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12 pages, 3098 KiB  
Article
Effect of Potassium on the Co-Combustion Process of Coal Slime and Corn Stover
by Jing Zheng, Chuanchuan Cai, Tao Ge and Mingxu Zhang
Energies 2024, 17(20), 5185; https://doi.org/10.3390/en17205185 (registering DOI) - 18 Oct 2024
Abstract
In this study, the combined combustion characteristics and gaseous product emissions of coal slime and corn stover were compared at different blending ratios. The TG-DTG curves indicate that the optimal performance is achieved when the corn straw blending ratio is 20%. Furthermore, the [...] Read more.
In this study, the combined combustion characteristics and gaseous product emissions of coal slime and corn stover were compared at different blending ratios. The TG-DTG curves indicate that the optimal performance is achieved when the corn straw blending ratio is 20%. Furthermore, the TG-FTIR coupling results demonstrated an increase in gas species as the blending ratio increased. The composition analysis of ash samples formed at various combustion temperatures using XRD and XRF indicated that a portion of KCl in the fuel was released as volatile matter, while another part reacted with Al2O3 and SiO2 components in the slime to form silica–aluminate compounds and other substances. Notably, interactions between the components of slime and potassium elements in corn stover primarily occurred within the temperature range of 800–1000 °C. These findings contribute to a comprehensive understanding of biomass and coal co-firing combustion chemistry, offering potential applications for enhancing energy efficiency and reducing emissions in industrial processes. Full article
(This article belongs to the Section I2: Energy and Combustion Science)
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<p>Thermogravimetric profile of slime and corn stover combustion alone: (<b>a</b>) slime and (<b>b</b>) corn stover.</p>
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<p>Thermogravimetric profile of mixed combustion of slime and corn stover: (<b>a</b>) TG curve and (<b>b</b>) DTG curve.</p>
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<p>TG-FTIR profiles of gases released during combustion at different blending ratios: (<b>a</b>) blend ratio 20%, (<b>b</b>) blend ratio 40%, and (<b>c</b>) blend ratio 60%.</p>
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<p>XRF analysis pattern of gray sample: (<b>a</b>) corn stover, (<b>b</b>) coal slime, and (<b>c</b>) mixture of corn stover and coal slime.</p>
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<p>XRD patterns of ash samples after different combustion temperatures: (<b>a</b>) raw materials, (<b>b</b>) corn stover, (<b>c</b>) coal slime, and (<b>d</b>) mixture of corn stover and coal slime. A—Al<sub>4</sub>(OH)<sub>8</sub>(Si<sub>4</sub>O<sub>10</sub>); B—SiO<sub>2</sub>; C—MgFeSiAlOOH; D—Mg<sub>7</sub>Si<sub>8</sub>O<sub>22</sub>(OH)<sub>2</sub>; E—Pb<sub>4</sub>(S<sub>2</sub>O<sub>3</sub>)O<sub>2</sub>(OH)<sub>2</sub>; F—Al<sub>2</sub>Si<sub>2</sub>O<sub>5</sub>(OH)<sub>4</sub>; G—Al<sub>2</sub>Si<sub>2</sub>O<sub>5</sub>; H—KCl; I—SnO<sub>2</sub>; J—CaMgSi<sub>2</sub>O<sub>6</sub>; K—Al<sub>2</sub>O<sub>3</sub>; O—KAlSiO<sub>4</sub>; P—CaCO<sub>3</sub>; Q—KAl<sub>2</sub>(AlSi<sub>3</sub>O<sub>10</sub>)(OH)<sub>2</sub>; R—KAlSi<sub>3</sub>O<sub>8</sub>; S—TiO<sub>2</sub>; T—Pb<sub>2</sub>O(SO<sub>4</sub>); U—CaSiBO<sub>5</sub>H; V—K<sub>2</sub>Ca<sub>2</sub>Mg(SO<sub>4</sub>)<sub>4</sub>; W—Si<sub>3</sub>N<sub>4</sub>; X—Na(AlSi<sub>3</sub>O<sub>8</sub>); Y—Al<sub>2</sub>(SiO<sub>4</sub>)(OH)<sub>2</sub>; Z—KAl<sub>3</sub>(SiO<sub>4</sub>)(OH)<sub>6</sub>.</p>
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<p>Possible transformation pathways of elemental K during combustion of slime and corn stover.</p>
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14 pages, 15081 KiB  
Article
Implementation of Regenerative Thermal Oxidation Device Based on High-Heating Device for Low-Emission Combustion
by Hoon-Min Park, Dal-Hwan Yoon, Joon-Seong Lee, Hyun-Min Jung, Dae-Hee Lee, Dong-Hwan Jeon and Tae-Yeung Lim
Energies 2024, 17(20), 5182; https://doi.org/10.3390/en17205182 (registering DOI) - 17 Oct 2024
Abstract
In this paper, a heating device is implemented by considering two large factors in a 100 cmm RTO design. First, when the combustion chamber is used for a long time with a high temperature of 750–1100 °C depending on the high concentration VOC [...] Read more.
In this paper, a heating device is implemented by considering two large factors in a 100 cmm RTO design. First, when the combustion chamber is used for a long time with a high temperature of 750–1100 °C depending on the high concentration VOC gas capacity, there is a problem that the combustion chamber explodes or the function of the rotary is stopped due to the fatigue and load of the device. To prevent this, the 100 cmm RTO design with a changed rotary position is improved. Second, an RTO design with a high-heating element is implemented to combust VOC gas discharged from the duct at a stable temperature. Through this, low-emission combustion emissions and energy consumption are reduced. By implementing a high heat generation device, the heat storage combustion oxidation function is improved through the preservation of renewable heat. Over 177 h of demonstration time, we improved the function of 100 cm by discharging 99% of VOC’s removal efficiency, 95.78% of waste heat recovery rate, 21.95% of fuel consumption, and 3.9 ppm of nitrogen oxide concentration. Full article
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<p>Various RTO accident examples.</p>
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<p>The 3D configuration in the combustion chamber and rotary part.</p>
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<p>The energy index flow according to the 100 cmm RTO design.</p>
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<p>Improved RTO according to rotary distributor side design.</p>
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<p>VOCs gas streamline analysis at rotary distributor inlet and outlet.</p>
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<p>Design of the combustion chamber with a high-heating element applied.</p>
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<p>Design of the ceramic heat storage in the chamber.</p>
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<p>Air flowability and temperature characteristics by burner and high-heating element. (<b>a</b>) Analysis with only burner. (<b>b</b>) Analysis with high-heating element.</p>
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<p>Characteristics analysis of rotary distributor by inlet and outlet.</p>
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<p>Integration of experimental RTO configuration.</p>
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<p>VOCs concentration change rate of dry and printing part.</p>
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<p>Combustion chamber operation characteristics with only burner.</p>
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<p>Combustion chamber characteristics with the burner and the high-heating element.</p>
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10 pages, 959 KiB  
Article
An Experimental Study of the Emission Characteristics and Soot Emission of Fatty Acid Methyl Esters (FAME) in an Industrial Burner
by István Péter Kondor and Krisztián Kun
Fuels 2024, 5(4), 650-659; https://doi.org/10.3390/fuels5040035 - 17 Oct 2024
Abstract
The aim of this research is to investigate the environmental emission effects and combustion properties of burning different types of FAME biodiesel fuels in an industrial oil burner. These burner heads are used in many areas of industry for heating various boilers and [...] Read more.
