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Search Results (466)

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Keywords = femtosecond laser processing

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13 pages, 3446 KiB  
Article
Femtosecond Laser Ablation and Delamination of Functional Magnetic Multilayers at the Nanoscale
by Pavel Varlamov, Jan Marx, Yoav Urbina Elgueta, Andreas Ostendorf, Ji-Wan Kim, Paolo Vavassori and Vasily Temnov
Nanomaterials 2024, 14(18), 1488; https://doi.org/10.3390/nano14181488 - 13 Sep 2024
Viewed by 200
Abstract
Laser nanostructuring of thin films with ultrashort laser pulses is widely used for nanofabrication across various fields. A crucial parameter for optimizing and understanding the processes underlying laser processing is the absorbed laser fluence, which is essential for all damage phenomena such as [...] Read more.
Laser nanostructuring of thin films with ultrashort laser pulses is widely used for nanofabrication across various fields. A crucial parameter for optimizing and understanding the processes underlying laser processing is the absorbed laser fluence, which is essential for all damage phenomena such as melting, ablation, spallation, and delamination. While threshold fluences have been extensively studied for single compound thin films, advancements in ultrafast acoustics, magneto-acoustics, and acousto-magneto-plasmonics necessitate understanding the laser nanofabrication processes for functional multilayer films. In this work, we investigated the thickness dependence of ablation and delamination thresholds in Ni/Au bilayers by varying the thickness of the Ni layer. The results were compared with experimental data on Ni thin films. Additionally, we performed femtosecond time-resolved pump-probe measurements of transient reflectivity in Ni to determine the heat penetration depth and evaluate the melting threshold. Delamination thresholds for Ni films were found to exceed the surface melting threshold suggesting the thermal mechanism in a liquid phase. Damage thresholds for Ni/Au bilayers were found to be significantly lower than those for Ni and fingerprint the non-thermal mechanism without Ni melting, which we attribute to the much weaker mechanical adhesion at the Au/glass interface. This finding suggests the potential of femtosecond laser delamination for nondestructive, energy-efficient nanostructuring, enabling the creation of high-quality acoustic resonators and other functional nanostructures for applications in nanosciences. Full article
(This article belongs to the Section Nanophotonics Materials and Devices)
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Figure 1
<p>Optical microscopy of the structures obtained by a single fs-laser pulse on the Ni films in reflection. The upper set of photos demonstrates the structures for the different thicknesses of Ni film produced by the laser pulse coming from air at the same pulse energy (E<sub>p</sub> = 16 μJ). The lower set shows the same for the case of irradiation from the substrate side. The red quarter circles indicate the diameters of ablation craters, where the film was completely removed. The yellow quarter circle for air side ablation of 100 nm Ni indicates the ablation crater due to surface ablation. The scale, indicated for the 20 nm Ni ablation in air at 125 μm, applies to all other micrographs.</p>
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<p>Optical microscopy of the structures obtained by a single fs-laser pulse on the Ni/Au films in reflection. The upper set of photos demonstrates the structures for the different thicknesses of Ni/Au film produced by the laser pulse coming from air at a specified energy pulse (E<sub>p</sub> = 16 μJ). The lower panel shows the same for the case of irradiation from the substrate side. The red quarter circles indicate the diameters of ablation holes, where the film was completely removed (ablated). The thickness mentioned for NiAu refers to the thickness of the Ni layer deposited on a 5 nm Au layer, which is situated on the glass substrate. The scale, indicated for the 10 nm NiAu ablation in air at 125 μm, applies to all other micrographs.</p>
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<p>Optical microscopy of the structures obtained by a single fs-laser pulse on Ni and Ni/Au films on glass in reflection. The set of photos demonstrates the structures for the different thicknesses of Ni and Ni/Au film produced by the laser pulse coming from the glass side at specified energy pulses. The red quarter circles indicate the diameters of structures, obtained with delamination. The thickness mentioned for NiAu refers to the thickness of the Ni layer deposited on a 5 nm Au layer, which was situated on the glass substrate. The scale, indicated for the 80 nm Ni delamination at 50 μm, applies to all other micrographs.</p>
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<p>Surface displacement of Ni (<b>a</b>) and Ni/Au (<b>b</b>) delaminated films on both air and glass sides, as measured by interferometry.</p>
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<p>(<b>a</b>) Time-resolved reflectivity measurements of acoustic pulses in a Ni (240 nm)/sapphire sample, obtained by pumping at the nickel–air interface and probing at the nickel–sapphire interface, alongside the modeled reflectivity. (<b>b</b>) Acoustic spectrum derived from the experimental reflectivity data and the sensitivity function used for modeling the acoustic spectrum. (<b>c</b>) Simulated acoustic pulse and the sensitivity function employed in the modeling process. (<b>d</b>) Reconstructed strain obtained from experimental data and the corresponding modeled strain. The reflectivity data were well-approximated using a model strain with an exponential decay characterized by a heating depth <span class="html-italic">h</span> = 24 nm. Both the acoustic spectra and pulses were well-reproduced using the two-temperature (TTM) model by Saito et al. [<a href="#B44-nanomaterials-14-01488" class="html-bibr">44</a>]. The Fourier reconstructed strain was derived using the algorithm developed by Manke et al. [<a href="#B30-nanomaterials-14-01488" class="html-bibr">30</a>]. Time-resolved reflectivity measurements enable precise evaluation of the heating depth <span class="html-italic">h</span> up to the damage threshold.</p>
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<p>Ablation and delamination thresholds as a function of thickness for Ni (<b>a</b>) and Ni/Au (<b>b</b>) thin films, subjected to irradiation from both the air and substrate sides. The individual dots denote the thresholds evaluated using Liu’s method (for ease of visual interpretation, these dots are interconnected by lines). The black crossed point in (<b>a</b>) is a threshold value for incomplete Ni ablation. The green lines and the shaded area represent the calculated nickel/substrate interface melting threshold given by Equation (5) for <span class="html-italic">h</span> in a range from 20 nm to 30 nm. The purple lines/shaded area represent the calculated fluence required to heat the nickel at the Ni/Au interface to the melting temperature of gold (1377 K). Yellow squares represent the fs-laser-induced melting thresholds at the nickel–air surface, experimentally obtained by Wellershoff et al. [<a href="#B26-nanomaterials-14-01488" class="html-bibr">26</a>]. The thickness mentioned for NiAu refers to the thickness of the Ni layer deposited on a 5 nm Au layer, which is situated on the glass substrate.</p>
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35 pages, 7517 KiB  
Review
Recent Advances in Applications of Ultrafast Lasers
by Sibo Niu, Wenwen Wang, Pan Liu, Yiheng Zhang, Xiaoming Zhao, Jibo Li, Maosen Xiao, Yuzhi Wang, Jing Li and Xiaopeng Shao
Photonics 2024, 11(9), 857; https://doi.org/10.3390/photonics11090857 - 11 Sep 2024
Viewed by 296
Abstract
Ultrafast lasers, characterized by femtosecond and picosecond pulse durations, have revolutionized material processing due to their high energy density and minimal thermal diffusion, and have played a transformative role in precision manufacturing. This review first traces the progression from early ruby lasers to [...] Read more.
Ultrafast lasers, characterized by femtosecond and picosecond pulse durations, have revolutionized material processing due to their high energy density and minimal thermal diffusion, and have played a transformative role in precision manufacturing. This review first traces the progression from early ruby lasers to modern titanium–sapphire lasers, highlighting breakthroughs like Kerr-lens mode-locking and chirped pulse amplification. It also examines the interaction mechanisms between ultrafast pulses and various materials, including metals, dielectrics, and semiconductors. Applications of ultrafast lasers in microstructure processing techniques are detailed, such as drilling, cutting, surface ablation, and nano welding, demonstrating the versatility and precision of the technology. Additionally, it covers femtosecond laser direct writing for optical waveguides and the significant advancements in imaging and precision measurement. This review concludes by discussing potential future advancements and industrial applications of ultrafast lasers. Full article
(This article belongs to the Special Issue New Perspectives in Ultrafast Intense Laser Science and Technology)
18 pages, 14328 KiB  
Article
Optimization of the Femtosecond Laser Machining Process for Single Crystal Diamond Using Response Surface Methodology
by Jiu Yin, Chuanbo Ming, Guangfu Zhang, Chang Chen, Qi Zeng and Yuan Li
Machines 2024, 12(9), 614; https://doi.org/10.3390/machines12090614 - 3 Sep 2024
Viewed by 335
Abstract
Femtosecond laser machining offers high precision and minimal thermal impact, making it a promising technique for processing hard and brittle materials like single-crystal diamonds (SCDs). In this study, the femtosecond laser machining process for SCD material was systematically optimized to improve both machining [...] Read more.
