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10 pages, 3109 KiB  
Article
A New Paradigm on Waste-to-Energy Applying Hydrovoltaic Energy Harvesting Technology to Face Masks
by Yongbum Kwon, Dai Bui-Vinh, Seung-Hwan Lee, So Hyun Baek, Hyun-Woo Lee, Jeungjai Yun, Inhee Cho, Jeonghoon Lee, Mi Hye Lee, Handol Lee and Da-Woon Jeong
Polymers 2024, 16(17), 2515; https://doi.org/10.3390/polym16172515 - 4 Sep 2024
Viewed by 475
Abstract
The widespread use of single-use face masks during the recent epidemic has led to significant environmental challenges due to waste pollution. This study explores an innovative approach to address this issue by repurposing discarded face masks for hydrovoltaic energy harvesting. By coating the [...] Read more.
The widespread use of single-use face masks during the recent epidemic has led to significant environmental challenges due to waste pollution. This study explores an innovative approach to address this issue by repurposing discarded face masks for hydrovoltaic energy harvesting. By coating the face masks with carbon black (CB) to enhance their hydrophilic properties, we developed mask-based hydrovoltaic power generators (MHPGs). These MHPGs were evaluated for their hydrovoltaic performance, revealing that different mask configurations and sizes affect their efficiency. The study found that MHPGs with smaller, more structured areas exhibited better energy output, with maximum open-circuit voltages (VOC) reaching up to 0.39 V and short-circuit currents (ISC) up to 65.6 μA. The integration of CB improved water absorption and transport, enhancing the hydrovoltaic performance. More specifically, MHPG-1 to MHPG-4, which represented different sizes and features, presented mean VOC values of 0.32, 0.17, 0.19 and 0.05 V, as well as mean ISC values of 16.57, 15.59, 47.43 and 3.02 μA, respectively. The findings highlight the feasibility of utilizing discarded masks in energy harvesting systems, offering both environmental benefits and a novel method for renewable energy generation. Therefore, this work provides a new paradigm for waste-to-energy (WTE) technologies and inspires further research into the use of unconventional waste materials for energy production. Full article
(This article belongs to the Section Circular and Green Polymer Science)
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Graphical abstract

Graphical abstract
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<p>Fabrication of MHPGs and their characterizations. (<b>a</b>) Schematic diagram of MHPG preparation; (<b>b</b>) four different types of MHPG derived from a single face mask; The morphologies of (<b>c</b>) non-coated (raw) face mask and (<b>d</b>) CB-coated face mask (MHPG); (<b>e</b>) MHPG mechanical stability and flexibility tests.</p>
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<p>Surface modification of MHPGs. (<b>a</b>) The structure of carbon black (CB) and its agglomeration characteristics with TEM image; (<b>b</b>) FT−IR spectroscopy comparing raw and CB−coated face masks; EDS patterns of (<b>c</b>) carbon (C, red) in non-coated (raw) face mask and (<b>d</b>) carbon (C, red) and bromine (Br, green) in CB−coated face mask.</p>
Full article ">Figure 3
<p>Operation principal of MHPGs and their electricity generation performance. (<b>a</b>) Schematic representation comparing MHPGs and plant transpiration; (<b>b</b>) open-circuit voltage (<span class="html-italic">V<sub>OC</sub></span>) and (<b>c</b>) short-circuit current (<span class="html-italic">I<sub>SC</sub></span>) distributions of different types of MHPGs. “x” and circle in those subfigures present mean values and electricity output values out of major ranges; long-term generation performance of (<b>d</b>) MHPG-1, (<b>e</b>) MHPG-2, (<b>f</b>) MHPG-3 and (<b>g</b>) MHPG-4; output voltages and currents of MHPG-1 connected (<b>h</b>) in series and (<b>i</b>) parallel.</p>
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<p>Perspectives on waste-to-energy paradigm with hydrovoltaic energy harvesting mechanism and its implications for future implementations.</p>
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15 pages, 5967 KiB  
Article
Advanced Recycling of Modified EDPM Rubber in Bituminous Asphalt Paving
by Daniela Laura Buruiana, Lucian Puiu Georgescu, Gabriel Bogdan Carp and Viorica Ghisman
Buildings 2024, 14(6), 1618; https://doi.org/10.3390/buildings14061618 - 1 Jun 2024
Viewed by 520
Abstract
One of the environmental problems worldwide is the enormous number of surgical masks used during the COVID-19 pandemic due to the measures imposed by the World Health Organization on the mandatory use of masks in public spaces. The current study is a potential [...] Read more.
One of the environmental problems worldwide is the enormous number of surgical masks used during the COVID-19 pandemic due to the measures imposed by the World Health Organization on the mandatory use of masks in public spaces. The current study is a potential circular economy approach to recycling the surgical masks discarded into the environment during the COVID-19 pandemic for use in bituminous asphalt pavement. FTIR analysis showed that the surgical masks used were made from ethylene propylene diene monomer (EPDM) rubber modified with polypropylene. The effects of the addition of surgical masks in bituminous asphalt on the performance of the base course were demonstrated in this study. The morphology and elemental composition of the bituminous asphalt pavement samples with two ratios of surgical mask composition were investigated by SEM-EDX and the performance of the modified bituminous asphalt pavement was determined by Marshall stability, flow rate, solid–liquid ratio, apparent density, and water absorption. The study refers to the technological innovation of using surgical masks in the formulation of AB 31.5 bituminous asphalt base course, which brings tremendous benefits to the environment by reducing the damage caused by the COVID-19 pandemic. Full article
(This article belongs to the Special Issue Advances in Road Pavements)
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Figure 1

Figure 1
<p>Life cycle assessment of surgical masks.</p>
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<p>Gradation of standard bituminous asphalt pavement type AB 31.5 and Sample 2 (0.3% EDPM-PP).</p>
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<p>FTIR spectra of surgical mask.</p>
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<p>FTIR spectra of standard bituminous asphalt pavement (black), Sample 1 (0.1% EDPM-PP) (green), and Sample 2 (0.3% EDPM-PP) (orange).</p>
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<p>SEM images of standard bituminous asphalt pavement, Sample 1 (0.1% EDPM-PP), and Sample 2 (0.3% EDPM-PP).</p>
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<p>EDX elemental map of Sample 2 (0.3% EDPM-PP) bituminous asphalt pavement.</p>
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<p>Stability at 60 °C and flow rate of standard bituminous asphalt pavement, Sample 1 (0.1% EDPM-PP), and Sample 2 (0.3% EDPM-PP).</p>
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<p>Solid–liquid report and water absorption of standard bituminous asphalt pavement, Sample 1 (0.1% EDPM-PP), and Sample 2 (0.3% EDPM-PP).</p>
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<p>Apparent density of standard bituminous asphalt pavement, Sample 1 (0.1% EDPM-PP), and Sample 2 (0.3% EDPM-PP).</p>
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46 pages, 18613 KiB  
Article
Improved Landsat Operational Land Imager (OLI) Cloud and Shadow Detection with the Learning Attention Network Algorithm (LANA)
by Hankui K. Zhang, Dong Luo and David P. Roy
Remote Sens. 2024, 16(8), 1321; https://doi.org/10.3390/rs16081321 - 9 Apr 2024
Cited by 1 | Viewed by 1603
Abstract
Landsat cloud and cloud shadow detection has a long heritage based on the application of empirical spectral tests to single image pixels, including the Landsat product Fmask algorithm, which uses spectral tests applied to optical and thermal bands to detect clouds and uses [...] Read more.
