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Search Results (2,909)

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21 pages, 2472 KiB  
Article
Sustainable Recovery of Polyphenols and Carotenoids from Horned Melon Peel via Cloud Point Extraction
by Vanja Travičić, Teodora Cvanić, Senka Vidović, Lato Pezo, Alyssa Hidalgo, Olja Šovljanski and Gordana Ćetković
Foods 2024, 13(18), 2863; https://doi.org/10.3390/foods13182863 - 10 Sep 2024
Viewed by 194
Abstract
Using natural plant extracts as food additives is a promising approach for improving food products’ quality, nutritional value, and safety, offering advantages for both consumers and the environment. Therefore, the main goal of this study was to develop a sustainable method for extracting [...] Read more.
Using natural plant extracts as food additives is a promising approach for improving food products’ quality, nutritional value, and safety, offering advantages for both consumers and the environment. Therefore, the main goal of this study was to develop a sustainable method for extracting polyphenols and carotenoids from horned melon peel using the cloud point extraction (CPE) technique, intending to utilize it as a natural food additive. CPE is novel promising extraction method for separation and pre-concentration of different compounds while being simple, inexpensive, and low-toxic. Three parameters within the CPE approach, i.e., pH, equilibrium temperature, and equilibrium time, were investigated as independent variables through the implementation of Box–Behnken design and statistical analyses. The optimized conditions for the maximum recovery of both polyphenols and carotenoids, reaching 236.14 mg GAE/100 g and 13.80 mg β carotene/100 g, respectively, were a pH value of 7.32, an equilibrium temperature of 55 °C, and an equilibrium time of 43.03 min. The obtained bioactives’ recovery values under the optimized conditions corresponded to the predicted ones, indicating the suitability of the employed RSM model. These results highlight the effectiveness of CPE in extracting bioactive compounds with varying polarities from agricultural by-products, underscoring its potential for enhancing the value of food waste and advancing sustainable practices in food processing. According to microbiological food safety parameters, the optimal CPE extract is suitable for food applications, while its storage under refrigerated and dark conditions is particularly beneficial. The CPE extract’s enhanced stability under these conditions makes it a more viable option for long-term storage, preserving both safety and quality. Full article
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<p>Appearances of the CPE extracts of horned melon peel obtained according to BBD experimental design.</p>
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<p>PCA ordination of variables based on component correlations is presented in the first and second factor planes, including total carotenoid content (TCs), total phenol content (TPs), DPPH radical scavenging activity, reducing power (RP), and ABTS radical scavenging activity (ABTS). “sp” in subscript indicates surfactant-rich phase, “wp” in subscript indicates water phase.</p>
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<p>Pareto charts for CPE outcomes for surfactant-rich phase of CPE extract.</p>
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<p>Contour plots for CPE outcomes for surfactant-rich phase of CPE extract.</p>
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<p>Standard scores.</p>
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<p>Storage stability of water-based and CPE extracts related to the microbiological parameters (room temperature with light (RT+L); room temperature without light (RT−L); refrigerated with light (FT+L); refrigerated without light (FT−L)): (<b>a</b>) total viable count; (<b>b</b>) yeast and mould count.</p>
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16 pages, 489 KiB  
Article
A Novel Approach for Testing Fractional Cointegration in Panel Data Models with Fixed Effects
by Saidat Fehintola Olaniran, Oyebayo Ridwan Olaniran, Jeza Allohibi and Abdulmajeed Atiah Alharbi
Fractal Fract. 2024, 8(9), 527; https://doi.org/10.3390/fractalfract8090527 - 10 Sep 2024
Viewed by 181
Abstract
Fractional cointegration in time series data has been explored by several authors, but panel data applications have been largely neglected. A previous study of ours discovered that the Chen and Hurvich fractional cointegration test for time series was fairly robust to a moderate [...] Read more.
Fractional cointegration in time series data has been explored by several authors, but panel data applications have been largely neglected. A previous study of ours discovered that the Chen and Hurvich fractional cointegration test for time series was fairly robust to a moderate degree of heterogeneity across sections of the six tests considered. Therefore, this paper advances a customized version of the Chen and Hurvich methodology to detect cointegrating connections in panels with unobserved fixed effects. Specifically, we develop a test statistic that accommodates variation in the long-term cointegrating vectors and fractional cointegration parameters across observational units. The behavior of our proposed test is examined through extensive Monte Carlo experiments under various data-generating processes and circumstances. The findings reveal that our modified test performs quite well comparatively and can successfully identify fractional cointegrating relationships in panels, even in the presence of idiosyncratic disturbances unique to each cross-sectional unit. Furthermore, the proposed modified test procedure established the presence of long-run equilibrium between the exchange rate and labor wage of 36 countries’ agricultural markets. Full article
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<p>Normal Q–Q plot of the modified [<a href="#B5-fractalfract-08-00527" class="html-bibr">5</a>] test under <math display="inline"><semantics> <msub> <mi>H</mi> <mn>0</mn> </msub> </semantics></math>.</p>
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<p>Normal Q–Q plot of the modified [<a href="#B5-fractalfract-08-00527" class="html-bibr">5</a>] test under <math display="inline"><semantics> <msub> <mi>H</mi> <mn>1</mn> </msub> </semantics></math>.</p>
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<p>Time plot of exchange rate <math display="inline"><semantics> <mrow> <mi>E</mi> <mi>X</mi> <mo>(</mo> <mi>t</mi> <mo>)</mo> </mrow> </semantics></math> and labor wage <math display="inline"><semantics> <mrow> <mi>L</mi> <mi>W</mi> <mo>(</mo> <mi>t</mi> <mo>)</mo> </mrow> </semantics></math> for Afghanistan, Armenia, Bangladesh, Burkina Faso, Burundi, Cameroon, Central African Republic, Chad, Democratic Republic of Congo, Republic of Congo, Gambia, and Guinea.</p>
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<p>Time plot of exchange rate <math display="inline"><semantics> <mrow> <mi>E</mi> <mi>X</mi> <mo>(</mo> <mi>t</mi> <mo>)</mo> </mrow> </semantics></math> and labor wage <math display="inline"><semantics> <mrow> <mi>L</mi> <mi>W</mi> <mo>(</mo> <mi>t</mi> <mo>)</mo> </mrow> </semantics></math> for Guinea-Bisau, Haiti, Indonesia, Iraq, Kenya, Lao PDR, Lebanon, Liberia, Libya, Malawi, Mali, and Mauritania.</p>
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<p>Time plot of exchange rate <math display="inline"><semantics> <mrow> <mi>E</mi> <mi>X</mi> <mo>(</mo> <mi>t</mi> <mo>)</mo> </mrow> </semantics></math> and labor wage <math display="inline"><semantics> <mrow> <mi>L</mi> <mi>W</mi> <mo>(</mo> <mi>t</mi> <mo>)</mo> </mrow> </semantics></math> for Mozambique, Myanmar, Niger, Nigeria, Philippines, Senegal, Somalia, South Sudan, Sri Lanka, Sudan, Syrian Arab Republic, and Yemen Republic.</p>
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22 pages, 2364 KiB  
Article
Water and Fertilizer Management Is an Important Way to Synergistically Enhance the Yield, Rice Quality and Lodging Resistance of Hybrid Rice
by Haijun Zhu, Lingli Nie, Xiaoe He, Xuehua Wang, Pan Long and Hongyi Chen
Plants 2024, 13(17), 2518; https://doi.org/10.3390/plants13172518 - 7 Sep 2024
Viewed by 302
Abstract
This study comprehensively investigated the synergistic effects and underlying mechanisms of optimized water and fertilizer management on the yield, quality, and lodging resistance of hybrid rice (Oryza sativa), through a two-year field experiment. Two hybrid rice varieties, Xinxiangliangyou 1751 (XXLY1751) and [...] Read more.
