p>
Full article ">Figure 4
<p>Traditional composites manufacturing processes showing (<b>a</b>) hand lay-up, (<b>b</b>) resign transfer molding, (<b>c</b>) vacuum-assisted resin transfer molding, and (<b>d</b>) prepreg lay-up.</p>
Full article ">Figure 5
<p>Additive manufacturing methods.</p>
Full article ">Figure 6
<p>Spinning techniques. (<b>a</b>) Electrospinning and (<b>b</b>) solution blow technique.</p>
Full article ">Figure 7
<p>Multilevel use case of multifunctional structures and their capabilities for health monitoring, reproduced with permission from [<a href="#B64-textiles-04-00023" class="html-bibr">64</a>].</p>
Full article ">Figure 8
<p>Multifunctional composite system with embedded conductive yarns for shock load monitoring and damage detection.</p>
Full article ">Figure 9
<p>Power conduction and high-current transmission capabilities of multifunctional carbon/epoxy composites. Note: The arrow represents the transition either to manufacturing procedures or corresponding performance.</p>
Full article ">Figure 10
<p>A schematic representation of power transfer and wireless communication utilizing multifunctional composites and smart textiles.</p>
Full article ">Figure 11
<p>A schematic representation of a multifunctional structure capable of energy harvesting using thermoelectric, piezoelectric, photovoltaic, and energy storage elements.</p>
Full article ">Figure 12
<p>Schematic illustration of the structure and working principle of the triboelectric generator (<b>a</b>) with the structure of an integrated generator in bending and releasing process and (<b>b</b>) proposed mechanism of the triboelectric generator, reproduced with permission from [<a href="#B78-textiles-04-00023" class="html-bibr">78</a>].</p>
Full article ">Figure 13
<p>Recent work on smart textiles showcasing the electromechanical performance of textile fabrics with conductive yarn elements for data transfer capabilities [<a href="#B14-textiles-04-00023" class="html-bibr">14</a>].</p>
Full article ">Figure 14
<p>Nano- and microscales in a progressive modeling framework of woven composites, reproduced with permission from [<a href="#B101-textiles-04-00023" class="html-bibr">101</a>].</p>
Full article ">Figure 15
<p>A multiscale optimization scheme using neural networks, reproduced with permission from [<a href="#B104-textiles-04-00023" class="html-bibr">104</a>].</p>
Full article ">
22 pages, 13362 KiB  
Article
Bio-Innovative Modification of Poly(Ethylene Terephthalate) Fabric Using Enzymes and Chitosan
by Ivana Čorak, Anita Tarbuk, Sandra Flinčec Grgac and Tihana Dekanić
Polymers 2024, 16(17), 2532; https://doi.org/10.3390/polym16172532 - 7 Sep 2024
Viewed by 787
Abstract
This article investigates the activation of surface groups of poly(ethylene terephthalate) (PET) fibers in woven fabric by hydrolysis and their functionalization with chitosan. Two types of hydrolysis were performed—alkaline and enzymatic. The alkaline hydrolysis was performed in a more sustainable process at reduced [...] Read more.
This article investigates the activation of surface groups of poly(ethylene terephthalate) (PET) fibers in woven fabric by hydrolysis and their functionalization with chitosan. Two types of hydrolysis were performed—alkaline and enzymatic. The alkaline hydrolysis was performed in a more sustainable process at reduced temperature and time (80 °C, 10 min) with the addition of the cationic surfactant hexadecyltrimethylammonium chloride as an accelerator. The enzymatic hydrolysis was performed using Amano Lipase A from Aspergillus niger (2 g/L enzyme, 60 °C, 60 min, pH 9). The surface of the PET fabric was functionalized with the homogenized gel of biopolymer chitosan using a pad–dry–cure process. The durability of functionalization was tested after the first and tenth washing cycle of a modified industrial washing process according to ISO 15797:2017, in which the temperature was lowered from 75 °C to 50 °C, and ε-(phthalimido) peroxyhexanoic acid (PAP) was used as an environmentally friendly agent for chemical bleaching and disinfection. The influence of the above treatments was analyzed by weight loss, tensile properties, horizontal wicking, the FTIR-ATR technique, zeta potential measurement and SEM micrographs. The results indicate better hydrophilicity and effectiveness of both types of hydrolysis, but enzymatic hydrolysis is more environmentally friendly and favorable. In addition, alkaline hydrolysis led to a 20% reduction in tensile properties, while the action of the enzyme resulted in a change of only 2%. The presence of chitosan on polyester fibers after repeated washing was confirmed on both fabrics by zeta potential and SEM micrographs. However, functionalization with chitosan on the enzymatically bioactivated surface showed better durability after 10 washing cycles than the alkaline-hydrolyzed one. The antibacterial activity of such a bio-innovative modified PET fabric is kept after the first and tenth washing cycles. In addition, applied processes can be easily introduced to any textile factory. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
Show Figures

Figure 1

Figure 1
<p>Protonation of chitosan amino groups in acidic medium.</p>
Full article ">Figure 2
<p>ε-(phthalimido) peroxyhexanoic acid (PAP).</p>
Full article ">Figure 3
<p>The process line diagram.</p>
Full article ">Figure 4
<p>Tensile index (TI) of PET fabrics before and after hydrolysis, chitosan functionalization and 1 and 10 washing cycles.</p>
Full article ">Figure 5
<p>Wicking rate (W) of PET fabrics before and after hydrolysis, chitosan functionalization and 1 and 10 washing cycles.</p>
Full article ">Figure 6
<p>FTIR analysis of untreated polyester fabric (PET) and chitosan powder (Ch) used for this research.</p>
Full article ">Figure 7