Landsat cloud and cloud shadow detection has a long heritage based on the application of empirical spectral tests to single image pixels, including the Landsat product Fmask algorithm, which uses spectral tests applied to optical and thermal bands to detect clouds and uses the sun-sensor-cloud geometry to detect shadows. Since the Fmask was developed, convolutional neural network (CNN) algorithms, and in particular U-Net algorithms (a type of CNN with a U-shaped network structure), have been developed and are applied to pixels in square patches to take advantage of both spatial and spectral information. The purpose of this study was to develop and assess a new U-Net algorithm that classifies Landsat 8/9 Operational Land Imager (OLI) pixels with higher accuracy than the Fmask algorithm. The algorithm, termed the Learning Attention Network Algorithm (LANA), is a form of U-Net but with an additional attention mechanism (a type of network structure) that, unlike conventional U-Net, uses more spatial pixel information across each image patch. The LANA was trained using 16,861 512 × 512 30 m pixel annotated Landsat 8 OLI patches extracted from 27 images and 69 image subsets that are publicly available and have been used by others for cloud mask algorithm development and assessment. The annotated data were manually refined to improve the annotation and were supplemented with another four annotated images selected to include clear, completely cloudy, and developed land images. The LANA classifies image pixels as either clear, thin cloud, cloud, or cloud shadow. To evaluate the classification accuracy, five annotated Landsat 8 OLI images (composed of >205 million 30 m pixels) were classified, and the results compared with the Fmask and a publicly available U-Net model (U-Net Wieland). The LANA had a 78% overall classification accuracy considering cloud, thin cloud, cloud shadow, and clear classes. As the LANA, Fmask, and U-Net Wieland algorithms have different class legends, their classification results were harmonized to the same three common classes: cloud, cloud shadow, and clear. Considering these three classes, the LANA had the highest (89%) overall accuracy, followed by Fmask (86%), and then U-Net Wieland (85%). The LANA had the highest F1-scores for cloud (0.92), cloud shadow (0.57), and clear (0.89), and the other two algorithms had lower F1-scores, particularly for cloud (Fmask 0.90, U-Net Wieland 0.88) and cloud shadow (Fmask 0.45, U-Net Wieland 0.52). In addition, a time-series evaluation was undertaken to examine the prevalence of undetected clouds and cloud shadows (i.e., omission errors). The band-specific temporal smoothness index (TSIλ) was applied to a year of Landsat 8 OLI surface reflectance observations after discarding pixel observations labelled as cloud or cloud shadow. This was undertaken independently at each gridded pixel location in four 5000 × 5000 30 m pixel Landsat analysis-ready data (ARD) tiles. The TSIλ results broadly reflected the classification accuracy results and indicated that the LANA had the smallest cloud and cloud shadow omission errors, whereas the Fmask had the greatest cloud omission error and the second greatest cloud shadow omission error. Detailed visual examination, true color image examples and classification results are included and confirm these findings. The TSIλ results also highlight the need for algorithm developers to undertake product quality assessment in addition to accuracy assessment. The LANA model, training and evaluation data, and application codes are publicly available for other researchers. Full article
(This article belongs to the Special Issue Deep Learning on the Landsat Archive)
Show Figures

Figure 1

Figure 1
<p>Distribution of the annotated USGS images, SPARCS image subsets and SDSU images, each composed of Collection 1 Landsat 8 OLI 30 m TOA reflectance bands and corresponding 30 m annotations (cloud, thin cloud, cloud shadow, or clear). The USGS and SDSU images cover ~185 × 180 km (typically 6200 × 6000 30 m pixels) and the SPARCS subsets cover 1000 × 1000 30 m pixels. The circled USGS images show the five set aside annotated USGS Landsat 8 OLI evaluation images used for accuracy assessment (<a href="#sec3dot5-remotesensing-16-01321" class="html-sec">Section 3.5</a>). The locations of the Collection 2 ARD 5000 × 5000 30 m pixel tiles are also shown (see <a href="#sec2dot4-remotesensing-16-01321" class="html-sec">Section 2.4</a>).</p>
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<p>The four 5000 × 5000 30 m pixel ARD tiles used in the time-series analysis (<b>a</b>) tile h28v04 (Canada/US), (<b>b</b>) tile h05v13 (Mexico/US), (<b>c</b>) tile h15v06 (South Dakota), (<b>d</b>) tile h27v19 (Florida). The median of the cloud-free red, green, blue (true color) Landsat 8 TOA reflectance sensed from 1 May to 30 September 2021 (with Fmask labeled clouds and cloud shadows masked out) is illustrated. The colored boxes show 500 × 500 30 m subsets selected for detailed visual examination that are illustrated in <a href="#sec4-remotesensing-16-01321" class="html-sec">Section 4</a>.</p>
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<p>The LANA structure used to classify 512 × 512 30 m pixel patches with eight Landsat 8 spectral bands into four classes: cloud, thin cloud, cloud shadow, and clear. The horizontal gray arrows show skip connections used to copy feature maps from the encoder (light gray rectangles) to their decoder block counterpart. The black curved arrows show the attention mechanism interactions.</p>
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<p>The overall accuracy of the 4% validation dataset as a function of training epoch ((<b>top</b>): Epochs 1–180; (<b>bottom</b>) epochs: 171–180) for different training parameters using the LANA (64) structure (shown in <a href="#remotesensing-16-01321-f003" class="html-fig">Figure 3</a>). The black line shows the optimal parameter set results (see text) and the colored lines show the results for parameter combinations where one parameter was different to the optimal set.</p>
Full article ">Figure 4 Cont.
<p>The overall accuracy of the 4% validation dataset as a function of training epoch ((<b>top</b>): Epochs 1–180; (<b>bottom</b>) epochs: 171–180) for different training parameters using the LANA (64) structure (shown in <a href="#remotesensing-16-01321-f003" class="html-fig">Figure 3</a>). The black line shows the optimal parameter set results (see text) and the colored lines show the results for parameter combinations where one parameter was different to the optimal set.</p>
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<p>The annual number of Landsat 8 OLI non-cirrus and non-saturated observations flagged as “clear” from 1 January to 31 December 2021 by the three algorithms at each 5000 × 5000 30 m ARD pixel of the Florida tile (h28v04, illustrated in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>d). The bottom row shows the annual number of Landsat 8 OLI observations, regardless of the cirrus or saturation state, and the annual number of non-cirrus and non-saturated (<span class="html-italic">n</span>) observations at each ARD pixel. The white and black squares show 500 × 500 30 m pixel subsets (also shown in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>d), for which algorithm classification results are illustrated in <a href="#remotesensing-16-01321-f006" class="html-fig">Figure 6</a> and <a href="#remotesensing-16-01321-f007" class="html-fig">Figure 7</a>.</p>
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<p>Two dates (columns) of the Fmask, LANA, and U-Net Wieland classification results (rows) for a 500 × 500 30 m pixel Florida tile subset over land (subset boundary shown black in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>d and <a href="#remotesensing-16-01321-f005" class="html-fig">Figure 5</a>). The top row shows the true color (red, green, blue) 30 m reflectance for context. The left and right columns show the dates in 2021 with the most different classification results between LANA and Fmask, and between LANA and U-Net Wieland, respectively. The LANA algorithm results are shown colored as cloud (dark blue), thin cloud (light blue), cloud shadow (black), and clear (green). The Fmask and U-Net Wieland results harmonized to three classes are shown similarly colored as cloud (dark blue), cloud shadow (black), and clear (green).</p>
Full article ">Figure 7
<p>As <a href="#remotesensing-16-01321-f006" class="html-fig">Figure 6</a> but for a 500 × 500 30 m pixel Florida tile subset over water (subset boundary show white in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>d and <a href="#remotesensing-16-01321-f005" class="html-fig">Figure 5</a>).</p>
Full article ">Figure 8
<p>The annual number of Landsat 8 OLI non-cirrus and non-saturated observations flagged as “clear” from 1 January to 31 December 2021 by the three algorithms at each 5000 × 5000 30 m ARD pixel of the Canada/US tile (h28v04, illustrated in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>a). The bottom row shows the annual number of Landsat 8 OLI observations, regardless of the cirrus or saturation state, and the annual number of non-cirrus and non-saturated (<span class="html-italic">n</span>) observations at each ARD pixel. The white and black squares show 500 × 500 30 m pixel subsets (also shown in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>a), for which algorithm classification results are illustrated in <a href="#remotesensing-16-01321-f009" class="html-fig">Figure 9</a> and <a href="#remotesensing-16-01321-f010" class="html-fig">Figure 10</a>.</p>
Full article ">Figure 9
<p>Two dates (columns) of the Fmask, LANA, and U-Net Wieland classification results (rows) for a 500 × 500 30 m pixel Canada/US tile subset over forest (subset boundary shown black in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>a and <a href="#remotesensing-16-01321-f007" class="html-fig">Figure 7</a>). The top row shows the true color (red, green, blue) 30 m reflectance for context. The left and right columns show the dates in 2021 with the most different classification results between LANA and Fmask, and between LANA and U-Net Wieland, respectively. The LANA algorithm results are shown colored as cloud (dark blue), thin cloud (light blue), cloud shadow (black), and clear (green). The Fmask and U-Net Wieland results harmonized to three classes are shown similarly colored as cloud (dark blue), cloud shadow (black), and clear (green).</p>
Full article ">Figure 10
<p>As <a href="#remotesensing-16-01321-f009" class="html-fig">Figure 9</a> but for a 500 × 500 30 m pixel Canada/US tile subset over a water and cropland mixed area (subset boundary shown in white in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>a and <a href="#remotesensing-16-01321-f008" class="html-fig">Figure 8</a>).</p>
Full article ">Figure 10 Cont.
