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Search Results (4,370)

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13 pages, 1444 KiB  
Article
Chemical Composition, Antioxidant, Antibacterial, and Hemolytic Properties of Ylang-Ylang (Cananga odorata) Essential Oil: Potential Therapeutic Applications in Dermatology
by Soukaina Alaoui Mrani, Hind Zejli, Dounia Azzouni, Driss Fadili, Mohammed M. Alanazi, Said Omar Said Hassane, Rachid Sabbahi, Atul Kabra, Abdelfattah El Moussaoui, Belkheir Hammouti and Mustapha Taleb
Pharmaceuticals 2024, 17(10), 1376; https://doi.org/10.3390/ph17101376 (registering DOI) - 16 Oct 2024
Abstract
Background/Objectives: This study investigates the chemical composition, antioxidant, antibacterial, and hemolytic properties of ylang-ylang (Cananga odorata) essential oil, with a focus on its potential therapeutic applications for dermatological diseases and the importance of transforming such bioactive properties into a stable, safe, [...] Read more.
Background/Objectives: This study investigates the chemical composition, antioxidant, antibacterial, and hemolytic properties of ylang-ylang (Cananga odorata) essential oil, with a focus on its potential therapeutic applications for dermatological diseases and the importance of transforming such bioactive properties into a stable, safe, and effective formulation. Methods/Rsults: Essential oils were extracted from flowers harvested in northern Grande Comore using hydro distillation at three different distillation times to examine the impact on yield and quality. Gas chromatographic analysis identified a complex mixture of compounds, including linalool, geranyl acetate, and benzyl benzoate. Antioxidant activity was assessed using DPPH, FRAP, TAC, and beta-carotene bleaching inhibition assays, revealing significant radical scavenging capabilities, with DPPH IC50 varying between 1.57 and 3.5 mg/mL. Antibacterial activity was tested against Escherichia coli, Staphylococcus aureus, Bacillus subtilis, and Pseudomonas aeruginosa, showing promising inhibition zones and minimum inhibitory concentrations. Hemolytic tests indicated varying degrees of red blood cell damage, emphasizing the need for careful concentration management in therapeutic applications. Molecular docking studies highlighted potential therapeutic targets for dermatological conditions, identifying high binding affinities for specific compounds against proteins involved in acne, eczema, and psoriasis. Conclusions: This comprehensive analysis underscores the potential of ylang-ylang essential oil (YEOs) as a natural alternative for antimicrobial treatments and dermatological applications, with its success dependent on optimized extraction methods and precise formulation to reduce cytotoxic effects. A formulation approach is crucial to ensure controlled release, improve bioavailability, and minimize skin irritation. Full article
(This article belongs to the Section Natural Products)
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<p>Total antioxidant capacity of <span class="html-italic">YEOs.</span></p>
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<p>Absorbance changes over time during incubation (37 °C) of erythrocyte suspensions with varying concentrations of <span class="html-italic">YEOs</span>, PBS + susp: red blood cell suspension from rat blood was incubated in a phosphate-buffered saline (PBS) solution at pH 7.4.</p>
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<p>Molecular structures of target molecules.</p>
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<p>The interaction pharmacology network for the treatment of the selected dermatological diseases.</p>
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14 pages, 279 KiB  
Article
Morocco’s Distinctive Islam at a Crossroads: The State’s Support for Sufism
by Mouad Faitour
Religions 2024, 15(10), 1257; https://doi.org/10.3390/rel15101257 (registering DOI) - 16 Oct 2024
Viewed by 106
Abstract
In the aftermath of the 2003 Casablanca bombings, the Moroccan state emphasized, through official public discourse, the components that constitute “official Moroccan Islam” to combat extremist ideologies. These religious elements include Mālikism in jurisprudence, Ashʿarism in theology, and the Sufism of Imam Al-Junayd [...] Read more.
In the aftermath of the 2003 Casablanca bombings, the Moroccan state emphasized, through official public discourse, the components that constitute “official Moroccan Islam” to combat extremist ideologies. These religious elements include Mālikism in jurisprudence, Ashʿarism in theology, and the Sufism of Imam Al-Junayd (d. 298/910), all balanced by the pledge of allegiance to King Mohammed VI (a descendant of the Sharifian lineage), the constitutionally designated Commander of the Faithful and sole religious leader. Since the reform policy initiated in 2004, the Moroccan state has constructed a narrative on the distinctiveness of Moroccan Islam—moderate and tolerant—and promoted it among its own citizens and beyond its borders. However, while the Moroccan state claims to have a unique form of Islam, controversial arguments have been raised questioning the nature of the state’s purported Islam. Other criticisms include investigating the state’s endorsement of Sufism and its broader policy of institutionalization. Yet, this article argues that the state supports any form of Islam, not necessarily Sufism, that aligns with its religious and political leadership. Like other Arab and Muslim states, Morocco’s religious policy is impacted by the global context, where Salafism is now perceived as a threat to established worldviews. In addition, this article argues that Morocco’s support for Sufi Islam is based not merely on its perceived political passivity, but because it complements the state’s policies and gains advantages from this support. It concludes that the official narrative of Moroccan Islam, which emphasizes a Sufi-oriented approach to counter extremism, is open to question, particularly given that Salafism was the state’s preferred form of Islam in post-colonial Morocco. This highlights the complex and often conflicting relationship between political actors and religious leaders in shaping Morocco’s religious discourse. Full article
16 pages, 7236 KiB  
Article
Reconstructing the Relative Ice-Flow Chronology South of Lake Mistassini in Canada from New Ice-Flow Indicator Mapping
by Mohamed El Amrani, Khadija Diani, Mohamed Hafedh Hamza, Mohamed Elhag, Said Courba, Afaf Amine, Moulay Ahmed Ben Driss, Lahcen Ousaid, Nabil Mdiker, Youssef Hahou and Larbi Boudad
Limnol. Rev. 2024, 24(4), 450-465; https://doi.org/10.3390/limnolrev24040026 (registering DOI) - 16 Oct 2024
Viewed by 146
Abstract
Understanding paleo-ice flow chronology is essential for reconstructing past ice mass dynamics, interpreting the current landscape, and identifying the sources of Quaternary sediments in deglaciated regions. A recent systematic mapping of striated bedrock and streamlined landforms south of Lake Mistassini in Canada reveals [...] Read more.
