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17 pages, 4321 KiB  
Article
Theoretical Investigation of Rate Coefficients and Dynamical Mechanisms for N + N + N Three-Body Recombination Based on Full-Dimensional Potential Energy Surfaces
by Chong Xu, Zhenxuan Wei, Huayu Hu, Xixi Hu and Daiqian Xie
Molecules 2024, 29(20), 4933; https://doi.org/10.3390/molecules29204933 (registering DOI) - 18 Oct 2024
Abstract
Three-body recombination reactions, in which two particles form a bound state while a third one bounces off after the collision, play significant roles in many fields, such as cold and ultracold chemistry, astrochemistry, atmospheric physics, and plasma physics. In this work, the dynamics [...] Read more.
Three-body recombination reactions, in which two particles form a bound state while a third one bounces off after the collision, play significant roles in many fields, such as cold and ultracold chemistry, astrochemistry, atmospheric physics, and plasma physics. In this work, the dynamics of the recombination reaction for the N3 system over a wide temperature range (5000–20,000 K) are investigated in detail using the quasi-classical trajectory (QCT) method based on recently developed full-dimensional potential energy surfaces. The recombination products are N2(X) + N(4S) in the 14A″ state, N2(A) + N(4S) in the 24A″ state, and N2(X) + N(2D) in both the 12A″ and 22A″ states. A three-body collision recombination model involving two sets of relative translational energies and collision parameters and a time-delay parameter is adopted in the QCT calculations. The recombination process occurs after forming an intermediate with a certain lifetime, which has a great influence on the recombination probability. Recombination processes occurring through a one-step three-body collision mechanism and two distinct two-step binary collision mechanisms are found in each state. And the two-step exchange mechanism is more dominant than the two-step transfer mechanism at higher temperatures. N2(X) formed in all three related states is always the major recombination product in the temperature range from 5000 K to 20,000 K, with the relative abundance of N2(A) increasing as temperature decreases. After hyperthermal collisions, the formed N2(X/A) molecules are distributed in highly excited rotational and vibrational states, with internal energies mainly distributed near the dissociation threshold. Additionally, the rate coefficients for this three-body recombination reaction in each state are determined and exhibit a negative correlation with temperature. The dynamic insights presented in this work might be very useful to further simulate non-equilibrium dynamic processes in plasma physics involving N3 systems. Full article
(This article belongs to the Special Issue Molecular Dynamics Study on Chemical Reactions)
Show Figures

Figure 1

Figure 1
<p>Potential energy curves as a function of <span class="html-italic">R</span><sub>1</sub> in the N<sub>3</sub> system at the bond angle of 180°. (<b>a</b>) The third N atom is far away. (<b>b</b>) The other N-N distance <span class="html-italic">R</span><sub>2</sub> is equal to 1.293Å which is the equilibrium bond length of N<sub>2</sub>(<span class="html-italic">A</span>). The quartet and doublet states are shown in solid and dashed lines, respectively.</p>
Full article ">Figure 2
<p>Scattering angle profiles in (<b>a</b>) N<sub>2</sub>(<span class="html-italic">X</span>) state and (<b>b</b>) N<sub>2</sub>(<span class="html-italic">A</span>) state for N + N system at specific relative translational energies based on N<sub>3</sub> PESs.</p>
Full article ">Figure 3
<p>The lifetimes of intermediates as a function of impact parameter in (<b>a</b>) the N<sub>2</sub>(<span class="html-italic">X</span>) state and (<b>b</b>) the N<sub>2</sub>(<span class="html-italic">A</span>) state for the N + N system at specific relative translational energies based on the N<sub>3</sub> PESs.</p>
Full article ">Figure 4
<p>A schematic of a three-body interaction in QCT calculations. This image shows the kinematic parameters for the first collision between A and B atoms and the second collision between the COM of the pair AB and the C atom.</p>
Full article ">Figure 5
<p>Typical recombination trajectories for (<b>a</b>) two-step transfer mechanism, (<b>b</b>) two-step exchange mechanism, and (<b>c</b>) one-step three-body direct recombination mechanism in 2<sup>4</sup><span class="html-italic">A</span>″ state of N<sub>3</sub> systems.</p>
Full article ">Figure 6
<p>Ratios of two-step exchange mechanism at different temperatures in each state.</p>
Full article ">Figure 7
<p>Recombination probabilities of the three-body collision for 1<sup>4</sup><span class="html-italic">A</span>″, 2<sup>4</sup><span class="html-italic">A</span>″, 1<sup>2</sup><span class="html-italic">A</span>″, and 2<sup>2</sup><span class="html-italic">A</span>″ states at different temperatures.</p>
Full article ">Figure 8
<p>Recombination probability distribution with impact parameters (<b>a</b>) <span class="html-italic">b</span><sub>1</sub> and (<b>b</b>) <span class="html-italic">b</span><sub>2</sub> for the 2<sup>4</sup><span class="html-italic">A</span>″ state at various temperatures.</p>
Full article ">Figure 9
<p>The distribution of <span class="html-italic">ω</span> for successful recombination of the 2<sup>4</sup><span class="html-italic">A</span>” state at different temperatures.</p>
Full article ">Figure 10
<p>The distributions of (<b>a</b>,<b>c</b>) vibrational states and (<b>b</b>,<b>d</b>) rotational states of N<sub>2</sub>(<span class="html-italic">X</span>) and N<sub>2</sub>(<span class="html-italic">A</span>) products at different temperatures.</p>
Full article ">Figure 11
<p>Rate coefficients of the three-body recombination for 1<sup>4</sup><span class="html-italic">A</span>″, 2<sup>4</sup><span class="html-italic">A</span>″, 1<sup>2</sup><span class="html-italic">A</span>″, and 2<sup>2</sup><span class="html-italic">A</span>″ states at different temperatures. The results of Kondur et al. [<a href="#B18-molecules-29-04933" class="html-bibr">18</a>], multiplied by a weight of 3/16, are also plotted for comparison.</p>
Full article ">
18 pages, 2665 KiB  
Article
The Key Role of Wettability and Boundary Layer in Dissolution Rate Test
by Alice Biasin, Federico Pribac, Erica Franceschinis, Angelo Cortesi, Lucia Grassi, Dario Voinovich, Italo Colombo, Gabriele Grassi, Gesmi Milcovich, Mario Grassi and Michela Abrami
Pharmaceutics 2024, 16(10), 1335; https://doi.org/10.3390/pharmaceutics16101335 (registering DOI) - 18 Oct 2024
Abstract
Background/Objectives: The present work proposes a mathematical model able to describe the dissolution of poly-disperse drug spherical particles in a solution (Dissolution Rate Test—DRT). DRT is a pivotal test performed in the pharmaceutical field to qualitatively assess drug bioavailability. Methods: The proposed mathematical [...] Read more.