<p>As <a href="#remotesensing-16-01321-f009" class="html-fig">Figure 9</a> but for a 500 × 500 30 m pixel Canada/US tile subset over a water and cropland mixed area (subset boundary shown in white in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>a and <a href="#remotesensing-16-01321-f008" class="html-fig">Figure 8</a>).</p>
Full article ">Figure 11
<p>The annual number of Landsat 8 OLI non-cirrus and non-saturated observations flagged as “clear” from 1 January to 31 December 2021 by the three algorithms at each 5000 × 5000 30 m ARD pixel of the Mexico/US tile (h05v13, illustrated in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>b). The bottom row shows the annual number of Landsat 8 OLI observations, regardless of the cirrus or saturation state, and the annual number of non-cirrus and non-saturated (<span class="html-italic">n</span>) observations at each ARD pixel. The white and black squares show 500 × 500 30 m pixel subsets (also shown in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>b), for which algorithm classification results are illustrated in <a href="#remotesensing-16-01321-f012" class="html-fig">Figure 12</a> and <a href="#remotesensing-16-01321-f013" class="html-fig">Figure 13</a>.</p>
Full article ">Figure 12
<p>Two dates (columns) of the Fmask, LANA, and U-Net Wieland classification results (rows) for a 500 × 500 30 m pixel Mexico/US tile subset over desert (subset boundary shown in black in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>b and <a href="#remotesensing-16-01321-f010" class="html-fig">Figure 10</a>). The top row shows the true color (red, green, blue) 30 m reflectance for context. The left and right columns show the dates in 2021 with the most different classification results between LANA and Fmask, and between LANA and U-Net Wieland, respectively. The LANA algorithm results are shown colored as cloud (dark blue), thin cloud (light blue), cloud shadow (black), and clear (green). The Fmask and U-Net Wieland results harmonized to three classes are shown similarly colored as cloud (dark blue), cloud shadow (black), and clear (green).</p>
Full article ">Figure 13
<p>As <a href="#remotesensing-16-01321-f012" class="html-fig">Figure 12</a> but for a 500 × 500 30 m pixel Mexico/US tile subset over a desert and cropland mixed area (subset boundary shown in white in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>b and <a href="#remotesensing-16-01321-f010" class="html-fig">Figure 10</a>).</p>
Full article ">Figure 13 Cont.
<p>As <a href="#remotesensing-16-01321-f012" class="html-fig">Figure 12</a> but for a 500 × 500 30 m pixel Mexico/US tile subset over a desert and cropland mixed area (subset boundary shown in white in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>b and <a href="#remotesensing-16-01321-f010" class="html-fig">Figure 10</a>).</p>
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<p>The annual number of Landsat 8 OLI non-cirrus and non-saturated observations flagged as “clear” from 1 January to 31 December 2021 by the three algorithms at each 5000 × 5000 30 m ARD pixel of the South Dakota tile (h15v06, illustrated in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>c). The bottom row shows the annual number of Landsat 8 OLI observations, regardless of the cirrus or saturation state, and the annual number of non-cirrus and non-saturated (<span class="html-italic">n</span>) observations at each ARD pixel. The white and black squares show 500 × 500 30 m pixel subsets (also shown in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>c), for which algorithm classification results are illustrated in <a href="#remotesensing-16-01321-f015" class="html-fig">Figure 15</a> and <a href="#remotesensing-16-01321-f016" class="html-fig">Figure 16</a>.</p>
Full article ">Figure 15
<p>As <a href="#remotesensing-16-01321-f015" class="html-fig">Figure 15</a>, but for a 500 × 500 30 m pixel South Dakota tile subset over a cropland area (subset boundary shown in white in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>c and <a href="#remotesensing-16-01321-f014" class="html-fig">Figure 14</a>).</p>
Full article ">Figure 15 Cont.
<p>As <a href="#remotesensing-16-01321-f015" class="html-fig">Figure 15</a>, but for a 500 × 500 30 m pixel South Dakota tile subset over a cropland area (subset boundary shown in white in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>c and <a href="#remotesensing-16-01321-f014" class="html-fig">Figure 14</a>).</p>
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<p>Two dates (columns) of the Fmask, LANA, and U-Net Wieland classifications results (rows) for a 500 × 500 30 m pixel South Dakota tile subset over Missouri River (subset boundary shown in black in <a href="#remotesensing-16-01321-f002" class="html-fig">Figure 2</a>c and <a href="#remotesensing-16-01321-f014" class="html-fig">Figure 14</a>). The top row shows the true color (red, green, blue) 30 m reflectance for context. The left and right columns show the dates in 2021 with the most different classification results between LANA and Fmask, and between LANA and U-Net Wieland, respectively. The LANA algorithm results are shown colored as cloud (dark blue), thin cloud (light blue), cloud shadow (black), and clear (green). The Fmask and U-Net Wieland results harmonized to three classes are shown similarly colored as cloud (dark blue), cloud shadow (black), and clear (green).</p>
Full article ">
17 pages, 3072 KiB  
Article
Mask-Pyramid Network: A Novel Panoptic Segmentation Method
by Peng-Fei Xian, Lai-Man Po, Jing-Jing Xiong, Yu-Zhi Zhao, Wing-Yin Yu and Kwok-Wai Cheung
Sensors 2024, 24(5), 1411; https://doi.org/10.3390/s24051411 - 22 Feb 2024
Cited by 1 | Viewed by 1055
Abstract
In this paper, we introduce a novel panoptic segmentation method called the Mask-Pyramid Network. Existing Mask RCNN-based methods first generate a large number of box proposals and then filter them at each feature level, which requires a lot of computational resources, while most [...] Read more.