The aim of this research is to investigate the environmental emission effects and combustion properties of burning different types of FAME biodiesel fuels in an industrial oil burner. These burner heads are used in many areas of industry for heating various boilers and tube furnaces. The fuels used, the area of use, the emission norm values, and the climatic conditions are key factors in this investigation. In this research, two plant-based oils are examined, the properties of which have been compared to standard commercial heating oil. The raw material of the two tested bio-based components was rapeseed. The main gas emission parameters CO, THC, CO2, O2, HC, water content, and consumption data were measured. The measurements were performed in an AVL engine brake platform infrastructure, where gas emissions were measured with an AVL AMA i60 FTIR emission gas analyzer, fuel consumption was meticulously gauged using a fuel flow meter, fuel temperature was monitored using an AVL 745 fuel temperature conditioning system, and air consumption was measured with an AVL Flowsonix intake air flow meter. The measurement results showed that both tested biofuels can be burned stably in industrial oil burners, have favorable properties in terms of ignition and flame extinction tendencies, and there is no significant difference in emission parameters compared to standard fuel oil. Full article
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<p>Performance and fuel consumption diagram of the burner.</p>
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<p>The chemical process of producing FAME fuel.</p>
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<p>Schematic diagram of AVL FTIR.</p>
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<p>Schematic diagram of experimental setup.</p>
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<p>Changes in H<sub>2</sub>O emissions for the fuels tested.</p>
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<p>Changes in CO<sub>2</sub> emissions for the fuels tested.</p>
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<p>Changes in CO emissions for the fuels tested.</p>
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<p>Changes in NO<sub>x</sub> emissions for the fuels tested.</p>
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<p>Changes in THC emissions for the fuels tested.</p>
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21 pages, 6291 KiB  
Article
Premixed Combustion Characteristics of Hydrogen/Air in a Micro-Cylindrical Combustor with Double Ribs
by Yi Ma, Wenhua Yuan, Shaomin Zhao and Hongru Fang
Energies 2024, 17(20), 5165; https://doi.org/10.3390/en17205165 - 17 Oct 2024
Abstract
Hydrogen is a promising zero-carbon fuel, and its application in the micro-combustor can promote carbon reduction. The structural design of micro-combustors is crucial for combustion characteristics and thermal performance improvement. This study investigates the premixed combustion characteristics of hydrogen/air in a micro-cylindrical combustor [...] Read more.
Hydrogen is a promising zero-carbon fuel, and its application in the micro-combustor can promote carbon reduction. The structural design of micro-combustors is crucial for combustion characteristics and thermal performance improvement. This study investigates the premixed combustion characteristics of hydrogen/air in a micro-cylindrical combustor with double ribs, using an orthogonal design method to assess the impact of various geometric parameters on thermal performance. The results indicate that the impact of rib height, rib position, and inclined angle is greater than rib width and their interactions, while their influence decreases in that order. Increased rib height improves mean wall temperature and exergy efficiency due to an expanded recirculation region and increased flame–wall contact, but negatively affects temperature uniformity and combustion efficiency. Although double ribs enhance performance, placing them too close may reduce heat transfer due to the low-temperature region between the ribs. When the double ribs are positioned at the axial third equinoxes of the micro-combustor, the highest mean wall temperature is achieved. Meanwhile, with a rib height of 0.3 and an inclined angle of 45°, the micro-combustor achieves optimal thermal performance, with the mean wall temperature increasing by 61.32 K. Full article
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<p>Schematic diagram of the micro-cylindrical combustor with double ribs.</p>
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<p>Grid-independent study for five mesh systems.</p>
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<p>Comparison between present simulation results with reported simulation and experimental results.</p>
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<p>Mean wall temperature and its nonuniformity coefficient at various <span class="html-italic">r</span> values: (<b>a</b>) Mean wall temperature at various <span class="html-italic">r</span> values; (<b>b</b>) Nonuniformity coefficient of mean wall temperature at various <span class="html-italic">r</span> values.</p>
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<p>Outer wall temperature distribution at various <span class="html-italic">r</span> values.</p>
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<p>Distribution of temperature inside the micro-combustor and at the symmetry plane under various <span class="html-italic">r</span> values at the double-rib positions of 3/9 and 5/9.</p>
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<p>Outlet mass fraction of H<sub>2</sub> at various <span class="html-italic">r</span> values.</p>
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<p>Exergy efficiency at various <span class="html-italic">r</span> values.</p>
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<p>Mean wall temperature increase and its nonuniformity coefficient decrease compared with Case0 at various <span class="html-italic">l</span><sub>1</sub> and <span class="html-italic">l</span><sub>2</sub> values: (<b>a</b>) Mean wall temperature increase compared with Case0 at various <span class="html-italic">l</span><sub>1</sub> and <span class="html-italic">l</span><sub>2</sub> values; (<b>b</b>) Nonuniformity coefficient of mean wall temperature decrease compared with Case0 at various <span class="html-italic">l</span><sub>1</sub> and <span class="html-italic">l</span><sub>2</sub> values.</p>
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<p>Mean wall temperature and outer wall temperature distribution under various distances between double ribs at the first rib position of <span class="html-italic">l</span><sub>1</sub> = 3/9 for (<b>a</b>,<b>c</b>) and <span class="html-italic">l</span><sub>1</sub> = 4/9 for (<b>b</b>,<b>d</b>).</p>