Background/Objectives: The present work proposes a mathematical model able to describe the dissolution of poly-disperse drug spherical particles in a solution (Dissolution Rate Test—DRT). DRT is a pivotal test performed in the pharmaceutical field to qualitatively assess drug bioavailability. Methods: The proposed mathematical model relies on the key hallmarks of DRT, such as particle size distribution, solubility, wettability, hydrodynamic conditions in the dissolving liquid of finite dimensions, and possible re-crystallization during the dissolution process. The spherical shape of the drug particles was the only cue simplification applied. Two model drugs were considered to check model robustness: theophylline (both soluble and wettable) and praziquantel (both poorly soluble and wettable). Results: The DRT data analysis within the proposed model allows us to understand that for theophylline, the main resistance to dissolution is due to the boundary layer surrounding drug particles, whereas wettability plays a negligible role. Conversely, the effect of low wettability cannot be neglected for praziquantel. These results are validated by the determination of drug wettability performed while measuring the solid–liquid contact angle on four liquids with decreasing polarities. Moreover, the percentage of drug polarity was determined. Conclusions: The proposed mathematical model confirms the importance of the different physical phenomena leading the dissolution of poly-disperse solid drug particles in a solution. Although a comprehensive mathematical model was proposed and applied, the DRT data of theophylline and praziquantel was successfully fitted by means of just two fitting parameters. Full article
(This article belongs to the Special Issue Mathematical Modeling in Drug Delivery)
Show Figures

Figure 1

Figure 1
<p>Particle size distribution referring to TPH and PRQ (symbols). Continuous lines indicate the best fitting of the cumulative Weibull distribution (Equation (3)), while dotted lines indicate the differential particle size distribution (right vertical axis).</p>
Full article ">Figure 2
<p>Four energetic barriers hinder the dissolution of a solid drug in a solvent: solid wetting (Δ<span class="html-italic">E</span><sub>w</sub>), breakdown (fusion) of solid molecular bonds (Δ<span class="html-italic">E</span><sub>f</sub>), drug molecules’ solvation (Δ<span class="html-italic">E</span><sub>s</sub>), and drug molecules’ diffusion through the boundary layer surrounding the solid particle (Δ<span class="html-italic">E</span><sub>d</sub>). These energies affect, in different manners, the mass transfer coefficient (<span class="html-italic">k</span><sub>m</sub>) at the solid–liquid interface and the dissolution constant <span class="html-italic">k</span><sub>d</sub>. Notably, due to possible solid surface wetting problems, the drug molecule concentration at the solid–liquid interface (<span class="html-italic">C</span>(ξ<sub>min</sub>)) can be lower than drug solubility in the dissolution medium. ξ indicates the radial coordinate while <span class="html-italic">V</span> is the dissolution environment volume. Adapted from [<a href="#B28-pharmaceutics-16-01335" class="html-bibr">28</a>].</p>
Full article ">Figure 3
<p>Temporary evolution of the dimensionless drug profile concentration (red lines, Equation (8)) inside BL (ξ<sup>+</sup> is the dimensionless radial coordinate). <span class="html-italic">C</span><sub>b</sub><sup>+</sup> (=<span class="html-italic">C</span><sub>b</sub>/<span class="html-italic">C</span><sub>s</sub>) is the dimensionless drug concentration inside the dissolution medium (dashed blue lines) being <span class="html-italic">C</span><sub>s</sub> drug solubility (assumed constant in time). Dashed green lines (Equation (8)) indicate the dimensionless drug concentration at the solid/liquid interface (ξ = ξ<sub>min</sub>). Three different ranges for the <span class="html-italic">k</span><sub>m</sub>/<span class="html-italic">k</span><sub>d</sub> ratio were considered: (<b>A</b>) 10 &lt; (<span class="html-italic">k</span><sub>m</sub>/<span class="html-italic">k</span><sub>d</sub>) &lt; 10<sup>2</sup> (no wettability issues. Vertical dashed and dotted lines indicate dimensionless BL thickness δ<sup>+</sup>), (<b>B</b>) 0.2 &lt; (<span class="html-italic">k</span><sub>m</sub>/<span class="html-italic">k</span><sub>d</sub>) &lt; 3 (moderate wettability issues), and (<b>C</b>) 10<sup>−3</sup> &lt; (<span class="html-italic">k</span><sub>m</sub>/<span class="html-italic">k</span><sub>d</sub>) &lt; 10<sup>−2</sup> (considerable wettability issues). All other parameters are equal and read as follows: ρ<sub>s</sub> = 1500 kg/m<sup>3</sup>, ρ<sub>f</sub> = 1000 kg/m<sup>3</sup>, η(Pa s) = 10<sup>−3</sup>, ν<sub>f</sub>(m<sup>2</sup>/s) = 10<sup>−6</sup>, <span class="html-italic">D</span>(m<sup>2</sup>/s) = 10<sup>−10</sup>, <span class="html-italic">C</span><sub>inf</sub>/<span class="html-italic">C</span><sub>s</sub> = 0.625 (<span class="html-italic">C</span><sub>inf</sub> is the drug concentration reached in the dissolution medium upon complete dissolution of the solid drug particles), <span class="html-italic">k</span><sub>r</sub> = 0, α = 1, and <span class="html-italic">g</span> = 9.81 m/s<sup>2</sup>. These values are typical of small organic drugs such as those considered in this work.</p>
Full article ">Figure 3 Cont.
<p>Temporary evolution of the dimensionless drug profile concentration (red lines, Equation (8)) inside BL (ξ<sup>+</sup> is the dimensionless radial coordinate). <span class="html-italic">C</span><sub>b</sub><sup>+</sup> (=<span class="html-italic">C</span><sub>b</sub>/<span class="html-italic">C</span><sub>s</sub>) is the dimensionless drug concentration inside the dissolution medium (dashed blue lines) being <span class="html-italic">C</span><sub>s</sub> drug solubility (assumed constant in time). Dashed green lines (Equation (8)) indicate the dimensionless drug concentration at the solid/liquid interface (ξ = ξ<sub>min</sub>). Three different ranges for the <span class="html-italic">k</span><sub>m</sub>/<span class="html-italic">k</span><sub>d</sub> ratio were considered: (<b>A</b>) 10 &lt; (<span class="html-italic">k</span><sub>m</sub>/<span class="html-italic">k</span><sub>d</sub>) &lt; 10<sup>2</sup> (no wettability issues. Vertical dashed and dotted lines indicate dimensionless BL thickness δ<sup>+</sup>), (<b>B</b>) 0.2 &lt; (<span class="html-italic">k</span><sub>m</sub>/<span class="html-italic">k</span><sub>d</sub>) &lt; 3 (moderate wettability issues), and (<b>C</b>) 10<sup>−3</sup> &lt; (<span class="html-italic">k</span><sub>m</sub>/<span class="html-italic">k</span><sub>d</sub>) &lt; 10<sup>−2</sup> (considerable wettability issues). All other parameters are equal and read as follows: ρ<sub>s</sub> = 1500 kg/m<sup>3</sup>, ρ<sub>f</sub> = 1000 kg/m<sup>3</sup>, η(Pa s) = 10<sup>−3</sup>, ν<sub>f</sub>(m<sup>2</sup>/s) = 10<sup>−6</sup>, <span class="html-italic">D</span>(m<sup>2</sup>/s) = 10<sup>−10</sup>, <span class="html-italic">C</span><sub>inf</sub>/<span class="html-italic">C</span><sub>s</sub> = 0.625 (<span class="html-italic">C</span><sub>inf</sub> is the drug concentration reached in the dissolution medium upon complete dissolution of the solid drug particles), <span class="html-italic">k</span><sub>r</sub> = 0, α = 1, and <span class="html-italic">g</span> = 9.81 m/s<sup>2</sup>. These values are typical of small organic drugs such as those considered in this work.</p>
Full article ">Figure 4
<p>Model’s best fitting (solid line) to experimental DRT data (symbols) referring to TPH (37 °C). Vertical bars indicate data standard error. The physical parameters adopted to perform data fitting read as follows: ρ<sub>s</sub> = 1490 kg/m<sup>3</sup>, ρ<sub>f</sub> = 993 kg/m<sup>3</sup>, η(Pa s) = 6.91 × 10<sup>−3</sup>, ν<sub>f</sub>(m<sup>2</sup>/s) = 0.696 × 10<sup>−6</sup>, <span class="html-italic">D</span>(m<sup>2</sup>/s) = 8.26 × 10<sup>−10</sup>, and <span class="html-italic">C</span><sub>s</sub> (kg/m<sup>3</sup>) = 12.49 [<a href="#B20-pharmaceutics-16-01335" class="html-bibr">20</a>] while <span class="html-italic">k</span><sub>r</sub> = <span class="html-italic">k</span><sub>rb</sub> = 0 as monohydrate TPH does not undergo re-crystallization upon dissolution. TPH particle size distribution is described by the Weibull distribution (Equation (3)), whose parameters are those reported in <a href="#pharmaceutics-16-01335-t004" class="html-table">Table 4</a>. Concentration data (<span class="html-italic">C</span>) are normalized with respect to the final concentration <span class="html-italic">C</span><sub>fin</sub> = <span class="html-italic">M</span><sub>0</sub>/<span class="html-italic">V</span>.</p>
Full article ">Figure 5
<p>Comparison between <span class="html-italic">k</span><sub>m</sub> and the <math display="inline"><semantics> <mrow> <msubsup> <mrow> <mi>k</mi> </mrow> <mrow> <mi mathvariant="normal">d</mi> </mrow> <mrow> <mi mathvariant="normal">i</mi> </mrow> </msubsup> </mrow> </semantics></math> − <span class="html-italic">K</span><sub>i</sub> trend referring to the interpretation of DRT data (TPH) according to the proposed mathematical model.</p>
