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Sensors, Volume 9, Issue 10 (October 2009) – 41 articles , Pages 7580-8381

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219 KiB  
Article
Arrays of Regenerated Fiber Bragg Gratings in Non-Hydrogen-Loaded Photosensitive Fibers for High-Temperature Sensor Networks
by Eric Lindner, Christoph Chojetztki, Sven Brueckner, Martin Becker, Manfred Rothhardt, Johan Vlekken and Hartmut Bartelt
Sensors 2009, 9(10), 8377-8381; https://doi.org/10.3390/s91008377 - 22 Oct 2009
Cited by 28 | Viewed by 12713
Abstract
We report about the possibility of using regenerated fiber Bragg gratings generated in photosensitive fibers without applying hydrogen loading for high temperature sensor networks. We use a thermally induced regenerative process which leads to a secondary increase in grating reflectivity. This refractive index [...] Read more.
We report about the possibility of using regenerated fiber Bragg gratings generated in photosensitive fibers without applying hydrogen loading for high temperature sensor networks. We use a thermally induced regenerative process which leads to a secondary increase in grating reflectivity. This refractive index modification has shown to become more stable after the regeneration up to temperatures of 600 °C. With the use of an interferometric writing technique, it is possible also to generate arrays of regenerated fiber Bragg gratings for sensor networks. Full article
(This article belongs to the Section Chemical Sensors)
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<p>Annealing behavior of the grating reflectivity at 700 °C.</p>
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<p>Spectrum of four gratings with maximum regeneration of reflectivity at 700 °C.</p>
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<p>Temperature calibration from 25 °C to 600 °C and back for the four gratings shown in <a href="#f2-sensors-09-08377" class="html-fig">Figure 2</a>.</p>
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820 KiB  
Article
Microgyroscope Temperature Effects and Compensation-Control Methods
by Dunzhu Xia, Shuling Chen, Shourong Wang and Hongsheng Li
Sensors 2009, 9(10), 8349-8376; https://doi.org/10.3390/s91008349 - 21 Oct 2009
Cited by 96 | Viewed by 14204
Abstract
In the analysis of the effects of temperature on the performance of microgyroscopes, it is found that the resonant frequency of the microgyroscope decreases linearly as the temperature increases, and the quality factor changes drastically at low temperatures. Moreover, the zero bias changes [...] Read more.
In the analysis of the effects of temperature on the performance of microgyroscopes, it is found that the resonant frequency of the microgyroscope decreases linearly as the temperature increases, and the quality factor changes drastically at low temperatures. Moreover, the zero bias changes greatly with temperature variations. To reduce the temperature effects on the microgyroscope, temperature compensation-control methods are proposed. In the first place, a BP (Back Propagation) neural network and polynomial fitting are utilized for building the temperature model of the microgyroscope. Considering the simplicity and real-time requirements, piecewise polynomial fitting is applied in the temperature compensation system. Then, an integral-separated PID (Proportion Integration Differentiation) control algorithm is adopted in the temperature control system, which can stabilize the temperature inside the microgyrocope in pursuing its optimal performance. Experimental results reveal that the combination of microgyroscope temperature compensation and control methods is both realizable and effective in a miniaturized microgyroscope prototype. Full article
(This article belongs to the Special Issue Modeling, Testing and Reliability Issues in MEMS Engineering - 2009)
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<p>The package and SEM photos of a microgyrosocpe.</p>
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<p>Simulation of the relationship between Q and temperature.</p>
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<p>Simulation of relationship between the output amplitude and the temperature.</p>
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<p>Temperature testing schemes and setup of microgyroscope.</p>
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<p>Trend of resonant frequency with temperature in drive mode.</p>
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<p>Trend of quality factor change with temperature in drive mode.</p>
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<p>Trend of resonant frequency change with temperature in sense mode.</p>
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<p>Trend of quality factor change with temperature in sense mode.</p>
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<p>Closed-loop drive circuit test of zero bias of microgyroscope at normal temperature.</p>
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440 KiB  
Article
A CMOS-Compatible, Low-Noise ISFET Based on High Efficiency Ion-Modulated Lateral-Bipolar Conduction
by Sheng-Ren Chang and Hsin Chen
Sensors 2009, 9(10), 8336-8348; https://doi.org/10.3390/s91008336 - 21 Oct 2009
Cited by 17 | Viewed by 15384
Abstract
Ion-sensitive, field-effect transistors (ISFET) have been useful biosensors in many applications. However, the signal-to-noise ratio of the ISFET is limited by its intrinsic, low-frequency noise. This paper presents an ISFET capable of utilizing lateral-bipolar conduction to reduce low-frequency noise. With a particular layout [...] Read more.
Ion-sensitive, field-effect transistors (ISFET) have been useful biosensors in many applications. However, the signal-to-noise ratio of the ISFET is limited by its intrinsic, low-frequency noise. This paper presents an ISFET capable of utilizing lateral-bipolar conduction to reduce low-frequency noise. With a particular layout design, the conduction efficiency is further enhanced. Moreover, the ISFET is compatible with the standard CMOS technology. All materials above the gate-oxide are removed by simple, die-level post-CMOS process, allowing ions to modulate the lateral-bipolar current directly. By varying the gate-to-bulk voltage, the operation mode of the ISFET is controlled effectively, so is the noise performance measured and compared. Finally, the biasing conditions preferable for different low-noise applications are identified. Under the identified biasing condition, the signal-to-noise ratio of the ISFET as a pH sensor is proved to be improved by more than five times. Full article
(This article belongs to the Special Issue ISFET Sensors)
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Graphical abstract

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<p>(a) The layout of the proposed ISFET (b) The cross-sectional view before the post-CMOS process (c) The cross-sectional view after the post-CMOS process.</p>
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<p>(a) The chip containing the testkeys of the proposed ISFET; (b) The packaged chip after post-CMOS process; (c) The schematic of the noise measurement system.</p>
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<p>The biasing circuits for the ISFET to function as a pH sensor. (a) The ISFET operates in MOS mode (b) The ISFET operates in the LBJT or the hybrid mode.</p>
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<p>(a) Sensor without post-CMOS process (b) Sensor after post-CMOS process.</p>
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<p>(a) The measured <span class="html-italic">I<sub>D</sub>-V<sub>SB</sub></span> characteristics of the ISFET for various <span class="html-italic">V<sub>GB</sub></span>. (b) The measured efficiency (<span class="html-italic">I<sub>D</sub>/I<sub>S</sub></span>) against <span class="html-italic">V<sub>GB</sub></span> of the ISFET when <span class="html-italic">I<sub>S</sub></span> is fixed at 10 μA. Operation modes are changed from MOS mode to the LBJT mode by increasing the gate voltage.</p>
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<p>The measured (a) <span class="html-italic">g<sub>m</sub>-V<sub>GB</sub></span> (b) <span class="html-italic">g<sub>m</sub>-I<sub>D</sub></span> of the ISFET for various <span class="html-italic">V<sub>SB</sub></span>.</p>
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<p>Noise measured with various V<sub>GB</sub> as the ISFET was biased with a constant <span class="html-italic">I<sub>D</sub></span>. (a) noise power spectral density (b) mean-square noise voltage integrated from 10 to 10 kHz</p>
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<p>Noise measured with various V<sub>GB</sub> as the ISFET was biased with a constant <span class="html-italic">g<sub>m</sub></span>. (a) noise power spectral density (b) mean-square noise current integrated from 10 to 10 kHz.</p>
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<p>The measured responses of <span class="html-italic">V<sub>S</sub></span> to solutions with different pH values as the ISFET was biased in the MOS mode (red) and in the hybrid mode (black).</p>
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453 KiB  
Review
Turbidimeter Design and Analysis: A Review on Optical Fiber Sensors for the Measurement of Water Turbidity
by Ahmad Fairuz Bin Omar and Mohd Zubir Bin MatJafri
Sensors 2009, 9(10), 8311-8335; https://doi.org/10.3390/s91008311 - 20 Oct 2009
Cited by 144 | Viewed by 31093
Abstract
Turbidimeters operate based on the optical phenomena that occur when incident light through water body is scattered by the existence of foreign particles which are suspended within it. This review paper elaborates on the standards and factors that may influence the measurement of [...] Read more.
Turbidimeters operate based on the optical phenomena that occur when incident light through water body is scattered by the existence of foreign particles which are suspended within it. This review paper elaborates on the standards and factors that may influence the measurement of turbidity. The discussion also focuses on the optical fiber sensor technologies that have been applied within the lab and field environment and have been implemented in the measurement of water turbidity and concentration of particles. This paper also discusses and compares results from three different turbidimeter designs that use various optical components. Mohd Zubir and Bashah and Daraigan have introduced a design which has simple configurations. Omar and MatJafri, on the other hand, have established a new turbidimeter design that makes use of optical fiber cable as the light transferring medium. The application of fiber optic cable to the turbidimeter will present a flexible measurement technique, allowing measurements to be made online. Scattered light measurement through optical fiber cable requires a highly sensitive detector to interpret the scattered light signal. This has made the optical fiber system have higher sensitivity in measuring turbidity compared to the other two simple turbidimeters presented in this paper. Fiber optic sensors provide the potential for increased sensitivity over large concentration ranges. However, many challenges must be examined to develop sensors that can collect reliable turbidity measurements in situ. Full article
(This article belongs to the Section Chemical Sensors)
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<p>Turbidity Measuring Techniques.</p>
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<p>Rayleigh scattering and Mie scattering cross section vs wavelength for particle size of 0.0285 μm and 0.2615 μm, respectively [<a href="#b31-sensors-09-08311" class="html-bibr">31</a>].</p>
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<p>Configurations for (a) PCOS and FIT Experimental Setup (b) Two Adjacent Linear Fibers Layers (c) Bundled Fibers [<a href="#b15-sensors-09-08311" class="html-bibr">15</a>,<a href="#b18-sensors-09-08311" class="html-bibr">18</a>].</p>
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<p>Schematic design of a simple turbidimeter [<a href="#b50-sensors-09-08311" class="html-bibr">50</a>].</p>
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<p>(a) and (b). Results from the experiment conducted by Mohd Zubir and Bashah [<a href="#b50-sensors-09-08311" class="html-bibr">50</a>].</p>
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<p>(a) Experimental setup for the measurement of light transmittance and 90° scattering; (b) Experimental setup for the measurement of surface reflectance [<a href="#b10-sensors-09-08311" class="html-bibr">10</a>].</p>
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<p>Detector Circuit Design [<a href="#b51-sensors-09-08311" class="html-bibr">51</a>].</p>
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<p>Illustration of Overall Design Concept [<a href="#b54-sensors-09-08311" class="html-bibr">54</a>].</p>
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<p>System Response Test for (a) BLUE System (b) RED System.</p>
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1292 KiB  
Article
Cross-Layer Active Predictive Congestion Control Protocol for Wireless Sensor Networks
by Jiangwen Wan, Xiaofeng Xu, Renjian Feng and Yinfeng Wu
Sensors 2009, 9(10), 8278-8310; https://doi.org/10.3390/s91008278 - 20 Oct 2009
Cited by 18 | Viewed by 12040
Abstract
In wireless sensor networks (WSNs), there are numerous factors that may cause network congestion problems, such as the many-to-one communication modes, mutual interference of wireless links, dynamic changes of network topology and the memory-restrained characteristics of nodes. All these factors result in a [...] Read more.