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<p>Mean wall temperature under various distances between double ribs at <span class="html-italic">l</span><sub>1</sub> = 3/9, <span class="html-italic">r</span> = 0.2, 0.3, and 0.4.</p>
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<p>Mass fraction increase of H<sub>2</sub> at the outlet compared with Case 0 under various <span class="html-italic">l</span><sub>1</sub> and <span class="html-italic">l</span><sub>2</sub> values.</p>
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<p>(<b>a</b>) Exergy efficiency increases and (<b>b</b>) outlet enthalpy decreases compared with Case 0 at various <span class="html-italic">l</span><sub>1</sub> and <span class="html-italic">l</span><sub>2</sub> values.</p>
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<p>Mean wall temperature and its nonuniformity coefficient at various <span class="html-italic">α</span> values: (<b>a</b>) Mean wall temperature at various <span class="html-italic">α</span> values; (<b>b</b>) Nonuniformity coefficient of mean wall temperature at various <span class="html-italic">α</span> values.</p>
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<p>Comparison of the temperature distribution at various <span class="html-italic">α</span> values at the rib height <span class="html-italic">r</span> = 0.3 (The low-temperature region distribution with different rib angles was marked by the red box).</p>
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<p>Outlet mass fraction of H<sub>2</sub> at various <span class="html-italic">α</span> values.</p>
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<p>Exergy efficiency at various <span class="html-italic">α</span> values.</p>
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15 pages, 4061 KiB  
Article
A Viability Study of Thermal Pre-Treatment for Recycling of Pharmaceutical Blisters
by Mertol Gökelma, Fabian Diaz, İrem Yaren Çapkın and Bernd Friedrich
Sustainability 2024, 16(20), 8968; https://doi.org/10.3390/su16208968 - 16 Oct 2024
Viewed by 319
Abstract
Pharmaceutical packaging is one of the most used packaging types which contains aluminum and plastics. Due to increasing amounts of waste and rising environmental concerns, recycling approaches are being investigated. Since blisters usually contain a balanced amount of plastics and metals, most of [...] Read more.
Pharmaceutical packaging is one of the most used packaging types which contains aluminum and plastics. Due to increasing amounts of waste and rising environmental concerns, recycling approaches are being investigated. Since blisters usually contain a balanced amount of plastics and metals, most of the approaches focus on recycling only one material. Therefore, more sustainable recycling approaches which recover both plastic and aluminum fractions are needed. This study investigates the thermal behavior and degradation mechanisms of plastic-rich and aluminum-rich pharmaceutical blisters using various analytical techniques. Structural characterization revealed that plastic-rich blisters have a thicker profile with plastic and aluminum layers, while aluminum-rich blisters consist of plastic layers between aluminum sheets. Thermal degradation analysis showed two main stages for both types: plastic-rich blisters (polyvinyl chloride) exhibited significant weight loss and long-chain hydrocarbon formation between 210 and 285 °C, and aluminum-rich blisters (polyamide/nylon) degraded from 240 to 270 °C. Differential Scanning Calorimetry and Fourier Transform Infrared Spectroscopy analyses confirmed the endothermic behavior of such a transformation. The gas emissions analysis indicated an increased formation of gasses from the thermal treatment of plastic-rich blisters, with the presence of oxygen leading to the formation of carbon dioxide, water, and carbon monoxide. Thermal treatment with 5% O2 in the carrier gas benefited plastic-rich blister treatment, reducing organic waste by up to 80% and minimizing burning risk, leveraging pyrolytic carbon for protection. This method is unsuitable for aluminum-rich blisters, requiring reduced oxygen or temperature to prevent pyrolytic carbon combustion and aluminum oxidation. Full article
(This article belongs to the Section Waste and Recycling)
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<p>Types of pharmaceutical blisters: (<b>a</b>) plastic-rich, (<b>b</b>) aluminum-rich.</p>
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<p>Schematic of the furnace used for laboratory-scale thermal pre-treatment trials.</p>
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<p>SEM images and EDS mapping of the blisters from the cross-sections of (<b>a</b>) plastic-rich and (<b>b</b>) aluminum-rich blisters.</p>
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<p>Weight loss, derivative thermogravimetry (DTG), and heat flow during TGA-DSC analysis of thermal pre-treatment of (<b>A</b>) plastic-rich blisters and (<b>B</b>) aluminum-rich blisters.</p>
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<p>FTIR analysis of plastic fractions of plastic-rich and aluminum-rich blisters.</p>
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<p>Temperature profile and main species concentration (ppm) during thermal treatment of plastic-rich blisters using 0%, 5%, and 20% oxygen heated at temperatures ranging from 600 °C/h to 800 °C.</p>
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<p>Temperature profile and main species concentration (ppm) during thermal treatment of aluminum-rich blisters using 0%, 5%, and 20% oxygen heated at temperatures ranging from 600 °C/h to 800 °C.</p>
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<p>Weight loss after thermal treatment of (<b>a</b>) plastic-rich and (<b>b</b>) aluminum-rich blisters with 0, 5, and 20% O<sub>2</sub>.</p>
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16 pages, 10438 KiB  
Article
Assessing the Fire Properties of Various Surface Treatments on Timber Components in Ancient Chinese Buildings: A Case Study from the Xianqing Temple in Changzhi, Shanxi, China
by Yupeng Li, Sokyee Yeo, Weihan Zou and Shibing Dai
Coatings 2024, 14(10), 1326; https://doi.org/10.3390/coatings14101326 - 16 Oct 2024
Viewed by 256
Abstract
Traditional and modern coatings play a key role in enhancing the fire resistance of ancient Chinese buildings. However, further comparative analysis is needed on the fire properties of the two coatings and their effects on different timber structural components. This study focuses on [...] Read more.