<p>FTIR analysis of untreated polyester fabric (PET) before (<b>a</b>) and after chitosan functionalization (PET_Ch) (<b>b</b>) and after the 1st (PET_1W, PET_Ch_1W) and 10th (PET_10W, PET_Ch_10W) washing cycle.</p>
Full article ">Figure 8
<p>FTIR analysis of alkali-hydrolyzed polyester fabric (PET_H) before (<b>a</b>) and after chitosan functionalization (PET_H_Ch) (<b>b</b>) and after the 1st (PET_H_1W, PET_H_Ch_1W) and 10th (PET_H_10W, PET_H_Ch_10W) washing cycle.</p>
Full article ">Figure 9
<p>FTIR analysis of enzyme-hydrolyzed polyester fabric (PET_ALA) before (<b>a</b>) and after chitosan functionalization (PET_ALA_Ch) (<b>b</b>) and after the 1st (PET_ALA_1W, PET_ALA_Ch_1W) and 10th (PET_ALA_10W, PET_ALA_Ch_10W) washing cycle.</p>
Full article ">Figure 10
<p>Zeta potential of non-hydrolyzed PET samples.</p>
Full article ">Figure 11
<p>Zeta potential of alkaline-hydrolyzed PET samples.</p>
Full article ">Figure 12
<p>Zeta potential of enzymatically hydrolyzed PET samples.</p>
Full article ">Figure 13
<p>SEM micrographs of unhydrolyzed and hydrolyzed PET fibers in fabrics at a magnification of 2000×, after the modification and 10 washing cycles.</p>
Full article ">Figure 14
<p>SEM micrographs of chitosan-functionalized PET fabrics at a magnification of 2000×, after the 1st and 10th washing cycle.</p>
Full article ">
14 pages, 2577 KiB  
Article
A Deep Learning Approach to Distance Map Generation Applied to Automatic Fiber Diameter Computation from Digital Micrographs
by Alain M. Alejo Huarachi and César A. Beltrán Castañón
Sensors 2024, 24(17), 5497; https://doi.org/10.3390/s24175497 - 24 Aug 2024
Viewed by 589
Abstract
Precise measurement of fiber diameter in animal and synthetic textiles is crucial for quality assessment and pricing; however, traditional methods often struggle with accuracy, particularly when fibers are densely packed or overlapping. Current computer vision techniques, while useful, have limitations in addressing these [...] Read more.
Precise measurement of fiber diameter in animal and synthetic textiles is crucial for quality assessment and pricing; however, traditional methods often struggle with accuracy, particularly when fibers are densely packed or overlapping. Current computer vision techniques, while useful, have limitations in addressing these challenges. This paper introduces a novel deep-learning-based method to automatically generate distance maps of fiber micrographs, enabling more accurate fiber segmentation and diameter calculation. Our approach utilizes a modified U-Net architecture, trained on both real and simulated micrographs, to regress distance maps. This allows for the effective separation of individual fibers, even in complex scenarios. The model achieves a mean absolute error (MAE) of 0.1094 and a mean square error (MSE) of 0.0711, demonstrating its effectiveness in accurately measuring fiber diameters. This research highlights the potential of deep learning to revolutionize fiber analysis in the textile industry, offering a more precise and automated solution for quality control and pricing. Full article
(This article belongs to the Section Sensing and Imaging)
Show Figures

Figure 1

Figure 1
<p>Illustration of a deep neural network applied to distance map computation (<a href="#sec3dot5-sensors-24-05497" class="html-sec">Section 3.5</a>).</p>
Full article ">Figure 2
<p>Schematic diagram of the overall network architecture.</p>
Full article ">Figure 3
<p>Illustration of U-Net architecture.</p>
Full article ">Figure 4
<p>Illustration of SkeletonNet architecture.</p>
Full article ">Figure 5
<p>Distance map label steps creation: Left: source synthetic micrograph; middle: binary image from source; right: distance map obtained from binary image with Euclidean distance transform algorithm (Equation (<a href="#FD5-sensors-24-05497" class="html-disp-formula">5</a>)).</p>
Full article ">Figure 6
<p>Samples of real OFDA fiber micrographs.</p>
Full article ">Figure 7
<p>Simulation of fiber micrograph by geometric model: a representation of the <math display="inline"><semantics> <mi>μ</mi> </semantics></math>-randomness method with sinusoid (<b>left</b>); the result with one fiber (<b>middle</b>); a synthetic micrograph sample with four fibers (<b>right</b>).</p>
Full article ">Figure 8
<p>Samples of synthetic micrographs with random features (number of fibers, thicknesses, curvatures, colors, and noise).</p>
Full article ">Figure 9
<p>Proposed experimental protocol: In the training stage, the real and synthetic micrographs for training are augmented and fused. In the testing stage, the real and synthetic micrographs are used.</p>
Full article ">Figure 10
<p>Samples of distance map results of the U-Net Regression using different loss functions on the real image testing subset.</p>
Full article ">Figure 11
<p>Samples of distance map results of the SkeletonNet Regression using different loss functions on the real image testing subset.</p>
Full article ">Figure 12
<p>Samples of distance map results of the U-Net Regression using different loss functions on the synthetic testing subset.</p>
Full article ">Figure 13
<p>Samples of distance map results of the SkeletonNet Regression using different loss functions on the synthetic testing subset.</p>
Full article ">
24 pages, 9193 KiB  
Article
Exploring Sustainable Approaches for Electronic Textile Products and Prototypes
by Nishadi Perera, Arash M. Shahidi, Kalana Marasinghe, Jake Kaner, Carlos Oliveira, Rachael Wickenden, Tilak Dias and Theo Hughes-Riley
Sensors 2024, 24(17), 5472; https://doi.org/10.3390/s24175472 - 23 Aug 2024
Viewed by 626
Abstract
This research investigated the sustainability of textile garments with integrated electronics and their potential impact on the environment. The electronic textiles (E-textiles) sector is booming, with many advancements in E-textile product designs and construction methods having been made in recent years. Although there [...] Read more.
