ABSTRACT Organic catalyst has recently been identified as the potential substitution for expensiv... more ABSTRACT Organic catalyst has recently been identified as the potential substitution for expensive platinum electrocatalyst for fuel cell application. Numerous studies have shown that the nitrogen-containing carbon nanotubes (N-CNT) can be synthesized through spray pyrolysis or floating chemical vapor deposition (CVD) technique using various type of organometallic as precursors. This paper presents the method of synthesis and the initial findings of the growth of N-CNT directly on carbon paper using a modified CVD technique. In this research, nickel (II) phthalocyanines (Ni-Pc) as precursor was dissolved in ethanol solvent, stirred and sonicated to become homogenized. The solution was poured into a bubbler and heated up to allow the mixture to vaporize. Subsequently, the solution vapor was flowed into the tubical reactor maintained at 900°C. Carbon paper sputtered with nickel nanoparticles was used as the substrate. The synthesized sample was examined through Field Emission Scanning Electron Microscopy (FESEM), Atomic Force Microscopy (AFM) and Fourier Transform Infra-Red (FTIR). Long, entangled and compartmentalized nanotubes with tube diameter ranging 23-27 nm were found covered the carbon paper surface with approximate of 5.5-6.0 μm in thickness. EDX analysis has successfully showed the presence of nitrogen in the carbon nanotube. FTIR analysis showed the presence of the C-N bond on CNT.
Chemical profiles or fingerprints of polyphenolic compounds (condensed and hydrolyzable tannins) ... more Chemical profiles or fingerprints of polyphenolic compounds (condensed and hydrolyzable tannins) in various fractions of Phyl-lanthus niruri Linn extracted using supercritical carbon dioxide and various polar cosolvents, namely water, methanol, and ethanol are presented. ...
Drying kinetics of Malaysian paddy dried in a laboratory scale batch rapid bin dryer was studied.... more Drying kinetics of Malaysian paddy dried in a laboratory scale batch rapid bin dryer was studied. Quality of paddy after drying at temperatures of 60 and 80°C, bed heights of 2 and 4 cm, and at different drying stages was presented in terms of cracking percentage. Moisture content of paddy reduced exponentially with time and became stable at equilibrium moisture content. Characteristic drying rate curves exhibited mainly falling rate period, with an induction period in deep beds, but without the constant rate period. A custom-made light box was built to visually analyze the cracking in paddy kernel. The extent of breakage is directly related to the crack percentage. The percentage of cracks increased with drying and tempering temperatures and was higher after 2 weeks of storage before milling. Bed heights did not significantly affect the head rice yield as much as tempering between two drying stages. Temperatures above 80°C caused severe cracking in paddy kernel and produced miserable yield of head rice after milling, which could be slightly improved by tempering. The use of a proper miller is also important in ensuring good head yield results and whiteness quality.
ABSTRACT Distributed parameter drying models such as the Fick's law diffusion model, unlike ... more ABSTRACT Distributed parameter drying models such as the Fick's law diffusion model, unlike the lumped parameter model of van Meel whose parameters can be easily estimated by regression, suffer from the difficulty in estimating the parameters of the models ...
A biophotovoltaic cell (BPV) is an electrobiochemical system that utilises a photosynthetic micro... more A biophotovoltaic cell (BPV) is an electrobiochemical system that utilises a photosynthetic microorganism for instance is algae to trap sunlight energy and convert it into electricity. In this study, a local algae strain, UKM2 Chlorella sp. was grown in a BPV under different trophic conditions and light wavelengths. Once the acclimatisation phase succeeded, and biofilm formed, power generation by UKM2 algae at the autotrophic mode in synthetic Bold’s Basal media (BBM) under white, blue and red lights were tested. Polarisation and power curves were generated at these different conditions to study the bioelectrochemical performance of the system. Later, the condition switched to algal mixotrophic nutritional mode, with palm oil mill effluent (POME) as substrate. Maximum power generation obtained when using UKM2 in BBM under red light where a power density of 1.19 ± 0.16 W/m3 was obtained at 25.74 ± 3.89 A/m3 current density, while the open circuit voltage OCV reached 226.08 ± 8.71 mV....