In wireless sensor networks (WSNs), there are numerous factors that may cause network congestion problems, such as the many-to-one communication modes, mutual interference of wireless links, dynamic changes of network topology and the memory-restrained characteristics of nodes. All these factors result in a network being more vulnerable to congestion. In this paper, a cross-layer active predictive congestion control scheme (CL-APCC) for improving the performance of networks is proposed. Queuing theory is applied in the CL-APCC to analyze data flows of a single-node according to its memory status, combined with the analysis of the average occupied memory size of local networks. It also analyzes the current data change trends of local networks to forecast and actively adjust the sending rate of the node in the next period. In order to ensure the fairness and timeliness of the network, the IEEE 802.11 protocol is revised based on waiting time, the number of the node‟s neighbors and the original priority of data packets, which dynamically adjusts the sending priority of the node. The performance of CL-APCC, which is evaluated by extensive simulation experiments. is more efficient in solving the congestion in WSNs. Furthermore, it is clear that the proposed scheme has an outstanding advantage in terms of improving the fairness and lifetime of networks. Full article
(This article belongs to the Section Chemical Sensors)
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<p>Grid definition.</p>
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<p>The data flow in the node.</p>
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<p>The relationship between inputting and outputting rate of node.</p>
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<p>The flow chart of the stable state M/M/1/m.</p>
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<p>The pseudo-code for single-node rate control method.</p>
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<p>Flow framework of system-level control method.</p>
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<p>The pseudo-code for local network (grid) rate control method.</p>
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<p>Neighbors in the communication range of one node.</p>
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<p>The pseudo-code for the revised IEEE 802.11 protocol.</p>
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198 KiB  
Communication
Fluorescence Enhancement of Fluorescein Isothiocyanate-Labeled Protein A Caused by Affinity Binding with Immunoglobulin G in Bovine Plasma
by Takehito Ogawa, Satoka Aoyagi, Takehiro Miyasaka and Kiyotaka Sakai
Sensors 2009, 9(10), 8271-8277; https://doi.org/10.3390/s91008271 - 20 Oct 2009
Cited by 16 | Viewed by 13084
Abstract
Fluorescence enhancement of fluorescein isothiocyanate-labeled protein A (FITC-protein A) caused by the binding with immunoglobulin G (IgG) in bovine plasma was studied. FITC-protein A was immobilized onto a glass surface by covalent bonds. An increase in fluorescence intensity was dependent on IgG concentration [...] Read more.
Fluorescence enhancement of fluorescein isothiocyanate-labeled protein A (FITC-protein A) caused by the binding with immunoglobulin G (IgG) in bovine plasma was studied. FITC-protein A was immobilized onto a glass surface by covalent bonds. An increase in fluorescence intensity was dependent on IgG concentration ranging from 20 to 78 μg/mL in both phosphate buffer saline and bovine plasma. This method requires no separation procedure, and the reaction time is less than 15 min. A fluorescence enhancement assay by the affinity binding of fluorescence-labeled reagent is thus available for the rapid determination of biomolecules in plasma. Full article
(This article belongs to the Section Biosensors)
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<p>Experimental setup for measurement of fluorescence intensity.</p>
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<p>Fluorescence spectrum of immobilized FITC-Protein A. Line ‘a’ is spectrum of bovine plasma without FITC-Protein A immobilized glass, Line ‘b’ is spectrum of immobilized FITC-Protein A immersed in bovine plasma, Line ‘c’ is enhanced fluorescence spectrum at 78 μg/mL IgG in bovine plasma.</p>
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<p>Dependency of relative fluorescence intensity on IgG concentration. Black circles denote FITC-protein A immobilized glass in bovine plasma, White circles denote FITC-protein A immobilized glass in PBS, Gray triangles denote plasma solution without glass for blank test.</p>
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<p>Procedure for immobilization of FITC-labeled protein A.</p>
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256 KiB  
Article
Major Improvements of Quartz Crystal Pulling Sensitivity and Linearity Using Series Reactance
by Vojko Matko and Riko Šafarič
Sensors 2009, 9(10), 8263-8270; https://doi.org/10.3390/s91008263 - 19 Oct 2009
Cited by 22 | Viewed by 10695
Abstract
This paper presents a new method of substantially improving frequency pullability and linearity using reactance in series with an AT fundamental crystal operated with a series load capacitance in the range of 3 to 50 pF and frequencies in the range of 3.5 [...] Read more.
This paper presents a new method of substantially improving frequency pullability and linearity using reactance in series with an AT fundamental crystal operated with a series load capacitance in the range of 3 to 50 pF and frequencies in the range of 3.5 to 21 MHz. The research describes high quartz pullability and linearity by varying the load capacitance. The paper also gives impedance circuits for crystal unit (3.5 MHz) together with load capacitance and compensation reactance. The experimental results show that the new approach using compensation method of quartz crystal connected in series reactance increases the frequency pulling range by ×25 to ×100 depending on the type of oscillator and compensation factor ˝k˝ in the temperature range of 10 to 40 °C. Full article
(This article belongs to the Special Issue Sensor Configuration and Smart Sensors)
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<p>Load capacitance C<sub>z</sub> and compensation impedance Z<sub>pw</sub> = j·ω·L<sub>pw</sub> + R<sub>pw</sub> in series with the quartz crystal equivalent circuit.</p>
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<p>Quartz crystal pulling sensitivity from 3 to 50 pF.</p>
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<p>Quartz crystal pulling and linearization for k = 1, 2, 3 in the range C<sub>z</sub> = 3–50 pF.</p>
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<p>Compensated quartz impedance (C<sub>o</sub>) for different k = 1, 2, 3 (Ω = 0.998, 0.99802…1.038).</p>
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1532 KiB  
Review
Breath Analysis Using Laser Spectroscopic Techniques: Breath Biomarkers, Spectral Fingerprints, and Detection Limits
by Chuji Wang and Peeyush Sahay
Sensors 2009, 9(10), 8230-8262; https://doi.org/10.3390/s91008230 - 19 Oct 2009
Cited by 526 | Viewed by 33998
Abstract
Breath analysis, a promising new field of medicine and medical instrumentation, potentially offers noninvasive, real-time, and point-of-care (POC) disease diagnostics and metabolic status monitoring. Numerous breath biomarkers have been detected and quantified so far by using the GC-MS technique. Recent advances in laser [...] Read more.
Breath analysis, a promising new field of medicine and medical instrumentation, potentially offers noninvasive, real-time, and point-of-care (POC) disease diagnostics and metabolic status monitoring. Numerous breath biomarkers have been detected and quantified so far by using the GC-MS technique. Recent advances in laser spectroscopic techniques and laser sources have driven breath analysis to new heights, moving from laboratory research to commercial reality. Laser spectroscopic detection techniques not only have high-sensitivity and high-selectivity, as equivalently offered by the MS-based techniques, but also have the advantageous features of near real-time response, low instrument costs, and POC function. Of the approximately 35 established breath biomarkers, such as acetone, ammonia, carbon dioxide, ethane, methane, and nitric oxide, 14 species in exhaled human breath have been analyzed by high-sensitivity laser spectroscopic techniques, namely, tunable diode laser absorption spectroscopy (TDLAS), cavity ringdown spectroscopy (CRDS), integrated cavity output spectroscopy (ICOS), cavity enhanced absorption spectroscopy (CEAS), cavity leak-out spectroscopy (CALOS), photoacoustic spectroscopy (PAS), quartz-enhanced photoacoustic spectroscopy (QEPAS), and optical frequency comb cavity-enhanced absorption spectroscopy (OFC-CEAS). Spectral fingerprints of the measured biomarkers span from the UV to the mid-IR spectral regions and the detection limits achieved by the laser techniques range from parts per million to parts per billion levels. Sensors using the laser spectroscopic techniques for a few breath biomarkers, e.g., carbon dioxide, nitric oxide, etc. are commercially available. This review presents an update on the latest developments in laser-based breath analysis. Full article
(This article belongs to the Special Issue Gas Sensors 2009)
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<p>Illustration of the CRDS concept. The effective absorption path-length is readily increased more than 10,000-fold in CRDS. With and without absorption the decay time constants (ringdown times) are different; a ringdown decay example is shown in the right.</p>
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<p>The combined time-domain and broadband ICOS spectra of the weak oxygen b-x (1,0) band is clearly seen. The broadband-ICOS spectrum can be recovered by doing a linear integration along a line at any constant height (the time axis in the Spectral Photography image) (reproduced with permission from the Optical Society of America [<a href="#b37-sensors-09-08230" class="html-bibr">37</a>]).</p>
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<p>Schematic of photoacoustic spectroscopy.</p>
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<p>Schematic of the cavity-enhanced direct-frequency-comb spectrometer, along with the gas handling system for breath analysis (reproduced with permission from the Optical Society of America [<a href="#b50-sensors-09-08230" class="html-bibr">50</a>]).</p>
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<p>A prototype acetone breath analyzer using pulsed-CRDS at 266 nm. Left: The instrumental package; right: Detailed pictorial view of the optical cavity configuration.</p>
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<p>Typical measurement of single-breath concentrations of C<sub>2</sub>H<sub>6</sub>, CO<sub>2</sub>, and O<sub>2</sub>. Each single expiration is analyzed separately. Only 160 s are displayed in the 360–520 s time windown. The complete measurement took 42 min. (Reproduced with permission from Spinger Link [<a href="#b45-sensors-09-08230" class="html-bibr">45</a>]).</p>
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507 KiB  
Article
Sensor Calibration Based on Incoherent Optical Fiber Bundles (IOFB) Used For Remote Image Transmission
by José L. Lázaro, Pedro R. Fernández, Alfredo Gardel, Angel E. Cano and Carlos A. Luna
Sensors 2009, 9(10), 8215-8229; https://doi.org/10.3390/s91008215 - 19 Oct 2009
Cited by 7 | Viewed by 15838
Abstract
Image transmission using incoherent optical fiber bundles (IOFB) requires prior calibration to obtain the spatial in-out fiber correspondence in order to reconstruct the image captured by the pseudo-sensor. This information is recorded in a Look-Up Table (LUT), used later for reordering the fiber [...] Read more.
Image transmission using incoherent optical fiber bundles (IOFB) requires prior calibration to obtain the spatial in-out fiber correspondence in order to reconstruct the image captured by the pseudo-sensor. This information is recorded in a Look-Up Table (LUT), used later for reordering the fiber positions and reconstructing the original image. This paper presents a method based on line-scan to obtain the in-out correspondence. The results demonstrate that this technique yields a remarkable reduction in processing time and increased image quality by introducing a fiber detection algorithm, an intensity compensation process and finally, a single interpolation algorithm. Full article
(This article belongs to the Special Issue Image Sensors 2009)
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<p>System setup.</p>
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<p>Pattern images and the effect on the bundle. Sequential images (bars) on the calibration screen. Projection at the input face. Excited fibers at the output face.</p>
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<p>Scanning effect on the fibers.</p>
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<p>Calibration Procedure.</p>
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<p>Fiber response example depending on fiber covering and fringe step.</p>
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<p>Image Progression and details.</p>
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1408 KiB  
Article
A Distributed Sensor Network for the Control of a Bioclimatic House in Spain
by Álvaro Gutiérrez, Javier Jiménez-Leube and Luis Magdalena
Sensors 2009, 9(10), 8197-8214; https://doi.org/10.3390/s91008197 - 19 Oct 2009
Cited by 8 | Viewed by 13898
Abstract
The XXI century home should be a digital habitat, a connected residence, but at the same time it should be involved in sustainability and the environment. The location of new technologies at home, and its acceptance by the user, requires, among other actions, [...] Read more.