Full article ">Figure 6
<p>Model’s best fitting (solid line) to experimental DRT data (symbols) referring to PRQ (37 °C). Vertical bars indicate data standard error. The physical parameters adopted to perform data fitting read as follows: ρ<sub>s</sub> = 1232 kg/m<sup>3</sup>, ρ<sub>f</sub> = 993 kg/m<sup>3</sup>, η(Pa s) = 6.91 × 10<sup>−3</sup>, ν<sub>f</sub>(m<sup>2</sup>/s) = 0.696 × 10<sup>−6</sup>, <span class="html-italic">D</span>(m<sup>2</sup>/s) = 1.0 × 10<sup>−9</sup>, and <span class="html-italic">C</span><sub>s</sub> (kg/m<sup>3</sup>) = 0.18 [<a href="#B35-pharmaceutics-16-01335" class="html-bibr">35</a>] while <span class="html-italic">k</span><sub>r</sub> = <span class="html-italic">k</span><sub>rb</sub> = 0 as PRQ does not undergo re-crystallization upon dissolution. PRQ particle size distribution is described by the Weibull distribution (Equation (3)), the parameters of which are those reported in <a href="#pharmaceutics-16-01335-t004" class="html-table">Table 4</a>. Concentration data (<span class="html-italic">C</span>) are normalized with respect to the final concentration <span class="html-italic">C</span><sub>fin</sub> = <span class="html-italic">M</span><sub>0</sub>/<span class="html-italic">V</span>.</p>
Full article ">Figure 7
<p>Comparison between <span class="html-italic">k</span><sub>m</sub> and the <math display="inline"><semantics> <mrow> <msubsup> <mrow> <mi>k</mi> </mrow> <mrow> <mi mathvariant="normal">d</mi> </mrow> <mrow> <mi mathvariant="normal">i</mi> </mrow> </msubsup> </mrow> </semantics></math> − <span class="html-italic">K</span><sub>i</sub> trend referring to the interpretation of DRT data (PRQ) according to the proposed mathematical model.</p>
Full article ">Figure 8
<p>Spreading coefficient (<span class="html-italic">S</span><sub>C</sub>) referring to the four liquids considered (of increasing polarity, see <a href="#pharmaceutics-16-01335-t002" class="html-table">Table 2</a>) on PRQ (solid line) and TPH (dashed line). Vertical solid and dotted lines indicate, respectively, PRQ and TPH’s polarities (see <a href="#pharmaceutics-16-01335-t003" class="html-table">Table 3</a>) (25 °C).</p>
Full article ">Figure A1
<p>UV calibration curve referring to TPH (optical path = 1 cm; 37 °C). While ABS is absorbance, <span class="html-italic">C</span> is concentration expressed in moles/liter. Red dots indicate experimental data while the solid line is the linear interpolant (ABS = (12,117 ± 277) × <span class="html-italic">C</span> + (0.05 ± 0.022); Pearson correlation coefficient = 0.999). Molar extinction ε(M<sup>−1</sup> × cm<sup>−1</sup>) = (12,117 ± 227).</p>
Full article ">Figure A2
<p>UV calibration curve referring to PRQ (optical path 2 cm; 37 °C). While ABS is absorbance, <span class="html-italic">C</span> is concentration expressed in moles/liter. Red dots indicate experimental data while the solid line is the linear interpolant (ABS = (685 ± 15) × <span class="html-italic">C</span> + (0.01 ± 0.005); Pearson correlation coefficient = 0.998). Molar extinction ε(M<sup>−1</sup> × cm<sup>−1</sup>) = (342.3 ± 7.5).</p>
Full article ">Figure A3
<p>Schematic representation of the iterative method adopted to numerically solve the proposed mathematical model.</p>
Full article ">
19 pages, 4224 KiB  
Article
A Rigid–Flexible Supernumerary Robotic Arm/Leg: Design, Modeling, and Control
by Jiajun Xu, Mengcheng Zhao, Tianyi Zhang and Aihong Ji
Electronics 2024, 13(20), 4106; https://doi.org/10.3390/electronics13204106 (registering DOI) - 18 Oct 2024
Abstract
As humans’ additional arms or legs, supernumerary robotic limbs (SRLs) have gained great application prospects in many fields. However, current SRLs lack both rigidity/flexibility adaptability and arm/leg function conversion. Inspired by the muscular hydrostat characteristics of octopus tentacles, fiber-reinforced actuators (FRAs) were employed [...] Read more.
As humans’ additional arms or legs, supernumerary robotic limbs (SRLs) have gained great application prospects in many fields. However, current SRLs lack both rigidity/flexibility adaptability and arm/leg function conversion. Inspired by the muscular hydrostat characteristics of octopus tentacles, fiber-reinforced actuators (FRAs) were employed to develop SRLs simultaneously realizing flexible operation and stable support. In this paper, an SRL with FRAs was designed and implemented. The analytic model of the FRA was established to formulate the movement trajectory and stiffness profile of the SRL. A hierarchical hidden Markov model (HHMM) was proposed to recognize the wearer’s motion intention and control the SRL to complete the specific working mode and motion type. Experiments were conducted to exhibit the feasibility and superiority of the proposed robot. Full article
(This article belongs to the Special Issue Advancements in Robotics: Perception, Manipulation, and Interaction)
Show Figures

Figure 1

Figure 1
<p>Schematic view of SRL. (<b>a</b>) The SRL comprise multiple FRAs; (<b>b</b>) the SRL is worn on the human body.</p>
Full article ">Figure 1 Cont.
<p>Schematic view of SRL. (<b>a</b>) The SRL comprise multiple FRAs; (<b>b</b>) the SRL is worn on the human body.</p>
Full article ">Figure 2
<p>Stress distribution of FRA microelements.</p>
Full article ">Figure 3
<p>Schematic illustration of hierarchical segmentation of human motion intention and the corresponding SRL state.</p>
Full article ">Figure 4
<p>Illustration of the HHMM state transition.</p>
Full article ">Figure 5
<p>Overall diagram of the human–SRL interaction control system.</p>
Full article ">Figure 6
<p>SRL prototype experiment. (<b>a</b>) The SRL prototype with the control system and different end-effectors; (<b>b</b>) the SRL fetches a toy in the wearer’s hand; (<b>c</b>) the SRL moves a bottle with large workspace and high flexibility; (<b>d</b>) the SRL wraps a box and lifts it up.</p>
Full article ">Figure 6 Cont.
<p>SRL prototype experiment. (<b>a</b>) The SRL prototype with the control system and different end-effectors; (<b>b</b>) the SRL fetches a toy in the wearer’s hand; (<b>c</b>) the SRL moves a bottle with large workspace and high flexibility; (<b>d</b>) the SRL wraps a box and lifts it up.</p>
Full article ">Figure 7
<p>Movement trajectory test of the SRL. (<b>a</b>) Pick-and-place task 1; (<b>b</b>) pick-and-place task 2; (<b>c</b>) pick-and-place task 3.</p>
Full article ">Figure 7 Cont.
<p>Movement trajectory test of the SRL. (<b>a</b>) Pick-and-place task 1; (<b>b</b>) pick-and-place task 2; (<b>c</b>) pick-and-place task 3.</p>
Full article ">Figure 8
<p>Stiffness test of the SRL. (<b>a</b>) Stiffness regulation task 1; (<b>b</b>) stiffness regulation task 2; (<b>c</b>) stiffness regulation task 3.</p>
Full article ">
19 pages, 345 KiB  
Article
Literature and Mysticism in the Wake of Silvano Panunzio: From The Divine Comedy to the European Literature of the Twentieth Century
by Piero Latino
Religions 2024, 15(10), 1278; https://doi.org/10.3390/rel15101278 (registering DOI) - 18 Oct 2024
Viewed by 106
Abstract
This article introduces one of the forgotten figures of religious and literary studies: the Italian scholar, philosopher, metaphysician, poet and writer Silvano Panunzio (1918–2010). His contribution has so far been relegated to the margins of academic debate, and, currently, there are no academic [...] Read more.
This article introduces one of the forgotten figures of religious and literary studies: the Italian scholar, philosopher, metaphysician, poet and writer Silvano Panunzio (1918–2010). His contribution has so far been relegated to the margins of academic debate, and, currently, there are no academic studies on his work, in which mysticism plays a pivotal role. Panunzio believed that the transcendental and mystical dimension is fundamental for fully understanding the social, cultural, historical and political events of humanity. Another relevant aspect of his work is the importance he gave to literature and its relationship with mysticism, as in the case of Dante’s Divine Comedy or other European and Eastern writers and poets, such as Goethe, Shakespeare, Ibn Arabi and Dostoevsky. Significantly, Panunzio saved from oblivion the work of a forgotten man of letters of the nineteenth century, Gabriele Rossetti (1783–1854), who proposed the first symbolic and esoteric interpretation of Dante’s literary production and of European medieval love literature. Raising awareness of the intellectual amnesia around the figure of Silvano Panunzio may be a useful contribution to future research, both in the field of religious and literary studies. Full article
14 pages, 285 KiB  
Article
Understanding Household Income Inequality in Rural Vietnam: A Regression-Based Decomposition Study
by Thi Thu Thuy Tran, Kazunari Tsuji and Miho Fujimura
Sustainability 2024, 16(20), 9010; https://doi.org/10.3390/su16209010 (registering DOI) - 17 Oct 2024
Viewed by 256
Abstract
Along with the rapid economic development that rural Vietnam has experienced since the implementation of the Doi Moi policy, increasing attention is being paid to the widening income inequality among rural households. Although several studies have been conducted to understand the drivers of [...] Read more.
