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13 pages, 1843 KiB  
Article
Evaluation of Advanced Biofuels in Internal Combustion Engines: Diesel/Fusel Oil/Vegetable Oil Triple Blends
by Rafael Estevez, Francisco J. López-Tenllado, Laura Aguado-Deblas, Felipa M. Bautista, Antonio A. Romero and Diego Luna
Fuels 2024, 5(4), 660-672; https://doi.org/10.3390/fuels5040036 (registering DOI) - 18 Oct 2024
Abstract
In this research work, the feasibility of using fusel oil, a by-product of the sugar–alcohol industry, as an LVLC solvent in blends with straight vegetable oils (SVOs) and diesel was investigated. Concretely, diesel/fusel oil/sunflower oil (D/FO/SO) and diesel/fusel oil/castor oil (D/FO/CO) triple blends [...] Read more.
In this research work, the feasibility of using fusel oil, a by-product of the sugar–alcohol industry, as an LVLC solvent in blends with straight vegetable oils (SVOs) and diesel was investigated. Concretely, diesel/fusel oil/sunflower oil (D/FO/SO) and diesel/fusel oil/castor oil (D/FO/CO) triple blends were prepared and characterized by measuring the most important physicochemical properties, i.e., viscosity, density, cold flow properties, flash point and cetane number. An appreciable improvement in cold flow values has been achieved with triple blends, without compromising properties such as calorific value and cetane number. Likewise, the triple blends meet the viscosity and density requirements specified by the European quality standard EN 14214 and the American standard ASTM D6751. After characterization, the triple blends were used on a diesel engine, evaluating different parameters such as power output, opacity, exhaust emissions (CO and NOx) and consumption at different engine loads. The results indicate that as the biofuel content in the blend increases, engine power decreases while fuel consumption rises. Nevertheless, the values obtained with D/FO/CO are better than those for D/FO/SO and are also very similar to those of fossil diesel. Regarding opacity values and NOx emissions obtained with the utilization of the triple blends, they are lower than those produced by diesel. However, in the case of CO emissions, it depends on the type of oil used, with the samples prepared with castor oil exhibiting the best results. Full article
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Figure 1

Figure 1
<p>Power output (in kW) based on the different engine loads (in kW) when operating with triple blends: (<b>A</b>) D/FO/SO and (<b>B</b>) D/FO/CO.</p>
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<p>BSFC values of triple blends, (<b>A</b>) D/FO/SO and (<b>B</b>) D/FO/CO, at low, medium and high engine loads (1, 3 and 5 kW, respectively).</p>
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<p>Opacity (Bosch number) produced (from 0 to 5 kW) by triple blends, (<b>A</b>) diesel/FO/SO and (<b>B</b>) diesel/FO/CO, at different engine loads.</p>
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<p>Carbon monoxide (CO) emissions (in ppm) generated at different engine loads: (<b>A</b>) D/FO/SO and (<b>B</b>) D/FO/CO.</p>
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<p>Nitrogen oxide (NO<sub>x</sub>) emissions (in ppm) generated at different engine loads: (<b>A</b>) D/FO/SO and (<b>B</b>) D/FO/CO.</p>
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20 pages, 25074 KiB  
Article
Unraveling Magnet Structural Defects in Permanent Magnet Synchronous Machines—Harmonic Diagnosis and Performance Signatures
by Mehdi Abdolmaleki, Pedram Asef and Christopher Vagg
Magnetism 2024, 4(4), 348-367; https://doi.org/10.3390/magnetism4040023 (registering DOI) - 18 Oct 2024
Abstract
Rare-earth-based permanent magnets (PMs) have a vital role in numerous sustainable energy systems, such as electrical machines (EMs). However, their production can greatly harm the environment and their supply chain monopoly presents economic threats. Alternative materials are emerging, but the use of rare-earth [...] Read more.
Rare-earth-based permanent magnets (PMs) have a vital role in numerous sustainable energy systems, such as electrical machines (EMs). However, their production can greatly harm the environment and their supply chain monopoly presents economic threats. Alternative materials are emerging, but the use of rare-earth PMs remains dominant due to their exceptional performance. Damage to magnet structure can cause loss of performance and efficiency, and propagation of cracks in PMs can result in breaking. In this context, prolonging the service life of PMs and ensuring that they remain damage-free and suitable for re-use is important both for sustainability reasons and cost management. This paper presents a new harmonic content diagnosis and motor performance analysis caused by various magnet structure defects or faults, such as cracked or broken magnets. The proposed method is used for modeling the successive physical failure of the magnet structure in the form of crack formation, crack growth, and magnet breakage. A surface-mounted permanent magnet synchronous motor (PMSM) is studied using simulation in Ansys Maxwell software (Version 2023), and different cracks and PM faults are modeled using the two-dimensional finite element method (FEM). The frequency domain simulation results demonstrate the influence of magnet cracks and their propagation on EM performance measures, such as stator current, distribution of magnetic flux density, back EMF, flux linkage, losses, and efficiency. The results show strong potential for application in health monitoring systems, which could be used to reduce the occurrence of in-service failures, thus reducing the usage of rare-earth magnet materials as well as cost. Full article
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Figure 1
<p>Cross-sectional presentation of the studied SPMSM.</p>
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<p>Cross-sectional view of the model in Ansys Maxwell: (<b>a</b>) 2D CAD and (<b>b</b>) meshed model.</p>
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<p>Proposed methodology to investigate harmonic and performance signatures in motors.</p>
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<p>Faulty SPMSM associated with fault type A in the 2D FEM environment, (<b>a</b>) CAD modeling, and (<b>b</b>) corresponding flux density distribution.</p>
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<p>Faulty SPMSM with fault type B using 2D FEM: (<b>a</b>) CAD modeling; (<b>b</b>) flux density distribution.</p>
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<p>Faulty SPMSM with fault type C using 2D FEM: (<b>a</b>) CAD modeling; (<b>b</b>) flux density distribution.</p>
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<p>Torque in the time domain in (<b>a</b>) transient and (<b>b</b>) electrical angle rated load states for healthy and faulty motors with A–C faults.</p>
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<p>Harmonic content analysis using FEM simulation results and rated load states for healthy and faulty motors with A–C faults: (<b>a</b>) FFT of output torque; (<b>b</b>) FFT of stator currents.</p>
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<p>Comparison of the amplitude of the harmonics (index) appearing in the output torque in healthy and faulty motors, consecutively.</p>
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<p>Comparison of the amplitude of the harmonics (index) appearing in the stator currents in healthy and faulty motors.</p>
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<p>The impact of the demagnetization faults for the healthy and faulty motors under faults A–C: (<b>a</b>) the output torque; and (<b>b</b>) total power.</p>
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<p>Impact of faults on losses of healthy and faulty motors: (<b>a</b>) copper loss; (<b>b</b>) core loss.</p>
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<p>The changes in the total loss and efficiency of the healthy and faulty motors under faults A–C: (<b>a</b>) total loss; (<b>b</b>) efficiency.</p>
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<p>Impact analysis of other types of alternative crack faults with depth, width, and different directions across the magnet. (<b>a</b>) depth cracking study; (<b>b</b>) depth and width cracking study; (<b>c</b>) depth and width cracking study in different magnet locations.</p>
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<p>Two-dimensional CAD models for (<b>a</b>) fault A: impact analysis of crack depth; (<b>b</b>) fault B: impact analysis of crack widths; and (<b>c</b>) fault C: the random cracks with certain sizes across the magnet.</p>
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<p>Harmonic content analysis using FEM when fault 1 occurs at rated load torque with the faulty SPMSM: (<b>a</b>) harmonic content analysis of output torque using FFT in healthy and faulty states; (<b>b</b>) harmonic content analysis of stator currents under healthy and fault conditions.</p>
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<p>Harmonic content analysis using FEM when fault 2 occurs at rated load torque with the faulty SPMSM: (<b>a</b>) harmonic content analysis of output torque using FFT in healthy and faulty states; (<b>b</b>) harmonic content analysis of stator currents in healthy and fault states.</p>
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<p>Harmonic content analysis using FEM when fault 3 occurs in rated load torque with the faulty SPMSM: (<b>a</b>) harmonic content analysis of output torque using FFT in healthy and faulty states; (<b>b</b>) harmonic content analysis of stator currents in healthy and fault states.</p>
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12 pages, 6333 KiB  
Article
Tribological and Corrosion Properties of Al2O3@Y2O3-Reinforced Ni60A Composite Coatings Deposited Using Laser Cladding
by Yu Yin, Xing-Hua Ma, Jingwei Li, Shuling Zhang, Zihao Yin, Minghao Ma and Feng Guo
Coatings 2024, 14(10), 1334; https://doi.org/10.3390/coatings14101334 (registering DOI) - 18 Oct 2024
Abstract
Since rare earth oxides and hard ceramic particles improve coating quality, a novel Al2O3@Y2O3 core–shell structure was prepared. Then, Ni60A coatings with different amounts (2~6 wt.%) of Al2O3@Y2O3 core–shell [...] Read more.