Femtosecond laser machining offers high precision and minimal thermal impact, making it a promising technique for processing hard and brittle materials like single-crystal diamonds (SCDs). In this study, the femtosecond laser machining process for SCD material was systematically optimized to improve both machining efficiency and quality. Initial single-factor experiments were conducted to explore the effects of key process parameters—laser power, scanning speed, and number of scans—on machining performance. Subsequently, response surface methodology (RSM)-based experiments designed using the Box–Behnken method were employed to comprehensively refine the process. A regression model was developed to analyze the data, and the interaction effects of the parameters were thoroughly evaluated. The validated model identified an optimal set of parameters, resulting in a significant improvement in machining performance. This research provides a comprehensive framework for optimizing femtosecond laser machining processes, offering valuable insights critical for the production of advanced lightweight components in industries such as aerospace, optical instruments, and high-performance electronics. Full article
(This article belongs to the Special Issue Design and Manufacturing for Lightweight Components and Structures)
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<p>Femtosecond laser machining experimental setup, (<b>a</b>) Schematic of the laser transmission path, (<b>b</b>) experimental platform.</p>
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<p>Microgroove structure and surface morphology of SCD observed under 3D digital microscope at different laser powers, (<b>a</b>) P = 6.5 W, (<b>b</b>) P = 11.1 W, (<b>c</b>) P = 16.5 W.</p>
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<p>Microgroove structure and surface morphology of SCD observed under SEM at different laser powers, (<b>a</b>) P = 6.5 W, (<b>b</b>) P = 11.1 W, (<b>c</b>) P = 16.5 W.</p>
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<p>Influence of laser power on (<b>a</b>) ablation width, (<b>b</b>) ablation depth and (<b>c</b>) <span class="html-italic">Ra</span>.</p>
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<p>Influence of scanning speed on (<b>a</b>) ablation width, (<b>b</b>) ablation depth and (<b>c</b>) Ra.</p>
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<p>Influence of number of scans on (<b>a</b>) ablation width, (<b>b</b>) ablation depth and (<b>c</b>) Ra.</p>
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<p>Interactive effect of laser power and scanning speed on ablation width, (<b>a</b>) contour plot, (<b>b</b>) response surface plot.</p>
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<p>Interactive effect of laser power and number of scans on ablation width, (<b>a</b>) contour plot, (<b>b</b>) response surface plot.</p>
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<p>Interactive effect of scanning speed and number of scans on ablation width, (<b>a</b>) contour plot, (<b>b</b>) response surface plot.</p>
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<p>Interactive effect of laser power and scanning speed on ablation depth, (<b>a</b>) contour plot, (<b>b</b>) response surface plot.</p>
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<p>Interactive effect of laser power and number of scans on ablation depth, (<b>a</b>) contour plot, (<b>b</b>) response surface plot.</p>
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<p>Interactive effect of scanning speed and number of scans on ablation depth, (<b>a</b>) contour plot, (<b>b</b>) response surface plot.</p>
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<p>Interactive effect of laser power and scanning speed on <span class="html-italic">Ra</span>, (<b>a</b>) contour plot, (<b>b</b>) response surface plot.</p>
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<p>Interactive effect of laser power and number of scans on Ra, (<b>a</b>) contour plot, (<b>b</b>) response surface plot.</p>
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<p>Interactive effect of scanning speed and number of scans on <span class="html-italic">Ra</span>, (<b>a</b>) contour plot, (<b>b</b>) response surface plot.</p>
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<p>Comparison of the predicted values and actual values, (<b>a</b>) ablation width, (<b>b</b>) ablation depth, (<b>c</b>) <span class="html-italic">Ra</span>.</p>
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13 pages, 8952 KiB  
Article
Superhydrophilic Surface Creation and Its Temporal Transition to Hydrophobicity on Copper via Femtosecond Laser Texturing
by Jeonghong Ha
Coatings 2024, 14(9), 1107; https://doi.org/10.3390/coatings14091107 - 2 Sep 2024
Viewed by 364
Abstract
We analyzed a process to fabricate a superhydrophilic surface on copper by forming various laser-induced periodic surface structures (LIPSS) using a Ti/sapphire femtosecond laser. For these structured surfaces, the correlation between the surface structure and the wetting characteristics was analyzed by scanning electron [...] Read more.
We analyzed a process to fabricate a superhydrophilic surface on copper by forming various laser-induced periodic surface structures (LIPSS) using a Ti/sapphire femtosecond laser. For these structured surfaces, the correlation between the surface structure and the wetting characteristics was analyzed by scanning electron microscopy, atomic force microscopy, and contact angle (CA) measurement. X-ray photoelectron spectroscopy (XPS) was also employed to analyze variation of the elemental composition of the surfaces. The laser treatment produced micro/nanostructures composed of ripples whose length and width are in microscale and nanoscale, respectively. At specific conditions, the CA of a water droplet was reduced to less than 1°. The superhydrophilcity is attributed to the effect of nanoholes and nanoclusters, which consist of copper (II) oxide and copper hydroxide, having a hydrophilic effect on LIPSS. However, the pristine superhydrophilic surface spontaneously became hydrophobic after being exposed to air at room temperature for about 10 days. According to XPS analysis, the surface’s transition to hydrophobic is attributed not only to the decomposition of Cu(OH)2 but also to the adsorption of oxygen molecules and/or airborne organic molecules containing carbon, which further influences the wettability. Full article
(This article belongs to the Section Laser Coatings)
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<p>Schematic overview of the experimental setup (M1, M2: mirrors).</p>
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<p>Schematic diagram of laser beam scanning parameters.</p>
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<p>SEM images of topographic variation on copper surface with various laser fluences and number of overlapped pulses on each spot.</p>
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<p>SEM images of dual-scale structures: (<b>a</b>) an overview; (<b>b</b>) a magnified image.</p>
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<p>Depth profiles of nanovalleys after (<b>a</b>) 150, (<b>b</b>) 400, and (<b>c</b>) 1000 laser pulses and those of nanoholes after (<b>d</b>) 150, (<b>e</b>) 400, and (<b>f</b>) 1000 laser pulses at <span class="html-italic">F</span> = 1.3 J/cm2.</p>
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<p>Variation of surface structures with increasing pulse number at <span class="html-italic">F</span> = 1.3 J/cm<sup>2</sup> and corresponding contact angle; (<b>a</b>) 150, (<b>b</b>) 400, (<b>c</b>) 700, and (<b>d</b>) 1000 pulse number.</p>
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<p>Contact angle on copper surface with varying laser fluence and pulse number.</p>
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<p>Quantified topographic variation of ripple at <span class="html-italic">F</span> = 1.3 J/cm<sup>2</sup>.</p>
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<p>High-resolution SEM images of topographic variation and the chemical composition obtained by EDS on nano ripples (LSFL) after (<b>a</b>) 150, (<b>b</b>) 400, and (<b>c</b>) 1000 laser pulses at <span class="html-italic">F</span> = 1.3 J/cm<sup>2</sup>.</p>
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<p>XPS spectra of a Cu 2p<sub>3/2</sub> region: (<b>a</b>) a virgin sample and (<b>b</b>) an aged sample.</p>
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<p>Variation of the contact angle of the laser-irradiated surface with the time exposed to air.</p>
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<p>XPS spectra of an O 1s region: (<b>a</b>) a virgin sample and (<b>b</b>) an aged sample.</p>
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<p>XPS spectra of a C 1s region of a virgin sample and an aged one.</p>
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20 pages, 4668 KiB  
Review
Microscopic Processing of Transparent Material with Nanosecond and Ultrafast Lasers
by Di Song, Jiaqi Wang, Xinyang Wu, Liancong Gao, Jiao Yang, Xiaoxu Liu, Qing Luo, Dongdong Wang and You Wang
Micromachines 2024, 15(9), 1101; https://doi.org/10.3390/mi15091101 - 30 Aug 2024
Viewed by 389
Abstract
Due to their excellent light transmission, heat resistance, corrosion resistance, high mechanical strength, and other characteristics, transparent materials have been widely used in emerging industries such as aviation, aerospace, microelectronics, interconnected communication, etc. Compared with the traditional mechanical processing and chemical processing of [...] Read more.