Along with the rapid economic development that rural Vietnam has experienced since the implementation of the Doi Moi policy, increasing attention is being paid to the widening income inequality among rural households. Although several studies have been conducted to understand the drivers of rural inequality, there is a lack of analysis that considers different household characteristics simultaneously and quantifies their contributions to inequality. Our study aims to fill this gap by applying the Fields’ regression-based decomposition method to household data collected from VARHS 2012 and VARHS 2016. The analysis results show that human capital, indicated by the quantity and quality of working members, and physical capital, indicated by household mobility and access to information, are the main contributors that explain this inequality. Additionally, the decreasing variation in specific characteristics, such as education level, is found to reduce their contribution to inequality over time, consequently preventing these factors from exacerbating overall inequality. Full article
(This article belongs to the Section Sustainable Urban and Rural Development)
16 pages, 12318 KiB  
Article
Digital Traffic Lights: UAS Collision Avoidance Strategy for Advanced Air Mobility Services
by Zachary McCorkendale, Logan McCorkendale, Mathias Feriew Kidane and Kamesh Namuduri
Drones 2024, 8(10), 590; https://doi.org/10.3390/drones8100590 (registering DOI) - 17 Oct 2024
Viewed by 264
Abstract
With the advancing development of Advanced Air Mobility (AAM), there is a collaborative effort to increase safety in the airspace. AAM is an advancing field of aviation that aims to contribute to the safe transportation of goods and people using aerial vehicles. When [...] Read more.
With the advancing development of Advanced Air Mobility (AAM), there is a collaborative effort to increase safety in the airspace. AAM is an advancing field of aviation that aims to contribute to the safe transportation of goods and people using aerial vehicles. When aerial vehicles are operating in high-density locations such as urban areas, it can become crucial to incorporate collision avoidance systems. Currently, there are available pilot advisory systems such as Traffic Collision and Avoidance Systems (TCAS) providing assistance to manned aircraft, although there are currently no collision avoidance systems for autonomous flights. Standards Organizations such as the Institute of Electrical and Electronics Engineers (IEEE), Radio Technical Commission for Aeronautics (RTCA), and General Aviation Manufacturers Association (GAMA) are working to develop cooperative autonomous flights using UAS-to-UAS Communication in structured and unstructured airspaces. This paper presents a new approach for collision avoidance strategies within structured airspace known as “digital traffic lights”. The digital traffic lights are deployed over an area of land, controlling all UAVs that enter a potential collision zone and providing specific directions to mitigate a collision in the airspace. This strategy is proven through the results demonstrated through simulation in a Cesium Environment. With the deployment of the system, collision avoidance can be achieved for autonomous flights in all airspaces. Full article
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<p>The air cell intersection for digital traffic lights.</p>
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<p>Air cell diagram.</p>
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<p>Data exchange for digital traffic management in the airspace.</p>
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<p>Block diagram scheme for the system.</p>
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<p>Octagon plot with corner ID.</p>
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<p>Cell center points plot.</p>
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<p>The generated intersection.</p>
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<p>The air cell intersection—overhead view.</p>
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<p>The air cell intersection—ground level view.</p>
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<p>The air cell intersection—close-up view.</p>
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20 pages, 1391 KiB  
Article
Communication Skills of Medical Interpreters: A Qualitative Explanatory Study of Healthcare Professionals’ and Medical Interpreters’ Perceptions
by Naoko Ono and Jinghua Yang
Healthcare 2024, 12(20), 2073; https://doi.org/10.3390/healthcare12202073 - 17 Oct 2024
Viewed by 263
Abstract
Background/Objectives: Medical interpreters support communication between medical professionals and foreign patients. However, the communication skills required of medical interpreters in the field are currently unclear. The purpose of this study was to investigate what medical professionals and medical interpreters consider to be [...] Read more.
Background/Objectives: Medical interpreters support communication between medical professionals and foreign patients. However, the communication skills required of medical interpreters in the field are currently unclear. The purpose of this study was to investigate what medical professionals and medical interpreters consider to be most important communication skills of medical interpreters, and whether there are differences in perceptions between medical professionals and medical interpreters. Methods: From December 2023 to February 2024, we interviewed 10 medical professionals and medical interpreters (five medical professionals and five medical interpreters) working throughout Japan and in the United States. The narratives collected in the interviews were analyzed and evaluated in a conceptual framework. Results: Healthcare professionals and medical interpreters exhibited differences in perceptions regarding the most important communication skills for medical interpreters. The narratives of medical professionals and medical interpreters regarding medical interpreters’ communication skills were divided into a 2 × 2 grid consisting of four quadrants with two axes (intervention and perspective). Regarding the communication skills of medical interpreters, medical professionals were primarily concerned with the transmission of medical information and felt that it was necessary for interpreters to understand medical professionals’ perspectives and what they wanted to say in order to convey it accurately. In contrast, medical interpreters emphasized the importance of empathy and communication skills for respecting the other person and understanding the other person’s opinion and perspective. Additionally, to understand the patient’s perspective, medical interpreters reported that it was important to understand the cultural background of the patient and to maintain good relationships with all of the people around the patient. Conclusions: We explored the communication skills of medical interpreters and the characteristics of the perceptions and narratives of medical professionals and medical interpreters. Concepts regarding the communication skills of medical interpreters were divided into two axes (intervention and perspective) and presented as a 2 × 2 grid with four quadrants. The results of our study suggested that medical interpreters should actively intervene in interpretation situations involving foreign patients. Full article
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<p>Conceptual diagram of the communication skills of medical interpreters.</p>
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18 pages, 1089 KiB  
Article
ViTDroid: Vision Transformers for Efficient, Explainable Attention to Malicious Behavior in Android Binaries
by Toqeer Ali Syed, Mohammad Nauman, Sohail Khan, Salman Jan and Megat F. Zuhairi
Sensors 2024, 24(20), 6690; https://doi.org/10.3390/s24206690 - 17 Oct 2024
Viewed by 248
Abstract
Smartphones are intricately connected to the modern society. The two widely used mobile phone operating systems, iOS and Android, profoundly affect the lives of millions of people. Android presently holds a market share of close to 71% among these two. As a result, [...] Read more.