This research investigated the sustainability of textile garments with integrated electronics and their potential impact on the environment. The electronic textiles (E-textiles) sector is booming, with many advancements in E-textile product designs and construction methods having been made in recent years. Although there is a rapidly increasing interest in the reusability and sustainability of textiles, work towards E-textile sustainability requires further attention. Vastly different components are combined when constructing an electronic textile product, which makes it challenging at the end of the life of these products to dispose of them in a responsible way. In this study, a teardown analysis was conducted using a structured method, which first mapped out the interactions between each component of the product with the environment, followed by using Kuusk’s sustainable framework to analyze sustainable strategies. The research provides a unique contribution to transitioning sustainability theories into practical applications in the area of E-textiles, and the method proposed in this work can be employed in modifying electronics-embedded textiles to improve longevity and reduce the negative environmental impact. The work has highlighted key points of improvement that could be applied to a series of commercial E-textile garments, as well as a prototype E-textile device. Beyond this, the work provides a systematic approach for implementing new E-textile product designs that can evaluate overall product sustainability from the design stage to material selection, construction, and the planning of the commercial approaches of a product. Full article
Show Figures

Figure 1

Figure 1
<p>Commercial E-textile garments that were used for the tear-down analysis. (<b>a</b>) Heated scarf. (<b>b</b>) Light-up cap. (<b>c</b>) Heart rate monitoring band.</p>
Full article ">Figure 2
<p>Temperature sensing sock prototype. (<b>a</b>) Schematic of the base of the sock showing the locations of the temperature sensing E-yarns and supporting hardware module. (<b>b</b>) Schematic showing the wiring of the embedded thermistor and resistor inside of the E-yarns. (<b>c</b>) Microscope image of a temperature sensing E-yarn. This image has been stitched together from two images.</p>
Full article ">Figure 3
<p>Heated scarf. (<b>a</b>) Product prior to the teardown. (<b>b</b>) Product following disassembly. (<b>c</b>) Detailed photograph of the wiring connection. (<b>d</b>) Detailed image of the conductive heating element.</p>
Full article ">Figure 4
<p>Kuusk’s eight sustainability qualities applied to the heated scarf.</p>
Full article ">Figure 5
<p>Photograph of the packaging of the light-up cap. (<b>a</b>) Front of packaging. (<b>b</b>) Rear of packaging. Note the inclusion of the WEEE symbol on the back of the packing.</p>
Full article ">Figure 6
<p>Light-up cap. (<b>a</b>) Product prior to teardown. (<b>b</b>) Product following disassembly. (<b>c</b>) Detailed photograph of the supporting electronics and power supply.</p>
Full article ">Figure 7
<p>Kuusk’s eight sustainability qualities applied to the LED light-up cap.</p>
Full article ">Figure 8
<p>Packaging for the heart rate monitoring chest strap. (<b>a</b>) Front of packaging. (<b>b</b>) Rear of packaging. The WEEE symbol is clearly shown.</p>
Full article ">Figure 9
<p>Heart rate monitoring strap. (<b>a</b>) Product prior to teardown. (<b>b</b>) Product following disassembly. (<b>c</b>) Detailed photograph of snap fastening connectors. (<b>d</b>) Photograph showing the disassembled supporting hardware module.</p>
Full article ">Figure 10
<p>Kuusk’s eight sustainability qualities applied to the heart rate monitoring band.</p>
Full article ">Figure 11
<p>Temperature sensing sock prototype created using electronic yarn technology. (<b>a</b>) Side view. (<b>b</b>) Bottom view showing the knitted channels into which the E-yarns are inserted.</p>
Full article ">Figure 12
<p>Temperature sensing sock prototype. (<b>a</b>) Image showing the connector to the supporting hardware module. (<b>b</b>,<b>c</b>) Images of the embedded electronic components. (<b>d</b>) Image of the supporting hardware module.</p>
Full article ">Figure 13
<p>Kuusk’s eight sustainability qualities applied to the temperature sensing sock prototype.</p>
Full article ">Figure 14
<p>New temperature sensing sock prototype hardware module. (<b>a</b>) Three-dimensional render of the casing. (<b>b</b>) Complete module.</p>
Full article ">
35 pages, 18128 KiB  
Article
Straightforward Production Methods for Diverse Porous PEDOT:PSS Structures and Their Characterization
by Rike Brendgen, Thomas Grethe and Anne Schwarz-Pfeiffer
Sensors 2024, 24(15), 4919; https://doi.org/10.3390/s24154919 - 29 Jul 2024
Cited by 1 | Viewed by 657
Abstract
Porous conductive polymer structures, in particular Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) structures, are gaining in importance due to their versatile fields of application as sensors, hydrogels, or supercapacitors, to name just a few. Moreover, (porous) conducting polymers have become of interest for wearable and [...] Read more.