Due to their excellent light transmission, heat resistance, corrosion resistance, high mechanical strength, and other characteristics, transparent materials have been widely used in emerging industries such as aviation, aerospace, microelectronics, interconnected communication, etc. Compared with the traditional mechanical processing and chemical processing of transparent materials, laser processing, with such characteristics as a high peak power, high energy density, and non-contact processing, has a lot of obvious advantages in processing efficiency and accuracy. In this paper, some of the recent research advancements concerning the laser processing of transparent materials are introduced in detail. Firstly, the basic mechanism of the interaction between the laser and material is briefly summarized on the time scale. The differences in principle between nanosecond, picosecond, and femtosecond pulse laser processing are analyzed. Then, the main technical means of the nanosecond laser processing of transparent materials are summarized. Next, the main application directions of the ultrafast laser processing of transparent materials are discussed, including the preparation of optical waveguide devices, periodic structure devices, micropores, and microchannels. Finally, this paper summarizes the prospects for the future development of laser processing transparent materials. Full article
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<p>Process of interaction between femtosecond lasers and solid-state materials [<a href="#B21-micromachines-15-01101" class="html-bibr">21</a>].</p>
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<p>Schematic diagram of the interaction between the laser and the matter [<a href="#B22-micromachines-15-01101" class="html-bibr">22</a>].</p>
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<p>Schematic diagram of laser pulse processing. (<b>A</b>) Nanosecond wet etching [<a href="#B26-micromachines-15-01101" class="html-bibr">26</a>]. (<b>B</b>) Picosecond processing [<a href="#B27-micromachines-15-01101" class="html-bibr">27</a>]. (<b>C</b>) Spatially shaped femtosecond laser processing [<a href="#B28-micromachines-15-01101" class="html-bibr">28</a>].</p>
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<p>SEM image of grid patterns on the surface of silica glass [<a href="#B37-micromachines-15-01101" class="html-bibr">37</a>].</p>
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<p>Front and back morphologies of a through-hole [<a href="#B44-micromachines-15-01101" class="html-bibr">44</a>].</p>
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<p>Hybrid Bottom-up Multilayer Increment and the Spiral Line method. (<b>A</b>) Schematic illustration of the laser drilling and cutting. (<b>B</b>) Experimental setup [<a href="#B46-micromachines-15-01101" class="html-bibr">46</a>].</p>
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<p>Schematic illustration of the optical waveguides. (<b>A</b>)Type I waveguide. (<b>B</b>) Type II waveguide [<a href="#B59-micromachines-15-01101" class="html-bibr">59</a>].</p>
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<p>Schematic of fabrication of a hybrid-integrated beam splitter in LiTaO<sub>3</sub> crystal by the fs-laser direct writing [<a href="#B67-micromachines-15-01101" class="html-bibr">67</a>].</p>
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<p>Schematic illustration of an experimental set up for a 1 × 5 beam splitter using a continuous-wave laser (central wavelength of 632.8 nm) [<a href="#B67-micromachines-15-01101" class="html-bibr">67</a>].</p>
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<p>Schematic illustration of processing. (<b>A</b>) Schematic illustration of the laser scribing experimental setup. (<b>B</b>) Direction of the etch [<a href="#B75-micromachines-15-01101" class="html-bibr">75</a>].</p>
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<p>Schematic illustration of the scanning path for the helix-loop-cut approach [<a href="#B76-micromachines-15-01101" class="html-bibr">76</a>].</p>
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<p>Processing schematic illustration of the water infiltration method [<a href="#B76-micromachines-15-01101" class="html-bibr">76</a>].</p>
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9 pages, 3183 KiB  
Article
The Orbital-Resolved Dissociative Ionization of the Molecular IBr in a Near-Infrared Femtosecond Laser Field
by Botong Liu and Zhipeng Li
Photonics 2024, 11(9), 810; https://doi.org/10.3390/photonics11090810 - 29 Aug 2024
Viewed by 347
Abstract
The dissociative ionization of molecular IBr in a near-infrared femtosecond laser field was investigated through the utilization of the DC-sliced ion imaging technique. Two pathways, denoted as (1, 0)a and (1, 0)b, were observed in the dissociation process of IBr [...] Read more.
The dissociative ionization of molecular IBr in a near-infrared femtosecond laser field was investigated through the utilization of the DC-sliced ion imaging technique. Two pathways, denoted as (1, 0)a and (1, 0)b, were observed in the dissociation process of IBr+ into an I+ ion and Br atom. The distinct angular distributions observed in these pathways were found to be a result of the removal of electrons from different molecular orbitals. Specifically, in pathway (1, 0)a, the electron was stripped from HOMO and HOMO-1, while in pathway (1, 0)b, the electron was removed from HOMO-2. The ultrafast dynamical processes of molecules influenced by intense femtosecond laser fields were investigated through an analysis of the angular distribution characteristics of fragment ions in conjunction with the spatial properties of molecular orbitals. Full article
(This article belongs to the Special Issue New Perspectives in Ultrafast Intense Laser Science and Technology)
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<p>The pseudo-color DC-sliced images and velocity distributions of I<sup>+</sup> and Br<sup>+</sup> in the laser intensity of 3.0 × 10<sup>14</sup> W/cm<sup>2</sup>, respectively. The labels represent the KER values (eV) of the fragment ions, the red solid lines (<b><span style="color:red">—</span></b>) represent the simulated distributions, the black hollow circles (<b>○</b>) represent the experimental data, and the green dashed lines (<b><span style="color:#00B050">---</span></b>) represent the single Gaussian function.</p>
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<p>The angular distribution of fragment ions (<b>a</b>) I<sup>+</sup> and (<b>b</b>) Br<sup>+</sup> in the laser intensity of 3.0 × 10<sup>14</sup> W/cm<sup>2</sup>. The double arrows represent laser polarization.</p>
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<p>The calculated frontier molecular orbitals of IBr. The red arrows represent the different electron spin.</p>
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<p>Calculated PECs of ground and several excited states of IBr and IBr<sup>+</sup> ions. The arrows represent the vertical excitation in the equilibrium internuclear distance (R<sub>e</sub>) of neutral IBr molecule.</p>
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<p>NBO charge distribution of IBr<sup>+</sup> ions and the charge assignment of the corresponding dissociation channels.</p>
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14 pages, 3615 KiB  
Article
Properties of Zirconia, Lithium Disilicate Glass Ceramics, and VITA ENAMIC® Hybrid Ceramic Dental Materials Following Ultra-Short Femtosecond (30 fs) Laser Irradiation
by Victor L. Lagunov, Bakhtiar Ali, Laurence J. Walsh, Andrew B. Cameron, Igor V. Litvinyuk, Maksym Rybachuk and Roy George
Appl. Sci. 2024, 14(17), 7641; https://doi.org/10.3390/app14177641 - 29 Aug 2024
Viewed by 436
Abstract
This study investigated the dose-dependent changes in the chemical composition of three dental ceramic materials—zirconia, lithium disilicate (LD), and VITA ENAMIC® hybrid composite (VITA En)—following irradiation with an ultra-short femtosecond (fs) laser (800 nm, 30 fs, 1 kHz) [...] Read more.