Smartphones are intricately connected to the modern society. The two widely used mobile phone operating systems, iOS and Android, profoundly affect the lives of millions of people. Android presently holds a market share of close to 71% among these two. As a result, if personal information is not securely protected, it is at tremendous risk. On the other hand, mobile malware has seen a year-on-year increase of more than 42% globally in 2022 mid-year. Any group of human professionals would have a very tough time detecting and removing all of this malware. For this reason, deep learning in particular has been used recently to overcome this problem. Deep learning models, however, were primarily created for picture analysis. Despite the fact that these models have shown promising findings in the field of vision, it has been challenging to fully comprehend what the characteristics recovered by deep learning models are in the area of malware. Furthermore, the actual potential of deep learning for malware analysis has not yet been fully realized due to the translation invariance trait of well-known models based on CNN. In this paper, we present ViTDroid, a novel model based on vision transformers for the deep learning-based analysis of opcode sequences of Android malware samples from large real-world datasets. We have been able to achieve a false positive rate of 0.0019 as compared to the previous best of 0.0021. However, this incremental improvement is not the major contribution of our work. Our model aims to make explainable predictions, i.e., it not only performs the classification of malware with high accuracy, but it also provides insights into the reasons for this classification. The model is able to pinpoint the malicious behavior-causing instructions in the malware samples. This means that our model can actually aid in the field of malware analysis itself by providing insights to human experts, thus leading to further improvements in this field. Full article
(This article belongs to the Special Issue AI Technology for Cybersecurity and IoT Applications)
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<p>Transformer architecture for multi-head attention model [<a href="#B34-sensors-24-06690" class="html-bibr">34</a>]. (<b>a</b>) Computation of attention and (<b>b</b>) multi-head attention model.</p>
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<p>ViTDroid proposed architecture.</p>
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<p>Visual representation of the GELU activation function.</p>
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<p>Effect of skip connections on energy landscape of loss in a transformer encoder. (<b>a</b>) No skip connection, (<b>b</b>) skip connection: <math display="inline"><semantics> <mrow> <mi>k</mi> <mo>=</mo> <mn>3</mn> </mrow> </semantics></math>, and (<b>c</b>) skip connection: <math display="inline"><semantics> <mrow> <mi>k</mi> <mo>=</mo> <mn>7</mn> </mrow> </semantics></math>.</p>
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<p>Loss plot for ViTDroid with early stopping.</p>
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<p>Receiver Operating Characteristic (ROC) curve for ViTDroid and previous models.</p>
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<p>Visual representation of three malware samples—S1: SendPay, S2: FakeRun and S3: SMSReg—at different values of <math display="inline"><semantics> <mo>Ω</mo> </semantics></math>. (<b>a</b>) S1: <math display="inline"><semantics> <mrow> <mo>Ω</mo> <mo>=</mo> <mn>200</mn> </mrow> </semantics></math>, (<b>b</b>) S1: <math display="inline"><semantics> <mrow> <mo>Ω</mo> <mo>=</mo> <mn>300</mn> </mrow> </semantics></math>, (<b>c</b>) S1: <math display="inline"><semantics> <mrow> <mo>Ω</mo> <mo>=</mo> <mn>320</mn> </mrow> </semantics></math>, (<b>d</b>) S2: <math display="inline"><semantics> <mrow> <mo>Ω</mo> <mo>=</mo> <mn>200</mn> </mrow> </semantics></math>, (<b>e</b>) S2: <math display="inline"><semantics> <mrow> <mo>Ω</mo> <mo>=</mo> <mn>300</mn> </mrow> </semantics></math>, (<b>f</b>) S3: <math display="inline"><semantics> <mrow> <mo>Ω</mo> <mo>=</mo> <mn>320</mn> </mrow> </semantics></math>, (<b>g</b>) S3: <math display="inline"><semantics> <mrow> <mo>Ω</mo> <mo>=</mo> <mn>200</mn> </mrow> </semantics></math>, (<b>h</b>) S3: <math display="inline"><semantics> <mrow> <mo>Ω</mo> <mo>=</mo> <mn>300</mn> </mrow> </semantics></math>, (<b>i</b>) S3: <math display="inline"><semantics> <mrow> <mo>Ω</mo> <mo>=</mo> <mn>320</mn> </mrow> </semantics></math>.</p>
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<p>Example attention maps learned for different combinations of malware samples and <math display="inline"><semantics> <mo>Ω</mo> </semantics></math> variations. (<b>a</b>) S1: <math display="inline"><semantics> <mrow> <mo>Ω</mo> <mo>=</mo> <mn>200</mn> </mrow> </semantics></math>, (<b>b</b>) S1: <math display="inline"><semantics> <mrow> <mo>Ω</mo> <mo>=</mo> <mn>320</mn> </mrow> </semantics></math>, (<b>c</b>) S3: <math display="inline"><semantics> <mrow> <mo>Ω</mo> <mo>=</mo> <mn>300</mn> </mrow> </semantics></math>.</p>
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20 pages, 1240 KiB  
Review
Handling the Imbalanced Problem in Agri-Food Data Analysis
by Adeyemi O. Adegbenjo and Michael O. Ngadi
Foods 2024, 13(20), 3300; https://doi.org/10.3390/foods13203300 - 17 Oct 2024
Viewed by 235
Abstract
Imbalanced data situations exist in most fields of endeavor. The problem has been identified as a major bottleneck in machine learning/data mining and is becoming a serious issue of concern in food processing applications. Inappropriate analysis of agricultural and food processing data was [...] Read more.
Imbalanced data situations exist in most fields of endeavor. The problem has been identified as a major bottleneck in machine learning/data mining and is becoming a serious issue of concern in food processing applications. Inappropriate analysis of agricultural and food processing data was identified as limiting the robustness of predictive models built from agri-food applications. As a result of rare cases occurring infrequently, classification rules that detect small groups are scarce, so samples belonging to small classes are largely misclassified. Most existing machine learning algorithms including the K-means, decision trees, and support vector machines (SVMs) are not optimal in handling imbalanced data. Consequently, models developed from the analysis of such data are very prone to rejection and non-adoptability in real industrial and commercial settings. This paper showcases the reality of the imbalanced data problem in agri-food applications and therefore proposes some state-of-the-art artificial intelligence algorithm approaches for handling the problem using methods including data resampling, one-class learning, ensemble methods, feature selection, and deep learning techniques. This paper further evaluates existing and newer metrics that are well suited for handling imbalanced data. Rightly analyzing imbalanced data from food processing application research works will improve the accuracy of results and model developments. This will consequently enhance the acceptability and adoptability of innovations/inventions. Full article
(This article belongs to the Special Issue Impacts of Innovative Processing Technologies on Food Quality)
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<p>Receiver operating characteristic (ROC) curves for different classifiers: A—good model, B and C—poor models.</p>
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<p>Typical precision-recall curve for best threshold identification.</p>
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<p>Typical precision-recall curve for optimal model identification (PPV-positive predictive value (precision), SEN- sensitivity (recall), MD1-MD15: Model1-Model15).</p>
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12 pages, 1982 KiB  
Article
Smith Chart-Based Design of High-Frequency Broadband Power Amplifiers
by Edison Ferney Angarita Malaver, Nelson Barrera Lombana and Jorge Julian Moreno Rubio
Electronics 2024, 13(20), 4096; https://doi.org/10.3390/electronics13204096 (registering DOI) - 17 Oct 2024
Viewed by 253
Abstract
This paper presents a comprehensive study on the design and performance of a high-power amplifier (PA) covering a broad frequency band from 0.1 to 4.8 GHz. Leveraging a 10 W GaN device, the amplifier achieves output power levels surpassing 10 W across the [...] Read more.
This paper presents a comprehensive study on the design and performance of a high-power amplifier (PA) covering a broad frequency band from 0.1 to 4.8 GHz. Leveraging a 10 W GaN device, the amplifier achieves output power levels surpassing 10 W across the entire frequency band. Furthermore, the power-added efficiency (PAE) of the amplifier ranges from 47% to 59%, indicating its energy-efficient operation. With consistent gain characteristics varying between 7 and 15 dB, the design ensures reliable signal amplification for diverse applications. Notably, the approach introduces a simplified output matching network based on an LC network, prioritizing practicality without sacrificing performance. Additionally, comprehensive guidance is provided on utilizing the Smith chart for streamlined amplifier design, enabling engineers with an accessible methodology. Through a meticulous analysis, this work contributes to advancing the field of high-power amplification, offering enhanced performance and usability for next-generation wireless communication systems. Full article
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<p>External optimal load <math display="inline"><semantics> <msub> <mi>Z</mi> <mrow> <mi>e</mi> <mi>x</mi> <mi>t</mi> </mrow> </msub> </semantics></math>: CGH40010 (above) and CGH40025 (below).</p>
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<p>Proposed output-matching network.</p>
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<p>Design graphical process: <math display="inline"><semantics> <msub> <mi>Z</mi> <mi>a</mi> </msub> </semantics></math> (red), <math display="inline"><semantics> <msub> <mi>Z</mi> <mrow> <mi>s</mi> <mi>y</mi> <mi>n</mi> </mrow> </msub> </semantics></math> (pink), and <math display="inline"><semantics> <msub> <mi>Z</mi> <mrow> <mi>e</mi> <mi>x</mi> <mi>t</mi> </mrow> </msub> </semantics></math> (blue).</p>
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<p>Intrinsic reflection coefficient (red) and <math display="inline"><semantics> <msub> <mi>P</mi> <mrow> <mi>r</mi> <mi>e</mi> <mi>f</mi> </mrow> </msub> </semantics></math> contour (black).</p>
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<p>IV characteristics of the chosen device: drain current vs. drain voltage (left) and drain current vs. gate voltage with <math display="inline"><semantics> <mrow> <msub> <mi>V</mi> <mrow> <mi>D</mi> <mi>D</mi> </mrow> </msub> <mo>=</mo> <mn>28</mn> </mrow> </semantics></math> V (right).</p>
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<p>Intrinsic reflection coefficient (red) and <math display="inline"><semantics> <msub> <mi>P</mi> <mrow> <mi>r</mi> <mi>e</mi> <mi>f</mi> </mrow> </msub> </semantics></math> contour (black) for CGH40025 (<b>left</b>) and WIN 8 × 100 μm NP15 (<b>right</b>) devices.</p>
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<p>Schematic and picture of the designed PA.</p>
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<p>Intrinsic impedance: ideal L and C components (red) and simulated hybrid implementation (green) (0.4 to 4.8) GHz.</p>
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<p>CW characterization of the designed PA.</p>
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<p>Measured gain, output power and PAE profiles at selected in-band frequencies.</p>
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<p>Normalized output power spectral density of the designed PA at 3.0 GHz with and without DPD.</p>
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23 pages, 3240 KiB  
Article
Development of the Separation Column’s Temperature Field Monitoring System
by Tatyana Kukharova, Alexander Martirosyan, Mir-Amal Asadulagi and Yury Ilyushin
Energies 2024, 17(20), 5175; https://doi.org/10.3390/en17205175 - 17 Oct 2024
Viewed by 209
Abstract
Oil is one of the main resources used by all countries in the world. The ever-growing demand for oil and oil products forces oil companies to increase production and refining. In order to increase net profit, oil producing companies are constantly upgrading equipment, [...] Read more.