This study comprehensively investigated the synergistic effects and underlying mechanisms of optimized water and fertilizer management on the yield, quality, and lodging resistance of hybrid rice (Oryza sativa), through a two-year field experiment. Two hybrid rice varieties, Xinxiangliangyou 1751 (XXLY1751) and Yueliangyou Meixiang Xinzhan (YLYMXXZ), were subjected to three irrigation methods (W1: wet irrigation, W2: flooding irrigation, W3: shallow-wet-dry irrigation) and four nitrogen fertilizer treatments (F1 to F4 with application rates of 0, 180, 225, and 270 kg ha−1, respectively). Our results revealed that the W1F3 treatment significantly enhanced photosynthetic efficiency and non-structural carbohydrate (NSC) accumulation, laying a robust foundation for high yield and quality. NSC accumulation not only supported rice growth but also directly influenced starch and protein synthesis, ensuring smooth grain filling and significantly improving yield and quality. Moreover, NSC strengthened stem fullness and thickness, converting them into structural carbohydrates such as cellulose and lignin, which substantially increased stem mechanical strength and lodging resistance. Statistical analysis demonstrated that water and fertilizer treatments had significant main and interactive effects on photosynthetic rate, dry matter accumulation, yield, quality parameters, NSC, cellulose, lignin, and stem bending resistance. This study reveals the intricate relationship between water and fertilizer management and NSC dynamics, providing valuable theoretical and practical insights for high-yield and high-quality cultivation of hybrid rice, significantly contributing to the sustainable development of modern agriculture. Full article
(This article belongs to the Special Issue Strategies to Improve Water-Use Efficiency in Plant Production)
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<p>(<b>a</b>,<b>b</b>) represent the tillering stages in 2022 and 2023, respectively; (<b>c</b>,<b>d</b>) represent the booting stages in 2022 and 2023, respectively; (<b>e</b>,<b>f</b>) represent the full heading stages in 2022 and 2023, respectively; (<b>g</b>,<b>h</b>) represent the grain filling stages in 2022 and 2023, respectively. Different lowercase letters on the error bars denote statistical differences (at the 0.05 level) among treatments of various varieties based on the LSD test. Significant differences within the same treatment are denoted by ns (<span class="html-italic">p</span> &gt; 0.05), * (0.01 &lt; <span class="html-italic">p</span> ≤ 0.05), and ** (<span class="html-italic">p</span> ≤ 0.01).</p>
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<p>TDW of XXLY1751 (<b>a</b>) and YLYMXXZ (<b>b</b>) in 2022, and XXLY1751 (<b>c</b>) and YLYMXXZ (<b>d</b>) in 2023.</p>
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<p>Figures (<b>a</b>,<b>b</b>) represent the yields of Xinxiangliangyou 1751 and Yueliangyou Meixiangxinzhan in 2022 and 2023, respectively. Different lowercase letters on the error bars indicate statistical differences (at a significance level of 0.05) between treatments of various cultivars in the LSD test. Significant differences within the same treatment are denoted by * (0.01 &lt; <span class="html-italic">p</span> ≤ 0.05), and ** (<span class="html-italic">p</span> ≤ 0.01).</p>
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<p>Head rice rate of XXLY1751 and YLYMXXZ in 2022 (<b>a</b>) and 2023 (<b>b</b>), and chalky grain rate of XXLY1751and YLYMXXZ in 2022 (<b>c</b>) and in 2023 (<b>d</b>). Different lowercase letters denote statistical differences between treatments of each season according to the LSD test (0.05). Significant differences within the same treatment are denoted by ns (<span class="html-italic">p</span> &gt; 0.05), * (0.01 &lt; <span class="html-italic">p</span> ≤ 0.05), and ** (<span class="html-italic">p</span> ≤ 0.01).</p>
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<p>Protein content of XXLY1751 and YLYMXXZ in 2022 (<b>a</b>) and 2023 (<b>b</b>), and amylose content of XXLY1751and YLYMXXZ in 2022 (<b>c</b>) and 2023 (<b>d</b>). Different lowercase letters denote statistical differences between treatments of each season according to the LSD test (0.05). Significant differences within the same treatment are denoted by ns (<span class="html-italic">p</span> &gt; 0.05), and ** (<span class="html-italic">p</span> ≤ 0.01).</p>
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<p>Plant height at center of gravity and panicle length of XXLY1751 (<b>a</b>) and YLYMXXZ (<b>b</b>) in 2022, and XXLY1751 (<b>c</b>) and YLYMXXZ (<b>d</b>) in 2023.</p>
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<p>(<b>a</b>,<b>b</b>) represent the full heading stages in 2022 and 2023, respectively; (<b>c</b>,<b>d</b>) represent the grain filling stages in 2022 and 2023, respectively; (<b>e</b>,<b>f</b>) represent the mature stage in 2022 and 2023, respectively. Different lowercase letters on the error bars denote statistical differences (at the 0.05 level) among treatments of various varieties based on the LSD test. Significant differences within the same treatment are denoted by ns (<span class="html-italic">p</span> &gt; 0.05), * (0.01 &lt; <span class="html-italic">p</span> ≤ 0.05), and ** (<span class="html-italic">p</span> ≤ 0.01).</p>
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<p>Lignin and cellulose of XXLY1751 (<b>a</b>) and YLYMXXZ (<b>b</b>) in 2022, and XXLY1751 (<b>c</b>) and YLYMXXZ (<b>d</b>) in 2023. Different lowercase letters denote statistical differences between treatments of each season according to an LSD test (0.05).</p>
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<p>SPS enzyme activity of XXLY1751 and YLYMXXZ in 2022 (<b>a</b>) and in 2023 (<b>b</b>), α-amylase activity of XXLY1751 and YLYMXXZ in 2022 (<b>c</b>) and in 2023 (<b>d</b>),and β-amylase activity of XXLY1751 and YLYMXXZ in 2022 (<b>e</b>) and in 2023 (<b>f</b>). Different lowercase letters denote statistical differences between treatments of each season according to an LSD test (0.05). Significant differences within the same treatment are denoted by * (0.01 &lt; <span class="html-italic">p</span> ≤ 0.05), and ** (<span class="html-italic">p</span> ≤ 0.01).</p>
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<p>Synergistic regulation of yield, quality, and lodging resistance by water and fertilizer management.</p>
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<p>Water pipes and water meters in the community.</p>
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14 pages, 2531 KiB  
Article
Analysis of the Status of Irrigation Management in North Carolina
by Anuoluwapo Omolola Adelabu, Blessing Masasi and Olabisi Tolulope Somefun
Earth 2024, 5(3), 463-476; https://doi.org/10.3390/earth5030025 - 7 Sep 2024
Viewed by 295
Abstract
Farmers in North Carolina are turning to irrigation to reduce the impacts of droughts and rainfall variability on agricultural production. Droughts, rainfall variability, and the increasing demand for food, feed, fiber, and fuel necessitate the urgent need to provide North Carolina farmers with [...] Read more.
Farmers in North Carolina are turning to irrigation to reduce the impacts of droughts and rainfall variability on agricultural production. Droughts, rainfall variability, and the increasing demand for food, feed, fiber, and fuel necessitate the urgent need to provide North Carolina farmers with tools to improve irrigation management and maximize water productivity. This is only possible by understanding the current status of irrigated agriculture in the state and investigating its potential weaknesses and opportunities. Thus, the objective of this study was to perform a comprehensive analysis of the current state of irrigation management in North Carolina based on 15-year data from the Irrigation and Water Management Survey by the United States Department of Agriculture–National Agricultural Statistics Service (USDA-NASS). The results indicated a reduction in irrigation acres in the state. Also, most farms in the state have shifted to efficient sprinkler irrigation systems from gravity-fed surface irrigation systems. However, many farms in North Carolina still rely on traditional irrigation scheduling methods, such as examining crop conditions and the feel of soil in deciding when to irrigate. Hence, there are opportunities for enhancing the adoption of advanced technologies like soil moisture sensors and weather data to optimize irrigation schedules for improving water efficiency and crop production. Precision techniques and data-based solutions empower farmers to make informed, real-time decisions, optimizing water use and resource allocation to match the changing environmental conditions. The insights from this study provide valuable information for policymakers, extension services, and farmers to make informed decisions to optimize agricultural productivity and conserve water resources. Full article
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<p>The geographical location of North Carolina in the U.S.</p>
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<p>Irrigated acres in North Carolina.</p>
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<p>Reasons for discontinuing irrigation by certain farms in North Carolina.</p>
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<p>Irrigated farms by size.</p>
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<p>Irrigated acres by irrigation method.</p>
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<p>Number of farms per irrigation scheduling method.</p>
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<p>Irrigated acres by sprinkler methods.</p>
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<p>Sources of irrigation information.</p>
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20 pages, 8004 KiB  
Article
An Efficient and Low-Cost Deep Learning-Based Method for Counting and Sizing Soybean Nodules
by Xueying Wang, Nianping Yu, Yongzhe Sun, Yixin Guo, Jinchao Pan, Jiarui Niu, Li Liu, Hongyu Chen, Junzhuo Cao, Haifeng Cao, Qingshan Chen, Dawei Xin and Rongsheng Zhu
Agronomy 2024, 14(9), 2041; https://doi.org/10.3390/agronomy14092041 - 6 Sep 2024
Viewed by 248
Abstract
Soybeans are an essential source of food, protein, and oil worldwide, and the nodules on their root systems play a critical role in nitrogen fixation and plant growth. In this study, we tackled the challenge of limited high-resolution image quantities and the constraints [...] Read more.