This study investigated the dose-dependent changes in the chemical composition of three dental ceramic materials—zirconia, lithium disilicate (LD), and VITA ENAMIC® hybrid composite (VITA En)—following irradiation with an ultra-short femtosecond (fs) laser (800 nm, 30 fs, 1 kHz) in an ambient air environment using average laser power (76 mW) and scanning speeds (50, 100, and 200 mm/s), simulating dental treatment processes. The chemical composition of the ablated regions was analyzed using energy dispersive spectroscopy. All irradiated samples showed increased carbon content (by up to 42%) and reduced oxygen (by up to 33%). The observed increase in C content is likely attributed to a combination of surface reactions, adsorption of carbon from the ambient environment, and carbon deposition from the laser-induced plasma, all facilitated by the high-energy conditions created by fs-laser pulses. Scanning electron microscopy revealed ablation with progressive controlled melting and recrystallization, with an absence of pile-up features typically associated with significant thermal damage. These findings demonstrate that ultra-short fs-laser irradiation induces highly controlled, dose-dependent changes in the chemical composition and surface morphology of dental ceramic materials. Full article
(This article belongs to the Special Issue New Advances in Laser Dental Science and Biophotonics)
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<p>Chemical composition of zirconia for selected key elements. (<b>A</b>) Prior to <span class="html-italic">fs</span>-laser irradiation, and (<b>B</b>) following laser irradiation using a 20 J/cm<sup>2</sup> fluence and 440 pulses.</p>
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<p>Chemical composition of lithium disilicate glass ceramic for selected key elements. (<b>A</b>) Prior to <span class="html-italic">fs</span>-laser irradiation, and (<b>B</b>) following laser irradiation using a 20 J/cm<sup>2</sup> fluence and 440 pulses.</p>
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<p>Chemical composition of VITA ENAMIC® hybrid ceramic for selected key elements. (<b>A</b>) Prior to <span class="html-italic">fs</span>-laser irradiation, and (<b>B</b>) following laser irradiation using a 20 J/cm<sup>2</sup> fluence and 440 pulses.</p>
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<p>The effect of <span class="html-italic">fs</span>-laser pulse number/scanning speed on wt.% constituent fractions of carbon, oxygen, aluminum and silicon in zirconia, lithium disilicate glass ceramic, and VITA ENAMIC<sup>®</sup> hybrid ceramic dental materials following ultra-short femtosecond (30 <span class="html-italic">fs</span>) laser irradiation.</p>
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<p>SEM micrographs of (<b>a</b>) zirconia, (<b>b</b>) lithium disilicate glass ceramic, and (<b>c</b>) VITA ENAMIC<sup>®</sup> hybrid ceramic composite material processed using <span class="html-italic">fs</span>-laser irradiation using a 20 J/cm<sup>2</sup> fluence at 440 pulses.</p>
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14 pages, 2519 KiB  
Review
Developments of Waveguide Lasers by Femtosecond Laser Direct–Writing Technology
by Yang Zhang, Boyan Yu, Zihao Zhang, Xinghao Duan and Junli Wang
Photonics 2024, 11(9), 803; https://doi.org/10.3390/photonics11090803 - 28 Aug 2024
Viewed by 479
Abstract
Waveguide lasers have the advantages of miniature and compact structure and have broad application prospects in photonic integration and on–chip laboratories. The development of femtosecond laser direct–writing technology makes the processing of transparent materials more flexible and controllable. This paper mainly introduces a [...] Read more.
Waveguide lasers have the advantages of miniature and compact structure and have broad application prospects in photonic integration and on–chip laboratories. The development of femtosecond laser direct–writing technology makes the processing of transparent materials more flexible and controllable. This paper mainly introduces a waveguide laser based on femtosecond laser direct–writing technology. Firstly, the applications of femtosecond laser direct–writing technology in an optical waveguide are introduced, including the principles of femtosecond laser direct–writing technology, common optical wave scanning methods, and types of optical waveguides. After that, we summarize the development of a waveguide continuous–wave laser, a Q–switched laser and a mode–locked laser from visible to mid–infrared wavebands and analyze some new representative work. Finally, we explain the difficulty of compensating for dispersion in pulse waveguide lasers and summarize some new ideas that have been proposed to solve the problem. Full article
(This article belongs to the Special Issue New Perspectives in Ultrafast Intense Laser Science and Technology)
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<p>Ion exchange technology diagram: (<b>a</b>) thermal ion exchange, (<b>b</b>) field-assisted ion exchange.</p>
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<p>The methods to achieve relative displacement between the laser focus and the sample: (<b>a</b>) sample fixed–laser focus moving method [<a href="#B18-photonics-11-00803" class="html-bibr">18</a>], (<b>b</b>) laser focus fixed–sample moving method [<a href="#B18-photonics-11-00803" class="html-bibr">18</a>]. Waveguide trace writing method: (<b>c</b>) longitudinal scanning method, (<b>d</b>) transverse scanning method.</p>
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<p>Optical microscope pictures of the different waveguide types fabricated in Pr:LLF: (<b>a</b>) circular cladding, (<b>b</b>) ear–like cladding, (<b>c</b>) hexagonal cladding, (<b>d</b>) stress–induced dual–line, (<b>e</b>) stress–induced dual–line with rhombic cladding, (<b>f</b>) single line [<a href="#B58-photonics-11-00803" class="html-bibr">58</a>].</p>
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<p>(<b>a</b>) Experimental setup and (<b>b</b>) output pulse characteristics of Nd:GdVO<sub>4</sub> crystal CW waveguide laser [<a href="#B48-photonics-11-00803" class="html-bibr">48</a>]. WP1 and WP2: waveplate; GTP: Glan Taylor prism; MO: microscope objective lens (20×); CL: convex lens; M1 and M2: laser cavity mirrors adhered to the two end facets of the sample; DB: dichroic beamsplitter; λ<sub>p</sub> and λ<sub>L</sub>: pump and generated laser beam; OC: output coupler.</p>
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<p>The common deposition methods of SA in waveguide lasers: (<b>a</b>) evanescent and (<b>b</b>) direct–field interaction with SA.</p>
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<p>The experimental setup for the Ti:sapphire channel waveguides soliton mode–locking [<a href="#B26-photonics-11-00803" class="html-bibr">26</a>]. DPSS laser: diode–pumped solid–state laser. The green arrow represents the propagation direction of the pump light, while the red arrow represents the propagation direction of the signal light.</p>
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<p>The experimental setup of a Yb:YAG crystal CWML waveguide laser from [<a href="#B65-photonics-11-00803" class="html-bibr">65</a>]. OPSL: optically pumped semiconductor laser; DM: dichroic beamsplitter; L, L1 and L2: lens; OC: output coupler.</p>
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20 pages, 17980 KiB  
Article
Integrated Optical Waveguide Electric Field Sensors Based on Bismuth Germanate
by Jin Wang, Yilin Song, Xuefei Song, Wei Zhang, Junqi Yang and Zhi Xuan
Sensors 2024, 24(17), 5570; https://doi.org/10.3390/s24175570 - 28 Aug 2024
Viewed by 344
Abstract
Bismuth germanate (Bi4Ge3O12, BGO) is a widely used optical sensing material with a high electro-optic coefficient, ideal for optical electric field sensors. Achieving high precision in electric field sensing requires fabricating optical waveguides on BGO. Traditional waveguide [...] Read more.