The XXI century home should be a digital habitat, a connected residence, but at the same time it should be involved in sustainability and the environment. The location of new technologies at home, and its acceptance by the user, requires, among other actions, a significant diffusion and activity to be undertaken. This work proposes the development of a Smart House network designed for its integration into a sustainable and bioclimatic solar house. The paper focuses on a specific aspect of the house design, the control system bus, developed for the management of the different parameters, variables, sensors and actuators which coexist at home. Finally, the system has been installed in a laboratory bioclimatic house. Environmental variable experiments based on the control of passive elements, such as phase shift gels, are presented. Experimental results show that the system is able to benefit from the bioclimatic elements in the house by taking into account the user preferences. Full article
(This article belongs to the Special Issue State-of-the-Art Sensors Technology in Spain)
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Graphical abstract

Graphical abstract
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<p>The bioclimatic solar house. (a) Bird's eye view. (b) South facade.</p>
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<p>The bioclimatic solar house. (a) Bird's eye view. (b) South facade.</p>
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<p>The false floor elements in the house.</p>
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<p>The false floor elements in the house.</p>
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<p>Temperature control in a summer (a) night and (b) day.</p>
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<p>Temperature control in a summer (a) night and (b) day.</p>
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<p>(a) The <span class="html-italic">NOD485</span>. (b) The functional architecture of the <span class="html-italic">NOD485</span>.</p>
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<p>(a) The <span class="html-italic">NOD485</span>. (b) The functional architecture of the <span class="html-italic">NOD485</span>.</p>
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<p>Sensor and actuator boards designed for its used on the <span class="html-italic">NOD485</span>.</p>
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<p>A communication frame structure.</p>
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<p>The software architecture.</p>
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<p>The user interface. (a) Main menu and (b) controller menu.</p>
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<p>The user interface. (a) Main menu and (b) controller menu.</p>
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<p>Data monitoring interface. (a) A map-like approach. (b) A node list approach.</p>
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<p>Data monitoring interface. (a) A map-like approach. (b) A node list approach.</p>
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832 KiB  
Review
Semiconducting Metal Oxide Based Sensors for Selective Gas Pollutant Detection
by Sofian M. Kanan, Oussama M. El-Kadri, Imad A. Abu-Yousef and Marsha C. Kanan
Sensors 2009, 9(10), 8158-8196; https://doi.org/10.3390/s91008158 - 16 Oct 2009
Cited by 373 | Viewed by 29769
Abstract
A review of some papers published in the last fifty years that focus on the semiconducting metal oxide (SMO) based sensors for the selective and sensitive detection of various environmental pollutants is presented. Full article
(This article belongs to the Special Issue Metal-Oxide Based Nanosensors)
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<p>A general schematic for SMO gas sensor devices.</p>
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<p>Electrical response of sprayed SnO<sub>2</sub> thin films vs. NO<sub>2</sub> concentration at 350 °C working temperature. (Reprinted from reference [<a href="#b139-sensors-09-08158" class="html-bibr">139</a>] with permission from Elsevier).</p>
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<p>(a) Gas sensing characteristics of tungsten oxide nanoparticles to 1,000 ppm H<sub>2</sub>S, and (b) variations in response with concentration of H<sub>2</sub>S at 250 °C. (Reprinted from reference [<a href="#b165-sensors-09-08158" class="html-bibr">165</a>] with permission from Elsevier).</p>
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<p>SMO sensors' normalized responses to the gases of interest and corresponding LDA. (Reprinted from reference [<a href="#b13-sensors-09-08158" class="html-bibr">13</a>] with permission from Elsevier).</p>
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<p>Sensor response to a three pulse sequence of methanol, t-butanol and DMMP for samples A and C based sensors. (Reprinted from reference [<a href="#b285-sensors-09-08158" class="html-bibr">285</a>] with permission from Elsevier).</p>
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1424 KiB  
Article
Biomimetic Yeast Cell Typing—Application of QCMs
by Karin Seidler, Miroslava Polreichová, Peter A. Lieberzeit and Franz L. Dickert
Sensors 2009, 9(10), 8146-8157; https://doi.org/10.3390/s91008146 - 16 Oct 2009
Cited by 23 | Viewed by 13130
Abstract
Artificial antibodies represent a key factor in the generation of sensing systems for the selective detection of bioanalytes of variable sizes. With biomimetic surfaces, the important model organism Saccharomyces cerevisiae and several of its growth stages may be detected. Quartz crystal microbalances (QCM) [...] Read more.
Artificial antibodies represent a key factor in the generation of sensing systems for the selective detection of bioanalytes of variable sizes. With biomimetic surfaces, the important model organism Saccharomyces cerevisiae and several of its growth stages may be detected. Quartz crystal microbalances (QCM) with 10 MHz fundamental frequency and coated with polymers imprinted with synchronized yeast cells are presented, which are able to detect duplex cells with high selectivity. Furthermore, a multichannel quartz crystal microbalance (MQCM) was designed and optimized for the measurement in liquids. This one-chip system based on four-electrode geometry allows the simultaneous detection of four analytes and, thus, provides a monitoring system for biotechnology and process control. For further standardization of the method, synthetic stamps containing plastic yeast cells in different growth stages were produced and utilized for imprinting. Mass-sensitive measurements with such MIPs resulted in the same sensor characteristics as obtained for those imprinted with native yeast cells. Full article
(This article belongs to the Section Chemical Sensors)
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<p>Budding yeast (S. cerevisiae) in late S phase marked with the fluorochrome bisbenzimide (fluorescence microscopy).</p>
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<p>Imprinting procedure with synchronized yeast: cell suspension is dropped on PU-layer and spun at 2,500 rpm.</p>
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<p>AFM image (lateral dimensions 20 × 20 μm, vertical axis 5 μm) of duplex yeast cell in MIP and imprints of duplex cells (light microscopy, 20 × 25 μm).</p>
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<p>QCM responses of MIP exposed to single and duplex cells (1.17 × 10<sup>6</sup> cells/μL).</p>
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<p>Normalized selectivity pattern (reference: single cell) of single/duplex yeast MIP.</p>
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<p>QCM sensor characteristic of duplex cell MIP: 2.3 × 10<sup>5</sup>, 1.15 × 10<sup>5</sup>, 5.8 × 10<sup>4</sup> and 2.9 × 10<sup>4</sup> cells/μL, respectively.</p>
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<p>AFM image of an artificial yeast stamp (25 × 25 μm, vertical axis 5 μm) (a) and reflected-light microscopy (b) (125 × 100 μm). (c) AFM image MIP polyurethane resulting from artificial stamp.</p>
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<p>QCM sensor response of artificial stamp MIP exposed yeast at 3 × 10<sup>5</sup>, 1.5 × 10<sup>5</sup>, 8 × 10<sup>4</sup> and 9 × 10<sup>4</sup> cells/μL, respectively.</p>
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<p>AFM image and section analysis of a polyurethane MIP of an artificial stamp mimicking growing yeast cells showing grown species and some buds.</p>
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437 KiB  
Review
Magnetic Nanoparticle Sensors
by Isaac Koh and Lee Josephson
Sensors 2009, 9(10), 8130-8145; https://doi.org/10.3390/s91008130 - 16 Oct 2009
Cited by 283 | Viewed by 23406
Abstract
Many types of biosensors employ magnetic nanoparticles (diameter = 5–300 nm) or magnetic particles (diameter = 300–5,000 nm) which have been surface functionalized to recognize specific molecular targets. Here we cover three types of biosensors that employ different biosensing principles, magnetic materials, and [...] Read more.
Many types of biosensors employ magnetic nanoparticles (diameter = 5–300 nm) or magnetic particles (diameter = 300–5,000 nm) which have been surface functionalized to recognize specific molecular targets. Here we cover three types of biosensors that employ different biosensing principles, magnetic materials, and instrumentation. The first type consists of magnetic relaxation switch assay-sensors, which are based on the effects magnetic particles exert on water proton relaxation rates. The second type consists of magnetic particle relaxation sensors, which determine the relaxation of the magnetic moment within the magnetic particle. The third type is magnetoresistive sensors, which detect the presence of magnetic particles on the surface of electronic devices that are sensitive to changes in magnetic fields on their surface. Recent improvements in the design of magnetic nanoparticles (and magnetic particles), together with improvements in instrumentation, suggest that magnetic material-based biosensors may become widely used in the future. Full article
(This article belongs to the Special Issue Nanotechnological Advances in Biosensors)
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<p>Principle of Type I MRSws. Dispersed magnetic nanoparticles (NPs) form an aggregate upon binding with target analytes (triangle). The aggregated form of the NPs dephases the spins of the surrounding protons of water molecules more efficiently than NPs present as the dispersed state. The effect is observed as a decrease in spin-spin relaxation time, T<sub>2</sub> (reproduced with permission from reference [<a href="#b52-sensors-09-08130" class="html-bibr">52</a>]).</p>
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<p>Methods for the improvement in MRSw assay sensitivities. (A) MPs (●) aggregate in a homogeneous magnetic field, whereas NPs (□) do not respond. A T<sub>2</sub> increase in time is observed in a 0.47 T field (gray) in an MP solution, but not in an NP solution. The T<sub>2</sub> value of the MP solution decreases as the MPs are dispersed with the field turn-off (white). Note that a T<sub>2</sub> increase is observed with MP aggregation. (type II MRSw). Since this effect is slowed by the viscosity of the medium, T<sub>2</sub>-based viscometer can be obtained, see [<a href="#b7-sensors-09-08130" class="html-bibr">7</a>]. (B) Three strategies for enhancing the sensitivities with a type II MRSw assay. (a) A decreased concentration of MPs formed aggregates at a lower concentration of analyte (anti-Tag antibody) than that of NPs. MPs are larger than NPs and used at a lower concentration. (b) Application of a magnetic field (0.47 T) induced aggregation of MPs as in (A) and accelerated the interaction between MPs and analytes. (c) Target valency enhancement by addition of a secondary antibody (sheep anti-mouse). The valency increase of targets from two (anti Tag) to four (anti Tag:anti mouse) enhanced MRSw sensitivities. Figure reproduced with permission from reference [<a href="#b6-sensors-09-08130" class="html-bibr">6</a>].</p>
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<p>(A). Schematic representation of a miniaturized chip-based NMR system, diagnostic magnetic resonance (DMR). (B). NMR based CMOS RF biosensor. A complete NMR system was built with a portable platform (reproduced with permission (A) from reference [<a href="#b10-sensors-09-08130" class="html-bibr">10</a>] and (B) from reference [<a href="#b21-sensors-09-08130" class="html-bibr">21</a>]).</p>
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<p>Principle of a SQUID-based homogeneous detector of bacteria. A. A pulse-form magnetic field orients the magnetic moments of NPs. B. After the field pulse is over, Brownian motion randomizes the magnetic moments of unbound NPs. However, the Brownian rotations of NPs bound to the bacteria are restricted. The bound NPs undergo Néel relaxation for reorientation of the magnetic moments. The SQUID detects the slower Néel relaxation for the bound NPs (reproduced with permission from reference [<a href="#b36-sensors-09-08130" class="html-bibr">36</a>]).</p>
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<p>A schematic representation of a giant magnetoresistive (GMR) sensor for an ELISA-type protein assay. A. The probe surface was functionalized with a specific antibody, while the control surface was passivated with BSA. B. A sample solution was added for a specific binding of analyte proteins to the probe surface. C. A biotinylated antibody bound to the surface-immobilized analytes. D. Finally streptavidin-coated NPs were added for tagging the probe surface by biotin-streptavidin interaction. GMR signals were detected for sensing the presence of analytes on the surface. Courtesy from [<a href="#b48-sensors-09-08130" class="html-bibr">48</a>].</p>
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143 KiB  
Editorial
Guest Editor’s Concluding Remarks―Advances in Usage of ANN, Discussion of an Unsolved Problem, and Some Differences between Papers Written by Engineers and by Physicians
by Michael W. Retsky
Sensors 2009, 9(10), 8126-8129; https://doi.org/10.3390/s91008126 - 16 Oct 2009
Viewed by 13114
Abstract
I take this opportunity to discuss a few things that I have learned from being Guest Editor of this special issue of Sensors devoted to Neural Networks and Sensors. The advancement in artificial neural network (ANN) technology is very impressive. The wide variety [...] Read more.