Understanding paleo-ice flow chronology is essential for reconstructing past ice mass dynamics, interpreting the current landscape, and identifying the sources of Quaternary sediments in deglaciated regions. A recent systematic mapping of striated bedrock and streamlined landforms south of Lake Mistassini in Canada reveals a complex sequence of five ice flows. The earliest flow was directed to the southeast (SE) and originated from a NE-SW ice divide located northwest of Lake Mistassini at the Last Glacial Maximum. A progressive clockwise rotation of this ice divide, likely triggered during the early deglaciation, appears to have generated ice flows toward the south–southeast (SSE) and then toward the south (S). During the later stages of deglaciation, the flow originated from the Québec–Labrador Dome, initially toward the south–southwest (SSW) and then toward the southwest (SW). This study presents new data on ice flows south of Lake Mistassini and shows that the southward and south–southeastward ice events occurred before the late stage of deglaciation. This interpretation contradicts some previous studies and will contribute to the discussion on the dynamics of the Laurentide Ice Sheet in the Mistassini area and support mineral exploration efforts in the region. Full article
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<p>Location map of the study area. Grenville Front from the geological map of Québec [<a href="#B19-limnolrev-24-00026" class="html-bibr">19</a>]. Hydrography data (1:20,000) from the Topographic Database of the Government of Québec available at: <a href="https://www.donneesquebec.ca/" target="_blank">https://www.donneesquebec.ca/</a>, accessed on 13 September 2022.</p>
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<p>Flowchart of the research process.</p>
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<p>Examples of small- to medium-scale ice movement indicators. (<b>A</b>) Illustration of a rat-tail ridge exhibiting a tapering tail in the lee side of a resistant rock fragment, indicating a south–southeastward ice flow. A hard rock fragment acts as a barrier, shielding softer rock in its lee from glacial erosion and resulting in the formation of a downstream ridge. (<b>B</b>) A whaleback form with a polished upstream side and a rough, plucked downstream side. (<b>C</b>) Crescentic gouges resulting from an ice mass moving toward the south–southwest. The steep side of each gouge faces upstream. (<b>D</b>) A stria with a relatively wider depression at its upstream end, marking the original position of the rock fragment that created the stria beneath a moving glacier. (<b>E</b>) Fine striae from an older SE-ice flow overprinted by coarse striae from a younger S-ice flow. (<b>F</b>) Preserved striae from an older ice flow (SE) on a lee side rock surface, sheltered from a younger ice flow (S).</p>
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<p>Sequence of ice flows derived from the mapping of striations and streamlined landforms during this study. Hydrography data from the Topographic Database of the Government of Québec.</p>
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<p>Examples of ice-flow indicators mapped in the study area. (<b>A</b>) Striations from the oldest ice flow toward 130° (lee side surface) crossed by those of the southward ice flow (185°). (<b>B</b>) Whaleback feature indicating ice flow to the south–southeast (170°). (<b>C</b>) Groove indicating south–southwestward ice flow. (<b>D</b>) Striated outcrop showing groove (G) and crescentic gouges (C) of the southward ice flow (185°). (<b>E</b>) Image from Google Earth showing many streamlined landforms (drumlinoids) associated with the southward ice flow north of Lake Clérac (central part of the study area). Image © 2023 CNES/Airbus.</p>
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<p>Till fabric analysis from two cross-sections in the southeastern part of the study area. (<b>A</b>) shows the southern cross-section, (<b>B</b>) illustrates the northern cross-section. Yellow stars indicate sampling sites.</p>
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<p>Ice-flow sequence south of Lake Mistassini and in the surrounding areas. A: This study, B [<a href="#B4-limnolrev-24-00026" class="html-bibr">4</a>], C [<a href="#B3-limnolrev-24-00026" class="html-bibr">3</a>], D [<a href="#B30-limnolrev-24-00026" class="html-bibr">30</a>], E [<a href="#B34-limnolrev-24-00026" class="html-bibr">34</a>], F [<a href="#B42-limnolrev-24-00026" class="html-bibr">42</a>], G [<a href="#B43-limnolrev-24-00026" class="html-bibr">43</a>], H [<a href="#B35-limnolrev-24-00026" class="html-bibr">35</a>], I [<a href="#B5-limnolrev-24-00026" class="html-bibr">5</a>], and J [<a href="#B39-limnolrev-24-00026" class="html-bibr">39</a>]. Mistassini ice divide [<a href="#B42-limnolrev-24-00026" class="html-bibr">42</a>,<a href="#B44-limnolrev-24-00026" class="html-bibr">44</a>]. Hydrography data from the Topographic Database of the Government of Québec.</p>
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<p>Elevation-based distribution of S and SSE-ice flow indicators.</p>
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<p>Distribution and orientation of elongated lakes (length:width ≥ 3) within the study area. Shaded relief derived from ASTER Global Digital Elevation Model V003. Hydrography data from the Topographic Database of the Government of Québec, accessed on 13 September 2022. Geological data from SIGÉOM (<a href="http://sigeom.mines.gouv.qc.ca/" target="_blank">http://sigeom.mines.gouv.qc.ca/</a>), accessed on 9 October 2024.</p>
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18 pages, 4286 KiB  
Article
Assessment of Ecological Hazards in the Inaouen Wadi and Its Tributaries Using the Presence of Potentially Toxic Elements in Its Sediments
by Sanae Rezouki, Tarik Moubchir, Laila El Hanafi, Rachid Flouchi, Ilham Zahir, Mashail N. Alzain, Bouchra El Guerrouj, Omar Noman, Abdelaaty A. Shahat and Aimad Allali
Water 2024, 16(20), 2936; https://doi.org/10.3390/w16202936 (registering DOI) - 15 Oct 2024
Viewed by 283
Abstract
Inaouen wadi is the second largest tributary of the Sebou river, one of Morocco’s major rivers, which holds significant economic and social importance. Unfortunately, this watercourse is severely impacted by pollution from various human activities, particularly industrial sources. However, available data on the [...] Read more.
Inaouen wadi is the second largest tributary of the Sebou river, one of Morocco’s major rivers, which holds significant economic and social importance. Unfortunately, this watercourse is severely impacted by pollution from various human activities, particularly industrial sources. However, available data on the presence of potentially toxic elements (PTEs) that could harm human health in this region remain limited. PTEs pose major environmental risks due to their toxicity, persistence, and bioaccumulation. This study aimed to assess the concentrations of PTEs in the sediments of Inaouen wadi and its main tributaries based on sediment samples collected from 12 locations in 2019. The concentrations of Cd, Pb, Cr, Ag, Al, Cu, Fe, and Zn were measured using inductively coupled plasma atomic emission spectroscopy (ICP–AES), and sediment contamination levels were evaluated using multiple indices: the enrichment factor (EF), the geo-accumulation index (Igeo), the potential ecological hazard index (RI), and the modified ecological risk index (MRI). The results indicate that concentrations of Pb, Cd, Cr, Cu, Fe, and Zn are significantly influenced by urban discharges, particularly at sites S1, S3, and S5 near the cities of Taza and Oued-Amlil. The maximum values recorded were 7.01 g/kg for Pb, 0.9 g/kg for Cd, 0.1 g/kg for Cr, 19.9 g/kg for Fe and 1.9 g/kg for Zn. The enrichment factor (EF) revealed anthropogenic sources of Fe and Pb, confirming the human origin of these elements. The geo-accumulation index (Igeo) showed that the areas around stations S1, S3, and S5 are highly contaminated by Pb, Cd, and Fe, a finding also supported by the MRI. The study identified potential ecological risks at stations S1, S3, and S5, highlighting the urgent need for improved pollution management practices to mitigate environmental risks. Full article
(This article belongs to the Special Issue Water Quality Assessment of River Basins)
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<p>Location of the sampling stations in the studied area.</p>
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<p>Distribution of sedimentary particles at each station along the Inaouene wadi and its tributaries.</p>
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<p>Concentrations of PTEs in sediment samples (g/kg) from the Inaouene wadi and its main tributaries.</p>
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<p>Hierarchical ascending classification (HAC) of the studied stations, where Y axis represent the sample sites and X axis represent the resized class combination distance.</p>
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<p>PTE concentrations as a function of background sediment sample texture.</p>
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<p>The stations in the F1 × F2 factorial plane.</p>
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<p>Spatial distribution of the geo-accumulation index values (Igeo).</p>
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<p>Spatial distribution of trace element enrichment factor values in the sediment samples of the Inaouene wadi.</p>
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<p>Spatial variation in the potential ecological hazard index (RI) along the Inaouene wadi.</p>
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<p>Spatial variation in the modified potential ecological hazard index (MRI) along the Inaouene wadi.</p>
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30 pages, 2563 KiB  
Article
Assessing the Opportunities and Risks of DUS and VCU Variety Testing for Sustainable Production through SWOT Analysis Results
by Nóra Mendler-Drienyovszki, Katalin Magyar-Tábori, Roberto Mancinelli, Lisa Black, Hazel Brown, Mohamed Allam, Sripada M. Udupa, Mariam Atait, Elena Novarina, Tommaso Bardelli, Preben Klarskov Hansen, Paul Cottney and Anna Giulini
Agriculture 2024, 14(10), 1817; https://doi.org/10.3390/agriculture14101817 (registering DOI) - 15 Oct 2024
Viewed by 443
Abstract
Within the European Union (EU), new plant varieties to be included in the Common catalog of a member state have to be registered on the national list after plant variety testing processes to establish whether the candidate variety is distinguishable, uniform, and stable [...] Read more.