Traditional and modern coatings play a key role in enhancing the fire resistance of ancient Chinese buildings. However, further comparative analysis is needed on the fire properties of the two coatings and their effects on different timber structural components. This study focuses on the main hall of the Shanxi Changzhi Xianqing Temple, a typical traditional column and beam construction built between the Song and Jin periods. Firstly, the combustion characteristics of various timber structural component samples with different surface treatments (traditional “Yi-ma-wu-hui” and modern flame retardants) were analyzed using cone calorimeter. Secondly, the fire development process of the Xianqing Temple building model was analyzed by a fire dynamics simulator (FDS), and the effect mechanism of different surface treatments on the burning process was further studied. The results show that the fire resistance of timber structural components is significantly improved after modern and traditional surface treatments. The traditional method is more effective in delaying the peak heat release rate and reducing the surface temperature during combustion, while the modern surface treatment significantly prolongs the ignition time of the timber structural components. The FDS results confirm that modern and traditional surface treatments significantly improve the fire resistance of the building, delaying the flashover time by about 300 s, with no collapse occurring within 800 s. In addition, the fire resistance of buildings after traditional surface treatment is better compared to traditional methods. The above research results can provide direct data support for the selection and optimization of fireproof coatings and treatment methods for ancient buildings. Full article
(This article belongs to the Special Issue Coatings for Cultural Heritage: Cleaning, Protection and Restoration)
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<p>Exterior and interior images of the Xianqing Temple.</p>
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<p>Timber species statistics of roof rafter in the main hall of Xianqing Temple.</p>
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<p>Timber sample processing flowchart.</p>
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<p>Schematic of FDS building model, temperature monitoring points, and profile locations.</p>
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<p>Variation in heat release rate of wood samples: (<b>a</b>) elm samples; (<b>b</b>) pine samples; (<b>c</b>) poplar samples.</p>
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<p>Mass change curves with time of wood samples: (<b>a</b>) elm mass change curve; (<b>b</b>) pine mass change curve; (<b>c</b>) poplar mass change curve.</p>
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<p>Curves of sample mass rate versus time: (<b>a</b>) untreated (R<sup>2</sup> = 0.73897); (<b>b</b>) modern treatment (R<sup>2</sup> = 0.77118); (<b>c</b>) traditional treatment (R<sup>2</sup> = 0.67378).</p>
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<p>Smoke generation rate curves for wood samples with different surface treatments: (<b>a</b>) elm samples; (<b>b</b>) pine samples; (<b>c</b>) poplar samples.</p>
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<p>Temperature changes in the main hall of Xianqing Temple (timber structural components without various surface treatments).</p>
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<p>Temperature change rate curves for the main hall of Xianqing Temple (timber structural components without various surface treatments): (<b>a</b>) monitoring point 1; (<b>b</b>) monitoring point 2; (<b>c</b>) monitoring point 3.</p>
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<p>Temperature distribution maps at Y = 10 m profiles of the main hall of Xianqing Temple (timber structural components without various surface treatments).</p>
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<p>Temperature distribution maps at Y = 7 m profiles of the main hall of Xianqing Temple (timber structural components without various surface treatments).</p>
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<p>Temperature distribution maps at Y = 4 m profiles of the main hall of Xianqing Temple (timber structural components without various surface treatments).</p>
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<p>Temperature changes in the main hall of Xianqing Temple with different surface treatments: (<b>a</b>) monitoring point 1; (<b>b</b>) monitoring point 2; (<b>c</b>) monitoring point 3.</p>
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16 pages, 6046 KiB  
Article
Numerical Study on the Explosion Reaction Mechanism of Multicomponent Combustible Gas in Coal Mines
by Dong Ma, Leilin Zhang, Guangyuan Han and Tingfeng Zhu
Fire 2024, 7(10), 368; https://doi.org/10.3390/fire7100368 - 16 Oct 2024
Viewed by 236
Abstract
Combustible gases, such as CO, CH4, and H2, are produced during spontaneous coal combustion in goaf, which may cause an explosion under the stimulation of an external fire source. It is of great significance to study the influence of [...] Read more.
Combustible gases, such as CO, CH4, and H2, are produced during spontaneous coal combustion in goaf, which may cause an explosion under the stimulation of an external fire source. It is of great significance to study the influence of combustible gases, such as CO and H2, on the characteristics of a gas explosion. In this study, CHEMKIN software (Version 17.0) and the GRI-Mech 3.0 reaction mechanism were used to study the influences of different concentration ratios between CO and H2 on the ignition delay time, free radical concentration, and key reaction step of a gas explosion. The results show that the increase in the initial CH4 and CO concentrations prolonged the ignition delay time, while the increase in the H2 concentration shortened the time and accelerated the explosion reaction. The addition of H2 promoted the generation of free radicals (H·, O·, ·OH) and accelerated the occurrence of the gas explosion. CO generated ·OH free radicals and dominated the methane consumption through the R119 and R156 reactions. As the concentrations of CO and H2 increased, the R38 reaction gradually became the main driving factor of the gas explosion. Full article
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<p>The technology roadmap of this study.</p>
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<p>Relationship between ignition delay time and concentration of added combustible gas.</p>
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<p>The influence of CO on H·, O·, and ·OH in the process of the 7% methane explosion.</p>
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<p>The influence of the concentration of CO and H<sub>2</sub> mixed gases on H·, O·, and ·OH in the 7% methane explosion process.</p>
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<p>The influence of CO or CO and H<sub>2</sub> on H·, O·, and ·OH during the methane explosion.</p>
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<p>Influence of CO on the reaction sensitivity of the 7% gas key elements.</p>
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<p>Effect of CO on the gas sensitivity of the 9.5% gas key element reaction.</p>
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<p>Effect of CO on gas sensitivity of 11% gas key elements.</p>
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<p>Influence of the CO and H<sub>2</sub> mixture on the sensitivity of 7% gas key elements.</p>
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<p>Influence of the CO and H<sub>2</sub> mixture on the reaction sensitivity of the 9.5% gas key elements.</p>
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<p>Influence of CO and H<sub>2</sub> mixture on the sensitivity of the 11% gas key elements.</p>
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12 pages, 2579 KiB  
Article
Study on the Characteristics of Combustible Mixed Gas Production during Lignite Oxidation Process
by Dong Ma, Tingfeng Zhu, Puchun Yuan and Leilin Zhang
Fire 2024, 7(10), 367; https://doi.org/10.3390/fire7100367 - 16 Oct 2024
Viewed by 309
Abstract
CO, H2, and other combustible gases will be produced during coal oxidation in coal mines, which will increase the risk of explosion when mixed with methane. Therefore, it is very important to understand the production characteristics of combustible gas during coal [...] Read more.