Since rare earth oxides and hard ceramic particles improve coating quality, a novel Al2O3@Y2O3 core–shell structure was prepared. Then, Ni60A coatings with different amounts (2~6 wt.%) of Al2O3@Y2O3 core–shell structures were prepared using laser cladding technology on an H13 steel surface. To demonstrate the unique effect of the core–shell structure on the performance of the coatings, a set of controlled experiments was also conducted with different proportions of Al2O3-Y2O3 mechanically mixed powders. The effect of Al2O3@Y2O3 addition on the phase composition, element distribution, microstructure, wear, and corrosion resistance of the coatings was characterized and tested thoroughly. By comparing the forming quality, hardness, wear, and corrosion resistance of the different coatings, 2 wt.% was confirmed as the optimal concentration of Al2O3@Y2O3, and its corresponding friction coefficient was about 0.44. The wear rate was approximately 4.15 × 10−3 mm3·(N·m)−1, the self-corrosion potential was around −0.3659 V, and the self-corrosion current density was about 1.248 × 10−6 A·cm−2. Full article
(This article belongs to the Section Laser Coatings)
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Figure 1

Figure 1
<p>(<b>a</b>) SEM image of the Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub> precursor powder. (<b>b</b>) SEM and EDS images of Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub>. (<b>c</b>) XRD pattern of Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub>. (<b>d</b>) TEM and EDS images of Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub>.</p>
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<p>XRD patterns of <span class="html-italic">x</span> wt.% (Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub>)/Ni60A composite coatings with (a) <span class="html-italic">x</span> = 0, (b) <span class="html-italic">x</span> = 2, (c) <span class="html-italic">x</span> = 4, (d) <span class="html-italic">x</span> = 6; <span class="html-italic">x</span> wt.% (Al<sub>2</sub>O<sub>3</sub>-Y<sub>2</sub>O<sub>3</sub>)/Ni60A composite coatings with (e) <span class="html-italic">x</span> = 2, (f) <span class="html-italic">x</span> = 4, (g) <span class="html-italic">x</span> = 6.</p>
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<p>(<b>a</b>) Cross-sectional SEM image of 2 wt.% (Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub>)/Ni60A coating and the corresponding mapping spectra of (<b>b</b>) Fe and (<b>c</b>) Ni.</p>
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<p>SEM images of <span class="html-italic">x</span> wt.% (Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub>)/Ni60A composite coatings with (<b>a</b>) <span class="html-italic">x</span> = 2, (<b>b</b>) <span class="html-italic">x</span> = 4, (<b>c</b>) <span class="html-italic">x</span> = 6; <span class="html-italic">x</span> wt.% (Al<sub>2</sub>O<sub>3</sub>-Y<sub>2</sub>O<sub>3</sub>)/Ni60A composite coatings with (<b>d</b>) <span class="html-italic">x</span> = 2, (<b>e</b>) <span class="html-italic">x</span> = 4, (<b>f</b>) <span class="html-italic">x</span> = 6.</p>
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<p>(<b>a</b>) SEM image of 2 wt.% (Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub>)/Ni60A composite coating and the corresponding EDS mapping spectra of (<b>b</b>) Fe, (<b>c</b>) Ni, (<b>d</b>) Si, (<b>e</b>) Cr and (<b>f</b>) Al.</p>
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<p>Microhardness curve of <span class="html-italic">x</span> wt.% (Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub>)/Ni60A and (Al<sub>2</sub>O<sub>3</sub>-Y<sub>2</sub>O<sub>3</sub>)/Ni60A composite coatings (<span class="html-italic">x</span> = 0, 2, 4, and 6).</p>
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<p>Schematic diagram of (<b>a</b>) (Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub>)/Ni60A and (<b>b</b>) (Al<sub>2</sub>O<sub>3</sub>-Y<sub>2</sub>O<sub>3</sub>)/Ni60A coatings.</p>
Full article ">Figure 8
<p>(<b>a</b>) COF curve and (<b>b</b>) wear rate of composite coatings. (I) stands for <span class="html-italic">x</span> = 0. (II)–(IV) stands for <span class="html-italic">x</span> = 2, 4, 6 of <span class="html-italic">x</span> wt.% (Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub>)/Ni60A composite coatings, and (V)–(VII) stands for <span class="html-italic">x</span> = 2, 4, 6 of <span class="html-italic">x</span> wt.% (Al<sub>2</sub>O<sub>3</sub>-Y<sub>2</sub>O<sub>3</sub>)/Ni60A composite coatings.</p>
Full article ">Figure 9
<p>Morphology of worn surfaces of (<b>a</b>) 2 wt.%, (<b>b</b>) 4 wt.% and (<b>c</b>) 6 wt.% (Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub>)/Ni60A composite coatings; (<b>d</b>) 2 wt.%, (<b>e</b>) 4 wt.% and (<b>f</b>) 6 wt.% (Al<sub>2</sub>O<sub>3</sub>-Y<sub>2</sub>O<sub>3</sub>)/Ni60A composite coatings taken by 3D microscope.</p>
Full article ">Figure 10
<p>(<b>a</b>) Polarization and (<b>b</b>) Nyquist curves of <span class="html-italic">x</span> wt.% (Al<sub>2</sub>O<sub>3</sub>@Y<sub>2</sub>O<sub>3</sub>)/Ni60A and (Al<sub>2</sub>O<sub>3</sub>-Y<sub>2</sub>O<sub>3</sub>)/Ni60A (<span class="html-italic">x</span> = 0, 2, 4, 6) composite coatings (the scatter charts stand for the experimental plots and the line charts stand for the modeled plots. Inset (<b>b</b>) is the equivalent circuit used for fitting of the EIS plots). (<b>c</b>) Enlarged curves to show the smallest three curves shown in (<b>b</b>).</p>
Full article ">
21 pages, 12855 KiB  
Article
Noise Study Auralization of an Open-Rotor Engine
by Qing Zhang, Siyi Jiang, Xiaojun Yang, Yongjia Xu and Maosheng Zhu
Aerospace 2024, 11(10), 857; https://doi.org/10.3390/aerospace11100857 (registering DOI) - 17 Oct 2024
Abstract
Based on the performance and acoustic data files of reduced-size open-rotor engines in low-speed wind tunnels, the static sound pressure level was derived by converting the 1-foot lossless spectral density into sound-pressure-level data, the background noise was removed, and the results were corrected [...] Read more.
