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42 pages, 113259 KiB  
Article
Hypogene Alteration of Base–Metal Mineralization at the Václav Vein (Březové Hory Deposit, Příbram, Czech Republic): The Result of Recurrent Infiltration of Oxidized Fluids
by Zdeněk Dolníček, Jiří Sejkora and Pavel Škácha
Minerals 2024, 14(10), 1038; https://doi.org/10.3390/min14101038 (registering DOI) - 17 Oct 2024
Abstract
The Václav vein (Březové Hory deposit, Příbram ore area, Czech Republic) is a base–metal vein containing minor Cu-Zn-Pb-Ag-Sb sulfidic mineralization in a usually hematitized gangue. A detailed mineralogical study using an electron microprobe revealed a complicated multistage evolution of the vein. Early siderite [...] Read more.
The Václav vein (Březové Hory deposit, Příbram ore area, Czech Republic) is a base–metal vein containing minor Cu-Zn-Pb-Ag-Sb sulfidic mineralization in a usually hematitized gangue. A detailed mineralogical study using an electron microprobe revealed a complicated multistage evolution of the vein. Early siderite and Fe-rich dolomite were strongly replaced by assemblages of hematite+rhodochrosite and hematite+kutnohorite/Mn-rich dolomite, respectively. In addition, siderite also experienced strong silicification. These changes were associated with the dissolution of associated sulfides (sphalerite, galena). The following portion of the vein contains low-Mn dolomite and calcite gangue with Zn-rich chlorite, wittichenite, tetrahedrite-group minerals, chalcopyrite, bornite, and djurleite, again showing common replacement textures in case of sulfides. The latest stage was characterized by the input of Ag and Hg, giving rise to Ag-Cu sulfides, native silver (partly Hg-rich), balkanite, and (meta)cinnabar. We explain the formation of hematite-bearing oxidized assemblages at the expense of pre-existing “normal” Příbram mineralization due to repeated episodic infiltration of oxygenated surface waters during the vein evolution. Episodic mixing of ore fluids with surface waters was suggested from previous stable isotope and fluid inclusion studies in the Příbram ore area. Our mineralogical study thus strengthens this genetic scenario, illustrates the dynamics of fluid movement during the evolution of a distinct ore vein structure, and shows that the low content of ore minerals cannot be necessarily a primary feature of a vein. Full article
(This article belongs to the Special Issue Mineralogy and Geochemistry of Polymetallic Ore Deposits)
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Figure 1

Figure 1
<p>The youngest mineral assemblage of a drusy cavity in sample P1N 9430. (<b>a</b>) A top view across the whole drusy cavity. (<b>b</b>) Calcite crystals with acicular ore aggregates. (<b>c</b>) Smooth and finely wrinkled surface of acicular ore aggregates. (<b>d</b>) Acicular ore aggregates enclosed in a transparent crystal of calcite.</p>
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<p>Geological position of the Březové Hory deposit in the Příbram ore area (modified from [<a href="#B1-minerals-14-01038" class="html-bibr">1</a>]). BHD—Březové Hory base–metal district, PUD—Příbram uranium district. Positions of some other sites mentioned in the text are also indicated.</p>
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<p>Position of the Václav vein in geological cross-section through the Březové Hory ore district (modified from [<a href="#B9-minerals-14-01038" class="html-bibr">9</a>]). The Anna shaft is situated north of the Prokop shaft, out of the section line.</p>
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<p>The macroscopic appearance of the sample P1N 9430 with marked zones A–E and sites, from which samples for preparation of polished sections were cut off. The left part of the figure illustrates the distribution of selected mineral phases. Sample width is 4.5 cm.</p>
Full article ">Figure 5
<p>Mineral assemblage and textures of the Václav vein in the BSE images. (<b>a</b>) A slightly zoned relic of siderite replaced by surrounding quartz, carbonates of the dolomite-kutnohorite series, hematite, and tetrahedrite. Right part is wall rock. Zone A, sample VA-1. (<b>b</b>) Relic of siderite strongly replaced by hematite, rhodochrosite, and zoned carbonates of the dolomite series. Zone A, sample VA-2. (<b>c</b>) Relic of siderite rimmed by rhodochrosite and hematite. Zone A, sample VA-2. (<b>d</b>) Euhedral rhodochrosite crystal enclosed in hematite in the proximity of a relic of siderite, which is strongly replaced by the rhodochrosite rim and carbonates of the dolomite group. Zone A, sample VA-2. (<b>e</b>) Boundary between Zone A (hematite-rich on the left) and Zone B (hematite-poor on the right) separated by quartz crystals. Replacement of Do-I by Do-II is observed in the right part. Sample VA-5. (<b>f</b>) Detailed view on replacement of Do-I by zoned Do-II containing inclusions of hematite. Zone B, sample VA-5.</p>
Full article ">Figure 6
<p>Variations in the chemical composition of siderite, rhodochrosite, and calcite from the Václav vein in comparison with published data. (<b>a</b>) Siderite and rhodochrosite in the classification diagram by [<a href="#B27-minerals-14-01038" class="html-bibr">27</a>]. (<b>b</b>) Fe vs. Mn and Fe vs. Mg plots for calcite. Comparative data for other deposits of the Příbram uranium and base metal district are from [<a href="#B5-minerals-14-01038" class="html-bibr">5</a>,<a href="#B6-minerals-14-01038" class="html-bibr">6</a>,<a href="#B7-minerals-14-01038" class="html-bibr">7</a>,<a href="#B28-minerals-14-01038" class="html-bibr">28</a>].</p>
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<p>Variations in the chemical composition of carbonates of the dolomite-ankerite series from the Václav vein in comparison with published data. (<b>a</b>) All data in the classification diagram by [<a href="#B27-minerals-14-01038" class="html-bibr">27</a>]. (<b>b</b>) Data sorted according to Zones. (<b>c</b>) Data arbitrarily grouped according to compositional similarities. Comparative data for other deposits of the Příbram uranium and base metal district are from [<a href="#B5-minerals-14-01038" class="html-bibr">5</a>,<a href="#B6-minerals-14-01038" class="html-bibr">6</a>,<a href="#B7-minerals-14-01038" class="html-bibr">7</a>,<a href="#B28-minerals-14-01038" class="html-bibr">28</a>]. PUD–average dolomite from the Příbram uranium and base–metal district according to wet-chemical analyses by [<a href="#B29-minerals-14-01038" class="html-bibr">29</a>].</p>
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<p>Mineral assemblage and textures of the Václav vein. (<b>a</b>) Contact between Do-II and Do-III dolomites. Note the corrosion of Do-II by Do-III just along the contact. Zone C, sample VA-7. (<b>b</b>) Zoned crystals of carbonates of the dolomite group (bright Do-II is overgrown by darker Do-III) growing over lenticular hematite crystals. Residual vug was later filled up by calcite with aggregates of tetrahedrite and chalcopyrite. Zone A, black domain, sample VA-6. (<b>c</b>) The latest Do-III dolomite crystals overgrown by chalcopyrite-bornite aggregates and calcite. Zone D, sample VA-9. (<b>d</b>) Aggregates of Zn-rich chlorite filling together with calcite residual cavities in the vein composed of euhedral lenticular hematite crystals, sulfidic aggregates, and Do-II+Do-III carbonates. Zone A, black domain, sample VA-6. (<b>e</b>) Two generations of hematite strongly differing in the quality of the polished surface. Fine-grained early hemispherical aggregates are poorly polished, whereas the latest hematite preceding crystallization of Do-II carbonate followed by sulfides is well polished. Sulfide aggregate is composed of sphalerite, chalcopyrite, tetrahedrite-(Zn) (Ttd-I), and an unknown reddish AgCu<sub>6</sub>Fe<sub>2</sub>S<sub>8</sub> phase. Zone A, sample VA-1. (<b>f</b>) The central area of Figure (<b>e</b>) in BSE image. Note the zonality of hematite and Do-II carbonate. Zone A, sample VA-1. Figure (<b>e</b>) is taken in plane-polarized reflected light, whereas the other pictures are BSE images.</p>