Within the European Union (EU), new plant varieties to be included in the Common catalog of a member state have to be registered on the national list after plant variety testing processes to establish whether the candidate variety is distinguishable, uniform, and stable (DUS) and meets the cultivation or use value requirement (VCU). Technical development, climate change, and changing consumer needs, including the detection of GMOs, necessitate the innovation of plant variety testing methods. In our study, we assessed new characters, testing methods, and inclusion of additional data for the potential to benefit the DUS and VCU protocols. To achieve our goal, we asked experts to fill in questionnaires for the DUS and VCU methods currently used for a selection of common crops, including potato, maize, lentil, oilseed rape, and perennial grass. Within the EU-funded “InnoVar” project, partners sent out questionnaires to 19 European Countries and to 3 countries outside Europe. Surveys were aimed at analyzing the strengths, weaknesses, opportunities, and threats (SWOT) of the current methods. With their help, it is possible to look for a new direction, opportunity, and strategy to incorporate, together with the innovative new techniques, into the development of the new methods. Our study demonstrated that the SWOT analysis could be used to achieve the set goals. Results obtained after evaluation of surveys confirmed that introduction of new characters such as cold tolerance, nitrogen and water efficiency, etc. has become necessary, as has the inclusion of new test methods (molecular markers, precision techniques, organic farming). The development of high-yielding, disease and/or pest-resistant plant varieties with good adaptability and the accurate evaluation of genotypes play a crucial role in ensuring that farmers can access high-performing plant varieties and contribute to sustainable food production. Full article
(This article belongs to the Section Crop Production)
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<p>Research methodology structure.</p>
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<p>The ear characteristics of durum wheat are important variety traits (Source ‘InnoVar’ experiment, Nyíregyháza, Hungary).</p>
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<p>Uniform and heterogenous seed colors of different lentil breeding lines (Source: photos were taken by Nóra Mendler-Drienyovszki).</p>
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<p>DUS observations of perennial ryegrass (source: photos were taken by Lisa Black).</p>
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<p>Different light-sprouts of potato breeding lines (Source: photos were taken by Katalin Magyar-Tábori).</p>
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<p>Frequency figures of answers to the SWOT questionnaire regarding DUS tests of maize (<b>A</b>), potato (<b>B</b>), perennial ryegrass (<b>C</b>), lentil (<b>D</b>), and oilseed rape (<b>E</b>), where S, W, O, and T mean strengths, weaknesses, opportunities, and threats, respectively. Codes of questions: S1. Do you consider the DUS protocol used conforms to an internationally accepted standard? S2. Scale used for expression level: Do you think it is a Strength? S3. The groups of characteristics: Do you think the characteristic lists complete and so can be considered Strength? S4. The characteristics used for differentiating varieties: Do you think it can be considered Strength? W1. Inaccurate expression categories (e.g., determination of seed color): Do you think it is correct? W2. Lack of total objectivity for not measurable characteristics (visually registered, pseudo-qualitative traits, such as shape, etc.): Do you think it is correct? O1. Use of molecular markers: Does molecular marker testing to be considered an Opportunity? O2. (in the case of maize) Priority of DUS data sharing between European countries. T1. Please suggest here any other aspects or innovations which can be considered! Categories: (1)—Yes; (2)—Yes, conditionally; (3)—Yes, partly; (4)—No; (5)—Not relevant.</p>
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<p>Frequency table of answers to the SWOT questionnaire regarding VCU tests of maize (<b>A</b>), potato (<b>B</b>), perennial ryegrass (<b>C</b>), and oilseed rape (<b>D</b>), where S, W, O, and T mean strengths, weaknesses, opportunities, and threats, respectively. Code of questions: S1: Quality control: Do you consider quality control a Strength in your scientific knowledge? S2: Varieties are tested in organic conditions: Are varieties tested in organic management? S3 (in the case of maize): Do you think adding organic test could be a S? W1: Lack of international standardization on methodologies (e.g., minimum values for content in protein, sugar, fat, etc.): Do you think this is a Weakness? W2: Lack of international standardization in the protocols: Do you think this is a Weakness? W3: Lack of available data. Do you think this is fundamental? W4: Varieties are tested only in conventional management: Do you think this is a Weakness? W5: Number of organic trial locations is low: Is it correct in your Country? W6: Lack of national and international priority of characteristics during the VCU test: Do you think this is a Weakness? O1: Involvement of special traits (e.g., weed competitiveness, nitrogen use efficiency, etc.). Do you think is this an Opportunity? O2: Decrease cost of post-registration tests: Do you think is this an Opportunity if applied? T1: Organic trials are more expensive than the conventional ones: Is it correct in your Country? T2 (in the case of potato and maize): If yes, do you think it should be supported by the government because it could become an Opportunity? T3: Expensive molecular studies: Does molecular testing have a reason to be applied? T4: If yes, do you think it should be supported by the government because it could become an Opportunity? Categories: (1)—Yes; (2)—Yes, conditionally; (3)—Yes, partly; (4)—No; (5)—Not relevant.</p>
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25 pages, 9319 KiB  
Article
Blind Separation of Skin Chromophores from Multispectral Dermatological Images
by Mustapha Zokay and Hicham Saylani
Diagnostics 2024, 14(20), 2288; https://doi.org/10.3390/diagnostics14202288 (registering DOI) - 14 Oct 2024
Viewed by 292
Abstract
Background/Objectives: Based on Blind Source Separation and the use of multispectral imaging, the new approach we propose in this paper aims to improve the estimation of the concentrations of the main skin chromophores (melanin, oxyhemoglobin and deoxyhemoglobin), while considering shading as a [...] Read more.
Background/Objectives: Based on Blind Source Separation and the use of multispectral imaging, the new approach we propose in this paper aims to improve the estimation of the concentrations of the main skin chromophores (melanin, oxyhemoglobin and deoxyhemoglobin), while considering shading as a fully-fledged source. Methods: In this paper, we demonstrate that the use of the Infra-Red spectral band, in addition to the traditional RGB spectral bands of dermatological images, allows us to model the image provided by each spectral band as a mixture of the concentrations of the three chromophores in addition to that of the shading, which are estimated through four steps using Blind Source Separation. Results: We studied the performance of our new method on a database of real multispectral dermatological images of melanoma by proposing a new quantitative performances measurement criterion based on mutual information. We then validated these performances on a database of multispectral dermatological images that we simulated using our own new protocol. Conclusions: All the results obtained demonstrated the effectiveness of our new approach for estimating the concentrations of the skin chromophores from a multispectral dermatological image, compared to traditional approaches that consist of using only the RGB image by neglecting shading. Full article
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<p>Chromophore absorption coefficient [<a href="#B25-diagnostics-14-02288" class="html-bibr">25</a>,<a href="#B39-diagnostics-14-02288" class="html-bibr">39</a>] and the 4 spectral bands of multispectral imaging.</p>
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<p>Flowchart illustrating the main steps of our method <span class="html-italic">BCSnmf-Irgb</span>.</p>
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<p>Processed dermatological image: (<b>a</b>) Image with specular reflection, (<b>b</b>) Image without specular reflection.</p>
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<p>Contributions of chromophores and shading estimated by each of the three methods: (<b>a</b>) <span class="html-italic">BCS-rgb</span>, (<b>b</b>) <span class="html-italic">BCS-Irgb</span> and (<b>c</b>) <span class="html-italic">BCSnmf-Irgb</span>.</p>
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<p>Example of dermatological images containing hair.</p>
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<p>(<b>a</b>) Simulated contributions of the three chromophores and shading, (<b>b</b>) Resulting RGB dermatological image.</p>
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<p>Contributions of the chromophores and shading estimated by each of the three methods: (<b>a</b>) <span class="html-italic">BCS-rgb</span>, (<b>b</b>) <span class="html-italic">BCS-Irgb</span> and (<b>c</b>) <span class="html-italic">BCSnmf-Irgb</span>.</p>
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14 pages, 6750 KiB  
Article
Comparative Analysis of NURBS and Finite Element Method in Computational Fluid Dynamics Applications: Case Study on NACA 2412 Airfoil Aerodynamics
by Sohaib Guendaoui, Lahcen El Ouadefli, Abdeslam El Akkad, Ahmed Elkhalfi, Sorin Vlase and Maria Luminița Scutaru
Mathematics 2024, 12(20), 3211; https://doi.org/10.3390/math12203211 (registering DOI) - 14 Oct 2024
Viewed by 395
Abstract
In this research, an attempt was made to employ the Non-Uniform Rational B-Splines (NURBS) method for a challenging computational fluid dynamics (CFD) problem of aerodynamics around NACA 2412 airfoils. The comparison was carried out thoroughly by using the same boundary conditions and geometry, [...] Read more.