Based on the performance and acoustic data files of reduced-size open-rotor engines in low-speed wind tunnels, the static sound pressure level was derived by converting the 1-foot lossless spectral density into sound-pressure-level data, the background noise was removed, and the results were corrected according to the environmental parameters of the low-speed wind tunnels. In accordance with the requirements of Annex 16 of the Convention on International Civil Aviation Organization and Part 36 of the Civil Aviation Regulations of China on noise measurement procedures, the takeoff trajectory was physically modeled; the static noise source was mapped onto the takeoff trajectory to simulate the propagation process of the noise during takeoff; and the 24 one-third-octave center frequencies that corresponded to the SPL data were corrected for geometrical dispersion, atmospheric absorption, and Doppler effects, so that the takeoff noise could be corrected to represent a real environment. In addition, the audible processing of noise data with a 110° source pointing angle was achieved, which can be useful for enabling practical observers to analyze the noise characteristics. Full article
(This article belongs to the Section Aeronautics)
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Figure 1
<p>The new-generation open-rotor engine configuration.</p>
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<p>Aircraft-noise-monitoring points for noise airworthiness requirements.</p>
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<p>Full- and reduced-thrust takeoff trajectories.</p>
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<p>Example of reduced-thrust takeoff trajectory noise source localization.</p>
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<p>Attenuation curve of the geometric dispersion effect.</p>
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<p>Atmospheric absorption sound attenuation curve.</p>
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<p>Doppler effect curve (The intersection of the blue dotted line and the Doppler effect curve is the angle at which the sound pressure level attenuation is 0).</p>
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<p>Source synthesis, propagation path and receiver setting.</p>
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<p>Broadband and monophonic filtering results.</p>
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<p>Broadband synthesis.</p>
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<p>Flight path simulated in a 3D virtual environment.</p>
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<p>The 110° angle noise-data audio realization point (at the red dot).</p>
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<p>Wind tunnel environment simulation.</p>
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<p>Acoustic measurement position.</p>
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<p>Mixed-reality environment visualization.</p>
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<p>Labeling of the test.</p>
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<p>Dynamic bar graph of the mixed-reality environment.</p>
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17 pages, 5414 KiB  
Article
Evaluation of Mechanical Properties of ABS-like Resin for Stereolithography Versus ABS for Fused Deposition Modeling in Three-Dimensional Printing Applications for Odontology
by Victor Paes Dias Gonçalves, Carlos Maurício Fontes Vieira, Noan Tonini Simonassi, Felipe Perissé Duarte Lopes, George Youssef and Henry A. Colorado
Polymers 2024, 16(20), 2921; https://doi.org/10.3390/polym16202921 (registering DOI) - 17 Oct 2024
Abstract
This study investigates the differences in mechanical properties between acrylonitrile butadiene styrene (ABS) samples produced using fused deposition modeling (FDM) and stereolithography (SLA) using ABS filaments and ABS-like resin, respectively. The central question is to determine how these distinct printing techniques affect the [...] Read more.
This study investigates the differences in mechanical properties between acrylonitrile butadiene styrene (ABS) samples produced using fused deposition modeling (FDM) and stereolithography (SLA) using ABS filaments and ABS-like resin, respectively. The central question is to determine how these distinct printing techniques affect the properties of ABS and ABS-like resin and which method delivers superior performance for specific applications, particularly in dental treatments. The evaluation methods used in this study included Shore D hardness, accelerated aging, tensile testing, Izod impact testing, flexural resistance measured by a 3-point bending test, and compression testing. Poisson’s ratio was also assessed, along with microstructure characterization, density measurement, confocal microscopy, dilatometry, wettability, Fourier-transform infrared spectroscopy (FTIR), and nanoindentation. It was concluded that ABS has the same hardness in both manufacturing methods; however, the FDM process results in significantly superior mechanical properties compared to SLA. Microscopy demonstrates a more accurate sample geometry when fabricated with SLA. It is also concluded that printable ABS is suitable for applications in dentistry to fabricate models and surgical guides using the SLA and FDM methods, as well as facial protectors for sports using the FDM method. Full article
(This article belongs to the Special Issue Resins for Additive Manufacturing)
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Figure 1

Figure 1
<p>(<b>1</b>) FFF-slicing process with Ultimaker Cura software (version 4.2). (<b>a</b>) 3-point flexural resistance, (<b>b</b>) compression, (<b>c</b>) izod impact, (<b>d</b>) tensile, (<b>e</b>) shore hardness samples. (<b>2</b>) The respective SLA-slicing process with Chitubox.</p>
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<p>Poisson’s ratio test. (<b>a</b>) Instron load frame, (<b>b</b>) tested sample with strain grid, and (<b>c</b>) P3 strain gauge reading box.</p>
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<p>Tensile properties: (<b>a</b>) tensile strength, (<b>b</b>) modulus of elasticity, and (<b>c</b>) strain.</p>
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<p>Flexural properties: (<b>a</b>) flexural strength and (<b>b</b>) strain.</p>
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<p>Compression properties: (<b>a</b>) strength and (<b>b</b>) strain.</p>
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<p>Izod impact resistance properties: (<b>a</b>) notch and (<b>b</b>) impact strength.</p>
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<p>The fracture behavior pattern of specimens in the Izod test, (<b>a</b>) ABS–FFF, and (<b>b</b>) ABS–SLA.</p>
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<p>Nanoindentation results for ABS–FDM and ABS–SLA samples.</p>
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<p>SEM micrographs of fractured surface for ABS–SLA samples at magnifications of (<b>a</b>) 30×, (<b>b</b>) 100×, and (<b>c</b>) 500×.</p>
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<p>SEM micrographs of fractured surface for ABS–FFF at magnifications of (<b>a</b>) 30×, (<b>b</b>) 100×, and (<b>c</b>) 500×.</p>
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<p>Dilatometry results for the sample made by ABS–FFF and ABS–SLA.</p>
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<p>KSV K100 drop tensiometer for contact angle assessment, (<b>a</b>) ABS–SLA and (<b>b</b>) ABS–FFF.</p>
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<p>FTIR spectrum of ABS–FFF.</p>
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<p>FTIR spectrum of ABS–SLA.</p>
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<p>Dental arch models and surgical guides with (<b>a</b>) ABS–FFF and (<b>b</b>) ABS–SLA.</p>
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<p>(<b>a</b>) Model ABS—SLA fittings/templates for the occlusal device, and (<b>b</b>) mouthguard facial protectors using ABS—FFF.</p>
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12 pages, 1074 KiB  
Article
A CMOS Optoelectronic Transimpedance Amplifier Using Concurrent Automatic Gain Control for LiDAR Sensors
by Yeojin Chon, Shinhae Choi and Sung-Min Park
Photonics 2024, 11(10), 974; https://doi.org/10.3390/photonics11100974 (registering DOI) - 17 Oct 2024
Abstract
This paper presents a novel optoelectronic transimpedance amplifier (OTA) for short-range LiDAR sensors used in 180 nm CMOS technology, which consists of a main transimpedance amplifier (m-TIA) with an on-chip P+/N-well/Deep N-well avalanche photodiode (P+/NW/DNW APD) and a replica [...] Read more.