In this paper, we introduce a novel panoptic segmentation method called the Mask-Pyramid Network. Existing Mask RCNN-based methods first generate a large number of box proposals and then filter them at each feature level, which requires a lot of computational resources, while most of the box proposals are suppressed and discarded in the Non-Maximum Suppression process. Additionally, for panoptic segmentation, it is a problem to properly fuse the semantic segmentation results with the Mask RCNN-produced instance segmentation results. To address these issues, we propose a new mask pyramid mechanism to distinguish objects and generate much fewer proposals by referring to existing segmented masks, so as to reduce computing resource consumption. The Mask-Pyramid Network generates object proposals and predicts masks from larger to smaller sizes. It records the pixel area occupied by the larger object masks, and then only generates proposals on the unoccupied areas. Each object mask is represented as a H × W × 1 logit, which fits well in format with the semantic segmentation logits. By applying SoftMax to the concatenated semantic and instance segmentation logits, it is easy and natural to fuse both segmentation results. We empirically demonstrate that the proposed Mask-Pyramid Network achieves comparable accuracy performance on the Cityscapes and COCO datasets. Furthermore, we demonstrate the computational efficiency of the proposed method and obtain competitive results. Full article
(This article belongs to the Section Sensing and Imaging)
Show Figures

Figure 1

Figure 1
<p>Overview of Mask-Pyramid Network architecture. It consists of Semantic Branch and Mask-Pyramid Branch. Semantic Branch produces coarse semantic segmentation mask logits, the segmentation mask will be improved when calculating SoftMax with MPN segmentation logits later. Mask-Pyramid Branch generates mask logits for each instance object in the image. Both branches generate H*W*k segmentation logits, the concatenated logits are naturally fused by applying SoftMax operation.</p>
Full article ">Figure 2
<p>Overview of the Mask-PNet Pipeline. The left part (<b>a</b>) shows the overall interactive flow. Take the “stuff” layers of the semantic segmentation result as the initial mask logits. Then, generate a seed map based on the empty area of the mask logits, and filter the ResNet features with the seed map. Afterward, feed the filtered features into CNN to obtain logits of the newly detected objects, and merge new logits to update the mask logits. Next, generate a new seed map and repeat these steps until the seed map is fulfilled. The right part (<b>b</b>) demonstrates in detail the process of generating a seed map and filtered features. Take the 4*4 feature level as an example. First, extract the empty area of the existing logits. By using the average low-pass filter, we can downsample the 128*128 empty area map into a 4*4 Boolean seed map. Then, elementary multiply the seed map with the features from the ResNet to obtain the filtered feature. Next, generate new logits via CNN and concatenate them with existing mask logits to obtain updated mask logits and execute the next loop.</p>
Full article ">Figure 3
<p>Illustration of the mask logits updating process. The first image shows the initial mask logits from the “stuff” area of the semantic segmentation result. The second image shows three newly generated object masks from the 2*2 features, the seed map provides four proposals, CNN predicts three valid mask logits, and the other logit is suppressed by the “stuff” logits. The third and fourth images show three new mask logits generated from the 4*4, and 8*8 features, respectively. The last image shows seven newly generated mask logits out of the 16*16 features.</p>
Full article ">Figure 4
<p>The segmentation precision comparison between the semantic segmentation branch result and the final fused result on “stuff” categories. At all categories, the “stuff” segmentation results after the MP branch fused logits are more accurate than the results of the original semantic branch.</p>
Full article ">Figure 5
<p>Visualization of panoptic segmentation performance comparison between Mask RCNN and proposed Mask Pyramids Network on the Cityscapes validation set. The difference area is marked in red circles.</p>
Full article ">Figure 6
<p>Visualization of panoptic segmentation performance results of the Mask Pyramids Network on the COCO validation dataset.</p>
Full article ">
18 pages, 17352 KiB  
Article
Experimental Study on the Mechanical Properties of Disposable Mask Waste–Reinforced Gangue Concrete
by Yu Yang, Changhao Xin, Yidan Sun, Junzhen Di, Fankang Meng and Xinhua Zhou
Materials 2024, 17(4), 948; https://doi.org/10.3390/ma17040948 - 18 Feb 2024
Cited by 1 | Viewed by 1283
Abstract
This paper is grounded on the following information: (1) Disposable masks primarily consist of polypropylene fiber, which exhibits excellent flexibility. (2) China has extensive coal gangue deposits that pose a significant environmental hazard. (3) Coal gangue concrete exhibits greater fragility compared to regular [...] Read more.
This paper is grounded on the following information: (1) Disposable masks primarily consist of polypropylene fiber, which exhibits excellent flexibility. (2) China has extensive coal gangue deposits that pose a significant environmental hazard. (3) Coal gangue concrete exhibits greater fragility compared to regular concrete and demonstrates reduced resistance to deformation. With the consideration of environmental conservation and resource reutilization, a preliminary concept suggests the conversion of discarded masks into fibers, which can be blended with coal gangue concrete to enhance its mechanical characteristics. In this paper, the stress–strain law of different mask fiber–doped coal gangue concrete (DMGC) under uniaxial compression is studied when the matrix strength is C20 and C30, and the effect of mask fiber content on the mechanical behavior and energy conversion relationship of coal gangue concrete is analyzed. The experimental results show that when the content of mask fiber is less than 1.5%, the strength, elastic modulus, deformation resistance, and energy dissipation of the concrete increase with mask fiber content. When the amount of mask fiber is more than 1.5%, because the tensile capacity and energy dissipation level of concrete produced by the mask fiber cannot compensate for the compression and deformation resistance of concrete of the same quantity and because excess fiber is difficult to evenly mix in the concrete, there are pore defects in concrete, which decreases the concrete strength due to the increase in mask fiber. Therefore, adding less than 1.5% mask fiber helps to improve the ductility, toughness, impermeability, and oxidation and control the cracking of coal gangue concrete. Based on Weibull theory, a constitutive model of DMGC is established, which fits well with the results of a uniaxial test, providing support for understanding the mechanical law of mask fiber–doped concrete. Full article
(This article belongs to the Section Construction and Building Materials)
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<p>Coarse aggregate of coal gangue and its energy spectrum. (<b>a</b>) Spontaneous combustion coal gangue from Haizhou Ping’an Mine in Fuxin; (<b>b</b>) energy spectrum of coal gangue.</p>
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<p>Test system.</p>
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<p>Coarse bone gradation curve. (<b>a</b>) 5~20 mm; (<b>b</b>) 5~10 mm.</p>
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<p>Concrete production process. (<b>a</b>) Mask fiber; (<b>b</b>) coal gangue concrete dry mix.</p>
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<p>The variation of the Poisson ratio and elastic modulus of DMGC. (<b>a</b>) Elastic modulus; (<b>b</b>) Poisson ratio.</p>
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<p>Stress–strain curves of DMGC. (<b>a</b>) C20; (<b>b</b>) C30.</p>
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<p>Energy evolution characteristics of mask–reinforced gangue concrete (DMGC).</p>
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<p>Energy evolution law of DMGC with a matrix strength grade of C20. (<b>a</b>) Elastic strain energy; (<b>b</b>) dissipated energy; (<b>c</b>) total strain energy.</p>
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<p>Energy evolution law of DMGC with a matrix strength grade of C30. (<b>a</b>) Elastic strain energy; (<b>b</b>) dissipated energy; (<b>c</b>) total strain energy.</p>
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<p>Energy conversion ratio of DMGC.</p>
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<p>Energy evolution law of DMGC with a matrix strength grade of C20. (<b>a</b>) DMGC–20–0.5; (<b>b</b>) DMGC–20–1.0; (<b>c</b>) DMGC–20–1.5; (<b>d</b>) DMGC–20–2.0; (<b>e</b>) DMGC–20–2.5; (<b>f</b>) OG–20.</p>
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<p>Damage evolution characteristics of DMGC. (<b>a</b>) C20; (<b>b</b>) C30.</p>
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16 pages, 4926 KiB  
Article
Pilot-Scale Melt Electrospinning of Polybutylene Succinate Fiber Mats for a Biobased and Biodegradable Face Mask
by Maike-Elisa Ostheller, Naveen Kumar Balakrishnan, Konrad Beukenberg, Robert Groten and Gunnar Seide
Polymers 2023, 15(13), 2936; https://doi.org/10.3390/polym15132936 - 3 Jul 2023
Cited by 6 | Viewed by 1640
Abstract
The COVID-19 pandemic led to a huge demand for disposable facemasks. Billions were manufactured from nonbiodegradable petroleum-derived polymers, and many were discarded in the environment where they contributed to plastic pollution. There is an urgent need for biobased and biodegradable facemasks to avoid [...] Read more.