CO, H2, and other combustible gases will be produced during coal oxidation in coal mines, which will increase the risk of explosion when mixed with methane. Therefore, it is very important to understand the production characteristics of combustible gas during coal oxidation. In this paper, a programmed temperature gas test system is built to study the impact of lignite on the production of gases at different particle sizes and temperatures, and the release characteristics of gases are also analyzed. The result shows that the production of combustible gas is influenced by the coal particle size significantly when the temperature is above 200 °C, and it decreases as the particle size increases. CO is the main gas during the early stage of coal spontaneous combustion, and the release of CH4 and H2 increases after 300 °C. The fitted equations of gas generation and temperature are consistent with the experimental results. The research results are helpful in understanding the hazards of coal spontaneous combustion and have a certain guiding significance for coal mine monitoring and prevention of coal spontaneous combustion. Full article
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<p>Coal spontaneous combustion programmed temperature gas test system.</p>
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<p>The concentration of gas with temperature during the heating process.</p>
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<p>The percentage of combustible gas during the heating process with different particle sizes.</p>
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<p>The percentage of combustible gas during the heating process with different particle sizes.</p>
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<p>Fitting results of combustible gas production in the oxidation process.</p>
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<p>Comparison of experimental data and calculated results of the total concentration of combustible gas generated from EMW lignite.</p>
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16 pages, 3920 KiB  
Article
Characterization of Lithium-Ion Battery Fire Emissions—Part 2: Particle Size Distributions and Emission Factors
by Matthew Claassen, Bjoern Bingham, Judith C. Chow, John G. Watson, Pengbo Chu, Yan Wang and Xiaoliang Wang
Batteries 2024, 10(10), 366; https://doi.org/10.3390/batteries10100366 - 16 Oct 2024
Viewed by 434
Abstract
The lithium-ion battery (LIB) thermal runaway (TR) emits a wide size range of particles with diverse chemical compositions. When inhaled, these particles can cause serious adverse health effects. This study measured the size distributions of particles with diameters less than 10 µm released [...] Read more.
The lithium-ion battery (LIB) thermal runaway (TR) emits a wide size range of particles with diverse chemical compositions. When inhaled, these particles can cause serious adverse health effects. This study measured the size distributions of particles with diameters less than 10 µm released throughout the TR-driven combustion of cylindrical lithium iron phosphate (LFP) and pouch-style lithium cobalt oxide (LCO) LIB cells. The chemical composition of fine particles (PM2.5) and some acidic gases were also characterized from filter samples. The emission factors of particle number and mass as well as chemical components were calculated. Particle number concentrations were dominated by those smaller than 500 nm with geometric number mean diameters below 130 nm. Mass concentrations were also dominated by smaller particles, with PM1 particles making up 81–95% of the measured PM10 mass. A significant amount of organic and elemental carbon, phosphate, and fluoride was released as PM2.5 constituents. The emission factor of gaseous hydrogen fluoride was 10–81 mg/Wh, posing the most immediate danger to human health. The tested LFP cells had higher emission factors of particles and HF than the LCO cells. Full article
(This article belongs to the Special Issue Thermal Safety of Lithium Ion Batteries)
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<p>Particle number distribution heatmaps for representative LFP and LCO tests at each SOC.</p>
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<p>Particle number distribution snapshots (<b>left</b>: log scale and <b>right</b>: linear scale) and heatmap (<b>bottom</b>) for a representative 0% SOC LFP test. GNMDs for t<sub>1–4</sub> are 59 nm, 22 nm, 91 nm, and 49 nm, respectively.</p>
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<p>Particle number distribution snapshots (<b>left</b>: log scale and <b>right</b>: linear scale) and heatmap (<b>bottom</b>) for a representative 60% SOC LCO test. GNMDs for t<sub>1–4</sub> are 117 nm, 59 nm, 195 nm, and 52 nm, respectively.</p>
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<p>Mass concentrations of PM<sub>1</sub>, PM<sub>2.5</sub>, and PM<sub>10</sub> for the representative tests: (<b>a</b>) LFP at 0% SOC and (<b>b</b>) LCO at 60% SOC (same as those in <a href="#batteries-10-00366-f002" class="html-fig">Figure 2</a> and <a href="#batteries-10-00366-f003" class="html-fig">Figure 3</a>). The coarse particles (PM<sub>2.5–10</sub>) are released predominantly during TR.</p>
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<p>Particle number (top panels) and mass (bottom panels) distributions for LFP (<b>a</b>,<b>c</b>) and LCO (<b>b</b>,<b>d</b>) tests. An outlier was removed from some SOC groups to better show the prevailing trends.</p>
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<p>Emission factors for (<b>a</b>) particle number and (<b>b</b>) particle mass by size fraction for LFP and LCO tests. Error bars represent the total PM<sub>10</sub> standard error (including all smaller particle sizes) and are symmetric.</p>
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<p>Emission factors for (<b>a</b>) PM<sub>2.5</sub> mass, OC, EC, and PO<sub>4</sub><sup>3−</sup> and (<b>b</b>) selected metals. The error bars represent the larger of the propagated analytical uncertainty or the standard error within each SOC and are symmetric.</p>
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<p>Emission factors for (<b>a</b>) selected acidic gases and (<b>b</b>) corresponding particulate anions. The error bars represent the larger of the propagated analytical uncertainty or the standard error within each SOC and are symmetric.</p>
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<p>Relationship between EFs and maximum detected combustion temperature for LFP tests. LCO tests showed little correlation, possibly due to poor temperature measurement, and are not shown.</p>
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20 pages, 4957 KiB  
Article
Analysis of Energy Efficiency Parameters of a Hybrid Vehicle Powered by Fuel with a Liquid Catalyst
by Tomasz Osipowicz, Wawrzyniec Gołębiewski, Wojciech Lewicki, Adam Koniuszy, Karol Franciszek Abramek, Konrad Prajwowski, Oleh Klyus and Dominik Gałdyński
Energies 2024, 17(20), 5138; https://doi.org/10.3390/en17205138 (registering DOI) - 16 Oct 2024
Viewed by 260
Abstract
A notable trend in the modern automotive market is the increased interest in hybrid cars. Hybrid cars combine a standard internal combustion engine with an electric motor solution. Research into increasing the energy efficiency of a conventional unit while meeting increasingly stringent exhaust [...] Read more.