I take this opportunity to discuss a few things that I have learned from being Guest Editor of this special issue of Sensors devoted to Neural Networks and Sensors. The advancement in artificial neural network (ANN) technology is very impressive. The wide variety of fields in which this technology applies in the form of practical applications to clearly identifiable real problems demonstrates that ANNs are being routinely used to solve non-trivial problems. I mention that because A. K. Dewdney wrote in 1997 that while ANNs have been used to solve a few toy problems, he was surprised that anyone takes them seriously as general problem-solving tools [1]. The ANN applications reported by Yu Liu et al. [2], Erkan Beşdok [3], Guillermo Zatorre et al. [4], Amir Jabbari et al. [5], Mohamed Lamine Hafiane et al. [6], Kai-Wei Chiang et al. [7], Raúl Vicen-Bueno et al. [8], Juan L. Pedreño-Molina et al. [9], and P. B. Garcia-Allende et al. [10] are far more than toy applications. The lesson to be learned here is that it is a bad idea to publically bet against technological progress in computer applications. [...] Full article
(This article belongs to the Special Issue Neural Networks and Sensors)
161 KiB  
Article
Neural Network Emulation of the Integral Equation Model with Multiple Scattering
by Luca Pulvirenti, Francesca Ticconi and Nazzareno Pierdicca
Sensors 2009, 9(10), 8109-8125; https://doi.org/10.3390/s91008109 - 15 Oct 2009
Cited by 3 | Viewed by 11976
Abstract
The Integral Equation Model with multiple scattering (IEMM) represents a well-established method that provides a theoretical framework for the scattering of electromagnetic waves from rough surfaces. A critical aspect is the long computational time required to run such a complex model. To deal [...] Read more.
The Integral Equation Model with multiple scattering (IEMM) represents a well-established method that provides a theoretical framework for the scattering of electromagnetic waves from rough surfaces. A critical aspect is the long computational time required to run such a complex model. To deal with this problem, a neural network technique is proposed in this work. In particular, we have adopted neural networks to reproduce the backscattering coefficients predicted by IEMM at L- and C-bands, thus making reference to presently operative satellite radar sensors, i.e., that aboard ERS-2, ASAR on board ENVISAT (C-band), and PALSAR aboard ALOS (L-band). The neural network-based model has been designed for radar observations of both flat and tilted surfaces, in order to make it applicable for hilly terrains too. The assessment of the proposed approach has been carried out by comparing neural network-derived backscattering coefficients with IEMM-derived ones. Different databases with respect to those employed to train the networks have been used for this purpose. The outcomes seem to prove the feasibility of relying on a neural network approach to efficiently and reliably approximate an electromagnetic model of surface scattering. Full article
(This article belongs to the Special Issue Neural Networks and Sensors)
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<p>The Neural Network architectures. Upper panel: NN topology for the nominal incidence angle (<span class="html-italic">N<sub>i</sub></span> = 3, <span class="html-italic">N<sub>h</sub></span><sub>1</sub> = 15, <span class="html-italic">N<sub>h</sub></span><sub>2</sub> = 10, <span class="html-italic">N<sub>o</sub></span> = 2); lower panel: NN topology for incidence angle assumed as an additional input parameter (<span class="html-italic">N<sub>i</sub></span> = 4, <span class="html-italic">N<sub>h</sub></span><sub>1</sub> = 30, <span class="html-italic">N<sub>h</sub></span><sub>2</sub> = 25, <span class="html-italic">N<sub>o</sub></span> = 2).</p>
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<p>Comparison between IEMM- and NN-derived <span class="html-italic">σ</span><sup>0</sup> (test sets of 500 records). Left panels: vertical polarization; right panels: horizontal polarization. Upper panels: L-band; lower panels: C-band. Dotted lines represent perfect agreement.</p>
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<p>Comparison between IEMM- and NN-derived <span class="html-italic">σ</span><sup>0</sup> (test sets of 500 records). Left panels: vertical polarization; right panels: horizontal polarization. Upper panels: L-band; lower panels: C-band. Dotted lines represent perfect agreement.</p>
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<p>Trend of the <span class="html-italic">rmse</span> (error bars) versus <span class="html-italic">k</span><sub>0</sub><span class="html-italic">s</span>. Left panels: vertical polarization; right panels: horizontal polarization. Upper panels: L-band; lower panels: C-band.</p>
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<p>Same as <a href="#f2-sensors-09-08109" class="html-fig">Figure 2</a>, but for <span class="html-italic">θ<sub>i</sub></span> assumed as an additional input parameter (test sets of 4,000 records).</p>
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<p>Same as <a href="#f2-sensors-09-08109" class="html-fig">Figure 2</a>, but for <span class="html-italic">θ<sub>i</sub></span> assumed as an additional input parameter (test sets of 4,000 records).</p>
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<p>Same as <a href="#f3-sensors-09-08109" class="html-fig">Figure 3</a>, but for <span class="html-italic">θ<sub>i</sub></span> assumed as an additional input parameter.</p>
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350 KiB  
Article
Efficient Aggregation of Multiple Classes of Information in Wireless Sensor Networks
by Xiaoling Qiu, Haiping Liu, Deshi Li, Jennifer Yick, Dipak Ghosal and Biswanath Mukherjee
Sensors 2009, 9(10), 8083-8108; https://doi.org/10.3390/s91008083 - 14 Oct 2009
Cited by 11 | Viewed by 16527
Abstract
Congestion in a Wireless Sensor Network (WSN) can lead to buffer overflow, resource waste and delay or loss of critical information from the sensors. In this paper, we propose the Priority-based Coverage-aware Congestion Control (PCC) algorithm which is distributed, priority-distinct, and [...] Read more.
Congestion in a Wireless Sensor Network (WSN) can lead to buffer overflow, resource waste and delay or loss of critical information from the sensors. In this paper, we propose the Priority-based Coverage-aware Congestion Control (PCC) algorithm which is distributed, priority-distinct, and fair. PCC provides higher priority to packets with event information in which the sink is more interested. PCC employs a queue scheduler that can selectively drop any packet in the queue. PCC gives fair chance to all sensors to send packets to the sink, irrespective of their specific locations, and therefore enhances the coverage fidelity of theWSN. Based on a detailed simulation analysis, we show that PCC can efficiently relieve congestion and significantly improve the system performance based on multiple metrics such as event throughput and coverage fidelity. We generalize PCC to address data collection in a WSN in which the sensor nodes have multiple sensing devices and can generate multiple types of information. We propose a Pricing System that can under congestion effectively collect different types of data generated by the sensor nodes according to values that are placed on different information by the sink. Simulation analysis show that our Pricing System can achieve higher event throughput for packets with higher priority and achieve fairness among different categories. Moreover, given a fixed system capacity, our proposed Pricing System can collect more information of the type valued by the sink. Full article
(This article belongs to the Special Issue Wireless Sensor Technologies and Applications)
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Graphical abstract

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<p>Collection of multiple classes of information in a WSN.</p>
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<p>The overall system model.</p>
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<p>Queue scheduler that allows dropping intermediate packets.</p>
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<p>A block diagram illustrating the overall structure of <span class="html-italic">PCC</span>.</p>
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<p>Candidate <span class="html-italic">F<sub>N</sub></span>(<span class="html-italic">N</span>) and <span class="html-italic">d<sub>E</sub></span>(<span class="html-italic">N</span>) functions.</p>
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<p>System throughput.</p>
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<p>Avgerage end-to-end delay.</p>
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<p>Jain's fairness of the different schemes.</p>
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<p>End-to-end delay for the three different functions for implementing <span class="html-italic">F<sub>E</sub></span>(<span class="html-italic">N</span>)</p>
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70 KiB  
Article
Identification of Tea Storage Times by Linear Discrimination Analysis and Back-Propagation Neural Network Techniques Based on the Eigenvalues of Principal Components Analysis of E-Nose Sensor Signals
by Huichun Yu, Yongwei Wang and Jun Wang
Sensors 2009, 9(10), 8073-8082; https://doi.org/10.3390/s91008073 - 14 Oct 2009
Cited by 50 | Viewed by 13904
Abstract
An electronic nose (E-nose) was employed to detect the aroma of green tea after different storage times. Longjing green tea dry leaves, beverages and residues were detected with an E-nose, respectively. In order to decrease the data dimensionality and optimize the feature vector, [...] Read more.
An electronic nose (E-nose) was employed to detect the aroma of green tea after different storage times. Longjing green tea dry leaves, beverages and residues were detected with an E-nose, respectively. In order to decrease the data dimensionality and optimize the feature vector, the E-nose sensor response data were analyzed by principal components analysis (PCA) and the five main principal components values were extracted as the input for the discrimination analysis. The storage time (0, 60, 120, 180 and 240 days) was better discriminated by linear discrimination analysis (LDA) and was predicted by the back-propagation neural network (BPNN) method. The results showed that the discrimination and testing results based on the tea leaves were better than those based on tea beverages and tea residues. The mean errors of the tea leaf data were 9, 2.73, 3.93, 6.33 and 6.8 days, respectively. Full article
(This article belongs to the Section Chemical Sensors)
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<p>The response curve of tea leaves, tea brew and tea residue.</p>
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<p>Discrimination and testing result of LDA based on the tea leaves.</p>
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<p>Discrimination and testing result of LDA based on the tea beverages.</p>
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<p>Discrimination and testing result of LDA based on the tea residues.</p>
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2061 KiB  
Article
A Radio-Aware Routing Algorithm for Reliable Directed Diffusion in Lossy Wireless Sensor Networks
by Yong-Pyo Kim, Euihyun Jung and Yong-Jin Park
Sensors 2009, 9(10), 8047-8072; https://doi.org/10.3390/s91008047 - 13 Oct 2009
Cited by 7 | Viewed by 14388
Abstract
In Wireless Sensor Networks (WSNs), transmission errors occur frequently due to node failure, battery discharge, contention or interference by objects. Although Directed Diffusion has been considered as a prominent data-centric routing algorithm, it has some weaknesses due to unexpected network errors. In order [...] Read more.