The COVID-19 pandemic led to a huge demand for disposable facemasks. Billions were manufactured from nonbiodegradable petroleum-derived polymers, and many were discarded in the environment where they contributed to plastic pollution. There is an urgent need for biobased and biodegradable facemasks to avoid environmental harm during future disease outbreaks. Melt electrospinning is a promising alternative technique for the manufacturing of filter layers using sub-microfibers prepared from biobased raw materials such as polybutylene succinate (PBS). However, it is not yet possible to produce sub-micrometer PBS fibers or uniform nonwoven-like samples at the pilot scale, which hinders their investigation as filter layers. Further optimization of pilot-scale PBS melt electrospinning is therefore required. Here, we tested the effect of different parameters such as electric field strength, nozzle-to-collector distance and throughput on the final fiber diameter and sample uniformity during PBS melt electrospinning on a pilot-scale device. We also studied the effect of a climate chamber and an additional infrared heater on the solidification of PBS fibers and their final diameter and uniformity. In addition, a post-processing step, including a hot air stream of 90 °C for 30 s has been studied and successfully lead to a nonwoven-like structure including filaments that weld together without changing their structure. The finest fibers (1.7 µm in diameter) were produced at an applied electric field strength of −40 kV, a nozzle-to-collector distance of 5.5 cm, and a spin pump speed of 2 rpm. Three uniform nonwoven-like samples were tested as filter layers in a medical face mask by measuring their ability to prevent the transfer of bacteria, but the pore size was too large for effective retention. Our results provide insight into the process parameters influencing the suitability of melt-electrospun nonwoven-like samples as biobased and biodegradable filter materials and offer guidance for further process optimization. Full article
(This article belongs to the Section Smart and Functional Polymers)
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<p>Pilot-scale melt electrospinning prototype including a 600-nozzle plate, showing the placement and design of the individual nozzles (upper magnifying glass); and the filaments ejected by the individual nozzles that are being collected as nonwoven like samples on an aluminum plate (lower magnifying glass).</p>
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<p>Schematic drawing of the melt-electrospinning setup showing (<b>a</b>) the 600-nozzle pilot-scale device; (<b>b</b>) the addition of a glass chamber; (<b>c</b>) the additional infrared heating source; and (<b>d</b>) the position of the infrared camera.</p>
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<p>The spinneret of the pilot-scale melt electrospinning device heated to 235 °C. The surface temperature of the nozzles was recorded (<b>a</b>) without a glass chamber and (<b>b</b>) with a glass chamber. (<b>c</b>) The temperature inside the glass chamber. (<b>d</b>) The surface temperature of the nozzles in the presence of a supplementary infrared heating device.</p>
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<p>Heating cycle of PBS cooled at different cooling rates from 100 K/s to 0.167 K/s using flash differential scanning calorimetry.</p>
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<p>Rheogram showing the complex viscosity of PBS as a function of temperature at an angular frequency of 10 rad/s.</p>
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<p>Diameter of PBS fibers produced using a pilot-scale melt electrospinning device with a spinneret temperature of 235 °C, a spin pump speed of 2, 5 or 10 rpm, a nozzle-to-collector distance of 3.5, 4, 5, 5.5, 6, 6.5 or 7 cm, 600 nozzles (0.3 mm diameter), and an electric field strength of (<b>a</b>) −30 kV, (<b>b</b>) −35 kV, (<b>c</b>) −40 kV and (<b>d</b>) −45 kV. Data are means ± standard deviation (<span class="html-italic">n</span> = 100).</p>
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<p>Fiber web samples produced using the pilot-scale melt electrospinning device at an applied field strength of −35 kV, a pump speed of 5 rpm, and a nozzle-to-collector distance of 5 cm. (<b>a</b>) Sample produced by the slow clockwise rotation of the thin paperboard placed above the collector. (<b>b</b>) Sample produced without the slow clockwise rotation of the thin paperboard placed above the collector.</p>
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<p>Optical microscopy images of PBS melt-electrospun fibers. (<b>a</b>) Sample before heat processing. (<b>b</b>) Sample after heat processing.</p>
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<p>Comparison of a commercial medical face mask and a prototype mask incorporating a melt-electrospun PBS filter layer. (<b>a</b>) The disassembled reference medical face mask. (<b>b</b>) The layers of the prototype mask before assembly.</p>
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<p>Comparison of the filter layers of (<b>a</b>) the commercial medical face mask and (<b>b</b>–<b>d</b>) three prototypes based on melt-electrospun PBS samples.</p>
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<p>Plate images to provide a visual representation of the differences in bacterial filtration efficiency between reference and prototype masks. (<b>a</b>) The reference face mask. (<b>b</b>) Positive control according to ASTM Test Method S210-01. (<b>c</b>–<b>e</b>) The three prototype masks.</p>
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19 pages, 6751 KiB  
Article
MRS-Transformer: Texture Splicing Method to Remove Defects in Solid Wood Board
by Yizhuo Zhang, Xingyu Liu, Hantao Liu and Huiling Yu
Appl. Sci. 2023, 13(12), 7006; https://doi.org/10.3390/app13127006 - 10 Jun 2023
Viewed by 1336
Abstract
Defects in wood growth affect the product’s quality and grade. At present, the research on texture defects of wood mainly focuses on defect localization, ignoring the splicing problem of maintaining texture consistency. In this paper, we designed the MRS-Transformer network and introduced image [...] Read more.
Defects in wood growth affect the product’s quality and grade. At present, the research on texture defects of wood mainly focuses on defect localization, ignoring the splicing problem of maintaining texture consistency. In this paper, we designed the MRS-Transformer network and introduced image inpainting to the field of solid wood board splicing. First, we proposed an asymmetric encoder-decoder based on Vision Transformer, where the encoder uses a fixed mask(M) strategy, discarding the masked patches and using only the unmasked visual patches as input to reduce model calculations. Second, we designed a reverse Swin (RS) module with multi-scale characteristics as the decoder to adjust the divided image patches’ size and complete the restoration from coarse to fine. Finally, we proposed a weighted L2 loss (MSE, mean square error), which assigns different weights to the unmasked region according to the distance from the defective region, allowing the model to make full use of the effective pixels to repair the masked region. To demonstrate the effectiveness of the designed modules, we used MSE (mean square error), LPIPS (learned perceptual image patch similarity), PSNR (peak signal to noise ratio), SSIM (structural similarity), and FLOPs (floating point operations) to measure the quality of the model generated wood texture images and the model computational complexity, we designed relevant ablation experiments. The results show that the MSE, LPIPS, PSNR, and SSIM of the wood images restored by the MRS-Transformer reached 0.0003, 0.154, 40.12, 0.9173, and the GFLOPs is 20.18. Compared with images generated by the Vision Transformer, the MSE and LPIPS were reduced by 51.7% and 30%, PSNR and SSIM were improved by 12.2% and 7.5%, and the GFLOPs were reduced by 38%. To verify the superiority of MRS-Transformer, we compared the image inpainting algorithms with Deepfill v2 and TG-Net, respectively, in which the MSE was 47.0% and 66.9% lower; the LPIPS was 60.6% and 42.5% lower; the FLOPs was 70.6% and 53.5% lower; the PSNR was 16.1% and 26.2% higher; and the SSIM was 7.3% and 5.8% higher. MRS-Transformer repairs a single image in 0.05 s, nearly five times faster than Deepfill v2 and TG-Net. The experimental results demonstrate that the RSwin module effectively alleviates the sense of fragmentation caused by the division of images into patches, the proposed weighted L2 loss improves the semantic consistency of the edges of the missing regions and makes the generated wood texture more detailed and coherent, and the adopted asymmetric encoder-decoder effectively reduces the computational effort of the model and speeds up the training. Full article
(This article belongs to the Special Issue AI Applications in the Industrial Technologies)
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<p>The architecture of wood texture restoration with Vision Transformer.</p>
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<p>Steps for restoring texture in defective solid wood board images.</p>
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<p>Architecture of the asymmetric encoder-decoder.</p>
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<p>The architecture of Decoder (RSwin) and principles of W-MSA and SW-MSA.</p>
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<p>The principle of Patch Diverging.</p>
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<p>The architecture of MRS-Transformer (texture splicing method to remove defects in the solid wood board).</p>
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<p>A sample of data augmentation.</p>
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<p>Some samples with texture defects.</p>
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<p>Effect of defective wood reconstruction.</p>
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<p>Comparison of results of ablation experiments.</p>
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<p>Comparison of restoration results with DeepFill v2 and TG-Net for MRS-Transformer.</p>
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16 pages, 5107 KiB  
Article
Efficacy Evaluation of Cu- and Ag-Based Antibacterial Treatments on Polypropylene Fabric and Comparison with Commercial Products
by Nunzia Gallo, Giorgia Natalia Iaconisi, Mauro Pollini, Federica Paladini, Sudipto Pal, Concetta Nobile, Loredana Capobianco, Antonio Licciulli, Giovanna Giuliana Buonocore, Antonella Mansi, Luca Salvatore and Alessandro Sannino
Coatings 2023, 13(5), 919; https://doi.org/10.3390/coatings13050919 - 14 May 2023
Cited by 2 | Viewed by 2500
Abstract
Filter masks are disposable devices intended to be worn in order to reduce exposure to potentially harmful foreign agents of 0.1–10.0 microns. However, to perform their function correctly, these devices should be replaced after a few hours of use. Because of this, billions [...] Read more.