A notable trend in the modern automotive market is the increased interest in hybrid cars. Hybrid cars combine a standard internal combustion engine with an electric motor solution. Research into increasing the energy efficiency of a conventional unit while meeting increasingly stringent exhaust emission standards is becoming a key postulate in this matter. This article discusses an analysis of modifying the fuel used by hybrid vehicles using the example of a selected drive unit equipped with a spark-ignition engine. This effect was tested after the Eco Fuel Shot liquid catalyst was added to the fuel. The research process was carried out in two stages, as follows: in road conditions using the Dynomet road dynamometer; and on the V-tech VT4/B2 chassis dynamometer. Tests were carried out to replicate road tests with a catalytic additive in the fuel. A mathematical model was created and the following energy efficiency parameters of the hybrid vehicle were calculated: the torque of the internal combustion engine, electric motor, and generator; the rotational speeds of the internal combustion engine, electric motor, and generator; the power of the internal combustion engine, electric motor, and generator; the equivalent fuel consumption of the electric motor and generator; the fuel consumption of the internal combustion engine, electric motor, and generator; and the mileage fuel consumption of the internal combustion engine, electric motor, and generator. The results of the tests made it possible to identify the benefits of using the tested liquid catalyst on the operation of the drive system of the analyzed hybrid vehicle. This research will be of benefit to both the demand side in the form of users of this category of vehicles, and the supply side represented by the manufacturers of power units. Full article
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<p>Portable road dynamometer type Dynomet.</p>
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<p>Methodology of measurement for the Dynomet road dynamometer.</p>
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<p>Tested vehicle on V-tech VT4/B2 chassis dynamometer.</p>
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<p>Base physical model of the powertrain of a hybrid vehicle.</p>
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<p>Speed and distance traveled by vehicle under test without the catalyst.</p>
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<p>Torques: generator, electric motor, internal combustion engine, on wheels: (<b>A</b>) standard fuel; and (<b>B</b>) fuel with catalytic converter Eco Fuel Shot.</p>
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<p>Rotational speeds: generator, electric motor, internal combustion engine: (<b>A</b>) standard fuel; and (<b>B</b>) fuel with catalytic converter Eco Fuel Shot.</p>
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<p>Mass fuel consumption: internal combustion engine, equivalent electric machines, total: (<b>A</b>) standard fuel; and (<b>B</b>) fuel with catalytic converter Eco Fuel Shot.</p>
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<p>Power and degree of charge of the traction battery: (<b>A</b>) standard fuel; and (<b>B</b>) fuel with catalytic converter Eco Fuel Shot.</p>
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<p>Mileage fuel consumption (internal combustion engine only).</p>
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<p>Total fuel consumption of an internal combustion engine with an electric motor.</p>
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15 pages, 8216 KiB  
Article
20 kHz CH2O- and SO2-PLIF/OH*-Chemiluminescence Measurements on Blowoff in a Non-Premixed Swirling Flame under Fuel Mass Flow Rate Fluctuations
by Chen Fu, Xiaoyang Wang, Yunhui Wu and Yi Gao
Appl. Sci. 2024, 14(20), 9419; https://doi.org/10.3390/app14209419 - 16 Oct 2024
Viewed by 288
Abstract
Blowoff limits are essential in establishing the combustor operating envelope. Hence, there is a great demand for practical aero-engines to extend the blowoff limits further. In this work, the behavior of non-premixed swirling flames under fuel flow rate oscillations was investigated experimentally close [...] Read more.
Blowoff limits are essential in establishing the combustor operating envelope. Hence, there is a great demand for practical aero-engines to extend the blowoff limits further. In this work, the behavior of non-premixed swirling flames under fuel flow rate oscillations was investigated experimentally close to its blowoff limits. The methane flame was stabilized on the axisymmetric bluff body and confined in a square quartz enclosure. External acoustic forcing at 400 Hz was applied to the fuel flow to induce a fuel mass flow rate fluctuation (FMFRF) with varying amplitudes. A high-speed burst-mode laser and cameras ran at 20 kHz for OH*-chemiluminescence (CL), CH2O-, and SO2-PLIF measurements, offering the visualization of the two-dimensional flame structure and heat release distribution, temporally and spatially. The results show that the effect of FMFRF is predominantly along the central axis without altering the time-averaged flame structure and blowoff transient. However, the blowoff limits are extended due to the enhanced temperature and longer residence time induced by FMFRF. This work allows us to explore the mechanism of flame instability further. Full article
(This article belongs to the Section Aerospace Science and Engineering)
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<p>(<b>a</b>) Schematic of the burner and (<b>b</b>) flame structure of non-premixed swirling flame [<a href="#B59-applsci-14-09419" class="html-bibr">59</a>,<a href="#B60-applsci-14-09419" class="html-bibr">60</a>].</p>
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<p>(<b>a</b>) Axial velocity fluctuation of the fuel at the jet nozzle as a function of the loudspeaker voltage for 5 different mean fuel velocities and (<b>b</b>) time-resolved velocity under a loudspeaker voltage of 0.6 V (FMFRF amplitude ~80%) along the jet centerline at the downstream height of 1 mm above the nozzle exit in three acoustic periods with a time interval of 0.1 ms.</p>
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<p>High-speed PLIF/chemiluminescence imaging system.</p>
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<p>The processes of laser intensity correction. (<b>a</b>) The images of the cuvette, (<b>b</b>) the profile of laser intensity, (<b>c</b>) uncorrected PLIF, and (<b>d</b>) corrected PLIF (CH<sub>2</sub>O-PLIF on the left and SO<sub>2</sub>-PLIF on the right). The sample image is from the flame forced by an 80% FMFRF amplitude at a mean fuel mass flow rate of 0.142 g/s and air velocity of 17.1 m/s.</p>
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<p>The left half of the inverse Abel-transformed time-averaged OH*-CL images with varying FMFRFs (displayed at the top of every image) at the conditions with a mean fuel mass flow rate of 0.142 g/s and air velocity of 17.1 m/s.</p>
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<p>Comparison of time-averaged (<b>a</b>) CH<sub>2</sub>O- and (<b>b</b>) SO<sub>2</sub>-PLIF images at the unforced (left half) and forced cases (right half) with 80% FMFRF amplitude at a mean fuel mass flow rate of 0.142 g/s and air velocity of 17.1 m/s.</p>