Porous conductive polymer structures, in particular Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) structures, are gaining in importance due to their versatile fields of application as sensors, hydrogels, or supercapacitors, to name just a few. Moreover, (porous) conducting polymers have become of interest for wearable and smart textile applications due to their biocompatibility, which enables applications with direct skin contact. Therefore, there is a huge need to investigate distinct, straightforward, and textile-compatible production methods for the fabrication of porous PEDOT:PSS structures. Here, we present novel and uncomplicated approaches to producing diverse porous PEDOT:PSS structures and characterize them thoroughly in terms of porosity, electrical resistance, and their overall appearance. Production methods comprise the incorporation of micro cellulose, the usage of a blowing agent, creating a sponge-like structure, and spraying onto a porous base substrate. This results in the fabrication of various porous structures, ranging from thin and slightly porous to thick and highly porous. Depending on the application, these structures can be modified and integrated into electronic components or wearables to serve as porous electrodes, sensors, or other functional devices. Full article
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Resistance measurement set-up.</p>
Full article ">Figure 2
<p>Bending and touch of PVA/micro cellulose/PEDOT:PSS samples. (<b>A</b>): P20C2; (<b>B</b>): P20C16.</p>
Full article ">Figure 3
<p>SEM images at 200× magnification showing the surface of the PVA/micro cellulose/ PEDOT:PSS networks with 20% PEDOT:PSS and different micro cellulose contents. (<b>A</b>): P20C2; (<b>B</b>): P20C4; (<b>C</b>): P20C8; (<b>D</b>): P20C16.</p>
Full article ">Figure 4
<p>Cross-section of P30C0a (<b>A</b>) at 600× magnification with a mean layer thickness of 25.9 µm, P30C4c (<b>B</b>) at 400× magnification with a mean layer thickness of 53.9 µm, and P30C16c (<b>C</b>) with a mean layer thickness of 94.5 µm.</p>
Full article ">Figure 5
<p>EDS mapping of the element sulfur at different PEDOT:PSS but same micro cellulose content in different PVA/micro cellulose/PEDOT:PSS samples. (<b>A</b>): P10C4; (<b>B</b>): P20C4; (<b>C</b>): P30C4.</p>
Full article ">Figure 6
<p>Atomic percentage of the elements found during EDS analysis of PVA/micro cellulose/PEDOT:PSS networks.</p>
Full article ">Figure 7
<p>Resistance measurement of PVA/micro cellulose/PEDOT:PSS network shows not only a decrease in resistance with increasing PEDOT:PSS content but also due to the addition of micro cellulose up to a certain degree and the saturation of the samples. (<b>A</b>): Overview of all samples; (<b>B</b>): Influence of PEDOT:PSS content; (<b>C</b>): Samples with 10% PEDOT:PSS and different micro cellulose contents; (<b>D</b>): Samples with 20% PEDOT:PSS and different micro cellulose contents; (<b>E</b>): Samples with 30% PEDOT:PSS and different micro cellulose contents.</p>
Full article ">Figure 8
<p>Bending and touch of porous PU/PEDOT:PSS sponges. (<b>A</b>): PUP1S2; (<b>B</b>): PUP1S2.5.</p>
Full article ">Figure 9
<p>SEM images at 100× magnification showing the surface of the porous PU/PEDOT:PSS sponges produced with different amounts of sugar. (<b>A</b>): PUP1S1; (<b>B</b>): PUP1S1.5; (<b>C</b>): PUP1S2; (<b>D</b>): PUP1S2.5.</p>
Full article ">Figure 10
<p>Cross-section of PUP1S2a at 50× magnification with a mean layer thickness of 1.3 mm.</p>
Full article ">Figure 11
<p>EDS mapping of the element sulfur in the samples of PU/PEDOT:PSS sponges prepared with different sugar concentrations. (<b>A</b>): PUP1S1; (<b>B</b>): PUP1S2.</p>
Full article ">Figure 12
<p>Atomic percentage of the elements found during EDS analysis of PU/PEDOT:PSS sponges.</p>
Full article ">Figure 13
<p>Mean pore size and pore size distribution of porous PU/PEDOT:PSS sponges produced with different sugar contents.</p>
Full article ">Figure 14
<p>Resistance measurement of porous PU/PEDOT:PSS sponges shows no difference in electrical resistance with different sugar contents and thus resulting pore sizes.</p>
Full article ">Figure 15
<p>Bending and touch of the puffed PEDOT:PSS structure. (<b>A</b>): TS1P1; (<b>B</b>): TS1P4.</p>
Full article ">Figure 16
<p>SEM images at 200× magnification showing the surface of the puffed PEDOT:PSS structure at different PEDOT:PSS contents. (<b>A</b>): 0% PEDOT:PSS—TS1P0; (<b>B</b>): 100% PEDOT:PSS—TS1P1; (<b>C</b>): 150% PEDOT:PSS—TS1P1.5; (<b>D</b>): 200% PEDOT:PSS—TS1P2; (<b>E</b>): 300% PEDOT:PSS—TS1P3; (<b>F</b>): 400% PEDOT:PSS—TS1P4.</p>
Full article ">Figure 17
<p>Cross-section of TS1P4b at 100× magnification with a mean layer thickness of 301.5 µm.</p>
Full article ">Figure 18
<p>EDS mapping of the element sulfur at different PEDOT:PSS concentrations in the puffed PEDOT:PSS structures. (<b>A</b>): TS1P0; (<b>B</b>): TS1P2; (<b>C</b>): TS1P4.</p>
Full article ">Figure 19
<p>Atomic percentage of the elements found during EDS analysis of porous puffed PEDOT:PSS samples.</p>
Full article ">Figure 20
<p>Mean pore size and pore size distribution of puffed PEDOT:PSS structures with different PEDOT:PSS contents.</p>
Full article ">Figure 21
<p>Resistance measurement of puffed PEDOT:PSS structure showing a decrease in resistance with increasing amount of PEDOT:PSS.</p>
Full article ">Figure 22
<p>Bending and touch of starch based puffed PEDOT:PSS structures.</p>
Full article ">Figure 23
<p>SEM examination (100×) of puffed PEDOT:PSS samples produced with starch based puffy paint. (<b>A</b>): F1P1.5BS1—top view; (<b>B</b>): F1P1.5BS3—top view; (<b>C</b>): F1P1.5BS1—cross-sectional view; (<b>D</b>): F1P1.5B3—cross-sectional view.</p>
