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14 pages, 3011 KiB  
Article
Influence of Precursor Mixtures on the Laser Chemical Vapor Deposition of TiC Fibers
by Kendall J. Mitchell and Gregory B. Thompson
Fibers 2024, 12(5), 43; https://doi.org/10.3390/fib12050043 - 13 May 2024
Viewed by 889
Abstract
In this study, the hyperbaric (2 bar) laser chemical vapor deposition of TiC fibers grown under various percent pressures of hydrogen and ratios of ethylene and titanium tetrachloride (2:1 or 1:1) are reported. In the hydrogen-rich (85%) condition, sequential fiber depositions became stunted [...] Read more.
In this study, the hyperbaric (2 bar) laser chemical vapor deposition of TiC fibers grown under various percent pressures of hydrogen and ratios of ethylene and titanium tetrachloride (2:1 or 1:1) are reported. In the hydrogen-rich (85%) condition, sequential fiber depositions became stunted as a result of a loss of hydrogen, which served as a reducing agent for the metal halide as hydrogen evolved with the hydrocarbon gas in the reaction zone because of the Le Chatelier principle. For the hydrogen-lean (25%) condition, the intrinsic fiber growth rate was invariant, but gas phase nucleation resulted in the hydrocarbon forming carbon soot in the chamber which subsequently deposited and coated on the fibers. In the hydrogen-balanced composition (50%), the 2:1 precursor ratio resulted in inconsistent intrinsic growth rates which ranged from approximately 30 μm/s to 44 μm/s. However, for the hydrogen-balanced (50%) 1:1 condition, the intrinsic growth rate variation was reduced to approximately 12 μm/s. The differences in fiber uniformity, composition, and structure under these process conditions are discussed in terms of hydrogen’s ability to serve as a reducing agent, a fluid to transport heat from the deposition zone, and alter the structure of the fiber through thermophoresis. Full article
(This article belongs to the Collection Feature Papers in Fibers)
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<p>A schematic of the LCVD setup.</p>
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<p>Series of time-lapse images for the 2 C<sub>2</sub>H<sub>4</sub>:1 TiCl<sub>4</sub> mixtures with hydrogen for the TiC fiber growth. (<b>a</b>) Hydrogen-rich (<b>b</b>) Hydrogen-balance and (<b>c</b>) Hydrogen-lean mixtures.</p>
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<p>Digital images of TiC fibers in the sequence of their subsequential growth sequence of i, ii, and iii, for the first, second, and third deposition for the (<b>a</b>) Hydrogen-rich (<b>b</b>) Hydrogen-balanced and (<b>c</b>) Hydrogen-lean conditions. The numerals i, ii, and iii denote the sequence of the fiber growth with i being the first, ii being the second, and iii being the third.</p>
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<p>XRD data showing peaks correlating to graphite and TiC peaks.</p>
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<p>Line profiles (shown by the red line) with corresponding XEDS data for the (<b>a</b>) Hydrogen-rich (2:1) (<b>b</b>) Hydrogen-balanced (2:1) and (<b>c</b>) Hydrogen-lean (2:1) deposits.</p>
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<p>Growth rate as the number of sequential fibers for various precursor mixtures.</p>
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<p>(<b>a</b>) Time-lapse images of the growth progression, (<b>b</b>) XRD and (<b>c</b>) SEM image of the hydrogen-balanced (1:1) condition fiber.</p>
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<p>The digital image comparing the two hydrogen-balanced mixtures. (<b>a</b>) The hydrogen-balanced (2:1) deposit of three fibers. (<b>b</b>) The hydrogen-balanced (1:1) deposit of three fibers. Note the bronze color for the (1:1) condition vs. the (2:1) condition. The numerals i, ii, and iii denote the sequence of the fiber growth.</p>
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13 pages, 3318 KiB  
Article
Multiphysics Modeling and Simulation of a Light-Controlled Variable Damping System
by Zhicheng Liu, Zhen Lv, Yujuan Tang, Xinjie Wang, Xiang Liu and Yusong Chen
Materials 2023, 16(8), 3194; https://doi.org/10.3390/ma16083194 - 18 Apr 2023
Viewed by 1022
Abstract
In this paper, a light-controlled variable damping system (LCVDS) is proposed based on PLZT ceramics and electrorheological fluid (ERF). The mathematical models for the photovoltage of PLZT ceramics and the hydrodynamic model for the ERF are established, and the relationship between the pressure [...] Read more.