Full article ">Figure 9
<p>Variations in the chemical composition of chlorite from the Václav vein and comparison with published data. (<b>a</b>) A Fe-Mg-Zn plot. (<b>b</b>) The Ca vs. Si plot. The comparative data from the Jerusalem deposit (Příbram uranium district) are from [<a href="#B5-minerals-14-01038" class="html-bibr">5</a>].</p>
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<p>Mineral assemblage and textures of the Václav vein. (<b>a</b>) Concentric zonation of hematite. Zone A, sample VA-2. (<b>b</b>) Patchy zonation of hematite caused by variable Sb contents. The youngest part of Zone A, sample VA-3. (<b>c</b>) The strongly corroded cassiterite hosted by sphalerite (partly Cu,Sn-enriched) replaced by hematite+Do-II aggregate. Zone A, sample VA-4. (<b>d</b>) Finely porous and non-porous bornite and chalcopyrite. Note a bluish tint of a part of porous bornite. Sample Dy-817. (<b>e</b>) Finely porous and non-porous bornite and chalcopyrite, with a short veinlet of tetrahedrite. Note the compositional homogeneity of bornite. Sample Dy-817. (<b>f</b>) An acicular polymineral aggregate composed of bornite, covellite, and Ag-Cu sulfides (Ag-Cu-S) with thick symmetrical rims of chalcopyrite I (Cpy-I). Zone E, sample Dy-973. Figures (<b>d</b>,<b>f</b>) are taken in plane-polarized reflected light, whereas the other pictures are BSE images.</p>
Full article ">Figure 11
<p>Variations in the chemical composition of hematite from the Václav vein. (<b>a</b>) The Si vs. Al plot. (<b>b</b>) The Si vs. Sb plot. (<b>c</b>) The Me<sup>2+</sup> vs. Sb plot. (<b>d</b>) The Pb vs. Sb plot.</p>
Full article ">Figure 12
<p>Mineral assemblage and textures of the Václav vein. (<b>a</b>) A crust formed by chalcopyrite (Cpy-I), partly filled and enclosed by bornite and overgrown by a tetrahedrite (Ttd-III) crystal. Part of the pores in bornite was filled by covellite and Ag-Cu sulfides. Bornite contains ribbons of chalcopyrite (Cpy-II). Zone E, sample Dy-973. (<b>b</b>) Three morphological forms of chalcopyrite, crust (Cpy-I), ribbon (Cpy-II), and symplectite with mckinstryite (Symplectite), hosted by bornite with late rims and fillings of covellite and Ag-Cu(-Hg)-S phases. The black rectangle shows the area of <a href="#minerals-14-01038-f012" class="html-fig">Figure 12</a>c. Zone E, sample Dy-973. (<b>c</b>) BSE detail of the central part of Figure (c) showing the nature of Ag-Cu(-Hg)-S phases: fine intergrowths of stromeyerite and mckinstryite are partly overgrown by balkanite. (<b>d</b>) Sphalerite grains are rimmed by bornite and chalcopyrite. Note the intense corrosion of both earlier sulfide phases by later ones. Zone A, sample VA-1. (<b>e</b>) Sphalerite rimmed by bornite, tetrahedrite (Ttd-I), and two generations of chalcopyrite differing in porosity. Note early porous chalcopyrite Cpy-I is replaced by Ttd-I. Zone D, sample VA-9. (<b>f</b>) Bright Ag-enriched zone in chalcopyrite. Zone D, sample VA-8. Figures (<b>c</b>,<b>f</b>) are BSE images; the other pictures are taken in plane-polarized reflected light.</p>
Full article ">Figure 13
<p>Variations in the chemical composition of some ore minerals from the Václav vein in comparison with published data. (<b>a</b>) Graph Ag versus Sb for chalcopyrite. (<b>b</b>) Graph Ag versus Cu for bornite. (<b>c</b>) Graph Sn versus Cu for sphalerite. (<b>d</b>) Graph Fe versus Cd for sphalerite. (<b>e</b>) Graph Ag versus Cu+Fe+Cd for mckinstryite. (<b>f</b>) Graph Ag versus Cu for balkanite. Comparative data for sphalerite from the Háje deposit (Příbram uranium district) are from [<a href="#B7-minerals-14-01038" class="html-bibr">7</a>], for mckinstryite from Milín from [<a href="#B31-minerals-14-01038" class="html-bibr">31</a>], for other mckinstryite data from [<a href="#B32-minerals-14-01038" class="html-bibr">32</a>], for danielsite from [<a href="#B33-minerals-14-01038" class="html-bibr">33</a>], and for published balkanite data from [<a href="#B5-minerals-14-01038" class="html-bibr">5</a>,<a href="#B34-minerals-14-01038" class="html-bibr">34</a>,<a href="#B35-minerals-14-01038" class="html-bibr">35</a>,<a href="#B36-minerals-14-01038" class="html-bibr">36</a>,<a href="#B37-minerals-14-01038" class="html-bibr">37</a>].</p>
Full article ">Figure 14
<p>Mineral assemblage and textures of the Václav vein. (<b>a</b>) Irregular aggregate of djurleite partly replaced by bornite, which is rimmed by a non-continuous zone of chalcopyrite and small grains of Ag-Cu-Hg-S phases. Note the abundant ribbons of chalcopyrite in the outer part of bornite adjacent to the chalcopyrite rim. Sample Dy-816. (<b>b</b>) Sphalerite rimmed by bornite (with brighter Ag-enriched domains) and then by chalcopyrite. Late microfractures contain Ag-Cu-S phases. Zone D, sample VA-9. (<b>c</b>) The brighter Cu,Sn-enriched domains in sphalerite in the vicinity of strongly corroded grains of cassiterite. Zone A, sample VA-4. (<b>d</b>) Sphalerite with brighter Cd-enriched domains (in the lower part of the grain), rimmed by chalcopyrite and enclosing grains of wittichenite and Bi-enriched tetrahedrite. Zone A, sample VA-4. Inset–Oscillatory zoning of a sphalerite grain due to changing Cd contents. Zone C, sample VA-7. (<b>e</b>) Mn-enriched sphalerite and hematite in the residual cavity in Mn-rich dolomite Do-II replacing Fe-rich dolomite Do-I. Zone B, sample VA-5. (<b>f</b>) Tetrahedrite Ttd-I is cut by veinlets of bornite and chalcopyrite Cpy-II. Zone D, sample VA-9. Figures (<b>a</b>,<b>f</b>) are taken in plane-polarized reflected light; the other pictures are BSE images.</p>
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<p>Mineral assemblage and textures of the Václav vein in BSE images. (<b>a</b>) Zonality of a tetrahedrite Ttd-I aggregate is largely caused by Fe-Zn substitution and also, exceptionally, by high Cd (arrowed). The Ttd-I is cut by veinlets of Bi-bearing Ttd-II and a narrow overgrowth of Ttd-III is observed in the lower part of the photograph. Zone D, sample VA-9. (<b>b</b>) Oscillatory zoned Bi-bearing Ttd-II rimming a grain of chalcopyrite. Zone A, sample VA-6. (<b>c</b>) Patchy zoning of Ttd-II. The brightest domain already corresponds to annivite-(Zn). Zone A, sample VA-6. (<b>d</b>) Zoned Bi-bearing tetrahedrite Ttd-II rimming and cutting tetrahedrite Ttd-I. The brightest domain corresponds to <span class="html-italic">annivite-</span>(<span class="html-italic">Cu</span>). Surrounding sphalerite encloses wittichenite. Zone A, sample VA-3. (<b>e</b>) Nature of Ag-Cu sulfides in chalcopyrite-hosted “acicular” polymineral aggregate from <a href="#minerals-14-01038-f010" class="html-fig">Figure 10</a>f: small domains of jalpaite are hosted by the mckinstryite matrix. Zone E, sample Dy-973. (<b>f</b>) A finely porous aggregate of Hg-absent native silver partly rimmed by stromeyerite. Zone E, sample Dy-973.</p>
Full article ">Figure 16
<p>Variations in the chemical composition of tetrahedrite-group minerals from the Václav vein (data points) in comparison with published data (outlined). (<b>a</b>) Graph Fe-Zn-Cd. (<b>b</b>) Graph As-Sb-Bi. Data in at. %. Comparative data for Jáchymov and Hřebečná sites are from [<a href="#B41-minerals-14-01038" class="html-bibr">41</a>]. Notably, data from the Příbram ore area are not visualized as they exhibit Fe-Zn and Sb-As substitutions only.</p>
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<p>Mineral assemblage and textures of the Václav vein in BSE images. (<b>a</b>) Balkanite-like phase rimming grains of probable (meta)cinnabar. Zone A, sample VA-1. (<b>b</b>) Grains of unspecified Ag-Cu-Hg-S phases (white) with variable compositions growing on a chalcopyrite finger-like aggregate. Zone E, sample Dy-973. (<b>c</b>) Individual grains of likely galena (GA) and unspecified Ag-Cu-Hg-S phases with variable compositions growing on a djurleite-bornite-chalcopyrite aggregate. Sample Dy-816. (<b>d</b>) An unknown (Cu,Ag)<sub>4</sub>FeS<sub>4</sub> phase associated with covellite in a sphalerite-chalcopyrite-hematite aggregate. Zone A, sample VA-3.</p>