Full article ">Figure 24
<p>Cross-section of F1P1.5BS1a at 25× magnification with a mean layer thickness of 1.94 mm (<b>A</b>) and F1P1.5BS2a at 25× magnification with a mean layer thickness of 2.85 mm (<b>B</b>).</p>
Full article ">Figure 25
<p>EDS mapping of the element sulfur at different baking soda concentrations in the starch-based puffed PEDOT:PSS structures. (<b>A</b>): F1P1.5BS1; (<b>B</b>): F1P1.5BS2; (<b>C</b>): F1P1.5BS3.</p>
Full article ">Figure 26
<p>Atomic percentage of the elements found during EDS analysis of porous starch-based puffed PEDOT:PSS samples.</p>
Full article ">Figure 27
<p>Mean pore size and pore size distribution of starch-based puffed PEDOT:PSS samples with different amounts of baking soda.</p>
Full article ">Figure 28
<p>Electrical resistance measurement of starch-based puffed PEDOT:PSS samples show no significant change in electrical resistance in dependence on baking soda content.</p>
Full article ">Figure 29
<p>Bending and touch of PEDOT:PSS sprayed non-wovens. (<b>A</b>): NWP2; (<b>B</b>): NWP16.</p>
Full article ">Figure 30
<p>SEM images at 100x magnification of the PEDOT:PSS sprayed non-wovens with different layers of PEDOT:PSS. (<b>A</b>): NWP0, 0 layers; (<b>B</b>): NWP2, 2 layers; (<b>C</b>): NWP4, 4 layers; (<b>D</b>): NWP8, 8 layers; (<b>E</b>): NWP16, 16 layers.</p>
Full article ">Figure 31
<p>Cross-section of NWP8a at 200× magnification with a mean layer thickness of 97.1 µm.</p>
Full article ">Figure 32
<p>EDS mapping of the element sulfur in PEDOT:PSS sprayed non-woven samples with an increasing number of spraying cycles. (<b>A</b>): NWP0; (<b>B</b>): NWP4; (<b>C</b>): NWP16.</p>
Full article ">Figure 33
<p>Atomic percentage of the elements found during EDS analysis of PEDOT:PSS-sprayed non-woven samples.</p>
Full article ">Figure 34
<p>Mean pore size and pore size distribution of PEDOT:PSS-sprayed non-wovens produced by different spraying cycles.</p>
Full article ">Figure 35
<p>Resistance measurement of PEDOT:PSS sprayed non-wovens shows that resistance decreases with the number of sprayed layers.</p>
Full article ">
25 pages, 3446 KiB  
Review
Recent Advancements in Acrylic Fabric Applications: A Comprehensive Review and Future Trends
by Raphael Palucci Rosa, Giuseppe Rosace and Valentina Trovato
Polymers 2024, 16(15), 2111; https://doi.org/10.3390/polym16152111 - 24 Jul 2024
Viewed by 770
Abstract
Acrylic fibres, as synthetic polymers, have been used extensively in the textile industry to create a wide variety of products, ranging from apparel and home furnishings to car rooftops and carbon fibres. Their widespread application is attributed to a combination of desirable properties, [...] Read more.
Acrylic fibres, as synthetic polymers, have been used extensively in the textile industry to create a wide variety of products, ranging from apparel and home furnishings to car rooftops and carbon fibres. Their widespread application is attributed to a combination of desirable properties, including a soft, wool-like texture, chemical stability, and robust mechanical characteristics. Furthermore, the chemical structure of acrylic fibres can be modified to imbue them with additional features, such as antimicrobial properties, fire resistance, conductivity, water repellency, and ultraviolet protection. This review explores the technological methods employed to functionalise acrylic fibres and discusses future trends in their development. Full article
(This article belongs to the Section Polymer Applications)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Global fibre production in 2022. Total acrylic fibres production is in bold. Data adapted from Textile Exchange [<a href="#B1-polymers-16-02111" class="html-bibr">1</a>].</p>
Full article ">Figure 2
<p>Acrylic fibre structure.</p>
Full article ">Figure 3
<p>Possible formation mechanism of O-AP-PAN fibres. Reproduced under the terms of the Creative Commons CC BY-NC-ND 4.0 license. Copyright 2023, the Authors [<a href="#B91-polymers-16-02111" class="html-bibr">91</a>]. Published by Elsevier.</p>
Full article ">Figure 4
<p>Combustion processes of T_260, ET_260, PT_260, EPT_260, and ZOLTEK OX during the UL 94 vertical burning test at different times. Reproduced under the terms of the Creative Commons CC BY-NC-ND 4.0 license. Copyright 2019, the Authors [<a href="#B122-polymers-16-02111" class="html-bibr">122</a>]. Published by Elsevier.</p>
Full article ">Figure 5
<p>The digital photographs of the fabrics before and after CC testing. (<b>a1</b>) PAN fabric; (<b>a2</b>) FR-PAN fabric; (<b>b1</b>) PAN fabric after burning; (<b>b2</b>) FR-PAN fabric after burning. Reproduced under the terms of the Creative Commons CC BY 4.0 license. Copyright 2018, the Authors [<a href="#B126-polymers-16-02111" class="html-bibr">126</a>]. Published by MDPI, Basel, Switzerland.</p>
Full article ">Figure 6
<p>UL-94 test photos of PAN (<b>a</b>), L/C/PAN (<b>b</b>), FR-PAN-5 (<b>c</b>), FR-PAN-8 (<b>d</b>), FR-PAN-10 (<b>e</b>), and FR-PAN-12 (<b>f</b>). Reproduced under the terms of the Creative Commons CC BY-NC-ND 4.0 license. Copyright 2023, the Authors [<a href="#B131-polymers-16-02111" class="html-bibr">131</a>]. Published by Elsevier.</p>
Full article ">Figure 7
<p>HRR (<b>a</b>), THR (<b>b</b>), SPR (<b>c</b>), and TSP (<b>d</b>) curves of PAN and FR-PAN fabrics. Reproduced under the terms of the Creative Commons CC BY 4.0 license. Copyright 2019, the Authors [<a href="#B134-polymers-16-02111" class="html-bibr">134</a>]. Published by MDPI, Basel, Switzerland.</p>
Full article ">Figure 8