In this paper, a light-controlled variable damping system (LCVDS) is proposed based on PLZT ceramics and electrorheological fluid (ERF). The mathematical models for the photovoltage of PLZT ceramics and the hydrodynamic model for the ERF are established, and the relationship between the pressure difference at both ends of the microchannel and the light intensity is deduced. Then, simulations are conducted by applying different light intensities in the LCVDS to analyze the pressure difference at both ends of the microchannel using COMSOL Multiphysics. The simulation results show that the pressure difference at both ends of the microchannel increases with the increase in light intensity, which is consistent with results from the mathematical model established in this paper. The error rate of the pressure difference at both ends of the microchannel is within 13.8% between the theoretical and simulation results. This investigation lays the foundation for the application of light-controlled variable damping in future engineering. Full article
(This article belongs to the Special Issue Advances in Smart Materials and Applications)
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<p>Light-controlled variable damping system.</p>
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<p>Schematic diagram showing ERF flow inside a microfluidic chip under different light intensities. (<b>a</b>) Light intensity of 0 mW/cm<sup>2</sup>; (<b>b</b>) light intensity of 50 mW/cm<sup>2</sup>; and (<b>c</b>) light intensity of 150 mW/cm<sup>2</sup>.</p>
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<p>Equivalent circuit model for the LCVDS.</p>
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<p>Relationship between light intensity and photovoltage.</p>
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<p>Stress in the ERF in the microchannel.</p>
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<p>Shear stress distribution in the ERF.</p>
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<p>Velocity distribution of the ERF in the microchannel without an electric field.</p>
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<p>Velocity distribution of the ERF in the microchannel.</p>
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<p>Relationship between viscosity and voltage.</p>
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<p>The relationship between the pressure difference at both ends of the microchannel and light intensity.</p>
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<p>Electric field intensity distribution.</p>
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<p>The flow velocity of the radial distribution.</p>
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<p>Pressure distribution in the microchannel. (<b>a</b>) The pressure distribution without photovoltage and (<b>b</b>) the pressure distribution with saturation photovoltage produced using PLZT ceramic under 200 mW/cm<sup>2</sup>.</p>
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<p>Comparison of the theoretical and simulation results.</p>
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6 pages, 1068 KiB  
Communication
The Spread of Peste Des Petits Ruminants Virus Lineage IV in West Africa
by Emmanuel Couacy-Hymann, Kouramoudou Berete, Theophilus Odoom, Lamouni Habibata Zerbo, Koffi Yao Mathurin, Valère Kouame Kouakou, Mohamed Idriss Doumbouya, Aminata Balde, Patrick Tetteh Ababio, Lalidia Bruno Ouoba, Dominique Guigma, Adama Dji-tombo Drobo, Mariétou Guitti, Sherry Ama Mawuko Johnson, David Livingstone Mawuko Blavo, Giovanni Cattoli, Charles E. Lamien and William G. Dundon
Animals 2023, 13(7), 1268; https://doi.org/10.3390/ani13071268 - 6 Apr 2023
Cited by 3 | Viewed by 1679
Abstract
Monitoring the transboundary spread of peste des petits ruminants (PPR) virus is an essential part of the global efforts towards the eradication of PPR by 2030. There is growing evidence that Lineage IV is becoming the predominant viral lineage, replacing Lineage I and [...] Read more.