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<p>Phase-averaged CH<sub>2</sub>O- (<b>every left</b>) and SO<sub>2</sub>-PLIF (<b>every right</b>) images from flames at a mean fuel mass flow rate of 0.142 g/s and air velocity of 17.1 m/s with 80% FMFRF, and the phase is marked in every subgraph.</p>
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<p>A sequence of instantaneous CH<sub>2</sub>O-PLIF (<b>a</b>,<b>c</b>) and SO<sub>2</sub>-PLIF (<b>b</b>,<b>d</b>) images taken in flames at a mean fuel mass flow rate of 0.142 g/s and air velocity of 17.1 m/s at the unforced (<b>a</b>,<b>b</b>) and forced cases (<b>c</b>,<b>d</b>) with 80% FMFRF. The SO<sub>2</sub>-PLIF signal at <span class="html-italic">z</span> = 18 mm (red dotted line in (<b>b</b>,<b>d</b>)) is presented in (<b>e</b>) to highlight the temperature rise in the shear layer. Note that the CH<sub>2</sub>O- and SO<sub>2</sub>-PLIF were not simultaneous.</p>
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<p>The blowoff air velocity as a function of the varying FMFRF amplitude at a mean fuel mass flow rate of 0.142 g/s.</p>
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<p>Time sequence of instantaneous OH*-CL images during an individual blowoff event at a mean fuel mass flow rate of 0.142 g/s with no acoustic forcing corresponding to a blowoff velocity of 16.5 m/s.</p>
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<p>Global OH*-CL signal intensity and the occurrence probability of blowoff precursors under various FMFRT amplitudes at a mean fuel mass flow rate of 0.142 g/s.</p>
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15 pages, 879 KiB  
Entry
Synthetic Fuels for Decarbonising UK Rural Transport
by Al-Amin Abba Dabo, Andrew Gough and F. Frank Alparslan
Encyclopedia 2024, 4(4), 1553-1567; https://doi.org/10.3390/encyclopedia4040101 - 15 Oct 2024
Viewed by 262
Definition
Decarbonising transport is a crucial element of the UK’s strategy to achieve net-zero carbon emissions by 2050, as the transport sector is currently the largest contributor to the UK’s greenhouse gas emissions. Rural communities face distinct challenges in this effort due to their [...] Read more.
Decarbonising transport is a crucial element of the UK’s strategy to achieve net-zero carbon emissions by 2050, as the transport sector is currently the largest contributor to the UK’s greenhouse gas emissions. Rural communities face distinct challenges in this effort due to their reliance on internal combustion engines (ICEs) across vehicles and machinery essential for daily life, including farming equipment and private transport. While the upcoming ban on new petrol and diesel vehicles paves the way for the adoption of Electric Vehicles (EVs), this solution may not fully address the unique needs of rural areas where infrastructure limitations and specific mobility requirements pose significant barriers. In this context, synthetic fuels, produced using renewable energy sources, offer a potential alternative. These fuels can be used directly in existing internal combustion engines without requiring major modifications and have the added benefit of reducing overall greenhouse gas emissions by capturing CO2 during production. This entry explores the potential advantages of adopting synthetic fuels, particularly in rural areas, and examines how community-based buying cooperatives could support their wider use through bulk purchasing, cost reduction, and community empowerment. Full article
(This article belongs to the Section Social Sciences)
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<p>Net CO<sub>2</sub> impact (gramme CO<sub>2</sub> per gramme of fuel) of synthetic fuel production methods: Sabatier, biomass pyrolysis, and heavy oil upgrading (source: [<a href="#B35-encyclopedia-04-00101" class="html-bibr">35</a>,<a href="#B36-encyclopedia-04-00101" class="html-bibr">36</a>,<a href="#B37-encyclopedia-04-00101" class="html-bibr">37</a>,<a href="#B38-encyclopedia-04-00101" class="html-bibr">38</a>]).</p>
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<p>Applications of Synthetic Fuels in Rural Transport.</p>
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8 pages, 1822 KiB  
Proceeding Paper
Improving Internal Combustion Engine Performance through Inlet Valve Geometry and Spray Angle Optimization: Computational Fluid Dynamics Study
by Muhammad Ahsan and Mian Noman
Eng. Proc. 2024, 72(1), 6; https://doi.org/10.3390/engproc2024072006 - 15 Oct 2024
Viewed by 144
Abstract
This study aimed to calculate the impact of inlet valve geometry and spray angle on the performance of internal combustion engines using computational fluid dynamics (CFD) analysis. CFD analysis was performed to explore the fuel flow dynamics within a combustion chamber at critical [...] Read more.
This study aimed to calculate the impact of inlet valve geometry and spray angle on the performance of internal combustion engines using computational fluid dynamics (CFD) analysis. CFD analysis was performed to explore the fuel flow dynamics within a combustion chamber at critical stages, considering factors such as swirl and tumble. This study investigated the role of the intake port’s geometry and spray angles in creating squish and swirl, which is crucial for enhancing combustion efficiency and overall engine performance. The analysis employed the Finite Volume Method (FVM), solved within ANSYS Fluent 2021 software, utilizing the standard k-ε turbulence model. Design Modeler was used for the geometry design and ANSYS Fluent facilitated the CFD analysis of the injection. Four distinct cases were explored to assess engine performance across various designs, examining parameters such as pressure, temperature, and velocity. These performance parameters were evaluated against the existing literature, enabling the identification of optimal configurations. This study identified optimal performance parameters based on the existing literature. The best design was further validated against existing designs under identical boundary conditions. This research demonstrates improved engine performance across all parameters compared to existing values in the literature. This suggests the efficacy of the proposed inlet valve geometry and spray angle configurations in increasing internal combustion engine efficiency. Full article
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<p>Mesh of a sector of the engine.</p>
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<p>Contours of static temperature.</p>
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<p>Velocity magnitude.</p>
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<p>Penetration length vs. crank angle.</p>
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15 pages, 8364 KiB  
Article
Research on the Design and Bidirectional Work Process of Metal Diaphragms in Small Double-Pulse Solid Rocket Motors
by Xueqin Du, Weihua Hui, Youwen Tan, Wen Feng and Yang Liu
Aerospace 2024, 11(10), 848; https://doi.org/10.3390/aerospace11100848 - 15 Oct 2024
Viewed by 179
Abstract
According to the requirements of the small double-pulse solid rocket motor, a compartmentalized isolation device has been designed. This device consists of a metal diaphragm and a support frame. An experimental study and numerical simulation were used to verify the bidirectional working process [...] Read more.