<p>Stress–strain curves of PANb (solid) and PANb-CCG (dashed) fibres and yarns. Reproduced under the terms of the Creative Commons CC BY-NC-ND 4.0 license. Copyright 2019, the Authors [<a href="#B22-polymers-16-02111" class="html-bibr">22</a>]. Published by Willey.</p>
Full article ">Figure 9
<p>Polyacrylonitrile functionalised with iodine-oxime groups. Reproduced under the terms of the Creative Commons CC BY 4.0 license. Copyright 2021, the Authors [<a href="#B147-polymers-16-02111" class="html-bibr">147</a>]. Published by MDPI, Basel, Switzerland.</p>
Full article ">
22 pages, 7069 KiB  
Article
Hybrid Soft Ballistic Panel Packages with Integrated Graphene-Modified Para-Aramid Fabric Layers in Combinations with the Different Ballistic Kevlar Textiles
by Silvija Kukle, Aleksandrs Valisevskis, Ugis Briedis, Ilze Balgale and Ieva Bake
Polymers 2024, 16(15), 2106; https://doi.org/10.3390/polym16152106 - 24 Jul 2024
Viewed by 659
Abstract
The purpose of the research discussed in this article is to explore the possibility of creating hybrid soft ballistic panel (BP) package variants by integrating into their composition layers of graphene-modified para-aramid fabrics in combinations with the different ballistic Kevlar textiles to improve [...] Read more.
The purpose of the research discussed in this article is to explore the possibility of creating hybrid soft ballistic panel (BP) package variants by integrating into their composition layers of graphene-modified para-aramid fabrics in combinations with the different ballistic Kevlar textiles to improve the durability of the first layers of the soft ballistic panel. To address this goal, the liquid-phase exfoliation (LPE) method was used for integrating dispersions into composites to solve a number of topical problems in the stages of the technological sequence development of processing methods and optimizing processing parameters in accordance with the processing specifics of aramid textiles to achieve the desired properties of modified ballistic fabric, including the provision of coating adhesion to the surface to be modified. To test the results, ballistic experiments were performed and the back-face signature (BFS) of bullet impact on a backing material was analysed according to standards. Bullet impacts on the first ballistic protective fabric layers were also studied. Full article
(This article belongs to the Special Issue High-Performance Functional Polymer Coatings)
Show Figures

Figure 1

Figure 1
<p>Rod-Like Kevlar fibre structure, showing the radial stacking of hydrogen-bonded sheets (<b>left</b>) (Technical Guide for Kevlar<sup>®</sup> Aramid Fiber). Energy absorption efficiency R of Twaron woven ballistic panel (BP) (<b>right</b>) [<a href="#B7-polymers-16-02106" class="html-bibr">7</a>].</p>
Full article ">Figure 2
<p>Technological sequence to obtain graphene-modified Kevlar fabric, <span class="html-fig-inline" id="polymers-16-02106-i001"><img alt="Polymers 16 02106 i001" src="/polymers/polymers-16-02106/article_deploy/html/images/polymers-16-02106-i001.png"/></span>—separated for dispersion, <span class="html-fig-inline" id="polymers-16-02106-i002"><img alt="Polymers 16 02106 i002" src="/polymers/polymers-16-02106/article_deploy/html/images/polymers-16-02106-i002.png"/></span>—separated in sediments.</p>
Full article ">Figure 3
<p>(<b>a</b>) Layers of matrix sensor, (<b>b</b>) matrix sensors before shooting (<b>top</b>) and after shooting (<b>bottom</b>), and (<b>c</b>) knitted sensor.</p>
Full article ">Figure 4
<p>Test range configuration (<b>a</b>); test stand with a test barrel (<b>b</b>–<b>d</b>).</p>
Full article ">Figure 5
<p>SEM micrographs of unmodified KM2 600D fabric.</p>
Full article ">Figure 6
<p>SEM micrographs of modified fabric fibre surfaces to which three coating layers were applied.</p>
Full article ">Figure 7
<p>SEM micrographs of modified fabric fibre surfaces to which five coating layers were applied.</p>
Full article ">Figure 8
<p>Lateral size distribution of graphene flakes obtained from micrographs measured at magnifications of 2000× (<b>left</b>) and 10,000× (<b>right</b>).</p>
Full article ">Figure 9
<p>Colour of pristine fabric (<b>a</b>), graphene functionalized fabric (<b>b</b>) and fabric quantified in CIELAB colour space L*a*b* (<b>c</b>).</p>
Full article ">Figure 10
<p>Quantified lightness difference (ΔL*), chroma (C*) and colour difference (ΔE*) of modified (I–V) and pristine fabric (Kevl-W) samples. (<b>a</b>) DMAc- and (<b>b</b>) Cyrene-based emulsions.</p>
Full article ">Figure 11
<p>First P2 perforated functionalized KM2 600 fabric layer striking face (<b>a</b>) and exit face (<b>b</b>), and matrix pressure sensor with BFS (<b>c</b>). Sensor resistance changes that represent the perceived bullet impact energy behind the ballistic package are shown in (<b>d</b>).</p>
Full article ">Figure 12
<p>Data corresponding to two shots that perforated the reference BP packages.</p>
Full article ">Figure 13
<p>Knitted sensor test results of UD-reference samples (IV-1, IV-2, IV-3: shot numbers).</p>
Full article ">
20 pages, 7012 KiB  
Article
Surface Modification of Silk Fabric by Polysaccharide Derivatives towards High-Quality Printing Performance Using Bio-Based Gardenia Blue Ink
by Yan Liang, Ni Wang, Qing Li and Huiyu Jiang
Materials 2024, 17(14), 3611; https://doi.org/10.3390/ma17143611 - 22 Jul 2024
Viewed by 647
Abstract
Ink-jet-printed silk, a premium textile material, was achieved by utilizing a bio-based gardenia blue dye. However, the sharpness of the printing pattern is difficult to control due to the limited water-retention capacity of silk. To address this issue, three polysaccharide derivatives, namely, sodium [...] Read more.