Monitoring the transboundary spread of peste des petits ruminants (PPR) virus is an essential part of the global efforts towards the eradication of PPR by 2030. There is growing evidence that Lineage IV is becoming the predominant viral lineage, replacing Lineage I and II in West Africa. As part of a regional investigation, samples collected in Burkina Faso, Côte d’Ivoire, Guinea and Ghana were screened for the presence of PPRV. A segment of the nucleoprotein gene from positive samples was sequenced, and phylogenetic analysis revealed the co-circulation of Lineage II and IV in Burkina Faso, Côte d’Ivoire and Guinea, and the identification of Lineage IV in Ghana. These data will be of importance to local and regional authorities involved in the management of PPRV spread. Full article
(This article belongs to the Collection Diseases of Small Ruminants)
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<p>Map showing the sampling locations of PPR-positive samples. Lineage II and IV viruses are indicated by blue and red circles, respectively.</p>
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<p>ML phylogenetic tree of the partial N gene sequences (219 nt) from the positive amplicons from this study combined with similar sequences available in GenBank. Sequences from Burkina Faso, Côte d’Ivoire, Ghana and Guinea are shown in blue, red, purple and green text, respectively. Lineages, subclades and bootstrap values &gt; 70% are indicated. Note: For image clarity some of the sequences/subclades in Lineage IV have been collapsed. An un-collapsed tree is available as <a href="#app1-animals-13-01268" class="html-app">Supplementary Figure S1</a>.</p>
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11 pages, 4290 KiB  
Article
Lymphocystis Disease Virus Infection in Clownfish Amphiprion ocellaris and Amphiprion clarkii in Taiwan
by Ming-Chung Cheng, Ming She See, Pei-Chi Wang, Yu-Ting Kuo, Yuan-Shing Ho, Shih-Chu Chen and Ming-An Tsai
Animals 2023, 13(1), 153; https://doi.org/10.3390/ani13010153 - 30 Dec 2022
Cited by 3 | Viewed by 2791
Abstract
Lymphocystic disease affects over 150 species of marine and freshwater fish worldwide. In this study, the lymphocystis pathogen was found in 2 (Amphiprion ocellaris and Amphiprion clarkii) of the 9 species of clownfish. Detection of lymphocystis disease virus (LCDV) was based [...] Read more.
Lymphocystic disease affects over 150 species of marine and freshwater fish worldwide. In this study, the lymphocystis pathogen was found in 2 (Amphiprion ocellaris and Amphiprion clarkii) of the 9 species of clownfish. Detection of lymphocystis disease virus (LCDV) was based on histopathological study, electron microscope observation of virus particles and gene sequence analysis from the MCP region. Infected A. ocellaris hosts showed sparse, multifocal, white, stiff, papilloma-like nodules on the body, skin, gills and fins; while, on A. clarkia, nodules were found on the operculum skin. Histopathologic study showed lymphocystic cells with an irregular nucleus, enlarged cytoplasm and intracytoplasmic inclusion bodies surrounded by the cell membrane. The viral particle presents virions 180–230 nm in diameter, hexagonal in shape with an inner dense nucleoid under transmission electron micrographs (TEM). From the ML polygenetic tree, the clownfish LCVD genotype was closely related to the LCDV strain from paradise fish, Macropodus opercularis (KJ408271) (pairwise distance: 92.5%) from China, then followed by the strain from Spain (GU320726 and GU320736) (pairwise distance: 90.8–90.5%), Korea (AB299163, AB212999, AB213004, and AB299164) (pairwise distance: 91.5–80.5%) and lastly Canada (GU939626) (pairwise distance: 83%). This is the first report of lymphocystis disease in A. clarkii in Taiwan. Full article
(This article belongs to the Section Veterinary Clinical Studies)
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<p>Macroscopic view of Lymphocystis disease virus (LCDV) infected <span class="html-italic">Amphiprion ocellaris</span> (<b>a</b>) and <span class="html-italic">A. clarkii</span> (<b>b</b>). Yellow arrows are white nodules.</p>
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<p>Macroscopic view of a 10× gill tissue slice (<b>a</b>) and a 10× fin tissue slice (<b>b</b>). Yellow arrow is a hyaline capsule.</p>
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<p>Histopathological findings of hypertrophic lymphocystis cells. (<b>a</b>) 40× view and (<b>b</b>) 40× view. HL: hypertrophic lymphocystis cell; HC with arrow: hyaline capsule.</p>
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<p>Histopathological findings of hypertrophic lymphocystis cells: (<b>a</b>) 100× view of single hypertrophic lymphocystic cell and (<b>b</b>) 100× view of lesion tissue on skin. HC: hyaline capsule; Arrowhead: intracytoplasmic inclusion bodies; N: nucleus.</p>