Bismuth germanate (Bi4Ge3O12, BGO) is a widely used optical sensing material with a high electro-optic coefficient, ideal for optical electric field sensors. Achieving high precision in electric field sensing requires fabricating optical waveguides on BGO. Traditional waveguide writing methods face challenges with this material. This study explores using femtosecond laser writing technology for preparing waveguides on BGO, leveraging ultrafast optical fields for superior material modification. Our experimental analysis shows that a cladding-type waveguide, written with a femtosecond laser at 200 kHz repetition frequency and 10.15 mW average power (pulse energy of 50.8 nJ), exhibits excellent light-guiding characteristics. Simulations of near-field optical intensity distribution and refractive index variations using the refractive index reconstruction method demonstrate that the refractive index modulation ensures single-mode transmission and effectively confines light to the core layer. In situ refractive index characterization confirms the feasibility of fabricating a waveguide with a refractive index reduction on BGO. The resulting waveguide has a loss per unit length of approximately 1.2 dB/cm, marking a successful fabrication. Additionally, we design an antenna electrode, analyze sensor performance indicators, and integrate a preparation process plan for the antenna electrode. This achievement establishes a solid experimental foundation for future studies on BGO crystal waveguides in electric field measurement applications. Full article
(This article belongs to the Special Issue Recent Advances of Optoelectronic Devices and Semiconductor Sensors)
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<p>Schematic diagram of the change in refractive index ellipsoid of a BGO crystal.</p>
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<p>Integrated optical field sensor system.</p>
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<p>Reflective MZI structure.</p>
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<p>Schematic diagram of the experimental platform for femtosecond laser inscription.</p>
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<p>Simulation of actual waveguide end face topography.</p>
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<p>The reconstructed modal field distribution.</p>
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<p>The near-field intensity distribution of the cladding-type waveguide.</p>
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<p>Results of refractive index characterization of the writing traces. (<b>a</b>) End face and (<b>b</b>) top-down view.</p>
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<p>The structure of the conical dipole antenna.</p>
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<p>Side view of waveguide and electrode combination.</p>
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<p>Antenna electrode process program flow.</p>
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<p>Electro-optic effect measurement. (<b>a</b>) Electric field measuring platform (complete device); (<b>b</b>) electrode contacts bonding; (<b>c</b>) electrode contacts bonding (microscopic image).</p>
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<p>The half-wavelength electric field <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>E</mi> </mrow> <mrow> <mi>π</mi> </mrow> </msub> </mrow> </semantics></math> and the electric field gain value at the probe position <math display="inline"><semantics> <mrow> <mi>ξ</mi> </mrow> </semantics></math> varying with the antenna width <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>W</mi> </mrow> <mrow> <mi>a</mi> </mrow> </msub> </mrow> </semantics></math> and the antenna height <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>H</mi> </mrow> <mrow> <mi>a</mi> </mrow> </msub> <mo>.</mo> </mrow> </semantics></math> (<b>a</b>) Relationship between the half-wavelength electric field and the electric field gain and the antenna width. (<b>b</b>) Relationship between the half-wavelength electric field and the electric field gain and the antenna height.</p>
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<p>The half-wavelength electric field <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>E</mi> </mrow> <mrow> <mi>π</mi> </mrow> </msub> </mrow> </semantics></math> and the electric field gain value at the probe position <math display="inline"><semantics> <mrow> <mi>ξ</mi> </mrow> </semantics></math> varying with the antenna length <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>L</mi> </mrow> <mrow> <mi>e</mi> <mi>l</mi> </mrow> </msub> </mrow> </semantics></math> when <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>H</mi> </mrow> <mrow> <mi>a</mi> </mrow> </msub> <mo>=</mo> </mrow> </semantics></math>1 mm and 3 mm.</p>
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<p>The half-wavelength electric field <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>E</mi> </mrow> <mrow> <mi>π</mi> </mrow> </msub> </mrow> </semantics></math> varying with the electrode width <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>W</mi> </mrow> <mrow> <mi>e</mi> <mi>l</mi> </mrow> </msub> </mrow> </semantics></math> and the electrode spacing <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>G</mi> </mrow> <mrow> <mi>e</mi> <mi>l</mi> </mrow> </msub> </mrow> </semantics></math>. (<b>a</b>) Relationship between the half-wavelength electric field and the electric field gain and the antenna width when <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>H</mi> </mrow> <mrow> <mi>a</mi> </mrow> </msub> <mo>=</mo> </mrow> </semantics></math>1 mm, 2 mm, and 3 mm. (<b>b</b>) Relationship between the half-wavelength electric field and the electrode spacing.</p>
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28 pages, 7926 KiB  
Review
Innovative Strategies in X-ray Crystallography for Exploring Structural Dynamics and Reaction Mechanisms in Metabolic Disorders
by Alice Grieco, Isabel Quereda-Moraleda and Jose Manuel Martin-Garcia
J. Pers. Med. 2024, 14(9), 909; https://doi.org/10.3390/jpm14090909 - 27 Aug 2024
Viewed by 450
Abstract
Enzymes are crucial in metabolic processes, and their dysfunction can lead to severe metabolic disorders. Structural biology, particularly X-ray crystallography, has advanced our understanding of these diseases by providing 3D structures of pathological enzymes. However, traditional X-ray crystallography faces limitations, such as difficulties [...] Read more.
Enzymes are crucial in metabolic processes, and their dysfunction can lead to severe metabolic disorders. Structural biology, particularly X-ray crystallography, has advanced our understanding of these diseases by providing 3D structures of pathological enzymes. However, traditional X-ray crystallography faces limitations, such as difficulties in obtaining suitable protein crystals and studying protein dynamics. X-ray free-electron lasers (XFELs) have revolutionized this field with their bright and brief X-ray pulses, providing high-resolution structures of radiation-sensitive and hard-to-crystallize proteins. XFELs also enable the study of protein dynamics through room temperature structures and time-resolved serial femtosecond crystallography, offering comprehensive insights into the molecular mechanisms of metabolic diseases. Understanding these dynamics is vital for developing effective therapies. This review highlights the contributions of protein dynamics studies using XFELs and synchrotrons to metabolic disorder research and their application in designing better therapies. It also discusses G protein-coupled receptors (GPCRs), which, though not enzymes, play key roles in regulating physiological systems and are implicated in many metabolic disorders. Full article
(This article belongs to the Section Mechanisms of Diseases)
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<p>Schematic representation of a catalytic cycle (left) of a model enzyme (magenta) and the associated conformational changes represented in the free-energy landscape (right) at the different steps: free enzyme (E), enzyme-substrate (ES), and enzyme-product (EP). The energy distribution is shown by the coloring pattern: blue defines the conformational space with minimum energy (stable state), while brown defines a conformational space with maximum energy (unstable state). Transient local energy states are defined by intermediate color patterns. The substrate and the product of the reaction are shown as balls represented in purple and yellow, respectively.</p>
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<p>Concept and experimental setup of a mix-and-inject serial crystallography (MISC) experiment. (<b>A</b>) Enzyme microcrystals are mixed with substrate (here, an NADH molecule). The substrate diffuses into the crystals and starts the enzymatic reaction to be probed by X-ray pulses at various mixing delays. (<b>B</b>) Upper row, steady state, no time resolution: simplified catalytic mechanism introduced by Michaelis-Menten. Second row, transient-state kinetics with time resolution: substrate binds non-covalently (nc) to the enzyme. The reaction proceeds through intermediates, which may (or may not) consist of a covalently (cov) bound substrate. The substrate is catalytically modified to a product with several enzyme-product intermediates. A rate-determining step parametrized by a rate coefficient k<sub>rd</sub> determines k<sub>cat</sub>. Arrows depict chemical reactions characterized by rate coefficients. (<b>C</b>) In an MISC experiment, a slurry of enzyme microcrystals is rapidly mixed with a substrate solution in a continuous flow-mixing device, initiating the reaction. As the reaction progresses, the crystals flow through the X-ray interaction region in a freestanding microfluidic jet, where they are probed by a pulsed X-ray source. By varying the distance between the mixer and the interaction region, different time points of the reaction can be measured.</p>
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<p>Schematic of the catalytic and inhibition mechanisms of the BlaC enzyme. (<b>A</b>) Inactivation mechanism of the antibiotic ceftriaxone (CEF) by the BlaC enzyme. All the states shown in the mechanism were captured by TR-SFX. The formation of the complex E-CEF occurs just 30 ms upon reaction initiation. As shown in the middle panel, the nucleophile attack, opening of the beta-lactam ring with the subsequent covalent bond formation between the Ser70 and a shortened specie (E-CFO*), and the release of the leaving group occur at time points between 100 and 500 ms. (<b>B</b>) Inhibition mechanism of BlaC by the inhibitor sulbactam (SUB). The formation of the complex E-I occurs 30 ms upon mixing. The nucleophilic attack by Ser70 opens the lactam ring of SUB, leading to the formation of acyl-enzyme intermediate (TEN) in a <span class="html-italic">trans</span> configuration 240 ms later.</p>