In this research, an attempt was made to employ the Non-Uniform Rational B-Splines (NURBS) method for a challenging computational fluid dynamics (CFD) problem of aerodynamics around NACA 2412 airfoils. The comparison was carried out thoroughly by using the same boundary conditions and geometry, comparing NURBS to standard FEM implementations. Our study was interested in demonstrating the foreseeable functionalities of NURBS for solving complex CFD problems and conducting a comparative effectiveness performance evaluation between them with traditional FEM methodologies. Full article
(This article belongs to the Special Issue Advanced Model Optimization and Data Fusion Methods in Aircraft)
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<p>B-spline basis functions at knot vector Ξ = {0,0,0,1,1,2,3,4,5,5,5}.</p>
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<p>Physical domain on the right and reference domain on the left.</p>
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<p>A representation of a blade’s cross-section using B-spline modeling for the control point coordinates.</p>
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<p>Multi-patch domain of airfoil NACA2412.</p>
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<p>IGA mesh generation for airfoil NACA 2412 domain.</p>
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<p>Mesh generation for airfoil NACA 2412 domain and isotropic mesh for boundary layer.</p>
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<p>Boundary conditions applied for airfoil NACA 2412 geometry.</p>
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<p>(<b>a</b>) Velocity field evaluation using NURBS method; (<b>b</b>) velocity field evaluation using FEM.</p>
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<p>(<b>a</b>) Pressure field evaluation using NURBS method; (<b>b</b>) pressure field evaluation using FEM.</p>
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<p>(<b>a</b>) Horizontal line left-side evaluation; (<b>b</b>) horizontal line right-side evaluation.</p>
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<p>Horizontal line left-side pressure evaluation using FEM and IGA.</p>
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<p>Horizontal line left-side velocity evaluation using FEM and IGA.</p>
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<p>Horizontal line right-side pressure evaluation using FEM and IGA.</p>
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<p>Horizontal line right-side velocity evaluation using FEM and IGA.</p>
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<p>(<b>a</b>) The convergence study of the FEM error curve; (<b>b</b>) the convergence study of the IGA posteriori error curve.</p>
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27 pages, 1069 KiB  
Article
Fractional Derivative to Symmetrically Extend the Memory of Fuzzy C-Means
by Safaa Safouan, Karim El Moutaouakil and Alina-Mihaela Patriciu
Symmetry 2024, 16(10), 1353; https://doi.org/10.3390/sym16101353 - 12 Oct 2024
Viewed by 279
Abstract
The fuzzy C-means (FCM) clustering algorithm is a widely used unsupervised learning method known for its ability to identify natural groupings within datasets. While effective in many cases, FCM faces challenges such as sensitivity to initial cluster assignments, slow convergence, and difficulty in [...] Read more.
The fuzzy C-means (FCM) clustering algorithm is a widely used unsupervised learning method known for its ability to identify natural groupings within datasets. While effective in many cases, FCM faces challenges such as sensitivity to initial cluster assignments, slow convergence, and difficulty in handling non-linear and overlapping clusters. Aimed at these limitations, this paper introduces a novel fractional fuzzy C-means (Frac-FCM) algorithm, which incorporates fractional derivatives into the FCM framework. By capturing non-local dependencies and long memory effects, fractional derivatives offer a more flexible and precise representation of data relationships, making the method more suitable for complex datasets. Additionally, a genetic algorithm (GA) is employed to optimize a new least-squares objective function that emphasizes the geometric properties of clusters, particularly focusing on the Fukuyama–Sugeno and Xie–Beni indices, thereby enhancing the balance between cluster compactness and separation. Furthermore, the Frac-FCM algorithm is evaluated on several benchmark datasets, including Iris, Seed, and Statlog, and compared against traditional methods like K-means, SOM, GMM, and FCM. The results indicate that Frac-FCM consistently outperforms these methods in terms of the Silhouette and Dunn indices. For instance, Frac-FCM achieves higher Silhouette scores of most cases, indicating more distinct and well-separated clusters. Dunn’s index further shows that Frac-FCM generates clusters that are better separated, surpassing the performance of traditional methods. These findings highlight the robustness and superior clustering performance of Frac-FCM. The Friedman test was employed to enhance and validate the effectiveness of Frac-FCM. Full article
(This article belongs to the Section Computer)
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<p>Genetic algorithm cycle.</p>
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<p>Methodology utilized in this paper to develop the Frac-FCM model.</p>
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<p>Genetic algorithm performance indicators for Haberman dataset optimization.</p>
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<p>Genetic algorithm performance indicators for Libra dataset optimization.</p>
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<p>Genetic algorithm performance indicators for Wine dataset optimization.</p>
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<p>Genetic algorithm performance indicators for Pima dataset optimization.</p>
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<p>Average performance of clustering based on the Silhouette index.</p>
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<p>Average clustering performance based on the Dunn index.</p>
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17 pages, 3926 KiB  
Article
Minimizing the Adverse Impacts of Soil Salinity on Maize and Tomato Growth and Productivity through the Application of Plant Growth-Promoting Rhizobacteria
by Hiba Yahyaoui, Nadia El Allaoui, Aziz Aziz, Majida Hafidi and Khaoula Habbadi
Crops 2024, 4(4), 463-479; https://doi.org/10.3390/crops4040033 (registering DOI) - 12 Oct 2024
Viewed by 335
Abstract
Soil salinity significantly impacts crop productivity. In response, plant growth-promoting rhizobacteria (PGPR) offer an innovative and eco-friendly solution to mitigate salinity stress. However, research on PGPR’s effects on crop physiology under varying salinity levels is still emerging. This study evaluates the impact of [...] Read more.