In Wireless Sensor Networks (WSNs), transmission errors occur frequently due to node failure, battery discharge, contention or interference by objects. Although Directed Diffusion has been considered as a prominent data-centric routing algorithm, it has some weaknesses due to unexpected network errors. In order to address these problems, we proposed a radio-aware routing algorithm to improve the reliability of Directed Diffusion in lossy WSNs. The proposed algorithm is aware of the network status based on the radio information from MAC and PHY layers using a cross-layer design. The cross-layer design can be used to get detailed information about current status of wireless network such as a link quality or transmission errors of communication links. The radio information indicating variant network conditions and link quality was used to determine an alternative route that provides reliable data transmission under lossy WSNs. According to the simulation result, the radio-aware reliable routing algorithm showed better performance in both grid and random topologies with various error rates. The proposed solution suggested the possibility of providing a reliable transmission method for QoS requests in lossy WSNs based on the radio-awareness. The energy and mobility issues will be addressed in the future work. Full article
(This article belongs to the Special Issue Sensor Algorithms)
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<p>The communication flow of Directed Diffusion.</p>
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<p>The node selection scheme of the proposed algorithm.</p>
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<p>The flow chart of fast re-route scheme.</p>
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<p>The topology used in the simulation (i.e., error rate: 10%). <b>(a)</b> Grid topology, <b>(b)</b> Random topology.</p>
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<p>Performance comparison based on error rate in grid topology (0%, 5%, 10%, 15%, 20%). (a) Data delivery rate, (b) Protocol overhead, (c) Total number of packets.</p>
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<p>Performance comparison based on error rate in grid topology (0%, 5%, 10%, 15%, 20%). (a) Data delivery rate, (b) Protocol overhead, (c) Total number of packets.</p>
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<p>The average transmission delay for each error rate in grid topology (0%, 5%, 10%, 15%, 20%).</p>
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<p>Performance comparison for each error rate in random topology (0%, 5%, 10%, 15%, 20%). (a) Packet delivery rate, (b) Protocol overhead, (c) Total number of packets.</p>
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<p>Performance comparison for each error rate in random topology (0%, 5%, 10%, 15%, 20%). (a) Packet delivery rate, (b) Protocol overhead, (c) Total number of packets.</p>
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<p>The average transmission delay for each error rate in random topology (5%, 10%, 15%, 20%).</p>
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<p>The topology used in the simulation for different MCP including multiple sources with different sink position (i.e., error rate: 10%) <b>(a)</b> Arrow type, <b>(b)</b> Cross (X) type, <b>(c)</b> Diamond type.</p>
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746 KiB  
Article
Fabrication of Poly(p-Phenylene)/Zeolite Composites and Their Responses Towards Ammonia
by Pimchanok Phumman, Sumonman Niamlang and Anuvat Sirivat
Sensors 2009, 9(10), 8031-8046; https://doi.org/10.3390/s91008031 - 13 Oct 2009
Cited by 22 | Viewed by 12912
Abstract
Poly(p-phenylene) (PPP) was chemically synthesized via oxidative polymerization using benzene and doped with FeCl3. The electrical conductivity response of the doped PPP (dPPP) towards CO, H2 and NH3 is investigated. dPPP shows no electrical conductivity response towards [...] Read more.
Poly(p-phenylene) (PPP) was chemically synthesized via oxidative polymerization using benzene and doped with FeCl3. The electrical conductivity response of the doped PPP (dPPP) towards CO, H2 and NH3 is investigated. dPPP shows no electrical conductivity response towards the first two gases (CO and H2), but it shows a definite negative response towards NH3. The electrical conductivity sensitivity of dPPP increases linearly with increasing NH3 concentration. To improve the sensitivity of the sensor towards NH3, ZSM-5 zeolite is added into the conductive polymer matrix. The electrical sensitivity of the sensor increases with increasing zeolite content up to 30%. The effect of the type of cation in the zeolite pores is investigated: namely, Na+, K+, NH4+ and H+. The electrical conductivity sensitivity of the composites with different cations in the zeolite can be arranged in this order: K+ < no zeolite < Na+ < NH4+ < H+. The variation in electrical sensitivity with cation type can be described in terms of the acid-base interaction, the zeolite pore size and surface area. The PPP/Zeolite composite with H+ possesses the highest electrical sensitivity of −0.36 since H+ has the highest acidity, the highest pore volume and surface area, which combine to induce a more favorable NH3 adsorption and interaction with the conductive polymer. Full article
(This article belongs to the Section Chemical Sensors)
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<p>NH<sub>3</sub>-TPD thermograms of ZSM-5(23) of various cation types.</p>
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<p>Morphology of dPPP particles, ZSM-5(23) powder, and dPPP(%v/v)/zeolite composites: a) 50:1dPPP at 1000×; b) ZSM-5(23) at 1500×; c) 50:1dPPP(90)/NaZ23 at 1000×; d) 50:1dPPP(80)/NaZ23 at 1000×; e) 50:1dPPP(70)/NaZ23 at 1000×; and f) 50:1dPPP(60)/NaZ23 at 1000×.</p>
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<p>Morphology of dPPP particles, ZSM-5(23) powder, and dPPP(%v/v)/zeolite composites: a) 50:1dPPP at 1000×; b) ZSM-5(23) at 1500×; c) 50:1dPPP(90)/NaZ23 at 1000×; d) 50:1dPPP(80)/NaZ23 at 1000×; e) 50:1dPPP(70)/NaZ23 at 1000×; and f) 50:1dPPP(60)/NaZ23 at 1000×.</p>
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<p>σ <span class="html-italic">vs.</span> zeolite% volume content of 50:1dPPP/NaZSM-5(23) composites in air and N<sub>2</sub> at 1 atm and (28 ± 1) °C; data shown were obtained from at least two samples.</p>
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<p>The specific conductivity of dPPP(60)/NaZ23 <span class="html-italic">vs.</span> time: (a) when exposed to 5%v NH<sub>3</sub>; (b) after evacuating 5%v NH<sub>3</sub> and exposure to N<sub>2</sub>, at 28 ± 1 °C and at 1 atm.</p>
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<p>Δ<span class="html-italic">σ/σ</span><sub><span class="html-italic">N</span><sub>2</sub></sub> of 50:1dPPP <span class="html-italic">vs.</span> NH<sub>3</sub> concentration at (29 ± 1) °C and at 1 atm.</p>
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<p>Proposed interaction between 50:1 dPPP and NH<sub>3</sub>.</p>
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<p>Δ<span class="html-italic">σ</span>/<span class="html-italic">σ</span><sub><span class="html-italic">N</span><sub>2</sub></sub> of 50:1dPPP/NaZSM-5(23) composites <span class="html-italic">vs.</span> NaZSM-5(23) content when exposed to different NH<sub>3</sub> concentrations at 28 ± 1 °C and at 1 atm.</p>
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<p>Δ<span class="html-italic">σ</span>/<span class="html-italic">σ</span><sub><span class="html-italic">N</span><sub>2</sub></sub> of 50:1 dPPP and 50:1 dPPP(90)/ZSM-5(23) composites of various cation types when exposed to 0.625%v NH<sub>3</sub>, at (28 ± 1) °C and at 1 atm.</p>
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<p>FT-IR spectra of 50:1 dPPP: (A) before; (B) during; and (C) after NH<sub>3</sub> exposure at (28 ± 1) °C and at 1 atm.</p>
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661 KiB  
Article
Collaborative Distributed Scheduling Approaches for Wireless Sensor Network
by Jianjun Niu and Zhidong Deng
Sensors 2009, 9(10), 8007-8030; https://doi.org/10.3390/s91008007 - 13 Oct 2009
Cited by 4 | Viewed by 10266
Abstract
Energy constraints restrict the lifetime of wireless sensor networks (WSNs) with battery-powered nodes, which poses great challenges for their large scale application. In this paper, we propose a family of collaborative distributed scheduling approaches (CDSAs) based on the Markov process to reduce the [...] Read more.
Energy constraints restrict the lifetime of wireless sensor networks (WSNs) with battery-powered nodes, which poses great challenges for their large scale application. In this paper, we propose a family of collaborative distributed scheduling approaches (CDSAs) based on the Markov process to reduce the energy consumption of a WSN. The family of CDSAs comprises of two approaches: a one-step collaborative distributed approach and a two-step collaborative distributed approach. The approaches enable nodes to learn the behavior information of its environment collaboratively and integrate sleep scheduling with transmission scheduling to reduce the energy consumption. We analyze the adaptability and practicality features of the CDSAs. The simulation results show that the two proposed approaches can effectively reduce nodes’ energy consumption. Some other characteristics of the CDSAs like buffer occupation and packet delay are also analyzed in this paper. We evaluate CDSAs extensively on a 15-node WSN testbed. The test results show that the CDSAs conserve the energy effectively and are feasible for real WSNs. Full article
(This article belongs to the Special Issue Sensor Algorithms)
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<p>Work cycle of a node.</p>
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<p>System running process.</p>
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<p>State transition diagram of a node in O-CDSA.where I<sub>0</sub> represents the Idle state with empty buffer, Ix is the Idle state with its FIFO queue not empty, S, R and T represent the states of Sleep, Receive and Transmit respectively.</p>
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<p>State transition of child nodes.where the transition probability <span class="html-italic">v</span> is the probability of at least one of its child nodes changed to Transmit state, and <span class="html-italic">m</span> is the transition probability from state V to state M.</p>
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<p>Parameter delivery procedure in O-CDSA.</p>
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<p>State transition diagram of a node in T-CDSA.where F denotes the state of Failure, S, I<sub>0</sub>, Ix, R and T have the same meaning as mentioned earlier.</p>
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<p>Parameter delivery procedure in T-CDSA.where N<sub>1</sub> ˜ N<sub>k</sub> is the child nodes of node N<sub>m</sub>, and node N<sub>n</sub> is the parent node of node N<sub>m</sub>.</p>
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<p>The sequences of SM and SP.where the superscript represents the number of round of a node, SM<span class="html-italic"><sup>i</sup></span> is the scheduling matrix at the <span class="html-italic">i<sup>th</sup></span> round, SP<span class="html-italic"><sup>i</sup></span> is the scheduling parameters at the <span class="html-italic">i<sup>th</sup></span> round, DD<span class="html-italic"><sup>i</sup></span> and SU<span class="html-italic"><sup>i</sup></span> are the data delivery stage and scheduling update stage at the <span class="html-italic">i<sup>th</sup></span> round</p>
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<p>State transition diagram of SP of a node.where ↑ denotes a tendency to rise up at the next DD stage, ↓ denotes a decline tendency at the next DD stage and → represents the stable tendency at the next DD stage.</p>
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971 KiB  
Article
A Coupled Field Multiphysics Modeling Approach to Investigate RF MEMS Switch Failure Modes under Various Operational Conditions
by Khaled Sadek, Jonathan Lueke and Walied Moussa
Sensors 2009, 9(10), 7988-8006; https://doi.org/10.3390/s91007988 - 12 Oct 2009
Cited by 11 | Viewed by 13064
Abstract
In this paper, the reliability of capacitive shunt RF MEMS switches have been investigated using three dimensional (3D) coupled multiphysics finite element (FE) analysis. The coupled field analysis involved three consecutive multiphysics interactions. The first interaction is characterized as a two-way sequential electromagnetic [...] Read more.