Soybeans are an essential source of food, protein, and oil worldwide, and the nodules on their root systems play a critical role in nitrogen fixation and plant growth. In this study, we tackled the challenge of limited high-resolution image quantities and the constraints on model learning by innovatively employing image segmentation technology for an in-depth analysis of soybean nodule phenomics. Through a meticulously designed segmentation algorithm, we broke down large-resolution images into numerous smaller ones, effectively improving the model’s learning efficiency and significantly increasing the available data volume, thus laying a solid foundation for subsequent analysis. In terms of model selection and optimization, after several rounds of comparison and testing, YOLOX was identified as the optimal model, achieving an accuracy of 91.38% on the test set with an R2 of up to 86%, fully demonstrating its efficiency and reliability in nodule counting tasks. Subsequently, we utilized YOLOV5 for instance segmentation, achieving a precision of 93.8% in quickly and accurately extracting key phenotypic indicators such as the area, circumference, length, and width of the nodules, and calculated the statistical properties of these indicators. This provided a wealth of quantitative data for the morphological study of soybean nodules. The research not only enhanced the efficiency and accuracy of obtaining nodule phenotypic data and reduced costs but also provided important scientific evidence for the selection and breeding of soybean materials, highlighting its potential application value in agricultural research and practical production. Full article
(This article belongs to the Section Precision and Digital Agriculture)
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<p>Overall Flow Chart.</p>
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<p>Model diagram. (<b>A</b>) YOLOX model diagram, 2 * CBS refers to 2 CBS modules; (<b>B</b>) YOLOv5 model diagram.</p>
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<p>Linear fitting diagram of the predicted and true values of the number of nodules in the YOLOX model.</p>
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<p>The confusion matrix of YOLOv5’s training set, validation set, and test set. (<b>A</b>) The confusion matrix of YOLOv5’s training set. (<b>B</b>) The confusion matrix of YOLOv5’s validation set. (<b>C</b>) The confusion matrix of YOLOv5’s test set.</p>
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<p>Histograms and bar charts of the mean root nodule area, mean root nodule circumference, mean root nodule length, mean root nodule width, mean length to width ratio, and mean number of root nodules in the imported population. (<b>A</b>,<b>B</b>) Histogram and bar chart of the mean number of root nodules in the imported population. (<b>C</b>,<b>D</b>) Histograms and bar charts of the mean area of root nodules in the imported population. (<b>E</b>,<b>F</b>) Histogram and bar chart of the average root nodule circumference of the imported population. (<b>G</b>,<b>H</b>) Histogram and bar chart of the mean root nodule length of the imported population. (<b>I</b>,<b>J</b>) Histograms and bar charts of the mean root nodule width of the imported population. (<b>K</b>,<b>L</b>) The mean histogram and bar chart of the length to width ratio of the imported population.</p>
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<p>Histograms and columns of variance for root nodule area variance, nodule circumference variance, nodule squareness variance, nodule width variance, and length to width ratio of the imported population. (<b>A</b>,<b>B</b>) Histogram and bar chart of the variance of the number of root nodules in the imported population. (<b>C</b>,<b>D</b>) Histogram and bar chart of the root nodule area variance of the imported population. (<b>E</b>,<b>F</b>) Histograms and bar charts of the root nodule circumference variance of the imported population. (<b>G</b>,<b>H</b>) Histogram and column chart of the root nodule rectangular difference of the imported population. (<b>I</b>,<b>J</b>) Histograms and bar charts of the root nodule width variance of the imported population. (<b>K</b>,<b>L</b>) Histograms and bar charts of the length to width ratio variance of the imported population.</p>
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<p>The detection effect of the object detection model YOLOX and the instance segmentation model YOLOv5 on root nodules. (<b>A</b>) YOLOX detects images with good results; (<b>B</b>) Typical images of YOLOX detection errors; (<b>C</b>) YOLOv5 detects images with good results; (<b>D</b>) Typical images of YOLOv5 detection error.</p>
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17 pages, 3790 KiB  
Article
Transport and Deposition of Microplastics at the Water–Sediment Interface: A Case Study of the White River near Muncie, Indiana
by Blessing Yaw Adjornor, Bangshuai Han, Elsayed M. Zahran, John Pichtel and Rebecca Wood
Hydrology 2024, 11(9), 141; https://doi.org/10.3390/hydrology11090141 - 6 Sep 2024
Viewed by 312
Abstract
Microplastics, plastic particles smaller than 5 mm, pose a significant environmental threat due to their persistence and distribution in aquatic ecosystems. Research on the dynamics of microplastics within freshwater systems, particularly concerning their transport and deposition along river corridors, remains insufficient. This study [...] Read more.
Microplastics, plastic particles smaller than 5 mm, pose a significant environmental threat due to their persistence and distribution in aquatic ecosystems. Research on the dynamics of microplastics within freshwater systems, particularly concerning their transport and deposition along river corridors, remains insufficient. This study investigated the occurrence and deposition of microplastics at the water–sediment interface of the White River near Muncie, Indiana. Sediment samples were collected from three sites: White River Woods (upstream), Westside Park (midstream), and Morrow’s Meadow (downstream). The microplastic concentrations varied significantly, with the highest concentration recorded upstream, indicating a strong influence from agricultural runoff. The types of microplastics identified were predominantly fragments (43.1%), fibers (29.6%), and films (27.3%), with fragments being consistently the most abundant at all sampling sites. A polymer analysis with selected particles using Fourier-transform infrared (FTIR) spectroscopy revealed that the most common polymers were polyethylene (PE), polypropylene (PP), and polyethylene terephthalate (PET). The hydrodynamic conditions played a crucial role in the deposition and transport of microplastics. The statistical analysis demonstrated a strong positive correlation between the microplastic concentration and flow velocity at the downstream site, suggesting that lower flow velocities contribute to the accumulation of finer sediments and microplastics. Conversely, the upstream and midstream sites exhibited weaker correlations, indicating that other environmental and anthropogenic factors, such as land use and the sediment texture, may influence microplastic retention and transport. This study provides valuable insights into the complex interactions between river dynamics, sediment characteristics, and microplastic deposition in freshwater systems. These findings contribute to the growing body of knowledge on freshwater microplastic pollution and can help guide mitigation strategies aimed at reducing microplastic contamination in riverine ecosystems. Full article
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<p>Sampling locations along the White River near Muncie. Sampling sites include the White River Woods (upstream); West Side Park, which crosses the urban sector of Muncie (midstream); and Morrow’s Meadow (downstream). The upstream zone is dominated by agricultural land.</p>
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<p>Water–sediment interface sampling in the White River. This diagram illustrates the cross-sectional setup for sediment sampling in a riverine system using a Ponar bottom grab sampler, positioned at 10-foot intervals for systematic collection. A flow meter is included to measure the water velocity.</p>
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<p>Grain size distribution curve for White River sediments. The particle size in millimeters is plotted on a logarithmic scale on the <span class="html-italic">x</span>-axis, with the percent value of particles finer than by weight on the <span class="html-italic">y</span>-axis.</p>
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<p>Normality plots of sediment grain size distribution by weight from samples collected across WRW, WSP, and MM.</p>
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<p>Microplastic types identified in White River sediment. Proportional distribution of microplastic types (<b>a</b>). Photos of microplastic fibers (<b>b</b>,<b>c</b>); fragment (<b>d</b>); and film (<b>e</b>).</p>
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<p>Correlation of microplastic concentration and flow velocity. Each point represents the microplastic concentration of the sample at a given flow velocity, with linear trend lines indicating the correlation trend for each site.</p>
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<p>Distribution of microplastic particles by river sampling location.</p>
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<p>Microplastic polymer composition. (<b>a</b>) displays the Fourier transform infrared (FTIR) spectra of different microplastic polymers identified in the sediment samples. (<b>b</b>) a pie chart that breaks down the relative proportions of various polymers found in the samples.</p>
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<p>Cross-sectional flow velocity profile of the White River. This line graph illustrates the flow velocity (<span class="html-italic">y</span>-axis) across a cross-sectional sample from the left bank (LB) to the right bank (RB) at each river sample location (<span class="html-italic">x</span>-axis). Each line represents one of the three sampling locations along the White River, with distinct markers denoting the specific site.</p>
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8 pages, 2951 KiB  
Article
Phenotypic Identification of Landraces of Phaseolus lunatus L. from the Northeastern Region of Brazil Using Morpho-Colorimetric Analysis of Seeds
by Emerson Serafim Barros, Marco Sarigu, Andrea Lallai, Josefa Patrícia Balduino Nicolau, Clarisse Pereira Benedito, Gianluigi Bacchetta and Salvador Barros Torres
Horticulturae 2024, 10(9), 948; https://doi.org/10.3390/horticulturae10090948 - 5 Sep 2024
Viewed by 420
Abstract
Phaseolus lunatus L. is a species of landrace bean widely cultivated in Northeast Brazil. The integration of new technologies in the agricultural sector has highlighted the significance of seed images analysis as a valuable asset in the characterization process. The objective was to [...] Read more.