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<p>Structure and mechanism of NQO1. (<b>A</b>) Surface representation of NQO1’s homodimer bound to NADH. The panel below shows a closer view of the catalytic site. (<b>B</b>) Schematic of the plausible mechanism for the reductive and oxidative half-reactions. Due to the cooperativity described for human NQO1, the reduction and the oxidation of the enzyme occur in a sequential manner and the oxidative half-reaction does not take place until the two catalytic sites of the enzyme are fully reduced.</p>
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<p>Crystal structures of the GAC and PNPOx enzymes. (<b>A</b>) Surface and cartoon representation of the homodimer of the GAC enzyme (upper panel, left) and the GAC tetramer (upper panel, right). Residues at the catalytic site are shown as sticks. A closer view of the catalytic site (black boxed in the upper panel) is shown in the lower panel. (<b>B</b>) Surface and cartoon representation of the homodimer of the PNPOx enzyme (upper panel). Residues and the PLP at the catalytic site are shown as sticks. A closer view of the catalytic site (black boxed in the upper panel) is shown in the lower panel.</p>
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<p>Seven-step mechanism of CYP enzymes. Initially, the heme iron is coordinated to a water molecule and is in a low-spin ferric resting state. (Step 1) The substrate enters the active site, displacing the water molecule and converting the heme iron to a high-spin FeIII state. (Step 2) This change increases the redox potential, allowing electron transfer from the reducing partner to form the ferrous FeII complex. (Step 3) The ferrous FeII complex binds O<sub>2</sub>, forming the oxyferrous complex. (Step 4) The oxyferrous complex is reduced to the peroxo complex. (Step 5) Water molecules return, forming a channel that protonates the peroxo complex to give Compound 0 (Cpd 0). (Step 6) Cpd 0 accepts an extra proton, releasing a water molecule and forming Compound I (Cpd I). (Step 7) Cpd I abstracts a hydrogen from the substrate, leading to its oxidation. The product leaves the pocket, and a water molecule re-coordinates with the heme iron, returning the enzyme to its initial resting state. All the steps are highlighted with black numbers. The enzyme open, semi-open, and closed conformations at each stage are denoted by a blue shape. The substrate, hydrogens, electrons, oxygen, and water are denoted by red, green, orange, violet, and cyan circles, respectively.</p>
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<p>Structure of AGT and scheme of the transamination reaction catalyzed by AGT. (<b>A</b>) Upper panel shows the structure of the AGT homodimer, with the residues at the catalytic site shown as sticks. Lower panel shows the interactions that stabilize the Schiff base at the catalytic site. (<b>B</b>) In a preliminary step, a conserved Asp residue (Asp183) protonates the pyridine nitrogen N1 of PLP. The first half-reaction (in purple) occurs through steps 1–3: (1) The transaldimination-action with the amino acid substrate only occurs when the internal aldimine is protonated at Nε. (2) The 1,3-prototropic shift represents the rate-limiting step of the first half-reaction. The amino group of the Lys residue acts as a base catalyst extracting the Cα hydrogen. (3) Hydrolysis of the resulting ketimine yields pyridoxamine phosphate (PMP) and the leaving α-keto acid. The second half-reaction occurs through the same steps (4–6) as the first half-reaction in inverse order.</p>
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13 pages, 2507 KiB  
Article
Controllable Preparation of Fused Silica Micro Lens Array through Femtosecond Laser Penetration-Induced Modification Assisted Wet Etching
by Kaijie Cheng, Ji Wang, Guolong Wang, Kun Yang and Wenwu Zhang
Materials 2024, 17(17), 4231; https://doi.org/10.3390/ma17174231 - 27 Aug 2024
Viewed by 319
Abstract
As an integrable micro-optical device, micro lens arrays (MLAs) have significant applications in modern optical imaging, new energy technology, and advanced displays. In order to reduce the impact of laser modification on wet etching, we propose a technique of femtosecond laser penetration-induced modification-assisted [...] Read more.
As an integrable micro-optical device, micro lens arrays (MLAs) have significant applications in modern optical imaging, new energy technology, and advanced displays. In order to reduce the impact of laser modification on wet etching, we propose a technique of femtosecond laser penetration-induced modification-assisted wet etching (FLIPM-WE), which avoids the influence of previous modification layers on subsequent laser pulses and effectively improves the controllability of lens array preparation. We conducted a detailed study on the effects of the laser single pulse energy, pulse number, and hydrofluoric acid etching duration on the morphology of micro lenses and obtained the optimal process parameters. Ultimately, two types of fused silica micro lens arrays with different focal lengths but the same numerical aperture (NA = 0.458) were fabricated using the FLPIM-WE technology. Both arrays exhibited excellent geometric consistency and surface quality (Ra~30 nm). Moreover, they achieved clear imaging at various magnifications with an adjustment range of 1.3×~3.0×. This provides potential technical support for special micro-optical systems. Full article
(This article belongs to the Special Issue Cutting Processes for Materials in Manufacturing)
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<p>Experimental setup and method. (<b>a</b>) Steps in the fabrication of micro lens array. Step 1: using femtosecond laser-induced modification, step 2: place the modified sample in HF acid solution for ultrasonic-assisted wet etching, step 3: surface cleaning of MLA, the illustration pointed to by the black arrow shows a vertical-sectional schematic of the morphology of the microlens array; (<b>b</b>) schematic diagram of device femtosecond laser-induced modification of fused silica; (<b>c</b>) comparison between penetration FLPIM method and traditional top-down modification method.</p>
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<p>Influence of laser parameters on micro modified hole dimensions. (<b>a</b>) Variation in the depth of the modified holes; (<b>b</b>) variation in major axis length of the modified holes; (<b>c</b>) variation in minor axis length of the modified holes; (<b>d</b>) variation in depth-to-diameter ratio of the modified holes.</p>
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<p>Morphological changes of micro lens under different HF solution etching times. (<b>a</b>) 0 min; (<b>b</b>) 60 min; (<b>c</b>) 120 min; (<b>d</b>) 150 min, scale bar in <a href="#materials-17-04231-f003" class="html-fig">Figure 3</a>a,b is 10 μm; (<b>e</b>) variation in micro lens contour profiles with the etching time.</p>
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<p>Controlled fabrication of micro lens profiles. (<b>a</b>) Profile curves of micro lens fabricated under different pulse numbers; (<b>b</b>) depth and diameter of the micro lens fabricated under different pulse numbers. The black arrow represents the depth curve of the left coordinate axis, and the red arrow represents the diameter curve of the right coordinate axis; (<b>c</b>–<b>g</b>) three-dimensional profiles of micro lens fabricated under different pulse numbers: (<b>c</b>) 20 pulses; (<b>d</b>) 40 pulses; (<b>e</b>) 60 pulses; (<b>f</b>) 80 pulses; (<b>g</b>) 100 pulses.</p>
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<p>MLA schematics. (<b>a</b>) Micro lens array fabricated with a single pulse energy of 1.39 μJ and 60 pulses, scale bar: 20 μm; (<b>b</b>) micro lens array fabricated with a single pulse energy of 1.89 μJ and 80 pulses, scale bar: 20 μm; (<b>c</b>) profiles of the two micro lens arrays. The red curve represents the profile measurement result of the micro lenses within the red box in <a href="#materials-17-04231-f005" class="html-fig">Figure 5</a>a. The gray curve represents the profiles measurement result of the micro lenses within the gray box in <a href="#materials-17-04231-f005" class="html-fig">Figure 5</a>b; (<b>d</b>,<b>e</b>) three-dimensional views of individual micro lens structures from the two micro lens arrays.</p>
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<p>Imaging performance testing of the two MLAs shown in <a href="#materials-17-04231-f005" class="html-fig">Figure 5</a>a,b. (<b>a</b>) Optical path diagram of the imaging analysis system. The system is equipped with optional imaging objectives; (<b>b</b>,<b>c</b>) place the MLA shown in <a href="#materials-17-04231-f005" class="html-fig">Figure 5</a>a,b in the imaging analysis system, respectively. The CCD imaging results without the mask using an imaging objective of 20×. The scales are 20 μm; (<b>d1</b>–<b>d3</b>) CCD imaging results of the MLA shown in <a href="#materials-17-04231-f005" class="html-fig">Figure 5</a>a after inserting the mask N. The objective lenses used are 20×, 20×, and 50× in sequence. Among them, <a href="#materials-17-04231-f006" class="html-fig">Figure 6</a>(<b>d3</b>) is the imaging pattern obtained by moving the mask upwards based on <a href="#materials-17-04231-f006" class="html-fig">Figure 6</a>(<b>d2</b>). (<b>e1</b>–<b>e3</b>) CCD imaging results under the MLA shown in <a href="#materials-17-04231-f005" class="html-fig">Figure 5</a>b using the same testing method, corresponding to <a href="#materials-17-04231-f006" class="html-fig">Figure 6</a>(<b>d1</b>)–(<b>d3</b>). The scales in <a href="#materials-17-04231-f006" class="html-fig">Figure 6</a>(<b>d1</b>,<b>e1</b>) are 20 μm. The scales in <a href="#materials-17-04231-f006" class="html-fig">Figure 6</a>(<b>d2</b>,<b>d3</b>) and <a href="#materials-17-04231-f006" class="html-fig">Figure 6</a>(<b>e2</b>,<b>e3</b>) are 20 μm.</p>
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14 pages, 5029 KiB  
Article
Characterization of Micro-Holes Drilled Using a UV Femtosecond Laser in Modified Polyimide Flexible Circuit Boards
by Lijuan Zheng, Shuzhan Lin, Huijuan Lu, Bing Huang, Yu Liu, Jun Wang, Xin Wei, Jun Wang and Chengyong Wang
Micromachines 2024, 15(9), 1078; https://doi.org/10.3390/mi15091078 - 26 Aug 2024
Viewed by 376
Abstract
Modified polyimide (MPI) flexible printed circuits (FPCs) are used as chip carrier boards. The quality of the FPC directly affects the reliability of the integrated circuit. Furthermore, micro-holes are critical components of FPCs. In this study, an ultraviolet (UV) femtosecond laser is used [...] Read more.