This paper presents a novel optoelectronic transimpedance amplifier (OTA) for short-range LiDAR sensors used in 180 nm CMOS technology, which consists of a main transimpedance amplifier (m-TIA) with an on-chip P+/N-well/Deep N-well avalanche photodiode (P+/NW/DNW APD) and a replica TIA with another on-chip APD, not only to acquire circuit symmetry but to also obtain concurrent automatic gain control (AGC) function within a narrow single pulse-width duration. In particular, for concurrent AGC operations, 3-bit PMOS switches with series resistors are added in parallel with the passive feedback resistor in the m-TIA. Then, the PMOS switches can be turned on or off in accordance with the DC output voltage amplitudes of the replica TIA. The post-layout simulations reveal that the OTA extends the dynamic range up to 74.8 dB (i.e., 1 µApp~5.5 mApp) and achieves a 67 dBΩ transimpedance gain, an 830 MHz bandwidth, a 16 pA/ noise current spectral density, a −31 dBm optical sensitivity for a 10−12 bit error rate, and a 6 mW power dissipation from a single 1.8 V supply. The chip occupies a core area of 200 × 120 µm2. Full article
(This article belongs to the Section Optoelectronics and Optical Materials)
12 pages, 999 KiB  
Article
The Impact of FDA-Approved Novel Agents for Steroid-Refractory Chronic Graft vs. Host Disease on Treatment Patterns and Outcomes—A Single-Center Longitudinal Cohort Analysis
by Gil Fridberg, Odelia Amit, Chen Karni, Dina Tshernichovsky, David Shasha, Vanessa Rouach, David Varssano, Amir Bar-Shai, Ilan Goldberg, Gilad Wasserman, Irit Avivi and Ron Ram
Cancers 2024, 16(20), 3521; https://doi.org/10.3390/cancers16203521 (registering DOI) - 17 Oct 2024
Abstract
Objectives—chronic graft vs. host disease (cGVHD) is associated with substantial morbidity and mortality. We aimed to analyze advances in treatment strategy and outcomes during the last decade due to the incorporation of novel immunosuppressive therapy (IST) drugs in the armamentarium. Methods—we [...] Read more.
Objectives—chronic graft vs. host disease (cGVHD) is associated with substantial morbidity and mortality. We aimed to analyze advances in treatment strategy and outcomes during the last decade due to the incorporation of novel immunosuppressive therapy (IST) drugs in the armamentarium. Methods—we retrospectively analyzed all patients > 18 years with cGVHD after their first hematopoietic cell transplantation (HCT) between 2012 and 2020 (n = 91), divided into three treatment periods: 2012–2014, 2015–2017, and 2018–2020 (groups 1, 2, and 3, respectively). Results—mean cumulative steroid dose and dose/total cGVHD-treatment days was lower in groups 2–3 compared to 1 (p = 0.008 and p = 0.042, respectively). The median IST-free survival was 79 (95%CI54–94) months, with more patients in group 3 (47% (95%CI 25–54%) discontinuing IST at 3 years, p = 0.1). Groups 2–3 compared to 1 had better glycemic control (p < 0.01), higher bone density (p = 0.06), and fewer cardiovascular events. The number of admissions/patient dropped from 0.7/year in group 1 to 0.24/year and 0.36/year in groups 2–3, respectively (p = 0.36). Employment reintegration was higher in groups 2–3 compared with 1 (p = 0.05) and so was earlier return to work (p = 0.01). There were no differences in survival outcomes. Conclusions—the incorporation of novel agents appears to be associated with reduced overall steroid burden, improved cGVHD control, and fewer long-term side effects. Full article
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<p>Patient flow chart.</p>
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<p>Accumulated steroid burden across time periods.</p>
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<p>Mortality or relapse rates and IST discontinuation.</p>
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15 pages, 545 KiB  
Article
Association Between Ultraprocessed Food Consumption and Metabolic Disorders in Children and Adolescents with Obesity
by Gyeong-yoon Lee, Joo Hyun Lim, Hyojee Joung and Dankyu Yoon
Nutrients 2024, 16(20), 3524; https://doi.org/10.3390/nu16203524 (registering DOI) - 17 Oct 2024
Abstract
Background/Objectives: We investigated the effects of ultraprocessed food (UPF) consumption on metabolic disorders (e.g., adiposity, metabolic associated steatotic liver disease [MASLD], and insulin resistance) in children and adolescents with obesity to improve dietary guidelines and public health strategies. Methods: The dietary intake of [...] Read more.
Background/Objectives: We investigated the effects of ultraprocessed food (UPF) consumption on metabolic disorders (e.g., adiposity, metabolic associated steatotic liver disease [MASLD], and insulin resistance) in children and adolescents with obesity to improve dietary guidelines and public health strategies. Methods: The dietary intake of 149 participants (aged 8–17 years) was assessed with food diaries. The NOVA classification system was used to classify food according to the degree of processing. Metabolic outcomes, including the fat mass index (FMI), hepatic fat percentage, and insulin resistance, were measured via dual-energy X-ray absorptiometry (DXA), magnetic resonance imaging proton density fat fraction (MRI-PDFF), and biochemical analysis, respectively. Results: Greater UPF consumption from baseline to the 6-month follow-up was significantly associated with increased insulin and decreased total cholesterol and LDL-cholesterol. UPF consumption was positively associated with the prevalence of MASLD (liver MRI-PDFF ≥ 5%; odds ratio T3 vs. T1 = 1.75; 95% confidence interval [CI] 1.03, 3.00), moderate-to-severe MASLD (liver MRI-PDFF ≥ 10%; OR T3 vs. T1 = 4.19; 95% CI 1.72, 10.22), and insulin resistance (OR T3 vs. T1 = 2.44; 95% CI 1.33, 4.48), after adjusting for covariates. A linear dose-response relationship was observed between UPF consumption and the odds of moderate-to-severe MASLD and insulin resistance. Conclusions: Greater UPF consumption was strongly associated with MASLD and insulin resistance in children and adolescents with obesity, underscoring the importance of reducing UPF consumption through dietary guidelines and public health interventions to mitigate the risk of obesity-related metabolic conditions in young populations. Full article
(This article belongs to the Special Issue Ultra-Processed Foods and Chronic Diseases Nutrients)
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<p>Associations between UPF consumption, MASLD, and insulin resistance in overweight children and adolescents (<span class="html-italic">n</span> = 149). The model was adjusted for month age, sex, ‘time’, maternal education attainment, birth weight, screen time, activity level, and daily energy intake. The continuous analysis was scaled for a 10% increase for easier interpretation. The HOMA-IR cutoff values for insulin resistance in the prepubertal period were 2.67 for boys, 2.22 for girls, and in the pubertal period, they were 5.22 for boys and 3.82 for girls. (<b>a</b>) Odds ratio of MASLD (hepatic fat ≥ 5%); (<b>b</b>) odds ratio of moderate-to severe MASLD (hepatic fat ≥ 10%); (<b>c</b>) odds ratio of insulin resistance.</p>
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16 pages, 12302 KiB  
Article
Digital Traffic Lights: UAS Collision Avoidance Strategy for Advanced Air Mobility Services
by Zachary McCorkendale, Logan McCorkendale, Mathias Feriew Kidane and Kamesh Namuduri
Drones 2024, 8(10), 590; https://doi.org/10.3390/drones8100590 - 17 Oct 2024
Abstract
With the advancing development of Advanced Air Mobility (AAM), there is a collaborative effort to increase safety in the airspace. AAM is an advancing field of aviation that aims to contribute to the safe transportation of goods and people using aerial vehicles. When [...] Read more.