Filter masks are disposable devices intended to be worn in order to reduce exposure to potentially harmful foreign agents of 0.1–10.0 microns. However, to perform their function correctly, these devices should be replaced after a few hours of use. Because of this, billions of non-biodegradable face masks are globally discarded every month (3 million/minute). The frequent renewal of masks, together with the strong environmental impact of non-biodegradable plastic-based mask materials, highlights the need to find a solution to this emerging ecological problem. One way to reduce the environmental impact of masks, decrease their turnover, and, at the same time, increase their safety level is to make them able to inhibit pathogen proliferation and vitality by adding antibacterial materials such as silver, copper, zinc, and graphene. Among these, silver and copper are the most widely used. In this study, with the aim of improving commercial devices’ efficacy and eco-sustainability, Ag-based and Cu-based antibacterial treatments were performed and characterized from morphological, compositional, chemical–physical, and microbiological points of view over time and compared with the antibacterial treatments of selected commercial products. The results demonstrated the good distribution of silver and copper particles onto the surface of the masks, along with almost 100% antibacterial capabilities of the coatings against both Gram-positive and Gram-negative bacteria, which were still confirmed even after several washing cycles, thus indicating the good potential of the developed prototypes for mask application. Full article
(This article belongs to the Special Issue Advances in Antibacterial Coatings: From Materials to Applications)
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<p>SEM images of the prototypal SIL (<b>a</b>–<b>c</b>) and COP (<b>d</b>–<b>f</b>) antibacterial fabric, before and after washing cycles. Scale bar: 50 µm.</p>
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<p>SEM images of the commercial ARG (<b>a</b>–<b>c</b>) and ABS (<b>d</b>–<b>f</b>) antibacterial fabric, before and after washing cycles. Scale bar: 50 µm.</p>
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<p>SEM images of the commercial OLV (<b>a</b>–<b>c</b>),RES (<b>d</b>–<b>f</b>) and PRI (<b>g</b>–<b>i</b>) antibacterial fabric, before and after washing cycles. Scale bar: 50 µm.</p>
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<p>XRD patterns of the prototypal SIL (<b>a</b>) and COP (<b>b</b>) and of the commercial OLV (<b>c</b>) and RES (<b>d</b>).</p>
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<p>Percentage reduction of the antibacterial activity of prototypal and commercial fabrics before (black) and after 3 W (dark gray) and 10 W (light gray), after 1 h of incubation with 4 × 10<sup>6</sup> CFU/mL <span class="html-italic">E. coli</span> suspension. Values indicated represent mean ± SD, where <span class="html-italic">n</span> = 4.</p>
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<p>Percentage reduction of the antibacterial activity of prototypal and commercial fabric before (black) and after 3 W (dark gray) and 10 W (light gray), after 1 h of incubation with 4 × 10<sup>6</sup> CFU/mL <span class="html-italic">S. aureus</span> suspension. Values indicated represent mean ± SD, where <span class="html-italic">n</span> = 4.</p>
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11 pages, 499 KiB  
Article
A Multidimensional Spectral Transformer with Channel-Wise Correlation for Hyperspectral Image Classification
by Kai Zhang, Zheng Tan, Jianying Sun, Baoyu Zhu, Yuanbo Yang and Qunbo Lv
Appl. Sci. 2023, 13(9), 5482; https://doi.org/10.3390/app13095482 - 28 Apr 2023
Viewed by 1149
Abstract
Convolutional neural networks (CNNs) have been developed as an effective strategy for hyperspectral image (HSI) classification. However, the lack of feature extraction by CNN networks is due to the network failing to effectively extract global features and poor capability in distinguishing between different [...] Read more.
Convolutional neural networks (CNNs) have been developed as an effective strategy for hyperspectral image (HSI) classification. However, the lack of feature extraction by CNN networks is due to the network failing to effectively extract global features and poor capability in distinguishing between different feature categories that are similar. In order to solve these problems, this paper proposes a novel approach to hyperspectral image classification using a multidimensional spectral transformer with channel-wise correlation. The proposed method consists of two key components: an input mask and a channel correlation block. The input mask is used to extract relevant spectral information from hyperspectral images and discard irrelevant information, reducing the dimensionality of the input data and improving classification accuracy. The channel correlation block captures the correlations between different spectral channels and is integrated into the transformer network to improve the model’s discrimination power. The experimental results demonstrate that the proposed method achieves great performance with several benchmark hyperspectral image datasets. The input mask and channel correlation block effectively improve classification accuracy and reduce computational complexity. Full article
(This article belongs to the Special Issue Spectral Detection: Technologies and Applications)
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<p>Architecture of our proposed MSTCC.</p>
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<p>Input mask to extract features. Each pixel generated its own mask with normalized corrections.</p>
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<p>Channel correlation block-computed matrix when training, supporting the matrix during testing.</p>
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<p>Classification maps of different classification methods on the IP dataset. (<b>a</b>) CNN-2D. (<b>b</b>) CNN-3D. (<b>c</b>) FCN-ELM. (<b>d</b>) Spectral Former. (<b>e</b>) Ours. (<b>f</b>) GroundTruth.</p>
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<p>Classification maps of different classification methods on the PU dataset. (<b>a</b>) CNN-2D. (<b>b</b>) CNN-3D. (<b>c</b>) FCN-ELM. (<b>d</b>) Spectral Former. (<b>e</b>) Ours. (<b>f</b>) GroundTruth.</p>
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12 pages, 724 KiB  
Review
Ambulatory Blood Pressure Monitoring for Diagnosis and Management of Hypertension in Pregnant Women
by Walter G. Espeche and Martin R. Salazar
Diagnostics 2023, 13(8), 1457; https://doi.org/10.3390/diagnostics13081457 - 18 Apr 2023
Cited by 2 | Viewed by 2304
Abstract
Hypertension disorders during pregnancy has a wide range of severities, from a mild clinical condition to a life-threatening one. Currently, office BP is still the main method for the diagnosis of hypertension during pregnancy. Despite of the limitation these measurements, in clinical practice [...] Read more.