Soil salinity significantly impacts crop productivity. In response, plant growth-promoting rhizobacteria (PGPR) offer an innovative and eco-friendly solution to mitigate salinity stress. However, research on PGPR’s effects on crop physiology under varying salinity levels is still emerging. This study evaluates the impact of five bacterial strains, isolated from compost, on the growth of maize (Zea mays) and tomato (Solanum lycopersicum) plants under different levels of salt stress. This study involved treating maize and tomato seeds with five bacterial strains, and then planting them in a greenhouse under varying salt stress conditions (43 mM, 86 mM, 172 mM, 207 mM NaCl) using a Randomized Complete Block Design. Results showed that bacterial inoculation improved plant growth under saline conditions. S2015-1, S2026-2, and S2027-2 (Bacillus cereus, Acinetobacter calcoaceticus, Bacillus subtilis) were particularly effective in promoting plant growth under salt stress, especially at ionic concentrations of 43 mM and 86 mM, leading to a substantial increase in fresh and dry weight, with strain S2015-1 boosting chlorophyll by 29% at 86 mM in both crops. These results highlight the potential of PGPR to enhance crop resilience and productivity under salinity stress, promoting climate-smart agricultural practices. Full article
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<p>Effects of bacterial strains irrigated with saline solution on (<b>A</b>) fresh weight (FW, g), (<b>B</b>) dry weight (DW, g), (<b>C</b>) shoot length (cm), and (<b>D</b>) relative water content (RWC) of tomato plants. Means sharing the same letter are considered relatively similar. The order of the letters (a &gt; b &gt; c &gt; d &gt; e &gt; f) indicates a decreasing value of the means. Some means may belong to multiple groups (for example, ‘cd’ indicates that this mean is relatively similar to the means of groups c and d).</p>
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<p>Effect of bacterial strains on fresh weight (FW, g) and dry weight (DW, g) of tomato plants under saline irrigation.</p>
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<p>Fresh weight (FW, g) variation in maize plants with increasing salinity levels.</p>
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<p>Photographs of tomato plants irrigated with varying salt concentrations. (<b>A</b>): not inoculated with bacterial suspension 2015-1. (<b>B</b>): inoculated with bacterial suspension 2015-1.</p>
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<p>Maize growth progression under varying salt concentrations (43 mM, 86 mM, 172 mM, 207 mM) and inoculation with bacterial suspensions.</p>
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<p>Photographs0 depicting (<b>A</b>,<b>B</b>) size regression, (<b>C</b>) leaf yellowing, and (<b>D</b>) leaf wilting as a function of increasing salt concentration of maize plants.</p>
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<p>Effect of rhizobacteria on (<b>A</b>) root length (cm) and (<b>B</b>) stem diameter (mm) during irrigation of maize plants with five NaCl concentrations.</p>
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<p>The effect of rhizobacteria on (<b>A</b>) chlorophyll content (CCl), (<b>B</b>) leaf area (mm<sup>2</sup>), and (<b>C</b>) the number of leaves per plant during irrigation with a range of saline concentrations. Means sharing the same letter are considered relatively similar. The order of the letters indicates a decreasing value of the means. Means may that belong to multiple groups, example, ‘cd’ indicates that this mean is relatively similar to the means of groups c and d.</p>
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<p>PCR amplification of 16S rDNA from five bacterial strains tested.</p>
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38 pages, 6410 KiB  
Review
Solar Energy Resource and Power Generation in Morocco: Current Situation, Potential, and Future Perspective
by Rania Benbba, Majd Barhdadi, Antonio Ficarella, Giovanni Manente, Maria Pia Romano, Nizar El Hachemi, Abdelfettah Barhdadi, Ahmed Al-Salaymeh and Abdelkader Outzourhit
Resources 2024, 13(10), 140; https://doi.org/10.3390/resources13100140 - 11 Oct 2024
Viewed by 385
Abstract
The world’s attention is currently focused on the energy transition to sustainable energy. The drive to reduce greenhouse gas emissions in order to limit global warming, energy security, and the generalization of access to energy have contributed to the adoption of the Moroccan [...] Read more.
The world’s attention is currently focused on the energy transition to sustainable energy. The drive to reduce greenhouse gas emissions in order to limit global warming, energy security, and the generalization of access to energy have contributed to the adoption of the Moroccan Energy Strategy, with a strong focus on renewable energy (RE). Morocco is notoriously poor in conventional primary fossil energy resources, with energy dependence on the order of 90%. In addition, the energy crisis that resulted from the COVID-19 pandemic and geopolitical conflicts, compounded with steady increase in demand, has heavily affected the security and stability of the country’s energy situation. The transition to RE by strongly engaging in the implementation of several solar, wind, and hydro energy projects has made the country the leader in RE in Africa. These projects benefit from the country’s excellent solar and wind energy potential. As a consequence, by 2030, the share of RE in the installed capacity is expected to reach 52%. An overview of the current situation of RE (particularly solar energy) in Morocco is provided, including the potentials, obstacles, challenges, and future perspectives. Thanks to its high solar potential, it is predictable that Morocco’s effort will be focused on this field: the Erasmus plus INNOMED project is a virtuous example of international cooperation, aiming at promoting solar energy through capacity building and the creation of solar energy networks, in synergy with EU Partners. Full article
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<p>Global coal consumption, 2002–2026. Source: [<a href="#B2-resources-13-00140" class="html-bibr">2</a>].</p>
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<p>(<b>a</b>) Natural gas and (<b>b</b>) oil consumption by regions, 2019–2023. From the Economist Intelligence Unit, International Energy Agency. <a href="https://www.rivistaenergia.it/2023/01/6-tendenze-dellenergia-nel-2023-secondo-economist-intelligence/" target="_blank">https://www.rivistaenergia.it/2023/01/6-tendenze-dellenergia-nel-2023-secondo-economist-intelligence/</a> Accessed on: 5 August 2024.</p>
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<p>Installed capacity by energy source in MW and maximum power demand in MW (2010–2023) in Morocco. Data from: <a href="http://www.one.org.ma/" target="_blank">http://www.one.org.ma/</a> Accessed on: 5 August 2024.</p>
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<p>(<b>a</b>) Distribution of primary energy demand in 2022. (<b>b</b>) Total energy consumption in Morocco in 2022. Data from: [<a href="#B20-resources-13-00140" class="html-bibr">20</a>].</p>
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<p>Evolution of the installed energy capacity by source between 2011 and 2023.</p>
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<p>Evolution of national electricity production by energy source in GWh (2010–2022). Data from [<a href="#B8-resources-13-00140" class="html-bibr">8</a>].</p>
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<p>Current organization of Morocco’s electricity sector, divided into a regulated sector and a liberalized sector. Arrows indicate the flow of electricity and responsibilities. Red arrows show the path of electricity received or output directly (to distributors or consumers) by ONEE as a single transport system. Green arrows: Indicate the paths for distributing electricity to customers in the medium-voltage (MV) and high-voltage (HV) segments, highlighting the distinction between private and public companies. Blue arrows: Represent the flow of electricity between the private producer and the various receivers. Source: [<a href="#B36-resources-13-00140" class="html-bibr">36</a>].</p>
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<p>Approximate average monthly sunshine duration and sunrise times in the case of Marrakech, Morocco. Source: [<a href="#B39-resources-13-00140" class="html-bibr">39</a>].</p>
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<p>Map of yearly global horizontal irradiation in Morocco (kWh/m<sup>2</sup>/day). Source: [<a href="#B43-resources-13-00140" class="html-bibr">43</a>] <a href="https://solaratlas.masen.ma/" target="_blank">https://solaratlas.masen.ma/</a>.</p>