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<p>Variations in the chemical composition of some ore minerals from the Václav vein in comparison with published data. (<b>a</b>) Graph Cu/Ag versus Hg for balkanite. (<b>b</b>) Graph Ag versus Cu or Hg for balkanite and possible intergrowths of Ag-Cu-Hg phases. (<b>c</b>) Graph Hg versus Cu for balkanite and possible intergrowths of Ag-Cu-Hg phases. (<b>d</b>) Graph Hg versus Ag+Cu+Fe for balkanite and possible intergrowths of Ag-Cu-Hg phases. Comparative published balkanite data are from [<a href="#B5-minerals-14-01038" class="html-bibr">5</a>,<a href="#B34-minerals-14-01038" class="html-bibr">34</a>,<a href="#B35-minerals-14-01038" class="html-bibr">35</a>,<a href="#B36-minerals-14-01038" class="html-bibr">36</a>,<a href="#B37-minerals-14-01038" class="html-bibr">37</a>], and data for danielsite are from [<a href="#B33-minerals-14-01038" class="html-bibr">33</a>].</p>
Full article ">Figure 19
<p>A sketch showing the interpreted textural evolution of the late ore assemblage from a drusy cavity of the sample P1N 9430. The crystallization of an acicular mineral (<b>a</b>) was followed by the deposition of a continuous layer of early chalcopyrite Cpy-I on its crystals (<b>b</b>). Then, the dissolution of acicular mineral took place (<b>c</b>), followed by the crystallization of bornite inside and outside of Cpy-I crusts (<b>d</b>). The crystallization of late chalcopyrite Cpy-II and tetrahedrite Ttd-III (<b>e</b>) was followed by minor fracturing of early ores and partial healing of the residual porosity by the latest ore minerals including covellite and Ag-Cu(-Hg) sulfides (<b>f</b>).</p>
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<p>The simplified paragenetic scheme of the Václav vein. Note that the position of some mineral phases is questionable (marked by ?); more problematic phases are missing.</p>
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<p>The interpreted scenario of the origin of the studied mineralization from the Václav vein. (<b>a</b>) Early stage characterized by the escape of “deep” fluids. (<b>b</b>) Late stage involving the circulation of basinal fluids—Scenario I. (<b>c</b>) Late stage involving the circulation of basinal fluids–Scenario II. Arrows characterize the direction of fluid movement.</p>
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31 pages, 628 KiB  
Article
A Dynamic Event-Triggered Secure Monitoring and Control for a Class of Discrete-Time Markovian Jump Systems: A Plug-and-Play Architecture
by Yi Gao, Yunji Li, Ziyan Hua, Junjie Chen and Yajun Wu
Information 2024, 15(10), 649; https://doi.org/10.3390/info15100649 (registering DOI) - 17 Oct 2024
Abstract
In modern industrial applications, production quality, system performance, process reliability, and safety have received considerable attention. This article proposes a dynamic event-triggered attack estimator for Markovian jump stochastic systems susceptible to actuator deception attacks. Utilizing the developed estimator, the presented attack-tolerant control strategy [...] Read more.
In modern industrial applications, production quality, system performance, process reliability, and safety have received considerable attention. This article proposes a dynamic event-triggered attack estimator for Markovian jump stochastic systems susceptible to actuator deception attacks. Utilizing the developed estimator, the presented attack-tolerant control strategy can tolerate the effects of such attacks and ensure the mean-square convergence of the overall closed-loop system. A dynamic event-triggered mechanism is implemented on the sensor side to optimize communication efficiency. To address the potential threat of deception attacks, a plug-and-play (PnP) secure monitoring and control architecture is introduced. This architecture facilitates the seamless integration of the designed attack-tolerant controller with the nominal feedback controller, thereby enhancing system security without requiring significant modifications to the existing control structure. The practicality and effectiveness of the proposed approaches are demonstrated through experimental results on a switched boost converter circuit. Full article
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Figure 1
<p>Architecture of an embedded system with the dynamic event-triggered sensor data transmission scheme.</p>
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<p>The existing nominal control loop.</p>
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<p>Plug-and-play secure monitoring and control structure.</p>
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<p>Operations of the plug-and-play secure monitoring and control framework.</p>
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<p>A brief working principle of the PnP secure monitoring and control.</p>
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<p>A modified PWM-driven boost converter.</p>
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<p>Evolution of Markov chain <math display="inline"><semantics> <msub> <mi>r</mi> <mi>k</mi> </msub> </semantics></math>.</p>
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<p>Attack monitoring results for the constant attack (<a href="#FD70-information-15-00649" class="html-disp-formula">70</a>).</p>
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<p>Attack monitoring results for the time-varying attack (<a href="#FD71-information-15-00649" class="html-disp-formula">71</a>).</p>
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<p>Attack monitoring results for the incipient attack (<a href="#FD72-information-15-00649" class="html-disp-formula">72</a>).</p>
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<p>Reconstruction of the constant attack (<a href="#FD70-information-15-00649" class="html-disp-formula">70</a>).</p>
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<p>Reconstruction of the time-varying attack (<a href="#FD71-information-15-00649" class="html-disp-formula">71</a>).</p>
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<p>Reconstruction of the incipient attack (<a href="#FD72-information-15-00649" class="html-disp-formula">72</a>).</p>
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<p>Comparative results of transmission efficiency under various attack scenarios.</p>
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<p>Results of the attack-tolerant controller under the constant attack (<a href="#FD70-information-15-00649" class="html-disp-formula">70</a>).</p>
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<p>Results of the attack-tolerant controller under the time-varying attack (<a href="#FD71-information-15-00649" class="html-disp-formula">71</a>).</p>
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<p>Results of the attack-tolerant controller under the incipient attack (<a href="#FD72-information-15-00649" class="html-disp-formula">72</a>).</p>
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15 pages, 9405 KiB  
Article
Study on the Synergistic Effect of Several Sulfur Compounds to the Corrosion Attack of Copper in Liquefied Petroleum Gas
by Chaoben Wang, Yuan Lu, Jinghui Ma and Hu Wang
Coatings 2024, 14(10), 1329; https://doi.org/10.3390/coatings14101329 (registering DOI) - 17 Oct 2024
Abstract
During the process of liquefied petroleum gas (LPG) exploitation, various sulfide-containing gases are produced, which significantly bring about corrosion attacks to copper equipment and facilities. Investigations on the effects of sulfides, hydrogen sulfide (H2S), carbonyl sulfide (COS), and ethanethiol (C2 [...] Read more.