Modified polyimide (MPI) flexible printed circuits (FPCs) are used as chip carrier boards. The quality of the FPC directly affects the reliability of the integrated circuit. Furthermore, micro-holes are critical components of FPCs. In this study, an ultraviolet (UV) femtosecond laser is used to drill micro-holes in double-layer flexible circuit boards with MPI as the substrate. The morphology of the micro-hole wall in the copper foil and MPI layer is observed, and the effects of the laser processing parameters on the diameter and depth of the micro-holes are analyzed. The drilling process and mechanism of micro-holes obtained using a UV femtosecond laser in MPI FPCs are discussed. The results show that the morphology of femtosecond laser-machined copper is closely related to the laser energy, and a periodic structure is observed during the machining process. Copper, MPI, and copper oxides are the most common molten deposits in micro-holes during drilling. The depth of the micro-holes increases with an increase in the energy of a single pulse, scanning time, and scanning overlap rate of the laser beam. However, the diameter exhibits no discernible alteration. The material removal rate increased significantly when laser processing was applied to the MPI resin layer. Full article
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<p>Experimental setup. (<b>a</b>) Processing system for the UV femtosecond laser; (<b>b</b>) modified polyimide resin substrate electron microscopy; (<b>c</b>) diagrammatic representation of the FPC cross section; (<b>d</b>) diagrammatic representation of micro-holes depth measurement; (<b>e</b>) diagrammatic representation of micro-hole diameter measurement; (<b>f</b>) diagrammatic representation of micro-hole drilling.</p>
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<p>SEM analysis of micro-hole formation in FPCs processed using a femtosecond laser (E = 4 μJ, PO = 98.33%).</p>
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<p>SEM analysis of the cross-sectional morphology of FPC micro-holes (E = 3.4 μJ, PO = 98.33%, Ns = 23).</p>
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<p>SEM and EDS analysis of femtosecond laser-machined micro-holes in FPCs (E = 3.4 μJ, PO = 98.33%, (<b>a</b>) Ns = 3; (<b>b</b>) Ns = 7; (<b>c</b>) Ns = 11).</p>
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<p>Schematic of removing micro-hole material from FPC using femtosecond laser processing. (<b>a</b>) Laser processing to the surface Cu (<b>b</b>) the surface Cu is removed (<b>c</b>) laser processing to the MPI layer (<b>d</b>) the MPI layer is removed (<b>e</b>) Laser processing to the bottom Cu (<b>f</b>) form through holes.</p>
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<p>Effects of laser drilling parameters on the diameter of micro-holes. (<b>a</b>) Variations in diameter with processing times at different pulse overlap rates (E = 8 μJ); (<b>b</b>) variations in diameter with single-pulse energy at different pulse overlap rates (Ns = six times).</p>
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<p>Effects of laser drilling parameters on the depth of micro-holes. (<b>a</b>) Depth variation with processing time at different pulse overlap rates (E = 8 μJ); (<b>b</b>) depth variation with single-pulse energy at different pulse overlap rates (Ns = six times).</p>
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<p>Effects of laser drilling parameters on the removal rate of micro-holes. (<b>a</b>) Material removal rate variation with processing time at different pulse overlap rates (E = 8 μJ); (<b>b</b>) material removal rate variation with single-pulse energy at different pulse overlap rates (Ns = six times).</p>
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16 pages, 4697 KiB  
Article
Study on the Thermal Radiation Characteristics of Tungsten Surface Grating Structures Prepared by Femtosecond Laser Direct Writing
by Ruxue Guo, Ping Zhou, Wanyun Zhang, Haiying Song and Shibing Liu
Coatings 2024, 14(8), 1045; https://doi.org/10.3390/coatings14081045 - 16 Aug 2024
Viewed by 442
Abstract
In this paper, using laser direct writing technology, a femtosecond laser was used to process a periodic grating structure on a 99.99% tungsten target. The specific parameters of the laser are as follows: a center wavelength of 800 nm, pulse width of 35 [...] Read more.
In this paper, using laser direct writing technology, a femtosecond laser was used to process a periodic grating structure on a 99.99% tungsten target. The specific parameters of the laser are as follows: a center wavelength of 800 nm, pulse width of 35 fs, repetition rate of 1 kHz, and maximum single pulse energy of 3.5 mJ. The surface morphology of the samples was characterized and analyzed using a scanning electron microscope (SEM, Coxem, Republic of Korea) and atomic force microscope (AFM, Being Nano-Instruments, China). The thermal radiation infrared spectrum of the tungsten target with grating structures was measured using a Fourier transform infrared spectrometer (Vertex 70, Bruker, Germany). The results show that as the laser fluence increases, the depth of the groove, the width of the nanostructure region, and the width of the direct writing etching region all increase. The peak thermal radiation enhancement appears around the wavenumber of 900 cm−1 when the laser fluence is sufficient. Additionally, its intensity initially increases and then decreases as the laser fluence increases. If the grating period is too large, the impact on thermal radiation is not clear. The heating temperature significantly affects the intensity of thermal radiation but does not have a noticeable effect on the position of thermal radiation peaks. Moreover, the relative weighting of different wavenumbers changes as the temperature increases. Full article
(This article belongs to the Special Issue Laser-Assisted Coating Techniques and Surface Modifications)
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<p>The equipment for measuring the infrared thermal radiation spectrum.</p>
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<p>The schematic diagram of an electromagnetic wave incident on the surface of the grating structure.</p>
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<p>(<b>a</b>) Energy distribution of femtosecond laser; (<b>b</b>) SEM image with a laser fluence of 5.73 J/cm<sup>2</sup> and scanning speed of 1 mm/s.</p>
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<p>(<b>a</b>) The variation of the depth of the groove under varying laser fluence; (<b>b</b>) AFM image with a laser fluence of 3.18 J/cm<sup>2</sup> and scanning speed of 1 mm/s (the red arrow corresponds to the start of the scanning range and the green arrow to the end).</p>
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<p>(<b>a</b>) The variation of the width of the nanostructured region under varying laser fluence; and (<b>b</b>) The variation of the width of the direct writing etching region under varying laser fluence.</p>
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<p>The SEM images of the grating structure prepared under varying laser fluence. (<b>a</b>,<b>d</b>,<b>g</b>) 1.91 J/cm<sup>2</sup>; (<b>b</b>,<b>e</b>,<b>h</b>) 3.18 J/cm<sup>2</sup>; (<b>c</b>,<b>f</b>,<b>i</b>) 4.46 J/cm<sup>2</sup>.</p>
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<p>The parameters of the grating structure prepared under varying laser fluence.</p>
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<p>The influence of grating structure processed by varying laser fluence on thermal radiation spectrum.</p>
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<p>The influence of different periodic grating structures on the thermal radiation spectrum.</p>
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<p>The relative intensity of the thermal radiation spectrum of grating structures with varying periods. (<b>a</b>) 5 μm; (<b>b</b>) 10 μm; (<b>c</b>) 15 μm; and (<b>d</b>) 20 μm.</p>
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<p>(<b>a</b>) The relative intensity thermal radiation spectrum of gratings with periods of 10 μm and 15 μm, and (<b>b</b>) the calculation results of COMSOL.</p>
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<p>The influence of varying heating temperatures on the thermal radiation spectrum.</p>
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10 pages, 1750 KiB  
Article
An Analysis of Ocular Biometrics: A Comprehensive Retrospective Study in a Large Cohort of Pediatric Cataract Patients
by Luca Schwarzenbacher, Lorenz Wassermann, Sandra Rezar-Dreindl, Gregor S. Reiter, Ursula Schmidt-Erfurth and Eva Stifter
J. Clin. Med. 2024, 13(16), 4810; https://doi.org/10.3390/jcm13164810 - 15 Aug 2024
Viewed by 420
Abstract
Objectives: This study aims to provide a comprehensive analysis of ocular biometric parameters in pediatric patients with cataracts to optimize surgical outcomes. By evaluating various biometric data, we seek to enhance the decision-making process for intraocular lens (IOL) placement, particularly with advanced technologies [...] Read more.