Phaseolus lunatus L. is a species of landrace bean widely cultivated in Northeast Brazil. The integration of new technologies in the agricultural sector has highlighted the significance of seed images analysis as a valuable asset in the characterization process. The objective was to assess the morphology of 18 P. lunatus varieties gathered from four states in the Brazilian Northeast. To achieve this, 100 seeds from each variety were utilized, and their images were acquired using a flatbed scanner with a digital resolution of 400 dpi. Subsequently, the images were processed using the ImageJ software package for analyzing seed size, shape and color characteristics. Statistical analyses were performed with SPSS software applying stepwise Linear Discriminant Analysis (LDA). The overall accuracy rate for correct identification was 80.5%. Among the varieties, the lowest classification percentage was attributed to the ‘Coquinho Vermelha’ variety (39%), while the highest rates were observed for ‘Fava Roxa’ and ‘Fava de Moita’ (98%). The morpho-colorimetric classification system successfully discriminated the varieties of P. lunatus produced in the northeastern region of Brazil, highlighting the -+*/high degree of diversity within them. In particular, seeds with uniform coloring or clearly defined secondary color patterns were easier to classify. The varieties showed low correlation, forming distinct groups based on background color, secondary color, or seed size. Full article
(This article belongs to the Section Propagation and Seeds)
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<p>Varieties of <span class="html-italic">P. lunatus</span> L. collected in Northeast Brazil.</p>
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<p>(<b>A</b>) Histogram of the standardized residuals, (<b>B</b>) normal probability plot (P-P) tested with the Kolmogorov–Smirnov test (K–S), and (<b>C</b>) dispersion plot of the standardized residuals tested with Levene’s test (F).</p>
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<p>Graphical representation of the discriminant analysis of the <span class="html-italic">P. lunatus</span> L. varieties.</p>
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<p>Dendrogram of distribution of the studied <span class="html-italic">P. lanatus</span> L. varieties.</p>
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23 pages, 3817 KiB  
Article
Future Impact of Climate Change on Durum Wheat Growth and Productivity in Northern Tunisia
by Mohamed Nejib El Melki, Imen Soussi, Jameel Mohammed Al-Khayri, Othman M. Al-Dossary, Bader Alsubaie and Slaheddine Khlifi
Agronomy 2024, 14(9), 2022; https://doi.org/10.3390/agronomy14092022 - 5 Sep 2024
Viewed by 466
Abstract
This study evaluates the projected impact of climate change on wheat production in Northwest Tunisia, specifically at Medjez El Beb (36.67 m, 9.74°) and Slougia (36.66 m, 9.6°), for the period 2041–2070. Using the CNRM-CM5.1 and GFDL-ESM2M climate models under RCP4.5 and RCP8.5 [...] Read more.
This study evaluates the projected impact of climate change on wheat production in Northwest Tunisia, specifically at Medjez El Beb (36.67 m, 9.74°) and Slougia (36.66 m, 9.6°), for the period 2041–2070. Using the CNRM-CM5.1 and GFDL-ESM2M climate models under RCP4.5 and RCP8.5 scenarios, coupled with the AquaCrop and SIMPLE crop growth models, we compared model outputs with observed data from 2016 to 2020 to assess model performance. The objective was to determine how different climate models and scenarios affect wheat yields, biomass, and growth duration. Under RCP4.5, projected average yields are 7.709 q/ha with AquaCrop and 7.703 q/ha with GFDL-ESM2M. Under RCP8.5, yields are 7.765 tons/ha with AquaCrop and 7.198 q/ha with SIMPLE Crop, indicating that reduced emissions could improve wheat growth conditions. Biomass predictions showed significant variation: in Medjez El Beb, average biomass is 17.99 tons/ha with AquaCrop and 18.73 tons/ha with SIMPLE Crop under RCP8.5. In Slougia, average biomass is 18.90 tons/ha with AquaCrop and 19.04 tons/ha with SIMPLE Crop under the same scenario. Growth duration varied, with AquaCrop predicting 175 days in Medjez El Beb and 178 days in Slougia, while SIMPLE Crop predicted 180 days in Medjez El Beb and 182 days in Slougia, with a standard deviation of ±12 days for both models. SIMPLE Crop demonstrated higher accuracy in predicting growth cycle duration and yield, particularly in Slougia, with mean bias errors of −3.6 days and 2.26 q/ha. Conversely, AquaCrop excelled in biomass prediction with an agreement index of 0.97 at Slougia. Statistical analysis revealed significant yield differences based on climate models and emission scenarios, with GFDL-ESM2M under RCP4.5 showing more favorable conditions. These findings emphasize the importance of model selection and calibration for accurately projecting the agricultural impacts of climate change, and they provide insights for enhancing prediction accuracy and informing adaptation strategies for sustainable wheat production in Northwest Tunisia. Full article
(This article belongs to the Section Farming Sustainability)
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<p>Locations of study area.</p>
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<p>Conceptual flow diagram illustrating the methodology adopted to evaluate the impact of climate change on wheat production parameters in the Northwest sites of Tunisia. ** obtained from the CORDEX portal (<a href="http://www.cordex.org/data-access/esgf/" target="_blank">www.cordex.org/data-access/esgf/</a>, (accessed on 1 January 2024)).</p>
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<p>Projection pathways used to evaluate wheat production parameters. This figure shows the simulation pathways combining climate models and RCP scenarios to assess wheat production from 2041 to 2070. Corrected climate data were used in the AquaCrop and SIMPLE models to evaluate the potential impact of different climate scenarios on wheat growth.</p>
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<p>Simulation of wheat yields in Slougia under different climate scenarios and growth models, using the AquaCrop and SIMPLE crop models for the period 2041–2070.</p>
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<p>Simulation of Wheat yields in Medjez el Beb under different climate scenarios and growth models, using the AquaCrop and SIMPLE crop models for the period 2041–2070.</p>
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<p>Wheat biomass production in Sloughia under climate scenarios RCP 4.5 and RCP 8.5, projected by the CNRM-CM5.1 and GFDL-ESM2M models, and simulated using AquaCrop and SIMPLE Crop models for the period 2041–2070.</p>
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<p>Wheat biomass production at Medjez El Beb under climate scenarios RCPs 4.5 and RCP 8.5, projected by the CNRM-CM5.1 and GFDL-ESM2M models and simulated using AquaCrop and SIMPLE Crop models for the period 2041–2070.</p>
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<p>Growth period in Medjez El Beb under different RCPs scenarios according to the CNRM-CM5.1 and GFDL-ESM2M climate models, simulated by the AquaCrop and SIMPLE Crop models for the period 2041–2070.</p>
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<p>Growth period in Sloughia under different RCP scenarios according to the CNRM-CM5.1 and GFDL-ESM2M climate models, simulated by the AquaCrop and SIMPLE Crop growth models for the period 2041–2070.</p>
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<p>Comparison of Means and Standard Deviations of Crop Growth Periods Across sites, Crop Models, and Climate Scenarios (RCP4.5 and RCP8.5) for the Period 2041–2070.</p>
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<p>Comparison of historical (1970–1997) and projected (2041–2070) biomass using climate models coupled with AquaCrop and SIMPLE Crop models.</p>
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<p>Comparison of historical (1970–1997) and projected (2041–2070) growth cycle duration using climate models coupled with AquaCrop and SIMPLE crop models.</p>
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18 pages, 3584 KiB  
Article
Advanced Predictive Modeling for Dam Occupancy Using Historical and Meteorological Data
by Ahmet Cemkut Badem, Recep Yılmaz, Muhammet Raşit Cesur and Elif Cesur
Sustainability 2024, 16(17), 7696; https://doi.org/10.3390/su16177696 - 4 Sep 2024
Viewed by 438
Abstract
Dams significantly impact the environment, industries, residential areas, and agriculture. Efficient dam management can mitigate negative impacts and enhance benefits such as flood and drought reduction, energy efficiency, water access, and improved irrigation. This study tackles the critical issue of predicting dam occupancy [...] Read more.