During the process of liquefied petroleum gas (LPG) exploitation, various sulfide-containing gases are produced, which significantly bring about corrosion attacks to copper equipment and facilities. Investigations on the effects of sulfides, hydrogen sulfide (H2S), carbonyl sulfide (COS), and ethanethiol (C2H6S) on copper corrosion and synergistic mechanisms are of great significance for LPG production. This paper studied the synergistic corrosion effects of mixed sulfide-containing gases in LPG on copper plates, including the influence of H2S + COS, H2S + C2H6S, as well as H2S + COS + C2H6S. The results showed that there exists an apparent synergistic effect between different sulfide-containing gases, which decreased the critical point of corrosion and enhanced the severity of copper corrosion. SEM observation on corrosion products with the addition of different sulfide-containing gases demonstrated that the microstructures of corrosion products are significantly different, which reveals different corrosion mechanisms. By characterizing the corrosion products on copper surfaces, corresponding corrosion mechanisms were proposed. Individual H2S reacts with copper directly as chemical corrosion. The presence of water leads to the dissolution of H2S into water film at the copper surface and results in electrochemical corrosion in nature. COS tends to decompose into acidic gas H2S and CO2, which accelerates the electrochemical corrosion at the copper surface. C2H6S can react with copper directly as chemical corrosion. A mixture of different sulfur-containing gases enhanced the corrosion attack by synergistic effect. Full article
(This article belongs to the Section Corrosion, Wear and Erosion)
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<p>The influence of concentration of H<sub>2</sub>S, COS, and C<sub>2</sub>H<sub>6</sub>S on the corrosion of copper plates (<span class="html-italic">RH</span> = 100%). (<b>a</b>) COS concentration on copper corrosion grade in the presence of H<sub>2</sub>S; (<b>b</b>) C<sub>2</sub>H<sub>6</sub>S concentration on copper corrosion grade in the presence of H<sub>2</sub>S; (<b>c</b>) mixture of H<sub>2</sub>S+C<sub>2</sub>H<sub>6</sub>S + COS on copper corrosion grade.</p>
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<p>The influence of relative humidity on the corrosion of copper plates by different concentrations of H<sub>2</sub>S, COS, and mixture of H<sub>2</sub>S + COS in the presence of 1 ppm H<sub>2</sub>S. (<b>a</b>) 1 ppm H<sub>2</sub>S + 1 ppm COS; (<b>b</b>) 1 ppm H<sub>2</sub>S + 1 ppm C<sub>2</sub>H<sub>6</sub>S; (<b>c</b>) 1 ppm H<sub>2</sub>S + 1 ppm C<sub>2</sub>H<sub>6</sub>S + 1 ppm COS.</p>
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<p>Microscopic morphologies of corrosion products on copper surface in LPG containing mixed sulfur gas. (H<sub>2</sub>S + 1 ppm, COS + 5 ppm and C<sub>2</sub>H<sub>6</sub>S + 5 ppm, <span class="html-italic">RH</span> = 100%).</p>
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<p>Elemental analysis of corrosion products on copper surface in LPG containing mixed sulfur gas, (<b>a</b>) 1 ppm H<sub>2</sub>S + 5 ppm COS, (<b>b</b>) 1 ppm H<sub>2</sub>S + 5 ppm C<sub>2</sub>H<sub>6</sub>S, and (<b>c</b>) 1 ppm H<sub>2</sub>S + 5 ppm COS + 5 ppm C<sub>2</sub>H<sub>6</sub>S.</p>
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<p>GIXRD analysis of surface corrosion products on copper samples in LPG containing different gases. (<b>a</b>) in the presence of H<sub>2</sub>S; (<b>b</b>) in the presence of H<sub>2</sub>S + COS; (<b>c</b>) in the presence of H<sub>2</sub>S + C<sub>2</sub>H<sub>6</sub>S; (<b>d</b>) in the presence of H<sub>2</sub>S + COS + C<sub>2</sub>H<sub>6</sub>S.</p>
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<p>GIXRD analysis of surface corrosion products on copper samples in LPG containing different gases. (<b>a</b>) in the presence of H<sub>2</sub>S; (<b>b</b>) in the presence of H<sub>2</sub>S + COS; (<b>c</b>) in the presence of H<sub>2</sub>S + C<sub>2</sub>H<sub>6</sub>S; (<b>d</b>) in the presence of H<sub>2</sub>S + COS + C<sub>2</sub>H<sub>6</sub>S.</p>
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<p>Corrosion mechanism of H<sub>2</sub>S in the presence (<b>a</b>) and absence (<b>b</b>) of water.</p>
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<p>Corrosion mechanism of synergistic effect between H<sub>2</sub>S and COS.</p>
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<p>Mechanism of synergistic corrosion effect between H<sub>2</sub>S and C<sub>2</sub>H<sub>6</sub>S.</p>
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11 pages, 6643 KiB  
Article
Assessment of Cooling Conditions of Thermoplastic Insulation and Uniformity of Breakdown Strength for Medium-Voltage Direct Current Extruded Cable Insulation
by Keon-Hee Park, Seung-Won Lee, Hae-Jong Kim and Jang-Seob Lim
Energies 2024, 17(20), 5167; https://doi.org/10.3390/en17205167 (registering DOI) - 17 Oct 2024
Abstract
Research has been conducted on medium-voltage direct current (MVDC) to address the limited transmission capacity of existing AC power transmission lines and to achieve efficient integration of renewable energy sources. Another method to increase the transmission capacity is to raise the maximum allowable [...] Read more.
Research has been conducted on medium-voltage direct current (MVDC) to address the limited transmission capacity of existing AC power transmission lines and to achieve efficient integration of renewable energy sources. Another method to increase the transmission capacity is to raise the maximum allowable temperature of the power cable. The maximum allowable temperature for cross-linked polyethylene (XLPE) in commercial power cables is 90 °C. Polypropylene (PP) is considered as an alternative material. PP has a maximum allowable temperature of 110 °C and possesses thermoplastic properties, making it environmentally friendly. However, PP may not ensure uniformity of the insulation layer depending on the extrusion process, including cooling conditions. This study aimed to determine the applicability of MVDC cables by assessing the uniformity of the insulation layer of extruded cables, considering the cooling conditions of PP in specimens. For the cooling conditions, ambient air, cooling press, and water cooling were evaluated for DC breakdown strength. Furthermore, the uniformity of the breakdown strength of the insulation layer, which was divided into sections such as conductor and sheath, was evaluated for commercial PP, XLPE, and the developed PP cables. This study aims to provide a comprehensive analysis of the DC BD strength of PP under various cooling conditions and emphasize the importance of uniformity in extruded cable sections. Full article
(This article belongs to the Section F6: High Voltage)
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<p>Configuration of hot press and cooling press.</p>
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<p>Peeling process and dividing sections of extruded cable.</p>
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<p>Configuration of the electrode system: (<b>a</b>) electrode system and (<b>b</b>) diagram of wire connections.</p>
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<p>PP1 AC breakdown strength (three sections).</p>
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<p>PP2 AC breakdown strength (three sections).</p>
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<p>XLPE AC breakdown strength (three sections).</p>
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<p>PP1 DC breakdown strength (five sections).</p>
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<p>PP2 DC breakdown strength (five sections).</p>
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14 pages, 778 KiB  
Review
Correlation between Periodontitis and Onset of Alzheimer’s Disease: A Literature Review
by Antonio Barbarisi, Valeria Visconti, Dorina Lauritano, Francesca Cremonini, Gianluigi Caccianiga and Saverio Ceraulo
Dent. J. 2024, 12(10), 331; https://doi.org/10.3390/dj12100331 (registering DOI) - 17 Oct 2024
Abstract
Background: Alzheimer’s disease is a slowly progressing neurodegenerative illness and the most common form of dementia. This pathology leads to an increase in cognitive decline and is responsible, in patients, for several difficulties in performing various activities of daily living, such as oral [...] Read more.
Background: Alzheimer’s disease is a slowly progressing neurodegenerative illness and the most common form of dementia. This pathology leads to an increase in cognitive decline and is responsible, in patients, for several difficulties in performing various activities of daily living, such as oral hygiene. Several experimental studies have shown that oral health in patients with Alzheimer’s disease worsens in direct proportion to the progression of the disease due to the appearance of gingivitis and periodontitis. Methods: This clinical literature review aims to evaluate a possible correlation between periodontal disease and Alzheimer’s disease, trying to understand if the periopathogens can contribute to the onset or the progression of Alzheimer’s disease (AD). The study was conducted on the database PubMed (MEDLINE) of full-text systematic reviews in English on humans and animals that were published in the last five years, from 2018 to 2023. This returned 50 publications, which, once the eligibility criteria were applied, resulted in the 10 publications examined in this review. The selected articles were organized through the construction of tables, analyzed, and compared through Judith Garrard’s Matrix method to arrive at the review results. Results: Infection by periopathogens can increase the risk of developing Alzheimer’s disease, but also the onset of the latter can make it more difficult to maintain proper oral hygiene, favoring the onset of periodontal disease: it is possible to affirm the existence of a correlation between periodontitis and AD. It was found that patients exposed to chronic periodontitis have a greater risk of developing a cognitive decline or AD and that oral pathogens can be responsible for neuropathologies and increasing systemic inflammation. Conclusions: Periodontitis and periodontal pathogens represent a real risk factor for the onset or worsening of AD; however, the pathogenetic mechanism is still not completely clear. Full article
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<p>A flowchart of the research process.</p>
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<p>How pathogens spread from the oral cavity to the brain.</p>
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18 pages, 2455 KiB  
Case Report
Thyrotoxic Myopathy with Nonspecific Ophthalmopathy in a Two-Year-Old Child: Case Report and Literature Review
by Katarzyna Smółka, Lidia Perenc, Joanna Pelc, Leon Smółka and Konrad Szajnik
J. Clin. Med. 2024, 13(20), 6180; https://doi.org/10.3390/jcm13206180 (registering DOI) - 17 Oct 2024
Abstract
Background: Myopathies encompass a wide range of diseases with diverse etiologies, courses, and prognoses, and can be either genetic or acquired in nature. One of the rare causes of acquired myopathies in children is hyperthyroidism. Ocular manifestations of hyperthyroidism include proptosis (exophthalmos) and [...] Read more.