Objectives: This study aims to provide a comprehensive analysis of ocular biometric parameters in pediatric patients with cataracts to optimize surgical outcomes. By evaluating various biometric data, we seek to enhance the decision-making process for intraocular lens (IOL) placement, particularly with advanced technologies like femtosecond lasers. Methods: This retrospective comparative study included pediatric patients with cataracts who underwent ocular biometric measurements and cataract extraction with anterior vitrectomy at the Medical University of Vienna between January 2019 and December 2021. Parameters measured included corneal diameter (CD), axial length (AL), corneal thickness (CT) and flat and steep keratometry (Kf and Ks). The study explored the correlations between these parameters and IOL placement. Results: A total of 136 eyes from 68 pediatric patients were included in the study. Significant positive correlations were found between corneal diameter, age and AL. The mean CD was 11.4 mm, mean AL was 19.5 mm, CT was 581.2 ± 51.8 µm, Kf was 7.76 ± 0.55 mm and Ks 7.41 ± 0.59 mm, respectively. Older pediatric patients with larger corneal diameters and longer ALs were more likely to receive in-the-bag IOL implantation. Conversely, younger patients often required alternative IOL placements or remained aphakic. Our data indicated that over 95% of the study population and all patients aged one year and older had a corneal diameter of 10 mm or larger. Conclusions: Detailed ocular biometric analysis is crucial for optimizing both surgical outcomes and postoperative care in pediatric cataract patients. The positive correlations between CD, age and AL underline the importance of individualized surgical planning tailored to each patient’s unique anatomical features. Additionally, our findings suggest that the use of a femtosecond laser is both feasible and safe for pediatric patients aged one year and older, potentially offering enhanced surgical precision and improved outcomes. Full article
(This article belongs to the Section Ophthalmology)
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<p>Correlation of corneal diameter to age (r = 0.7). Bivariate scatter plot of age (years) and corneal diameter (mm). The scatter plot demonstrates the positive correlation of corneal diameter with age.</p>
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<p>Correlation of corneal diameter to axial length (r = 0.6). Bivariate scatter plot of axial length (mm) and corneal diameter (mm). The scatter plot demonstrates the positive correlation of corneal diameter with axial length.</p>
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<p>IOL implantation dependent on age. Box plots of the distribution of age across different intraocular lens (IOL) placement groups. The asterisks (*) mark extreme outliers more than 3 times the interquartile range and circles (o) indicate mild outliers.</p>
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<p>IOL implantation dependent on axial length. Box plots of the distribution of axial length across different intraocular lens (IOL) placement groups. The circle (o) indicates a mild outlier between 1.5 and 3 times the interquartile range.</p>
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<p>IOL implantation dependent on corneal diameter. Box plots of the distribution of corneal diameter across different intraocular lens (IOL) placement groups. The asterisks (*) mark extreme outliers more than 3 times the interquartile range and circles (o) indicate mild outliers.</p>
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17 pages, 2610 KiB  
Review
The Design and Analysis of the Fabrication of Micro- and Nanoscale Surface Structures and Their Performance Applications from a Bionic Perspective
by Haohua Zheng, Jiawei Liu and Yake Qiu
Materials 2024, 17(16), 4014; https://doi.org/10.3390/ma17164014 - 12 Aug 2024
Viewed by 723
Abstract
This paper comprehensively discusses the fabrication of bionic-based ultrafast laser micro–nano-multiscale surface structures and their performance analysis. It explores the functionality of biological surface structures and the high adaptability achieved through optimized self-organized biomaterials with multilayered structures. This study details the applications of [...] Read more.
This paper comprehensively discusses the fabrication of bionic-based ultrafast laser micro–nano-multiscale surface structures and their performance analysis. It explores the functionality of biological surface structures and the high adaptability achieved through optimized self-organized biomaterials with multilayered structures. This study details the applications of ultrafast laser technology in biomimetic designs, particularly in preparing high-precision, wear-resistant, hydrophobic, and antireflective micro- and nanostructures on metal surfaces. Advances in the fabrications of laser surface structures are analyzed, comparing top-down and bottom-up processing methods and femtosecond laser direct writing. This research investigates selective absorption properties of surface structures at different scales for various light wavelengths, achieving coloring or stealth effects. Applications in dirt-resistant, self-cleaning, biomimetic optical, friction-resistant, and biocompatible surfaces are presented, demonstrating potential in biomedical care, water-vapor harvesting, and droplet manipulation. This paper concludes by highlighting research frontiers, theoretical and technological challenges, and the high-precision capabilities of femtosecond laser technology in related fields. Full article
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<p>Organisms with specialized functional surfaces and their microstructures [<a href="#B23-materials-17-04014" class="html-bibr">23</a>]. Reproduced with permission from Dong Wu. Bioinspired micro-/nanostructured surfaces prepared by femtosecond laser direct writing for multi-functional applications; published by IOP Publishing Ltd., 2020.</p>
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<p>SEM images of three LIPSS structures produced under different laser irradiation conditions, distinguished fundamentally by the laser fluence and pulse number Neff_2D (parameters given in the text). (<b>A</b>) ripples with a periodicity Λy = 850 nm, (<b>B</b>) grooves, Λy = 840 nm, Λx = 2.6 μm, and (<b>C</b>) spikes. (<b>D</b>) Highly irregular (“damaged”) morphology (optical micrograph) obtained at high fluence and Neff_2D values. (<b>E</b>) Schematic distribution of the different structures found with one single scan, depending on the laser fluence and the effective number of pulses in an area (Neff_2D). The positions on this plot for the structures shown in (<b>A</b>–<b>D</b>) are represented accordingly. The scanning direction and laser polarization for all the images shown are included in (<b>A</b>) [<a href="#B42-materials-17-04014" class="html-bibr">42</a>]. Reproduced with permission from Jan Siegel. Biomimetic surface structures in steel fabricated with femtosecond laser pulses: influence of laser rescanning on morphology and wettability; published by Beilstein-Institut, 2018.</p>
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<p>(<b>a</b>) Measured contact-angle values as a function of laser energy density. (<b>b</b>) Contact-angle values obtained from measurements of different surface roughness values at the same energy injection [<a href="#B55-materials-17-04014" class="html-bibr">55</a>].</p>
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<p>Characterization of VSMCs and HUVECs. (<b>a</b>) AFM image of the morphology of VSMCs (The dashed lines 1-1’ and 2-2’ serve as size reference scales.); (<b>b</b>) line contours of individual lines in (<b>a</b>); (<b>c</b>) diameters of the fiber structures (The blue dashed line indicates the peak diameters of the two fiber structures.); (<b>d</b>) height distribution of the cell surface; (<b>e</b>) AFM image of the morphology of HUVECs(The dashed line serves as a size reference scale.); (<b>f</b>) line contours of the white dashed lines in (<b>e</b>). [<a href="#B61-materials-17-04014" class="html-bibr">61</a>] Reproduced with permission from Chunyong Liang, Biomimetic cardiovascular stents for in vivo re-endothelialization; published by Elsevier Ltd., 2016.</p>
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<p>The application of the motion detection of TPSs for recognizing gestures and gaits [<a href="#B70-materials-17-04014" class="html-bibr">70</a>]. Reproduced with permission from Saihua Jiang. Facile monitoring of human motions on a fireground by using an MiEs-TENG sensor; published by Elsevier Ltd., 2021.</p>
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