Oil is one of the main resources used by all countries in the world. The ever-growing demand for oil and oil products forces oil companies to increase production and refining. In order to increase net profit, oil producing companies are constantly upgrading equipment, improving oil production technologies, and preparing oil for further processing. When considering the elements of primary oil refining in difficult conditions, such as hard-to-reach or in remote locations, developers face strict limitations in energy resources and dimensions. Therefore, the use of traditional systems causes a number of difficulties, significantly reducing production efficiency. In this study, the authors solve the problem of improving the characteristics of the oil separation process. In their work, the authors analyzed the separation columns of primary oil distillation, identified the shortcomings of the technological process, and searched for technological solutions. Having identified the lack of technical solutions for monitoring the state of the temperature field of the separation column, the authors developed their own hardware–software complex for monitoring the separation column (RF patents No. 2020665473, No. 2021662752 were received). The complex was tested and successfully implemented into production. The study provides an assessment of the economic efficiency of implementation for a year and a forecast of the economic effect for 10 years. Full article
(This article belongs to the Section K: State-of-the-Art Energy Related Technologies)
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<p>Algorithm for obtaining and processing values for Arduino UNO.</p>
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<p>Window application operation algorithm.</p>
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<p>DS18B20 outputs.</p>
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<p>“Parasitic power” connection mode.</p>
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<p>Simplified connection diagram.</p>
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<p>Example of displaying temperature from sensors.</p>
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<p>Example of displaying temperature from sensors after changes.</p>
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<p>Working window interface.</p>
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<p>Results of experiment.</p>
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<p>Results of experiment No. 4.</p>
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12 pages, 2246 KiB  
Article
First Overview of Zoological Medicine on Iberian Countries
by Fábio Cardoso-Freitas, Vanessa Silva, Albert Martinez-Silvestre, Ângela Martins and Patrícia Poeta
Vet. Sci. 2024, 11(10), 512; https://doi.org/10.3390/vetsci11100512 - 17 Oct 2024
Viewed by 231
Abstract
The role of veterinary doctors, particularly those dedicated to Zoological Medicine, is becoming increasingly relevant and essential within the One Health framework. Educational and employment opportunities in this field vary widely across Europe, prompting us to characterise the sector in Portugal and Spain. [...] Read more.
The role of veterinary doctors, particularly those dedicated to Zoological Medicine, is becoming increasingly relevant and essential within the One Health framework. Educational and employment opportunities in this field vary widely across Europe, prompting us to characterise the sector in Portugal and Spain. A survey was conducted, resulting in 169 valid responses from veterinarians. Respondents were characterised based on gender, age, work environment, the highest level of education, additional training, whether they attended zoological medicine classes at university and their perception of the adequacy of that training. Further factors included years of experience, the percentage of their work involving zoological medicine, sectors they work in, the types of animals they treat, their confidence in treating these animals, sources of information they use, and membership in relevant professional associations. Relationships between these variables were examined. The results describe Iberian professionals working with non-traditional pets, wildlife, and zoo animals. Notably, only half of these professionals had taken zoological medicine classes at university; among those, the majority felt they inadequately prepared them for their work. Given the findings, enhancing the training and resources available to these professionals is crucial to prepare them for their roles better. Full article
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<p>Distribution by number of answers from veterinarians (according to NUTS II).</p>
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<p>Zoological Medicine workload (x: percentage of ZM, y: proportion of the respondents).</p>
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<p>Sectors of Zoological Medicine.</p>
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<p>Prevalence of attendance of various animal groups.</p>
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<p>Comparison between total confidence in treating groups of animals and the difference in those attending or not attending those same animals.</p>
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<p>Percentages of usage of different sources to search for drugs and dosages.</p>
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24 pages, 12289 KiB  
Article
Kinematic and Workspace Analysis of RRU-3RSS: A Novel 2T2R Parallel Manipulator
by Paul Diego, Erik Macho, Saioa Herrero, Francisco J. Campa, Mikel Diez, Javier Corral and Charles Pinto
Appl. Sci. 2024, 14(20), 9491; https://doi.org/10.3390/app14209491 - 17 Oct 2024
Viewed by 229
Abstract
This paper presents a novel parallel manipulator capable of generating two translations (2T), inside a vertical plane, and two rotations (2R), about horizontal axes, which are required in aerospace, manufacturing and rehabilitation fields. These four degrees of freedom are reached by means of [...] Read more.
This paper presents a novel parallel manipulator capable of generating two translations (2T), inside a vertical plane, and two rotations (2R), about horizontal axes, which are required in aerospace, manufacturing and rehabilitation fields. These four degrees of freedom are reached by means of a unique RRU and three RSS kinematic chains connected to a rhomboid-shaped mobile platform. The kinematic analysis of the new manipulator is provided, which includes the resolution of the inverse position problem and the velocity equations relating to input and output variables. Additionally, a methodology is proposed for obtaining the workspace free of singularities, collisions and kinematic joint range limitation. This systematic methodology allows designers to identify the critical factors affecting the workspace and, thus, to rearrange the mechanical design accordingly for optimum path planning. We represent the workspace using its two-dimensional subspaces (i.e., translational and rotational workspace). The results are analyzed for different working modes of the manipulator to see its potential use in applications wherein 2T2R motion is necessary. Full article
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<p>Schematic representation of RRU-3RSS PM (<b>a</b>) geometrical parameters; (<b>b</b>) input-output variables.</p>
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<p>Equivalence between circumference-sphere intersection and two circumferences intersection in RSS KCs.</p>
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<p>Example of the symbolic notation used for the inverse kinematic problem solutions (working modes).</p>
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<p>Example of some working modes for the same pose of the RRU-3RSS mobile platform.</p>
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<p>Proposed methodology for obtaining the useful WS.</p>
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<p>Shape of the RRU-3RSS translational WS for different <math display="inline"><semantics> <mrow> <mi>φ</mi> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>θ</mi> </mrow> </semantics></math> values.</p>
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<p>Shape of the RRU-3RSS rotational WS for different <math display="inline"><semantics> <mrow> <mi>x</mi> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>z</mi> </mrow> </semantics></math> values.</p>
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<p>Translational and rotational WS<sub>DKP</sub> for two working modes of the RRU-3RSS PM. Light-green-colored regions correspond to <math display="inline"><semantics> <mrow> <mfenced open="|" close="|" separators="|"> <mrow> <msub> <mrow> <mi mathvariant="bold-italic">J</mi> </mrow> <mrow> <mi>x</mi> </mrow> </msub> </mrow> </mfenced> <mo>&gt;</mo> <mn>0</mn> </mrow> </semantics></math>, whereas dark-green-colored regions correspond to <math display="inline"><semantics> <mrow> <mfenced open="|" close="|" separators="|"> <mrow> <msub> <mrow> <mi mathvariant="bold-italic">J</mi> </mrow> <mrow> <mi>x</mi> </mrow> </msub> </mrow> </mfenced> <mo>&lt;</mo> <mn>0</mn> </mrow> </semantics></math>.</p>