Dams significantly impact the environment, industries, residential areas, and agriculture. Efficient dam management can mitigate negative impacts and enhance benefits such as flood and drought reduction, energy efficiency, water access, and improved irrigation. This study tackles the critical issue of predicting dam occupancy levels precisely to contribute to sustainable water management by enabling efficient water allocation among sectors, proactive drought management, controlled flood risk mitigation, and preservation of downstream ecological integrity. Our research suggests that combining physical models of water inflow and outflow “such as evapotranspiration using the Penman–Monteith equation, along with parameters like water consumption, solar radiation, and rainfall” with data-driven models based on historical reservoir data is crucial for accurately predicting occupancy levels. We implemented various prediction models, including Random Forest, Extra Trees, Long Short-Term Memory, Orthogonal Matching Pursuit CV, and Lasso Lars CV. To strengthen our proposed model with robust evidence, we conducted statistical tests on the mean absolute percentage errors of the models. Consequently, we demonstrated the impact of physical model parameters on prediction performance and identified the best method for predicting dam occupancy levels by comparing it with findings from the scientific literature. Full article
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<p>(<b>a</b>) Ömerli Dam, (<b>b</b>) Darlık Dam, (<b>c</b>) Elmalı Dam, and (<b>d</b>) Terkos Dam.</p>
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<p>(<b>a</b>) Alibey Dam, (<b>b</b>) Büyükçekmece Dam, and (<b>c</b>) Sazlıdere Dam.</p>
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<p>Dam occupancy levels for a 5-year period.</p>
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<p>Evapotranspiration levels for the 5-year period.</p>
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<p>(<b>a</b>) MAPE in dataset basis and (<b>b</b>) MAPE of AI methods.</p>
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<p>(<b>a</b>) Prediction of the Ömerli, Darlık, and Elmalı Dams’ occupancies. (<b>b</b>) Prediction of the Terkos, Alibey, Büyükçekmece, and Sazlıdere Dams’ occupancies.</p>
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22 pages, 5116 KiB  
Article
Application of Fluorescence Spectroscopy for Early Detection of Fungal Infection of Winter Wheat Grains
by Tatiana A. Matveeva, Ruslan M. Sarimov, Olga K. Persidskaya, Veronika M. Andreevskaya, Natalia A. Semenova and Sergey V. Gudkov
AgriEngineering 2024, 6(3), 3137-3158; https://doi.org/10.3390/agriengineering6030179 - 4 Sep 2024
Viewed by 306
Abstract
Plant pathogens are an important agricultural problem, and early and rapid pathogen identification is critical for crop preservation. This work focuses on using fluorescence spectroscopy to characterize and compare healthy and fungal pathogen-infected wheat grains. The excitation–emission matrices of whole wheat grains were [...] Read more.
Plant pathogens are an important agricultural problem, and early and rapid pathogen identification is critical for crop preservation. This work focuses on using fluorescence spectroscopy to characterize and compare healthy and fungal pathogen-infected wheat grains. The excitation–emission matrices of whole wheat grains were measured using a fluorescence spectrometer. The samples included healthy control samples and grains manually infected with Fusarium graminearum and Alternaria alternata fungi. The five distinct zones were identified by analyzing the location of the fluorescence peaks at each measurement. The zone centered at λem = 328/λex= 278 nm showed an increase in intensity for grains infected with both pathogens during all periods of the experiment. Another zone with the center λem = 480/λex = 400 nm is most interesting from the point of view of early diagnosis of pathogen development. A statistically significant increase of fluorescence for samples with F. graminearum is observed on day 1 after infection; for A. alternata, on day 2, and the fluorescence of both decreases to the control level on day 7. Moreover, shifts in the emission peaks from 444 nm to 452 nm were recorded as early as 2–3 h after infection. These results highlight fluorescence spectroscopy as a promising technique for the early diagnosis of fungal diseases in cereal crops. Full article
(This article belongs to the Section Sensors Technology and Precision Agriculture)
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<p>Wet control wheat and wheat infected with <span class="html-italic">F. graminearum</span> and <span class="html-italic">A. alternata</span> on different days after infection in experiment No. 2.</p>
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<p>Wet control wheat and wheat infected with <span class="html-italic">F. graminearum</span> and <span class="html-italic">A. alternata</span> on different days after infection in experiment No. 2.</p>
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<p>Cultures of <span class="html-italic">F. graminearum</span> (<b>a</b>) and <span class="html-italic">A. alternata</span> (<b>b</b>) in plastic Petri dishes (diameter 9 cm). Typical EEMs of fungal cultures <span class="html-italic">F. graminearum</span> (<b>c</b>) and <span class="html-italic">A. alternata</span> (<b>d</b>). The spectrofluorometer settings were the same for all measurements (see “<a href="#app1-agriengineering-06-00179" class="html-app">Supplementary Materials</a>”). Asterisks on EEMs denote peaks indicating emission and excitation wavelengths.</p>
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<p>EEMs depict wet wheat and wheat infected with <span class="html-italic">F. graminearum</span> and <span class="html-italic">A. alternata</span> on days 0, 1, 2, 4, and 7 following infection. EEMs are averaged over three experiments, each comprising 2–3 independent measurements. Consistency was maintained across all measurements using identical spectrofluorometric settings. Asterisks on EEMs denote peaks indicating emission and excitation wavelengths.</p>
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<p>EEMs depict dry wheat on days 0 and 7. EMMs are averaged over three experiments, each comprising 2–3 independent measurements. Consistency was maintained across all measurements using identical spectrofluorometer settings. Asterisks on EEMs denote peaks indicating emission and excitation wavelengths.</p>
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<p>Results of PCA for dry (day 0 and 7) and wet wheat and for wheat infected with <span class="html-italic">F. graminearum</span> and <span class="html-italic">A. alternata</span> at 0 (few hours, (<b>a</b>,<b>b</b>)), 1 (<b>c</b>,<b>d</b>), 2 (<b>e</b>,<b>f</b>), 4 (<b>g</b>,<b>h</b>), and 7 (<b>i</b>,<b>j</b>) days after infection. Results for PC1 and PC2 are shown on the left and for PC3 and PC4 on the right. The areas of control (blue), <span class="html-italic">F. graminearum</span> (red), and <span class="html-italic">A. alternata</span> (green) infected samples are marked with ellipses. Ellipses were constructed for the purpose of visualisation so that all points of the corresponding group were inside them.</p>
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<p>Results of PCA for dry (day 0 and 7) and wet wheat and for wheat infected with <span class="html-italic">F. graminearum</span> and <span class="html-italic">A. alternata</span> at 0 (few hours, (<b>a</b>,<b>b</b>)), 1 (<b>c</b>,<b>d</b>), 2 (<b>e</b>,<b>f</b>), 4 (<b>g</b>,<b>h</b>), and 7 (<b>i</b>,<b>j</b>) days after infection. Results for PC1 and PC2 are shown on the left and for PC3 and PC4 on the right. The areas of control (blue), <span class="html-italic">F. graminearum</span> (red), and <span class="html-italic">A. alternata</span> (green) infected samples are marked with ellipses. Ellipses were constructed for the purpose of visualisation so that all points of the corresponding group were inside them.</p>
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<p>The loading matrices for different excitation and emission wavelengths for different components, PC1 (<b>a</b>), PC2 (<b>b</b>), PC3 (<b>c</b>), and PC4 (<b>d</b>). Asterisks on EEMs denote peaks indicating emission and excitation wavelengths.</p>
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<p>The peaks of each measurement of EEMs depict wet wheat and wheat infected with <span class="html-italic">F. graminearum</span> and <span class="html-italic">A. alternata</span> for all days (<b>a</b>), on day 0 (<b>b</b>), day 1 (<b>c</b>), day 2 (<b>d</b>), day 4 (<b>e</b>), and day 7 (<b>f</b>) following infection. Consistency was maintained across all measurements with identical spectrofluorometer settings.</p>