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<p>Map of yearly direct normal irradiation in Morocco (kWh/m<sup>2</sup>/year) Source: [<a href="#B43-resources-13-00140" class="html-bibr">43</a>] <a href="https://solaratlas.masen.ma/" target="_blank">https://solaratlas.masen.ma/</a>.</p>
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<p>Map of yearly photovoltaic output in Morocco (kWh/kWp/year). Source: [<a href="#B43-resources-13-00140" class="html-bibr">43</a>] <a href="https://solaratlas.masen.ma/" target="_blank">https://solaratlas.masen.ma/</a>.</p>
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<p>Average monthly variations in PVOUT, GTI, and PR in the case of Marrakech, Morocco.</p>
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<p>Map of yearly wind potential in Morocco. Source: [<a href="#B45-resources-13-00140" class="html-bibr">45</a>] <a href="https://solaratlas.masen.ma/" target="_blank">https://solaratlas.masen.ma/</a>.</p>
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<p>Geographical locations of the installed and planned solar plants (Source MASEN, <a href="https://www.masen.ma/en" target="_blank">https://www.masen.ma/en</a>).</p>
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<p>Evolution of installed RE capacity (2010–2023). Data From <a href="http://www.one.org.ma/" target="_blank">http://www.one.org.ma/</a> and [<a href="#B8-resources-13-00140" class="html-bibr">8</a>].</p>
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<p>Evolution of the installed capacity of solar energy plants by technology (CSP and PV) in Morocco between 2010 and 2023. Source: (ANRE Annual Report 2021) <a href="https://anre.ma/en/publicationdocs/rapport-annuel-2021-version-anglaise/" target="_blank">https://anre.ma/en/publicationdocs/rapport-annuel-2021-version-anglaise/</a> (Accessed on 5 August 2024).</p>
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<p>Evolution of the solar energy fed to the grid by plant in Morocco between 2010 and 2021 (ANRE Annual Report 2021. <a href="https://anre.ma/en/publicationdocs/rapport-annuel-2021-version-anglaise/" target="_blank">https://anre.ma/en/publicationdocs/rapport-annuel-2021-version-anglaise/</a> (Accessed on 5 August 2024)).</p>
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<p>Evolution of installed wind-energy capacity by framework (2010–2023). Data from <a href="https://www.mem.gov.ma/" target="_blank">https://www.mem.gov.ma/</a>.</p>
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<p>Evolution of the total energy generated and the energy generated from renewable sources (2010–2022). Data from: <a href="http://www.one.org.ma/" target="_blank">http://www.one.org.ma/</a>.</p>
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<p>CO<sub>2</sub> emissions by sector and energy source in Morocco (2010–2022). Data from: IRENA [<a href="#B66-resources-13-00140" class="html-bibr">66</a>] and <a href="https://www.iea.org/countries/morocco/electricity" target="_blank">https://www.iea.org/countries/morocco/electricity</a> (Accessed on 5 August 2024).</p>
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<p>Morocco’s 2020–2050 RE capacity targets (%). Source: Global Data <a href="https://w3.windfair.net/wind-energy/news/39797-globaldata-morocco-renewable-energy-renewables-wind-wind-power-solar-tender-target-aim-progress-energy-transtion" target="_blank">https://w3.windfair.net/wind-energy/news/39797-globaldata-morocco-renewable-energy-renewables-wind-wind-power-solar-tender-target-aim-progress-energy-transtion</a> (Accessed on: 5 August 2024).</p>
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<p>Cumulative capacity of Morocco’s renewable power market in 2010–2030. Source: Global Data <a href="https://w3.windfair.net/wind-energy/pr/40252-globaldata-morocco-capacity-installation-investment-thermal-power-renewable-power-wind-energy-program-wind-farm" target="_blank">https://w3.windfair.net/wind-energy/pr/40252-globaldata-morocco-capacity-installation-investment-thermal-power-renewable-power-wind-energy-program-wind-farm</a> (Accessed on: 5 August 2024).</p>
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<p>MASEN’s plan to reach 52% by 2030. Source: [<a href="#B56-resources-13-00140" class="html-bibr">56</a>].</p>
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<p>Variation of the LCOE cost projection of CSP versus PV (six hours of storage), 2015–2030. Source: [<a href="#B74-resources-13-00140" class="html-bibr">74</a>].</p>
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17 pages, 8854 KiB  
Article
Economic Assessment of Hydrologic Ecosystem Services in Morocco’s Protected Areas: A Case Study of Ifrane National Park
by Oumayma Sadgui and Abdellatif Khattabi
Sustainability 2024, 16(20), 8800; https://doi.org/10.3390/su16208800 - 11 Oct 2024
Viewed by 702
Abstract
This study delves into the complex interplay between land use dynamics, hydrological services, and intangible benefits within the context of Ifrane National Park (INP) in Morocco. Due to its extensive mountain forests and numerous wetlands, INP is a crucial contributor to the nation’s [...] Read more.
This study delves into the complex interplay between land use dynamics, hydrological services, and intangible benefits within the context of Ifrane National Park (INP) in Morocco. Due to its extensive mountain forests and numerous wetlands, INP is a crucial contributor to the nation’s water supply and a vital source of hydrological ecosystem services (HES). However, climate change and evolving land use patterns have led to diminishing water resources and the desiccation of certain wetlands. This research used the Integrated Valuation of Ecosystem Services and Tradeoffs software (InVEST 3.10.2) for HES quantification and environmental economics approach for monetization to comprehend how HES values respond to challenges posed by urbanization, intensive agriculture, and other land use alterations. This work underscores INP’s role as a significant “water tower”, emphasizing the evolution of its services amidst challenges. Our findings reveal an annual decrease in HES economic value by USD 4000. This economic assessment serves as a compelling tool to enlighten decision-makers and park users about the imperative need to preserve natural ecosystems and use water resources judiciously. It advocates for investments in conservation and restoration within protected areas to sustain these vital services. Full article
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<p>Map of the geographical location of the INP watershed.</p>
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<p>Changes in land use in INP between 2008 and 2020.</p>
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<p>Soil loss maps of the INP watershed in 2008 and 2020.</p>
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<p>Evolution of the quantities of sediments lost, exported, retained, and deposited in the INP watershed: upstream part of the Sebou watershed (<b>a</b>) and upstream part of the Oum Er-Rabia watershed (<b>b</b>).</p>
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<p>Maps of nitrogen exported to the INP watershed in 2008 and 2020.</p>
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<p>Maps of phosphorus exported to the INP watershed in 2008 and 2020.</p>
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<p>Evolution of the quantities of nitrogen (<b>a</b>) and phosphorus (<b>b</b>) exported in the INP watershed between 2008 and 2020.</p>
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<p>Sediment retention by land use in the INP watershed (%).</p>
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<p>Water yield maps for the INP watershed in 2008 and 2020.</p>
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<p>Water yield in the INP watershed between 2008 and 2020.</p>
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<p>Land use map of the INP watershed in 2008 and 2020.</p>
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<p>InVEST models input rasters: precipitation (<b>a</b>), evapotranspiration (<b>b</b>), digital elevation model (<b>c</b>), erosivity (<b>d</b>), soil erodibility (<b>e</b>), roots depth (<b>f</b>), and plants’ available water content (<b>g</b>).</p>
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23 pages, 3582 KiB  
Article
A Sustainable Solution for the Adsorption of C.I. Direct Black 80, an Azoic Textile Dye with Plant Stems: Zygophyllum gaetulum in an Aqueous Solution
by Chaimaa Haoufazane, Fatima Zaaboul, Hanae El Monfalouti, Nada Kheira Sebbar, Mohamed Hefnawy, Abderrahim El Hourch and Badr Eddine Kartah
Molecules 2024, 29(20), 4806; https://doi.org/10.3390/molecules29204806 - 11 Oct 2024
Viewed by 537
Abstract
The presence of pollutants in water sources, particularly dyes coming by way of the textile industry, represents a major challenge with far-reaching environmental consequences, including increased scarcity. This phenomenon endangers the health of living organisms and the natural system. Numerous biosorbents have been [...] Read more.