With the advancing development of Advanced Air Mobility (AAM), there is a collaborative effort to increase safety in the airspace. AAM is an advancing field of aviation that aims to contribute to the safe transportation of goods and people using aerial vehicles. When aerial vehicles are operating in high-density locations such as urban areas, it can become crucial to incorporate collision avoidance systems. Currently, there are available pilot advisory systems such as Traffic Collision and Avoidance Systems (TCAS) providing assistance to manned aircraft, although there are currently no collision avoidance systems for autonomous flights. Standards Organizations such as the Institute of Electrical and Electronics Engineers (IEEE), Radio Technical Commission for Aeronautics (RTCA), and General Aviation Manufacturers Association (GAMA) are working to develop cooperative autonomous flights using UAS-to-UAS Communication in structured and unstructured airspaces. This paper presents a new approach for collision avoidance strategies within structured airspace known as “digital traffic lights''. The digital traffic lights are deployed over an area of land, controlling all UAVs that enter a potential collision zone and providing specific directions to mitigate a collision in the airspace. This strategy is proven through the results demonstrated through simulation in a Cesium Environment. With the deployment of the system, collision avoidance can be achieved for autonomous flights in all airspaces. Full article
20 pages, 4383 KiB  
Article
Coupling and Coordination Analysis of High-Quality Agricultural Development and Rural Revitalization: Spatio-Temporal Evolution, Spatial Disparities, and Convergence
by Yaoyao Wang, Yifan Lei and Muhammad Haroon Shah
Sustainability 2024, 16(20), 9007; https://doi.org/10.3390/su16209007 - 17 Oct 2024
Abstract
The coupling and coordination of high-quality agricultural development (HQAD) and rural revitalization is an inevitable choice to accelerate the realization of Chinese-style agricultural and rural modernization. Based on system theory, this study reconstructs the indicator systems of both and conducts measurements by applying [...] Read more.
The coupling and coordination of high-quality agricultural development (HQAD) and rural revitalization is an inevitable choice to accelerate the realization of Chinese-style agricultural and rural modernization. Based on system theory, this study reconstructs the indicator systems of both and conducts measurements by applying the improved AHP–entropy weight method. This study has extended the analytical methods of kernel density estimation, Dagum Gini coefficient, σ convergence, and spatial β convergence to further investigate the spatio-temporal evolution, regional disparities, and convergence effect of the coupling coordination degree (CCD) of HQAD and rural revitalization in China from 2010 to 2020. The results show that the CCD has a tendency to increase year by year, presenting the characteristics of ‘high coupling degree–low comprehensive development level–low coupling coordination degree’, and also has the spatial distribution pattern of ‘high in the east and low in the west’. In addition, most of the provinces have a tendency to jump to a higher stage of coupling coordination; the overall trend of the kernel density curves is favorable; the results of Dagum’s Gini coefficient show that inter-regional disparities contribute the most to regional spatial disparities; and there is a significant tendency towards σ convergence and spatial β convergence of the CCD in China and the four regions. This study stimulates a broader discussion of rural revitalization, with potential implications for decision making in practice. Full article
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<p>Connotation and concept of HQAD.</p>
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<p>Mechanism of mutual reinforcement between HQAD and rural revitalization.</p>
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<p>Evolution trends of the CCDs across provinces in 2010, 2016, and 2020.</p>
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<p>Evolution trends of CCD classification of provinces in 2010, 2012, 2016, and 2020.</p>
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<p>Evolution trends of the CCDs in China and four regions in 2010, 2016, and 2020. Aggregate (<b>a</b>); east (<b>b</b>); central (<b>c</b>); northeast (<b>d</b>); west (<b>e</b>).</p>
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<p>Evolution trends of the CCDs in China and four regions in 2010, 2016, and 2020. Aggregate (<b>a</b>); east (<b>b</b>); central (<b>c</b>); northeast (<b>d</b>); west (<b>e</b>).</p>
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<p>σ convergence coefficient of CCD in China and four regions.</p>
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24 pages, 3171 KiB  
Article
Detoxification of Acrylamide by Potentially Probiotic Strains of Lactic Acid Bacteria and Yeast
by Agnieszka Maher, Karolina Miśkiewicz, Justyna Rosicka-Kaczmarek and Adriana Nowak
Molecules 2024, 29(20), 4922; https://doi.org/10.3390/molecules29204922 - 17 Oct 2024
Abstract
Some potentially probiotic strains of lactic acid bacteria (LAB) and yeast that inhabit the digestive tract of humans are known to detoxify xenobiotics, including acrylamide (AA). The objective of the subsequent research was to evaluate the AA-detoxification capability of LAB and yeast isolated [...] Read more.