Background: Myopathies encompass a wide range of diseases with diverse etiologies, courses, and prognoses, and can be either genetic or acquired in nature. One of the rare causes of acquired myopathies in children is hyperthyroidism. Ocular manifestations of hyperthyroidism include proptosis (exophthalmos) and widening of the palpebral fissure. Conversely, ptosis may indicate co-existing myasthenia or primary or secondary myopathy. Methods: This study presents a case of a 2-year-old child exhibiting both ocular disorders—each in one eye—along with features of proximal myopathy associated with undiagnosed thyrotoxicosis. Results: To our knowledge, this unique presentation of thyrotoxicosis in a young child has not been previously reported. After appropriate treatment for thyrotoxicosis, the child’s ocular and muscular symptoms showed improvement. Conclusions: Given that thyroid disorders can be a rare cause of both myopathy and ocular disorders in children, it is recommended that any child presenting with such symptoms undergo thyroid function screening tests. Full article
(This article belongs to the Section Clinical Pediatrics)
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<p>The myopathic face with unique ophthalmopathy—a slightly widened right palpebral fissure, a forward protrusion of the right eyeball, and evident ptosis on the left. Lip closure weakness is visible.</p>
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<p>(<b>a</b>–<b>c</b>) Gower’s maneuver: using her hands and arms to “walk” up her body when standing up from the floor.</p>
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<p>Head lag was observed during the examination.</p>
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<p>The patient’s face after 12 months of thiamazole treatment no longer exhibits a myopathic appearance. There is no weakness in lip closure or signs of ptosis. However, a slight protrusion of the right eyeball remains.</p>
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22 pages, 4224 KiB  
Article
Weighting Variables for Transportation Assets Condition Indices Using Subjective Data Framework
by Abdallah B. Al-Hamdan, Yazan Ibrahim Alatoom, Inya Nlenanya and Omar Smadi
CivilEng 2024, 5(4), 949-970; https://doi.org/10.3390/civileng5040048 (registering DOI) - 17 Oct 2024
Abstract
This study proposes a novel framework for determining variables’ weights in transportation assets condition indices calculations using statistical and machine learning techniques. The methodology leverages subjective ratings alongside objective measurements to derive data-driven weights. The motivation for this study lies in addressing the [...] Read more.
This study proposes a novel framework for determining variables’ weights in transportation assets condition indices calculations using statistical and machine learning techniques. The methodology leverages subjective ratings alongside objective measurements to derive data-driven weights. The motivation for this study lies in addressing the limitations of existing expert-based weighting methods for condition indices, which often lack transparency and consistency; this research aims to provide a data-driven framework that enhances accuracy and reliability in infrastructure asset management. A case study was performed as a proof of concept of the proposed framework by applying the framework to obtain data-driven weights for pavement condition index (PCI) calculations using data for the city of West Des Moines, Iowa. Random forest models performed effectively in modeling the relationship between the overall condition index (OCI) and the objective measures and provided feature importance scores that were converted into weights. The data-driven weights showed strong correlation with existing expert-based weights, validating their accuracy while capturing contextual variations between pavement types. The results indicate that the proposed framework achieved high model accuracy, demonstrated by R-squared values of 0.83 and 0.91 for rigid and composite pavements, respectively. Additionally, the data-driven weights showed strong correlations (R-squared values of 0.85 and 0.98) with existing expert-based weights, validating their effectiveness. This advanceIRIment offers transportation agencies an enhanced tool for prioritizing maintenance and resource allocation, ultimately leading to improved infrastructure longevity. Additionally, this approach shows promise for application across various transportation assets based on the yielded results. Full article
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<p>Proposed framework.</p>
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<p>Road network of the city of West Des Moines.</p>
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<p>Proposed procedure for obtaining weights for PCI calculations.</p>
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<p>Cross-validation RMSE for PCC pavement (<b>left</b>) and COM pavement (<b>right</b>) during the application of RFE for feature selection.</p>
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<p>Partial dependence plots for the weights of IRI and transverse cracking for PCC pavement vs. RMS, standard deviation, and IQR.</p>
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<p>Partial dependence plots for the weights of IRI and transverse cracking for COM pavement vs. RMS, standard deviation, and IQR.</p>
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<p>The relationship between the old PCI and new PCI for PCC pavements (<b>left</b>) and COM pavements (<b>right</b>) for West Des Moines area in the year 2015.</p>
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13 pages, 272 KiB  
Article
Some Remarks on Existence of a Complex Structure on the Compact Six Sphere
by Daniel Guan, Na Li and Zhonghua Wang
Axioms 2024, 13(10), 719; https://doi.org/10.3390/axioms13100719 (registering DOI) - 17 Oct 2024
Abstract
The existence or nonexistence of a complex structure on a differential manifold is a central problem in differential geometry. In particular, this problem on S6 was a long-standing unsolved problem, and differential geometry is an important tool. Recently, G. Clemente found a [...] Read more.
The existence or nonexistence of a complex structure on a differential manifold is a central problem in differential geometry. In particular, this problem on S6 was a long-standing unsolved problem, and differential geometry is an important tool. Recently, G. Clemente found a necessary and sufficient condition for almost-complex structures on a general differential manifold to be complex structures by using a covariant exterior derivative in three articles. However, in two of them, G. Clemente used a stronger condition instead of the published one. From there, G. Clemente proved the nonexistence of the complex structure on S6. We study the related differential operators and give some examples of nilmanifolds. And we prove that the earlier condition is too strong for an almost complex structure to be integrable. In another word, we clarify the situation of this problem. Full article
(This article belongs to the Section Geometry and Topology)
15 pages, 11465 KiB  
Article
Data-Driven Sparse Sensor Placement Optimization on Wings for Flight-by-Feel: Bioinspired Approach and Application
by Alex C. Hollenbeck, Atticus J. Beachy, Ramana V. Grandhi and Alexander M. Pankonien
Biomimetics 2024, 9(10), 631; https://doi.org/10.3390/biomimetics9100631 (registering DOI) - 17 Oct 2024
Abstract
Flight-by-feel (FBF) is an approach to flight control that uses dispersed sensors on the wings of aircraft to detect flight state. While biological FBF systems, such as the wings of insects, often contain hundreds of strain and flow sensors, artificial systems are highly [...] Read more.