Ink-jet-printed silk, a premium textile material, was achieved by utilizing a bio-based gardenia blue dye. However, the sharpness of the printing pattern is difficult to control due to the limited water-retention capacity of silk. To address this issue, three polysaccharide derivatives, namely, sodium alginate (SA), low-viscosity hydroxypropyl methyl cellulose (HPMC-I), and high-viscosity hydroxypropyl methyl cellulose (HPMC-II), were employed as thickeners to modify the silk by the dipping–padding method. Firstly, the preparation of the gardenia blue ink and the rheology assessment of the thickener solution were conducted. Furthermore, the impacts of different thickeners on the micro-morphology, element composition, and hydrophilicity of the silk, along with the wetting behavior of the ink on the silk, were analyzed comparatively in order to identify an appropriate thickener for preserving pattern outlines. Lastly, the color features, color fastness, and wearing characteristics of the printed silk were discussed to evaluate the overall printing quality. Research results showed that the optimized ink formulation, comprising 12% gardenia blue, 21% alcohols, and 5.5% surfactant, met the requirements for ink-jet printing (with a viscosity of 4.48 mPa·s, a surface tension of 34.12 mN/m, and a particle size of 153 nm). The HPMC-II solution exhibited prominent shear-thinning behavior, high elasticity, and thixotropy, facilitating the achievement of an even modification effect. The treatment of the silk with HPMC-II resulted in the most notable decrease in hydrophilicity. This can be attributed to the presence of filled gaps and a dense film on the fibers’ surface after the HPMC-II treatment, as observed by scanning electron microscopy. Additionally, X-ray photoelectron spectroscopy analysis confirmed that the HPMC-II treatment introduced the highest content of hydrophobic groups on the fiber surface. The reduced hydrophilicity inhibited the excessive diffusion and penetration of gardenia blue ink, contributing to a distinct printing image and enhanced apparent color depth. Moreover, the printed silk demonstrated qualified color fastness to rubbing and soaping (exceeding grade four), a soft handle feeling, an ignorable strength loss (below 5%), and a favorable air/moisture penetrability. In general, the surface modification with the HPMC-II treatment has been proven as an effective strategy for upgrading the image quality of bio-based dye-printed silk. Full article
Show Figures

Figure 1

Figure 1
<p>(<b>a</b>) Natural <span class="html-italic">Gardenia</span> plant, (<b>b</b>) gardenia blue dyestuff, (<b>c</b>) molecular formula of the dyestuff, (<b>d</b>) polymer formula of sodium alginate, and (<b>e</b>) hydroxypropyl methyl cellulose.</p>
Full article ">Figure 2
<p>Preparation processes of gardenia blue ink.</p>
Full article ">Figure 3
<p>Schematic diagram of the ink-jet printing process.</p>
Full article ">Figure 4
<p>Absorption spectra curve and calibration curve of gardenia blue ink with various concentrations.</p>
Full article ">Figure 5
<p>Steady-shear properties of the thickener aqueous solutions: (<b>a</b>) SA, (<b>b</b>) HPMC-I, and (<b>c</b>) HPMC-II; viscoelasticity of the thickener aqueous solutions: (<b>d</b>) SA, (<b>e</b>) HPMC-I, and (<b>f</b>) HPMC-II; (<b>g</b>) thixotropic properties of the SA, HPMC-I, and HPMC-II aqueous solutions.</p>
Full article ">Figure 6
<p>SEM images of differently treated silk fabrics: (<b>a</b>,<b>b</b>) Fabr.I; (<b>c</b>) thickener-free-treated fabric; (<b>d</b>) Fabr.II; (<b>e</b>) Fabr.III; (<b>f</b>) Fabr.IV.</p>
Full article ">Figure 7
<p>(<b>a</b>) XPS spectra of the differently treated fabrics; XPS spectra of the C1s of the differently treated fabrics: (<b>b</b>) Fabr.I; (<b>c</b>) polymer-free-treated fabric; (<b>d</b>) Fabr.II; (<b>e</b>) Fabr.III; (<b>f</b>) Fabr.IV.</p>
Full article ">Figure 8
<p>Hydrophilicity of differently treated silk fabrics (the error bar means the standard deviation).</p>
Full article ">Figure 9
<p>Shapes of ink droplet spread on differently treated fabrics (<b>a</b>); micrographs of the ink-jet-printed lines on differently treated fabrics in the warp (<b>b</b>) and weft (<b>c</b>) directions; ink-jet-printed patterns (<b>d</b>) and corresponding detailed pictures (<b>e</b>) on differently treated fabrics; the diffusion area and circularity of ink droplets (<b>f</b>); the change rate in the line width in the warp and weft directions (<b>g</b>) (the error bar means the standard deviation).</p>
Full article ">Figure 10
