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Synthesis of Hydroxyphenylpropanoid β‐ D ‐glucosides

Synthesis of Hydroxyphenylpropanoid β‐ D ‐glucosides

Journal of Wood Chemistry and Technology, 2007
Abstract
Dihydroconiferyl alcohol glucoside has been synthesized from cinnamic acid ethyl ester glucoside. Two reaction systems were investigated; one involving hydrogenation of the cinnamic acid ethyl ester glucoside intermediate followed by dii- sobutylaluminium hydride (DIBAL-H) reduction of the ester to the alcohol, and the other involving DIBAL-H reduction of the cinnamic acid ethyl ester to the alcohol (coniferin) followed by hydrogenation.

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