Some potentially probiotic strains of lactic acid bacteria (LAB) and yeast that inhabit the digestive tract of humans are known to detoxify xenobiotics, including acrylamide (AA). The objective of the subsequent research was to evaluate the AA-detoxification capability of LAB and yeast isolated from various sources. Namely, the effect of AA was tested on the growth of LAB and yeast strains, as well in the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay. Subsequently, the AA-binding ability of LAB and yeast was investigated in various environments, including the pH, incubation temperature, cell density, and with inanimate cells. The ability of selected LAB and yeast to reduce the genotoxicity of AA was tested on Caco-2 and Hep-G2 cell lines. The results showed that all tested strains exhibited strong resistance to AA at concentrations of 5, 10, and 50 µg/mL. Also, AA was detected in the intracellular and membrane extracts of tested strains. The most effective binding strain was Pediococcus acidilactici 16 at pH = 5, cell density = 109 CFU/mL, and incubation temperature = 37 °C (87.6% of AA removed). Additionally, all tested strains significantly reduced the genotoxicity of AA, with the greatest reduction observed at the highest concentration of 50 µg/mL. The phenomena of detoxification by potentially probiotic strains could reduce the toxic and harmful effects of AA exposure to humans every day. Full article
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<p>Heatmaps of lactic acid bacteria (<b>A</b>) and yeast (<b>B</b>) cell growth after acrylamide (5, 10, 50 µg/mL) exposition during 24 h incubation using the spectrophotometric method. Each data point represents the mean from eight individual wells. The evaluation was conducted in two or three independent experiments. The figures were generated using R Studio software, version 4.3.3.</p>
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<p>Heatmaps of lactic acid bacteria (<b>A</b>) and yeast (<b>B</b>) cell growth after acrylamide (5, 10, 50 µg/mL) exposition during 24 h incubation using the spectrophotometric method. Each data point represents the mean from eight individual wells. The evaluation was conducted in two or three independent experiments. The figures were generated using R Studio software, version 4.3.3.</p>
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<p>Effect of acrylamide (0, 5, 10, 50 µg/mL) on the growth of lactic acid bacteria (<b>A</b>) and yeast (<b>B</b>) strains during 24 h incubation and evaluated using the pour plate method in an appropriate agar medium. The experiment was performed with two repetitions for each strain. The evaluation was conducted with three independent experiments. Results are visualized as dots and represent the mean ± standard deviation (SD), with the significance of the difference from the unexposed control at * <span class="html-italic">p</span> ≤ 0.0332, ** <span class="html-italic">p</span> ≤ 0.0021, and **** <span class="html-italic">p</span> ≤ 0.0001. The figures were generated using R Studio software, version 4.3.3.</p>
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<p>Effect of acrylamide (0, 5, 10, 50 µg/mL) on the growth of lactic acid bacteria (<b>A</b>) and yeast (<b>B</b>) strains during 24 h incubation and evaluated using the pour plate method in an appropriate agar medium. The experiment was performed with two repetitions for each strain. The evaluation was conducted with three independent experiments. Results are visualized as dots and represent the mean ± standard deviation (SD), with the significance of the difference from the unexposed control at * <span class="html-italic">p</span> ≤ 0.0332, ** <span class="html-italic">p</span> ≤ 0.0021, and **** <span class="html-italic">p</span> ≤ 0.0001. The figures were generated using R Studio software, version 4.3.3.</p>
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<p>Effect of acrylamide (5, 10, 50 µg/mL) on the cell viability of lactic acid bacteria (<b>A</b>) and yeast (<b>B</b>) strains during 24 h of exposure in the MTT assay. Each data point represents the mean from eight individual wells. The evaluation was conducted using two independent experiments. Results are presented as the mean ± standard deviation (SD), with the significance of the difference from the unexposed control at * <span class="html-italic">p</span> ≤ 0.0332, ** <span class="html-italic">p</span> ≤ 0.0021, *** <span class="html-italic">p</span> ≤ 0.0002, and **** <span class="html-italic">p</span> ≤ 0.0001. The figures were generated using R Studio software, version 4.3.3.</p>
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<p>Basic endogenous DNA damage in (<b>A</b>) Caco-2 and (<b>B</b>) Hep-G2 after exposure to acrylamide in the presence of lactic acid bacteria and yeast strains, expressed as the mean percentage of DNA in the comet tail in the alkaline comet assay. Fifty cells were analyzed for each treatment. Results are presented as the mean ± standard error of the mean (S.E.M.), with the significance of the difference from the positive control at * <span class="html-italic">p</span> ≤ 0.0332, ** <span class="html-italic">p</span> ≤ 0.0021, and *** <span class="html-italic">p</span> ≤ 0.0002. Positive control 5 µg/mL acrylamide—blue, positive control 50 µg/mL acrylamide—pink, samples with lactic acid bacteria or yeast with addition of 5 or 50 µg/mL acrylamide—black. The figures were generated using GraphPad Prism 10 software.</p>
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<p>Representative images of 1 mg/mL PI-stained comets of Caco-2 cells: (<b>A</b>) untreated cells; (<b>B</b>) cells treated with 5 µg/mL acrylamide; (<b>C</b>) cells treated with 50 µg/mL acrylamide; (<b>D</b>) cells treated with 5 µg/mL acrylamide + <span class="html-italic">Pediococcus acidilactici</span> 16; (<b>E</b>) cells treated with 50 µg/mL acrylamide + <span class="html-italic">Lactococcus lactis</span> 3; (<b>F</b>) cells treated with 50 µg/mL acrylamide + <span class="html-italic">Kluyveromyces lactis</span> D2. Fluorescence microscopy; 200× magnification.</p>
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26 pages, 3651 KiB  
Article
Land Use, Travel Patterns and Gender in Barcelona: A Sequence Analysis Approach
by Lídia Montero, Lucía Mejía-Dorantes and Jaume Barceló
Sustainability 2024, 16(20), 9004; https://doi.org/10.3390/su16209004 - 17 Oct 2024
Abstract
Transport systems are essential for the path toward sustainable urbanisation and the transition to more sustainable living. Recently, European cities have undergone substantial changes, and suburbanisation is posing new challenges. Suburban areas are often more affordable in terms of housing, but these neighbourhoods [...] Read more.
Transport systems are essential for the path toward sustainable urbanisation and the transition to more sustainable living. Recently, European cities have undergone substantial changes, and suburbanisation is posing new challenges. Suburban areas are often more affordable in terms of housing, but these neighbourhoods tend to be car-oriented. This leads to higher commuter costs, immobility, transport and time poverty, pollution, higher accident rates and a lack of social interactions. To offer sustainable mobility options to citizens, we must comprehensively understand, together with their individual characteristics, their specific mobility practices and the built environment where they live. This study is centred on the Barcelona Metropolitan Region, which has a public transport network that covers its entire area. The aim of this study is to examine the relationships between travel behaviour, transport mode use, individual characteristics and built environment characteristics in the place of residence using detailed information sources. Herein, we used data from the 2018 to 2021 annual travel survey conducted in the Barcelona region, together with land use and sociodemographic information. Our findings suggest that transport policies have encouraged sustainable mobility practices, particularly in the centre of Barcelona. Despite the positive results, considerable disparities exist between the inner and outer city, with a notable decline in sustainable mobility practices in the latter, due to the uneven distribution of basic services and uneven provision of public transport, together with lower density areas. Our results demonstrate that this uneven distribution reduces the available sequence profiles of inhabitants. In conclusion, the promotion of sustainable mobility policies necessitates further advances in transport, city and land-use planning that consider equity, gender, the socioeconomic profiles of citizens and mixed urban planning. Full article
(This article belongs to the Section Sustainable Transportation)
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<p>Metropolitan Region of Barcelona: “Crowns” and TAZ-EMEF.</p>
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<p>Principal component analysis (base analysis): (<b>left</b>) dimensions 1 and 2; and dimensions 3 and 4 (<b>right</b>).</p>
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<p>Base analysis: spatial clustering of the TAZs.</p>
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<p>PCA (full analysis): Contributions to the first to fourth dimensions in the PCA and variable projections: (left) dimensions 1–2; (right) dimensions 3–4.</p>
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<p>Full analysis: spatial clustering of the TAZs.</p>
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<p>PCA results by year. Data sources: 2018 to 2021 EMEF surveys, land-use and built-environment data.</p>
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<p>Percentages of the transport modes used by zone and gender. Data source: EMEF data, 2018 to 2021.</p>
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<p>(<b>upper</b>) Number of public transport stops by zone; (<b>middle</b>) extra travel time required when taking public transport to Barcelona’s CBD according to zone; (<b>lower</b>) transport mode shared by gender and number of public transport stops (with the <span class="html-italic">y</span>-axis as the discretised number of stops by zone).</p>
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<p>(<b>upper</b>) Number of public transport stops by zone; (<b>middle</b>) extra travel time required when taking public transport to Barcelona’s CBD according to zone; (<b>lower</b>) transport mode shared by gender and number of public transport stops (with the <span class="html-italic">y</span>-axis as the discretised number of stops by zone).</p>
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<p>Optimal spatial clustering according to the base analysis variables.</p>
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<p>State distribution of the activity sequences subclusters in spatial group III by gender ((<b>top</b>)—men; (<b>bottom</b>)—women). All years are based on EMEF survey data.</p>
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<p>State distribution of the activity sequences subclusters in spatial group III by gender ((<b>top</b>)—men; (<b>bottom</b>)—women). All years are based on EMEF survey data.</p>
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<p>Percentage of SA subclusters for spatial group I.</p>
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<p>Percentage of SA subclusters for spatial group II.</p>
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<p>Percentage of SA subclusters for spatial group III.</p>
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12 pages, 1815 KiB  
Article
Trabecular Attenuation of L1 in Adult Patients with Multiple Myeloma: An Observational Study on Low-Dose CT Images
by Carlo Augusto Mallio, Valeria Tomarchio, Francesco Pulcini, Edoardo Verducci, Caterina Bernetti, Maria Antonietta Tafuri, Federico Greco, Luigi Rigacci, Bruno Beomonte Zobel and Ombretta Annibali
Hematol. Rep. 2024, 16(4), 624-635; https://doi.org/10.3390/hematolrep16040061 - 17 Oct 2024
Abstract
Background: The aim of this study was to evaluate the impact of trabecular attenuation of the L1 vertebral body in low-dose CT in adult patients with multiple myeloma (MM), smoldering multiple myeloma (SMM), and monoclonal gammopathy of undetermined significance (MGUS). Materials and Methods: [...] Read more.