In this paper, the reliability of capacitive shunt RF MEMS switches have been investigated using three dimensional (3D) coupled multiphysics finite element (FE) analysis. The coupled field analysis involved three consecutive multiphysics interactions. The first interaction is characterized as a two-way sequential electromagnetic (EM)-thermal field coupling. The second interaction represented a one-way sequential thermal-structural field coupling. The third interaction portrayed a two-way sequential structural-electrostatic field coupling. An automated substructuring algorithm was utilized to reduce the computational cost of the complicated coupled multiphysics FE analysis. The results of the substructured FE model with coupled field analysis is shown to be in good agreement with the outcome of previously published experimental and numerical studies. The current numerical results indicate that the pull-in voltage and the buckling temperature of the RF switch are functions of the microfabrication residual stress state, the switch operational frequency and the surrounding packaging temperature. Furthermore, the current results point out that by introducing proper mechanical approaches such as corrugated switches and through-holes in the switch membrane, it is possible to achieve reliable pull-in voltages, at various operating temperatures. The performed analysis also shows that by controlling the mean and gradient residual stresses, generated during microfabrication, in conjunction with the proposed mechanical approaches, the power handling capability of RF MEMS switches can be increased, at a wide range of operational frequencies. These design features of RF MEMS switches are of particular importance in applications where a high RF power (frequencies above 10 GHz) and large temperature variations are expected, such as in satellites and airplane condition monitoring. Full article
(This article belongs to the Special Issue Modeling, Testing and Reliability Issues in MEMS Engineering - 2009)
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<p>Flow chart for coupled field analysis procedure for RF MEMS switch.</p>
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<p>Corrugated RF MEMS switch.</p>
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<p>Distribution of displacement vertical component along x-coordinate predicted by coupled EM-thermal analysis followed by a coupled thermal-structural analysis for corrugated aluminum RF MEMS switch membrane (<span class="html-italic">l<sub>m</sub></span> = 91<span class="html-italic">μm, W<sub>m</sub></span> = 20<span class="html-italic">μm, t<sub>m</sub></span> = 0.4<span class="html-italic">μm, t<sub>c</sub></span> = 4<span class="html-italic">t<sub>m</sub>, N<sub>c</sub></span> = 13, <span class="html-italic">ω</span> = 20 GHz, <span class="html-italic">P</span> = 0.75 W).</p>
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<p>Substructured EM-thermal model predictions versus numerical model results reported by Jensen <span class="html-italic">et al.</span> [<a href="#b5-sensors-09-07988" class="html-bibr">5</a>] of the temperature distribution versus coordinate along beam length for fixed-fixed gold beam at frequencies of 40 MHz and 40 GHz (<span class="html-italic">l<sub>m</sub></span> = 400 <span class="html-italic">μm, W<sub>m</sub></span> = 50 <span class="html-italic">μm, t<sub>m</sub></span> = 2 <span class="html-italic">μm</span>).</p>
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<p>Substructured EM-thermal model predictions versus numerical model results and experimental data reported by Wang <span class="html-italic">et al.</span> [<a href="#b20-sensors-09-07988" class="html-bibr">20</a>] of spatially average temperature rise versus input power for fixed-fixed gold beam at frequencies of 2 GHz, 13.5 GHz and 18 GHz (<span class="html-italic">l<sub>m</sub></span> = 400 <span class="html-italic">μm, W<sub>m</sub></span> = 20 <span class="html-italic">μm, t<sub>m</sub></span> = 2 <span class="html-italic">μm</span>).</p>
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<p>Substructured structural-electrostatic model predictions versus analytical results reported by Pamidighantam <span class="html-italic">et al.</span> [<a href="#b12-sensors-09-07988" class="html-bibr">12</a>] of pull-in-voltage versus beam length for fixed-fixed gold beam at different values of microfabrication residual stresses (<span class="html-italic">W<sub>m</sub></span> = 50 <span class="html-italic">μm, t<sub>m</sub></span> = 1 <span class="html-italic">μm, g<sub>o</sub></span> = 2.5 <span class="html-italic">μm, β<sub>PI</sub></span> = 0.4, <span class="html-italic">E<sub>m</sub></span> = 77 GPa).</p>
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<p>Pull-in-voltage versus membrane length at different membrane thickness of flat aluminum RF MEMS switch (<span class="html-italic">σ<sub>M</sub></span> = <span class="html-italic">σ<sub>G</sub></span> = 0 MPa, <span class="html-italic">W<sub>m</sub></span> = 20 <span class="html-italic">μm, T(x)</span> = <span class="html-italic">T<sub>r</sub></span>).</p>
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<p>Critical buckling strain versus membrane length at different membrane thickness of flat aluminum RF MEMS switch.</p>
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<p>Temperature distribution along membrane length of flat aluminum RF MEMS switch at an operating frequency range of 0.1-100 GHz (<span class="html-italic">l<sub>m</sub></span> = 400 <span class="html-italic">μm, W<sub>m</sub></span> = 20 <span class="html-italic">μm, t<sub>m</sub></span> = 3 <span class="html-italic">μm, P</span> = 0.75 W)</p>
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1492 KiB  
Article
Micro Sensor Node for Air Pollutant Monitoring: Hardware and Software Issues
by Sukwon Choi, Nakyoung Kim, Hojung Cha and Rhan Ha
Sensors 2009, 9(10), 7970-7987; https://doi.org/10.3390/s91007970 - 12 Oct 2009
Cited by 91 | Viewed by 17898
Abstract
Wireless sensor networks equipped with various gas sensors have been actively used for air quality monitoring. Previous studies have typically explored system issues that include middleware or networking performance, but most research has barely considered the details of the hardware and software of [...] Read more.
Wireless sensor networks equipped with various gas sensors have been actively used for air quality monitoring. Previous studies have typically explored system issues that include middleware or networking performance, but most research has barely considered the details of the hardware and software of the sensor node itself. In this paper, we focus on the design and implementation of a sensor board for air pollutant monitoring applications. Several hardware and software issues are discussed to explore the possibilities of a practical WSN-based air pollution monitoring system. Through extensive experiments and evaluation, we have determined the various characteristics of the gas sensors and their practical implications for air pollutant monitoring systems. Full article
(This article belongs to the Special Issue Modeling, Testing and Reliability Issues in MEMS Engineering - 2009)
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<p>Add-on sensor board and dual power system.</p>
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<p>Sensing values with multiple nodes.</p>
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<p>Power consumption breakdown for the sensor board and the base board.</p>
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<p>Software architecture of APOLLO on RETOS.</p>
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<p>Screenshots of the host PC application. a) Single mote monitoring and sensing data logging b) Multi-mote monitoring and sensing data logging</p>
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<p>Sensing value changes over time.</p>
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<p>Response to a pollutant (tobacco smoke).</p>
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<p>Average energy consumption.</p>
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<p>Energy consumptions of each gas sensor.</p>
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522 KiB  
Article
A Label-Free Electronic Biosensor for Detection of Bone Turnover Markers
by Yeo-Heung Yun, Amit Bhattacharya, Nelson B. Watts and Mark J. Schulz
Sensors 2009, 9(10), 7957-7969; https://doi.org/10.3390/s91007957 - 12 Oct 2009
Cited by 39 | Viewed by 15243
Abstract
This paper describes the development of a biosensor based on label-free immunosensing for the detection of the C-terminal telopeptide bone turnover marker from type-1 collagen. A self-assembled monolayer (SAM) of dithiodipropionic acid was deposited on a gold electrode. Then streptavidin and biotinylated anti-human [...] Read more.
This paper describes the development of a biosensor based on label-free immunosensing for the detection of the C-terminal telopeptide bone turnover marker from type-1 collagen. A self-assembled monolayer (SAM) of dithiodipropionic acid was deposited on a gold electrode. Then streptavidin and biotinylated anti-human C-terminal telopeptide antibody were successively conjugated on the self-assembled monolayer. Electrochemical impedance measurements were made to characterize each step of the SAM/streptavidin/biotinylated antibody binding. Subsequently, electrochemical impedance was measured with different concentrations of C-teminal telopeptide. A detection limit of 50 ng/mL and a dynamic range up to 3 μg/mL were achieved. To our knowledge, this is the first attempt to develop a label-free immunosensor based on electrochemical impedance with DC bias for detection of bone-related degradation and rebuilding products. The electronic biosensor might eventually be used for quantitative point-of-care screening of bone health. It is hoped that analysis of bone turnover markers can indicate the beginning of bone diseases such as osteoarthritis and osteoporosis so that treatment might start early when it is most effective. Full article
(This article belongs to the Section Biosensors)
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<p>Schematic representation of a label-free immunosensor for bone maker detection. Part (A) shows a self-assembled monolayer of dithiodipropionic acid deposited on a gold surface with streptavidin immobilized next as a self-assembled monolayer. Then the biotinylated antibody was bound to the streptavidin. Part (B) illustrates the antigen-antibody binding event and how it hinders the interfacial electron transfer reaction of [Fe(CN)<sub>6</sub>]<sup>3−/4−</sup>.</p>
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<p>Optical picture of gold array electrodes which were patterned by a lithography technique.</p>
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<p>Electrochemical impedance spectra for a cleaned gold electrode at 0.2 V over a frequency range between 0.1 Hz and 300 kHz. The sinusoidal potential magnitude is 20 mV in 5.0 mM K<sub>3</sub>Fe(CN)<sub>6</sub> and 5.0 mM of K<sub>4</sub>Fe(CN)<sub>6</sub> in PBS (pH 7.0). The inset is an equivalent circuit model used to fit the experimental data. <span class="html-italic">C<sub>dl</sub></span>, is the double layer capacitance; <span class="html-italic">R<sub>et</sub></span>, is the electron transfer resistance; <span class="html-italic">W</span>, is Warburg impedance; and <span class="html-italic">R<sub>s</sub></span>, is the solution resistance. The final curve-fit theoretical data in curve b matched well with curve a.</p>
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<p>Three dimensional electrochemical impedance spectra of: (A) a self-assembled monolayer with carboxylic terminals on a gold electrode; and (B) a streptavidin immobilized electrode. EIS was done at DC potentials from 0 V to 0.5 V with frequencies between 0.1 Hz and 300 KHz. The sinusoidal potential magnitude was 20 mV in 5.0 mM K<sub>3</sub>Fe(CN)<sub>6</sub> and 5.0 mM of K<sub>4</sub>Fe(CN)<sub>6</sub> in PBS (pH 7.0).</p>
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<p>Electrochemical impedance spectra response recorded for the biotinylated anti-human C-terminal telopeptides antibody with the incubation time of one-half (a), one (b), two (c), four (d), and 24 hours (e). EIS was done at a DC potential of 0.2 V with frequencies between 0.1Hz and 300 KHz. The sinusoidal potential magnitude is ±20 mV in 5.0 mM K<sub>3</sub>Fe(CN)<sub>6</sub> and 5.0 mM of K<sub>4</sub>Fe(CN)<sub>6</sub> with PBS (pH 7.0).</p>
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<p>Electrochemical impedance spectra response recorded at the biotinylated anti-human C-terminal telopeptide antibody modified electrode in the presence of increasing concentration of human C-terminal telopeptide: 0 (a), 0.2 (b), 0.5 (c), 1(d), and 10 (e) μg/mL concentration of antigen. EIS was done at a DC potential of 0.2 V at frequencies between 0.1 Hz and 300 KHz. The sinusoidal potential magnitude was ±20 mV in 5.0 mM K<sub>3</sub>Fe(CN)<sub>6</sub> and 5.0 mM of K<sub>4</sub>Fe(CN)<sub>6</sub> in PBS (pH 7.0).</p>
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<p>The relationship between the change in electron transfer resistance and the concentration of <span class="html-italic">C</span>-terminal telopeptide antigen.</p>
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<p>Fluorescence image of gold electrodes; (a) a gold electrode is coated with antibody and (b) a gold electrode is coated with antibody/antigen/fluorescence dye.</p>
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<p>Cyclic voltammetry of 5.0 mM K<sub>3</sub>Fe(CN)<sub>6</sub> and 5.0 mM of K<sub>4</sub>Fe(CN)<sub>6</sub> in PBS (pH 7.0) with a 100 mV/s scan rate for: (a) the bare gold electrode; (b) the biotinylated anti-human <span class="html-italic">C</span>-terminal telopeptide antibody immobilized on the electrode after functionalizing with 3,3-dithiodipropionic acid; and (c) with 10 μg/mL human <span class="html-italic">C</span>-terminal telopeptide antigen in the solution.</p>
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1559 KiB  
Article
Vehicle Signal Analysis Using Artificial Neural Networks for a Bridge Weigh-in-Motion System
by Sungkon Kim, Jungwhee Lee, Min-Seok Park and Byung-Wan Jo
Sensors 2009, 9(10), 7943-7956; https://doi.org/10.3390/s91007943 - 12 Oct 2009
Cited by 48 | Viewed by 13864
Abstract
This paper describes the procedures for development of signal analysis algorithms using artificial neural networks for Bridge Weigh-in-Motion (B-WIM) systems. Through the analysis procedure, the extraction of information concerning heavy traffic vehicles such as weight, speed, and number of axles from the time [...] Read more.