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<p>The fluorescence intensities of the peaks on different days after infection with phytopathogen for dry wheat grains, wet wheat grains (control), and wheat grains infected by <span class="html-italic">A. alternata</span> and <span class="html-italic">F. graminearum</span>. The peaks are located in λ<sub>em</sub> = 328/λ<sub>ex</sub> = 278 nm (<b>a</b>), λ<sub>em</sub> = 454/λ<sub>ex</sub> = 364 nm (<b>b</b>), λ<sub>em</sub> = 486/λ<sub>ex</sub> = 400 nm (<b>c</b>), λ<sub>em</sub> = 535/λ<sub>ex</sub> = 420 nm (<b>d</b>), and λ<sub>em</sub> = 553/λ<sub>ex</sub> = 486 nm (<b>e</b>). Intensities of the peaks are averages of 5–9 independent measurements in 3 experiments. Standard errors of mean are set as an error. The spectrofluorometer settings were the same for all measurements. * (above column)—the difference between this group and wet grain in same day at this time (<span class="html-italic">p</span> &lt; 0.05, Two-way ANOVA with Tukey’s Test). * (inside column)—the difference between this group and the group in the same category on day 0 (<span class="html-italic">p</span> &lt; 0.05, Two-way ANOVA with Tukey’s Test).</p>
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<p>The fluorescence intensities of the peaks on different days after infection with phytopathogen for dry wheat grains, wet wheat grains (control), and wheat grains infected by <span class="html-italic">A. alternata</span> and <span class="html-italic">F. graminearum</span>. The peaks are located in λ<sub>em</sub> = 328/λ<sub>ex</sub> = 278 nm (<b>a</b>), λ<sub>em</sub> = 454/λ<sub>ex</sub> = 364 nm (<b>b</b>), λ<sub>em</sub> = 486/λ<sub>ex</sub> = 400 nm (<b>c</b>), λ<sub>em</sub> = 535/λ<sub>ex</sub> = 420 nm (<b>d</b>), and λ<sub>em</sub> = 553/λ<sub>ex</sub> = 486 nm (<b>e</b>). Intensities of the peaks are averages of 5–9 independent measurements in 3 experiments. Standard errors of mean are set as an error. The spectrofluorometer settings were the same for all measurements. * (above column)—the difference between this group and wet grain in same day at this time (<span class="html-italic">p</span> &lt; 0.05, Two-way ANOVA with Tukey’s Test). * (inside column)—the difference between this group and the group in the same category on day 0 (<span class="html-italic">p</span> &lt; 0.05, Two-way ANOVA with Tukey’s Test).</p>
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21 pages, 10998 KiB  
Article
Developing Sustainable Groundwater for Agriculture: Approach for a Numerical Groundwater Flow Model in Data-Scarce Sia Kouanza, Niger
by Alexandra Lutz, Yahaya Nazoumou, Adamou Hassane, Diafarou Moumouni Ali, Abdou Guero, Susan Rybarski and David Kreamer
Water 2024, 16(17), 2511; https://doi.org/10.3390/w16172511 - 4 Sep 2024
Viewed by 354
Abstract
The area of Sia Kouanza in the Sahel of southwestern Niger is a potential location for expanding agriculture through irrigation with groundwater. Agriculture is key to supporting smallholders and promoting food security. As plans proceed, questions include how much water is available, how [...] Read more.
The area of Sia Kouanza in the Sahel of southwestern Niger is a potential location for expanding agriculture through irrigation with groundwater. Agriculture is key to supporting smallholders and promoting food security. As plans proceed, questions include how much water is available, how is groundwater replenished, many hectares to develop, and where to locate the wells. While these questions can be addressed with a model, it is difficult to find detailed procedures, especially when data are scarce. How can we use existing information to develop a model of a natural system where groundwater development will take place? We describe an approach that can be employed in data-scarce areas where similar questions are being asked. The approach includes setting details; conceptual model development; water balance; numerical code MODFLOW; model construction, calibration, and statistics; and result interpretation. Conceptual model component estimates are derived from field data: recharge, evapotranspiration, wetlands discharge, existing extraction, and river stages. When field data are not available or scarce, we employ other sources and describe how they are validated with field data or analog sites. The calibrated steady-state model gives a water balance of 22 × 106 m3/yr with inflows (recharge 22 × 106 m3/yr) and outflows (extraction 7.2 × 105 m3/yr, wetlands 5.7 × 106 m3/yr, evapotranspiration 11.9 × 106 m3/yr). The model is a point of departure; approaches for transient and predictive models, which can be used to simulate changes in irrigation pumping volumes and drought, for example, will be described subsequently. Full article
(This article belongs to the Section Hydrogeology)
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<p>Maps showing: (<b>a</b>) the location of Sia Kouanza in the Sahel of southwestern Niger, West Africa; and (<b>b</b>) the outline of the model domain is in black, and the area of primary interest for development—the terrasse—is outlined in pink.</p>
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<p>Diagram of the approach employed for the Sia Kouanza model, describing the setting, conceptual model, numerical model, calibration, and steady-state model.</p>
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<p>Maps showing: (<b>a</b>) the location of the Sia Kounza modeling domain in black, the terrasse area of primary interest outlined in pink, and hydrogeologic setting of the domain in yellow and green; and (<b>b</b>) delineation of kori watersheds outlined in black and denoted as BV1 through BV8, ephemeral surface water runoff as blue lines, and chloride mass balance (CMB) sample sites shown as triangles.</p>
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<p>Average monthly Niger River flow (between 1952 and 2021) and precipitation (between 1981 and 2021) in the Sia Kouanza area. Seasonal variability is observed for both precipitation and river flow.</p>
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<p>One-to-one plot of monthly CHIRPS precipitation and measured monthly precipitation between 2015 and 2021.</p>
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<p>Sketch of the chloride mass balance (CMB) approach. Chloride originates from precipitation (P) and is transported to groundwater by water infiltrating the subsurface (blue arrows) as recharge (R).</p>
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<p>Identification of vegetation from satellite imagery. (<b>a</b>) Smaller shrubs were identified from the higher resolution Lidar flight imagery collected over the terrasse area for use in this study, within a 250 m × 250 m square. (<b>b</b>) Trees were identified from Landsat imagery within a 1 km × 1 km square.</p>
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<p>Maps showing: (<b>a</b>) the delineation of riparian areas (green) along the southwest boundary, which is also the river and locations of wetlands (blue) in and near the terrasse (pink) believed to be fed by groundwater; and (<b>b</b>) locations and populations of existing communities shown in the terrasse (outlined in pink) and larger modeling domain (outlined in black).</p>
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<p>Maps showing: (<b>a</b>) location of aquifer pump test locations in and adjacent to the terrasse (pink) that were used for pilot points of hydraulic conductivity (K); and (<b>b</b>) Distribution of K values based on pilot points of the aquifer pump test locations for alluvium in Layer 1 of the groundwater flow model.</p>
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<p>Maps showing: (<b>a</b>) residual head, or observed groundwater level subtracted from the simulated groundwater level, in the steady-state model where larger circles show larger differences and smaller circles show smaller differences; and (<b>b</b>) contours of simulated head (groundwater level) shown as meters above sea level (masl) and generally following the topography.</p>
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<p>One-to-one plot of circles that represent observed heads and the corresponding simulated heads in the steady-state model. No extreme departures or biases (generally high or low) are observed.</p>
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12 pages, 1835 KiB  
Article
Low Concentrations of Biochar Improve Germination and Seedling Development in the Threatened Arable Weed Centaurea cyanus
by Riccardo Fedeli, Tiberio Fiaschi, Leopoldo de Simone, Claudia Angiolini, Simona Maccherini, Stefano Loppi and Emanuele Fanfarillo
Environments 2024, 11(9), 189; https://doi.org/10.3390/environments11090189 - 4 Sep 2024
Viewed by 491
Abstract
In the context of sustainable agriculture, the search for soil improvers that boost crop growth without harming biodiversity is gaining much attention. Biochar, the solid residue resulting from the pyrolysis of organic material, has recently emerged as a promising bioproduct in enhancing crop [...] Read more.