Flight-by-feel (FBF) is an approach to flight control that uses dispersed sensors on the wings of aircraft to detect flight state. While biological FBF systems, such as the wings of insects, often contain hundreds of strain and flow sensors, artificial systems are highly constrained by size, weight, and power (SWaP) considerations, especially for small aircraft. An optimization approach is needed to determine how many sensors are required and where they should be placed on the wing. Airflow fields can be highly nonlinear, and many local minima exist for sensor placement, meaning conventional optimization techniques are unreliable for this application. The Sparse Sensor Placement Optimization for Prediction (SSPOP) algorithm extracts information from a dense array of flow data using singular value decomposition and linear discriminant analysis, thereby identifying the most information-rich sparse subset of sensor locations. In this research, the SSPOP algorithm is evaluated for the placement of artificial hair sensors on a 3D delta wing model with a 45° sweep angle and a blunt leading edge. The sensor placement solution, or design point (DP), is shown to rank within the top one percent of all possible solutions by root mean square error in angle of attack prediction. This research is the first to evaluate SSPOP on a 3D model and the first to include variable length hairs for variable velocity sensitivity. A comparison of SSPOP against conventional greedy search and gradient-based optimization shows that SSPOP DP ranks nearest to optimal in over 90 percent of models and is far more robust to model variation. The successful application of SSPOP in complex 3D flows paves the way for experimental sensor placement optimization for artificial hair-cell airflow sensors and is a major step toward biomimetic flight-by-feel. Full article
(This article belongs to the Special Issue Bio-Inspired Fluid Flows and Fluid Mechanics)
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<p>Lift-inducing LEV formation and evolution in (<b>a</b>) flapping dragonfly wings (from [<a href="#B45-biomimetics-09-00631" class="html-bibr">45</a>]) and (<b>b</b>) a delta-canard fighter at high AoA (from [<a href="#B46-biomimetics-09-00631" class="html-bibr">46</a>]).</p>
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<p>45 deg sweep, NACA 4415 delta wing model. (<b>a</b>) Matrix of airflow velocity magnitude for the 1cm hair length model at each of 238 nodes (columns) over 40 angles of attack (rows) from −10<math display="inline"><semantics> <mo>°</mo> </semantics></math> to 20<math display="inline"><semantics> <mo>°</mo> </semantics></math>. (<b>b</b>) CFD°: Velocity magnitude at three heights above wing for 11 slices at <math display="inline"><semantics> <mrow> <mi>α</mi> <mo>=</mo> <msup> <mn>20</mn> <mo>∘</mo> </msup> </mrow> </semantics></math>.</p>
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<p>Node locations and numbers. There are 238 nodes spaced evenly over the top and bottom surfaces.</p>
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<p>The Sparse Sensor Placement Optimization for Prediction (SSPOP) algorithm. From [<a href="#B20-biomimetics-09-00631" class="html-bibr">20</a>].</p>
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<p>Performance and ranking for the three individual hair length models and the variable hair length model.</p>
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<p>Design points for SSPOP and best possible with four sensors for (<b>a</b>) 5 mm, (<b>b</b>) 1 cm, (<b>c</b>) 2 cm, and (<b>d</b>) three sensors for variable AHS hair lengths.</p>
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<p>DP performance (degrees AoA prediction) of a greedy Search and SSPOP for two through ten sensors.</p>
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<p>Ten-sensor design points for SSPOP and greedy search solutions for a 2D airfoil (model from [<a href="#B20-biomimetics-09-00631" class="html-bibr">20</a>]).</p>
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<p>Flowchart of auto-differentiated sequential data processing.</p>
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51 pages, 1377 KiB  
Article
Beyond Compliance: A Deep Dive into Improving Sustainability Reporting Quality with LCSA Indicators
by Suzana Ostojic, Jana Gerta Backes, Markus Kowalski and Marzia Traverso
Standards 2024, 4(4), 196-246; https://doi.org/10.3390/standards4040011 (registering DOI) - 17 Oct 2024
Viewed by 51
Abstract
This study addresses the critical need for improved sustainability reporting in the construction sector, focusing on the integration of Life Cycle Sustainability Assessment (LCSA) indicators to enhance reporting quality and promote standardization. The increasing regulatory pressure from the European Commission, particularly in sustainability [...] Read more.
This study addresses the critical need for improved sustainability reporting in the construction sector, focusing on the integration of Life Cycle Sustainability Assessment (LCSA) indicators to enhance reporting quality and promote standardization. The increasing regulatory pressure from the European Commission, particularly in sustainability reporting, has intensified the demand for corporate transparency. Despite these efforts, many companies still face challenges in implementing robust sustainability performance measures. This research employs a systematic literature review alongside the case studies of three leading German construction companies to critically assess the current reporting practices and explore the integration potential of LCSA indicators. The findings highlight a significant gap between the existing sustainability disclosures and LCSA indicators, with only 7–19% of the assessed indicators being integrated into the current reporting practices. Although some consistency in reporting themes and qualitative disclosures is evident, the misalignment with LCSA indicators underscores the need for further integration of standardized, life cycle-based metrics. This study concludes that collaborative efforts among companies, policymakers, and LCSA researchers are required to bridge this gap, ensuring the adoption of the existing, scientifically robust indicators that enhance the precision, comparability, and transparency of sustainability reporting in the construction sector. Full article
(This article belongs to the Special Issue Sustainable Development Standards)
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<p>Schematic illustration of the article selection approach.</p>
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<p>Result of LCSA indicator mapping (HT).</p>
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<p>Result of LCSA indicator mapping (ST).</p>
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<p>Result of LCSA indicator mapping (HC).</p>
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22 pages, 3605 KiB  
Article
Instance-Level Scaling and Dynamic Margin-Alignment Knowledge Distillation for Remote Sensing Image Scene Classification
by Chuan Li, Xiao Teng, Yan Ding and Long Lan
Remote Sens. 2024, 16(20), 3853; https://doi.org/10.3390/rs16203853 (registering DOI) - 17 Oct 2024
Viewed by 65
Abstract
Remote sensing image (RSI) scene classification aims to identify semantic categories in RSI using neural networks. However, high-performance deep neural networks typically demand substantial storage and computational resources, making practical deployment challenging. Knowledge distillation has emerged as an effective technique for developing compact [...] Read more.
Remote sensing image (RSI) scene classification aims to identify semantic categories in RSI using neural networks. However, high-performance deep neural networks typically demand substantial storage and computational resources, making practical deployment challenging. Knowledge distillation has emerged as an effective technique for developing compact models that maintain high classification accuracy in RSI tasks. Existing knowledge distillation methods often overlook the high inter-class similarity in RSI scenes, leading to low-confidence soft labels from the teacher model, which can mislead the student model. Conversely, overly confident soft labels may discard valuable non-target information. Additionally, the significant intra-class variability in RSI contributes to instability in the model’s decision boundaries. To address these challenges, we propose an efficient method called instance-level scaling and dynamic margin-alignment knowledge distillation (ISDM) for RSI scene classification. To balance the target and non-target class influence, we apply an entropy regularization loss to scale the teacher model’s target class at the instance level. Moreover, we introduce dynamic margin alignment between the student and teacher models to improve the student’s discriminative capability. By optimizing soft labels and enhancing the student’s ability to distinguish between classes, our method reduces the effects of inter-class similarity and intra-class variability. Experimental results on three public RSI scene classification datasets (AID, UCMerced, and NWPU-RESISC) demonstrate that our method achieves state-of-the-art performance across all teacher–student pairs with lower computational costs. Additionally, we validate the generalization of our approach on general datasets, including CIFAR-100 and ImageNet-1k. Full article
(This article belongs to the Section AI Remote Sensing)
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<p>Motivation (dashed boxes) and main idea (solid boxes). Blue dashed box: high and low inter-class similarities lead to poor soft labels. Green dashed box: large intra-class variability leads to a poor decision boundary. Blue solid box: instance-level scaling can optimize the poor soft labels. Green solid box: dynamic margin-alignment can result in a more rational decision boundary. Pink circles and yellow triangles are samples from two classes. Orange arrows represent the margin.</p>
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<p>Overview of our method. The left side depicts the overall framework of ISDM: the instance-level scaling module optimizes the teacher model’s soft labels at instance-level, followed by distillation with a dynamic margin-alignment strategy. The right side illustrates the specific implementations of IS and DM. Notably, different shapes represent sample categories, and color variation indicates soft label optimization in IS. Different shapes represent samples from different classes. Blue and green represent the outputs of the student model and the teacher model respectively.</p>
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<p>Examples of fixed and dynamic margin for easy and hard samples. Orange circles and blue circles are samples from two classes.</p>
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<p>Examples of fixed and dynamic margin for easy and hard samples. Orange circles and blue circles are samples from two classes.</p>
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<p>Motivation validation. (<b>a</b>): Visualization of inter-class similarity for ResNet18 model trained with Vanilla method on CIFAR-100 dataset. (<b>b</b>–<b>d</b>): Visualization of inter-class similarity for ResNet18 model trained with Vanilla, KD, and ISDM methods on UCM datasets.</p>
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<p>Motivation validation. (<b>a</b>): Visualization of inter-class similarity for ResNet18 model trained with Vanilla method on CIFAR-100 dataset. (<b>b</b>–<b>d</b>): Visualization of inter-class similarity for ResNet18 model trained with Vanilla, KD, and ISDM methods on UCM datasets.</p>
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<p>Visualizations illustrating the scaling process of soft labels from both easy sample (<b>top</b>) and hard sample (<b>bottom</b>). (<b>a</b>) Scaling process of soft label from easy samples; (<b>b</b>) scaling process of soft label from hard samples.</p>
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<p>Visualizations illustrating the scaling process of soft labels from both easy sample (<b>top</b>) and hard sample (<b>bottom</b>). (<b>a</b>) Scaling process of soft label from easy samples; (<b>b</b>) scaling process of soft label from hard samples.</p>
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<p>t-SNE of features learned by KD (<b>left</b>) and ISDM (<b>right</b>). (<b>a</b>) KD; (<b>b</b>) ISDM.</p>
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<p>Difference of student and teacher logits. ResNet34–ResNet18 as the teacher–student pair on the UCM dataset. (<b>a</b>) KD (max diff: 1.95; mean diff: 0.42); (<b>b</b>) ISDM (max diff: 1.71; mean diff: 0.35).</p>
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<p>Training time vs. top-1 accuracy on CIFAR-100 with ResNet34 as teacher and ResNet18 as student.</p>
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21 pages, 1156 KiB  
Article
EDSCVD: Enhanced Dual-Channel Smart Contract Vulnerability Detection Method
by Huaiguang Wu, Yibo Peng, Yaqiong He and Siqi Lu
Symmetry 2024, 16(10), 1381; https://doi.org/10.3390/sym16101381 (registering DOI) - 17 Oct 2024
Viewed by 80
Abstract
Ensuring the absence of vulnerabilities or flaws in smart contracts before their deployment is crucial for the smooth progress of subsequent work. Existing detection methods heavily rely on expert rules, resulting in low robustness and accuracy. Therefore, we propose EDSCVD, an enhanced deep [...] Read more.