This paper describes the procedures for development of signal analysis algorithms using artificial neural networks for Bridge Weigh-in-Motion (B-WIM) systems. Through the analysis procedure, the extraction of information concerning heavy traffic vehicles such as weight, speed, and number of axles from the time domain strain data of the B-WIM system was attempted. As one of the several possible pattern recognition techniques, an Artificial Neural Network (ANN) was employed since it could effectively include dynamic effects and bridge-vehicle interactions. A number of vehicle traveling experiments with sufficient load cases were executed on two different types of bridges, a simply supported pre-stressed concrete girder bridge and a cable-stayed bridge. Different types of WIM systems such as high-speed WIM or low-speed WIM were also utilized during the experiments for cross-checking and to validate the performance of the developed algorithms. Full article
(This article belongs to the Special Issue Neural Networks and Sensors)
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<p>(a) Geumdang Bridge site. (b) Main girders, cross beams and a concrete deck. (c) Typical section (unit: m).</p>
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<p>Seohae Bridge.</p>
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<p>Sensor disposition of Geumdang Bridge (unit: m).</p>
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<p>Sensor disposition of Seohae Bridge (unit: m).</p>
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<p>(a) Experimental test on Seohae Bridge. (b) Static weighing of test trucks for Geumdang Bridge.</p>
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<p>Representative B-WIM signals of (a) Geumdang Bridge. (b) Seohae Bridge.</p>
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<p>Geumdang Bridge random truck cases' histogram of (a) Number of axles. (b) Gross vehicle weight (GVW).</p>
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<p>Results of training of (a) Geumdang Bridge—cross beam strain. (b) Seohae Bridge—north bound 3<sup>rd</sup> lane.</p>
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<p>Results of validation test of (a) Geumdang Bridge—cross beam strain. (b) Seohae Bridge—north bound 3<sup>rd</sup> lane.</p>
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1014 KiB  
Review
Magnetic Field Sensors Based on Giant Magnetoresistance (GMR) Technology: Applications in Electrical Current Sensing
by Càndid Reig, María-Dolores Cubells-Beltrán and Diego Ramírez Muñoz
Sensors 2009, 9(10), 7919-7942; https://doi.org/10.3390/s91007919 - 12 Oct 2009
Cited by 228 | Viewed by 28512
Abstract
The 2007 Nobel Prize in Physics can be understood as a global recognition to the rapid development of the Giant Magnetoresistance (GMR), from both the physics and engineering points of view. Behind the utilization of GMR structures as read heads for massive storage [...] Read more.
The 2007 Nobel Prize in Physics can be understood as a global recognition to the rapid development of the Giant Magnetoresistance (GMR), from both the physics and engineering points of view. Behind the utilization of GMR structures as read heads for massive storage magnetic hard disks, important applications as solid state magnetic sensors have emerged. Low cost, compatibility with standard CMOS technologies and high sensitivity are common advantages of these sensors. This way, they have been successfully applied in a lot different environments. In this work, we are trying to collect the Spanish contributions to the progress of the research related to the GMR based sensors covering, among other subjects, the applications, the sensor design, the modelling and the electronic interfaces, focusing on electrical current sensing applications. Full article
(This article belongs to the Special Issue State-of-the-Art Sensors Technology in Spain)
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<p>Basic GMR structures.</p>
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<p>Different current sensor configurations as a function of the current path arrangement (<span class="html-italic">a, b, c</span> and <span class="html-italic">d</span> are the bridge contacts; <span class="html-italic">a</span> and <span class="html-italic">B</span> are the current path ends). (a) Straight path (half-bridge behavior), (b) 'U' shaped path (bridge contacts must be rearranged), (c) 'S' or serial shaped path, (d) parallel shaped path.</p>
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<p>Cross section a of a current sensor with integrated current straps. Nomenclature detailed in <a href="#f2-sensors-09-07919" class="html-fig">Figure 2</a>.</p>
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<p>Power measurement with a MR sensor. (a) Description of instantaneous power, (b) Possible configuration with a Wheatstone bridge MR sensor.</p>
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<p>IC current meters. The function scheme and nomenclature can be found in <a href="#f2-sensors-09-07919" class="html-fig">Figure 2</a>. Arrows indicate real magnetoresistor locations. (a) Spin-valve [<a href="#b45-sensors-09-07919" class="html-bibr">45</a>], (b) Magnetic tunnel junctions [<a href="#b21-sensors-09-07919" class="html-bibr">21</a>].</p>
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<p>Generalized impedance converter (GIC) as a constant current biasing of magnetoresistive sensors (see the main text for details).</p>
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<p>SPICE model of a NVE AA002 sensor and Gnucap model of a Honeywell HMC1021S sensor. Comparison with measured response.</p>
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<p>SPICE model of a NVE AA002 sensor and Gnucap model of a Honeywell HMC1021S sensor. Comparison with measured response.</p>
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<p>SPICE model of a NVE AA002 sensor and Gnucap model of a Honeywell HMC1021S sensor. Comparison with measured response.</p>
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<p>SPICE model of a NVE AA002 sensor and Gnucap model of a Honeywell HMC1021S sensor. Comparison with measured response.</p>
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<p>Finite Element Method (FEM) model of a spin-valve based IC sensor.</p>
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<p>Finite Element Method (FEM) model of a spin-valve based IC sensor.</p>
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<p>Finite Element Method (FEM) model of a spin-valve based IC sensor.</p>
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<p>Finite Element Method (FEM) model of a spin-valve based IC sensor.</p>
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355 KiB  
Article
Determination of Diclofenac on a Dysprosium Nanowire- Modified Carbon Paste Electrode Accomplished in a Flow Injection System by Advanced Filtering
by Parandis Daneshgar, Parviz Norouzi, Mohammad Reza Ganjali, Rasoul Dinarvand and Ali Akbar Moosavi-Movahedi
Sensors 2009, 9(10), 7903-7918; https://doi.org/10.3390/s91007903 - 30 Sep 2009
Cited by 45 | Viewed by 13687
Abstract
A new detection technique called Fast Fourier Transform Square-Wave Voltammetry (FFT SWV) is based on measurements of electrode admittance as a function of potential. The response of the detector (microelectrode), which is generated by a redox processes, is fast, which makes the method [...] Read more.
A new detection technique called Fast Fourier Transform Square-Wave Voltammetry (FFT SWV) is based on measurements of electrode admittance as a function of potential. The response of the detector (microelectrode), which is generated by a redox processes, is fast, which makes the method suitable for most applications involving flowing electrolytes. The carbon paste electrode was modified by nanostructures to improve sensitivity. Synthesized dysprosium nanowires provide a more effective nanotube-like surface [1-4] so they are good candidates for use as a modifier for electrochemical reactions. The redox properties of diclofenac were used for its determination in human serum and urine samples. The support electrolyte that provided a more defined and intense peak current for diclofenac determination was a 0.05 mol L−1 acetate buffer pH = 4.0. The drug presented an irreversible oxidation peak at 850 mV vs. Ag/AgCl on a modified nanowire carbon paste electrode which produced high current and reduced the oxidation potential by about 100 mV. Furthermore, the signal-to-noise ratio was significantly increased by application of a discrete Fast Fourier Transform (FFT) method, background subtraction and two-dimensional integration of the electrode response over a selected potential range and time window. To obtain the much sensivity the effective parameters such as frequency, amplitude and pH was optimized. As a result, CDL of 2.0 × 10−9 M and an LOQ of 5.0 × 10−9 M were found for the determination for diclofenac. A good recovery was obtained for assay spiked urine samples and a good quantification of diclofenac was achieved in a commercial formulation. Full article
(This article belongs to the Section Chemical Sensors)
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<p>The schematic of the flow injection analysis.</p>
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<p>TEM image of dysprosium nanowire.</p>
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<p>Diagram of the potential waveform used in measurements.</p>
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<p>The voltammograms of 5.0 × 10<sup>−7</sup> M diclofenac on the modified (a) and unmodified (b) carbon paste electrode at acetate buffer pH 4, (c) acetate buffer using NWCPE.</p>
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<p>Influence of pH on the (a) peak current and (b)peak potential for 5.0 × 10<sup>−7</sup> M in acetate buffer.</p>
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<p>Effect of the accumulation time on the peak current in the presence for diclofenac solution a) 1.0 × 10<sup>−8</sup> M and at inst figure: 5.0 × 10<sup>−7</sup> M at acetate buffer pH = 4. E<sub>acc</sub>. = 0.1 V., ƒ = 600 Hz., amplitude□ = 50 mV.</p>
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<p>The effect of frequency and amplitude (the inset figure) on the response of CPE for 5.0 × 10<sup>−7</sup> M diclofenac in 0.05 M of acetate buffer.</p>
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<p>FFT Square-Wave voltammograms at a DyNW/CPE recorded during some injection experiment. The bulk solution was 0.05 M of acetate buffer., and the frequency was 600 Hz. The injected amount of solution contained 1.0 × 10<sup>−6</sup> M diclofenac.</p>
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<p>Adsorptive square wave voltammograms obtained for the increasing concentration of diclofenac in acetate buffer (pH = 4) (a-k) at concentration (1, 0.7, 0.5, 0.3, 0.1, 0.08, 0.05, 0.03, 0.02 and 0.01 μM) respectively. Intercept: dependence of peak current on the diclofenac concentration under the optimized conditions mentioned before.</p>
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1455 KiB  
Article
Synthesis Methods, Microscopy Characterization and Device Integration of Nanoscale Metal Oxide Semiconductors for Gas Sensing
by Randy L. Vander Wal, Gordon M. Berger, Michael J. Kulis, Gary W. Hunter, Jennifer C. Xu and Laura Evans
Sensors 2009, 9(10), 7866-7902; https://doi.org/10.3390/s91007866 - 30 Sep 2009
Cited by 26 | Viewed by 15331
Abstract
A comparison is made between SnO2, ZnO, and TiO2 single-crystal nanowires and SnO2 polycrystalline nanofibers for gas sensing. Both nanostructures possess a one-dimensional morphology. Different synthesis methods are used to produce these materials: thermal evaporation-condensation (TEC), controlled oxidation, and [...] Read more.