In the context of sustainable agriculture, the search for soil improvers that boost crop growth without harming biodiversity is gaining much attention. Biochar, the solid residue resulting from the pyrolysis of organic material, has recently emerged as a promising bioproduct in enhancing crop yield, but there is a lack of information regarding its effects on arable biodiversity. Thus, in this study, we tested the effect of biochar application on the germination and seedling growth of cornflower (Centaurea cyanus L., Asteraceae), a threatened arable weed, under laboratory conditions. We investigated various parameters, including germination percentage (GP%), mean germination time (MGT), germination rate index (GRI), germination energy (GE%), fresh and dry weight (mg) of seedlings, and radicle length (mm) under biochar treatments at different concentrations: 0% (control), 0.1%, 0.2%, 0.5%, 1%, and 2%. Our findings revealed a significant increase in GP, GE, and GRI at biochar concentrations of 0.5% and 1%. MGT slightly increased at 0.1% biochar. Seedling fresh weight was unaffected by biochar application, whereas seedling dry weight exhibited a significant increase at 0.5% biochar. Radicle length showed a substantial increase under 0.1% biochar on day one, and was significantly higher at 0.2% and 1% biochar on day two. However, by day three, no more statistically significant differences in radicle length were observed between biochar-treated diaspores and controls (i.e., biochar had positive effects only in the first stages). These results suggest that the application of biochar at intermediate concentrations (0.5% and 1%) overall provides the most benefit to the germination and seedling growth of C. cyanus. Full article
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<p>Experimental design (created with BioRender).</p>
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<p>Germination percentage for each day (GP) of <span class="html-italic">C. cyanus</span> seeds. B = biochar. Different letters indicate statistically significant differences (<span class="html-italic">p</span> &lt; 0.05) between the different biochar concentrations.</p>
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<p>(<b>A</b>) Mean germination time (MGT), (<b>B</b>) germination rate index (GRI), (<b>C</b>) germination energy (GE) of <span class="html-italic">C. cyanus</span> seeds. Different letters indicate statistically significant differences (<span class="html-italic">p</span> &lt; 0.05) between the different biochar concentrations.</p>
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<p>(<b>A</b>) Fresh weight (FW), (<b>B</b>) dry weight (DW) of <span class="html-italic">C. cyanus</span> seeds. Different letters indicate statistically significant differences (<span class="html-italic">p</span> &lt; 0.05) between the different biochar concentrations.</p>
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<p>Radicle length of <span class="html-italic">C. cyanus</span> seeds. B = biochar. Different letters indicate statistically significant differences (<span class="html-italic">p</span> &lt; 0.05) between the different biochar concentrations.</p>
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19 pages, 2242 KiB  
Article
Presence of Heavy Metals in Irrigation Water, Soils, Fruits, and Vegetables: Health Risk Assessment in Peri-Urban Boumerdes City, Algeria
by Mohamed Younes Aksouh, Naima Boudieb, Nadjib Benosmane, Yacine Moussaoui, Rajmund Michalski, Justyna Klyta and Joanna Kończyk
Molecules 2024, 29(17), 4187; https://doi.org/10.3390/molecules29174187 - 4 Sep 2024
Viewed by 431
Abstract
This study investigates heavy metal contamination in soils, irrigation water, and agricultural produce (fruits: Vitis vinifera (grape), Cucumis melo var. saccharimus (melon), and Citrullus vulgaris. Schrade (watermelon); vegetables: Lycopersicum esculentum L. (tomato), Cucurbita pepo (zucchini), Daucus carota (carrot), Lactuca sativa (lettuce), Convolvulus Batatas (potato), [...] Read more.
This study investigates heavy metal contamination in soils, irrigation water, and agricultural produce (fruits: Vitis vinifera (grape), Cucumis melo var. saccharimus (melon), and Citrullus vulgaris. Schrade (watermelon); vegetables: Lycopersicum esculentum L. (tomato), Cucurbita pepo (zucchini), Daucus carota (carrot), Lactuca sativa (lettuce), Convolvulus Batatas (potato), and Capsicum annuum L. (green pepper)) in the Boumerdes region of Algeria. The concentrations of seven heavy metals (cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), nickel (Ni), lead (Pb), and zinc (Zn)) in soil and food samples were analyzed using atomic absorption spectrometry. Health risks associated with these metals were evaluated through the estimated daily intake (EDI), non-carcinogenic risks (using target hazard quotient (THQ), total target hazard quotient (TTHQ), and hazard index (HI)), and carcinogenic risks (cancer risk factor (CR)). Statistical analyses, including cluster analysis (CA) and Pearson correlation, were conducted to interpret the data. The results revealed the highest metal transfer as follows: Cd was most significantly transferred to tomatoes and watermelons; Cr to carrots; Cu to tomatoes; and Fe, Ni, Pb, and Zn to lettuce. Among fruits, the highest EDI values were for Zn (2.54·10−3 mg/day) and Cu (1.17·10−3 mg/day), with melons showing the highest Zn levels. For vegetables, the highest EDI values were for Fe (1.68·10−2 mg/day) and Zn (8.37·10−3 mg/day), with potatoes showing the highest Fe levels. Although all heavy metal concentrations were within the World Health Organization’s permissible limits, the HI and TTHQ values indicated potential health risks, particularly from vegetable consumption. These findings suggest the need for ongoing monitoring to ensure food safety and mitigate health risks associated with heavy metal contamination. Full article
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Graphical abstract

Graphical abstract
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<p>Comparison of the metal content in the waters of different regions of Algeria [<a href="#B26-molecules-29-04187" class="html-bibr">26</a>,<a href="#B27-molecules-29-04187" class="html-bibr">27</a>,<a href="#B28-molecules-29-04187" class="html-bibr">28</a>,<a href="#B29-molecules-29-04187" class="html-bibr">29</a>,<a href="#B30-molecules-29-04187" class="html-bibr">30</a>,<a href="#B31-molecules-29-04187" class="html-bibr">31</a>,<a href="#B32-molecules-29-04187" class="html-bibr">32</a>].</p>
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<p>Dendrogram resulting from the hierarchical cluster analysis of the heavy metal concentrations in the studied soils.</p>
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<p>Comparison of the metal content in soils of different regions of Algeria [<a href="#B23-molecules-29-04187" class="html-bibr">23</a>,<a href="#B33-molecules-29-04187" class="html-bibr">33</a>,<a href="#B38-molecules-29-04187" class="html-bibr">38</a>,<a href="#B39-molecules-29-04187" class="html-bibr">39</a>,<a href="#B40-molecules-29-04187" class="html-bibr">40</a>,<a href="#B41-molecules-29-04187" class="html-bibr">41</a>,<a href="#B42-molecules-29-04187" class="html-bibr">42</a>,<a href="#B43-molecules-29-04187" class="html-bibr">43</a>].</p>
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<p>Dendrogram resulting from the hierarchical cluster analysis of the heavy metal concentration in the studied food.</p>
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<p>Transfer factors of the fruits and vegetables grown in the studied region of Boumerdes.</p>
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<p>Target hazard quotient (THQ) (<b>A</b>) and total target hazard quotient (TTHQ) (<b>B</b>) for consumers of the food from the studied area.</p>
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<p>Study area with sampling sites and location of industrial activities (a—Ezmam/Solgen Paper Factory; b—Imotep Pharm; c—EURL Lepro Chemical Plant Pack; d—GC BFE; e—SNC Hassani; f—Socotid).</p>
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24 pages, 10548 KiB  
Article
A Statistical Analysis of Drought and Fire Weather Indicators in the Context of Climate Change: The Case of the Attica Region, Greece
by Nadia Politi, Diamando Vlachogiannis and Athanasios Sfetsos
Climate 2024, 12(9), 135; https://doi.org/10.3390/cli12090135 - 3 Sep 2024
Viewed by 366
Abstract
As warmer and drier conditions associated with global warming are projected to increase in southern Europe, the Mediterranean countries are currently the most prone to wildfire danger. In the present study, we investigated the statistical relationship between drought and fire weather risks in [...] Read more.