Background: The aim of this study was to evaluate the impact of trabecular attenuation of the L1 vertebral body in low-dose CT in adult patients with multiple myeloma (MM), smoldering multiple myeloma (SMM), and monoclonal gammopathy of undetermined significance (MGUS). Materials and Methods: The study population consisted of 22 patients with MGUS and 51 consecutive patients with newly diagnosed MM (SMM, n = 21; symptomatic MM, n = 36). CT scans were conducted using a 128-slice CT scanner (Somatom go.Top, Siemens, Munich, Germany). Low-dose whole-body CT scans were performed at a single time point for each patient. Trabecular bone density values were obtained by defining regions of interest on non-contrast images at the level of L1 vertebra. A threshold of p = 0.05 was applied to determine statistical significance. Results: The median Hounsfield unit (HU) value in patients with MGUS, SMM, and MM was 148 HU (range 81–190), 130 HU (range 93–193), and 92 HU (range 26–190), respectively, with a statistically significant difference between the groups (p = 0.0015). Patients with HU values ≤ 92 had lower progression-free survival with statistically significant differences compared to the group with HU values > 92 (p < 0.0499). Conclusions: This is the earliest evidence of the importance of evaluating L1 attenuation values in low-dose CT images in patients with MGUS, SMM, and MM. Further prospective studies could contribute to reinforcing these results and exploring the clinical applicability and generalization of L1 attenuation values in low-dose whole-body CT scans in routine clinical practice. Full article
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<p>Axial CT image showing ROI placement at the level of the trabecular bone of the L1 vertebra. Purple and orange lines are for anatomical reference of correct positioning.</p>
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<p>Box plot of HU value in patients with MGUS, smoldering MM, and symptomatic MM. ANOVA, analysis of variance.</p>
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<p>Kaplan–Meier curves showing the survival analysis of MM patients divided according to HU values.</p>
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<p>Axial low-dose CT images at the level of L1, showing the progressive reduction in bone density across the three groups: monoclonal gammopathy of undetermined significance (MGUS), smoldering multiple myeloma (SMM), and multiple myeloma (MM).</p>
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16 pages, 9232 KiB  
Article
DSM Reconstruction from Uncalibrated Multi-View Satellite Stereo Images by RPC Estimation and Integration
by Dong-Uk Seo and Soon-Yong Park
Remote Sens. 2024, 16(20), 3863; https://doi.org/10.3390/rs16203863 - 17 Oct 2024
Abstract
In this paper, we propose a 3D Digital Surface Model (DSM) reconstruction method from uncalibrated Multi-view Satellite Stereo (MVSS) images, where Rational Polynomial Coefficient (RPC) sensor parameters are not available. While recent investigations have introduced several techniques to reconstruct high-precision and high-density DSMs [...] Read more.
In this paper, we propose a 3D Digital Surface Model (DSM) reconstruction method from uncalibrated Multi-view Satellite Stereo (MVSS) images, where Rational Polynomial Coefficient (RPC) sensor parameters are not available. While recent investigations have introduced several techniques to reconstruct high-precision and high-density DSMs from MVSS images, they inherently depend on the use of geo-corrected RPC sensor parameters. However, RPC parameters from satellite sensors are subject to being erroneous due to inaccurate sensor data. In addition, due to the increasing data availability from the internet, uncalibrated satellite images can be easily obtained without RPC parameters. This study proposes a novel method to reconstruct a 3D DSM from uncalibrated MVSS images by estimating and integrating RPC parameters. To do this, we first employ a structure from motion (SfM) and 3D homography-based geo-referencing method to reconstruct an initial DSM. Second, we sample 3D points from the initial DSM as references and reproject them to the 2D image space to determine 3D–2D correspondences. Using the correspondences, we directly calculate all RPC parameters. To overcome the memory shortage problem while running the large size of satellite images, we also propose an RPC integration method. Image space is partitioned to multiple tiles, and RPC estimation is performed independently in each tile. Then, all tiles’ RPCs are integrated into the final RPC to represent the geometry of the whole image space. Finally, the integrated RPC is used to run a true MVSS pipeline to obtain the 3D DSM. The experimental results show that the proposed method can achieve 1.455 m Mean Absolute Error (MAE) in the height map reconstruction from multi-view satellite benchmark datasets. We also show that the proposed method can be used to reconstruct a geo-referenced 3D DSM from uncalibrated and freely available Google Earth imagery. Full article
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<p>Pipeline of the proposed method. (Reference: GEMVS [<a href="#B14-remotesensing-16-03863" class="html-bibr">14</a>], 3D to 2D correspondence search [<a href="#B17-remotesensing-16-03863" class="html-bibr">17</a>], MS2P [<a href="#B25-remotesensing-16-03863" class="html-bibr">25</a>]).</p>
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<p>3D-to-2D projection process for finding correspondence.</p>
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<p>2D-to-3D correspondence search process. For example, an image space is divided into <math display="inline"><semantics> <mrow> <mn>3</mn> <mo>×</mo> <mn>3</mn> </mrow> </semantics></math> tiles. Red-color points are uniform samples in image <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>I</mi> </mrow> <mrow> <msub> <mrow> <mi>C</mi> </mrow> <mrow> <mi>i</mi> </mrow> </msub> </mrow> </msub> </mrow> </semantics></math>. A sampled point is reprojected to geo-referencing space by each tile’s inverse RPCs to obtain <math display="inline"><semantics> <mrow> <msub> <mrow> <mi mathvariant="bold-italic">P</mi> </mrow> <mrow> <msub> <mrow> <mi>T</mi> </mrow> <mrow> <mi>j</mi> </mrow> </msub> </mrow> </msub> </mrow> </semantics></math>. Then, all <math display="inline"><semantics> <mrow> <msub> <mrow> <mi mathvariant="bold-italic">P</mi> </mrow> <mrow> <msub> <mrow> <mi>T</mi> </mrow> <mrow> <mi>j</mi> </mrow> </msub> </mrow> </msub> </mrow> </semantics></math> are weighted averaged by the distance of the point to each tile center to obtain the final correspondence <math display="inline"><semantics> <mrow> <msub> <mrow> <mi mathvariant="bold-italic">P</mi> </mrow> <mrow> <msub> <mrow> <mi>S</mi> </mrow> <mrow> <mi>k</mi> </mrow> </msub> </mrow> </msub> </mrow> </semantics></math>.</p>