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<p>Regions of the WS<sub>DKP</sub> with the same sign of <math display="inline"><semantics> <mrow> <mfenced open="|" close="|" separators="|"> <mrow> <msub> <mrow> <mi mathvariant="bold-italic">J</mi> </mrow> <mrow> <mi>x</mi> </mrow> </msub> </mrow> </mfenced> </mrow> </semantics></math> for the (<math display="inline"><semantics> <mrow> <mo>+</mo> <mo>−</mo> <mo>+</mo> <mo>−</mo> </mrow> </semantics></math>) working mode. Variation of the negative (<b>a</b>) and positive (<b>b</b>) sign regions of the translational WS for different values of <math display="inline"><semantics> <mrow> <mi>φ</mi> </mrow> </semantics></math>, being <math display="inline"><semantics> <mrow> <mi>θ</mi> <mo>=</mo> <mn>0</mn> <mo>°</mo> </mrow> </semantics></math>. Variation of the negative (<b>c</b>) and positive (<b>d</b>) sign regions of the rotational WS for different values of <math display="inline"><semantics> <mrow> <mi>z</mi> </mrow> </semantics></math>, being <math display="inline"><semantics> <mrow> <mi>x</mi> <mo>=</mo> <mn>0</mn> <mo> </mo> <mi>m</mi> </mrow> </semantics></math>.</p>
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<p><math display="inline"><semantics> <mrow> <mfenced open="|" close="|" separators="|"> <mrow> <msub> <mrow> <mi mathvariant="bold-italic">J</mi> </mrow> <mrow> <mi>x</mi> </mrow> </msub> </mrow> </mfenced> </mrow> </semantics></math> values inside the translational WS when the mobile platform is parallel to the fixed one (<math display="inline"><semantics> <mrow> <mi>φ</mi> <mo>=</mo> <mi>θ</mi> <mo>=</mo> <mn>0</mn> <mo>°</mo> </mrow> </semantics></math>) for the three groups of working modes (Group A, B and C).</p>
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<p><math display="inline"><semantics> <mrow> <mfenced open="|" close="|" separators="|"> <mrow> <msub> <mrow> <mi mathvariant="bold-italic">J</mi> </mrow> <mrow> <mi>x</mi> </mrow> </msub> </mrow> </mfenced> </mrow> </semantics></math> values inside the rotational WS corresponding to different working modes, when <math display="inline"><semantics> <mrow> <mi>x</mi> <mo>=</mo> <mn>0</mn> <mo> </mo> <mi>m</mi> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>z</mi> <mo>=</mo> <mn>0.3</mn> <mo> </mo> <mi>m</mi> </mrow> </semantics></math> (<math display="inline"><semantics> <mrow> <mi>φ</mi> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>θ</mi> </mrow> </semantics></math> range is ± 180°). Red curves represent the DKP singularity locus.</p>
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<p>Three parallelism cases to check the possibility of collision.</p>
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<p>Minimum distance (<b>a</b>) inside the limits of the links and (<b>b</b>) outside the limits.</p>
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<p>Procedure to check the collisions between the links of different KCs.</p>
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<p>Translational and rotational WS<sub>KCs</sub> for different working modes. Blue-colored regions are free of collisions between chains.</p>
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<p>Translational and rotational WS<sub>platform</sub> for a mobile platform that consists of two cross-links. Yellow-colored regions are free of collisions with the platform.</p>
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<p>Schematic representation of (<b>a</b>) non-collision and (<b>b</b>,<b>c</b>) collision positions.</p>
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<p>Translational and rotational WS<sub>platform</sub> for an infinite plane mobile platform. Orange-colored regions are free of collisions with the platform.</p>
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<p>Representation of the angles involved in the kinematic joint motion range restrictions.</p>
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<p>Translational and rotational WS<sub>joints</sub> for different working modes. Magenta-colored poses can be reached without surpassing the kinematic joints motion range.</p>
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<p>Translational and rotational WS<sub>useful</sub> when <math display="inline"><semantics> <mrow> <mi>x</mi> <mo>=</mo> <mn>0</mn> <mo> </mo> <mi mathvariant="normal">m</mi> <mo>,</mo> <mo> </mo> <mi>z</mi> <mo>=</mo> <mn>0.3</mn> <mo> </mo> <mi mathvariant="normal">m</mi> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mi>φ</mi> <mo>=</mo> <mn>0</mn> <mo>°</mo> <mo>,</mo> <mo> </mo> <mi>θ</mi> <mo>=</mo> <mn>0</mn> <mo>°</mo> </mrow> </semantics></math> is selected as the initial position. Valid poses are represented in purple.</p>
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<p>Influence of the initial position (black rectangle) on translational WS subsets (<math display="inline"><semantics> <mrow> <mi>x</mi> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>z</mi> </mrow> </semantics></math> range is <math display="inline"><semantics> <mrow> <mo>±</mo> </mrow> </semantics></math>0.7 m).</p>
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<p>Influence of the initial position (black rectangle) on rotational WS subsets (<math display="inline"><semantics> <mrow> <mi>φ</mi> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>θ</mi> </mrow> </semantics></math> range is <math display="inline"><semantics> <mrow> <mo>±</mo> </mrow> </semantics></math>180°).</p>
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26 pages, 8947 KiB  
Article
Angle of Attack Characteristics of Full-Active and Semi-Active Flapping Foil Propulsors
by Lei Mei, Wenhui Yan, Junwei Zhou, Yongqi Tang and Weichao Shi
Water 2024, 16(20), 2957; https://doi.org/10.3390/w16202957 - 17 Oct 2024
Viewed by 210
Abstract
As a propulsor with a good application prospect, the flapping foil has been a hot research topic in the past decade. Although the research results of flapping foils have been very abundant, the performance-influencing mechanism of flapping foils is still not perfect, and [...] Read more.
As a propulsor with a good application prospect, the flapping foil has been a hot research topic in the past decade. Although the research results of flapping foils have been very abundant, the performance-influencing mechanism of flapping foils is still not perfect, and the research considering three-dimensional (3D) effects for engineering applications is still very limited. Based on the above considerations, a systematic and parametric analysis of a small aspect ratio flapping foil is conducted to correlate the influencing factors including angle of attack (AoA) characteristics and wake vortex on the propulsive efficiency. Three-dimensional numerical analyses of full-active and semi-active flapping foils are carried out in this paper, in which the former focuses on different heave amplitudes and pitch amplitudes, and the latter concentrates on different spring stiffnesses. The analysis covers the full range of advance coefficient, which starts around 0 and ends at a thrust drop of 0. Firstly, the influence of the maximum AoA (αmax) on the efficiency and thrust coefficient of these two kinds of flapping foils is analyzed. The results show that for the small aspect ratio flapping foil in this paper, regardless of the full-active or semi-active form, the peak efficiency as high as 75% for both generally appears around αmax = 0.2 rad, while the peak thrust coefficient of 0.5 occurs near αmax = 0.3 rad. Then, by analyzing the wake flow field, it is found that the lower efficiency of larger αmax working points is mainly due to the larger vortex dissipation loss, while the lower efficiency of smaller αmax working points is mainly due to the larger friction loss of the foil surface. Furthermore, the plumpness of different AoA curves is compared and analyzed. It was found that, unlike the results of full-active flapping foils, the shape of the AoA curve of semi-active flapping foils with different spring stiffnesses is similar, and the relationship with efficiency is not strictly corresponding. This study is expected to provide guidance on both academics and industries in relevant fields. Full article
(This article belongs to the Special Issue CFD in Fluid Machinery Design and Optimization)
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Figure 1
<p>Three-dimensional geometric shape of the flapping foil.</p>
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<p>Sketch of the flapping foil propulsion motion.</p>
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<p>Schematic illustration of a semi-active flapping foil with forced heave motion and attached torsion spring (The blue part is the torsion spring, and the red part is the rigid connection with the actuator).</p>
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<p>Schematic diagram of the computational domain and gradual mesh refinement.</p>
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<p>Comparisons of the propulsive efficiency <span class="html-italic">η</span> and the thrust coefficient <span class="html-italic">c<sub>T</sub></span> with previous experimental results for <span class="html-italic">α<sub>max</sub></span> = 20°.</p>
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<p>Comparison of vorticity patterns visualized in the foil wake (<math display="inline"><semantics> <mrow> <msub> <mrow> <mi>S</mi> <mi>t</mi> </mrow> <mrow> <mi>D</mi> </mrow> </msub> <mo>=</mo> <mn>0.08</mn> <mo>,</mo> <mtext> </mtext> <msub> <mrow> <mi>A</mi> </mrow> <mrow> <mi>D</mi> </mrow> </msub> <mo>=</mo> <mn>1.4</mn> </mrow> </semantics></math>). (Experimental results are from Figure 3c in Schnipper [<a href="#B29-water-16-02957" class="html-bibr">29</a>]).</p>
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<p>Experimental site and related equipment.</p>