Ensuring the absence of vulnerabilities or flaws in smart contracts before their deployment is crucial for the smooth progress of subsequent work. Existing detection methods heavily rely on expert rules, resulting in low robustness and accuracy. Therefore, we propose EDSCVD, an enhanced deep learning vulnerability detection model based on dual-channel networks. Firstly, the contract fragments are preprocessed by BERT into the required word embeddings. Next, we utilized adversarial training FGM to the word embeddings to generate perturbations, thereby producing symmetric adversarial samples and enhancing the robustness of the model. Then, the dual-channel model combining BiLSTM and CNN is utilized for feature training to obtain more comprehensive and symmetric information on temporal and local contract features.Finally, the combined output features are passed through a classifier to classify and detect contract vulnerabilities. Experimental results show that our EDSCVD exhibits excellent detection performance in the detection of classical reentrancy vulnerabilities, timestamp dependencies, and integer overflow vulnerabilities. Full article
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<p>Reentrancy source code. (Source: Own elaboration).</p>
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<p>Timestamp Dependency source code. (Source: Own elaboration).</p>
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<p>Integer Overflow source code. (∗ denotes the multiplication operator. <math display="inline"><semantics> <mrow> <mo>&amp;</mo> <mo>&amp;</mo> </mrow> </semantics></math> denotes a logical symbol used to combine two Boolean expressions). (Source: Own elaboration).</p>
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<p>The overall architecture of EDSCVD. (Source: Own elaboration).</p>
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<p>Contract fragment representation. (Source: Own elaboration).</p>
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<p>The structure of BERT. (Source: Own elaboration based on literature [<a href="#B49-symmetry-16-01381" class="html-bibr">49</a>]).</p>
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<p>Adversarial Training Methods FGM. (Source: Own elaboration).</p>
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<p>Dual-Channel Network Architecture. (Source: Own elaboration based on literature [<a href="#B49-symmetry-16-01381" class="html-bibr">49</a>]).</p>
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<p>Structure of a single LSTM module. (Source: Own elaboration based on literature [<a href="#B22-symmetry-16-01381" class="html-bibr">22</a>]).</p>
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<p>Multi-Head Attention Mechanisms. (Source: Own elaboration).</p>
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<p>Epochs and Evaluation Metrics in model training. (Source: Own elaboration).</p>
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Article
Tree-Ring-Based Hydroclimatic Variability in the Southeast Coastal Region of China
by Xinguang Cao, Pei-ken Kao, Yingjun Li, Zheng Zhao, Hongbing Hu, Jing Hu, Di Zhang and Keyan Fang
Forests 2024, 15(10), 1813; https://doi.org/10.3390/f15101813 (registering DOI) - 17 Oct 2024
Viewed by 79
Abstract
The frequency and severity of extreme hydroclimatic events in humid southeastern China have increased in the past half century, which is a serious concern. In this research, we used wood samples from 134 trees growing in the southeast coastal region of China (SECC) [...] Read more.
The frequency and severity of extreme hydroclimatic events in humid southeastern China have increased in the past half century, which is a serious concern. In this research, we used wood samples from 134 trees growing in the southeast coastal region of China (SECC) to reconstruct the Standardized Precipitation Evapotranspiration Index (SPEI) for the last 173 years (1843–2015 CE). Our reconstruction explained 41.6% of the variance contained in the November SPEI at a 7 month scale for the period 1957–2015. 17 extremely wet and 16 extremely dry events, 8 dry and 9 wet periods have been identified since 1843, and the most severe drought, coinciding with historical records, occurred in 1869 and 1870. The reconstruction reveals. Although the results reveal a modest upward trend in the SPEI and a predominance of extreme wet events over droughts throughout the period, the 20th century accounted for nine of the summers classified as extremely dry. Strong agreement between the current reconstruction and existing hydroclimatic reconstructions in southeastern China implied that our reconstruction exhibited high reliability. The composite anomalies of circulation during the period from May to November (MJJASON) indicate that the temporal variability in the SPEI reconstruction might be modulated by the local Hadley cell. These findings underscore the effectiveness of tree-ring-derived indices for reconstructing hydroclimatic trends in China’s humid regions and enhance our understanding of these changes within a long-term framework. Full article
(This article belongs to the Section Forest Hydrology)
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<p>(<b>Left</b>) the location of the study area in the southeast coastal region of China (SECC) on a topographic map. (<b>Right</b>) the location of the sampling sites in the study area (see <a href="#forests-15-01813-t001" class="html-table">Table 1</a>).</p>
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<p>(<b>a</b>) Regional composite tree-ring width (TRW) chronology (CTRW-1) produced by pooling all the TRW measurements from the three sites together; (<b>b</b>) the number of sampled cores included in the chronology; (<b>c</b>,<b>d</b>) expressed population signal (EPS) and running inter-series correlation (Rbar) statistics; (<b>e</b>) regional composite TRW chronology (CTRW-2) produced via principal component analysis (PCA) of the three chronologies (GS, FGY, and BSC); (<b>f</b>) regional composite TRW chronology (CTRW-3) produced by arithmetically averaging the three chronologies.</p>
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<p>The flowchart of the methodology section.</p>
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<p>(<b>a</b>) A Walter-Lieth diagram showing monthly temperature (red line) and precipitation (blue line). The annual average temperature and monthly average rainfall data (1957–2015) from the meteorological stations are located in the upper left and upper right corners, respectively. (<b>b</b>) Correlation between SPEI index at different time scales (X axis) from 1 to 24 months (Y axis) and CTRW-1 for the period 1957–2015. The highest correlation was in November after 7 months.</p>
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<p>(<b>a</b>) A comparison between actual and estimated SPEI values during 1957–2015. (<b>b</b>) The coherent spectrum of the cross-wavelet between the actual and estimated time series. (<b>c</b>) The Nov. SPEI 07 reconstruction from 1843 to 2015 for the SECC. The red line represents a 10 year low-pass filter of the annual values. The black line is the variation trend of Nov. SPEI 07. Extreme wet and dry years are represented by blue and red triangles, respectively.</p>
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<p>The split and cross-validation: (<b>a</b>,<b>b</b>) represent the time series of observed (green) and reconstructed Nov. SPEI 07 data for the calibration (red) and verification (purple) periods of the split sample procedure; (<b>c</b>) represents the time series of observed (green) and reconstructed Nov. SPEI 07 (black) data.</p>
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<p>Spatial correlations (α = 0.10) across China’s southeast region between the (<b>a</b>) non-transformed and (<b>b</b>) first-year difference CTRW-1 chronology and the SPEI for the period 1957–2015. The positions of the three tree-ring sampling points are represented by solid black circles.</p>
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<p>Comparisons of the reconstructed Nov. SPEI 07 with other hydroclimatic reconstructions. The referenced reconstructions are (<b>a</b>,<b>d</b>) May–November precipitation from GPCC v2020, (<b>b</b>,<b>e</b>) the tree-ring chronology of <span class="html-italic">Cryptomeria fortune</span> from Meihua Mountains in southeastern China [<a href="#B5-forests-15-01813" class="html-bibr">5</a>], and (<b>c</b>,<b>f</b>) the dryness/wetness index (DWI). The interannual (<b>a</b>–<b>c</b>) and decadal fluctuations (<b>d</b>–<b>f</b>) were separated using the 10-year low-pass filter.</p>
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<p>May to November (MJJASON) composite anomalies from 1981, 1982, 2005, and 2015, with (<b>a</b>) precipitation, (<b>b</b>) outgoing longwave radiation (OLR), (<b>c</b>) omega at 500 hPa, and (<b>d</b>) height-latitude cross-profiles (averaged over 110°−120° E) of omega.</p>
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23 pages, 10799 KiB  
Article
The Development and Experimental Validation of a Real-Time Coupled Gear Wear Prediction Model Considering Initial Surface Topography, Dynamics, and Thermal Deformation
by Jingqi Zhang, Jianxing Zhou, Quanwei Cui, Ning Dong, Hong Jiang and Zhong Fang
Machines 2024, 12(10), 734; https://doi.org/10.3390/machines12100734 (registering DOI) - 17 Oct 2024
Viewed by 102
Abstract
Errors affect the actual meshing process of gears, alter the actual wear pattern of the tooth profile, and may even impact the overall service life of machinery. While existing research predominantly focuses on individual errors or a narrow set of factors, this study [...] Read more.