<p>Front color depth and penetration ratio of gardenia blue for differently treated fabrics: (<b>a</b>) printed but not steamed fabrics; (<b>b</b>) steamed but not washed fabrics; (<b>c</b>) steamed and washed fabrics; CIE color coordinates (<b>d</b>); reflectance curves (<b>e</b>); photos of washed and printed Fabr.I, Fabr.II, Fabr.III, and Fabr.IV (<b>f</b>) (the error bars mean the standard deviation).</p>
Full article ">Figure 11
<p>The function of HPMC-II to improve the performance of the ink-jet printing of silk using gardenia blue. (<b>a</b>) Drying process after HPMC-II treatment; (<b>b</b>) Steaming process after ink-jet printing; (<b>c</b>) Dye and fibre binding mechanism.</p>
Full article ">Figure 12
<p>Surface and bending properties of Fabr.I and printed Fabr.IV in the warp (<b>a</b>) and weft (<b>b</b>) directions; mechanical properties (<b>c</b>), and air penetrability and moisture transmittance (<b>d</b>) of Fabr.I and printed Fabr.IV (the error bars mean the standard deviation).</p>
Full article ">
13 pages, 4035 KiB  
Article
Characterization of Melt-Spun Recycled PA 6 Polymer by Adding ZnO Nanoparticles during the Extrusion Process
by Anja Ludaš Dujmić, Rafaela Radičić, Sanja Ercegović Ražić, Ivan Karlo Cingesar, Martinia Glogar, Andrea Jurov and Nikša Krstulović
Polymers 2024, 16(13), 1883; https://doi.org/10.3390/polym16131883 - 1 Jul 2024
Viewed by 920
Abstract
With recent technological advances and the growing interest in environmentally friendly fiber production processes, the textile industry is increasingly turning to the spinning of filaments from recycled raw materials in the melt spinning process as the simplest method of chemical spinning of fibers. [...] Read more.
With recent technological advances and the growing interest in environmentally friendly fiber production processes, the textile industry is increasingly turning to the spinning of filaments from recycled raw materials in the melt spinning process as the simplest method of chemical spinning of fibers. Such processes are more efficient because the desired active particles are melt-spun together with the polymer. The study investigates the melt spinning of recycled polyamide 6 (PA 6) fibers modified with zinc oxide nanoparticles (ZnO NPs) in concentrations ranging from 0.1 to 2.0 wt% of the polymer. The extrusion process was optimized under laboratory conditions. An analysis of the effectiveness of the nanoparticle distribution and chemical composition was performed using scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS), differential scanning calorimetry (DSC), and Fourier transform infrared spectroscopy (FTIR). The results of the thermal analysis show an increase in the glass transition temperature of the extruded material from 50.97 °C (raw polymer) to 51.40 °C to 57.98 °C (polymer modified with ZnO NPs) and an increase in the crystallization point from 148.19 °C to a temperature between 175.61 °C and 178.16 °C, while the molar enthalpy (ΔHm) shows a decreasing trend from 65.66 Jg−1 (raw polymer) to 48.23 Jg−1 (PA 6 2.0% ZnO). The FTIR spectra indicate PA 6 polymer, with a characteristic peak at the wavelength 1466 cm−1, but pure ZnO and PA 6 blended with ZnO show a characteristic peak at 2322 cm−1. The distribution of nanoparticles on the fiber surface is more or less randomly distributed and the different size of NPs is visible. These results are confirmed by the EDS results, which show that different concentrations of Zn are present. The mechanical stability of the extruded polymer modified with NPs is not affected by the addition of ZnO NPs, although the overall results of strength (2.56–3.22 cN/tex) and modulus of elasticity of the polymer (28.83–49.90 cN/tex) are lower as there is no drawing process at this stage of the experiment, which certainly helps to increase the final strength of the fibers. The results indicate the potential of modification with ZnO NPs for further advances in sustainable fiber production. Full article
(This article belongs to the Special Issue Advances in Textile Based Polymer Composites)
Show Figures

Figure 1

Figure 1
<p>Melt-spun filaments of extruded and modified polymer with adding of ZnO nanoparticles (<b>a</b>–<b>f</b>).</p>
Full article ">Figure 2
<p>Molar enthalpy and maximum melting temperature, determined from the second heating cycle.</p>
Full article ">Figure 3
<p>Reflectance curves.</p>
Full article ">Figure 4
<p>Morphological SEM analysis of PA 6 and extruded PA 6 polymers with different concentrations of ZnO nanoparticles: (<b>a</b>,<b>b</b>) sample of PA 6 granulate with magnifications of 800–1600×; (<b>c</b>–<b>h</b>) sample of PA 6 filaments with magnifications up to 8000×.</p>
Full article ">Figure 5
<p>Energy-dispersive X-ray spectroscopy.</p>
Full article ">Figure 6
<p>FTIR spectrum of modified polymers.</p>
Full article ">
Back to TopTop