A comparison is made between SnO2, ZnO, and TiO2 single-crystal nanowires and SnO2 polycrystalline nanofibers for gas sensing. Both nanostructures possess a one-dimensional morphology. Different synthesis methods are used to produce these materials: thermal evaporation-condensation (TEC), controlled oxidation, and electrospinning. Advantages and limitations of each technique are listed. Practical issues associated with harvesting, purification, and integration of these materials into sensing devices are detailed. For comparison to the nascent form, these sensing materials are surface coated with Pd and Pt nanoparticles. Gas sensing tests, with respect to H2, are conducted at ambient and elevated temperatures. Comparative normalized responses and time constants for the catalyst and noncatalyst systems provide a basis for identification of the superior metal-oxide nanostructure and catalyst combination. With temperature-dependent data, Arrhenius analyses are made to determine activation energies for the catalyst-assisted systems. Full article
(This article belongs to the Special Issue Gas Sensors 2009)
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<p>Schematic illustration of (a) potential barriers between nanoparticles formed by the juxtaposition of depletion layers within a polycrystalline nanofiber and (b) the continuous depletion layer surrounding the nanowire.</p>
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<p>Schematic of the experimental setup for TEC synthesis of nanowires.</p>
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<p>Schematic of the experimental setup for electrospinning synthesis of nanofibers.</p>
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<p>SEM image of (a) a single-crystal SnO<sub>2</sub> nanowire, VLS mechanism. (b) a single-crystal SnO<sub>2</sub> nanowire, VS mechanism.</p>
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<p>HRTEM image of <b>(a)</b> a single-crystal SnO<sub>2</sub> nanowire, VLS mechanism. <b>(b)</b> a single-crystal SnO<sub>2</sub> nanowire, VS mechanism.</p>
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<p>SEM image of (a) a single-crystal ZnO nanowire, lower resolution. (b) a single-crystal ZnO nanowire, higher resolution.</p>
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<p>SEM image of TiO<sub>2</sub> nanowires as grown upon Ti foil using the controlled oxidation method.</p>
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<p>HTREM image of a TiO<sub>2</sub> nanowire.</p>
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<p>Optical micrograph of electrospun nanofibers bridging across opposing electrodes.</p>
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2925 KiB  
Article
Integration of an On-Axis General Sun-Tracking Formula in the Algorithm of an Open-Loop Sun-Tracking System
by Kok-Keong Chong, Chee-Woon Wong, Fei-Lu Siaw, Tiong-Keat Yew, See-Seng Ng, Meng-Suan Liang, Yun-Seng Lim and Sing-Liong Lau
Sensors 2009, 9(10), 7849-7865; https://doi.org/10.3390/s91007849 - 30 Sep 2009
Cited by 57 | Viewed by 19387
Abstract
A novel on-axis general sun-tracking formula has been integrated in the algorithm of an open-loop sun-tracking system in order to track the sun accurately and cost effectively. Sun-tracking errors due to installation defects of the 25 m2 prototype solar concentrator have been [...] Read more.
A novel on-axis general sun-tracking formula has been integrated in the algorithm of an open-loop sun-tracking system in order to track the sun accurately and cost effectively. Sun-tracking errors due to installation defects of the 25 m2 prototype solar concentrator have been analyzed from recorded solar images with the use of a CCD camera. With the recorded data, misaligned angles from ideal azimuth-elevation axes have been determined and corrected by a straightforward changing of the parameters’ values in the general formula of the tracking algorithm to improve the tracking accuracy to 2.99 mrad, which falls below the encoder resolution limit of 4.13 mrad. Full article
(This article belongs to the Section Chemical Sensors)
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<p>The flow chart of the computational program to determine the three unknown orientation angles that cannot be precisely measured by tools in practice, i.e., <span class="html-italic">φ</span>, <span class="html-italic">λ</span> and <span class="html-italic">ζ</span>.</p>
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<p>A prototype of on-axis solar concentrator that has been constructed at Universiti Tunku Abdul Rahman (UTAR).</p>
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<p>A Windows-based control program that has been integrated with the on-axis general formula.</p>
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<p><b>(a).</b> Block diagram to show the complete open-loop feedback system of the prototype solar concentrator. <b>(b).</b> Schematic diagram to show the detail of the open-loop sun-tracking system of the prototype solar concentrator where AA' is azimuth-axis and BB' is elevation-axis.</p>
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<p>The recorded solar images on the target of prototype solar concentrator using a CCD camera from 10:07 am. to 4:25 pm. on 13 January 2009 with <span class="html-italic">φ</span>࿠= <span class="html-italic">λ</span>࿠= <span class="html-italic">ζ</span>࿠= 0°.</p>
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<p>The plot of pointing error (mrad) versus local time (hours) for the parameters, i.e.,࿠<span class="html-italic">φ</span>࿠= <span class="html-italic">λ</span>࿠= <span class="html-italic">ζ</span>࿠= 0°, on 13 January 2009.</p>
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<p>The plot of pointing error (mrad) versus local time (hours) for the parameters, i.e.,࿠<span class="html-italic">φ</span>࿠= −0.1°; <span class="html-italic">λ</span>࿠= 0°; and <span class="html-italic">ζ</span>࿠= −0.5°, on 16 January 2009.</p>
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<p>The recorded solar images on the target of prototype solar concentrator using a CCD camera from 10:25 am. to 4:54 pm. on 16 January 2009 with <span class="html-italic">φ</span>࿠= −0.1°; <span class="html-italic">λ</span>࿠= 0°; and <span class="html-italic">ζ</span>࿠= −0.5°.</p>
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624 KiB  
Article
Optimization of TiO2 and PMAPTAC Concentrations of a Chemical Humidity Sensing Mechanism
by Souhil Kouda, Zohir Dibi, Abdelghani Dendouga, Fayçal Meddour and Samir Barra
Sensors 2009, 9(10), 7837-7848; https://doi.org/10.3390/s91007837 - 30 Sep 2009
Cited by 2 | Viewed by 10460
Abstract
This work aims to achieve an optimization of the TiO2 and PMAPTAC concentrations in a chemical resistive-type humidity sensing mechanism (RHSM). Our idea is based primarily on the modeling of the sensing mechanism. This model takes into account the parameters of non-linearity, [...] Read more.
This work aims to achieve an optimization of the TiO2 and PMAPTAC concentrations in a chemical resistive-type humidity sensing mechanism (RHSM). Our idea is based primarily on the modeling of the sensing mechanism. This model takes into account the parameters of non-linearity, hysteresis, temperature, frequency, substrate type. Furthermore, we investigated the TiO2 and PMAPTAC effects concentrations on the humidity sensing properties in our model. Secondly, we used the Matlab environment to create a database for an ideal model for the sensing mechanism, where the response of this ideal model is linear for any value of the above parameters. We have done the training to create an analytical model for the sensing mechanism (SM) and the ideal model (IM). After that, the SM and IM models are established on PSPICE simulator, where the output of the first is identical to the output of the RHSM used and the output of the last is the ideal response. Finally a “DIF bloc” was realized to make the difference between the SM output and the IM output, where this difference represents the linearity error, we take the minimum error, to identify the optimal TiO2 and PMAPTAC concentrations. However, a compromise between concentrations, humidity and temperature must be performed. The simulation results show that in low humidity and at temperature more than 25 °C, sample 1 is the best (in alumina substrate). However, the sample 9 represents the best sensor (in PET substrate) predominately for the lowest humidity and temperature. Full article
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Graphical abstract

Graphical abstract
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<p><b>(a)</b> Symbolic notation of the ANN optimized model <b>(b)</b> Training program flowchart.</p>
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<p>ANN model performance for the sample 1, measured at 1 KHz at fixed temperatures 15, 25 and 35 °C.</p>
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<p>Ideal model output for sample 3 at T = 25 °C and F = 1 KHz in the humidification state.</p>
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<p><b>(a)</b> The humidity sensor electrical circuit <b>(b)</b> The measurement circuit of the sensor resistance.</p>
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<p><b>(a)</b> SM output for a parametric SWEEP analysis for sample 1–4 at fixed temperature and frequency 25 °C, 1 KHz respectively <b>(b)</b> SM output for a parametric SWEEP analysis for the sample 1 at fixed frequency 1KHz, for the temperatures 15, 25 and 35 °C <b>(c)</b> SM output for a parametric SWEEP analysis for sample 8–9 at fixed temperature and frequency 25 °C, 1 KHz respectively <b>(d)</b> SM output for a parametric SWEEP analysis for the sample 1 at fixed temperature 25 °C, for the frequencies 1, 10 and 100 KHz.</p>
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<p><b>(a)</b> SM output for a parametric SWEEP analysis for samples 1–4 at fixed temperature and frequency 25 °C and 1 KHz respectively <b>(b)</b> SM output for a parametric SWEEP analysis for the sample 1 at fixed frequency 1KHz, for the temperatures 15, 25 and 35 °C.</p>
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<p>Electrical circuit.</p>
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<p><b>(a)</b> The delivered resistances R<sub>SM</sub> and R<sub>IM</sub>, by a DC SWEEP analysis for sample 1 <b>(b)</b> The delivered resistance Rerror ‖ (Log(R(SM)-Log(IM))) ‖, by a DC SWEEP analysis for sample 1.</p>
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<p>Parametric SWEEP analysis for samples 1–4, at fixed temperature <b>(a)</b> 15 °C. <b>(b)</b> 25 °C. <b>(c)</b> 35 °C.</p>
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827 KiB  
Article
Investigation of SOI Raman Lasers for Mid-Infrared Gas Sensing
by Vittorio M. N. Passaro and Francesco De Leonardis
Sensors 2009, 9(10), 7814-7836; https://doi.org/10.3390/s91007814 - 30 Sep 2009
Cited by 19 | Viewed by 13695
Abstract
In this paper, the investigation and detailed modeling of a cascaded Raman laser, operating in the midwave infrared region, is described. The device is based on silicon-on-insulator optical waveguides and a coupled resonant microcavity. Theoretical results are compared with recent experiments, demonstrating a [...] Read more.
In this paper, the investigation and detailed modeling of a cascaded Raman laser, operating in the midwave infrared region, is described. The device is based on silicon-on-insulator optical waveguides and a coupled resonant microcavity. Theoretical results are compared with recent experiments, demonstrating a very good agreement. Design criteria are derived for cascaded Raman lasers working as continuous wave light sources to simultaneously sense two types of gases, namely C2H6 and CO2, at a moderate power level of 130 mW. Full article
(This article belongs to the Special Issue Gas Sensors 2009)
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<p>Schematic architecture of a cascaded racetrack-resonator SOI Raman laser.</p>
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<p>Cross-section of SOI waveguide.</p>
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<p>Comparison between experimental data in literature and modeling of this paper in terms of CW cascaded Raman emission versus input pump power (<span class="html-italic">λ<sub>p</sub></span> = 1.55 μm, <span class="html-italic">λ<sub>s</sub></span><sub>1</sub> = 1.686 μm, <span class="html-italic">λ<sub>s</sub></span><sub>2</sub> = 1.848 μm).</p>
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<p>Modal birefringence spectra for different values of <span class="html-italic">r</span> and <span class="html-italic">W</span>.</p>
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<p>Walk-off parameter spectra for different values of <span class="html-italic">W</span> and <span class="html-italic">r</span>.</p>
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<p>Ethane spectrum around 3.35 μm.</p>
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<p>Walk-off parameter between first-order Stokes and pump waves for different values of <span class="html-italic">H</span> and <span class="html-italic">r</span> (<span class="html-italic">λ<sub>p</sub></span> = 2.8519 μm, <span class="html-italic">λ</span><sub>s1</sub> = 3.3485 μm).</p>
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<p>Modal birefringence for pump and first-order Stokes waves versus waveguide width for different values of <span class="html-italic">H</span> (<span class="html-italic">λ<sub>p</sub></span> = 2.8519 μm, <span class="html-italic">λ<sub>s</sub></span><sub>1</sub> = 3.3485 μm).</p>
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<p>GVD and TOD coefficients versus waveguide width for pump and Stokes waves (<span class="html-italic">λ<sub>p</sub></span> = 2.8519 μm, <span class="html-italic">λ<sub>s</sub></span><sub>1</sub> = 3.3485 μm).</p>
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