ABSTRACT Organic catalyst has recently been identified as the potential substitution for expensiv... more ABSTRACT Organic catalyst has recently been identified as the potential substitution for expensive platinum electrocatalyst for fuel cell application. Numerous studies have shown that the nitrogen-containing carbon nanotubes (N-CNT) can be synthesized through spray pyrolysis or floating chemical vapor deposition (CVD) technique using various type of organometallic as precursors. This paper presents the method of synthesis and the initial findings of the growth of N-CNT directly on carbon paper using a modified CVD technique. In this research, nickel (II) phthalocyanines (Ni-Pc) as precursor was dissolved in ethanol solvent, stirred and sonicated to become homogenized. The solution was poured into a bubbler and heated up to allow the mixture to vaporize. Subsequently, the solution vapor was flowed into the tubical reactor maintained at 900°C. Carbon paper sputtered with nickel nanoparticles was used as the substrate. The synthesized sample was examined through Field Emission Scanning Electron Microscopy (FESEM), Atomic Force Microscopy (AFM) and Fourier Transform Infra-Red (FTIR). Long, entangled and compartmentalized nanotubes with tube diameter ranging 23-27 nm were found covered the carbon paper surface with approximate of 5.5-6.0 μm in thickness. EDX analysis has successfully showed the presence of nitrogen in the carbon nanotube. FTIR analysis showed the presence of the C-N bond on CNT.
Chemical profiles or fingerprints of polyphenolic compounds (condensed and hydrolyzable tannins) ... more Chemical profiles or fingerprints of polyphenolic compounds (condensed and hydrolyzable tannins) in various fractions of Phyl-lanthus niruri Linn extracted using supercritical carbon dioxide and various polar cosolvents, namely water, methanol, and ethanol are presented. ...
Drying kinetics of Malaysian paddy dried in a laboratory scale batch rapid bin dryer was studied.... more Drying kinetics of Malaysian paddy dried in a laboratory scale batch rapid bin dryer was studied. Quality of paddy after drying at temperatures of 60 and 80°C, bed heights of 2 and 4 cm, and at different drying stages was presented in terms of cracking percentage. Moisture content of paddy reduced exponentially with time and became stable at equilibrium moisture content. Characteristic drying rate curves exhibited mainly falling rate period, with an induction period in deep beds, but without the constant rate period. A custom-made light box was built to visually analyze the cracking in paddy kernel. The extent of breakage is directly related to the crack percentage. The percentage of cracks increased with drying and tempering temperatures and was higher after 2 weeks of storage before milling. Bed heights did not significantly affect the head rice yield as much as tempering between two drying stages. Temperatures above 80°C caused severe cracking in paddy kernel and produced miserable yield of head rice after milling, which could be slightly improved by tempering. The use of a proper miller is also important in ensuring good head yield results and whiteness quality.
ABSTRACT Distributed parameter drying models such as the Fick's law diffusion model, unlike ... more ABSTRACT Distributed parameter drying models such as the Fick's law diffusion model, unlike the lumped parameter model of van Meel whose parameters can be easily estimated by regression, suffer from the difficulty in estimating the parameters of the models ...
A biophotovoltaic cell (BPV) is an electrobiochemical system that utilises a photosynthetic micro... more A biophotovoltaic cell (BPV) is an electrobiochemical system that utilises a photosynthetic microorganism for instance is algae to trap sunlight energy and convert it into electricity. In this study, a local algae strain, UKM2 Chlorella sp. was grown in a BPV under different trophic conditions and light wavelengths. Once the acclimatisation phase succeeded, and biofilm formed, power generation by UKM2 algae at the autotrophic mode in synthetic Bold’s Basal media (BBM) under white, blue and red lights were tested. Polarisation and power curves were generated at these different conditions to study the bioelectrochemical performance of the system. Later, the condition switched to algal mixotrophic nutritional mode, with palm oil mill effluent (POME) as substrate. Maximum power generation obtained when using UKM2 in BBM under red light where a power density of 1.19 ± 0.16 W/m3 was obtained at 25.74 ± 3.89 A/m3 current density, while the open circuit voltage OCV reached 226.08 ± 8.71 mV....
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