Hypertension disorders during pregnancy has a wide range of severities, from a mild clinical condition to a life-threatening one. Currently, office BP is still the main method for the diagnosis of hypertension during pregnancy. Despite of the limitation these measurements, in clinical practice office BP of 140/90 mmHg cut point is used to simplify diagnosis and treatment decisions. The out-of-office BP evaluations are it comes to discarding white-coat hypertension with little utility in practice to rule out masked hypertension and nocturnal hypertension. In this revision, we analyzed the current evidence of the role of ABPM in diagnosing and managing pregnant women. ABPM has a defined role in the evaluation of BP levels in pregnant women, being appropriate performing an ABPM to classification of HDP before 20 weeks of gestation and second ABMP performed between 20–30 weeks of gestation to detected of women with a high risk of development of PE. Furthermore, we propose to, discarding white-coat hypertension and detecting masked chronic hypertension in pregnant women with office BP > 125/75 mmHg. Finally, in women who had PE, a third ABPM in the post-partum period could identify those with higher long-term cardiovascular risk related with masked hypertension. Full article
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<p>Evolution of blood pressure in a normal pregnancy.</p>
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<p>Hypertensive disorder pregnancy according to weeks of gestation.</p>
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16 pages, 3604 KiB  
Article
Adsorption Studies on the Removal of Anionic and Cationic Dyes from Aqueous Solutions Using Discarded Masks and Lignin
by Penghui Li, Chi Yang, Yanting Wang, Wanting Su, Yumeng Wei and Wenjuan Wu
Molecules 2023, 28(8), 3349; https://doi.org/10.3390/molecules28083349 - 10 Apr 2023
Cited by 8 | Viewed by 2383
Abstract
The carbon materials derived from discarded masks and lignin are used as adsorbent to remove two types of reactive dyes present in textile wastewater: anionic and cationic. This paper introduces the results of batch experiments where Congo red (CR) and Malachite green (MG) [...] Read more.
The carbon materials derived from discarded masks and lignin are used as adsorbent to remove two types of reactive dyes present in textile wastewater: anionic and cationic. This paper introduces the results of batch experiments where Congo red (CR) and Malachite green (MG) are removed from wastewater onto the carbon material. The relationship between adsorption time, initial concentration, temperature and pH value of reactive dyes was investigated by batch experiments. It is discovered that pH 5.0–7.0 leads to the maximum effectiveness of CR and MG removal. The equilibrium adsorption capacities of CR and MG are found to be 232.02 and 352.11 mg/g, respectively. The adsorption processes of CR and MG are consistent with the Freundlich and Langmuir adsorption models, respectively. The thermodynamic processing of the adsorption data reveals the exothermic properties of the adsorption of both dyes. The results show that the dye uptake processes follow secondary kinetics. The primary adsorption mechanisms of MG and CR dyes on sulfonated discarded masks and alkaline lignin (DMAL) include pore filling, electrostatic attraction, π-π interactions and the synergistic interactions between the sulphate and the dyes. The synthesized DMAL with high adsorption efficiency is promising as an effective recyclable adsorbent for adsorbing dyes, especially MG dyes, from wastewater. Full article
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<p>(<b>a</b>) IR spectrum of DMAL with alkaline lignin, (<b>b</b>) TG curve of DMAL with alkaline lignin, (<b>c</b>) DTG curve of DMAL with alkaline lignin.</p>
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<p>(<b>a</b>–<b>c</b>) SEM images of DMAL, (<b>d</b>) TEM image of alkaline lignin carbon, (<b>e</b>) TEM image of DMAL, and (<b>f</b>) nitrogen adsorption-desorption isotherms of the DMAL carbon material, inset shows the pore size distribution of DMAL.</p>
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<p>(<b>a</b>) XRD patterns, (<b>b</b>) raman spectra and (<b>c</b>) high resolution XPS spectra of full spectrum (<b>d</b>) C 1s, (<b>e</b>) O 1s and (<b>f</b>) S 2p from DMAL.</p>
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<p>CR and MG adsorption on (<b>a</b>) effect of pH, (<b>b</b>) effect of time, (<b>c</b>) effect of temperature.</p>
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<p>The effects of the initial dyes concentration (<b>a</b>), the Langmuir isotherm model (<b>b</b>).</p>
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<p>Thermodynamic study on the adsorption of MG (<b>a</b>) and CR (<b>b</b>) dyes by DMAL.</p>
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<p>Adsorption kinetic studies of dye adsorption onto DMAL, pseudo-first-order model of MG (<b>a</b>) and CR (<b>d</b>); pseudo-second-order model of MG (<b>b</b>) and CR (<b>e</b>); intragranular model of MG (<b>c</b>) and CR (<b>f</b>).</p>
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<p>Structural formulae of CR and MG.</p>
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<p>Equation of the fitted standard curve, CR (<b>a</b>) MG (<b>b</b>).</p>
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19 pages, 2431 KiB  
Article
Characterization of the Products of the Catalytic Pyrolysis of Discarded COVID-19 Masks over Sepiolite
by Francisco Ortega, María Ángeles Martín-Lara, Héctor J. Pula, Montserrat Zamorano, Mónica Calero and Gabriel Blázquez
Appl. Sci. 2023, 13(5), 3188; https://doi.org/10.3390/app13053188 - 2 Mar 2023
Cited by 8 | Viewed by 3352
Abstract
This research aims to develop a new strategy to valorize wasted COVID-19 masks based on chemical recycling by pyrolysis to convert them into useful products. First, surgical and filtering face piece masks, as defined in Europe by the EN 149 standard (FFP2), were [...] Read more.
This research aims to develop a new strategy to valorize wasted COVID-19 masks based on chemical recycling by pyrolysis to convert them into useful products. First, surgical and filtering face piece masks, as defined in Europe by the EN 149 standard (FFP2), were thermally pyrolyzed at temperatures of 450, 500, and 550 °C, and the yields of valuable solid (biochar), liquid (biooil), and syngas products and their characteristics were determined. At low temperatures, biochar formation was favored over biooil and syngas production, while at high temperatures the syngas product yield was enhanced. The highest yield of biooil was found at a pyrolysis temperature of 500 °C, with both surgical and FFP2 masks achieving biooil yields of 59.08% and 58.86%, respectively. Then, the pyrolysis experiments were performed at 500 °C in a two-stage pyrolysis catalytic reactor using sepiolite as a catalyst. Sepiolite was characterized using nitrogen adsorption–desorption isotherms and Fourier-transform infrared spectroscopy. Results showed that the two-stage process increased the final yield of syngas product (43.89% against 39.52% for surgical masks and 50.53% against 39.41% for FFP2 masks). Furthermore, the composition of the biooils significantly changed, increasing the amount of 2,4-Dimethyl-1-heptene and other olefins, such as 3-Eicosene, (E)-, and 5-Eicosene, (E)-. Additionally, the methane and carbon dioxide content of the syngas product also increased in the two-stage experiments. Ultimately, the effect of sepiolite regeneration for its use in consecutive pyrolysis tests was examined. Characterization data showed that, the higher the use-regeneration of sepiolite, the higher the modification of textural properties, with mainly higher changes in its pore volume. The results indicated that the pyrolysis of face masks can be a good source of valuable products (especially from biooil and syngas products). Full article
(This article belongs to the Section Energy Science and Technology)
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<p>A photograph of the mask separated into its different parts: surgical mask (<b>left</b>), FFP2 mask (<b>right</b>).</p>
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<p>Pyrolysis experimental installation.</p>
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<p>FTIR spectra of the different layers of the surgical mask.</p>
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<p>FTIR spectra of the different layers of the FFP2 mask.</p>
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<p>Thermal pyrolysis yields of surgical masks (<b>left</b>) and FFP2 masks (<b>right</b>).</p>
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<p>Comparative pyrolysis yields of surgical masks (<b>left</b>) and FFP2 masks (<b>right</b>).</p>
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<p>Catalyst FTIR comparison.</p>
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18 pages, 3752 KiB  
Article
Extending the Protection Ability and Life Cycle of Medical Masks through the Washing Process
by Julija Volmajer Valh, Tanja Pušić, Mirjana Čurlin and Ana Knežević
Materials 2023, 16(3), 1247; https://doi.org/10.3390/ma16031247 - 1 Feb 2023
Cited by 1 | Viewed by 1694
Abstract
The reuse of decontaminated disposable medical face masks can contribute to reducing the environmental burden of discarded masks. This research is focused on the effect of household and laboratory washing at 50 °C on the quality and functionality of the nonwoven structure of [...] Read more.