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<p>A simplified flow diagram of MS2P. The baseline algorithm for MVS is EnSoft3D [<a href="#B29-remotesensing-16-03863" class="html-bibr">29</a>], and it is modified to use the estimated RPC parameters.</p>
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<p>Results of the proposed method on GE imagery. The area of the first row is Sigiriya, Sri-Lanka (7°57′22″N 80°45′32″E), and second row is Sydney, Australia (33°51′25″S 151°12′42″E).</p>
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<p>Comparison of the height map results from uncalibrated satellite images using the pin-hole camera model with GEMVS [<a href="#B17-remotesensing-16-03863" class="html-bibr">17</a>] and the RPC model with MS2P [<a href="#B25-remotesensing-16-03863" class="html-bibr">25</a>].</p>
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<p>Comparison of the DSM reconstruction of two camera models, COLMAP and GEMVS, with the pin-hole model and MS2P with the estimated RPC model.</p>
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<p>MAE and RMSE error of the height map compared with the GT DSM from the DFC19 dataset.</p>
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<p>Error analysis of the OMA_284 tile. From the left, reconstructed DSM, GT model, and error map.</p>
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13 pages, 4592 KiB  
Article
Inkjet-Printed Silver Lithiophilic Sites on Copper Current Collectors: Tuning the Interfacial Electrochemistry for Anode-Free Lithium Batteries
by Seyedalireza Mirbagheri, Eugenio Gibertini and Luca Magagnin
Batteries 2024, 10(10), 369; https://doi.org/10.3390/batteries10100369 - 17 Oct 2024
Abstract
Anode-free lithium batteries (AFLBs) present an opportunity to eliminate the need for conventional graphite electrodes or excess lithium–metal anodes, thus increasing the cell energy density and streamlining the manufacturing process. However, their attributed poor coulombic efficiency leads to rapid capacity decay, underscoring the [...] Read more.
Anode-free lithium batteries (AFLBs) present an opportunity to eliminate the need for conventional graphite electrodes or excess lithium–metal anodes, thus increasing the cell energy density and streamlining the manufacturing process. However, their attributed poor coulombic efficiency leads to rapid capacity decay, underscoring the importance of achieving stable plating and stripping of Li on the negative electrode for the success of this cell configuration. A promising approach is the utilization of lithiophilic coatings such as silver to mitigate the Li nucleation overpotential on the Cu current collector, thereby improving the process of Li plating/stripping. On the other hand, inkjet printing (IJP) emerges as a promising technique for electrode modification in the manufacturing process of lithium batteries, offering a fast and scalable technology capable of depositing both thin films and patterned structures. In this work, a Fujifilm Dimatix inkjet printer was used to deposit Ag sites on a Cu current collector, aiming to modulate the interfacial electrochemistry of the system. Samples were fabricated with varying areas of coverage and the electrochemical performance of the system was systematically evaluated from bare Cu (non-lithiophilic) to a designed pattern (partially lithiophilic) and the fully coated thin film case (lithiophilic). Increasing lithiophilicity resulted in lower charge transfer resistance, higher exchange current density and reduced Li nucleation overpotential (from 55.75 mV for bare Cu to 13.5 mV for the fully coated case). Enhanced half-cell cyclability and higher coulombic efficiency were also achieved (91.22% CE over 76 cycles for bare Cu, 97.01% CE over 250 cycles for the fully coated case), alongside more uniform lithium deposition and fewer macroscopic irregularities. Moreover, our observations demonstrated that surface patterning through inkjet printing could represent an innovative, easy and scalable strategy to provide preferential Li nucleation sites to guide the subsequent Li deposition. Full article
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Figure 1

Figure 1
<p>(<b>a</b>) Schematic representation of interfacial litiophilicity tuning by IJP of Ag nanoparticle ink. (<b>b</b>) Optical images of the Ag40ds@Cu sample after the thermal treatment and the SEM image of a single printed dot. (<b>c</b>) XRD of the Ag10ds@Cu after thermal treatment.</p>
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<p>Cyclic voltammetry plots of half cells batteries cycled between −0.2 and 0.6 V at 0.5 mV s<sup>−1</sup> scan rate for the (<b>a</b>) 1st cycle and (<b>b</b>) 5th cycle. (<b>c</b>) Transferred charge values during the plating step in the first and fifth cycles. Tafel plots derived from CV; (<b>d</b>) 1st cycle, (<b>e</b>) 5th cycle. (<b>f</b>) Exchange current density values extrapolated from the Tafel plots.</p>
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<p>SEM images of electrode surfaces at limited Li-plated capacity (0.05 mA cm<sup>−2</sup>, 0.006 mAh cm<sup>−2</sup>); (<b>a</b>) bare Cu, (<b>b</b>) Ag40ds@Cu and (<b>c</b>) Ag10ds@Cu. SEM images of electrode surfaces for higher Li-plated capacity (0.05 mA cm<sup>−2</sup>, 0.2 mAh cm<sup>−2</sup>); (<b>d</b>) bare Cu, (<b>e</b>) Ag40ds@Cu, (<b>f</b>) Ag10ds@Cu.</p>
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<p>(<b>a</b>) Voltage profiles of plating-stripping over a maximum of 250 cycles at 0.2 mA cm<sup>−2</sup> and 0.2 mAh cm<sup>−2</sup>. The onset of irregular cycling, corresponding to a sudden drop of CE, was considered as a threshold for test stop. (<b>b</b>) Coulombic efficiency (CE %) with cycling. Voltage profiles and Li nucleation overpotentials observed from each electrode during cycling; (<b>c</b>) 10th cycle. (<b>d</b>) 30th cycle. (<b>e</b>) 50th cycle. (<b>f</b>) 70th cycle.</p>
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<p>Nyquist plots of the samples in Li-plated state (0.2 mAh cm<sup>−2</sup>, 0.1 mA cm<sup>−2</sup>); (<b>a</b>) 1st cycle, (<b>b</b>) 5th cycle and (<b>c</b>) 40th cycle; (<b>d</b>) charge transfer resistance values extracted by the fitting the plots with the equivalent circuit (inset image).</p>
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<p>SEM images at different magnitudes of electrodes in a lithiated state (0.2 mAh cm<sup>−2</sup>) after 40 cycles cycled at 0.1 mA cm<sup>−2</sup>; (<b>a</b>,<b>d</b>) bare Cu, (<b>b</b>,<b>e</b>) Ag40ds@Cu and (<b>c</b>,<b>f</b>) Ag10ds@Cu.</p>
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