The presence of pollutants in water sources, particularly dyes coming by way of the textile industry, represents a major challenge with far-reaching environmental consequences, including increased scarcity. This phenomenon endangers the health of living organisms and the natural system. Numerous biosorbents have been utilized for the removal of dyes from the textile industry. The aim of this study was to optimize discarded Zygophyllum gaetulum stems as constituting an untreated natural biosorbent for the efficient removal of C.I. Direct Black 80, an azo textile dye, from an aqueous solution, thus offering an ecological and low-cost alternative while recovering the waste for reuse. The biosorbent was subjected to a series of characterization analyses: scanning electron microscopy (SEM), thermogravimetric analysis (TGA), Brunauer–Emmett–Teller (BET) method, X-ray diffraction (XRD), and infrared spectroscopy (IR) were employed to characterize the biosorbent. Additionally, the moisture and ash content of the plant stem were also examined. The absorption phenomenon was studied for several different parameters including the effect of the absorption time (0 to 360 min), the sorbent mass (3 to 40 g/L), the pH of the solution (3 to 11), the dye concentration (5 to 300 mg/L), and the pH of the zero-charge point (2–12). Thermodynamic studies and desorption studies were also carried out. The results showed that an increase in plant mass from 3 to 40 g/L resulted in a notable enhancement in dye adsorption rates, with an observed rise from 63.96% to 97.08%. The pH at the zero-charge point (pHpzc) was determined to be 7.12. The percentage of dye removal was found to be highest for pH values ≤ 7, with a subsequent decline in removal efficiency as the pH increased. Following an initial increase in the amount of adsorbed dye, equilibrium was reached within 2 h of contact. The kinetic parameters of adsorption were investigated using the pseudo-first-order, pseudo-second-order and Elovich models. The results indicated that the pseudo-first-order kinetic model was the most appropriate for the plant adsorbent. The isotherm parameters were determined using the Langmuir, Frendlich, Temkin, and Dubinin–Radushkevich models. The experimental data were more satisfactory and better fitted using the Langmuir model for the adsorption of dye on the plant. This study demonstrated that Zygophyllum gaetulum stems could be employed as an effective adsorbent for the removal of our organic dye from an aqueous solution. Full article
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<p>N<sub>2</sub> adsorption–desorption isotherm of <span class="html-italic">Z. Gaetulum</span> stem powder.</p>
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<p>FTIR spectra of <span class="html-italic">Zygophyllum gaetulum</span> stem powder.</p>
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<p>(<b>a</b>) TGA/DTG analysis; (<b>b</b>) TGA/DSC analysis of <span class="html-italic">Zygophyllum Gaetulum</span> stems.</p>
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<p>XRD diffractogram of <span class="html-italic">Zygophyllum gaetulum</span> stems.</p>
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<p>SEM images and EDX spectra of <span class="html-italic">Zygophyllum gaetulum</span> stem powder before adsorption.</p>
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<p>Determination of pHpzc of <span class="html-italic">Zygophyllum gaetulum</span> stems.</p>
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<p>Effect of initial pH on the removal efficiency of C.I. Direct Black 80 dye on <span class="html-italic">Zygophyllum Gaetulum</span> stems (C<sub>0</sub> = 50 mg.L<sup>−1</sup>, t = 2 h30, V = 25 mL, biosorbent dosage = 20 g.L<sup>−1</sup>, T = 25 °C).</p>
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<p>Effect of adsorbent dose on the removal efficiency of C.I. Direct Black 80 dye on <span class="html-italic">Zygophyllum gaetulum</span> stems (C<sub>0</sub> = 50 mg.L<sup>−1</sup>, t = 150 min, V = 25 mL, T = 25 °C).</p>
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<p>Non-linear fitting of kinetic models for the adsorption of C.I. Direct Black 80 dye on <span class="html-italic">Zygophyllum gaetulum</span> stems (C<sub>0</sub> = 50 mg.L<sup>−1</sup>, T = 25 °C, V = 25 mL, adsorbent dosage = 20 g.L<sup>−1</sup>).</p>
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<p>Non-linear fitting of adsorption isotherms of C.I. Direct Black dye 80 on <span class="html-italic">Zygophyllum gaetulum</span> stems (T = 25 °C, t = 150 min, V = 25 mL, adsorbent dosage = 20 g.L<sup>−1</sup>).</p>
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<p>Plot: ln(K<sub>ad</sub>) vs. 1/T for determination of thermodynamic parameters of C.I. Direct Black 80 adsorption on <span class="html-italic">Zygophyllum gaetulum</span> stems.</p>
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<p>Desorption of C.I. Direct Black 80 from <span class="html-italic">Zygophyllum gaetulum</span> stems.</p>
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<p>SEM images and EDX spectra of <span class="html-italic">Zygophyllum gaetulum</span> stem powder after adsorption (C<sub>0</sub> = 50 mg.L<sup>−1</sup>, T = 25 °C, t = 150 min, V = 25 mL, adsorbent dosage = 20 g.L<sup>−1</sup>).</p>
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<p>FTIR spectra of <span class="html-italic">Zygophyllum gaetulum</span> stem powder after adsorption.</p>
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<p>Chemical structure of C.I. Direct Black 80.</p>
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23 pages, 3251 KiB  
Article
Regeneration and Single Stage Batch Adsorber Design for Efficient Basic Blue-41 Dye Removal by Porous Clay Heterostructures Prepared from Al13 Montmorillonite and Pillared Derivatives
by Saheed A. Popoola, Hmoud Al Dmour, Rawan Al-Faze, Mohd Gulfam Alam, Souad Rakass, Hicham Oudghiri Hassani and Fethi Kooli
Materials 2024, 17(20), 4948; https://doi.org/10.3390/ma17204948 - 10 Oct 2024
Viewed by 550
Abstract
Porous clay heterostructures are a hybrid precursor between the pillaring process and organoclays. In this study, the organoclay was substituted by an aluminium intercalated species clay or pillared alumina clays. A porous clay heterostructure was successfully achieved from an aluminium intercalated species clay, [...] Read more.
Porous clay heterostructures are a hybrid precursor between the pillaring process and organoclays. In this study, the organoclay was substituted by an aluminium intercalated species clay or pillared alumina clays. A porous clay heterostructure was successfully achieved from an aluminium intercalated species clay, due to the easy exchange of the aluminium species by the cosurfactant and silica species. However, using alumina pillared clays, the porous clay heterostructures were not formed; the alumina species were strongly attached to clay sheets which made difficult their exchange with cosurfactant molecules. In this case, the silica species were polymerized and decorated the surface of the used materials as indicated by different characterization techniques. The specific surface area of the porous clay heterostructure material reached 880 m2/g, and total pore volume of 0.258 cc/g, while the decorated silica alumina pillared clays exhibited lower specific surface area values of 244–440 m2/g and total pore volume of 0.315 to 0.157 cc/g. The potential of the synthesized materials was evaluated as a basic blue-41 dye removal agent. Porous clay heterostructure material has a removal capacity of 279 mg/g; while the other materials exhibited lower removal capacities between 75 mg/g and 165 mg/g. The used regeneration method was related to the acidity of the studied materials. The acidity of the materials possessed an impact on the adopted regeneration procedure in this study, the removal efficiency was maintained at 80% of the original performance after three successive regeneration cycles for the porous clay heterostructure. The Langmuir isotherm characteristics were used to propose a single-stage batch design. Porous clay heterostructures with a higher removal capacity resulted in a decrease in the quantities needed to achieve the target removal percentage of the BB-41 dye from an aqueous solution. Full article
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<p>(<b>left</b>) PXRD patterns of raw clay, intercalated with the Al<sub>13</sub> species and calcined at different temperatures; (<b>right</b>) after reaction with C<sub>12</sub>amine and TEOS, then calcined at 550 °C.</p>
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<p>TEM micrographs of (<b>a</b>) raw Mt, (<b>b</b>) intercalated with the Al13 species (Al-IMt), (<b>c</b>) after calcination at 500 °C, (<b>d</b>) PAl-MtCH, and (<b>e</b>) PAl-Mt500CH.</p>
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<p>(<b>left</b>) <sup>29</sup>Si MAS NMR and (<b>right</b>) <sup>27</sup>Al MAS NMR of the different materials.</p>
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<p>TGA (black) and DTG (red) features of the different materials: (<b>a</b>) Mt, (<b>b</b>) Al-IMt, (<b>c</b>) PAl-IMtCH, (<b>d</b>) PAl-Mt(500), and (<b>e</b>) derived PAl-Mt(500)CH.</p>
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<p>N<sub>2</sub> adsorption-desorption isotherms of different materials: (<b>a</b>) Mt, (<b>b</b>) Al-IMt, (<b>c</b>) PAlMtCH, (<b>d</b>) Al-PMt(500), and (<b>e</b>) PMt(500)CH.</p>
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<p>Effect of on the removal properties of BB-41 dye, (<b>left</b>) PAl-IMtCH used mass and (<b>right</b>) initial BB-41 pH solution.</p>
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<p>Effect of the BB-41 initial concentration of the removal properties of the PAl-IMtCH (filled triangles) and PAl-PMt(500)CH (non-filled triangles).</p>
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<p>Variation of removal percentage (%) after different regeneration cycles.</p>
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<p>Required masses of PAl-IMtCH (<b>left</b>) and PAl-PMt(500)CH (<b>right</b>) to reduce different volumes (L) of BB-41 solutions (C<sub>i</sub> = 200 mg/L) to different removal percentages.</p>
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30 pages, 27337 KiB  
Article
Nested Cross-Validation for HBV Conceptual Rainfall–Runoff Model Spatial Stability Analysis in a Semi-Arid Context
by Mohamed El Garnaoui, Abdelghani Boudhar, Karima Nifa, Yousra El Jabiri, Ismail Karaoui, Abdenbi El Aloui, Abdelbasset Midaoui, Morad Karroum, Hassan Mosaid and Abdelghani Chehbouni
Remote Sens. 2024, 16(20), 3756; https://doi.org/10.3390/rs16203756 - 10 Oct 2024
Viewed by 769
Abstract
Accurate and efficient streamflow simulations are necessary for sustainable water management and conservation in arid and semi-arid contexts. Conceptual hydrological models often underperform in these catchments due to the high climatic variability and data scarcity, leading to unstable parameters and biased results. This [...] Read more.