The reuse of decontaminated disposable medical face masks can contribute to reducing the environmental burden of discarded masks. This research is focused on the effect of household and laboratory washing at 50 °C on the quality and functionality of the nonwoven structure of polypropylene medical masks by varying the washing procedure, bath composition, disinfectant agent, and number of washing cycles as a basis for reusability. The barrier properties of the medical mask were analyzed before and after the first and fifth washing cycle indirectly by measuring the contact angle of the liquid droplets with the front and back surface of the mask, further by measuring air permeability and determining antimicrobial resistance. Additional analysis included FTIR, pH of the material surface and aqueous extract, as well as the determination of residual substances—surfactants—in the aqueous extract of washed versus unwashed medical masks, while their aesthetic aspect was examined by measuring their spectral characteristics. The results showed that household washing had a stronger impact on the change of some functional properties, primarily air permeability, than laboratory washing. The addition of the disinfectant agent, didecyldimethylammonium chloride, contributes to the protective ability and supports the idea that washing of medical masks under controlled conditions can preserve barrier properties and enable reusability. Full article
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<p>Colonies of aerobic microorganisms on a pristine medical mask (N).</p>
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<p>Colonies of aerobic microorganisms on a medical mask after household washing (H 5×).</p>
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<p>Colonies of aerobic microorganisms on a medical mask after laboratory washing (L 5×).</p>
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<p>Colonies of aerobic microorganisms on a medical mask after laboratory washing with the addition of DDAC (L<sub>DS</sub> 5×).</p>
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<p>Droplets of the liquid with the front surface of the medical mask before and after washing.</p>
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<p>Droplets of the liquid with the surface of the back surface of the medical mask before and after laboratory washing with a standard detergent and rinsing with a disinfectant.</p>
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<p>FTIR spectra of the back (black spectrum) and front (blue spectrum) nonwoven layer, the ear loops (green spectrum), and nose pads (red spectrum) of the medical mask.</p>
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<p>FTIR spectra of the front nonwoven layers of the medical mask before and after the first and fifth washing cycle.</p>
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<p>FTIR spectra of the back nonwoven layers of the medical mask before and after the first and fifth washing cycle.</p>
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<p>Dendrogram of Euclidean distance for contact angle, air permeability, and whiteness as variables of unwashed and 1× and 5× washed samples. Red circle indicates samples with very small distances.</p>
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34 pages, 5866 KiB  
Review
Microplastics: A Real Global Threat for Environment and Food Safety: A State of the Art Review
by Khaled Ziani, Corina-Bianca Ioniță-Mîndrican, Magdalena Mititelu, Sorinel Marius Neacșu, Carolina Negrei, Elena Moroșan, Doina Drăgănescu and Olivia-Teodora Preda
Nutrients 2023, 15(3), 617; https://doi.org/10.3390/nu15030617 - 25 Jan 2023
Cited by 95 | Viewed by 23090
Abstract
Microplastics are small plastic particles that come from the degradation of plastics, ubiquitous in nature and therefore affect both wildlife and humans. They have been detected in many marine species, but also in drinking water and in numerous foods, such as salt, honey [...] Read more.
Microplastics are small plastic particles that come from the degradation of plastics, ubiquitous in nature and therefore affect both wildlife and humans. They have been detected in many marine species, but also in drinking water and in numerous foods, such as salt, honey and marine organisms. Exposure to microplastics can also occur through inhaled air. Data from animal studies have shown that once absorbed, plastic micro- and nanoparticles can distribute to the liver, spleen, heart, lungs, thymus, reproductive organs, kidneys and even the brain (crosses the blood–brain barrier). In addition, microplastics are transport operators of persistent organic pollutants or heavy metals from invertebrate organisms to other higher trophic levels. After ingestion, the additives and monomers in their composition can interfere with important biological processes in the human body and can cause disruption of the endocrine, immune system; can have a negative impact on mobility, reproduction and development; and can cause carcinogenesis. The pandemic caused by COVID-19 has affected not only human health and national economies but also the environment, due to the large volume of waste in the form of discarded personal protective equipment. The remarkable increase in global use of face masks, which mainly contain polypropylene, and poor waste management have led to worsening microplastic pollution, and the long-term consequences can be extremely devastating if urgent action is not taken. Full article
(This article belongs to the Section Nutrition and Public Health)
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<p>Microplastics in aquatic environment. Created with BioRender.com.</p>
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<p>Sources of microplastic contamination (original photographs taken by the authors in isolated locations from Fortul I, Chitila 44°29′46″ N 25°59′12″ E in Romania on 17 September 2022).</p>
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<p>Sources of microplastic contamination (original photographs taken by the authors in isolated locations from Fortul I, Chitila 44°29′46″ N 25°59′12″ E in Romania on 17 September 2022).</p>
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<p>Microplastics detection stages. Created with BioRender.com.</p>
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<p>The presence of microplastics on the surface of a bee’s body, especially on the edge of the wings and the head. Created with BioRender.com.</p>
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<p>Microplastics in the terrestrial environment and the influence on apicultural products. Created with BioRender.com.</p>
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<p>Insulin resistance and exposure to microplastics. Created with BioRender.com.</p>
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<p>Crossing of microplastics in the digestive tract. Created with BioRender.com.</p>
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17 pages, 7787 KiB  
Article
Evaluation of Mask Performances in Filtration and Comfort in Fabric Combinations
by Ji Wang, Renhai Zhao, Yintao Zhao and Xin Ning
Nanomaterials 2023, 13(3), 378; https://doi.org/10.3390/nano13030378 - 17 Jan 2023
Cited by 2 | Viewed by 1522
Abstract
A systemic study on improving particulate pollutant filtration efficiency through the combination of conventional fabrics is presented with the objective of finding comfortable, yet effective airway mask materials and products. Fabrics, nonwovens, and their combinations made of cotton, silk, wool, and synthetic fibers [...] Read more.
A systemic study on improving particulate pollutant filtration efficiency through the combination of conventional fabrics is presented with the objective of finding comfortable, yet effective airway mask materials and products. Fabrics, nonwovens, and their combinations made of cotton, silk, wool, and synthetic fibers are examined on their filtration efficiency for aerosol particles with diameters ranging from 0.225 μm to 3.750 μm under industry-standard testing conditions. It is found that composite fabrics can improve filtration efficiency more than just layers of the same fabric, and the filtration quality factor of some of the fabric combinations can exceed that of the standard melt-blown materials. In addition, fabric friction and charging between the combined layers also improve filtration efficiency substantially. With a broader understanding of the fabric characteristics, we may design mask products with reduced facial skin discomfort, better aesthetics, as well as the ability to alleviate the environmental impact of discarded protective masks in the extended period of controlling the transmission of pollutants and viruses, such as during the COVID-19 pandemic. Full article
(This article belongs to the Section Nanocomposite Materials)
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<p>(<b>a</b>) The experimental device and (<b>b</b>) the schematic diagram of the filter media test rig.</p>
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<p>(<b>a</b>) The filtration efficiency in the range from 0.225 μm to 3.75 μm and (<b>b</b>) the pressure drop for the 13 samples.</p>
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<p>SEM images of (<b>a</b>) Cotton 3, (<b>b</b>) Wool 1, (<b>c</b>) Polyester 2, (<b>d</b>) Silk 1, (<b>e</b>) Blend 1, (<b>f</b>) Blend 2, and (<b>g</b>) Melt-blown fabrics.</p>
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<p>(<b>a</b>,<b>b</b>) Filtration efficiency, (<b>c</b>) pressure drop, and (<b>d</b>,<b>e</b>) quality factor of six fabrics at particle size of 0.3 um and 2.5 μm. Water contact angle of (<b>f</b>) Polyester 2, (<b>g</b>) Wool 1, (<b>h</b>) Blend 1, and (<b>i</b>) Blend 2 fabrics.</p>
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<p>Filtration efficiency of silk before and after friction under DEHS aerosol.</p>
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<p>(<b>a</b>) The filtration efficiency curve, (<b>b</b>) photographs, and (<b>c</b>) SEM images of nanofiber film mask.</p>
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<p>Filtration efficiency of electrospinning film (PLA), PLA/silk, PLA+silk, and melt-blown samples.</p>
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<p>The filter efficiency of PLA spun for 40 min, PLA+silk, and melt-blown samples.</p>
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