Errors affect the actual meshing process of gears, alter the actual wear pattern of the tooth profile, and may even impact the overall service life of machinery. While existing research predominantly focuses on individual errors or a narrow set of factors, this study explores the combined effects of multiple errors on tooth profile wear. A comprehensive gear wear prediction model was developed, integrating the slice method, lumped mass method, Hertz contact model, and Archard’s wear theory. This model accounts for initial tooth surface topography, thermal deformation, dynamic effects, and wear, establishing strong correlations between gear wear prediction and key factors such as tooth surface morphology, temperature, and vibration. Experimental validation demonstrated the model’s high accuracy, with relatively small deviations from the observed wear. Initial profile errors (IPEs) at different positions along the tooth width result in varying relative sliding distances, leading to differences in wear depth despite a consistent overall trend. Notably, large IPEs at the dedendum and addendum can influence wear progression, either accelerating or decelerating the wear process over time. Full article
(This article belongs to the Section Machines Testing and Maintenance)
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<p>Flow chart of IPE data acquisition.</p>
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<p>Profile data alignment.</p>
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<p>IPEs of tooth surface.</p>
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<p>Dynamic model.</p>
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<p>Time-varying meshing stiffness model of the gear.</p>
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<p>Diagram of gear TVMS.</p>
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<p>TVMS result.</p>
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<p>Tooth profile before and after thermal deformation.</p>
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<p>The tooth profile is deformed by heat.</p>
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<p>Feedback mechanism of tooth surface wear.</p>
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<p>Equivalent wear experiment.</p>
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<p>EWE data acquisition: (<b>a</b>) Specimen hardness measurement; (<b>b</b>) friction and wear experiments; (<b>c</b>) Specimen wear mark treatment.</p>
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<p>Friction coefficient.</p>
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<p>Specimen wear depth.</p>
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<p>Gear wear prediction process.</p>
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<p>Sliding distance.</p>
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<p>Comparison of sliding distance.</p>
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<p>Meshing force results.</p>
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<p>Wear depth results.</p>
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<p>Wear depth comparison.</p>
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<p>Experimental bench.</p>
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<p>Mass comparison.</p>
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<p>Wear depth obtained based on the tooth profile.</p>
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<p>Average wear at different locations.</p>
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<p>Average wear of different wear times.</p>
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20 pages, 5099 KiB  
Article
Proteomics and EPS Compositional Analysis Reveals Desulfovibrio bisertensis SY-1 Induced Corrosion on Q235 Steel by Biofilm Formation
by Yanan Wang, Ruiyong Zhang, Krishnamurthy Mathivanan, Yimeng Zhang, Luhua Yang, Fang Guan and Jizhou Duan
Materials 2024, 17(20), 5060; https://doi.org/10.3390/ma17205060 (registering DOI) - 17 Oct 2024
Viewed by 108
Abstract
Microorganisms that exist in the seawater form microbial biofilms on materials used in marine construction, especially on metal surfaces submerged in seawater, where they form biofilms and cause severe corrosion. Biofilms are mainly composed of bacteria and their secreted polymeric substances. In order [...] Read more.
Microorganisms that exist in the seawater form microbial biofilms on materials used in marine construction, especially on metal surfaces submerged in seawater, where they form biofilms and cause severe corrosion. Biofilms are mainly composed of bacteria and their secreted polymeric substances. In order to understand how biofilms promote metal corrosion, planktonic and biofilm cells of Desulfovibrio bizertensis SY-1 (D. bizertensis) from Q235 steel were collected and analyzed as to their intracellular proteome and extracellular polymeric substances (EPS). The intracellular proteome analysis showed that the cellular proteins were strongly regulated in biofilm cells compared to planktonic cells, e.g., along with flagellar proteins, signaling-related proteins were significantly increased, whereas energy production and conversion proteins and DNA replication proteins were significantly regulated. The up-and-down regulation of proteins revealed that biofilm formation by bacteria on metal surfaces is affected by flagellar and signaling proteins. A significant decrease in DNA replication proteins indicated that DNA is no longer replicated and transcribed in mature biofilms, thus reducing energy consumption. Quantitative analysis and lectin staining of the biofilm on the metal’s surface revealed that the bacteria secreted a substantial amount of EPS when they began to attach to the surface, and proteins dominated the main components of EPS. Further, the infrared analysis showed that the secondary structure of the proteins in the EPS of the biofilm was mainly dominated by β-sheet and 3-turn helix, which may help to enhance the adhesion of EPS. The functional groups of EPS analyzed using XPS showed that the C element of EPS in the biofilm mainly existed in the form of combinations with N. Furthermore, the hydroxyl structure in the EPS extracted from the biofilm had a stronger hydrogen bonding effect, which could maintain the stability of the EPS structure and biofilm. The study results revealed that D. bizertensis regulates the metabolic pathways and their secreted EPS structure to affect biofilm formation and cause metal corrosion, which has a certain reference significance for the study of the microbially influenced corrosion (MIC) mechanism. Full article
(This article belongs to the Special Issue Future Trend of Marine Corrosion and Protection)
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<p>Scanning electron microscopy (SEM) micrograph images of the Q235 surface from (<b>a</b>) control and (<b>b</b>) <span class="html-italic">D. bizertensis</span>-containing medium. Confocal laser scanning microscopy images of the biofilm cells on the Q235 surface after 15 days immersion, stained with the LIVE/DEAD Biofilm Viability kit (<b>c</b>), and EPS distribution ((<b>d</b>) proteins stained with FITC, (<b>e</b>) polysaccharides stained with Concanavalin A-TRITC, and (<b>f</b>) lipids stained with Nile red). Green coloring indicates live cells, red coloring indicates dead cells, and yellow coloring indicates partially damaged/dead cells.</p>
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<p>(<b>a</b>) XRD of surface products of Q235 steel from control and <span class="html-italic">D. bizertensis</span>-containing medium, and (<b>b</b>) annual corrosion rates of Q235 steel after 15 days incubation. (<b>c</b>,<b>d</b>) The pits and their depths on the Q235 steel coupons from control and <span class="html-italic">D. bizertensis</span>-inoculated media after 15 days.</p>
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<p>(<b>a</b>) Summary of detectable protein contents and functions. (<b>b</b>) Volcano plots representing the results of the proteome analysis in biofilm vs. planktonic cells.</p>
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<p>Up- and down-regulated flagellum-related DEPs in biofilm and planktonic cells.</p>
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<p>Functional category distribution of differentially expressed proteins by GO in biofilm and planktonic cells.</p>
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<p>Differentially expressed proteins in KEEG pathway biofilm cells on the Q235 surface and planktonic cells, (<b>a</b>) biofilm.vs. plankton_up, (<b>b</b>) biofilm.vs.plankton_down.</p>
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<p>Intermittent protein restriction of differentially expressed proteins in biofilm cells on the Q235 surface and in planktonic cells.</p>
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<p>Growth curve (<b>a</b>) and EPS concentration of plankton cell and biofilm cell: (<b>b</b>) total, (<b>c</b>) protein, (<b>d</b>) polysaccharide, and (<b>e</b>) DNA.</p>
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<p>Deconvoluted C 1s and O 1s: High-resolution XPS spectra of EPS of biofilm and planktonic cells. (<b>a</b>) EPS of planktonic cells C 1s, (<b>b</b>) EPS of biofilm cells C 1s, (<b>c</b>) EPS of planktonic cells O 1s, (<b>d</b>) EPS of biofilm cells O 1s.</p>
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<p>FTIR spectra of the amide I region in the EPS: (<b>a</b>) biofilm cells and (<b>b</b>) planktonic cells.</p>
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