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<p>Comparisons of the propulsive efficiency <span class="html-italic">η</span> with experimental results for <span class="html-italic">α<sub>max</sub></span> = 20°.</p>
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<p>Comparison of hydrodynamic force between simulation and experimental results. (<b>a</b>) <span class="html-italic">J</span> = 2.45, (<b>b</b>) <span class="html-italic">J</span> = 5.24.</p>
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<p>Propulsive efficiency <span class="html-italic">η</span> and thrust coefficient <span class="html-italic">K<sub>T</sub></span> of a full-active flapping foil as function of <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>m</mi> <mi>a</mi> <mi>x</mi> </mrow> </msub> </mrow> </semantics></math>, for different pitching angles. (<b>a</b>) <math display="inline"><semantics> <mrow> <mi>η</mi> <mo>−</mo> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>m</mi> <mi>a</mi> <mi>x</mi> </mrow> </msub> </mrow> </semantics></math>, (<b>b</b>) <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>K</mi> </mrow> <mrow> <mi>T</mi> </mrow> </msub> <mo>−</mo> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>m</mi> <mi>a</mi> <mi>x</mi> </mrow> </msub> </mrow> </semantics></math>.</p>
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<p>Propulsive efficiency <span class="html-italic">η</span> and thrust coefficient <span class="html-italic">K<sub>T</sub></span> of a full-active flapping foil as function of advance coefficient <span class="html-italic">J</span>, for different pitching angles. (<b>a</b>) <math display="inline"><semantics> <mrow> <mi>η</mi> <mo>−</mo> <mi>J</mi> </mrow> </semantics></math>, (<b>b</b>) <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>K</mi> </mrow> <mrow> <mi>T</mi> </mrow> </msub> <mo>−</mo> <mi>J</mi> </mrow> </semantics></math>.</p>
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<p>Propulsive efficiency <span class="html-italic">η</span> of a full-active flapping foil as function of <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>m</mi> <mi>a</mi> <mi>x</mi> </mrow> </msub> </mrow> </semantics></math>, for a series of heaving amplitudes. (<b>a</b>) <span class="html-italic">θ</span><sub>0</sub> = 0.3 rad, (<b>b</b>) <span class="html-italic">θ</span><sub>0</sub> = 0.5 rad.</p>
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<p>Thrust coefficient <span class="html-italic">K<sub>T</sub></span> of a full-active flapping foil as function of <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>m</mi> <mi>a</mi> <mi>x</mi> </mrow> </msub> </mrow> </semantics></math>, for a series of heaving amplitudes. (<b>a</b>) <span class="html-italic">θ</span><sub>0</sub> = 0.3 rad, (<b>b</b>) <span class="html-italic">θ</span><sub>0</sub> = 0.5 rad.</p>
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<p>Propulsive efficiency <span class="html-italic">η</span> of a semi-active flapping foil as function of <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>m</mi> <mi>a</mi> <mi>x</mi> </mrow> </msub> <mtext> </mtext> </mrow> </semantics></math>and advance coefficient <span class="html-italic">J</span> for a series of spring stiffness ratios. (<b>a</b>) <span class="html-italic">θ</span><sub>0</sub> = 0.3 rad, (<b>b</b>) <span class="html-italic">θ</span><sub>0</sub> = 0.5 rad.</p>
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<p>Thrust coefficient <span class="html-italic">K<sub>T</sub></span> of a semi-active flapping foil as function of <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>m</mi> <mi>a</mi> <mi>x</mi> </mrow> </msub> </mrow> </semantics></math><span class="html-italic">,</span> for a series of heaving amplitudes. (<b>a</b>) <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>K</mi> </mrow> <mrow> <mi>T</mi> </mrow> </msub> <mo>−</mo> <mi>J</mi> </mrow> </semantics></math>, (<b>b</b>) <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>K</mi> </mrow> <mrow> <mi>T</mi> </mrow> </msub> <mo>−</mo> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>m</mi> <mi>a</mi> <mi>x</mi> </mrow> </msub> </mrow> </semantics></math>.</p>
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<p>Vortex structure and distribution of an active flapping foil under six working conditions (<math display="inline"><semantics> <mrow> <msub> <mrow> <mi>y</mi> </mrow> <mrow> <mn>0</mn> </mrow> </msub> <mo>/</mo> <mi>c</mi> <mo>=</mo> <mn>2.5</mn> <mo>,</mo> <mtext> </mtext> <msub> <mrow> <mi>θ</mi> </mrow> <mrow> <mn>0</mn> </mrow> </msub> <mo>=</mo> <mn>0.5</mn> <mtext> </mtext> <mi mathvariant="normal">r</mi> <mi mathvariant="normal">a</mi> <mi mathvariant="normal">d</mi> </mrow> </semantics></math>).</p>
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<p>Velocity distributions and tip vortex structure of flow field at different pitching angles.</p>
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<p>Sketch of forces on a flapping foil.</p>
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<p>Velocity cloud diagrams and tip vortex structures of flow fields at different heave amplitudes.</p>
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<p>Flow field vortex structure of a semi-active flapping foil with different spring stiffnesses.</p>
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<p>Comparison of AoA time-history curves at different pitch amplitudes.</p>
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<p>AoA duration curves of a semi-active flapping foil with different spring stiffnesses. (<b>a</b>) <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>m</mi> <mi>a</mi> <mi>x</mi> </mrow> </msub> <mo>=</mo> <mn>0.18</mn> <mtext> </mtext> <mi mathvariant="normal">r</mi> <mi mathvariant="normal">a</mi> <mi mathvariant="normal">d</mi> </mrow> </semantics></math>, (<b>b</b>) <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>m</mi> <mi>a</mi> <mi>x</mi> </mrow> </msub> <mo>=</mo> <mn>0.5</mn> <mtext> </mtext> <mi mathvariant="normal">r</mi> <mi mathvariant="normal">a</mi> <mi mathvariant="normal">d</mi> </mrow> </semantics></math>.</p>
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<p>Pitch motion and AoA time-history curves of a semi-active flapping foil (<math display="inline"><semantics> <mrow> <msup> <mi>K</mi> <mo>′</mo> </msup> <mo>=</mo> <mn>0.8</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>m</mi> <mi>a</mi> <mi>x</mi> </mrow> </msub> <mo>=</mo> <mn>0.18</mn> <mo>,</mo> <mtext> </mtext> <mn>0.5</mn> <mtext> </mtext> <mi mathvariant="normal">r</mi> <mi mathvariant="normal">a</mi> <mi mathvariant="normal">d</mi> </mrow> </semantics></math>).</p>
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34 pages, 1600 KiB  
Article
Empowering Women in Tech Innovation and Entrepreneurship: A Qualitative Approach
by Teresa Felgueira, Teresa Paiva, Catarina Alves and Natália Gomes
Educ. Sci. 2024, 14(10), 1127; https://doi.org/10.3390/educsci14101127 - 17 Oct 2024
Viewed by 182
Abstract
Women’s participation and leadership in technology and entrepreneurship are crucial for advancing innovation and ensuring inclusive economic development. Despite progress in gender equality, women in tech face challenges like under-representation and systemic biases. This research delves into the multifaceted experiences of women in [...] Read more.
Women’s participation and leadership in technology and entrepreneurship are crucial for advancing innovation and ensuring inclusive economic development. Despite progress in gender equality, women in tech face challenges like under-representation and systemic biases. This research delves into the multifaceted experiences of women in tech innovation and entrepreneurship, highlighting the barriers they face and the strategies they use to overcome them. This study used a qualitative, observational design with semi-structured interviews and thematic analysis to explore the experiences and perceptions of entrepreneurial women in the Science, Technology, Engineering, and Mathematics (STEM) field. It was possible to conclude that entrepreneurial women exhibit a strong sense of autonomy, competence, and leadership, enabling them to manage their ventures independently and effectively. Also, the success of entrepreneurial women is multifaceted, combining personal fulfilment, professional achievements, and financial stability, with positive feedback and recognition playing a key role. Building strong social and supportive relationships is vital for entrepreneurial women, providing a sense of belonging, community, and emotional support. In this context, to empower women in STEM and entrepreneurship, Higher Education Institutions (HEIs) should promote entrepreneurship as a career path, provide practical and value-based education, and foster a work environment of trust, communication, and continuous learning. Full article
(This article belongs to the Special Issue Gender and STEM Education)
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<p>Self-Determination Theory: main objective questions.</p>
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<p>Categories and subcategories of the autonomy construct.</p>
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<p>Categories and subcategories of the competence construct.</p>
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<p>Categories and subcategories of the relatedness construct.</p>
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<p>HEI environment characteristics.</p>
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