According to the requirements of the small double-pulse solid rocket motor, a compartmentalized isolation device has been designed. This device consists of a metal diaphragm and a support frame. An experimental study and numerical simulation were used to verify the bidirectional working process of the metal diaphragm during operation of the double-pulse motor. The results show that the pressure-bearing capacity of the metal diaphragm meets the requirements under the working conditions of pulse I without affecting pulse II, because the metal diaphragm can provide insulation and flame retardancy. The metal diaphragm can be cracked in the direction of the preset V-groove in a relatively short time under the working conditions of pulse II, which allows the gas to flow to the first pulse combustion chamber normally. This indicates that the metal diaphragm can meet the requirements of bidirectional working process in dual-pulse motors. Full article
(This article belongs to the Section Astronautics & Space Science)
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<p>The longitudinal section of the double-pulse motor.</p>
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<p>(<b>a</b>) The structure of the cross-support frame; (<b>b</b>) the metal diaphragm plate (pulse I view); (<b>c</b>) the dimensions of the V-grooves.</p>
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<p>(<b>a</b>) The mesh model; (<b>b</b>) the boundary condition; (<b>c</b>) the working load of the PSD.</p>
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<p>Von Mises stress contour plot of the metal diaphragm: (<b>a</b>) pulse I view; (<b>b</b>) pulse II view; (<b>c</b>) lateral view.</p>
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<p>Von Mises stress contour plot of the support frame.</p>
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<p>(<b>a</b>) The metal diaphragm; (<b>b</b>) the cross-type support frame after the experiment.</p>
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<p>Metal diaphragm after the experiment: (<b>a</b>) pulse I view; (<b>b</b>) pulse II view; (<b>c</b>) lateral view.</p>
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<p>Pressure profile during the operation of the pulse I motor.</p>
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<p>The uniaxial tensile stress–strain curve of a typical metal specimen [<a href="#B27-aerospace-11-00848" class="html-bibr">27</a>].</p>
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<p>(<b>a</b>) The mesh model; (<b>b</b>) the boundary condition; (<b>c</b>) the working load of the diaphragm.</p>
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<p>Von Mises stress contour plot of the metal diaphragm at six moments.</p>
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<p>Components of the motor after the experiment: (<b>a</b>) pulse II combustion chamber and separation device; (<b>b</b>) ignition apparatus; (<b>c</b>) support frame; (<b>d</b>) metal diaphragm.</p>
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<p>Metal diaphragm after the experiment: (<b>a</b>) slotted side; (<b>b</b>) smooth side; (<b>c</b>) lateral side; (<b>d</b>) deformation of the metal diaphragm.</p>
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<p>Pressure profile of pulse I and pulse II in the test.</p>
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<p>Double-pulse motor before the experiment.</p>
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<p>Working process of the pulse I motor.</p>
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<p>Working process of the pulse II motor.</p>
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<p>Components of the motor after the experiment: (<b>a</b>) the pulse II motor section; (<b>b</b>) the support frame; (<b>c</b>) the metal diaphragm.</p>
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<p>Pressure profile of the pulse I motor during operation.</p>
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<p>Pressure profile of the pulse II motor during operation.</p>
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16 pages, 8467 KiB  
Article
Quality Enhancement of Torrefied Biopellets Prepared by Unused Forest Biomass and Wood Chip Residues in Pulp Mills
by Tae-Gyeong Lee, Chul-Hwan Kim, Hyeong-Hun Park, Ju-Hyun Park, Min-Sik Park and Jae-Sang Lee
Appl. Sci. 2024, 14(20), 9398; https://doi.org/10.3390/app14209398 - 15 Oct 2024
Viewed by 373
Abstract
The effects of torrefaction of the biopellets made from hardwood chip residue (HW), camellia oilseed cake (CO), and pruning remnants of the toothache tree (TA) and mulberry tree (MT) were evaluated. Torrefaction of the biopellets reduced the volatile matter content of biopellets by [...] Read more.
The effects of torrefaction of the biopellets made from hardwood chip residue (HW), camellia oilseed cake (CO), and pruning remnants of the toothache tree (TA) and mulberry tree (MT) were evaluated. Torrefaction of the biopellets reduced the volatile matter content of biopellets by 18–58% and increased their heating value by 18–58% without negatively impacting durability or fines content. Torrefaction also reduced the initial ignition time of biopellets by 50–59% and prolonged their combustion duration by 15–24%. Regardless of the type of feedstock, all biopellets exhibited mass yields in the range of 60–80% and energy yields ranging from 80–95%. The novelty of this study lies in the application of torrefaction to already-formed biopellets, which enhances pellet quality without the need for binders, and the use of unused forest biomass and wood chip residue from pulp mills. The use of unused forest biomass and wood chip residue from pulp mills for biopellet production not only provides a sustainable and efficient method for waste utilization but also contributes to environmental conservation by reducing the reliance on fossil fuels. Overall, the torrefaction of biopellets represents a promising technology for producing high-quality solid biofuel from a variety of woody biomass feedstocks without compromising pelletizing efficiency. Full article
(This article belongs to the Section Applied Industrial Technologies)
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<p>Ground woody biomass used to manufacture biopellets.</p>
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<p>Pelletizer with a flat die.</p>
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<p>Images of pellets before and after torrefaction using various raw materials.</p>
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<p>Experimental image of analyzing time for the initial ignition and combustion duration of biopellets: (<b>a</b>) pellet ignition by a potable gas torch; (<b>b</b>) ignited pellet with a flame.</p>
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<p>Proximate analysis of the prepared pellets before and after torrefaction.</p>
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<p>Ultimate analysis of the prepared pellets before and after torrefaction.</p>
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<p>Durability of the prepared pellets before and after torrefaction: (<b>a</b>) durability; (<b>b</b>) fines content.</p>
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<p>Bulk density of the prepared pallets before and after torrefaction.</p>
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<p>Calorific value of the prepared biopellets before and after torrefaction.</p>
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<p>Mass and energy yield of the prepared biopellets by torrefaction.</p>
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<p>Ignition and combustion time of the biopellets before and after torrefaction: (<b>a</b>) ignition time; (<b>b</b>) combustion duration.</p>
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<p>Thermogravimetric analysis of the biopellets before and after torrefaction: (<b>a</b>) HW; (<b>b</b>) CO; (<b>c</b>) TA; (<b>d</b>) MT.</p>
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<p>SEM images of biopellets before and after torrefaction.</p>
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<p>Importance and applications of torrefied biopellets.</p>
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