As warmer and drier conditions associated with global warming are projected to increase in southern Europe, the Mediterranean countries are currently the most prone to wildfire danger. In the present study, we investigated the statistical relationship between drought and fire weather risks in the context of climate change using drought index and fire weather-related indicators. We focused on the vulnerable and long-suffering area of the Attica region using high-resolution gridded climate datasets. Concerning fire weather components and fire hazard days, the majority of Attica consistently produced values that were moderately to highly anti-correlated (−0.5 to −0.9). This suggests that drier circumstances raise the risk of fires. Additionally, it was shown that the spatial dependence of each variable on the 6-months scale Standardized Precipitation Evapotranspiration Index (SPEI6), varied based on the period and climate scenario. Under both scenarios, an increasing rate of change between the drought index and fire indicators was calculated over future periods versus the historical period. In the case of mean and 95th percentiles of FWI with SPEI6, abrupt changes in linear regression slope values were observed, shifting from lower in the past to higher values in the future periods. Finally, the fire indicators’ future projections demonstrated a tendency towards an increasing fire weather risk for the region’s non-urban (forested and agricultural) areas. This increase was evident from the probability distributions shifting to higher mean and even more extreme values in future periods and scenarios. The study demonstrated the region’s growing vulnerability to future fire incidents in the context of climate change. Full article
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<p>Attica topographic map.</p>
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<p>Non-urban areas (yellow color) and urban areas (red) of the Attica region according to CORINE 2020.</p>
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<p>Correlation of SPEI6_oct and mean FWI for the Attica region for (<b>a</b>) the historical and future periods: (<b>b</b>) near future under RCP4.5, (<b>c</b>) near future under RCP8.5, (<b>d</b>) far future under RCP4.5, and (<b>e</b>) far future under RCP8.5. The black dotted areas show a statistically significant correlation at the 5% significance level.</p>
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<p>Correlation of SPEI6_oct and FWI95 for the Attica region for (<b>a</b>) the historical and future periods: (<b>b</b>) near future under RCP4.5, (<b>c</b>) near future under RCP8.5, (<b>d</b>) far future under RCP4.5, and (<b>e</b>) far future under RCP8.5. The black dotted areas show a statistically significant correlation at the 5% significance level.</p>
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<p>Correlation of SPEI6_oct and high fire danger days index for the Attica region for (<b>a</b>) the historical and future periods: (<b>b</b>) near future under RCP4.5, (<b>c</b>) near future under RCP8.5, (<b>d</b>) far future under RCP4.5, and (<b>e</b>) far future under RCP8.5. The black dotted areas show statistically significant correlation at the 5% significance level.</p>
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<p>Correlation of SPEI6_oct and extreme fire danger days index for the Attica region for (<b>a</b>) the historical and future periods: (<b>b</b>) near future under RCP4.5, (<b>c</b>) near future under RCP8.5, (<b>d</b>) far future under RCP4.5, and (<b>e</b>) far future under RCP8.5. The black dotted areas show a statistically significant correlation at the 5% significance level.</p>
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<p>Correlation of SPEI6_oct and mean FFMC for the Attica region for (<b>a</b>) the historical and future periods: (<b>b</b>) near future under RCP4.5, (<b>c</b>) near future under RCP8.5, (<b>d</b>) far future under RCP4.5, and (<b>e</b>) far future under RCP8.5. The black dotted areas show a statistically significant correlation at the 5% significance level.</p>
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<p>Correlation of SPEI6_oct and mean ISI for the Attica region for (<b>a</b>) the historical and future periods: (<b>b</b>) near future under RCP4.5, (<b>c</b>) near future under RCP8.5, (<b>d</b>) far future under RCP4.5, and (<b>e</b>) far future under RCP8.5. The black dotted areas show a statistically significant correlation at the 5% significance level.</p>
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<p>Spatial trend results of the SPEI6–FWI95 relationship for the historical and future periods under RCP4.5 and RCP8.5 for the Attica region.</p>
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<p>Spatial trend results of the relationship between SPEI6 and FWI &gt; 38 for the historical and future periods under RCP4.5 and RCP8.5 for the Attica region.</p>
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<p>Spatial trend results of the relationship between SPEI6 and FWI &gt; 38 for the historical and future periods under RCP4.5 and RCP8.5 for the Attica region.</p>
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<p>Spatial trend results of the relationship between SPEI6 and mean ISI for the historical and future periods under RCP4.5 and RCP8.5 for the Attica region.</p>
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<p>Spatial trend results of the relationship between SPEI6 and mean ISI for the historical and future periods under RCP4.5 and RCP8.5 for the Attica region.</p>
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<p>Spatial trend results of the relationship between SPEI6 and mean FFMC for the historical and future periods under RCP4.5 and RCP8.5 for the Attica region.</p>
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<p>Spatial trend results of the relationship between SPEI6 and mean FFMC for the historical and future periods under RCP4.5 and RCP8.5 for the Attica region.</p>
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<p>Probability density distributions of the examined fire indicators for the historical and future periods under RCP4.5 and RCP8.5 considering only the forest and agricultural areas in the Attica region: (<b>a</b>) FWI95, (<b>b</b>) mean FWI, (<b>c</b>) extreme fire days, (<b>d</b>) high fire days, (<b>e</b>) mean ISI, and (<b>f</b>) mean FFMC.</p>
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17 pages, 17982 KiB  
Article
Comprehending Spatial Distribution and Controlling Mechanisms of Groundwater in Topical Coastal Aquifers of Southern China Based on Hydrochemical Evaluations
by Jun He, Pan Wu, Yiyong Li, Min Zeng, Chen Chen, Hamza Jakada and Xinwen Zhao
Water 2024, 16(17), 2502; https://doi.org/10.3390/w16172502 - 3 Sep 2024
Viewed by 357
Abstract
Groundwater quality and availability in coastal aquifers have become a serious concern in recent times due to increased abstraction for domestic, agricultural and industrial purposes. (1) Background: Zhuhai city is selected as a representative coastal aquifer in Southern China to comprehensively evaluate the [...] Read more.
Groundwater quality and availability in coastal aquifers have become a serious concern in recent times due to increased abstraction for domestic, agricultural and industrial purposes. (1) Background: Zhuhai city is selected as a representative coastal aquifer in Southern China to comprehensively evaluate the hydrochemical characteristics, spatial distribution and controlling mechanisms of groundwater. (2) Methods: A detailed study utilizing statistical analyses, a Piper diagram, Gibbs plots, and ion ratios was conducted on 114 surface water samples and 211 groundwater samples. (3) Results: The findings indicate that the pH of most groundwater is from 6.06 to 6.52, indicating a weakly acidic environment. The pH of surface water ranges from 5.35 to 9.86, with most values being weakly alkaline. The acidity in the groundwater may be related to the acidic atmospheric precipitation, an acidic unsaturated zone, oxidation of sulphide minerals and tidal action. The groundwater chemical types are predominantly mixed, followed by Ca-Mg-HCO3 type. Surface water samples are predominantly Na-Cl-SO4 type. The NO3 concentration in groundwater is relatively high, with a mean value of 17.46 mg/L. The NO2 and NH4+ concentrations in groundwater are relatively low, with mean values of 0.46 mg/L and 7.58 mg/L. (4) Conclusions: The spatial distribution of the principal chemical constituents in the groundwater is related to the landform. The chemical characteristics of groundwater in the study area are mainly controlled by the weathering and dissolution of silicate and sulfate minerals, evaporation, seawater mixing and cation exchange. Nitrate in clastic fissure groundwater, granite fissure groundwater and unconfined pore groundwater primarily originates from atmospheric precipitation, agricultural activities of slope farmland and forest land. Nitrate in confined pore groundwater and karst groundwater primarily originates from domestic sewage and mariculture wastewater. Our findings elucidate the processes characterizing the hydrogeology and surface water interactions in Zhuhai City’s coastal system, which are relevant to other catchments with similar geological characteristics. Full article
(This article belongs to the Special Issue Soil and Groundwater Quality and Resources Assessment)
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<p>Simple hydrogeological map of study area and location of samples.</p>
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<p>Section map of study area (location of the section is in <a href="#water-16-02502-f001" class="html-fig">Figure 1</a>).</p>
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<p>Piper diagram of water samples.</p>
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<p>Relationship between acidic groundwater and landform.</p>
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<p>Box diagram of main chemical composition of groundwater.</p>
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<p>Gibbs diagram of water samples.</p>
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<p>Relationship between Na<sup>+</sup> and Cl<sup>−</sup> of water samples.</p>
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<p>Relationship between HCO<sub>3</sub><sup>−</sup>/Na<sup>+</sup>, Mg<sup>2+</sup>/Na<sup>+</sup> and Ca<sup>2+</sup>/Na<sup>+</sup> of water samples.</p>
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<p>Relationships between (Ca<sup>2+</sup> + Mg<sup>2+</sup>) and (HCO<sub>3</sub><sup>−</sup>+ SO<sub>4</sub><sup>2−</sup>) of water samples.</p>
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<p>Relationships between (Na<sup>+</sup> − Cl<sup>−</sup>) and (Ca<sup>2+</sup> + Mg<sup>2+</sup>) − (HCO<sub>3</sub><sup>−</sup> + SO<sub>4</sub><sup>2−</sup>) of water samples.</p>
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<p>Chlor-alkali index of water samples.</p>
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<p>Relationship between NO<sub>3</sub><sup>−</sup>/Na<sup>+</sup>, Cl<sup>−</sup>/Na<sup>+</sup> and SO<sub>4</sub><sup>2−</sup>/Na<sup>+</sup> of groundwater. (<b>a</b>) NO<sub>3</sub><sup>−</sup>/Na<sup>+</sup> and Cl<sup>−</sup>/Na<sup>+</sup>; (<b>b</b>) Cl<sup>−</sup>/Na<sup>+</sup> and SO<sub>4</sub><sup>2−</sup>/Na<sup>+</sup>.</p>
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<p>Relationship between I<sup>−</sup>/Na<sup>+</sup> and Br<sup>−</sup> of groundwater.</p>
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