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<p>Transmission electron microscopy image of an ultra-thin section of a hypertrophic lymphocystis cell. (<b>a</b>) Ultrastructure of a hypertrophic lymphocystis cell with an LCDV virus particle, (<b>b</b>) LCDV virus. Red arrow: virus particle; H with yellow arrow: hexagonal profile protein shell; White arrow: inner membrane; *: central DNA core.</p>
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<p>Maximum likelihood polygenetic trees from <span class="html-italic">Lymphocystivirus</span> spp. based on the major capsid protein (MCP) gene under the K2+G (Kimura 2 + Gamma Distributed) model. Accession numbers were reported in the text. Number on node is 1000 bootstrap replications. * represent the present study.</p>
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11 pages, 2107 KiB  
Article
Laser-Assisted Growth of Carbon-Based Materials by Chemical Vapor Deposition
by Abiodun Odusanya, Imteaz Rahaman, Pallab Kumar Sarkar, Abdelrahman Zkria, Kartik Ghosh and Ariful Haque
C 2022, 8(2), 24; https://doi.org/10.3390/c8020024 - 26 Apr 2022
Cited by 1 | Viewed by 3323
Abstract
Carbon-based materials (CBMs) such as graphene, carbon nanotubes (CNT), highly ordered pyrolytic graphite (HOPG), and pyrolytic carbon (PyC) have received a great deal of attention in recent years due to their unique electronic, optical, thermal, and mechanical properties. CBMs have been grown using [...] Read more.
Carbon-based materials (CBMs) such as graphene, carbon nanotubes (CNT), highly ordered pyrolytic graphite (HOPG), and pyrolytic carbon (PyC) have received a great deal of attention in recent years due to their unique electronic, optical, thermal, and mechanical properties. CBMs have been grown using a variety of processes, including mechanical exfoliation, pulsed laser deposition (PLD), and chemical vapor deposition (CVD). Mechanical exfoliation creates materials that are irregularly formed and tiny in size. On the other hand, the practicality of the PLD approach for large-area high-quality CMB deposition is quite difficult. Thus, CVD is considered as the most effective method for growing CBMs. In this paper, a novel pulsed laser-assisted chemical vapor deposition (LCVD) technique was explored to determine ways to reduce the energy requirements to produce high quality CBMs. Different growth parameters, such as gas flow rate, temperature, laser energy, and deposition time were considered and studied thoroughly to analyze the growth pattern. CBMs are grown on Si and Cu substrates, where we find better quality CBM films on Cu as it aids the surface solubility of carbon. Raman spectroscopy confirms the presence of high-quality PyC which is grown at a temperature of 750 °C, CH4 gas flow rate of 20 sccm, a laser frequency of 10 Hz, and an energy density of 0.116 J/cm2 per pulse. It is found that the local pulsed-laser bombardment helps in breaking the carbon-hydrogen bonds of CH4 at a much lower substrate temperature than its thermal decomposition temperature. There is no significant change in the 2D peak intensity in the Raman spectrum with the further increase in temperature which is the indicator of the number of the graphene layer. The intertwined graphene flakes of the PyC are observed due to the surface roughness, which is responsible for the quenching in the Raman 2D signal. These results will provide the platform to fabricate a large area single layer of graphene, including the other 2D materials, on different substrates using the LCVD technique. Full article
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<p>Schematic diagram of the deposition process in the chamber.</p>
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<p>Raman spectra of pristine high−quality graphene.</p>
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<p>Raman spectra at a constant CH<sub>4</sub> flow rate at 10 sccm and different deposition temperatures.</p>
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<p>(<b>a</b>–<b>o</b>) Raman spectra at constant CH<sub>4</sub> flow rate at 20 sccm with different deposition temperatures on Cu and Si substrates.</p>
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<p>(<b>a</b>–<b>o</b>) Raman spectra at constant CH<sub>4</sub> flow rate at 20 sccm with different deposition temperatures on Cu and Si substrates.</p>
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<p>(<b>a</b>–<b>f</b>) Raman spectra at different deposition times with a constant CH<sub>4</sub> flow rate of 20 sccm and 850 °C deposition temperature.</p>
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<p>(<b>a</b>–<b>c</b>) Raman data plots showing the effect of: (<b>a</b>) no laser pulses; (<b>b</b>) laser incident spot; (<b>c</b>) laser non-incident spot on PyC deposition.</p>
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