Accurate and efficient streamflow simulations are necessary for sustainable water management and conservation in arid and semi-arid contexts. Conceptual hydrological models often underperform in these catchments due to the high climatic variability and data scarcity, leading to unstable parameters and biased results. This study evaluates the stability of the HBV model across seven sub-catchments of the Oum Er Rabia river basin (OERB), focusing on the HBV model regionalization process and the effectiveness of Earth Observation data in enhancing predictive capability. Therefore, we developed a nested cross-validation framework for spatiotemporal stability assessment, using optimal parameters from a donor-single-site calibration (DSSC) to inform target-multi-site calibration (TMSC). The results show that the HBV model remains spatially transferable from one basin to another with moderate to high performances (KGE (0.1~0.9 NSE (0.5~0.8)). Furthermore, calibration using KGE improves model stability over NSE. Some parameter sets exhibit spatial instability, but inter-annual parameter behavior remains stable, indicating potential climate change impacts. Model performance declines over time (18–124%) with increasing dryness. As a conclusion, this study presents a framework for analyzing parameter stability in hydrological models and highlights the need for more research on spatial and temporal factors affecting hydrological response variability. Full article
(This article belongs to the Special Issue Multi-Source Remote Sensing Data in Hydrology and Water Management)
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<p>Location of the seven study catchments in the Oum Er Rabia river basin. Land use and Land cover of the study area.</p>
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<p>HBV (Hydrologiska Byråns Vattenbalansavedelning) model scheme, modified from [<a href="#B83-remotesensing-16-03756" class="html-bibr">83</a>].</p>
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<p>Work modeling flowchart. Note that the warm-up year (2000–2001) is not included in the original modeling time series.</p>
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<p>Hydrograph of observed against simulated streamflow in AOCH (donor catchment) and the six target catchments calibrated and validated in the year 2009–2010 (as example).</p>
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<p>Hydrograph of observed against simulated streamflow in AOCH (donor catchment) and the six target catchments calibrated and validated in the year 2009–2010 (as example).</p>
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<p>Resume of optimal parameter sets versus performance metrics during spatiotemporal cross validation process.</p>
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<p>Best parameter set variation over seven sub-catchments of the study area.</p>
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<p>Variation of long-term trend of KGE performance metric across study catchments between 2001 and 2019 (mean: blue line, median: red line, standard deviation: orange line, trend: black line).</p>
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<p>Variation of long-term trend of NSE performance metric across study catchments between 2001 and 2019 (mean: blue line, median: red line, standard deviation: orange line, trend: black line).</p>
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<p>Variation of long-term trend of RMSE performance metric across study catchments between 2001 and 2019 (mean: blue line, median: red line, standard deviation: orange line, trend: black line).</p>
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<p>KGE, NSE, R<sup>2</sup>, and RMSE metric variations for different catchments across years.</p>
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<p>Variation of long-term trend of optimal parameters, across study catchments over time between 2001 and 2019 (mean: blue line, median: red line, standard deviation: orange line, trend: black line).</p>
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<p>Variation of long-term trend of optimal parameters, across study catchments over time between 2001 and 2019 (mean: blue line, median: red line, standard deviation: orange line, trend: black line).</p>
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<p>HBV model performance loss assessment over time and space using MRC criterion [<a href="#B98-remotesensing-16-03756" class="html-bibr">98</a>]. Green icon: No performance loss (or performance gain), yellow icon: low performance loss, and red icon: high performance loss (model crash).</p>
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<p>HBV model performance loss trend over time and space ((<b>A</b>) KGE, (<b>B</b>) NSE, (<b>C</b>) R<sup>2</sup>).</p>
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<p>Variation of long-term trend of R<sup>2</sup> performance metric across study catchments between 2001 and 2019 (mean: blue line, median: red line, standard deviation: orange line, trend: black line).</p>
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<p>Variation of long-term trend of RVE performance metric across study catchments between 2001 and 2019 (mean: blue line, median: red line, standard deviation: orange line, trend: black line).</p>
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<p>RVE metric variation for different catchments across years.</p>
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16 pages, 577 KiB  
Article
Improved Quantum Particle Swarm Optimization of Optimal Diet for Diabetic Patients
by Abdellah Ahourag, Zakaria Bouhanch, Karim El Moutaouakil and Abdellah Touhafi
Eng 2024, 5(4), 2544-2559; https://doi.org/10.3390/eng5040133 - 10 Oct 2024
Viewed by 402
Abstract
The dietary recommendations for individuals with diabetes focus on maintaining a balanced nutritional intake to manage blood sugar levels. This study suggests a nutritional strategy to improve glycemic control based on an analysis of a dietary optimization problem. The goal is to minimize [...] Read more.
The dietary recommendations for individuals with diabetes focus on maintaining a balanced nutritional intake to manage blood sugar levels. This study suggests a nutritional strategy to improve glycemic control based on an analysis of a dietary optimization problem. The goal is to minimize the overall glycemic loads (GLs) of specific foods. Two variations of the particle swarm optimization (PSO) method, as well as random quantum process optimization (GQPSO), are introduced. The findings demonstrate that the quantum and random methods are more effective than the traditional techniques in reducing the glycemic loads of diets and addressing nutritional deficiencies while also aligning nutrient intake with the recommended levels. The resolution of this diet optimization model, executed multiple times with adjustments to the parameters of both methods, enables dynamic exploration and provides a wide range of diverse and effective food choices. Full article
(This article belongs to the Special Issue Artificial Intelligence for Engineering Applications)
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<p>Illustration of PSO and QPSO methods.</p>
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<p>The negative nutrient requirements.</p>
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<p>The positive nutrient requirements.</p>
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<p>Optimal diet choices proven using standard PSO method.</p>
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<p>Optimal diet choices proven using the standard GQPSO method.</p>
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<p>Comparison of improvements in glycemic load demonstrated by PSO and GQPSO methods.</p>
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<p>Comparison of positive nutrients gaps of diets generated by PSO and GQPSO techniques.</p>
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<p>Comparison of negative nutrients gaps of diets generated by PSO and GQPSO techniques.</p>
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